ML18038A292
ML18038A292 | |
Person / Time | |
---|---|
Site: | Nine Mile Point ![]() |
Issue date: | 09/12/1989 |
From: | Joseph Willis NIAGARA MOHAWK POWER CORP. |
To: | |
Shared Package | |
ML17056A673 | List: |
References | |
AP-3.7.1, NUDOCS 9003150343 | |
Download: ML18038A292 (76) | |
Text
PROCEDURE
SUMMARY
SHEET Rev B Procedure Number: 'P-3.7.1 Revision Number: 03 Procedure
Title:
Unit 2 Radwaste Process Control Program Descri tion of Chan es Incorporated appropriate technical change to NOTE on page 1, Section 1.2, as requested by Oscar Henderson.
Comment Resolution The attached comments have either been incorporated or deferred to Phase II as applicable. A resolution for each comment is noted on the returned review sheets.
later The following reviewer comments have been deferred to Phase II or and are highlighted.
Name of Reviewer s NONE Recommended Actions Before Im lementation NONE Completed by: Robert Vandevender II Ext: ~76 3 Date: ll 89 9003150343 900302 PDR ADOCK 050004l0 R PDC
NIAGARA MOHAWK POWER CORPORATION NINE MILE POINT NUCLEAR STATION ADMINISTRATIVE PROCEDURE
~AP- .7.1 REVISION 03 UNIT 2 RADWASTE PROCESS C NTR L PROGRAM Approved By:
J. L. Willis ig8~g(
General Supe dent, Nuclear Generation Date q/2 Effective Date: September l5, l989 NOT TO BE USED AFTER September SUBJECT TO PERIODIC REVIEW
P LIST OF EFFECTIVE PAGES
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Page i AP-3.7.1 Rev. 03
TABLE OF CONTENTS SECTION PAGE 1.0 PURPOSE. ~ ~ ~ 1 2 i 0 SCOPE ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ 1
3.0 REFERENCES
AND COMMITMENTS ~ ~ ~ 2 4.0 DEFINITIONS. 5 5.0 RESPONSIBILITIES ~ ~ ~ 5 6.0PROCEDURE. ~ ~ ~ 7 6.1 System Description. ~ 7 6.2 Asphalt Volume Reduction System . ~ ~ ~ 11 6.3 Administrative Controls ~ ~ ~ 18 7.0 ATTACHMENTS. ~ ~ ~ 22 Attachment 1: Unit 2 Radwaste Process Control Program Implementing Procedures ~ ~ 0 23 Attachment 2: Solid Waste Sources ~ ~ ~ 25 Attachment 3: Process Control Flowpath. ~ ~ ~ 27 Attachment 4: System Flow Schematic ~ ~ ~ 28 Attachment 5: Operator Worksheet. ~ ~ ~ 29 Attachment 6: Temperature Profile Log ~ ~ ~ 30 Attachment 7: Barnwell Manifest ~ ~ ' ~ ~ ~ 31 Attachment 8: US Ecology Manifest ~ ~ ~ 33 Page ii AP-3.7.1 Rev. 03
1.0 PURPOSE 1.1 To describe the methods for processing, packaging and transportation of low-level radioactive waste and provide assurance of complete solidification of various radioactive "wet wastes" in accordance with applicable NRC regulations and guidelines.
1.2 To satisfy the Nuclear Regulatory, Commission's Low-Level Waste and Uranium Recovery Projects Branch (WMLU) requirement and establish process parameters within which the Werner Sc Pfleiderer Corporation Volume Reduction System (WPC-VRS) must be operated to ensure complete solidification.
1.3 Waste process under this program using asphalt as the media is limited to Class A Waste.
NOTE: Conformance with WMLU requirements provides assurance that the requirements identified in 10CFR61, Sub Part D, Technical Requirements for Land Disposal Facilities and Final Waste Classification and Waste Form, Technical Position Papers, which requires that Class A Waste shall be a free standing monolith with < .05 / free standing liquid.
2.0 SCOPE 2.1 A licabilit This procedure applies to the Unit 2 Radwaste Process Control Program for solidification and transportation of radioactive waste.
2.2 Ob ectives
'2.2.1 To satisfy the Nuclear Regulatory Commission's Low-Level Waste and Uranium Recovery Projects Branch (WMLU) requirements.
2.2.2 To establish process parameters within which the Werner and Pfleiderer Corporation Volume Reduction System (WPC-VRS) shall operate to ensure complete solidification of waste.
2 ~2~3 To ensure compliance with Federal regulations for the packaging and transportation of radioactive materials.
2.2.4 To ensure Radwaste Operators are trained and qualified in the operation of radioactive waste processing equipment.
2.2.5 To ensure Chemistry Technicians are trained and qualified in the sampling and analysis of wet radioactive waste.
2.2.6 To ensure Radiation Protection Technicians are trained and qualified in radiological controls monitoring of radioactive waste shipments.
Page 1 of 34 AP-3.7.1 Rev. 03
3.0 REFERENCES
AND COMMITMENTS 3.1 Standards and Re ulations 3.1.1 ANSI/ANS 55.1, 1979, American National Standard for Solid Radioactive Waste Processing System for Light Water Cooled Reactor Plants 3.1.2 10CFR20.311, Transfer for Disposal and Manifest 3.1.3 10CFR20.311.d.3, Transfer for Disposal and Manifest 3.1.4 10CFR61, Sub Part D, Technical Requirements for Land Disposal Facilities and Final Waste Classification and Waste Form Technical Position Papers 3.1.5 10CFR61.55, Waste Classification 3.1.6 10CFR61.56, Waste Characteristics 3.1.7 10CFR71, Packaging and Transportation of Radioactive Material 3.1.8 49CFR173.l.b, Transportation 3.1.9 49CFR173.425, Transport Requirements for Low Specific Activity (LSA) Radioactive Materials 3.1.10 NUREG-0123, Standard Radiological Effluent Technical Specifications for Boiling Water Reactors
'.1.11 NUREG-0800,
- a. Section 11.2, Standard Review Plan for Liquid Waste Management Systems
- b. Section 11.4, Standard Review Plan for Solid Waste Management Systems 3.1.12 Resource Conservation and Recovery Act (RCRA) of 1976 (Ref.
Corporate Guide to Hazardous Waste Disposal and Spill Reporting) 3.2 Re ulator and Indust Guidelines 3.2.1 Regulatory Guide 1.143, Rev. 0, Design Guidance for Radioactive Waste Management Systems, Structures, and Components Installed in Light Water Cooled Nuclear Power Plants Page 2 of 34 AP-3.7.1 Rev. 03
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I 3.3 Licensee Documentation 3.3.1 QATR-l, Quality Assurance Program Topical Report for Nine Mile Point Nuclear Station Operations, Section 17.0, Quality Assurance Records 3.3.2 Unit 2 Technical Specifications:
- a. Section 3.11.3.a, Solid Radioactive Wastes
- b. Section 3.11.3.b, Solid Radioactive Wastes
- c. Section 4.11.3.a, Solid Radioactive Wastes
- d. Section 4.11.3.b, Solid Radioactive Wastes
- e. Section 6.5.2.11, Review and Audit, Technical Review and Control Activities
- f. Section 6.5.3.8.i, Review and Audit, Safety Review and Audit Board
- g. Section 6.9.1.8, Semi-Annual Radioactive Effluent Release Report
- h. Section 6.13, Process Control Program 3.4 Site Procedures 3.4.1 AP-2.0, Production and Control of Procedures 3.4.2 AP-7.2, Control of Material Storage Areas 3.4.3 AP-9.0, Administration of Training 3.4.4 AP-10.1, Management of Station Records 3.4.5 N2-CSP-14, Solid Radwaste Chemical Surveillance at Unit 2 3.4.6 N2-0P-41, Asphalt Solidification Operating Procedure 3.4.7 N2-NTP-13, Nuclear Department Training Manual 3.4.8 N2-WHP-l, Required Documents Concerning Packaging and Shipping of Radioactive Wastes
'I 3.4.9 N2-WHP-2, Paperwork for a Radioactive Waste Shipment 3.4.10 N2-WHP-4, Cask Loading Procedure 3.4.11 N2-WHP-8B, Flatbed Loading Procedure Page 3 of 34 AP-3.7.1 Rev. 03
3.4.12 N2-WHP-9, Asphalt Solidification 3.4.13 N2-WHP-9A, Operating Procedure Vendor Solidification 3.4.14 N2-WHP-9B, Process Control LN Cement Solidification 3.4.15 N2-WHP-10A, Process Control Oil/Cement Solidification Procedure 3.4.16 N2-WHP-lOB, Cement/Oil Solidification Procedure 3.4.17 N2-WHP-ll, Process Control Dry Solid Waste 3.4.18 N2-WHP-12, Solid Dry Waste Collection and Compaction 3.4.19 N2-WHP-14, Solidified Liner Inspection Program 3.4.20 NTP-l, Training and Continued Training of Chemistry and Radiochemistry Technicians 3.4.21 NTP-13, Training and Continued Training of Radwaste Operators 3.4.22 NTP-14, Training and Continued Training ,of Radiation Protection Technicians 3.4.23 S-RP-6, The Packaging and Transportation of Radioactive Material 3.5 Other References 3.5.1 South Carolina Department of Health and Environmental Control, Radioactive Material License 097, as amended 3.5.2 State of Washington Radioactive Material License No.
WN-I019-2, as amended 3.5.3 Werner and, Pfleiderer Corporation Topical Report No.
WPC-VRS-001, November 1976, Rev. 1, May 1978, Appendix B, Solid Content 3.5.4 NRC Special Nuclear Material License No. 12-13536-02, as amended, for Barnswell, SC 3.5.5 NRC Special Nuclear Material License No. 16-19204-01, as amended, for Richland, WA 3.5.6 Nuclear Regulatory Commission Branch Technical Position on Waste Classification and Waste Form, May 1983 Page 4 of 34 AP-3.7.1 Rev. 03
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3.6 Commitments Section/Step Number NCTS Number Description None 4.0 DEFINITIONS 4.1 Class "A" Waste Waste usually segregated from other waste classes at the disposal site. The physical form and characteristics shall meet the minimum requirements of 10CFR61.56, Waste Characteristics.
4.2 Class "B" Waste Waste meeting more rigorous waste form requirements to ensure stability after disposal. Class B waste form shall meet both the minimum and stability requirements of 10CFR61.56, Waste Characteristics.
4.3 Class "C" Waste Waste meeting Class B standards and requiring additional measures at the disposal facility to prevent inadvertent intrusion.
I 5.0 RESPONSIBILITIES 5.1 General Su erintendent Nuclear Generation The General Superintendent, Nuclear Generation shall review and approve changes to the Unit 2 Radwaste Process Control Program in accordance with Unit 2 Technical Specification, Section 6.5.2.11, Review and Audit, Technical Review and Control Activities.
5.2 Station Su erintendent The Station Superintendent shall ensure the Unit 2 Radwaste Process Control Program provides for the health and safety of the general public as it applies to Radwaste Management.
5.3 Su ervisor Radwaste 0 erations The Supervisor Radwaste Operations shall:
5.3.1 Implement the Radwaste Process Control Program.
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5.3.2 Interface with the Unit Supervisor Chemistry and Radiochemistry on matters concerning radwaste processing and disposal, as required.
5.3.3 Interface with the Manager Radiation Protection on matters concerning radwaste processing and disposal, as required.
5.3.4 Supervise activities related to radwaste collection, processing, packaging, storage, transportation, and disposal.
5.3.5 Review Radwaste Process Control Program implementing procedures to ensure validity of technical content and compliance with applicable Federal and State Regulations, Technical Specifications, Company Policies, and the Station Operating License.
5.3.6 Ensure compliance with Federal and State Regulations governing the transportation and disposal of radioactive material.
5.3.7 Ensure Radwaste Operators complete required training and qualification and maintain proficiency, as required.
5.4 Unit Su ervisor Chemist and Radiochemist The Unit Supervisor Chemistry and Radiochemistry shall:
5.4.1 Interface with the Supervisor Radwaste Operations on matters concerning radwaste processing and disposal, as required.
5.4.2 Ensure Chemistry Technicians complete required training and qualification and maintain pro'ficiency, as required.
5.4.3 Ensure Chemistry Technicians calculate and determine Waste-to-Asphalt flow rates and contents in accordance with established procedures.
5.5 Mana er Radiation Protection The Manager Radiation Protection shall:
5.5.1 Interface with the Supervisor Radwaste Operations on matters concerning radwaste processing and disposal, as required.
5.5.2 Ensure Radiation Protection Technicians complete required training and qualification and maintain proficiency, as required.
5.6 Chemist and Radiochemistr Technician Chemistry and Radiochemistry Technicians shall perform analysis of radioactive waste samples.
Page 6 of 34 AP-3.7.1 Rev. 03
5.7 Radiation Protection Technician Radiation Protection Technicians shall perform radiological controls monitoring on radwaste shipments.
5.8 Radwaste 0 erator Radwaste Operators shall perform operations associated with radwaste processing.
6.0 PROCEDURE 6.1 S stem Descri tion 6.1.1 General a ~ The Solid Waste Management System (SWMS), implemented by the procedures identified in the Unit 2 Radwaste Process Control Program Implementating Procedures (Attachment 1) collects, reduces the volume, solidifies, and packages wet and dry types of radioactive waste in preparation for shipment off-site to a licensed burial site.
- b. Types of solid waste sources are identified in Solid Waste Sources (Attachment 2).
- c. Radwaste Process Control Flowpath (Attachment 3) and System Flow Schematic (Attachment 4) are provided for the Unit 2 SWMS.
- d. The Solid Waste Management System accepts dry solid trash which is, when physically possible, compacted with a trash compactor.
- e. Bead resins or powdered resins are dewatered in high integrity containers or processed along with evaporator bottoms through the extruder evaporator.
- f. When required, Unit 2 will use the services of a vendor to solidify waste.
6.1.2 Extruder/Evaporator
- a. The extruder/evaporator is a one-step volume reduction and solidification process.
- b. Two screws inside the twin screw extruder/evaporator convey the waste/asphalt mixture along the length, continually shearing and mixing the waste/asphalt.
Page 7 of 34 AP-3.7.1 Rev. 03
P l 6.1.2 (Cont)
- c. The screw ,speed can be regulated to control the evaporating capacity and residence time of the waste.
- d. The extruder/evaporator discharges a homogeneous mixture of asphalt and waste containing NO free standing water.
- e. The solid radwaste system uses the extruder/evaporator to process waste fed from two inputs; the evaporator bottoms tank or the waste sludge tank. The waste is mixed with asphalt in the extruder. Only one waste feed path can be processed at a time.
- f. Operation of the extruder/evaporator is detailed in N2-0P-41, Asphalt Solidification Operating Procedure.
6.1.3 Evaporator Bottoms Tank
- a. The evaporator bottoms tank and lines are electrically heat traced to prevent crystallization of waste salts.
- b. The contents of the tank are fed to the extruder/evaporator via a transfer pump that supplies redundant metering pumps.
- c. The waste flow rate is controlled manually by adjusting the flow rates on the metering pumps.
6.1.4 Waste Sludge Tank a ~ The contents of the waste sludge tank are fed to the extruder/evaporator by a separate system from the evaporator bottoms feed system. This system has redundant waste sludge metering pumps.
- b. The waste sludge tank is supplied by waste from three sources: the radwaste filters, the floor drain filter, and the spent resin tank.
C ~ The waste flow rate is controlled manually by adjusting the flow rates on the metering pumps.
- d. The waste sludge tank has the ability for decantation. A decant pump takes a suction off the sludge tank and discharges to the spent resin tank.
Page 8 of 34 AP-3.7.1 Rev. 03
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I4 6.1.5 Asphalt Tank
- a. The contents of the asphalt tank is fed to the extruder/evaporator via redundant recirculation pumps, strainers, and metering pumps.
- b. The asphalt flow rate is automatically adjusted to yield the, proper ratio of asphalt to solids.
- c. The asphalt tank and lines are continuously steam heated to keep the asphalt in a liquid state for ease in pumping.
6.1.6 Electric Radwaste Boiler
- a. As the waste/asphalt mixture moves through the extruder/evaporator, the mixture is heated by steam from the electric radwaste boiler.
- b. The boiler is a skid mounted boiler system which uses electricity for steam production.
- c. The boiler is a closed system, therefore, most of the water used for steam is returned to the boiler as condensate via the boiler feedwater system.
- d. The boiling vessel is capable of supplying 14008/hr of steam at 233 psig and 400 F.
- e. The steam applied to the extruder is used in six separate heating zones for moisture evaporation.
- f. Each zone has a separate temperature controller for optimum operating conditions.
6.1.7 Devolatization Ports a ~ Three devolatization ports along the extruder allow for water vapor to separate from the product and enter the three steam domes.
- b. A predetermined amount (4 gal.) of demineralized water is used, which dissolves and boils out salt sediment at the devolatization port.
C ~ The vapors are condensed in the steam domes using turbine building closed loop cooling and drained to the distillate collection system.
Page 9 of 34 AP-3.7.1 Rev. 03
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6.1.8 Distillate Collection System The distillate collection is I'.
system a recirculating system used to continuously filter and cool the condensate from the extruder/evaporator steam domes.
- b. The condensate is recirculated from the distillate collection tank through the distillate pumps, roughing filter, and the distillate cooler, then routed back to the collection tank.
- c. The level controller maintains collection tank level and system flow.
6.1.9 Ventilation System
- a. A forced circulation ventilation system is incorporated into this system.
- b. The system consists of a vent hood over the extruder/evaporator turntable, a fan which draws air from the plant ventilation system across the extruder/evaporator turntable, and liner cool down areas.
6.1.10 Liners a~ The extruder/evaporator product empties into 50 cubic feet liners.
- b. The The liners are placed on the fill station turntable.
operator indexes (turns) the turntable via a control switch, placing a liner under the discharge chute of the extruder/evaporator.
c~ The turntable holds three liners. When the liner level reaches a predetermined level, a high level alarm sounds to inform the operator it is time to index the container.
- d. Liners are indexed without shutting down the extruder/evaporator. Using control switches, the operator, via a pneumatic carrier, extends a drip pan under the extruder/evaporator discharge chute. The operator then indexes the turntable.
- e. Once the new liner is in place under the extruder/evaporator discharge chute, the pneumatically operated carrier is withdrawn.
Page 10 of 34 AP-3.7.1 Rev. 03
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6.1.10 (Cont)
- f. During this withdrawal operation, the drip pan is removed from the carrier by a stationary arm as the carrier retracts past the arm and drops the drip pan into the new liner.
6.1.11 Crane
- a. Full liners are removed from the turntable to the cooldown area via a radio controlled/operated crane.
- b. After cooldown is completed, the liners are moved by crane to the storage area using a ceiling grid coordinated system for placement of the liner.
- c. When the liners are to be shipped, the liners are moved to the capping station and capped just before shipment then loaded for transportation to the burial location.
6.2 As halt Volume Reduction S stem 6.2.1 Radwaste Operators shall ensure proper equipment is available before beginning radwaste processing. Radwaste Operators may process wastes through the extruder/evaporator when the following equipment is operable:
- a. Closed circuit television system at the asphalt loading stations
- b. Calibrated temperature profile monitoring instrumentation,
- c. Operational asphalt and waste metering equipment
- d. Solid radwaste sampling stations.
6.2.2 Variables Influencing End Product Properties Radwaste Operators shall control the following variables to ensure the final waste product is a free standing monolith with essentially NO free standing water:
~'
~ Asphalt type
- b. Waste chemical species being incorporated into the asphalt matrix/water. content C ~ Ratio of waste-to-asphalt Page ll of 34 AP-3.7.1 Rev. 03
6.2.2 (Cont)
- d. Process temperature
- e. Additional process variables such as pH, that do NOT affect the ability of the waste product to form a solid free standing monolith upon cooling.
6.2.3 Asphalt Type Radwaste Operators shall:
- a. Use an oxidized petroleum-based asphalt, conforming to ASTM-D-312-71, Type III requirements with the following properties:
- 1. Has a low residual volatile content
- 2. Has a high molecular weight
- 3. At room temperature, or ambient conditions, is a free standing monolith
- 4. Specify Witco Pioneer 221, or an equivalent asphalt.
NOTE: Consult Werner and Pfleiderer Corporation if an alternate asphalt material is to be used.
- b. Ensure verification of asphalt type is conducted per N2-CSP-14, Solid Radwaste Chemical Surveillance at Unit 2.
6.2.4 Waste Chemical Species Radwaste Operators shall ensure:
- a. Testing is performed to determine the oil content and physical properties of the waste to be solidified per N2-CSP-14, Solid Radwaste Chemical Surveillance at Unit 2
- b. Adherence to the Werner and Pfleiderer limit of 1.0%
oil and organic contaminants in the waste feed stream for process control.
NOTE: Type and relative quantity (waste-to-asphalt) of waste chemicals being incorporated in the asphalt matrix has a direct influence on the properties of the final product:
Page 12 of 34 AP-3.7.1 Rev. 03
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6.2.4.b (Cont).
l." Encapsulation of inorganic salts and solids typically "stiffen" and harden the waste product.
- 2. Encapsulation of organic liquids typically softens the waste product.
6.2.5 Waste-to-Asphalt Ratio Radwaste Operators shall use the following waste-to-asphalt ratios:
NOTE Optimum values depend on type and quantity of contaminants present.
- a. Evaporator Concentrates 40/60 to 50/50
- b. Spent Resins 45/55 to 50/50
- c. Filter Sludge 40/60 to 50/50.
NOTE'hen the ratio of waste-to-asphalt is increased above the range specified above, the end product viscosity will increase and may exhibit a grainy texture. This could lead to "pyramiding" of the product in the container, thereby decreasing the container filling efficiency.
6.2.6 Waste-to-Asphalt Flow a ~ Radwaste Operators shall set the initial proportion of waste-to-asphalt flow based on Chemistry Department calculations.
- b. The Chemistry Department shall determine the solids content of the waste feed by sampling.
C ~ The Chemistry Department shall:
- 1. Determine the proper feed control settings in accordance with N2-CSP-14, Solid Radwaste Chemical Surveillance at Unit 2, for flow rate calculations.
- 2. Calculate flow rates based on the information supplied in Werner and Pfleiderer Corporation Topical Report No. WPC-VRS-001, November 1976, Rev. 1, May 1978. Appendix B Solid Content.
Page 13 of 34 AP-3.7.1 Rev. 03
i 6.2.6 (Cont)
- d. Radwaste Operators shall visually confirm the proper ratios are being maintained on the Solid Radwaste Control Panel.
- 1. A closed circuit television camera may be used to view the discharge from the extruder/evaporator.
- 2. The television monitor located in the control room allows observation of the physical consistency as the product is discharged into the container.
6.2.7 Process Temperature Radwaste Operators shall:
- a. Ensure a proper temperature profile is maintained along the length of the extruder/evaporator to provide adequate evaporative (process) capacity
- b. Ensure free water is NOT discharged from the machine.
NOTE'ow temperature alarms are provided to alert the operator to a low temperature off-normal condition which could lead to the discharge of free water.
NOTE: Low temperature alarms are typically based on a
+10'F deviation from setpoint. The above can be adjusted up to +25% (+75 F) of the instrument range.
Co Adhere to the following (approximate) temperature profiles:
- l. Evaporator Concentrates:
Zone 1 165'F Zone 2 265 F Zone 3 300 F Zone 4 3300F Zone 5/6 375 F Zone 7 350 F.
- 2. Spent Resins, Filter Sludge:
Zone 1 165 F Zone 2 265 F Zone 3 2850F Zone 4 300 F Zone 5/6 2850F 34'P-3.7.1 Zone 7 2300F.
Page 14 of Rev. 03
6.2.7 (Cont)
- d. Log temperature profiles every two hours during equipment operating run time.
6.2.8 High Integrity Containers (HIC)
The Supervisor'Radwaste Operations shall ensure:
a ~ High Integrity Containers (HIC) are used for dewatering to satisfy the stability requirements.
- b. Each HIC is accompanied by a certificate of compliance.
co Dewatering procedures based on an NRC approved vendor process control program or "Topical Report" are part of N2-WHP-4, Cask Loading Procedure.
- d. Documentation of adherence to procedures are maintained as records.
6.2.9 Contaminated Oils The Supervisor Radwaste Operations shall ensure:
- a. Contaminated oils are stored in containers at designated areas within the plant.
- b. A vendor with an approved process control program acceptable at the selected burial site is used to solidify the oil.
- c. N2-WHP-10A, Process Control Oil/Cement Solidification Procedure, is used for operating the portable oil solidification system.
- d. N2-WHP-10B, Cement/Oil Solidification Procedure, is used to sample production level.
6.2.10 Temporary Radwaste Processing The Supervisor Radwaste Operations shall ensure:
- a. The vendor is NRC approved and has demonstrated a commitment to 10CFR61, Sub Part D, Technical Requirements for Land Disposal Facilities and Final Waste Classification and Waste Form Technical Position Papers stability requirements.
- b. The vendor has completed Class B and C waste testing or has provided a schedule of completion.
Page 15 of 34 AP-3.7.1 Rev. 03
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6.2.10 (Cont) c~ The vendor has an approved procedure to process Class A waste (Dewatering, Solidification).
- d. Vendor procedures are acceptable if:
- 1. Vendor procedures are reviewed and approved in accordance with AP-2.0, Production and Control of Procedures.
- 2. A production sample level process control procedure is implemented.
- 3. The vendor is provided samples in accordance with N2-0P-41, Asphalt Solidification Operating Procedure, and N2-CSP-14, Solid Radwaste Chemical Surveillance at Unit 2.
6.2.11 Dry Active Waste (DAW)
The Supervisor Radwaste Operations shall ensure:
a ~ The proper and safe steps are performed to collect and prepare low specific activity (LSA) DAW in accordance with N2-WHP-12, Solid Dry Waste Collection and Compaction.
- b. Items most directly influencing the quality of the end product are identified and controlled in accordance with N2-WHP-ll, Process Control Dry Solid Waste.
C ~ DAW is examined for liquids or items that would compromise the integrity of the package or violate the burial site license and/or criteria before compacting is removed or separated.
- d. DAW is shipped in containers meeting the transport requirements of 49CFR173.425, Transport Requirements for Low Specific Activity (LSA) Radioactive Materials.
- e. Waste precluded from disposal in LSA boxes or drums due to radiation limits is disposed of in liners in accordance with N2-WHP-4, Cask Loading Procedure.
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6.2.12 Sampling Radwaste Operators and the Chemistry Department shall ensure:
a 0 The evaporator bottoms tank (Tk10) and the waste sludge tank (Tk8) are isolated from further input when preparing to process waste and a batch number is assigned in accordance with the Operator Worksheet (Attachment 5).
- b. The evaporator bottoms tank (TklO) is recirculated to ensure a homogeneous mixture.
- c. The waste sludge tank (Tkg) is agitated to ensure a homogeneous mixture.
- d. A sample is obtained from the tank(s) to be processed in accordance with N2-0P-41, Asphalt Solidification Operating Procedure and N2-CSP-14, Solid Radwaste Chemical Surveillance at Unit 2.
- e. The sample from the tank(s) to be processed is analyzed and the sample data sheet form in N2-CSP-14, Solid Radwaste Chemical Surveillance at Unit 2, is completed.
- f. The Chemistry Department shall determine the chemical and radionuclide content of each sample.
- g. Completion of the Operator Worksheet (Attachment 5).
- h. Completion of the Temperature Profile Log (Attachment
- 6) during processing.
- i. After obtaining feed rate data from the Chemistry Department, the given feed rates for introduction into the extruder/evaporator are selected.
- j. If batch processing is interrupted, the Radwaste Operator shall isolate the source tank until processing can resume.
6.2.13 Waste Classification
- a. The Unit 2 Radwaste Process Control Program assures that wastes determined acceptable for near surface disposal are properly classified.
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6.2.13 (Cont)
- b. Waste classification is performed consistent with the guidance provided in the Branch Technical Position pertaining to Waste Classification and is based upon the concentration of certain radionuclides in the waste form as given in 10CFR61.55, Waste Classifica-tion, and 10CFR61.56, Waste Characteristics.
NOTE: The methods used by Unit 2 and the frequency for determining the radionuclide concentration of the final waste form are conducted in accordance with N2-CSP-14, Solid Radwaste Chemical Surveillance at Unit 2.
- c. The Supervisor Radwaste Operations shall ensure:
The minimum waste characteristic requirements identified in 10CFR61.56, Waste Characteristics, are satisfied by implementation of S-RP-6, The Packaging and Transportation of Radioactive Material.
- 2. The radionuclide concentration determination methods and frequency are conducted in accordance with N2-CSP-14, Solid Radwaste Chemical Surveillance at Unit 2.
- d. The Unit Supervisor Chemistry and Radiochemistry and Manager Radiation Protection shall ensure classification of waste is performed in accordance with S-RP-6, The Packaging and Transportation of Radioactive Material.
6.3 Administrative Controls NOTE The Manager, Nuclear QA, Operations has the authority to stop work when significant conditions adverse to quality exist and require corrective action.
6.3.1 Quality Assurance (QA) procedures and the Nuclear QA Program require:
a ~ Ongoing review, monitoring, and audit functions.
- b. Performance of audits, under the cognizance of the SRAB, of the Process Control Program and implementing procedures for processing and packaging of radioactive waste at least once every 24 months as required by Unit 2 Technical Specification 6.5.3.8.i, Review and Audit, Safety Review and Audit Board.
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6.3.1 (Cont)
- c. Compliance with the waste classification and characterization requirements of 10CFR61.55, Waste Classification and 10CFR61.56, Waste Characteristics.
- d. Quality Assurance Inspectors performing radwaste inspections have documented training in Department of Transportation and NRC radwaste regulatory requirements.
- e. Quality Assurance review of vendor procedures.
- f. Quality Assurance review of vendor programs to ensure compliance with 10CFR71, Packaging and Transportation of Radioactive Naterials, Quality Assurance requirements.
6.3.2 Training Procedures and Training Programs require:
- a. Radwaste Operator qualification by completion of the Radwaste Operations Unit 2 Plant Training Program with:
- l. An average grade of 80 percent or above.
- 2. On-the-job training in conjunction with classroom instruction to ensure each radwaste operator maintains an acceptable level of skill and familiarity associated with radwaste controls and operational procedures.
- 3. Training in accordance with NTP-13, Training and Continued Training of Radwaste Operators.
- b. Training of Radwaste Operators includes, but is NOT limited to, familiarity with the following radwaste components or related systems:
- 1. Liquid-drains, collection tanks with subsystems, waste and regeneration evaporators, and seal water
- 2. Solid-Extruder/evaporator and associated support systems
- 3. LWS-Computer operation and interfaces
- 4. Waste handling procedures for packaging and shipping of radioactive materials
- 5. Condensate demineralizer system Page 19 of 34 AP-3.7.1 Rev. 03
1 6.3.2.b (Cont)
- 6. Spent fuel and phase separators subsystem
- 7. Steam supplies.
- c. Chemistry and Radiochemistry Technicians are trained in accordance with NTP-l, Training and Continued Training of Chemistry and Radiochemistry Technicians.
- d. Radiation Protection Technicians are trained in accordance with NTP-14, Training and Continued Training of Radiation Protection Technicians.
- e. A formal classroom Radwaste Training Program is scheduled based on the needs of Radwaste Operations personnel.
NOTE: This training may be covered in a continuous cycle or as part of the normal rotating shift schedule.
- f. Retraining of Radwaste Operator personnel on an annual basis identifies individual needs for retraining.
- 1. Personnel demonstrating a significant deficiency in a given area of knowledge and proficiency are placed in a remedial training program as directed by the Supervisor Radwaste Operations".
- 2. Successful completion of the accelerated training program is evaluated by a written and/or oral examination as directed by the Supervisor Radwaste Operations.
NOTE 'he a Requalification Training Program covers fundamental review of system modifications, revisions or changes to procedures, and changes or experiences in the nuclear industry.
- g. Training records:
- 1. Are maintained for audit and inspection purposes.
- 2. Are considered permanent records.
- 3. Shall meet the applicable requirements of QATR-l, Quality Assurance Program Topical Report for Nine Mile Point Nuclear Station Operations, Section 17.0, Quality Assurance Records, AP-9.0, Administration of Training, and AP-10.1, Management of Station Records.
Page 20 of 34 AP-3.7.1 Rev. 03
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6.3.3 Documentation Control and Record Retention a ~ Station management shall evaluate QA program audits of waste classification records to satisfy the requirements of 10CFR20.311.d.3, Transfer for Disposal and Manifests.
- b. Personnel shall forward changes affecting operating procedures to Nuclear-QA for review in parallel with the NMPC Operations review as required.
- c. Site Records Management shall maintain waste management records in accordance with the appropriate administrative procedures.
6.3.4 Licensee-initiated changes to the Unit 2 Radwaste Process Control Program:
- a. Are submitted to the Commission by the method and containing the information as required by Technical Specification 6.13, Process Control Program.
- b. Become effective upon review and acceptance by the SORC.
6.3.5 The Supervisor Radwaste Operations shall ensure:
a ~ Shipping manifests are completed and tracked to satisfy the requirements of 10CFR20.311, Transfer for Disposal and Manifests, in accordance with Waste Handling Procedures.
- b. Radwaste Management monitors the status of the manifests in accordance with N2-WHP-2, Paperwork for a Radioactive Waste Shipment.
c~ Temporary storage of solid radioactive material awaiting shipment in an area other than a designated area is done in accordance with AP-7.2, Control of Material Storage Areas.
Page 21 of 34 AP-3.7.1 Rev. 03
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- 7. 0 ATTACHMENTS Attachment 1: Unit, 2 Radwaste Process Control Program Implementing Procedures Attachment 2: Solid Waste Sources Attachment 3: Process Control Flowpath Attachment 4: System Flow Schematic Attachment 5: Operator Worksheet Attachment 6: Temperature Profile Log Attachment 7: Barnwell Manifest Attachment 8: US Ecology Manifest Page 22 of 34 AP-3.7.1 Rev. 03
C I ATTACHMENT 1". UNIT 2 RADWASTE PROCESS CONTROL PROGRAM IMPLEMENTING PROCEDURES (Sheet 1 of 2)
Waste Handlin Procedures WHPs N2-WHP-1 Required Documents Concerning Packaging and Shipping of Radioactive Wastes N2-WHP-2 Paperwork for a Radioactive Waste Shipment t
N2-WHP-3 Cask Handling Procedure N2-WHP-4 Cask Loading Procedure N2-WHP-6., Van Handling Procedure N2-WHP-7 Van Loading Procedure N2-WHP-8A Flatbed Handling Procedure N2-WHP-8B Flatbed Loading Procedure N2-WHP-9 Asphalt Solidification N2-WHP-9A Cement Solidification Procedure N2-WHP-9B Process Control LN Cement Solidification N2-WHP-10A Process Control Oil/Cement Solidification Procedure N2-WHP-10B Cement/Oil Solidification Procedure N2-WHP-11 Process Control Dry Solid Waste N2-WHP-12 Solid Dry Waste Collection and Compaction N2-WHP-14 Solidified Liner Inspection Procedure Radiation Protection Procedures RPs S-RP-1 Access and Radiological Control S-RP-2 Radiation Work Permit Procedure S-RP-3 Performance of Radiological Surveys S-RP-4 Picking Up, Receiving and Opening Packages Containing Radioactive Material S-RP-5 Radiation and Radioactive Contamination Control S-RP-6 The Packaging and Transportation of Radioactive Material Page 23 of 34 AP-3.7.1 Rev. 03
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ATTACHMENT 1: UNIT 2 RADWASTE PROCESS CONTROL PROGRAM IMPLEMENTING PROCEDURES (Cont)
(Sheet 2 of 2)
Chemist Procedure CSP N2-CSP-14 Solid Radwaste Chemical Surveillance at Unit 2 ualit Assurance Procedures APs QAP-10.03 QAD Surveillance Activities for Operations QAP-10.30 QAD Inspection Activities QAP-15.01 Control of Nonconforming Items QAP-18.10 QAD Audits='
eratin Procedures OPs N2-OP-40 Liquid Radwaste Operating Procedures N2-OP-41 Asphalt Solidification Operating Procedure Site Administrative Procedure AP AP-10.1 Management of Station Records Page 24 of 34 AP-3.7.1 Rev. 03
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ATTACHMENT 2: SOLID WASTE SOURCES (Sheet 1 of 2) 1.0 RADWASTE FILTERS 1.1 Mechanical radwaste filters filter resin and crud (backwash material) from the waste collector sub-system.
1.2 When a filter reaches a pre-determined differential pressure, the filter backwashes the material into the backwash tank, which is then pumped to the spent resin tank.,
2.0 RADWASTE DEMINERALIZERS 2.1 The radwaste demineralizers are used as an ionic exchange media for processing high quality water from the waste collector tanks.
2.2 When determined the resin can NO longer be regenerated, the depleted resin is pumped to the spent resin tank.
3.0 CONDENSATE DEMINERAI IZER 3.1 The condensate demineralizers remove soluble and insoluble impurities from the condensate water to maintain reactor feedwater purity.
3.2 After it is determined these resins can NO longer be regenerated, the depleted resins are pumped to the spent resin tank.
4.0 FLOOR DRAIN FILTER 4.1 The floor drain filter contributes to solid waste because the filter uses diatomaceous earth to process liquid waste of low quality. Input to the filter is from the floor drain system and the regeneration waste tank.
4.2 When the filter r'caches a pre-determined pressure drop the filter backwashes to the waste sludge tank for processing through the extruder/evaporator.
5.0 SPENT FUEL PHASE SEPARATOR These tanks receive the exhausted powdered filter media (resins) from the fuel pool cleanup system which is subsequently pumped to the spent resin tank.
6.0 RWCU PHASE SEPARATOR These separator tanks receive exhausted powdered filter media (resins) from the water cleanup system which is subsequently pumped to the spent resin tank.
Page 25 of 34 AP-3.7.1 Rev. 03
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ATTACHMENT 2: SOLID WASTE SOURCES (Cont)
(Sheet 2 of 2) 7.0 CONTAMINATED OIL Oil from sources within Unit 2 that become contaminated are stored in containers to be solidified by a vendor with an approved procedure.
8.0 COMPACTIBLE SOLIDS 8.1 Compactible low level trash is processed and compacted in a hydraulically operated box compactor.
8.2 Shoe covers, trash, contaminated paper from the chemistry lab, and similar materials are included in this category.
9.0 FILTERS AND MISCELLANEOUS ITEMS Solid items with high dose rates are handled on a case-by-case basis, being disposed of by methods acceptable to the burial site.
10.0 WASTE EVAPORATOR 10.1 The waste evaporator processes low quality waste from the floor drain collector system and, as an option, waste from the waste discharge tanks.
10.2 The waste evaporator is designed to concentrate the waste to a 25%
solid concentration. The concentrates are then discharged to the evaporator bottoms tank for processing through the extruder/evaporator.
11.0 REGENERANT EVAPORATOR The regenerant waste evaporator receives regeneration solutions from the condensate demineralizer system and radwaste demineralizer resin regeneration system as well as the radwaste regeneration sump.
11.2 The regenerant waste evaporator is designed to concentrate to a 25% by weight solid concentration of sodium sulfate.
11.3 The concentrates are then discharged to the evaporator bottoms tank to be processed through the extruder/evaporator.
12.0 SPENT RESIN STORAGE TANK 12.1 Exhausted resin from the condensate demineralizer, the radwaste demineralizer, RWCU phase separator, the spent fuel pool phase separator, and the radwaste filter backwash tanks are sluiced to the spent resin storage tank.
12.2 The waste from the spent resin storage tank is pumped to the waste sludge tank for processing through the extruder/evaporator.
Page 26 of 34 AP-3.7.1 Rev. 03
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~r e ATTACHMENT 3'ROCESS CONTROL FLOWPATH Start Pre-Req Asphalt Sampled.N2.CSP-14 2N SS.OP.41 N2.CSP-14 N2-WHP-9 B Isolate and Mix Sample Waste Form Chemical Analysis N2-WHP.10 B WSS-OP-41 N2-WHP-9 N2-WHP.88 N2-WHP.QA N2-'WHP.4 Process Waste Form N2-WHP.9B N2.WHP.11 N2:WHP-12 S-RP.6 To Storage P. T.
Classify. Label and or Ship for N2-WHP-9 Store Waste Form Disposal N2.CSP-14 N2.WHP-2 S.RP.6 Prepare Manliest N2.WHP-2 Notification Ior Shipping to Disposal Site Close Rte N2-WHP.2 N2-WHP-2 On Waste Form S.RP-6 Ship Waste Form Close F8e Waste Received Investigate N2.WHP.2 On Waste Form At Disposal Site Disposal Site If needed, follow tlute to N.R.C.
N2-WHP-2 Page 27 of 34 AP-3.7.1 Rev. 03
Reactor Water Clean Up Phase Separator Spent Fuel Phase Separator Condensate Radwaste Demineraizers Radwaste Demineralizers Radwaste Boor Drain Filter Spent Filters Resin To Floor Tank Drain Waste Sludge Waste Tank Evaporator FLT Waste Tank Evap. Sludge oo er Bottoms Mete ring C
~~
Tank Ptsnp Distillate Collection Waste Sudge Pump Steam Domes Evaporator Evaporator Bottoms Metering Bottoms p Pum Vent ube Oit EXTRN)ER/EVAPORATOR sphal Pumps Cooler Tank Cool Down Lube Oil Filter Fill Area Tank Station M 0
n Asphalt Metering
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ATTACHMENT 5: OPERATOR WORKSHEET (Reproduced from N2-WHP-9, Process Control for Asphalt Systems) 10,2 Operator Norksbeet 10.2.1 batch Nunber A batch ia considered (1) ~ saepled Sludge Ty, or (2) a saepled EVAP bottoas tank rich no waste being added co the tank during che processing of that batch NOTEs Batch nuaber will consist of; BA (batch Asphalt), year, enl a four digit successive nunber, (beginning with 001) ~
Ezi bA 84 001 Unit Tear Batch Nunber 10.2.2 Tnla oi Vista iuia/tilter Maiia Coaeeaeeite lfaita A) Vesta Teaperature b) Red Level C) Specific ravity
- 0) pN E) I P) Z Solid
- 0) Activity Ci/ei 10.2.3 Peed Plow Settings 10.2.3.1 Asphalt Peed Plow Settings 10o2.3.2 Nests Peed Plow Sate 10.2.4 Radioactive nate A) Radio b) Othe 10.2.4.1 Vesta con ns la e4 in respect to $ %~.
NOTEt Labels with the approyriate data will be supplied to tbe Radwaste Operator bp cbe Radiation Protection Departnent/Cheaistry Departeenc. The operator susC label container, 10.2 5 Radioactive wasCe classifica'cion A) Class A NasCe B) i Ci ~ I~ II~ ILQ C> ciaI ~ C llaiie 10.2.5.1 Vesta container labeled in respect to SAP-O.
NOTEC The radwaste operator will receive labels end sacking froe che Radiatioa yroceccioe Departnant ~ The rsdwste operacer will label coatainersi Page 29 of 34 AP-3.7.1 Rev. 03
Ti ta ATTACHMENT 'EMPERATURE PROFILE LOG (Reproduced from N2-WHP-9, Process Control for Asphalt Systems) 10.3 1 Tesperatsre Profile Log Record of Tasperature in Degree op every tso hours of run tine for a particular batch TTPH Oy QASTH bATCH Nmmba STAHT TIKH batch p 1 2 3 4 5 6 7 Initials/Tine Norsal Tespi Sludge 165 265 300 330 375 375 350 Norsal Tesp. Conc. Haste 16$ 265 385 300 285 285 230 After 2 Hours After 4 Hours After 6 Hours After 8 Hours After 10 Hours After 12 Hours After 14 Hours After 16 Hours After 18 Hours After 20 Hours After 22 Hours After 24 Hours 10.3.2 Did tcsperature profile resain vithin lisits7 NOTXt The tesperaturs profile should be sonitored constantly but wet be logged every tso hours.
Page 30 of 34 AP-3.7.1 Rev. 03
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ADDRESS PO Box 728. Bamwel. South Caro(tns 29812 SIOPPINO DATE 4 (803) 259-178(
RAO(OACT(VE SHIPMENT MANIFEST FORM (5) AADOACTIYE WASTE TRANSPORTATION PEAIST NO.
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