ML072000423
| ML072000423 | |
| Person / Time | |
|---|---|
| Site: | Rancho Seco |
| Issue date: | 04/17/2007 |
| From: | Rosalyn Jones Sacramento Municipal Utility District (SMUD) |
| To: | John Hickman NRC/FSME/DWMEP/DURLD/RDB |
| References | |
| 151732 | |
| Download: ML072000423 (61) | |
Text
Rancho Seco Well Sample Analysis Page 1 of 1 John Hickman - Rancho Seco Well Sample Analysis From: "Robert E. Jones" <RJones2@smud.org>
To: <jbh@nrc.gov>
Date: 04/17/2007 7:34 PM
Subject:
Rancho Seco Well Sample Analysis
- John, Attach is the case narrative for one of our quarterly well samples at Rancho Seco. The one I sent you earlier was generic and probably not as helpful to you.
- Thanks, Bob
<<Case Narrative.pdf>>
file://C:\temp\GW}00001 .HTM 07/17/2007
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Subject:
Rancho Seco Well Sample Analysis Creation Date 04/17/2007 7:34:07 PM From: "Robert E. Jones" <RJones2(@smud.org>
Created By: RJones2(@smud.org Recipients nrc.gov OWGWPOO4.HQGWDOO1 JBH (John Hickman)
Post Office Route OWGWPO04.HQGWDO0 1 nrc.gov Files Size Date & Time MESSAGE 205 04/17/2007 7:34:07 PM TEXT.htm 852 Case Narrative.pdf 1204193 Mime.822 1651335 Options Expiration Date: None Priority: Standard ReplyRequested: No Return Notification: None Concealed
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TABLE OF CONTENTS Case Narrative ............................. 1 C hain of C ustody ............. ......... ........ ......... , ............. 3 Cooler Receipt Checklist ............................................. 5 Radiological Analysis ................................................... 7 Sample Data Summary ........................................... 28 Quality Control Data ....................... 38
CASE NARRATIVE ED -I
Receipt Narrative for Rancho Seco Nuclear Generating Station Work Order: 151.732 January 03, 2006 Laboratory Identification:
General Engineering Laboratories, LLC 2040 Savage Road Charleston, South Carolina 29407 (843.) 556-8171 Summary_
Sample receipt The samples arrived at General Engineering Laboratories, LLC, Charleston, South Carolina on December 12, 2005 for analysis.
Sample Identification The laboratory received the following samples:
Laboratory ID Client ID 151732001 #1 MWIC 151732002 #2 MW2A 151732003 #3 MW3A 151.732004 #4 MW4A Case Narrative Sample analyses were conducted using methodology as outlined in General Engineering Laboratories (GEL) Standard Operating Procedures. Any technical or administrative problems during analysis, data review, and reduction are contained in the analytical case narratives in the enclosed data package.
Data Package_.
The enclosed data package contains the following sections: Case Narrative, Chain of Custody, Cooler Receipt Checklist, Data Package Qualifier Definitions and data from the following fr-actions:
Radiochemistry.
Project Manager GENERAL ENGINEERING LABORATORIES. LLC a Member of THE GEL GROUP, INC.
Page 2 of 58 P.O. Box 30712 ° Charleston, SC 2941.7 - 2040 Savage Road (29407)
Phone (843) 556-8171 - Fax (843) 766-1178 - www.gel.com
CHAIN OF CUSTODY Palcyp 3
20060997M Page: of t General Engineering Laboratories. LLC Project #: GEL Chain of Custody and Analytical Request 21040 Savage Road GEL Quote 4:G .L P7- Charleston, SC 29407 COC Number GEL Work Order Number: Phone: 1243) 556-8171 PO Number: .Fax: (943) 766-1178 C (.L2 Phone #: 7/ - 32 Sample Analysis Requested ( (Fill in the number of containers for each test)
- oject/Site Name: ,12ý Sold2- - - Preservati e Type' (6)
~~~~~~~S uld- this *_________
satinpiee be -. , - . -
'r V osord by: Sen Reslt To 4 - Comments
(&Ilected by:-~ Sen Reut To:t t& 2C Note: extra sample is 75->'Sml I Ti5e o I Xd tld ai4 Clets required for sample specific QC 1Z Sample ID' t N,,,. QC Field,,, .i "c Forcompxosiies,- 1ndicate startand stop doate/time tmm-d-,) tlilttara(hhmm) . - -
IL% 8i 1__ o q, N11 GM "i II S 4_ __
2* PA Wu fr ... j..-dc, wlo tk} Nq 6A-eJ 1 11 S TA eqet -VNomlRush:" Specify: tResrults:t Faxjec Yes I K- ) Circle Deliverable of A (QC Summar Level I /Level 2 ILevel?/Lel Remarks: Are there an' known hazards applicableto these samples? Ifso. please list the hazards Samtle Collection Tinme.Zne Eastern Pacific Central Other Mountain Chain of Custody Signatures Sample Shipping and Delivery Details Relinquished By (Signed) Date Time Recalled by (signed) Date Time (GEL PM:
~ 4 I A~n. % stiLeA~L/
j~D ('i~t{L~ L~i ~ 10 LY Method of Shipment: Date Shippd:
2 2 0:
4:irbilt 3 3 Airbilt 5:
I.) Chuin kJ`CustlkxkNumber= Client Determined For Lab Receiving Use Only Z, )C Codes: N - Normal Sample. TB = Trip Blank. FD Field Duplicate. EB = Equipment Bla"k. MS = Matrix Spike Sample. MSD = Matrix Spike Duplicate Sample. G = Grob. C - Composite 3.I Vild Filtjtered:Frr liquid matrices. indicate stith a - Y - Ibr yes the sample was Iield filtered or - N - for sample was noI littered.
teld Custho."Seol Intact?
4.1t M;,rix Cdes: DWt)rinking Water. GW=Groundwaier. SW-Sutface Water. WW-)Vaste Water. W=Water. SO=Soil. SD=Sediment- SL=Sludge. SS-Solid Waste. O0Oil. F=Fttter. P=Wipe. Vt=Urine. F=Fecal. N-Nasal YES NO 3.t Sample Analysis Requested: Analytical method requested (i.e. 8260B. 60108/74"0A I and number ofcontainers provided for each ti.e. 8260B . 3. 6010.&77470A .1t.. Cooler Tentp:
6.1 Prcservative I'sype:HA = lisdrt,,hloric Acid. N1 = Nitric Acid, SH = Sodium Hydroxide. SA - Sulfuric Acid. AA = Ascorbic Acid. HX = I lexane. ST = Sodium Thkictlr.e, If no preservative is added - leave field blank C WHITE = LABORATORY :YELLOW = FILE PINK = CLIENT
COOLER RECEIPT CHECKLIST PA- f
SAMPLE RECEIPT & REVIEW FORM PM me only
[Client: [SDGARCOC/Work jDate Received: \ \\ y" (PM(A) Review (ensure non-conforming items are resolved prior to signing):
,Received By: L M . .
Sample Receipt Criteria Comments/Qualifiers (Required for Non-Conforning Items)
Shipping containers received intact ircle Applicable: seals broken damaged container leaking container other (describe) and sealed? - .
Samples requiring cold ircie Coolant k iee bags blue ice (try icC ( otber descrbe) 2 preservation within (4 +/- 2 C)?
Record preservation method. ,__ ___
Chain of custody documents included with shipment?
inSample containers intact and Circle Applicable: seals broken damaged container leaking container oilier (descrbe) sealed? __
5 Samples requiring chemical Sampl ID's, containers affected and observed pH:
preservation at proper pH?
Sample ID's and containers affected:
6 VOA vials free of headspace ,
(defined as < 6mm bubble)? ,,
Are Encore containers present?
7 (If yes, immediately deliver to
-VOA laboratory) __,
8 Samples received within holding Id's and tests affected:
time?
9 Sample ID's on COC match ID's Sample [Ys and containers affected:
9 on bottles?
10 Date & time on COC match date Sample ID's affecte:
& time on bottles?
Number of containers received Sample ID's affected:
match number indicated on COC?
COC form is properly signed in relinquished/received sections? . /0 Air Bill ,Tracking #'s,&&2 i- L ( L ' - Licf*/ O -
1 4 Additional Comments I2 [ *&L- 1 4 c*V1 c(3?
o
&uL~I~*or Z RSORAD Receipt # _ _ _ _ _ _
r *If > x2 area background is observed on samples identified as 'non-Suspae a's . regulated/non-radioactive', contact the Radiation Safety group for finther
_______________________ ~investigation.
A Radiological Classification? Maximum Counts Observed*: ('7 BlPCB Regulated? Comments-Shipped as DOT'Hazardous ciMaterial? If yes,. contact Waste Hazard Class Shipped:
[Manager or ESH Manager. V PM,(or PMA) review of Hazard classification: nitials 11,; Date:
~*UULJ 6
RADIOLOGICAL ANALYSIS Page 7 of 58
Radiochemistry Case Narrative Rancho Seco Nuclear Generating Station (SMUD)
Work Order 151732 Method/Analysis Information Product: AIphaspec Np, Liquid Analytical Method: DOE EML HASL 300 Analytical Batch Number: 487213 Sample ID Client ID 151732001 #1 MW1C 151732002 #2 MW2A 151732003 #3 MW3A 151732004 #4 MW4A 1200994824 Method Blank (MB) 1200994825 151732002(#2 MW2A) Sample Duplicate (DUP) 1200994826 151732002(#2 MW2A) Matrix Spike (MS) 1200994827 Laboratory Control Sample (LCS)
SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-032 REV# 6.
Calibration Information:
Calibration Information All initial and continuing calibration requirements have been met.
Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).
Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.
Quality Control (0C) Information:
Blank Information The blank volume is representative of the sample volume in this batch.
Designated QC The following sample was used for QC: 151732002 (#2 MW2A).
QC Information All of the QC samples met the required acceptance limits.
Technical Information:
Holding Time All sample procedures for this sample set were performed within the required holding time.
Preparation Information All preparation criteria have been met for these analyses.
Page 8 of 58
Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis.
Miscellaneous Information:
NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. An NCR was not generated for this SDG.
Manual Integration No manual integrations were performed on data in this batch.
Oualifier information Manual qualifiers were not required.
Method/Analysis Information Product: Alphaspec Am241, Cm244, Liquid Analytical Method: DOE EML HASL-300, Am-05-RC Modified Analytical Batch Number: 487212 Sample ID Client ID 151732001 #1 MW1C 151732002 #2 MW2A 151732003 #3 MW3A 151732004 #4 MW4A 1200994820 Method Blank (MB) 1200994821 151732001(#1 MW1C) Sample Duplicate (DUP) 1200994822 151732001(#1 MW1C) Matrix Spike (MS) 1200994823 Laboratory Control Sample (LCS)
SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-01 1 REV# 14.
Calibration Information:
Calibration Information All initial and continuing calibration requirements have been met.
Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).
Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.
Quality Control (OC) Information:
Blank Information The blank volume is representative of the sample volume in this batch.
Designated QC The following sample was used for QC: 151732001 (#1 MW1C).
Page 9 of 58
QC Information Matrix Spike 1200994822 (#1 MW1C) failed required detection limit.
Technical Information:
Holding Time All sample procedures for this sampleset were performed within the required holding time.
Preparation Information All preparation criteria have been met for these analyses.
Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis.
Miscellaneous Information:
NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. An NCR was not.generated for this SDG.
Manual Integration No manual integrations were performed on data in this batch.
Qualifier information Manual qualifiers were not required.
Method/Analysis Information Product: Alphaspec Pu, Liquid Analytical Method: DOE EML HASL-300, Pu-I I-RC Modified Analytical Batch Number: 487214 Sample ID Client ID 151732001 #1 MW1C 151732002 #2 MW2A 151732003 #3 MW3A 151732004 #4 MW4A 1200994828 Method Blank (MB) 1200994829 151732001 (# 1 MW IC) Sample Duplicate (DUP) 1200994830 151732001(#1 MWIC) Matrix Spike (MS) 1200994831 Laboratory Control Sample (LCS)
SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-01 1 REV# 14.
Calibration Information:
Calibration Information All initial and continuing calibration requirements have been met.
Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).
Page 10 of 58
Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.
Ouality Control (0C) Information:
Blank Information The blank volume is representative of the sample volume in this batch.
Designated QC The following sample was used for QC: 151732001 (#1 MW IC).
QC Information All of the QC samples met the required acceptance limits.
Technical Information:
Holding Time All sample procedures for this sample set were performed within the required holding time.
Preparation Information All preparation criteria have been met for these analyses.
Sample Re-prep/Re-analysis None of the samples in-this sample set required reprep or reanalysis.
Miscellaneous Information:
NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. An NCR was not generated for this SDG.
Manual Integration No manual integrations were performed on data in this batch.
Qualifier information QualifierT.
Q Reason Analyte Sample esults rejected due to tailing from the Pu-242 tracer region. Plutonium-244 151732004 Method/Analysis Information Product: Liquid Scint Pu241, Liquid Analytical Method: DOE EML HASL-300, Pu- 11-RC Modified Analytical Batch Number: 487216 Sample ID Client ID 151732001 #1 MW1C 151732003 #3 MW3A 151732004 #4 MW4A 1200994833 Method Blank (MB) 1200994834 151732003(#3 MW3A) Sample Duplicate (DUP) 1200994835 151732003(#3 MW3A) Matrix Spike (MS) 1200994836 Laboratory Control Sample (LCS)
Page 11 of 58
SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-035 REV# 7.
Calibration Information:
Calibration Information All initial and continuing calibration requirements have been met.
Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).
Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.
Quality Control (0C0 Information:
Blank Information The blank volume is representative of the sample volume in this batch.
Designated QC The following sample was used for QC: 151732003 (#3 MW3A).
QC Information All of the QC samples met the required acceptance limits.
Technical Information:
Holding Time All sample procedures for this sample set were performed within the required holding time.
Preparation Information All preparation criteria have been met for these analyses.
Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis.
Miscellaneous Information:
NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. An NCR was not generated for this SDG.
Manual Integration No manual integrations were performed on data in this batch.
qualifier information Manual qualifiers were not iequired.
Method/Analysis Information Product: Liquid Scint Pu241, Liquid Analytical Method: DOE EML HASL-300, Pu-I 1-RC Modified Analytical Batch Number: 490003 Page 12 of 58
Sample ID Client ID 151732002 #2 MW2A 1201001147 Method Blank (MB) 1201001148 151732002(#2 MW2A) Sample Duplicate (DUP) 1201001149 151732002(#2 MW2A) Matrix Spike (MS) 1201001150 Laboratory Control Sample (LCS)
SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-035 REV# 7.
Calibration Information:
Calibration Information All initial and continuing calibration requirements have been met.
Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).
Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.
Ouality Control (0C0 Information:
Blank Information The blank volume is representative of the sample volume in this batch.
Designated QC The following sample was used for QC: 151732002 (#2 MW2A).
QC Information All of the QC samples met the required acceptance limits.
Technical Information:
Holding Time All sample procedures for this sample set were performed within the required holding time.
Preparation Information All preparation criteria have been met for these analyses.
Sample Re-prep/Re-analysis Samples were reprepped once due to interference and once for low tracer yield.
Miscellaneous Information:
NCR Documentation Nonconformance reports are generated to document any procedural anomalies that' may deviate from referenced SOP or contractual documents. The following NCR was generated for this SDG:
NCR 280211 was generated due to RDL less than MDA. 1. Sample 151732002, 1201001147, and 1201001148 did not meet the client's detection limit due to small sample aliquot. The samples were reprepped twice and the aliquots reduced due to interference and low tracer yields. I. Reporting results.
Page 13of 58
Manual Integration No manual integrations were performed on data in this batch.
Oualifier information Manual qualifiers were not required.
Method/Analysis Information Product: Gammaspec, Gamma, Liquid (Standard List)
Analytical Method: EPA 901.1 Analytical Batch Number: 488129 Sample ID Client ID 151732001 #1 MWIC 151732002 #2 MW2A 151732003 #3 MW3A 151732004 #4 MW4A 1200996967 Method Blank (MB) 1200996968 151732001 (# I MW1 C) Sample Duplicate (DUP) 1200996969 151732001(#1 MW1C) Matrix Spike (MS) 1200996970 Laboratory Control Sample (LCS)
SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-013 REV# 10.
Calibration Information:
Calibration Information All initial and continuing calibration requirements have been met.
Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).
Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.
Quality Control (OC) Information:
Blank Information The blank volume is representative of the sample volume in this batch.
Designated QC The following sample was used for QC: 151732001 (#1 MWlC).
QC Information All of the QC samples met the required acceptance limits.
Technical Information:
Holding Time All sample procedures for this sample set were performed within the required holding time.
Preparation Information Page 14 of 58
All preparation criteria have been met for these analyses.
Sample Re-prep/Re-analysis Sample 1200996967 (MB) was recounted due to analyst error.
Sample 151732001 (#1 MW 1C) was recounted due to high relative percent difference/relative error ratio.
Sample 1200996969 (#1 MW1C) was recounted due to low/high recovery.
Miscellaneous Information:
NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. An NCR was not generated for this SDG.
Additional Comments The relative percent difference for K-40 did not meet the client requirements. However, precision is shown when a relative error ratio of 2.37 is calculated.
Oualifier information Qualifier Reason Analyte Sample UI Data rejected due to high peak uncertainty. Thorium-230 151732002 UI Data rejected due to high uncertainty. Potassium-40 1200996967 UI Data rejected due to low abundance.' Bismuth-214 151732003 Lead-212 151732002 Lead-214 151732003 Promethium- 146 1200996967 Fhorium-234 1200996968 Uranium-238 1200996968.
UI ata rejected due to no valid peak. Bismuth-212 151732003 1 _Cerium- 144 1200996967 Method/Analysis Information Product: GFPC, Gross A/B, liquid Analytical Method: EPA 900.0 Analytical Batch Number: 489159 Sample ID Client ID 151732001 #1 MWIC 151732002 #2 MW2A 151732003 #3 MW3A 151732004 #4 MW4A 1200999365 Method Blank (MB) 1200999366 151735002(S-0000222701) Sample Duplicate (DUP) 1200999367 151735002(S-0000222701) Matrix Spike (MS) 1200999368 151735002(S-0000222701) Matrix Spike Duplicate (MSD) 1200999369 Laboratory Control Sample (LCS)
SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-00 1 REV# 9.
Page 15 of 58
Calibration Information:
Calibration Information All initial and continuing calibration requirements have been met.
Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).
Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.
Quality Control (0C) Information:
Blank Information The blank volume is representative of the sample volume in this batch.
Designated QC The following sample was used for QC: 151735002 (S-0000222701).
QC Information All of the QC samples met the required acceptance limits.
Technical Information:
Holding Time All sample procedures for this sample set were performed within the required holding time.
Preparation Information All preparation criteria have been met for these analyses.
-Sample Re-prep/Re-analysis Samples were reprepped due to high relative percent difference/relative error ratio.
Chemical Recoveries All chemical recoveries meet the required acceptance limits for this sample set.
Gross Alpha/Beta Preparation Information High hygroscopic salt content in evaporated samples can cause the sample mass to fluctuate due to moisture absorption. To minimize this interference, the salts are converted to oxides by heating the sample under a flame until a dull red color is obtained. The conversion to oxides stabilizes the sample weight and ensures that proper alpha/beta efficiencies are assigned for each sample. Volatile radioisotopes of carbon, hydrogen, technetium, polonium and cesium may be lost during sample heating.
Miscellaneous Information:
NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. An NCR was not generated for this SDG.
Oualifier information Manual qualifiers were not required.
Method/Analysis Information Product: GFPC, Total Sr, Liquid Analytical Method: EPA 905.0 Modified Page 16 of 58
Analytical Batch Number: 487482 Sample ID Client ID 151732001 #1 MWIC 151732002 #2 MW2A 151732003 #3 MW3A 151732004 #4 MW4A 1200995396 Method Blank (MB) 1200995397 151732003(#3 MW3A) Sample Duplicate (DUP) 1200995398 151732003(#3 MW3A) Matrix Spike (MS) 1200995399 Laboratory Control Sample (LCS)
SOP Reference Procedure for preparation, analysis and reporting df analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-004 REV# 9.
Calibration Information:
Calibration Information All initial and continuing calibration requirements have been met.
Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).
Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.
Quality Control (OC) Information:
Blank Information The blank volume is representative of the sample volume in this batch.
Designated QC The following sample was used for QC: 151732003 (#3 MW3A).
QC Information All of the QC samples met the required acceptance limits.
Technical Information:
Holding Time All sample procedures for this sample set were performed within the required holding time.
Preparation Information All preparation criteria have been met for these analyses.
Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis.
Chemical Recoveries All chemical recoveries meet the required acceptance limits for this sample set.
Miscellaneous Information:
Page 17 of 58
NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. An NCR was not generated for this SDG.
Qualifier information Manual qualifiers were not required.
Method/Analysis Information Product: Liquid Scint Tc99, Liquid Analytical Method: DOE EML HASL-300, Tc-02-RC Modified Analytical Batch Number: 487449 Sample ID Client ID 151732001 #1 MWIC 151732002 #2 MW2A 151732093 #3 MW3A 151732004 #4 MW4A 1200995311 Method Blank (MB) 1200995312 151732001 (#1 MWIC) Sample Duplicate (DUP) 1200995313 151732001(#l MWlC) Matrix Spike (MS) 1200995314 Laboratory Control Sample (LCS)
SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-005 REV# 12.
Calibration Information:'
Calibration Information All initial and continuing calibration requirements have been met.
Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).
Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.
Ouality Control (OC) Information:
Blank Information The blank volume is representative of the sample volume in this batch.
Designated QC The following sample was used for QC: 151732001 (#1 MW IC).
QC Information All of the QC samples met the required acceptance limits.
Technical Information:
Holding Time All sample procedures for this sample set were performed within the required holding time.
Page 18 of 58
Preparation Information All preparation criteria have been met for these analyses.
Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis.
Miscellaneous Information:
NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. An NCR was not generated for this SDG.
Qualifier information Manual qualifiers were not required.
Method/Analysis Information Product: Liquid Scint Fe55, Liquid Analytical Method: DOE RESL Fe-1, Modified Analytical Batch Number: 487444 Sample ID Client ID 151732001 #1 MW1C 151732002 .#2 MW2A 151732003 #3 MW3A 151732004 #4 MW4A 1200995299 Method Blank (MB) 1200995300 151732001(#l MW1C) Sample Duplicate (DUP) 1200995301 15173200 1(#1 MWI C) Matrix Spike (MS) 1200995302 Laboratory Control Sample (LCS)
SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-040 REV# 3.
Calibration Information:
Calibration Information All initial and continuing calibration requirements have been met.
Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).
Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.
Ouality Control (0C) Information:
Blank Information.
The blank volume is representative of the sample volume in this batch.
Designated QC The following sample was used for QC: 151732001 (#1 MW1C).
Page 19 of 58
QC Information All of the QC samples met the required acceptance limits.
Technical Information:
Holding Time All sample procedures for this sample set were performed within the required holding time.
Preparation Information -
All preparation criteria have been met for these analyses.
Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis.
Miscellaneous Information:
NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. An NCR was not generated for this SDG.
Oualifier information Manual qualifiers were not required.
Method/Analysis Information Product: Liquid Scint Ni63, Liquid Analytical Method: DOE RESL Ni-l, Modified Analytical Batch Number: 487445 Sample ID Client ID 151732001 #1 MWIC 151732002 #2 MW2A 151732003 #3 MW3A 151732004. #4 MW4A 1200995303 Method Blank (MB) 1200995304 151732001(#1 MWIC) Sample Duplicate (DUP) 1200995305 151732001(#l MW1C) Matrix Spike (MS) 1200995306 Laboratory Control Sample (LCS)
SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-022 REV# 7.
Calibration Information:
Calibration Information All initial and continuing calibration requirements have been met.
Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).
Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.
Page 20 of 58
Quality Control (OC) Information:
Blank Information The blank volume is representative of the sample volume in this batch.
Designated QC The following sample was used for QC: 151732001 (#1 MWIC).
QC Information All of the QC samples met the required acceptance limits.
Technical Information:
Holding Time All sample procedures for this sample set were performed within the required holding time.
Preparation Information All preparation criteria have been met for these analyses.
Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis.
Miscellaneous Information:
NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. An NCR was not generated for this SDG.
Qualifier information Manual qualifiers were not required.
Method/Analysis Information Product: LSC, Tritium Dist, Liquid Analytical Method: EPA 906.0 Modified Analytical Batch Number: 487451 Sample ID Client ID 151732001 #1 MWIC 151732002 #2 MW2A 151732003 #3 MW3A 151732004 #4 MW4A 1200995315 Method Blank (MB) 1200995316, 151732001(#l MW1C) Sample Duplicate (DUP) 1200995317 151732001(#1 MWIC) Matrix Spike (MS) 1200995318 Laboratory Control Sample (LCS)
SOP Reference Procedure' for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-002 REV# 10.
Calibration Information:
Calibration Information Page 21 of 58
All initial and continuing calibration requirements have been met.
Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).
Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.
Quality Control (QC) Information:
Blank Information The blank volume is representative of the sample volume in this batch.
Designated QC The following sample was used for QC: 151732001 (#1 MW1C).
QC Information All of the QC samples met the required acceptance limits.
Technical Information:
Holding Time All sample procedures for this sample set were performed within the required holding time.
Preparation Information All preparation criteria have been met for these analyses.
Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis.
Miscellaneous Information:
NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. An NCR was not generated for this SDG.
Oualifier information Manual qualifiers were not required.
Method/Analysis Information Product: Liquid Scint C14, Liquid Analytical Method: EPA EERF C-01 Modified Analytical Batch Number: 487453 Sample ID Client ID 151732001 #1.MW1C 151732002 #2 MW2A 151732003 #3 MW3A 151732004 #4 MW4A 1200995323 Method Blank (MB) 1200995324 151732001(#l MW1C) Sample Duplicate (DUP) 1200995325 151732001(#l MWlC) Matrix Spike (MS) 1200995326 Laboratory Control Sample (LCS)
Page 22 of 58
SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering
- Laboratories,'LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-003 REV# 8.
Calibration Information:
Calibration Information All initial and continuing calibration requirements have been met.
Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).
Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.
Ouality Control (0C) Information:
Blank Information The blank volume is representative of the sample volume in this batch.
Designated QC The following sample was used for QC: 151732001 (#1 MW1C).
QC Information All of the QC samples met the required acceptance limits.
Technical Information:
Holding Time All sample procedures for this sample set were performed within the required holding time.'
Preparation Information All preparation criteria have been met for these analyses.
Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis.
Miscellaneous Information:
NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. An NCR was not generated for this SDG.
Qualifier information Manual qualifiers were not required.
Method/Analysis Information Product: Liquid Scint Pm147, liquid Analytical Method: EPA EERF PM-01-1 Modified Analytical Batch Number: 487442 Sample ID Client ID Page 23 of 58
151732001 #1 MW1C 151732002 #2 MW2A 151732003 #3 MW3A 151732004. #4 MW4A 1200995295 Method Blank (MB) 1200995296 151732004(#4 MW4A) Sample Duplicate (DUP) 1200995297 151732004(#4 MW4A) Matrix Spike (MS) 1200995298 Laboratory Control Sample (LCS)
SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-020 REV# 6.
Calibration Information:
Calibration Information All initial and continuing calibration requirements have been met.
Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).
Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.
Quality Control (0C) Information:
Blank Information The blank volume is representative of the sample volume in this batch.
Designated QC The following sample was used for QC: 151732004 (#4 MW4A).
QC Information All of the QC samples met the required acceptance limits.
Technical Information:
Holding Time All sample procedures for. this sample set were performed within the required holding time.
Preparation Information.
All preparation criteria have been met for these analyses.
Sample Re-prep/Re-analysis Samples 1200995295 (MB), 1200995296 (#4 MW4A), 151732001 (#1 MWIC), 151732002 (#2 MW2A),
151732003 (#3 MW3A) and 151732004 (#4 MW4A) were recounted due to high MDAs.
Miscellaneous Information:
NCR Documentation Nonconformance reports are generated to document any procedural, anomalies that may deviate from referenced SOP or contractual documents. An NCR was not generated for this SDG.
Oualifier information Manual qualifiers were not required.
Page 24 of 58
Method/Analysis Information Product: Gamma Ni59, Liquid Analytical Method: DOE RESL Ni-I Analytical Batch Number: 490999 Sample ID Client ID SOP Reference 151732001 #1 MWIC Procedure for preparation, 151732002 #2 MW2A analysis and reporting of 151732003 #3 MW3A analytical data are 151732004
- 4 MW4A controlled by General Engineering Laboratories, 1201003355 Method Blank (MB)
LLC as Standard Operating 1201003356 151732001 (#1 MW I C) Sample Duplicate (DUP)
Procedure (SOP). The data 1201003357 151732001(#1 MWIC) Matrix Spike (MS) discussed in this narrative 1201003358 Laboratory Control Sample (LCS) has been analyzed in accordance with GL-RAD-A-022 REV# 7.
Calibration Information:
Calibration Information All initial and continuing calibration requirements have been met.
Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).
Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.
Quality Control (0C) Information:
Blank Information The blank volume is representative of the sample volume in this batch.
Designated QC The following sample was used for QC: 151732001 (#1 MW1C).
QC Information All of the QC samples met the required acceptance limits.
Technical Information:
Holding Time All sample procedures for this sample set were performed within the required holding time.
Preparation Information All preparation criteria have been met for these analyses.
Sample Re-prep/Re-analysis Page 25 of 58
Samples were reprepped with a higher volume to meet therequired detection limits.
Chemical Recoveries All chemical recoveries meet the required acceptance limits for this sample set.
Miscellaneous Information:
NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. An NCR was not generated for this SDG.
Qualifier information Manual qualifiers were not required.
Certification Statement Where the analytical method has-been performed under NELAP certification, the analysis has met all of the requirements of the NELAC standard unless otherwise noted in the analytical case narrative.
Review Validation:
GEL requires all analytical data to be verified by a qualified data validator. In addition, all data designated for CLP or CLP-like packaging will receive a third level validation upon completion of the data package.
The following data validator verified the information presented in this case narrative:
Reviewer: Q o, ' ,,.'( 0.
Page 26 of 58
General Engineering Laboratories NCR Report No.: 280211 Form GEL-NCR Revision No.-
Rev. 06/05 COMPANY - WIDE NONCONFORMANCE REPORT Mo.Day Yr. Division: Quality Criteria: Type:
29-DEC-05 Radiochemistry Specifications Process Instrument Type: Test I Method: Matrix Type: Client Code:
LSC DOE EML HASL-300, Pu-11-RC Liquid SMUD Modifled Batch ID:_ Sample Numbers:
490003 See Below Potentially affected work order(s)(SDG): 151732 Application Issues:
RDL less than MDA Specification and Requirements NRG Disposition:
Nonconformance
Description:
- 1. Sample 151732002, 1201001147, and 1201001148 did not meet the 1. Reporting results.
client's detection limit due to small sample aliquot. The samples were reprepped twice and the aliquots reduced due to interference and low tracer yields.
Originator's Name: Data Validator/Group Leader:
Melanie Aycock 29-DEC-05 Heather Anderson 30-DEC-05 Quality Review:
Director:
Page 1 Page 27 of 58
SAMPLE DATA
SUMMARY
Page 28 of 58
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Report for for SMUDOO 1 Rancho Seco Nuclear Generating Station Client SDG: 151732 GEL Work Order: 151732
. Sample(s) Contained within this report:
Lab Sample ID Client Sample ID Sample Description Collected 151732001 #1 MW1C N/A 12/05/2005 14:00 151732002 #2 MW2A N/A 11/29/2005 12:30 151732003 #3 MW3A N/A 12/05/2005 14:50 151732004 #4 MW4A N/A 12/06/2005 11:50 Where the analytical method has been performed under NELAP certification, the analysis has met all of the requirements of the NELAC standard unless qualified on the Certificate of Analysis.
This data report has been prepared and reviewed in accordance with General Engineering Laboratories, LLC standard operating procedures. Please direct any questions to your Project Manager, Martha Harrison.
Re by ve.,e Reviewed by Page 29 of 58
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com 10 CFR Part 50/61 Certificate of Analysis GEL Sample ID: 151732001 Client: Rancho Seco Nuclear Generating Station Client Sample ID: #1 MW1C Collect Date: December 05, 2005 Matrix: Ground Water Receive Date: December 12, 2005 Amount of Sample Received: Report Date: December 31, 2005 2 I .Critical
.An.aly te .................... Run Date Qualifier Activity Uncertaini tyMDA RL TPU Level Units ALPHA 12/23/05 5.05E-01 6.26E-01 1.13E+00 5.OOE+00 6.29E-01 4.20E-01 pCi/L BETA 12/23/05 2.23E+00 1.89E+00 3.71E+00 5.OOE+00 1.89E+00 1.77E+00 pCi/L H-3 12/14/05 1.13E+02 2.11 E+02 3.59E+02 7.OOE+02 2.11 E+02 1.73E+02 pCi/L C-14 12/14/05 9.08E+00 1.57E+01 2.66E+01 5.OOE+01 1.57E+0 1 1.30E+01 pCi/L Fe-55 12/15/05 -2.82E+01 3.71E+01 5.66E+01 1.00E+02 3.71 E+0 I 2.79E+01 pCi/L Ni-63 12/15/05 1.76E+00 1.46E+01 2.51 E+0 1 5.OOE+01 1.46E+01 1.22E+01 pCi/L Tc-99 12/19/05 -5.14E+00 1.34E+01 2.3 1E+01 5.OOE+01 1.34E+01 1.13E+01 pCi/ll Pm-147 12/21/05 3.04E+00 4.19E+00 7.06E+00 1.00E+01 4.20E+00 3.47E+00 pCi/L Pu-241 12/16/05 -1.29E+00 7.06E+00 1.22E+01 1.50E+01 7.06E+00 5.95E+00 pCi/L Total Strontium 12/14/05 -7.03E-01 4.89E-01 1.27E+00 2.OOE+00 4.90E-01 5.98E-01 pCi/L Alpha Spec Np-237 12/15/05 3.85E-02 1.53E-01 4.39E-01 1.00E+00 1.53E-01 1.1 9E-0 I pCi/L Pu-238 12/15/05 0.OOE+00 1.62E-01 2.24E-01 1.00E+00 1.62E-01 0.OOE+00 pCi/L Pu-239/240 12/15/05 -5.96E-02 6.74E-02 5.51E-01 1.00E+00 6.77E-02 1.63E-01 pCi/L Pu-244 12/15/05 1.65E-01 2.29E-01 2.24E-01 1.00E+00 2.30E-01 0.OOE+00 pCi/L Am-241 12/15/05 2.02E-01 2.37E-01 3.28E-01 1.00E+00 2.38E-01 7.5 1E-02 pCi/L Cm-243/244 12/15/05 -4.74E-02 1.40E-01 4.39E-01 1.00E+00 1.40E-01 1.30E-01 pCi/L Gamma Spec Be-7 12/28/05 -6.28E-01 1.88E+01 3.17E+01 1.00E+01 1.85E+01 1.50E+01 pCi/L Na-22 12/28/05 - 1.20E+00 1.86E+00 3.14E+00 1.00E+01 1.82E+00 1.43E+00 pCi/L K-40 12/28/05 3.27E+01 2.75E+01 3.05E+01 1.00E+01 2.70E+0I 1.39E+01 pCi/L Cr-51 12/28/05 -2.41E+00 2.50E+01 4.25E+01 1.00E+01 2.45E+01 2.03E+01 pCi/L Mn-54 12/28/05 -1.08E+00 1.57E+00 2.58E+00 1.00E+01 1.53E+00 1.1 9E+00 pCi/L Fe-59 12/28/05 1.72E+00 4.28E+00 8.09E+00 1.00E+01 4.20E+00 3.73E+00 pCi/L Co-56 12/28/05 2.13E-01 1.88E+00 3.34E+00 1.00E+01 1.84E+00 1.55E+00 pCi/L Co-57 12/28/05 7.97E-01 1.66E+00 2.96E+00 1.00E+01 1.63E+00 1.43E+00 pCi/L Co-58 12/28/05 -1.79E+00 1.94E+00 3.13E+00 1.00E+01 1.90E+00 1.45E+00 pCi/L Co-60 12/28/05 -1.02E-01 1.84E+00 3.32E+00 1.00E+01 1.80E+00 1.52E+00 pCi/L Ni-59 12/29/05 1.51E+01 1.04E+01 1.66E+01 2.OOE+01 1.02E+01 7.68E+00 pCi/L Zn-65 12/28/05 -7.23E-01 3.71E+00 6.63E+00 1.00E+01. 3.64E+00 3.05E+00 pCi/L Y-88 12/28/05 -3.74E-01 1.65E+00 2.94E+00 1.00E+01 1.61 E+00 1.28E+00 pCi/L Zr-95 12/28/05 -2.36E-01. 3.75E+00 6.55E+00 1.00E+01 3.67E+00 3.06E+00 pCi/L Nb-94 12/28/05 6.19E-01 1.67E+00 3.01E+00 1.00E+01 1.64E+00 1.42E+00 pCi/L Nb-95 12/28/05 7.80E-01 2.43E+00 4.40E+00 1.00E+01 2.38E+00 2.05E+00 pCi/L Ru- 106 12/28/05 1.15E+01 1.64E+01 3.03E+01 1.00E+01 1.60E+01 1.43E+01 pCi/L Ag-110m 12/28/05 -2.34E-01 1.61E+00 2.82E+00 1.00E+01 1.58E+00 1.32E+00 pCi/L Sn-113 12/28/05 -9.27E-01 2.56E+00 4.25E+00 1.00E+01 2.5 1E+00 2.02E+00 pCi/L Note(s): 1. Calculated MDAs are a-posteriori values.
- 2. Activity concentration net +/- 2 sigma overall on reference date.
- 3. Results are statistically positive at the 99.9% confidence level (activity is greater than three times the one sigma uncertainty)
U Target analyte was analyzed for but not detected above the MDL or LOD.
UI Uncertain identification for gtamma spectroscopy.
X Lab-specific qualifier-please see case narrative, data summary package or contact your project manager for details.
Page 30 of 58
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com 10 CFR Part 50/61 Certificate of Analysis GEL Sample ID: 151732001 Client: Rancho Seco Nuclear Generating Station Client Sample ID: #1MW1C Collect Date: December 05, 2005 Matrix: Ground Water Receive Date: December 12, 2005 Amount of Sample Received: Report Date: December 31, 2005 2 Critical Analyte Run Date Qualifier Activity Uncertainty MDA R. TPU Level Units Sb-124 12/28/05 U -1.85E+00 3.98E+00 6.82E+00 1.00E+01 3.90E+00 2.98E+00 pCi/L Sb-125 12/28/05 U 2.44E+00 5.31E+00 8.24E+00 1.00E+01 5.20E+00 3.90E+00 pCi/L Cs-134 12/28/05 U 6.24E-01 1.82E+00 3.30E+00 1.00E+01 1.78E+00 1.54E+00 pCi/L Cs-136 12/28/05 U 5.23E+00 6.86E+00 1.30E+01 1.003E+01 6.72E+00 5.99E+00 pCi/L Cs-137 12/28/05 U 3.08E-01 2.38E+00 2'99E+00 1.00E+01 2.33E+00 1.40E+00 pCi/L Ba-133 12/28/05 U' 5.06E-01 2.60E+00 3.95E+00 1.00E+01 2.55E+00 1.88E+00 pCi/L Ba-140 12/28/05 U 1.07E+01 2.01E+01 3.69E+01 1.00E+01 1.97E+01 1.75E+01 pCi/L Ce-139 12/28/05 U -4.91E-01. 1.86E+00 3.19E+00 1.00E+01 1.82E+00 1.54E+00 pCi/L Ce-141, 12/28/05 U 2.85E+00 6.81E+00 7.27E+00 1.00E+01 6.67E+00, 3.51E+00 pCi/L Ce-144 12/28/05 U -6.92E+00 1.25E+01 2.14E+01 1.00E+01 1.22E+01 1.03E+01 pCi/L Nd-147 12/28/05 U 1.63E+01 4.62E+01 8.41E+01 I1.00E+01 4.53E+01 3.97E+01 pCi/L Pm-144 12/28/05 U -5.1 IE-03 1.70E+00 2.99E+00 1.00E+01 1.67E+00 1.41E+00 pCi/L Pm-146 12/28/05 U 2.65E+00 2.38E+00 4.31E+00 1.00E+01 2.33E+00 2.05E+00 pCi/L Eu-152 12/28/05 U 4.63E+00 6.19E+00 9.76E+00 1.00E+01 6.06E+00 4.67E+00 pCi/L Eu-154 12/28/05 U -3.39E+00 5.16E+00 8.72E+00 1.00E+01 5.05E+00. 3.97E+00 pCi/L Eu-155 12/28/05 U 1.39E-01 6.87E+00 1.13E+01 1.00E+01 6.73E+00 5.46E+00 pCi/L lr- 192 12/28/05 U -1.13E+00 2.03E+00 3.36E+00 1.00E+01 1.99E+00 1.60E+00 pCi/L Hg-203 12/28/05 U -2.83E-01 2.55E+00 4.35E+00 1.00E+01 2.50E+00 2.08E+00 pCi/L TI-208 12/28/05 U 9.45E-01 2.91E+00 3.41E+00 1.00E+01 2.85E+00 1.61E+00 pCi/L Pb-210 12/28/05 U -1.98E+01 3.87E+02 5.80E+02 1.00E+01 379E+02 2.80E+02 pCi/L Pb-212 12/28/05 U 1.35E+00 5.89E+00 5.61E+00 1.00E+01 5.77E+00 2.70E+00 pCi/L Pb-214 12/28/05 U 4.05E+00 6.54E+00 6.16E+00 1.00E+01 6.41E+00 2.93E+00 pCi/L Bi-212 12/28/05 U 5.49E+00 1.32E+01 2.40E+01 1.00E+01 1.29E+01" 1.13E+01 pCi/L Bi-214 12/28/05 U 4.62E+00 8.74E+00 7.62E+00 1.00E+01 8.56E+00 3.64E+00 pCi/L Ra-228 12/28/05 U -3.73E-01 6.17E+00 1.07E+01 1.00E+01 6.05E+00 4.99E+00 pCi/L Ac-228 12/28/05 U -3.73E-01 6.17E+00 1.07E+01 1.00E+01 6.05E+00 4.99E+00 pCi/L Th-230 12/28/05 U 4.62E+00 8.73E+00 5.56E+00 1.00E+01 8.56E+00 2.61E+00 pCi/L.
Th-234 12/28/05 3,U 1.66E+02 9.50E+01 1.68E+02 1.00E+01 9.31E+01 8.18E+01 pCi/L U-235 12/28/05 U 8.78E+00 1.84E+01 2.24E+01 1.00E+01 1.81E+01 1.09E+01 pCi/L U-238 12/28/05 3,U 1.66E+02 9.50E+01 1.68E+02 1.00E+01 9.31E+01 8.18E+01 pCi/L Np-239 12/28/05 U 2.1IE-01 1.27E+01 2.07E+01 1.00E+01 1.24E+01 1.00E+01 pCi/L Am-241 12/28/05 U -5.11E+00 1.16E+01 1.90E+01 1.00E+01 1.13E+01 9.17E+00 pCi/L Note(s): 1. Calculated MDAs are a-posteriori values.
- 2. Activity concentration net +/- 2 sigma overall on reference date.
- 3. Results are statistically positive at the 99.9% confidence level (activity is greater than three times the one sigma uncertainty)
U Target analyte was analyzed for butnot detected above the MDL or LOD.
UI Uncertain identification for gamma spectroscopy.
X Lab-specific aualifier-please see case narrative, data summary package or contact your project manager for details.
Page 31 of 58
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com 10 CFR Part 50/61 Certificate of Analysis GEL Sample ID: 151732002 Client: Rancho Seco Nuclear Generating Station Client Sample ID: #2 MW2A Collect Date: November 29, 2005 Matrix: Ground Water Receive Date: December 12, 2005 Amount of Sample Received: Report Date: December 31, 2005 2 1Critical Analyte Run Date Qualifier Activity Uncertainty MDA RL TPU Level Units ALPHA 12/22/05 3 7.07E+00 2.45E+00 2.95E+00 5.OOE+00 2.57E+00 1.34E+00 pCi/L BETA 12/22/05 3 1.71E+01 3.07E+00 4.36E+00 5.OOE+00 3.12E+00 2.12E+00 pCi/L H-3 12/14/05 U 2.62E+02 2.17E+02 3.59E+02 7,00E+02 2.17E+02 1.73E+02 pCi/L C-14 12/14/05 U 6.18E+00 1.56E+01 2.66E+01 5.00E+01 1.56E+01 1.30E+01 pCi/L Fe-55 12/15/05 U -1.98E+01 3.26E+01 5.02E+01 1:00E+02 3.26E+01 2.47E+01 pCi/L Ni-63 12/15/05 U 3.05E+00 1.69E+01 2.89E+01' 5.00E+01 1.69E+01 1.41E+01 pCi/L Tc-99 12/19/05 U -3.14E+00 1.17E+01 2.01E+01 5.OOE+01 1.17E+01 9.89E+00 pCi/L, Pm-147 12/21/05 U 4.64E+00 5.15E+00 8.64E+00 1.00E+01 5.16E+00 4.25E+00 pCi/L Pu-241 12/28/05 U 2.13E+01 3.44E+01 5.79E+01 1.50E+01 3.44E+01 2.85E+01 pCi/L Total Strontium 12/14/05 U -2.20E-02 4.46E-01 1.03E+00 2.OOE+00 4.45E-01 4.77E-01 pCi/L Alpha Spec Np-237 12/15/05 U 8.02E-02 1.57E-01 2.17E-01 1.00E+00 1.57E-01 0.OOE+00 pCi/L Pu-238 12/15/05 U -5.22E-02 2.59E-01 8.37E-01 1.00E+00 2.59E-01 3.08E-01 pCi/L Pu-239/240 12/15/05 U -1.34E-01 2.04E-01 8.36E-01 1.00E+00 2.05E-01 3.08E-01 pCi/L Pu-244 12/15/05 U 2.05E-01 2.82E-01 4.83E-01 1.00E+00 2.83E-01 1.31E-01 pCi/L Am-241 12/15/05 U 5.45E-02 1.45E-01 2.72E-01 1.00E+00 1.45E-01 0.OOE+00 pCi/L Cm-243/244 12/15/05 U 7.64E-02 2.03E-01 5.01E-01 1.00E+00 2.03E-01 1.15E-01 pCi/L Gamma Spec Be-7 12/19/05 U -9.72E+00 1.71E+01 2.78E+01 1.OOE+01 1.68E+01 1.30E+01 pCi/L Na-22 12/19/05 U -2.31E-01 1.68E+00 3.01E+00 1.00E+01 1.65E+00 1.34E+00 pCi/L K-40 12/19/05 4.38E+01 3.61E+01 2.74E+01 1.00E+01 3.54E+01 1.20E+01 pCi/L Cr-51 12/19/05 U -4.62E+00 2.46E+01 4.14E+01 1.00E+01 2.41E+01 1.97E+01 pCi/L Mn-54 12/19/05 U -1.37E-01 1.62E+00 2.91E+00 1.00E+01 1.59E+00 1.33E+00 pCi/L Fe-59 12/19/05 U 1.59E+00 6.03E+00 8.22E+00 1.00E+01 5.91E+00 3.76E+00 pCi/L Co-56 12/19/05 U 2.72E-01 1.93E+00 3.52E+00 1.00E+01 1.89E+00 1.62E+60 pCi/L Co-57 12/19/05 U -2.26E-01 1.76E+00 3.01E+00 1.00E+01 1.72E+00 1.46E+00 pCi/L Co-58 1.2/19/05 U 1.38E+00 1.83E+00 3.55E+00 1.00E+01 1.79E+00 1.64E+00 pCi/L Co-60 . 12/19/05 U 1.88E-01 1.68E+00 3.12E+00 1.00E+01 .1.65E+00 1.39E+00 pCi/L Ni-59 12/30/05 U 1.37E+01 9.82E+00 1.57E+01 2.OOE+01 9.68E+00 7.49E+00 pCi/L Zn-65 12/19/05 *U -1.19E+00 3.98E+00 6.90E+00 1.00E+01 3.90E+00 3.14E+00 pCi/L Y-88 12/19/05 U 1.89E+00 1.99E+00 4.30E+00 1.00E+01 1.95E+00 1.91E+00 pCi/L Zr-95 12/19/05 U 3.29E+00 4.39E+00 6.18E+00 1.00E+01 4.30E+00 2.85E+00 pCi/L Nb-94 12/19/05 U -5.65E-01 1.69E+00 2.95E+00 1.00E+01 1.66E+00 1.38E+00 pCi/L Nb-95 12/19/05 U -4.92E-01 2.23E+00 3.95E+00 1.00E+01 2.19E+00 1.81E+00 pCi/L Ru-106 12/19/05 U -1.15E+01 1.51E+01 2.55E+01 1.00E+01 1.48E+01 1.18E+01 pCi/L Ag-ll0m 12/19/05 U -9.87E-01 1.42E+00 2.41E+00 1.00E+01 1.39E+00 1.1OE+00 pCi/L Sn-113 12/19/05 U 1.18E+00 2.41E+00 4.27E+00 1.00E+01 2.37E+00 2.02E+00. pCi/L Note(s): 1. Calculated MDAs are a-posteriori values,
- 2. Activity concentration net +/- 2 sigma overall on reference date.
- 3. Results are statistically positive at the 99.9% confidence level (activity is greater than three times the one sigma uncertainty)
U Target analyte was analyzed for but not detected above the MDL or LOD.
UI Uncertain identification for gamma spectroscopy.
X Lab-specific qualifier-please see case narrative, data summary package or contact your project manager for details.
Page 32 of 58
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com 10 CFR Part 50/61 Certificate of Analysis GEL Sample ID: 151732002 Client: Rancho Seco Nuclear Generating Station Client Sample ID: #2 MW2A Collect Date: November 29, 2005 Matrix: Ground Water Receive Date: December 12, 2005 Amount of Sample Received: Report Date: December 31, 2005 2 1 Critical
.A..Anallyte
.y. ..............
te... Run Date Qualifier Activity Uncertainty MDA TPU Level _Uni-ts.-..
Sb- 124 12/19/05 U 3.20E+00 4.60E+00 9.54E+00 1.00E+01 4.5 1E+00 4.25E+00 pCi/L Sb-125 12/19/05 U 2.82E+00 5.09E+00 9.01E+00 1.00E+01 4.99E+00 4.26E+00 pCi/L Cs-134 12/19/05 U 4.83E-01 1.75E+00 3.26E+00 1.001E+01 1.72E+00 1.50E+00 pCi/L Cs-136 12/19/05 U -3.68E-01 6.08E+00 1.09E+01 1.00E+01 5.96E+00 4.95E+00 pCi/L Cs-137 12/19/05 U 6.04E-0 1 1.65E+00 2.75E+00 1.001E+01 1.61E+00 I .27E+00 pCi/L Ba-133 12/19/05 U 9.28E-01 2.32E+00 3.64E+00 1.00E+01 2.28E+00 1.72E+00 pCi/L Ba-140 12/19/05 U 1.07E+01 2.12E+01 3.28E+01 1.60E+01 2.07E+01 1.54E+01 pCi/L Ce-139 12/19/05 U 9.16E-02 1.85E+00 3.17E+00 1.00E+01 1.81E+00 1.53E+00 pCi/L Ce-141 12/19/05 U -5.OOE-01 4.52E+00 7.72E+00 1.00E+01 4.43E+00 3.74E+00 pCi/L Ce- 144 12/19/05 U -4.37E+00 1.39E+01 2.35E+01 1.00E+01 1.36E+01 1.14E+01 pCi/L Nd-147 12/19/05 U -1.47E+01 3.85E+01 6.35E+01 1.00E+01 3.77E+01 2.95E+01 pCi/L Pm-144 12/1 9/05 U 2.17E-01 1.59E+00 2.89E+00 1.00E+01 1.55E+00 1.34E+00 pCi/L Pm-146 12/19/05 U -7.84E-01 2.3 1E+00 3.83E+00 1.001E+01 2.26E+00 1.80E+00 pCi/L Eu-152* 12/19/05 U 3.25E+00 5.27E+00 9.34E+00 1.00E+01 5.16E+00 4.44E+00 pqCi/L Eu- 154 12/19/05 -6.3 1E-01 4.69E+00 8.40E+00 1.00E+01 4.60E+00 3.73E+00 pCi/L U
Eu-155 12/19/05 3.97E+00 7.25E+00 1.28E+01 1.00E+01 7.1OE+00 6.19E+00 pCi/L U
Ir- 192 12/19/05 1.92E+00 2.17E+00 3.87E+00 1.00E+01 2.13E+00 1.85E+00 pCi/L U
Hg-203 '12/19/05 -1.55E+00 2.47E+00 4.07E+00 1.00E+01 2.42E+00 1.95E+00 pCi/L U
TI-208 12/19/05 1.55E+00 1.95E+00 3.67E+00 1.00E+01 1.91E+00 1.73E+00 pCi/L U
Pb-210 12/19/05 2.04E+02 5.25E+02 8.32E+02 1.00E+01 5.14E+02 4.02E+02 pCi/L UU Pb-212 12/19/05 0.OOE+00 3.74E+00 6.76E+00 1.00E+01 3.66E+00 3.27E+00 pCi/L UU Pb-214 12/19/05 5.40E+00 8.77E+00 7.77E+00 1.00E+01 8.60E+00 3.72E+00 pCi/L U
Bi-212 12/19/05 9.351E+00 1.211E+01 2.35E+01 1.00E+01 1.19E+01 1.08E+01 pCi/L U
Bi-214 12/19/05 5.80E+00 7.27E+00 8.56E+00 1.00E+01 7.12E+00 4.09E+00 pCi/L U
Ra-228 12/19/05 6.35E+00 6.28E+00 1.23E+01 1.00E+01 6.15E+00 5.69E+00 pCi/L U
Ac-228 12/19/05 6.35E+00 6.28E+00 1.23E+01 1.00E+01 6.15E+00 5.69E+00 pCi/L UU Th-230 12/19/05 0.OOE+00 7.27E+00 5.72E+00 1.00E+01 7.12E+00 2.67E+00 pCi/L Th-234 12/19/05 U 5.44E+01 1.66E+02 1.91E+02 1.00E+01 1.62E1+02 9.26E+01 pCi/L U-235 12/19/05 U 1.26E+01 1.53E+01 2.38E+01 1.00E+01 1.501E+01 1.16E+01 pCi/L U-238 12/19/05 U 5.44E+01 1.66E+02 1.91E+02 1.00E+01 1.62E+02 9.26E+01 pCi/L Np-239 12/19/05 U -6.41 E+00 1.34E+01 2.26E+01 1.00E+01 1.31E+01 1.1OE+01 pCi/L Am-241 12/19/05 U -1.38E+01 1.59E+01 2.32E+-01 1.56E+01 1.12E+01 pCi/L Note(s): 1. Calculated MDAs are a-posteriori values.
- 2. Activity concentration net +/- 2 sigma overall on reference date.
- 3. Results are statistically positive at the 99.9% confidence level (activity is greater than three times the one sigma uncertainty)
U Target analyte was analyzed for but not detected above the MDL or LOD.
U' Uncertain identification for gamma spectroscopy.
X Lab-specific tqualifier-please see case narrative, data summary vPackage or contact your proiect manager for details.
Page 33 -of58
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com 10 CFR Part 50/61 Certificate of Analysis GEL Sample ID: 151732003 Client: Rancho Seco Nuclear Generating Station Client Sample ID: #3 MW3A Collect Date: December 05, 2005 Matrix: Ground Water Receive Date: December 12, 2005 Amount of Sample Received: Report Date: December 31, 2005 2
Critical
- I---
Analyte Run Date Qualifier Activity Uncertainty MDA R. TPU Level Units ALPHA 12/23/05 U -3.14E-01 3.74E-01 1.25E+00 5.OOE+00 3.74E-01 4.89E-01 pCi/L BETA 12/23/05 U 2.18E+00 2.19E+00 4.38E+00 5.OOE+00 2.19E+00 2.10E+00 pCi/L H-3 12/14/05 U 5.03E+01 2.12E+02 3.65E+02 7.OOE+02 2.12E+02 1.76E+02 pCi/L C-14 12/14/05 U. 7.OOE+00 1.57E+01 2.67E+O1 5.OOE+01 1.57E+01 1.30E+01 pCi/L Fe-55 12/15/05 U -1.19E+01 3.88E+01 5.89E+01 1.00E+02 3.88E+01 2.90E+01 pCi/L Ni-63 12/15/05 3 2.76E+01 1.62E+01 2.64E+01 5.OOE+01 1.62E+01 1.28E+01 pCi/L Tc-99 12/19/05 U 5.45E-01 1.23E+01 2.10E+01 5.OOE+01 1.23E+01 1.03E+01 pCi/L Pm-147 12/21/05 U 6.44E-OO 4.71E+00 7.82E+00 1.00E+01 4.72E+00 3.84E+00 pCi/L Pu-241 12/16/05 U -2.02E+00 5.63E+00 9.75E+00 1.50E+01 5.64E+00 4.77E+00 pCi/L Total Strontium 12/14/05 U -2.79E-01 3.81E-0I 9.55E-01 2.OOE+00 3.81E-01 4.43E-01 pCi/L Alpha Spec Np-237 12/15/05 U -1.08E-01 9.48E-02 7.03E-01 1.00E+00 9.54E-02 2.30E-01 pCi/L Pu-238 12/15/05 U -1.33E-01 2.43E-01 8.56E-01 1.00E+00 2.43E-01 3.30E-01 pCi/L Pu-239/240 12/15/05 U -8.40E-02 1.75E-01 6.91E-01 1.00E+00 1.75E-01 2.47E-01 pCi/L Pu-244 12/15/05 U 5.50E-02 1.46E-01 3.61E-01 1.00E+00 1.46E-01 8.25E-02 pCi/L Am-241 12/i5/05 U 6.33E-02 1.40E-0I 3.10E-01 1.00E+00 1.40E-01 7.08E-02 pCi/L Cm-243/244 12/15/05 U 4.72E-02 1.25E-01 3.10E-01 1.00E+00 1.25E-01 7.08E-02 pCi/L Gamma Spec Be-7 12/19/05 U 2.78E+00 1.90E+01 3.32E+01 1.00E+01 1.86E+61 1.57E+01 pCi/L Na-22 12/19/05 -U 7.56E-01 1.84E+00 3.49E+00. 1.00E+01 1.80E+00 1.58E+00 pCi/L K-40 12/19/05 U 1.11E+01 2.92E+01 2.90E+01 1,00E+01 2.87E+01 1.29E+01 pCi/L Cr-51 12/19/05 U -1.17E+00 2.23E+01 3.87E+01 1;00E+01 2.18E+01 1.85E+01 pCi/L Mn-54 12/19/05 U 2.41E+00 1.93E+00 3.77E+00 1.00E+01 1.89E+00 1.77E+00 pCi/L Fe-59 12/19/05 U 4.17E-02 4.52E+00 8.08E+00 1.00E+01 4.43E+00 3.73E+00 pCi/L Co-56 12/19/05 U -3.13E-01 1.91E+00 3.41E+00 1.00E+01 1.88E+00 1.57E+00 pCi/L Co-57 12/19/05 U 8.OOE-01 1.93E+00 2.91E+00 1.00E+01 1.89E+00 1.41E+00 pCi/L Co-58 12/19/05 U 1.54E+00 2. 15E+00 4.06E+00 1.00E+01 2.11 E+00 1.90E+00 pCi/L Co-60 12/19/05 U 1.32E+00 2.29E+00 3.35E+00 1.00E+01 2.25E+00 1.51E+00 pCi/L Ni-59 12/30/05 U 2.67E+00 1.07E+01 1.56E+01 2.OOE+01 1.04E+01 7.34E+00 pCi/L Zn-65 12/19/05 U -6.19E+00 4.57E+00 7.02E+00 1.00E+01 4.48E+00 3.21E+00 pCi/L Y-88 12/19/05 U -7.51E-02 1.95E+00 3.65E+00 1.00E+01 1.91E+00 1.60E+00 pCi/L Zr-95 12/19/05 U -2.56E+00 4.02E+00 5.76E+00 1.00E+01 3.94E+00 2.66E+00 pCi/L Nb-94 12/19/05 U -1.22E+00 1.86E+00 3.02E+00 1.00E+01 1.82E+00 1.41E+00 pCi/L Nb-95 12/19/05 U 1.18E+00 2.39E+00 4.44E+00 1.00E+01 2.34E+00 2.08E+00 pCi/L Ru-106 12/19/05, U 1.01E+01 1.70E+01 3.08E+01 1.00E+01 1.67E+01 1.45E+01 pCi/L Ag-110m 12/19/05 U -1.86E+00 2.14E+00 3.42E+00 1.00E+01 2. i 0E+00 1.61E+00 pCi/L Sn-113 12/19/05 U 1.80E+00 2.55E+00 4.62E+00 1.00E+01 2.50E+00 2.20E+00 pCi/L Note(s): 1. Calculated MDAs are a-posteriori values.
- 2. Activity concentration net +/- 2 sigma overall on reference date.
- 3. Results are statistically positive at the 99.9% confidence level (activity is greater than three times the one sigma uncertainty)
U Target analyte was analyzed for but not detected above the MDL or LOD.
UI Uncertain identification for gamma spectroscopy.
X Lab-specific qualifier-please see case narrative, data summary package or contact your proiect manager for details.
Page 34 of 58
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 -:www.gel.com 10 CFR Part 50/61 Certificate.of Analysis GEL Sample ID: 151732003 Client: Rancho Seco Nuclear Generating Station Client Sample ID: #3 MW3A Collect Date: December 05, 2005 Matrix: Ground Water Receive Date: December 12, 2005 Amount of Sample Received: Report Date: December 31, 2005 2
Critical Run Date Qualifier Activity Uncertainty MDA RL TPU Level .U-nits-----
Sb-124 12/19/05 U -1.85E+00 4.85E+00 8.59E+00 1.00E+01 4.75E+00 3.82E+00 pCi/L Sb-125 12/19/05 U -2.58E+00 5.5 1E+00 9.30E+00 1.00E+01 5.40E+00 4.4 1E+00 pCi/L Cs-134 12/19/05 U 7.61E-02 2.03E+00 3.67E+00 1.00E+01 1.99E+00 1.70E+00 pCi/L Cs-136. 12/19/05 'U -3.79E-01 4.54E+00 8.16E+00 1.00E+01 4.45E+00 3.7 1E+00 pCi/L Cs-137 12/19/05 U 1.1OE+00 2.25E+00 3.99E+00 1.00E+01 2.20E+00 1.88E+00 pCi/L Ba-133 12/19/05 U 1.21E+00 2.88E+00 4.5 1E+00 1.00E+01 2.82E+00 2.15E+00 pCi/L Ba-140 12/19/05 U 5.81E+00 1.41E+01 2.50E+01 1.00E+01 1.39E+01 1.18E+01 pCi/L Ce-139 12/19/05 U -1.16E-01 1.95E+00 3.26E+00 1.00E+01 1.9 IE+00 1.58E+00 pCi/L Ce-141 12/19/05 U 1.50E+00 4.3 1E+00 6.79E+00 1.00E+01 4.22E+00 3.29E+00 pCi/L Ce-144 12/19/05 U 8.16E+00 1.57E+01 2.37E+01 1.00E+01 1.54E+01 1.15E+01 pCi/L Nd-147 12/19/05 U 9.92E+00 3.03E+01 5.39E+01 1.00E+01 2.97E+01 2.54E+01 pCi/L Pm- 144 12/19/05 U 8.05E-01 1.81E+00 3.23E+00 1.00E+01 1.77E+00 1.52E+00. pCi/L Pm-146 12/19/05 U -3.64E-01 2.52E+00 4.34E+00 1.00E+01 2.47E+00 2.05E+00 pCi/L Eu-152 12/19/05 U -7.22E-01 5.94E+00 1.03E+01 1.00E+01 5.82E+00 4.92E+00 pCi/L Eu-154 12/19/05 U 2.06E+00 5.14E+00 9.72E+00 1.00E+01 5.03E+00 4.4 1E+00 pCi/L Eu-155 12/19/05 U 2.24E-01 8.12E+00 1.21E+01 1.00E+01 7.96E+00 5.84E+00 pCi/L Ir- 192 12/19/05 U -1.04E-01 2.12E+00 3.70E+00 1.00E+01 2.08E+00 1.77E+00 pCi/L Hg-203 12/19/05 U 8.70E-01 2.4 1E+00 4.28E+00 1.00E+01 2.36E+00 2.06E+00 pCi/L TI-208 12/19/05 U 3.1OE+00 2.26E+00 4.22E+00 1.00E+01 2.22E+00 2.OOE+00 pCi/L Pb-210 12/19/05 U 2.6 1E+02 4.18E+02 6.52E+02 1.00E+01 4.09E+02 3.16E+02 pCi/L Pb-212 12/19/05 U 3.96E+00 4.04E+00 6.92E+00 1.00E+01 3.96E+00 3.35E+00 pCi/L Pb-214 12/19/05 UUI 0.OOE+00 8.05E+00 9.68E+00 1.00E+.01 7.89E+00 4.68E+00 pCi/L Bi-212 12/19/05 UUI 0.OOE+00 5.17E+01 2.38E+01 1.00E+01 5.07E+01 1. 1OE+01 pCi/L Bi-214 12/19/05 UUI 0.00E+00 8.41E+00 9.97E+00 1.00E+01 8.24E+00 4.79E+00 pCi/L Ra-228 12/19/05 U 5.42E+00 1.48E+01 1.34E+01 1.00E+01 1.45E+01 6.25E+00 pCi/L Ac-228. 12/19/05 U 5.42E+00 1.48E+01 1.34E+01 1.00E+01 1.45E+01 6.25E+00 pCi/L Th-230 12/19/05 .3 1.76E+01 8.4 1E+00 6.54E+00 1.00E+01 8.24E+00 3.08E+00 pCi/L Th-234 12/19/05
.U -7.78E+01 1.22E+02 1.75E+02 1.00E+01 1.1 9E+02 8.52E+01 pCi/L U-235 12/19/05 U 8.68E+00 1.52E+01 2.29E+01 1.00E+01 1.49E+01 1.1 ]E+01 pCi/L U-238 12/19/05 U -7.78E+01 1.22E+02 1.75E+02 1.00E+01 1.1 9E+02 8.52E+01 pCi/L Np-239 12/19/05 U 6.77E+00 1.48E+01 2.24E+01 1.00E+01 1.45E+01 I.09E+01 pCi/L Am-241 12/19/05 U -1 .04E+01 1.49E+01 2.15E+01 1.00E+01 1.46E+01 1.05E+01 pCi/L Note(s): 1. Calculated MDAs are a-posteriori values.
- 2. Activity concentration net +/- 2 sigma overall on reference date.
- 3. Results are statistically positive at the 99.9% confidence level (activity is greater than three times the one sigma uncertainty)
U Target analyte was analyzed for but not detected above the MDL or LOD.
UI Uncertain identification for gamma spectroscopy.
X Lab-specific rlualifier-please see case narrative, data summary Packa2e or contact your project manager for details.
Page 35 of 58
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com 10 CFR Part 50/61 Certificate of Analysis GEL Sample ID: 151732004 Client: Rancho Seco Nuclear Generating Station Client Sample ID: #4 MW4A Collect Date: December 06, 2005 Matrix: Ground Water Receive Date: December 12, 2005 Amount of Sample Received: Report Date: December 31, 2005 2 M Critical Analyte Run Date Qualifier Activity Uncertaint y MA L PU Level Units ALPHA 12/23/05 U 1.21E+00 1.80E+00 3.61E+00 5.00E+00 1.80E+00 1.65E+00 pCi/L BETA 12/23/05 U 1.53E+00 2.13E+00 4.30E+00 5.OOE+00 2.13E+00 2.06E+00 pCi/L H-3 12/15/05 U -2.70E+01 2.07E+02 3.62E+02 7.OOE+02 2.07E+02 1.75E+02 pCi/L C-14 12/14/05 U 1.25E+01 1.59E+01 2.67E+01 5.00E+01 1.59E+01 1.30E+01 p~ifll Fe-55 12/16/05 U 2.07E-01 3.37E+01 5.07E+01 1.00E+02 3.37E+01 2.49E+01 pCi/L Ni-63 12/15/05 U 5.74E+00 1.56E+01 2.67E+01 5.OOE+01 1.56E+01 1.30E+01 pCi/L Tc-99 12/19/05 U -3.57E+00 1.30E+01 2.23E+01 5.OOE+01 1.30E+01 1.1OE+0I pCi/L Pm-147 12/22/05 U 3.20E+00 4.65E+00 7.83E+00 1.00E+01 4.65E+00 3.85E+00 pCi/L Pu-241 12/16/05 U -3.20E+00 6.15E+00 .1.07E+01 1.50E+01 6.16E+00 5.23E+00 pCi/L Total Strontium 12/14/05 U -I.51E-01 4.01E-01 9.64E-01 2.OOE+00 4.01E-01 4.47E-01 pCi/L Alpha Spec Np-237 12/15/05 U -1.01E-01 7.50E-02 5.27E-01 1.00E+00 7.56E-02 1.82E-01 pCi/L Pu-238 12/15/05 U -2.20E-01 2.46E-01 -1.05E+00 1.00E+00 .2.47E-01 3.98E-01 pCi/L Pu-239/240 12/15/05 U -6.72E-02 1.98E-01 6.21E-01 1.00E+00 1.98E-01 1.84E-01 pCi/L Pu-244 12/15/05 3,X 1.07E+00 6.36E-01 5.53E-01 1.00E+00 6.48E-01 1.50E-01 pCi/L Am-241 12/15/05 U -4.60E-02 3.13E-01 4.32E-01 1.00E+00 3.14E-01 0.00E+00 pCi/L Cm-243/244 12/15/05 U 0.00E+00 3.13E-01 4.32E-01 1.00E+00 3.13E-01 0.00E+00 pCi/L GammaSpec Be-7 12/20/05 U -9.69E+00 2.06E+01 3.37E+01 1.00E+01 2.02E+01 I1.57E+01 pCi/L Na-22 12/20/05 U -2.26E-01 2.08E+00 3.82E+00 1.00E+01 2.04E+00 1.70E+00 pCi/L K-40 12/20/05 U 2.97E+01 2.56E+01 5.20E+0I 1.00E+01 2.51E+01 2.39E+01 pCi/L Cr-51 12/20/05 U 1.77E+01 4.01E+01 4.56E+01 1.00E+01 3.93E+01 2.17E+01 pCi/L Mn-54 12/20/05 U -3.57E-01 1.87E+00 3.28E+00 1.00E+01 1.83E+00 1.49E+00 pCi/L Fe-59 12/20/05 U -1.34E+00 4.66E+00 7.16E+00 I.00E+01 4.57E+00 3.17E+00 p~i/L Co-56 12/20/05 U -4.89E-01 2.19E+00 3.81E+00 1.00E+01 2.14E+00 1.74E+00 p~i/L Co-57 12/20/05 U -3.93E-01 2.07E+00 3.61E+00 1.00E+01 2.03E+00 1.74E+00 pCi/ll Co-58 12/20/05 U -7.12E-01 1.99E+00 3.43E+00 1.00E+01 1.95E+00 1.55E+00 pCi/ll Co-60 12/20/05 U -1.30E+00 1.99E+00 3.38E+00 1.00E+01 1.95E+00 1.48E+00 pCi/L Ni-59 12/30/05 U 8.76E+00 1.01E+01 1.56E+61 2.OOE+01 9.93E+00 7.41E+00 pCi/L Zn-65 12/20/05 U 4.93E+00 4.32E+00 8.35E+00 1.00E+01 4.23E+00 3.79E+00 PCi/L Y-88 12/20/05 U -8.22E-01 2.58E+00 4.49E-00 1.00E+01 2.53E+00 1.97E+00 pCi/L Zr-95 12/20/05 U -2.74E+00 3.83E+00 6.35E+00 1.00E+01 3.75E+00 2.88E+00 pCi/L Nb-94 12/20/05 U -5.10E-01 1.97E+00 3.44E+00 1.00E+01 1.93E+00 1.59E+00 pCi/L Nb-95 12/20/05 U -9.82E-01 2.66E+00 4.56E+00 1.00E+01 2.60E+00 2.1OE+00 pCi/L Ru-106 12/20/05 U 6.36E+00 1.88E+01 3.48E+01 i.00E+01 1.85E+01 1.62E+01 pCi/L Ag-110m 12/20/05 U 9.81E-0I 2.08E+00 3.88E+00 1.00E+01 2.04E+00 1.80E+00 pCi/L Sn- 113 12/20/05 U -2.40E+00 3.03E+00 4.87E+00 1.00E+01 2.97E+00 2.28E+00 pCi/L Note(s): 1. Calculated MDAs are a-posteriori values.
- 2. Activity concentration net +/- 2 sigma overall on reference date.
- 3. Results are statistically positive at the 99.9% confidence level (activity is greater than three times the one sigma uncertainty)
U Target analyte was analyzed for but not detected above the MDL or LOD.
UI Uncertain identification for gamma spectroscopy.
X Lab-specific clualifier-please see case narrative, data summary package or contact your project manager for details.
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GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com 10 CFR Part 50/61 Certificate ofAnalysis GEL Sample ID: 151732004 Client: Rancho Seco Nuclear Generating Station Client Sample ID: #4 MW4A Collect Date: December 06, 2005 Matrix: Ground Water Receive Date: December 12, 2005 Amount of Sample Received: Report Date: December 31, 2005 2 1 Critical Analyte Run Date Qualifier Activity Uncertainty MDA RL TPU Level Units Sb-124 12/20/05 3.25E-01 5.39E+00 1.00E+01 1.00E+01 5.28E+00 4.43E+00 pCi/L pCi/L Sb-125 12/20/05 -2.19E+00 6.33E+00 1.05E+01 1.00E+01 6.20E+00 4.94E+00 pCi/L Cs-134 12/20/05 -6.57E-01 2.23E+00 3.87E+00 1.001E+01 2.19E+00 1.76E+00 pCi/L Cs-136 12/20/05 1.83E+00 4.90E+00 9.24E+00 1.00E+01 4.80E+00 4.16E+00 pCi/L Cs-137 12/20/05 -1.69E+00 2.47E+00 3.48E+00 1.00E+01 2.42E+00 1.60E+00 pCi/L Ba-133 12/20/05 3.61E+00 3.14E+00 5.29E+00 1,00E+01 3.08E+00 2.5 1E+00 pCi/L Ba-140 12/20/05 6.49E+00 1.71E+01 2.79E+0 1 1.00E+01 1.67E+01 1.30E+01 pCi/L Ce-139 12/20/05 -3.90E-01 2.23E+00 3.87E4-00 1.001E+01 2.18E+00 1.86E+00 pCi/L Ce-i141 12/20/05 1.86E+00 4.70E+00 8.38E+00 1.00E+01 4.6 1E+00 4.04E+00 pCi/L Ce-I144 12/20/05 -6.07E-02 1.57E+01 2.77E+01 1.00E+01 1.54E+01 1.33E+01 pCi/L Nd-147 12/20/05 2.08E+01 3.57E+01 5.98E+01 1.00E+01 3.49E+01 2.79E+01 pCi/L Pm-144 12/20/05 -5.03E-01 1.87E+00 3.26E+00 1.00E+01 1.83E+00 1.50E+00 pCi/L Pm-146 12/20/05 -1 .02E+00 3.46E+00 4.97E+00 1.001E+01 3.39E+00 2.33E+00 pCi/L Eu-152 12/20/05 -5.91E-01 7.19E+00 1.23E+01 1.00E+01 7.04E+00 5.8]E+00 pCi/L Eu-154 12/20/05 -6.31E-01 5.8 1E+00 1.07E+01 1.001E+01 5.70E+00 4.75E+00 pCi/L Eu-155 12/20/05 1.34E+00 8.18E+00 1.37E+01 1.00E+01 8.01E+00 6.555E+00 pCi/L Ir-192 12/20/05 1.69E+00 3.82E+00 4.36E+00 1.00E+01 3.75E+00 2.07E+00 pCi/L Hg-203 12/20/05 2.50E+00 2.91E+00 5.26E+00 1.00E+01 2.85E+00 2.5 1E+00 pCi/L TI-208 12/20/05 1.73E+00 2.26E+00 4.29E+00 1.00E+01 2.2 1E+00 2.01E+00 pCi/L Pb-210 12/20/05 -3.84E+01 4.92E+02 7.41E+02 1.001E+01 4.82E+02 3.56E+02 pCi/L Pb-212 12/20/05 4.07E+00 6.35E+00 8.07E+00 1.00E+01 6.22E+00 3.88E+00 pCi/L Pb-214 12/20/05 2.03E+01 9.05E+00 9.3 1E+00 1.001E+01 8.87E+00 4.43E+00 pCi/L Bi-212 12/20/05 8.61E+00 3.71E+01 2.50E+01 1.00E+01 3.64E+01 1.14E+01 pCi/L Bi-214 12/20/05 1.61E+01 7.58E+00 8.04E+00 1.00E+01 7.43E+00 3.76E+00 pCi/L Ra-228 ..12/20/05 2.79E+00 1.43E+01 1.56E+01 1.00E+01 1.40E+01 ,7.20E+00 pCi/L Ac-228 12/20/05 2.79E+00 1.43E+01 1.56E+01 1.00E+01 1.40E+01 7.20E+00 pCi/L Th-230 12/20/05 1.61E+01 7.58E+00 8.04E+00 1.00E+01 7.43E+00 3.76E+00 pCi/L Th-234 12/20/05 6.71 E+0 I 1.78E+02 1.96E+02 1.00E+01 1.74E+02 9.44E+0 I pCi/L U-235 12/20/05 1.25E+01 1.85E+01 2.97E+01 1.00E+01 1.82E+01 1.44E+01 pCi/L U-238 12/20/05 6.71 E+0 1 1.78E+02 1.96E+02 1.00E+01 1.74E+02 9.44E+0 I pCi/L Np-239 12/20/05 -1.111E+01 1.56E+01 2.48E+01 1.00E+01 1.53E+01 1.19E+01 pCi/L Am-241 12/20/05 7.88E+00 2.04E+01 2.50E+01 1.00E+01 2.OOE+01 1.20E+01 Note(s): 1. Calculated MDAs are a-posteriori values.
- 2. Activity concentration net +/- 2 sigma overall on reference date.
- 3. Results are statistically positive at the 99.9% confidence level (activity is greater than three times the one sigma uncertainty)
U Target analyte was analyzed for but not detected above the MDL or LOD.
UI Uncertain identification for gamma spectroscopy.
X Lab-specific oualifier-please see case narrative, data summary package or contact your Proiect manager for details.
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I. II QUALITY CONTROL DATA II JI Page 38 of 58
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com QC Summary Revort Date: December 31, 2005 Client: Rancho Seco Nuclear Generating Page 1 of 20 Station 14440 Twin Cities Road Herald, California
Contact:
Mr. John Newey Workorder: 151732 Parmname NOM Sample Qual QC. Units RPD% REC%. Range Anlst Date Time Rad Alpha Spec Batch 487212
. QC1200994821 151732001 DUP Americium-241 U 0.202 U -0.0245 pCi/L N/A (0% - 100%) DDRI 12/15/05 16:40 Uncert: +/-0.237 +/-0.114 TPU: +/-0.238 +/-0.114 Curium-243/244 U -0.0474 U -0.0736 pCi/L N/A (0%- 100%)
Uncert: +/-0.140 +/-0.167 TPU: +/-0.140 +/-0.167 QC1200994823 LCS Americium-241 27.2 .26.3' pCi/L. 97 (75%-125%) 12/15/05 16:40 Uncert: +/-2.60 TPU: +/-4.22 Curium-243/244 33.0 30.3 pCi/L 92 Uncert: +/-2.79 TPU: +/-4.74 QC 1200994820 MB Americium-241 U 0.0263 pCi/L 12/15/05 16:40 Uncert: +/-0.129 TPU: +/-0.129 Curium-243/244 U 0.00 pCiIL Uncert: +/-0.111 TPU: +/-0.111
. QC1200994822 151732001 MS Americium-241 54.5 U 0.202 48.7 pCiIL 87 (75%-125%) 12/16/05 16:39 Uncert: +/-0.237 +/-4.64 TPU: +/-0.238 +/-7.51 Curium-243/244 66.2. U -0.0474 67.2 pCi/L 98 Uncert: +/-0.140 +/-5.45 TPU: +/-0.140 +/-9.80 Batch 487213 QC1200994825 151732002 DUP Neptunium-237 U 0.0802 U -0.0939 pCi/L N/A (0% - 100%) DDRI 12/15/05 08:05 Uncert: +140.157 +/-0.0752 TPU: +/-0.157 +/-0.0757 QC1200994827 LCS Neptunium-237 37.3 42.7 pCi/L 115 (75%-125%) 12/15/05 08:04 Uncert: +/-3.35 TPU: +/-5.21 QC1200994824 MB Neptunium-237 U -0.0305 pCi/L 12/15/05 08:05 Uncert: +/-0.0423 TPU: +/-0.0424 QC1200994826 151732002 MS Neptunium-237 74.5 U 0.0802 86.9 pCi/L 117 (75%-125%) 12/15/05 08:04 Page 39 of 58
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com QC Summary Workorder: 151732 Page 2 of 20 Parmname NOM Sample Qual QC Units RPD% REC% Range Anist Date Time Rad Alpha Spec Batch 487213 Uncert: +/-0.157 +/-6.66 TPU: +/-0.157 +/-10.5 Batch 487214 QC1200994829 151732001 DUP Plutonium-238 U 0.00 U 0.0724 pCi/L 0 (0% - 100%) DDRI 12/15/05 08:04 Uncert: +/-0.162 +/-0.298 TPU: +/-0.162 +/-0.298 Plutonium-239/240 U .- 0.102 pCi/L N/A (0%- 100%)
U -0.0596 Uncert: +/-0.0674 +/-0.156 TPU: +/-0.0677 +/-0.157.
Plutonium-244 U . 0.0798, pCi/L 70 (0%- 100%)
U 0.165 Uncert: +/-0.229 +/-0.180 TPU: +/-0.230 +/-0.180 QC1200994831 LCS Plutonium-238 U 0.418 pCi/L (75%-125%) 12/15/05 08:04 Uncert: +/-0.410 TPU: +/-0.413 Plutonium-239/240 25.2 23.5 pCi/L 93 (75%-125%)
Uncert: +/-2.90 TPU: +/-3.91 Plutonium-244 0.370 pCifL (75%-I 25%)
Uncert: +/-0.362 TPU: +/-0.365 QC1200994828 MB Plutonium-238' U -0.121 pCi/L 12/15/05 08:04 Uncert: +/-0.0898 TPU: +/-0.0907 Plutonium-239/240 U 0.00289 pCi/L Uncert: +/-0.157 TPU: +/-0.157 Plutonium-244 U 0.0722 pCi/L Uncert: +/-0.141 TPU: +/-0.142 QC1200994830 151732001 MS Plutonium-238 U 0.00 U -0.152 pCi/L (75%-125%) 12/15/05 08:04 Uncert: +/-0.162 +/-0.550 TPU: +/-0.162 +/-0.550 Plutonium-239/240 50.3 U -0.0596 51.2 pCi/L 102 (75%-125%)
Uncert: +/-0.0674 +/-5.27 TPU: +/-0.0677 +/-7.39 Plutonium-244 U .0.165 U 0.636 pCi/L (75%-125%)
Uncert: +/-0.229 +/-0.623 TPU: +/-0.230 +/-0.627 Batch 487216 QC1200994834 .151732003 DUP Plutonium-241 U -2.02 U -1.91 pCi/L N/A (0% - 100%) DDRI 12/16/05 18:46 Uncert: +/-5.63 +/-6.31 TPU: +/-5.64 +/-6.31 Page 40 of 58
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com QC Summary Workorder: 151732 Page 3 of 20 Parmname. NOM Sample Qual QC Units RPD% REC% Range Anist Date Time Rad Alpha Spec Batch 487216 QC1200994836 LCS Plutonium-241 181 175 pCi/L 97 (75%-125%) 12/16/05 20:05 Uncert: +/-17.1 TPU: +/-24.3 QC1200994833 MB Plutonium-241 U -1.32 pCifL 12/16/05 17:43 Uncert: +/-6.13 TPU: +/-6.13 QC1200994835 151732003 MS Plutonium-241 725 *U -2.02 641 pCiIL 88 (75%-125%) 12/16/05 19:48 Uncert: +/-5.63 +/-64.8 TPU: +/-5.64 +/-89.1 Batch 490003 QC1201001148 151732002 DUP Plutonium-241 U 21.3 U 55.8 pCi/L 0* (0% - 100%) DDR1 12/28/05 21:59 Uncert: +/-34.3 +/-38.2 TPU: +/-34.4 +/-38.6 QC1201001150 LCS Plutonium-241 1810 1710 ,pCi/L 94 (75%-125%) 12/29/05 02:07 Uncert: +/-56.9 TPU: +/-174 QC1201001147 MB Plutonium-241 U 13.9 pCi/L 12/28/05 19:54 Uncert: +/-36.9 TPU: +/-36.9 QC1201001149 151732002 MS Plutonium-241 1810 U 21.3 1690 p~i/L 93 (75%-125%) .12/29/05 00:03 Uncert: +/-34.3 +/-82.9 TPU: +/-34.4 +/-214 Rad Gamma Spec Batch 488129 QC1200996968 151732601 DUP Actinium-228 U -0.373 U 3.36 pCi/L N/A (0%- 100%) MJHI 12/20/05 18:26 Uncert: +/-6.17 +/-9.43 TPU: +/-6.05 +/-9.24 Americium-241 U -5.11 U -0.209 pCi/L N/A (0%- 100%)
Uncert: +/-11.6 +/-16.3 TPU: +/-11.3 +/-16.0 Antimony- 124 U -1.85 U -1.88 pCi/L N/A (0%- 100%)
Uncert: +/-3.98 +/-3.01 TPU: +/-3.90 "+/-2.95 Antimony- 125 U 2.44 U 0.160 pCi/L 127 (0% - 100%)
Uncert: +/-5.31 +/-3.75 TPU: +/-5.20 +/-3.67 Barium-133 u 0.506 U 1.30 pCi/L 162 (0%- 100%)
Uncert: +/-2.60 +/-2.09 TPU: +/-2.55 +/-2.05 Barium- 140 U 10.7 U -4.75 pCi/L N/A (0%- 100%)
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GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com QC Summary Workorder: 151732 Page 4 of 20 Parmname NOM Sample Qual QC Units RPD% REC% Range Anist Date Tim e Rad Gamma Spec Batch 488129 Uncert: +/-20.1 +/-10.2 TPU: +/-19.7 +/-10.0 Beryllium-7 U -0.628 U -9.6 pCi/L N/A (0%- 100%)
Uncert: +/-18.8 +/-13.1 TPU: +/-18.5 +/-12.8 Bismuth-212 5:49 U 3.50 pCi/L 82 (0%- 100%)
U Uncert: +/-13.2 +/-14.4 TPU: +/-12.9 +/-14.1 Bismuth-214 4.62 U .3.05 pCi/L 147 (0%- 100%)
Uncert: +/-8.74 +/-5.18 TPU: +/-8.56 +/-5.08 Cerium- 139 -0.491 U -1.03 pCi/L N/A (0%- 100%)
U Uncert: +/-1.86 +/-1.46 TPU: +/-1.82 +/-1.43 Cerium- 141 2.85 U -0.205 pCi/L N/A (0%- 100%)
U Uncert: +/-6.81 +/-3.17, TPU: +/-6.67 +/-3.11 Cerium- 144 -6.92 U 0.212 pCi/L N/A (0%- 100%)
U Uncert: +/-12.5 +/-10.5 TPU: -+/-12.2 +/-10.3 Cesium- 134 U .0.624 0.878 pCi/L 35 (0%- 100%)
Uncert: +/-1.82 :U +/-1.43 TPU: +/-1.78 +/-1.40 Cesium- 136 5.23 U -1.1 pCi/L N/A (0%- 100%)
U Uncert: +/-6.86 U +/-4.22 TPU: +/-6.72 +/-4.13 Cesium- 137 0.308 U -0.602 pCi/L N/A (0%- 100%)
U Uncert: +/-2.38 U +/-1.22 TPU: +/-2.33 +/-1.19 Chromium-51 U -2.41 -15.9 pCi/L N/A (0%- 100%)
Uncert: +/-25.0 U +/-16.0 TPU: +/-24.5 +/-15.7 Cobalt-56 U 0.213 0.750 pCi/L 232 (0%- 100%)
Uncert: +/-1.88 U +/-1.36 TPU: +/-1.84 ,+/-1.33 Cobalt-57 U 0.797 0.718 pCi/L 846 (0%- 100%)
Uncert: +/-1.66 U +/-1.34
+/-1.63 +/-1.31 TPU:
Cobalt-58 U -1.79 -0.526 pCi/L N/A (0%- 100%)
Uncert: +/-1.94 U +/-1.34 TPU: +/-1.90 +/-1.31 Cobalt-60 U -0.102 0.322 pCi/L N/A (0%- 100%)
Uncert: +/-1.84 +/-1.51 TPU: +/-1.80 +/-1.48 Europium- 152 U 4.63 -2.21 pCi/L N/A (0%- 100%)
Uncert:. +/-6.19 +/-4.08 TPU: +/-6.06 +/-4.00 Europium- 154 U -3.39 U -1.44 pCi/L N/A (0%- 100%)
Page 42 of 58
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel~com QC Summary Workorder: 151732 Page 5 of 20 Parmname NOM Sample Qual QC Units RPD% REC% Range Anist Date Time Rad Gamma Spec Batch 488129 Uncert: +/-5.16 +/-4.05 TPU: +/-5.05 +/-3.97 Europium-155 U 0.139 U 2.75 pCi/L 1660 (0%- 100%)
Uncert: +/-6.87 +/-5.69 TPU: +/-6.73 +/-5.58 Iridium-192 U -1.13 U 0.963 pCi/L N/A (0%- 100%)
Uncert: +/-2.03 +/-1.49 TPU: +/-1.99 +/-1.46 Iron-59 u 1.72 U 0.443 pCi/L 108 (0%- 100%)
Uncert: +/14.28 +/-3.07.
TPU: +/-4.20 +/-3.01 Lead-210 U -19.8 .U 315 pCi/L N/A Uncert: +/-387 +/-416 TPU: +/-379 +/-407 Lead-212 U 1.35 U 2.98 pCi/L 71 (0%- 100%)
Uncert: +/-5.89 +/-4.73 TPU: +/-5.77 +/-4.63 Lead-214 U 4.05 U 1.79 pCi/L 128 (0%- 100%)
Uncert: +/-6.54 +1-5.30 TPU: +/-6.41 +/-5.20 Manganese-54 U -1.08 U 0.740 pCi/L N/A (0%- 100%)
Uncert: +/-1.57 +/-1.31 TPU: +/-1.53 +/-1.28 Mercury-203 U -0.283 U 2.19 pCi/L N/A (0% - 100%)
Uncert: .+/-2.55 +/-1.79 TPU: +/-2.50 +/-1.76 Neodymium-147 U 16.3 U 0.741 pCi/L 169* (0%- 100%)
Uncert: +/-46.2 +/-22.5 TPU: +/-45.3 +/-22.1 Neptunium-239 U 0.211 U 4.99 pCi/L 153 (0%- 100%)
Uncert: +/-12.7 +/-9.79 TPU: +/-12.4 +/-9.60 Niobium-94 IU 0.619 U -1.18 pCi/L N/A (0%- 100%)
Uncert: +/-1.67 +/-1.42 TPU: +/-1.64 +/-1.39 Niobium-95 . U 0.780 U 0.919 pCi/L 533 (0%- 100%)
Uncert: +/-2.43 +/-1.81 TPU: +/-2.38 +/-1.77 Potassium-40 32.7 43.5 pCi/L 182* (0% - 100%)
Uncert: +/-27.5 +/-20.2 TPU: +/-27.0 +/-19.8 Promethium-144 U -0.00511 U 2.23 pCi/L N/A (0%-,100%)
Uncert: +/-1.70 +/-1.95 TPU: +/-1.67 +/-1.91 Promethium-146 U 2.65 U 0.0729 pCi/L 262 (0%- 100%)
Uncert: +/-2.38 +/-1.72 TPU: +/-2.33 +/-1.69 Radium-228 U -0.373 U 3.36 pCi/L N/A (0% - 100%)
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GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com
- QC Summary Workorder: 151732 Page 6 of 20 Parmname NOM Sample Qual QC Units RPD% REC% Range Anist Date Time Rad Gamma Spec Batch 488129 Uncert: +/-6.17 +/-9.43 TPU: +/-6.05 +/-9.24 Ruthenium- 106 U 11.5 U -8.42 pCi/L N/A (0%- 100%)
Uncert: +/-16.4 +/-11.4 TPU: +/-16.0 +/-11.2 Silver-I 10m U -0.234 U 0.379 pCi/L N/A (0%- 100%)
Uncert: +/-1.61 +/-1.09 TPU: +/-1.58 +/-1.06 Sodium-22 U -1.2 U -0.511 pCi/L N/A (0%- 100%)
Uncert: +/-1.86 +/-.1.45 TPU: +/-1.82 +/-1.42 Thallium-208 U 0.945 U 2.00 pCifL 110 (0%- 100%)
Uncert: +/-2.91 1-4-1.44 TPU: +/-2.85 +/-1.41 Thorium-230 . U 4.62 U 3.05 pCi/L 147 (0%- 100%)
Uncert: +/-8.73 +/-5.18 TPU: +/-8.56 +/-5.08 Thorium-234 U 166 UUI 0.00 pCi/L 210*
Uncert: +/-95.0 +/-107 TPU: +/-93.1 +/-105 Tin-1 13 U -0.927 U -0.698 pCi/L N/A (0%- 100%)
Uncert: +/-2.56 +/-1.86 TPU: +/-2.51 +/-1.82 Uranium-235 U 8.78 U -0.125 pCi/L N/A (0%- 100%)
Uncert: +/-18.4 +/-10.8 TPU: +/-18.1 +/-10.6 Uranium-238 U 166 UUI 0.00 pCi/L 210*
Uncert: +/-95.0 +/-107 TPU: +/-93.1 +/-105 Yttrium-88 U -0.374 U 0.147 pCi/L N/A (0%- 100%)
Uncert: +/-1.65 +/-1.51 TPU: +/-1.61 +/-1.48 Zinc-65 U -0.723 U -6.22 pCi/L N/A (0%- 100%)
Uncert: +/-3.71 +/-3.75 TPU: +/-3.64 +/-3.68 Zirconium-95 U -0.236 U 0.555 pCi/L N/A (0% 100%)
Uncert: +/-3.75 +/-2.61 TPU: +/-3.67 +/-2.55 QC1200996970 LCS Actinium-228 U 15.7 pCi/L 12/21/05 07:25 Uncert: +/-47.7 TPU: +-/-46.7 Americium-241 1220 1270 pCi/L 104 (75%-125%)
Uncert: +/-111 TPU: +/-109 Antimony-124 U 1.21 pCi/L Uncert: +/-14.7 TPU: +/-14.4 Page 44 of 58
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com QC Summary Workorder: 151732 Page 7 of 20 Parmname NOM Sample Qual QC Units RPD% REC% Range AnIst Date Time Rad Gamma Spec Batch 488129 Antimony- 125 U 4.35 pCi/L Uncert: +/-27.1 TPU: +/-26.6 Barium- 133 U -3.36 pCi/L Uncert: +/-11.4 TPU: +/-11.2 Barium- 140 U -1.36 pCi/L Uncert: +/-47.7 TPU: +/-46.7 Beryllium-7 U -87.7 pCi/L Uncert: +/-90.7 TPU: +/-88.9 Bismuth-212 U. -18.1 pCi/L Uncert: +/-86.5 TPU: +/-84.7 Bismuth-214 U 0.727 pCi/L Uncert: +/-19.9 TPU: +/-19.5 Cerium-139 164 pCi/L Uncert: +/-21.1 TPU: +/-20.6 Cerium- 141 U 9.14 pCi/L Uncert: +/-14.0 TPU: +/-13.7 Cerium-144 U -41.9 pCi/L Uncert: +/-57.0 TPU: +/-55.9 Cesium- 134 U 11.8 pCi/L Uncert: +/-12.4 TPU: +/-12.2 Cesium-136 U -0.399 pCi/L Uncert: +/-23.0 TPU: +/-22.6 Cesium-137 467 486 pCi/L 104 (75%-125%)-
Uncert: +/-47.6 TPU: +/-46.7 Chromium-51 U -11.1 pCi/L Uncert: +/-76.7 TPU: +/-75.1 Cobalt-56 U 3.63 pCi/L Uncert: +/-11.8 TPU: +/-11.6 Cobalt-57 215 pCi/L Uncert: +/-22.7 TPU: +/-22.3 Cobalt-58 U -0.964 pCi/L Uncert: +/-12.8 TPU: +/-12.6 Page 45 of 58
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com QC Summary Workorder: 151732 Page 8 of 20 Parmname NOM Sample Qual QC Units RPD% REC% Range Anlst Date Tim4e Rad Gamma Spec Batch 488129 Cobalt-60 691 708 pCi/L 103 (75%-125%)
Uncert: +/-66.2 TPU: +/-64.9 Europium- 152 U 7.28 pCi/L Uncert: +/-26.5 TPU: +/-26.0 Europium- 154 U -8.05 pCi/L Uncert: +/-25.6 TPU: +/-25.1 Europium- 155 U -7.14 pCi/L Uncert: +/-33.7 TPU: +/-33.0 Iridium- 192 U 1.00 pCi/L Uncert: +/-8.22 TPU: +/-8.06 Iron-59 U 9.36 pCi/L Uncert: +/-29.9 TPU: +/-29.3 Lead-210 U -23.8 pCi/L Uncert: +/-244 TPU: +/-239 Lead-212 U 8.65 pCi/L Uncert: +/-22.2 TPU: +/-21.8 Lead-214
- U 0.698 pCi/L Uncert: +/-18.6 TPU: +/-18.2 Manganese-54 U -7.99 pCi/L Uncert: +/-11.7 TPU: +/-11.5 Mercury-203 44.9 pCi/L Uncert: +/-13.1 TPU: +/-12.9 Neodymium- 147 U -132 pCi/L Uncert: +/-103 TPU: +/-100 Neptunium-239 U -3.93 pCi/L Uncert: +/-56.4 TPU: +/-55.3 Niobium-94 U 4.84 pCi/L Uncert: +/-10.0 TPU: +/-9.82 Niobiumn-95 U -0.316 pCi/L Uncert: +/-11.8 TPU: +/-11.6 Potassium-40 U -11.9 pCi/L Uncert: +/-81.9 TPU: +/-80.2 Page 46 of 58
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com QC Summary Workorder: 151732 Page 9 of 20 Parmname NOM Sample Qual 0C Units RPD% REC% Ranae Anist Date Time Rad Gamma Spec Batch 488129 Promethium-144 U 2.27 pCi/L Uncert: +/-9.76 TPU: +/-9.57 Promethium- 146 U -3.19 pCi/L Uncert: +/-13.2 TPU: +/-12.9 Radium-228 U 15.7 pCiIL Uncert: +/-47.7 TPU: +/-46.7 Ruthenium-106 U . 123 pCiIL Uncert: +/-98.8 TPU: +/-96.9 Silver-1 ICin U -5.37 pCiIL Uncert: +/-11.7 TPU: +/-11.4 Sodium-22 U -2.77 pCi/L Uncert: +/-9.14 TPU: +/-8.96 Thallium-208 U 12.84 pCi/L Uncert: +/-12.1 TPU: +/-11.9 Thorium-230 U 0.727 pCiIL Uncert: +/-19.9 TPU: +/-19.5 Thorium-234 U 185 pCi/ll Uncert: +/-203 TPU: +/-199 Tin-I 13 162 pCiIL Uncert: +/-32.4 TPU: +/-31.7 Uranium-235 U -31 pCifL Uncert: +/-56.8 TPU: +/-55*6 Uranium-238 U 185 pCiIL Uncert: +/-203 TPU: +/-199 Yttrium-88 325 pCiIL Uncert: +/-42.8 TPU: +/-41.9 Zinc-65 U 15.7 pCifL Uncert: +/-28.3 TPU: +/-27.7 Zirconium-95 U. -4.02 pCiIL Uncert: +/-20.1 TPU: +/-19.7 QC1200996967 MB Actinium-228 U 6.14 pCi/L 12/29/05 13:19 Uncert: +/-8.67 Page 47 of 58
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com QC Summary Workorder: 151732 Page 10 of 20 Parmname NOM Sample Qual QC Units RPD% REC% Range AnIst Date Timie Rad Gamma Spec Batch 488129 TPU: +/-8.50 Americium-241 U 1.83 pCi/L Uncert: +/-16.2 TPU: +/-15.9 Antimony- 124 U -1.3 pCi/L Uncert: +/-4.40 TPU: +/-4.31 Antimony-125 U -2.94 pCi/L Uncert: +/-5.70 TPU: +/-5.58 Barium-133 U -1.96 pCi/L Uncert: +/-2.76 TPU: +/-2.71 Barium- 140 U 2.08 pCi/L Uncert: +1-15.1 TPU: +/-14.8 Beryllium-7 U 28.4 pCi/L Uncert: +/-20.2 TPU: +/-19.8 Bismuth-212 U 10.8 pCi/L Uncert: +/-16.9 TPU: +/-16.6 Bismuth-214 U 6.83 pCi/L Uncert: +/-5.32 TPU: *+/-5.21 Cerium- 139 U -0.279 pCi/L Uncert: +/-1.75 TPU: +/-1.71 Cerium- 141 U 0.947 pCi/L Uncert: +/-4.22 TPU: +/-4.13 Cerium-144 UUI 0.00 pCi/L Uncert: +/-15.3 TPU: +/-15.0 Cesium- 134 U 0.191 pCi/L Uncert: +/-2.08 TPU: +/-2.04 Cesium- 136 U -2.64 pCi/L Uncert: +/-5.56 TPU: +/-5.44 Cesium-137 U 1.64 pCi/L Uncert: +/-2.11 TPU: +/-2.07 Chromium-51 U 10.7 pCi/L Uncert: +/-21.8 TPU: +/-21.4 Cobalt-56 . U 2.84 pCi/L Uncert: +/-3.25 Page 48 of 58
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com QC Summary Workorder: 151732 Page 11 of 20 Parmname NOM SamDle Oual OC Units RPD% REC% Ranae Anist Date Time Rad Gamma Spec Batch 488129 TPU: +/-3.19 Cobalt-57 0.813 pCi/L Uncert: +/-2.05 TPU: +/-2.00 Cobalt-58 0.302 pCi/L Uncert: +/-2.03 TPU: +/-1.99 Cobalt-60 2.73 pCi/L Uncert: +/-2.37 TPU: +/-2.33 Europium- 152 . 6.90 pCi/L Uncert: +/-5.83 TPU: +/-5.71 Europium- 154 -0.415 pCi/L Uncert: +/-5.30 TPU: +/-5.19 Europium-I 55 1.88 pCi/L Uncert: +/-6.38 TPU: +/-6.25 Iridium-192 -0.679 pCi/L Uncert: +/-2.16 TPU: +/-2.12 Iron-59 0.523 pCi/L Uncert: +/-4.37 TPU: +/-4.28 Lead-210 724 pCi/L Uncert: +/-596 TPU: +/-584 Lead-212 -0.886 pCi/L Uncert: +/-3.80 TPU: +/-3.73 Lead-214 5.83 pCi/L Uncert: +/-4.60 TPU: +/-4.51 Manganese-54 -0.298 pCi/L Uncert: +/-2.14 TPU: +/-2.10 Mercury-203 0.0663 pCi/L Uncert: +/-2.42 TPU: +/-2.37 Neodymium- 147 -4.28 pCi/L Uncert: +/-34.0 TPU: +/-33.3 Neptunium-239 -5.05 pCi/L Uncert: +/-11.8 TPU: +/-11.5 Niobium-94 -1.8 pCi/L Uncert: +/-2.17 Page 49 of 58
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com QC Summary Workorder: 151732 Page 12 of 20 Parmname NOM Sample Qual QC Units RPD% REC% Range AnIst Date Time Rad Gamma Spec Batch 488129 TPU: +/-2.13 Niobium-95 U 2.71 pCi/L Uncert: +/-2.42 TPU: +/-2.37 Potassium-40 UUI 0.00 pCi/L Uncert: +/-36.6 TPU: +/-35.8 Promethium- 144 U -2.14 pCi/L Uncert: +/-2.22 TPU: +/-2.18 Promethium- 146 UUI 0.00 pCi/L Uncert: +/-2.79 TPU: +/-2.74 Radium-228 U 6.14 pCi/L Uncert: +/-8.67.
TPU: +/-8.50 Ruthenium- 106 U -0.281 pCi/L Uncert: +/-20.1 TPU: +/-19.7 Silver-110m U -0.852 pCi/L Uncert: +/-2.09 TPU: +/-2.05 Sodium-22 U -0.157 pCi/L Uncert: +/-1.90 TPU: +/-1.86 Thallium-208 U 2.60 pCiIL Uncert: +/-2.39 TPU: +/-2.34 Thorium-230 U 6.83 pCi/L Uncert: +/-5.32 TPU: +/-5.21 Thorium-234 U 33.3 .pCi/L Uncert: +/-143 TPU: +/-140 Tin-] 13 U -1.62 pCi/L Uncert: +/-2.27 TPU: +/-2.23 Uranium-235 U 3.20 pCiIL Uncert: +/-14.2 TPU: +/-14.0 Uranium-238 U 33.3 pCi/L Uncert: +/-143 TPU: +/-140 Yttrium-88 U 1.84 pCi/L Uncert: +/-2.23 TPU: +/-2.19 Zinc-65 U 2.91 pCi/L Uncert: +/-4.39 Page 50 of 58
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road' Charleston SC 29407 - (843) 556-8171 - www.gel.com QC Summary Workorder: 151732 Page 13 of 20 Parmname NOM Sample Qual QC Units RPD% REC% Range Anist Date Time Rad Gamma Spec Batch 488129 TPU: +/-4.31 Zirconium-95 U -1.8 pCi/L Uncert: +/-3.88 TPU: +/-3.80 QC1 200996969 151732001 MS Actinium-228 U -0.373 U -148 pCi/L 12/28/05 10:41 Uncert: +/-6.17 +/-599
. TPU +/-6.05 +/-590 Americium-241 9760 U -5.11 10800 pCi/L III Uncert: +/-11.6 +/-2250 TPU +/-11.3 +/-4770 Antimony- 124 U -1.85 U 44.7 pCi/L Uncert: +/-3.98 +/-279 TPU +/-3.90 +/-274 Antimony- 125 U 2.44 U 110 pCi/L Uncert: +/-5.31 +/-297 TPU +/-5.20 +/-295 Barium-133 U 0.506 U -45.2 pCi/L Uncert: +/-2.60 +/-155 TPU +/-2.55 +/-153 Barium- 140. U 1 10.7 U -146 pCi/L Uncert: +/-20.1 +/-1330 TPU +/-19.7 +/-1300 Beryllium-7 u -0.628 U 373 pCi/L Uncert: +/-18.8 +/-1380 TPU +/-18.5 +/-1360 Bismuth-212 U 5.49 U 619 pCi/L Uncert: +/-13.2 +/-1030 TPU +/-12.9 +/-1040 Bismuth-214 U 4.62 U 327 pCi/L Uncert: +/-8.74 +/-251 TPU +/-8.56 +/-278 Cerium-139 U -0.491 1540 pCi/L Uncert: +/-1.86 +/-266 TPU +/-1.82 +/-656 Cerium- 141 U 2.85 U 25.1 pCi/L Uncert: +/-6.81 +/-218 TPU +/-6.67 +/-214 Cerium-144 U -6.92 U , 603 pCi/L Uncert: +/-12.5 +/-751 TPU +/-12.2 +/-773 Cesium- 134 U 0.624 U 29.0 pCi/L Uncert: +/-1.82 +/-162 TPU +/-1.78 +/-160 Cesium- 136 U 5.23 U 355 pCi/L Uncert: +/-6.86 .+/-647 TPU +/-6.72 +/-649 Cesium-137 '3740 U 0.308 3850 pCi/L 103 Page51 of 58
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com QC Summary Workorder: 151732 Page 14 of 20 0
Parmname NOM Samnle flual OC llnit* RPDf% ~WC A Rano~ Anid flat Tump Rad Gamma Spec Batch 488129 Uncert: +/-2.38 +/-519 TPU +/-2.33 +/-1590 Chromium-51 U -2.41 U 377 pCi/L Uncert: +/-25.0 +/-1500 TPU +/-24.5 +/-1480 Cobalt-56 U 0.213 U 64.1 pCi/L Uncert: +/-1.88 +/-165 TPU +/-1.84 +/-164 Cobalt-57 U 0.797 1460 pCi/L Uncert: +/-1.66 +/-255 TPU: +/-1.63 +/-624 Cobalt-58 U -1.79 U 118 pCi/L Uncert: +/-1.94 +/-166 TPU +/-1.90 +/-169 Cobalt-60 5550 U -0.102 5480 pCi/L 99 Uncert: +/-1.84 +/-729 TPU +/-1.80 +/-2260 Europium- 152 U 4.63 U -134 pCi/L Uncert: +/-6.19 +/-313 TPU +/-6.06 +/-312 Europium- 154 U -3.39 U -44.1 pCi/L Uncert: +/-5.16 +/-296 TPU +/-5.05 +/-291 Europium- 155 U 0.139 U 81.8 pCi/L Uncert: +/-6.87 +/-390 TPU +/-6.73 +/-384 Iridium-192 U -1.13 U 69.4 pCi/L Uncert: +/-2.03 +/-128 TPU +/-1.99 +/-128 Iron-59 U 1.72 U -21 pCi/L Uncert: +/-4.28 +/-415 TPU .+/-4.20 +/-407 Lead&210 U -19.8 U 5040 pCi/L Uncert: +/-387 +/-39000 TPU +/-379 +/-38300 Lead-212 U 1.35 U 63.6 pCi/L Uncert: +/-5.89 +/-196 TPU +/-5.77 +/-194 Lead-214 U 4.05 U 107 pCi/L Uncert: +/-6.54 +/-255 TPU +/-6.41 +/-253 Manganese-54 U -1.08 U -44 pCi/L Uncert: +/-1.57 +/-118 TPU +/-1.53 +/-117 Mercury-203 U -0.283 U 194 pCi/L Uncert: +/-2.55 +/-260 TPU +/-2.50 +/-266 Neodymium- 147 U 16.3 U -589 pCi/L Page 52 of 58
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com QC Summary Workorder: 151732 Page 15 of 20 Parmname NOM Sample Qual QC Units RPD% REC% Range AnIst Date Time Rad Gamma Spec Batch 488129 Uncert: +/-46.2 +/-3090 TPU +/-45.3 +/-3030 Neptunium-239 U 0.211 U -143 pCi/L Uncert: +/-12.7 +/-707 TPU +/-12.4 +/-695 Niobium-94 U 0.619 U -2.06 pCi/L Uncert: +/-1.67 +/-120 TPU +/-1.64 ,+/-117 Niobium-95 U 0.780 U 152 pCi/L Uncert: +/-2.43 +/-201 TPU +/-2.38 +/-206 Potassium-40 32.7 U 1350 pCi/L Uncert: +/-27.5 +/-1210 TPU +/-27.0 +/-1300 Promethium- 144 U -0.00511 U -5.0 pCi/L Uncert: +/-1.70 +/-109.
TPU +/-1.67 +/-107 Promethium- 146 U 2.65 U -60.5 pCiIL Uncert: +/-2.38 +/-174 TPU +/-2.33 +/-172 Radium-228 U -0.373 U -148 pCiIL Uncert: +/-6.17 +/-599 TPU +/-6.05 +/-590 Ruthenium- 106 U 11.5 U 517 pCiIL Uncert: +/-16.4 +/-1270 TPU +/-16.0 +/-1260 Silver- I Om. U -0.234 U -10 pCi/L Uncert: +/-1.61 +/-139 TPU +/-1.58 +/-136 Sodium-22 U -1.2 U -16.4 pCiJL Uncert: +/-1.86 +/-106 TPU +/-1.82 +/-104 Thallium-208 U 0.945 U 79.9 pCiIL Uncert: +/-2.91 +/-142 TPU +/-2.85 +/-143 Thorium-230 U 4.62 U 327 pCiIL Uncert: +/-8.73 +/-251 TPU +/-8.56 +/-278 Thoriurni-234 U 166 U 3030 pCiIL Uncert: +/-95.0 +/-7400 TPU +/-93.1 +/-7350 Tin-I 13 U -0.927 1700 pCi/L Uncert: +/-2.56 +/-324 TPU +/-2.51 +/-740 Uranium-235 U 8.78 U 49.0 pCiIL Uncert: +/-18.4 +/-639 TPU +/-18.1 +/-627 Uranium-238 U 166 U 3030 pCiIL Page 53 'of 58
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com QC Summary Workorder: 151732 Page 16 of 20 Parmname NOM Sample Qual QC Units RPD% REC% Range AnIst Date Time Rad Gamma Spec Batch 488129 Uncert: +/-95.0 +/-7400 TPU: +/-93.1 +/-7350 Yttrium-88 U -0.374
- 2470 pCi/L Uncert: +/-1.65 +/-537 TPU: +/-1.61 +/-1100 Zinc-65 U -0.723 U -19.9 pCi/L Uncert: +/-3.71 +/-299 TPU: +/-3.64 +/-294 Zirconium-95 U -0.236 U -39.5 ,pCi/L Uncert: +/-3.75 +/-297 TPU: +/-3.67 +/-291 Batch 490999 QC1201003356 151732001 DUP Nickel-59 SU 15.1 U .0.141 pCi/L 196 (0% - 100%) BXFI 12/30/05 16:51 Uncert: +/-10.4 +/-11.6 TPU: +/-10.2 +/-11.4 QC1201003358 LCS Nickel-59 380 358 pCi/L 94 (75%-125%) 12/29/05 17:59 Uncert: +/-45.5 TPU: +/-52.7 QC1201003355
- MB Nickel-59 U 7.92 pCi/L 12/30/05 14:49.
Uncert: +/-10.2.
TPU: +/-10.1 QC1201003357 151732001 MS Nickel-59 380 U 15.1 355 pCi/L 93 (75%-125%) 12/29/05 19:06 Uncert: +/-10.4 +/-50.4 TPU: +/-10.2 +/-56.7 Rad Gas Flow Batch 487482 QC1200995397 151732003 DUP Total Strontium U -0.279 U -0.434 pCi/L N/A (0% - 100%) 31XW I 12/14/05 17:28 Uncert: +/-0.381 +/-0.357 TPU: +/-0.381 +/-0.357 QC1200995399 LCS Total Strontium 51.8 46.6 pCi/L 90 (75%-125%) 12/14/05 17:33 Uncert: +/-3.22 TPU: +/-3.51 QC1200995396 MB Total Strontium U 0.212 pCi/L 12/14/05 17:28 Uncert: +/-0.428 TPU: +/-0.428 QC1200995398 151732003 MS Total Strontium 104 U -0.279 92.0 pCi/L 89 (75%-125%) 12/14/05 17:28 Uncert: +/-0.381 +/-6.57 TPU: +/-0.381 +/-7.12 Batch 489159 QC1200999366 151735002 DUP Page 54 of 58
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com QC Summary Workorder: 151732 Page 17 of 20 Parmname NOM Sample Qual QC Units RPD% REC% Range Anlst Date Time Batch 489159 Alpha U 0.831 U 1.01 pCi/L .19 (0%- 100%) CXo I 12/23/05 15:37 Uncert: +/-1.27 +/-1.36 TPU +/-1.27 +/-1.37 Beta U . -1.94 U 1.07 pCi/L N/A (0%- 100%)
Uncert: +/-2.06 +/-2.11 TPU +/-2.07 +/-2.11 QC1200999369 LCS Alpha 108" 109 pCiIl 101 (75%-125%) 12/23/05 15:48 Uncert: +/-10.7 TPU: +/-13.4 Beta 311 311 pCi/ll 100 (75%-125%)
Uncert: +/-14.8 TPU: +/-19.3 QC1200999365 MB Alpha U 0.421 pCiIL. 12/23/05 15:48 Uncert: +/-1.16
+/-1.17 TPU:
Beta U -1.54 pCiIL Uncert: +/-1.86 TPU: +/-1.86 QC1200999367 151735002 MS Alpha 108 U 0.831 89.6 pCi/L 83 (75%-125%) 12/23/05 15:48 Uncert: +/-1.27 +/-12.1 TPU: +/-1.27 +/-13.7 Beta 311 U -1.94 328 pCiIL 106 (75%-125%)
Uncert: +/-2.06 +/-15.6 TPU: +/-2.07 +/-18.6 QC1200999368 .151735002 MSD Alpha 108 U 0.831 96.5 pCi/L 7 89 (0%-20%)
Uncert: +/-1.27 +/-12.5 TPU: +/-1.27 +/-13.7
. -1.94 Beta 311 U 364 pCi/L 11 117 (0%-20%)
Uncert: +/-2.06 +/-16.8 TPU: +/-2.07 +/-22.9 Rad Liquid Scintillation Batch 487442 QC1200995296 151732004 DUP Promethium- 147 U . 3.20 U 4.90 pCi/L 0 (0% - 100%) AFI 12/22/05 04:23 Uncert: +/-4.65 +/-4.84 TPU: +/-4.65 +/-4.84 QC1200995298 LCS Promethium-147 138 -137 pCi/L 100 (75%-125%) 12/21/05 05:25 Uncert: +/-12.3 TPU: +/-13.5' QC1200995295 MB Promethium-147 U 4.32 pCi/L 12/22/05 02:51 Uncert: +/-4.52 TPU: +/-4.52 QC1200995297 151732004 MS Page 55 of 58
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com QC Summary Workorder: 151732 Page 18 of 20 Parmname NOM Sample Qual QC Units RPD% REC% Range Anist Date Time Rad Liquid Scintillation Batch 487442 Promethium- 147 278 U 3.20 229 pCi/L 82 (75%-125%)
Uncert: +/-4.65 +/-22.1 TPU: +/-4.65 +/-24.0 Batch 487444 QC1200995300 151732001 DUP Iron-55 U -28.2 U -1.51 pCi/L N/A (0%- 100%) BXFI -12/16/05 06:35 Uncert: +/-37.1 +/-28.2 TPU: +/-37.1 +/-28.2 QC1200995302 LCS lron-55 2000 2030 pCi/L 101 (75%-125%) 12/16/05 08:55 Uncert: +/-179 TPU: +/-251 QC1200995299 MB Iron-55 U -16.4 pCifL 12/16/05 04:29 Uncert: +/-36.0 TPU: +/-36.0 QC1200995301 151732001 M.S lron-55 2010 U -28.2 1940 pCi/L 97 (75%-125%) 12/16/05 08:38 Uncert: +/-37.1 +/-129 TPU: +/-37.1 +/-210 Batch 487445
. QC1200995304 151732001 DUP U 8.46 Nickel-63 U 1.76 pCi/L 0 (0% - 100%) BXFI 12/15/05 05:00 Uncert: t/-14.6 +/-13.9 TPU: +/-14.6 +/-13.9 QC1200995306 LCS Nickel-63 1570 1370 pCi/L 87 (75%-125%) 12/15/05 06:34 Uncert: +/-39.0 TPU: +/-51.0 QC1200995303 MB Nickel-63 U -3.38 pCi/L 12/15/05 04:13 Uncert: +/-13.4
-TPU: +/-13.4 QC1200995305 151732001 MS Nickel-63* 1570 U 1.76 1390 pCi/L 89 (75%-125%) 12/15/05 05:47 Uncert: +/-14.6 +/-38.2 TPU:. +/-14.6 +/-50.7 Batch 487449 QC1200995312 151132001 DUP Technetium-99 U -5.14 U 0.989 pCi/L N/A (0% - 100%) SLN1 12/19/05 23:54 Uncert: +/-13.4 +/-10.4 TPU: +/-13.4 +/-10.4 QC1200995314 LCS Technetium-99 1180 1270 pCi/L 107 (75%-125%) 12/20/05 01:13 Uncert: +/-50.6 TPU: +/-59.6 QC1200995311 MB Technetium-99 U 5.13 pCi/L 12/19/05 22:51 Page 56 of 58
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com QC Summary Workorder: 151732 Page 19 of 20 Parmname NOM Sample Qual QC Units RPD% REC% Range Anist Date Time Rad Liquid Scintillation Batch 487449 Uncert: +/-12.2 TPU: +/-12.2 QC1200995313 151732001 MS Technetium-99 1180 U -5.14 989 pCi/L 84 (75%-125%) 12/20/05 00:56 Uncert: +/-13.4 +/-42.5 TPU: +/-13.4 +/-49.2 Batch 487451 ý QC1200995316 151732001 DUP Tritium IU 113 U 129 pCi/L 0 (0% - 100%) MXP1 12/15/05 01:35 Uncert: +/-211 +/-215 TPU: +/-211 +/-215 QC1200995318 LCS Tritium 2990 2900 pCi/L 97 (75%-125%) 12/15/05 02:39' Uncert: +/-488 TPU: +/-490 QC1200995315 MB Tritium U 23.1 pCi/L 12/15/05 00:48 Uncert: +/-212 TPU: +/-212 QC1200995317 151732001 MS Tritium 3000 U 113 3200 pCi/L 107 (75%-125%) 12/15/05 02:22 Uncert: +/-211 +/-504 TPU: +/-211 +/-567 Batch 487453 QC1200995324 151732001 DUP Carbon-14 U 9.08 U 9.32 pCi/L 0 (0% - 100%) SLNI 12/14/05 22:44 Uncert: +/-15.7 +/-15.7 TPU: +/-15.7 +/-15.7 QC1200995326 LCS Carbon- 14 1080 1090 pCi/L 101 (75%-125%) 12/15/05 00:19 Uncert: +/-36.4 TPU: +/-40.2 QC1200995323 MB Carbon-14 U 8.73 pCi/L 12/14/05 21:56 Uncert: +/-15.7 TPU: +/-15.7 QC1200995325 151732001 MS Carbon-14 1080 U 9.08 1050 pCi/L 97 (75%-125%) 12/14/05 23:32 Uncert: +/-15.7 +/-35.8 TPU: +/-15.7 +/-39.4 Notes:
The Qualifiers in this report are defined as follows:
B Target analyte was detected in the sample as well as the associated blank.
BD Results below the MDC or low tracer recovery.
E Concentration of the target analyte exceeds the instrument calibration range.
Analytical holding time exceeded.
Page 57 of 58
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com QC Summary Workorder: 151732 Page 20 of 20 Parmname NOM Sample Qual QC Units RPD% REC% Range Anist Date Time H
J Indicates an estimated value.
U Target analyte was analyzed for but not detected above the MDL or LOD.
UI Uncertain identification for gamma spectroscopy.
X Lab-specific qualifier-please see case narrative, data summary package or contact your project manager for details.
d The 2:1 depletion requirement was not met for this sample h Sample preparation or preservation holding time exceeded.
N/A indicates that spike recovery limits do not apply when sample concentration exceeds spike conc. by a factor of 4 or more.
- Indicates analyte is a surrogate compound.
^ The Relative Percent Difference (RPD) obtained from the sample duplicate (DUP) is evaluated against the acceptence criteria when the sample is greater than five times (5X) the contract required detection limit (RL). In cases where either the sample or duplicate value is less than 5X the RL, a control limit of +/- the RL is used to evaluate the DUP result.
For PS, PSD, and SDILT results, the values listed are the measured amounts, not final concentrations.
Where the analytical method has been performed under NELAP certification, the analysis has met all ofthe requirements of the NELAC standard unless qualified on the QC Summary..
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