ML18009A908
| ML18009A908 | |
| Person / Time | |
|---|---|
| Site: | Harris |
| Issue date: | 03/22/1991 |
| From: | Decker T, Seymour D NRC OFFICE OF INSPECTION & ENFORCEMENT (IE REGION II) |
| To: | |
| Shared Package | |
| ML18009A907 | List: |
| References | |
| RTR-NUREG-0737, RTR-NUREG-737 50-400-91-03, 50-400-91-3, NUDOCS 9105290097 | |
| Download: ML18009A908 (16) | |
See also: IR 05000400/1991003
Text
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UNITED STATES
NUCLEAR REGULATORYCOMMISSION
REGION II
101 MARIETTASTREET, N.W.
ATLANTA,GEORGIA 30323
SlR2 P ]ggt
Report No.:
50-400/91-03
Licensee:
Carolina
Power and Light Company
P. 0.
Box 1551
Raleigh,
NC
27602
Docket Nos.:
50-400
Facility Name:
Shearon Harris Nuclear
Power Plant
Inspection
Con
ted:
F bruary 25 - March 1,
1991
Inspector:
D. A. Sey our
License No.:
D te
igned
Accompanying Personnel:
K. G..McNeill
/a
Approved by:
.
R.
Dec er,
ref
Radiological Effluents
and Chemistry Section
Radiological Protection
and
Emergency
Preparedness
Branch
Division of Radiation Safety
and Safeguards
2Z/i/
Date. Signed
SUMMARY
Scope:
This routine;
unannounced
inspection
was
conducted
in the
areas
of the
Post-Accident
Sampling
System
(PASS),
audits
and
appraisals,
confirmatory
measurements,
the
Energy
and
Environmental
Center,
chemistry
procedures,
and
the Spent
Fuel Pool.
Results:
The
Crud
Task
Force
recommended
that
the
spent
fuel
be
cleaned
prior to
shipment.
Corporate
management
approved
these
recommendations
on December
14,
1990.
The cleanup of the spent fuel pools
and transfer canals
had progressed
well.
One violation was
determined
in the Post Accident Sampling
System
due to the
lack of
a
procedure
for the
removal
of
a post-accident
undiluted liquid
sample
from the shielded container
in which it is collected.
One
deviation
was
also
determined
for failure to
meet
a
commitment
to
semiannual
retraining of all technicians
who could
be required to obtain
samples.
The status
of procedure
development,
training procedures,
as well
, as further examination
of knowledgeability of NUREG-0737 criteria were areas
needing
improvement.
9105Z90097
910327
ADOCK 05000400
G
REPORT
DETAILS
Persons
Contacted
. Licensee
Employees
G.
D.
- M
- C
S.
- B
- R
- G
- C
M,
D.
- B
- M.
- F
D.
- M
T.
- W
Baker, Nuclear Assessment
Department
(NAD)
Boley, Technician,
Environmental
and Chemistry
(EKC)
Elkins, Shipment Director, Spent Nuclear Fuel
Hamby, Project Specialist,
Regulatory
Compliance
Hinnant, Plant General
Manager
Johnson,
Chemistry
Foreman
Meyer, Manager,
Environmental
and Radiation Control
(ESRC)
Morgan, Manager,
Nuclear Assessment
Nathan,
Senior Specialist,
EKRC
Olexi k, Manager,
Regulatory
Compliance
Pate,
Manager, Training, Harris Energy and Environmental
Center
(ESEC)
Redmond, Technician,
Sears,
Foreman,
E&C
Station, Site Representative,
Power Agency
Strehle,
Manager, guality Assurance
Engineering
Tysinger, Technician,
EEC
Wallace, Senior Specialist,
Regulatory Compliance
Williams, Manager,
Health Physics
and Chemistry Training,
ELEC
Wilson, Manager,
Spent Nuclear
Fuel
Other
licensee
employees
contacted
during this
inspection
included
engineers,
operators,
technicians,
and administrative
personnel.
NRC Inspectors
M.'hannon,
Resident
Inspector
W. Stansberry
- Attended exit interview
and Initialisms
used
throughout this report
are listed in the
last paragraph.
Post Accident Sampling
System
(PASS)
(84750)
NUREG-0737, Criterion
2a provides specifications for the establishment
of
'nsite
radiological
analysis
capabilities
to provide quantification of
noble
gases,
and non-volatile
radionuclides
in the
reactor
coolant
system
(RCS)
and containment
atmosphere.
Technical Specification (TS) 6.8.4.e
requires
that
a
program
be established,
implemented
and
maintained
to ensure
the capability to obtain and analyze,
.under accident
conditions, reactor coolant, radioactive
and particulates
in 'plant
gaseous
effluents,
and
containment,
atmosphere
samples.
The
should
provide
these
capabilities,
and
should
enable
the licensee
to obtain
information critical to the efforts to assess
and control the course
and
effects of an accident.
Pursuant
to
these
specifications,
the
inspector
reviewed
portions of,
selected
procedures
for the operation,
maintenance,
and testing of the
PASS,
and
di.scussed
system operation,
performance testing,
and analytical
capabilities of the
PASS with the licensee.
The inspector also observed
EKC technicians
obtain
PASS samples.
The inspector
reviewed
selected
portions of two procedures
dealing with
the
operation
and
maintenance
of the
PASS.
These
procedures
were
No.
CRC-821, entitled "Postaccident
RCS/RHR Sampling," dated
May 9,
1989;
and
No.
CRC-830,
entitled
"Periodic
Maintenance
and
Operability
Verification of the
PASS,"
dated
May 20,
1988.
The portions reviewed were
adequate for their intended
purpose.
The inspector
determined
through discussions
with the license'e,
that
as
part of operation of the
PASS,
the capability existed for the collection
of
a post-accident,
undiluted,
ten milliliter, liquid reactor
coolant
'ample
in an shielded
container
or "pig." This sample
could s'erve several
functions. It could
be sent to
an off-site vendor, still in the pig, for
isotopic
or chloride analysis,
or it could
be
analyzed
on site for
by the li'censee,
after
a thirty day decay time.
The inspectors
determined,
at the time of this inspection, that the licensee
did not have
a procedure for the removal of this sample
from the pig.
The inspector
considered
the lack of this procedure
to be
a violation of
TS 6.8. 1 a,
which requires
that written procedures
be established
and
implemented.
Since this is
an anticipated
sampling
point following an
accident,
the inspectors
believe that
a procedure
covering the sampling,
including the
removal of the
sample
from the pig, should
be developed
and
tested.
Due to the nature
and timing of this sample, it could
be expected
to have
a very high activity level. Considering this, the use of "generic"
site
procedures
for handling radioactive materials
might not ensure
the
safety of the technician
who would
have to
remove this sample, for the
first time ever, with little prior training and with instructions that had
not
been verified
as effective.
The inspectors
did not consider
the
possibility of developing this procedure
during the thirty day decay time
as
appropriate.
The
reduction
or elimination
of
any
unnecessary
uncertainties
following an accident
would obviously increase
the overall
effectiveness
of the licensee's
program for dealing with an accident.
Another
consideration
was
the
possible
importance
of
sample
volume
changes
and/or dilution factors that
may
be associated
with the
removal
of this
sample
from the pig.
This
knowledge, if needed,
would help
ensure
that
the
licensee
could
accurately
quantify
chosen
sample
parameters
upon analysis.
Site
management,
durino the exit interview,
committed to the
development
of
a procedure
to
r'emove this
sample
from
the pig (Violation 50-400/91-03-01).
3
The
inspector
also
reviewed
the training that
the
ETC technicians
received
on the
PASS.
This included interviews with the licensee,
and
a
document
review.
The
inspectors
determined
that'ew,
or previously
untrained,
technicians
would initially receive eight hours of training on
the
PASS, with annual
retraining of two hours
a year thereafter.
This
training
was
not
"hands-on,"
training.
The- hands-on
training
was
accomplished
during the required quarterly operability verification of the
PASS.
The inspector
determined that there
were nineteen
ETC technicians;
twelve
of these
technicians
were qualified to operate
the
PASS (i.e.
had received
the initial and
annual
retraining)
and
were
also respirator qualified
(which would
be required
to operate
the
during
an emergency).
A
review of records for 1988,
1989,
1990
and
1991 to date,
indicated that
only
a small portion of these technicians
were receiving opportunities to
operate
the
PASS during the quarterly
checks.
Two of the technicians
operated
the
a majority of the time, five had operated
the
PASS once
or twice,
and five of the technicians
had not received
the opportunity to
'perate
the
PASS during the quarterly checks.
During discussions
with the inspector,
the licensee
indicated that
any
one of the qualified technicians
could be required to obtain
a
sample
following an accident.
The inspectors
also
determined that the licensee
was
not tracking'his
type of training for the technicians,
as this
information
was
not readily available
when
requested,
and
had to
be
generated
from several
different
documents.
The licensee
was also not
aware that
CPSL
had committed,
in
a letter to headquarters
dated
Yiay 18,
1986, to semiannual
retraining of the technicians
who could
be required to
operate
the
PASS. This retraining
was to be performed in conjunction with
the quarterly operability verification testing of the
PASS.
The inspectors
considered
the failure to meet this
commitment
a deviation
(Deviation
50-400/91-03-02).
The inspector
discussed
this with the licensee,
and the licensee verbally
committed to tracking the training of their technicians
to ensure that the
semiannual
retraining
commitment
on the
PASS would be met.
The licensee
also
indicated
that
they
might specify
which technicians
would
be
considered
qualified to operate
the
PASS system,
thus reducing the number
of technicians
who would require
semiannual
retraining
on the
PASS.
The
effect of this proposed
reduction in the
number of technicians
qualified
to operate
the
PASS, if implemented,
would
be
examined
by regional
inspectors
in terms of the safety significance
and effectiveness
of the
PASS program,
during
subsequent
inspections.
As part of the
review,
the
inspectors
also
examined
PASS quarterly
-Operability Yerification Test Results for 1987,
1988,
1989,
1990,
and
1991
to date.
These
records
summarized
the results of the quarterly tests
in
terms of passing
or fai ling the
comparisons
between
analyses
and
routine
sampling,
as
detailed
in
Criteri'on
10
and-
Attachment
No ~
1 to the Generic Letter.
These
analyses
included:
isotopic activity,
and
for diluted
RCS liquid; dissolved
and isotopic activity for'stripped
RCS gas; in-line pH, in-line
dissolved
and in-line hydrogen;
and
gas activity and
activity for containment air.
Inspection
Report
No.
50-400/90-12-
had
previously detailed
a poor history of meeting the
PASS acceptance
criteria
for several
of these tests,
and
had indicated
a continuing problem with
the stripped
gas results
and with the in-line pH, dissolved
and
At the time of this inspection
several
of these
problems
had
been eliminated;
however, there were continuing problems with stripped
gas
isotopic results.
The inspectors
determined that the
was continuing
to receive
attention
and
support,
from the
system engineer
and Technical
Support organization.
The
inspectors
questioned
the
usefulness
of comparing
the
isotopic
activity of a highly diluted
sample to
a
much less diluted, primary
reactor
coolant
sample,
as
a
means
to determine
PASS operability.
The
point of this comparison is to verify that the
PASS system operates,
and
that
the dilution ratios
and
sample
volumes
have
been
accurately
determined.
In cases
where the fuel integrity was high,
as at Harris, the
highly diluted
samples
may
not contain
enough activity to
be
detected.
This results in comparisons
being performed
between
samples with
activity levels below the "lower limit of detection" with samples
from the
primary
RCS,
which
have
measurable
activity.
The
licensee
agreed
to
investigate
the possibility of improving the
comparisons,
by either
increasing
the volume of the
PASS sample,
or by increasing
the count time.
The inspectors
also
observed
two
EKC technicians
obtain
PASS samples,
and
one
E&C technician
obtain
a
primary
sample.
In
each
case,
the
appropriate
procedures
were
followed,
proper
sampling
techniques
and
health
physics
practices
were
observed,
and
the
technicians
seemed
knowledgeable
and competent.
The sampling
and analysis of the
PASS samples
were accomplished
in under three hours,
meeting the criteria in NUREG 0737
for the
time limit on sampling
and analysis.
The analysis for boron
was
not performed
because
the level of boron in the
was
72 parts
per
billion (ppb).
The tremendous
dilution of the liquid- PASS sample
(1000: 1)
prevents
boron analysis if the
boron level is
below
500 ppb.
The
stripped
gas isotopic activity results
did not meet
NUREG 0737 acceptance
criteria.
All other
parameters
passed.
The inspectors
determined
that
there
was
an ongoing effort by the system engineer to determine
the cause
of this
disagreement.
The inspectors
did not observe
containment air
sampling.
The inspectors
also discussed,
with the system engineer,
the ability to
provide
an alternate
source of power to the
PASS, in the event of the loss
of site
power during
an accident.
The
system
engineer
indicated,
on at
least
two occasions,
that this capability did not exist.
The inspectors
discussed
this with site
management,
and
pointed- out that
an alternate
power source
was required
by the criteria of NUREG 0737.
The licensee
then
'determined,
and
discussed
with the inspectors,
that
an alternate
power
source
did exist, in that the
PASS could
be
powered
by the site diesels.
The inspectors
discussed
the procedure
by which this would be accomplished
with the licensee
by telephone
on March 6,
1991.
The inspectors
considered
the
program to be adequately
implemented
and maintained;
with areas
in procedure
development,
technician training,
and knowledgeability of NUREG-0737 criteria needing
improvement.
One violation and one deviation 'were identified.
3.
Audits,and Appraisals
(84750)
TS 6.5.4. 1 requires
the licensee's
Corporate guality Assurance
Department
(C(AD) to perform periodic
audits
of Facility activities,
including:
training
and qualification of the facility staff;
the
Radiological
Environmental
Monitoring Program
(REMP);
the Offsite
Dose Calculation
Manual
(ODCM); and the Process
Control
Program
(PCP).
These audits provide
assurance
that these
programs
are properly and effectively implemented.
Pursuant
to these
requirements,
the inspector discussed
the status of the
C/AD with cognizant licensee
personnel.
The inspector
determined that the
licensee's
C(AD department
had
been
recently
reorganized
in December,
1990, with an approximately
50 percent
reduction in personnel,
and
was
renamed
the Nuclear Assurance
Department
(NAD). As with the C(AD, the
NAD
has
branches
at
each
CPKL site
and in Raleigh;
and
the organization
continued
to
be responsible
to corporate
management
in Raleigh.
The
licensee
explained that the focus'f the
new organization
was different
from the old.
The
focus of the
NAD will be to identify problems
and
anticipate
and
im'plement changes,
not just react to findings. Additional
details
of the
new organization
can
be
found in Inspection
Report
50-324,325/91-04.
The inspectors briefly reviewed
the guality Assurance
Audits conducted
in
1989
and
1990.
These
audits
were conducted
over
an approximate
two week
time frame with five to seven, auditors,
and covered
a very broad
scope.
The inspectors
determined that there were
no significant audit findings in
the areas of the
REMP,
ODCM, or the
PCP.
Although the concept of the
NAD appeared
to
be
an
improvement over the
C(AD, the
inspectors
considered it premature
to
make
any conclusions
concerning its effectiveness,
since this organization
was still in its
infancy
and
required further development,
planning
and
implementation.
This area will be reviewed during subsequent
regional inspections.
No violations or deviations
were identified.
4 ~
Confirmatory Measurements
(84750)
As part of the
NRC Confirmatory
Measurements
Program,
spiked liquid
samples
were
sent
to
SHNPP for selected
radiochemical
analyses.
The
samples
were
received
by Harris in October
1990.
The
NRC received
the
.
analytical
results
from
CPSL in
a letter dated
December
10,
1990.
The
comparison
of licensee
results
to
known
values
are
presented
in
Attachment
1.
The acceptance
criteria for the comparisons
are presented
in
Attachment
2.
The results
were all in agreement.
No violations or deviations
were identified.
5.
I
Energy and Environmental
Center
(EEEC)
and Chemistry Procedures
Technical Specification (TS) 6.8. 1 requires
written procedures
to
be
established,
implemented
and maintained for the equality Assurance
Program
for effluent and environmental
monitoring.
Inspection
Report
No.
50-400
(90-21 detailed
a violation (failure to
properly
implement
a radiochemistry
procedure)
for failure to add nitric
acid to liquid samples
prior to counting
as required
by TSs.
This report
detailed
the licensee's
study to qualify the effects of not treating
liquid samples
with nitric acid prior to compositing
and analyzing.
At
that
time
the
licensee
decided
to perform
a
more
thorough
study to
quantify the effects of not acidifying liquid samples.
During this inspection
the results
of the effects of acidification of
liquid samples
were
reviewed.
CPSL
Memorandum,
Serial
891LF5013
was
discussed
at
length
with the
Senior
Specialist-Environmental.
The
memorandum
described
two sets
of samples
which were
counted for
gamma
spectroscopic
analysis
and aliquots
which were
analyzed
for Iron-55,
Strontium-89,
and Strontium-90.
Several
flaws were noted in the samples of BNP reactor coolant which were
analyzed for
gamma activity.
The samples
were "aged", or left standing
for an unspecified
amount of time; composited,
and
then diluted.
The
samples
were then counted over an eight hour period without acidification.
An examination of the activities reported yielded very little in the way
of direct information which
can
be of use
as
there is
no comparison
between acidified and non-acidified
samples.
Any plating out of-isotopes
may have already occurred
and the time of eight hours is not comparable
to
that which might be encountered
in monthly composite
samples.
The Senior
Specialist-Env.
stated that this portion of the analyses
may
be repeated
to correct the aforementioned
limitations.
The
second
section of the
memorandum dealt with three analyses;
Iron-55,
Strontium-89,
and Strontium-90.
One liter aliquots of deionized
water
were spiked with known activities of these
isotopes
and the samples
were
stored for thirty days.
The Iron-55 samples
showed
a significant (up to twenty percent)
difference
in the
amounts
recorded
as
gamma activity.
Those
samples
which were not
acidified yielded
a consistently
lower activity than
those
which were
acidified.
Based
on
these
analyses
the
July
1-December
31,
1990
SemiAnnual
Radioactive
Effluent Release
Report
was
changed
to reflect
this twenty percent
increase
in activity.
This amount of change
had
no
significant impact
on the overall effluent releases
from
SHNPP for the
time frame noted.
The Strontium-90
samples
were subjected
to the
same analysis
parameters
as
above.
Larger (750 ml
as
opposed to 50 ml) aliquots were analyzed for this
portion of the study.
The analyses
yielded very little (less. than five
" percent)
difference in the acidified and non-acidified samples.
Due to
a
spiking error
in the
Strontium-89
samples
these
analyses
were
not
performed.
Strontium analysis
requires
many steps
leading to preparation
of the isolated. strontium precipitate
which is analyzed for beta activity.
Among these
steps
are several
additions of acid to the aliquot which may
or may not account for the relatively minor difference in the reported
activities.
RESL ~et al)have demonstrated
significant "plating" of gamma nuclides
(such's
Iron-55 and Cobalt-60)
onto collection container
surfaces.
The
analyses
provided
by
CP&L in
Memorandum
h'91LFS013
in part,
at least,
substantiates
those conclusions.
The
inspectors
also
toured
the
Energy
and
Environmental
Center
Laboratories
(ESEC)
and
discussed
analysis
parameters
and
laboratory
equipment to gain familiarity with operations.
Based
on this selective
review, the actions
taken concerning revision of
the
1990 Radioactive Effluent Release
Report
appeared
to be appropriate.
Further revisions
may
be necessary
dependent
upon further examination
by
the
ESEC
personnel.
Appropriate
procedures
were in place'o
prevent
recurrence
of the failure to add nitric acid to liquid samples.
Ho violations or deviations
were identified.
Spent
Fuel
Pool
(SFP) Facility (84750)
The inspectors
met with licensee
representatives
to discuss
the status of
the continued
cleanup of the Spent
Fuel
Pools.
Items discussed
with the
licensee
included
those
described
in
NRC
Inspection
Report
No.
50-400/90-22.
Particular
emphasis
was
placed
on the progress
made in
the filtration process,
status
of the fuel
pools at present,
and the
disposition
of Corporate
Task
Force
recommendations
concerning
the
treatment of spent fuel received
from other sites.
The licensee
representative
outlined the current cleanup
under way on 2-3
canal.
The filters
had
been effective in reducing
crud deposited
on
fuel pool surfaces,
and
on removal of fine particles in suspension
in the
pool water.
Eight spent filters were stored in
D pool.
These filters were
replaced
upon reaching
a maximum differential pressure
of 20 psi
(planned
maximum
was
60 psi)
and
have
a worst case
contact
reading of 200 R/hour
(planned
maximum was
300-400 R/hour).
Cleanup
had
been
completed
on the
1-4 canal
and
the main pool.
The licensee
representative
stated
that
they planned
to reclean
the
1-4 transfer
canal
as well as the transfer
tube prior to refueling.
The licensee
planned
on suspending
cleaning of
the fuel pools during the outage,
and
resume
when refueling was completed.
The licensee
described
an'nomaly
observed
in the water condition of the
2-3 canal.
awhile work was
ongoing in the
canal
the water clarity was
fairly clear.
Overnight, over
a time period of approximately eight to ten
hours,
while
no work was
ongoing,
the
pool
suddenly
turned
opaque
and
green in color.
The licensee
continued
to operate
the filters passively
with the suction
head
not in contact with any surface.
The pool returned
to clarity after
48 to
72 hours8.333333e-4 days <br />0.02 hours <br />1.190476e-4 weeks <br />2.7396e-5 months <br />.
The licensee
representative
stated that
.the cause of this transformation
was not known and that Corporate
Chemistry
representatives
were currently examining this phenomenon.
The licensee
representative
also discussed
with the inspectors
the status
of Task
Force
Recommendations
concerning
future processing
of offsite
spent fuel shipments
and the handling of spent fuel shipments
upon receipt
at
SHNPP.
The Task
Force
has
recommended
that the fuel
be cleaned
at
Brunswick Steam Electric Plant
(BSEP) prior to shipment.
The Task Force
also
recommended
the
vendor for implementation
of these
processes.
The recommendations
were
approved
by Corporate
on December
14,
1990.
No
formal
announcements
have
as yet
been
announced
nor have
the
necessary
contracts
been formalized.
Based
on this review, the actions
taken to cleanup
the fuel pools appear
to
be effective.
This
area
will
be
reviewed
during
subsequent
regional
inspections.
No violations or deviations
were identified.
Exit Interview
The inspection
scope
and results
were
summarized
on
Yiarch 1,
1991 with
those
persons
indicated
in Paragraph
1.
The inspectors
described
the
areas
inspected
and discussed
in detail
the inspection 'results
as listed
in the
summary.
Proprietary information is not contained
in this report.
Dissenting
comments
were not received from the licensee.
Item No.
50-400/91-03-01
50-400/91-03-02
and Initialisms
Description
and Reference
Violation - Lack of a procedure for the
removal of a
PASS sample
from a shielded
container
(Paragraph
2).
Deviation - Failure to train technicians
qualified to operate
the
PASS on a
semiannual
basis
(Paragraph
2).
Program
es Laboratory
BNP - Brunswick Nuclear Plant
BSEP - Brunswick Steam Electric Plant
BMR - Boiling Mater Reactor
CFR - Code of Federal
Regulation
CP8L, - Carolina
Power and Light Company
CLEAD - Corporate guality Assurance
Department
ESEC - Energy and Environmental
Center
EKRC - Environmental
and Radiation Control
ERC - Environmental
and Chemistry
mR/h - milliRoentgen
per, hour
NAD - Nuclear Assurance
Department
NRC - Nuclear Regulatory
Commission
NRR - Nuclear Reactor Regulation
OOCYTE - Offsite Dose Calculation
Yianual
PASS - Post Accident Sampling
System
PCP - Process
Control
Program
ppb - parts
per billion
PMR - Pressurized
Mater Reactor
REHP - Radiological
Environmental
Monitoring
RESL - Radiological
and Environmental
Scienc
SFP - Spent
Fuel
Pool
SHNPP - Shearon Harris Nuclear
Power Plant
TS - Technical Specification
10
ATTACHMENT 1
CONFIRMATORY MEASUREMENT COMPARISONS
OF H-3,
Fe-55, Sr-89,
AND Sr-90
ANALYSES FOR
HARRIS NUCLEAR PLANT REPORTED
ON
DECEMBER 10,
1990
~isoto
e
Sr-89
NRC
~uC i /ml )
5.59 +0.22 E-5
4. 06 +0. 16 E-5
7.29 +0.29 E-5
2.17 +0.09 E-6
Licensee
~uC i /ml
5.59 E-05
3.90 E-05
6.57 E-05
1.92 E-06
Resolution
25
25
25
Ratio
Licensee/NRC
~Com ariso
1.00
Agreement
0.96
Agreement
0.90
Agreement
0.88
Agreement
ATTACHMENT 2
CRITERIA FOR
COMPARISONS
OF ANALYTICALMEASUREMENTS
This attachment
provides criteria for the comparison of results of analytical
radioactivity
measurements.
These
criteria
are
based
on
empirical
relationships
which
combine
prior experience
in
comparing radioactivity
analyses,
the
measurement
of the statistically
random process
of radioactive
emission,
and the accuracy
needs of this program.
In
these
criteria,
the
"Comparison
Ratio
Limits"~ denoting
agreement
or
disagreement
between
licensee
and
NRC results
are variable.
This variability
is
a function of the ratio of the
NRC's analytical
value relative to its
associated
statistical
and analytical uncertainty,
referred to in this program
as "Resolution"~.
For comparison
purposes,
a ratio between
the
1icensee's
analytical
value
and
the NRC's analytical value is computed for each radionuclide present in a given
sample.
The
computed ratios
are
then evaluated for agreement
or disagreement
based
on "Resolution."
The
corresponding
values
for,"Resolution"
and the
"Comparison
Ratio Limits" are listed" in the Table
below.
Ratio va1ues
which
ar'e either above or below the "Comparison Ratio Limits" are considered
to be in
disagreement,
while ratio values within or encompassed
by the "Comparison Ratio
Limits" are considered
to be in=agreement.
TABLE
NRC Confirmatory Measurements
Acceptance Criteria
Resolution vs.
Comparison
Ratio Limits
Resolution
Comparison
Ratio Limits
for A reement
<4
.,4"
7
8-15
16 - 50
51 - 200
>200
0.4 " 2.5
0.5 - 2.0
0.6 - 1.66
0.75 - 1.33
0.80 - 1.25
0.85 - 1.18
'Comparison
Ratio = Licensee
Value
NRC Reference
Value
~Resolution
=
NRC Reference
Value
Associated
Uncertainty