ML20090D204

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Semiannual Effluent Release Rept for Jul-Dec 1991
ML20090D204
Person / Time
Site: Sequoyah  Tennessee Valley Authority icon.png
Issue date: 12/31/1991
From:
TENNESSEE VALLEY AUTHORITY
To:
Shared Package
ML20090D199 List:
References
NUDOCS 9203060086
Download: ML20090D204 (17)


Text

. . , .

ENCLOSURE 1 SEMI-ANNUAL EFFLUENT RELEASE REPORT FOR Ti!E PERIOD OF JULY 1 TO DECEMBER 31, 1991 (S$2 920214 088) lDR203060006 92030p g ADOCK 05000j27 PDR'

l EFFLUENT AND WASTE DISPOSAL SEMIANNUAL REPORT SUPPLEMENTAL INFORMATION Znd HALF 1991

1. REcuLATORY-LIMITS l

A. Caseous Effluents '

1. Doso ratos duo to radioactivity roloaned in gaseous offluents from  !

the utto to areas at and beyond the sito boundary shall bo limited to the following: '

a. Noble gases - Loss than or equal to 500 mrom/ year to the total body.  ;

- Loss than or equal to 3000 mrom/yoar to the skin,

b. 1odino-131, lodino-133, tritium, and all radionuclidos in ,

particulato form with half-livos greator than 8 days:

- Loss than or equal to 1500 mrom/yoar to any organ.

2. Air doso duo to nob 10 gases rolosood in gaseous offluents to areas at and beyond the mito boundary shall bo limited to the followingt
  • a. Loss than or equal 5 mead for gamma radiation and loss than or equal to 10 mead for bota radiation during any calendar quartor.
b. Loss than_or equal to 10 mead for gamma radiation and loss than or equal to 20 mead for bota radiation during any ,

calendar year.

B

3. Doso to a member of the public from lodino-131, lodino-133, tritium, and all radionuclidos in particulato- form with half-lives

.greator than eight days in gaseous offluonto rolossed to areas at and bayond tho site boundary shall bo limited to tho following:

  • a. Loss-than or oqual to 7.5 mrom to any organ during any calendar quartor,
b. Loss than or equal to 15 mrom-to any organ during any calendar year.

B. Liquid Effluents

1. The concentration of radioactivity rolossed in liquid offluents to-unrestricted areas--shall be-limited to the concentrations epociflod in Titio 10 of the Codo of-Fadoral Regulations, Part 20 (Standards for Protection Against Radiation), Appendix U, Tablo 11, Column 2, for radionuclidee_other than dissolved or entrained nobio gason. For dissolved or entrained nobio gases, the concentration'shall bo limited to 2.0E-04 microcurlo/millilitor (uC1/ml) total activity.
  • These vatuos are used as applicablo limits for gaseous roloacos.

. - _ -. -_ - - - _ - _ _ - - _ _ . , . _ . . - ~ . - . - _

EFFLUENT AND WASTE DISPOSAL SEMIANNUAL REPCMT SUPPLEMENTAL INFORMATION 2Dd_l!ALF_1221

2. The dopo or dose commitment to a member of the public from radioactivity in liquid offluents roloused to unrestricted arous shall be limited tot
    • a. Less than or equal to 1.5 mrem to tho total body and loss than or equal to 5 mrom to any organ during any calendar quarter,
b. Loss than or equal to 3 mrom to thv total body and loss than or equal to 10 mrem to any organ during any calendar year.
2. MAXIMUM PERMISSIBLE CONENTHATION A. Liquids
1. The maximum permissibio concentrations (HPC) for liquids are thoso listed in 10 CFR 20, Appendix D. Tablo 11, Colurrai 2, with the most rostrictivo HPC bein6 used in all cases. For dissolved and entrained gases the MPC of 2.0E-04 uC1/mi is applied. This HPC is based on the Xo-135 HPC in air (submersion doso) converted to an equivalent concentration in water as discussed in the International Connission on Radiological Protection (ICRP),

Pubilcation 2.

B. Caseous

1. The maximum permissible dose rates for gaseous releason are defined in plant Offsite Doso Calculation Manual (ODCM)..
a. Noble gas dose rato at the nite boundaryt

- Less than or equal to 500 mrom/ycar to the total body.

- Loss than or equal to 3000 mrom/ year to skin,

b. Todino-131, lodino-133, tritium, and particulatos with half-lives greator than olSht days dopo rato at the sito boundary!

- Loso than or equal to 1500 mrom/ year to any organ.

3. AVERACE ENERGY Sequoyah's ODCH limit tho doso equivalent ratos due to the release of fission and activation products to loss than or equal to 500 mrem / year to the total body and loss than or equal to 3000 meem/yoar to the skin.

L -Thoroforo; the averago bota and gamma enorgios (E) for gaseous offluento j as described in Regulatory Guido 1.21, "Heasuring, Evaluation, and l

Reporting Radioactivity in Solid Wastos and Rolossos of Radioactive l Materials in Liquid and Caseous Effluents from Light-Water-cooled Nuclear i Power Plants," are not applicablo.

I l'

l **Those values are used as applicable !!mits for liquid offluents.

i

~. . , . . . . , . _ _ _ - . _,..-.y... . . . . . . _ , . , . _.,,._,.,.,,._..w.. . . _ _ , . .,,.,.m , ,, . .-_,.,

1 EFFLUENT AND WASTE DISPOSAL SEM1 ANNUAL REPORT SUPPLEMENTAL INFORMATION Znd_H6bF 1991 1

4.. Moncurements and Approximations of Total Radioactivity NOTE! Every effort is made to ensure that all offluents fror Sequoyah are conducted such that all offsite Doso calculation Manual (ODcM)

Lower Limits of Detection (LLDs) are mot. Whencvor an analysis does not identify a radioisotopo, a "0.00E-01 Ci" is recorded for l the releano, This does not necessarily mean that no activity was rolossod for that particular radionuclido, but that the concentration was below tho ODCH and analysis LLDs. Hofer to Tables A and B for estimatos of those typical LLD valuce. l

a. Fission and Activation cason Airborno offluent gasoous activity-is continuously noittored and

-recorded. Additional grab samples from the shiold building, auxiliary building, service building, and condonsor vacuum oxhauals are taken and analyzed at least monthly to datormino the quantity of noblo gas activity rolcased for the month based on the avorago vont flowrates recorded for the samplo period. Also, nobio gas samples are collected and ovaluated for the shtold and ouxiliary buildings following ,

startup, shutdown, or rated thermal power chango excooding 15 porcent i wl'hin one hour (sampling only required if doso equivalent 1-131 concentration in the prinary coolant has increased moro than a factor of 3 and the nobio gas activity monitor shows that the containment activity has ircreased more than a factor of 3).

The quantity of nobio gases rolossed through the shield and auxiliary building oxhausto due to purging or venting of containment and rolonsos of waste gas decay tanks are also dolormined.

The total nobio nas activity released for the month is then dolormined ,

Lby summing all of the activity rolonsed from each vont for all -

-sampling porlods,.the activity colossed from purging or venting of 1 containment, and tho activity roloosed f rom wasto gas decay tank (s). t

b. lodinos and particulatos lodino and particulato activity is continuously samplod. Charcoal and particulato samples are taken from the shtold and auxiliary building exhausts and analyzed at least wookly to determino the total activity i

released from the plant based on the averato vont flowratos recorded for sampling period.

Also, particulate and charconi camplos aro taken from the auxiliary and shield building exhausts onco por 24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br /> for 2 days following startup, shutdown, or a rated thonuti powor'chango excooding 15 parcont within ono hour. The quantity of iodino and particulato reloaced from occh vont during onch sampling period is then determined using the averano vont flowratos recorded for the sampling period and activity concentration.

The total particulate and iodino activity released for the month in then determined by summing all of the activity released from the shield and auxiliary building exhausto for all sampling portods.

__ _. _ . _ _ _ . _ . _ . _ _ _ _ _ . . _ . _ . _ _ __, . ~ .._ .- - __

EFFLUENT AND WASTE DISPOSAL SEMIANWUAL HEPORT SUPPLEMENTAL INFONMATION fnd HALY _1991 i

1

4. Measuromonte and Approximation of Total Radioactivity (continued)

' I

c. tAquid Effluonts j (1) patch (Radwaalo and condonsato regonorants to cooling tower blowdown)

Total samma isotopic activity concentrations are dotot1nined on each batch of liquid offluent prior to rolosso. The total activity of a ,

released batch is deturmined by summing each nuclide's concentration and na11tiplying by tho total volume discharged. The total activity colossed during a month to then determined by summing the activity T content of each batch discharged during the manth.

i (2) Continuous Holossos and periodic Continuous Releauco (Condensato resonorants, turbino building nump and steam generator blowdown)

Total gamma isotopic activity concentration la determined daily on a composite sample from the condensato system and turbino building sump and wookly for steam generator blowdown. The total activity of tho -

continuous rolosso is dolormined by summing each nuc11do's concentration and multiplying by the total volumo discharged. The total activity-relonsod during the month is then datot1nined by summing the activity content of each daily and wookly composito for the month. >

5. Bst ch Valuo Unito Quartog QuartoI 3rd 4th
a. Liquid
1. Number of batches rolenced (Radwaste only) 131 100 Each
2. Total timo period for batch ,

relonsco .

18,871 13,819 Minutos 3.- Maximum timo period for a batch release 200 172 Minutoo

4. Averago time-period for batch-
  • releases 144 138 Minutoo S. Minimum stream flow during periods of offluent into a flowing stream N/A N/A
b. Casoous-
1. Number of batchen released 206 127 Each

-2. Total timo period for batch releases: 19,327 26,409 Minutos 3 ', Maximum tl.no period - for a batch reloaco 1.1/4 6,576 Minuten-

4. Averato timo period for batch releases- 94 208 Minutos
5. Minimum timo period for a batch releaso 14 19 Minutos

_ 4 f _ + ,w-

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l EFFLUENT AND WASTE DISPOSAL SEMIANNUAL hep 0HT SUPPLEMENTAL INFORMAT1f'1 2nd_liahr 1991

6. Abnormal Releases Valuo_ Unitg  !

Qugig Quant _g  :

3rd 4th__

a. Liquid .

(1) Number of Releases 0 0 (2) Total Activity Roloaned 0,0QE;21 g,00E-01 Cl

b. Caseous (1) Number of Releases Q_ 0 (2) Total Activity Released 91pgE 21 2100E-01 Ci
1. Offsite Doso Ceiculation Manual (ODCM)

Were any changes made to the ODCH during the reporting period?

Yes _,3__ No.

IN0pERABLE INSTHUMENTATION Pursuant to ODCH Section 1.3.1, the f ollowing information is provided concerning radioactivo effluent monitoring instrumentation which was inoperable for greater than 30 consecutivo days during the period July 1, 1991 through December 31, 1991.

Unit 2 shield bui131ng radiation monitor 2-RE-90-400 was inoperable from 7/8/91 to 8/28/91. In Januncy 1991 TVA changed out its post accident shield building radiation monitors with Sorrento Electronics wide range gas monitors.- In order'to' complete the radiatlon monitor nodification the now radiation monitors had to be removed from service for the removal of the old radiation monitors. .The physical work was completed in a timely manner and the radiation monitors returned to service. The required documentation and review extended the completion of the Work Plan and Unit 2 radiation uonitor was not considered operabic within the scheduled 30-day reporting limit.

In December 1991 during the performance of SI-198.3 it was determined that the flow instrumentation for the auxiliary _ building exhaust was out of calibration. The instrumentation was not out of servico (inoperablo) but

= 18% Jow. Since this instrumentation is used to evaluate monthly offsito dose for the auxiliary-building the 18% orror would result'in the following potential offsite dose errorst-Total _ Gamma Doso - 2.6%

Total Beta Doso - 2.6%

Max.iorgan Dopo - 18%

.l i

i

-S-

+ EFFLUENT AND WASTE DISPOSAL SEM1 ANNUAL REPORT Z!LtJ!ALF 1991_

LIQUID ElU.UENTS - SUMMATION OF ALL NHLEASES

-3rd Atjt A. F!solon and_Actila QoD tJnit _Qt1 %Ert oy Jir  % Error l'_Co_dysc1.s -

1. Total Rolenced Curlos 2.67E-01 11.8E401 8. 09 E- 01 11.8E401
2. Avorago Diluted Conc. ]

Durint, Porlod of All ',

identifiod Isotopos uC1/mi 1.40E-07 6.55E-07

3. porcent of Applicable Limit (Total Body Dopo)  % 8.00E-01 1.07E400 B. Trit lum i
1. Total Holoased Curlen 4.41E402 +1.8E401 3.97E402 41.8E401
2. Avorage Diluted uCL/ml 2.31E-04 3.2?E-04 Conc. During Porlod
3. Percent- of AppJicablo Limit (3.0E-03 uCL/ml)  % 1.70E400 1.07Ef01 C. Dissolved and Entrainod canon
1. Total Italoased Curios 1. 4'0 E + 00 13 9E401 1.30E-01 13.9E401 .
2. Avorago Diluted uC1/mi 1. 3,s E- 0 7 1.12E-07  !

Conc. During, Period

3. Forcent of Applicablo Limit (2.0E-04 uCL/ml)  % 3.67E-01 5.58E-02 D.- Cross A1.pha Hadlonctivity.
1. Total Holoaned Curion 0.00E-01 12.0E401 0.00E-01 12.0E+01 E. Volume of Westo Nolonsed (Before Dilut. ion) Litors 3.01E407 14.0E400 2.61E407 14.08400 F. Volumn of Dilutton Litors 1.88El09 11.1Et01 1.21E409 11.1E101 Water for Parlod i

f 1 [-

_ _, u _ _ . , _ . _ ., _ _ _ _ _ _ - _ _ _ _ _ _ _ . - _ , _ _ . _ _ _ _ _ . . _ , . _ _ . _ . _ . . ~ . , . . . . _ _ . . _ . _

EFFLUENT AND WASTE DISPOSAL SEH1 ANNUAL REPORT Jnd HALF 1991 LIQUID EFFLUENTS - TOTAL PLANT DISCHARGE G. 1g010p0 Summat2 (Notel Refer to Table A for ODCH nucliden reported as 0.00E-01)

Required by ODCM/Others Fission and Activation Products Continuoup_fiedq_ Batch Modo Nucilde Unit Quartet ' g_untin_t gu_a_rior qu, arig 3rd 4th 3rd__ 4 th _.

1. Strontium-89 C1 Q100E-01 0.00E-Q1 0.00E-01 2.93E-04
2. Strontium-90 Ci 0.00E-01 0.00E-01 0.00E-01 2.96E-04
3. Iron-55 Ci 0,00E-01 Q100E-01 1 06E-02 2.88E-02
4. Mantanoso-54 Ci 0.00E-01 0.00E-01 4.49E-03 1.56E-02
5. Cobalt-58 Ci 2.90E-06 f.63E-07 6.34E-0R 2 15E-01
6. ' Iron-59 Ci 0 00E-01 Qt00E-01 0.00E-01 1290E-03
7. Cobalt-60 C1 1.80E-05 6.92E-07 7.25E-02 4.27E-02
8. Zine-65 Ci. 0.00E-01 0.00E-01 1 36E-04 1,86E-05
9. Molybdenum-99 Ci 0.00E-01 0.00E-01 1.64E-04 1.21E-03
10. 1odino-131 Ci 3.91E-06 1.42E-Q1 5.77E-03 11.25E-03
11. . Costum-134 Ci- 0.00E-01 3.77E-04 1.65E-02 4.41E-02
12. Cesium-137 C1 2.66E-05 3.78E-04 2.05E-02 lt66E,Q1
13. Cerium-141 Ci 0.00g; 21 -0.00E-01 6.09E-05 3 67E-03
14. Corium-144 Cl 9.67E-06 0.00E-01 7.26E-04 8.00E-03
15. Antimony-125 Ci 0.00E-pl 0.00E-01 2.058-01 sj56E-02

. 16 . - Cobalt-57 -Ci - Q2n0E-01 0.00E-01 1402E-03 1.57E-03

17. Chromium-51 C1' RtQ0E-01 0.00E-01 3.14E-03 7.42E-02

-18. Niobium-95 Cl 0.00E-01 0,00E-01 3.66E-03 2 14E-02 1 i

-1 L--

EVVLUENT AND WASTE DISI'OSAL SEMIANNUAL REl' ORT 2nd llALF 1991 LIQUID EFTLUENTS - TOTAL PLANT DIScilARGE (CONTI nut.D)

Eontitspu939 o_d PAt ejt!!gdo Nuclido Unit Quartor Quartf f Qua rt er Quartf r 3rd 4th 3rd 4th

19. Iodino-133 Ci v.00E-01 7.19E-06 8.19E-04 8.64E-05
20. 71rconium-95 Ci 0.00E-01 0.00E-01 1.63E-03 1.36E-02
21. Technetlum-99m Cl 0.00E-01 0.00E-01 I t 64E-04 1.21E-03
22. Ruthenium--103 Cl 0.00E-01 0.00E-01 1.49E-04 5,98E-03
23. Tollurium-132 Ci 0.00E-01 0.00E-01 4.74E-06 1.86E-03
24. Antimony-124 Cl OJ0E-01 0.00E-01_ 2. 0SE- 04 9.34E-03
25. Lanthanum-140 Ci 0.00E 91 0,00E-01 2.39E-04 3,11E-03
26. Cenium-136 Cl 0,00E0_1_ 0
0. 0_0fl _01 1 d2E-04 2.098-03
21. Sodium-24 Ci 0.00E-01 0.00E-01 1.49E-05 8.11E-05
28. odino-13S Cl 0.00E-01 0.00E-01 0.00E-01 0.00E-01
29. Strontium-92 Ci 0.00E-01 0.00E-01 2.03E-OS 1.49E-04
30. Yttrium-91 Ci 0.00E-01 0.00E-01 OJO_E- 01 1,2 7 E- 03 31 lodino-132 Ci 0.00E-01 0.00E-01 0.00E-01 2.37E-03 32 Zinc-69H Cl 0.00E-01 0.00E-01 0,00E- 01 q._00E-01 33 Corium-143 Cl 0.00E-01 0 . 00 E-.01 0.00E-01 0.00E-01 34 S11ver-110m Cl 0.00E-01 0.00E-01 S.73E-OS 2.41E-04 35 Arr.on-41 Ci 0.00E-01 0.00E-01 4.20E-06 0.00E-01 36 Barium-140 Ci 0.00E-01 0.00E-01 2.0?E-OS 4.20E-04 31 Copper-64 Ci 0._00 E- 01 0.00E-01 6,64E-04 O_.00E-01 38 Niobium-97 Cl 0.00E-01 0.00E-01 7.61E-05 2.44E-04 39 Ruthenium-10S Ci 0.00E-01 O_.00E01, ,3 g !E-05 0.00E-01 L

EFFLUENT AND WASTE DISPOSAL SEM1 ANNUAL REPORT End_.HAbF_1991 ,

LIQUID EFFLUENTS - TOTAL PLANT DISCHANGE l (CONTINUED)

Continuous 3o,4g pa_tch Hojp Nuclido Unit. Quarter Qtlart or. Quattyr Qusrlor a

3rd 4th 3rd ,_4Jh ,_

40 To11urium-129m Ci 0.00Fc01 0.00E-01, p.99E-05 J dlE 02 41 Strontium-91 Ci 0.00E-01, p JO E-0_1_ g_d}J-05 0.00E-01 42 Tint. sten-107 Ci p DOM-01 p.00E01 1.29E-05 0.00E-01 43 Yttt lum-91m Ci 0.00E-0_1 0.00E-01 0.00E-01 4 70E-05 44 Nickel-65 b,Q0E-01 QJ0E-01 0. 00E- 01 gu 17E-05 45 Neptanium-239 Ci 0.00E-01 0.00E-01 0.00E_Ol 2. 4 7 E-02_

46 Tc11urium-131m C1 0.00E-0_1 0.00E-01 0.00E-01 2,15E-04 Total for Period Ci p_dlE-05 7.77E-04 p.67E-01 B,08E-01 C. Juotope,_Suvunary, (NOTE: Refor to Table A for ODCM nuclidou reported as 0.00E-01)

Requirco by ODCM/Others Dissolved and Entrained Noble casos Continuous Mode. Untch Modo Nuclido Unit Quarter Quarter Quarter Quarter

_ }rd 4 tiL_,, 3rd 4th.

1. Krypton-87 Ci 0. 00 E-01_ _0.00E-01 1.14E-05 0.00E-01
2. Krypton-88 Ci 0.00E-01 pto_0E- 01 ,3.54E-05 0.00E-01
3. Xenon-133 C1 4.65E-05 0.00E-01 1.35E+00 _1.30E-01
4. Xenon-133m Ci 0.00E-01 0 00E-01 1.67E-02 ld 5E-Q),
5. Xenon-135 Ci 0.00E-01 0.00E-01 luB6E-01 3.67E-01
6. Xenon-138 Cl 0.00E-0_1 0,00E -01 0.00E-01 0.00E-01 l
7. Krypton-85m Ci 3.23E-06 0.00E-01 6.72E-06 9&OOE-01
8. Xenon-131m Ci 0.00E-01 0.00E-01 1.21E-02 3.03E-03
9. Xenon-135m Cl 0.00E-01 p,00E-01 0.00h-01 0.00E-01 10 Kr-85 Ci 0.00E-01 0.00E-01 1 27E-03 .Q 00E-01 Total for Period Ci 4.97E-05 0.00E-01 1.40Kt00 1.38E-01 9-l

EFFLUENT AND WASTE DISPOSAL SEMIANNUAL REPORT 2!1$ l!AIf I193.

TABLE A LIQUID " TYPICAL LLD" EVALUATION (U At(2) puelldo .ODCH Lt,D _15 telrL_ _)9 tn10. -_1 hr 2 h r .___

Hant,anoso- 54 )_OE-07 9.12E-09 h}?E-09 9,12 E- 09 9 .12 E- 09_

Cobalt-58 p20 E-0 7, 8,21E-09 8,21E-09 8,21E-09 8,21E-09 Iron-59 },OE-07 JJ 2E-08 1,62E-08 1,62E-08 1,6 2E-_08 Cobalt-60 #20E-07 LOBE-08 1,08E-08 J208E-08 J,0BE-08 Zinc-65 5,0E-07  ?214E-08 2 2 14E-08 2,14E-08 P,14E-08 Molybdenum-99 5,0E-07 5,248-08 }225E-08 5,288-08 5,34E-08 Cos t um-134 $20E-07 9,82E-09 9,8 2 E- 09 9,82E-09 9,8?E-09 Cesium-137 }2qE-01 L3}E-09 9,31E-09 9,31E-09 9.31E,,03 Cerium-141 $2Qfe,QJ, 1.06E-00 h06E_Q8 hq]I-08 J ,.0 7 Fc08, Cerium-144 2.dB-06 4.03E-Q8 4,03E-08 4,03E-08 M )_E-08 lodine-131 0 q Ja01_0!! Ja 2_8 E-09 7.28E-09 J2),,0fcQ3 7,3?E-09 Krypton-87 1.0E-05 1_,62E-08 J21Fcq8 8 2,43E-08 4a20_E-08 Krypton-88 1,0E-05 2.13E-08 ,2,2?E-08 2256E-08 3,27E-08 Xenon-133 1,0 E- 05_ 2.03E-08 LO4E-08 LO_4);-08 2,05E-08 Xenon-133m JJE- 05 },05E-08 5,07E-08 5.10E-08 5,17E-08 Xenon-135 -),0E-05 ),603-09 5,70E-09 5,9 3 E- 09 6,40E-09 Xenon-138 hQfcQ1 f.82E-08_ 5,87E-08 fa.5 5 E- 0 7, 4,79E-06 EFFLUENT AND WASTK DISPOSAL SEMI ANNUAL REP 01<T 2.nlllALP 1991 TABLE A >

LIQUID " TYPICAL LLD" EVALUATION (1)

(Continued)

Nue }Jd,o d pptCtLbt.g Iyp,lga1 t.Lp Tritium LfFc_91 L.9hol .

Gross Alpha 1. 0E- 0]. /E;pt Stront. lum 89 1 0E-08 7 0E-08 Strontium-90 Lag-08 1. 0 E-08_

1ron-S5 1. 0E-Oft 21_ycql 0

potES1 (1) LLD valuco are in uCi/ml. Samplo analyson are performod to onnuro that ODCH LLD limits are mot. Theco are typical LLD valuco.

(2) At in the time betwoon compte collection and countinr, time.  !

1

't

EFFLUENT AND WASTE DISPOSAL SEMIANNUAL REPORT 2nd HALF 1991 CASEOUS EFFLUENIS-SUKMATION OF ALL RELEASES l (GROUND LEVEL RELEASES) I i

I i

3rd_ - 4th_

Summation of All Releases Unit _gtr  % Error _QLt_  % Error A .- Nobio casos

1. Totai Holossed Cl 6.20E+02 11.1E401 2.36E+02 11.1E+01  ;
2. Avorage Nolcaso Rato of Period uC1/ soc 1.80E401 2.97E+01
3. Percent of Applicablo  % 1.14E400 5.00E-01 Limit (Canem)

B. Jodines

1. Total lodino-131 C1 2.07E-07 11.3E401 3.30E-04 11.3Et01
2. Average Releaso Raio for Pericd uC1/sec 2.26E-0R 4.16E-05 C. Particulatog L1. Partieuircos with Ci 0.00E-01 11.6E+01 5.92E-04 11.6E401 half-11*es >8 days i
2. Averar,s notenso Rato for Porlod uct/soe 0.00E-01 7.44E-05
3. Cross Alpha Radio- Ci 0. 00E- 01 12.1E+01 0.00E-01 12.1Et01 activity D. Tritium
1. Total Holonso ci 3.51Et00 11.5Et01 1.88E+01 11.5E+01

.2. Average Holoaso Rato for Period uCi/sec 4.42E-01 2.36E401 E. 1-131, 1-13 3, 11-3 and Particulates with half lifes >8 days  :

1. Percent of applicablo  % 4. 4 7E- 02 2.27E-01 Limit. (Max. Organ-Child Thyroid)

EFFLUENT AND WASTE DISPOSAL SEMIANNUAL HEPORT 2nd HAl.F 1991 CASE 0VS EFFLUENTS-EUMMATION OF ALL RELEASES (CROUND LEVEL RELEASES)

E2nihuouLMolo liatch Modq Unit Qu_atter Q atter Qu_atter guartor 3to___ 4 tin __3_t_ d 4th _

F. Poble_ Cases Required by ODCM/Others

1. Krypton 87 Ci 9._09E. ,0,1 0,00E-01 p . 2 5 E- 0_3, 0.00E-0_1
2. Krypton-88 Ci 2,18E-01 0.00E-01 5.85E-01 9.41E-01
3. Xenon-133 Ci 7.73E400 3.24E401 }.78E402 1.80E402
4. Xenon-133m Ci Q200E-01 0.00E-01 9.82E+00 3.15E400
5. Xenon-135 Cl 6.42E-01 4 165E+00 1,71E401 1 20E+01
6. Xenon-138 Ci 0.00E-01 0 . 00 E- 01 0,00E-01 0_,00E-01
7. Krypton-85 Ci 0.00E-01 0,00E-01 4.44E-01 0,00E-01
8. Argon- 41 Ci 0.00E-01 0.00E-01 1,91E+00 1. 82};f 00
9. Krypton-85m Ci 4.32E-02 0,00E-01 8283E-01 9.09E-01
10. Xenon-131m Ci 0.00E-01 0,00E-01 1.78E+00 1.03E-02
11. Xenon 'a35m Ci 0,00E-01 0,00E- 01 9,190E-01 9 00E-01 Total for period Ci 8,63E+00 1 71E+01 6.11E+02 1.99E+02 G. lodines
1. lodine-131 C1 2.87E-07 3.30E-04
2. lodine-133 Ci 1.27E-07 Q.00E-01
3. lodine-1_11 C1 0.00E-01 4.01E-06
4. lodine-132 Qi 0,00 E- 01 1193E-06 Total for period Ci 4.14E-07 3.36E-04 NOTE: Refer to Tablo B for ODCM nuclides reported as 0.00E-01.

EFFLUENT AND WASTE D1CPOSAL SEM1 ANNUAL REI' ORT 7f1 d jlALFj.9E CASE 0VS EFFLUENTS-SUMMATION OF ALL RELEASES (GROUND LEVEL RELF.ASES)

II . l'at ting at es Required by ODCH/Others Nuclido Unit Continuous Hodo quarict 9tiat!"t

_3rd ,4th

1. Strontium-89 Ci p.00E-01 8,59E-06
2. Strontium-90 Ci 0.00E-01 0. 00 E- 01
3. Iron-59 Ci 0,00F.-01 0. 00E- 01
4. Cobalt-60 Cl 0.00E-01 1JSE-04
5. Zine 65 Ci 0.00E-01 p100E 01
6. Mant,anese-54 Ci 0.00E-01 1.21E-05
7. Cobalt-50 C1 0.00E-01  ? ,6 0 LEO 4, B. Holybdenum 99 Ci 01 00bO1 0.00b ol
9. Coolum-134 Ci 0,00E-01 p200 E- 0.1
10. Costum-137 Ci Ot0_0_E-01 3.84E-06
11. Corium-141 Ci 0.00E-01 1.88E-06

~

12. Corium-144 Ci 0.00E-01 1_. 9 3 E- 05 Others (Specify) 13 Chromo-51 Ci 0.00E-01 5.4BE-05 14 Niobium-95 Ci 0.00E-01 ,3 .15 E- 95 15 Ruthenium-103 Ci 0,00E-0J 7. 7?b05 16 Zircomum-95 Ci p 00E-01 lt44E-06 Total for Porlod Ci p.00E-01 1 921,94 NOTE: Refer to Tablo B for ODCH nuclideo reported up 0.00E-01.

EFFLUENT AND WASTE DISPOSAL SEM1 ANNUAL REPORT {

2nd itALF 1991 TABLE B CASEOUS " TYPICAL" LLD EVALUATION (1) l Noble _ Cast At(2)

Hucil(q ODC1,LLD _1 hr 1. 5 hy.

Krypton-87 } . 0E- 04 1_,198-06_ 2.69E-06 Krypton-88 1.0E-04 J,22E-06 LJ6E-06 Xonon-133 1.0E-04 5,51E-07 5,56E-0!

Xenon-133m 1,0E-04 1 99E-06 J,02E-06 Xenon-135 1.0E-04 2.59E-07 2 90E-07 Xenon-138 }JE- 04 5,38E-05 8,55E-05 Earticulate Sampl_o LO2 du_ 2,79 da __ 5.19 da e Manganoco-54 1 0E-10 1 83E-12 7,65E-14 ,12 0_E- 14 Cobalt.-58 1,OE-10_ 1J_0E-12 4.79E_,14 9,99E-15 Iron-59 1.0E-10 3,21E-12 1.36E-13 2.03E-14 Cobalt-60 1.0E-10 _1,19E-12 7,46E-14 ld7E-1{ ,

Zine-65 1.0E-10 4,08E-12 1. 71 E-13 2.46E-14 Molybdenum-99 LOE-10 f.08E-12 1,05E-13 ,3,18E-14 Conium-134 IJE}q 2,03E-12 Rze5E-14 },21E-14 Coalum-13 7 1.0E-10 1.85E-12 7,71E-14 1,10E-14 Cerium 141 L0E-10 2,32E-12 9 82E-14 1 50E-14 Corium-144 }.0E-10 1 03E-12 4.28E-13 6,16E-14 lodine-131 _1.0E-10 1,85E-12 8,22E-14 1,52E-1A glarcoal Sampin 2.0 da 2.5 da 5 ,5 d a_

lodino-131 L 0E-11 7 53E-12 1.10E-13 2.00E-14

EFFLUENT AND WASTE D1SI'OSAL CEHI ANNUAL REpoltT 2 fl d ,,,_11 Al.y__1,931 TABLE 11 CASE 00S "TYp1 CAL" LLD EVALUATION (1)

(continued)

Nuc1ido ODCH LLD Typllaj_id1]

Tritium 1.0E-06 1.0E-11 Croso Alpha 1. 0 F.- 11 1.5E-14 Stcontlum-89 1. 0lG 11 1.0E-14 Strontium-90 1.0E-11 1.0E-15 NOTES: (1) LLD valuou are in uC1/ce.

(2) A6 for noblo guaca is the timo from campling to atialynio.

At for charcoal and particulato natuples to the raldpoint of nampling, to analynic.

EFFLUENT AND WASTE DISPOSAL SEM1 ANNUAL HEPORT 2nd HALF 1991 SOLID WASTE (RADIDACTIVE Sil!PMENTS)

A. Solid Waste Shipped Offsito for Durial or Disposal (not Irradiated Fuel) f_.H9Itth Fut . Toli.

1. IrrJL9f Wuts  !!!1Lt fo_.ti_od filrotl
a. Spent resins, filter sludgca, m3 3.67E+1 11.00E-1 ovaporator bottoms, etc. C1 6.97E+2 11.50E+1
b. Dry Activo Waste, Compressible Watto m3 4.60E+1 11.00E-1 Contaminated Equipment, etc. Ci 6.01E40 11.50E+1
c. Irradiated Components, m3 Nono N/A Control Rods, etc. Ci None N/A
d. Othert Nono m3 Nono N/A Ci Nono N/A ,
2. Dilmate of HeJor Nuclido Cofjp_gjtlilon (by type of wastel
a. Spent resin, filter sludges, evaporator bottoms, etc.

(nuclidos determined by measurement)

Curios Eeteant c

1. Manganeso-54 2.72E&1 3.90Et0
2. Iron-55 8.19E+1 1.18Et1
3. Cobalt-58 7.73E+1 1.11Et1
4. Cobalt-60 1.38E+2 1.98E+1
5. Nickol-63 1.34E+2 1.92Et1
6. Cosium-134 1.02E+2 1.46Ett
7. Cesium-137 1.35E+2 1.93E+1
b. Dry active waste, compressible waste, contaminated equipment etc.

(nuelldes determined by estimato)

1. Chromium-51 5.19E-1 8.62E+0
2. Iron-55 2.53Et0 4.21E+1
3. Cobalt-58 1.59E+0 2.64E+1
4. Cobalt-60 7,74E-1 1.29E+1
5. Nickol- 63 3.50E-l' 5.81E&O
6. Niobiune95 1.34E-1 2.22E40
c. Irradiated Components N/A N/A l
d. Other: None N/A N/A 419/1/1 l

l I

, i EFFloUENT AND WASTE DISPOSAL SEMI ANNUAL hep 0HT 2nd italy 1991 SOLID WASTE (RADIDACTIVE SillpHENTS)

3. En1Ld._WasL931eenaillsn FL8d tr of Rlit MJ1LR IIP 0_%L8 Billy BoMit PLINDEPMitiiPD PJ1!ttiftdlRD a) Spent resin, filter sludges, evaporator bottoms, etc.

6 A-LSA Hotor Froight 11ernwell, 30 4 B-1.S A Hotor Freight llarnwoll, SC Mu_phgp _ of Shiltmgpig Iypg_Q9an(lir Upd9, of Tangpgjig11011 pgttt,ingl{pg b) Dry active waste, compressible westo, contaminated equipment, etc.

59 A-LSA Motor Prolght  !!arnwell, SC U18dir_SL Ship _meqig Iypo_Qgantliy Ngogg_SLIrapppglatign pagljng[lpn c) Irradiated components, control rods, etc.

None Numbog_g,(,,,phlgssnig Iyp3._Q9aD1111 H2$0 of._IDDEPRtlAllE11 DoctIR911RR d) Othor: None Hono

4. Irradialed Fuel ShlPM9D11 (Disposition)

F#EhfrJf_Shipmenig Iypo_Quaatjiy tiodo of Tratigrortatton p3glittaljgn None N/A N/A N/A

5. Polidiffration of Wasig s Was solidification performed? _No If yes, solidification media: N/A
6. Wero any changes made to the process control programt Yes ,,,,,_LN o If-yes, add no an attachment at the end of report in accordance with Process Control Program Section 9.0.
7. Woro any major changes made to the radioactive waste systems (liquid, gaseous or solid)? Yes X_ No. -If yes, add an attachment at the end of_ report-in accordance with Technical Specification Administration Control 6.15.

419/1/2

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