Text

Effluent & Waste Disposal Semiannual Rept 1989
	ML20006F605
Person / Time
Site:	Zion File:ZionSolutions icon.png
Issue date:	12/31/1989
From:	; COMMONWEALTH EDISON CO.
To:	; Office of Nuclear Reactor Regulation
References
	NUDOCS 9002280219
	Download: ML20006F605 (33)
	v • d • e

y Commonwoolth Edison fUnoYhaYuinhigan a

TIM 7N46-2os4 February 21, 1990 Director of Nuclear Reactor Regulation U. S. Nuclear Regulatory Comission Mail Station Pl-137 Mashington, DC 20555

Subject:

Zion Station Operating Report NRC Dockets 50-295 and 50-304 To Whom It May Concern:

Enclosed is the Radioactive Effluent Report for July through December, 1989 for Zion Nuclear Station.

A copy of this report will be furnished to the NRC Resident Inspector.

Sincerely, ia J 43 T. P. Joyce ~

(~

Station Manager Zion Station TPJ/BT/es Enclosure cc:

Distribution List i

Q22gjM[$3b

$5 R

-1427o 1

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)

DISTRIBUTION Director of Nuclear Reactor Regulation-U.S. Nuclear Regulatory Commission l

Mail Station P1-137 Washington, DC 20555 Nuclear Regulatory Commission, Region III 799 Roosevelt Road Glen Ellyn, IL 60137 Illinois Department of Nuclear Safety Office of Nuclear Facility Safety 1035 Outer Park Drive Springfield, IL 62704 4

ANI

-i Librarian I - Technical Processing The Exchange, Suite 245 270 Farmington Avenue Farmington, CT 06032 B.P.I.

Associate General Counsel 17 East Monroe St; Suite 212 Chicago, IL 60613 American Electric Power Service Corp.

Nuclear Operations Division 1 Riverside Plaza Columbus, OH 43216 U.S. Environmental Protection Agency Air and Radiation Branch, Region V Health Physicist l

230 S. Dearborn Street l

Chicago, IL 60606 L

-j Illinois Environmental Protection Agency Region III - DNPC/F05 5415 North University Peoria, IL 61614 i

1427o i

Illinois Environmental Pr;tection Agency Division of Water P:llution Control Environmental Protection Specialist 2200 Churchill Road Springfield, IL 62706 Murray & Trettel, Inc.

Environmental Meteorologist 414 West frontage Road Northfield, IL 60093 Teledyne Isotopes Midwest Laboratory General Manager 700 Landwehr Road Northbrook, IL 60062 City of North Chicago, Water Department Argonne Drive & Lewis Avenue North Chicago, IL 60064 Lake County Health Department Division of Environmental Health Environmental Control Engineer 3010 Grand Ave.

Waukegan, IL 60085 Performance Assessments Manager Suite 300 Opus III West f

Chemistry Services Chemistry Services Director Room 1237 Edison Building Emergency Preparedness Emergency Preparedness Director Room 1237 Edison Bldg.

NRC Resident Inspector Zion Station 14270

m Station Manager

+

Zion Station Chemistry Department Zion Station i

l 5

p 1427o

I ZION STATION EFFLUENT AND HASTE DISPOSAL SEMIANNUAL REPORT 1989 GASEOUS EFFLUENTS - SUMMATION OF ALL RELEASES A. Gaseous Effluents Released - Summary Sheet Third Units July August September Quarter 1.

Gross Radioactivity Releases a.

Total Release C1 2.2 E+1 5.4 E+1 6.6 E+1 1.4 E+2 b.

Max. Release Rate pCi/Hr 3.5 E+4 8.8 E+4 5.8 E+5 5.8 E+5 c.

% of Quarterly Limit 0.11-(5mRy/10mR 8)1 0.33 2.

Iodine Releases a.

Total I-131, I-133 Ci 7.9 E-5 2.5-E-4 6.7 E-4 1.0 E-3 3.

Particulate Releases a.

Gross Radioactivity Ci 1.6 E-3 8.7 E-4 2.7 E-4 2.7 E-3 b.

Gross Alpha Radioactivity:

Ci i

c.

Gross Particulate with Ci 2.6 E-4 2.4 E-4 5.6 E-5 5.6 E-4 Half Lives > 8 Days 4.

Sum of I-131 I-133 & Particulte With Half Lives Greater Than 8 Days a.

Total Ci 3.6 E 4.9 E-4 7.3 E-5 9.2 E-4 b.

% of Quarterly Limit 0.26 j

(7.5 mR Organ) i 5.

Tritium Releases l

a.

Total Release Ci 1.4 [+1 8.3 EO

-1,1 E0 2.3 E+1-1-

Noble Gas Gansna/ Beta 2-Data will be presented in an errata to the Semi-Annual Report

<LLD - No detectable activity above background 0697R 1

r ZION STATION l

EFFLUENT AND HASTE DISPOSAL SEMIANNUAL REPORT 1989 GASEOUS EFFLUENTS - VENT STACK RELEASES A. Gaseous Effluents Released - Isotopes s

Units July August September p

er 1.

Gross Radioactivity Releases Ar-41 Ci 2.0 E-2 1.2 E-2 5.6 E-1 5.9 E-1 Kr-85 (LLD 1.9 E-1 7.6 E-1 9.5 E-1 Kr-85M

<LLD (LLD (LLD (LLD

=

Kr-87 Ci

<LLD

<LLD Kr-88 (LLD

<LLD 6.2 E-1 6.2 E-1 Xe-131 Ci (LLD

<LLD

<LLD Xe-131M (LLD 8.4 E-3 3.2 E-1 3.3 E-1 Xe-133 2.1 E+1 5.1 E+1 6.3 E+1 1.4 E+2 Xe-133M dLD

<lLD 9.5 E-2 9.5 E-2 Xe-135 Ci 1.2 EO 3.2 EO 3.7 E-1 4.8 EO Xe-135M

<LLD (LLD

<LLD

<LLD j

. Xe-138 (LLD (LLD

<LLD (LLD Ci I

Ci I

I

<LLD - No detectable activity above background 0697R 2

ZION STATION e

EFFLUENT AND HASTE DISPOSAL SEMIANNUAL REPORT 1989.

GASEOUS EFFLUENTS - VENT STACK RELEASES B. Gaseous Effluents Released - Isotopes (continued)

P'l Units July August September

$r u

r er 2.

Iodine Releases Na-24 Ci 2.2 E-8 9.4_E-9 5.8 E-8 _

B.9 E-8 Mn-54

<LLD

<LLD 8.6 E-10 8.6 E-10 Co-58 C1

<LLD

<LLD 1.8 E-7 1.8 E-7 Co-60 3.5 E-9 9.7 E-9 7.7 E-9 2.1 E-8 Co-57

<LLD (LLD (LLD

<LLD Se-75 Ci

<LLD (LLD (LLD

<LLD

~

Br-82 3.0 E-6 3.0 E-6 2.5 E-6 8.5 E-6 Rb-88 (LLD (LLD

<LLD

<LLD Ci

__Bu-105

<LLD

<LLD (LLD

_ I-130 (LLD_

<LLD (LLD

<LLD Ag-110M (LLD

<LLD

<LLD Sn-113

<LLD

<LLD 4.4 E-10 4.4 E-10_

I-131 C1 2.8 E-5 1.5 E-4

'6.4 E-4 8.2 E-4 I-132 5.0 E-6 8.2 E-6 1.7 E-5 3.0 E-5 I-133 7.3 E-5 9.9 E-5 3.2 E-5 2.0 E-4 I-134 6.7 E-7 8.0 E-6 3.9 E-7 9.1 E-6 Cs-134 4.1 E-8 7.2 E-8 6.2 E-9 1.2 E-7 I-135 Ci 3.0 E-4 5.4 E-4 3.3 E-6 8.4 E-4 Ce-144 (LLD

<LLD

<LLD _ _.

Cs-136

<LLD

<LLD (LLD Cs-137 3.9 E-9 8.8 E-4 1.0 E-8 8.8 E-4 Cs-138 (LLD

<LLD 1.5 E-7 1.5 E 7

<LLD - No detectable activity above background l

0697R 3

l

' ZION STATION EFFLUENT AND HASTE DISPOSAL SEMIANNUAL REPORT 1989 CASEOUS EFFLUENTS - VENT STACK RELEASES B. Gaseous Effluents Released - Isotopes (continued) p,f0P'l 80 Units July August September 0 rt r 3.

Particulate Releases Na-24 Ci

__9.7 E-7 7.0 E-7 1.2 E-5 1.4 E-5 Mn-54

.4.8_E-9 4.9 E-8 8.6 E-8 1.4 E-7 Mn-56 1.4 E-8 5.3 E-8 4.9 E-8 f.2 E-7 Co-58 C1 1.0 E-8 2.8 E-8 8.0 E-7 8.4 E-7 r

__.Cn-60 1.4 E-8 7.0 E-6 8.3 E-7 J. 8 E-6 Ci

_ Br-82 3.8 E-9 2.1 E-8 1.4 E-8 3.9 E-8 i

Rb-88 Ci 2.3 E-4 1.9 E-4 4.6 E-5 4.7 E-4 Sr-891 Sr-901 Sr-91 Ci

<lLD 1.8 E-8 1.1 E-7 1.3 E-7

. Sr-92 (LLD (LLD -

<LLD

<LLD Nb-95 (LLD

<LLD

<LLD Ci Mo-99 4.3 E-8 2.0 E-6 1.8 E-7 2.2 E-6 Tc-99H

<LLD

<LLD (LLD

<LLD - No detectable activity above background 1 - Data will be presented in an errata to the Semi-Annual Report 4

0697R 4

1

ZION STATION EFFLUENT AND HASTE DISPOSAL SEMIANNUAL REPORT 1989 GASEOUS EFFLUENTS - VENT STACK RELEASES B. Gaseous Effluents Released - Isotopes (continued)

S tope Units July August September

[jir p,.,

gr er 3.

Farticulate Releases (continued)

Ru-103 Ci

<LLD

<LLD t

Ag-110M (LLD 3.1 E-9

<LLD

?. 3.1 E-9 l

Sb-122 Ci

<LLD (LLD'

<LLD.

<LLD Sb-124 (LLD (LLD

< lLD _ _,.,

(LLD I-131 1.5 E-7 1.1 E-6 2.2 E-7 1.5 E-6__

I-132 4.3 E-7 7.0 E-7 1.5 E-7 1.3 E-6 Te-132

<LLD

<LLD (LLD

<lLD I-133 Ci 5.2 E-7 1.2 E-6 2.6 E-7 2.0 E-6

__Cs-134 1.7 E-6 1.4 E-5 1.3 E-6 1.7 E-5 I-134 6.8 E-8 7.3 E-8 (LLD 1.4 E-7 I-135 7.1 E-7 7.5 E-7 1.3 E-7 1.6 E-6__

Cs-136 Ci (LLD 2.9 E-6 3.9 E-8 2.9 E-6 Cs-137 1.9 E-6 2.4 E-6 5.1 E-7 4.8 E-6 Cs-138 2.2 E-5 2.5 E-5 6.1-E-6 5.3 E-5 Ba-139 1.1 E-7 4.3 E-7 3.7 E-7 9.1 E-7 Ba-140 Ci 4.1 E-9 1.2 E-7 1.5 E-7 2.7 E-7 La-140 1.8 E-9 3.2 E-B 2.7 E-8 6.1 E-8 H-187 Ci 8.8 E-9 1.7 E-8 1.3 E-8 3.9 E-8 Bi-214 (LLD (LLD

<LLD

<LLD Pb-214

<LLD

<lLD

<LLD

<LLD - No detectable activity above background 0697R 5

ZION STATION EFFLUENT AND HASTE DISPOSAL SEMIANNUAL REPORT 1989 1.10U10 EFFLUENTS - SUMMATION OF ALL RELEASES UNIT 1 l

C. Liquio Effluents Released - Summary Sheet Third Units July August September Quarter 1.

Gross Radioactivity 1 a.

Total Release Ci

<LLD 2.6 E-2 1.3 E-2 3.9 E 2_

b.

Avg. Concentration pCi/mi

[

Released

<LLD 7.6 E-10 7.4 E-10 5.0 E-10

t.. Max. Concentration pCi/mi i

d.

f e h. Spec. Otr.

Limit (1.5mR/5mR)2 i

0.00 i

0.03 e.

% of Tech. Spec Yearly l

Limit (3mR/10mR):

0.01 2.

Tritium a.

Total Release Ci 6.7 E-3 1.1 E+1 7.8 E0 1.9 E+1 b.

Avg. Concentration pCi/mi Released 3.3 E-10 3.2 E-7 4.4 E-7 2.5 E-7 3.

Dissolved Noble Gases I

a.

Total Release Ci 3.9 E-5 1.8 E-2 4.7 E-2 6.5 E-2 b.

Avg. Concentration p )j,j g

Released 1.9 E-12 5.3'E 2.7 E-9 1.1 E-9 4.

Gross Alpha Radioactivity a.

Total Release Ci' 5.9 E-6 7.3 E-6 2.8 E-6 1.6 E-5 b.

Avg. Concentration Released ECi/ml 2.9 E-13 2.1 E-13 1.6 E-13 2.2 E-13 L

5.

Volume of Liquid Haste Liters 1.9 E+6 2.4 E+6 9.5 E+5 5.3 E+6 to Dhcharge 6.

Volume of Dilution Hater Liters 1.1 E+11 1.1 E+11 3.7 E+10 2.6 E+11 1 - Excludes Tritium,-Alpha, and Dissolved Noble Gases 2 - Hhole body / organ

<LLD - No detectable activity above background 0697R 6

l-

ZION STATION EFFLUENT AND HASTE DISPOSAL SEMIANNUAL REPORT 1989 LIQUID EFFLUENTS UNIT 1 D. Liquid Effluents Released - Isotopes

._p{ fop ll rhr 8

Units July August

, September _0 Na-24 Ci

<LLD

<LLD (LLD i

Cr-51 C1 (LLD

<LLD (LLD (LLD Mn-54

<LLD 4.0 E-5 1.8 E-4 2.2 E-4 Co-57

<LLD (LLD 2.0 E-5 2.0 E-5__

Co-58 (LLD 9.6 E-4 2.6 E-3 3.6 E-3 Fe-59

<LLD

.(LLD (LLD ___

Co-60 Ci

<LLD 3.3 E-3 5.5 E-3 8.8 E-3 K r-85M._

<LLD

<LLD 2.7 E-5 2.7 E-5 Kr-85 Ci (LLD

<LLD (LLD

<LLD Kr-88

<LLD (LLD

<LLQ

<LLD Rb-88

<lLD (LLD 2.1 E-4 2.1 E-4 Sr-891 Sr-901 Sr-92 (LLD

<LLD

<(LD Nb-95 Ci

<LLD

<LLD 8.7 E-4 8.7 E-4 Zr-95

<LLD

<LLD 3.4 E-4 3.4 E-4 Mo-99 (LLD

<LLD (LLD

<LLD-Tc-99M (LLD

<LLD

<LLD - No detectable activity above background 1 - Data will be presented in an errata to the Semi-Annual Report i

0697R 7

i

ZION STATION EFFLUENT AND HASTE DISPOSAL SEMIANNUAL REPORT 1989 LIQUID EFFLUENTS UNIT 1 D. Liquid Effluents Released - Isotopes (continued)

Units July August September fffer s0op[$

_ p9 g

Ci Ru-105 (LLD (LLD

<LLD

<LLD Sn-113 (LLD

<LLD (LLD (LLD Ag-110M

<tLD 2.1 E-2 1.0 E-3 2.2 E-2 Sb-122 Ci (LLD

<LLD

<LLD Sb-124

<LLD (LLD 6.6 E-5 6.6 E-5 Sb-125

<LLD 1.1 E-4 9.5 E-4 1.1 E-3 Xe-131M

<LLD 4.0 E-4 (LLD 4.0 E-4 I-131 Ci (LLD 2.3 E-5 (LLD 2.3 E-5 I-132

<LLD (LLD

<LLD

<LLD-I-133 (LLD

<LLD

<LLD Xe-133 3.9 E-5 1.7 E-2 4.6 E-2 6.3 E-2 Xe-133M Ci (LLD 2.9 E-4 4.2 E-4 7.1 E-4 Cs-134 (LLD 2.9 E-5 4.5 E-4

-4 8 E-4 I-134

<LLD (LLD (LLD

<LLD Xe-135 (LLD 3.1 E-4 1.8 E-3 2.1 E-3

_Cs-136 Ci

<LLD

<lLD

<lLD Cs-137

<LLD 5.9 E-5 7.2 E-4 7.8 E-4 Cs-138 (LLD

<LLD

__La-140 Ci

<LLD 1.5 E-4 8.8 E-S 2.4 E-4 H-187 (LLD

<LLD (LLD (LLD

<LLD - No detectable activity above-background 0697R 8

ZION STATION EFFLUENT AND NASTE DISPOSAL SEMIANNUAL REPORT 1989 LIQUID EFFLUENTS - SUMMATION OF ALL RELEASES UNIT 2 C. Liquid Effluents Released. Summary Sheet Third Units July August September Quarter

1. Gross Radioactivity 1 a.

Total Release C1 1.6 E-1 1.6 E-1 1.2E-1l4.4E-1 b.

Avg. Concentration pC1/ml 1.4 E-9 1.4 E-9 1.0 E-9 1.3 E-9 Released C'

a centration pCi/ml 9.2 E-9 7.4 E-9 9.2 E-9 9.2 E-9

0. /02 d.

% of Tech. Spec. Qtr.

Limit (1.5mR/5mR)8

/ 0.02 e.

% of Tech. Spec. Yearly 0.0 /8 Limit (3mR/10mR):

/ 0.03

2. Tritium a.

Total Release Ci 7.6 E+1 8.5 E+1 6.2 E+1 2.2 E42 b.

v centration pCi/mi 6.7 E-7 7.5 E-7 5.3 E-7' 6.5 E-7

3. Dissolved Noble Gases a.

Total Release C1 1.3 E-1 5.2 E-1 3.6 E-1 1.0 E0 b.

Y centration pCi/ml 1.2 E-9 4.6 E-9 3.1 E-9 3.0 E-9

4. Gross Alpha Radioactivity a.

Total Release Ci 4.9 E-5 6.9 E-5 3.5 E-5 1.5 E-4 b.

C centration Ci/ml 4.3 E-13 6.1 E-13 3.0 E-13 4.5 E-13 5.

id Haste Liters 1.5 E+7 1.7 E+7 2.0 E+7 5.2 E+7 charg 6.

Volume of Dilution Hater Liters 1.3 E+11 1.3 E+11 1.3 E+11 3.9 E+11 1 - Excludes Tritium, Alpha, and Dissolved Noble Gases 2 - Whole Body / Organ

<LLD - No detectable activity above background 0697R 9

ZION STATION EFFLUENT AND HASTE DISPOSAL SEMIANNUAL REPORT 1989 LIQUID EFFLUENTS UNIT 2 D. Liquid Effluents Released - Isotopes soopej Units July August September

-[f[fer p

9 Na-24 Ci

<LLD 3.2 E-5

6. 8 E-5 1.0 E-4 Ar-41 (LLD (LLD

<LLD

<LLD Cr-51 C1 1.0 E-2

<lLD 2.8 E-3 1.3 E-2 Mn-54 2.5 E-3 4.4 E-4 4.2 E-4 3.4 E-3 Co-57 2.4 E-4

<LLD 1.4 E-5 2.5 E-4 Co-58 6.5 E-2 1.1 E-2 5.2 E-2 1.3 E-1

__EE-59 1.0 E-3

<LLD 7.5 E-4 1.8 E-3 Co-60 Ci 4.7 E-2 2.2 E-2 1.3 E-2 8.2 E-2 Kr-85M

<LLD (LLD 3.6 E-5 3.6 E-5 Kr-85 Ci (LLD

<LLD

<LLD (LLD Kr-88

<LLD (LLD (LLD (LLD Sr-891 Sr-901 C1 Sr-92

<llD

<LLD (LLD

<LLD Nb-95 Ci 1.3 E-2 1.7 E-4 3.4 E-4 1.4 E-2 Zr-95 6.7 E-3 8.0 E-5 1.4 E-4 6.9 E-1__

Mo-99 4.6 E-5 1.1 E-5 4.1 E-4 4.7 E-4 Tc-99M

<LLD

<LLD (LLD (LLD - No detectable activity above background 1 - Data will be presented in an errata to the Semi-Annual Report 0697R 10

m ZION STATION EFFLUENT AND HASTE DISPOSAL SEMIANNUAL REPORT 1989 o

LIQUID EFFLUENTS UNIT 2 D. Liquid Effluents Released - Isotopes (continued)

I Units July August September fhfr,,

d 5UfP[j p

Ru-103 Ci

<LLD

<LLD 1.6 E-5 1.6 E-5 Ru-105 (LLD (LLD (LLD (LLD

, LLD 1.1 E-4 1.3 E-3 Sn-113-1.2 E-3 Sn-117M (LLD (LLD 4.3 E-4 4.3 E-4 Aa-110M 1.1 E-2 1.2 E-1 3.9 E-3 1.3 E-1 Sb-122 C1 (LLD (LLD (LLD (LLD Sb-124 2.0 E-4 2.6 E-3 7.8 E-3 1.1 E-2

__Sb-125 2.5 E-3 7.3 E-4 9.6 E-3 1.3 E-2 Sb-126.

(LLD

<LLD 7.4 E-5 7.4 E-5 Xe-131M

<LLD 2.0 E-3 3.8 E-3 5.8 E-3 Te-132

<LLD

<LLD 3.9 E-4 3.9 E-4 1-131 Ci 4.9 E-4 4.2 E-4 1.6 E-2 1.7 E-2 I-132 (LLD

<LLD 4.3 E-4 4.3 E-4 I-133

__j(.3 E-4 1.3 E-4 3.3 E-3 3.7 E-3 Xe-133 1.3 E-1 5.0 E-1 3.5 E-1 9.8 E'-1 Xe-133M Ci 8.6 E-4 1.0 E-2 2.6 E-3 1.3 E-2 Cs-134 5.5 E-4 1.4 E-3 3.1 E-3 5.1 E-3 I-134

<LLD (LLD

<LLD

<tLD I-135 (LLD (LLD

<LLD

<LLD Xe-135 2.9 E-3 1.0 E-2 7.8 E-3 2.1 E-2 Cs-136 Ci

<lLD (LLD (LLD

<LLD Cs-137 1.2 E-3 2.3 E-3 4.5 E-3 8.0 E-3 Cs-138 (LLD

<tLD (LLD

<LLD Ba-140

<LLD

<LLD-La-140 Ci 4.8 E-5 6.4 E-4 9.7 E-4 1.7 E-3 H-187 (LLD (LLD (LLD

<LLD

<LLD - No detectable activity above background 0697R 11

ZION STATION EFFLUENT AND WASTE DISPOSAL SEMIANNUAL REPORT 1989 GASEOUS EFFLUENTS - SUMMATION OF ALL RELEASES A. Gaseous Effluents Released - Summary Sheet l

Fourth Units October November December Quarter 1.

Gross Radioactivity Releases a.

Total Release C1 2.4 E0 1.2 E-1 1.6 EO 4.1 E0 b.

Max. Release Rate pC1/Hr.

0 7.7 E+2-2.4 E+5 2.4 E+5 c.

% of Quarterly Limit 0.03

[

(5mRy/10mR 0)1 0.02 2.

Iodine Releases a.

Total I-131, I-133 C1 2.7 E-4 9.6 E-6 9.6 E-6 2.9 E-4 i

3.

Particulate Releases a.

Gross Radioactivity 1.5 E-3 3.0 E-4 1.5 E-4 2.0 E-3 b.

Gross Alpha Radioactivity' C1 c.

Gross Particulate with C1 4.3 E-5 Half Lives > 8 Days 4.5 E-5 7.3 E-5 1.6 E-4 4.

Sum of I-131, I-133 & Particulate With Half Lives Greater Than 8 Days a.

Total C1 3.1 E-4 5.5 E-5 8'3 E-5 4.5 E-4 b.

% of Quarterly Limit 0.05 (7.5 mR Organ) 1 5.

Tritium Releases a.

Total Release C1 2.8 EO 8.0 E-1 1.3 EO 4.9 E0 1-Noble Gas Gamma / Beta 2-Data will be presented in an errera to the Semi-Annual Report (LLD - No detectable activity above background 12 0660R 0798A

ZION STATION EFFLUENT AND HASTE DISPOSAL SEMIANNUAL REPORT 1989 GASEOUS EFFLUENTS - VENT STACK RELEASES B.

Gaseous Effluents Released - Isotopes h0urh f5f0P[j Units October November December

,y,,

1.

Gross Radioactivity Releases Ar-41 C1 1.8 EO 6.8 E-2 9.1 E-1 2.8 E0

,,i Kr-85 (LLD (LLD 2.2 E-1 2.2 E-1 Kr-85M 2.0 E-2 1.2 E-3 1.0 E-2 3.1 E-2

__Kr-87 C1 5.0 E-2 1.2 E-3 1.0_E-2 6.1 E-2 Kr-88 F.0 E-2 1.2 E-3 3.1 E-1 3.8 E-1

-_Xe-131 C1

<LLD (LLD (LLD

<LLD-Xe-13]M

<LLD

<LLD Xe-133 9.0 E-2 2.4 E-3 3.5 E-2 1.3 E-1 Xe-133M

<LLD

<LLD 1.8 E-4 1.8 E-4 Xe-135 Ci 1.9 E-1 4.6 E-2 1.1 E-1 3.5 E-1 Xe-135M 5.0 E-2

<LLD (LLD 5.0 E-2 Xe-138 9.0 E-2 3.6 E-3 (LLD 9.4 E-2 Ci r

Ci

<LLD - No detectable activity above background 13 0660R 0798A

ZION. STATION' i

EFFLUENT AND HASTE DISPOSAL SEMIANNUAL REPORT 1989 GASEOUS EFFLUENTS - VENT STACK RELEASES B. Gaseous Effluents Released - Isotopes (continued)

$r y

Units October November December r

2.

Iodine Releases Na-24

, Ci 6.6 E-8 1.3 E-6 8.6 E-8 1-5 E-6

^

_._Co-58 Ci (LLD 5.8 E-7 1.8 E-7 7.6 E-7 Co-60 1.9 E-5 8.0 E-7 5.5 E-7 2.0 E-5 Ci

]

Br-82 1.0 E-6 1.4 E-6 1.0'E-6 3.4 E-6 Rb-88

<LLD (LLD

<LLD

<LLD-Mo-99 Ci

<LLD LD

<LLD

~ LLD

^

Aa-110M

<LLD _

.LLD

<LLD

<LLD l

I I-131 C1 2.7 E-4 9.3 E-6 4.0 E-6 2.8 E-4 I-132

<LLD (LLD 7.5 E-7 7.5 E-7 I-133 3.0 E-6 3.0 E-7 5.6 E-6 8.9 E-6 I-134 (LLD

<LLD 7.3 E-7 7.3 E-7 Cs-134

<LLD

<LLD 8.1 E-9 8.1 E-9 I-135 C1 1.9 E-8 3.9 E-8 1.1 E-6' 1.2 E,

_Ba-140

<LLD

'<LLD

<LLD l

Cs-116

<LLD

<LLD Cs-137

<LLD

<LLD 1.0 E-8 1.0 E-8 Cs-138

<LLD

<LLD i

<LLD - No detectable activity above background-I 14

-0660R 0798A i

i

ZION STATION

.g EFFLUENT AND HASTE DISPOSAL SEMIANNUAL REPORT 1989 GASEOUS EFFLUENTS - VENT STACK RELEASES

_c B. Gaseous Effluents Released - Isotopes (continued) 50f0P[l Units October November December oahr p

3.

Particulate. Releases i

Na-24 C1 1.0 E-6 2.8 E-6 1.8 E-5 2.2 E-5 Cr-51

<LLD' 3.4 E-6

<LLD 3.4 E-6 Mn-54

<LLD 1.9 E-6 3.8 E-9 1.9 E-6 Mn-56

<LLD (LLD

<LLD

<LLD I

Co-58 C1 2.1 E-6 1.4 E-5 1.6 E-7 1.6 E Co-60 3.6 E-5 2.3 E-5 2.4 E-7 5.9 E-5 Ci Br-82 (LLD

<LLD

<LLD Br-84

<LLD

<LLD (LLD Rb-88 C1

<LLD

<llIL.

6.2 E-5 6.2_E-5 Rb-89

<LLD

<LLD 2

__3r-39 Sr-90' Sr-91 Ci

<LLD

<LLD-Sr-92

<LLD

<LLD Nb-95 1.4 E-9 5.6 E-6 6.7 E-9 5.6 E-6 Zr-95 C1 (LLD 3.4 E-6 2.4 E-9 3.4 E-6 Mo-99

<LLD

<LLD 2.9 E-10 2.9 E-10 Tc-99M

<LLD

<LLD 8.3 E-8 8.3 E-8

<LLD - No detectable activity above background 1 - Data will be presente'd in an errata to the Semi-Annual Report 15 0660R 0798A

ZION STATION e.

~.

EFFLUENT AND WASTE DISPOSAL SEMIANNUAL REPORT 1989 GASEOUS EFFLUENTS - VENT STACK RELEASES B. Gaseous Effluents Released - Isotopes (continued) fsotopej Units October November December 0

r 3.

Particulate Releases (continued) i Ru-103 C1 4.6 E-8

<LLD (LLD 4.6 E-8 i

Aa-110M (LLD (LLD 1.8 E-8

'1.8 E-8 Sb-122 Ci

<LLD

{

I-131

<LLD 9.5 E-10 2.3 E-8 2.4 E-8 I-132 (LLD

<LLD 3.9 E-7 3.9 E-7 Te-132

<LLD (LLD

<LLD

<LLD I

I-133 Ci 8.0 E-9 3.0 E-8 3.7 E-7 4.1 E-7 Cs-134 1.9 E-6 2.1 E-7 1.5 E-7 2.3 E-6 I-134

<LLD

<lLD-I-135

<LLD

<LLD 5.7 E-7 5.7 E-7 Cs-136 Ci

<LLD

< L LD___.

Cs-137 2.9 E-6 5.1 E-7 1.9 E-7 3.6 E-6 Cs-138

<LLD

<LLD 9.6 E-f; 9.6 E-6 Ba-139

<LLD (LLD 3.9 E-7 3.9 E l Ba-140 Ci

<LLD

<LLD (LLD La-140 (LLD

<LLD

<LLD Ba-142

<LLD

<LLD l

H-187 Ci (LLD (LLD 2.9 E 7

-2.9 E-7 Bi-214

<LLD

<LLD Pb-214

<LLD

<LLD (LLD

<LLD i

(LLD - No detectable activity above background 16 0660R 0798A L.,

ZION STATION EFFLUENT AND HASTE DISPOSAL' SEMIANNUAL REPORT 1989 LIQUID EFFLUENTS - SUMMATION OF ALL RELEASES UNIT 1 C. Liquid Effluents Released - Summary Sheet fourth Units October November December Quarter-1.

Gross Radioactivity 1 No a.

Total Release Ci No No No p,j, b.

C centration pC1/mi Releases Releases Releases Q

er l

c.

Max. Concentration C1/ml This This.

This Released

[

O'00 d.

% of Tech. Spec. Qtr.

.j, Limit (1.5mR/5mR):

Month Month Month-0.00-0.03 e.

% of Tech. Spec. Yearly g

g g

Limit (3mR/10mR)2 l

l.

l

-0.01 2.

Tritium l

l l

l I

a.

Total Release C1 b.

Avg. Concentration Released EC1/mi 3.

Dissolved Noble Gases

~ I I

I I

i I

I I

a.

Total Release C1 b.

Avg. Concentration C1/ml Released I

I 4.

Gross Alpha Radioactivity a.

Total Release C1 b.

Avg. Concentration

'I pC1/mi Released i

i i

i I

I 5.

Volume of Liquid Haste Liters to Discharge 6.

Volume of Dilution Water Liters 1.1 E+10 2.3 E+10 4.9 E+10 8.3 E+10 1 - Excludes Tritium, Alpha, and Dissolved Noble Gases 1

2 - Whole body / organ

<LLD - No detectable activity above background 17 5

0660R 0798A j

j

ZION STATION' e -'

EFFLUENT AND HASTE DISPOSAL SEMIANNUAL REPORT 1989 LIQUID EFFLUENTS UNIT 1 D. Liquid Effluents Released - Isotopes Units October November December r

Na-24 Ci No No No No Releases Releases Releases Releases This This This This i

Ar-41 Month Month Month Ouarter l-1 I

l Cr-51 Ci i

i i

i Mn-54 I

I I

I

_Co-57 i

i i

i A SB I

I I

I Fe-59 I

I I

e i

i Fe-55 I

I I

I Co-60 Ci i

i e

i i

i l

I i

e i

i 1.

I I

i 1

Kr-85M i

i i

i I

i i

i I

Kr-85 Ci e

Kr-88 I

I I

I i

i i

Rb-88 l

i i

i i-Sr-89 I

I I

I i

I I

I l

Sr-90 Ci i

i i

i I

I I

I l

Sr-92 I

I I

I

{

H I

I l

l l

4 i

i i

i Nb-95 Ci i

I I

l' Zr-95 i

i i

i Mo-99 i

i i

I I

.I I

<LLD - No detectable activity above background 1 - Data will be presented in errata to Semi-Annual Report 18' 0660R 0798A d

ZION STATION 2

EFFLUENT AND HASTE DISPOSAL SEMIANNUAL REPORT 1989 LIQUID EFFLUENTS UNIT 1 D.

Liquid Effluents Released'- Isotopes (continued)

[f r S

Units October November December R

Ru-103 Ci No No No No RU-105 Reigases Releases Releases Releases Sn-113 This This This This Sn-117M Month Month Month

-Ouarter Aa-110M I

I I

I Sb-122 Ci i

i Sb-124 I

I I

I Sb-125 i

i l

l l

l Xe-131M i

l i

I I

I-131 Ci I-132 i

I-133 3

I I

I t

Xe-133 I

I I

I l-I Xe-133M Cl i

Cs-134 3

I I

I I-134 I-135 I

I I

l-Xe-135 i

1 i

I l

Cs-136 Ci Cs-137 Cs-138 I

I I

I j.

j i

l i

I I

a

(

La-ido Ci I

_ i i

I I

I l

1 l

H-187 l

l l

l

(

<LLD - No detectable activity above background l

l 19 0660R 0790A

ZION STATION.-

.j.

EFFLUENT AND HASTE DISPOSAL SEMIANNUAL. REPORT 1989 LIQUID EFFLUENTS - SUMMATION OF ALL RELEASES.

UNIT 2 C. Liquid Effluents Released - Summary Sheet Fourth Units October-November December Quarter

1. Gross Radioactivity 1 a.

Total Release C1 4.5'E-1 2.3 E-1 1.3 E-1 8.1 E b.

Avg. Concentration pCi/ml 3.8 E-9 1.9 E-9 1.3 E-9 2.3 E-9.

Released c.

Max. Concentration pC1/ml 1.1 E 1.5 E-8 7.8 E-9 1.5 E-8 Released d.

% of Tech. Spec Qtr.

0.03 g

Limit (1.5mR/5mR):

0.02 0.08 e.

% of Tech. Spec. Yearly Limit (3mR/10mR)a 0.11

2. Tritium i

i a.

Total Release C1 2.9 E+1 6.4 E+1

.3.9 E+1 1.3 E+2-b.

v C centration Ci/ml 2.4 E-7 5.4 E-7.

3.8 E-7 3.'9 ~' E-7

3. Dissolved Noble Gases a.

Total Release Ci 6.1 E-3 4'.9 E-3 3.7~E-3 1.5 E-2' b.

C centration pC1/ml-5.1 E-11 4.1 E 3.6 E-11

~4.3 E-11

4. Gross Alpha Radioactivity

'i i

a.

Total Release C1 1.6 E-5 1.1 E-4 9.3 E-5

-2.2 E j b.

C centration pC1/ml 1.3 E-13 9.2 E-13 9.1 E-13 6.5 E-13 5.

uld ste Liters 1.8 E+7 2.0 E+7 2.7 E+7 6.5.E+7 c rg

^

. 6.

Volume of Dilution Water Liters 1.4 E+11 8.9 E+10 1.1 E+11 3.4 E+11 l

1 - Excludes Tritium, Alpha, and Dissolved Noble Gases 4

2 - Whole Body / Organ

<LLD - No detectable activity above background 20 0660R

i~'

R ZION STATION EFFLUENT AND HASTE DISPOSAL SEMIANNUAL REPORT 1989

- a LIQUID EFFLUENTS

+

UNIT 2 D.

Liquid Effluents Released - Isotopes fsotopej Units October November December 9

O ar r Na-24 C1 1.2 E-3 1.1 E-4 8.2 E-6 1.3 E-3 Cr-51 C1 3.7 E-2 2.4 E-2 7.0 E-3 6.8 E-2 Mn-54 4.0 E-4 1.5 E-3 9.9 E-4 2.9 E-3 Co-57 1.2 E-3 8.1 E-5 2.8 E-5 1.3 E-3 Co-58 2.4 E-1 9.3 E-2 5.2 E-2 3.9 E-1 Fe-59 9.1 E-4 2.0 E-3 1.1 E-3 4.0 E-3

__Co-60 C1 3.5 E-2 4.0 E-2 1.9 E-2 9.4 E-2 Zn-65

<LLD 7.5 E-5

<LLD 7.5 E-5 Se-75

_1.6 E <LLD (LLD 1.6 E-4 Kr-85M

<LLD

<LLD Kr-85 Ci

<LLD (LLD

<LLD

<LLD Kr-88 2.6 E-4 (LLD

<LLD 2.6 E-4

_-.B b-81___

<LLD

<LLD Sr-891 Sr-901 C1 Sr-92

<LLD

<LLD Nb-95 C1 3.6 E-3 8.3 E-3 4.0 E-3 1.6 E-2

__Jr-95 1.8 E-3 4.8 E-3 2.4 E-3 9.0 E-3 Mo-99

<LLD

<LLD 9.3 E-5 9.3 E-5

<LLD - No detectable activity above background 1 - Waiting for analysis results - Data will be presented in an errata to the Semi-Annual Report 21 0660R.

i 0798A

ZION STATION EFFLUENT AND HASTE DISPOSAL SEMIANNUAL REPORT 1989 LIQUID EFFLUENTS UNIT 2 D.

Liquid Effluents Released - Isotopes h

p{ tope Units October November Cecember h e, s

g D

Ru-103 Ci 8.7 E-5 2.9 E-4

<LLD 3.8 E-4 Ru-105

.. <ll D

<LLD (LLD

<LtD Sn-113 1.2 E 1.6 E-3 6.2 E-4 3.4 E-3 Sn-117M 6.9 E-4 6 6 E-4

<LLD 1.4 E-3 1

Aa-110M 1.5 E-2 9.3 E-3 8.4 E-3 3.3 E-2 Sb-122 C1

<LLD

<LLD (LLD

<LLD Sb-124 5.1 E-2 1.8 E-2 7.9 E-3 7.7 E-2 Sb-125 4.2 E-2 1.9 E-2 1.8 E-2 7.9 E-2 Sb-126 7.4 E-5

<LLD

<LLD 7.4 E-5 Xe-131H

<LLD (LLD

<LLD

<LLD I-131 C1 5.6 E-3

<LLD 2.9 E-4 5.9 E-3 I-132

<LLD

<LLD (LLD

<LLD I-133 3.2 E <LLD 7.6 E-4 7.9 E-4 Xe-133 5.8 E-3 4.8 E-3 3.7 E-3 1.4 E-2 Xe-133M Ci (LLD

<LLD

<LLD Cs-134 3.6_E-3 4.3 E-3 3.7 E-3 1.2 E-2 1-134

<LLD

<LLD I-135

<LLD (LLD 5.5 E-5 5.5 E-5 Xe-135 8.9 E-5 7.9 E 4.5 E 2.1 E-4 Cs-136 C1

<LLD

<LLD Cs-137 6.7 E-3 6.9 E-3 5.4 E-3 1.9 E-2 Cs-138

<LLD

<LLD Ba-140

<LLD

<LLD La-140 C1 3.6 E-5 6.8 E-6 1.6 E-5 5.9 E-5 H-187

<LLD

<LLD - No detectable activity above background 22 0660R 0798A

4 ZION GENERATING STATION UNIT 1/2 Month JULY Year.

1989 SOLID RADI0 ACTIVE WASTE

-(Tech Spec 6.6.1.D.3) 8 Destination Haste Principal Container Solidification Volume Activity

LSA/

Date of Material Material Radionuclides

NON LSA Type

-Agent (ft8)

(millicuries)

(If ADolicable) 07/18/89 BARNHELL Solidified-Co-58(M) Cs-134(M)

LSA 8-120B CNSI-MIX 125.2.

690,075.76(C)

Spent Bead Ni-63(E) Cs-137(M)

Cement Resins Ca-60(M) 07/25/89 BARNHELL Dewatered Cs-137(M) Co-58(M)

LSA 14-215 N/A' 205.8 18,084.72(C)

Spent Bead Cs-134(M) Co-60(M)

Resins Fe-55(E)

MONTH TOTAL.

331.0 '/_lqLJ60.48(C)e- - -

Specify whether measured (M), estimated (E), or a combination (C).

0625R-

._.s._._

...._u..i

~..

___m.

v i

ZION GENERATING STATION UNIT 1/2

+

l Month AUGUST Year 1989 l

SOLID RADI0 ACTIVE HASTE l..

(Tech Spec 6.6.1.D.3) l Destination

-Haste Principal' Container Solidification Volume Activity

Date LSA/

I of Material Material Radionuclides

NON LSA Type Agent (fts)

(millicuries)

(If Aeolicable) 08/08/89 BARNHELL Solidified Co-60(M) Cs-134(M)

LSA 8-120A CMSI - Mix 125.2 261,825.51(C)

- Spent Bead Co-58(M) Cs-137(M)

. Cement Resins Ni-63(E) 08/09/89 BARNMELL Dewatered.

Fe-55(E) Co-60(M)

LSA 14-215-H N/A 205.8 182.02(C)

Spent Bead C-14(E) Cs-137(M) l.

Resins I-131(M) 08/29/89 BARNHELL Solidified Co-60(M) Fe-55(E)

LSA 8-1208 CNSI - Mix 125.2 60,166.67(C)

- Spent Bead-Ni-63(E) Cs-137(M)

Cement Resins' Co-58(M)

MONTH TOTAL 456.2 322.174.20(C)

' Specify whether measured (M),; estimated (E), or a combination'(C).

0625RL nm< -, =---w rav %ee. e e

.o-

-4 w

s-

~

- - - ~

p n---r p

w--

s-.e-s--*

y, g

aw m.iye m

.sfew, w

.r.

-e-w.

e.,

,y y

.r

..c,-

y w.%r - --

4 ZION GENERATING STATION UNIT 1/2 Month SEPTEMBER Year 1989 SOLID RADIOACTIVE WASTE (Tech Spec 6.6.1.D.3)

Destination Haste.

Principal Container Solidification Volume Activity

LSA/

Date of Material Material Radionuclides

NON LSA Type Agent (ft8)

(millicuries)

(If Anolicable) 09/12/89 BARNHELL Dewatered Co-58(M) Cs-137(M)

LSA 14-215 N/A 205.8 1,987.44(C)

Spend Bead Fe-55(E) Cs-134(M)

Resins' Co-60(M)'

09/25/89 BARNHELL Dewatered-Cs-137(M)-Co-58(M)

LSA 14-195 N/A

.205.8 2,019.88(C)

Spent Bead Cs-134(M) Fe-55(E)

Resins Co--60(M)

MONTH-TOTAL "411.6 4.007.32(C)

Specify-whether' measured.(M), estimated (E), or a combination (C).

0625R w

ZION GENERATING STATION UNIT 1/2 1

Month OCTOBER Year 1989 SOLID RADI0 ACTIVE WASTE (Tech Spec 6.6.1.D.3)

Destir,ation Haste Principal Container Solidification Volume Activity

Date LSA/

of Material Material Radionuclides

NON LSA Type Agent

. ft3)

(millicuries)

(

(If Anolicable) 10/24/89 "MRNHELL Dewatered Fe-55(E) Co-58(M)

LSA 14-195 N/A 205.8 14,654.07(C)

Spent Bead Co-60(M) C-14(E)

Resins N1-63(E)

' MONTH TOTAL 205.8 14.654.07(C).

Specify whether measured (M), estimated (E), or'a combination (C).

10625R

4 9

ZION GENERATING STATION UNIT 1/2 I

Month ___ NOVEMBER Year 1989 SOLID RADIOACTIVE HASTE (Tech Spec 6.6.1.D.3)

Destination Haste Principal Container Solidification Volume Activity

Date LSA/

of Material Material Radionuclices

NON LSA Type Agent (ft3)

(millicuries)

(If Aoolicable) 11/02/89 BARNHELL Solidified Cr-51(M) Sb-125(M)

LSA 8-1208 CNSIL-MIX 125.2 11,086.82(C)

Spent Bead Co-60(M) N1-63(E)

Cement Resins.

Sb-124(M) 11/14/89 BARNHELL Dewatered.

Co-58(M) C-14(E)

LSA 14-215 N/A 205.8 6,471.04(C)

Spent Bead Fe-55(E) Ni-63(E)

Resins Co-60(M) 11/15/89 BARNHELL DAH and Co-60(M) Co-58(M)

LSA 14-2151 N/A 120.3 5,156.72(C)

(Dry); Boric:

Fe-55(E) Cs-137(M)

Acid Ni-63(E) Cs-134(M) 11/30/89 BARNHELL Dewatered Fe-55(E) Cr-51(E)

NON 8-120B N/A 120.3 64,602.00(E)

' Filters Co-60(E) Cs-137(E)

LSA,

'and DAM Ni-63(E)

MONTH: TOTAL 571.6 87.316.58(C)-

~

"Specify whether measured?(M), estimated ~(E), or a comb'ination (C).

3 0625R

.u.__~_-

.. -... ~

=

..-m.

o o ZION GENERATING STATION UNIT 1/2 Month DECEMBER Year 1989 SOLID RADIOACTIVE HASTE (Tech Spec 6.6.1.D.3)

Destination Haste Principal Container Solidification Volume Activity

Date LSA/

of Material Material Radionuclides

NON LSA Type Agent (ft3)

(millicuries)

(If Anolicable) 12/05/89 BARNMELL-Dewatered Co-58(M) N1-63(E)

LSA 14-215 N/A 205.8 12,333.06(C)

Spent Bead Fe-55(E) Cs-137(M)

Resins Co-60(M) 12/08/89 BARNMELL.

Dewatered Co-58(M) Ni-63(E)1 LSA 14-195 N/A 205.8 10,591.67(C)

Spent. Bead Fe-55(E) Cs-137(M)

" Resins Co-60(M) 12/18/89 BARNMELL-Dewatered' Co-60(M) Cs-137(M)

'LSA 14-215 N/A 205.8 90.80(C)

Spent Bead Fe-55(E) C-14(E)

~ Resins-Ni-63(E) 12/19/89 BARNMELL Dewatered Co-58(M) N1-63(E)

LSA-14-195 N/A 205.8 1,557.97(C)

Spent Bead Fe-55(E)'Cs-137(M)

Resins Co-60(M) 1

. MONTH TOTAL.

823.2

__24.573.50(C)

"Specify whether measured (M), estimated'(E), or a combination (C).

0625R w,

.. ~.

_.. 2 s.

4.

ae.

r-

,;,-~,.

'9' s

o ATTACHMENT A 1

OlJu189 31Dec89 Semi-AnnualfReport Pursuant.to Zion Nuclear Generating Station, Technical _

j Specifications, Units.1 and 2, paragraph 6.6.1.D.5,.-the.

following change was made to'the Process Control Program:-

U.S. Ecology was added for the purpose of solidifying; glycol and oily' wastes.-

q v

l r

f

.h

\\

r i

+

t.

j i

k i

.

ML20006F605

Text

Subject:

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