ML19030B036
| ML19030B036 | |
| Person / Time | |
|---|---|
| Site: | Clinch River |
| Issue date: | 01/18/2019 |
| From: | James Shea Tennessee Valley Authority |
| To: | Office of New Reactors |
| Fetter A | |
| References | |
| TVACLINCHRIVERESP, TVACLINCHRIVERESP.SUBMISSION.6, CRN.P.PART08, CRN.P.PART08.2 | |
| Download: ML19030B036 (21) | |
Text
.............. LINKS............
Review your project results through TotdAccess Have a Question?
~
k The Ex ert Visit us at:
www.testa merica i nc.com Page H.2-91 of 111 Test America THE LEADER IN ENVIRONMENTAL TESTING ANALYTICAL REPORT TestAmerica Laboratories, Inc.
TestAmerica St. Louis 13715 Rider Trail North Earth City, MO 63045 Tel: (314)298-8566 TestAmerica Job ID: 160-4643-1 Client Project/Site: Clinch River For:
AMEC Environment & Infrastructure, Inc.
4021 Stirrup Creek Drive Suite 100 Durham, North Carolina 27703 Attn: Mr. Allan Tice Authorized for release by:
211712014 4:53:36 AM Ivan Vania, Project Manager II (314 )298-8566 ivan. van ia@testam ericainc. com This report has been electronically signed and authorized by the signatory. Electronic signature is intended to be the legally binding equivalent of a traditionally handwritten signature.
Results relate only to the items tested and the sample(s) as received by the laboratory.
. 4 CRP-1112.16 RCN : CRP-1208.0 Page 1 of 21 II
Client: AMEC Environment & Infrastructure, Inc.
Project/Site: Clinch River Table of Contents TestAmerica Job I D: 160-4643-1 Cover Page.............................................. 1 Table of Contents.........................................
2 Case Narrative...........................................
3 Chain of Custody.......................................... 6 Receipt Checklists......................................... 8 Definitions/Glossary.......................................
9 Method Summary.........................................
1 o Sample Summary.........................................
11 Client Sample Results...................................... 12 QC Sample Results........................................ 15 QC Association Summary................................... 20 Clinch River Data Report Rev. 4 CRP-1112.16 Page H.2-92 of 111 Page 2 of 21 RCN: CRP-1208.0 Page 2 of 21
Client: AMEC Environment & Infrastructure, Inc.
Project/Site: Clinch River Job ID: 160-4643-1 Laboratory: TestAmerica St. Louis Narrative Case Narrative CASE NARRATIVE Client: AMEC Environment & Infrastructure, Inc.
Project: Clinch River Report Number: 160-4643-1 TestAmerica Job 10: 160-4643-1 With the exceptions noted as flags or footnotes, standard analytical protocols were followed in the analysis of the samples and no problems were encountered or anomalies observed. In addition all laboratory quality control samples were within established control limits, with any exceptions noted below. Each sample was analyzed to achieve the lowest possible reporting limit within the constraints of the method. In some cases, due to interference or analytes present at high concentrations, samples were diluted. For diluted samples, the reporting limits are adjusted relative to the dilution required.
TestAmerica St. Louis attests to the validity of the laboratory data generated by TestAmerica facilities reported herein. All analyses performed by TestAmerica facilities were done using established laboratory SOPs that incorporate QA/QC procedures described in the application methods. TestAmerica's operations groups have reviewed the data for compliance with the laboratory QA/QC plan, and data have been found to be compliant with laboratory protocols unless otherwise noted below.
The test results in this report meet all NELAP requirements for parameters for which accreditation is required or available. Any exceptions to NELAP requirements are noted in this report. Pursuant to NELAP, this report may not be reproduced, except in full, without the written approval of the laboratory.
Calculations are performed before rounding to avoid round-off errors in calculated results.
All holding times were met and proper preservation noted for the methods performed on these samples, unless otherwise detailed in the individual sections below.
All solid sample results for Chemistry analyses are reported on an "as received" basis unless otherwise indicated by the presence of a %
solids value in the method header. All soil/sediment sample results for radiochemistry analyses are based upon sample as dried and disaggregated with the exception of tritium, carbon-14, and iodine-129 by gamma spectroscopy unless requested as wet weight by the client."
This laboratory report is confidential and is intended for the sole use of TestAmerica and its client.
RECEIPT The samples were received on 11 /23/2013; the samples arrived in good condition, properly preserved and on ice. The temperature of the coolers at receipt was 2.6 C.
METALS (ICPMSl Samples OW 420-L (160-4643-1 ), OW 421-L (160-4643-2), OW 202-L (160-4643-3) and DUP-1 (160-4643-4) were analyzed for Metals (ICPMS) in accordance with EPA SW-846 Methods 6020A. The samples were prepared on 12/02/2013 and analyzed on 12/07/2013 and 12/09/2013.
The presence of the '4' qualifier in the data indicates analytes where the concentration in the unspiked sample exceeded four times the spiking amount.
Preparation Batch 88861, Analytica. Batch 90379:
The following samples were diluted to bring the concentration of target analytes within the calibration range: (160-4625-3 MS),
(160-4625-3 MSD), (160-4625-3 SO), OW 202-L (160-4643-3), OW 417-L-C (160-4625-3), OW 421-L (160-4643-2). Elevated reporting Clinch River Data Report Rev. 4 CRP-1112.16 Page H.2-93 of 111 Page 3 of 21 TestAmerica St. Louis RCN: CRP-1208.0 Page 3 of 21
Client: AMEC Environment & Infrastructure, Inc.
Project/Site: Clinch River Job ID: 160-4643-1 (Continued)
Laboratory: TestAmerica St. Louis (Continued) limits (Rls) are provided.
Case Narrative TestAmerica Job 10: 160-4643-1 Due to the high concentration of calcium, the matrix spike I matrix spike duplicate (MSIMSD) could not be evaluated for accuracy and precision. (160-4625-3 MS), (160-4625-3 MSD)The associated laboratory control sample (LCS) met acceptance criteria.
Preparation Batch 88861, Analytical Batch 90921:
The following sample was diluted to bring the concentration of target analytes within the calibration range: OW 202-L (160-4643-3).
Elevated reporting limits (Rls) are provided.
No other difficulties were encountered during the metals analysis. All other quality control parameters were within the acceptance limits.
TOTAL DISSOLVED SOLIDS Samples OW 420-L (160-4643-1 ), OW 421-L (160-4643-2), OW 202-L (160-4643-3) and DUP-1 (160-4643-4) were analyzed for total dissolved solids in accordance with EPA Method 160.1. The samples were analyzed on 1112712013.
No difficulties were encountered during the TDS analysis. All quality control parameters were within the acceptance limits.
ANIONS Samples OW 420-L (160-4643-1 ), OW 421-L (160-4643-2), OW 202-L (160-4643-3) and DUP-1 (160-4643-4) were analyzed for anions in accordance with EPA Method 300.0. The samples were analyzed on 1112312013.
Batch 91006:
The following samples were diluted to bring the concentrations of Fluoride, Chloride, and Sulfate within the calibration range in IC batch 91006: OW 202-L (160-4643-3), OW 421-L (160-4643-2). Elevated reporting limits (Rls) are provided.
The matrix spike I matrix spike duplicate (MSIMSD) recoveries were outside control limits for Fluoride and Nitrite in IC batch 91006.
(160-4643-1 MS), (160-4643-1 MSD) The associated laboratory control sample (LCS) recovery met acceptance criteria, as did the recoveries for the other reported anions in this batch.
The initial calibration verification (ICV) failed low (89%) for Nitrite in IC batch 91006. The following samples in this batch were all NO for Nitrite: DUP-1 (160-4643-4), OW 202-L (160-4643-3), OW 420-L (160-4643-1 ), OW 421-L (160-4643-2). By the time this excursion was discovered, the samples were out of 2x hold for Nitrite. Thus, a reanalysis of the samples was performed on 12106113, which verified the original NO status of the samples. These samples are reported for Nitrite from the original run, with the reanalysis data provided in the data package.
No other difficulties were encountered during the anions analysis. All other quality control parameters were within the acceptance limits.
ALKALINITY Samples OW 420-L (160-4643-1 ), OW 421-L (160-4643-2), OW 202-L (160-4643-3) and DUP-1 (160-4643-4) were analyzed for alkalinity in accordance with EPA Method 31 0.1. The samples were analyzed on 1210312013.
No other difficulties were encountered during the alkalinity analysis. All other quality control parameters were within the acceptance limits.
AMMONIA Samples OW 420-L (160-4643-1 ), OW 421-L (160-4643-2), OW 202-L (160-4643-3) and DUP-1 (160-4643-4) were analyzed for ammonia in accordance with EPA Method 350.1. The samples were analyzed on 0110712014 and 1212312013.
Batch 94338:
The samples were analyzed outside of holding time, but within 2X hold: DUP-1 (160-4643-4), OW 202-L (160-4643-3), OW 420-L (160-4643-1)
The matrix spike (MS) recoveries for NH3 batch 94338 were outside control limits. Sample matrix interference is suspected because the associated laboratory control sample (LCS) recovery was within acceptance limits.
The continuing calibration verification (CCV) for analytical batch 94338 recovered outside control limits (111.6%) for NH3, due to Clinch River Data Report Rev. 4 CRP-1112.16 Page H.2-94 of 111 Page 4 of 21 TestAmerica St. Louis RCN: CRP-1208.0 Page 4 of21
Client: AMEC Environment & Infrastructure, Inc.
Project/Site: Clinch River Job ID: 160-4643-1 (Continued)
Laboratory: TestAmerica St. Louis (Continued)
Case Narrative TestAmerica Job 10: 160-4643-1 suspected matrix interference after analyzing the samples several times. The data have been qualified and reported. (160-4643-1 MS),
DUP-1 (160-4643-4), OW202-L (160-4643-3), OW420-L (160-4643-1)
The continuing calibration verification (CCV) for analytical batch 96594 recovered outside control limits (82%) for NH3, due to suspected matrix interference after analyzing the samples several times. The data have been qualified and reported. (160-4643-2 DU), (160-4643-2 MS), OW 421-L (160-4643-2)
Batch 96594:
The sample was analyzed outside of hold time, but within 2X hold: OW 421-L (160-4643-2)
No other difficulties were encountered during the ammonia analysis. All other quality control parameters were within the acceptance limits.
CATION ANION BALANCE Samples OW 420-L (160-4643-1 ), OW 421-L (160-4643-2), OW 202-L (160-4643-3) and DUP-1 (160-4643-4) were analyzed for Cation Anion Balance in accordance with Cation Anion Balance. The samples were analyzed on 12/30/2013.
No difficulties were encountered during the Cation Anion Balance analysis. All quality control parameters were within the acceptance limits.
Clinch River Data Report Rev. 4 CRP-1112.16 Page H.2-95 of 111 Page 5 of 21 TestAmerica St. Louis RCN: CRP-1208.0 Page 5 of 21
Chain of Custody No.
AMEC Environment & Infrastructure, Inc. Chain of Custody Form 1 0/
CRP-25 Prepared By: --'K==im=--=Cc=::h=ar=lc:::es:__c-S=m=it=h-~----==------
c..flq ')
Clinch River SMR Project Checked By: Kristen Lloyd
{ fd--
~ g AMEC Proiect Name (Q :::l
.I t1) n
?= ~
AMEC Project Number N -*
6468131072 Transferred From: Site
., !!l COCDate 0 c 11122/13 Transferred To: Test America
~~~~~~---------------------
-~~~
.... I>>
.... ::0 t1)
"'C 0
~
Page_l_of 2_.-+
~
(')
- 0
"'C N....
C7>
"U Q)
(Q co (j) 0 -
rv
- o 0 z
-oo
~;o CD 'U Ol~
0 1'0
_o I'VOl
~a I
SAMPLE COLLECTED BY COLLECTION IDENTIFICATION SAMPLE TYPE ORGANIZATION DATE INTENDED USE REMARKS
. cr-z OW420-L-A Water-1000 ml AMEC 11/22/13 IDS, Anions (Br Cl. F,_ S04, N03, N02)
Unpreserved I
OW 420-L-B Water-500 ml AMEC 11/22/13 Alkalinity Unpreserved 1
OW 420-L-C Water - 250 ml AMEC 11/22/13 Metals w/HN03 OW 420-L-D Water-500 ml AMEC 11/22/13 NH3 w/H2S04 OW 421-L-A Water-1000 ml AMEC 11/22/13 IDS, Anions (Br, Cl, F, S04, N03, N02)
Unpreserved OW 421-L-B Water-500 ml AMEC 11/22/13
. Alkalinity Unpreserved,
OW 421-L-C Water-250 ml AMEC 11122/13 Metals w/HN03 OW 421-L-D Water-250ml AMEC 11/22/13 NH3 w/H2S04 I
i OW202-L-A Water-I 000 ml AMEC 11/22/13 IDS, Anions (Br, Cl, F, S04, N03, N02)
Unpreserved I
OW202-L-B Water-500 ml AMEC 11/22/13 Alkalinity Unpreserved OW202-L-C Water-250 ml AMEC 11/22/13 Metals w/HN03 OW202-L-D Water-500ml AMEC 11122/13 NH3 w!H2S04 1;~qui~bv *~
I YJ.*Cr-1 y /V 1
- 1. Received by: fo~/
tl }:£1[!ime
- 2. Relinquished by:
- 2. Received by::
- 2. Dateffime f """0 (si<t:/i ~
(signature) I igt;s;-
(signature)
(signature)
- 3. Relinquished by:
>.J i (!Je;;ed~
- 3. Date/Time
- 4. Relinquished by:
- 4. Received by::
- 4. Date/Time I
1! * ;)3 *15' (signature)
(/
/A~ature) lc./.3 f.)
(signature)
(signature)
I
- 5. Relinquished by:
- 5. Received by:
- 5. Dateffime
- 6. Relinquished by:
- 6. Received by:
- 6. Date/Time I
(signature)
(signature)
(signature)
(signature)
I Work to be performed in accordance with AMEC Work Instruction 64 Remarks/FreightBiJIJTrackingNo:
F-e J f¥ \\rt._cJcp,?
86 ~ '3 J4 5 ~
~ TDJ Recipient: After signing for receipt, copy the form and forward to the AMEC Project Manager,
. Keep original form with the samples.
Final sample disposition: - ---- ------ ---- ----- ----- ----- ---- --------- ------
W1P Form o " lA (Rev 0)
{2.crv cP..f oq"f1-o II
AMEC Environment & Infrastructure, Inc. Chain of Custody Form
..,1, q __
Chain of Custody No.
~ g AMEC Project Name tO :::I t1) n CRP-25 Prepared By:....:Ki=*m:::.......::::C-=h=ar"-'l..c.::es'--S.:.om_a.c;;*th~~---===-----
Clinch River SMR Project Checked By: Kristen Lloyd ~
?= ~
AMEC Project Number N
Transferred From: Site
~~-----------------------------
6468131072
<D<
.._. ~
COCDate 11/22/13 Transferred To: Test America 0 0
-~~~
... I>>
.... ::0 t1)
"'0 0
~
~
(')
- 0
~
N "U
!l)
(Q CD 0.....,
N _.
- o
(')
z "U()
~:;o CD "U
-..,J~
oN
...,o NCXl
~o Page _2_ of_2_
SAMPLE SAMPLE TYPE COLLECTED BY COLLECTION INTENDED USE REMARKS IDENTIFICATION ORGANIZATION DATE Dup-1-A Water-1000 ml AMEC 11/22/13 TDS, Anions (Br, Cl, F S04, N03, N02)
Unpreserved Dup-1-B Water-500 m1 AMEC 11122/13 Alkalinity Unpreserved Dup-1-C Water-250 m1 AMEC 11/22/13 Metals w/HN03 Dup-1-D Water-500 m1 AMEC 11122/13 NH3 w!H2S04
- 1. Relinquished by:
~!<ive~
- 1. Date!rime
- 2. Relinquished by:
- 2. Received by::
- 2. Date!fime
/./
/1..;.13 -13 (signature) v ~~ature) lr./..JO (signature)
(signature)
- 3. Relinquished by:
- 3. Received by:
- 3. Date/Time
- 4. Relinquished by:
- 4. Received by::
- 4. Datefrime (signature)
(signature)
(signature)
(signature)
- 5. Relinquished by:
- 5. Received by:
- 5. Date!fime
- 6. Relinquished by:
- 6. Received by:
- 6. Datefrime (signature)
(signature)
(signature)
(signature) c. _
Work to be performed in accordance with AMEC Work Instruction 64 Remarks/Freight Billffracking No:
Recipient: After signing for receipt, copy the form and forward to the AMEC Project Manager,
. Keep original form with the samples.
Final sample disposition: - ---- ----- -------- ------------ --- ----- --------
WIP Form" "lA (Rev 0) pc;J cAf-oq-:r-J.o II I
Login Sample Receipt Checklist Client: AMEC Environment & Infrastructure, Inc.
Login Number: 4643 List Number: 1 Creator: Clarke, Jill C Question Radioactivity wasn't checked or is </= background as measured by a survey meter.
The cooler's custody seal, if present, is intact.
Sample custody seals, if present, are intact.
The cooler or samples do not appear to have been compromised or tampered with.
Samples were received on ice.
Cooler Temperature is acceptable.
Cooler Temperature is recorded.
COC is present.
COC is filled out in ink and legible.
COC is filled out with all pertinent information.
Is the Field Sampler's name present on COC?
There are no discrepancies between the containers received and the COC.
Samples are received within Holding Time.
Sample containers have legible labels.
Containers are not broken or leaking.
Sample collection date/times are provided.
Appropriate sample containers are used.
Sample bottles are completely filled.
Sample Preservation Verified.
There is sufficient vol. for all requested analyses, incl. any requested MS/MSDs Containers requiring zero headspace have no headspace or bubble is
<6mm (1 /4").
Multiphasic samples are not present.
Samples do not require splitting or com positing.
Residual Chlorine Checked.
TestAmerica St. Louis Clinch River Data Report Rev. 4 CRP-1112.16 Page H.2-98 of 111 Page 8 of 21 Answer True True N/A True True True True True True True False True True True True True True True True True N/A True True N/A Comment Job Number: 160-4643-1 List Source: TestAmerica St. Louis RCN: CRP-1208.0 Page 8 of 21
Client: AMEC Environment & Infrastructure, Inc.
Project/Site: Clinch River Qualifiers Metals Qualifier Qualifier Description Definitions/Glossary TestAmerica Job 10: 160-4643-1 4
MS, MSD: The analyte present in the original sample is greater than 4 times the matrix spike concentration; therefore, control limits are not applicable.
General Chemistry Qualifier Qualifier Description 4
MS, MSD: The analyte present in the original sample is greater than 4 times the matrix spike concentration; therefore, control limits are not applicable.
F H
J Glossary Abbreviation
%R CNF DER Oil Fac DL, RA, RE, IN DLC MDA EDL MDC MDL ML NC ND POL QC RER RL RPD TEF TEO ICV,CCV,ICB,CCB, ISA, ISB, CRI, CRA, DLCK or MRL standard: Instrument related QC exceeds the control limits.
MS/MSD Recovery and/or RPD exceeds the control limits Sample was prepped or analyzed beyond the specified holding time Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value.
These commonly used abbreviations may or may not be present in this report.
Listed under the "D" column to designate that the result is reported on a dry weight basis Percent Recovery Contains no Free Liquid Duplicate error ratio (normalized absolute difference)
Dilution Factor Indicates a Dilution, Re-analysis, Re-extraction, or additional Initial metals/anion analysis of the sample Decision level concentration Minimum detectable activity Estimated Detection Limit Minimum detectable concentration Method Detection Limit Minimum Level (Dioxin)
Not Calculated Not detected at the reporting limit (or MDL or EDL if shown)
Practical Quantitation Limit Quality Control Relative error ratio Reporting Limit or Requested Limit (Radiochemistry)
Relative Percent Difference, a measure of the relative difference between two points Toxicity Equivalent Factor (Dioxin)
Toxicity Equivalent Quotient (Dioxin)
Clinch River Data Report Rev. 4 CRP-1112.16 Page H.2-99 of 111 Page 9 of 21 TestAmerica St. Louis RCN: CRP-1208.0 Page 9 of 21
Client: AMEC Environment & Infrastructure, Inc.
Project/Site: Clinch River Method 6020A 160.1 300.0 310.1 350.1 SM 1030F Method Description Metals (ICP/MS)
Solids, Total Dissolved (TDS)
Anions, ion Chromatography Alkalinity Nitrogen, Ammonia Cation Anion Balance Protocol
References:
Method Summary TestAmerica Job 10: 160-4643-1 Protocol Laboratory SW846 TAL SL MCAWJV TAL SL MCAWJV TAL SL MCAWJV TAL SL MCAWJV TAL SL SM TAL SL MCAWW ="Methods For Chemical Analysis Of Water And Wastes", EPA-600/4-79-020, March 1983 And Subsequent Revisions.
SM = "Standard Methods For The Examination Of Water And Wastewater",
SW846 ="Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates.
Laboratory
References:
TAL SL = TestAmerica St. Louis, 13715 Rider Trail North, Earth City, MO 63045, TEL (314)298-8566 Clinch River Data Report Rev. 4 CRP-1112.16 Page H.2-100 of 111 Page 10 of21 TestAmerica St. Louis RCN: CRP-1208.0 Page 10 of21 II
Client: AMEC Environment & Infrastructure, Inc.
Project/Site: Clinch River Lab Sample ID Client Sample ID 160-4643-1 160-4643-2 160-4643-3 160-4643-4 OW420-L OW421-L OW202-L DUP-1 Clinch River Data Report Rev. 4 CRP-1112.16 Page H.2-101 of 111 Sample Summary Page 11 of 21 Matrix Water Water Water Water TestAmerica Job 10: 160-4643-1 Collected Received 11/22/13 00:00 11/23/13 14:30 11/22/13 00:00 11/23/13 14:30 11/22/13 00:00 11/23/13 14:30 11/22/13 00:00 11/23/13 14:30 TestAmerica St. Louis RCN: CRP-1208.0 Page 11 of 21 El
Client Sample Results Client: AMEC Environment & Infrastructure, Inc.
Project/Site: Clinch River Client Sample ID: OW 420-L Date Collected: 11/22/13 00:00 Date Received: 11/23/13 14:30 Method: 6020A-Metals (ICP/MS)
Analyte Calcium Iron Potassium Magnesium Manganese Sodium Silicon Si02, Silica General Chemistry Analyte Total Anions Total Cations Anion/Cation Balance Percent Difference Analyte Total Dissolved Solids (TDS)
Nitrate as N Nitrite as N Fluoride Chloride Bromide Sulfate Alkalinity Bicarbonate Alkalinity as CaC03 Carbonate Alkalinity as CaC03 Ammonia Client Sample ID: OW 421-L Date Collected: 11/22/13 00:00 Date Received: 11/23/13 14:30 Method: 6020A-Metals (ICP/MS)
Analyte Calcium Iron Potassium Magnesium Manganese Sodium Silicon Si02, Silica General Chemistry Analyte Total Anions Total Cations Anion/Cation Balance Percent Difference Result Qualifier 59000 250 1800 26000 33 1200 4200 9000 Result Qualifier 5.0 5.2 2.1 2.1 Result Qualifier 270 0.36 ND A
0.31 2.1 ND 14 230 230 ND 110 H A Result Qualifier 38000 230 12000 27000 10 12000 6000 13000 Result Qualifier 4.6 5.0 3.9 3.9 Clinch River Data Report Rev. 4 CRP-1112.16 Page H.2-102 of 111 RL 100 50 100 50 2.0 50 250 540 NONE RL 5.0 0.020 0.020 0.10 0.20 0.25 0.50 5.0 5.0 5.0 50 RL 100 50 100 50 2.0 50 1300 2700 NONE MDL Unit
~6=8 -ug~/L~-----
20 ug/L 42 ug/L 5.6 ug/L 0.25 ug/L 15 ug/L 18 ug/L 38 ug/L NONE Unit
-m-eq~/:-L -----
meq/L MDL Unit
~3~.5 -m-g/~L------
0.0040 mg/L 0.0030 mg/L 0.010 mg/L 0.020 mg/L 0.025 mg/L 0.050 mg/L 0.54 mg/L 0.54 mg/L 0.54 mg/L 9.2 ug/L MDL Unit
~6=8 -ug~/L~-----
20 ug/L 42 ug/L 5.6 ug/L 0.25 ug/L 15 ug/L 89 ug/L 190 ug/L NONE Unit
-m-eq~/:-L -----
meq/L Page 12 of21 TestAmerica Job 10: 160-4643-1 Lab Sample ID: 160-4643-1 Matrix: Water D
Prepared Analyzed Oil Fac D
D 12/02/1315:52 12/07/13 21:39 12/02/1315:52 12/07/13 21:39 12/02/1315:52 12/07/13 21:39 12/02/1315:52 12/07/13 21:39 12/02/1315:52 12/07/13 21:39 12/02/1315:52 12/07/13 21:39 12/02/1315:52 12/07/13 21:39 12/02/1315:52 12/07/13 21:39 Prepared Prepared Analyzed 12/30/13 06:51 12/30/13 06:51 12/30/13 06:51 12/30/13 06:51 Analyzed 11127/13 11:00 11123/13 15:51 11123/13 15:51 11123/13 15:51 11123/13 15:51 11123/13 15:51 11123/13 15:51 12/03/13 10:59 12/03/13 10:59 12/03/13 10:59 12/23/13 18:20 Oil Fac Oil Fac Lab Sample ID: 160-4643-2 Matrix: Water D
Prepared Analyzed Oil Fac D
12/02/1315:52 12/07/13 21:46 12/02/1315:52 12/07/13 21:46 12/02/1315:52 12/07/13 21:46 12/02/1315:52 12/07/13 21:46 12/02/1315:52 12/07/13 21:46 12/02/1315:52 12/07/13 21:46 12/02/13 15:52 12/07/13 22:13 12/02/13 15:52 12/07/13 22:13 Prepared Analyzed 12/30/13 06:51 12/30/13 06:51 12/30/13 06:51 12/30/13 06:51 5
5 Oil Fac TestAmerica St. Louis RCN: CRP-1208.0 Page 12 of21
Client Sample Results Client: AMEC Environment & Infrastructure, Inc.
Project/Site: Clinch River Client Sample ID: OW 421-L Date Collected: 11/22/13 00:00 Date Received: 11/23/13 14:30 Analyte Total Dissolved Solids (TDS)
Nitrite as N Fluoride Chloride Bromide Sulfate Alkalinity Bicarbonate Alkalinity as CaC03 Carbonate Alkalinity as CaC03 Ammonia
[
General Chemistry - DL Analyte Nitrate as N Client Sample ID: OW 202-L Date Collected: 11/22/13 00:00 Date Received: 11/23/13 14:30 Method: 6020A-Metals (ICP/MS)
Analyte Calcium Iron Potassium Magnesium Manganese Sodium Silicon Si02, Silica General Chemistry Analyte Total Anions Total Cations Anion/Cation Balance Percent Difference Analyte Total Dissolved Solids (TDS)
Nitrate as N Nitrite as N Bromide Alkalinity Bicarbonate Alkalinity as CaC03 Carbonate Alkalinity as CaC03 Ammonia General Chemistry - DL Analyte Fluoride Chloride Sulfate Result Qualifier 230 ND A
0.58 2.6 ND 8.3 210 210 ND ND H A Result Qualifier 1.6 Result Qualifier 23000 19000 14000 9900 160 280000 82000 170000 Result Qualifier 17 16
-3.2
-3.2 Result Qualifier 1100 0.028 ND A
0.17 J 680 600 78 580 H A Result Qualifier 7.4 24 93 Clinch River Data Report Rev. 4 CRP-1112.16 Page H.2-103 of 111 RL 5.0 0.020 0.10 0.20 0.25 0.50 5.0 5.0 5.0 50 RL 0.40 RL 100 50 100 50 2.0 250 13000 27000 NONE RL 5.0 0.020 0.020 0.25 5.0 5.0 5.0 50 RL 2.0 4.0 10 MDL Unit 3.5 mg/L 0.0030 mg/L 0.010 mg/L 0.020 mg/L 0.025 mg/L 0.050 mg/L 0.54 mg/L 0.54 mg/L 0.54 mg/L 9.2 ug/L MDL Unit
~o~.0~8=o -m-g/~L------
MDL Unit
~6=8 -ug~/L~-----
20 ug/L 42 ug/L 5.6 ug/L 0.25 ug/L 75 ug/L 890 ug/L 1900 ug/L NONE Unit
-m-eq~/:-L -----
meq/L MDL Unit
~3~.5 -m-g/~L------
0.0040 mg/L 0.0030 mg/L 0.025 mg/L 0.54 mg/L 0.54 mg/L 0.54 mg/L 9.2 ug/L MDL Unit
~0~.2~0 -m-g/~L------
0.40 mg/L 1.0 mg/L Page 13 of21 D
D TestAmerica Job 10: 160-4643-1 Lab Sample ID: 160-4643-2 Matrix: Water Prepared Prepared Analyzed 11127/13 11:00 11123/13 18:20 11123/13 18:20 11123/13 18:20 11123/13 18:20 11123/13 18:20 12/03/13 10:59 12/03/13 10:59 12/03/13 10:59 01107/14 14:29 Analyzed 11123/13 18:35 Oil Fac Oil Fac 20 Lab Sample ID: 160-4643-3 Matrix: Water D
Prepared Analyzed Oil Fac D
D D
12/02/1315:52 12/07/13 21:52 12/02/1315:52 12/07/13 21:52 12/02/1315:52 12/07/13 21:52 12/02/1315:52 12/07/13 21:52 12/02/1315:52 12/07/13 21:52 12/02/13 15:52 12/07/13 22:33 12/02/13 15:52 12/09/13 20:01 12/02/13 15:52 12/09/13 20:01 Prepared Prepared Prepared Analyzed 12/30/13 06:51 12/30/13 06:51 12/30/13 06:51 12/30/13 06:51 Analyzed 11127/13 11:00 11123/13 18:50 11123/13 18:50 11123/13 18:50 12/03/13 10:59 12/03/13 10:59 12/03/13 10:59 12/23/13 18:23 Analyzed 11123/13 19:05 11123/13 19:05 11123/13 19:05 5
50 50 Oil Fac Oil Fac Oil Fac 20 20 20 TestAmerica St. Louis RCN: CRP-1208.0 Page 13 of21
Client Sample Results Client: AMEC Environment & Infrastructure, Inc.
Project/Site: Clinch River Client Sample ID: DUP-1 Date Collected: 11/22/13 00:00 Date Received: 11/23/13 14:30 Method: 6020A-Metals (ICP/MS)
Analyte Result Qualifier Calcium 59000 Iron 290 Potassium 1900 Magnesium 26000 Manganese 32 Sodium 1300 Silicon 4400 Si02, Silica 9400 General Chemistry Analyte Result Qualifier Total Anions 5.2 Total Cations 5.2 Anion/Cation Balance
-0.019 Percent Difference
-0.019 Analyte Result Qualifier Total Dissolved Solids (TDS) 280 Nitrate as N 0.25 Nitrite as N ND A
Fluoride 0.35 Chloride 2.6 Bromide ND Sulfate 15 Alkalinity 240 Bicarbonate Alkalinity as CaC03 240 Carbonate Alkalinity as CaC03 ND Ammonia 140 HA Clinch River Data Report Rev. 4 CRP-1112.16 Page H.2-104 of 111 RL MDL 100 68 50 20 100 42 50 5.6 2.0 0.25 50 15 250 18 540 38 NONE NONE RL MDL 5.0 3.5 0.020 0.0040 0.020 0.0030 0.10 0.010 0.20 0.020 0.25 0.025 0.50 0.050 5.0 0.54 5.0 0.54 5.0 0.54 50 9.2 Page 14 of21 Unit D
ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L Unit D
meq/L meq/L Unit D
mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L ug/L TestAmerica Job 10: 160-4643-1 Lab Sample ID: 160-4643-4 Matrix: Water Prepared Analyzed Oil Fac 12/02/13 15:52 12/07/13 21:59 12/02/13 15:52 12/07/13 21:59 12/02/13 15:52 12/07/13 21:59 12/02/13 15:52 12/07/13 21:59 12/02/13 15:52 12/07/13 21:59 12/02/13 15:52 12/07/13 21:59 12/02/13 15:52 12/07/13 21:59 12/02/13 15:52 12/07/13 21:59 Prepared Analyzed Oil Fac 12/30/13 06:51 12/30/13 06:51 12/30/13 06:51 12/30/13 06:51 Prepared Analyzed Oil Fac 11127/13 11:00 11123/13 17:20 11123/13 17:20 11123/13 17:20 11123/13 17:20 11123/13 17:20 11123/13 17:20 12/03/13 11 :00 12/03/13 11 :00 12/03/13 11 :00 12/23/13 18:25 TestAmerica St. Louis RCN: CRP-1208.0 Page 14 of21 D
QC Sample Results Client: AMEC Environment & Infrastructure, Inc.
Project/Site: Clinch River Method: 6020A-Metals (ICP/MS)
Lab Sample ID: MB 160-88861/1-A Matrix: Water Analysis Batch: 90379 MB MB Analyte Result Qualifier
~C-a~lc~iu_m______________________ ------~N=o Iron ND Potassium ND Magnesium ND Manganese ND Sodium ND Silicon ND Si02, Silica ND Lab Sample ID: LCS 160-88861/2-A Matrix: Water Analysis Batch: 90379 Analyte Calcium Iron Potassium Magnesium Manganese Sodium Silicon Lab Sample ID: 160-4625-A-3-B MS Matrix: Water Analysis Batch: 90379 Sample Sample Analyte Result Qualifier
~C-a~lc~iu_m ___________________
~6~10~0~0 Iron 41 J
Potassium 3400 Magnesium 31000 Manganese 21 Sodium 22000 Lab Sample ID: 160-4625-A-3-B MS Matrix: Water Analysis Batch: 90379 Analyte Sample Sample Result Qualifier Silicon Lab Sample ID: 160-4625-A-3-C MSD Matrix: Water Analysis Batch: 90379 6100 Sample Sample Analyte Result Qualifier Spike Added 10000 10000 10000 10000 1000 10000 5000 Spike Added 10000 10000 10000 10000 1000 10000 Spike Added 5000 Spike Added RL 100 50 100 50 2.0 50 250 540 MDL Unit
~6~8 -ug~/L~-----
20 ug/L 42 ug/L 5.6 ug/L 0.25 ug/L 15 ug/L 18 ug/L 38 ug/L LCS LCS Result Qualifier Unit 10500 9560 9740 9950 968 9770 4590 MS MS ug/L ug/L ug/L ug/L ug/L ug/L ug/L Result Qualifier Unit 72900 4 10100 13700 41900 1040 32500 MS MS ug/L ug/L ug/L ug/L ug/L ug/L Result Qualifier Unit 11300 ug/L MSD MSD Result Qualifier Unit TestAmerica Job 10: 160-4643-1 Client Sample ID: Method Blank Prep Type: Totai/NA Prep Batch: 88861 D
Prepared Analyzed Oil Fac 12/02/13 15:52 12/07/13 19:51 12/02/13 15:52 12/07/13 19:51 12/02/13 15:52 12/07/13 19:51 12/02/13 15:52 12/07/13 19:51 12/02/13 15:52 12/07/13 19:51 12/02/13 15:52 12/07/13 19:51 12/02/13 15:52 12/07/13 19:51 12/02/13 15:52 12/07/13 19:51 Client Sample ID: Lab Control Sample Prep Type: Totai/NA Prep Batch: 88861
%Rec.
D
%Rec 105 96 97 99 97 98 92 Limits80-120 80-120 80-120 80-120 80-120 80-120 80-120 Client Sample ID: Matrix Spike Prep Type: Totai/NA Prep Batch: 88861
%Rec.
D
%Rec 120 100 102 110 102 108 Limits75-125 75-125 75-125 75-125 75-125 75-125 Client Sample ID: Matrix Spike Prep Type: Totai/NA Prep Batch: 88861
%Rec.
D
%Rec Limits 105 Client Sample ID: Matrix Spike Duplicate Prep Type: Totai/NA Prep Batch: 88861
%Rec.
RPD D
%Rec Limits RPD Limit
~C~a~lc~iu_m ___________________
~6~10~0~0 10000 10000 10000
~7~38~0~0 4
-ug~/~L-----
129 75-125 1
20 Iron 41 J
Potassium 3400 Clinch River Data Report Rev. 4 CRP-1112.16 Page H.2-105 of 111 9730 13300 Page 15 of21 ug/L ug/L 97 98 3
3 20 20 TestAmerica St. Louis RCN: CRP-1208.0 Page 15 of21 I
QC Sample Results Client: AMEC Environment & Infrastructure, Inc.
Project/Site: Clinch River Method: 6020A-Metals (ICP/MS) (Continued)
Lab Sample ID: 160-4625-A-3-C MSD Matrix: Water Analysis Batch: 90379 Sample Sample Analyte Result Qualifier Magnesium 31000 Manganese 21 Sodium 22000 Lab Sample ID: 160-4625-A-3-C MSD Matrix: Water Analysis Batch: 90379 Sample Sample Analyte Result Qualifier Silicon 6100 Method: 160.1 -Solids, Total Dissolved (TDS)
Lab Sample ID: MB 160-87715/1 Matrix: Water Analysis Batch: 87715 MB MB Analyte Result Qualifier
=T~ot~ai~D~is-s~ol~ve-d~S~o~lid~s~(=To~S~)---------
~N=o Lab Sample ID: LCS 160-87715/2 Matrix: Water Analysis Batch: 87715 Analyte Total Dissolved Solids (TDS)
Lab Sample ID: 160-4600-A-9 DU Matrix: Water Analysis Batch: 87715 Sample Sample Analyte Result Qualifier
=T~ot~ai~D~is-s~o1~ve-d~S~o~lid~s~(=TD~S~)-----
~2~9~0 Method: 300.0- Anions, lon Chromatography Lab Sample ID: MB 160-91006/9 Matrix: Water Analysis Batch: 91006 Analyte Nitrate as N Nitrite as N Fluoride Chloride Bromide Sulfate MB MB Result Qualifier ND ND A
ND ND ND ND Clinch River Data Report Rev. 4 CRP-1112.16 Page H.2-106 of 111 Spike Added 10000 1000 10000 Spike Added 5000 RL 5.0 Spike Added 500 RL 0.020 0.020 0.10 0.20 0.25 0.50 MSD MSD Result Qualifier Unit 41000 ug/L 1010 ug/L 31700 ug/L MSD MSD Result Qualifier Unit 11200 ug/L MDL Unit
~3~.5 -m-g/~L------
LCS LCS Result Qualifier Unit 486 mg/L DU DU Result Qualifier Unit 287 mg/L MDL Unit 0.0040 mg/L 0.0030 mg/L 0.010 mg/L 0.020 mg/L 0.025 mg/L 0.050 mg/L Page 16 of21 TestAmerica Job 10: 160-4643-1 Client Sample ID: Matrix Spike Duplicate Prep Type: Totai/NA Prep Batch: 88861 0/oRec.
RPD D
%Rec Limits RPD Limit 101 75-125 2
20 99 75-125 3
20 100 75-125 2
20 Client Sample ID: Matrix Spike Duplicate D
D D
Prep Type: Totai/NA Prep Batch: 88861
%Rec.
RPD
%Rec Limits RPD Limit 103 75-125 1
20 Client Sample ID: Method Blank Prep Type: Totai/NA Prepared Analyzed Oil Fac 11127/1311:00 1
Client Sample ID: Lab Control Sample D
D Prep Type: Totai/NA
%Rec.
%Rec Limits 97 90- 110 Client Sample ID: Duplicate Prep Type: Totai/NA RPD RPD Limit 1
20 Client Sample ID: Method Blank Prep Type: Totai/NA Prepared Analyzed Oil Fac 11123/1315:21 1
11123/1315:21 11123/1315:21 11123/1315:21 11123/1315:21 11123/1315:21 TestAmerica St. Louis RCN: CRP-1208.0 Page 16 of21 I
QC Sample Results Client: AMEC Environment & Infrastructure, Inc.
Project/Site: Clinch River Method: 300.0- Anions, lon Chromatography (Continued)
Lab Sample ID: LCS 160-91006/10 Matrix: Water Analysis Batch: 91006 Analyte Nitrate as N Nitrite as N Fluoride Chloride Bromide Sulfate Lab Sample ID: 160-4643-1 MS Matrix: Water Analysis Batch: 91006 Sample Sample Analyte Result Qualifier Nitrate as N 0.36 Nitrite as N ND A Fluoride 0.31 Chloride 2.1 Bromide ND Sulfate 14 Lab Sample ID: 160-4643-1 MSD Matrix: Water Analysis Batch: 91006 Sample Sample Analyte Result Qualifier Nitrate as N 0.36 Nitrite as N ND A Fluoride 0.31 Chloride 2.1 Bromide ND Sulfate 14 Method: 310.1 -Alkalinity Lab Sample ID: MB 160-89196/1 Matrix: Water Analysis Batch: 89196 MB MB Analyte Result Qualifier Alkalinity ND Bicarbonate Alkalinity as CaC03 ND Carbonate Alkalinity as CaC03 ND Lab Sample ID: LCS 160-89196/3 Matrix: Water Analysis Batch: 89196 Analyte Alkalinity Clinch River Data Report Rev. 4 CRP-1112.16 Page H.2-107 of 111 Spike LCS Added Result 0.400 0.397 0.160 0.151 1.00 0.982 2.00 1.93 2.00 1.98 8.00 7.62 Spike MS Added Result 0.400 0.730 0.100 0.0705 2.00 2.55 2.00 3.99 2.00 1.95 4.00 17.9 Spike MSD Added Result 0.400 0.730 0.100 0.0708 2.00 2.56 2.00 4.00 2.00 1.96 4.00 17.8 RL 5.0 5.0 5.0 Spike LCS Added Result 400 369 Page 17 of21 LCS Qualifier A
MS Qualifier AF F
MSD Qualifier AF F
MDL Unit 0.54 mg/L 0.54 mg/L 0.54 mg/L LCS Qualifier Unit mg/L mg/L mg/L mg/L mg/L mg/L Unit mg/L mg/L mg/L mg/L mg/L mg/L Unit mg/L mg/L mg/L mg/L mg/L mg/L D
Unit mg/L TestAmerica Job 10: 160-4643-1 Client Sample ID: Lab Control Sample Prep Type: Totai/NA 0/oRec.
D
%Rec Limits 99 90-110 95 90-110 98 90-110 96 90-110 99 90-110 95 90-110 Client Sample ID: OW 420-L Prep Type: Totai/NA
%Rec.
D
%Rec Limits 92 90-110 70 90-110 112 90-110 96 90- 110 97 90- 110 99 90- 110 Client Sample ID: OW 420-L Prep Type: Totai/NA
%Rec.
RPD D
%Rec Limits RPD Limit 92 90- 110 0
20 71 90- 110 0
20 112 90- 110 20 96 90-110 0
20 98 90-110 20 97 90-110 0
20 Client Sample ID: Method Blank Prep Type: Totai/NA Prepared Analyzed Oil Fac 12/03/13 10:55 12/03/13 10:55 12/03/13 10:55 Client Sample ID: Lab Control Sample D
Prep Type: Totai/NA
%Rec.
%Rec Limits 92 90- 110 TestAmerica St. Louis RCN: CRP-1208.0 Page 17 of21 I
QC Sample Results Client: AMEC Environment & Infrastructure, Inc.
Project/Site: Clinch River Method: 310.1 -Alkalinity (Continued)
Lab Sample ID: LLCS 160-89196/2 Matrix: Water Analysis Batch: 89196 Spike LLCS LLCS Analyte Added Result Qualifier Alkalinity 200 184 Lab Sample ID: 160-4584-A-2 MS Matrix: Water Analysis Batch: 89196 Sample Sample Spike MS MS Analyte Result Qualifier Added Result Qualifier Alkalinity 300 20.0 316 4 Lab Sample ID: 160-4584-A-2 DU Matrix: Water Analysis Batch: 89196 Sample Sample DU DU Analyte Result Qualifier Result Qualifier Alkalinity 300 299 Bicarbonate Alkalinity as CaC03 300 299 Carbonate Alkalinity as CaC03 ND ND Method: 350.1 -Nitrogen, Ammonia Lab Sample ID: MB 160-94338/12 Matrix: Water Analysis Batch: 94338 MB MB Analyte Result Qualifier RL MDL Unit Ammonia ND A Lab Sample ID: LCS 160-94338/13 Matrix: Water Analysis Batch: 94338 Analyte Ammonia Lab Sample ID: 160-4584-A-4 MS Matrix: Water Analysis Batch: 94338 Sample Sample Analyte Result Qualifier Ammonia 710 A Lab Sample ID: 160-4643-1 MS Matrix: Water Analysis Batch: 94338 Sample Sample Analyte Result Qualifier Ammonia 110 HA Clinch River Data Report Rev. 4 CRP-1112.16 Page H.2-108 of 111 50 9.2 ug/L Spike LCS LCS Added Result Qualifier 500 523 A Spike MS MS Added Result Qualifier 500 1280 FA Spike MS MS Added Result Qualifier 500 709 AF Page 18 of21 Unit mg/L Unit mg/L Unit mg/L mg/L mg/L D
Unit ug/L Unit ug/L Unit ug/L TestAmerica Job 10: 160-4643-1 Client Sample ID: Lab Control Sample Prep Type: Totai/NA 0/oRec.
D
%Rec Limits 92 90-110 Client Sample ID: Matrix Spike Prep Type: Totai/NA
%Rec.
D
%Rec Limits 90 80-120 Client Sample ID: Duplicate Prep Type: Totai/NA RPD D
RPD Limit 0.3 20 0.3 20 NC 20 Client Sample ID: Method Blank Prep Type: Totai/NA Prepared Analyzed Oil Fac 12/23/13 17:48 Client Sample ID: Lab Control Sample D
D D
Prep Type: Totai/NA
%Rec.
%Rec Limits 105 90-110 Client Sample ID: Matrix Spike Prep Type: Totai/NA
%Rec.
%Rec Limits 115 90-110 Client Sample ID: OW 420-L Prep Type: Totai/NA
%Rec.
%Rec Limits 119 90-110 TestAmerica St. Louis RCN: CRP-1208.0 Page 18 of21 I
QC Sample Results Client: AMEC Environment & Infrastructure, Inc.
Project/Site: Clinch River Method: 350.1 -Nitrogen, Ammonia (Continued)
Lab Sample ID: 160-4584-A-4 DU Matrix: Water Analysis Batch: 94338 Sample Sample Analyte Result Qualifier
~A_m_m_o~ni_a _________________
~7~1~0 A Lab Sample ID: MB 160-96594/11 Matrix: Water Analysis Batch: 96594 MB MB Analyte Result Qualifier
~A_m_m_o~ni_a ____________________
~N=o A Lab Sample ID: LCS 160-96594/12 Matrix: Water Analysis Batch: 96594 Analyte Ammonia Lab Sample ID: 160-4643-2 MS Matrix: Water Analysis Batch: 96594 Sample Sample Analyte Result Qualifier
~A_m_m_o~ni_a _________________
~N=o HA Lab Sample ID: 160-4643-2 DU Matrix: Water Analysis Batch: 96594 Sample Sample Analyte Result Qualifier
~A_m_m_o~ni_a _________________
~N=o HA Clinch River Data Report Rev. 4 CRP-1112.16 Page H.2-109 of 111 Spike Added 500 Spike Added 500 DU DU Result Qualifier Unit
~7=2~1 A
-ug~/~L-----
RL 50 MDL Unit
~9~
. 2
-ug~/L~-----
D D
TestAmerica Job 10: 160-4643-1 Client Sample ID: Duplicate Prep Type: Totai/NA RPD RPD Limit 2
20 Client Sample ID: Method Blank Prep Type: Totai/NA Prepared Analyzed Oil Fac 01107/14 14:26 1
Client Sample ID: Lab Control Sample Prep Type: Totai/NA LCS LCS Result Qualifier Unit 519 A
ug/L MS MS Result Qualifier Unit 458 A
ug/L DU DU Result Qualifier Unit
~N=o A
-ug~/~L-----
D
%Rec
%Rec.
Limits 104
--9~0~-~1~1~0- ---- ----
Client Sample ID: OW 421-L Prep Type: Totai/NA D
%Rec
%Rec.
Limits D
92
--9~0~_~1~1~0- ---- ----
Client Sample ID: OW 421-L Prep Type: Totai/NA RPD RPD Limit NC 20 TestAmerica St. Louis Page 19 of21 RCN: CRP-1208.0 Page 19 of21 I
QC Association Summary Client: AMEC Environment & Infrastructure, Inc.
Project/Site: Clinch River Metals Prep Batch: 88861 Lab Sample ID Client Sample ID 160-4625-A-3-B MS Matrix Spike 160-4625-A-3-C MSD Matrix Spike Duplicate 160-4643-1 OW420-L 160-4643-2 OW421-L 160-4643-3 OW202-L 160-4643-4 DUP-1 LCS 160-88861/2-A Lab Control Sample MB 160-88861/1-A Method Blank Analysis Batch: 90379 Lab Sample ID Client Sample ID 160-4625-A-3-B MS Matrix Spike 160-4625-A-3-B MS Matrix Spike 160-4625-A-3-C MSD Matrix Spike Duplicate 160-4625-A-3-C MSD Matrix Spike Duplicate 160-4643-1 OW420-L 160-4643-2 OW421-L 160-4643-2 OW421-L 160-4643-3 OW202-L 160-4643-3 OW202-L 160-4643-4 DUP-1 LCS 160-88861/2-A Lab Control Sample MB 160-88861/1-A Method Blank Analysis Batch: 90921
[ Lab Sample ID Client Sample ID 160-4643-3 OW202-L General Chemistry Analysis Batch: 87715 Lab Sample ID Client Sample ID 160-4600-A-9 DU Duplicate 160-4643-1 OW420-L 160-4643-2 OW421-L 160-4643-3 OW202-L 160-4643-4 DUP-1 LCS 160-87715/2 Lab Control Sample MB 160-87715/1 Method Blank Analysis Batch: 89196 Lab Sample ID Client Sample ID 160-4584-A-2 DU Duplicate 160-4584-A-2 MS Matrix Spike 160-4643-1 OW420-L 160-4643-2 OW421-L 160-4643-3 OW202-L 160-4643-4 DUP-1 LCS 160-89196/3 Lab Control Sample LLCS 160-89196/2 Lab Control Sample Clinch River Data Report Rev. 4 CRP-1112.16 Page H.2-110 of 111 Prep Type Totai/NA Totai/NA Totai/NA Totai/NA Totai/NA Totai/NA Totai/NA Totai/NA Prep Type Totai/NA Totai/NA Totai/NA Totai/NA Totai/NA Totai/NA Totai/NA Totai/NA Totai/NA Totai/NA Totai/NA Totai/NA Prep Type Totai/NA Prep Type Totai/NA Totai/NA Totai/NA Totai/NA Totai/NA Totai/NA Totai/NA Prep Type Totai/NA Totai/NA Totai/NA Totai/NA Totai/NA Totai/NA Totai/NA Totai/NA Page 20 of 21 Matrix Water Water Water Water Water Water Water Water Matrix Water Water Water Water Water Water Water Water Water Water Water Water Matrix Water Matrix Water Water Water Water Water Water Water Matrix Water Water Water Water Water Water Water Water TestAmerica Job 10: 160-4643-1 Method Prep Batch 3010A 3010A 3010A 3010A 3010A 3010A 3010A 3010A Method Prep Batch 6020A 88861 6020A 88861 6020A 88861 6020A 88861 6020A 88861 6020A 88861 6020A 88861 6020A 88861 6020A 88861 6020A 88861 6020A 88861 6020A 88861 Method Prep Batch 6020A 88861 Method Prep Batch 160.1 160.1 160.1 160.1 160.1 160.1 160.1 Method Prep Batch 310.1 310.1 310.1 310.1 310.1 310.1 310.1 310.1 TestAmerica St. Louis RCN: CRP-1208.0 Page 20 of21
QC Association Summary Client: AMEC Environment & Infrastructure, Inc.
Project/Site: Clinch River General Chemistry (Continued)
Analysis Batch: 89196 (Continued) l Lab Sample ID Client Sample ID MB 160-89196/1 Method Blank Analysis Batch: 91006 Lab Sample ID Client Sample ID 160-4643-1 OW420-L 160-4643-1 MS OW420-L 160-4643-1 MSD OW420-L 160-4643-2 OW421-L 160-4643 DL OW421-L 160-4643-3 OW202-L 160-4643 DL OW202-L 160-4643-4 DUP-1 LCS 160-91006/10 Lab Control Sample MB 160-91006/9 Method Blank Analysis Batch: 94338 Lab Sample ID Client Sample ID 160-4584-A-4 DU Duplicate 160-4584-A-4 MS Matrix Spike 160-4643-1 OW420-L 160-4643-1 MS OW420-L 160-4643-3 OW202-L 160-4643-4 DUP-1 LCS 160-94338/13 Lab Control Sample MB 160-94338/12 Method Blank Analysis Batch: 96594 Lab Sample ID Client Sample ID 160-4643-2 OW421-L 160-4643-2 DU OW421-L 160-4643-2 MS OW421-L LCS 160-96594/12 Lab Control Sample MB 160-96594/11 Method Blank Analysis Batch: 104463 Lab Sample ID Client Sample ID 160-4643-1 OW420-L 160-4643-2 OW421-L 160-4643-3 OW202-L 160-4643-4 DUP-1 Clinch River Data Report Rev. 4 CRP-1112.16 Page H.2-111 of 111 Prep Type Totai/NA Prep Type Totai/NA Totai/NA Totai/NA Totai/NA Totai/NA Totai/NA Totai/NA Totai/NA Totai/NA Totai/NA Prep Type Totai/NA Totai/NA Totai/NA Totai/NA Totai/NA Totai/NA Totai/NA Totai/NA Prep Type Totai/NA Totai/NA Totai/NA Totai/NA Totai/NA Prep Type Totai/NA Totai/NA Totai/NA Totai/NA Page 21 of 21 Matrix Water Matrix Water Water Water Water Water Water Water Water Water Water Matrix Water Water Water Water Water Water Water Water Matrix Water Water Water Water Water Matrix Water Water Water Water TestAmerica Job 10: 160-4643-1 Method Prep Batch 310.1 Method Prep Batch 300.0 300.0 300.0 300.0 300.0 300.0 300.0 300.0 300.0 300.0 Method Prep Batch 350.1 350.1 350.1 350.1 350.1 350.1 350.1 350.1 Method Prep Batch 350.1 350.1 350.1 350.1 350.1 Method Prep Batch SM 1030F SM 1030F SM 1030F SM 1030F TestAmerica St. Louis RCN: CRP-1208.0 Page 21 of 21