ML061730219

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Annual Groundwater Monitoring Report, Vermont Yankee Power Plant, Sms Site #99-2617 Vernon, Vermont
ML061730219
Person / Time
Site: Vermont Yankee Entergy icon.png
Issue date: 02/07/2006
From:
State of VT, Agency of Natural Resources
To: Dewald L
Entergy Nuclear Operations, Office of Nuclear Reactor Regulation
References
%dam200611, 04-201215.00, FOIA/PA-2010-0209
Download: ML061730219 (80)


Text

State of Vermont AGENCY OF NATURAL RESOURCES Department of Fish and Wildlife Department of Forests, Parks, and Recreation 103 South Main Street / West Building Department of Environmental Conservation Waterbury, Vermont 05671-0404 State Geologist 802-241-3877 RELAY SERVICES FOR THE HEARING IMPAIRED Fax 802-241-3296 1-800-253-0191 TDD>Voice gerold.noyes@state.vt.us 1-800-253-0195 Voice>TDD Received February 7, 2006 FEB 9 2006 ENTERGY NUCLEAR VERMONT YANKEE ATTN: LYNN DEWALD By GOVERNOR HUNT ROAD VERNON, VERMONT 05354 Lpr'7~

RE: Annual groundwater monitoring report, Vermont Yankee Power Plant, SMS Site # 99-2617 Vernon, Vermont

Dear Ms. DeWald:

The SMS has reviewed the January 23, 2006 groundwater monitoring and product recovery report for samples collected on October 17, 2005 and product removal from December 2004 to December 2005. The report was prepared by Environmental Compliance Services. Drinking water samples are collected quarterly by Vermont Yankee with the most recent sample collected on December 12, 2005.

One or more of the following petroleum compounds: naphthalene, 1,2,4- and 1,3,5-trimethylbenzene were detected at levels above the Vermont Groundwater Enforcement Standards (VGES) in monitor wells MW-I and -8. MW-6 contained trace petroleum contaminants below the VGES. Monitor well MW-2 had tetrachloroethene (PCE) contamination above the VGES. MW-5 and -7 contained PCE below the VGES.

Monitor well MW-9 contained free product on the sample date and was not sampled. To date approximately 149 liters of free product have been recovered from MW-1, -6, -8, and -9..

Free product monitoring and recovery should continue to be performed on a quarterly, monthly, or weekly basis by Vermont Yankee personnel as needed. All monitor wells should be sampled via EPA Method 8260 for volatile organic compounds (VOCs) in Fall 2006. If any monitor wells contain measurable free product, they should not be sampled, and they should be reported as containing free product on the sample date.

The SMS looks forward to reviewing the next annual report by January 15, 2007. If I can be of assistance, please contact me at (802) 241-3877 or gerold.noves(state.vt.us.

Sincerely, SAJft4 5 over Regional Offices - BarrelEssex Jcl./Rutland/Sprinafier!i/St ,Inhnshtirv

Vermont Yankee, SMS Site #99-2617 February 7, 2006 Page 2 of 2 Gerold Noyes, P.E.

Environmental Engineer Sites Management Section CC: David Balk, ECS (via electronic mail)

K:\Site.Files\ 999.2601 .to. 1999,2700\1 999.2617.Vermont.Yankee'2006\020706.dewald.let.doc

Phase (check one) Type (Check one)

I] Initial Site Investigation

[] Corrective Action Work Te Scope Feasibility Investigation Technical P Report El Corrective Action Plan PCF Re El Corrective Action Reimbursement Summary Report Request 0 Operations and General Corr Monitoring Report Correspondence 2005 Annual Monitoring Report Entergy Nuclear Vermont Yankee, LLC 320 Governor Hunt Road Vernon, Vermont SMS Site #99-2617 Prepared for:

MR. GEROLD NOYES SITES MANAGEMENT SECTION VT DEC WASTE MANAGEMENT DIVISION 103 SOUTH MAIN STREET WEST BUILDING WATERBURY, VERMONT 05671-0404 FILE No. 04-201215.00 DOCUMENT: DEc05REPoRT JANUARY 23,2006 PREPARED BY:

ENVIRONMENTAL COMPLIANCE SERVICES, INC.

30 HARms PLACE; BRATTLEBORO, VT 05301 802-257-1195 FAX: 802-257-1603 www.ecsconsult.com

Am k- 30 HARRIS PLACE BRATTLEBORO, VT 05301 802-257-1195 FAX: 802-257-1603 WWW. ECSCONSULT.COM January 23, 2006 Project: 04-201215.00 Document: Dec05report Mr. Gerold Noyes Sites Management Section VT DEC Waste Management Division 103 South Main Street/West Building Waterbury, VT 05671-0404 RE: 2005 Annual Monitoring Report, October 2004 - October 2005 Entergy Nuclear Vermont Yankee, LLC 320 Governor Hunt Road Vernon, Vermont SMS Site #99-2617

Dear Mr. Noyes:

Enclosed please find the above-referenced report for your review. This report includes groundwater sampling data from October 2005. Also provided is data compiled by Vermont Yankee, on drinking water analyses completed on samples from the COB potable water supply well #20559 and recovery data for removal of light non-aqueous phase liquid (LNAPL) from selected wells in 2005. If you have any questions or require further information, please contact me at the Brattleboro office of ECS at 802-257-1195.

Sincerely ENVIRONMENTAL COMPLIANCE SERVICES, INC.

David Balk, P.G., R.S.

Senior Project Manager Enclosure cc: Lynn DeWald, Environmental Specialist, Entergy Nuclear Vermorit Yankee, LLC HADDAM, CT TAMPA, FL AGAWAM, MA AUBURN, MA WAKEFIELD, MA Bow. NH MARION MY PDA^r-ri -tr- %rr ........ I -

TABLE OF CONTENTS 1.0 INTR OD UCTIO N ................................................................................................................................................ 1 2.0 GROUNDWATER AND DRINKING WATER MONITORING ................................................................. 2 2.1 LABORATORY ANALYSIS OF DRINKING WATER SAMPLES ......................................................................... 2 2.2 LABORATORY ANALYSIS OF GROUNDWATER SAMPLES .............................................................................. 3 2.2.1 V OC Analyses ......................................................................................................................................... 3 2.2.1.1 Petroleum Hydrocarbons................................................................................................................................ 3 2.2.1.2 ChlorinatedVOCs andKetones ...................................................................................................................... 3 3.0 RESULTS OF LNAPL REMOVAL ACTIVITIES.

4.0 CONCLUSION

S ........................................ . .

. . . . . . . . . . . . . . . . . . . . . . . . ... . ... . . . . ..... . .. ..... . . . 6 DOX E fl I.. YJRT'*J.-.... ................

O...................................................................................

.r...e' . ......................7 FIGURES:

Figure 1 Site Locus Map Figure 2 Groundwater Potentiometric Map Figure 3 Naphthalene Isoconcentration Map TABLES:

Table 1 Groundwater Potentiometric Data Table 2 Results and Standards of Petroleum Hydrocarbons in Groundwater Table 3 Results and Standards of Chlorinated VOCs and Ketones in Groundwater Table 4 Free Product Recovery Table for December 2004 through December 2005 APPENDICES:

Appendix A Groundwater Gauging & Sampling Log Appendix B COB Potable Water Supply Well #20559 Summary Table Appendix C Laboratory Data Sheets & Chain of Custody AppendixD Graphs

Annual Monitoring Report, Site #99-2617 Document: 04-201215.00\DecO5 report Vermont Yankee Nuclear Power Station January 23, 2006 Vernon, Vermont Page 1

1.0 INTRODUCTION

This report documents annual groundwater sampling results conducted at the No. 2 Fuel Oil release area located at Entergy Nuclear Vermont Yankee, LLC (Vermont Yankee) in Vernon, Vermont (the Site)(see Site Locus, Figure 1). It has been prepared by Environmental Compliance Services, Inc., (ECS) of Brattleboro, Vermont on behalf of Entergy Nuclear Northeast.

Vermont Yankee is a nuclear powered electrical generating station which has been in operation since 1972. In the spring of 1999 groundwater monitoring wells were installed in the vicinity of a former underground storage tank (UST) as part of an environmental assessment for the Site. Groundwater samples collected during the initial environmental assessment from the on-Site groundwater monitoring wells contained volatile organic compounds (VOCs) that exceeded Vermont Department of Environmental Conservation (VTDEC) Primary Groundwater Quality Standards (PGQS). An additional five (5) groundwater monitoring wells were installed at the Site during subsequent investigations. Light non-aqueous phase liquid (LNAPL) identified as #2 fuel oil was encountered in monitoring wells MW-1,

-8 and -9. The Site Investigation Report recommended free product recovery and natural attenuation with quarterly groundwater monitoring as a remedial alternative. Quarterly groundwater monitoring commenced in December 1999. The Sites Management Section (SMS) of the VTDEC issued Site #99-2617 in 1999. Beginning in 2002, monitoring was reduced to once annually.

Vermont Yankee began a free product collection program for monitoring wells MW-1 during July 1999, MW-6 during January 2004, MW-8 during December 1999, and MW-9 in November 2002. Due to heightened security, sampling in 2002 was performed by Vermont Yankee personnel.

This report summarizes the following:

" annual groundwater gauging and groundwater sample collection by ECS;

" fourth quarter drinking water sample data completed by Vermont Yankee personnel;

" LNAPL removal and recovery data compiled by Vermont Yankee personnel;

" annual report preparation by ECS, including conclusions and recommendations.

Annual Monitoring Report, Site #99-2617 Document: 04-201215.00\DecO5 report Vermont Yankee Nuclear Power Station January 23, 2006 Vernon, Vermont Page 2 2.0 GROUNDWATER AND DRINKING WATER MONITORING Annual groundwater gauging and sampling was performed by ECS personnel on October 17, 2005.

Depth to groundwater in each well was measured with a Solinst electronic oil and water interface probe (I-probe) level indicator from the top of the monitoring well PVC. The instrument is accurate to 0.01 foot.

Groundwater samples were collected from eight of the nine monitoring wells associated with the Site.

Well MW-9 was not sampled due to the presence of LNAPL on the sampling date. Groundwater samples were obtained using disposable plastic bailers following the purging of a minimum of three well volumes of groundwater (except for MW-3 which required a larger purge than could be accomplished in a reasonable amount of time by bailer sampling). Each collected sample was placed into two 40 milliliter (ml) glass VOA vials preserved with HCI. All samples including the trip blank were immediately stored on ice upon collection, and refrigerated until delivery was made to the Spectrum Analytical, Inc.

laboratory located in Agawam, Massachusetts. Samples were submitted for analysis of VOCs by EPA Method 8260. A copy of the groundwater gauging and sampling log is included in Appendix A.

All gauging data obtained to date from monitoring wells associated with the Site are presented in Table 1.

Depth to groundwater ranged from 17.63 feet to 18.27 feet. Groundwater elevations varied slightly since October 2004, with an average increase of 0.20 feet at the nine monitoring locations. The October 17, 2005 data was used to generate a groundwater potentiometric map presented as Figure 2.

Groundwater at the Site was determined to flow in a northerly direction during the October 2005 gauging event. This flow direction is consistent with past observations at the site. This flow direction may be influenced by building footprints, properties of geological features in the area, or other hydrological irregularities.

Contaminant concentrations at the site do not appear to be influenced by fluctuations in groundwater elevations observed at the site since 1999.

2.1 LABORATORY ANALYSIS OF DRINKING WATER SAMPLES Vermont Yankee personnel collected a drinking water sample from the COB potable water supply well (WSDT) # 20559) on February 9, May 10, July 28, and December 6, 2005. A summary table of the results of analyses on these samples is provided in Appendix B.

The December 6, 2005 drinking water sample collected from the COB system was analyzed for VOCs via EPA Method 524.2. The sample was collected at the first floor lunch room sink of the COB system. No parameters tested for in COB potable water supply well drinking water sample for the 12/6/05 were detected above Minimum Detection Limits (MIDLs). No contaminant concentrations detected in drinking water exceeded Vermont PGQS.

Annual Monitoring Report, Site #99-2617 Document: 04-201215.00\DecO5 report Vermont Yankee Nuclear Power Station January 23, 2006 Vernon, Vermont Page 3 2.2 LABORATORY ANALYSIS OF GROUNDWATER SAMPLES 2.2.1 VOC Analyses The groundwater samples obtained on October 17, 2005 were analyzed by EPA Method 8260.

Results are summarized in Table 2 and Table 3, which include VT PGQS and results of previous analyses for reference. The complete laboratory data sheets and chain of custody record are presented in Appendix C.

2.2.1.1 PetroleumHydrocarbons A summary of petroleum hydrocarbons detected in groundwater collected is presented as Table 2. A Naphthalene isoconcentration map constructed from the October 17, 2005 laboratory data is presented as Figure 3. Groundwater samples collected from monitoring wells MW-1, and MW-8 contained VOC concentrations that exceed VTDEC PGQS.

Although well MW-9 was not sampled due to the presence of LNAPL, it is assumed based upon historical data that PGQS were exceeded by VOC concentrations in groundwater at this monitoring point. The highest concentrations of dissolved petroleum VOCs were reported in the groundwater samples collected from monitoring well MW-8.

Concentrations of 1,2,4-Trimethylbenzene (124 micrograms per liter, lag/L), 1,3,5-Trimethylbenzene (53.6 pg/L) and Naphthalene (250 .igfL) were detected at MW-8.

Groundwater samples collected from MW-1 revealed concentrations of 1,2,4-Trimethylbenzene (69.2 jig/L), 1,3,5-Trimethylbenzene (46 jig/L), and Naphthalene (175

.tg/L) which exceed PGQS. Concentrations of petroleum hydrocarbons above PGQS were not reported in samples collected from monitoring wells MW-3, MW-4, MW-5 MW-6 or MW-7.

Contaminant concentrations in groundwater exhibited an increase in the sample from MW-1 compared to the data from October 2004, but data collected since 1999 suggest an overall decreasing trend at MW-i.

Contaminant concentrations in groundwater exhibited a decrease in the sample from MW-6 (to levels below PGQS) compared with the data from October 2004, and data collected since 1999 suggest an overall decreasing trend at MW-6.

Contaminant concentrations in groundwater exhibited a decrease in the sample from MW-8 compared to the last time the monitoring well was sampled in 2002, and there is insufficient historical data to suggest a trend. The presence of LNAPL in this monitoring well in 2003 and 2004; as well as its continued presence in MW-9 since 2003 suggests that contaminant levels will persist at these locations.

Graphs showing 1,2,4 & 1,3,5-Trimethylbenzenes and Napthalene concentrations, and groundwater elevations over time for monitoring wells MW-1, MW-6 and MW-8 are provided in Appendix D.

2.2.1.2 ChlorinatedVOCs and Ketones Historical laboratory data relating to chlorinated VOCs and Ketones is included as Table

3. Groundwater samples collected from monitoring wells MW-2, MW-5, and MW-7

Annual Monitoring Report, Site #99-2617 Document: 04-201215.00\DecO5 report Vermont Yankee Nuclear Power Station' January 23, 2006 Vernon, Vermont Page 4 contained concentrations of Tetrachloroethene (PCE), with the reported concentration of 13.7 jig/L at MW-2 exceeding VTDEC PGQS.

PCE concentration in groundwater exhibited an increase in the sample from MW-2 compared to the data from October 2004, but data collected since 1999 suggest an overall decreasing trend in PCE concentration at MW-2. A graph of PCE concentration and groundwater elevation over time at monitoring well MW-2 is included in Appendix D.

The only other chlorinated VOC reported in samples above MDLs was 1 jig/L of TCE reported in the MW-2 sample, which is below the VTDEC PGQS.

Annual Monitoring Report, Site #99-2617 Document: 04-201215.00\DecO5 report Vermont Yankee Nuclear Power Station January 23, 2006 Vernon, Vermont Page 5 3.0 RESULTS OF LNAPL REMOVAL ACTIVITIES Vermont Yankee personnel completed LNAPL gauging and removal activities throughout the monitoring period by gauging monitoring wells MW-1, -6, -8, and -9 with a GeoTech I-probe and removing any detected LNAPL with a disposable bailer. All product and groundwater collected is placed into a 55 gallon drum for disposal.

Vermont Yankee initiated weekly LNAPL recovery efforts in November 2002 due to the discovery of 3 feet of LNAPL in MW-9. During the October 2005 sampling event, 0.01 foot of product was noted in MW-9 and sheen of product was noted in MW-1, MW-6 and MW-8.

From December 2004 to December 2005, 0.1 milliliters (ml) of fuel oil was recovered from MW-1, a total of approximately 2.6 ml from MW-6, 0.8 ml from MW-8, and 15.2 ml from MW-9. To date, total recovery amounts of fuel oil are 2.23 liters from MW-1, 17.9 ml from MW-6, 26.08 liters from MW-8, and 120.68 liters from MW-9. A free product recovery table for December 2004 through December 2005 is included as Table 4.

Annual Monitoring Report, Site #99-2617 Document: 04-201215.00\DecO5 report Vermont Yankee Nuclear Power Station January 23, 2006 Vernon, Vermont Page 6

4.0 CONCLUSION

S Based on the information provided by Vermont Yankee and review of the laboratory reports of analyses completed on sampled collected by ECS on October 19, 2004, the following conclusions are made:

Depth to groundwater ranged from 17.63 feet to 18.27 feet. Groundwater elevations increased an average of 0.20 feet since 2004 based on the data collected from nine monitoring wells.

Groundwater flow is interpreted to flow in an easterly direction towards the Connecticut River, which is consistent with past observations at the site.

" LNAPL was present on the water table at monitoring well MW-9 in a measurable quantity during the sampling event, and during LNAPL recovery events at monitoring wells MW-I, MW-6, MW-8 and MW-9.

  • Groundwater samples collected from monitoring wells MW-i and MW-8 contained Petroleum Hydrocarbon concentrations that exceed VTDEC PGQS.

" The concentrations of PCE detected at MW-2 exceeded PGQS.

  • Dissolved concentrations of petroleum hydrocarbons exhibited an increase at MW-i; and a decrease at MW-6 from October 2004 to October 2005, and a decrease at MW-8 from October 2002 to October 2005.
  • From December 2004 to December 2005, 0.1 milliliters (ml) of fuel oil was recovered from MW-1, a total of approximately 2.6 ml from MW-6, 0.8 ml from MW-8, and 15.2 ml from MW-9. To date, total recovery amounts of fuel oil are 2.23 liters from MW-1, 17.9 nil from MW-6, 26.08 liters from MW-8, and 120.68 liters from MW-9.

Annual Monitoring Report, Site #99-2617 Document: 04-201215.00\DecO5 report Vermont Yankee Nuclear Power Station January 23, 2006 Vernon, Vermont Page 7 5.0 RECOMMENDATIONS

" ECS recommends continuing the annual groundwater sampling program for selected wells, with the analysis of VOCs via EPA Method 8260. The next annual sampling event is scheduled for October 2006. Results shall be presented in an annual report including field data, laboratory data sheets, groundwater and isoconcentration maps, conclusions and recommendations.

  • ECS recommends the continuation of LNAPL removal on a bi-weekly schedule at monitoring wells MW-1, -8, and -9.

FIGURE 1 SITE LOCUS MAP.

Environmental Compliance Services, Inc.

30 Harris Place, Brattleboro, VT 05301 Phone (802)-257-1195 Fax (802).257-1603 SITE LOCUS,

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1' I 1/2 0 1 Mile 1 inch = 1500 feet Contour Interval: 6 Meters North Base Map: U.S. GeologicalSurvey; QuadrangleLocation: Brattleboro,VT UTM Coordinates: 18 0703358 East / 47 39063 North £ Map Edited: 1984 Map Revised: GeneratedBy: ELP

FIGURE 2 GROUNDWATER POTENTIOMETRIC MAP

U Legend Building Footprint Monitoring Well MW-4 Well I.D.

Road Box Elevation r199"44 PVC Elevation 1181.81 Groundwater Elevation 181.70 - Groundwater Contour (Dashed where Inferred)

[E*> Groundwater now Direction North General Notes:

Site plan prepared from a base map created by SVE Associates dated Oct. 27, 2000.

MW-9 Mw-1 All locations, dimensions, and property lines

_ WWdepicted on this plan are approximate. This 199.5 S -,1199.691 plan should not be used for construction or

= 11182 81.26ý 7.

  • 0 18_9_ land conveyance purposes.

M, P' o) *Horizontal, and vertical locations of wells, and S00 selected site features determined through

,-'J measurements made by SVE personnel, and have not been verified by ECS. Inc.

/Groundwater elevations are based on measure-ments taken on 10/17/05 by ECS. Inc.

SMW-8 personnnel.

199.49 e 6> Groundwater contours, and flow directions 181.75 assume homogenous, Isotropic aquifer conditions, and horizontal flow.

Fluctuations In the level of the water table may occur due to factors not accounted for at the time of measurement.

TURBINE BUILDING Water table contours ore Interpolated between BAY DOOR data points, and Inferred in other areas.

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FIGURE 3 NAPHTHALENE ISOCONCENTRATION MAP

I Legend Building Footprint Monitoring Well MW-4 Well I.D.

SI J<1Nophtholene ug/L 0 Naphtholene Isoconcentration North I£ 0 General Notes:

Site plan prepared from a base mop created by SVE Associates dated Oct. 27. 2000.

All locations. dimensions. and property lines depicted on this plan are approximate. This plan should not be used for construction or MW-9 MW-1 ( land conveyance purposes.

im [Horizontal, and vertical locations of wells, and selected site features determined through Lai measurements mode by SVE personnel, and have not been verified by ECS, Inc.

Groundwater elevations are based on measure-ments taken on 10/17/05 by ECS. Inc.

20

  • personnnel.

Groundwater contours, and flow directions assume homogenous, Isotropic aquifer conditions, and horizontal flow.

Fluctuations In the level of the water table may occur due to factors not accounted for B at the time of measurement.

TURBINE BUILDING Water table contours ore interpolated between BAY DOOR data points, and inferred In other areas.

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TABLE 1 GROUNDWATER POTENTIOMETRIC DATA

Vermont Yankee Nuclear Table I Power Station Vernon, Vermont Groundwater Potentlometric Data SMS Site #99-2617 Data reported In feet Depth to 1 Groundwater Reference Elevation WELL ID Groundwater Elevation Samplino Date JPVC after 2000)

MW-1 200.16 12116/1999 18.75 181.41 4120/2000 NA NA 7(6/2000 18.41 181.75 9/20/2000 18.74 181.42 12/4-5/2000 19.17 180.99 10/1112001 19.30 180.39 199,69 11114/2002 19.29 180.40 10/2412003 18.22* 181.47 10/19/2004 18.14 181.55 10117/2005 17.78 181.91 MW-2 200.21 12/16/1999 18.87 181.34 4/20/2000 NA NA 7/6/2000 18.35 181.86 9/20/2000 18.80 181.41 1214-5/2000 19.17 181.04 10/16/2001 19.30 180.48 199.78 11/14/2002 19.36 180.42 10/2412003 18.19 181.59 10119/2004 18.18 181.60 10117/2005 18.00 181.78 MW-3 200 12116/1999 18.73 181.27 4/20/2000 NA NA 7/6/2000 18.39 181.61 9/20/2000 18.64 181.36 1214-5/2000 19.17 180.83 10116/2001 11.74 187.94 199.68 11114/2002 18.85 180.83 10/24/2003 18.19 181.49 10/19/2004 18.11 181.57 10/17/2005 17.96 181.72 MW-4 _ - 199.67 12116/1999 18.37 181.30 4120/2000 NA NA 7/6/2000 17.96 181.71 9/20/2000 18.08 181.59 12/4-5/2000 18.75 180.92 10/16/2001 18.75 180.69 199.44 11/1412002 18.83 180.61 10/24/2003 17.79 181.65 10/19/2004 17.83 181.61 10117/2005 17.63 181.81 MW-5 200.17 12116/1999 18.84 181.33 4/20/2000 NA NA 71612000 18.44 181.73 9/20/2000 18.80 181.37 12/4-5/2000 19.00 181.17 10116/2001 19.27 180.72 199.99 11/14/2002 19.31 180.68 10/24/2003 18.25 181.74 10/1912004 18.24 181.75 10/17/2005 18.07 181.92 F.Wal3~ojedsNO4.201000 lo 20150"4.201215 VYNPCNo 2 OAJTsb1Ws'W EIev (T~i~eItMASTER

Vermont Yankee Nuclear Table I Power Station Vernon. Vermont Groundwater Potentlometrlc Data SMS Site #99-2817 Data reported In feet Depth to Groundwater Reference WELL ID Groundwater Elevation Elevation Sampling Date (PVC after 2000)

MW-6 200.19 1211811999 18.82 181.37 4/20/2000 NA NA 7/612000 18.55 181.64 9/20/2000 18.98 181.21 12/4-512000 19.10 181.09 10116/2001 19.27 180.54 199.81 11/14/2002 19.32 180.49 10/24/2003 18.30" 181.51 10/1912004 18.26 181.55 10/1712005 18.00 181.81 MW-7 200.23 12/116/1999 18.84 181.39 4/20/2000 NA NA 716/2000 18.35 181.88 9/20/2000 18.78 181.45 12/4-5/2000 19.17 181.06 1011612001 19.30 180.55 199.85 11114/2002 19.33 180.52 10/24/2003 18.29 181.58 10/19/2004 18.27 181.58 10/17/2005 18.13 181.72 MW-8 200.29 12/116/1999 18.87 181.42 4/20/2000 NA NA 7/6/20001 18.55 181.74 9/20/2000 18.88 181.41 12/4-5/2000 19.17 181.12 10/16/2001 19.12 180.37 199.49 11/14/2002 19.07 180.42 10/24/2003 18.08" 181.41 10/19/2004 18.01" 181.48 10/17/2005 17.74 181.75 MW-9 200.32 12/16/1999 18.91 181.41 4/20/2000 NA NA 7/8/2000 18.88 181.44 9/20/2000 19.39 180.93 12/4-5/2000 19.33 180.99 10/16/2001 19.38 180.15 199.53 11/14/2002 19.45 180.08 10/24/2003 18.49* 181.04 10/1912004 18.37" 181.16 10117/2005 18.27" 181.26 NIOTES:

NG = Not Gauged NA = Not Available

= Free Product elevations corrected based on product thickness F.Vjai~prvjedM420100 to 20150OM4-20l2l5 VYNPONo2 MWP~Co.~etedi AegvoesW Elev(TaNeI)MASTER

TABLE 2 RESULTS AND STANDARDS OF PETROLEUM HYDROCARBONS IN GROUNDWATER

Table 3 veI .=tty..k R-a*bo-Io Atory.. ofCaaa,.ds,,

N?4lcir P"W St1" by EPA Metbad 2:1641 Vere... Verusa limits and Staidarda reported I adevskrgram per fit" (.z/L)

SMS 199-2617 Pelrofem Ilydrocarb'os WELL9 1.2.4. i1.2.5 Ti.e*l Tdeimlii Iaepep ema-.bw$ aec-buty a-bwyl 14.10.ompl Ov)1Iiep)

S.W-I Do- Ber Tohu*e b= Xte6. leb . bm e Nap*thalene beroe bImae bcree.' b-e.. al...

% b-~e 1,000 700 10.000 5 4 20 NA NA MW-l 12rZ9/19991 I 1 0 1 39 1 9 1 90 94 1 300 I NT NT NT Ni NT NT NT N"T

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<1 71 <1 NT

'2 <1 NT NT NT NT ND ND ND ND ND ND ND ND ND I2V5/2000I ND ND I 21J I <10 W/26420011 <1 '1

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10/16/2001 <1 <1 11/14/2002 <1 02J <1 <1 10/21/2003 <I <1 <2 '2 10119/2004 <1 <1 10127/2001 41 MW.4

<1 22 4 91 31 200 I 12/29/1999 ND 90 60 4/2/20o0o ND 7/6/2000 410* 7/9 17 NT NT 9/202000 <' 4 74 220 NT NT 46 10 2100 I 3) 125//2000( <10" 65 120 46 <2 43 5.4 34 5 93 8I <3 6 140 4) 111 I1/1I20021 <5 I <I 1 <

2"4 54 <2 22S II <5 10 96 102 216 10117/20051 <I I I ý2

ELL 1)

EI13 Y*

y ff-1 TUnu0m I 34t2-3.3-r~o bourne bensnd ,,,me D-"r benum

=9~

W.-

Is~

b-n xleen S Ii.Of. 7ft Ilee $ 4 20 NA ND NT NT I Tr Kr NI NT NT 7/6120001 <1 cl NT NT I C1 l <t I <I 7f 0 IJB ND ND ND ND NO ND -

<1 <1 C1 I t <1c <1c C1 0.5)

<1 c 1 <2 c1

<l <1 <1 I <1 tMW.3 D <t 120 1 70 430 180 320 NT NT NTr NT NT NTr 9/20201 <25? - 1 380 I40 1 650 173 7J 26 230 1-"1 <2S 1-29 1 27 250 2 330 14J A25 NS 10117r200! <5 1 <5 1 242 1 <10 I ii 53.6 4r20r2001 ND I 'CO 1 38 1 42 1 1270 70 520 210 s6o1 Kr NT I NT NT NKr 4/262tIl <S I <3 39 1 33 I 200 49 I 27e08 9) 16J I 81 <20 ISJ 1 13J 20/29/20041 NS I NS I NS I NS I NS NS INS S I NS NS NS I NS NS I NS NS I NS I NS I NS NOTES:

ND - Not Detected above Indicated deccdon limit TCE - Tr.hlooetiene NT - Not Tested (for specific manis) PCE - Tcbtacorooethe NS - Not Sampled DC! - D3tchlooetlane

'Note thatminimum detection limit IspFestr dtmi*PQS

    • Satvtawere uAhnd by SRecwnmAnalytical InApwamt Massachusetts m lts Indicaee ednce of PQS IM eJ resu I- Indiscatsanestimated value This aMg bued under the fonowins chcumstances: 1) wb*e atimatinga concentration for tentatively identifloeopou&dswherc a Useapose hbummed oel2) when ite Owameets heIdentlfcation ctitesLabut the remultI lessOmadie apeciled detection lmh but Feater than Foreowle. lIthe inl ofidetection

,em. 0 mass Ipectral dataIndicatethepr*m oe ofs compounid a,/1. and Ow cenarntron of3 S/L. Iscalculated. t i reported as MJ identiied compound as 8- TrI fin it usedwbenahewalyte found Inthe assocdatd blank at well as Indt ample. It hdicates po ,tc/leobableblankcontamlnation. This fOa i also uswedR a tentaively well asfe a posi*i*ly Identidfed TCL compound

TABLE 3 RESULTS AND STANDARDS OF CHLORINATED VOCS AND KETONES IN GROUNDWATER

Table 3 Vermont Yankee Results of Laboratory Analysis of Groundwater Nuclear Power Station by EPA Method 8260B Vernon, Vermont Results and Standards reported In micrograms per liter (ug/L)

SMS #99-2617 Chlorinated VOCs and Ketones WELL ID 11,1,1- Carbon methylene Sampling Date 1.1-DCE TCE TCE Disulfide PCE chloride Acetone PGQS 70 5 200 NA 5 NA 700 MW-I_

12/29/1999 NT NT NT NT ND NT ND 4/20/2000 NT NT NT NT ND NT 160 7/6/2000 NT NT NT NT <50' NT <500 9/2012000 NT NT NT NT <100 NT <100 12/4-12/5/00 21 <2 ND ND 41 NT <100 4/26/01** <2 <2 <2 <10 <2 <2 <200 I0/16/2001 IJ <5 <5 <5 I1 <5 <50 11/14/2002 0.8J <5 31 <5 31 0.71 <50 10/2812003 <2 <2 <2 <10 <2 <10 <20 10/19/2004 <5 <5 <5 <25 <5 <50 <100 10/17/2005 <5 <5 <5 <25 <5 <50 <100 12/29/1999 NT NT NT NT 22 NT ND 4120/2000 NT NT NT NiT 21 NT 7 7/6/2000 NT NT NT NT <1 NT <10 9/20/2000 NT NT NT NT 16. NT <10 12/4-12/5/00 ND ND 0.21 ND Is NT <10 4/26/01"* <1 <1 <1 <I 24 <1 <100 10/16/2001 <I <1 0.1J <1 16 <1 <10 11/14/2002 0.11 0.11 0.4J <1 14 <1I 2J 10/28/2003 <1 1.3 <1 <5 14.2 <5 <10 10/19/2004 <1 1.2 <1 <5 12.5 <10 <20 10/17/2005 <1 I <1 <5 13.7 <10 <20 MW-3 12/29/1999 NT NT NT NT ND NT ND 4/20/2000 NT NT NT NT ND NT 7 7/6/2000 NT NT NT NT <1 NT <10 9/20/2000 NT NT NT NT 17 NT <10 12/4-12/5/00 ND ND ND 0.4 ND NT 6B 4/26/01"* <1 <1 <1 <5 <I <I <100 10116/2001 <1 <1 <1 <1 <1 <I <10 11/14/2002 <1 <1 <1 0.31 <1 <1 <t0 10/28/2003 <1 <1 <1 <5 <1 <5 <10 10/19/2004 <1 <1 <1 <5 <1 <10 <20 10/17/2005 <1 <1 <1 <5 <1 <10 <20 F:~data~projects\04-201000 to 201500%04-201215 VYNPO No.2 DAIPDF Completed ReportsGW VOC (Tabfte2 3)Cbdnated I1oof [Pagesl Pgs

Table 3 Vermont Yankee Results of Laboratory Analysis of Grou~tdwater Nuclear Power Station by EPA Method 8260B Vernon, Vermont Results and Standards reported In micrograms per liter (ug/L)

SMS #99-2617 Chlorinated VOCs and Ketones WELL ID 1,,- Carbon methylene Sampling Date ,I-DCE TCE TCE Disulfide PCE chloride Acetone PGQS 70 5 200 NA 5 NA 700 MW-4 12/29/1999 NT NT NT NT ND NT ND 4/20/2000 NT NT NT NT ND NT ND 7/6/2000 NT NT NT NT NS NT NS 9/20/2000 NT NT NT NT 0.1 NT 4 1214-12/5/00 ND ND ND ND 0.2J NT ND 4/26/01"* <I <1 <1 <5 <1 <1 <100 10/16/2001 <1 <1 <1 <I 0.21 <1 <10 11/14/2002 <1 <1 <1 <I 0.3O <1 <10 10/28/2003 <1 <1 <1 <5 <1 <5 <10 10/19/2004 <1 <1 <1 <5 <1 <10 <20 10/17/2005 <1 <1 <1 <5 <I <10 <20 NMW_-5 12/29/1999 NT NT NT NT ND NT ND 4/20/2000 NT NT NT NT ND NT ND 7/6/2000 NT NT NT NT <1 NT <10 9/20/2000 NT NT NT NT I NT <10 12/4-12/5/00 ND ND ND ND ND NT 5.

4/26/01*" <1 <1 <1 <5 <i <1 <100 10/16/2001 <1 <1 <1 <1 0.2. <1 <10 11/14/2002 <1 <1 <1 <1 0.51 <1 <10 10/28/2003 <1 <1 <1 <5 <1 <5 <10 10/19/2004 <1 <1 <1 <5 1.2 <10 <20 10/17/2005 <1 <1 <1 <5 2.1 <10 <20 MW-6 12/29/1999 NT NT NT NT ND NT ND 4/20/2000 NT NT NT NT ND NT 27 7/6/2000 NT NT NT NT <10* NT <100 9/20/2000 NT NT NT NT <10" NT <100 12/4-12/5/00 ND ND ND ND <10' NT <100 4/26/01"* <2 <2 <2 <10 <2 <2 <200 10/16/2001 <5 <5 <5 <5 0.81 <5 <50 11/14/2002 <5 <5 <5 <5 Ii Ii <50 10/28/2003 <2 <2 <1 <10 <2 <10 <20 10/19/2004 <5 <5 <5 <25 <5 <50 <100 10/17/2005 <5 <5 <5 <25 <5 <50 <100 NlW-7 12/29/1999 NT NT NT NT ND NT ND 4/20/2000 NT NT NT NT 6 NT ND 7/6/2000 NT NT NT NT 5 NT 4 9/20/2000 NT NT NT NT 5 NT <10 12/4-12/5/00 ND ND 0.21 ND 7 NT 5J 4/26/01"* <1 <1 4.3 <5 5.6 <I <100 10/16/2001 <1 <1 .I J <1 5 <I <10 11/14/2002 <1 <I <1 <1 14 <1 0.2I 10/28/2003 <1 <I <1 <1 2.0 <5 <10 10/19/2004 <1 <1 <1 <5 3.8 <10 <20 10/17/2005 <1 <1 <1 <5 3.7 <10 <20 Repofls\GW VOC (Tables 2 3)Chlorhnated F.WatalprooectsNO4-201000 to 201500\04-201215 VYNPC No2 OJ'PDF Comwpleted 22cof IPagesl Pgs

Table 3 Vermont Yankee Results of Laboratory Analysis of Groundwater Nuclear Power Station by EPA Method 8260B Vernon, Vermont Results and Standards reported In micrograms per liter (ugIL)

SMS #99-2617 Chlorinated VOCs and Ketones WELL ID S1,1,1- Carbon methylene Sampling Date] .I-DCE TCE TCE Disulfide PCE chloride Acetone PGQS 70 5 200 NA 5 NA 700 NlW-8 12/29/1999 NT NT NT NT ND NT ND 4/20/2000 NT NT NT NT NS NT NS 7/6/2000 NT NT NT NT <50* NT 52 9/20/2000 NT NT NT NT <25* NT <250 12/4-12/5/00 ND ND ND ND <25* NT <25 4/26/01 ** NS NS NS NS NS NS NS 10/16/2001 3.01 <10 <10 <10 <10* 17 <100 11114/2002 <25 <25 <25 <25 <25* <25 <250 10/28/2003 NS NS NS NS NS NS NS 10/19/2004 NS NS NS NS NS NS NS 10/17/2005 <5 <5 <5 <25 <25* <50 <100 MW-9 12/2911999 NT NT NT NT ND NT ND 4/20/2000 NT NT NT NT ND NT 21 7/6/2000 NT NT NT NT <25* NT <250 9/20/2000 NT NT NT NT <I NT <250 12/4-12/5/00 61 ND ND ND <10" NT <100 4/26/01 ** <5 <5 <5 <25 <5 5 <500 10/16/2001 3.0J <20 <20 <20 <20* <20 <200 11/14/2002 <25 <25 <25 <25 <25* <25 <250 10/28/2003 NS NS NS NS NS NS NS 10/19/2004 NS NS NS NS NS NS NS 10/17/2005 NS NS NS NS NS *NS NS NOTES:

ND = Not Detected above indicated detection limit TCE = Trichloroethene NT Not Tested (for specific analyte) PCE = Tetrachloroethene NS - Not Sampled DCE = Dichloroethane

  • Note that minimum detection limit is greater than PGQS "Samples were analyzed by Spectrum Analytical in Agawam, Massachusetts Shaded results indicate exceedence of PGQS J = Indicates an estimated value. This flag is used under the following circumstances: 1) when estimating a concentration for tentatively identified compouds where a 1: response is assumed; or 2) when the mass spectral data indicate the presence of a compound that meets the identification criteria but the result is less than the specified detection limit but greater than zero.

B = This flag is used when the analyte is found in the asssociated blank as well as in the sample. It indicates possible/probable blank contamination. This flag is also used for a tentaively identified compound as well as for a positively identified TCL compound I'Adata'lrtoects%04-201000 to 201500X04-201215 VYNPC NW2 0rPOF Comprleted Reports\GW VOC (Tables 2 3)CNoxinated 3EPgs 3 of [Pagesl

TABLE 4 FREE PRODUCT RECOVERY TABLE FOR DECEMBER 2004 THROUGH DECEMBER 2005

Entergy Nuclear Vermont Yankee - SMS #99-2617 Free Product Recovery Summary Table - 2005 MW-1 Depth to Depth to Volume Recovered Total Product Date Groundwater Product (mL) Thickness (inches) Notes 12/18/2004 18.33 18.33 0.00 0.00 1114/2005 18.43 18.43 0.00 0.00 2/12/2005 18.43 18.43 0.00 0.00 3/26/2005 18.8 18.7 0.00 0.10 4/9/2005 18.6 18.6 0.00 0.00 5/31/2005 17.79 17.79 0.00 0.00 6/24/2005 17.98 17.98 0.00 0.00 7/20/2005 17.65 17.65 0.00 0.00 8/24/2005 18.13 18.11 0.10 "0_.01 9/26/2005 18.42 18.4 0.00 0.02 11/1/2005 18.12 18.12 0.00 0.00 11/15/2005 17.2 17.2 0.00 0.00 12115/2005 17.2 17.2 0.00 0.00_

Total: 0.1

Entergy Nuclear Vermont Yankee - SMS #99-2617 Free ProductRecovery Summary Table - 2005 LqW-R Depth to Depth to Volume Recovered Total Product Date Groundwater Product (mL) Thickness (inches) Notes 12/18/2004 18.53 18.50 0.00 0.03 1114/2005 18.54 18.53 0.00 0.01i 2/12/2005 18.58 18.53 0.20 0.05 3/26/2005 18.85 18.72 2.45 0.101 _ _ _

4/9/2005 18.23 18.21 0.00 0.02 5/31/2005 18.93 18.9 0.10 0.03 6/24/2005 18.1 18.1 0.00 0.00 7/20/2005 17.73 17.73 0.00 0.00 8/24/2005 18.2 18.19 0.00 0.01 9/26/2005 18.55 18.55 0.00 0.00 11/1/2005 18.3 18.3 0.00 0.00 11/15/2005 17.3 17.3 0.00 0.00 12116/2005 17.3 17.3 0.00 0.00 Total: 2.6 1

EntergyNuclear Vermont Yankee - SMS #99-2617 Free Product Recovery Summary Table - 2005 RRIMA1 Depth to Depth to Volume Recovered Total Product Date Groundwater Product (mL) Thickness (Inches) Notes 12/18/2004 18.24 18.22 0.00 0.02 1/14/2005 18.23 18.23 0.00 0.00 2/12/2005 18.34 18.29 0.10 0.05 3/26/2005 18.75 18.6 0.80 0.15 4/9/2005 18.02 18.02 0.00 0.00 5/31/2005 17.7 17.7 0.00 0.00 6/24/2005 17.88 17.88 0.00 0.00 7/20/2005 17.5 17.5 0.00 0.00 8/24/2005 18 17.97 0.00 0.03 9/26/2005 18.28 18.28 0.00 0.00 11/1/2005 17.8 17.8 0.00 0.00 1111512005 17.1 17.1 0.00 0.00 12/16/2005 17.32 17.1 0.00 0.01 Total: 0.81

Entergy Nuclear Vermont Yankee - SMS #99-2617 Free ProductRecovery Summary Table - 2005 MW-9 Depth to Depth to Volume Recovered Total Product Date Groundwater Product (mL) Thickness (inches) Notes 12/18/2004 18.71 18.52 0.00 0.19 1/14/2005 18.8 18.55 0.40 0.25 2/12/2005 18.82 18.59 0.40 0.23 3/26/2005 19.31 18.92 0.20 0.39 4/9/2005 18.55 18.35 1.10 0.20 5/31/2005 17.99 17.89 3.35 3.35 6/2412005 18.26 17.36 1.85 0.90 7/20/2005 17.85 17.8 0.50 0.05 8/24/2005 18.36 18.24 3.10 0.12 9/26/2005 18.65 18.5 1.10 0.15 11/1/2005 18.32 18.3 0.85 0.02 11/15/2005 17.57 17.49 1.25 0.08 12/16/2005 17.31 17.23 1.13 0.08 Total: I _ _ I 15.21

APPENDIX A GROUNDWATER GAUGING & SAMPLING LOG

Environmental Compliance Services, Inc. Sheet 1 of 1 30 Harris Place, Brattleboro, Vermont 05301 (802) 257-1195 FAX (802) 257-1603 GROUNDWATER SAMPLING LOG Client: Entergy Nuclear Vermont Yankee Job Number 04-201215 Location: Governor Hunt Road, Vernon Date: October 17, 2005 Personnel: R. Kemp Weather Conditions: sunny, breezy, 50-60" Pomof Total Depth to Depth to Water Standing Volume Sp.

Well ID Time D Rofemee Depth Product Water Height Volume Purged Odors pH Cond. Temp Sampled (in.) pPVcInR (feet) (feet) (feet) (feet) (gallons) (YIN) -ccv=. (0C) Comments MW-1 2:14 2 PVC 25.5 17.78 17.78 7.72 1.26 3.5 Y 6.54 765 18.4 black, silty purge, odor & sheen (<0.01' product). Slow recharge MW-2 1:58 2 PVC 28.0 na 18.00 10.00 1.63 5.0 N 6.52 719 17.2 silty purge MW-3 2:01 4 PVC 103.0 na 17.96 85.04 55.48 20.0 N 8.66 150 16.7 black, silty purge MW-4 2:24 2 PVC 27.5 na 17.63 9.87 1.61 5.0 N 6.78 1110 16.9 silty purge MW-5 1:52 2 PVC 25.0 na 18.07 6.93 1.13 3.5 N 6A5 1300 17.7 silty purge MW-6 2:09 2 PVC 23.5 18.00 18.00 5.50 0.90 3.0 Y 6.31 669.0 18.0 silty purge, odor & sheen (<0.01' product)

MW-7 14:05 2 PVC 23.5 na 18.13 5.37 0.88 5.0 N 6.20 1316 17.4 black, silty purge, odor. Slow recharge MW-8 14:20 2 PVC 27.5 na 17.74 9.76 1.59 5.0 Y 6.32 1194.0 19.1 silty purge, odor and sheen MW-9 NS 2 PVC 26.0 18.26 18.27 7.73 1.26 4.0 Y NG NG NG 0.01' product - NOT SAMPLED Field Instrumentation I.D. Number Calibration Water Level Indicator Solinst Hanna Instruments pH, temp., sp. cond.

Disposable Bailers NOTES: Standing Volume (gallons) = pr2(H)(7.48/144)

+Lynn Dewald of Entergy escorted & assisted with groundwater monitoring event r = inside radius of well (inches)

"MW-4 roadbox contained water with sheen H = standing height of water (feet)

" MW-1 roadbox damaged, needs to be replaced

+insufficient time to purge the required 3-well volume (167 gallonsl) from MW-3 NS = not sampled

+Alconox not on VYs approved chemical list - wiped off water level indicator with paper towel na = not applicable

+Duplicate sample (DUP) collected from MW-1 @ 2:15 NG = not gauged eeta~offce~fwmT~ssampJ0ng\GW Log VGauoaS

APPENDIX B COB POTABLE WATER SUPPLY WELL #20559

SUMMARY

TABLE

2005 Potable Water Sample Results - COB Well #20559 Sample Period 1st Quarter 2nd Quarter 3rd Quarter 4th Quarter Units Limit Method Sample Date 2/9/2005 5110/2005 7/28/2005 12/6/2005 Parameter Total Coliform <1 <1 <1 <1 MPN/100ml 0 SM 9223 E. Coil <1 <1 <1 <1 MPN/100ml 0 SM 9223 Metals Nitrogen, Nitrate <0.02 NT NT NT mg/L 10 EPA 300.0 mg/L 1 EPA 300.0 Nitrogen, Nitrite NT NT NT NT Fluoride NT NT NT NT mg/IL 4 EPA 340.2 Turbidity NT NT NT NT N.T.U. 0.5 to 1.0 EPA 180.1 Cyanide NT <10 NT NT ug/L 200 EPA 335.4 Antimony NT NT NT NT mg/L 0.006 SM 3113B Arsenic NT NT NT NT mng/L 0.05 SM 3113B Barium NT NT NT NT mg/I 2 EPA 200.7 Beryllium NT NT NT NT mg/L 0.004 EPA 200.7 Cadmium NT NT NT NT mg/L 0.005 EPA 200.7 Chromium NT NT NT NT mg/L 0.1 EPA 200.7 Mercury NT NT NT NT mg/L 0.002 EPA 245.1 Nickel NT NT NT NT mg/L 0.1 EPA 200.7 Selenium NT NT NT NT mg/L 0.05 SM 3113B Thallium NT NT NT NT mg/L 0.002 SM 3113B Lead NT NT NT NT mg/L 0.015 Copper NT NT NT NT mn/l 1.3 VOCs Benzene <0.5 <0.5 <0.5 <0.5 ug/L 5 EPA 524.2 Bromobenzene <0.5 <0.5 <0.5 <0.5 ug/L NA EPA 524.2 Bromochloromethane <0.5 <0.5 <0.5 <0.5 ug/L NA EPA 524.2 Bromomethane <0.5 <0.5 <0.5 <0.5 ugI. NA EPA 524.2 n-Butylbenzene <0.5 <0.5 <0.5 <0.5 ug/L NA EPA 524.2 sec-Butylbenzene <0.5 <0.5 <0.5 <0.5 ug/L NA EPA 524.2 NT = Not tested NA = Not available

= Bromodichloromethane, Bromoform, Chloroform, and Dibromochloromethane

= Limit is for Radium 226 and Radium 228 combined.

U = Compound was analyzed for but not detected.

J = Indicateds an estimated value.

B = This flag is used when the analyte is found in the associated blank as well as in the sample.

2005 Potable Water Sample Results - COB Well #20559 Sample Period 1stQuarter 2nd Quarter 3rd Quarter 4th Quarter Units Limit Method Sample Date 2/9/2005 5/10/2005 7/28/2005 1216/2005 Parameter Tert-Butylbenzene <0.5 <0.5 <0.5 <0.5 ug/L NA EPA 524.2 Carbon Tetrachloride <0.5 <0.5 <0.5 <0.5 ug/L 5 EPA 524.2 Chlorobenzene <0.5 <0.5 <0.5 <0.5 ug/L 100 EPA 524.2 Chloroethane <0.5 <0.5 <0.5 <0.5 ug/L NA EPA 524.2 Chloromethane <0.5 <0.5 <0.5 <0.5 ug/L NA EPA 524.2 4-Chlorotoluene <0.5 <0.5 <1.0 <0.5 ugIL NA EPA 524.2 2-Chlorotoluene <0.5 <0.5 <1.0 <0.5 u g/L NA EPA 524.2 Dibromomethane <1 1.0 <1.0 <1.0 ug/L NA EPA 524.2 1,2-Dichlorobenzene <0.5 <0.5 <0.5 <0.5 ug/L 600 EPA 524.2 1,3-Dichlorobenzene <0.5 <0.5 <0.5 <0.5 ug/L NA EPA 524.2 1,4-Dichlorobenzene <0.5 <0.5 <0.5 <0.5 ug/ NA EPA 524.2 Dichlorodifluoromethane <0.5 <0.5 <0.5 <0.5 ug/L NA EPA 524.2 1.1-Dichlomethane 0.6 0.6 0.5 <0.5 ug/L NA EPA 524.2 1,2-Dichloroethane <0.5 <0.5 <0.5 <0.5 ug/L 5 EPA 524.2 1,1-Dichloroethene <0.5 <0.5 <0.5 <0.5 ug/L 7 EPA 524.2 cis-1,2-Dichloroethene <0.5 <0.5 <0.5 <0.5 ug/L 70 EPA 524.2 trans-i.2-Dichloroethene <0.5 <0.5 <0.5 <0.5 ug/L 100 EPA 524.2 Dichloromethane <1.0 <1.0 <2.0 <1.0 ug/L 5 EPA 524.2 1,2-Dichloropropane <0.5 <0.5 <0.5 <0.5 ug/L 5 EPA 524.2 1,3-Dichloropropane <0.5 <0.5 <0.5 <0.5 ug/L NA EPA 524.2 2,2-Dichloropropane <0.5 <0.5 <0.5 <0.5 ug/L NA EPA 524.2 1,1-Dichloropropene <0.5 <0.5 <0.5 <0.5 ug/L NA EPA 524.2 cis-1,3-Dichloropropene <0.5 <0.5 <0.5 <0.5 ug/L NA EPA 524.2 trans-I,3-Dichloropropene <0.5 <0.5 <0.5 <0.5 ug/L NA EPA 524.2 Ethylbenzene <0.5 <0.5 <0.5 <0.5 ug/L 700 EPA 524.2 Hexachlorobutadiene <0.5 <0.5 <0.5 <0.5 ugiL NA EPA 524.2 NT = Not tested NA = Not available

  • = Bromodichloromethane, Bromoform, Chloroform, and Dibromochloromethane

= Limit is for Radium 226 and Radium 228 combined.

U = Compound was analyzed for but not detected.

J = Indicateds an estimated value.

B = This flag is used when the analyte Is found in the associated blank as well as in the sample.

2005 Potable Water Sample Results - COB Well #20559 Parameter 1stQuarter 2nd Quarter 3rd Quarter 4th Quarter Units Limit Method Sample Date 2/9/2005 5/10/2005 7/28/2005 12/6/2005 Parameter Isoprpoylbenzene <0.5 <0.5 <0.5 <0.5 ug/L NA EPA 524.2 4-1sopropyltoluene <0.5 <0.5 <0.5 <0.5 ug/L NA EPA 524.2 MTBE <1.0 <1.0 <1.0 <1.0 ug/L NA EPA 524.2 Napthalene <1.0 <1.0 <1.0 <1.0 ug/L NA EPA 524.2 n-Propylbenzene <0.5 <0.5 <0.5 <0.5 ug/L NA EPA 524.2 Styrene <0.5 <0.5 <0.5 <0.5 ug/L 100 EPA 524.2 1,1,1,2-Tetrachloroethane <0.5 <0.5 <0.5 <0.5 ug/L NA EPA 524.2 1,1,2,2-Tetrachloroethane <1.0 <1.0 <1.0 <1.0 ug/L NA EPA 524.2 Tetrachloroethene <0.5 <0.5 <0.5 <0.5 ug/L 5 EPA 524.2 Toluene <0.5 <0.5 <0.5 <0.5 ug/L 1000 EPA 524.2 1,2,3-Trichlombenzene <0.5 <0.5 <0.5 <0.5 ug/L NA EPA 524.2 1,2,4-Trichlorobenzene <0.5 <0.5 <0.5 <0.5 ug/L 70 EPA 524.2 1,1,1-Trichloroethane <0.5 <0.5 <0.5 <0.5 ug/L 200 EPA 524.2 1,1,2-Trichloroethane <0.5 <0.5 <0.5 <0.5 ug/L 5 EPA 524.2 Trichloroethene <0.5 <0.5 <0.5 <0.5 ug/L 5 EPA 524.2 Trichlorofluoromethane <1.0 <1.0 <1.0 <1.0 ug/L NA EPA 524.2 1,2,3-Trichloropropane <0.5 <0.5 <0.5 <0.5 ug/L NA EPA 524.2 1,2,4-Trimethylbenzene <0.5 <0.5 <0.5 <0.5 ug/L NA EPA 524.2 1,3,5-Trimethylbenzene <0.5 <0.5 <0.5 <0.5 ug/L NA EPA 524.2 Vinyl Chloride <0.5 <0.5 <0.5 <0.5 ug/L 2 EPA 524.2 Xylenes, Total <1.0 <1.0 <1.0 <1.0 ug/L 10000 EPA 524.2 Bromodichlormethane <0.5 <0.5 <0.5 <0.5 ug/L NA EPA 524.2 Bromoform <0.5 <0.5 <0.5 <0.5 ug/L NA EPA 524.2 Chloroform <0.5 <0.5 <0.5 <0.5 ug/L NA EPA 524.2 Dibromochloromethane <0.5 <0.5 <0.5 <0.5 ug/L NA EPA 524.2 Total Trihalomethanes* <0.5 <0.5 <0.5 ug/L 0.1 EPA 524.2 NT = Not tested NA = Not available

  • = Bromodichloromethane, Bromoform, Chloroform, and Dibromochloromethane

= Limit is for Radium 226 and Radium 228 combined.

U = Compound was analyzed for but not detected.

J = Indicateds an estimated value.

B = This flag is used when the analyte is found In the associated blank as well as in the sample.

2005 Potable Water Sample Results - COB Well #20559 Parameter lstQuarter 2nd Quarter 3rd Quarter 4th Quarter Units Limit Method Sample Date 2/9/2005 5/10/2005 07/280/5 12/6/2005 Parameter Alachlor NT NT NT NT ug/L 2 EPA 525.2 Alddin NT NT NT NT ug/L NA EPA 525.2 Atrazine NT NT NT NT ugIL 3 EPA 525.2 Benzo(a)pyrene NT NT NT. NT ug/L 0.2 EPA 525.2 Butachlor NT NT NT NT ug/L NA EPA 525.2 Dieldrin NT NT NT NT ug/L NA EPA 525.2 Di(2-ethylhexyl) adipate NT NT NT NT ug/L 400 EPA 525.2 Di(2-ethylhexyl) phthalate NT NT NT NT ug/L 0.6 EPA 525.2 Endrin NT NT NT NT ug/L 2 EPA 525.2 Heptachlor NT NT NT NT ug/L 0.4 EPA 525.2 Heptachlor epoxide NT NT NT NT ug/L 0.2 EPA 525.2 Hexachlorobenzene NT NT NT NT ug/L 1 EPA 525.2 Hexachlorocyclopentadiene NT NT NT NT ug/L 50 EPA 525.2 Lindane (gamma-BHC) NT NT NT NT ug/L 0.2 EPA 525.2 Methoxychlor NT NT NT NT ug/L 40 EPA 525.2 Metolachlor (Dual) NT NT NT NT ug/L NA EPA 525.2 Metribuzin (Sencor) NT NT NT NT ug/L NA EPA 525.2 Propachlor NT NT NT NT ugIL NA EPA 525.2 Simazine NT NT NT NT ug/L 4 EPA 525.2 2,4-D NT NT NT NT ug/L 70 EPA 515.2 2,4-DB NT NT NT NT ug/L NA EPA 515.2 Dicamba NT NT NT NT ug/L NA EPA 515.2 Dinoseb NT NT NT NT ug/L 7 EPA 515.2 Pentachlorophenol NT NT NT NT ug/L 1 EPA 515.2 Picloram NT NT NT NT ug/L 500 EPA 515.2 2.4.5-TP (Silvex) NT NT NT NT ug/L 50 EPA 515.2 NT = Not tested NA = Not available

= Bromodichloromethane, Bromoform, Chloroform, and Dibromochloromethane

= Limit is for Radium 226 and Radium 228 combined.

U = Compound was analyzed for but not detected.

J = Indicateds an estimated value.

B = This flag is used when the analyte is found in the associated blank as well as in the sample.

2005 Potable Water Sample Results - COB Well #20559 Parameter 1st Quarter 2nd Quarter 3rd Quarter 4th Quarter Units Limit Method Sample Date 2/9/2005 5/10/2005 7/28/2005 12/6/2005 Parameter 2,4,5-T NT NT NT NT ug/L NA EPA 515.2 Chlordane NT NT NT NT ug/L 2 EPA 505 Toxaphene NT NT NT NT ug/L 3 EPA 505 Aroclor 1016 NT NT NT NT ug/L 0.5 EPA 505 Arocior 1221 NT NT NT NT ug/L 0.5 EPA 505 Aroclor 1232 NT NT NT NT ug/L 0.5 EPA 505 Aroclor 1242 NT NT NT NT ug/L 0.5 EPA 505 Aroclor 1248 NT NT NT NT ug/L 0.5 EPA 505 Aroclor 1254 NT NT NT NT ug/L 0.5 EPA 505 Aroclor 1260 NT NT NT NT ug/L 0.5 EPA 505 Aldicarb Sulfoxide NT NT NT NT ug/L NA EPA 531.1 Aldicarb Sulfone NT NT NT NT ug/L NA EPA 531.1 Oxamyl (Vydate) NT NT NT NT ug/L 200 EPA 531.1 Methomyl NT NT NT NT ug/L NA EPA 531.1 3-Hydroxycarbofuran NT NT NT NT ug/L NA EPA 531.1 Aldicarb NT NT NT NT ug/L NA EPA 531.1 Carbofuran NT NT NT NT ug/L 40 EPA 531.1 Carbaryl NT NT NT NT ug/L NA EPA 531.1 Ethylene Dibromide NT NT NT NT ug/L 0.05 EPA 504.1 1.2-Dibromo-3-chloropropan NT NT NT NT ug/L 0.2 EPA 504.1 NT = Not tested NA = Not available

= Bromodichloromethane, Bromoform, Chloroform, and Dibromochloromethane

= Limit is for Radium 226 and Radium 228 combined.

U = Compound was analyzed for but not detected.

J = Indicateds an estimated value.

B = This flag is used when the analyte is found in the associated blank as well as in the sample.

2005 Potable Water Sample Results - COB Well #20559 Parameter 1st Quarter 2nd Quarter 3rd Quarter 4th Quarter Units Limit Method Sample Date 2/9/2005 5/10/2005 7/28/2005 12/6/2005 Parameter Gross Alpha NT NT NT NT pCi/L 15 Radon NT NT NT NT pCl/L 10000 Radium 226 and 228 NT NT NT NT pCiL **5 Uranium 234 NT NT NT NT pCiIL NA Uranium 238 NT NT NT NT pCVL NA NT = Not tested NA = Not available

= Bromodichloromethane, Bromoform, Chloroform, and Dibromochloromethane

= Limit is for Radium 226 and Radium 228 combined.

U= Compound was analyzed for but not detected.

J = Indicateds an estimated value.

B = This flag Is used when the analyte is found Inthe associated blank as well as in the sample.

APPENDIX C LABORATORY DATA SHEETS & CHAIN OF CUSTODY

Report Date: F 2inal Report 27-Oct-05 11:52 0l Re-Issued Report 0l Revised Report SPECTRUIMANALYTICAL, INC.

Featuring- . ..RECEIVED NOV .04 2005 LHANMbALTECorRLOGY LaboratoryReport, Environmental Compliance Services 30 Harris Place Project:.Entergy Nuclear Vermont Yankee - Vernon, VT Brattleboro, VT .'05301 Projectf#: 04-2012.15 Attn: Randall Kemp Laboratory ID Client Sample ID Matrix Date Sampled DAte Receive1d

.SA35951-01 MW-I ". Ground Warter 17-Oct05 14:14 18-Oct-05 13: 12 SA35951-02 MW-2 Ground Water 17-Oct-05 13:58 18-Oct-05 13: 12 SA35951-03 *MW-3 Ground Water 17-Oct-05 14:01 18:Oct-05 13: 12 SA35951-04 MW-4 Ground Water 17-Oct-05 14:24 18-Oct-05 13: 12 SA35951-05 MW-5 Ground Water 1.7-Oct-05 13:52 .18-Oct205 13: 12 SA35951-06 MW-6 Ground Water. 17-Oct-05 14:09 18-Oct-05.13: 12 SA35951-07 MW-7. Ground Water 17-Oct-05 14:05 18-Oct-05 13: 12 SA35951-08 MW-8 Ground Water. 17-0ct-05 14:20 .18-Oct-05 13: :12 SA35951-09 DUP Ground Water "17-Oct-05 14:15 . 18-Oct-05 13: 12 SA35951-10 TRIP. Deionized Water 17-.0c-05"08:08 18-Oct-05 13: :12 I attest that the information contained within the'report has been reviewed for accuracy and checked against thequality control requiremnents for each method. All applicable NELAC reqluirements have been mnet. '

Please note.thai this report contains 31 pages of analytical data plus Chain of Custody document(s)..'

This report may not be reproduced, except in full, without written approval from Spectrum Analytical, Inc.

Massachusetts Certification # M-MAl.38IMAI 110~ rid.b Connecticut PH-0777o Florida # E87600/E87936 Maine#MA138 New HBmpshire # 2538/2972 New York# 11393/11840 Rhode Island # 98 " ' Han . T.yeh, Ph.D.

USDA # S-51435 sid.n ratory Director Vermont # VT-11393 -

Spectrum Analytical,Inc. Is a.NELA C accreditedlaboratoryorganizationand meets NELAC testing standards. Use of the NELAC logo however does not insure that Spectrum is currently i'ccreditedfor the specific method indicated. Please refer to our "Quality" webpage at w'ww.spectrion-analytical.comfor afull.listing of our current .certaficirtions.

ENVIRONMENvTAL ANALYSES

  • 11 Alh gren Drive. Agawam, Massachusetts 01001, Operational Building &Sampile Receiving 830 Silver St'reit Agawarm, Massachusetts 01001, Administrative Offices, Volatile &Air Departments Page I of 31 1'800-789-91'15, 413-789-9018 Fax 413-789-4076

-Sample Identification Client Project A Matrix Collection Date/Time Received MW-I 04-201215 Ground Water 17-Oct-05 14:14 18-Oct-05 SA35951-01

-CASNo. Analyte(s) Result *RDL/Units Dilution MethodRef. PreparedAnalyzed Batch Analyst Flag Volatile Organic Compounds Volatile Organic Compounds by SW846 8260B Prepared by method SW846 5030 Water MS 67-64.1 Acetone BRL 100 pg/l 5 SW846 8260B 24-Oct-05 24-Oct-05 5101451 KS 107-13-1 Acrylonitrile BRL 5.0 pg/I 71-43-2 Benzenc BRL 5.0 pg/i 5 P a 10-8.6-1 Bromobenzene BRL 5.0 pg/i 74.97-5 Bromochloromethane BRL 5.0 pg/I 5 N a a 75-274 Bromodichloromethane BRL 5.0 pg/i 5 a a a 75-25-2 Bromoform BRL 5.0 pg/i Sq it a 74-83-9 Bromomethane BRL 10.0 pg/I 5 it a o 78-93-3 2-Butanone (MEK) BRL 50.0 pg/I 5 a ao o 104-514 n-Butylbenzene 5.9 5.0 pg/I 135-98-8 sec-Butylbenzene 6.5 5.0 pg/I 55 a a

a a

a 91-06-6 tert-Butylbenzene BRL 5.0 pg/I 5

5aaa S a a 75-15-0 Carbon disulfide BRL 25.0 pg/I Carbon tetrachloride BRL 5 5a U a a

56-23-5 5.0 pg/i 108-90-7 Chlorobenzene BRL 5.0 pg/I 5 aa 55aaa a a #a 75-00-3 Chloroethane BRL 10.0 pg/I 67-66-3 Chloroform BRL 5.0 pg/I 5aaa 5 a a a Chloromethane BRL 10.0 pg/I 5 5aaa a a 74-17-3 9549-8 2-Chlorotoluene BRL 5.0 pg/I 55a a a a

a 106-434 4-Chlorotoluene BRL 5.0 pg/i 5aaa 96-12-8 1,2-Dibromo-3-chloropropane BRL 10.0 pg/I 5 aa 5 a a a 124-48-1 Dibromochloromethane BRL 5.0 pg/I 5aaa 106-934 1,2-Dibromoethane (EDB) BRL 5.0 pg/I 74-95-3 Dibromomethane BRL 5.0 pg/I 95-S0-1 1,2-Dichlorobenzene BRL 5.0 pg/I 541-73-1 1,3-Dichlorobenzene BRL 5.0 Pg/I 11

  • 10646-7 1,4-Dichlorobenzene BRL 5.0 pg/I 75-71-8 Dichlorodifluoromethane BRL 10.0 pg/I (Freonl2) N 75-34-3 1,1-Dichloroethane BRL 5.0 pg/I m 107-06-2 1,2-Dichloroethane BRL 5.0 pg/I 75-35-4 I,I-Dichloroethene BRL 5.0 pg/I m m 156-59-2 cis-1,2-Dichloroethene BRL 5.0 Pg/I 156-60-5 trans-I ,2-Dichloroethene BRL 5.0 pg/I 79-97-5 1,2-Dichloropropane BRL 5.0 pg/i 142-28-9 1,3-Dichloropropane BRL 5.0 pg/I 594-20-7 2,2-Dichloropropane BRL 5.0 pg/l 563-58-6 1,1-Dichloropropene BRL 5.0 pg/I W

10061-01-S cis-1,3-Dichloropropene BRL 5.0 pg/I 10061-02-6 trans-1,3-Dichloropropene BRL 5.0 pg/I 100-41-4 Ethylbenzene 11.8 5.0 pg/I 17-68-3 Hexachlorobutadiene BRL 5.0 pg/i 591-7S-6 2-Hexanone (MBK) BRL 50.0 pg/l 99-82-8 Isopropylbenzene 7.4 5.0 pgA 99-87-6 4-Isopropyltoluene 7.4 5.0 pg/l 1634-04-4 Methyl tert-butyl ether BRL 5.0 pg/i This laboratoryreport Is not valid without an authorizedsignatureon the coverpage.

  • .Reportable Detection Limit BRL - Below Reporting Limit Page 2 of 31

Sample Identification Client Proiect # Collection Date/Time Received Matrix MW-2 04-201215 Ground Water 17-Oct-05 13:58 18-Oct-05 SA35951-02

-.CASNo. Analyte(s) .Result *RDL/Units Dilution MethodRef. PreparedAnalyzed Batch Analyst Flag Volatile Organic Compounds Volatile Organic Compounds by SW846 8260B Prepared by method SW846 5030 Water MS Isw846 8260B 24-Oct-OS 24-Oct-05 5101451 KS 67-64-1 Acetone BRL 20.0 pg/l p

107-13-1 Acrylonitrile BRL 1.0 pg/I 71-43.2 Benzene BRL 1.0 Pg/I op 108-86-1 Bromobenzene BRL 1.0 pg,1 I

74-97-S Bromochloromethane BRL 1.0 pg/

p 75-274 Bromodichloromethane BRL 1.0 Pg/I 75-25-2 Bromoform BRL 1.0 pg/l 74-83-9 Bromomethane BRL 2.0 pg/I 78.93-3 2-Butanone (MEK) BRL 10.0 pg/Il 104-51-8 n-Butylbenzene BRL 1.0 pg/I 135-98-8 sec-Butylbenzene BRL 1.0 pg/ I p 98-06-6 tert-Butylbenzene BRL 1.0 pg/I BRL 1 75-1S-0 Carbon disulfide 5.0 pg/l p

S6-23-5 Carbon tetrachloride BRL 1.0 pg/I I it 108-90-7 Chlorobenzene BRL 1.0 pg/

75-00-3 Chloroethane BRL 2.0 pg/I p

67-66-3 Chloroform BRL 1.0 pg/I p 74-87-3 Chloromethane BRL 2.0 ptg/I 9549-8 2-Chlorotoluene BRL 1.0 pig/I 106-434 4-Chlorotoluene BRL 1.0 pg/I 96-12-8 1.2-Dibromo-3-chloropropane BRL 2.0 pg/I 124-4S-I Dibromochloromethane BRL 1.0 pg/I 106-934 1,2-Dibromoethane (EDB) BRL 1.0 PgI p

74-95.3 Dibromomethane BRL 1.0 pg/I 95-50-1 1,2-Dichlorobenzene BRL 1.0 pg/I 541-73.1 1,3-Dichlorobenzcne BRL 1.0 pg/I 106-46-7 1,4-Dichlorobenzene BRL 1.0 Ttv/

75-71-8 Dichlorodifluoromethane BRL 2.0 pg/l (Freonl2) 75-34-3 1,l-Dichloroethane BRL 1.0 pg/I 107-06-2 1,2-Dichloroethane BRL 1.0 pg/l 75-354 1,1-Dichloroethene BRL 1.0 pg/

156-59-2 cis- 1,2-Dichloroethene BRIL 1.0 Pg/I 156-60-5 trans- 1,2-Dichloroethene BRL 1.0 pg/I 71-.87- 1.2-Dichloropropane BRL 1.o Pg/l 142-28-9 1,3-Dichloropropane BRL 1.0 pg/I 594-20-7 2,2-Dichloropropane BRL 563-58-6 1,l-Dichloroproplne BRL 1.0 pg/l 10061-01-3 cis-1,3-Dichloropropene BRL 1.0 Pg/I 10061-02-6 trans- l,3-Dichloropropene BRL 1.0 pg/l 100414 Ethylbenzene BRL 1.0 PgI 87-68-3 Hexachlorobutadiene BRL 591-78-6 2-Hexanone (MBK) BRL 10.0 pg/I 98-82-8 Isopropylbenzene BRL 1.0 pg/I 99-87-6 4-Isopropyltoluene BRL 1.0 pg/i 1634-044 Methyl tert-butyl ether BRL 1.0 pg/

This laboratoryreportIs not valid without an authorizedsignatureon the coverpage.

Rýyortable Detection Limit BRL - Below Reporting Limit Page 4 of 31

Sample Identification Collection Date/Time Received Client Project # Matrix MW-2 04-201215 Ground Water 17-Oct-05 13:58 18-Oct-05 SA35951-02 CASNo. Analyte(s) Result *RDLJUnits Dilution MethodRef. PreparedAnalyzed Batch Analyst Flag Volatile Organic Compounds Volatile Organic Compounds by SW846 8260B Prepared by method SW846 5030 Water MS 108.10-1 4-Methyl-2-pentanone (MIBK) BRL 10.0 pg/I 1 SW846 8260B 24-Oct.05 24-Oct-05 5101451 KS 75-09-2 Methylene chloride BRL 10.0 Pg/I 1 ... . .

91.20-3 Naphthalene 1.1 1.0 Pg/I 1 ... . .

103-65-1 n-Propylbenzene BRL 1.0 ig/I IN... . .

100-42.5 Styrene BRL 1.0 Pg/i 1 ... . .

630-20-6 1.1,1,2-Tetrachloroethane BRL 1.0 Pg/I I ... . .

79-34-5 1,1,2,2-Tetrachloroethane BRL 1.0 pg/I 1 ... . .

127-184 Tetrachloroethene 13.7 1.0 Pg/I 1 N.. N .

108.-8-3 Toluene BRL 1.0 Pg/I I ... . .

87-61-6 1,2,3-Trichlorobenzene BRL 1.0 pg/l  ! ... . .

120-82.1 1,2,4-Trichlorobenzene BRL 1.0 Pg/l N N.. N .

71.55-6 1,1,1-Trichloroethane BRL 1.0 Pg/I 1 ... . .

79.00-S 1,1,2-Trichloroethane BRL 1.0 Pg/I 1 ... . .

79-01.-6 Trichloroethene 1.0 1.0 Pg/I 1 .... .

75.694 Trichlorofluoromethane (Freon BRL 1.0 Pg/l 1 N. . N .

11) 96.184 1,2,3-Trichloropropane BRL 1.0 Pg/I 1 ... . .

95-63.6 1,2,4-Trimethylbenzene BRL 1.0 Pg/I 1 N.. N .

108-67-8 1,3,5-Trimethylbenzene BRL 1.0 Pg/l 1 N N. . .75-014 Vinyl chloride BRL 1.0 pg/I 1 ... . .

1330.20-7 m,p-Xylene BRL 2.0 pg/I 1 N.. N .

95-47.6 o-Xylene BRL 1.0 Pg/l 1 ... . .

Surrogate recoveries:

460-00-4 4-Bromofluorobenzene 105 70-130 %

2037-26-S Toluene-d8 96.8 70-130 % N. . . .

17060-07-0 1,2-Dichloroethane-d4 106 70-130 % N N N "" "

1868-S3-7 Dibromofluoromethane 101 70-1"30 % .. .N.

This laboratoryreportis not valid without an authorizedsignatureon the coverpage.

  • Reportable Detection Limit BRL - Below Reporting Limit Page 5 of 31

Sample Identification Client Project # Matrix Collection Date/Time Received MW-3 04-201215 Ground Water 17-Oct-05 14:01 18-Oct-05 SA35951-03 CASNo. Analyte(s) Result *RDL/Unlts Dilution MethodRef. Prepared Analyzed Batch Analyst Flag Volatile Organic Compounds Volatile Organic Compounds by SW846 8260B Prepared by method SW846 5030 Water MS 1 sw846 8260B 24-Oct -05 25-Oct-0S 5101451 KS 67-64.1 Acetone BRL 20.0 pg/I 107-13-1 Acrylonitrile BRL 1.0 Pg/I N Nt N 71-43-2 Benzene BRL 1.0 Pg/I 1N N 108-86-I Bromobenzenc BRL 1.0 pg/I 74.97-5 Bromochloromethane BRL 1.0 pg/I 75.27-4 Bromodichloromethane BRL 1.0 pg/I I N 75-25-2 Bromoform BRL 1.0 pg/I 74-83-9 Bromomethane BRL 2.0 pg/Il 78.93.3 2-Butanone (MEK) BRL 10.0 pg/I 104-51-s n-Butylbenzene BRL 1.0 jpg/i N N N

135-98.8 sec-Butylbenzene BRL 1.0 pg/I 98-06-6 tert-Butylbenzene BRL 1.0 pg/I 1N N*

75.15-0 Carbon disulfide BRL 5.0 pg/i I Nt 56-23-S Carbon tetrachloride BRL 1.0 pg/I I N 108-90-7 Chlorobenzene BRL 1.0 pg/i 75-00.3 Chloroethane BRL 2.0 pg/I 67.66-3 Chloroform BRL 1.0 Pg/I 4.0 I N 74.87-3 Chloromethane 2.0 pg/I N N N 95-49-8 2-Chlorotoluene BRL 1.0 pg/I 106-43-4 4-Chlorotoluene BRL 1.0 pg/I 96-12-8 1,2-Dibromo-3-chloropropane BRL 2.0 pg/I I 124-48-1 Dibromochloromethane BRL 1.0 pg/I 106-93-4 1,2-Dibromoethane (EDB) BRL 1.0 pg/I 74-95-3 Dibromomethane BRL 1.0 pg/I 95-50-1 1,2-Dichlorobenzene BRL 1.0 pg/I 541-73-1 1,3-Dichlorobenzene BRL 1.0 pg/i 106-46-7 1,4-Dichlorobenzene BRL 1.0 pg/I 75.71-8 Dichlorodifluoromethane BRL 2.0 pg/I (Freonl2) 75-34-3 I,I-Dichloroethane BRL 1.0 pg/I I I

107-06-2 1,2-Dichloroethane BRa 1.0 Pgi 1

75-35-4 1,1-Dichloroethene BRL 1.0 pg/I 1.0 pgf/ I 156-59-2 cis-1,2-Dichloroethene BRL 1.0 pg/I I 136-60-S trans- 1,2-Dichloroethene BRL I II 7-5 1,2-Dichloropropane BRL 1.0 pg/I 142-28-9 1,3-Dichloropropane BRL 1.0 pg/I I 594-20-7 2,2-Dichloropropane BRL 1.0 pg/I I v

563-58-6 l,l-Dichloropropene BRL 1.0 pg/I 10061-01-5 cis-1,3-Dichloropropene BRL 1.0 pg/I 10061-02-6 urans-l,3-Dichloropropene BRL 1.0 pgIl 100-41-4 Ethylbcnzene BRL .1.0 pg/I 87-61-3 Hexachlorobutadiene BRL 1.0 pg/I l 591-78-6 2-Hexanone (MBK) BRL 10.0 pg/I 98-82-8 Isopropylbenzene BRL, 1.0 pg/I 99-87-6 4-Isopropyltoluene BRL 1.0 pg/I BRL 1.0 Pg/I 1634-044 Methyl tert-butyl ether This laboratoryreportis not valid without an authorizedsignature on the coverpage.

  • Reportable Detection Limit BRL = Below Reporting Limit Page 6 of 31

Sample Identification Client Proiect # Matrix Collection Date/Time Received MW-3 SA35951-03 04-201215 Ground Water 17-Oct-05 14:01 18-Oct-05 CASNo. Analyte(s) Result *RDLIUnnits Dilution MethodRef. PreparedAnalyzed Batch Analyst Flag Volatile Organic Compounds Volatile Organic Compounds bvSW846 8260B Prepared by method SW846 5030 Water MS 108.10-1 4-Methyl-2-pentanone (MIBK) BRL 10.0 Pg/l I SW846 8260B 24-Oct-05 25-Oct.05 5101451 KS 75-09-2 Methylene chloride BRL 10.0 pg/l 1 ...

91.20.3 Naphthalene BRL 1.0 pg/Il I ..

103-65-1 n-Propylbenzene BRL 1.0 pg/I I .. . . .

100-42-5 Styrene BRL 1.0 pg/l I..

630-20.6 1,1,1,2-Tetrachloroethane BRL 1.0 pg/Il 1 79-34-5 1,1,2,2-Tetrachloroethane BRI, 1.0 Pg/I 1 .

127.18-4 Tetrachloroethene BRL 1.0 pg/l 1 .. . . .

108-88-3 Toluene BRL 1.0 pg/Il 1 .. N . .

87.61.6 1,2,3-Trichlorobenzene BRL 1.0 pg/l 1 .. . . .

120-82-1 1,2,4-Trichlorobenzene BRL 1.0 pg/I 1 .

71.55.6 1,1,1-Trichloroethane BRL 1.0 pg/I1 79-00-5 1,1,2-Trichloroethane BRLL 1.0 pg/Il 1 ..

79-01.6 Trichloroethene BRL 1.0 pg/I 1 ...

75.694 Trichiorofluoromethane (Freon BRL 1.0 pg/l 1 .. . N .

11) 96-18-4 1,2,3-Trichloropropane BRL 1.0 pg/Il 1.. . N 95.63-6 1,2,4-Trimethylbenzene BRL 1.0 pg/l 108.67-8 1,3,5-Trimethylbenzene BRL 1.0 pg/il .. . .

75-01-4 Vinyl chloride BRL 1.0 pg/l 1.N N.

1330-20-7 mp-Xylene BRL 2.0 pg/l .. . . .

95.47.6 o-Xylene BRL 1.0 pg/l 1.N N Surrogaterecoveries:

460-00-4 4-Bromofluorobenzene 103 70-130 %

2037-26-5 Toluene-d8 97.4 70-130 % .. . . .

17060-07-0 1,2-Dfchloroethane-d4 107 70-130 % .. . . .

1168-53.7 Dibromofluoromethane 100 70-130 % .. . . .

This laboratoryreport Is not valid without an authorizedsignatureon the cover page.

  • Reportable Detection Limit BRL - Below Reporting Limit Page 7 of 31

Sample Identification Client Project # Matrix Collection Date/Time Received MW-4 04-201215 Ground Water 17-Oct-05 14:24 18-Oct-05 SA35951-04 CASINo. Analyte(s) Result *RDLIUnits Dilution Method Ref Prepared Analyzed Batch Analyst Flag Volatile Organic Compounds Volatile OrganicCompounds by SW846 8260B Prepared by method SW846 5030 Water MS BRL 20.0 pg/I SW846 8260B 24-Oct-OS 25-Oct-05 5101451 KS 67-64-1 Acetone N N N N 107-13-1 Acrylonitrile BRL, 1.0 pg/I N N N N 71-43-2 Benzene BRL 1.0 Pg/I 10846-1 Bromobenzene BRL 1.0 Pg/l N N1 N N 74-97.5 Bromochloromethane BRL 1.0 Pg/I It 75-27-4 Bromodichloromethane BRL 1.0 Pg/I tt 75-25-2 Bromoform BRL 1.0 Pg/I 74-83-9 Bromomethane BRa 2.0 pg/I 78-93.3 2-Butanone (MEK) BRL 10.0 Ag/I 104-51-8 n-Butylbenzene BRL 1.0 .g/l 135-98-8 sec-Butylbenzene BRL 1.0 pg/l 98-06-6 tcrt-Butylbenzene BRL 1.0 Pg/Il 75.15-0 Carbon disulfide BRL 5.0 pg/

m 56-23.5 Carbon tetrachloride BRL 1.0 pg/I 108-90-7 Chlorobenzene BRL 1.0 pg/I 75.00-3 Chloroethane BRL 2.0 pg/l 67-66-3 Chloroform BRL 1.0 Pg/I 74-87.3 Chloromethane BaL 2.0 pg/i It 9549-8 2-Chlorotoluene BRa 1.0 pg/I t 106434 4-Chlorotoluene BRa 1.0 Pg/Il 96.12-8 1,2-Dibromo-3-chloropropane BRL 2.0 pg/I 12448.1 Dibromochloromethane BRL 1.0 pg/i 106-934 1,2-Dibromoethane (EDB) BRL 1.0 Pg/I 74-95-3 Dibromomethane BRL 1.0 ptg/I 95-50-1 1,2-Dichlorobenzene BRL 1.0 pg/I 541-73-1 1,3-Dichlorobenzene BRa 1.0 PgI 10646-7 1,4-Dichlorobenzene BRL 1.0 Ag/I 75-71.8 Dichlorodifluoromethane BRL 2.0 pg/I (Freonl2) 75-34-3 1,1-Dichloroethane BRL 1.0 Pg/I 107.06-2 1,2-Dichloroethane BRa 1.0 pg/l 75-354 1,1-Dichloroethene BRa 1.0 pg/I 156.59.2 cis-l ,2-Dichloroethene BRL 1.0 pg/l 156-60-5 trans- 1,2-Dichloroethene BRL 1.0 pg/I 78-87-5 1,2-Dichloropropane BRL 1.0 pg/I 0 142-2 -9 1,3-Dichloropropane BRa 1.0 pg/I 594-20-7 2.2-Dichloropropane BRL 1.0 Pg/I 563-58-6 Il-Dichloropropene BRa 1.0 pg/I 10061-01-5 cis-l1,3-Dichloropropene BRa 1.0 pg/I 10061-02-6 trans-I ,3-Dichloropropene BRa 1.0 pg/I m

100.414 Ethylbenzene BRa 1.0 pg/I 97-68-3 Hexachlorobutadiene .BRL 1.0 pgfl

  1. $I 591-78-6 2-Hexanone (MBK) BRa 10.0 Pg/I m

98-82.8 Isopropylbenzene BRa 1.0 pg/I D 99-87.6 4-Isopropyltoluene BRa 1.0 pg/I N N 1634-044 Methyl tert-butyl ether BRa 1.0 pg/I This laboratoryreportis not valid without an authorizedsignatureon the coverpage.

  • Reportable Detection Limit BRLL = Below Reporting Limit Page 8 of 3i

Sample Identification Client Proiect 4 Matrix Collection Date/Time Received MWV-4 04-201215 Ground Water 17-Oct-05 14:24 18-Oct-05 SA35951-04 CASNo. Analyte(s) Result *RDLIUnits Dilution MethodRef. Prepared Analyzed Batch Analyst Flag Volatile Organic Compounds Volatile Organic Compounds by SW846 8260B Prepared by method SW846 5030 Water MS 108-10-I 4-Methyl-2-pentanone (MIBK) BRL 10.0 Pg/I 1 SW846 8260B 24-Oct.05 25-Oct-05 5101451 KS 75-09-2 Methylene chloride BRL 10.0 pg/I 1. . . .

91-20-3 Naphthalene BRL 1.0 pg/I 1 .

103-65-1 n-Propylbenzene BRL 1.0 pg/l 1 .

10042-S Styrene BRL 1.0 pg/I 1 .

630-20-6 1,1,1,2-Tetrachloroethane BRL 1.0 pg/I I .

79-34-3 1,1,2,2-Tetrachloroethane BRL 1.0 pg/i I .. . . .

127-18.4 Tetrachloroethene BRL 1.0 pg/I 1 .

108-s8-3 Toluene BRL 1.0 pg/I 1 .

s7-61.6 1,2,3-Trichlorobenzene BRL 1.0 pg/I 1 ... . .

120.82-1 1,2,4-Trichlorobcnzene BRL 1.0 pg/I 1 ... . .

71-55-6 I,1,1-Trichloroethane BRL 1.0 pg/I 1 .

79-00-S 1,1,2-Trichloroethane BRL 1.0 pg/I I ... . .

79-01-6 Trichloroethene BRL 1.0 pg/l I .. . . .

75-69-4 Trichlorofluoromethane (Freon BRL 1.0 pg/l I .

11) 96-18-4 1,2,3-Trichloropropane BRL 1.0 pg/Il I ... .

95.63-6 1,2,4-Trimethylbenzene BRL 1.0 pg/I 1 .

108-67.8 1,3,5-Trimethylbenzene BRL 1.0 pg/I I ... . .

75-01-4 Vinyl chloride BRL 1.0 pg/I I .

1330-20-7 mp-Xylene BRIL 2.0 pg/I I ... . .

95-47-6 o-Xylene BRL 1.0 pg/l I 1. . .. .

Surrogate recoveries:

460-00-4 4-Bromofluorobenzene 102 70-130 % ... . .

2037-26-S Toluene-d8 96.8 70-130 % ... . .

17060-07-0 1,2-Dlchloroethane-d4 109 70-130 % ... . .

1868-53-7 Dibromofluoromethane 103 70-130 % ... . .

This laboratoryreport is not valid without an authorizedsignatureon the cover page.

  • Reportable Detection Limit BRL - Below Reporting Limit Page 9 of 31

Sample Identification Matrix Collection Date/Time Received Client Project #

MW-5 04-201215 Ground Water 17-Oct-05 13:52 18-Oct-05 SA35951-05 CASNo. Analyte(s) Result *RDL/Units Dilution MethodRef. Prepared Analyzed Batch Analyst Flag Volatile Organic Compounds Volatile OrganicCompounds by SW846 8260B Prepared by method SW846 5030 Water MS I sw846 8260B 24-Oct-OS 25-Oct-O5 5101451 67-64-1 Acetone BRL 20.0 pg/I KS Acrylonitrile BRL 1.0 pgI 1 0 107.13-1 71.43-2 Benzene BRL 1.0 Pg/I 1

  • 108-86-1 Bromobenzene BRL 1.0 pg/I j 0 0 74-97-S Bromochloromethane BRL 1.0 Pg/I 75-27-4 Bromodichloromethane BRL 1.0 Pg/I 1 0 75-25-2 Bromoform BRL 1.0 pg/I 74-83-9 Bromomethane BRL 2.0 pgA 1 0 78-93-3 2-Butanone (MEK) BRL 10.0 Pg/I 104-51-8 n-Butylbenzene BRL 1.0 pg/I 135-98-8 sec-Butylbenzene BRL 1.0 Pg/I 98-06-6 tert-Butylbenzene BRL 1.0 pg/I 7S-15-0 Carbon disulfide BRL 5.0 pg/I S6.23-S Carbon tetrachloride BRL 1.0 pgA 101.90-7 Chlorobenzene BRL 1.0 pg/

75-00-3 Chloroethane BRL 2.0 pg/

67-66-3 Chloroform BRL 1.0 pg/I 1 0*

74-87.3 Chloromethane BRL 2.0 pg/I I 0 95-49-8 2-Chlorotoluene BRL 1.0 pg/I 4-Chlorotoluene BRL 1 106-43-4 1.0 pg/I -

96-12-8 1,2-Dibromo-3-chloropropane BRL 2.0 pg/

124-48-1 Dibromochloromethane BRL 1.0 pg/I 106-93-4 1,2-Dibromoethane (EDB) BRa 1.0 pg/I 74-95-3 Dibromomethane BRL 1.0 pg/l 95.50-1 1,2-Dichlorobenzcne BRL 1.0 pg/l 541-73-1 1,3-Dichlorobenzcne BRL I0646-7 1,4-Dichlorobenzene BR. 2.0 pg/I 75-71-8 Dichlorodifluoromethane BRL 2.0 1.0 pg/I Pg/I (Freonl2) 75-34-3 1,1-Dichloroethane BRL 107-06-2 1,2-Dichloroethane BRa pg/I 1.0 Pg/I 75-35-4 ,1-Dichloroethene BaL 1.0 Pg/

156-59-2 cis- 1,2-Dichloroethene BRL 1.0 pg/I 156-60-5 trans-l,2-Dichloroethene BRL 1.0 Pg/I 78-87-5 1,2-Dichloropropane BRL 1.0 pg/I 142-28-9 1,3-Dichloropropane BRL 594-20-7 2,2-Dichloropropane BRL I 1.0 pg/I 563-58-6 1,1 -Dichloropropene BR.

1.0 pg/I 10061-01-5 cis-l,3-Dichloropropene BaL 1.0 pg/I 10061-02-6 trans-I,3-Dichloropropene BRL 100-41-4 Ethylbenzene BRL 1.0 tg/I 87-68-3 Hexachlorobutadiene BRL N 591-78-6 2-Hexanone (MBK) Ba, 98-82-8 Isopropylbenzene BRL 1.0 pg/l 99-87-6 4-Isopropyltoluene BRa 1634-04-4 Methyl tert-butyl ether BRL 1.0 pg/I This laboratoryreportis not valid without an authorizedsignatureon the coverpage.

  • Reportable Detection Limit BRL = Below Reporting Limit Page 10 of 31

Sample Identification Client Project # Matrix Collection Date/Time Received MW-5 04-201215 Ground Water 17-Oct-05 13:52 18-Oct-05 SA35951-05 CASNo. Analyte(s) Result *RDL/Units Dilution MethodRef. PreparedAnalyzed Batch Analyst Flag Volatile Organic Compounds Volatile Organic Compounds by SW846 8260B Prepared by method SW846 503 0 Water MS 108-10-1 4-Methyl-2-pentanone (MIBK) BRL 10.0 jg/I 1 SW846 8260B 24-Oct-05 25-Oct-)5 5101451 KS 75-09-2 Methylene chloride BRL 10.0 pg/I 1 ...

91-20-3 Naphthalene BRL 1.0 pg/Il 1 .. . .

103-65-1 n-Propylbenzene BRL 1.0 pg/l I 100o42.5 Styrene BRL 1.0 pg/l 1 .. . . .

630-20-6 1,1,1,2-Tetrachloroethane BRL 1.0 pg/I .. . . .

79-34-5 1,1,2,2-Tetrachloroethane BRL 1.0 pg/I I ...

127-18-4 Tetrachloroethene 2.1 1.0 pg/I 1 ... . .

108-88-3 Toluene BRL 1.0 pg/Il I .. . . .

87-61-6 1,2,3-Trichlorobenzene BRL 1.0 pg/I I ...

120-82-1 1,2,4-Trichlorobenzene BRL 1.0 pg/I I .. . . .

71-55-6 1,1,1-Trichloroethane BRL 1.0 pg/I 1 ...

79-00-S 1, 1,2-Trichloroethane BRL 1.0 pg/Il 1 ..

79-01.6 Trichloroethene BRIL 1.0 pg/Il I ..75-694 Trichlorofluoromethane (Freon BRL 1.0 pg/Il 1 .. . .

11)96-184 1,2,3-Trichloropropane BRL 1.0 pg/I ...

95-63-6 1,2,4-Trimethylbenzene BRL 1.0 pg/I .. . . .

108-67-8 1,3,5-Trimethylbenzene BRL 1.0 pg/I .. . . .75-014 Vinyl chloride BRL 1.0 pg/Il I.. .

1330-20-7 m,p-Xylene BRL 2.0 pg/Il .. . .

9547-6 o-Xylene BRL 1.0 pg/l .. N N.

Surrogaterecoveries:

460-004 4-Bromofluorobenzene 102 70-130 % .. . . .

2037-26-5 Toluene-d8 97.4 70-130 % .N N . .

17060-07-0 1.2-Dichloroethane-d4 109 70-130 % .. . . .

1868-53-7 Dibromofluoromethane 103 70-130 %

This laboratoryreport is not valid Without an authorizedsignature on the coverpage.

  • Reportable Detection Limit BRL - Below Reporting Limit Page I11of 31

Sample Identification Client Proiect # Collection Date/Time Received Matrix MW-6 04-201215 Ground Water 17-Oct-05 14:09 18-Oct-05 SA35951-06 CASNo. Analyte(s) Result *RDLIUnits Dilution MethodRef. PreparedAnalyzed Batch Analyst Flag Volatile Organic Compounds Volatile Organic Compounds by SW846 8260B Prepared by method SW846 5030 Water MS Acetone BRL 20.0 pg/l 1 SW846 8260B 24-Oct-O5 25-Oct-05 5101451 KS 67-64-1 107.13.1 Acrylonitrile BRL 1.0 Pg/ 1 N N 7143-2 Benzene BRL 1.0 pg/I 1081-6-1 Bromobenzene BRL 1.0 Pg/I Bromochloromethane BRL I N N 74.97-5 1.0 pg/I 75.27-4 Bromodichloromethane BRL 1.0 Pg/I 75-25.2 Bromoform BRL 1.0 Pg/i 74-83-9 Bromomethane BRL 2.0 pg/I 1 N N 78-93.3 2-Butanone (MEK) BRL 10.0 pg/I 104-51-8 n-Butylbenzene BRL 1.0 pg/I 135-98.8 sec-Butylbenzene BRL 1.0 Pg/i 1 N N 93-06-6 tert-Butylbenzene BRL 1.0 Pg/I 75-15-0 Carbon disulfide BRL 5.0 pg/I 56.23-5 Carbon tetrachloride BRL 1.0 pg/I 108-90.7 Chlorobenzene BRL 1.0 pg/I 75-00-3 Chloroethane BRL 2.0 pg/I I N N 67.66-3 Chloroform BRL 1.0 pg/I 74-87.3 Chloromethane BRL 2.0 pg/I 1 N N 9549-8 2-Chlorotoluene BRL 1.0 pg/I 106-434 4-Chlorotoluene BRL 1.0 pg/I 1 N N 96-12.8 1,2-Dibromo-3-chloropropane BRL 2.0 pg/I BRL 1 N N 124-48.1 Dibromochloromethane 1.0 pg/I 106-93-4 1,2-Dibromoethane (EDB) BRL 1.0 pg/I 1 N N 74-95-3 Dibromomethane BRL 1.0 pg/I 95-50.1 1,2-Dichlorobenzene BRL 1.0 pg/I I N N 541-73.1 1,3-Dichlorobenzene BRL 1.0 pg/I 10646.7 1,4-Dichlorobenzene BRL 1.0 pg/I 75.7-18 Dichlorodifluoromethane BRL 2.0 pg/I (Freonl2) 75-34-3 Il-Dichloroethane BRL 1.0 pg/i 107-06-2 1,2-Dichloroethane BRL 1.0 pg/I 75-35-4 Il-Dichloroethene BRL 1.0 pg/I 156-59-2 cis-l ,2-Dichloroethene BRL 1.0 pg/i 156-60-5 trans- 1,2-Dichloroethene BRL 1.0 pg/I 758-87.5 1,2-Dichloropropane BRL 1.0 pg/I 142-28.9 1,3-Dichloropropane BRL 1.0 pg/I 594-20-7 2,2-Dichloropropane BRL 1.0 pg/I 563-58.6 II-Dichloropropene BIL 1.0 pg/i BRL 10061-01-5 cis-1,3-Dichloropropene 1.0 pg/I 10061-02-6 trans-1,3-Dichloropropene BRa 1.0 pg/I 10041-4 Ethylbenzene BRL 1.0 pg/I 87-6-.3 Hexachlorobutadiene B RL 1.0 pg/I 591-78-6 2-Hexanone (MBK) BRL 10.0 pg/I 98-82.8 Isopropylbenzene BRL 1.0 pg/I 99-87.6 4-Isopropyltoluene BRL 1.0 pg/I 1634-044 Methyl tert-butyl ether BRL, 1.0 pg/I This laboratoryreport is not valid without an authorizedsignatureon the cover page.

  • Reportable Detection Limit BIL = Below Reporting Limit Page 12 of 31

Sample Identification Client Project 9 Matrix Collection Date/Time Received MW-6 SA35951-06 04-201215 Ground Water 17-Oct-05 14:09 18-Oct-05 CASNo. Analyte(s) Result *RDL/Units Dilution MethodRef. Prepared Analyzed Batch Analyst Flag Volatile Organic Compounds Volatile Organic Compounds by SW846 8260B Prepared by method SW846 5030 Water MS 108-10-1 4-Methyl-2-pentanone (MIBK) BRL 10.0 pg/l 1 SW846 8260B 24-Oct-05 25-Oct-05 5101451 KS 75-09-2 Methylene chloride BRL 10.0 Pg/I 1 .

91.20-3 Naphthalene 9.1 1.0 Pg/I 1 ... . .

103-65-1 n-Propylbenzene BRL 1.0 Pg/I 1 100-42-S Styrene BRL 1.0 Pg/I 1 ... . .

630-20-6 1,1,1,2-Tetrachloroethane BRL 1.0 pgoI .. . . .

79-34-5 1,1,2,2-Tetrachloroethane BRL 1.0 pg/I 1 ... . .

127.18.4 Tetrachloroethene BRL 1.0 ag/ 1 ... . .

108.88-3 Toluene BRL 1.0 Pg/] I 1.. . .

87-61-6 1,2,3-Trichlorobenzene BRL 1.0 pg/I  ! .. . . .

120-82-1 1,2,4-Trichlorobenzene BRL 1.0 Pg/I 1... U .

71.55-6 1,1,1-Trichloroethane BRL 1.0 pg/I 1 ... .

79.00-5 1,1,2-Trichloroethane BRL 1.0 pg/I 1U.. U .

79-01.6 Trichloroethene BRL 1.0 Pg/l I U.. U .

75-69-4 Trichlorofluoromethane (Freon BRL 1.0 Pgo I .. U U .

11) 96.18.4 1,2,3-Trichloropropane BRL 1.0 pg/I 1U.. . .

95-63.6 1,2,4-Trimethylbenzene 3.3 1.0 pg/I 1 ... . .

108.67.8 1,3,5-Trimethylbenzene 1.6 1.0 Pg/ 1 U.. . .

75-01-4 Vinyl chloride BRL 1.0 pg/I  ! .. . . .

1330-20-7 m,p-Xylene BRI, 2.0/pg/I 1 U.. . .

95-47.6 o-Xylene BRL 1.0 pg/I  ! ... .

Surrogate recoveries:

460-00.4 4-Bromofluorobenzene 105 70-130 %/ .. . . .

2037-26-5 Toluene-d8 98.0 70-130 % .. . . .

17060.07.0 1,2-Dichloroethane-d4 109 70-130 % .. . . .

1868-53-7 Dibromofluoromethane 104 70-130 % U. U U .

This laboratoryreportis not valid without an authorizedsignatureon the coverpage.

  • Reportable Detection Limit BRL = Below Reporting Limit Page 13 of 31

Sample Identification Client Project # Matrix Collection Date/Time Received MW-7 04-201215 Ground Water 17-Oct-05 14:05 18-Oct-05 SA35951-07 CASNo. Analyte(s) Result *RDLIUnlts Dilution MethodRef. Prepared Analyzed Batch Analyst Flag Volatile Organic Compounds Volatile OrganicCompounds by SW846 8260B Prepared by method SW846 5030 Water MS 1 SW846 8260B 24-Oct-OS 25-Oct-05 5101451 KS 67-64-1 Acetone BRL 20.0 pg/I 107.13-1 Acrylonitrile BRL 1.0 Pg/I I * - N N 71-43-2 Benzene BRL .OPg/I I N N N N 108-46-1 Bromobenzene BRL 1.0 Pg/I l N N N N 74-97.s Bromochloromethane BRL 1.o pg/

75-27-4 Bromodichloromethane BRL 1.0 pg/I 1 N N N N 75.25.2 Bromoform BRL 1.0 Pg/I 74-83.9 Bromomethane BRL 2.0 pg/I 7"-93.3 2-Butanone (MEK) BRL 10.0 pg/I 104-SI-8 n-Butylbenzene BRL 1.0 pg/I 1 a a N 135.98-8 sec-Butylbenzene BRa 1.0 pg/I 9.-06-6 tert-Butylbenzene BRL 1.0 pg/I 75.15-0 Carbon disulfide BRL 5.0 Pg/I 1 N N N N 56.23-S Carbon tetrachloride BRL 1.0 pg/I 3 N N N N 105-90-7 Chlorobenzene BRL 1.0 pg/i 1 a a a a 75-00.3 Chloroethane BRa 2.0 pg/I I N N N 67.66-3 Chloroform BRL 1.0 Pg/I 74.87.3 Chloromethane BRL 2.0 pg/I 95-49-S 2-Chlorotoluene BRa 1.0 pg/I 106-434 4-Chlorotoluene BRL 1.0 pg/I 96-12-8 1,2-Dibromo-3-chloropropane BRL 2.0 pg/I 1 N N* N N 124.48-1 Dibromochloromethane BRL 1.0 pg/I 106-934 1,2-Dibromoethane (EDB) BRL 1.0 pg/I 74-95-3 Dibromomethane BaL. 1.0 pg/I 1 N Nt N N 95.50-I 1,2-Dichlorobenzene BRL l.O pg/I 541.73-1 1,3-Dichlorobenzene BRL 1.0 pg/I I N N N 10646-7 1,4-Dichlorobenzene BRL 1.0 pg/i 75-71-S Dichlorodifluoromethane BRL 2.0 Pg/I (Freon 12) 75-34-3 l,l-Dichloroethane BRa 1.0 pg/l 107-06-2 1,2-Dichloroethane BRL 1.0 pg/

75-35-4 1,1-Dichloroethene BRL 1.0 pg/I I

156-59-2 cis- 1,2-Dichloroethene BRL 1.0 pg/I 156-60-5 trans-1,2.Dichloroethene BRa 1.0 pg/Il 78-$7-5 1,2-Dichloropropane BRL 1.0 pg/I 142-28-9 1,3-Dichloropropane BRL 1.0 pg/I 594-20-7 2,2-Dichloropropane BRL 1.0 pg/I 563-58-6 I, 1-Dichloropropene BRL 1.0 Pg/I 10061-01-5 cis-1,3-Dichloropropene BRL 1.0 pg/I 10061-02-6 trans-I ,3-Dichloropropene BRL 1.0 pg/I I 0

100-414 Ethylbenzene BRL 1.0 pg/I N 87-69-3 Hexachlorobutadiene BRa 1.0 pg/I N *g 591-78-6 2-Hexanone (MBK) BRa 10.0 Pg/I 98-82-8 Isopropylbenzene BRL 1.0 pg/I 99-87-6 4-Isopropyltoluene BRL 1.0 pg/I 1634-044 Methyl tert-butyl ether BRL 1.0 pg/I This laboratoryreportIs not valid without an authorizedsignatureon the cover page.

  • Reportable Detection Limit BRL - Below Reporting Limit Page 14 of 31

Sample Identification Client Proiect # Matrix Collection Date/Time Received MW-7 04-201215 Ground Water 17-Oct-05 14:05 18-Oct-05 SA35951-07 CASNo. Analyte(s) Result *RDLUnnlts Dilution Method Ref. PreparedAnalyzed Batch Analyst Flag Volatile Organic Compounds Volatile Organic Compounds by SW846 8260B Prepared by method SW846 5030 Water MS t0s9-o0- 4-Methyl-2-pentanone (MIBK) BRL 10.0 pg/I I SWE46 8260B 24-Oct-05 25-Oct-05 5101451 KS 75-09.2 Methylene chloride BRLL 10.0 pg/l 1 .

91-20-3 Naphthalene BRL 1.0 pg/I 1 .. . . .

103-65.1 n-Propylbenzene BRL 1.0 pg/l 1 " N " "

100-42-5 Styrene BRL 1.0 pg/i 1 .

630-20-6 1,1,1,2-Tetrachloroethane BRL 1.0 pg/I 1 p.. . .

79.34-S 1,1,2,2-Tetrachloroethane BRL 1.0 pg/I I .. . . .

127.18-4 Tetrachloroethene 3.7 1.0 pg/Il p.p. p 108-88-3 Toluene BRL 1.0 pg/I .

87-61.6 1,2,3-Trichlorobenzene BRL 1.0 pg/l 1 .. . . .

120-82-1 1,2,4-Trichlorobenzene BRL 1.0 Pg/l 1 ...

7155s.6 1,1,1-Trichloroethane BRL 1.0 pg/l 1 .. . . .

79-00.5 1,1,2-Trichloroethane BRL 1.0 pg/i I .. N . .

79-01-6 Trichloroethene BRL 1.0 pg/I 1 .. p p .

75-69-4 Trichlorofluoromethane (Freon BRL 1.0 pg/l I .. p 11) 96-18-4 1,2,3-Trichloropropane BRL 1.0 pg/l 1 95-63-6 1,2,4-Trimethylbenzene BRL 1.0 pg/I 1.. . . .

108o67-8. ,3,5-Trimethylbenzene BRLL 1.0 pg/I 1 .. . . .

75-01-4 Vinyl chloride BRL 1.0 pg/l I .. . .

1330-20-7 m,p-Xylene BRL 2.0 pg/I 1 95.47-6 o-Xylene BRL 1.0 pg/l I .. . P .

Surrogate recoveries:

460-00-4 4-Bromofluorobenzene 105 70-130 ?%1 2037-26-S Toluene-d8 99.0 70-130 0%

11060-07-0 1.2-Dichloroethane-d4 110 70-130 % ...

1868.53-7 Dibromofluoromethane 104 70-130 %

This laboratory reportIs not valid without an authorizedsignatureon the coverpage.

  • Reportable Detection Limit BI.L = Below Reporting Limit Page 15 of 31

Sample Identification Client Project . Matrix Collection Date/Time Received MW-8 04-201215 Ground Water 17-Oct-05 14:20 18-Oct-05 SA35951-08 CASINo. Analyte(s) Result *RDJ./Units Dilution MethodRef. PreparedAnalyzed Batch Analyst Flag Volatile Organic Compounds Volatile OrganicCompounds by SW846 8260B Prepared by method SW846 5030 Water MS 67-64-1 Acetone BRL 100 pg/l 5 SW846 8260B 24-Oct-05 25-Oct-05 5101451 KS 107-13-1 Acrylonitrile BRL 5.0 pg/l 5

  • P 5 P
  • 71-43-2 Benzene BRLL 5.0 Pg/I 108-86-1 Bromobenzcne BRLL 5.0 pg/I 5 P
  • 74-97-5 Bromochloromethane BRL 5.o.pg/ 5 P P 75-274 Bromodichloromethane BRL 5.0 pg/I 75-25-2 Bromoform BRL 5.0 pg/I 5 P P 5
  • P 74-93-9 Bromomethane BRL 10.0 pg/I 5

78-93.3 2-B utanoni (MEK) BRL 50.0 pg/l 5

104-51-s n-Butylbenzene 8.7 5.0 pg/l 5*

135-9g-8 sec-Butylbenzene 9.8 5.0 pg/l 5 P P 98-06-6 tert-Butylbenzene BRL 5.0 pg/I 5 P P 75-So-0 Carbon disulfide BRL 25.0 pg/I 5 P P 56-23-5 Carbon tetrachloride BRL 5.0 pg/l 5 P P 108-90-7 Chlorobenzene BRLL 5.0 pg/I 5

  • P 75-0o-3 Chloroethane BRL 10.0 pg/I 67-66-3 Chloroform BRL 5.0 pg/l 7447.3 Chloromethane BRLL 10.0 pg/I 5
  • 95-494 2-Chlorotoluene BRL 5.0 pg/I 5*

106434 4-Chlorotoluene BRL 5.0 pg/i 5 P P I

96-12.- 1,2-Dibromo-3-chloropropane BRLL 10.0 pg/Il 12449-I Dibromochloromethane BRL 5.0 pg/i 5 P P 5*

106-934 1,2-Dibromoethane (EDB) BRL 5.0 pg/l 74-95-3 Dibromomethane BRL 5.0 pg/I 95-50.1 1,2-Dichlorobenzene BRL 5.0 pg/i 5PP 541-73-1 1,3-Dichlorobenzene BRL 5.0 pg/l 5PP W 10646-7 1,4-Dichlorobenzene BRLL 5.0 pg/I 5 P 75-71.8 Dichlorodifluoromethane BRL 10.0 pg/I 5 (Freonl2) 75-34-3 1,1 -Dichloroethane BRL 5.0 pg/Il 5 107-06-2 1,2-Dichloroethane BRL 5.0 pg/I 5 75-354 1,1-Dichloroethene BRL 5.0 pg/I 5 156-59-2 cis-l ,2-Dichloroethene BRL 5.0 pgn 5 156-60-5 trans-1,2-Dichloroethene BRIL 5.0 pg/I 5 78-37-5 1,2-Dichloropropane BRL 5.0 pg/l 5 tl 142-28-9 1,3-Dichloropropane BRL 5.0 pg/I 5 It It 594-20-7 2,2-Dichloropropane BRL 5.0 tpg/ 5 563-58-6 I,1-Dichloropropene BRL 5.0 pg/l 5 tl 10061-01-5 cis- 1,3-Dichloropropene BRL 5.0 pg/I 5 10061-02-6 trans-I ,3-Dichloropropene BRL 5.0 pg/I 5 100414 Ethylbenzene 14.2 5.0 pg/I 5 97-68-3 Hexachlorobutadiene BRL 5.0 pgn 5 591-78-6 2-Hexanone (MBK) BRL 50.0 pg/I 5 10.5 5.0 Pg/ .5 98-92-8 Isopropylbenzene 99-87-6 4-Isopropyltoluene 11.0 5.0 pg/I 5 m

1634-044 Methyl tert-butyl ether BRL 5.0 pgf/ 5 This laboratoryreportis not valid without an authorizedsignatureon the cover page.

  • Reportable Detection Limit BRL = Below Reporting Limit Page 16 of 31

Sample Identification Client Project # Matrix Collection Date/Time Received MW-8 04-201215 Ground Water 17-Oct-05 14:20 I -Oct-05 SA35951-08 CASNo. Analyte(s) Result *RDL/Units Dilution MethodRef. PreparedAnalyzed Batch Analyst Flag Volatile Organic Compounds Volatile Organic Compounds by SW846 8260B Prepared by method SW846 5030 Water MS 108-10-1 4-Methyl-2-pentanone (MIBK) BRL 50.0 pg/l S SW846 8260B 24-Oct-05 25-Oct-05 5101451 KS 75-09.2 Methylene chloride BRL 50.0 pg/l 5 ... . .

91.20-3 Naphthalene 250 5.0 pg/i 5N... .

103-65.1 n-Propylbenzene 15.9 5.0 pg/l 5 ... . .

100-42-5 Styrene BRL 5.0 pg/l 5 . ... N .

630-20-6 1,1,1,2-Tetrachloroethane BRL 5.0 Pg/I 5 ... . .

79-34-5 1,1,2,2-Tetrachloroethane BRL 5.0 Pg/I 5 .. N N .

127.18-4 Tetrachloroethene BRL 5.0 Pg/ 5.

108-88-3 Toluene BRL 5.0 pg/I 5N... . .

87-61.6 1,2,3-Trichlorobenzene BRL 5.0 pg/i 5 N.. . .

120.82-1 1,2,4-Trichlorobenzene BRL 5.0 pg/l 5 N.. N .

71-55-6 1,1,1-Trichloroethane BRL 5.0 pg/I 5 .. N . .

79-00-5 1,1.,2-Trichloroethane BRL 5.0 pg/l 5 ... . .

79-01-6 Trichloroethene BRL 5.0 pg/I 5 ... . .

75-69-4 Trichlorofluommethane (Freon BRL 5.0 pg/I 5 11) 96-18-4 1,2,3-Trichloropropane BRL 5.0 pg/I 5 ... . .

95-63-6 1,2,4-Trimethylbenzene 124 5.0 Vg/I 5 ... . .

108-67-8 1,3,5-Trimethylbenzene 53.6 5.0 pg/I 5 ... . .

75-01-4 Vinyl chloride BRL 5.0 pg/I 5 1330-20-7 m,p-Xylene BRL 10.0 Pg/I 5 ... . .

95-47-6 . o-Xylene BRL 5.0 pg/l 5 ... . .

Surrogaterecoveries:

460-004 4-Bromofluorobenzene 104 70-130 % N. . . .

2037-26-5 Toluene-d8 98.0 70-130 % ... . .

17060-07.0 1.2-Dichloroethane-d4 109 70-130 % ... . .

1868-53.7 Dibromofluoromethane 105 70-130% .. . . .

This laboratoryreport is not valid without an authorizedsignatureon the coverpage.

  • Reportable Detection Limit BRL = Below Reporting Limit Page 17 of 31

. -Sample Identification Collection Date/Time Received Client Proiect # Matrix DUP 04-201215 Ground Water 17-Oct-05 14:15 18-Oct-05 3A35951-09

" "CASNo. Analyte(s) Result *RDLJUnits Dilution Method Ref. PreparedAnalyzed Batch Analyst Flag Volatile Organic Compounds Volatile Organic Compounds by SW846 8260B Prepared by method SW84 6 5030 Water MS 67-64-1 Acetone BRL 100 pg/I S SW846 8260B 24-Oct-OS 25-Oct-05 5101451 KS BRL 5.0 pg/I 5 a 107-13-1 Acrylonitrile 5

71-43.2 Benzene BRL 5.0 pg/I 108-86-1 Bromobenzene BRL 5.0 pg/I 5aa 74-97-5 Bromochloromethane BRL 5.0 Pg/ 5aa 75-27-4 Bromodichloromethane BRL 5.0 pg/I 5 fi 75-25-2 Bromoform BRL 5.0 Pg/I 5 a a 74.83.9 Bromomethane BRL 10.0 Pg/I 5 aa a 78-93-3 2-Butanone (MEK) BRL 50.0 13g/I 5aaa 104-SI-8 n-Butylbenzene BRI 5.0 pg/I 5aaa a 135-98-8 sec-Butylbenzene BRL 5.0 pg/I 5aaa a 98-06-6 tert-Butylbenzene BRL 5.0 pg/I 5aaa 75-15.0 Carbon disulfide BRL 25.0 pg/I 5aaa a 56-23-5 Carbon tetrachloride BRL 5.0 pg/I 5 aa a 108-90-7 Chlorobenzene BRL 5.0 pg/I 5aaa a 75.00-3 Chloroethane BRL 10.0 pg/I 5fa 67-66.3 Chloroform BRL 5.0 pg/I 5aaa a 74-87.3 Chloromethane BRL 10.0 pg/I 5aaa a 95.49-. 2-Chlorotoluene BRI 5.0 pg/I 5aaa a 106-43-4 4-Chlorotoluene BRL 5.0 pg/I 5aaa a 96-12-8 1,2-Dibromo-3-chloropropane BRIL 10.0 Pg/I 5 i 12448.1 Dibromochloromethane BRIL 5.0 pg/I 5aaa a 106-93-4 1,2-Dibromoethane (EDB) BRL 5.0 pg/I 5aaa a 74-95-3 Dibromomethane BRI 5.0 pg/I 5aaa a 95.50-1 1,2-Dichlorobenzene BRL 5.0 Pg/I 5aaa 541.73-1 1,3-Dichlorobenzene BRL 5.0 pg/I 5 aa 10646.7 1,4-Dichlorobenzene BRL 5.0 p~g/I 5aa a a 75-7.38 Dichlorodifluoromethane BRL 10.0 pg/I (Freonl2) 75-34-3 I,I-Dichloroethane BRL 5.0 pg/I tl 107-06-2 1,2-Dichloroethane BRL 5.0 pg/I 75.35-4 I,I-Dichloroethene BRL 5.0 pg/I 156-59-2 cis-1,2-Dichloroethene BRL 5.0 pg/I 156-60-5 trans- 1,2-Dichloroethene BRL 5.0 pg/I BRIL 5,0 pg/I 78-87-5 1,2-Dichloropropane BRL 142-28-9 1,3-Dichloropropane 5.0 pg/I BRa 594-20-7 2,2-Dichloropropane 5.0 pg/I 563-58-6 1,-Dichloropropene BRLL 5.0 pg/I 10061-01-5 cis- 1,3-Dichloropropene BRLL 5.0 pg/I 10061.02-6 trans- 1,3-Dichloropropene BRL 5.0 pg/I U

10041-4 Ethylbenzene 11.4 5.0 pg/I tl 87-65.3 Hexachlorobutadiene BRI 5.0 pg/I It 591-.8-6 2-Hexanone (MBK) BRL 50.0 pg/I m

98-82-8 Isopropylbenzene 7.4 5.0 pg/i N

99-87.6 4-Isopropyltoluene 5.5 5.0 pg/I U

1634-04-4 Methyl tert-butyl ether BRL. 5.0 pg/I This laboratoryreport Is not valid without an authorizedsignature on the coverpage.

  • Reportable Detection Limit BRI - Below Reporting Limit Page 18 of 31

Sample Identification Client Project i# Matrix Collection Date/Time Received DUP 04-201215 Ground Water 17-Oct-05 14:15 18-Oct-05 SA35951-09 CASNo. Analyte(s) Result *RDL/Units Dilution MethodRef. PreparedAnalyzed Batch Analyst Flag Volatile Organic Compounds Volatile Or-ganic Compounds by SW846 8260B Prepared by method SW846 5030 Water MS 108.10-1 4-Methyl-2-pentanone (MIBK) BRL 50.0 pg/I 5 SW846 8260B 24-Oct-05 25-Oct-05 5101451 KS 75-09-2 Methylene chloride BRL 50.0 pg/I 5 .

91-20-3 Naphthalene 154 5.0 pg/I 5 ...

103-65-1 n-Propylbenzene 7.0 5.0 pg/1 5 ...

10042.5 Styrene BRL 5.0 pg/l 5 ...

630-20-6 1,1,1,2-Tetrachloroethane BRL 5.0 pg/il 5 ... .

79-34-5 1,1,2,2-Tetrachloroethane BRL 5.0 pg/l 5 ...

127-184 Tetrachloroethene BRL 5.0 pg/I 5 ...

108-88-3 Toluene BRL 5.0 pg/I 5 .

87-61-6 1,2,3-Trichlorobenzene BRL 5.0 pg/I 5 120-82-1 1,2,4-Trichlorobenzene BRL 5.0 pg/l 5 .

71-55-6 1,1,1-Trichloroethane BRL 5.0 pg/I 5 .

79-00-5 1,1,2-Trichloroethane BRL 5.0 pg/l 5 .

79-01-6 Trichloroethene BRL 5.0 pg/l 5 .75-694 Trichlorofluoromethane (Freon BRL 5.0 pg/l 5 .

11)96-184 1,2,3-Trichloropropane BRL 5.0 pg/l 5 ... . .

95-63-6 1,2,4-Trimethylbenzene 61.7 5.0 pg/I 5 .

108-67-8 1,3,5-Trimethylbenzene 39.5 5.0 pg/I 5 ...75-014 Vinyl chloride BRL 5.0 pg/l 5 1330-20.7 m,p-Xylene BRL 10.0 pg/I 5 " p 9547-6 o-Xylene BRL 5.0 pg/l 5 ... . p Surrogaterecoveries:

460-004 4-Bromofluorobenzene 102 70-130 % .. p p .

2037-26-5 Toluene-d8 98.8 70-130 % ... . .

17060-07-0 1,2-Dichloroethane-d4 101 70-130 % ... . .

1868-53-7 Dibromofluoromethane 98.4 70-130 % ... . .

This laboratoryreport Is not valid without an authorizedsignatureon the cover page.

  • Reportable Detection Limit BRL - Below Reporting Limit Page 19 of 31

Sample Identification Client Proiect #g Matrix Collection Date/Time Received TRIP 04-201215 Deionized Water 17-Oct-05 08:08 18-Oct-05 SA35951-10

.. CAS No. Analyte(s) Result *RDLJUnits Dilution M'ethodRef. PreparedAnalyzed Batch Analyst Flag Volatile Organic Compounds Volatile Organic Compounds by SW846 8260B Prepared by method SW846 5030 Water MS 1 SW846 8260B 25-Oct-05 25-Oct-05 5101534 KS 67-64-1 Acetone BRL 20.0 pg/I 107-13-1 Acrylonitrile BRL 1.o Pg/I 1 p

  • VOCII 71-43-2 Benzene 1.0 1.0 Pgi 1
  • 108-96-1 Bromobenzene BRL 1.0 pg/I 74-97-5 Bromochloromethane BRL 1.0 pg/I I p.,

75.27-4 Bromodichloromethane BRL 1.0 Pg/i I

  • 75.25-2 Bromoform BRL 1.0 Pg/I 74-.3-9 Bromomethane BRL 2.0 pg/1 78-93-3 2-Butanone (MEK) 12.1 10.0 pg/i
  • VOC 11 104-51-8 n-Butylbenzene BRL 1.0 pg/I 135-93-8 sec-Butylbenzene BRL 1.0 Pg/I 98-06-6 tert-Butylbenzene BRL 1.0 pg/I 1

75.15-0 Carbon disulfide BRL 5.0 Pg/I p*

BRL I

  • 56-23-5 Carbon tetrachloride 1.0 pg/I 109-90-7 Chlorobenzene BRL 1.0 pg/i 75-00-3 Chloroethane BRL 2.0 pg/I 1
  • p 67-66-3 Chloroform BRL 1.0 pg/I 74-87-3 Chloromethane 2.5 2.0 pg/I 0 VOCI!

95-49-8 2-Chlorotoluene BRL 1.0 pg/I BRL 1 p 106-43-4 4-Chlorotoluene 1.0 Pg/I 1 II 96.12.- 1,2-Dibromo-3-chloropropane BRL 2.0 pg/I p

124-48-1 Dibromochloromethane BRL 1.0 pg/I 106.93-4 1,2-Dibromoethane (EDB) BRL 1.0 pg/I 74-95.3 Dibromomethane BRL 1.0 pg/i 1 *'

95-S0-1 1,2-Dichlorobenzene BRL 1.0 pg/I 1 p 541-73-1 1,3-Dichlorobenzene BRL 1.6 pg/i 106-46-7 1,4-Dichlorobenzene BRL 1.0 pg/I I

  • 75-71-3 Dichlorodifluoromethane BRL 2.0 pg/i (Freonl2) 75-34-3 1,1 -Dichloroethane BRL 1.0 pg/I W

107-06-2 I,2-Dichloroethane BRL 1.0 pg/I II 75-35-4 I,l-Dichloroethene BRL 1.0 pg/I 156-59-2 cis-l ,2-Dichloroethene BRL 1.0 pg/I m

156-60-5 trans- 1,2-Dichloroethene BRL 1.0 pg/I 78-87-5 1,2-Dichloropropane BRL 1.0 pg/I 142-28-9 1,3-Dichloropropane BRL 1.0 pg/i 594-20-7 2,2-Dichloropropane BRL 1.0 pg/I 563-59-6 1.1-Dichloropropene BRL 1.0 pig/I 10061-01.$ cis-1,3-Dichloropropene BRL 1.0 pg/i 10061-02-6 trans-i ,3-Dichloropropene BRL 1.0 pg/I 100-41-4 Ethylbenzene BRL 1.0 pg/I 37-68-3 Hexachlorobutadiene BRL 1.0 pg/I 591-78-6 2-Hexanone (MBK) BRL 10.0 pg/I 98-82-8 Isopropylbenzene BRL 1.0 pg/I 99-87-6 4-Isopropyltoluene BRL 1.0 pg/i 16344-44 Methyl tert-butyl ether 2.1 1.0 pg/I " VOCII This laboratoryreport Is not valid without an authorizedsignatureon the cover page.

Reportable Detection Limit BRL = Below Reporting Limit Page 20 of 31

Sample Identification TRIP Client Project i# Matrix Collection Date/Time Received 04-201215 Deionized Water 17-Oct-05 08:08 18-Oct-05 SA35951-10 CAS No. Analyte(s) Result *RDJJUnIts Dilution MethodRef. Prepared Analyzed Batch Analyst Flag Volatile Organic Compounds Volatile Organic Compounds by SW846 8260B Prepared by method SW846 5030 Water MS 108.10-1 4-Methyl-2-pentanone (MIRK) BRL 10.0 Pg/l I SW846 8260B 25-Oct-05 25-Oct-05 5101534 KS 75-09-2 Methylene chloride BRL 10.0 pg/l I ... . .

91.20-3 Naphthalene BRL 1.0 Pg/I I ...

103-65-1 n-Propylbenzene BRL 1.0 Pg/l 1 .

100-42.5 Styrene BRL 1.0 Pg/l 1 ...

630-20-6 l1,1,,2-Tetrachloroethane BRL 1.0 Pg/l I ...

79-34-5 1,1,2,2-Tetrachloroethane BRL 1.0 Pg/Il 1 ..

127.18-4 Tetrachloroethene BRL 1.0 jig/I I .

108.-8.3 Toluene 2.2 1.0 Pg/I I . vociz 87-61-6 1,2,3-Trichlorobenzene BRI, 1.0 pg/I 1 ...

120-82-1 1,2,4-Trichlorobenzene BRL 1.0 jig/Il 1 ..

71-55-6 1,1,1-Trichloroethane BRL 1.0 pg/i I ...

79-00-5 1,1,2-Trichloroethane BRL 1.0 jig/Il .. p. p 79-01-6 Trichloroethene BRL 1.0 Pg/I 1 ... . .

75-69-4 Trichlorofluoromethane (Freon BRL 1.0 jig/I 1 I1)96-184 1,2,3-Trichloropropane BRL 1.0 Pg/i 1 ... . .

95-63-6 1,2,4-Trimethylbenzene BRL 1.0 jig/Il 1 ... .

108-67-8 1,3,5-Trimethylbenzene BRL 1.0 Pg/I I 75-014 Vinyl chloride BRL 1.0 pg/I .

1330-20.7 m,p-Xylene BRL 2.0 pg/l i ... . .

9547-6 o-Xylene BRL 1.0 Pg/l I ...

Surrogate recoveries:

460-004 4-Bromofluorobenzene 103 70-130 % p.p. p 2037-26-S Toluene-d8 99.2 70-130 % .. p 17060-07-0 1,2-Dichloroethane-d4 105 70-130 % .. p p .

1868-53-7 Dibromofluoromethane 99.8 70-130 % ... . .

This laboratoryreport Is not valid without an authorizedsignatureon the cover page.

  • Reportable Detection Limit BRL = Below Reporting Limit Page 21 of 31

Volatile Organic Compounds - Quality Control Spike Source %REC RPD Result *RDL Units Level Result %REC Limits RPD Limit Flag Analyte(s)

Batch 5101451 - SW846 5030 Water MS Blank (5101451-BLKI) Prepared & Analyzed: 24-Oct-05 Acetone BRL 20.0 pg/Il Acrylonitrile BRL 1.0 Pg/I Benzene BRL 1.0 Pg/I Bromobcnzene BRL 1.0 pg/I

- Bromochloromethane BRL 1.0 pg/I Bromodichloromethane BRL 1.0 Pg/I Bromoforrn BR!L 1.0 Pg/I Bromomethane BRL 2.0 pgA/

2-Butanone (MEK) BRL 10.0 pg/I n.Butylbonzene BRL 1.0 pgA sec-Butylbcnzene BRL 1.0 pg/I tert-Butylbcnzene BRL. 1.0 pg/I Carbon disulfide BRL 5.0 pAgI Carbon tetrachloride BRL 1.0 pg/

Chlorobenzcne BRL 1.0 pg/

Chloroethane BR!L 2.0 pg/

Chloroform BRL 1.0 Pg/

Chloromethane BRL 2.0 pgn 2-Chlorotoluene BR!L 1.0 pug/I 4-Chlorotoluene BRL 1.0 pg/I 1,2-Dibromo-3-chloropropane BRL 2.0 pg/I Dibromochloromethane BR!L 1.0 pg/I I .2-Dibromoethane (EDB) BRL 1.0 pg/I Dibromomethane BRL 1.0 pg/I 1,2-Dichlorobenzene BRL 1.0 pg/i 1.3-Dichlorobenzene BRIL 1.0 pg/I 1,4-Dichlorobenzene BRL 1.0 pg/I Dichlorodifluoromethane (Freonl2) BRL 2.0 pg/I I,1-Dichloroethane BRL 1.0 pg/I 1,2-Dichlorocthane BRL .1.0 "I I,1-Dichloroethcne BRL 1.0 pg/I cis-1,2-Dichloroethene BR!L 1.0 Pg/I trans-i ,2-Dichloroethene BRL 1-.0 Pg/I 1,2-Dichloropropane BRL 1.0 pg/I 1.3-Dichloropropane BR!L 1.0 PgI 2.2-Dichloropropane BRL 1.0 Pi'l I.1-Dichloropropene BRL 1.0 pg/I cis-I.3-Dichloropropene BRL 1.0 Pg/I trans- l,3-Dichloropropcne BRL 1.0 Pg/I Ethylbenzcne BRL 1.0 pg/I Hexachlorobutadiene BRL 1.0 pg/I 2-Hexanone (MBK) BRL 10.0 pg/I Isopropylbenzcne BRL 1.0 Pg/I 4-1sopropyltoluene BRL 1.0 Pg/I Methyl tert-butyl ether BRL 1.0 Pg/I 4-Methyl-2-pentanone (MIBK) BRL 10.0 pg/I Methylene chloride BRPL 10.0 pig/I Naphthalene BR!L 1.0 pg/I n-Propylbenzene BRL 1.0 pg/I Styrene BRPL 1.0 pg/I l,l.I,2-Tctrachloroethane BR!. 1.0 pg/I I.l.2,2-Tetachloroethane BR!L 1.0 pg/I Tetrachloroethene BRL 1.0 pg/I Toluene BRL 1.0 pig/I This laboratoryreportIs not validwithout an authorizedsignatureon the cover page.

  • Reportable Detection Limit BRL - Below Reporting Limit Page 22 of 31

Volatile Organic Compounds - Quality Control Spike Source %REC RPD Analyte(s) Result *RDL Units Level Result %REC Limits RPD Limit Flag Batch 5101451 - SW846 5030 Water MS Blank (5101451-BLKI) Prepared & Analyzed: 24-Oct-05 1,2,3-Trichlorobenzene BRL 1.0 pg/I 1,2,4-Trichlorobenzcne BRL 1.0 pg/I

!,1,l-Trichloroethane BRL 1.0 pg/l I,l,2-Trichloroethane BRIL 1.0 pg/I Trichloroethene BRL 1.0 pg/I Trichlorofluoromethane (Freon 11) BRL 1.0 pg/l 1,2.3-Trichloropropane BRL 1.0 pg/I 1,2,4-Trimethylbenzene BRL 1.0 pg/I 1,3,5-Trimethylbcnzene BRL 1.0 pg/I Vinyl chloride BR.L 1.0 pg/I m,p-Xylene BRL 2.0 pg/I o-Xylene BRL 1.0 jIgA Surrogate: 4-Bromofluorobenzene 51.8 pg/I 50.0 104 70-130 Surrogate: Toluene-d8 48.4 pg/I 50.0 96.8 70-130 Surrogate: 1,2-Dichloroeihane-d4 50.9 pg/I 50.0 102 70-130 Surrogate:Dibromofluoromethane 49.6 pg/l 50.0 99.2 70-130 LCS (5101451.BS1) Prepared & Analyzed: 24-Oct-05 Acetone 12.3 pg/I 20.0 61.5 0.671-198 Acrylonitrile 18.5 pg/I 20.0 92.5 70-130 Benzene 20.1 pg/I 20.0 100 70-130 Bromobenzene 23.4 pg/I 20.0 117 70-130 Bromochloromethane 20.6 pg/I 20.0 103 70-130 Bromodichloromethane 22.3 pg/I 20.0 112 70-130 Bromoform 21.7 pg/I 20.0 108 70-130 Bromomethane 22.8 pg/I 20.0 114 64.5-146 2-Butanone (MEK) 14.0 pg/l 20.0 70.0 14.3-172 n-Butylbenzene 21.7 pg/I 20.0 108 70-130 sec-Butylbenzene 23.1 pg/I 20.0 116 70-130 tert.Butylbenzene 23.3 pg/I 20.0 116 70-130 Carbon disulfide 19.5 pg/I 20.0 97.5 70-130 Carbon tetrachloride 21.5 pg/I 20.0 108 70-130 Chlorobenzene 22.7 pg/I 20.0 114 70-130 Chloroethane 21.1 pg/I 20.0 106 66.3-135 Chloroform 21.9 pg/I 20.0 110 70-130 Chloromethane 25.1 pg/I 20.0 126 70-130 2-Chlorotoluene 21.9 pg/I 20.0 II0 70-130 4-Chlorotoluene 22.6 pg/l 20.0 113 70-130 1.2-Dibromo-3-chloropropane 20.6 pg/l 20.0 103 70-130 Dibromochloromethane 20.8 pg/l 20.0 104 52.9-141 1,2-Dibromoethane (EDB) 20.5 pg/l 20.0 102 70-130 Dibromomcthane 20.4 pg/I 20.0 102 70-130 1.2-Dichlorobenzene 22.8 pg/l 20.0 114 70-130 1.3-Dichlorobenzene 24.2 pg/I 20.0 121 70-130 1.4-Dichlorobenzene 22.7 pg/I 20.0 114 70-130 Dichlorodifluoromehane (Freonl2) 26.6 pg/I 20.0 133 50.5-203 l,l-Dichloroethane 20.8 pg/I 20.0 104 70-130 1,2-Dichloroethane 21.3 pg/I 20.0 106 70-130 1I,-Dichloroethene 20.7 pg/I 20.0 104 70-130 cis- 1.2-Dichloroethene 21.2 pg/I 20.0 106 70-130 trans- 1.2-Dichloroethenc 20.2 pg/I 20.0 101 70-130 1,2-Dichloropropane 19.9 pg/I 20.0 99.5 70-130 1,3-Dichloropropane 20.0 pg/I 20.0 100 70-130 2,2-Dichloropropane 19.1 pg/I 20.0 95.5 70-130 1.1-Dichloropropene 20.2 pg/I 20.0 101 70-130 This laboratoryreportIs not valid without an authorizedsignatureon the coverpage.

  • Reportable Detection Limit BRL = Below Reporting Limit Page 23 of 31

Volatile Organic Compounds - Quality Control Spike Source %REC RPD Analyte(s) Result *RDL Units Level Result %REC Limits RPD Limit Flag Batch 5101451 - SW846 5030 Water MS LCS (5101451-BSI) Prepared & Analyzed: 24-Oct-05 cis-l.3-Dichloropropene 20.3 jig/I 20.0 102 70-130 trans-l,3-Dichloropropene 20.8 jig/I 20.0 104 70-130 Ethylbcnzene 22.5 jig/ 20.0 112 70-130 Hexachlorobutadiene 23.7 ig/I 20.0 118 68.9-138 2-Hexanone (MBK) 14.6 jig/I 20.0 73.0 70-130 lsopropylbenzene 22.2 20.0 111 70-130 4-1sopropyltoluene 23.0 20.0 115 70-130 Methyl tert-butyl ether 20.0 20.0 100 70-130 4-Methyl-2-pentanone (MIBK) 15.0 jig/I 20.0 75.0 51.5-134 Methylene chloride 21.2 jig/I 20.0 106 70-130 Naphthalene 21.8 jig/ 26.0 109 70-130 n-Propylbenzene 22.6 jig/ 20.0 113 70-130 Styrene 22.9 jig/ 20.0 114 70-130 1.1.1.2-Tetrachloroethane 23.4 jig/I 20.0 117 70-130 1,1,2,2-Tetrachloroethane 21.1 jig/ 20.0 106 70-130 Tetrachloroethene 21.5 jig/ 20.0 108 70-130 Toluene 20.8 jig/ 20.0 104 70-130 1,2.3-Trichlorobenzene 22.4 20.0 112 70-130 1,2,4-Trichlorobenzene 21.7 20.0 108 70-130 l,l,l-Trichloroethane 21.4 20.0 107 70-130 1,1,2-Trichloroethane 20.8 Pg/I 20.0 104 70-130 Trichloroethene 21.4 jig/ 20.0 107 70-130 Trichlorofluoromethane (Freon 11) 23.3 jig/ 20.0 116 70-143 1,2,3-Trichloropropane 21.1 20.0 106 70-130 1,2,4-Trimethylbenzene 23.2 jig/I 20.0 116 70-130 1,3.5-Trimethylbenzene 22.9 jig/ 20.0 114 70-130 Vinyl chloride 25.9 jig/ 20.0 130 70-130 m.p-Xylene 46.1 jig/ 40.0 115 70-130 o-Xylene 23.6 20.0 118 70-130 Surrogate:4-Bromofluorobenzene 52.4 50.0 105 "70-130 Surrogate:Toluene-d8 47.9 50.0 95.8 70-130 Pg/I 50.0 101 70-130 Surrogate: 1,2-Dichloroethane-d4 50.5 jig/

Surrogate:Dibromofluoromethdne 50.0 50.0 100 70-130 LCS Dup (5101451-BSD1) Prepared & Analyzed: 24-Oct-05 Acetone 12.3 jg/I 20.0 61.5 0.671-198 0.00 50 Acrylonitrile 19.3 ig/I 20.0 96.5 70-130 4.23 25 19.5 20.0 97.5 70-130 2.53 25 Benzene PgA Bromobenzene 21.2 pg/ 20.0 106 70-130 9.87 25 Bromochloromethane 21.4 *,gA 20.0 107 70-130 3.81 25 Bromodichloromethane 22.0 PgA 20.0 110 70-130 1.80 25 Bromoform 20.9 20.0 104 70-130 3.77 25 Bromomethane 23.1 pgA 20.0 116 64.5-146 1.74 50 jg/I 2-Butanone (MEK) 14.8 ig/I 20.0 74.0 14.3-172 5.56 50 n-Butylbenzene 20.3 20.0 102 70-130 5.71 25 sec-Butylbenzene 20.8 Ptg" i g/I 20.0 104 70-130 10.9 25 tert-Butylbenzene 21.2 20.0 106 70-130 9.01 25 Carbon disulfide 18.6 jig/I 20.0 93.0 70-130 4.72 25 Carbon tetrachloride 20.5 Pig/I 20.0 102 70-130 5.71 25 Chlorobenzene 20.8 20.0 104 70-130 9.17 25 Chloroethane 19.9 PtgA 20.0 99.5 66.3-135 6.33 50 Chloroform 21.4 20.0 107 70-130 2.76 25 Chloromethane 24.6 pgA 20.0 123 70-130 2.41 25 2-Chlorotoluene 20.8 jig/I 20.0 104 70-130 5.61 25 4-Chlorotoluene 20.8 20.0 104 70-130 8.29 25 This laboratoryreport is not valid without an authorizedsignatureon the coverpage.

  • Reportable Detection Limit BRL = Below Reporting Limit Page 24 of 31

Volatile Organic Compounds - Quality Control Spike Source %REC RPD Analyte(s) Result *RDL Units Level Result %REC Limits RPD Limit Flag Batch 5101451 - SW846 5030 Water MS LCS Dup (5101451-BSDI) Prepared & Analyzed: 24-Oct-05 1,2-Dibromo-3-chloropropane 19.2 jig/ 20.0 96.0 70-130 7 .04 25 Dibromochloromethane 21.4 jig/I 20.0 107 52.9-141 2 .84 50 1,2-Dibromoethane (EDB) 21.3 20.0 106 70-130 3 .85 25 Dibromomethane 20.8 20.0 104 70-130 1.94 25 1,2-Dichlorobenzene 22.1 jig/I 20.0 110 70-130 3 .57 25 1,3-Dichlorobenzene 22.4 jig/I 20.0 112 70-130 7.73 25 1,4-Dichlorobenzene 22.1 jig/ 20.0 110 70-130 3 .57 25 Dichlorodifluoromethane (Freon 12) 25.5 20.0 128 50.5-203 3 .83 50 1 l-Dichloroethane 20.3 20.0 102 70-130 1.94 25 1,2-Dichloroethane 21.4 20.0 107 70-130 0.939 25 l.1-Dichloroethene 19.6 jig/I 20.0 98.0 70-130 5.94 25 cis- I,2-Dichloroethene 20.8 jig/I 20.0 104 70-130 1.90 25 trans-i,2-Dichloroethene 19.7 Pg/I 20.0 98.5 70-130 2 .51 25 1,2-Dichloropropane 19.9 jig/I 20.0 99.5 70-130 0).00 25 1.3-Dichloropropane 20.3 jig/ 20.0 102 70-130 1.98 25 2.2-Dichloropropane 18.8 jig/ 20.0 94.0 70-130 1.58 25 1.1-Dichloropropene 19.8 20.0 99.0 70-130 2.00 25 cis-1,3-Dichloropropene 20.4 hg/I 20.0 102 70-130 0 .00 25 trans-1,3-Dichloropropeno 20.9 jig/I 20.0 104 70-130 CI.00 25 Ethylbenzcne 20.7 jig/I 20.0 104 70-130 7.41 25 Hexachlorobutadiene 22.8 20.0 114 68.9-138 3.45 50 2-Hexanone (MBK) 14.4 jig/I 20.0 72.0 70-130 1.38 25 Isopropylbenzene 20.1 jig/I 20.0 100 70-130 1.0.4 25 4-Isopropyltoluene 21.5 jig/ 20.0 108 70-130 6,.28 25 Methyl tert-butyl ether 20.5 jig/ 20.0 102 70-130 1.98 25 4-Methyl-2-pentanone (MIBK) 16.0 Pg/I 20.0 80.0 51.5-134 6i.45 50 Methylene chloride 21.1 jig/I 20.0 106 70-130 C.00 25 Naphthalene 21.5 20.0 108 70-130 0.922 25 n-Propylbenzene 20.3 jig/I 20.0 102 70-130 110.2 25 Styrene 21.4 jig/ 20.0 107 70-130 66.33 25 1.1 ,2-Tetrachloroethane 21.9 jig/I 20.0 110 70-130 .17 25 1,1,2.2-Tetrachloroethane 20.2 Pg/I 20.0 101 70-130 1.83 25 Tetrachloroethene 20.9 jig/ 20.0 104 70-130 3.77 25 Toluene 20.4 jig/ 20.0 102 70-130 1.94 25 1,2,3-Trichlorobenzene 21.8 ni/I 20.0 109 70-130 2.71 25 1,2.4-Trichlorobenzene 21.7 20.0 108 70-130 0.00 25 I 1.1-Trichloroethane 20,8 20.0 104 70-130 2.84 25 1,l.2-Trichloroethane 20.9 20.0 104 70-130 0.00 25 Trichloroethene 20.2 jig/I 20.0 101 70-130 5.77 25 Trichlorofluoromethane (Freon 11) 22.3 20.0 112 70-143 3.51 50 1,2,3-Trichloropropane 20.0 20.0 100 70-130 5.83 25 1,2.4-Trimethylbenzene 21.6 jig/I 20.0 108 70-130 7.14 25 1.3.5-Trimethylbenzene 21.1 jig/I 20.0 106 70-130 7.27 25 Vinyl chloride 24.3 jig/I 20.0 122 70-130 6.35 25 m,p-Xylene 42.6 p jig/I 40.0 106 70-130 8.14 25 o-Xylene 21.6 Ag/I 20.0 108 70-130 8.85 25 Surrogate:4-Bromofluorobenzene 50.8 50.0 102 70-130 Surrogate: Toluene-d8 49.M 50.0 98.8 70-130 Surrogate: 1,2-Dlchloroethane-d4 52.4 Pg/I 50.0 105 70-130 Surrogate:Dibromofluoromethane 51.1 P Pg/I 50.0 102 70-130 Mantrix Snilke U51014S1-MS1'I Source: SA35951-03 Prepared: 24-Oct-05 Analyzed: 25-Oct-05 Matrix S ike (5101451-MS11 Benzene 24.2 pg/I 20.0 BRLL 121 70-130 Chlorobenzene 26.4 Pg/I 20.0 BRL 132 70-130 QM-07 1,1-Dichloroethene 25.2 jig/I 20.0 BR!L 126 70-130 This laboratoryreportIs not valid without an authorizedsignatureon the cover page.

  • Reportable Detection Limit BRL = Below Reporting Limit Page 25 of 31

Volatile Organic Compounds - Quality Control Spike Source %REC RPD Analyte(s) Result *RDL Units Level Result %REC Limits RPD Limit Flag Batch 5101451 - SW846 5030 Water MS Matrix Spike (5101451-MS1) Source: SA35951-03 Prepared: 24-Oct-05 Analyzed: 25-Oct-05 Toluene 25.5 pg/I 20.0 BRL 128 70-130 Trichloroethene 24.3 pg/I 20.0 BRL 122 70-130 Surrogate:4-Bromofluorobenzene 52.6 pg/ 50.0 105 70-130 Surrogate: Toluene-d& 49.9 pg/l 50.0 99.8 70-130 Surrogate:1,2-Dichloroethane-d4 52.3 pg/I 50.0 105 70-130 Surrogate: Dibromofluoromethane 50.3 pg/I 50.0 101 70-130 Matrix Spike Dup (5101451-MSDI) Source: SA35951-03 Prepared: 24-Oct-05 Analyzed: 25-Oct-05 Benzene 23.6 pg/I 20.0 BRL 118 70-130 2.51 30 Chlorobenzene 24.4 pg/I 20.0 BRL 122 70-130 7.87 30 1,I-Dichloroethene 23.8 pg/I 20.0 BRL 119 70-130 5.71 30 Toluene 24.4 Pg,/ 20.0 BR!.. 122 70-130 4.80 30 Trichloroethene 23.4 pg/I 20.0 BR.L 117 70-130 4.18 30 Surrogate: 4-Bromofluorobenzene 50.6 pg/I 50.0 101 70-130 Surrogate: Toluene-d8 49.8 pg/I 50.0 99.6 70-130 Surrogate: 1.2-Dichloroethane.d4 52.7 pg/I 50.0 105 70-130 Surrogate:Dibromofluoromethane 51.0 pg/I 50.0 102 70-130 Batch 5101534 - SW846 5030 Water MS Blank (5101534-BLKI) Prepared & Analyzed: 25-Oct-05 Acetone BRL 20.0 pg/I Acrylonitrile BRL 1.0 pg/l Benzene BRL 1.0 pg/I Bromobenzene BRL 1.0 pg/l Bromochloromethane BRL 1.0 pg/l Bromodichloromethane BR L 1.0 pg/I Bromoform BRL 1.0 pg/I Bromomethane BRL 2.0 pg/l 2-Butanone (MEK) BRL 10.0 pg/I n-Butylbcnzene BRL 1.0 pg/I sec-Butylbenzene BRL 1.0 pg/I tert-Butylbenzenc BRIL 1.0 pg/I Carbon disulfide BR.L 5.0 pg/I Carbon tetrachloride BRL. 1.0 pg/I Chlorobenzene BRL. 1.0 pg/l Chloroethane BRL 2.0 pg/i Chloroform BRI 1.0 pg/I Chloromethane BPlL 2.0 pg/I 2-Chlorotoluene BRL 1.0 pg/I 4-Chlorotoluene BRL. 1.0 pg/I 1,2-Dibromo-3-chloropropane BR.L 2.0 pg/I Dibromochloromethane BI.L 1.0 pg/I 1,2-Dibromoethane (EDB) BRL 1.0 pg/I Dibromomethane BRL 1.0 pg/I 1,2-Dichlorobenzene BRL 1.0 pg/I 1,3-Dichlorobenzene BRL 1.0 pg/I 1,4-Dichlorobenzene BRL 1.0 pg/I Dichlorodifluoromethane (Freonl2) BRIL 2.0 pg/I l,I-Dichloroethane BRL 1.0 pg/I 1.2-Dichloroethane BRL 1.0 pg/i 1.1-Dichloroethene BR.L 1.0 pg/I cis- 1,2-Dichloroethene BRIL 1.0 pg/I tmns-1,2-Dichloroethene BRL 1.0 pg/I 1.2-Dichloropropane BRL 1.0 pg/I 1,3-Dichloropropane BI.L 1.0 pg/I This laboratoryreport Is not valid without an authorizedsignatureon the coverpage.

  • Reportable Detection Limit BRL = Below Reporting Limit Page 26 of 31

Volatile Organic Compounds - Quality Control Spike Source %REC RPD Analyte(s) Result *RDL Units Level Result %REC Limits RPD Limit Flag Batch 5101534 - SW846 5030 Water MS Blank (5101534-BLKI) Prepared & Analyzed: 25-Oct-05 2.2-Dichloropropane BRL 1.0 ,g/I II-Dichloropropene BRL 1.0 jg/I cis-I ,3-Dichloropropene BRL 1.0 jg/I trans- 1.3-Dichloropropene BRL 1.0 jg/I Ethylbenzene BRL 1.0 jg/I Hexachlorobutadiene BRL 1.0 ILgI 2-Hexanone (MBK) BRL 10.0 jg/I Isopropylbenzene BRL 1.0 jg/I 4-1sopropyltoluene BRL 1.0 jig/I Methyl tert-butyl ether BRL 1.0 jg/l 4-Methyl-2-pentanone (MIBK) BRL 10.0 jig/l Methylene chloride BRL 10.0 jig/I Naphthalene BRL 1.0 jg/I n-Propylbenzene BRL 1.0 jg/I Styrene BRL 1.0 Pg/l 1.i.1,.2-Tetrachloroethane BRL 1.0 jg/I I.1.2,2-Tetrachloroethane BRL 1.0 jg/I Tetrachloroethene BRL 1.0 jg/I Toluene BRL 1.0 PgI 1.2,3-Trichlorobenzene BRL 1.0 jg/l 1.2,4-Trichlorobenzene BRL 1.0 jig/I I.ll.lTrichloroethane BRL 1.0 jg/I I, 1,2-Trichloroethane BaL 1.0 PgI Trichloroethene BRL 1.0 jg/I Trichlorofluoromethane (Freon 11) BaL 1.0 jg/I 1,2.3-Trichloropropane BRL 1.0 jg/I i ,2,4-Trimethylbenzene BRa 1.0 jg/I 1.3.5-Trimethyibenzene BRL 1.0 jg/l Vinyl chloride BaL 1.0 jIg/

m,p-Xylene BaL 2.0 jgA o-Xylene BRL 1.0 uPg/

Surrogate:4-Bromofluorobenzene 50.6 Pg/I 50.0 101 70.130 Surrogate: Toluene-d8 49.3 Pg/l 50.0 98.6 70-130 Surrogate: 1,2-Dichloroethane-d4 51.4 jig/S 50.0 103 70-130 Surrogate:Dibromofluoromethane 49.6 pg/I 50.0 99.2 70-130 LCS (5101534-BSI) Prepared & Analyzed: 25-Oct-05 Acetone 12.5 Pg/l 20.0 62.5 0.671-198 Acrylonitrile 21.1 pg/I 20.0 106 70-130 Benzene 20.1 pg/I 20.0 100 70-130 Bromobenzene 22.6 Pg/l 20.0 113 70-130 Bromochloromethane 21.0 pg/I 20.0 105 70-130 Bromodichloromethane 22.1 pg/I 20.0 110 70-130 Bromoform 21.2 Pg/l 20.0 106 70-130 Bromomethane 25.6 Pg/I 20.0 128 64.5-146 2-Butanone (MEK) 14.3 Pg/I 20.0 71.5 14.3-172 n-Butylbenzene 20.4 Pg/l 20.0 102 70-130 sec-Butylbenzene 22.7 Pg/I 20.0 114 70-130 tert-Butylbcnzene 22.8 ig/I 20.0 114 70-130 Carbon disulfide 19.5 jig/l 20.0 97.5 70-130 Carbon tetrachloride 21.6 Pg/l 20.0 108 70-130 Chlorobenzene 21.8 Pg/I 20.0 109 70-130 Chloroethane 22.0 Pg/I 20.0 110 66.3-135 Chloroform 21.5 Pg/I 20.0 108 70-130 Chloromethane 25.5 Pg/I 20.0 128 70-130 This laboratoryreportIs not valid without an authorizedsignatureon the cover page.

  • Reportable Detection Limit BRL = Below Reporting Limit Page 27 of 31

Volatile Organic Compounds - Quality Control Spike Source %REC RPD Analyte(s) Result *RDL Units Level Result %REC Limits RPD Limit Flag Batch 5101534 - SW846 5030 Water MS LCS (5101534-BS1) Prepared & Analyzed: 25-Oct-05 2-Chlorotoluene 21.7 Pg/I 20.0 108 70-130 4-Chlorotoluene 21.6 pg/l 20.0 108 70-130 1,2-Dibromo-3-chloropropane 19.9 Pg/I 20.0 99.5 70-130 Dibromochloromethane 21.1 Pg/I 20.0 106 52.9-141 1,2-Dibromoethane (EDB) 20.4 Pg/I 20.0 102 70-130 Dibromomethane 20.1 Pg/I 20.0 100 70-130 1,2-Dichlorobenzene 21.8 pg/I 20.0 109 70-130 1,3-Dichlorobenzene 23.6 Pg/I 20.0 118 70-130 1,4-Dichlorobenzene 21.5 pg/I 20.0 108 70-130 Dichlorodifluoromethane (Freon 12) 27.2 Pg/I 20.0 136 50.5-203 1,1-Dichloroethane 20.8 Pg/I 20.0 104 70-130 1,2-Dichlorocthane 20.9 pg/I 20.0 104 70-130 1.1-Dichloroethene 21.2 ;1g/I 20.0 106 70-130 cis-l ,2-Dichloroethene 21.1 20.0 106 70-130 trans-l,2-Dichloroethene 20.2 pg/I 20.0 101 70-130 1,2-Dichloropropane 20.4 pg/I 20.0 102 70-130 1.3-Dichloropropane 20.1 pg/I 20.0 100 70-130 2,2-Dichloropropane 19.0 pg/I 20.0 95.0 70-130 1.1-Dichloropropene 21.0 Pg/I 20.0 105 70-130 cis-1,3-Dichloropropene 20.3 20.0 102 70-130 trans-I,3-Dichloropropene 20.6 pg/I 20.0 103 70-130 Ethylbenzene 21.7 pg/I 20.0 108 70-130 Hexachlorobutadient 24.0 pg/I 20.0 120 68.9-138 2-Hexanone (MBK) 14.3 pg/I 20.0 71.5 70-130 Isopropylbcnzene 21.3 jig/I 20.0 106 70-130 4-Isopropyltoluene 21.8 pg/I 20.0 109 70-130 Methyl tert-butyl ether 19.9 pg/I 20.0 99.5 70-130 4-Methyl-2-pentanone (MIBK) 15.4 pg/I 20.0 77.0 51.5-134 Methylene chloride 20.7 Pg/I 20.0 104 70-130 Naphthalene 20.8 Pg/i 20.0 104 70-130 n-Propylbcnzene 21.1 pig/I 20.0 106 70-130 Styrene 22.2 pg/I 20.0 111 70-130 1,1,1.2-Tetrachloroethane 23.2 Pg/I 20.0 116 70-130 I,.,2,2-Tetrachloroethane 20.1 20.0 100 70-130 Tetrachloroethene 22.1 pg/I 20.0 110 70-130 Toluene 20.9 pg/I 20.0 104 70-130 1.2,3-Trichlorobenzene 21.2 p1g/I 20.0 106 70-130 1.2,4-Trichlorobenzene 21.0 pg/I 20.0 105 70-130 I,1,-Trichloroethane 21.6 pg/I 20.0 108 70-130 I,1,2-Trichlorocthane 20.5 pg/I 20.0 102 70-130 Trichloroethene 20.3 pg/I 20.0 102 70-130 Trichlorofluoromethane (Freon 11) 23.1 pg/I 20.0 116 70-143 1,2,3-Trichloropropane 20.4 pg/I 20.0 102 70-130 1.2,4-Trimethylbenzene 22.5 ig/I 20.0 112 70-130 1,3,5-Trimethylbenzene 22.4 pg/I 20.0 112 70-130 Vinyl chloride 25.4 Pg/l 20.0 127 70-130 m,p-Xylene 44.7 pg/I 40.0 112 70-130 o-Xylene 22.9 pg/I 20.0 114 70-130 Surrogate: 4-Bromofluorobenzene 52.2 pg/I 50.0 104 70-130 Surrogate: Toluene-d8 48.3 Pg/I 50.0 96.6 70-130 Surrogate: 1,2-Dtchloroethane-d4 50.6 pg/I 50.0 101 70-130 Surrogate:Dibromofluoromethane 48.9 pg/I 50.0 97.8 70-130 LCS Dup (5101534-BSD1) Prepared & Analyzed: 25-Oct-05 Acetone 14.3 pgA 20.0 71.5 0.671-198 13.4 50 This laboratory report Is not valid without an authorizedsignatureon the cover page.

  • Reportable Detection Limit BRL = Below Reporting Limit Page 28 of 31

Volatile Organic Compounds - Quality Control Spike Source %RBC RPD Analyte(s) Result *RDL Units Level Result %REC Limits RPD Limit Flag Batch 5101534 - SW846 5030 Water MS LCS Dup (5101534-BSDI) Prepared & Analyzed: 25-Oct-05 Acrylonitrile 21.4 Pg/I 20.0 107 70-130 0.939 25 Benzene 18.8 Pg/I 20.0 94.0 70-130 6.19 25 Bromobenzene 21.4 Pg/I 20.0 107 70-130 5.45 25 Bromochloromethane 20.5 pg/I 20.0 102 70-130 2.90 25 Bromodichloromethane 20.9 pg/I 20.0 104 70-130 5.61 25 Bromoform 20.8 Pg/I 20.0 104 70-130 1.90 25 Bromomethane 23.2 Pg/I 20.0 116 64.5-146 9.84 50 2-Butanone (MEK) 14.1 Ag/I 20.0 70.5 14.3-172 1.41 50 n-Butylbenzene 18.8 Pg/I 20.0 94.0 70-130 8.16 25 sec-Butylbenzene 21.0 Pg/I 20.0 105 70-130 8.22 25 tert-Butylbenzene 21.4 Pg/I 20.0 107 70-130 6.33 25 Carbon disulfide 17.6 Pg/I 20.0 88.0 70-130 10.2 25 Carbon tetrachloride 20.2 Pg/I 20.0 101 70-130 6.70 25 Chlorobenzene 20.5 Pg/I 20.0 102 70-130 6.64 25 Chloroethane 19.9 Wg/ 20.0 99.5 66.3-135 10.0 50 Chloroform 20.5 Pg/I 20.0 102 70-130 5.71 25 Chloromethane 23.0 Pg/I 20.0 115 70-130 10.7 25 2-Chlorotoluene 19.6 Pg/I 20.0 98.0 70-130 9.71 25 4-Chlorotoluene 20.2 Wg/ 20.0 101 70-130 6.70 25 1,2-Dibromo-3-chloropropane 12.6 Pg/I 20.0 63.0 70-130 44.9 25 QR-02 Dibromochloromethane 20.9 pg/I 20.0 104 52.9-141 1.90 50 1,2-Dibromoethane (EDB) 20.7 pg/I 20.0 104 70-130 1.94 25 Dibromomethane 19.8 pg/I 20.0 99.0 70-130 1.01 25 1,2-Dichlorobenzene 20.5 pg/I 20.0 102 70-130 6.64 25 1,3-Dichlorobenzene 22.3 pg/I 20.0 112 70-130 5.22 25 1,4-Dichlorobenzene 20.1 Pg/I 20.0 100 70-130 7.69 25 Dichlorodifluoromethane (Freonl2) 25.8 Pg/I 20.0 129 50.5-203 5.28 50 I,1-Dichloroethane 19.3 Pg/I 20.0 96.5 70-130 7.48 25 1,2-Dichloroethane 20.8 Pg/I 20.0 104 70-130 0.00 25 II-Dichloroethene 19.5 pgA 20.0 97.5 70-130 8.35 25 cis-1,2-Dichloroethene 20.0 pg/I 20.0 100 70-130 5.83 25 trans- 1.2-Dichloroethene 18.5 Pg/I 20.0 92.5 70-130 8.79 25 1.2-Dichloropropane 19.3 Ag/I 20.0 96.5 70-130 5.54 25 1.3-Dichloropropane 20.1 Pg/I 20.0 100 70-130 0.00 25 2,2-Dichloropropane 17.8 Pg/I 20.0 89.0 70-130 6.52 25 Il-Dichloropropene 19.3 20.0

  • 96.5 70-130 8.44 25 cis- 1.3-Dichloropropene 19.6 pg/I 20.0 98.0 70-130 4.00 25 trans-l ,3-Dichloropropene 19.9 Pg/I 20.0 99.5 70-130 3.46 25 Ethylbenzene 20.1 20.0 100 70-130 7.69 25 Hexachlorobutadiene 22.2 pg/I 20.0 111 68.9-138 7.79 50 2-Hexanone (MBK) 14.4 20.0 72.0 70-130 0.697 25 Isopropylbenzene 19.9 pg/I 20.0 99.5 70-130 6.33 25 4-Isopropyltoluene 20.3 pg/I 20.0 102 70-130 6.64 25 Methyl tert-butyl ether 20.0 pg/I 20.0 100 70-130 0.501 25 4-Methyl-2-pentanone (MIBK) 16.3 Pg/I 20.0 81.5 51.5-134 5.68 50 Mcthylene chloride 20.1 Pg/I 20.0 100 70-130 3.92 25 Naphthalene 15.2 Pg/I 20.0 76.0 70-130 31.1 25 QR-02 n-Propylbenzene 20.0 20.0 100 70-130 5.83 25 Styrene 20.8 Pg/I 20.0 104 70-130 6.51 25 1,1,1.2-Tetrachloroethane 21.9 Pg/I 20.0 110 70-130 5.31 25 1,1,2,2-Tetrachloroethane 12.2 20.0 61.0 70-130 48.4 25 QC-I Tetrachloroethene 20.6 pg/I 20.0 103 70-130 6.57 25 Toluene 19.5 Pg/I 20.0 97.5 70-130 6.45 25 1,2,3-Trichlorobenzene 20.2 pg/I 20.0 101 70-130 4.83 25 This laboratoryreport is not valid without an authorized signatureon the coverpage.
  • Reportable Detection Limit BRL = Below Reporting Limit Page 29 of 31

Volatile Organic Compounds - Quality Control Spike Source %REC RPD Analyte(s) Result *RDL Units Level Result %REC Limits RPD Limit Flag Batch 5101534 - SW846 5030 Water MS LCS Dup (5101534-BSDI) Prepared & Analyzed: 25-Oct-05 1,2,4-Trichlorobenzene 19.8 pg/I 20.0 99.0 70-130 5.88 25 11,1-Trichloroethane 19.9 pg/I 20.0 99.5 70-130 8.19 25 1,1,2-Trichloroethane 21.0 pg/1 20.0 105 70-130 2.90 25 Trichloroethene 22.4 pg/I 20.0 112 70-130 9.35 25 Trichlorofluoromethane (Freon 11) 21.8 pg/I 20.0 109 70-143 6.22 50 1,2,3-Trichloropropane 20.6 pg/I 20.0 103 70-130 0.976 25 1,2,4-Trimethylbenzcne 21.0 pg/I 20.0 105 70-130 6.45 25 1,3,5-Trimethylbenzene 21.0 pg/l 20.0 105 70-130 6.45 25 Vinyl chloride 23.6 pg/I 20.0 118 70-130 7.35 25 m,p-Xylene 41.2 pg/I 40.0 103 70-130 8.37 25 o-Xylene 21.4 pg/l 20.0 107 70-130 6.33 25 Surrogate: 4-Bromofluorobenzene 52.3 pg/li 50.0 105 70-130 Surrogate: Toluene-d8 48.6 pg/li 50.0 97.2 70-130 Surrogate: 1,2-Dichloroethane-d4 52.7 pg/I 50.0 105 70-130 Surrogate: Dibromofluoromethane 49.1 pg/i 50.0 98.2 70-130 Matrix Spike (5101534-MSI) Source: SA36008-02 Prepared: 25-Oct-05 Analyzed: 26-Oct-05 Benzene 23.6 pg/I 20.0 BRL 118 70-130 Chlorobenzene 24.8 pg/I 20.0 BRL 124 70-130 1,1-Dichloroethene 23.4 pg/I 20.0 BRL 117 70-130 Toluene 24.5 pg/I 20.0 BRL 122 70-130 Trichloroethene 24.0 pg/I 20.0 BRL 120 70-130 Surrogate: 4-Bromofluorobenzene 51.2 pg/I 50.0 102 70-130 Surrogate: Toluene-d8 50.2 pg/l 50.0 100 130 Surrogate: 1.2-Dckhloroethane-d4 56.6 pg/I 50.0 113 70-130 Surrogate: Dibromofluoromethane 53.5 pg/l 50.0 107 70-130 Matrix Spike Dup (5101534-MSDI) Source: SA36008-02 Prepared: 25-Oct-05 Analyzed: 26-Oct-05 Benzene 23.3 pg/I 20.0 BRL 116 70-130 1.71 30 Chlorobenzene 24.9 pg/I 20.0 BRL 124 70-130 0.00 30 1,1-Dichloroethene 25.3 pg/I 20.0 BRL 126 70-130 7.41 30 Toluene 24.3 pg/A 20.0 BRL 122 70-130 0.00 30 Trichloroethene 24.4 pg/l 20.0 BRL 122 70-130 1.65 30 Surrogate:4-Bromofluorobenzene 51.44 Pg/I 50.0 103 70-130 Surrogate:Toluene-d8 50.' 50.0 100 70-130 Surrogate: 1,2-Dtchloroethane-d4 53.: 2 pg/ 50.0 106 70-130 Surrogate:Dibromofluoromethane 50. 7 Pg/I 50.0 101 70-130 This laboratoryreport Is not valid without an authorized signature on the cover page.

  • Reportable Detection Limit BRL - Below Reporting Limit Page 30 of 31

Notes and Definitions QC-1 Analyte out of acceptance range.

QM-07 The spike recovery was outside acceptance limits for the MS and/or MSD. The batch was accepted based on acceptable LCS recovery.

QR-02 The RPD result exceeded the QC control limits; however, both percent recoveries were acceptable. Sample results for the QC batch were accepted based on percent recoveries and completeness of QC data.

VOCI I Analyte presence was confirmed by duplicate analysis.

BRL Below Reporting Limit - Analyte NOT DETECTED at or above the reporting limit dry Sample results reported on a dry weight basis NR Not Reported RPD Relative Percent Difference A plus sign (+) in the Method Reference column indicates the method is not accredited by NELAC.

Laboratory Control Sample (LCS): A known matrix spiked with compound(s) representative of the target analytes, which is used to document laboratory performance.

Matrix Duplicate: An intra-laboratory split sample which is used to document the precision of a method in a given sample matrix.

Matrix Spike: An aliquot of a sample spiked with a known concentration of target analyte(s). The spiking occurs prior to sample preparation and analysis. A matrix spike is used to document the bias of a method in a given sample matrix.

Method Blank: An analyte-free matrix to which all reagents are added in the same volumes or proportions as used in sample processing. The method blank should be carried through the complete sample preparation and analytical procedure. The method blank is used to document contamination resulting from the analytical process.

Method Detection Limit (MDL): The minimum concentration of a substance that can be measured and reported with 99%

confidence that the analyte concentration is greater than zero and is determined from analysis of a sample in a given matrix type containing the analyte.

Reportable Detection Limit (RDU: The lowest concentration that can be reliably achieved within specified limits of precision and accuracy during routine laboratory operating conditions. For many analytes the RDL analyte concentration is selected as the lowest non-zero standard in the calibration curve. While the RDL is approximately S to 10 times the MDL, the RDL for each sample takes into account the sample volume/weight, extract/digestate volume, cleanup procedures and, if applicable, dry weight correction.

Sample RDLs are highly matrix-dependent.

Surrogate: An organic compound which is similar to the target analyte(s) in chemical composition and behavior in the analytical process, but which is not normally found in environmental samples. These compounds are spiked into all blanks, standards, and Validated by:

Hanibal C. Tayeh, Ph.D.

Nicole Brown This laboratoryreport is not valid without an authorizedsignature on the cover page.

  • Reportable Detection Limit BRL - Below Reporting Limit Page 31 of 31

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APPENDIX D GRAPHS

Chart I Selected Contaminant Concentrations and Groundwater Elevation Over Time at Monitoring Well MW-I 10,000 186 185 1,000--

16.

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Chart 2 Selected Contaminant Concentrations and Groundwater Elevations Over Time at Monitoring Well MW-6 10,000 186 185

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Chart 3 Selected Contaminant Concentrations and Groundwater Elevation Over Time at Monitoring Well MW-8 10,000 186 185 1,000

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Chart 4 PCE Concentration and Groundwater Elevation Over Time at Monitoring Well MW-2 25 186 185 20 CL 184 15 E

2 co 2 183 0 LU 0

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Chart 5 PCE Concentration and Groundwater Elevation Over Time at Monitoring Well MW-7 25 186.00 185.00 20 I--

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Date I -- o - PCE - A-- Groundwater elevation I PFdatalprotedtsN04-20 1000 to 201 500\04-20121 5 VYNPC No.2 OifTsbfesGraphsffw?