ML18009A908

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Insp Rept 50-400/91-03 on 910225-0301.Violations & Deviation Noted.Major Areas Inspected:Pass,Audits & Appraisals, Confirmatory Measurements & Chemistry Procedures
ML18009A908
Person / Time
Site: Harris 
Issue date: 03/22/1991
From: Decker T, Seymour D
NRC OFFICE OF INSPECTION & ENFORCEMENT (IE REGION II)
To:
Shared Package
ML18009A907 List:
References
RTR-NUREG-0737, RTR-NUREG-737 50-400-91-03, 50-400-91-3, NUDOCS 9105290097
Download: ML18009A908 (16)


See also: IR 05000400/1991003

Text

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UNITED STATES

NUCLEAR REGULATORYCOMMISSION

REGION II

101 MARIETTASTREET, N.W.

ATLANTA,GEORGIA 30323

SlR2 P ]ggt

Report No.:

50-400/91-03

Licensee:

Carolina

Power and Light Company

P. 0.

Box 1551

Raleigh,

NC

27602

Docket Nos.:

50-400

Facility Name:

Shearon Harris Nuclear

Power Plant

Inspection

Con

ted:

F bruary 25 - March 1,

1991

Inspector:

D. A. Sey our

License No.:

NPF-63

D te

igned

Accompanying Personnel:

K. G..McNeill

/a

Approved by:

.

R.

Dec er,

ref

Radiological Effluents

and Chemistry Section

Radiological Protection

and

Emergency

Preparedness

Branch

Division of Radiation Safety

and Safeguards

2Z/i/

Date. Signed

SUMMARY

Scope:

This routine;

unannounced

inspection

was

conducted

in the

areas

of the

Post-Accident

Sampling

System

(PASS),

audits

and

appraisals,

confirmatory

measurements,

the

Energy

and

Environmental

Center,

chemistry

procedures,

and

the Spent

Fuel Pool.

Results:

The

Crud

Task

Force

recommended

that

the

spent

fuel

be

cleaned

prior to

shipment.

Corporate

management

approved

these

recommendations

on December

14,

1990.

The cleanup of the spent fuel pools

and transfer canals

had progressed

well.

One violation was

determined

in the Post Accident Sampling

System

due to the

lack of

a

procedure

for the

removal

of

a post-accident

undiluted liquid

reactor coolant

sample

from the shielded container

in which it is collected.

One

deviation

was

also

determined

for failure to

meet

a

commitment

to

semiannual

retraining of all technicians

who could

be required to obtain

PASS

samples.

The status

of procedure

development,

training procedures,

as well

, as further examination

of knowledgeability of NUREG-0737 criteria were areas

needing

improvement.

9105Z90097

910327

PDR

ADOCK 05000400

G

PDR

REPORT

DETAILS

Persons

Contacted

. Licensee

Employees

G.

D.

  • M
  • C

S.

  • B
  • R
  • G
  • C

M,

D.

  • B
  • M.
  • F

D.

  • M

T.

  • W

Baker, Nuclear Assessment

Department

(NAD)

Boley, Technician,

Environmental

and Chemistry

(EKC)

Elkins, Shipment Director, Spent Nuclear Fuel

Hamby, Project Specialist,

Regulatory

Compliance

Hinnant, Plant General

Manager

Johnson,

Chemistry

Foreman

Meyer, Manager,

Environmental

and Radiation Control

(ESRC)

Morgan, Manager,

Nuclear Assessment

Nathan,

Senior Specialist,

EKRC

Olexi k, Manager,

Regulatory

Compliance

Pate,

Manager, Training, Harris Energy and Environmental

Center

(ESEC)

Redmond, Technician,

ESC

Sears,

Foreman,

E&C

Station, Site Representative,

Power Agency

Strehle,

Manager, guality Assurance

Engineering

Tysinger, Technician,

EEC

Wallace, Senior Specialist,

Regulatory Compliance

Williams, Manager,

Health Physics

and Chemistry Training,

ELEC

Wilson, Manager,

Spent Nuclear

Fuel

Other

licensee

employees

contacted

during this

inspection

included

engineers,

operators,

technicians,

and administrative

personnel.

NRC Inspectors

M.'hannon,

Resident

Inspector

W. Stansberry

  • Attended exit interview

Acronyms

and Initialisms

used

throughout this report

are listed in the

last paragraph.

Post Accident Sampling

System

(PASS)

(84750)

NUREG-0737, Criterion

2a provides specifications for the establishment

of

'nsite

radiological

analysis

capabilities

to provide quantification of

noble

gases,

iodines,

and non-volatile

radionuclides

in the

reactor

coolant

system

(RCS)

and containment

atmosphere.

Technical Specification (TS) 6.8.4.e

requires

that

a

program

be established,

implemented

and

maintained

to ensure

the capability to obtain and analyze,

.under accident

conditions, reactor coolant, radioactive

iodines

and particulates

in 'plant

gaseous

effluents,

and

containment,

atmosphere

samples.

The

PASS

should

provide

these

capabilities,

and

should

enable

the licensee

to obtain

information critical to the efforts to assess

and control the course

and

effects of an accident.

Pursuant

to

these

specifications,

the

inspector

reviewed

portions of,

selected

procedures

for the operation,

maintenance,

and testing of the

PASS,

and

di.scussed

system operation,

performance testing,

and analytical

capabilities of the

PASS with the licensee.

The inspector also observed

EKC technicians

obtain

PASS samples.

The inspector

reviewed

selected

portions of two procedures

dealing with

the

operation

and

maintenance

of the

PASS.

These

procedures

were

No.

CRC-821, entitled "Postaccident

RCS/RHR Sampling," dated

May 9,

1989;

and

No.

CRC-830,

entitled

"Periodic

Maintenance

and

Operability

Verification of the

PASS,"

dated

May 20,

1988.

The portions reviewed were

adequate for their intended

purpose.

The inspector

determined

through discussions

with the license'e,

that

as

part of operation of the

PASS,

the capability existed for the collection

of

a post-accident,

undiluted,

ten milliliter, liquid reactor

coolant

'ample

in an shielded

container

or "pig." This sample

could s'erve several

functions. It could

be sent to

an off-site vendor, still in the pig, for

isotopic

or chloride analysis,

or it could

be

analyzed

on site for

chlorides

by the li'censee,

after

a thirty day decay time.

The inspectors

determined,

at the time of this inspection, that the licensee

did not have

a procedure for the removal of this sample

from the pig.

The inspector

considered

the lack of this procedure

to be

a violation of

TS 6.8. 1 a,

which requires

that written procedures

be established

and

implemented.

Since this is

an anticipated

sampling

point following an

accident,

the inspectors

believe that

a procedure

covering the sampling,

including the

removal of the

sample

from the pig, should

be developed

and

tested.

Due to the nature

and timing of this sample, it could

be expected

to have

a very high activity level. Considering this, the use of "generic"

site

procedures

for handling radioactive materials

might not ensure

the

safety of the technician

who would

have to

remove this sample, for the

first time ever, with little prior training and with instructions that had

not

been verified

as effective.

The inspectors

did not consider

the

possibility of developing this procedure

during the thirty day decay time

as

appropriate.

The

reduction

or elimination

of

any

unnecessary

uncertainties

following an accident

would obviously increase

the overall

effectiveness

of the licensee's

program for dealing with an accident.

Another

consideration

was

the

possible

importance

of

sample

volume

changes

and/or dilution factors that

may

be associated

with the

removal

of this

sample

from the pig.

This

knowledge, if needed,

would help

ensure

that

the

licensee

could

accurately

quantify

chosen

sample

parameters

upon analysis.

Site

management,

durino the exit interview,

committed to the

development

of

a procedure

to

r'emove this

sample

from

the pig (Violation 50-400/91-03-01).

3

The

inspector

also

reviewed

the training that

the

ETC technicians

received

on the

PASS.

This included interviews with the licensee,

and

a

document

review.

The

inspectors

determined

that'ew,

or previously

untrained,

technicians

would initially receive eight hours of training on

the

PASS, with annual

retraining of two hours

a year thereafter.

This

training

was

not

"hands-on,"

training.

The- hands-on

training

was

accomplished

during the required quarterly operability verification of the

PASS.

The inspector

determined that there

were nineteen

ETC technicians;

twelve

of these

technicians

were qualified to operate

the

PASS (i.e.

had received

the initial and

annual

retraining)

and

were

also respirator qualified

(which would

be required

to operate

the

PASS

during

an emergency).

A

review of records for 1988,

1989,

1990

and

1991 to date,

indicated that

only

a small portion of these technicians

were receiving opportunities to

operate

the

PASS during the quarterly

checks.

Two of the technicians

operated

the

PASS

a majority of the time, five had operated

the

PASS once

or twice,

and five of the technicians

had not received

the opportunity to

'perate

the

PASS during the quarterly checks.

During discussions

with the inspector,

the licensee

indicated that

any

one of the qualified technicians

could be required to obtain

a

PASS

sample

following an accident.

The inspectors

also

determined that the licensee

was

not tracking'his

type of training for the technicians,

as this

information

was

not readily available

when

requested,

and

had to

be

generated

from several

different

documents.

The licensee

was also not

aware that

CPSL

had committed,

in

a letter to headquarters

dated

Yiay 18,

1986, to semiannual

retraining of the technicians

who could

be required to

operate

the

PASS. This retraining

was to be performed in conjunction with

the quarterly operability verification testing of the

PASS.

The inspectors

considered

the failure to meet this

commitment

a deviation

(Deviation

50-400/91-03-02).

The inspector

discussed

this with the licensee,

and the licensee verbally

committed to tracking the training of their technicians

to ensure that the

semiannual

retraining

commitment

on the

PASS would be met.

The licensee

also

indicated

that

they

might specify

which technicians

would

be

considered

qualified to operate

the

PASS system,

thus reducing the number

of technicians

who would require

semiannual

retraining

on the

PASS.

The

effect of this proposed

reduction in the

number of technicians

qualified

to operate

the

PASS, if implemented,

would

be

examined

by regional

inspectors

in terms of the safety significance

and effectiveness

of the

PASS program,

during

subsequent

inspections.

As part of the

review,

the

inspectors

also

examined

PASS quarterly

-Operability Yerification Test Results for 1987,

1988,

1989,

1990,

and

1991

to date.

These

records

summarized

the results of the quarterly tests

in

terms of passing

or fai ling the

comparisons

between

PASS

analyses

and

routine

RCS

sampling,

as

detailed

in

NUREG-0737

Criteri'on

10

and-

Attachment

No ~

1 to the Generic Letter.

These

analyses

included:

boron,

isotopic activity,

and

chlorides

for diluted

RCS liquid; dissolved

hydrogen

and isotopic activity for'stripped

RCS gas; in-line pH, in-line

dissolved

oxygen,

and in-line hydrogen;

and

gas activity and

iodine

activity for containment air.

Inspection

Report

No.

50-400/90-12-

had

previously detailed

a poor history of meeting the

PASS acceptance

criteria

for several

of these tests,

and

had indicated

a continuing problem with

the stripped

gas results

and with the in-line pH, dissolved

oxygen

and

hydrogen.

At the time of this inspection

several

of these

problems

had

been eliminated;

however, there were continuing problems with stripped

gas

isotopic results.

The inspectors

determined that the

PASS

was continuing

to receive

attention

and

support,

from the

system engineer

and Technical

Support organization.

The

inspectors

questioned

the

usefulness

of comparing

the

isotopic

activity of a highly diluted

PASS

sample to

a

much less diluted, primary

reactor

coolant

sample,

as

a

means

to determine

PASS operability.

The

point of this comparison is to verify that the

PASS system operates,

and

that

the dilution ratios

and

sample

volumes

have

been

accurately

determined.

In cases

where the fuel integrity was high,

as at Harris, the

highly diluted

PASS

samples

may

not contain

enough activity to

be

detected.

This results in comparisons

being performed

between

samples with

activity levels below the "lower limit of detection" with samples

from the

primary

RCS,

which

have

measurable

activity.

The

licensee

agreed

to

investigate

the possibility of improving the

comparisons,

by either

increasing

the volume of the

PASS sample,

or by increasing

the count time.

The inspectors

also

observed

two

EKC technicians

obtain

PASS samples,

and

one

E&C technician

obtain

a

primary

RCS

sample.

In

each

case,

the

appropriate

procedures

were

followed,

proper

sampling

techniques

and

health

physics

practices

were

observed,

and

the

technicians

seemed

knowledgeable

and competent.

The sampling

and analysis of the

PASS samples

were accomplished

in under three hours,

meeting the criteria in NUREG 0737

for the

time limit on sampling

and analysis.

The analysis for boron

was

not performed

because

the level of boron in the

RCS

was

72 parts

per

billion (ppb).

The tremendous

dilution of the liquid- PASS sample

(1000: 1)

prevents

boron analysis if the

RCS

boron level is

below

500 ppb.

The

stripped

gas isotopic activity results

did not meet

NUREG 0737 acceptance

criteria.

All other

parameters

passed.

The inspectors

determined

that

there

was

an ongoing effort by the system engineer to determine

the cause

of this

disagreement.

The inspectors

did not observe

containment air

sampling.

The inspectors

also discussed,

with the system engineer,

the ability to

provide

an alternate

source of power to the

PASS, in the event of the loss

of site

power during

an accident.

The

system

engineer

indicated,

on at

least

two occasions,

that this capability did not exist.

The inspectors

discussed

this with site

management,

and

pointed- out that

an alternate

power source

was required

by the criteria of NUREG 0737.

The licensee

then

'determined,

and

discussed

with the inspectors,

that

an alternate

power

source

did exist, in that the

PASS could

be

powered

by the site diesels.

The inspectors

discussed

the procedure

by which this would be accomplished

with the licensee

by telephone

on March 6,

1991.

The inspectors

considered

the

PASS

program to be adequately

implemented

and maintained;

with areas

in procedure

development,

technician training,

and knowledgeability of NUREG-0737 criteria needing

improvement.

One violation and one deviation 'were identified.

3.

Audits,and Appraisals

(84750)

TS 6.5.4. 1 requires

the licensee's

Corporate guality Assurance

Department

(C(AD) to perform periodic

audits

of Facility activities,

including:

training

and qualification of the facility staff;

the

Radiological

Environmental

Monitoring Program

(REMP);

the Offsite

Dose Calculation

Manual

(ODCM); and the Process

Control

Program

(PCP).

These audits provide

assurance

that these

programs

are properly and effectively implemented.

Pursuant

to these

requirements,

the inspector discussed

the status of the

C/AD with cognizant licensee

personnel.

The inspector

determined that the

licensee's

C(AD department

had

been

recently

reorganized

in December,

1990, with an approximately

50 percent

reduction in personnel,

and

was

renamed

the Nuclear Assurance

Department

(NAD). As with the C(AD, the

NAD

has

branches

at

each

CPKL site

and in Raleigh;

and

the organization

continued

to

be responsible

to corporate

management

in Raleigh.

The

licensee

explained that the focus'f the

new organization

was different

from the old.

The

focus of the

NAD will be to identify problems

and

anticipate

and

im'plement changes,

not just react to findings. Additional

details

of the

new organization

can

be

found in Inspection

Report

50-324,325/91-04.

The inspectors briefly reviewed

the guality Assurance

Audits conducted

in

1989

and

1990.

These

audits

were conducted

over

an approximate

two week

time frame with five to seven, auditors,

and covered

a very broad

scope.

The inspectors

determined that there were

no significant audit findings in

the areas of the

REMP,

ODCM, or the

PCP.

Although the concept of the

NAD appeared

to

be

an

improvement over the

C(AD, the

inspectors

considered it premature

to

make

any conclusions

concerning its effectiveness,

since this organization

was still in its

infancy

and

required further development,

planning

and

implementation.

This area will be reviewed during subsequent

regional inspections.

No violations or deviations

were identified.

4 ~

Confirmatory Measurements

(84750)

As part of the

NRC Confirmatory

Measurements

Program,

spiked liquid

samples

were

sent

to

SHNPP for selected

radiochemical

analyses.

The

samples

were

received

by Harris in October

1990.

The

NRC received

the

.

analytical

results

from

CPSL in

a letter dated

December

10,

1990.

The

comparison

of licensee

results

to

known

values

are

presented

in

Attachment

1.

The acceptance

criteria for the comparisons

are presented

in

Attachment

2.

The results

were all in agreement.

No violations or deviations

were identified.

5.

I

Energy and Environmental

Center

(EEEC)

and Chemistry Procedures

Technical Specification (TS) 6.8. 1 requires

written procedures

to

be

established,

implemented

and maintained for the equality Assurance

Program

for effluent and environmental

monitoring.

Inspection

Report

No.

50-400

(90-21 detailed

a violation (failure to

properly

implement

a radiochemistry

procedure)

for failure to add nitric

acid to liquid samples

prior to counting

as required

by TSs.

This report

detailed

the licensee's

study to qualify the effects of not treating

liquid samples

with nitric acid prior to compositing

and analyzing.

At

that

time

the

licensee

decided

to perform

a

more

thorough

study to

quantify the effects of not acidifying liquid samples.

During this inspection

the results

of the effects of acidification of

liquid samples

were

reviewed.

CPSL

Memorandum,

Serial

891LF5013

was

discussed

at

length

with the

Senior

Specialist-Environmental.

The

memorandum

described

two sets

of samples

which were

counted for

gamma

spectroscopic

analysis

and aliquots

which were

analyzed

for Iron-55,

Strontium-89,

and Strontium-90.

Several

flaws were noted in the samples of BNP reactor coolant which were

analyzed for

gamma activity.

The samples

were "aged", or left standing

for an unspecified

amount of time; composited,

and

then diluted.

The

samples

were then counted over an eight hour period without acidification.

An examination of the activities reported yielded very little in the way

of direct information which

can

be of use

as

there is

no comparison

between acidified and non-acidified

samples.

Any plating out of-isotopes

may have already occurred

and the time of eight hours is not comparable

to

that which might be encountered

in monthly composite

samples.

The Senior

Specialist-Env.

stated that this portion of the analyses

may

be repeated

to correct the aforementioned

limitations.

The

second

section of the

memorandum dealt with three analyses;

Iron-55,

Strontium-89,

and Strontium-90.

One liter aliquots of deionized

water

were spiked with known activities of these

isotopes

and the samples

were

stored for thirty days.

The Iron-55 samples

showed

a significant (up to twenty percent)

difference

in the

amounts

recorded

as

gamma activity.

Those

samples

which were not

acidified yielded

a consistently

lower activity than

those

which were

acidified.

Based

on

these

analyses

the

July

1-December

31,

1990

SemiAnnual

Radioactive

Effluent Release

Report

was

changed

to reflect

this twenty percent

increase

in activity.

This amount of change

had

no

significant impact

on the overall effluent releases

from

SHNPP for the

time frame noted.

The Strontium-90

samples

were subjected

to the

same analysis

parameters

as

above.

Larger (750 ml

as

opposed to 50 ml) aliquots were analyzed for this

portion of the study.

The analyses

yielded very little (less. than five

" percent)

difference in the acidified and non-acidified samples.

Due to

a

spiking error

in the

Strontium-89

samples

these

analyses

were

not

performed.

Strontium analysis

requires

many steps

leading to preparation

of the isolated. strontium precipitate

which is analyzed for beta activity.

Among these

steps

are several

additions of acid to the aliquot which may

or may not account for the relatively minor difference in the reported

activities.

RESL ~et al)have demonstrated

significant "plating" of gamma nuclides

(such's

Iron-55 and Cobalt-60)

onto collection container

surfaces.

The

analyses

provided

by

CP&L in

Memorandum

h'91LFS013

in part,

at least,

substantiates

those conclusions.

The

inspectors

also

toured

the

Energy

and

Environmental

Center

Laboratories

(ESEC)

and

discussed

analysis

parameters

and

laboratory

equipment to gain familiarity with operations.

Based

on this selective

review, the actions

taken concerning revision of

the

1990 Radioactive Effluent Release

Report

appeared

to be appropriate.

Further revisions

may

be necessary

dependent

upon further examination

by

the

ESEC

personnel.

Appropriate

procedures

were in place'o

prevent

recurrence

of the failure to add nitric acid to liquid samples.

Ho violations or deviations

were identified.

Spent

Fuel

Pool

(SFP) Facility (84750)

The inspectors

met with licensee

representatives

to discuss

the status of

the continued

cleanup of the Spent

Fuel

Pools.

Items discussed

with the

licensee

included

those

described

in

NRC

Inspection

Report

No.

50-400/90-22.

Particular

emphasis

was

placed

on the progress

made in

the filtration process,

status

of the fuel

pools at present,

and the

disposition

of Corporate

Task

Force

recommendations

concerning

the

treatment of spent fuel received

from other sites.

The licensee

representative

outlined the current cleanup

under way on 2-3

canal.

The filters

had

been effective in reducing

crud deposited

on

fuel pool surfaces,

and

on removal of fine particles in suspension

in the

pool water.

Eight spent filters were stored in

D pool.

These filters were

replaced

upon reaching

a maximum differential pressure

of 20 psi

(planned

maximum

was

60 psi)

and

have

a worst case

contact

reading of 200 R/hour

(planned

maximum was

300-400 R/hour).

Cleanup

had

been

completed

on the

1-4 canal

and

the main pool.

The licensee

representative

stated

that

they planned

to reclean

the

1-4 transfer

canal

as well as the transfer

tube prior to refueling.

The licensee

planned

on suspending

cleaning of

the fuel pools during the outage,

and

resume

when refueling was completed.

The licensee

described

an'nomaly

observed

in the water condition of the

2-3 canal.

awhile work was

ongoing in the

canal

the water clarity was

fairly clear.

Overnight, over

a time period of approximately eight to ten

hours,

while

no work was

ongoing,

the

pool

suddenly

turned

opaque

and

green in color.

The licensee

continued

to operate

the filters passively

with the suction

head

not in contact with any surface.

The pool returned

to clarity after

48 to

72 hours8.333333e-4 days <br />0.02 hours <br />1.190476e-4 weeks <br />2.7396e-5 months <br />.

The licensee

representative

stated that

.the cause of this transformation

was not known and that Corporate

Chemistry

representatives

were currently examining this phenomenon.

The licensee

representative

also discussed

with the inspectors

the status

of Task

Force

Recommendations

concerning

future processing

of offsite

spent fuel shipments

and the handling of spent fuel shipments

upon receipt

at

SHNPP.

The Task

Force

has

recommended

that the fuel

be cleaned

at

Brunswick Steam Electric Plant

(BSEP) prior to shipment.

The Task Force

also

recommended

the

vendor for implementation

of these

processes.

The recommendations

were

approved

by Corporate

on December

14,

1990.

No

formal

announcements

have

as yet

been

announced

nor have

the

necessary

contracts

been formalized.

Based

on this review, the actions

taken to cleanup

the fuel pools appear

to

be effective.

This

area

will

be

reviewed

during

subsequent

regional

inspections.

No violations or deviations

were identified.

Exit Interview

The inspection

scope

and results

were

summarized

on

Yiarch 1,

1991 with

those

persons

indicated

in Paragraph

1.

The inspectors

described

the

areas

inspected

and discussed

in detail

the inspection 'results

as listed

in the

summary.

Proprietary information is not contained

in this report.

Dissenting

comments

were not received from the licensee.

Item No.

50-400/91-03-01

50-400/91-03-02

Acronyms

and Initialisms

Description

and Reference

Violation - Lack of a procedure for the

removal of a

PASS sample

from a shielded

container

(Paragraph

2).

Deviation - Failure to train technicians

qualified to operate

the

PASS on a

semiannual

basis

(Paragraph

2).

Program

es Laboratory

BNP - Brunswick Nuclear Plant

BSEP - Brunswick Steam Electric Plant

BMR - Boiling Mater Reactor

CFR - Code of Federal

Regulation

CP8L, - Carolina

Power and Light Company

CLEAD - Corporate guality Assurance

Department

ESEC - Energy and Environmental

Center

EKRC - Environmental

and Radiation Control

ERC - Environmental

and Chemistry

mR/h - milliRoentgen

per, hour

NAD - Nuclear Assurance

Department

NRC - Nuclear Regulatory

Commission

NRR - Nuclear Reactor Regulation

OOCYTE - Offsite Dose Calculation

Yianual

PASS - Post Accident Sampling

System

PCP - Process

Control

Program

ppb - parts

per billion

PMR - Pressurized

Mater Reactor

RCS - Reactor Coolant System

REHP - Radiological

Environmental

Monitoring

RESL - Radiological

and Environmental

Scienc

SFP - Spent

Fuel

Pool

SHNPP - Shearon Harris Nuclear

Power Plant

TS - Technical Specification

10

ATTACHMENT 1

CONFIRMATORY MEASUREMENT COMPARISONS

OF H-3,

Fe-55, Sr-89,

AND Sr-90

ANALYSES FOR

HARRIS NUCLEAR PLANT REPORTED

ON

DECEMBER 10,

1990

~isoto

e

H-3

Fe-55

Sr-89

Sr-90

NRC

~uC i /ml )

5.59 +0.22 E-5

4. 06 +0. 16 E-5

7.29 +0.29 E-5

2.17 +0.09 E-6

Licensee

~uC i /ml

5.59 E-05

3.90 E-05

6.57 E-05

1.92 E-06

Resolution

25

25

25

Ratio

Licensee/NRC

~Com ariso

1.00

Agreement

0.96

Agreement

0.90

Agreement

0.88

Agreement

ATTACHMENT 2

CRITERIA FOR

COMPARISONS

OF ANALYTICALMEASUREMENTS

This attachment

provides criteria for the comparison of results of analytical

radioactivity

measurements.

These

criteria

are

based

on

empirical

relationships

which

combine

prior experience

in

comparing radioactivity

analyses,

the

measurement

of the statistically

random process

of radioactive

emission,

and the accuracy

needs of this program.

In

these

criteria,

the

"Comparison

Ratio

Limits"~ denoting

agreement

or

disagreement

between

licensee

and

NRC results

are variable.

This variability

is

a function of the ratio of the

NRC's analytical

value relative to its

associated

statistical

and analytical uncertainty,

referred to in this program

as "Resolution"~.

For comparison

purposes,

a ratio between

the

1icensee's

analytical

value

and

the NRC's analytical value is computed for each radionuclide present in a given

sample.

The

computed ratios

are

then evaluated for agreement

or disagreement

based

on "Resolution."

The

corresponding

values

for,"Resolution"

and the

"Comparison

Ratio Limits" are listed" in the Table

below.

Ratio va1ues

which

ar'e either above or below the "Comparison Ratio Limits" are considered

to be in

disagreement,

while ratio values within or encompassed

by the "Comparison Ratio

Limits" are considered

to be in=agreement.

TABLE

NRC Confirmatory Measurements

Acceptance Criteria

Resolution vs.

Comparison

Ratio Limits

Resolution

Comparison

Ratio Limits

for A reement

<4

.,4"

7

8-15

16 - 50

51 - 200

>200

0.4 " 2.5

0.5 - 2.0

0.6 - 1.66

0.75 - 1.33

0.80 - 1.25

0.85 - 1.18

'Comparison

Ratio = Licensee

Value

NRC Reference

Value

~Resolution

=

NRC Reference

Value

Associated

Uncertainty