ML050870442
| ML050870442 | |
| Person / Time | |
|---|---|
| Site: | Haddam Neck File:Connecticut Yankee Atomic Power Co icon.png |
| Issue date: | 02/18/2005 |
| From: | Keyes C, Wager J Connecticut Yankee Atomic Power Co |
| To: | Document Control Desk, NRC/FSME |
| References | |
| CY-05-040 9524-0000 | |
| Download: ML050870442 (145) | |
Text
-I I-I Ie
-II Final Status Survey Final Report Phase 11 Appendix A2 Survey Unit Release Record 9524-0000, South Site Grounds February 2005 m
CYAPCO FINAL STATUS SURVEY RELEASE RECORD SOUTH SITE GROUNDS SURVEY UNIT 9524-0000 7/
Prepared By:
Date:-25a.-
FSS Engineer Reviewed Bum Approved By:
FSS Pro ead Em Date:-)'-\\ IL Date:
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SOUTH SITE GROUNDS SURVEY UNIT 9524-0000 RELEASE RECORD TABLE OF CONTENTS
- 1.
SURVEY UNIT DESCRIPTION.............................
3
- 2.
CLASSIFICATION BASIS..............................
3
- 3.
DATA QUALITY OBJECTIVES (DQO)...............................
5
- 4.
SURVEY DESIGN..............................
6
- 5.
SURVEY IMPLEMENTATION..............................
10
- 6.
SURVEY RESULTS.............................
11
- 7.
QUALITY CONTROL..............................
13
- 8.
INVESTIGATIONS AND RESULTS.............................
14
- 9.
REMEDIATION AND RESULTS..............................
14
- 10. CHANGES FROM THE FINAL STATUS SURVEY PLAN.
14
- 11. DATA QUALITY ASSESSMENT (DQA).14
- 12. ANOM ALIES........................................................................................ 15
- 13. CONCLUSION.15
- 14. ATTACHMENTS.16 14.1 Attachment 1 - Figures (7 pages including cover) 14.2 Attachment 2-Sample and Statistical Data (121 pages including covers)
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SOUTH SITE GROUNDS SURVEY UNIT 9524-0000 RELEASE RECORD
- 1.
SURVEY UNIT DESCRIPTION Survey Unit (SU) 9524-0000, (South Site Grounds) is designated as Final Status Survey (FSS) Class 3 and consists of approximately 61,974.8 m2 (15.3 acres) of uninhabited, undeveloped land located about a 0.85 miles from the center of the Haddam Neck Plant (HNP) Containment Building (see Attachment 1-Figure 1).
The survey unit is an open space with little or no obstructions. Most of the area consisted of ancient glacial sand dunes that were mined during the construction of the HNP. Glacial till and occasional rock masses containing naturally occurring radioactive minerals have been identified during trenching. Survey Unit 9524-0000 is bounded to the north by SU 9528, to the east the Salmon
.River, and to the south SU 9523. The South Site Grounds also acts as a buffer zone for several survey areas with more restrictive classification designations.
Four (4) survey units are situated interior of this unit, SU 9535, 9536, 9537 and 9538. The area topography is a small-elevated saddle situated between two hills that slope downward towards the wetlands associated with the Salmon River.
The area was excavated and reshaped over the years for various reasons.
The reference coordinates associated with SU 9524-0000 are E010 through E021 by S116 through S172 (see License Termnination Plan Section 5.4.4). The reference coordinates provide the maximum dimensions of a rectangle containing this survey unit. Some areas contained in this rectangle may not be part of this survey unit. The boundary of the survey unit was defined using a Global Positioning System (GPS).
The historic files indicate that this area was originally wooded then cleared during construction of the HNP. Sand and fill materials were taken from the area and eventually backfilled with construction debris placed in the area for disposal. The South Site Grounds contained the former shotgun range and pistol/rifle range that was used from the late 1960s, when the plant opened, through 1997.
Hazardous materials related to the shooting range, construction materials, debris and spoils were removed from the area prior to FSS. This activity and the materials removal disturbed the soil down to two (2) meters in depth. Portions of the area were backfilled, graded and seeded for erosion control.
- 2.
CLASSIFICATION BASIS The survey unit was classified in accordance with Procedure RPM 5.1-10, "Survey Unit Classification." The historical information and scoping results provide sufficient data to designate SU 9524-0000 as Class 3 in April 2004.
The "Classi~tication Basis Summary" conducted for SU 953 8-0000 consisted of:
a) A review of the 10CFR50.75 (g) (1) database, b) A review of the "Initial Characterization Report" and "Historic Site Assessment Supplement, "
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SOUTH SITE GROUNDS SURVEY UNIT 9524-0000 RELEASE RECORD c) Historic and current survey records review, d) Personal interviews, e) Visual inspections and a "walk down."
A review of the IOCFR50.75 (g) (1) database report identified one document HP99-057 associated with this survey area described the addition of a monitoring well with survey results indicating no plant related activity in the soil or water.
Current survey records were reviewed. Two (2) scoping surveys were noted.
Both surveys (SSWP N2. BCY-SSWP-03-08-002 and SSWP X2. BCY-SSWP-03-10-002) indicated Cs-137 levels less than background as reported in Health Physics Technical Support Document (TSD) BCY-HP-0063, "Background Cs-137 Concentration in Soil."
A review of the "Initial and Supplemental Characterization Reports " as well as the previous "Classification Basis Summaries" provided no additional information pertinent to classification.
To obtain the necessary data of sufficient data quality for FSS planning purposes, two (2) work plans were developed and implemented during August and October 2003. Twenty (20) biased samples were obtained throughout SU 9524-0000. The mean value of the samples taken for classification did not exceed 3% of the Cs-137 Administrative Level Derived Concentration Guideline Level (DCGL) (see Table 1). One classification sample in this set contained a maximum Cs-137 concentration of 0.415 pCi/g, or 13% of the Base Case DCGL for Cs-137. It was unlikely that the aggregate concentration of the other nineteen (19) radionuclides listed in Table 2 would be identified or exceeds 10% of the Administrative Level DCGL. The concentrations of Cs-137 found in the soil were below those concentrations determined from off-site locations as documented by Health Physics TSD BCY-HP-0063.
Table 1 - Basis Statistical Quantities for Cesium-137 from the Characterization Survey Parameter.
Cesium-137 (pCi/g)
Minimum Value:
-0.006 Maximum Value:
0.415 Mean:
0.088 Median:
0.034 Standard Deviation:
0.122 No formal interviews were conducted.
The FSS Engineer performed a visual inspection and walk down during April 2004. By this time, all RCRA remediation and material removal projects had Revision I 4
SOUTH SITE GROUNDS SURVEY UNIT 9524-0000 RELEASE RECORD been completed. The classification process continues to support the original Class 3 designation.
At the time of FSS, the dose impact from groundwater contamination was not considered. However, spoils from Monitoring Well MW207 were analyzed with no activity identified other than naturally occurring radionuclides. Survey Areas 9535, 9536, 9537, and 9538 were separated from this Survey Area and classified Class 1 and Class 2. A large section of this survey unit was split off and added to Area 9523 to facilitate the construction of the Independent Spent Fuel Storage Installation (ISFSI) pad and access road. The classification basis shows that the expected residual radioactivity in the survey unit would be below the site remediation criteria and are consistent with procedural guidance, thereby sufficient to justify final designation as Class 3.
- 3.
DATA QUALITY OBJECTIVES (DQO)
The primary objective of the Final Status Survey Plan (FSSP) was to demonstrate that the level of residual radioactivity in Survey Unit 9524-0000 did not exceed the release criteria specified in the License Termination Plan (LTP), was below the 10 mrem/yr Administrative Level DCGLs, and that the potential dose from residual radioactivity is As Low As Reasonably Achievable (ALARA).
FSS design and planning endorsed the use of the Data Quality Objective (DQO) process as described by the LTP, Procedure RPM 5.1 - 11, "Preparation of Final Status Survey Plan, "
and the "Multi-Agency Radiation Survey and Site Investigation Manual" (MARSSIM). A summary of the main features of the DQO process are provided herein.
The DQO process incorporated hypothesis testing and probabilistic sampling distributions to control decision errors during data analysis. Hypothesis testing is a process based on the scientific method that compares a baseline condition to an alternate condition. The baseline condition is technically known as the null hypothesis. Hypothesis testing rests on the premise that the null hypothesis is true and that sufficient evidence must be provided for rejection. In designing the survey plan, the underlying assumption, or null hypothesis was that residual activity in the survey unit exceeded the release criteria. Rejection of the null hypothesis would satisfy the release criteria objective of the FSS.
The DQO process determined that Cs-137 would be the radionuclide of concern during the 9524-0000 FSS process. Additionally, to provide conservatism, the Base Case DCGLs for radionuclides in soil was reduced by 60% to establish the Administrative Level DCGL.
Instrument DQOs included a verification of the ability of the survey instrument to detect the radiation(s) of interest relative to the DCGL. Survey instrument response checks were performed before issue and after the instrument had been Revision l 5
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SOUTH SITE GROUNDS SURVEY UNIT 9524-0000 RELEASE RECORD used.
Control and accountability of survey instruments were maintained to assure the quality and prevent the loss of data.
Laboratory DQOs and analysis results were reported as actual calculated results.
Results reported as less than Minimum Detectable Concentration (<MDC) would not be accepted for FSS. Sample report summaries included unique sample identification, analytical method, radionuclide, result and uncertainty of two standard deviations (2a), laboratory data qualifiers, units and the required and observed MDC (Table 2).
Table 2 - FSS DCGL Values and Required Minimum Detectable Concentrations Radionuclide Base Case Soil Administrative Level Required MDC DCGL (pCiIg) (1)
DCGL (pCi/9)
(pCi/g) (3)
H-3 4.12E+02 1.65E+02 1.6513+01 C-14 5.66E+00 2.2613+00 2.26E-01 Mn-54 1.74E+01 6.96E+00 6.96E-O1 Fe-55 2.7413+04 I.1.OE+04 1.1013+03 Co-60 3.81 E+00 1.52E+00 1.5213-01 Ag-108m 7.14E+00 2.8613+00 2.8613-01 Ni-63 7.23E+02 2.8913+02 2.8913+01 Sr-90 1.55E+0O 6.2013-01 6.20E-02 Nb-94 7.12E+00 2.8513+00 2.85E-01 Tc-99 1.2613+01 5.04E+00 5.0413-01 Cs-134 4.6713+00 1.8713+00 1.87E-01 Cs-137 7.91 E+00 3.1613+00 3.16E-01 Eu-152 1.011E+01 4.0413+00 4.04E-01 Eu-154 9.2913+00 3.7213+00 3.7213-01 Eu-155 3.92E+02 1.5713+02 1.5713+01 Pu-238 2.96E+01 1.18E+01 1.1813+00 Pu-239/240 2.67E+01 1.07E+01 1.07E+00 Pu-241 8.7013+02 3.4813+02 3.48E+01 Am-241 2.58E+01 1.0313+01 1.0313+00 Cm-243/244 2.90E+01 1.16E+01 1.1613+00 (1) The Base Case DCGLs for soil are specified by the LTP in Chapter 6.
(2) The Administrative Level DCGL is 40% of the Base Case DCGL.
(3) The required MDC was 10% of the Administrative Level DCGL.
- 4.
SURVEY DESIGN The level of effort associated with planning a survey is based on the complexity of the survey and nature of the hazards. To assist the FSS Engineers when preparing survey plans for FSS, guidance is provided in Procedure RPM 5. 1-11.
By design, the FSSP meets the ALARA criteria for soils as specified in Chapter 4 of the LTP.
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SOUTH SITE GROUNDS SURVEY UNIT 9524-0000 RELEASE RECORD The LTP specifies that the selection of the scan area size is judgmental for Class 3 areas. The fraction of scanning coverage was determined during the DQO process with the total amount, and location(s) based on the likelihood of finding elevated activity during FSS. Based on conditions found during the area inspection tours, four (4) areas, totaling 1,949.8 m2 the SU surface area, were selected for scanning in SU 9524-0000. Four (4) areas were chosen for scanning based on proximity to Class 1 and 2 areas and excavation activities.
Scans were also prescribed for a one (1) meter radius around each random and biased Sample Measurement Location (SML).
During the characterization and classification surveys conducted in 2003, only Cs-137 was identified in nine (9) of the twenty (20) samples collected. This data, presented in Table 1, was used to determine the radiological concentration variability Radionuclide-specific analyses of soil samples collected from this survey unit and adjacent land areas with similar history and physical characteristics have identified principally Cs-137. The data collected prior to FSS indicated that the remaining radionuclides listed in Table 2 would not be present in quantities greater than 5% of the applicable Base Case DCGL in this survey unit at the time of FSS. It was unlikely that the aggregate concentration of the remaining radionuclides would exceed 10% of the DCGL; therefore, only Cs-137 was used in the survey planning of SU 9524-0000. The use of the 5% and 10% rule is consistent with the development of surrogate ratio DCGLs as described in the LTP.
The DQO process determined that Cs-137 would be the radionuclide of concern during the 9524-0000 FSS process. The Operation DCGL of 3.16 pCi/g for Cs-137 was used to demonstrate compliance with the release criteria.
Surrogate DCGLs are not required for this survey unit because of the radionuclide specific analysis and radionuclide de-selection in accordance with the 5% and 10% rule.
The Elevated Measurement Comparison (EMC) does not apply to this survey unit since discrete, elevated areas of contamination are not expected.
The Sign Test was selected as the non-parametric statistical test. The use of the Sign Test did not require the selection or use of a background reference area, which simplified survey design and implementation.
This approach was conservative since it included background Cs-137 as part of the sample set.
The number of soil samples for FSS was determined in accordance with Procedure RPM 5.1-12, "Determination of the Number of Surface Samples for FSS. " Survey design specified fifteen (15) surface soil samples for the Sign Test non-parametric statistical testing.
For the FSS, six (6) biased soil SMLs were selected in the area where soil was either removed or added to backfill trenches excavated for the material removal project. Two (2) additional biased soil SMLs were selected "at depth" Revision 1 7
SOUTH SITE GROUNDS SURVEY UNIT 9524-0000 RELEASE RECORD from locations closest to the area of disturbance following the collection of surface samples. These samples will be collected from a horizontal profile to a dept of 2 meters, which is the assumed depth of soil disturbance.
Although Procedure RPM 5.1-11 only specified that 5% of the samples be selected for Hard-to-Detect (HTD) analysis, two (2) soil samples or 13% were randomly selected for HTD radionuclide analysis by using the Microsoft Excel "RANDBETWEEN" function. Each sample will be sent for a full suite analysis of the HTD radionuclides specified in the LTP, Table 2-12, "Radionuclides Potentially Present at Haddam Neck Plant."
The implementation of survey specific quality control measures as referenced by Procedure RPM 5.1-24, "Split Sample Assessment for Final Status Survey, "
included the collection of two (2) soil samples for "split sample" analysis by the off site laboratory. These locations were selected randomly using the Microsoft Excel "RANDBETWEEN" function.
The number of quality control soil samples was determined to be 13% of seventeen (17) samples, rounded up to the next whole number.
The grid pattern and locations of the soil samples were determined using Visual Sample Plan (VSP) in accordance with Procedure RPM 5.1-14, "Identifying and Marking Surface Sample Locations for FSS. " Visual Sample Plan was created by Pacific Northwest National Laboratory (PNNL) for the United States Department of Energy. A random grid pattern with a random starting point was selected for sample design, which is appropriate for a Class 3 area.
Sample location and scan areas were identified using AutoCAD-LtD a commercially available plotting software with coordinates consistent with the Connecticut State Plane System. These coordinates were integrated with a GPS to locate sample and scan locations in the field. The SMLs for the design are listed with the GPS coordinates in Table 3.
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SOUTH SITE GROUNDS SURVEY UNIT 9524-0000 RELEASE RECORD Table 3 -Sample Measurement Locations (SML) with Associated GPS Coordinates.
Designation Northing Easting.
9524-0000-00 IF 673238.9049 236077.8409 9524-0000-002F 673135.6742 235772.5947 9524-0000-003F 673728.7060 236095.8389 9524-0000-004F 672980.3854 235831.8972 9524-0000-005F 673230.9546 235910.5774 9524-0000-006F 673191.4437 236142.2527 9524-0000-007F 673135.1205 235619.4970 9524-0000-008F 672959.5741 235802.1848 9524-0000-009F 672879.8205 235964.2611 9524-0000-01OF 673225.5406 236241.6248 9524-0000-011 F 673419.5139 236119.745 9524-0000-012F 673266.3626 236090.4119 9524-0000-013F 673370.7049 235724.5897 9524-0000-014F 673318.4618 236041.9947 9524-0000-015F 673041.82 235865.0027 For this Class 3 survey unit, the "Investigation Level" for area scanning and soil sample measurement results are those levels specified in LTP, Table 5-8, "Investigation Levels."
The Lower Bound of the Gray Region (LBGR) was adjusted in accordance with Procedure RPM 5.1-11 to 0.924 of the Operational DCGL to maintain the relative shift (A/a) in the range of I and 3. In a Class 3 survey unit the median concentration is expected to be below the LBGR; however a Prospective Power Curve was generated using the data described in this FSSP and COMPASS, a software package developed under the sponsorship of the USNRC for implementation of the MARSSIM in support of the decommissioning license termination rule (Title 10 CFR 20, Subpart E). The result of the COMPASS computer run shows adequate power for this survey design.
Table 4 provides a synopsis of the survey design.
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SOUTH SITE GROUNDS SURVEY UNIT 9524-0000 RELEASE RECORD Table 4-Synopsis of the Survey Design Feature Design Criteria -
Basis Based on AutoCAD and Survey Unit Size 61,974.8 m2 Visual Sample Plan calculations Type I (a) and Type II ()
error were 0.05; relative shift Number of Measurements 15 V)sta2bypoeu, (A/ar) set at 2 by procedure, the LBGR was set to 0.924.
Grid Spacing Random and Appropriate design for Class Random Start 3 Area.
Interval Spacing Not Applicable Not appropriate design for Class 3 random sampling DCGL 3.16 pCi/g Operational DCGL applied Cs-137 to field data ('
Based on likelihood of 1,949.8 m 2 finding elevated readings in Scan Survey Coverage (3.1%)
this particular Class 3 survey unit Detectable over Based on achieving the Scan Investigation Level background Administrative Level DCGL (I) The Operational DCGL was based on achieving an administrative level that was 40% of the soil DCGL and assuming no impact from radioactive contanination in groundwater or from buried concrete debris.
- 5.
SURVEY IMPLEMENTATION Final status survey field activities were conducted under Work Plan and Inspection Record (WP&IR) 000-GEN-9245-001056-000.
The WP&IR package included a detailed FSSP, job safety analysis, job planning checklist and related procedures for reference. Daily briefings were conducted to discuss the expectations for job performance and the safety aspects of the survey. The "Daily Survey Journal" was used to document field activities and other information pertaining to the FSS.
Survey activities occurred between May 12 and May 25, 2004.
Four (4) land areas, Scan Areas 1 through 4, were marked out using GPS coordinates consistent with the Connecticut State Plane System and scanned for elevated readings (see Attachment 2 for Scan Area Results). Scanning was performed with an Eberline E-600 using a SPA-3 sodium iodide detector. The E-600 was operated in the rate-meter mode and used with audio response. The probe was positioned as close to the ground as possible and was moved at a scan speed of about 0.5 meters per second.
Using GPS coordinates, SMLs were identified and marked with a surveyor's flag for identification. At each SML, a one (1) meter radius around the sample flag was scanned for elevated radiation levels.
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SOUTH SITE GROUNDS SURVEY UNIT 9524-0000 RELEASE RECORD Fifteen (15) surface soil samples were collected in random locations and packaged in accordance with HNP Procedure RPM 5.1-3, "Collection of Surface and Subsurface Soil, Shoreline Sedimnent, Asphalt and Liquid samples for Scoping, Characterization and Final Status Survey" and FSS design.
Samples were controlled, transported, stored, and transferred to the off site laboratory using Chain-of-Custody (COC) protocol in accordance with Procedure RPM 5.1-5, "Chain of Custody for Scoping, Characterization and Final Status Samples. "
Two (2) samples (007F and 010F) were randomly selected for HTD radionuclide analysis.
Six (6) biased samples (016F to 021F) were collected in areas where the soil appeared "disturbed" or excavated. Two (2) "at depth" samples were taken, (016FD and 017FD). Because of "resistance" to digging, sample 9524-0000-016FD was taken at a depth of five (5) feet (1.5 in); whereas, sample 9524-0000-017FD was taken at a depth of four (4) feet (1.2 in).
Two (2) "split samples" were collected at SML 009FS and 013FS for analysis.
- 6.
SURVEY RESULTS No elevated readings were identified during scanning at the SMLs. Scan Area 1 contained an area with an elevated reading, which prompted the collection of investigation samples from this area. The investigation results are discussed in Section 8 of this report. Table 5 provides a summary of the Scan Area survey.
All scan area results are provided in Attachment 2.
Table 5-Scan Area Results Highest Scan Logged Investigation Elevated Investigation Area'Raig ee Reading Sample (MDC-cpm)
Identification 1
8010 8389 16900 8617 ER-0001 9524-0000-0221 8040 8140 2
6800 6832 8270 9363 3
8450 9114 8670 9028 4
8510 88232 8010 8422-Revision 1 11
SOUTH SITE GROUNDS SURVEY UNIT 9524-0000 RELEASE RECORD The off site laboratory employed for the radiological analyses of samples was General Engineering Laboratories-LLC; Charleston, South Carolina. The laboratory analyzed the fifleen (15) samples taken for non-parametric statistical testing, the associated duplicates, biased and scan area samples using gamma spectroscopy.
Gamma spectroscopy analysis was performed to the required MDC.
Cesium-137 was the only gamma-emitting radionuclides detected at statistically significant concentrations and in most cases greater than the MDC.
The results of gamma spectrometry analysis for a majority of the samples indicated Cs-137 at or below levels consistent with concentrations of Cs-137 found in soil at offsite locations within the vicinity of the HNP. A summary of the sample results is provided in Table 6.
Table 6-Summa of Soil Sample Results Sample Number Cs-137 f-DCGL (l)
P C ilg 9524-0000-001F 0.0161 0.005 9524-0000-002F 0.0204 0.006 9524-0000-003F 0.392 0.124 9524-0000-004F 0.646 0.204 9524-0000-005F 0.0465 0.0 15 9524-0000-006F 0.103 0.033 9524-0000-007F 0.0333 0.011 9524-0000-008F 0.607 0.192 9524-0000-009F 0.192 0.061 9524-0000-01OF 0.0768 0.024 9524-0000-01IF
-0.00595 0
9524-0000-012F 0.0137 0.004 9524-0000-013F 0.378 0.120 9524-0000-014F 0.0651 0.021 9524-0000-015F 0.042 0.013 (I) f-DCGL-raction of the Administrative Level DCGL The offsite laboratory processed two (2) samples for HTD analysis as required by the sample plan, 9524-0000-007F and 01OF. The requested analyses included alpha spectroscopy, gas proportional counting and liquid scintillation depending on the radionuclide and the measurement method. In both samples, Sr-90 was the only HTD listed above the lab reported MDC. Table 7 lists all radionuclides found in the analysis of 007F and OIOF, greater than two standard deviations (2u), as a fraction of the Administrative Level DCGL. In total with all other radionuclides detected, the f-DCGL for sample 007F is 0.063 or 6.3% of the 10 mrem/yr Administrative Level DCGL (see Table 6 and 7). No further action or investigations were required.
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SOUTH SITE GROUNDS SURVEY UNIT 9524-0000 RELEASE RECORD Table 7-Hard-to-Detect Sample Results pCi/g Sample Number C-14 lSr-90 f-DCGL(')
9524-0000-007F l 0.0328 0.052 9524-0000-OlOF 0.172 0.045 0.14 (I) f-ICGLfraction of the Administrative Level DCGL The offsite laboratory analyzed the six (6) biased samples and the two (2) "at depth" (D) samples using gamma spectroscopy. Gamma spectroscopy analysis was performed to the required MDC. The results of gamma spectrometry analysis for a majority of the samples indicated only Cs-137 at levels consistent with concentrations of Cs-137 found in soil at offsite locations within the vicinity of the HNP. The highest f-DCGL in the sample set was 0.269 or 27% of the Administrative Level DCGL, well below any investigation level. No further action or investigations were required (see Table 8).
Table 8-Biased Sample Results Sample Number Cs-137 f-DCGL()l 9524-0000-016F 0.00124 0.0004 9524-0000-016FD 0.0 0
9524-0000-017F 0.0162 0.0051 9524-0000-017FD 0.0826 0.0261 9524-0000-018F 0.12 0.0380 9524-0000-019F 0.116 0.0367 9524-0000-020F 0.853 0.2699 9524-0000-021 F 0.022 0.0070 (1) f-DCGL-fraction of the Administrative Level DCGL
- 7.
QUALITY CONTROL The off site laboratory processed the split samples and performed gamma spectroscopy analysis. Thirteen (13%) percent of the samples were selected for analysis, which exceeds the 5% minimum required by the LTP. The data were evaluated using United States Nuclear Regulatory Commission acceptance criteria specified in Inspection Procedure 84750 as detailed in Procedure RPM 5.1-24. There was acceptable agreement between field split results. The sample analysis vendor, General Engineering Laboratories-LLC; Charleston, South Carolina, maintains quality assurance and quality control plans as part of normal operation. Refer to Attachment 2 for data and data quality analysis results.
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SOUTH SITE GROUNDS SURVEY UNIT 9524-0000 RELEASE RECORD
- 8.
INVESTIGATIONS AND RESULTS During Area I scanning, one (1) location above the scan investigation level was identified and designated ER-0001. Sample 9524-0000-022I was collected from this location. The results of gamma spectrometry analyses of this sample indicated only Cs-137 at levels consistent with concentrations of Cs-137 found in soil at offsite locations within the vicinity of the HNP. No further action or investigations were required. See Scan Area Readings in Attachment 2.
Table 9-Scan Area Sample Results Scan Elevated
'Cs-137.
I Area Reading pCi/g DCGL(1 )
1 9524-0000-022I ER-0001 0.052 0.017 (I) f-DCGL-fraction of the Administrative Level DCGL
- 9.
REMEDIATION AND RESULTS Historically, no remediation was performed in this survey unit prior to or as a result of the FSS. Health Physics TSD BCY-HP-0078, "ALARA Evaluation of Soil Remediation in Support of Final Status Survey," determined that remediation beyond that required to meet the release criteria to be unnecessary and that the remaining residual radioactivity in soil was ALARA.
- 10.
CHANGES FROM THE FINAL STATUS SURVEY PLAN The change made from the LTP, prior to this FSS, was a decrease in the concentrations for the Base Case DCGLSoijs. The LTP presents DCGLs that correspond to a Total Effective Dose Equivalent (TEDE) of 25 mrem/yr. This survey unit was evaluated against Administrative Level DCGLs that correspond to 10 mrem/yr.
- 11.
DATA QUALITY ASSESSMENT (DQA)
The DQO sample design and data were reviewed in accordance with Procedure RPM 5.1-23, "Data Quality Assessment," for completeness and consistency.
The sampling design had adequate power as indicated by the Retrospective Power Curve. The Sign Test was performed on the data and compared to the original assumptions of the DQOs. All sample results were less than the release criteria. Therefore, the Sign Test shows that the survey unit passes Final Status Survey.
Documentation was complete and legible. Surveys and sample collection were consistent with the DQOs and were sufficient to ensure that the survey unit was properly designated as Class 3.
The preliminary data review consisted of converting the data into units relative to the release criteria (i.e., pCi/g) and calculating basic statistical quantities (e.g., mean, median, standard deviation).
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SOUTH SITE GROUNDS SURVEY UNIT 9524-0000 RELEASE RECORD For Cs-137, the sample standard deviation was almost twice the value used for the survey design, which reflects the variability of the soils sampled in this excavated area. The range of the data, about three standard deviations (3a), was not unusually large.
The frequency plot indicates that the data is skewed positive.
Analysis of the data utilizing a cumulative frequency distribution indicates that more than one distribution exists within the data set. This occurrence is a normal expectation and is frequently seen when sampling areas of varied geographical terrain as found in nature.
This data is consistent with the distribution of Cs-137 found in soil at off site locations within the vicinity of the HNP.
All data, assessments and graphical representations are provided in Attachment 2.
- 12.
ANOMALIES All data is considered valid including negative values, zeros, values reported below the MDC and values reported with uncertainties greater than two standard deviations.
Some radionuclides have been reported at low concentrations that are statistically significant at the 95% confidence level, but with a relatively high level of uncertainty.
Hard-to-Detect analyses results identified Sr-90 in two (2) samples. The Sr-90 value compares favorably with research conducted in other regional areas concerning fallout resultant from nuclear testing in the past as referenced in EPRI Technical Report 1003030, "Determining Background Radiation Levels in Support of Decommnissioning Nuclear Power Plants." No further actions were taken or needed.
In several of the samples, C-14, Co-60, Cs-134, Eu-154 and Eu-155 were listed in the analysis as meeting the criteria for detection, greater than two standard deviations (2a); however, all were reported below the laboratory listed MDC.
The data shows that the quantities of identified radionuclides do not represent quantities that would increase the requisite number of samples for non-parametric statistical sampling or cause the survey unit to fail to meet the release criteria. Most radionuclides were reported at levels near or below the required MDC.
- 13.
CONCLUSION Survey Unit 9524-0000 has met the DQOs of the Final Status Survey. For this survey unit, the ALARA criteria for soils as specified in Section 4 of the LTP were achieved. Elevated Measurement Comparison and remediation was not required.
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SOUTH SITE GROUNDS SURVEY UNIT 9524-0000 RELEASE RECORD The sample data passed the Sign Test.
The null hypothesis was rejected.
Evaluation of the data shows that none of the FSS design radionuclides or HTD soil concentration values exceeded the Administrative Level DCGL or unity. No large anomalies were observed in the graphical representation of the data. The survey unit was properly designated as Class 3. The Retrospective Power Curve generated using COMPASS shows adequate power was achieved.
This survey unit is not considered impacted by radioactive contamination in groundwater based on location, topography and current hydro-geologic sampling data as referenced in Health Physics TSD CY-HP-0193, "Assessment of Existing Groundwvater Dose for Phase II Release Areas of the Final Status Survey Report. "
- 14.
ATTACHMENTS 14.1 Attachment 1 - Figures 14.2 Attachment 2 - Sample and Statistical Data Revision I 16 Revision I 16
SOUTH SITE GROUNDS SURVEY UNIT 9524-0000 RELEASE RECORD Figures (6 pages)
Revision 1
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Site Map With Reference To Survey Unit 9524-0000 CD}
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SOUTH SITE GROUNDS SURVEY UNIT 9524-0000 RELEASE RECORD Sample and Statistical Data
SOUTH SITE GROUNDS SURVEY UNIT 9524-0000 RELEASE RECORD a Gamma Spectroscopy Data (94 Pages)
Table of Contents Case Narrative..........................................................
I Chain of Custody.................................................
4 Cooler Receipt Checklist............................................
8 Radiological Analysis..
10 Sample Data Summary..............................................
26 Quality Control Data 81
CASE NARRATIVE
CASE NARRATIVE For CONNECTICUT YANKEE RE: Soils PO# 002332 Work Order: 114103 SDG: MSR#04-1708 July 1,2004 Laboratory Identification:
General Engineering Laboratories, ILC Mailing Address:
P.O. Box 30712 Charleston, South Carolina 29417 Express Mail Delivery and Shipping Address:
2040 Savage Road Charleston, South Carolina 29407 Telephone Number:
(843) 556-8171 Summary:
Sample receipt The samples for the Soil Project for work order 114103 arrived at General Engineering Laboratories, 1LC, (GEL) in Charleston, South Carolina June 3, 2004 for environmental analysis. All sample containers arrived without any visible signs of tampering or breakage. The chain of custody contained the proper documentation and signatures.
The laboratory received the following samples:
114103001 9524-0000-O00F 114103002 9524-0000-002F 114103003 9524-0000-005F 114103004 9524-0000-006F 114103005 9524-0000-008F 114103006 9524-0000-009F 114103007 9524-0000-009FS 114103008 9524-0000-011F 114103009 9524-0000-012F 114103010 9524-0000-014F 114103011 9524-0000-015F 114103012 9524-0000-0221 GENERAL ENGINEERING LABORATORIES, LLC a Member of THE GEL GROnUP, IN:
P.O. Box 30712 - Charilston, SC 29417 a 2040 Savaga Road (29407)
Phone (843) 556-8171
- Fax (0$3) 766.1178 - www.gelcom
114103013 9524-0000-019F 114103014 9524-0000-003F 114103015 9524-0000-004?
114103016 9S24-0000-013FS 114103017 9524-0000-013F 114103018 9524-0000-016F 114103019 9524-0000-016FD 114103020 9524-0000-017F 114103021 9524-0000-017FD 114103022 9524-0000-018F 114103023 9524-0000-020?
114103024 9524-0000-021F 114103025 9524-0000-007F 114103026 9524-0000-01OF Items of Note:
There are not items to note.
Case Narrative:
Sample analyses were conducted using methodology as outlincd in General Engineering Laboratories (GEL) Standard Operating Procedures. Any technical or administrative problems during analysis, data review, and reduction are listed below by analytical parameter.
Analytical Request:
Twenty-four soil samples were analyzed for FSSGAM. Two additional soil samples were analyzed for FSSGAM and FSS ALT; Internal Chain of Custody:
Custody was maintained for all of these samples.
Data Packare:
The enclosed data package contains the following sections: Case Narrative, Chain of Custody, Cooler Receipt Checklist. Laboratory Certifications, and Radiachemistry.
I certify that this data package is in compliance with the SOW, both technically and for completeness, for other than the conditions detailed above. Release of the data contained in this hard copy data package has been authorized by the Laboratory Manager or a designee, as verified by the following signature.
Project Mana GENERAL ENGINEERING LABORAMRIES, ELC a Member of THE GEL GROUF INC P.O. Box 30712
- Charleston, SC 29417 a 2040 Savago Road (29407)
Phone (843) 658-5171
- Fax (S3) 761-1 178
- www.geLcom
- CHAIN OF CUSTODY
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r-Health Physics Procedure GPP-GGGR-R5104-003-Attachment B-CY-001 Major Connecticut Yankee Atomic Power Company ChIIain of Custody Form No. 2004-00090 362 Tjun Hollow RUastHampton, CT 06424
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960-267-2S56 tq53 ProjectName: Haddam NeckDecomrnissioning Analyses Requested Lab Use Only ContactName & Phone:
Comments:
lackMiCarthy 860-267-2556 ExL 3024 M
A.
Analytical Lab (Namne, City, State C
&Typ.
General Engineering LaboratoTies C od 2040 SavageRoad 8
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Charleston, SC 29407 C843-556-8171 )
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Sarah Koziik Priority: 0 30 D. Q 15 El 7D. Elo.tier.
Sample Designation Date Time C-nunent, Ptesmation Lab Sample Jr?
O 9524-0000-OOLF 5A4/04 1359 TS G
BP X
_=_=_=_
Z 9524-0000-002P 5/24/04 1419 TS G
BP X
9524-O00-005F 514104 1405 TS G
BP X
0 9524-0000.006?F 524104 1410 TS a
BP X
9524-0000-007F-5/24l04 1442 TS a
BP X
X 9 9524-0000-008?
5f24/04 1430 TS G
BP X
0ip 9524-0000-009F 5124104 1505 TS G
BP X
o 9524-000CO009FS 5N24/04 1505 TS G
BP X
,9524-0000-OlOF-5/4/04 1418 TS G
BP X
X NOTES: PO.
002332 MSR f. 04-1708 U
[I Radwaste QA El Non QA Sampm Shipped Via Internal Cqntainer C]ed Ex Temp.: ZPDeg. C O
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1)Rel qu By DarTflme 2), Ri mve Custody Seal Intact?
et/zl/oy A M/)q(t E Other
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- 5) Relinquished By DsteTiame 6)Re-eivedBy Datefinime 7>I "
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Health Physics Procedure GPP-GGGR-R5104-003-AttachmentB-CY-O01 Major Connecticut Yankee Atomic Power Company Ch of Custody Form No. 2004-00091 362 Injun Hotlow RoW, East Hampton, C 06424 86G-267-2556
/ I/
_/ _
ProjectName: Haddain NeckDecommissioning
-Analyses Requested Lab Use Only Contact Name & Phone:
Comments:
Jack McCarthy 860-267-2556 Ext. 3024 MAo Typ1 Slze n-Analytical Lab (Name, City, State
- COLI,
&7POpc GenerAl Enginuring Laboratories C
t UdeF 2040 Savage Rcad
- 4) ce a
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Charleston, SC 29407 (843-556B171)
Sarah Kozlik Priority: 13 30D. E 15 D.
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jOther Sampl Designation Date Time Commentr PnueratJion Lab Sample ID 9
9524-0000-011F 514A104 1413 TS G
BP X
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9524-0000-012 5/24/04 1400 TS G
BP X
- 9524-0000-014P 52404 1408 TS G
BP X
I 9t 9524-00-oD15TF Sf24/04 1418 TS G
BP X
9524-0000-0221 524104 1445 TS G
BP X
9524-0000-019F 5124/04 1425 TS G
BP X
9524-0000-003F 5S25104 0940 TS G
BP X
9524-A00-004F 525/04 1010 TS G
BP X
X 5
9524-0000O13FS.
52504 0950 TS G
BP X
NOTES: PO#:002332 MSR 04-1708 3
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- 5) Reinquished By Datetlime
- 6) Received By Datmeirin I
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Health Physics Procedure GPP-GGGR-R5104-003-Attachment B-CY-O1 Major Connecticut Yankee Atomic Power Company Chain of Custody Form No. 2004-00092 3
62 Injun HllowRoad, MasHampton, Cr 06424
, / ILv 36 nu
~~ w960-267.2 5 I ).
Project Name: Haddam Neck Decommissioning Analyses Requested Use Only*
Contact Name & Phone:
Comments:
JackMcCarlhy 960-267-2556 Ext 3024 Me&
Szm~la Sl obJw Analytical Lab (Name, City, State Cod
&T General Erngineerng Laboratories Code 2040 Savage Road 0
0n Charleston,SC 29407 (843-556-8171)
E, n i
Sarah KoZiIL P4 Priority:
30 D. 0 15 D El 7 D. C]Other:
Sampie Designation Date Time CEInunenf t Prervadon lab Sample ID 9524-0000-013F 5125104 0950 TS G
BP X
9524-000D-016P.
5/25/04 0855 TS G
I BP X
9524-0000-016FD 50/504 0915 TS G
BP X
9524-0000-017F St25/04 0830 TS G
BP X
9524-0000-017FD Sf25/04 0848 TS G
BP X
2 9524-0000018F 5n2S104 1010 TS a
BP X
=
9524-OD-02OP 5f25/04 1020 TS G
BP X
9524-000D-O21t 5/25/04 0920 TS G
BP X
NOTES: PO #: 002332 MSR #: 04.1708 0 LTP QA
] Radwaste QA 0 Non QA Samples Shipped Via:
Tntetl qp1tainer El Fed Ex Temp.:Z-V4Deg. C Culps Hilknd Cudy Sealed?
[Y-N 1)Rel n2edz Datetml Datelthm Custody Seal Intact?
3Wallnqulshed By DatThme
- 4) Received By DathnC B
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- 5) i Bill of Lading i dmyN
- 5) Relinquished By Da~rimc.
-no Reie yDte5m
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COOLER RECEIPT CHECKLIST w -
Connecticut Yankee Statement of Work for Analytical Lab Services CY-ISC-SOW-OO1 Figure 1. Sample Check-inList Date/Time Received: 6-
- v SDG.k\\
Work OrderNumber.
C a9of CLa y Shipping ContainerID.
1 Chain of Custody b OO ?0. ovO 9/
VPo 9L
- 1.
Custody Seals on shipping container intact?
yes [J1 o I t
- 2.
Custody Seals dated and signed?
Yes [
No t ]~
- 3.
Chain-of-Custody record present?
Yes [
(N t
- 4.
Cooler tempcmrture 7t-. I
- 5.
Vermiculitelpacking materials is: t Wet Dr Diy []
- 6.
Number of samples in shipping container.
7 o
- 7.
Sample holding times exceeded?
Yes Hj1 O I I
- 8. Samples have:
tap hzard labels custody seals
-appropriate sample labels
- 9. Samples are:
.jn good condition leaking lbroken mve air bubbles
- 10.
Were any anomalies identified in sample receipt?
Yes [
No [
- 11.
Description of anomalies (include sample numbers):
Sample Custodin1Laboratorztory Date*i, 4kCi Telephoned to:
On By 9 ;
10
Radlochemistry Case Narrative Connecticut Yankee Atomic Power Co. (YANK)
SDG MSR#04-1708 Method/Anulysis Tnformation Product:
Alphnspec Am241, Cm, Solid ALL FSS Analytical Method:
DOE EML HASL-300, Aim-05-RC Modified Prep Methad:
Ash Soil Prcp Dry Soil Prep GL-RAD-A-021 Method:
Dry Soil Prep Analytical Batch Numbcr 342904 Prep Batch Number 338594 Dry Soil Prep GL-RAD-A-021 3Batch Numbcr 338588 Sample ID Client ID 114103025 9524-0000-007F 114103026 9524-0000-0lOF 1200648444 Method Blank (MB) 1200648447 Laboratory Control Sample (LCS) 1200648445 114103025(9524-0000-007F) Sample Duplicate (DUP) 1200648446 1 14103025(9524-0000-007F) Matrix Spike (MS)
SOP Referencc Procedure for preparation, analysis and reporting of analytical data arc controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-0 II REVII 13.
Calibration Information:
Calibratlon Information All initial and continuing calibration requirements have been meL Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration datc(s).
Sample Geometry All counting sources vcre prepared in the same geometry as the calibration stnndards.
Oualitv Control (OC) Tnformation:
Blank Information The blank volume is representative of thce sample volume in this batch.
Designated QC The following sample vas used for QC: 114103025 (9524-0000-007F).
QC Information All of the QC samples mct the required acceptance limits.
Technical Informatlon:
Holding Time All sample procedures for this sample set were performed within the required holding time.
Preparation Information All preparation criteria have been met for these analyses.
11
Sample Re-preplRe-analysis Sample 114103025 (9524-0000-007F) was recounted due to a peak shift.
Miscellaneous Information:
NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. An NCR was not gencrated for this SDG.
Manual Integration No manual integrations werc performed an data in this batch.
Ounlifler information Manual qualifiers wvere not required.
Method/Analysis information Product:
Alphaspec Pu, Solid-ALL FSS Analytical Method:
DOE EML HASL-300, Pu-I l-RC Modified Prep Method:
Ash Soil Prep Dry Soil Prep GL-RAD-A-021 Method:
Dry Soil Prep Analytical Batch Number 342900 Prep Hatch Number; 338594 Dry Soil Prep GL-RAD-A-021 Batch Number 338588 Snmple ID Client ID 114103025 9524-0000-007F 114103026 9524-0000-01OF 1200648424 Method Blank (MB) 1200648427 Laboratory Control Sample (LCS) 1200648425 114103025(9524-0000-007F) Sample Duplicate (DUP) 1200648426 1 14103025(9524-0000-007F) Matrix Spike (MS)
SOP Reference Procedure for preparation, analysis and reporting ofanalytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-0 II REV# 13.
Calibration Information:
CalibratIon Information All initial and continuing calibration requirements have been met.
Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).
Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.
Ounlitv Control (OC) Information:
Blank Information The blank volume is representative of the sample volume in this batch.
12
Designated QC The following sample was used for QC: 114103025 (9524-0000-007F).
QC Informalion All of the QC samples met thc required acceptance limits.
Technical Information:
Holding Time All sample procedures for this sample set were performed within the required holding time.
Preparation Information All preparation criteria have been met for these analyses.
Sample Re-prep/Re-analysis Nonc of the samples in this sample set required reprep or reanalysis.
Miseellancous Inrormntlon:
NCR Documentation Nonconformance reports arc generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. An NCR was not generated for this SDG.
Manual Integration No manual integrations were performed on data in this batch.
Ounlitler information Manual qualifiers were not required.
MethodlAnalysls Inrormation Product:
Liquid Scint Pu241, Solid-ALL FSS Analytical Method:
DOE EML HASE-300, Pu-I I-RC Modified Prep Method:
Ash Soil Prep Dry Soil Prep GL-RAD-A.021 Method:
Dry Soil Prep Analytical Batch Number:
342903 Prep Batch Number:
338594 Dry Soil Prep GL-RAD-A-021 B3atch Number.
338588 Sample ID Client ID 114103025 9524-0000-007F 114103026 9524-0000-OlOF 1200648437 Method Blank (MB) 1200648440 Laboratory Control Sample (LCS) 1200648438 114103025(9524-0000-007F) Samplc Duplicate (DUP) 1200648439 114103025(9524-0000-007F) Matrix Spike (MS)
SOP Referencc Procedure for preparation, analysis and reporting of analytical data arc controlled by General Enginecring Laboratories, LLC as Standard Operating Procedurc (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-035 REV# 5.
Calibration Information:
Calibration Information All initial and continuing calibration requirements have been met.
13
Standards Informatlon Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).
Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.
Oualttv Control (OC) Information:
Blank Tnformatlon The blank volume is representative of the sample volume in this batch.
Designated QC The following sample was used for QC: 114103025 (9524-0000-007F).
QC Information All of the QC samples met the required acceptance limits.
Technical Informatlon:
Holding Time All sample procedures for this sample set were performed within the required holding time.
Preparation Information All preparation criteria have been met for these analyses.
Sample RL-preptRe-analysls None of the samples in this sample set required rcprep or reanalysis.
Miscellaneous Information:
NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. An NCR was not generated for this SDG.
Manual Integration No manual integrations wvere performed on data in this batch.
Oualllfer Information Manual qualifiers were not required.
Mletiod/Annlvsis Information Product:
Gammaspec, Gamma, Solld-FSS CAM & ALL FSS Analytical Method:
EML HASL 300,4.52.3 Prep Method:
Dry Soil Prep Analytical Batch Number:
339714 Prep Batch Number 338588 Sample ID Client ID 114103014 9524-0000-003F 114103015 9524-0000-004F 114103016 9524-0000-013FS 114103017 9524-0000-013F 114103018 9524-0000-016F 114103019 9524-000-016FD 14
114103020 9524-0000-017F 114103021 9524-0000-017FD 114103022 9524-O0000018F 114103023 9524-0000-020F 114103024 9524-0000-021F 114103025 9524-0000-007F 114103026 9524-0000-OOF 1200640440 Method Blank (MB) 1200640442 Laboratory Control Sample (LCS) 1200640441 114103014(9524-0000-003F) Sample Duplicate (DUP)
SOP Refcrence Procedure for preparation, analysis and reporting oF analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been nnalyzed in accordance witi GL-RAD-A-013 REV# tO.
Calibration Information:
Calibration Information All initial and continuing calibration requirements have been met.
Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).
Sample Ceometry All counting sources were prepared in the same geometry as the calibration standards.
Ouality Control (OC) Inrormation:
Blank Information The blank volume is representative of the sample volume in this batch.
Designated QC The following sample was used for QC: 114103014 (9524-0000-003F).
QC Information All of the QC samples met the required acceptance limits.
Technical Information:
Holding Time All sample procedures for this sample set were performed within the required holding time.
Preparation Information All preparation criteria have been met for these analyses.
Sample Re-prep/Re-nnalysis None of the samples in this sample set required reprep or reanalysis.
Mlscellaneous Wnformation:
NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. An NCR was not generated for this SDG.
15
Ounlilier Information Qualiller Reason Analyte Sample Ul Data rejected due to low abundance.
j Actinium-228 114103025 l
Lead-212 1200640440 Silver-108m 1200640441 Ul Data rejected due to no valid peak.
j Cesium-137 114103019 I__ Europium-155 14103022 Nlethod/Analysis In formation Product:
Gammaspec, Gamma, Solid-FSS GAM & ALL FSS Analytical Method:
EML HASL 300,4.5.2.3 Prep Method:
Dry Soil Prep Analytical Batch Number:
339715 Prep Batch Numbcr 338587 Sample ID Client 1D 114103001 9524-0000-GOIF 114103002 9524-0000-002F 114103003 9524-0000-405F 114103004 9524-0000-006F 114103005 9524-0000-008F 114103006 9524-0000-009F 114103007 9524-0000-009FS 114103008 9524-0000-01 IF 114103009 9524-0000-012F 114103010 9524-0000-014F 114103011 9524-0000-015F 114103012 9524-0000-0221 114103013 9524-0000-019F 1200640443 Method Blank (MB) 1200640445 Laboratory Control Sample (LCS) 1200640444 114103001(9524-0000-001F) Sample Duplicate (DUP)
SOP Reference Procedure for preparation, analysis and reporting of analytical data arc controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-013 REV#I 10.
Calibration Information:
Calibration Information All initial and continuing calibration requirements have been met.
Standards Information Standard solution(s) for these analyses are NIST traceable and used berbre the expiration date(s).
Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.
Ounlity Control (OC) Information:
Blank Information The blank volume is representative of the sample volume in this batch.
16
Designated QC The following sample was used for QC: 114103001 (9524-0000-OOlF).
QC Information All of thc QC sampies met the required acceptance limits.
Technical Tnrormflion:
Holding Time All sample procedures for this sample set vcrc performed within the required holding time.
Preparation Inrormation All prepamtion criteria have been met for these analyses.
Sample Re-prep/Re-annalysis None of the samples in this samplc set required reprep or reanalysis.
Misecllnneaus Tnformation:
NCR Documentntlon NCR ID 121363 The following NCR was generated for this SDG:
NCR 121363 was generated due to Non-Rad samples analyzed with Red Samples. Non-Rnd samples analyzed with Rad Samples: 114103 001,002,003,004,005,006,007,008,009, 010,011,012,013 Above sampies are "Non RAD" No cross-contamination occurred. Reporting results.
Ounlller informatlon Qualifier Reason Analyte Sample Ul Data rejected due to interference.
Europium-155 114103006 Ul Data rejected due to low abundance.
Actinium-228 114103005 114103007 Cesium-134 114103002 114103003 114103006 114103009 114103012 114103013 Method/Analysis Information Product:
Analytical Method:
Prep Method:
Dry Soil Prep GL-RAD-A-021 Method:
Analytical Batch Number Prep Batch Number Dry Soil Prep GL-RAD-A-021 Batch Number GFPC, Sr90, solid-ALL FSS EPA 905.0 Modified Ash Soil Prep Dry Soil Prep 341279 338594 338588 Sample ID 114103025 114103026 1200644297 1200644300 1200644298 1200644299 Client ID 9524-0000-007F 9524-0000-OIOF Method Blank (MB)
Laboratory Control Sample (LCS) 114103026(9524-0000-OIOF) Sample Duplicate (DUP) 114103026(9524-0000-0 lOF) Matrix Spike (MS) 17
SOP Referenec Procedure for preparation, analysis and reporting ofanalytical data are controlled by General Engincering Laboratorics, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-004 RBVfi 8.
Calibration Information:
Calibration Inrormation All initial and continuing calibration rcquiremcnts have been meL Standards Inrormatlon Standard solution(s) for these analyses are NIST traceable and used before thc expiration datc(s).
Sample Ccometry All counting sources were prepared in (he same geometry as the calibration standards.
Ounlitv Control (00C) Inrormnntion:
Blank Information The blank volume is representative of the sample volumc in this batch.
Designated QC The following sample was used forQC: 114103026 (95240000-010F).
QC Information All of the QC samples met the required acceptance limits.
Technical Inrormation!
Holding Time All sample procedures for this sample set were performed within the required holding time.
Preparation Intormation All preparation criteria have been met for these analyses.
Sample Re-prep/Re-arnlysis None of the samples in this sample set required reprep or reanalysis.
Chemical Recoveries All chemical recoveries meet the required acceptance limits for this sample set.
Miscellaneous Intormatlon:
NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. An NCR was not generated for this SDG.
l2unlifier Information Manual qualifiers were not required.
NMethodlAnaivsis Information Product:
Liquid Scint Tc99, Solid-ALL FSS Analytical Method:
DOE EML HASL-300, Tc-02-RC Modified Analytical Batch Number 341070 18
Sample ID Client ID 114103025 9524-0000-007F 114103026 9524-O000-O0OF 1200643929 Method Blank (MB) 1200643932 Laboratory Control Sample (LCS) 1200643930 114644001 (WWTPJEPOTW Sludge) Sample Duplicate (DUP) 1200643931 11464400 1(WWTP/EPOTW Sludge) Matrix Spike (MS)
SOP Rererenee Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with OL-RAD-A-005 REV# 11.
Calibration Information:
Calibration Information All initial and continuing calibration requirements have been met.
Standards InFormation Standard solution(s) for these analyses arc NIST traceable and used before the expiration datc(s).
Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.
Ounlity Control (9C) InFormatlon:
Blank Information The blank volume is representative of the sample volume in this batch.
Designated QC The following sample was used for QC: 114644001 (WWTPIEPOTW Sludge).
QC Information All of the QC samples met the required acceptance limits.
Technical nFormatlion:
Holding Timc All sample procedures for this sample set were performed within the required holding time.
Preparation Information All preparation criteria have been met for these analyses.
Sample Re-prep/Re-anulysis None of the samples in this sample set required reprep or reanalysis.
Miscellaneous Information:
NCR Documentation Nonconformance reports are generated to document any procedural anomalics that may deviate from referenced SOP or contractual documents. An NCR was not gcncratcd for this SDG.
Oualirler information Manual qualificrs were not required.
19
Method/Analysis Information Product:
Liquid Sclnt Fc55, Solid-ALL FSS Analytical Method:
DOE RESL Fe-l, Modificd Prep Method:
Ash Soil Prep Dry Soil Prep GL-RAD-A-021 Method:
Dry Soil Prep Analytical Batch Number 342541 Prep Batch Number 338594 Dry Soil Prep GL-RAD-A-021 Batch Number 338588 Sample ID Client ID 114103025 9524-aOO-007F 114103026 9524-0000-O1OF 1200647440 Method Blank (MB) 1200647443 Laboratory Control Sample (LCS) 1200647441 113282019(9535-0001-002F) Sample Duplicate (DUP) 1200647442 113282019(9535-0001-002F) Matrix Spike (MS)
SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-040 REV# 2.
Calibration Information:
Calibration Information All initial and continuing calibration requirements have been meL Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration datc(s).
Sample Ccometry All counting sources were prepared in the same geometry as the calibration standards.
Ouality Control (OC) Information:
Blank Information The blank volume is representative of the sample volume in this batch.
Designated QC The following sample was used for QC: 113282019 (9535-0001-002F).
QC Information All of thc QC samples met the required acceptance limits.
Technicnl Information:
Holding Time All sample procedures for this sample set were performed within the required holding time.
Preparation Information All preparation criteria have been met for these analyses.
Sample Re-prep/Re-analysis Samples 114103026 (9524-0000.OI1OF), 1200647440 (MB) and 1200647441 (9535-0001-002F) were recounted due to a negative result greater than three times the error.
20
Samples werc reprepped due to low/high recovery.
Miscellaneous Information:
NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from refcrenced SOP or contractual documents. An NCR was not generated for this SDG.
Additional Comments The absolute value of thc sample 1200647440 (MB) activity is greatcr than thrce times the one sigma total propagated uncertainty due to subtraction of the cross talk from the Iron-59 tracer.
Oualifier Information Manual qualifiers were not required.
Method/Analysis Information Product:
Liquid Scint N163, Solid-ALL FSS Analytical Method:
DOE RESL Ni-I, Modified Prep Method:
Ash Soil Prep Dry Soil Prep GL-RAD-A-02 1 Method:
Dry Soil Prep Analytical Batch Number:
342542 Prep Batch Number:
338594 Dry Soil Prep GL-RAD-A-021 Batch Number:
338588 Sample ID Client ID 114103025 9524-0000-007F 114103026 9524-0000-OlOF 1200647444 Method Blank (MB) 1200647447 Laboratory Control Sample (LCS) 1200647445 1 141 03026(9524-0000-OIOF) Sample Duplicate (DUP) 1200647446 114103026(9524-0000-OIOF) Matrix Spike (MS)
SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-022 REV# 6.
Calibration Thformation:
Calibration Informatlon All initial and continuing calibration requirements have been met.
Standards Information Standard solution(s) for these analyses arc NIST traceable and used before the expiration date(s).
Sample Geometry All counting sources werc prepared in the same geometry as the calibration standards.
Ouality Control (OCI Inftormntion Blank Information The blank volume is representative of thc sample volume in this batch.
Designated QC The following sample was used forQC: 114103026 (9524-0000-010F).
21
QC Inrormation All of the QC samples met thc required acceptance limits.
Technical InFormation:
Holding Time All sample procedures for this sample set were performed within the required holding time.
Preparation InFormation All preparation criteria have been met for these analyses.
Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis.
Miscellaneous Inrormatlon:
NCR Documentation Nonconformance reports arc genecnted to document any procedural anomalies that may deviate from referenced SOP or contractual documents. An NCR was not generated for this SDG.
Qunaller information Manual qualifiers were not required.
Method/Analysis InFormation Product:
LSC, Tritium Dist, Solid-}lTD2,ALL FSS Analytical Method:
EPA 906.0 Modified Analytical Batch Number 342680 Sample ID Client ID 114103025 9524-0000-007F 114103026 9524-0000-OIOF 1200647787 Method Blank (MB) 1200647791 Laboratory Control Sample (LCS) 1200647788 1 15079001(SSIBFI58) Sample Duplicate (DUP) 1200647789 11S079001(SSIBFI58) Matrix Spike (MS) 1200647790 1 15079001(SSIBFIS8) Matrix Spike Duplicate (MSD)
SOP Rercrence Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-002 REV# 9.
Calibration Information:
Calibratlon Informnation All initial and continuing calibration requirements have been met.
Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).
Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.
Ounlity Control (OC) Information:
22
Blank Information The blank volume is reprcsentative of the sample volume in this batch.
Designated QC The followving sample was used for QC: 115079001 (SS113F158).
QC Information All of the QC samples mct the required acceptance limits.
Technical Information:
Holding Time All sample procedures for this sample set were performed %vithin the required holding time.
Preparation Information All preparation criteria havc becn mct for these analyses.
Sample Re-prep/Re-analysis Sample t200647788 (SSIBFI58) was recounted due to high MDA.
Miscellaneous Information:
NCR Documentation Nonconformance reports arc generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. An NCR was not generated for this SDG.
Oualifier information Manual qualifiers were not required.
Method/Analysis Information Product:
Liquid Scint C14, Solid FSS Analytical Mcthod:
EPA EERF C-01 Modified Analytical Batch Number 342387 Sample ID Client ID 114103025 9524-0000-007F 114103026 9524-0000-OlOF 1200647032 Method Blank (MB) 1200647035 Laboratory Control Sample (LCS) 1200647033 113282020(9535-0001-006F) Samplc Duplicate (DUP) 1200647034 113282020(9535-0001-006F) Matrix Spike (MS)
SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-B-023 REVR 0.
Calibration Information:
Calibration Information All initial and continuing calibration requirements have been met.
Standards Information 23
Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).
Samplc Geometry All counting sources were prepared in the same gcometry as the calibration standards.
Ounlity Control (OC) Informallon:
Blank Information The blank volume is represenlative of the sample volume in this batch.
Designated QC The following sample was used ror QC: 113282020 (9535-0001-006F).
QC Inrormation All of the QC samples met the required acceptance limits.
Technical Tnaformation:
Holding Time All sample procedures for this sample set were performcd within the required holding time.
Preparation lnformation All preparation criteria have been met for these analyses.
Sample Re-prep/Re-onalysls Samples 114103025 (9524-0000-007F), 114103026 (9524-0000-OO1F), 1200647032 (NMB) and 1200647033 (9535-0001-006F) were recounted due to high MDAs.
Samples were reprepped due to lowthigh recovery.
Miscellaneous Inrorm r tion:
NCR Documentation Nonconformance reports arc generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. An NCR was not generated for this SDG.
Qualifier information Manual qualifiers were not required.
Certifieation Statement Where the analytical method has been performed underNELAP certification, the analysis has met all of the requirements of the NELAC standard unless othenvise noted in the analytical case narrative.
Review Validation:
GEL requires all analytical data to be verified by a qualified data validator. In addition, all data designated for CLP or CLP-like packaging will receive a third level validation upon completion of the data package.
The Following data validator verified the Information presented in this case narrative:
4L{ QUJUi 2fo Reviewer:
24
General Engineering Laboratories Form GEL-XXX Rev. 06102 NCR Report No.:
121363 Revision No.:
COMPANY - WIDE NONCONFORMANCE REPORT Mo.Day Yr.
Division:
Type:
22-JUN-04 Radlochemistiy Process Instrument Type:
quality Criteria:
Client Code:
GAMMA SPECTROMETER Specifications YANK Test I Method:
Matrix Type:
Batch ID:
Sample Numbers:
EML HASL 3ao. 4.52.3 Solid 339715 See Below Potentially affected work order(s)(SOG): 114103(MSR#04-1708),114379(MSR#04-1324),114738(MSR#04-1763&1704)
Application Issues:
Non-Rad samples analyzed with Rad Samples Specification and Requirements NRG Disposition:
Nonconformance
Description:
Non-Rad samples analyzed with Rad Samples:
No cross-contamination occunred. Reporting results.
114103 001,002.003.004,005,008.007,008,009.
010,011,012.013 Above samples ara 'Non RAD Originators Nama:
Seth Wells Quality Review,.
22-JUN-04 Data ValidatorlGroup Leader.
Scott Baskalt 22-JUN-04 Corrective Action:
Director.
Corrective Action ID and Complete Date:
Page 1 25
SAMPLE DATA
SUMMARY
.I 26
GENERAL ENGINEERING LABORATORIES, LLC GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Chaleston SC 29407 - (843) 5588171 - WW.gel.Com Certificate of Analysis Company: ConnecticutYank=eAtomhcPower Address:
HJaddanNcckPlant 362 Injun Hollow Read EButHampton, Connecticut 06424 Contnct Mr. Pete Hollenbeck Project:
Solls PON 002332 ReportDate: Julyl,2004 Page 1 of 2 Clicnt Sample I:
9524-0000OO01F Picc YANK00504 SamplEID:
114103001 ol.rent:
YANK001 SoilVol.
Recv
- Couect)ate:
24-MAY-04 Rzceive Dale 03-JUN404 Collector.
Clicat Moistre:
4.74%
Parameter Qunaler Result Uncertainty LC TPU MDA Unlis DF AnalystDate Time BatchMtd.
Rad Gamma Spec Analysis Cam7rpee, CGa. Slid -FSS CAM& ALL FSS Actlniuz-22 0.529 1/0.176 0.0575
+1-0.173 0.122 Amedcium-241 U
-(.00178
+/.O.M84 0.0229 dl0.0278 0.047 Blsmunt-212 0557 4/ om 0.135
+/-0.266 0M3 EIsmUth-214 0.317
+/-0.0855 O0319 41-0.0838 0.0664 Cesium-134 U
0.0313
+/-0.0338 0.0185 +1-0.0331 O.0389 Cesiun-137 U
0.0161
+W-0020 0.0176 4/-0.0196 0.036S Cobalt-60 U
0.0199
+14-09 0.0186 +1-0.0205 0.0396 Europlum-152 U
-0.00309
+/).0426 0.0393 +1-0.0418 0.0796 EuruplSm-154 U
0.0183
+/4.0681 0.0572 +1-0.0668 0.121 Europium-155 U
0.0656
+10.039 0.0381 +/-0.0382 0.0782 LtAd-212 0.434
+1-0.0577 0.0223 +10.0565 0.046 Lcad-214 0.365
+1-0.0712 0.028 +41-0.0692 0.0582 Manganese-S4 U
0.0149
+1.0.21 0.0.174 +140.0213 0.0365 Nlobuin-94 U
0.00791
+I-O.019 0.0162 +1-0.0185 0.0338 Potnhssl-40 11.7
+/-1.06 0.132
+1-1.04 0.288 Radlum-226 0.317
+1-0.0855 0.0319 +-0.0838 0.0664 Silycr-loom U
0.0064 U-+0.0149 0.0134 +1-0.0146 0.0279 Thallum-208 0.152
+1-0.0419 0.0172 4-0.041 0.0359 pCug pClg pCl/g palg paig PC~g pCig pClg palg pcug pCig pCVi SRB W19104 1541 3397151 The rotlawngPrep tethods were ptrformed Method DescripUan Anayst Date Time Prep Batch Dry Sail Prep DMySolPrepGaLRAD-A-021 DSWI 06&I4 1508 338587 The 6allowag Analytical Methods were purarmed Method Dese*rfpton 1
EML HASL 300, 4.523 Notes:
The Qualifiers in this report are defined as follows:
B Targt anlytowas dct i t sampl m we as thesociated bla BD Flag foresults blow ft MDC or a fg forlow txuccrecovey.
E Concentraion of the target analyto exceeds the Insbncmcnt calfbation range.
27
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (43) 556-171 - www.getom Certificate of Analysis Company: ConnecticatYankee Atomic Power Addrcss:
HaddamNcckPlant 362 Injun Hollow Road Enst Hampton, Connecticut 06424
Contact:
Mr. Pete Hoilcebck Project Soils PON 002332 Client Sample ID:
Sample ID:
ReportDate: July 1.2004 Page 2 of 2 9524-00 FOOIF 114103001 Proj YANKDO504 ClienwD:
YANKODI Vol. Recv.
Parameter Qualiller Result Uncertainty LC lTU bDA Units DF AnalystDate Time BatchMild.
H Analytical bolding timexceedcd.
J Indicates in estimated value The result was grcate tOan the detection limit, but less than the reporting ilmIL U
Indicat e targt analyte waS analyzed forbut not detcted abovc the detection limiL UI Uncertain Identification for gamma spectroscopy.
X Lab-specific qualifier-please see case narrative, data summary package or contact your project manager for details.
h Sample praparation orbprcscvatco bading o
rmC exceded Toe aove sample Is reportcd on a dry wcight basis.
This data report has been prepared and reviewed In accordance with General Engieering Lboratories, LLC standard operating procedurts. Please direct any questions to your Project Manager, Sarah KozliL Reviewed by 28
GENERAL ENGINEERING LABORATORIES, LLC GENERAL ENGINERERING LABORATORIES, LLC 204a Savage Road Chadleston SC 29407- (M 65G8171 - www.gel.com Certificate of Analysis Company: CannecticutYankee Atomic Power Address:
HaddonNcckPlant 362 tnjua Hollow Road East Hampton, Connecticut 06424
Contact:
Mr. Pete Holleabeck Pm3ecLt Soils PO# 002332 Cient Sample ID:
Samp I 1D:
Matrix:
CollectDate:
Receive Datc:
Collector Moisture Report Date: July 1,2004 Page I of 2 9524-0000-002F 114103002 Sonl 24-MAY-04 03-JUN.04 Client 9.54%
YANK}W504 9ent 1D:
YANKOOI Vol. Recv.:
Parameter Qualifler Result Uncertainty LC TPU MDA Units DF AndlYstDate r1me Batch Mtd.
Rad Gamma Spec Analysis Ganmarpe4 Ganma, Solid-FSS CAM & AL FSS Actlaluni-228 0.690 J-/0.199 O.552 4t-0.195 Amnrieium-241 U
-0.012 1.0.0261 OM233 -/4.0256 Blsmuth-212 0334
+140.23 0.129
+1-0.22B Bismuth-214 0.619
+-0.107 0o04 +1-0.105 Cesium-134 U
0.00
+/4.048 0,0236 W-0.0471 Ul CcsJ1m-137 U
0.024
+1-0.0271 00174 41M0.0265 Cobalt60 U
0.00863 41/4022 002M 424/0224 Eurmpium.152 U
-4.0156 4M.0469 00398 3
-40.0459 Europium-154 U
0.0743 41-0.0694
.0593 +1-0.069 Europiumt-l5 U
0.0673 41-0.0639 0.033 +1-0.0626 Led-212 0.654 41-0.O746 0.0204 41-0.0731 Lead-214 0.616 41-0.0834 0.025S +1-0.0817 Manganese-54 U
-O.604 41-0.0197 0.0163 41-0.0193 Niobiuns-94 U
0.0154 41-0.019S 0.0177 +1-0.0191 Pbtasuium40 11.8 41-1.12 0.158
+1-1.10 Radium-226 0.619
+1-0.107 0.0304 W-0.105 SIlver.-lOm U
-0.000W724 41-0OI0SS 0.0131 +1M.0152 Thalilum-208 0.228
+O.0528 0.056 +1-0.0517 0.120 0.048 0.276 0.0645 0.0498 0.0369 0.0439 0.0836 0.128 0065s 0.0426 0.0545 0.035 0.0374 0.351 0.0645 0.0Q78 0.0333 pCug pCig pClg pCVC pCUg pCI/g pC11g pCI/g pCI/g pC/g pClg pClg pC11g pCVg pCVg pCUg pCt/g SRB 06/19/04 1541 339715 1 hefoUnwingPreM Methods were performed Method Description Analyst Date Time PreP Batch Dry SoU Prep Dry Sall Ptcp GERAD-A.021 ESWI 0/04J04 1508 331387 The followng Analytical Methods were performed Method Description I
BMLHASL300,4.5.13 Notes:
'Me Qualiiers in is report are defined as follows:
B Target aayt was detected In de s picas weadthassated bla.
DD Plngforrmsltsbelow theMDCoraflagforlowtmwerrecrvcly.
B Concentation of the target analyte exceeds the Instrument calibration mnge.
29
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savagd Road Chaadeston S0 29407 - (643) 556-8171 -www.gel.com Certificate of Analysis Company: ConnecticutYanke Atonic Power Addrs:
HaddamNeck Plant 362 lnJunlfollowRoad EastLHainptcn, Connecticut 06424 Contacl:
Mr.PeteHollenbeck Pwject Sols PO#tD002332 ClientrSample ID:
Sample D:
Rx potDatc: July 1,2004 Page 2 of 2 9524-0000-=02 114103002 ePrvicc YANKS0004 Wient ID:
YANK00I Vol. Racv.:
Palrareler QualiUer Result Uncertainty LC TWU MIIA Unith DF Avalysfl~afe Time Dateh Mid.
H Analytical holding time exceeded.
J bndicate an estimated value. Ihe result was greater tban the detection limit, but less than the reporting llmik U
Indicates the target analyte was analyzed for but not detected above the detection limit.
Ul Unccrtini identificadon forgammaspecrocopy.
X Lab-specific qualifier-plcase see case nnrativeC data summary package or contact your project manager (or details.
h Sample preparation orpreservytlon holding time exceeded.
The above sample Is reported on a dry weght bsi.
This data report has been prepared and reviewed In accordance with General Engineering Laboratorics, LLS standard operating procedures. Please direct any qucstions to your Project Manager, Sarah Kozlk 44Uff-FO0JX j e Reviewed by 30
GENERAL ENGINEERING LABORATORIES, LLC GENERAL ENGINEERING LABORATORIES, LLC 2040 Savags Road Claodeston SC 29407 - (843) 556-8171 -WWW.9ge.com Certificate of Anglysis Company:
Connecticut Yankee Atomdc Power Address:
HaddamNeckPlant.
362 Injun Hollow Road EAstHampton, Connecticut 06424
Contact:
Mr. Pete Hollenbeck Project:
Soils PON 002332 ReportlDae: Iulyl.2004 Page 1 of 2 Client Sample D:
SampleID:
Matrix:
CollectDaie:
Receive Date:
Collector Moisture:
95244-O005-F 114103003 Soil 24-MAY-04 03-JUN-04 Client 8.73%
Pw cL YANK00504 Client ID:
YANKOOI Vol. Recv.:
mrameter Qualifier Result Uncerlnlnty LC TPU MDA Units DF AnlystDate Time Dalebbild.
Rad GCinmaSpec Analysis Cammwper. Gammag Salld-FSS GAU & ALL FSS
-Actinim-223 0.694 41-0.145 Amclclum-241 U -0.000356
+W-O.1O6 Bismuth-212 0.447
+J-0.160 Biscautb-214 511 4t-0.0737 Caslum-134 UI 0.0474
+/-0.0273 Ceshum-137 0.046S 14-0.024 Cobalt-60 U
0.0163 41M0.0136 Europlum-152 U
-. 0191
+/..052 Europhlm-154 U
-0.017 4+.0388 Europium455 U
-0.0168
+140.046 Lud-212 05S4
+1-0.0601 Lad-214 0.638 41-0.0764 Mangase-54 U
0.015S
+/-0.0177 Nloblun-94 U
0.000242
+/.0121 Potassham-40 12.6 W-1.09 Radium-226 0511 1/4.0737 SlSver-loom U
0.00164 41-0.0114 Thnlailum-208 0.185
+140036 0.0361 t4/0142 0.067 140.104 0Q0769 414.157 0.0233 4/40M22 0.0141 +1-0.0267 0.0102 4040236 0.0125 +140134 0.0295 +140345 0.0316
+14MM 0.0395 +410451 0.02081 +-0.0589 Q0204 +/.0`748 0.011 +1-0.0173 0.0103 *t10011 0.0898
+r11o7 0.0233 +.0.0722 0.010 +14.0112 0.0116 41-0.033 0.0761 0.137 0.162 0.0484 0.0293 0.014 0.0265 Q0612 0.0674 0.081 0.0427 0.0423 0.0232 0.0216 0.195 0.0484 0.020 0.0242 pC11g pCi/
pCVg pCUg pCVg pCS/g pCI/g pCl/g pCUg pcVg PCU8 pC~rg pCV9 PCV SB 06n19/04 1542 339715 1
'ne following Prep Methods were performed Method Desription Analyst Date ime PrepaDtch Dr Son Prep Dry Sol Prep O1RAD-A-021 BSWI 0604/04 150C 338587 The fallowtag Analydca Methods were performed Method Descrption EMLHASL300.4.5.23 Notes:
The Qualferas in hi report =r dcfincd as follows:
D Taract Iayto WOJ dectd i th mrplo as wcn a the sceledblank.
BD Flag for result below theMDCora rlagforlow tracer covy.
E Concetruaion ol the target anlyte cxceeds the instnrmcnt calibtion range.
31
GENERAL ENGINEERiNG LABORATORIES, LLC 2040 Savage Road Charleston SC 29407- (843)555-8171 - www.geLcom Certificate of Analysis Company: CantctiutYankee Atomlc Power Adde:
HaddamNeckPlant 362 bjun Hollow Road East Hampton, Connecticut 06424
Contact:
Mr. Pete Hollenbeck Project:
Sois PO# 002332 Report Datc: July 1. 2004 Page 2 of 2 Client Sample lD:
SamplelD:
9524-0000005 114103003 ol Rcv YANY-0004 e
lctVD:
YANKOO1 YoL. Rccv.:
Parameter Qualimir Result Uncertainty LC TPU MDA Unlis DF AnralysDute Time Btch Mid.
H Analytical holding time exceeded.
J Indicates an estimated value. Ie rcsult was greater than the detection limit, but lesa than he reporting limit.
U Indicates the target analyte was analyzed for but not detected above the detection UmniL UI Uncectalaidentdficaton forgammaspectrscopy.
X Lab-specfic qualifier-please se caue namitive, data smumary package or contact your prolect manager for details.
h Sample preparation orprservaton holding timo exceedcd.
The above sample Is reported on a dry welght basis.
This data report has been prepared and rviewed In accoudanco with General Engineering Laboratories, LLC standard opcraig procedures. Pleaso dliect any questions to your Project Manager, Sarah Kozli.
Reviewed by 32
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atoamc Power Addrs:
Haddn iNck Plant 362 lnjun Hollow Road, Eadt Hampton, Connecticut 06424
Contact:
Mr. Pete Hoilenbeck PWeCCt:
Soils PO#002332 Report Date: ludy 1.2004 Page I of 2 Client Sxunple ID:
Samelc]D:
Mtnx:
CollectDatew:
Receive Date:
Collector Moisture:
9524-000-006F so14f103004 24-MAY-04 03-JUN-04 Client 6.83%
HPTled:
YANKOOSO4 llent ID:
YANKOOI Vol. Reev.:
I Paramefer Qualilier Result Unctsnty LC TPU MDA units DF Analyst])te 7Ine BatchMtd.
Rad GC-ma Spee Analysis Gammnaec Gamunm Salid-FSS GAM & AL FSS Actlnlm-228 0.647
+1-0.197 C/S2 +I 0.193 Americium-241 U
0.0101 4-0.0504 0D467 +140494 Bismuth-212 0.562
+1-0280 0.162 +1-0274 BMsmulh-214 0.478
+140.122 0.0365
+14.120 Calumn-134 U
0.0304 4-0.037 0.25 +1-00363 Ceuium-137 0.103 t410531 0.021 4/40521 Cobalt-60 U
0.0355 4/410195 0.0213 +14-.0191 Eumplam-152 U
0.0023 4/4/0576 0.051 t4-0.0565 Europlum-154 U
-0.0199
+140837 0.0577 414082 Europlum-l55 U
0.0475
+/410602 O0551
+14059 Lend-212 0.565 4140767 O.MW +1-040751 Lead-214 0.574
+1-Q0972 0.0325 41-0093 Mangnese-54 U
000139
/-0.02,4S 0.0213
+140.024 Nioblum-94 U
-0.0152
+1/0.0249 0.0166 41-0.0744 Potnlum40 12.1
+1-1.16 0.146
+1-1.14 Rndium-226 OA78 4140.122 M0365
+/4120 S11ver-108m U
-0.Q0444
+1-0.0203 0.173 +1-0.0199 nallum-208 0.203 41-0.0493 0.0199 +1-0.0483 The followdng PEp Meihods were peformed Method Decdpltlou Aznwly 0.161 0.0956 0.345 0.0775 0.0532 00445 0.0467 0.10 0.127 0.113 0.607 0Q0682 0.0455 Q03S6 0.333 0.0775 0.036s Q0423 pCllg pCi/i pCig pCI/g pCI/g pCilk pCl/g pCUg pCI/g pCU/g pCUg Paz pCllg PCl/g pCig pCi/g pCvg pCig SRB 06/19/04 1542 339715 1 Dry Soi Prep Dry Soil Prep GL-RAD)A-021 NSWI t
Date Time Prep latch 06/04104 1508 335857 The following Analytical Methods were verformed Method Descriptlon I
iML HASL 300,4.523 Noteu:
The Qualificis in ts report ame defined as follows:
nU T~rrt mlyte was dtcda In samploa wel as the ssciated blank.
BD lag for results bclow lth MDC oranflg forlow mer rccvey.
E Concentation of the ttet analyte cxceds the instrunent calibralonm range.
33
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Chaleston SC 29407 - (843) 556-8171 - www.geLcom Certificate of Analysis Company: ConnecticutYankee Atomic Power Address:
HaddamNeckPlaaz 362 Injun Hollow Road Easlt llnmptoan. Connecticut 06424 Contact Mr. Pete Hollenbeck Proecet:
Soils PO# 0032 Rcport Date July 1. 2004 Page 2 of 2 Cliet Sample ID:
Sample ID:
9524-OW6F 114103004 CPMIec YANKO0534 Clet 11):
YANK001 Vol. Rec.:
Ponanlter Qualier Result Uncertainty LC TPU bDA UWts DF AnlysuDate Time ButchMid.
H Analytical holding time exceeded.
J Indicates an cstimweed value. The result was greater than eho detection limit, but less than the reporting 11mIL U
Intdicales the target analyte was anatyzed for but not detected above thc detcction limit.
Ul UncerTain Identification forgamma spectroscopy.
X lab-specific qualifier-pleasicsecae narrativec, data hummuy packageorcontactyourprojectmanager rordetais.
h Sample preparation or preservation holding time exceeded.
The above sample is reported an a dry weight basis.
this data report has been prepared and reviewed In accordance with Generml Engineering Laboratodes. LLC standard operating procedures. Please direct any questions to your Project Manager, Sarh Kozlik.
Reviewed by 34
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407- (843) 555-8171 - ww.gelcom Certificate of Analysis Company.
Connectcul Yankcc Atomic Power Addms:
H1ddaNeckPlant 362 Injun Hcllow Road Ent Hampton, Connecticut 06424 Cootact Mr. Pete Hollenbeck PWIecLt Soils PON 002332 ReportDate July 1,2004 Page I of 2 Client sample D:
SameleD:
Matnr:
CollectDate:
ReceiveDate:
Collector.
Mobitu=a.
952440000-008F 114103005 Soil 24-MAY-04 03-JUN-04 Client 34%
t~iect:
YANK00504 pusecntD:
YANKODI Vol.Racv.:
Paramretr Qualifier Result Uncertainty LC TPU MDA ad GammaSpecAluyis Gammaxpec, Gamma, Soifd-FSS GAM & ALL FSS Acffilum-228 U
0.00 4/4128 0.0821 41-0.126 0.170 UM Ameulcium-241 U
0.0397
+140.0522 0.0459 +1-0.0512 0.0948 Blsmuth-212 U
0.227
-0.133 0.119
+1-0.130 02SO Bsismuth-214 0.321 41-0.0784 0.027 *t-0.0769 0.0566 Ccslum.134 U
0.0218
+1-0.018 0.0158 4/-0.0176 0.0334 Cesaum-137 0.607 t-0.0767 0.0129 41-0.1751 0.0274 Cobalt-60 U
-0.00429 41-0.0171 0.0136
/0.0167 0.0294 Europlum4152 U
0.0221
+/.0.0487 0.0365 4/-0.0477 QX0761 Europkun-154 U
0.00695
-/40575 0.0411 4/-0.0563 M0884 Europlum-155 U
0.0272 40.0477 0.0406 4+-0.046 0.0838 Ltad-212 0.378
+1-0.0541 0.0212
+1-053 0.0438 Lead-214 0374 41-0.0796 0.0261
+/-0.078 0.0544 Manllnlc-54 U
-0.00376
+14.017 0.0136 4-0.0166, 0.0287 Mioblum-94 U
-0.00711 41-0.015 0.012 4/-0.0147 0.0253 PoFtaslum,40 11.3 41.1.O5 0.132 41-1.03 0.288 Radium-226 0.321 4/-0.0784 0.027 4/-0.0769 0.066 Silver-lOam U
0.00153 44016 0.0131 4/-0.0157 0.0273
-Tlilllum-208 0.114
+/-0.0333 0.0123 41-0.0326 0.0261 Units DV AnlystDute lTime Batch Mtd.
Pag pC/g pcl/g pClg pcug pC~g PCu8 pCl/g pCUg Pag pCl/g pCU8 pCVg SRB 06/19(04 1543 339715 1 The ftllowig Prep Methods were performed MTthod Description Anralyt Date Time Prep Batch Dry Soil Prep Dry Soil Prep CLAD-A-021 BSWI 004/04 1508 338587 The following Analytical Methods wen Verformed Method Description
.1 EMLHsL300.45.23 Nota:
mhe Qualifie*s In this reportm defined s follows:
8 Target analyte was detected in thc snple oa wl Das the associatedi bl.
BD Flagforrsls below the MDC or aflag forlow term covry.
E C cenurtion of the target maniyta exceeds the inJtument calibrdon mng.
35
GENERAL ENGINEERING LABORATORIES, LLC GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Chareaston SC 29407- (843) 556-8171 -www.gel.com Certiffcate of Analysis Company: Connecticut Yankee Atomic Power Address:
HaddamNcckPlant 362 Injun Hollow Road East Hampton, Connecticut 06424
Contact:
Mr. Pcte Hollenbeck Pject:
Soils PON 002332 Report Datc. July 1,2004 Page 2 or 2 Client Sample ID:
Sample ID:
9524-00008OOHF 114103005 et YANMK0504 calt YANKOOI Val. Recv.:
Pnrameter Qudlier Result Uncertaiuty LC TM MDA Unlls DF AanlystDaf a Tlne BatCIMcd H
Analytical holding tima exceeded.
I Indicates an estimated value. The result was greater than the detection flrmt, but Ics3 than the reporting lImit.
U Indicates tho target analyto was analyzed forbut not detected above the detection lmiL Ul UncertaIn identifcation for gamma spectrscopy.
X Lab-speciefic quallfier-please sae case narrative, data summary package or contat yourprojectmanagerfordetails.
h Sample preparadion or preservation holding time exceeded.
The above sample Is reported on a dry weight basis.
This data report has been prepared and reviewed In accordance with General Engineering Laboratories, LLC standard operating pwcedures. Pkase direct any questions to your Poject Manager, Sarah Xozlik Reviewed by 36
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savago Road Charleston SC 29407 - (843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankec Atomlc Powcr Addr:u Haddan Neck Plant 362 Iijun HollowRBoad East Hampton, Connectlcut 06424 Conle:
Mr. Ptel Halleabeck Prowece Soils POP 002332 Client Sample ID:
Sample ID:
Maru CollectDate:
Receive Datc:
Collectar Moistlre Report Dat July 1,2004 Pagc 1 of 2 9524-0000-009F Poe YAN004 114103006 Vl.c YANKDO Soll Vl. Recv 24-MAY-04 03-JUN-04 Client 29.9%
Parameter Qunaliier Result Uncertainty LC TPU MDA Units DF AwnlyutDate Time nichb MiLd.
Rad Gamma Spec Ailys Gammaspe4 Gamma, Solid FSSGAUf &ALL FSS Actinlum-228 0.479
.4-0.133 O.OU2 4/.0J30 Americlum,241 U
.00316 41-0.0898 0.0573 41-0.088 Bismuth-212 0.437
+I-0.233 0.0 41.229 Bismnuth-214 0354
+/-0.0793 0.0279 +1.0.0767 Ccsium-134 U
0.00
+M.0195 0.0191 41-0.0191 Ut Cesium-137 0.192
+4-0.036 0.014 +1-0.0353 Cobnlt-60 U
-0.00196
+1-0.0163 0.0135 410.016 Europlum-152 U
0.0405 4tl-0736 0.0348 +W-0.0721 Europlum-154 U
0.0182
+/41.0575 Q.04B
-tl0.0564 Europlum-15S U
0.00
+/.00653 0.0368 41-0.064 Uq Lcad-212 0510 4/-0.0636 0.0216 +/.0.0623 Lead-214 0.482
+1-.0804 0.0259 4/-0.0788 Manganese-54 U
0.00328 1-0.0167 0.0141 4"1..0163 Nlobfum-94 U
0.00394 410.0157 0.0135
-O0.0154 Potassum40 11.8
+1-1.13 0.151 41-1.11 Radlum-226 0354 4/-0.0783 0.0279
/ -0.0?67 SlIverr-108m U -3.170WS 4/-0.0139 0.0113 +1/0.0136 TbalIlum-208 0.156 4/-0.0406 0.0137 +1-0.0398 0.105
.119 02M3 0.0593 0.0407 O.0102 0.0305 0.0734 0.10S 0.0764 0.04S 0.0547 0.0306 0.0289 0335 0.0593 0.0242 0.0294 pC/g FCi/g pC/g9 palg Pa/g SRB 06/19104 2149 339715 1 pati pCI: g pCl/g qClg pC1Ug Patz pacg pC/g Paig pcl/g T-e followin Preo Mebods wre erfonned Method Descriptin Analyst Date Time Prep Batch Dhy Son Prep DrySailPrep GLRAD-A-0Z1 BSWI 06104/
1508 338587 The foioowinr Analjfl Mehods wr performed Method Description 1
EMLllASL300,4.5.23 Notes:
The Qualifiers In this report a defined as follows:
B Target anDlyto was detected I the sample as well aS the associated blarkJ BD Flag for results below the MDC orn flag fcr low tracer recovery.
37
GENERAL ENGINEERING LABORATORIES, LLG GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.geLcom Certificate of Analysis Company: Conncticut Yankee AtomricPower Addrm:
Hiddam Neck Plant 362 InJun Hollow Road East Hamptoc, Connecdeut 06424 CoanacI Mr. Pete Hollenbeck PwjecLe SoUs PO# 002332 Report Date: July 1. 2004 Page 2 of 2 Client Sample ID:
Sample I:
952440040F 114103006 Ptpicbt:
YANKOSO4 C Vleinftl YANKOO1 Vol. Racy.:
7 Parameter QualIIer ResIt Uncertainty LC TPU MDA Units DF AnalystDate Tlime Bflt Mtd.
E Concentration of th target analyte exceeds the instument clibraton range.
H Analytical holding time cxcecded.
1 Indicates an estimated value. The result was greater than the dctection Limlt but less th the reporting limit.
U Indicates the target nalyte was analyzed for but not detected above tde detection linitL IA Uncertain Ideanillcadon rorgammnspectoscopy.
X Lab-specific qualifier-please see case narrative, data summary package or contact your project manager for details.
h Sample preparallon orpreservallon bolding timn exceeded.
The above sample is reported on a dry welghtbasis.
This dtareportbas been prepared and reviewcd in accordance with General EogineesingLaboratories, LLC standard operating procedures. Please direct any questions to yourProject Manager, Sarah Kozlik.
Reviewed by 38
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Chadeston CC 29407- (843) 6S-8171 -www.gol.com Certificate of Analysis Company: Connecticut Yankc Atomic Power Addres:
Haddam N{eck Plant 362 Injun Hallow Road East Hanpton, Connecticut 06424
Contact:
Mr. Pclc Hofenbeck Project:
SclU PO# 002332 Clent Sample ID:
Samele ID:
Matrix:
CollectDate:
Rccive Date:
Collector Moisture:
ReportDatc: July 1,2004 Page I of 2 95244000009FS 114103007 Sail 24-MAY-04 03-UN-04 Client 273%
lea:
YANKIOSW4 Mllnt VD:
YANKU01 VoL Racy.:
Parzameter Qualifier Result Urntrtaity LC TPU MDA Units DF AnalystDate Time Bmtch Mtd.
Rad Gamma pec Analyis Gammaspe4 Gamma, SolId-MFSS GAf & ALL FSS Actlnlum-228 U
0.00
+1-0Q170 0.123 4-.166 0.256 Ul Amerdcum-241 U
0.0335 tl-0.0969 0.0762 41-0.095 0l5o Blsmuth-212 0.641
+1 0.351 0.12S -- 0344 0.269 Bbsmuth-214 OA14
+1-0.0962 0.0289 +140943 0.0619 Cesium-134 U
0.0201
+/-0.0279 0.0204 +1-D.0273 O.D437 Ceflum-137 0.197 41-0.0465 0.0184 41-0.0455 om0l1 Cobalt-60 U
0.0169
+1-0.0173 0.0218 q-00169 Q0475 Europlum-lS2 U
-0.0344 4-.0597 0.0477 +-0.0585 0Q0998 Euraplum-154 U
-0.0261 4/-0.0669 OQ535 4/-0.0656 0.117 Europlum-lSS U
-0.00344 10.0542 0.0486 +1 0.0531 0.100 Lcad-212 0.562 41-0.0742 0.027 4/-0.0727 0.056 Lcad-214 0.524
+1-0.103 0.0338
+1-0.101 0.0709 Manganese-54 U
0.0124
+1-0.021 0.01Q 2 +1-0.0205 0.039 Wloblum-94 U
-0.00339 410.0195 0.0161 41-0.0191 Ut1343 Potasslum-40 12.3 1-1.26 0.155 1-123 0348 Radlum-226 0414
- 1-0.0962 0.02B9 +1-0.0943 0.0619 SUver-tO8m U
-0.01 41-0.0192 0.015 41-00138 0.0316 Thallium-20S 0217 40.0465 0.019 +*.0456 0.0402 pCI'g pCI/g pCllg pcilg PCi/g pCI'g FCI/g pCI'g pCI/g pCI/g pCI/g PCl/g pcl/g PC/g pCl/g pCl1g pCVg PC119 SRB 06/19/04 2149 339715 1 The follwing Prep Methods were performed Method Description Dry Soil Prep Dry Soll Prep GL-RAD-A-fll Analyst Date Time Prep Batch BSWt 0W04/04 150I 338587 The roUowhrng Analytical Methods were performed Method Description I
EMLIIASL300,4.S23 Notes:
The Qualifiers in tis report are defied as folows:
B Targctnnalytewoadetcctcdlnthcsamplcaswella theassodatedblnk.
1BD Flag for rsuts below the MDC or a flsg for low tracer rcovery.
E Concentlton of the arget analytc xceds the Instrument calbtion range.
39
GENERAL ENGiNEERING LABORATORIES, LIC GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charteston SC 29407 - (843) 5568171 -www.gel.com Certificate of Analysis Conpany: Connecticut Yankee Aalic Power Addnss:
HaddamnNeckPlant 362Injun Hollow Road East Hamptou, Connecticut 06474
Contact:
Mr.PcitelHollcubeck Projecte Sols P0# 002332 ReportDate: July l.2004 Page 2 or 2 Clieal Sample ID:
Sample 1D:
9524-0000-C09FS 114103007 PWpcc YANKl00504 Clent I:
AICO V.
YANK041 Vol. Racc:
Parnameter Qualfer Result Uncertainty LC TPU MIDA units DF AvalyistDote Ttme flatchbild.
H Analytical holding tunc exceeded.
J Indicates an estimated value. The mault was Erer than the detlon lt, but lc~s thn the nportng limlt.
U Indicates the tatget anndytc was analyzed for but not detected above the detection limit.
UI Uncerain Identl3fcation for gamma spectroscopy.
X Lab-specilic quillflcr-plcase see casm narrative, data summazy paeinge or contact your project manager for details.
h Sample preparation or preservation holding time exceeded.
The above sample is rcported on a dry weight badss.
Thi, data report hls been prepared and reviewed In accordance with General Engineering Laboratories, LLC standanrd opcrating procedues. Please dircct any qucstions to your Project Mnnager, Sarah Kozik.
Reviewed by 40
GENERAL ENGINEERING LABORATORIES, LLG GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 558-171 - www.gel.com Certficate of Analysis Company: ConnectcutcYanee Atomic Power Address:
ItaddamNeckPlant 362 IiJunHollowRoad Enst Hampton, Connecticut 06424
Contact:
M. Pete Iollenlc ck Projcct:
SollsP0#002332 Report Date: July 1. 2004 Page I of 2 Client Sample ID:
Sample ED:
Matrix:
Collect Datec Receive Date:
Collcctor:
Moisture:
952440000-011F 114103008 Soil 24-MAY-04 03-JUN.04 Client 3.61%
i ee:
YANKOOS04 AVoL :
YANK0 Vol. Recv.:
01 Pammeter QUtler Result Uncertainty LC TPU MDA Unitji DF AnalutDale Time Datch M.
Rnd Gamm Spec Ainmyds Gammaspec4 Goamun Soli dFSS GAM &AU FSS Actinlum-228 0.416
./-0.137 0.0481 4-0.134 0.103 Amedclum-241 U
-0.0756 4/.0.068 0.0575 +/-0.0666 0.119 Bismuth-212 0.347 41-0.180 0.101 W40.177 0.216 Blsmuth-214 0345 4140.0681 0.0237 4/-0.0668 0.0503 Cesdum-134 U
0.0352
+1Q.0245 0.0191 410.024 0.0402 Ceahm-137 U
-0.00595 4/-0.0158 0.0129 4/4.0155 0.0276 Cobalt-60 U
-00128 41/0.0176 0.0132
-0.0172 0.0292 Eurmplum-152 U
.0.0157 1-0.0375 0.0329 +1-0.0367 0.0691 Europlum-154 U
-0.0352 41-0.050 0.0382 4/-0.049 0.0837 Eurpium-155 U
0.0447 41-0.0409 0.0393 +1-0.0401 0.081 Lead-212 0.410
+14.0521 0.0203 4/-0.051I 0.042 Lead.214 0.441 41-0.0745 0.0236 4W0.073 0.0496 Mangtanse-54 U
0.0124
-I0.0185 0.015 +1-0.0181 0.032 Nioblun-94 U
0.00175 4/410148 0.0125 +1-0.0145 0.0266 Potassium40 13.6
+1-1.19 0.130 41-117 0.287 Radium-226 0.345 4M-0.0681 0.0237 41-0.0668 0.050 Sllvcr-108m U
-O.031 4/0.0123 0.0106
-0.0121 0.0225 TbaIluum-208 0.154
+1-0m045 0.0134 41-0.0338 0.0284 poi/g pcl/g pcllg pCl/g PCISg pCVg PUS/
PCl/g pCI/g pct/g pcl/g pcl/g pcilg pCI/s pcvg pCI/g PCi/g PCVg SRB 0W19104 2150 339715 1 The fotlowing PrEp Methods were performed Metbad Descripton Analyst Date T1me PrepBatch Dry Soil Prep Dry Soil Prep CILRAD-A-021 BSWI 06/04104 1508 338587 The following Analricul Methods were performed Method Defteptlon I
EMILASL 300. 4.523 Notes:
The Qualifiers In this report ae delined as follows:
D Trget annlyto wn detected l the amplo as wll s the asscated blank BD Flag for results below the MDC or a flag for low tracer recovery.
E Coacentrention of the target analytc exceeds the instrtment calibration range.
41
GENERAL ENGINEERING LABORATORIES, LLC GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Chadeston SC 2407 - (843) 5558171 - www.gecom Certifacate of Analysis Company: ConaecticutYankea Atomic Power Address:
HaddamNeckPlWnt 362 Injun Hallow Road East Haptmn, Connecticut 06424 Conncl Mr. Petc Hollenbcck Project:
Sols PO# 002332 ReportDate: Julyl 2004 Page 2 at 2 Clicnt Sample O:
Sample 1D:
9524-000001 IF 114103008 PrpTect YANK00SO4 Cl ent %D: YANKOOI Vol. Recv.:
Parameter Qualifier Result Uncertainty LC TPU MDA Units DPf AnalystData Time Dateh Mtd.
H Analytical holding time exceede*
I Indicates an estimated value. The result was greater than the detcction limit, but les than the reporting limit.
U Indicates the target analyte was analyzed for but not detected above the detection limit U1 UncertaIn identificnoan for gma spectxnscopy.
X Lab-specific qualifier-please acc cue narrative, data mmunasy package or contnet your prolect manager fordetnils.
h Sample preparation or preservation holding time exceeded.
_ he above sample is reported on a dry weight basis This data report has been prepared and reviewed In accordance with General Engineering Laboratories, LLC standard operating procedures. Please direct any questions to your Project Manager, Sanh Kozlit Reviewed by 42
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Chareston SC 29407 - (843) 655-8171 - ww.gel.com Certificate of Analysis Company:
ConnectIcctYankee Atomic Power Address:
Haddam NeckPlant 362 Injun Hallow Road East Hauipton, Connecticut 06424 Contact Mr. Pete Hollcubeck Project:
So PO# 002332 ReportDatc: July 1,.2004 Page 1 of 2 Client Sample ID:
Samulc ID:
Matrix:
Collect Date:
Receive Date:
Collector Moisture:
9524-0000-012F 114103009 Sou 24-MAY-04 03-JUN-04 Client 4.58%
Protec YANK00504 Clicnt vD:
YANKOOI Vol. Recv_
Parameter Qualifer Result Unceertalinty LC TPU MDA Units DF AnalystDate Time Batch Mtd had Gam SpecAnalysis Gammaspec, Gamnum Solld-FSS GAM & ALLFSS Actalum-228 0.429
+W-0.122 0.0397 41..120 Amcriclum-241 U
0.0226
+1-0.0605 O.537 +40.0593 DBlsuth-212 U
0.084 W-0.161 0.096 41-0.158 Bismuth-214 0345 W1-0.0692 Q023 +1.0.0678 Cesium-134 U
0.00 41-O.0256 0.0156 4M.0251
_Ul Ceslum-137 U
0.0137
/-0.0216 0.0118 414.0212 Cobalt-60 U
-0.0113 Q1-0.0152 0.0114 4140149 Europlum-152 U
-0.00737
+-00354 0.0295 4/-0.0347 Europium-154 U
-I.011
+1-0.0524 0.0433 +/-QO.S14 Europlum-155 U
0.0055
+/-0.0369 0.0346 +/40.0362 lad-212 OA0S
+/-0.0549 0.0186 4140538 Led-214 0393 4/-0.0665 0.0251 1-0.0652 Moganesc-54 El 0.010
- 1-0.0154 0.136 I-0.0151 Nloblum-94 U
Q0.102 41-0.016 0.0115 4JO.0IS7 PotaMum40 1i.5 41-L02 0.0994 41-1.00 Radlum-226 0345
+/-0.0692 0.023 o0.0678 Silver-lOBm U
.0.006IS
+"-0.011S 0.0098 4/40112
_ Thillum-208 0.119
+/-0.0274 0.0129 41-40268 Q0863 0.111 0.205 0.0488 0.0332 0.0253 0.0255 0.06Z3 0.0935 0.0716 0.0358 0.0526 00291 0.0243 0226 0.0488 0.0209 0.0274 PCUS PC/g pCl/g PCI/g pcvg PCV9 pcl/g pCYg PCVA pC/g pCI1g PCUg SRB 0619104 2150 339715 1 The following Prep Methods were pierformed Method Description DMy Soll Prep Dry Sail Prep GL-RAD-A.021 Analyt Date Tlme Prep Dntch BSWI 06MI4104 ISOS 338587 The following Analytical Methods were pedfmed Method Description I
EMLHASL300,452.3 Note:
The Quifiers In this repont are defined as follows:
B Target analyte was detctead in the ample as wehslb the boclatedML J
3D Flag for results blow the MDC ora lag for low tracer r vey.
E Concentration of the target analytc exccc the Instrument calibration range.
43
GENERAL ENGINEERING LABORATORIES, LLC GENERAL ENGINEERING LABORATORIES, LLC 2040 Savaga Road Charleston SC 29407 - (843) 55658171 - w.gel.com Certificate of Analysis Campany: Conaecdcut Yankec Atomlc Power Address:
lMddamNcckPlant 362 Injun Hollow Road East Hampton, Connecticut 06424 ContLc-:
Mr. Pete Hollenbeck PrlecL Soils PO#002332 ReportDate: July 1,2004 Page 2 of 2 Client Sanplc ID:
Sample ID:
9524-0000-012F 114103009 hriectL YANKO504 Nlent ID:
YANKOOI Val. Rccv -
Parameter Qualler Result Uncertainty LC TPU MbDA Units DF AnalystDate Time DatthMtL.-
H Analytical holding time exceeded.
I Indicates an estimated value. 'lMe result was greater than the detection limit, but less than the reporting limint U
Indicates the target nnalytc was analyzed for but not delecte ove the detion liniL Ul Uncertain identlficadion forgaxmaspectscopy.
X Lb-specific quallfcr plcase see case naffative, data summary package or contact your project managcr for details.
h Sample preparadon or preservation holding time exceeded.
The above sample Is reported on a dry weight basis.
This data report has been prepared and reviewed In accordance with General Engineering Lzboratorles, LLC standard operating procedures. Please direct any questions to your Project Manager, Sarh Kozilk.
Reviewed by 44
GENERAL ENGINEERING LABORATORIES, LLC GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407- (843) 658-8171 - www.gel.com Certificate of Analysis Company:
ConnectlcutYankc Atomic Power Addruss:
Haddam NeckPlant 362 Inun Hallow Road East Hampton, Canuccicut 06424 Contact M.PktcHollenbcck Project:
Soils PO# 002332 Report Date: July 1. 2004 PagC I of 2 Client Sample ID:
SampielD:
Matdx:
CollectDnte:
Receive Date:
Collector:
Moistur:
9524-00O-14F 114103010 Soll 24-MAY-04 03-JUN-04 Client 4.18%
Pro ect YANXOOS04 CUnt cD:
YANK001 VoL Rrcv.:
Paramnetr Quallfer Result Uncertalnty LC TPU bDA Unlits DF AnalystDate Time latch Mtd.
Had Gamma SpecAnalyls Gamwpec:, Gmwa, SadFS-S CAMA &ALL FSS Actinlumn-228 0565
+1-0.183 0.0668
+4/0.179 Amcdcium-241 U
0.0133
+1-0.0559 0.0462 W-0.048 Dlsmuth-212 U
0310
+1.-0398 0.187 41-0390 Blsmuth-214 0.433 41-0.115 0.0392 41-0.113 Ceslum-134 U
0.0307
- 1-0.0421 0.026 +/-.0413 Ceslum-137 0.06SI
+-10.0509 0.013 414.0499 Cobalt-60 U
0.00515
+/-0.0252 0.0214 41-)M47 Eamoplum-152 U
-. 0M9
+4-0.0583 0.0498 +1.OS71 Euraplum-154 U
0.0204 4/-0.0792 0.0675 4/.OT76 EuraplUMl55 U
-0.00283
+1-0.0614 0.0544 +P0.0602 Lead-212 0.525
+1.0.0767 0.0276 +1-0.0751 Lcd-214 0.542
+1-0.0996 0.035 +4/0.0976 Mnanganec-54 U
.00683 4-0.0258 0.0218 +1.0.0253 Nioblum-94 U
-0.00512 41-0.02 0.018 +1-0.0218 PotasslmA40 14.1 41-135 0.172 W-132 Radlm-226 0.433
+/-0.115 0.0392 t-0.113 Salver-103m U
-0.00758 1-0.0201 0.0169 4/4.0197 Thallium-208 0.194
+1-0.0448 0.0203 +-0.0439 0.145 0.0946
'0395 0.A29 0.0553 0.0o86 0.0469 0.104 0.146 0.112 0.72 0.0734 0.0466 0.0395 0386 0.0829 0.0357 0.0431 pC0g prllg pC/g pCOg pC1g pCVg pCYS pC/g pCUg pCUg pCl/g PCag pcilg pC/g pOIg pCVg pC~g SRB 06/19104 2151 339715 1 The following Prep Methods wer performed Method Description Dry Soil Prep DTy Soil Prep 0L.RAD-A.021 A
lpyst Dale Time Frep Bauch BSWI 0604U0 1508 338587 The feuowlng Analyffcal Methods were performed Method Description I
EML HASL 300,.453 Notes:
_ 'M Qualifiers in this report are defined as follows:
B Taget analyto was detected in the samplc 8s wel as the associated blanL.
j BD Iag forults below l MOC or a ag (orlow ruecacovcry.
E Concentrailon of the target analyte exceeds the instiument calibradon nge.
45
GENERAL ENGINEERING LABORATORIES, LLC GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 -www.geLcom Certifcate of Analysis Company: ConnectlcutYankee Atomic Power Address:
HaddamNeckPlant 362 INlun Hollow Road East Hampton. Coanuedcut 06424
Contact:
Mr. Pete HoUcabeck Project:
Soals PON 002332 Client Sample 1D:
SampleED:
Report Date: July 1.2004 Page 2 of 2 9524SOt-014F 114103010 Ppect YAM54 Ciaent ID:
YANK00l Vol. Recv.:
anmmeter Quallhler Result Uncertabnly LC TPU MDA Units DF AnnlystDate Time DatchMid.
H Analytical holding time exceeded 1 Indicates an estimated value. Thz result was greater than the detection limit, but less than the reporting linuit U
Indicates th target analyte was analyzed for but not detected above the dclectioa limit.
UI Uncertain Idendficadon for gamma spectroscopy.
X Lab-specific qualifier-please see case narrative, data summary package or contact your project manager for details h
Sample preparation or presernatton holding time exceeded.
TMc above sample Is reported on a dry weght basis.
This data report has been prepared and reviewed In accordance with General Engineering Laboratories. LLC standard operating procedures. Please direct any questions to your Project Manager, Sarah KoZilC.
- VfA Ci Q/2" Reviewed by 46
GENERAL ENGINEERING LABORATORIES, LLC GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Chnrloston SC 29407- (843) 555-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address:
Haddam Neck Plant 362 InJmu Hollow Road East Hfanptc, Connecticut 06424
Contact:
Mr. Pete Hllocnbcck Proct:
Soils POC02332 CMeat Sample ID:
SomRlc ID:
Matri:
Collect Date:
Receive Date:
Collector.
Moisture:
ReportDate: July 1,2004 Paoe 1 of 2 95240WI.0151F Prolect YANlC00504 114103011 ClicntlD:
YANKOOI Soil Vol. Recv.:
24-MAY-04 03-JUN-04 Client 9.28%
Parameter Qualfler Rsult Uncertainty LC TPU MDA Units DF AnalystDate Tnme Bateh Mid.
Rad GaCma Spec Analysis Gammpc4 Gamma, Solld-FSS GAM & ALL FSS Actlnium-228 0.571 414143 0.0517
+/-J140 QllO Araericium-241 U
0.0385
+1-0.0878 0.0788
+/-0.036 0.163 Blismulh-212 0.416
+1-0.181 0.0845 410.177 0.182 Birmuth-214 0.465 41-0.0767 0.02
+1-0.0752 0.0474 Ccslum-134 U
0.0204
+-0.0288 0.0164 +/0.0282 0.0347 Ceslum-137 0042
+1/0.0278 0.015 +1-0.0272 0.0316 Cobalt-60 U
-0.00277
+1-0.0169 0.0139 +/-Q.0165 0.0304 Europlum-152 U -0.00488
+1.0.0414 0.0352 +/.0406 0.0737 Europiun=4S4 U
0.0164
+1.0.0504 0.0439 +10.0494 0.0951 Europhum-tSS U
0.0504 4Q00604 0.038 W4-0.092 0.0737 Lcd-212 0554
+1.0.0736 0.0226 +4-0.0721 0.0468 Lead-214 0.581 4/-0.0867 0.m44 4/-0.0849 0.0512 Maaganesc-54 U
0.00543
+1-0.0165 0.0142
-10.0162 0.0302 Nloblum-94 U
0.0023
+1-0.0134 0.0116 +1-0.0132 0.0247 Potassium40 11.1
+t-1.08 0.112 41-1.06 0.251 Radium-226 0.465 1-0.0767 0.0223 +t-0.0752 0.0474 Silver-lOtm U
-0.00512 W-0.0121 0.0105 +1-0.0119 0.0223 Thallium-208 0.178
/40386 0.0129 +/O0.0379 0.0273 pLrg pC11g pCitg pCl/g pC/g pcifg pCM/
pCI/g pCUg PCrk pCUg pcvg pci" pCV9 SRB 06119/04 2151 339715 1 Thefolowing Prp Methods were performed Method Dry Soil Prep Description Dry Soil Prep GL-RAD-A-021 Analyst Date Itme Prep Batch WSWI 06104/04 1508 338587 The aollowbig ASaltical Methods wre performed Method Deseription 1
EML HASL 300,452.3 Notes:
Mhe Qualifiers in this repotar defined as follows:
B Target annlyte was detected In the sample as well as the associated blank BD Flag for Inaulu bclow tho MDC or a lg f tow tracr covcry.
E Concenation of the target analyteexceeds the nsrmetcaliaon rage 47
GENERAL ENGINEERING LABORATORIES, LLC GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - ww.galcom Certificate of Analysis Company: ConnecticutYankee Atomic Power Address:
Hmddam NeckPlant 362 Injun Hollow Raad East Hampton, Connecticut 06424 Contact Mr. Pete Hollenbeck Project:
Solls PON 002332 RcportDate: July 1.2004 Paec 2 of 2 Client Samplc ID:
Sample ID:
9524-0000-015F 114103011 POicc:
YANKOO504 C eotl.D: YANK Vol. Rmc.:
0 Parameter Qualiler Result Uncertalnty LC TPU MDA Units DF AnraltDule Time BatchMLd H
Analytical holding time exceeded.
J ITdicas an estimated value.
he rsult was greater than the detction limit, but less than thc MrportDg lniiL U
Indicates the target analyte was analyzcd forbut not detcted above the detection limit.
UI Uncrtain ldcndllcation forgamma spectroscopy.
X Lab-specific qualifler-plcase sec cas nartive, data umunary package or contact your projcct manager for detais.
h Sample preparation or preservation holding time exceeded.
The above sample Is reported on a dry weight basis.
This data report has been prepared and reviewed In accordance with General Engineering Laboratodes, LLC standard operating procedures. Please direct any questions lo your Prject Manager, Sarah Kozilk Reviewed by 48
GENERAL ENGINEERING LABORATORIES, LLC GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gal.Com Cerfficate of Analysis Company: Connecticut Yankee Atumic Power Address:
HFadmNecPlant 362[njunaHollowlRoad But Harpton, ConnectIcut 06424
Contact:
Mr. Pete Haltenbeck Project:
Soels PON 002332 Report Date: July 1.2004 Page I of 2 Client Sample ID:
SamnmeID:
Collect Date:
Receive Dant Collector:
Moisture:
9524-0000.0221 114103012 Soil 24-MAY-04 03-JUN.04 Client 6.96%
Pi ojecL AN:OO Clet D:
YANKOl504 Vol. Rec.:
Parameter Qualifter Recult Uncertalnty LC TPU MDA unils DF Analystmat Time ButchMtd.
Rad Ganma Spec Analyss Gammmrpec, Gamma. Soltd-FSS GAM & ALL FSS Actinfum-229 0396
+1-0.131 O.479
+1.0.129 0.103 Americlum-241 U
0.0158 4t-0.062 0.0541 4/-0.0608 0.112 Bismtlh212 0235 4/-0.163 0.104
+1-0.160 0.220 9unulh-214 OA70
+1-0.0807 0.0233 +/-0.0791 0.0494 Ccslum-134 U
0.00
+1-0.0221 0.0159 4/-0.0216 0.0338 UI Ceslum-137 0052
+1-0.020 0.0156 +1.0.0196 0.0329 Cobalt-60 U
-O.0155
+1-0.0162 0.0116 +1400159 O.D15 Eumcplum-15Z U
0.00524 41-0.0389 0.0327 +1-0.0381 0.068S Euxoplum-154 U
-0.0411
+1-0.0546 0.0415 +1-0.0535 00903 Eumeplum-155 U
0.0532
+t-0.060 0.035 +1-0.0588 0.0723 Lead-212 0A68
+loo0561 0.0198 +1-0.0549 0.0409 Lead-214 0.587
+1-0.0866 0.0233 +1-0.0M4B 0.0489 Manganese.54 U -0.000163 41-0.0167 0.0137 +/-0.0164 0.02-9Z MNoblum-94 U
0.0109
+1-0.0136 0.0121 +/-0.0133 0.0256 Potnsslum40 11.1
- t-1.05 0.127
+/-1.03 0.282 Radlum-226 OA70
+.0.0807 0.0233 +1-0.0791 0.0494 Sllvcr-108m U
Q00515
+10.0126 0.0114 +/-0.0124 0.0239 Tballium-209 0.164 41-0.0323 0.010
+/-0.0317 0.0221 PCig pCUg Pag pCUg pcug POg PCil8 pCUg Pcug Par9 PCU9 pCI/
pCUg SRB 06/19104 2152 339715 1 he fboiowM Prep Methods were perormed Method DescsipUan Analyst Dale Time Prep BDtch DrySoil Prep DrySoal Prcp 01RAD-A-021 BSWI 06104104 150I 33857 The following Annlytcal Methods were verformed Method Description I
EML HASL 300. 45.273 Notes:
The Quallfle in this rport ax delined ns follows:
B Targ mnlytc was decctd In the ampleas wcal as hca socaed blank.
BD Flag for rults below e MDC era flag for low 1t eovery.
E Concentrloa of the turget ailytc c eds he ntnnment calraton mnge.
49
GENERAL ENGINEERING LABORATORIES, LLC GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407- (843) 556-8171 - wwwgel.com Certificate of Analysis Company: ConcellcutYankee Atomlc Power Addres s:
Hiddam Neck PlInt 362 Injun Hallow Road East Hampton, Connecticut 06424 Contact Mr. Pete Holleubeck Project:
Salls PO# 002332 RcportDate: July 1,2004 Page 2 of 2 Client Sample ID:
Sample ID:
9524-000-21 114103012 EPrject:
YAN-00504 Cle-nt I:
YANK001 Vol. Recv.:
Parameter Qualiler Rsult Uncertainty LC TPU MDA units DF AnalDysDate Tme Batch Mrd.
H Analytical holding time exceeded.
J Indicates an estimnted vlue."T'he rsult was greater than the detection limit, but less than the reporting limit.
U Indicates the btget analyte was nnalyzed for but not doteted abovc the detection limil.
UI Uncertain identification for gamma spectroscopy.
X Lab-specific qualifier-please see case narradve, data summary package or contact your project manager for details.
h Sarnple preparation or preservation holding time exceeded.
Mm above sample Is repored on t dry weight basis.
hlis data report has been prepared and reviewed In accornlanc with General Engineering Laboratories, LLC standard operating procedures. Please direct nay questions to your Project Manager, Sarah KozMlil Reviewed by 50
GENERAL ENGINEERING LABORATORIES, LLC GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407- (843) 5S58171 -www.geLcom Certfficate of Analysis Company: Connecticut Yankee Atoml: Power Addres:
Hathfam Neck Plant 362 injun Hollow Road Eat Hampton, Cooneedcut 06424 Contacl:
Mr.PeteHolllcbeck Project:
Soils PON 002332 Client Sample D:
Samplc ED:
Matfix:
CollectDate:
RecsdveDale:
Collector:
Moisture:
Report Date: July 1, 2004 Page 1 of 2 9524-0000-019F PT iec YANK00504 114103013 Col eq YANKOO 1
Soil Vol. Rr.:
24-MAY-04 03-JUN-04 Client
- 13.2%
Parameter Quallfer Result Uncertainty LC TPU MDA Units DF AnalystDate Time BatchMtd.
Rnd Gamma Spec Analysi Gammapec, Gwnnunn SolJd-FSS GAM &AL FSS Actdum-228 0.661 41-0.164 0.0408
+1-0.161 Americum-241 U -0.000717 41-0.120 0.074
+1-0.118 flisruth-212 0544 414-73 0.0904
+/-0J69 Blsmuth-214 0.751 4/40963 0.0218 +1-0.0943 Ceslum-134 U
0.00 41-0.0268 0.0166 +1-0.0263 Ul Ceslum-137 0.116
+/-0.0258 0.0114 +1.0.0253 Cobalt-60 U
0.0129 4-0-.0257 0.013S +10.0252 Buropium-152 U
0.0133 4/-0.0442 0.0334 1-0.0433 Europium-154 U
-000367
+1-0.0495 o.m5s 41.0.0485 Europkun-155 U
0.0456 41-0.0508 0.0445 +I4Q.0498 Lcad-212 0.703 41.0.0721 0.0207 +41..070 Lc z-214 0.949 41-0.106 0.OZ44
+10.104 bManganese-S4 U
ONS5
+1-0.0157 0.0133 +1-0.0153 Nlobtum-94 U
0.0137 4/Q0.0134 0.0119 +14.0131 Polasslum40 143 W1-124 Q0924 4/-1.21 Radlum-226 0.75O 4-0.0963 0.L211 +IQ0.0943 Sllvcr-108ir U
0.00281
+1-0.0132 0.0111
-0/0.013 ThalIum-208 0.218
+/-0.0398 0.0121 41-OM9
.086 0.152 0.190 0.0455 0.0345 0.0238 0.0287 0.0691 0.0755 0.0911 0.0425 0.0504 O.OZ78 0.0248 Q022 0.0455 0.0231 0.0252 pCl/g pCi/g pCUg pCi/g pcig pCi/g pcl/g pCi/g pCi/i pCYg pci"e pCilg PCL/g PCUS pcig pCVg Dearg SRB 06119104 2152 339715 I The rollowing Prep Melhods were performed Mdethod Description Analst Date Time Prep Batch Dry Sonl Prep Dry Soil Prp GILRAD-A-021 BSW1 06104/04 1508 338537 The following Atalytical Methods were performed Method Descriptlon I
EML HASL 300,4523 Notes:
The Qualifiers in thUs rcport aue defined as follows:
I8 Targot analyto was dctcd in umplo as wdl Ias sclatcd blank.
BD Flag for results blow the MDC ora flag for low tracer rcovery.
E Concentrtion af the tagetmnalyte exceeds theIstrument callbration range 51
GENERAL ENGINEERING LABORATORIES, LLC GENERAL ENGINEERlING LABORATORIES, LLC 2040 Savage Road atarleston SC 29407 - (843) 556-8171 -www.a9tcom Certificate of Analysis Company: Connecticut Yankee Atomic Power Addres:
HaddaraNcckPlant 362 InJun Hollow Rnad East Hampton, Connecticut 06424
Contact:
Mr. Pte Hollcabeck Project:
Soils POD 002332 ReportDatc: July 1,2004 Page 2 of 2 Client Sample ID:
Sample ID:
9524-000-019F 114103013 Proect:
YANKOOS04 CLet YANK001 Vol. Recv.:
Paraneter QuaMer Result Uncertainty LC TPU MDA Units Dr AnalystDale Time Butca hMtd H
Analytical holding time exceeded.
J TIdicates an cstinmated valuc lihe result was greater than the detection limlt, but less than the reporting limit.
U Tndicates the tntgct analyte was analyzed for but not detected abovo the detection limit.
UI Uncetain Identification for gamma spectroscopy.
X Lab-speciic qualfier-pleas s casc native, dat smunry packago or contact your project manager for details.
h Sample preparation or preservation holding time exceeded.
The above sample Is reported on a dry weight basis.
This data report has been prepared and reviewed In atccordancc with Gcnernl Engineering Laboratories, LLC standard operating procedures. Please direct any questions to your Project Manager, Sarah Koz3lk.
Reviewed by 52
GENERAL ENGINEERING LABORATORIES, LLC GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charlostan SC 29407 - (843) 558-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address:
HaddamNeckPIni 362 Wan Hollow Road But Hampton, Connecticut 06424 Contact Mr. Pete Hollenbeck Project:
Soils Po0002332 Report Date: July 1. 2004 Page I of 2 Client Sample ID:
Sampla ID:
Matix:
CollectDatc:
Receive Date:
Collector.
Moisture:
9524-0000-003F PTectL YA1IK00S04 114103014 Cticnt ID. YANKOOt Sail Vol. Recy.:
25-MAY-04 03-JUN-04 Client 18.7%
paramtter Qualifier Result Uncertainty LC TPU MDA Units DF Analystate tme Datch Mid.
Rad Ganna Spec Analysis Canmaspc, Gamma, Solid-FES GAU A ALL FSS ActinIum-228 OASS
+4.185 0.0617 +/-0.182 0.133 Americiom-241 U
0.0212 4-0.147 0.116 4+0.144 0M9 Bismuth-212 0353
+41.193 0.126
+4-0189 0269 BlsTiul-214 0550
+1-0.0989 0.0278 t.10969 0.0594 Ccari-134 U
0.030
+J-00311 0.0194 +1400305 0.0413 Ceusum-137 0.392
+/-0.0607 0.0153 +Q.0.0595 0.0329 Cobalt-60 U
-0.0131 4-0.0214 00163 41-0.021 00361 Eureplum-152 U
-0.0132
+I-0.0551 0.0467
+/10.054 0.0978 Europlua-154 U
.0.0238
+1410731 0.0495 +1-Qa7i6 0.109 Europlum-tS5 U
0.0336
+1-0.0631 0.0549 4/40618 0.113
-1d-212 0.535
+1-0.0729 0.0269 +/4-0714 0.0558 Lead-214 0.601 414101 0.0312 41-.0989 0.0656 Mangunese-54 U
0.0251
+10.0222 0.0143 41.0.017 0.031 Niobtum-94 U
.O.42
+1-0.0179 0.0152 4140176 0.0323 Patuslam-40 11A
+/-1.11 0.141
+1-1.16 0.318 Radium-226 0.550
+/.0.0999 0.0218 4140969 0.0594 Silver-108m U
0.0103
+1D0.0191 0.0167 1-.0187 0.03S1 rhillimn-208 0.171
+/-0.0449 0.0142 /0.0439 0.0306 pCVg pC/g pClg pCl/g pC/g pC11g parg pCug pc/zg pC/g pCVg pcl/g pCits pcl/g pCrg pCI/g pOCg pcug SRB 06118104 1057 339714 1 The foflowbn Pntp Methods were pulormed Method Descriplon D
Dsy Soil Prep Dy SoU Pep GLRAD-A-021 Anyt Date Time Prep Batch BSW1 06104104 1510 33858 The tolowlng Analytical Methods were performed Method Description I
EMLHASL 300.4.52.3 Notes:
The Quallflers in this report arn deined as follows:
B Target analyta was deteted in the samples well s thc associated blnn BD F:>
lag forrsults below the MDC or ags forloaw rbcovcry.
E Concention of thc ingct yntlyt exceds the Instnnie n calibraticn rangc 53
GENERAL ENGINEERING LABORATORIES, LLC GENERAL ENGINEERING LABORATORIES, ILLC 2040 Savage Road Charleston SC 29407- (843) 5568171 - www.gel.com Certificate of Analysis Company: ConneedcutYankec Atomic Power Address:
Hddam Neck Plant 362 njun Hollow Road EastHunpton, Connecticut 06424 Canact:
Mr. Pcte Hollkabeck Prqject:
SoHs POP 002332 Report Date: July 1, 2004 Page 2 of 2 Client Sample ID:
SamplelD:
9524-ODOB-003F 114103014 PicttiD:
YANKl0504 Vol. RecYA Pnrameter Quaiier Result Uncertainty LC TPU MDA Units DF AnalstDate Time Dateh Mtd.
H Analytical holding time exceeded.
J IndicAtes an estimated value, The result was greater than the detection limit, but less than the reporting limiL U
Indicates th target analyto was analyzed for but not detected above the detection limit Ul Uncertain identifition for gamma spectroacopy.
X Lab-specific quafier-please *eo cacs aunailve, data suumnasy package or contact your project manager for deails.
h Sample prepasalion or preservation holding time exceeded.
The above sample Is reported on a day weight bads.
This data report has been prepared and retiewcd In accordance with General Engineering Laboratories, LLC standard operating procedures. Please direct any questions to your Project Manager, Sarah KozliL lleviewed by 54
GENERAL ENGINEERING LABORATORIES, LLC GENERAL ENGINEERlING LABORATORIES, LL C 2040 Savage Rond Charleston SC 29407- (843) 65588171 -www.gel.com Certificate of Analysis Company:
Connecticut Yankee Atomic Power Address:
Haddam Neck Plant 362 Injun Hollow Road East Hampton, Connecticut 06424 ContactL Mr. Pete Holleabeck Prnjectc Sails PO# 002332 client Sample Mf.
Samele ID:
Matnx:
Collect Date:
Receive Date:
Collector Moisture:
Repoit Date: July 1,2004 Page I of 2 9524-0000-404F Ulect:
YANK00504 114103015 let iD:
YANKU01 Sail Vol. Recv.
25-MAY-04 03-JUN.04 Client 30.8%
Paraureter Qualtifer Result Uncerlalnty LC TPU IUDA Units DF AnnlystDate Time DadhlMid.
Rad Gamm Spec Analysts Gammaspc. Canmma. SolIU-FSS GU7A AU FSS Actinium-228 0.537
+1-0.165 0.0554
+1-0.61 Americhum-241 U
0.06a 5
+1-0.147 0.11t
+1-0.144 Blsmulh-212 U
Q00737 41-0236 0.146
+f-0.232 lsmuth-214 0334
+1-0.0919 0.0292
+.0.090 Ccslam-134 U
0.00929
- 1-0.0223 0.0189 +/-0.0219 Ccsium-137 a646
+1-0.0769 0.0182 44.0754 Coblt-60 U
0.00924 41-0.0209 0.0133 41-005 Europuim-152 U
-0.00509
+1-0.0583 00465 41.0.0571 Europlum-154 U
0.0307
+1-0.068 OO091 +14.0667 Europium-15S U
Q.0449
- /-0.0584 0.0516 4-10572 Lead-212 0.494
+1-0.0752 0.0249 4*t-OD737 Leid-214 0.431
+1-0.0913 0.0298 4/40895 Manganese-54 U
0.00376
+/-.q0239 0.0173 4/-0034 Nlobluu-94 U
Q.0012 4+-0.0182 0.01SI 41/0.017S Patasslum40 11.2
+1-.26 0.174
+1-1.23 Rzldium-226 0.334
+1-0.0919 0.092.1-0.090 Silver-108m U
0D189
+/-0.0138 0.0149 41-0.0184 Thallium-208 0.164 41-0.042 0.0161 +/-0.0412 0121 0.231 0310 0062S 0.0407 0.0387 0.0405 0.0978 0129 0.107 0.052 0.063 0.0373 0.0322 0389 0.0625 0.0315 0.0345 pCI/i PCl/g PCli' PCl/g PCv9 PCI/i pa/s pC?/g pCI/g PCI/g pCI/g pcl/g pCI/g pCi/g
- pcl1, PC1/g PCUS PCI/g SRB 06118/04 1053 339714 1 Tbe following Prep Methods were performed Method DescripUon Analyst Date TIme Prp Batch DMy Soil Prep Dry Soil Prep 0L.RAD-A-021 BSWI 061D4104 1510 338588 The following Analytical Methods wera performed Method Descriptlon 1
liML HASL 300,4.523 Notes:
The Qualifiers in this report are defined as fellows:
B Target nnalyte was detected In the sarnple as well as the assodated blnk.
BD Plng for rsults bdlow th MDC or a Dag for low cer recovey.
E Concenation of tbe target analyte exceeds the instrument caibration ange.
55
GENERAL ENGINEERING LABORATORIES, LLC GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Chadtoaon SC 29407 - (843) 556-8171 - www.gLcom Certificate of Analysis Company:
Connecticut Yankee Atomic Power Addus:
Haddam NeckPlant 362 Injun Hollow Road East Hamptao, Connecticut 06424
Contact:
Mr. Pedc Hlllenbeck Project:
Soils PON 002332 Report Due: July 1,2004 Pago 2 of 2 Client Sample ID:
SampleID:
9524-0000-004F 114103015 PTi'lct YANKOOS)4 CliCt ID:
YANKODI Vol. Recv.:
Parameter Qualifier Result Uncertainty LC 7TU MDA Unils DF AnalyulDate Time BatchMid.
H Analytical holding time exceeded.
J Indicates an estimated value. The result was greater than the detection limlt, but less than the reporting limit.
U Indicat the target mnalyte was analyzed for but not detected above the detection limit.
UI Uncertnin identification forgamnutspectmscopy.
X Lab-specific qualifter-pleaesee caue narerative, ta summary package or contct your project manager for details.
h Sample preprtion orprcsezvailon holding timre exceeded.
The above sample Is reported on adhy weight basis.
This data report has been prepared and reviewed in accordance with General Engineering Laboratories. LLC standard operating procedures. Pleasc direct any questions to your PromcctManager, Sarah KoWilk Reviewed by 56
GENERAL ENGINEERING LABORATORIES, LLC GENERAL ENGINEERING LABORATORIES3 LLC 2040 Savage Road Charlaslon SC 29407 - (843) 55B 8171 -
nmW.ga1.com Certificate of Analysis Company: ConnectlicutYankco Atomic Power Addre":
lhddam Neck plant 362 Injun Hollow Road East lampton. Connecticut 06424 Conac Mr. Pete Hollenbeck Project Soats POW 002332 Report Datec: July 1,2004 Page I of 2 Clicnt Sample ID:
SanmeleID:
Matix:
Collect Date:
Reccive Date:
Collector.
Moisture:
9524-0000.DI3FS Pg~iecI YANKY0504 114103016 Vol. ct W:
YANK001 Sall Vol. Reev.:
25-MAY-04 03-JUN-04 Client 212%
Parameter Qualilner Result Uncrtalnly LC TPM MDA Units DV AnnlysWtDate Time DntchMtd.
Rad Gamma Spec Analysis Gawmnawpc Gamma, Solid-FSS GAU & ASLI FSS Actilum-228 0.6S0
+1-0.166 0.046 +-0.162 O.101 Ameidcurn-241 U
0.779
+1-0.123 0.0957
+J0.120 0.199 Bismuth-212 0.458
+1-0.391 0.115
+-0383 0.247 Bismuth-214 0.502
+J-O.0873 0.027 +r.o0ss6 0.0578 Cesium-134 U
0.013
+1-0.023 0.0201 4/-O.225 0.0428 Cesium.137 0.346
+.4.033 0.018
+/40.022 0.0599 Cobalt-60 U
0.0153
+1-0.0219 0.0195 44.0214 0.0427 Europlum-152 U
0.0218
+/-0.0534 0.04 41-0.0523 0.0936
- uroplum-154 U
-0.0347
+41/0603 0.0464 41-0.0591 0.103 Eurapiun-155 U
0.0753
+1-0.0576 0.0528 +0.056 0.109 Lead-212 0.59S
+/-0.032 0.0291 +1-0.0815 0.060 Lead-214 0.614 4/-0.107 0.0308 4-0.105 0.0647 Manganese-54 U
0.00286 41.0.0186 0.0154 +/-0.013 0.0333 Moblum-94 U
0.00402
+-0.0159 0.0135 +14.0156 Q0Q29 Potalum40 11.0 1-1.20 0.143 4-1.17 0323 Radlum-226 0.502
+1-0.0873 0027 +/-0.0156 0.0578 Silver-lOSm U
-0.00943
+/.0.0162 0.0134 41-0O159 0.0234 Tballhm-208 0.165
.- 0.0393 0.0156 41.0.0385 0.0333 pCJ/g pcI/g pCl/g p~ilk pCI/g pCL/g pCUg pCI/g pCI/g pCi/g PCL/g pCI/g PCUS pC1/g PCi/g pCl/g Pcl/g pCVg SRB 0611V04 1143 339714 1 The foltoD Prep Methods were pnforned Method Desceptlau Analyst Date Time Prep Batch f
DySoil Prep Dry Soll Prep OL.RAD-A-021 BSWI 0604104 1510 338588 Mh vllowtog Analytical Methods wer performed Method Descdption I
EML HASL 300.4523 Notes:
The Qualifiers In this report ar defined as follows:
B Target analyto was detected in Ihe ansple as we as the assoclated blank.
- D Flnag for zus below tho MDC o a nng for low mrccr aovcry.
E Concentation of the tret annlyte exceeds the instrument callbration mnne.
57
GENERAL ENGINEERING LABORATORIES, LLC GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 55-171 - www.geLtcom Certificate of Analysis Company: Comnecticut Yankee Atomic Power Address:
Haddam Neck Plant 362 Injun Holiow Road East HimVon, Connecticut 06424
Contact:
Mr. Pete Hollenbeck Project Solls POMt 002332 ReportDate July 1.2.004 Page 2 af 2 Client Sample 11):
Sample 11:
9524-0000-013FS 114103016 FPiect YANK005O4 CUVeat 11:
YANKCO1 Vol. Recy.:
Parameter QualWer Result Uncertainty LC TPU MDA Units DF AnaualDate Time BatchMid.
H Analytical holding time exceeded 3 Indicates an estinaed value. The rsult was greater than the detection limit. but less than the reporting limit.
U Indlcates he target analytz was analyzed for but not dedcted aove the detection liiL Ut Uncertain identification for gamma spectroscopy.
X Lab-specific quliiicr-plemase see cas narrative, data sunmary package or contact yourproject managerfordetlnls.
h Sample preparallon or prsesvaton holding time exceeded.
The above sample is reported on a dry weight basis.
This data report has been pmpard and reviewed in accordance with General Engineering Laboratories, LLC standard operating procedures. Please direct any questions to your Pkqject Manager, Sarah Kozlik.
Reviewed by 58
GENERAL ENGINEERING LABORATORIES, LLC GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Chatleston SC 29407- (843) 558 8171 -www.geLcom Certiicate of Analysis Company: Connecticut Yankee Atomic Power Addres:
Huddam NeckPlant 362 Injun Hollow Rolad EAst Hampton, Connecticut 06424 Contactr
- r. Pete Hollcabeck PwlIcet:
Soils Po W002332 Report Date-July 1.2004 Page I of 2 Client Sample 11:
SampleD:
Matnx:
CollectDate:
Receive Date Collector Moisture:
9524-0000013F 114103017 soil 25-MAY-04 03-JUN-04 Client 21A%
PT.ec0t YANK00504 Cle YANK001 Vol. Recv.:
Phrameter Qualifler Result Uncertainty LC TFU MDA units DP AsalystDate Time BatchMid.
Rad Gamma Spec Analysts Gamnmaspcc. Guinwma, SaIld-FSS GWf & AL FSS Actlnium-228 0.448
+1-0.194 0.0679 41-0.190 0.147 Anacdclum-241 U
0.0409
+1-0.107 0.0822 4t4.105 0.170 Bbimuth-212 0543
+/1OL323 0.154 41.0317 0329 Bismuth-214 0562 tl 0.122 0.0338 4I-0.119 0.072 Cedlum-134 U
0.0035
+1-0.0257 0O213 +f-0.M52 00459 Cesium-137 0378
+14.0558 0.0205 +I40547 0.0437 Cobalt.60 U
0.0101 41-0.0232 0.0203 4140227 0.0449 Eumoplhum52 U
- 0.0815 t/-0.0649 0.0484 +1Q0.0636 0.102 Europlum154 U
0.0533
+1-0m34 0.0662 41-01112 0.144 Europfum-nS5 U
0.0487 4/4-.0597 0.0539 410.0585 0.111 Le=-&212 0.452
+/.0.0816 O.M37 41-0.080 0.0697 Lead-214 0569
+ 0.123 0.0364
+1-0.120 0.0763 Manganese-54 U
0.016
+1-0.0235 0.0204 41-0.023 0.0437 Nloblum-94 U
0.00949
+1-.0196 0.0169 4/.0192 0.0362 Pomium-40 12.6 41-131 0.167
+/.1.28 0.378 Radlum-226 0562
+1-0.122 0.0338
+/-0.1t9 0.072 Silvcr-108m U
0.0111 41-0.0215 0.0179 +1.0.0211 Q0376 Thalllum-708 0.152
+10.0616 0.019 +.0.0604 0.0404 pcug PLUg pCI/g pCVg
- pcug YCISg FCUg pCUSg SRB 06/18/04 1143 339714 1 The followig Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dty Soil Prep OL-RAD-A-021 BSWI 06104104 1510-338583 The flowbing Analyffea Methods were performed Method Descriptlon I
EML HASL 3000 45.2.3 Notes:
Ihe Qualifies In this report arc defined as follows:
B Target analyte was deteced In the sample as well as he assocated blank.
VD Fag forrulc bclow tho MDC ara flag forlowu crrecovery.
E Canccntrntion of tho target aalyt excecds he nstument calibraton nge.
59
GENERL ENINEEING LBORAORIE, LL GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Cerfiflcate of Analysis Company: Conneicut Yank= Atomic Power Address:
Haddam Neck Plant 362 Inabn Hollow Rood East Hampton, Conneticut 06424
Contact:
Mr. Pete Hollenbeck PRmJcct:
Sails PO# 002332 ReportDatc: Julyl,2004 Page 2 of 2 Client Sarmple ID Sample 1D 9524-OOUO-013F 114103017 PCoiect YANK00504 CUent 6.
YANKO1 Vol. Rlcv.:
Parameter Qualifer Rcalt Uncertainty LC TPU MDA Unilts DF AnalyslData TIme Bateb Mtd.
H Analytical holding time excecded.
I Indicates an estimated value. The result was greater than dhe detection Maic, but less than the reporting limit.
U Indicates the target annlytc was analyzed for but not detected above the detection ImitL UI Uncertain Identification for gamma spectroscopy.
X Lab-specdfic qualifier-please see case narrative. data summary package or contact your project manager for details.
h Sample preparation or preservation holding lrne exceeded.
The above sample is reported on a dry weight basis.
This data report has been prepared and mrviewed in accordance with General Engineering Laboratades, LLC standard operating procedures. Plense direct any questions to your Project Managcr, Sarah Kozlik.
Reviewed by 60
GENERAL ENGINEERING LABORATORIES, LLC GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556 8171 - ww.gel.com Certificate of Analysis Company: Connecdtcut Yailwc Atomlc Power Address:
Haddam Neck Plant 362 lajun Hallow Road East Hampton. Coneccticut O6424 Contact Mr. Petw Hallenbeck Project Sols PMO00m332 Client Sample ID:
Sarnele ID:
Matix:
CollectDate:
Receive Dale:
Collector Moisture Report Date: July 1,2004 Paor I of 2 9524-0000-016F 114103018 Soil 25 MAY-04 03-JUN-04 CMcat 4.9%
EIojct.
YANK00504 Cl.ent RD:
YANKOOI Vol. Recv.:
Parameter QuaUler Result Uncertainty LC TPU ADA Rad GrunnSpec Analyis Gammapce Gamma, Solid-FSS JAM & ALL FSS Actinium-228 0.561
+1-0.138 0.0432 W/0.135 0.0921 Amedcium-241 U
-.00366 4,0.102 A0791 +140998 0.163 Blsnuh-212 0.433
+1-0.02 0.101
+1.198 0.213 Bismuth-214 0.434 41-0.0859 0.0251 +M-0.0M42 0.0526 Cesium-134 U
0.0306
+/40218 0.0167 4/".0214 0M0351 Ceslum-137 U
0.0124
+1.0146 0.0132 +4100143 0.0277 Cobalt-60 U
0.00163 41-0.0145 0.0123 +1-00142 o026s Europlum-152 U
.0.0103
+1-0.0402 0.0338 +1.0.0394 0.0706 Enroplum-154 U
.0.0879
+140471 0.07 41.0.0462 0.0693 Earoplum-US U
0007
+10.106 0.0467
-0.103 0.0962 Ladi-212 0.608
+t.0.0665 0.0208 +1.0.0651 0.043!
Leadz214 0.561
+1-0.0862 0.0236 -+/-0.0844 0.0493 Mangnnese-54 U
0.00719
+1-0.0177 0.0152 +1.0.0174 Q0319 Nloblun-94 U
0.013
+4-0.014 0.0126 41.0t37 0.0264 PoatssiunD40 15.1 4-132 0.112
+1-1.30 0.245 Rndium-226 0.434
+1-0.0859 0.0251 +1I0.0842 0.0526 Silyer-1011.
U 0.00395
+1-0.0135 0.011S 4.0.0132 Q0242 Thalfizmr-203 0.157
+/Q1355 0.0129 +/-0.0348 0.0272 Units DF AnalystDate Time Batldcltd.
pCsg pC/g pclvg PCVS PCag pCilg pClk pa/g pCvk pcllg pCIyg VCl/g pC~g pcl/g pd/g pOtg pC~g SRB 06/184 1217 339714 1 The following Prep Methods were ptrfortned Method DaerlpUon Dry Soil Prep Dry Soil Prep GL.RAD-A.021 Analyst Date Time Prep Batch BSWI 06M04/0M 1510 333598 The followfig AmalyticalMethods were peformed Method DacapUon 1
EMLHASL 300, 45.23 Note:
The QualfflenrI lbis report ue defincd as fMlows:
B Tget analyte was detected In thc sample as well as thec associated bnk.
HD Flag forn:sus below thc MDC or n(ag for lowt recovery.
E Concetratdon ofthc target analyt cxceeds thc instument calibmron rnge.
61
GENERAL ENGINEERING LABORATORIES, LLC GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 6569171 - www.got.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Add=es:
HaddamNeckPtant 362 Injun Hollow Road But Kamaptoa, Connecticut 06424 ContacL Mr. Pete Hallenbeck Prqject Seils P0# 002332 Client Sample ID:
Sample ID:
ReportDatc July 1,2004 Page 2 of 2 9524-0000-016F 114103018 PTpel YANK00504 Vol. Rac:
YANK001 Parmeter Qualier Result Uncertainty LC TPU MA Units DF AnalystDate Time Batch Mid.
H Analytical holding time exceeded.
J Indicat n estimated value. The rsultwLsgmatr thnl the detectionliralt, butless than the rcporting ilmlL U
Indicates the target analyte was analyzed for but not detected above the detection UnmIL Ul Uncertaln Identificadon forgamma spectroscopy.
X Iab-specific qualIfier-pcase see case narrative, data summary package or contact your projcct manager for deails.
h Sample prepamtion orpreservadon holding tnme excecded.
The above sample Is reported on a dry weight basis.
This data report has been prepared and reviewed In accordance with Gcneral Engineering Laboratories, LLC standard operating procedures. Please direct any questions to your Project Manager, Sarah Kozlk.
Reviewed by 62
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 55"8171 - www.gel.com Certificate of Analysis Company: ConnectiutYxnkc Atomcl Power Address:
Haddam.NeckPlant 362 Ijun Hotlow Road EBt Hamptoc. Connectfcut 06424
Contact:
Mr. Pctc HoIlcaibeck Pwlect.
Sols PO#02332 ReportDatc: July 1.2004 Page 1 of 2 Client Sample ID:
SamplelD:
Mail:
CollectDale:
Recelvo Date.
Collector Moishte:
9S24400 16FD 114103019 Soil 25-MAY-04 03-JUN-04 Client 7.75%
sPTiect YANKC00504
.n YANKO1 VoL. Racv.:
Parameter Qulmler Result Uncertalnty LC IPV MDA Units DF AnnlystDale Time BatchMtd.
Bnd Gamma Spec Analysis Gamarper, Gamma4 Solid-FSS GAM & ALL FSS Actinium-228 0550 t4tQ143 0.0414 41-0.140 Q0896 Amcriclum-241 U
0.0267
+/-0.0911
.Q0766 +1-0.093 0.158 Bismulh-212 0360 4.0.20 0.0952
+10.201 0.203 Bimuth-214 0515
+1-0.0805 0.024 +/.0789 0.0507 Cesium-134 U
0.0339
+J-0.0213 0162 +-Q0209 0.0344 Ceslum-137 U
0.00
+/4-Q032 0.0133 +1-0.0296 0.0281 UW Cobalt-60 U
3.0031
+1-0.0188 0.0131 41-00114 0.0289 Eroplum-1S2 U
0.0119 4/-0.0377 0.0339 4+0.0369 0.071 Europlum-154 U
-0.0249
+t-0.0508 0.0401 4".00498 0.0875 Europlum-1S5 U
0.0734
+t-0.062 om92 +/-0060S 0.009 Lcad-212 0.622
+/.00719 0.0182 +1-0.0705 0.038 Lead-214 0.599 4/40823 0.0238 +/-0.0906 0.049S Manganese-54 U
-0.0132
+t.0.0157 0.0118 +1-0.153 0.0253 Nlobfum-94 U -0.000999
+1-0.146 Q012t 1/-0.0143 0.0257 Potamlum40 12.8 4/-1.24 0.149
+411.22 0326 Radlum-226 0515
+/-.0805 0.024 +/0.0789 0.0507 Silver-lO8m U
40095
+/-0.0129 0.0107 41.0127 0.0226 Thalum-208 0.190
+4100312 0.0119 +1-0.0306 Q0252 pCI/g pCIlg pCf/g pCl/g pcl/g pC~g PC1g PC1,g pC/g pClg pdug PCi/g PCIVg pC1/g PCVg PCl/g pCVg pCIVg SRBi 06/18/04 1341 3397141 The Following Prep Methods wre performed Method DescripUon Analyst Date TlIme Prep Batch Dry SoU Prep Dry Soll Pap OL-RAD-A-021 BSWI 06/W04 1510 338588 Ihe following Analytlcal Methods were efronned Method Descriptlon I
MALHASL300 45.23 Notes:
The Qualifiers In this Kepott am defined as follows:
B Targct mcalyt vtu w
adctetcd in tho sample as wcU ns tho odated blank.
BD Flag for result below Ihe MDC or n fag for low tracer necovery.
E Concentradon of the target analyte exceeds the imtimcnt calibration rangc 63
GENERAL ENGINEERING LABORATORIES, LLC GENERAL ENGINEERING LABORATORIES, LLC 2040Savage Road Charfeston SC20407- (843) 65565171 - www.gaLcem Certificate of Analysis Company:
ConnectlcutYankee AtomlcPowcr Address:
Haddam Iqeck Plant 362 Injun Hollow Road East Hampton, Connecticut 06424 Contck Mr. Pete Holncabeck Pmocct:
Solls POD002332 ReportDate: July 1.2004 Page 2 of 2 Client Sample ED:
SamplelD:
9524.0000 O6FD 114103019 Fpriect YANKO05O4 clietyl):
YANKIOI Vol. Recy.:
Parameter Qualier Result Unceriainty LC TrU MDA Unlbs DF AnnlYsWate Time Datcoh W.
H Analytical holding time exceeded.
I Indicates an estimated value. The result was greater than the detection ltmit, but less than the reporting ILlt.
U Indlcates the target nalyte was nalyzed for but not detced above the detection 11lmiL Ul Uncertain Identificadon for gamm spectroscopy.
X Lab-specific qualifler-please see case narrative, data summary package or contact your project manager for details.
h Sample preparation or preservation holding time exceded.
The above samnple s reported on a dry weight basis.
This data report has been prepared and reviewed In accordance with Genel Engineering Laboratories, LLC standard operatlng procedures. Please direct nay questions to your Project Manager, Sah Kozlk.
vw QQb yQ Q)CU Revlewed by 64
GENERAL ENGINEERING LABORATORIES, LLC GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Chafleslon SC 29407 - (843) 556-171 -www.geLcom Certificate of Analysis Company: ComiectIcut Yankec Atomic Power Address:
HaddazmNeckPlant 362 hnqun Hallow Road Ean Hampton, Connecticut 06424
Contact:
Mr. Pete Hollenbeck Project:
Solts POP 002332 ReportDate: July 1.2004 Page I of 2 Client Sample ID, Snele ED:
Matrx:
CoUcct Dote:
ReceiveDate:
Collector Moisture:
9524-0000-017F 114103020 Sonl 25-MAY-04 03-JUN-04 Client 4.16%
Pr tect YANK00504 Client ID:
YANK0OI Vol. Recv.:
Parameter QualIier Result Uncertalnty LC TPU MDA UnIts DF AnalystDate 7tme atch Mid.
Rad GamnSpecAnnlysls Cammasper Gama, Solld-FSS GAM & ALL FSS Actdlum-229 0.502 41-0.140 0.0452 41-0.137 Anedclum-241 U
0.0112
+1-0.0617 0.0566 41-0.0605 Bismuth-212 0.323 4-10.265 0.0937 4-0.260 hismuth-214 0.411
+/-0.0174 0.0246 41-0.0758 Ceslun-134 U
0.00319
+1-0.M79 0.0157 41-0.0273 Cahimi-137 U
0.0162
+1-00166 0.0148 41-0.0163 Cobalt-60 U -8.4301-OS
+I-0.058 0.0131 41-0.0155 Europlum-152 U
0.0017 4/-.0394 0.034 41-0.0386 Europlum-l54 U
0.0179 4-0048 0.0416 41-0.0471 Europlum-155 U
0.9S
+10.046 0.041 41-0.0451 Lead-212 0.435 41-00S1 0.0206 +-0.054 Lead-214 0.424 41-0.0696 0.0258 4/-0.0672 Mangunesc-54 U
0.014
+1-0.0211 0.0137 41-0.0207 Nlobium-94 U
.0.00259
+1/4.0145 0.0119 +-0.0142 Potaslum-40 13.8 41-1.27 0.06 W-1.24 Rafdlur-226 0A11
+1-0.0774 0.0246 41-0.0758 Silvcr-lCSm U
-000319 41-0.013 0.0111 4/.0127 Thalflum-208 0.143
+1-0.0325 0.0132 41-0.0318 0.097Z 0.117 0201 0.0519 0.0333 M.13 0.02S8 0.0727 0.0902 0.0845 0.0428 0.0539
.ms92 0.0252 0.198 0.0519 0.0233 0.0279 pC4g pCVg pcllg pclvg pCI/g pClJ/g pCl~g pC/g SR8 0W1/04 1341 339714 1 The following Prtp Methods were performed Method Description Analyst Date Time nrep iBici Drysoil Prep Dry Soil Prep GL-RAD-A-021 BSWI 06104J04 1510 338588 The following Analytcal Methods wetr perfonmed Method Descrpton I
EML HASL 300, 45.23 Notes:
The Qualifiers in this report are defied as follows:
B Target analyte was detected In the sample as well as tib associated blank.
BD Flog for results below thz bDC or lingg for bw taerrcovcry.
B Conctrtdon of the targct nalyte excceds the instrumant callbralon mngc.
65
GENERAL ENGINEERING LABORATORIES, C
GiENERAL ENGINEERING LAE30RATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 656-8171 - ww.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Addtess:
Haddam Nock Plant 362 Injun Hollow Road EAst Hampton, Conacticut 06424 Contact Mr. Petw Holicabeck Project:
Soils PO 002332 Client Samplc ID:
Sample ID:
Report Date: July 1,2004 Page 2 of 2 9524-OOOG-017F 114103020 PtpicvD:
YANK00504 Cfeat: - YANK0OI Vol. Pecy.:
Parameter Qualller Result Uncertainty LC TPU MDA units DF AnalystDate Time BatchMid.
K Analytical holding time exceeded.
1 Indicates an estimated value. Tbe reult was grater tan th detection limit, but less than the reporting limit.
U Indicates th atnrgetanalyte was aunayzed forbutinotdetected above tho detection imit.
U1 Uncertainidentifcationforgamm apectroscopy.
X Lab-speciic quaifler-plcass sce case rautive, data sumany package or contact your pmject manager tor details.
b Sample preparadon or preservadon holding tine excedcd.
The above sample Is reported on a dry weight basis.
This dau repont has been prepared and reviewed in accordance with General Engiaeering Laboratories, LLC standard operating procedures. Please direct any questions to your Prtect Manager, Sarah Kozlk.
Reviewed by 66
GENERAL ENGINEERING LABORATORIES, hG GENERAL ENGINEERING LABORATORIESs LLC 2040 Savago Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address:
HaddambeckPlant 362 WIan HolUow Raad East Hampton, Connecdcut.06424
Contact:
Mr. Pete HoDlabeck Project:
Soils PO1002332 Client Samnple ED:
Sam.nle ID:
Matrix:
CollectDatc:
Receive Dae:
Coliector Moisturt:
ReportDate: July 1,2004 Page I of 2 95244000 017FD 114103021 Soil 25-MAY-04 03-JUN-04 Client 8.35%
KPIecet YANK00054 CVl.en 9): YANKOOI Parmeter Qualifter Result Uncrtainty LC TPU MDA Units DF Anam tslate Time BatchMid.
Rad GnaSpecAnlyuds Gammaspec GemrA Satid-FSS CAM &ALL FSS Actinlum-228 0.523
+1-0.134 0.0633
+/-0.151 0.134 Anicdcium-241 U
0.0408 4t0.0409 0.0248
-0.040t 0.0508 Blsmuth-212 0.458 41-0.290 0.137
+1-Q2S5 0289 Btsinuti-214 0.492
+1-0.113 0.0327
+1-0.111 0.0685 Ceulum-134 U
0.0368
+1-0308 0.0234 +1-0.0301 0.049 Cculum-137 0.0826
+/-0.0405 0.0174 +1-0.0397 0.0365 Cobalt-60 U
0.0188 41-0.0253 0.0218 41-0248 0.0465 Europlum-152 U
4.0291
+1-0.0503 0.0433 t1-0.0493 0.0B99 Europlum.154 U
40233
+1-0.0703 0.0557 4S-0.0689 0.119 Huroplut-15S U
-0.0154
+1.046Z 0.0415 41.0453 0.0852 Lead-212 0.640
+1-0.080 0.0232 +1-0.0784 0.0479 Lnd-214 0550 41-0.0899 0.0328 +140.0881 0.068 Manganese-54 U
-0.018
+1-0.021 0.0169 41-0.0206 0.0358 Nlablum-94 U
-0.00922
+1-0.0216 0.0173 +I-0.0211 0.0362 Potasslum-40 13.1 41-1.17 0.169 41-1.15 0367 Radium-226 0.492
+1-0.113 0.0327
+1-0.111 0.0685 Silver-108m U
0.00168
+1-0.0174 0.0151
+1-0.017 0.0315 Thalilum-208 0.154
+1-0.0449 0.0172
+1-0.044 0.036 Pd/g PCUg pci/S pCvg pcl~g Pat' pcug pCi/i pCi/i pCv8 pCl/g PCVB SRB 06/18104 1342 339714 1 The following Prp Meihads were performed Method Descripffan Analyst Dale llme Prep Batch Dzy Sol Pzrp Dq Soil Prep L-RAD-A-021 BSW1 06(04/
1510 338588 The fbUolling An i cnl Mlethods were performed Method Desripoon I
EMILHASL300,4.523 Notes:
lhc Qualifiers In Us report am defined as follows:
B Target analyte was detected In the sample as well as the associated blank.
BD alq for raults blow thc bDC or a lag for low trcer rccovefy.
E Concentration of the Iarget analyte exceeds the instumnent ca8lbraion range.
67
GENERAL ENGINEERING LABORATORiES, LIG GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 5558171 - www.geltcom Certificate of Analysis Company: Ccnnecticut Yankee Atomtc Power Address:
Haddam NeckPlant 362 injun HloUw Road East Hampton, Connecticut 06424
Contact:
Mr. Pete Hollenbeck Poject Sals PO O02332 ReportDate:
ulyul,2004 Page 2 af 2 Client Sample D:
SamplelD:
95244OO017FD 114103021 EUMD:
YANKOD0 Vol. Recv.
Farameter Quafler Result Uncertainty LC TPU MDA Units DF AnaalytDat.
Thne UatchMlid.
H Analytical holding time exceeded.
J Indicates an estimated value. The result was greater than the detection Uimit, but less than the reporting limit.
U Indicntes the t analyte was nalyzed for but not dettedabove te detection Umit.
Ul Uncertain identification for gamma spectruscopy.
X LAb-specific qualfifer-please sec case nartive, data summary package or contact your project manager for detais.
h Sample preparation or preservation holding time exceeded.
'rhe above sample is reported on a dry weight basis.
This data report has been prepared and reviewed in accordance with Gencral Engineering Laboratories, LLC standard operatng procedures. Please direct any questions to your Project Manager, Samh KozHlk 020&C L@ Q Reviewed by 68
GENERAL ENGINEERING LABORATORIES, LLC GENERAL ENGINEERRING LABORATORIES, LLC 2040 Savago Road Chadeston SC 29407 - (843) 556-8171 - 1ww.geLcom Certificate of Analysis Company: Connecticut Yaniee Atomic Power Address:
Haddan Neck Plant 362 injun Hollow Road BEst Hampton, Connecticut 06424 Contact M. Pete Hollenbeck Projeet:
Soils PONl 002332 RepartDate: July 1,2004 Page I of 2 Client Samplc ID:
Samele ID:
Matrix:
Collect Date:
Reeive Date:
Collcctor.
Moistu=:
9524-0000-018F 114103022 Soil 25-MAY-04 03-JUN-04 Client 12.9%
PT c AN YO 04 C lnecmD:
YANl00O Vol. Recv 0
Parameter Qualifier Result Uncerlainty LC TPU MDA Units DF AnalptDnte Time Batch Mtd.
Rnd Gnmmn Spec Analysis Ganm ec, CGerr, Solid-FSS GAUM ALL FSS Actinlum-229 0.744 41-0.189 0.0717 4+40.185 0.154 Amedclur-241 U
- 0.0251 400297 0.0229 +10.0291 0.0474 Bismuth-212 0.542
+1.0.446 0.137
+/40.437 0.295 Bismuth-214 0539
+W-0.103 0.0363
+1-0.106 0.077 Cesuln-134 U
0.0354
+-0Qm61 0.0236 +/Q.0256
.0504 Ceslum-137 0.120
+1-.0037 0.0192 41-0.0379 0.0409 Cobalt-60 U
0.0113
+41M239 0.0212 41-0.0234 0.0466 Europlum-152 U
0.0103
+100498 0.0o23 +1-0o.8 0.0m Europium-154 U
0.0959
+/0.0892 0.0604 1/-0.0874 0.132 Europlm-0S5 U
o.0 W-0.0831 0.037 41-0.0514 0.0769 Ul Lad-212 0.687
+1-00849 0.0259 +1-0.0832 0.0538 Lcead-2t4 0.666
+1.0.10 0.0294 +14.106 0.0621 Manganese-54 U
0.0161
+1-0.°02W 0.0207 +1-0.0218 0.0442 Nloblum-94 U
0.00925
+/-0.0206 0.0182 +.0.0202 0.0386 PotassIum-40 13.1
+1-1.30 0.182
+1-1.27 0.406 Radlumt-226 0-539.108 0.0363 0.106 0.077 Silver-lOtni
- U
-0.0174
+140.0195 0.01St 4140191 0.032 Thiiliwu-208 0.232
+140.0539 0.0195 414.0528 0.0414 pCi/8 pci/g pci/g pci/g pri/g pCL'g pC/g9 pci/g Pci/g PC118 PC/i pCY:
pCug pci/g PCL4 pci/g pcl/g pdlg SRB 06/1/04 1343 339714 1 The fofloirng Prep Methods wrie perfomed Method Description Analyst Date Time Prep Ratch BSWI 06/04 1510 33858a Dry Soil Prep Dry Soll Pump GL-RAD-A-021 The [ollwing Analytcal Methods were performed Method Description I
E.MU HASL 3W,45.23 Notes:
The Qualiilers In this report are defined as follows:
b Targec analyc was dtctd a tha smpla s wcUl ahassociatedblank.
BD lqag for resu below thc MDC ora flag ror low tracer recovery.
E Concention of the target analyte exceeds the Instument calbration rang 69
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Report D= July 1.2004 Page 2 of 2 9524-0000-018F 114103022 Prciec*
YANK0O504 C
B.
YANKCOI YOL ZcV.:
Flrameter Qualifier Result Uncertalaty LC fTU MDA Units DF AntystlDate Time BntthMId.
}I Analytical holding time exceeded.
I Indicates an eatimated valum The result was greater than the detection lliIt, but less than the reporting limit.
U Indlcates the target analytc was analyzed for but not detected above the detection linmiL Ul Uncertain Identification for gamma spectmscopy.
X Lab-specific qualifier-ple=se see case narrative, dama sumnary package or contact your project manager for details.
h Sample preparation or presevation holding time exceeded.
'The abovc samplc Is reported on a dy weight basis.
This data report has been prepared and reviewed in accordance with Gencral Engineering Labomrtores, LLC standard operatiog procedures. Pleasc direct any questions to your Project Manager, Sarah KozLik.
Reviewed by 70
GENERAL ENGINEERING LABORATORIES, LLC GENER1AL EENGINEERING LABORATO0RIES, LLC 2040 Savage Road Charleslon SC 29407 - (843) 65"171 - www.gel.com Certificate of Analysis Company: ConnecticutYankee Atomic Power Atdess:
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Moistnre 9524-0000-020F 114103023 Soil 25-MAY-04 03-JUN-04 Client 42.8%
PwIT YANOOSO4 Ceat eW:
YANKOOI VoL RK:
Parameter Qual2fter Resnlt Uncertinly LC TPU MDA Units DF AnalysfDa.e Time akifthMUiL Kid Gamm Spec Analyu*
Gantma G
=amat Salid-FSS AI &ALL FSS Actinurn-228 Q569 4-0.187 O.OS88
+1 O.1S3 Amcdclum-241 U
-0.0243
+/-0.0926 0.0678 40.0907 BEimuth-212 0.577
+1-0.277 0.134 4/0.272 Dismuth-214 0.676 4t-0.108 O.M326
+1/4.106 Ccsium-134 U
Q007
.1-0m63 o02ii +1-0.025s Cesium-137 0.853 4/40989 0.0174 41-0.0969 Coualt-60 U
0.00385
+1-0.0256 0208 +1-0.0251 Europlha-IS2 U
0.00931
+t-0.0601 O
0465 +t-0.059 Euoplum-154 U
4.0.029
+140674 0.0512 +/-OM61 Europlum-15S U
0.00688
+1-0.0546 0.0443 4-0.0535 Lead-212 0.608 41-0.0816 0,0229
+14-.80 Lcad-214 0.627
+140.104 O.OS41
+14-001 Mangunmse-54 U
-0.00612
+1-0.0239 0.0182 +1-0.0234 Nloblun-94 U
0.00401 10.0207 0.0166 41-0.023 Potasam-40 937
+1-1.11 0167 4/-1.09 Badlum-226 0.676 4J10.108 0.0326 41-0.106 Sliyer-1om U
o0.061 l-0n01 0.0168 4/-0.0197 Thalltum-208 o.2M 4-0.0451 0.0161 4/10.0442 0.127 0.140 0.287 0.06S9 0.0449 OM71 0.0454 0.097 0.113 0.0916 0.0477 0.0712 0.0389 OM0 2 0.373 0.0689 0.0351 0.0343 Pas pCl~g pCl/g pcllg pcl/g PC/g pcug pel~g pal/g PCl/g pol/g SRB 061204 1109 339714 1 The fOllowin Prep Mdhads werS performed Method DesiptPu=
Analyst DAte Time Prep Batch Dry Soil Prep Dry Soll Pr=p GILRAD-A-021
)SW1 004104 1510 338588 The follwnolea AnlyUIcl Methods were perfirmed Method DVecrIptlau I
EMLHASL300.45.23 Notes:
lhe QualiIerS In this report am defined as follows:
B Targetanalytew^sdettedie;n mplea swellastbens IsoclAe blank.
BD Ping formnuls bow the MDC nra nag for low errecovery.
E Concentration of the trget analyt cxceeds the instrumntcallbrion mrnge.
71
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9524-O000-020F 114103023 Piect YANK00504 ClI icnt D YANK001 Vol. Recv.-
Parameter Qunller Resut Uncertawnty LC WU MDA Units DF AnalystDate Time Bach blId.
H Analyticalholding timeexceeded.
J Indicnte n estimated value The result was greater than the detection limit, but less than the reportng limit.
U Indicatcs the targct analyto was analyzed for but not detected above the detedion lmit.
U Uncertain IdentificatIon for gammoa spectroscopy.
X Lab-speciflc qualifier-please see cse nartive, data wmnmary package or contact your project manager for detaih.
h Sample preparation orpreservation holding time exceeded.
Tbe above samplo Is reported on a dry weight basis.
This data report has been prepared and reviewed In accordanco with General Engineering Laboratories, LLC standard operallng procedures. Please direct any qtions to your Project Manager, Sarh Kozm Reviewed by 72
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9524-0000-0212 F YANK0050 114103024 Cle'CtD:
YANKWI Solt Vol. Rev.:
25-MAY-04 03-JUN-04 Client 4.81%
Parameter Qualfler Result Uncertainty LC TPU MDA Uails DF Anlfsktoae Time BlaltdMtd.
Rod GaCma Spec Anlyslb Gammospse Gamme, 5011d.FSS GAM &ALLFSS Actinlum-223 0508
+1-0.155 0.0523 41-0.152 Amedclum-241 U
0.00417
+1-0.0702 0,0573 4140689 Bsmuffi-212 0.323
+14205 0.0986
+-0.200 Blimuth-214 0347
+/-0.084 0.0257 4+0-OS23 Ceslum-134 U
0.0283
+1-0.0224 0.0164
.Io.0022 Cesum.137 U
0.022
+410.0265 C0L141
+1-.026 Cobalt-60 U
0.0233
+1-0.0276 0.0161 va-.071 Eutopium-S2 U
-0.00725 4-W0.0407 0.0355 41-M399 Europlum-154 U
-0.0496
+1-0.0532 0.039a 4-00522 Eumpium-SS U
0.0362
+1-0.0468 0.0424
/-0.0458 Lcad-212 0.525
+14.0613 00201 +/-0.0601 Lead-214 0.473
+/1-.0732 0.Oa +10.0718 Mangunese-54 U
0.00806
+1-0.016 0.0144 +1-0.0157 Niobium-94 U
-0.00533
+4/0.0173 0.0121
+-0.017 Potalum-40 13.2
+/-1.24 0.131 41-1.22 Radium-226 0.347 4+/4.084 0.027 4/-.0823 Silver-108m U
0.00622
+/.0.0137 0Q0122 +/-0.0134 Thallium-203 0.142
+1.0343 0.0125 +1-0.0336 0.111 0.118 0.210 0.0542 0.0348 0.0298 0.0348 0.0741 0.0867 0.0872 0.0417 0.058 0.0306 0.0257 0.289 O.0S42 0.0255 0.0264 pCIg pC11g pCUS pCUK pcltg polg pCilg pCt/g pCI/g pCUg pCYe pCUg pCUg pClg pCUg pCUg pCyg pci/g SRB 06W0/04 1109 3397141 The rollowhng Pnp Methods were performed Method Description L-Dry Soli Prep Dry SoalPrep GLRAD-A-021 Analyst Date Tlme Prgp Batca BSWI 06/04/04 1510 338.588 The following Analytiall MeWhods were perormed Method Descritpton I
EML HASL 300. 45.23 Notesr The Qunlifieus In Mhia report are defined as follows:
B Trget anayte was detected in the sampl as well oa the aioated blank 1D lFlag forreslt below Ube MDC ra nag (orlow ucrrccayy.
E Concentaton of lu target analyto exceeds the instrumeatcallbraon mang 73
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Report Date: July 1, 2004 Page 2 of 2 95244O000-021F 114103024 Vioct YAK04 ent &D YANKOOI Vol. Rccv.:
Parnmeter Qualliler Result Ungertainty LC TPU MDA Units DF Analysiate 21me.DtchMtL H
Analytical holding time excecded.
J IndIcates an estimated value. 1The result was greater than the detection timit, but leas than the reporting limiL U
Indicates the target analyte was analyzed for but not detected above the dctection Lixat.
UI Uncettain identification for gamma spectuscopy.
X Lab-specific qualiflcrplease see case narrazlve, datasummary pachge or contact your prJcct manager for detLils.
h Sample preparation or preservation holding time exceeded.
ne above sample is reported an a dry weight basis.
"his data report has been prepared and reviewed in accordance wih General Engineering Lboratories, LLC standard operating procedures. Please direct any questions to your Project Manager, Sarah Xo21Lk Reviewed by 74
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Molsturc 9524-00000oO7F PWI ct YANKWS04 114103025 CetD:YANK001 Sotl Vol. Recv.
24-MAY-04 03-JUN-04 Client 11%
Parameter Qualifer Result Uncertalnty LC TPU MDA Units DF AnalyatDate Time Balta Mtd.
Rid Alpha Spec Analysis Alphaspc Am24I, On. Sold AU FSS meticlunm-241 U
0.00119
+140646 0.0677 41-0.0646 0.216 Curdu-242 U
-0.00W37
+1-0.0164 0.0397 t-0.0164 0.174 Cutum-2431244 U
0.00
+/Q0.0584 0.00 4/0.0584 0.08M7 AlphazspecP, Solid-ALL FNS Pltaonlum-238 U
-0.0444
+/.00329 0.0797 41-0.0332 0.231 Plutonlinn-239/240 U
0.0148
+4-.40792 0.0737 4-/.0793 0.219 Liquid Sent Pu241, Salld-UALL FSS Plulonlun-241 U
3.47
+1-4.82 3.98 41.4.83 8.12 RndGarz aSpecAnalys GanmuepAc Gamma, Sold FSS GAM &ALL FSS Actinunim228 U
0.00
+1-0.154 0.119
+1-0.151 0.248 UI Arnesidum-241 U
-0.0388
+1-0.2M 0.120
+/-0.199 0.249
-Blsnuth-212 U
0358 4.0.20 0.171
+1-0.199 0360 Bhsnruth-214 0.581
+1-0.105 0.0335
+/WI03
.071 Ccslum-134 U
0.0411 41-0.027 0.0243 41-0-0264 0.0514 Cesura-137 U
0.0333
+1.0.0284 0226 41-0.0279 0.0477 Cobalt-60 U
0.000406
/-00284 0.0203 d-0.0279 0.0445 Euwoplum.152 U
0.0412 4/-0.0549 0.0486 +14.0538 0.102 EurophtuI-154 U
0.0605
+/40711 0.0637 +-0.097 0.138 E
PIuMp-15S U
0.0295 4/-040688 0.0586 +1-0.0674 0.121 Lc V-212 0.648
+-0.0836 0.0m84 41-0.0819 0.059 Leid-214 0.594 41-0.109 0.0326
+/-0.107 0.0687 Manganese-S4 U
0.00865 40.0M22 0.0194 414.0217 0.0415 Nlobimn-94 U
0.00398 41-0.020 0.0166 1-0.0196 0.0353 Potassium.40 13.2 41-138 0.138 41-135 0.315 Padinn-226 0.581 41-0.105 0.0335 0/4.103 0.071 Saver-108m U
-0.00202 41.0.019 0.0O59 4/.0.0187 0.0335 Thallium-208 0.224
+/-0.0567 0.0152 41-.055 0.0326 Rzd Gas Boiw Proportlona Comalng GFPC, MO, solid-ALL FSS Stntiam.90 0.0328 41-0.00856 0.00622 41-0.0122 0.0128 adLIquiSdnUchzt ff Analysts
- ZaCq fgtm Dur. Sol-zrIDZ.ALL F~s Ttidam U
0.868
+1-520 433 41-5.20 8.66 pClg pCl/g pCl/
pClg pClg pClg pCI/g Pag palg pC3g pCVg pCl/g pCl/g pci/a pClg pcl/g pCUg Palk pcl/g PCV9 pCdg pCIg polfg Palk JSI 06/3G04 1840 342904 1 ISI 06126104 1541 3429002 JSI 06129/04 2314 3429M 3 SRB 06,21104 16163397144 pCUg pCUg HOB11 062M4 0257 341279 5 JLBI 06M204 1916 342680 6 75
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9524-0000-007F 114103025 it YANKW4 Client ID:
YANK.OO Vol. Rv..
Parmeter Qualifier Reslt Uncertainty LC 7TU bDA units DF AnalystDate Time DatchJMtd.
Bad Liquid Scintillation Analysis Liquid Scint C14, Solid FSS Carbon-14 U
fUqutdScbnu Fc55. Solid-ALL FSS Iron-55 U
quiddScintNid3, So WI-ALL FSS Nilckl-63 U
Liquid Scdi T9, Solld-AL FSS Technedium-99 U
0.0683 4-0.125 0.0845 4/-0.12S 0.174 3U9 21.8 15.8
+1-37.5 1523 37.5 0.416 41-12.7 10.6 W-12.7 pCI!1 PCI/B pCi/g MWX 06121/04 1701 342317 7 1
JLt3 I622104 215H 342541 9 JLB1 06127/04 2055 342542 10 DAII 06127B04 304 3410(7011 0.0W5 W-0254 0.211 4"-0M24 0A32 pc!/g The folowlng Prtp Mdhods era perormed Method Description Analyst Date Time Prep BRain Ash Soil Prep Ash SollPrep. GL-RAD-A-2IB BSWI 0107104 1610 338594 Dry Soil Pop Dry Soil ap CL-RAD-A-021 BSWI 060/404 1510 338588 The following AnalyIcA Methods wrv performed Metbod Description 1
DOE EMLHASL300, An-05-RC Modified 2
DOE EML HASL-300. Pu-l I-RC Modified 3
DOB BML HIASL300, Pu-I I-RC Modified 4
EMLHASL300,45.23 5
EPA 905.OModled 6
EPA 906.0 Modified 7
EPA EERP C01 Modified a
EPA EERFC 01 Modifid 9
DOERESLFe-1,ModIflied 10 DOERESLNI-1, Modified 11 DOE EML HASL-300, Tc02-RC Modliled Suoatelrracer recovry Test Rewme Acceptable Limits Amneciume243 Alphaspec Amr24l. Cm. Solid ALL 82 (25%-125%)
Pluhoalumt-242 Carriefrfrucrterccovcry Caiedrrmcricvcry AMpbspc Pu. SoUd-ALL FSS Llquld cing1u241, SaUd-ALLFS OFPC SW9O, solid-ALL PSS LMquld ScintleSS, Solid-ALL FS SO 79 E6 81 (25%-125%)
76
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,iece YANICO04 oLnD:
YANKDOI VoL. Racv-Parameter Qualiler Result Uncertainty LC TPU MDA Units DF AnalsiDate lime Eateb Mld.
Calerlarmcet Recovery Cartiet/recer Recovery Liquld Seint N163, Solid-ALL PS Liqid ScinTc99, Solid-ALL FS 87 73 Notes The Qualifiers in this report =a defined as follows:
B Target anulyte was detected In the sample as well as the associated blanln BD Fiag forresults beow thMDC ora flag forlowtmcerrecovery.
H Concentration of the target analyte exceeds the instrument calibration range.
H Analytical holding time exceeded.
I Indicates an estimated value. lmc result was greater than the detection limit, but less than the reporting limit.
U Indicates the target analyte was analyzed for but not detected above the dclection limit.
UI Uncertnin identlficationforg mspcctxscopy.
X Lab-spedfic qualfier-please ace casc nanative, data summary package or contact your project mnnager for details.
h Sample preparation or preservaion holding timc exceeded.
Thc above sarmple Is reported an a dry weight basis.
This data report has been prepared and reviewed in accordance with General Engineedng Laboratories, LLC standard operating procedures. Plause direct nay questions to your Project Manager, Samh KozliL Reviewed by 77
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95244000O010F 114103026 Soil 24-MAY-04 03-JUN-04 Client 12.4%
Ppiect YANK00504 Vol. Rwc.:
Paamder Qualffler Result Uncertainty LC TPU MDA Unils DF Anal yetle Time DutchMti Rad Alpha Spec AnalyuIs AlpharecAm24l. Cm, Solid(ALL FSS Amcriciun-241 U
4.0726 41-0.10; Cwlum-242 U
0.177 41-0347 Curtiun-2431244 U
0.115
+1-0.306 AlpharpdcfP, Soid-ALL FSS Plutonium-238 U
0.00 V41.288 Plutoviurm239f140 U
0.147 414X288 Liqutd Scft Fu241. Solid-ALL FSS Pluwalnn-241 U
0.143 W1-13.7 Rad G -mmaSpec Analds G-ammspte4 Gamm, Solld-FSSGAU &ALL FSS Actinlum-229 0.446
+1.0.162 Amsrlium-241 U
.0.0141 41-0.123 Dismuth-212 U
0.235 41-221
_ inauth-214 0.411
+1-0.0869 CWslum-134 U
0.0116 1-0.0188 Ceslair-137 0.0765 41-0.0293 Cobalt-W0 U
0.00932
+/-0.0179 Evroplum-IS2 U
.0.00325 41-0.0434 E-pium-154 U
-0.0565 41-.0538 Eu nmpiuS5 U
0.0128 4.0ao449 LAed-212 0.433 440.0615 lUd-214 0.500
+4-0814 Manganese-54 U
0.00316 441017 Nlobium-94 U
-0.00031 41-0.0155 Potasdum-40 11.5 41-1.23 Rladium-226 0.411
+M-0.0J69 Silver-1OSm U
- 0.00293 4140135 Tbatltmn-20s 0.120 4W140394 Rad CG Flow Proportional Counftng GFPC, Sr9,4 jolid-ALL FSS Strntium-90 0.045 4-100116 Rod liquid Sdntillation Aualysis LSM Trkidn DlMr Soll-HD2.AUl FSS Trlnm U
1.70
+/-5.49 LIUdSdm C14. SolId ESS 0.744 41-0.101 0.00 41-0.343 0.173 41-0306 0.0o 14-0288 0.00 41-0.259 0W97 pC/g OA.80 pCIg 0.757 pCUg 0399 pC/g 0.398 pCOg 11.5 41-13.7 23A pCIg 0.0443 41-0.159 0.0933 414.120 0.112 4J-0.217 0.026M= +1.0851 0.0164 1-0.0184 0.0129.140288 0.0159
-10.0175 0.0357 41-0.0425 0.039Z 41410527 0.0407
+1.0.044 0.0218 4140602 0.0241.1410798 0.0143 W-40167 0.013
-1.40152 Q118 41-1.21 0.0268 +1-0.0851 0.0119 414-.0135 0.0137 41-0M86 0.0075 41-0.016S 0.0964 0.194 0.239 0.0569 0.0352 0.0277 0.0349 0.0752 0.0869 01046 0.0455 0.0509 0.0308 o.0m7 0.268 0.0569 m0252 Q0291 0.0179 pCIg pCUg pci/g pCl/g pCl/g pCi~g pCI/g pCVg pCUg pCUg pCitg pCUg pCtg pCUg PC's ISl 06301W4 0925 342904 1 JSI 06126104 1541 3429002
.15 06/3004 0W46 34290 3 SRB 0602004 11103397144 H081061204 0411 3412795 nLIt 06J26r04 1948 34260 6 4S4 W-5.49 78
GEEA ENIERN AOAOIS L
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Solls PON 002332 ClentSample I:
SamplolD:
ReportDute: July 1.2004 Page 2 of 3 952440000-010F 114103026 L 1elffD:
YANK001 Vol. RecV.
Parameter Qualliler Result Uncertalinty LC TPU MDA Units DF Analyslate ime Daldh MiLd.
Rad Liquid SdnlIllaUon Analyss Lfquld Scli C14, Solid FSS Carbon-14 U
0.172
+/-0.153 Liquid Scint FcSS, Solid-AL FSS
[ron-S5 U
-502
+/41.6 lUquldScInINI6I, Solid-ALLFSS Nlckel-63 U
-12
+/.12.9 Lquid Scint Tc99, Solid-ALL FSS Techneflum-99 U
0.0104
+1-0.237 0.102 +/-0.153 17.0
+1-41.6 11.2 l-12.9 0.193
+-0.237 0209 35.4 23.1 0.406 pCi/g pcllg pugs pCug8 MWX 06/21104 1904 342331 7 JILBI 06W23IM4 1637 3425419 JLBI 06t27104 2126 342542 10 DAl1 06212M 0436 341070 11 The fallowing Prep Methods were perfermd Method Description Anlst Date Time Prep Batch AshSoilPrep AshSoUPrep,43LRAD-A-021D BSW1 06/07/04 1610 338594 Dry Sall Prep Dry Sall Prep CL-RAD-A-021 BSW1 06/404 1510 338588
'Tbe foUowlng Analytical Methods were performed Method Description I
DOE EML HASL-3Wo, Am-OS-RC Modified 2
DOE EnL HASL-300, Pu-l1 I-RC Modified 3
DOEI EdL HASL-300, Pu-l I-RC Modified 4
BML HASL 300, 4.5.3 S
EPA90.OModlfled 6
EPA 906.0 Modificd 7
EPA EERFC-01 Modified 8
EPA EERF C01 Modified 9
DOE RESLFe-1, Modified 10 DOERESLNI-t,Modified 11 DOE BML HASL-300, Tc02-RC Modified Sunrogatertlncerrecovery Test Recnyery%
Acceptable lmits Arnriclum-243 Aipbuype Am241. Cm. Solid ALL 82 (25%-125%)
Piutonlum-242 C!0vicrrmccritecoyayy CarrietlrraccrRecovery CuzricrfracerRecovery Alphupec Pu, Solid-ALL FSS Liquid Sdnt PuZ4t, Solid-ALL FS (3FPC, Si9O. solid-ALL FSS Liqd Scint FeSS, Sclld-ALL PS 9
Es 87 83 (25%-125%)
79
GENERAL ENGiNEERING LABORATORIES, LIC GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 656-8171 - wWW.goLcom Cerificate of Analysi9 Company: ConnctdcutYankee Atomic Power Address:
HaddamNeckPlant 362 IjunHouaw Road Hut Hamptoa, Coanectlcut 06424 CooDct:
Mr. Pete Hallenbeck Project:
Sos PO#002332 Client Sample ID:
SamplelD:
Report Date: July 1, 2004 Page 3 of 3 9524-0000-OIDF 114103026 Frject:
YANK00504 RIteat ID:
YANK0OI Vol.Reav.:
Parameter Qualltler Result Uncertainty LC TPU MDA Units DF AnalystDate Time Dak'h Mid.
Canicrtrracer Recovety CarrlerlTrnccr Recovery Liquid Scit N163, Solid-ALL FS Liquld SciatTc99, Solid-ALL FS 78 76 Notes:
The Qualifiera in this report are defined as follows:
B Target analytc was detected In the sample as wel as the asociated bland BD FLbg for results below the MDC or 4 lag for low tracer rwcovery.
E Concentration of the rget analyte exceeds tho instrument calibration rnge.
H Analytical holding time exceeded J
Indicates an estimated value. The result was greater than the detection llmit, but less than the reporting limit.
U Indicate the target anyIe was nalyzed for but not detected above the detection limit.
UI Uncertain identification for gamma spectroscopy.
X. Lab-specific qualier-please see case narrative, data summary package or contact your pzoject manager for details&
h Sample preparation or preservation holding time exceeded.
The above onapla Is reported on a dry weight basis.
This data repoet has been prepared and reviewed In eccordance with General Engineering Laboratories, LLC standard operating procedures. Please direct any questions to your Prmect Mmasger, Sarah KozliL Reviewed by 80
QUALITY CONTROL DATA 81
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 55-83171 - www.gel.com QC Summary Connecticut Yankee Atomic Power Haddam Neck Plant 362 Injun Hollow Road East Hampton, Connecticut Mr.
Pcte Hollenbeck Renort Date: July 1, 2004 Page 1 of 12 ontact:
IWorkarder:
114103 Parmnnme MNOh Sample Qual QC Unils RPD%
RECM.
Range Anist Date 7Jme lad Alpha Spec latch 342900 QC1200618425 114103025 DUP Plutonium-238 Plulonium-239/240 QC1200648427 LCS Plutonium-23 8 L-Plutanium-239/240 QC1200648424 MB
-.PIutonium-238 Plutonium-239/240 QC1200648426 114103025 MS Plutanium-238
- Plutonium-239/240 Batch 342903 U
-0.0444 Uncert:
4/.0.0329 TPU:
+1-0.0332 U
0.0148 Uncert:
+1-0.0792 TPU:
+t-0.0793 Uncert:
TPU:
8.54 Uncert:
TPU:
Uncert:
TPU:
Uncert TPU:
U 0.0517
+/-0.102
+/-0.102 U
0.000876
+1-0.0476
+1-0.0476 U
-0.0189
+I-0.105
+/.0.105 9.05
+1-0.908
+1-1.41 U
-0.0105
+1-0.0146
+1-0.0146 U
-0.0105
+1-0.0146
+1-0.0146 pC/g NIA (0%- 100° %)
JSI 06/26/04 15:41 (0%. - I 0 0 %)
pCilg 178 pCi/g pCi/g 106 pCi~g pCi/g U
-0.0444 Uncert:
+1-0.0329 TPU:
+1-0.0332 9.19 U
0.0148 Uncert:
+1-0.0792 TPU:
+1-0.0793 U
0.0247
+/-0.120
+/-0.120 113 41-1.10
+/-1.77 pCi/g 123 QC1200648438 Plutonium-241 QC1200648440 Plutonium-241 QC1200648437 Plutonium-241 114103025 DUP LCS MB U
3A7 Uncert:
+14.82 TPU:
+14.83 128 Uncert:
TPU:
Unccrl:
TPU:
U 5.15
+1-5.31 I-533 110 41-6.23
+1-12.0 U
3AO
+1-4.15
+14.16 102
+1-5.71 pCi/g 0
(0%-.100%)
JSI 06/30/040350 pCvg 86 (75IS-125%)
pCi/g 06/30104 06:S4 06/30/04 02:18 06/30104 05:22 QC1200645439 114103025 MS Plutonium-241 129 U
Uncert:
3A7
+14.82 pCi/g 77 (75%-125%/.)
82
GENERAL ENGINEERING LABORATORIES, LIC GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charlestcn SC 29407 - (843) 556-8171 - www.geLcom QC Summary Varkorder.
114103 Page 2 or 12 lunmf Nnmnl n..n1 nor It-to,.
DIIflOL lowf'ot nn A-.-.-
n1...
Tlm.
s..,r..*'.V MUf~l U8 J*-t fl-
.d*
- U.iU lflC UJ3 ll Rad Alpha Spe 3Batch 342903 IBatCI 342904 TPU:
+14.83
+1-11.0 QC[200648445 Amcricium-241 114103025 DUP Curium-242 Curium-243/244 QC120064W447 LCS Ancricium-241 Curium-242 Curium-243t244 QC1200648444 MD Asnericium-241 Curium-242 Cuirium-243/244 QC1200648446 114103025 MS Ameticium-24 1 Curium-242 Curium-243/244 Rid Cnmnn Spec Batch 339714 QC1200640441 114103014 DUP Actinium-228 U
0.00119 Uncert:
+1-0.0646 TPU:
+*-0.0646 U
-0.00837 Uncert
- t-0.0164 TPU:
+1-0.0164 U
0.00 Uncert
+1-0.0584 TPU:
+/-0.0584 9.59 Unccrt:
TPU:
Uncelt:
TPU:
123 Uncert:
TPU:
Uncer:l TPU:
Unccit:
TPU:
Uncurt TPU:
U
-0.0182 4/-0.0206
+/-0.0208 U
-0.0142
+1-0.0197
+/-0.0198 U
0.0142 41.0.0762
+/-0.0762 10.0 41-0.928
+1-1.66 U
-0.00552
+1.0.0108
+/-0.0108 12.5
+1-1.04
+/-2.00 U
0.00922
+M.0956
+/-0.0957 U
-0.0127
+1-0.0176 4/-0.0177 U
0.0645
+1-0.0886
+/-0.089 pCIg NIA pCi/t NtA pCIg 200 pCi/g (0% - I000A)
JSI 06/30/0409:25 (0%/ - 100°%a)
(0%. 100%)
104 (75M-125%K) pCi/g pctig 102 (75%-125%/.)
pct/g pCi/g pci/g 10.3 U
0.00119 Uncert:
+/-0.0646 TPU:
+/-0.0646 U
-0.00837 Uncert:
+/-0.0164 TPU:
41.0.0164 13.3 U
0.00 Uncert:
1/-0.0584 TPU:
+1-0.0584 U
ID2
+1-1.00
+1-1.74 0.00
+1-0.0585
+1-0.05B5 139
+1.1.17
+1-2.26 pCtlg 99 (75%-125%/*)
pCi/g pCilg 105 (75%-125%/.)
0.48S Uncelt
+1.0.185 TPU:
+/.0.182 0.534
+1-0.156
+/-0.153 pCi/g 9
(0% - 100%1a) SRB 06/20/0411:11 83
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 -vxr.gel.com WVorkerder:
114103
- Parmnnme Rad Gamma Spec Batch 339714 Americium-241 I3ismuth-212 Bismulh-214 Cesium-134 Ccsium-137 Cobalt-60 Europium-152 Europium-154 Europium-1S5 Lend-212 Lcad-214 Manganese-54 Niobium-94 Polassium-40 Rndium-226 Silver-108m QC Summary Sdmnn-Ounl ac Page 3 ar 12 REC°%V Rnnee Anlst Dnat Time NAM%
Unliq RPD%
M._..
y_.y_
u 0.0212 U
0.0389 pCi/g 59 Uncert:
+1.0.147
+1-0.0436 TPU:
+1.0.144
+1-0.0427 0.353 0.374 pCt/g 6
Unced:
+1-0.193
+/-0.277 TPU:
+1-0.189
+1-0.271 0.550 0512 pCi/g 7
Uncert:
+1-0.0989
+1.0.0957 TPU:
+1-.0969
+1-0.0938 u
0.030 U
0.0109 pC/g 93 Uncer:
+1-0.0311
+1-0.0237 TFU:
+1-0.0305
+1-0.0232 0.392 0.399 pCi/g 2
Unciet
+1-0.0607
+1-0.0616 TPU:
+/-0.0595
+1-0.0603 U
-0.0131 U
-0.0274 pCi/g NIA Uncert:
+1-0.0214
+1-0.0239 TPU:
+1-0.021
+1-0.0235 u
-0.0132 U
0.0403 pCi/g N/A Uncert:
+1-0.0551
+1-0.0467 TPU:
+1-0.054
+1-0.0457 U
-0.0238 U
0.0125 pCi/g NIA Unccrt
+1-0.0731
+/-0.0729 TPU:
+1-0.0716
+1-0.0715 u
0.0336 U
0.0342 pCig 2
Uncert
+1.0.0631
+/-0.0444 TPU:
+/-0.0618
+1-0.0435 0.535 0.545 pCVg 2
Ur.crt:
+I-0.0729
+/-0.0682 TPU:
41-0.0714
+1-0.0668 0.601 0.539 pCiUg I I Uncert:
+/-0.101
+1-0.0944 TPU:
+/-0.0989
+1-0.0925 u
0.025I U
0.000734 pCUg 189 Uncert:
+1-0.0222
+1-0.0229 TPU:
+/-0.0217
+1-0.0224 u
0.00641 U
-0.00206 pCVg NIA Uncert:
+1-0.0179
+/1
.0189 TPU:
+/-0.0176
+1-0.0185 I.IA 9.97 pCi/g 14 Uncest
+/-1.18
+1-1.05 TPU:
+1-1.16
+/-1.03 0.550 0.512 pCUg 7
Uncerl:
+1-0.0989
+/-0.0957 TPU:
+/10.0969
+/-0.0938 U
0.0103 UUI 0.00 pCilg 122 Uncert:
+/-0.0191
+1-0.0357 TPU:
+1.0.0187
+/-0.035 (O./- 100%M/)
(0%/ - 100%)
(0% - 100%)
(0%O
- 100/h)
(O0%- 100%)
(0%- 1OOo)
(0%m-100%~)
(0%- I00%)
(0%/.
100%e)
(0% -200%6)
(O0o - 20%h)
(0%- 100%)
(0%MO-100%N/)
(0%- IOOe) 84
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gal.com QC Summary
/7orkorder:
114103 Page 4 of 12
%rnnnmme Nfllt s5imnpi. Onnl ac unipt y naDY. RFC%/.
Minnot Anltt flatc Tl1mc G mm
.a S,;
.lc
. e_.v Rod Gamma Spec itch 339714 hallium-208 QC20604 0.171 Uncert:
+/-0.0448 TPU:
+1 0.0439 0.172 4/-0.0411
+/-0.0403 pCUg I
(0%- 100%)
QC1200640142
.ctinium-228 rnicricium-241 LCS Uncert:
TpU:
23.4 Uncert:
TPU:
S3ismuLh-212 Uncerl:
TPU:
Bismuth-214
.2esium-134 Uncert TPU:
Uncert:
TPU:
9.25 Uncert TPU:
14.4 Uncert:
TPU:
'.obalt-60 Eumpium-l 52 U
0.276
+1-0.422
+1-0.413 23.7
+/.2.10
+/.2.06 U
-0.171
+/-0.744
+/-0.729 U
-0.0842
+/-0.171 4/-0.167 U
0.000649
+/10.109
+/-0.106 10.1 41-1.09
+/-1.07 15.2
+1-1.14
+/1.1.11 U
0.0841
+/-0.234
+/-0.230 U
0.284
+/-0.231
+/10.226 U
-0.104
+1-0.289 1.0.283 U
0.075
+/-0.196 41.0.192 U
0.00716
+/-0.167
/-0.164 U
0.0272 F/-0.0938
+1-0.0919 U
-0.0445
+1.0.0865
+/.0.0948 U
1.7
+/-0.947 pCig 101 (75/-125%16) pCi/g pcitg pCi/i pCi/g PCi/g PCi/g 109 (75%-125%/)
106 (75%-125%)
06/18/04 09:28 UnccrU TPU:
-- !uropium-154 Uncert:
TPU:
!umpium-155 Uneerl:
TPU:
'.nd-212 Uncert:
TPU:
pCi/g pCig pCi/g PCUB pCi/g PCUS FCi/g Lead-214 Uncert:
TPU:
-Manganese-54 Uncer:
TPU:
llobium-94 Uncert:
TPU:
- Potassium40 Uncerl
85
GENERAL ENGINEERING LABORATORIESs LLC 2040 Savage Road Charleston SC 29407 - (843) 55568171 - mgw.gel.com
.Verkorder:
114103 QC Summary Page s or 12 Tun" c -
- t. n
... t1il nr-llnl14 nPn°o..
IlF7t?°1o lnn..
Anlrt Dn~f nmr
-urm-a-c s....
w-u
- 1.
JU,..
.M
- 1
'o.*
Rad Gamma Spec
_ atclh 339714 TPU:
Radium-226 Uncert TPU:
iilvcr-l08m Uncert:
TPU:
,ntillium-208 UncerL TPU:
QC1200640440 6bctinium-228 hin2 Uncert:
TPU:
Armcriclum-241 3isinuth-212 Uncert:
TPU:
Uncen:
TPU:
.'.ismuth-214 Uncert:
TPUI:
Cesium-134
+/-0.928 U
-0.0842
+1-0.171
+1-0.167 U
-0.0112 41-0.0983
+/.0.0964 U
0.0773
+10.0899 4/-0.0881 U
0.0246
+1-0.158
+/-0.155 U
0.0017 t/.0.0296
+/-0.029 U
0.100
+/.0.236
+/-0.232 U
0.0391
+/-0.0951 W-10.0932 U
0.0266
+/-0.031
+/-0.0304 U
0.00305
+1-0.0319
+/-0.0312 U
0.00573
+/40.0319
- /.0.0313 U
0.0347
+/-0.0621
+/-0.0609 U
-0.0707 4/-0.0819
+/10.0802 U
.0.0202
+/-0.0555 4/-0.0544 UUI 0.00
+/-0.040
+/-0.0392 U
0.0181
+1-0.0704
+/-0.069 U
0.012 Uncert:
TPU:
pOi/g pCilg pCug 06/18/04 09:26 pCUg (75%-I1 25%)
Ccsium-137 Uncurt TPU:
Uncert:
TPU:
Pcl/g pCi/g Pci/g Pci/g pCi/g pCVg
-Europium-152 Unccrt:
TPU:
,Europium-154 Uncert.
TPU:
Eurmpium-155 Uncert:
TPU:
Lend-212 Uncerl:
TPU:
-Lead-214 Unccrt TPU:
Mannganese-54 86
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Rcad Charteston SC 29407 -(843) 555-8171 -www.gel.com loarkorder.
114103 Parmname Rad Camma Spec Batch 339714 QC Summary Page 6of 12 Snmpile ounl OC Units RPD%
REC%
Rnnse Anist Date Tlme NOhl Nicbtum-94 Potassium40
_ Radium-226 Silver-108m Thollium-208 aatch 339715 QC1200640444 114103061 DUP Actinium-228 Americium-24 1 fBismuth-212 EBlsmuth-214 Cesium-134 Cesium-137 Cobalt.60 Eurapium-1 52 Europium-154 Europium-1 55 Uncerl:
TPU:
Uncert:
TPU:
Uncert:
.TPU:
Uncett:
TPU:
Uncert:
TPU:
Uncerl:
TPU:
+/-0.0249 41-0.0244 U
0.00627
+1-0.0282 4/-0.0276 U
0.295
+1-0.273
+1-0.267 U
0.0391 41-0.0951 4/-0.0932 U
0.00328
+1-0.0226
+/-0.0222 U
0.036 tl-0.0289 41-0.0283 pCi/g pCi/g pCilg pCi/g 0.529 0A22 Uncert
+1-0.176
+/-0.0972 TPU:
+/-0.173
+1-0.0952 U
-0.00178 U
-0.0232 Uncert:
+1/0.0284 41-0.0412 TPUJ:
+/-0.0278
+1-0.0404 0.557 0.366 Uncert:
+/-0272
+1-0.150 TPU:
+1-0.266
+1.0.147 0317 0.355 Uncert
+1-0.0855
+/t0.0638 TPU:
+1-0.0838
+/-0.0625 U
0.0313 U
0.020 Unccrt:
+/-0.0338
+t-0.0225 TPU:
+/-0.0331
+/10.022 U
0.0161 U
0.00443 Uncert:
+1-0.020
+1-0.0111 TPUI:
+/-0.0196
+Q-0.0109 u
0.0199 U
0.00192 Uncert:
+/-0.0209
+/4.DI I TPU:
+1-0.0205
+/-0.0108 U
-0.00309 U
-0.032 Uncert:
+/-0.0426
+/-0.0277 TPU:
+/10.0418
+1-0.0272 U
0.0183 U
0.00912 Uncert:
+/-0.0681
+/40.033 TPU:
+/-0.0668
+/-0.0324 U
0.0656 U
0.0534 Uncert:
+/-0.039
+1-0.0463 pCitg 23 pCi/g N/A pC/g 41 pCilg It pCilg 44 pCig 114 pCi/g 165 pCitg NtA pCitg 67 pCt/g 21 (0%- 100°/C)
SRB 06/19/0421k56 (0%- IO00%)
(0%- I00%)
(0%- 1000%)
(0%- 100%)
(0% - 100%)
(0%- 100%)
(0% - I 00%/)
(0% - 1 00%)
(0% - I COO')
87
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 555-8171 - w-mvg.eLcomn
.Vorkorder:
114103
.- armname Rad Gamma Spec
'latch 339715 Lend-212
__lead-214 Mnnganesc-54 Niobium-94 Potassium40
_Radium-226 Silver-108m Thallium-208 QC1200640445 LCS
-Actinium-228 Amenricium-241
-Bismuth-212 Bismuth-214 Cesium-134 Cesium-137
-Cobalt-60 Eurmpium-152 OC Summ Sample Qual lary Page 7ar 12 OC Units RPD%
REC%
Rnanpe Anlst Date Time NO;M TPU:
+1-0.0382
+1-0.0454 0.434 0.455 Uncert:
f1-0.0577
+1.0.0471 TPU:
+/-0.0565
+/-0.0467 0.365 0.389 Uncert:
+/-0.0712
+/-0.0543 TPU:
+1-0.0698
+/-0.0532 U
0.0149 U
0.0099 Uncert
+/-D.0218
+/-0.013 TPU:
+/-0.0213
+/-0.0127 U
0.00791 U
0.00158 Unceit:
+/-0.0189
+/-0.00963 TPU:
+I-OD185
+/-0.00944 11.7 12.8 Uncert:
+1-1.06
+1-1.03 TPU:
+/-1.04
+1-1.01 0.317 0.355 Unccr
+1-0.0855 4/-0.063S TPU:
f/-0.0838
+/-0.0625 U
0.0064 U
0.0059 Uncret
+/-0.0 149
+1-0.00932 TPU:
4f-0.0146
+1-0.00914 0.152 0.140 Uncert:
+-0.0419
+1-0.0243 TPU:
+1-0.041
+140.023S U
0.207 Uncert:
+/-0.412 TPU:
+/-0.44 23.4 24.2 Uncert:
+1-2.50 TPU:
+/-2A5 U
0.155 UncrrL
+4.0.770 TPU:
+/-0.755 U
0.0532 Unccrt:
+/-0.186 TPU:
+/-0.182 U
.0.0338 Uncert:
+/-0.127 TPU:
+/-0.125 9.24 9.54 Uncerl:
+/-0.872 TPU:
+1-0.855 14.3 15.2 Uncet
+1-1.20 TPU:
+/-1.17 U
0.0179 pC/g S
pCi/g 7
pCi/g 40 pCVg 133 pCi/g 10 pCag I I pCi/g 8
pCilg 8
(0% - 100%)
(0% - 100%)
(0% - 100%)
(0%- I00%)
(0% - 20%/)
(0%- 100%)
(0% - 100%)
(0% - 100%/.)
PCi/g poi/g 13ilg pCi/g pCils pCi/g PCilg PCi/g 06J20/04 10:38 103 (75%-125S) 103 (75%-I125%.)
106 (75%-125¶1) 89
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleslon SC 29407 - (843) 556-8171 - wm.geLcom QC Summary
'Vorkorder:
114103 Page 8ao 12
_ armname NOM SamnIe OuDI QC Units RPD%
REC% 6 Ranae Anist Dale Time Rod Camma Spec alch 339715 Eurupium-1S4 Europium-lS5 Uncert TPU:
Uncert:
TPU:
Uncert:
TPU:
__end-212 Uncert:
TPU:
Uncert:
TPU:
Mangancsc-54 Niebium-94 Uncerl:
TPU:
Uncert:
TPU:
.- atassium40 Uncert:
TPU.
- ndium-226
+1-0.241
+1-0.236 U
-0.0453
+1-0.230
+1-0.225 U
0.160
+/-0.339
+/-0.332 U
0.00789
+1.0.146
+/-0.143 U
-0.00281
+/-0.184
+/-0.180 U
0.011
+1-0.0984
+/-0.0965 U
0.0296
+1-0.0927
+/-0.0909 U
0.526
+1-0.921 41.0.903 U
0.0532
+1.0.186
+1-0.182 U
-0.0944
+1-0.093
+/-0.0911 U
0.0854
+/-0.0977
+1-0.0957 U
0.0888
+/I0.108
+/-0.106 U
0.00766
+/-0.0339
+1-0.0332 U
0.0866
+1-0.208
+1-0.204 U
0.0177
+V-0.0845
+/-0.0828 U
0.00791
+/-0.0305
+/-0.0298 PCI/g Pci/g PCi/g PCvg PCIV8 pCi/g PCi/g pC0g (75%-125%/e)
Uncerte TPU:
'ilver-1O0m Thallium-208 QC1200640443
%In Actinium-228
-nmericium-241 Ilismulh-212
- isrnuth-214 Cesium-134 Uncert:
TPU:
Uncert:
TPU:
Uncert:
TPU:
Uncert:
TPU:
Uncere TPU:
Uncert:
TPU:
Uncerc TPU:
Pci/g pCilg PC0/g 06119104 21:56 pCi/g Pci/g pCi/g pCi/g 89
GENERAL ENGINEERING LABORATORIES, LLC 2040 Svagae Road Charleston SC 29407 - (843) 556-8171 - vwga.aLcom QC Summary IVarkorder:
114103 Page 9 of 12 L.-armname NONI Samplc ouel OC Units RPD%
REC%
Range Anist Date Time Rlad Gamma Spec latch 339715
__Ccsium-137 Uncert:
TPU:
Cobalt-60 Uncert:
TPU:
Eurmpium-152 Unccrr.
TPU:
Europium-154 Uncert:
Tru:
-Europium-lSS Uncert:
TPU:
Lcad-212 Uncert:
TPU:
Lecd-2 14 Uncert:
TPU:
U 0.00287
+I-OM87
+1-0.0282 U
0.020
+/-0.0311 W/-0.0305 U
-0.0261 41-0.0615
+1-0.0603 U
0.00115 1-0.0801
+I-OD785 U
0.015
+1-0.0507 V1-0.0497 U
0.056 4*-0.038S
+1-0.038 U
0.0779
+1.0.048
+1-0.047 U
0.0115 41-0.0258
+I-0.0253 U
0.0369
+1-0.027
+1-0.0265 U
0.209
+1-0.303
+/-0.297 U
0.0177
+1-0.0845
+/-0.0828 U
0.00786
+1-0.0232
+/-0.022S U
0.0148 4/-0.0595
+/-0.0583 pCi/g POi/g PCilg Pci/g Pci/g Pci/g PCi/g PCI/g Mangancse-54
-Niobium-94 Uncere TPU:
Uncert:
TPU:
- PotassiumA40 Uncert:
TP(:
Radium-226 Uncert:
TPU:
Silver-108m Uncert:
TPU:
Thallium-208 Unccrt:
TPU:
-Ind Gas Flow Batch 341279 QC1200644298 Strontium-90 114103026 DUP 0.045 Uncere 4/-0.0116 TPU:
+1-0.0165 0.0291
+1-0.00953
+1-0.0119 pCilg 43 (0%- 100'%)HOB1 06/28/0404:11 QC1200644300 LCS Strontium-90 1.84 Uncert:
202
+1-0.0954 pCi/g 110 (75%-125%/.)
06/28/04 07:51 90
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com QC Summary
- Workorder
114103 Page 10 or 12 REC%
Runve Anist Date Time nnrmname NOM Sample Ount OC Units RPD%
Rad Gas Flaw gatch 341279 TPU:
+1-0.552 QC1200644297 blB Stronlium-90 QC1200644299 114103026 MS Strontium-90 Rad Liquid Scinfllallon Datch 341070 QC1200643930 114644001 DUr
_Technelium-99 QC1200643932 LCS
_Technelium-99 Uncert:
TPU:
U 0.00852
+1-0.00848
+-a0.oos0s pCi/g 3.81 Uncert TPU:
0.045
+1-0.0116 W/-0.0165 3.87 4/-0.188
+1-0.998 pCi/g 100 (75%-125%)
U
-3.85 Uncert:
+/-3.39 TPU:
+1-3.39 U
-2.67
+1-3.07
+/-3.07 pCit/
NIA (0% - 100%) DAJI 06/28/0404:11 06/28/04 0751 0618/0406:13 06J28104 07:17 0612U04 05:41 06/28/M4 06:45 142 Uncert:
TPU:
14.4
+I-OA39 410.573 pC/g 101 (7M%-125%)
QC1200643929
_Tcchnetium-99 MB Unccrte TPU:
U 0.0183 4/-0.209
+/-0.209 pCUg QC1200643931 114644001 MIS
_rcchnetium-99 210 U
UncertL TPU:
-3.85
+1-339
- /-339 207
+/-6.57
+1-8AS pCi/g 99 (751/6-125%)
latch 342387 QC1200647033 Carbon-14 QC1200647035 Carbon-14 113282020 DUP LCS U
-0.0219 Uncert:
+1-0.115 TPU:
+1-0.1 IS U
0.0321
+1-0.155
+1-0.155 pCi/C N/A (0%- 100%) MWX 06/22J04 01:09 8.21 Uncert TPU:
7.60 4/-0.541
+I-0.554 pCig 93 (75%.-125%)
QC1200647032 MB Carbon-14 Uncert:
TPU:
U 0.122
+/-0.184
+/-0.184 pCi/g 06120/04 17:23 062110422:36 06120/04 16.51 QC1200647034 Carbon-14 113282020 MS 8.15 U
Uncert:
TPU:
-0.0219
+/.0.1 Is
+1-0.115 7.75
+1-0.614
+/-0.626 pCi/n 95 (7516-125%)
-Jatch 342541 QC120G647441 113282019 DUP Iran-55 U
-31A Uncert:
+/-41.4 TPU:
+1.41.4 U
-45.5
+1-40.7
+140.8 pCI/g NIA (0M%- 100%)
JLBI 06123/04 17:41 91
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 -
Mwv.Gelcom Workarder:
114103 Parmname Rad Llqutd Sdatillatlon OatcI 342541 QC1200647443 LCS Irmn-55 QC1200647440 1MD Iron-SS QC1200647442 113282019 MIS Ircn-55
_ atch 342542 QC1200647445 114103026 DUP Nickel-63 QC1200647447 LCS Nickel-63 QC1200647444 M11 Nickel-63 QC1200647446 114103026 MS Nickel-63 Batch 342680 QC1200647788 115079001 DUP Tritiun QC1200647791 LCS TFritium QC1200647787 MB Tritium QC1200647789 115079001 MS Tritium QC1200647790 115079001 MSD Tritiurn QC Summary Page ii or 12 NON Saimpte Qual QC Units RPD%
RECM Range Anist Date Time 1170 Uncerte TPU:
Uncert TPU:
1510 U
-31.4 Uncer
+1/41.4 TPU:
+1/41.4 U
-12 Uncert:
+1-12.9 TPU:
+1-12.9 486 Uncert:
TPU:
Unccrt:
TPu:
618 U
-12 Uncer 4+l-12.9 TPU:
+/-12.9 U
0.0936 Uncert:
+/-0.766 TPU:
+1-0.766 5.25 Uncen:
TPU:
Uncert:
TPU:
539 U
0.0936 Uncert:
+1-0.766 TPWJ:
+1-0.766 5.25 U
0.0936 Uncert:
+/.0.766 1110
+1-58.2
+/-75.4 U
-73.1
+/-37.1
+/-37.2 1450
+/-53.5 4/-82.4 U
-2.06
+/-I 1.0
+1-1 1.0 417
+/-19.5
+/120.9 U
-2.24
+1-1 0.1 S56
+/-27.0
+1-28.8 U
-0.032
+/-0.782
+/-0.782 5.58
+1/0.599
+1-0.689 U
0.201
+I-OA02
+/-0.402 S24
+/-0.951
+1-0.994 4.75
+1-0.969 pCOg pCUg pCi/g 95 (75%.125'%*)
96 (75V-125%)
pCUg pCi/g pCi/g pCilg pCi/g pCUg pCi/g pCUg NIA (0°S41-Omd)
JLB1 86 (75%.125%/.)
06/23104 00:37 05/23/04 17:09 06/23/04 00:05 06/27/04 2229 06/27/04 23:32 06/27/0421:57 06/27104 23:00 06/30/04 13 30 06/27/04 01.06 06/261042258 06/27/04 00:02 06127104 00:34 90 (75%-125%)
N/A 10 (0%- 100CO)
ILLI 106 (75%-125'%)
95 (75%/-125%/)
89 92
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com QC Summary Workarder:
114103 Page 12 or 12 Parmname NOM Sample Qual QC Units RPD%
REC%
Range Anist Date Time Rad Liquld Scintillation Batch 342680 TPU:
+1-0.766
+1.1.01 Notes:
The Qualifiers in this report are defined as follows:
B Target analyte was detected in the sample as well as the associated blank.
HD Flag ror results below the MDC or a nag for low tracer recovery.
E Concentration afthe target analyte exceeds the Instrument calibration range.
H Analytical holding time exceeded.
J Indicates an estimnted value. The result was greater than the detection limit, but less than the reporting limit.
U Indicates the target analyte was analyzed for but not detected above the detection limit.
Ul Uncertain identification For gamma spectroscopy.
X Lab-specific qualifier-please see ease narrative, data summary package or contact your project manager for details.
h Sample preparation or preservation holding time exceeded.
N/A Indicates that spike recovery limits do not apply when sample concentration exceeds spike eonca by a factor of 4 or more.
- Indicates analyle is a surrognte compound.
"'Me Relative Percent Difference (RPD) obtained from the sample duplicate (DUP) is evaluated against the acceptence criteria when the sample Is greater than five times (5X) the contract required detection limit (RL). In cases where either the sample or duplicate value is less than 5X the RL, a control limit ort+- the RL Is used to evaluate the DUP reult.
For PS, PSD. and SDILT results, the values listed are the measured amounts, not final concentrations.
Where the analytical method has been performed underNELAP certification, the analysis has met all of the requirements or Lhe NELAC standard unless qualified on the QC Summary.
93
SOUTH SITE GROUNDS SURVEY UNIT 9524-0000 RELEASE RECORD b Hard-to-Detect Data (6 Pages)
GENERAL ENGiNEERING LABORATORIES, LLC GENERAL ENGINEERING LABIORATORIES, LLC 2040 Savage Road Chadeston SC 29407 - (843) 55S-8171 - www.gl.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address:
Haddar NeckPlant 362 Igun Hollw Road East Hampton, CoMnecdcut 06424
Contact:
Mr. Pete Hollenbeck ProJect:
Sols P0#4002332 RcportDate: July 1.2004 Page I of 3 cient Sample ID:
Sam ID :
Maii:
CollectDate.
Receive Date:
Collector.
Moisture:
9524-0000-007W ProjecL YANK045O 11410302 CetI:
YANKOOI Soil VoL Recv.:
24-MAY-04 03-JUN-04 Ctlent 11%
Pameter Qualifier Result Uncertainty LC TPU MDA Rnd Atphn Spec Aalyss A:iphwapecAm241, CGn SoalkAL FSS Amerclum-241 U
0.00119 40.0646 0.0677 +1-0.0646 0.216 CurlumZ242 U
-0.00837 1-0.0164 0.0397 41.0.0164 0.174 Curium-2431244 U
0.00 4+/0.0584 0.00 +1-O.05B4 0.0307 Alphaspec Pf Solld-ALU FSS Plutonlum-238 U
-0.0444 41.0.0329 0.0797 4-0.0332 0.231 Plutonlum-2391240 U
0.0148
+-0.0792 0.0737 41-0.0793 0.219 Liquid Scint Pu24J, Solid-ALL FSS Plutonlum-241 U
3.47
+1-4.82 398 414.83 8.12 Rod Gamma Spec Analysts Gaomaspec; Gamma; Solid-FSS JAM
& ALL FSS Actinium-22S U
0.00
+1-0.154 0.119 4/-0.151 0.248 U'
Aniciun:-241 U
-0.0388
+1-0.203 0.120 41.l.99 0.249 Blsmuth-212 U
0358
+/-0203 Ql71
- 41.199 0.360 Blumaih-214 0581
+1-0.105 0.0335 41..103 0071 Ceshim.134 U
0.0411
.4/0.027 0.0243 +1-0.0264 O.OS14 Ceslhn.137 U
0.0333 48-04 0.0226 41-0.0279 0.0477 Cobalt-60 U
0.000406 410.0284 0.0203 -W-0.0279 0.0445 Earopium-152 U
0.0412 44-0.0549 0.0486 41-0.0538 0.102 Europlum-154 U
0.05 41-0.0711 0.0637 +1-40697 0.138 Earoplum-15S U
0.0295 41-00688 0.0586 +4140674 0.121 Lxa&212 0.648 41-0.0836 0.0284 +1-0.0819 0.059 Lead-214 0.594
+1-0.109 0.0326 41-a.107 0.0687 Manganuc-54 U
0.0065
+41-0M22 0.0194 41.0.027 00415 Nloboirn-94 U
0.00398 4-0.020 0.0166 -4.0.0196 0.0353 Posusiun-40 13.2 4W-1.38 0.138 4-1.3S 0.315 Radima-226 0.581 41.0.105 0.0335
+1-0.103 0.011 SD'cr-108m U
-0.0202
+1.0.019 0.0159 4/-0.0117 0.033S Thalliur-208 0.224
+1-.00567 0.0152 +1.0.0555 0.0326 Rad Gas FlowProporflatal Countlng GFPC, Sr9 sold-ALL FSS Stzrntiu-90
.0328
+1-0.008S6 0.00622 41.0.122 0.0128 Rad Liquid Sdntillatlon Analysts Mr4 Mflum D>U Sotldt-flT)2,L fSS TrIdum U
0.68
+1-5.20 433
+1-5.20 8.66 Units DF AnalystDate Tme Balch MWi.
pCVg PCak pcilg PCug pC/g JS1 0630/04 1403429041 lSI 06U 04 1541 3429002 JSI 06t29/04 2314 342903 3 SRB 06/21J04 1616 339714 4 pCag pCug PCL pCilk pCVlg PCag pCV3 pCUg pCltg pCYg pCUg pCag Pcig pCL'g Pci/
HOB 06104 0257 3412795 n15 I 06124 1916 342680 6 75
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 55648171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Powcr Address:
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Contact:
Mr.te Holfenbeck Project:
Solls PO# 002332 RepoctDale: July 1.2004 Page 2 or 3 Clidet SamplelDJ:
Samplem D:
9524000-007F 114103025 roject YANKOMS04 Client iD:
YANK00I Vol. Remv.:
Parameter Qunlwfer Result Uncertnlnty LC TPU MDA units DF AnalyulDate Time Datch Mild.
Itnd Liquid Sdntl~latoUn Analysis Liquid Scint C14, Solid FSS Cacbon-14 U
0.0683 4/.0.125 0.0845 +1-0.125 0.174 pClg LiquldScInt Fc55 Solid-ALL FSS Ibon-55 U
15.1
+1-37.5 LiquidScintNi63. Sdlid-ALLFSS Nickel-63 U
0.416
+/-12.7 Liquid ScinY TP9. Solid-ALL FSS Technedum-99 U
0.0885
+I-O54 15.3 4/-37.5 31.9 10.6
.1-12.7 21.8 pC11g pCI/g MWX 06/21/04 1701 342387 7 1
J.D1 0&6/04 2158 342S41 9 JLBI 0627104 2055 34254210 DAII 06/29104 0404 34107011 0.211
+10254 0.432 PCI/g The following Prep Methods weroperfonued Method Desedptlon Analyst Date Tlme
'rep Bltch Ash Soil Prep Ash Soil Pep, GL-RAD-A-021B BSWI 06107104 1610 338594 DrySollPrep DrySolPrepGleRAD-A-02t DSWI 06M1104 1510 338588 The following AnEa!Ztl Methods were performed Melhod Descuiption I
DOE EML HASL-300, Am-05-RC Modificd 2
DOE EML. HASL300,Pu-I-RCModified 3
DOt3 EML IIAS1300, Pu-l I-RC Modilied 4
EML L300.,4.23 S
EPA 90S.0 Modified 6
EPA 906.0 Modifed 7
EPABERPC 01 Modified e
EPA EERFC-01 Modified 9
DOE RESLFc-l, Modified 10 DOBRESLNI-,Modified 11 DOE EML fASL-300.Tc-02-RC Modified Surrogutdrracer recovery Test Rtcoverye Acceptable Lbilts Azericum-243 Alphaspce Am24l. Cm, Solid ALL 92 (25%-1259)
Plutonium-242 C-ciT mu= Recovery Carrflducer Rtecovcry Carric(rfracer Recovery Alphaspec Pu, Soald-ALL FSS XJqad Sciat Pu241. SeUd-AM. FS GPPC, Sr9O, solid-ALL FSS Liquid Scint FeS5, Solid-ALL FS 90 79 16 81 (25%-12S%)
76
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charlston SC 29407 - (843) 555-8171 - www.gel.com Certificate of Analysis Company:
CoanectlcutYankee AtomicPower Address:
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Contact:
Mr. Pete Hollenbeck Project Sils PO# 002332 CMentSarnpletD:
SampleID:
Report Date: July!, 2004 Page 3 of 3 9524-0000-00F 114103025 "Piclci YANKLOS04 ient D:
YANK001 Vol. Recv.:
Parameter Qualifler Result Unceranty LC TPU MDA Units DF AruilyslDate Time Batchb td.
Carierfrracer Recovery Canderfrncer Recovery Liquid Scint N163. Solid-ALL FS Liquid ScintTc99, Solld-AMLFS 87 73 Notes:
TIe QualifiEcs In this report am defined as follows:
B Target analyte was detected In the sample as well as the associated blank.
DD Flag for results below the MDC or a fg for low tracer rrcovery.
e Concntration of tho target analyte exceeds the instrnncat calibration range.
H Analytical holding time exceeded.
I Indicates an estimated value. lhe result was greater than thc detection lirnit, but less than the reporting imifL U
Indicats the target analyte was analyzed for but not detcted above the detection l1miL UlI Uncertain identification forgamma spectroscopy.
X Lab-specific quallfier-pleassee cas nrativ, data aummay package orcontact yourproject mnager fordetails.
h Sample preparation or preservation holding time exceeded.
The above sample b reported oan a dry weight basLs.
This data report has been prepared and reviewed In accordance with General Engineering Laboratories, LLC standard operating procedures. Please direct any questions to your Project Manager. Sarah Kozlik Reviewed by 77
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 -www.geLcom Certificate of Analysis Company: Connecticut Yankee Atomic Power Address:
HaddamNcckPlant 362 Injun Hollow Road East Hampton, Connecticut 06424 Contact.
Mr. Pete Hollenbeck Project:
Soils PON 002332 Client Sample 1D:
Sarmle ID:
Matrix:
Colicct Date:
Receive Date:
Collector Moisture:
Report Datc July 1.2004 Page 1 of 3 9524-0000-0IOF Proiect:
YANK00504 114103026 Client ID:
YANKOoI S1il Vol. Reav.:
24-MAY-04 03-JUN-04 Client 12.4%
Parameter Qualifier Result Uncertainty LC TPU MDA Units DF AnalysDalc Time BatchMit Enid Alpha Spec Analystis AlphapccAmZ41, Ca, SValdALZ. FSS Americim-241 U
-0.0726 41.0.101 Curlum-242 U
0.177 40.347 Curlum-2431244 U
0.115 41.0306 Alp hpecPu, Solld-ALLFSS Plutonium-238 U
0.00 41-0.28B Plutonlum-239WO U
0.147 41-0 ZB Lqud Sctint Pu241. Solid-ALL FSS Plutonium-241 U
0.143 4-13.7 Rtad GamM SpecAnalys Gemmcapc4 Gamma, Solld-FSS GAU &ALL FSS Actinium-228 0.446 1.0.162 Americlum-241 U
-O141 41-0.123 BIhmuth-212 U
0S35 4-0.221 Bismuth-214 0.411 41-0.0869 Ceslum-134 U
0.0116
+I-0.0138 Ceslum-137 0.0768
+140.0293 Cobalt-60 U
0.00932
+1-0.0179 Europlum-152 U
.000325
.1-0.0434 Europium-154 U
-O0OS65 4/-0.0538 Europlum-155 U
0.012B
+1-0.0449 Lcad-212 0.433
+1-0.0615
_ lcd-214 0.50 44.0.14 Manganese-54 U
0.00316 4l.017 Nioblum-94 U
-0.00031
-0.015S Potnsshmu40 11.5
+/-123 Rindlum-226 0.411 4-0.0869 Silver-108m U
-0.00293 41-0.0138 Tbalflum-208 0.120 4*10.0394 Rad Gas Flow Proportionl Counting GFPC, S90, walld-ALL FSS Stronflum-90 0.045 W4.0116 Rad Liquld Scintillaton Analysis LSC Triwum Dlis. Solid-1D2.ALL FSS Tritium U
1.70
- 1-5.49 LWd Sclnt C4. Solld FSS 0.244 41-0.101 M0O W-0.348 0.173 41-0.306 0.00 41-0.28 0.00 t-0289 1 1.5 4-13.7 Q0443 41-0.159 0.0933 40.120 0.112
+00217 0.026B 41-0.051 0.0164 4-0.0154 0.0129 W/-0.021 0.0159 +/.0175 0.0357 +4-100425 om92 4-0.0527 0.0407
+1-0.044 0.0218 *t-0.0602 0.0241 41-0.0798 0.0143 F1-0.0167 0.013 +1-0.0152 0.118 1-1.21 0.026S J4-0.0851 0.0119 W-0.0135 0.0137 tJ-0.0386 0.0075 4/-0.0165 0.897 pCilg 0.480 pCUg 0.757 pCIg 0.399 0.398 23.4 0.0964 0.194 0.239 0.0569 0.0352 0.0277 0.0349 0.0752 0.0869 0.0846 0.0455 00509 0.0308 0.0277 0.263 0.0569 0.0252 0.0291 0.0179 pClg pCi/g pCVg pCI~g pCl/g pCUg pCI~g pCUg pCUg pClg pCllg pCi/g pCUS pCVg pCeg pCl/g pCig pCl/g pCIMs JSI 0613/G04 0925 34294 1 JSI 0660=4 1541 342900 2 JS1 06/1Y04 0046 34290 3 SRB 06/20/04 1110 3397144 HJOBI 0U21V04 0411 3412795 MM o0&I04 3948 342680 d 454
-1S.49 78
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407- (843) 556-8171 -www.gel.com Certificate of Analysis Company: ConnectlcutYankec Atomic Power Address:
HaddamNeckPlant 362.Injun Hollow Rood East Hxraptan, Connecticut 06424 Cotact:c Mr. Pete HollenbCck Projcct:
Salls PO 002332 Client Samplc ID:
Sauplc ED:
Parameter Qualifer Result Uncertauinty Rod Liquld Sclntllntion Analysis Liquid Sct C14, Solid FSS Carbon-14 U
0.172 4/-0.153 Liquid Setnt FcS5, Solid-ALL FSS Iron-55 U
-502
+/-41.6 Liquid Scint N163, Solid-AtL FSS Nickel-63 U
-12
+/-12.9 liquid Scit Tc99, Sclid-ALL FSS Techactium-99 U
0.0104
+/-0.237 Report Dae: July 1.2004 PAgr 2 of 3 9524-0000-01OF 114103026 Pwpicct YANK00504 ColenID:
YANK0O:
Vol. Recv.:
LC TPU MlDA units DF AnalystDato Time Batch Mid.
0.102
+/-0.153 17.0
+141.6 11.2
+1-12.9 0.193
+.,0.237 0.2W pCig 35.4 23.1 Q406 pCUg PClg VCVg MWX 06121/04 1904 342387 7 1
JLBI 06123/4 1637 342541 9 J131 06127/04 2126 342547 10 DAJ1 062WD4 0436 341070 It The (f[lowing Prte Methods were verforned Method Description Analyst Date Time Prep Datch Ash Soil Prep Ash Soil Frp, GOtRAD-A-021B BSWI 06107104 1610 33S594 DrySollrep DrySollPrcp UtRAD-A-021 BSWI 06104104 1510 338588 Ibe following A!Hytical Metods were performed Method Descripffon.
I DOE EML HASL-300, Am-05-RC Modlficd 2
DOE EML HASL,300. Pu-I I-RC Modified 3
DOE EML. HASL-300, Pu-I I-RC Modified 4
EMALHASL300.4.5.23 5
EPA 905.0 ModIfied 6
EPA 906.0 Modified 7
EPAEERFC-O0 Modifled 8
EPA EERF C-C1 bodiffed 9
DOE RESL Fc-Il Modified 10 DOE RESL NM-. Modified 11 DOE EML HASL-300, Tc-02-RC Modified Sarropletracer recoray Test Recovesy%
AcJccptable Lmits Amralcrum-243 Alphaspec Am241. Cm. Solid ALL 82 (25%-125%)
Plutonlum-242 C1uCocrRCeayerY CardcrfrmcerRccovery CanaitcraccrRecovery Alphaspec Pu, Soetd-ALL PSS Uqud ScntPu241,Ba1ld-/TLPS OFPC, Sz9O, solid-ALLFSS Liquid Scint cSS, Solid-ALL FS 9
as B7 83 (25t-125%)
79
GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Read Charleslon SC 29407 - (843) 655-8171 - wwwg.el.com Certificate of Analysis Company: C nocttYankce Atomic Power Addrem:
Haddam Neck PIant 362 Injun Hollow Road EastHampton, Conxecticut 06424 Contacl:
Mr. Pelc Hollenbeck Project:
Soils PO# 002332 Report Date July 1,2004 Page 3 of 3 Cieat Sample 1D:
Sample 11:
9524-4XOIOP 114103026 Proct:
YANCOO04 cient mD:
YANICOO1 Vol.RccV.
Parameter Qualifier Result Uncertainty LC TPU MDA Unils DF AnalystDate Time DatchMid.
Carrierflraeer Recovery Carric ractr Recovery Liquid Scint N163. Solid-ALL FS Liquid Scint Tc99, Solid-ALL FS 78 76 Notes:
Tha Qualiflers In this report are defined as follows:
B Target naalyte was detectkd in thc samplc wel as the associated blank.
BD Flag for rcsults below the MDC or a flag for low tracer recovery.
E ConcentrIon of thc target analyte exceeds the instrument calibration range.
H Analyticalholding timee xcceeded.
J Indicates an estimated value. The result was greaterthan the detection limit, but less than the reporting liUrlL U
Indicalca the target aonlyte wsanayzecd forbut not dctected abovc the detcctio limlt.
UI Uncertain identilcation for gamma spectroscopy.
X. Labspecific qualfier-pleasesce casc narrafive, data summary package orconiact yourproject managerfordetails.
h Samplc prepaation or prscrvation holding time exceeded.
7hc above sample Is rWorted on a dry weight basisL This data report has been prepared and reviewed In accordance with General Enginecring Laboratories, LLC standard operating procedures. Please direct any questions to your Project Manager, Sarah Kozlk W4k6cu f Reviewed by CD CA-0 80
SOUTH SITE GROUNDS SURVEY UNIT 9524-0000 RELEASE RECORD c Sample and Scan Area Data (4 Pages)
Survey Release Record Scan Area Results Survey Unit 9524-0000 Survey Unit 9524-0000 Scan Area 1 SryLoaon
Background
Acin RaigE-600 Probe Survey Location p
Level (gross Log Date Log Time SIN SPo (cp m)
(cpm )
Cpm )__
9524-oo-001-BC-00I1 0
7390 5/17/2004 10:07:00 1112 1005 9524-00-001-BC-002 0
7180 5/12/2004 13:41:00 1112 1005 9524-o0-o01-SC-001 7180 8389 7750 5/12/2004 13:54:00 1112 1005 9524-00-001-SC-002 7390 8617 6040 5/17/2004 10:10:00 1112 1005 9524-00-00l-SC-003 7180 8389 6560 5/12/2004 13:57:00 1112 1005 9524-00-001 SC-004 7390 8617 6980 5/17/2004 10:13:00 1112 1005 9524-00-001-SC-o05 7180 8389 7510 5/12/2004 14:12:00 1112 1005 9524-00-001-SC-006 7390 8617 6760 5/17/2004 10:18:00 1112 1005 9524-00-o01uSC-007 7180 8389 7040 5/12/2004 14:15:00 1112 1005 9524-00-001-SC-008 7390 8617 5950 5/17/2004 10:21:00 1112 1005 9524-O0-001 -SC-009 7180 8389 7250 5/12/2004 14:22:00 1112 1005 9524-00-001-ER-001 7390 8617 16900 5/17/2004 10:25:00 1112 1005 9524-o0-001-SC-010 7390 8617 6560 5/17/2004 10:27:00 1112 1005 9524-o0-o01-SC-01 1 7180 8389 6890 5/12/2004 14:24:00 1112 1005 9524-00-o0l-SC-012 7390 8617 6260 5/17/2004 10:29:00 1112 1005 9524-00-001-SC-013 7180 8389 7060 5/12/2004 14:37:00 1112 1005 9524-00-001-SC-014 7180 8389 7050 5/12/2004 14:38:00 1109 1009 9524-00-00l-SC-015 7180 8389 8010 5/12/2004 14:41o00 1112 1005 9524-o0-001-SC-016 7180 8389 7480 5/12/2004 14:4A.00 1109 1009 9524-00-001-SC-017 7180 8389 6620 5/12/2004 14:44:00 1112 1005 9524-00-001-SC-018 7180 8389 7270 5/12/2004 14:47:00 1109 1009 9524-00-001-SC-019 7180 8389 7080 5/12/2004 14:49.00 1112 1005 9524-00-001-SC-020 7180 8389 7070 5/12/2004 14:51:00 1112 1005 9524-00-002-BC-001 0
7090 5112/2004 15:00:00 1112 1005 9524-00-002-BC-002 0
7870 5/12/2004 14:59:00 1109 1009 Scan Area 2 ActIon Reading Survy Location
Background
E-600 Probe SreLoain (cpm)
Level (gross Log Date L~og Time SIN SI
~~ ~ cpm) 9524-00-002-BC-003 0
6950 5/18/2004 12:43:00 1111 1001 9524-00-002-SC-019 6950 8140 6970 5/18/2004 12:49:00 1111 1001 9524-00-002-SC-020 6950 8140 6310 5/18/2004 12:51:00 1111 1001 9524-00-002-SC-021 6950 8140 8040 5/18/2004 12:52:00 1111 1001 9524-00-002-Sc-022 6950 8140 6340 5/18/2004 12:54:00 1111 1001 9524-00-002-SG-023 6950 8140 6290 5/18/2004 12:56:00 1111 1001 9524-00-002-SC-024 6950 8140 7630 5/18/2O04 12:58:00 1111 1001 9524-00-002-SC-026 6950 8140 7240 5/18/2004 13:00:00 1111 1001 9524-00-002-Sc-025 6950 8140 7170 5/18/2004 13:01:00 1111 1001 9524-00-002-SC-026 6950 8140 7090 5/18/2004 13:03:00 1111 1001 9524-00-002-SC-027 6950 8140 6860 5/18/2004 13:05:00 1111 1oo1 9524-00-002-SC-028 6950 8140 7200 5/18/2004 13:07:00 1111 1001
Survey Release Record Scan Area Results Survey Unit 9524-0000 Scan Area 2
Background
Action Reading Survey Location (cpm)
Level (gross Log Date Log Time EI00 Probe (Cpm) cpm)
______SIN_
9524-00-002-SC-029 6950 8140 6630 5/18/2004 13:10:00 1111 1001 9524-00-002-SC-030 6950 8140 6440 5118/2004 13:12:00 1111 1001 9524-00-002-SC-031 6950 8140 7660 5118/2004 13:14:00 1111 1001 9524-00-002-SC-033 6950 8140 7380 5/18/2004 13:16:00 1111 1001 9524-00-002-SC-032 6950 8140 7430 511812004 13:17:00 1111 1001 9524-00-002-SC-033 6950 8140 6480 5/18/2004 13:19:00 1111 1001 9524-00-002-SC-034 6950 8140 6170 5/18/2004 13:21:00 1111 1001 9524-00-002-SC4035 6950 8140 7220 5/18/2004 13:23:00 1111 1001 9524-00-002-SC-036 6950 8140 7170 5/18/2004 13:24:00 1111 1001 9524-00-002-SC-037 6950 8140 7630 5/18/2004 13:26:00 1111 1001 9524-00-002-SC-038 6950 8140 7200 5/1812004 13:29:00 1111 1001 9524-00-002-SC-039 6950 8140 7720 5118/2004 13:31:00 1111 1001 Scan Area 3 Action Reading E60 rb Survey Location
Background
Level (gross Log Date Log Time SIN 9524-00-003-BC4001 0
7850 5/19/2004 10:23:00 13124097 1007 9524-00-003-SC-001 7850 9114 8140 5/19/2004 10:27:00 13124097 1007 952400-003-SC-002 7850 9114 8030 5/19/2004 10:30:00 13124097 1007 9524-00-003-SC-003 7850 9114 7220 5/19/2004 10:34:00 13124097 1007 9524-00-003-SC-004 7850 9114 8050 5/19/2004 10:37:00 13124097 1007 9524-00-003-SC4005 7850 9114 7250 5/19/2004 10:41:00 13124097 1007 9524-00-003-SC-006 7850 9114 8070 5/19/2004 10:44:00 13124097 1007 9524-00-003-SC-007 7850 9114 7190 5/19/2004 10:46:00 13124097 1007 9524400-003-SC-008 7850 9114 7670 5/19/2004 10:49:00 13124097 1007 9524-00-003-SC-009 7850 9114 6820 5/1912004 10:54:00 13124097 1007 9524-00-003-SC-010 7850 9114 7010 5/19/2004 10:57:00 13124097 1007 952i-00-003-SC-011 7850 9114 7840 5/19/2004 11:02:00 13124097 1007 9524-00-003-SC-012 7850 9114 6850 5/19/2004 11:07:00 13124097 1007 9524400-003-SC-013 7850 9114 6880 5/19/2004 11:11:00 13124097 1007 9524-00-003-SC-014 7850 9114 7000 5/1912004 11:15:00 13124097 1007 9524400-003-SC-015 7850 9114 8450 5/1912004 11:19:00 13124097 1007 9524-00-003-SC-016 7850 9114 7020 5/19/2004 11:23:00 13124097 1007 9524-00-003-SC-017 7850 9114 7930 5/19/2004 11:26:00 13124097 1007 9524-00-003-BC-002 0
7770 5/19/2004 13:34:00 13124097 1007 9524-00-003-SC-018 7770 9028 7300 5/19/2004 13:38:00 13124097 1007 9524400-003-SC-019 7770 9028 7280 5/19/2004 13:42:00 13124097 1007 9524-00-003-SC-020 7770 9028 7890 5/19/2004 13:45:00 13124097 1007 9524-00-003-SC4021 7770 9028 7360 5/19/2004 13:49:00 13124097 1007 9524-00-003-SC-022 7770 9028 7250 5/19/2004 13:53:00 13124097 1007 9524-00-003-SC-023 7770 9028 6830 5/1912004 13:56:00 13124097 1007 9524-00-003-SC-024 7770 9028 7670 5/19/2004 14:01:00 13124097 1007
Survey Release Record Scan Area Results Survey Unit 9524-0000 Scan Area 3 Backgound Action ReadingE60 Prb Survey Location
Background
Level (gross Log Date Log Time E600 lProbe (PM) cm)
Cpm)
I 9524-00-003-SC-026 7770 9028 7670 5/19/2004 14:04:00 13124097 1007 9524-00-003-SC-025 7770 9028 7170 5119/2004 14:04:00 13124097 1007 9524-00-003-SC-026 7770 9028 7580 5/19/2004 14:09:00 13124097 1007 9524-00-003-SC-027 7770 9028 6690 5/19/2004 14:13:00 13124097 1007 9524-00-003-SC-028 7770 9028 8340 5/19/2004 14:20:00 13124097 1007 9524-00-003-SC-030 7770 9028 6410 511912004 14:25:00 13124097 1007 9524-00-003-SC-029 7770 9028 6610 5/1912004 14:27:00 13124097 1007 9524-00-003-SC-030 7770 9028 7770 5/19/2004 14:30:00 13124097 1007 9524-00-003-SC-031 7770 9028 7120 5/19/2004 14:33:00 13124097 1007 9524-00-032-SC-032 7770 9028 8120 5/19/2004 14:36:00 13124097 1007 9524-00-003-SC-033 7770 9028 8630 5/19/2004 14:39:00 13124097 1007 9524-00-003-SC-034 7770 9028 7920 5/19/2004 14:43:00 13124097 1007 9524-00-003-SC035 7770 9028 6900 5119/2004 14:46:00 13124097 1007 9524-00-003-SC-036 7770 9028 8330 5/19/2004 14:50:00 13124097 1007 9524-00-003-SC-037 7770 9028 8670 5/19/2004 14:53:00 13124097 1007 Scan Area 4 Action Reading
Background
Lvl (rg LgDt LoTie E-600 Survey Location
(
)Level Ross Log Date Log Time Probe SIN 9524-00-004-BC-001
_0 7580 5/20/2004 8:52:00 13124097 1007 9524-00-004-SC-001 7580 8823 8020 5/20/2004 8:56:00 13124097 1007 9S24-00-004-SC-002 7580 8823 6850 5/20/2004 8:59:00 13124097 1007 9524-00-004-SC-003 7580 8823 8170 5/20/2004 9:OL:OO 13124097 1007 9524-00-004-SC-004 7580 8823 7200 5/20/2004 9:03:00 13124097 1007 9524-00-004-SC-00s 7580 8823 8400 5/20/2004 9:05.00 13124097 1007 9524-00-004-SC-006 7580 8823 6320 5/20/2004 9:07:00 13124097 1007 9524-00-004-SC-007 7580 8823 7380 5/20/2004 9:10:00 13124097 1007 9524-004)04-SC-008 7580 8823 8510 5/20/2004 9:13o0o 13124097 1007 9524-00-004-SCM09 7580 8823 8500 5/20/2004 9:17:00 13124097 1007 9524-00-004-SC-010 7580 8823 7670 5/20/2004 9:19:00 13124097 1007 9524-00-004-SC-011 7580 8823 8510 5/20/2004 9:21:00 13124097 1007 9524-00-004-SC-012 7580 8823 7140 5/20/2004 9:24:00 13124097 1007 9524-00-004-SC-013 7580 8823 7700 5/20/2004 9:27:00 13124097 1007 9524-00-003-SC014 7580 8823 7210 5/20/2004 9:30:00 13124097 1007 9524-00-004-SC-015 7580 8823 8240 5/20/2004 9:33:00 13124097 1007 9524-00-004-SC-016 7580 8823 6800 5/20/2004 9:36:00 13124097 1007 952400-004-SC-017 7580 8823 7900 5/20/2004 9:39:00 13124097 1007 9524-00-004-SC-018 7580 8823 7440 5/20/2004 9:42:00 13124097 1007 9524-00-04-SC-019 7580 8823 6720 5/20/2004 9:44.00 13124097 1007 9524-00-004-SC-020 7580 8823 6860 5/20/2004 9:47o00 13124097 1007 9524-00-004-SC-021 7580 8823 7050 5/20/2004 10:25:00 13124097 1007 9524-00-004-SC-022 7580 8823 7570 5/20/2004 10:28:00 13124097 1007
Survey Release Record Scan Area Results Survey Unit 9524-0000 Scan Area 4
Background
Acin RaigE-600 Survey Location Level (gross Log Date Log Time Probe S/N
-(cpm)
(Cpm) cpm)
SIN 9524-00-004-SC-023 7580 8823 7870 5s20o2004 10:32:00 13124097 1007 9524-00-004-SC-024 7580 8823 7570 5/20/2004 10:35:00 13124097 1007 9524-00-04-SC.025 7580 8823 7400 s52012004 10:37:00 13124097 1007 9524-00-004-SC-026 7580 8823 7840 s52O/2004 10:41:00 13124097 1007 9524-00-004-SC-027 7580 8823 7050 s520/2004 10:44:00 13124097 1007 9524-00-004-SC-028 7580 8823 7590 5/20oo4 10:47:00 13124097 1007 9524-00-004-SC-029 7580 8823 7090 5/20/2004 10:49:00 13124097 1007 9524-00-004-SC-030 7580 8823 7610 5/20/2004 10:52:00 13124097 1007 9524-00-004-SC-031 7580 8823 7910 5/20/2004 10:54:00 13124097 1007 9524-00-004-SC-032 7580 8823 7270 520/0oo4 10:58.so0 13124097 1007 9524-00-004-SC-033 7580 8823 7550 5/20/2004 11:02:00 13124097 1007 9524-00-004-BC-002 Disregard
- VALUEI 6670 5/20/2004 13:40:00 13124097 1007 9524-00-004-BC-002 0
7210 5/20/2004 13:42:00 13124097 1007 9524-00-004-SC-034 7210 8422 7520 5/20/2004 13:48:00 13124097 1007 9524-00-004-SC-035 7210 8422 7260 5/20/2004 13:54:00 13124097 1007 9524-00-004-SC-036 7210 8422 6970 5/20/2004 13:58:00 13124097 1007 9524-00-004-SC-037 7210 8422 7540 5/20/2004 14:04:00 13124097 1007 9524-00-004-SC-038 7210 8422 7030 5/20/2004 14:09:00 13124097 1007 9524-00-004-SC.039 7210 8422 7320 5/20/2004 14:12:00 13124097 1007 9524-00-004-SC-040 7210 8422 7360 5/20/2004 14:17:00 13124097 1007 952400-004-SC-041 7210 8422 7730 5/20/2004 14:20:00 13124097 1007 9524-00-004-SC-042 7210 8422 6960 5/20/2004 14:24:00 13124097 1007 9524-00-004-SC-043 7210 8422 7200 5/20/2004 14:27:00 13124097 1007 9524-00-004-SC-044 7210 8422 7500 5/20/2004 14:30:00 13124097 1007 9524-00-004-SC-045 7210 8422 7160 5/20/2004 14:33:00 13124097 1007 9524-00-004-SC-046 7210 8422 8010 5/20/2004 14:37:00 13124097 1007 9524-00-004-SC-047 7210 8422 7290 5/20/n4 14:39:00 13124097 1007 95240-004-SC-048 7210 8422 7190 5/20/2004 14:40:00 13124097 1007
SOUTH SITE GROUNDS SURVEY UNIT 9524-0000 RELEASE RECORD d Split Sample Assessment Forms (2 Pages)
Health Physics Procedure 24265-000-GPP-GGGR-R5124-000-Rev.CY-000 Attachment A Health Physics Procedure 24265-000-GPP-GGGR-R5 124-000-Rev.CY-000 Attachment A Split Sample Assessment Form Survey Area#: 9524 lSurvey Unit #: 0000 Survey Unit name: South Site Grounds Sample Plan or WPIR#: 000-GEN-9524-001056-000 SML#: 9524-0000-009F/9FS Sample
Description:
Comparison of split samples from sample measurement location #9 and analyzed using gamma spectroscopy by off-site Vendor Laboratory.
STANDARD COMPARISON Radionuclide Activity Standard Resolution Agreement Activity Standard Comparison Acceptable Value Error Range Value Error Ratio (YIN)
P~lgg 0.036__
5.3__
0.5-2.0 0.465pCi/g Cs-137 0.192 0.036 5.3 j
0.5-2.0 0.197 0.0465 1.02
.1.
3 4
.1.
-4 4
4 1
4 4
4-4-
4 4
I 4-4 4
4 4-4 4
4 4-4-
4 4
4-4 4
4 4-
+
4 1
4-4 1
I
.1.
a 4
Comments/Corrective Actions: N/A Table is provided to show acceptance criteria used to assess split samples.
Resolution 4 -7 8 - 15 16 -50 51 -200
>200 Agreement Range 0.5 -2.0 0.6 - 1.66 0.75 - 1.33 0.80 - 1.25 0.85 - 1.18 Perfo By:
l Date l
Date II <,
c 7.4 1 /a7:^1a
//
Page I of I
Health Physics Procedure 24265-000-GPP-GGGR-R5124-000-Rev.CY-000 Attachment A Health Physics Procedure 24265-000-GPP-GGGR-R5 1 24-000-Rev.CY-000 Attachment A Split Sample Assessment Form Survey Area#: 9524 l Survey Unit #: 0000 ISurvey Unit name: South Site Grounds Sample Plan or WPIR#: 000-GEN-9524-001056-000 lSML#: 9524-0000-013F/13FS Sample
Description:
Comparison of split samples from sample measurement location #13 and analyzed using gamma spectroscopy by off-site Vendor Laboratory.
STANDARD COMPARISON Radionuclide Activity Standard Resolution Agreement Activity Standard Comparison Acceptable Value Error Range Value Error Ratio (Y/N) pCi/g pCig Cs-137 0.378 0.0558 6.7 0.5-2.0 0.346 0.0533 0.915 Y
Comments/Corrective Actions: N/A Table is provided to show acceptance criteria used to assess split samples.
Resolution Agreement Rangee 4 -7 0.5 - 2.0 8 -15 0.6 -1.66 16 - 50 0.75 - 1.33 51 -200 0.80 - 1.25
>200 0.85 - 1.18 Perfbd.By
- l Date j;
ie9 j
D te7
-~
~~~d l nfcs
[/oz lSi r/
/0'
Page I of I
SOUTH SITE GROUNDS SURVEY UNIT 9524-0000 RELEASE RECORD e Preliminary Data Review Form (1 Page)
Heath Physics Procedure 24265-000-GPP-GGGR-R5123-000-Rev.CY-000 Attachment B PRELIMINARY DATA REVIEW FORM Survey Unit:
9524-0000 Survey Unit Name:
South Site Grounds Classification:
3 Survey Media:
Soil Type of Survey:
Final Status Survey Type of Measurement:
Radionuclide Specific Number of Measurements:
15 Operational DCGL (pCi/g) 3.16pCi/g BASIC STATISTICAL QUANTITIES Cs-137 Minimum Value:
-5.95E-03 Maximum Value:
6.46E-01 Mean:
1.75E-01 Median:
6.5 1E-02 Standard Deviation:
2.21E-01 0
NUMBER 9524-0000-001 F 9524-0000-002F 9524-0000-003F 9524-0000-004F 9524-0000-005F 9524-0000-006F 9524-0000-007F 9524-0000-008F 9524-0000-009F 9524-0000-01 OF 9524-0000-011 F 9524-0000-012F 9524-0000-013F 9524-0000-014F 9524-0000-015F
( C) Q I.e4 Submitted by/Date Reviewed by/Date RADIONUCLIDE CONCENTRATION (pCi/g)
Cs-137 Identified?
1.61E-02 N
2.04E-02 N
3.92E-01 N
6.46E-01 Y
4.65E-02 N
1.03E-01 N
3.33E-02 N
6.07E-01 Y
1.92E-01 N
7.68E-02 N
-5.95E-03 N
1.37E-02 N
3.78E-01 N
6.51E-02 N
4.20E-02 N
/
I of I
SOUTH SITE GROUNDS SURVEY UNIT 9524-0000 RELEASE RECORD f Graphical Representation of Data (2 Pages)
HISTOGRAM PRESENTATION OF Cs-137 DATA Survey Unit:
Survey Unit Name:
9524-0000 South Site Grounds Frequency Plot For Cesium-137 8
U6 a= 4 2
IL 0
Upper End Value (pCi/g)
Observation Observation Upper End Value Frequency Frequency 0.00 1
7%
0.05 6
40%
0.10 2
13%
0.15 1
7%
0.20 1
7%
0.25 0
0%
0.30 0
0%
0.35
- 0.
0%
0.40 2
13%
0.45 0
0%
0.50 0
0%
0.55 0
0%
0.60 0
0%
0.65 2
13%
0.70 0
0%
Total=
15 100%
C ran I. " q
) ~
Submitted by/Date OA go~
- 2-/7 /k Re/ewed by/Date
Health Physics Procedure 24265-000-GPP-GGGR-R5123-000-Rev.CY-000 Attachment C Health Physics Procedure 242 65-000-GPP-GGGR-R5 I 23-000-Rev.CY-000 Attachment C Survey Unit:
Survey Unit Name:
DATA QUANTILE PLOT 9524-0000 South Site Grounds Quantile Plot For Cesium-137 0.7 -
0.6) -
0.2 -
~
0.1 ii o 0 -
-~-'-
oi.5 77.; ?
- 1.
I.:+*,
??, i'I?.
^ ~ ? ;-
, I
-0.1 0
20 40 60 80 100 Percentage Cs-I 37 pCi/g Rank Percentage
-5.95E-03 1
3%
1.37E-02 2
100/o 1.61E-02 3
17%
2.04E-02 4
23%
3.33E-02 5
30%
4.20E-02 6
37%
4.65E-02 7
43%
6.51E-02 8
50%
7.68E-02 9
57%
1.03E-01 10 63%
1.92E-01 11 70%
3.78E-01 12 77%
3.92E-01 13 83%
6.07E-01 14 900/O 6.46E-01 15 97%
Page 3 of 4
SOUTH SITE GROUNDS SURVEY UNIT 9524-0000 RELEASE RECORD g Sign Test Calculation (1 Page)
Health Physics Procedure 24265-000-GPP-GGGR-R512 I -000-Rev.CY-000 Attachment B Health Physics Procedure 24265-000-GPP-GGGR-R5 121 -000-Rev.CY-000 Attachment B Sign Test Calculation Sheet for a Single Radionuclide Survey Unit Number: 9524-0000 Survey Unit Name: South Site Grounds WP&IR#: 000-GEN-9524-001056-000 Classification: 3 TYPE I (a error): 0.05 TYPE II (f3 error): 0.05 Radionuclide:
Cesium-137 Survey Design DCGL (pCi/g):
3.16 Results (pCilg)
DCGL - Results Sign 1.61E-02 3.14 1
2.04E-02 3.14 1
3.92E-01 2.77 1
6.46E-01 2.51 1
4.65E-02 3.11 1
1.03E-01 3.06 1
3.33E-02 3.13 1
6.07E-0 1 2.55 1
1.92E-01 2.97 1
7.68E-02 3.08 1
-5.95E-03 3.17 1
1.37E-02 3.15 1
3.78E-01 2.78 1
6.5 J.E-02 3.09 1
4.20E-02 3.12 1
Number Of Positive Differences (S+):
15 Critical Value: 11 Survey Unit: Meets Acceptance Criterion Performed By:.
Independent Review B.
Date:
it 6 '.C.J Date: ), //)
f,,4 Page I of I
SOUTH SITE GROUNDS SURVEY UNIT 9524-0000 RELEASE RECORD h COMPASS DQA Surface Soil Report with Retrospective Power Curve (2 Pages)
DQA Surface Soil Report Assessment Summary Site:
Planner(s):
Survey Unit Name:
Report Number:
Survey Unit Samples:
Reference Area Samples:
Test Performed:
Judgmental Samples:
Assessment
Conclusion:
Survey Unit 9524-0000 CE Davis South Site Ground 1
15 0
Sign Test Result:
Not Performed 0
EMC Result:
Not Performed Reject Null Hypothesis (Survey Unft PASSES)
Retrospective Power Curve I
E.s a 0.9 M 0.8
- 0.7 it 0.4 0.3 C. 0.2 0.1 a10.-0 rII I
II Im I I
,r
=__
1 0.0 0.5 1.0 1.5 2.0 2.5 3.0 Soil Comexeuatlex (pCilg), iclubdig backgrnaui Prospective Power l-beta Actual Power LsGR Esinated Power DCGL Retrospective Power 3.5
'-.4 C07 COMPASS vl.O.O
,/11472005 Page 1 COMPASS v1.0.0
/111"142005 Page I
'M' DQA Surface Soil Report Survey Unit Data NOTE:
Type =S Indicates survey unit sample.
Type = 'R' Indicates reference area sample.
Sample Number Type Cs-137 (pCl1g) 9524-4000-001F S
0.02 9524-0000-002F S
0.02 9524-0000-003F S
0.39 9524-0000-004F S
0.65 9524-0000-005F S
0.05 9524-0000-006F S
0.1 9524-0000-007F S
0.03 9524-0000-008F S
0.61 9524-0000-009F S
0.19 9524-0000-01 OF S
0.08 9524-0000-011 F S
-0.01 9524-0000-012F S
0.01 9524-0000-013F S
0.38 9524-0000-014F S
0.07 9524-0000-015F S
0.04 Basic Statistical Quantities Summary Statistic Survey Unit
Background
DQO Results Sample Number 15 N/A N=15 Mean (pCl/g) 0.18 N/A 0.09 Median (pCl/g) 0.07 N/A N/A Std Dev (pCVg) 0.22 N/A 0.122 High Value (pClg) 0.65 N/A N/A Low Value (pCIg)
-0.01 N/A N/A COMPASS v1.0.0 174120tg Page 2