ML103360364
| ML103360364 | |
| Person / Time | |
|---|---|
| Site: | Palo Verde  |
| Issue date: | 05/14/2010 |
| From: | Grossclose M, Sheldon M Brown & Caldwell |
| To: | Office of Nuclear Reactor Regulation, Arizona Public Service Co |
| References | |
| P-100388 | |
| Download: ML103360364 (353) | |
Text
{{#Wiki_filter:2009ANNUALMONITORINGAND _,-COMPLIANCEREPORTPALOVERDENUCLEARGENERATINGSTATIONAPPPERMITNO.P-100388PreparedforArizonaPublicServiceCompanyTonopah,Arizona -_-May14,2010 2009ANNUALMONITORINGANDCOMPLIANCEREPORTFORTHEPALOVERDENUCLEARGENERATINGSTATIONAPPPERMITNO.P-100388PreparedforArizonaPublicServiceCompanyTonopah,ArizonaMay14,2010BrownandCaldwellProj ect#:138949 Mark G r o s e c l ose,R.G.M e ganProjectManager Project333EastWetmoreRoad,Suite165Tucson,Arizona85705 Cont en t s 2 009A nnu alM o ni toringan d Compli a n ce R e p o rtAPPNO.P.100388TABLEOFCONTENTS _-INTRODUCTION 1.GROUNDWATERMONITORINGA.
SUMMARY
TABLES /SPREADSHEETSOFANALYTICALRESULTSB.TRENDSINGROUNDWATERCHEMISTRY C.INDICATORPARAMETERCONCENTRATIONCONTOURMAPS,ANDALLEXCEEDANCESVERIFIEDDURINGTHEONE-Y EARREPORTINGPERIODD.QUARTERLYSHALLOWGROUNDWATERMAPSANDANNUALREGIONALGROUNDWATEREQUlPOTENTIALMAPSE.PROVIDETDSANDCHLORIDECONCENTRATIONCONTOURMAPSFORTHESHALLOWAQUIFERONABIENNIALBASIS2.IMPOUNDMENTMONITORINGA.LCRSSUMPMONITORINGRESULTSB.SUMMARIESOFANALYTICALRESULTSC.
SUMMARY
OFMAINTENANCEANDREPAIRACTIVITIESD.
SUMMARY
OFTHERESULTSOFALLLINERLEAKAGEE.
SUMMARY
TABLESOFALLBASIN,IMPOUNDMENT,ANDRESERVOIRDATAWHICHALLOWSDATATOBEREADILYCOMPAREDTOLEAKAGEANDDISCHARGEQUALITYALERTLEVELSANDPREVIOUSDATA 3.SLUDGEMONITORINGA.SLUDGELANDFILLMONITORINGANALYTICALRESULTSB.COOLINGTOWERSLUDGEANALYTICALRESULTSC.
SUMMARY
OFANYEXCEEDANCESOFPERMITLIMITSFORSLUDGEQUALITYD.DESCRIPTIONOFANYVIOLATIONSOFTHEARRASPECIALLICENSEFORSLUDGERADIOISOTOPE LIMITS..4.COMPLIANCESTATUSA.VOLUMEOFALLNON-STORMWATERRELEASESTOTHEUNLINEDDITCHESORSEDIMENTATION BASINS.....B.SOURCEANDCHARACTERIZATIONOFRELEASESTOBASINSC.CONTINGENCYPLANACTIONSTAKENFORRELEASESD.VIOLATIONSOFTHISPERMIT .....E.IDENTIFICATIONOFALERTLEVELS,AQLS,AQUIFERWATERQUALITYSTANDARDS,ORDISCHARGELIMITATIONSTHATHAVEBEENEXCEEDEDDURINGTHEREPORTINGPERIODANDADISCUSSIONOFTHETRENDINCONCENTRATIONSCOMPAREDTOTHEPREVIOUS:IEPORTING _.PERIODSANDACTIONSTAKENTOCORRECTTHEEXCEEDEDLEVELS .:: l_.l ,,, t._-ll_.l t_i,,, l_I: iP:\APS-PVNGS\138949-2009AnnualMon.and ComplRepor t'\Deliverables\Reports\Final\FinalAP$-PVNGSAnnua lReport2009.doc Contents2009Annual MonitoringandComplianceReportAPPNO.P-100388LISTOFFIGURESFigure1SiteMapFigure2Selected2009BoronConcentrationsFigure3Selected2009ChlorideConcentrations Figure4QuarterlyShallowA cuiferContourMap-January2009Figure5QuarterlyShallowA cuiferContourMap-April2009Figure6Quarterly ShallowAcuiferContourMap-July2009Figure7 QuarterlyShallowA cuiferContourMap-October2009Figure8QuarterlyPaloVerdeClayAquiferContourMap-January2009Figure9QuarterlyPaloVerdeClayAquiferContourMap-April2009Figure10QuarterlyPaloVerdeClayAquiferContourMap-July2009Figure11QuarterlyPaloVerdeClayAquiferContourMap-October2009Figure12RegionalAquifer GroundwaterElevations-2009Figure13APP-3GroundwaterElevations Figure14APP-4andAPP-4RGroundwaterElevations Figure15APP-5GroundwaterElevationsFigure16APP-6GroundwaterElevationsFigure17APP-7GroundwaterElevationsFigure18APP-8GroundwaterElevationsFigure19APP-9GroundwaterElevationsFigure20APP-10GroundwaterElevations Figure21APP-11GroundwaterElevations Figure22APP-12GroundwaterElevationsFigure23APP-13GroundwaterElevations Figure24APP-14GroundwaterElevationsFigure25APP-15GroundwaterElevations Figure26PV-14HGroundwaterElevations Figure27PV-174GroundwaterElevationsFigure28PV-183GroundwaterElevationsFigure29PV-192AGroundwaterElevationsFigure30PV-193AGroundwaterElevationsFigure31PV-195AGroundwaterElevationsFigure32PV-196AGroundwaterElevationsFigure33PV-197AGroundwaterElevations , u-"1a[e l ,;jmiO]_l_l*A , L_I U°APS-PV_',_G%1389 49_2009Annua!MonariaComplReportDe! verab!esRepons,F_naiFina%APSPVNGSAnnualReport2009doc C o n te nts2009A nnual M onit oringandComplian ce ReportAPPNO,P-100388Figure34PV-198ARGroundwaterElevationsFigure35PV-201AGroundwaterElevationsFigure36PV-202AGroundwaterElevations Figure37PV-203AGroundwaterElevations Figure38PV-204AGroundwaterElevations ....Figure39PV-205AGroundwaterElevations Figure40PV-206AGroundwaterElevations Figure41PV-216RGroundwaterElevationsFigure42PV-21HGround waterElevationsFigure43PV-24HGroundwaterElevations Figure44PV-24HBGroundwaterElevationsFigure45PV-25HAGroundwaterElevations Figure46PV-28HBGroundwaterElevationsFigure47PV-29HBGroundwaterElevationsFigure48PV -33HGroundwaterElevationsFigure49PV-34HGroundwaterElevationsFigure50PV-Q5GroundwaterElevationsFigure51PV-Q8GroundwaterElevations.......Figure52PV-R2ARGroundwaterElevationsFigure53PV-TR1GroundwaterElevationsFigure54U5-PTWBGroundwaterElevationsFigure55TDSConcentrationsforShallowAquiferWellsLISTOFAPPENDICESAPPENDIXAANNUALRADIOLOGICALENVIRONMENTALOPERATINGREPORT ......APPENDIXBELECTRONICDATA(CDincludesPDFofentirereport) APPENDIXCOTHERREQUIREDINFORMATION ......A pp e n dixC1V erticalTr e ndA naly s i sAppendixC2AnalyticalDataOutsideQ NQCorPermitDetectionLimits .....AppendixC3SummaryofAllWellData(2009)'."-!a[el,,,ft u i_'lL_l, ,'r f_lIiiP:',APS-PVNGS\138949-200gAnnu alMon.andCompl.Repor t\Deliverab
- es\Reports\Finat\FinalAPS-PVNGSAnnualReport2009.d o c 1.G ro u ndw a t e r Mo nito r ing 2009A nn ualM o n itoringandC o mpli a nceRepo rtAPPNO,P-100388 INTRODUCTIONThisreportdocumentsmonitoring andcomplianceactivitiesconductedby ArizonaPublicService(A PS)CompanyforthePaloVerdeNuclearGeneratingStation(PVNGS)duringcalendaryear2009inaccordancewithAquiferProtectionPermit(APP)No.P-10 0388.ThePVNGS,locatedapproximately45mileswestofPhoenixnearWintersburg,Arizona,(Figure1),isastandar dizedtriple-unitnuclearpowerfacility.Thesitebeganoperationsin1985andconsistsofanexistingelectricgeneratingbaseloadplantutilizingnuclearfissionforgenerationofelectricalpower.Thefacilityissituatedon4,280acresandconsistsofthreeseparate,identicalgeneratingunits
/reactors.Eachreactorisequippedwiththreecoolingtowersandiscapableof independentoperation.FollowingsteamgeneratorreplacementsandthermalupratesinUnits1,2,and3,eachunitnowhasanominalnetelectricaloutputofapproximately 1,346megaw atts(MW),foratotalplantcapacityofabout4, 038MW.Theorigina lAPPforthesitewasissuedbytheArizonaDepartmentofEnvironmentalQuality(A DEQ)inDecember2 003andhasundergonemultiplerevisions.Allre ferencesinthisreportrefertotheAPPrevisiondatedFebruary 10,2010(thePermit).Section14.0ofthePermitprovidesreportingandrecordkeepingrequirements.Inadditiontoselfmonitoring reportforms,op erationinspection /logbookrecordkeeping,andpermitviolationandalertlevelstatusreporting,elementsoftheannualmonitoringandcompliancereportarespecified.ThefollowingannualmonitoringandcompliancereportoutlineistakendirectlyfromSection14.4ofthePermit:1.GroundwaterMonitoringThissectionofthereportshallcontainthefollowinginformation: a.S umm a ry tables/spreadsh e ets of a n a lyticalresults; b.Trendsingroundwaterche m ist{y;_;Ind icatorparameterconcentrationcontourmaps,andallex c eedan cesverifiedduringtheoneyearreporting perio&d.Qua rterlyshallowgroundwatermapsandannual RegionalGroundwaterequipotentialmaps(usingthe potentio metricsurfaceforco n touri ngflow)withmapslabeledbyaquifer," e.ProvideTDSand chloridecon c entrationc ontour mapsfortheshallowaquiferonabie nnialbasis.Groundwatercontou ringmaybepetformedbyhandorbyusinganaa 'eptedcomputerprogra m/m odel.All calculationsforcontouringshallbei ncludedi nthesub m ittal.Eachwellshallhaveitsowndatatablethatallowsall dataforthatwellto beassessedandco mparedtobaselinedata,AL ,,a ndAQL rforthatsamewell .Thepermitteeshallprovi deasu mm a{y table ofalldataforallwellsinbothelectronicandhardcopyform .Usingcrosssectionsor3 -Dmodels,thereportshallas sessdownward concentrationtrendsforindicatorpara m etersandA IgQSconstitue nts,ifa ny,andshallconsidersu chtre ndsincombi nationwithtopogra p hy oftheuppermostsurfaceoftheaquitard .Appropriatecomponentsofthe re po rtshallbesealedbyanA ri zona registeredgeologistorprofissionalengineer,inaccor dancewithArizonaBoardofTe chnicalRegistration(BTR)require m ents.Therepo rtshallinclu de a n up dateonwellAPP -Iandstatusrepo rtingtoverifithatthiswellisd 0,andthereforenotsuitableforuseinthegroundwatermonitoringprogra m.P:',APS-PVNGS\138949-2009Annu alMon.andCom p l R ep o r t',Del i verab l e s\Repor t s',Final\Fna lAPS-PVNGSAn nualR eport2009doc 1.Gro un d wa ter Mo nit o ring 2 0 09A nnu a l Mo ni to r i n gandC o mplianc e R e p or t 2.ImpoundmentMonitoringThissectionofthereportshallcontainthefollowinginformation:
a.LCRSsu m p m o n ito ringresults," b.Su mmariesofa n a ly ti calresults;c.Su mm a{yofm aintenan ceandrepairactivities," d.Su mm a r yoftheresultsofalllinerleakage," and e.Su mm ar ytablesofallbasin,impoundment,andreservoirdatawhichallows datatobe readilyco mparedtoleakageanddischargequali(y Ak r andprevious da ta.3.SludgeMonitoring Thisse ctionofther eportshall containthefollowinginfo rm ation: a.Sludgelandfill m o n ito ri n g ana ly ti calresults; b.Coolingtowerana ly ti calresults," c.Summat7ofanyex c ee da n cesofpe rmitli mitsforsludgequali _," d_Des criptionofanyviolationsoftheARRASpe cialIa'censeforsludgeradioisotopelimits;and, e.TheRadiologicalEnviron mentalMonito ringProgra mReport(REMP) .4.Comp_'anc e StatusThissection ofther eportshallcontainthefollowi ngi n fo rm ation: a.Volumeofal l non-sto rmwaterreleasestotheunlinedditchesorsed imentationbasins," b.Sour ceand c haracte rizationof releasestobasins,"_: Contingen cyPlanactionstakenforreleases," d.Violations ofthispermit;and e.IdentificationofAt r,AQL r,AWQSsorDk rthathavebeenex ceededduringthereportingperiodanda discussion ofthet rendinconcentrationsco mparedtothepreviousr eportingperiodsandactionstakentocorrectthecause#ofexcee da nce(s).Thisreportisorganizedbasedonthefoursectionslistedabove.',=-_=[, l, , ,J,_==#,]_1I t t, , ,l=.]l l iP:'&PS-PVNGS',138949-2009AnnualMort.andComplR e port\Deliv e rab l es'_Reports',F l na l\FinalAPS-PVNG$AnnualReport2O09.doc 1.GroundwaterMonitoring 2009 AnnualMonitoringandComplianceReportAPPNO.P-1003881.GROUNDWATERMONITORINGA.
SUMMARY
TABLES /SPREADSHEETSOFANALYTICAL RESULTSInaccordancewithSection12.4.2.3ofthePermitandtheComplianceScheduleinthePermit,transducershavebeeninstalledinAPPwellslistedinTable17.2-34.Wellscontainingtransducersincludepiezometers, pointofcompliance(POC)wells,andalertwells.However,APP-1andPV-191Adonotcontaintransducerssincethesewellshavebeendrysinceinstallation.ThelocationandaquifermonitoredbyeachwelllistedinTable17.2-34ispresentedinFigure1.ItshouldbenotedthatPV-201A,PV-202A,PV-203AandPV-204AwereabandonedinAugust2008.Thesamplingplan,approvedbyADEQ,containsthefollowingorderforsamplingmonitoringwellsatthePVNGS:APP-12,APP-10,APP-9,APP-8,PV-206A,PV-198AR,PV-Q8,APP-3,APP-4R,PV-193A,APP-5,PV-34H,APP-6,PV-14H,APP-13,APP-14,APP-15,PV-195A,PV-R2AR,andAPP-7.Section12.4ofthePermitrequeststhatadescriptionofdeviationsfromthesamplingorderbeincludedintheannualreport.Thefollowingdeviationsfromthesamplingorderoccurredin2009:*GroundwatersamplesfromAPP-9,APP-10andAPP-12werecollectedoutoforderonJanuary15,2009.Allthreesampleswerecollectedonthesameday,butthesamplefromAPP-9wascollectedbeforethesamplesfromAPP-10andAPP-12andthesamplefromAPP-10wascollectedbeforethesamplefrom APP-12.*FiringrangeactivityimpactedthesamplingschedulesforPV-195A,PV-14HandAPP-6.InJune2009,thesamplefromPV-195AwascollectedbeforethesamplesfromPV-14HandAPP-6andthesamplefromPV-14HwascollectedbeforethesamplefromAPP-6.InOctober2009,thesamplesfromAPP-6andPV-14HwerecollectedbeforesamplesfromAPP-12,APP-10andAPP-9.*GroundwatersamplesfromPV-198ARandPV-193AwerecollectedinJulyandAugust2009,respectively.However,thesegroundwatersampleswerecollectedoutoforderaspartofverification sampling.*GroundwatersamplesfromAPP-3andAPP-13werecollectedoutoforderinNovember2009.TheinitialsamplefromAPP-3wascollectedonOctober29,2009.However,asecondsamplewascollectedfromAPP-3onNovember3,2009,tobeanalyzedforgammaemittingradionuclides(Cesium-134, Cesium-137,Cobalt-60,Iodine-131).Thesecondsamplewascollectedoutoforder,afterPV-193A.ThegroundwatersamplefromAPP-13wascollectedoutoforder,beforePV-34H.Althoughthereweredeviationsinthesamplingorder,sampleswerecollectedatthefrequencyspecifiedbythePermitandthesampleorderdidnotadverselyaffectthegroundwatermonitoringresults.Ataminimum,transducersrecordgroundwaterelevationsonadailybasis.Atablesummarizingselectedgroundwaterlevelsfor2009isprovidedinTable1A-1.Thetableincludestransducerdataormanualreadingsrecordedpriortosamplecollection.InaccordancewithTable17.2-10ofthePermit,POCwellsandalertwellsarerequiredtobesampledonaquarterlybasisforindicatorparameters.TritiumisanindicatorparameteratallofthePOCandalertwells;however,boronandchlorideareadditionalindicatorparametersattheshallowalertwells.AnalyticalresultsfortheindicatorparametersarepresentedinTables1A-2through1A-21ofthisreport."-"!iO I'A'IiE I_"U[ol'_,l.=]!iP_PS-PVNGSi38949-2009AnnualMot;andCompRepoqDeJiverabesRe_ortsF_naiFinalAPS-PVNGSAnnualReport2009doc 1.Groundwater M onitoring 200 9 Annual MonitoringandComplianceReportAPPNO.P-100388Groundwatersamplesarealsocollectedonabiennialbasis(everytwoyears)fortheextendedlistofparameterslistedinTables17.2-11through17.2-20andTables17.2-24through17.2-30ofthePermit.Ingeneralfor2009,groundwatersamplescollectedinMayorJunewereanalyzedfortheextendedlistofparametersfordatacontinuity(biennialsamplingoccurredin2008).Theassociatedwaterqualitydatafor2009arepresentedinTables1A-2through1A-21ofthisreport.TheambientmonitoringperiodsforPOCwellAPP-13andalertwellsAPP-14andAPP-15werecompletedinAugust2009;groundwatersamplescollectedfromthesewellsduringNovember2009wereanalyzedforthequarterlyindicatorparameterslistedinTable17.2-10.Samplestobecollectedin2010willbeanalyzedfortheextendedlistofparametersinaccordancewithTables17.2-31through17.2-33ofthePermit.Analyticalresultsforthegroundwatersamplesarecomparedtoalertlevels(ALs)andaquiferqualitylimits(AQLs)specifiedinthepermit,aswellasAWQSs.ExceedancesarediscussedinSection1.Cofthisreport. 'i!lel,,,inmd_'l[Il,,'I_.1liP, A PS-PvNGS138949-2009AnnqaMonandComplReportDeiiverab4esRepotsFinal'FinalAPS-PVNG$AnnuaiReport2009doc APS-PVNGS2009AnnualMonitoringandComplianceReport D A TE W ELL I DTYPEOF M EASURE M ENT M EASUREDAPP-103/10/09 920.64 Dry Dry Qtr lyWQ 06/24/09 920.64 Dry DryQtrlyWQ 08/28/09 920.64 Dry DryQtrlyWQ 10/15/09 920.64 Dry DryQtrlyWQAPP-302/18/09 916.73 225,78 690.95QuarterlyIndicator 05/28/09 916.73 225.87 690.86QuarterlyIndicator 08/06/09 916.73 227.65 689.08QuarterlyIndicator 11/03/09 916.73 228.97 687.76QuarterlyIndicatorAPP-4R02/19/09 917.08 161.60 755.48QuarterlyIndicator 05/27/09 917.08 161.31 755.77QuarterlyIndicator 08/05/09 917.08 161.51 755,57QuarterlyIndicator 10/28/09 917.08 161.16 755.92QuarterlyIndicator APP-502/27/09 912,53 136.31 776.22QuarterlyIndicator 06/09/09 912.53 135.65 776.88QuarterlyIndicator 09/16/09 912.53 136.68 775.86QuarterlyIndicator 11/08/09 912.53 133.26 779.27QuarterlyIndicator APP-603/10/09 920.80 194.19 726.61QuarterlyIndicator 06/15/09 920.80 194.45 726.35QuarterlyIndicator 09/16/09 920,80 195,40 725,40QuarterlyIndicator 10/21/09 920.80 195.5!725,29QuarterlyIndicator APP-703/12/09 970.63 129.00 841,63QuarterlyIndicator 06/16/09 970.63 129.41 841.22QuarterlyIndicator 09/29/09 970.63 130.29 840.34QuarterlyIndicator 11/18/09 970.63 131.41 839.22QuarterlyIndicatorAPP-80!/16/09 948.57 100.50 848.07QuarterlyIndicator 02/10/09 948.57 100.43 848.14QuarterlyIndicator(repeatsample,samplererror) 05/07/09 948.57 100.61 847.96QuarterlyIndicator 07/23/09 948.57 100.90 847.67QuarterlyIndicator 10/28/09 948.57 101.25 847.32QuarterlyIndicatorAPP-901/15/09 952.00 93.72 858.48QuarterlyIndicator 05/06/09 952.00 93.92 858.28QuarterlyIndicator 07/08/09 952.00 94.15 858.05QuarterlyIndicator 07/21/09 952.00 94.10 858.10Verificationsamplingforchromium 10/21/09 952,00 94.34 857.86QuarterlyIndicatorP:_APS-PVNGS\138949-2009AnnualMoil.andComplReport\Deliverables\Reports\F vlal\Section1T ables\20OgTable1A1WaterLevelsxlsPage1of6............................ v,mulJuf_u_ l lveraoles/KeportsU-vlal\Section1Tables\20OgTaMe1A1WaterLevelsxlsPage1of6 APS-PVNGS2009AnnualMonitoringandComplianceReportTOPOFCAS INGMEASU R ED D EPTHW ATE RWELLIDDATEELEVATIONTOWATE R ELEVATION T YPEOFMEASU R EMENT MEASU R ED APP-1001/14/09 956.27114.55" 841.92QuarterlyIndicator 05/06/09 956.27!15.15 841.32QuarterlyIndicator 06/08/09 956.27 115.34 841.13Verificationsamplingforsulfate 07/08/09 956.27 115.69 840.78QuarterlyIndicator 10/21/09 956.27 116.69 839.78QuarterlyIndicatorAPP-1!03/10 /09 950.27 71.45 879.02FromTransducer 08/27/09 950.277!.85 878.62FromTransducer 10/16/09 950.27 72.15 878.32FromTransducer 12/16/09 950.27 72.25 878.22FromTransducerAPP-1201/15/09 957.83 130.29 827.54QuarterlyIndicator 05/06/09 957.83 130.55 827.28QuarterlyIndicator 07/08/09 957.83!31.05 826.78QuarterlyIndicator 10/21/09 957.83 131.75 826.08QuarterlyIndicatorAPP-1301/07/09 920.69 87.83 832.86MonthlyAmbient 02/04/09 920.69 87.82 832.87MonthlyAmbient 03/05/09 920.69 87.94 832.75MonthlyAmbient 04/29/09 920.69 87.88 832.81MonthlyAmbient 05/20/09 920,69 87.98 832.71MonthlyAmbient 06/04/09 920.69 87.90 832.79MonthlyAmbient 07/14/09 920.69 87.95 832.74MonthlyAmbient 08/19/09 920.69 87.80 832,89MonthlyAmbient 11/05/09 920.69 87.61 833.08QuarterlyIndicator APP-1401/07/09 920.52 60.40 860.12MonthlyAmbient 02/04/09 920.52 60.08 860.44MonthlyAmbient 03/05/09 920.52 60.10 860.42MonthlyAmbient 04/29/09 920.52 60.13 860.39MonthlyAmbient 05/20/09 920.52 60.13 860.39MonthlyAmblent 06/04/09 920.52 60.15 860.37MonthlyAmbient 07/14/09 920.52 60.20 860,32MonthlyAmbient 08/19/09 920.52 60.30 860.22MonthlyAmbient 11/09/09 920.52 60.71 859.81QuarterlyIndicatorP:_APS-PVNGS\1389492009AnnualMenandComp[.Report\Deliverables\Reports\Final\Section1Tables\2009Table1A1WaterLevels.xlsPage2of6 APS-PVNGS2009AnnualMonitoringandComplianceReport TOPOFCAS I NG M EAS UR EDD EPTHW A T ER D A T E W ELLI D M EAS UREDELE V A TI ON T O W A T E R ELE V AT I ON TYPEOF M EAS U RE M EN T (FTAM SL)(FTBMP)(F T A M SL)APP-1501/07/09 924.74 62.09 862,65MonthlyAmbient 02/04/09 924.7 4 61.88 862.86MonthlyAmbient 03/05/09 924.74 61.9 7 862.77 M onthlyAmbient 04/29/09 924.7 46!.95 862.79MonthlyAmbient 05/20/09 924.74 61.96 862.78MonthlyAmbient 06/04/09 924.74 61.99 862.75MonthlyAmb i ent 07/15/09 92 4.74 62.15 862.59 M onthlyAmbient 08/19/09 924.74 61.95 862.7 9MonthlyAmbient 11/09/09 924.74 62.19 862.55Quarter lyIndicatorPV+14H03/!1/09 922.01 57.96 864.05QuarterlyIndicator 06/15/09 922.01 58.08 863.93QuarterlyIndicator 09/17/09 922.01 58.13 863.88QuarterlyIndicator 10/22/09 922.01 58.10 863.91QuarterlyIndicatorPV-17403/05/09 955.75 59.76 895.99FromTransducer 06/18/09 955.75 61.10 894.65FromTransducer 08/27/09 955.75 61.10 894.65FromTransducer 10/16/09 955.75 61.61 894.14FromTransducerPV-18303/11/09 951.70 60.01 891.69FromTransducer 06/18/09 951.70 60.55 891.15FromTransducer 08/27/09 951.706!.00 890.70FromTransducer 10/23/09 951.7061.!1 890.59FromTransducerPV191A03/03/09 943.60 Dry DryQtdyWQ 06/t8/09 943.60 Dry DryQtrlyWQ 08/28/09 943.60 Dry DryQtrlyWQ 10/21/09 943.60 Dry DryQtrlyWQ PV-192A03/03/09 943.31 95.68 847.63FromTransducer 06/18/09 943.31 95.75 847.56FromTransducer 08/28/09 943.31 95.8!847.50FromTransducer 10/16/09 943.31 95.88 847.43FromTransducerPV-193A02/27/09 943.7!79.63 864.08QuarterlyIndicator 05/27/09 943.71 79.48 864.23QuarterlyIndicator 08/03/09 943.71 79.55 864.!6QuarterlyIndicator 10/28/09 943.71 79.11 864.60QuarterlyIndicatorP\APS-PVNGS\1389492009AnnualMortandComplReport\Deliverables\Reports\Final\Section1Tabies\2OO9T able1A-1WaterLevels.xlsPage3of6 APS-PVNGS2009AnnualMonitoringandComplianceReport TOPO F C A S I NGMEA S U R ED DEPTHWAT ER D AT E W ELLID E L EVATIONTOWAT E R E LEVATION TYP E O F M E ASUREMENT MEASURED(FTAM SL)(FTBMP),,(FTAMSL)PV-195A03/11/09 921.71 48.80 872.91QuarterlyIndicator 06/23/09 921.71 48.99 872.72QuarterlyIndicator 09/17/09 921.71 49.08 872.63QuarterlyIndicator 11/10/09 921.71 49.04 872.67QuarterlyIndicatorPV-198AR01 /13/09 931.48 75.78855.70Contingencymonthlyindicatorsamplingforchloride exceedance 02 il1/09 931.48 75.81 855.67QuarterlyIndicator 05/27/08 931.48 76.33 855.15QuarterlyIndicator 07/22/09 931.48 76.59 854.89Quarterlyindicatorandverificationsamplingforboron,chloride,totaldissolvedsolids,potassium , and chromium.10/14/09 931.48 76.85 854.63Quarterlyindicatorandcontingencymonthlyindicatorsamplingforchlorideexceedance 11/04/09 931.48 76.83854.65Contingencymonthlyindicatorsamplingforchloride exceedance PV-205A03/24/09 907.23 69.94 837.29FromTransducer 08/28/09 907.23 69.92 837.31FromTransducer 10/15/09 907.237000 837.23FromTransducerPV-206A02/10/09 947.91 82.30 866.61QuarterlyIndicator 05/20/09 947.9!82.56 865.35Quarterlyindicator 08/03/09 947.91 82.81 865.10QuarterlyIndicator !0/28/09 947.91 82.96 864.95QuarterlyIndicator PV-207A03/30/09 967.24 DryDryFromTransducer;Confirmedquarterlywithsounder 06/30/09 967.24 DryDryFromTransducer;Confirmedquarterlywithsounder 09/30/09 967.24 DryDryFromTransducer;Confirmedqua,,terlywithsoundeT !0/28/09 967.24 DryDryFromTransducer;Confirmedquarterlywithsounder 12/30/09 967.24 DryDryFromTransducer;ConfirmedquarterlywithsounderPV-216R03/17/09 891.01 198.16 692.85FornitrateexceedanceinAPP-3 06/17/09 891.01 199.33 691.68FornitrateexceedanceinAPP*3 08/20/0989!.01 202.15 688.86FornitrateexceedanceinAPP -3,WLrecheckedon9 /1/09:DTW@12:50=202.57flbmp,TROLL=14.34ft 11/18/0989!.01 202.82 688.19FornitrateexceedanceinAPP-3PV-21H03/05/09 962.!0 72.78 889.32FromTransducer 06/18/09 962.10 73.40 888.70FromTransducer 08/27/09 962.10 73.64 888.46FromTransducer 10/16/09 962.10 73.82 888.28FromTransducer3:_APSPVNGS_1389492009AnnualMonandComplReport\Deliverables\Reports\Final\Section1Tabfes\2OO9Table1A-1WaterLevelsxlsPage4of6 APS-PVNGS2009AnnualMonitoringandComplianceReportTOPOFCASINGM EASU R E D DEPTHW ATER D ATEWELLIDELEVATIONTOWATERELEVATIONTYPEOFMEASUREMENT MEASUR E D(FTAMSL)(FTBMP)(FTAM S L)PV-24H0!/06/09 947.00 59.63 887.37FromSounder 03/12/09 947.00NoreadingProbedryFromTransducer 06/23/09 947.00 59.85 887.15FromSounder 09/0!/09 947.00NoreadingProbedryFromTransducerPV-24HB01/02/09 940.91 54.43 886.48FromTransducer 06/!7/09 940.91 54.80 886.11FromTransducer 08/28/09 940.91 55.03 885.88FromTransducer 10/16/09 940.91 55.10 885.81FromTransducerPV-25HA01/02/09 942.10 60.11 88!.99FromTransducer 06/17/09 942.10 60.69 881,41FromTransducer 08/27/09942.!0 61.18 880.92FromTransducer 10/23/09 942.10 61.24 880.86FromTransducerPV-28HB01/06/09 93081 47.32 883.49FromTransducer 06/17/09 930.81 47.67 883.14FromTransducer 08/27/09 930.81 48.38 882.43FromTransducer 10/23/09 930.81 48.71 882.10FromTransducerPV-29HB03/13/09 928.40 48.85 879.55FromTransducer 06/17/09 928.40 49.17 879.23FromTransducer 08/28/09 928.40 49.51 878.89FromTransducer 10/23/09 928.40 49.60 878.80FromTransducerPV-34H02/27/09 911.51 45.88 865.63QuarterlyIndicator 06/23/09 911.51 46.45 865.06QuarterlyIndicator 09/16/0991!.5!46.87 864.65QuarterlyIndicator!1/05/09 911.51 46.86 864.65QuarterlyIndicatorPV-Q501/08/09 938.31 58.12 880,19FromTransducer 03/13/09 938.31 58.44 879.87FromTransducer 06/18/09 938.31 58.90 879.41FromTransducer 10/23/09 938.31 59.55 878.76FromTransducer P:LAPS-PVNGS\138949 -2009AnnualMonandCompl.Report\Deliverables\Reports\Final\Section1T ables\2OO9Tabre1A!WaterLevels.xlsPage5of6 APS-PVNGS2009AnnualMonitoringandComplianceReport TOPOF C ASINGMEA S U REDDEPTHWATE R D A T EWELLID ELE VATIONTOWATER E L E VATIONTYPEO F MEASUR E MENT MEA S U R ED(FTAM S L)(FT B MP)(FTAM S L)PV-Q802/10/09 923.80 79.00 844.80QuarterlyIndicator 05/27/09 923.80 78.97 844.83QuarterlyIndicator 08/05/09 923.80 78.97 844.83QuarterlyIndicat o r 10/07/09 923.80 79.07 844.73Verificationsamplingforboron 10/28/09 923.80 78.88 844.92QuarterlyIndicator 12/01/09 923.80 79.07844.73Contingencymonthlyindicatorsamplingforboron exceedancePV-R2AR03/12/09 961.15 76.08 885.07QuarterlyIndicator 06/17/09 961.15 76.55 884.60QuarterlyIndicator 09/24/09 961.15 77.35 883.80QuarterlyIndicator1!/18/09 961.15 77.70 883.45QuarterlyIndicatorPV-TR103/10/09 962.60 64.35 898.25FromTransducer 06/17/09 962.60 67.04 895.56FromTransducer 08/27/09 962.60 67.05 895.55FromTransducer 10/16/09 962.60 68.25 894.35FromTransducer U5-PTWB03/13/09 930.81 45.50 885.31FromTransducer 06/18/09 930.81 45.65 885.16FromTransducer 08/28/09 930.81 46.05 884.76FromTransducer 10/23/09 930.81 46.34 884.47FromTransducer Notes: DTW-DepthToWater[tamsl-feetabovemeansealevel _tbmp-feetbelowmeasuringpointWL-WaterLevelWQ-WaterQualityP:_APS-PVNGS\138949-2009AnnualM ortandComplReport\Deliverables\Reports\Flnal\Section1Tables\2OOgTable1A-1WaterLeversxIsPage6of6......................,_,,_.u_umpl_epor[lue!lverables\h:eports\Flnal\Section1Tables\2OO9Table1A-1WaterLeversxlsPage6of6 APS-PVNGS:2009AnnualMonitor ingandComplianceReport Analyte A Q L pH NESpecConducta n c e@25Cpmhos/om240028002 .7002,800 NE Monit oronlyNE Antimo n y mg/L<0002 0<00020<00020<000200006000540006 Di ssolvedAntimonym g/L<00020<00020<0002 0<00020 Arsenic mg/L00229002240021700247 0050045005DissolvedArsenic mg/L00219002210022400247 Bar i um mg/L004260033004410050 7 2182DissolvedBarium mg/L00321003390033800342 Boron mg/L14!41413NENE!89NEDissolvedBoron mg/L14121414 Beryllium mg/L<00005<0.0005<00005<00005 0004000360004DissolvedBeryllium mg/L<0.0005<00005<00005<00005 Cadmium mg/L<0.0020<00020<00020<000200005000450005DissolvedC admiummg/L<00020<00020<00020<0.0020 Chromium mg/L00756007370086200916_008630100901DissolvedChromiummg /L0074400747008030087900824 Chloride mg/L570630580570NENE642NE Fluonde mg/L555657546 4NA94 Lead mg/L0.0027<00020c0.0020<000200050045005DissolvedLead mg/L<00020<00020<00020<00020 Mercury mg/L<00002c00002<00002<00002 0002000180002DissolvedMercury mg/L<00002c00002c00002<00002 Nickel mg/L00073<000500.007700120000790100901DissolvedNic k el mg/L<00050<00050<00050<00050<00050 Nitrate/NitriteasN mg/L94A97r'96F97F 10910 Potassium mg/L55L_85E2957_ NE437NEDissolvedPotassiummg /L67'722653 Selenium mg lL000300003700034000530050045005DissolvedSeleniummg /L00035000330003300056
Sulfate mg/L150170160160 NE199NETotalDissolvedSolidsmg /L15001,50015001,500 NE1,513NE Thallium mg/L<00005<00005<00005<00005 0002NA00021DissolvedThallium mg/L<00005<00005c00005<00005Bromodichloromethanemg /L<000050 Bromoform mg/L<00010 Chloroform mg/L<000050Dibromochloromethanemg /L<000050TotalTrihalomethanesmg /L<00025<00025<00025<00025010.0901 Tri t ium pCi/Lc323c316<493<48020000300018 ,00020,000 Iodine-131 pCi/L<33<45<34<38 10090t00 Cesium-134 pCi/L<19<19<22<24 7567575 Cesium-137 pCi/L<16<19<19<22 11099110 Cobalt-60 pCi/L<!9<18<23<22 200180200 No t e s: lJmhos icmmicromhospercent i meterA-Reanalysisresul tformtrate/ni t n teasNwas93mg /LALAlertLevelspecified tnTable172-18ofthePermitB-Reanalysisresut tforpo tassiumwas67mg /LAQL-AquiferQuali tyLimi t specified inTablet72-18ofthePermitC-Reanalysisresultfordissolvedpo tassiumwas56mg /L AWQS-AquderWaterQuahtyStandardDReanalysisresul tfornitrate i ni t ri teasNwas96mg /LIALIndicatorAler tLevelspecifiedinTable172 -10of thePermitE-Reanalysisresultforpotassiumwas71mg /L mg/L-milligramsperhterF-Reanalysisresul tfornitrate /nitriteasNwas95mg l LNENo testablishedin thePermit G-Reanalys rsresultforchromiumwas00951mg /L pCi/Lpmocunesperh t erH-Reanalysisresultfornitrate /nitri teasNwas96mg i LI-Reanalysisresul tforpotassiumwas45mg /LP_APS-PVNGS',138949-2009AnnualMonandComp l Report\Deliver a bles\Reports\F inal\Section1Tab les\2OO9Table1A-2thru1A-21WQxlsAPP-3Page1of20 APS-PVNGS:2009AnnualMonitoringandComplianceReport Ana lyl eAWQSIALALAQL pH NE<6>9NESpecConductance@25Cpmhos /cm 2,900 NEMonitoronlyNE Ant imony mg/L<00100 0006ReservedReservedDissolvedAntimonymg /L<00040 Arsenic mg/L<00150 005ReservedReservedDissolvedArsenic mg!L00106 Barium mg/L0024 2ReservedReservedDissolvedBarium mg/L00278 Boron mg/L18202217NEReservedReservedNEDissolvedBoron mg/L18191819 Beryllium mg/L<000250004ReservedReservedDissolvedBeryllium mg/L<00010 Cadmium mg/L<00100 0.005ReservedReservedDissolvedCadmiummg /L<00040 Chromium mg/L<0025001ReservedReservedDtssolvedChrom tummg/L00119 Chloride mg/L550550600560NEReservedReservedNE Fluoride mg/L47 4ReservedReserved Lead mg/L<00100 005ReservedReservedDissolvedLead mg/L<00040 Mercury mg/L<000020002ReservedReservedDissolvedMercury mg/L<00002 Nicke!mg/L<0025001ReservedReservedDissolvedNickel mg/L<00100 Nitrate/NitriteasN mg/L45 10ReservedReserved Potassium mg/L58 NEReservedNEDissolvedPotass tummg/L53 Selenium mg/L<00100 005ReservedReservedDissolvedSeleniummg /L<00040 Sulfate mg/L 310 NEReservedNE[olalDissolvedSolidsmg /L 11700 NEReservedNE Thallium mg/L<00025 0002ReservedReservedDissolvedThallium mg i L<00010Bromodichloromethanemg /L Bromoform mg/L Chloroform mg/LDibromochloromethanemg /L TotalTrihalomethanesmg /L<0002501ReservedReserved TritiumpCi/L<323<316<493<48020.0003,000ReservedReserved Iodine-131 pCi/L<35 100ReservedReserved Cesium-134 pOi/L<19 75ReservedReserved Cesium-137 pCi/L<18 110ReservedReserved Cobalt-60 pCi/L<21 200ReservedReserved Notes pmhos/cm-mlcromhospercentimeterAL-AlertLevelspecifiedinTable172-19ofthePerm t tAQL-AquiferQualityLimitspecified tnTable172-19ofthePerm t tAWQS-AquiferWaterQualityStandardIAL-IndicatorAlertLevelspecifiedinTable172-10ofthePermit mg/LmilligramsperliterNE-NotestablishedinthePermil pCi/L-picocuriesperliterP\APS-PVNGS1389492009AnnualMonandComplReport\Dehverabies\Reports\Final/Section1Tables\2OO9Table1A-2thru1A-21WQxlsAPP-4RPage2of20 APS-PVNGS:2009AnnualMonitoringandComplianceReport AnalyteAWQSIALALA Q L pH NE<6,>11NESpecConductance@25C#mhos /cm 1,100 NEMonitoronlyNE Ant i mony mg/L<00020 0006000540006 D tssolvedAntimonymg /L<00020 Arsenic mg/L 00466005NA0175DissolvedArsenic mg/L<00030 Barium mg/L00112 2182DissolvedBarium mg/L0012 Boron mg/L062066059065NENE079NE D issolvedBoron mg/L0690/6061068 Beryll i um mg/L<00005 0004000360004 D issolvedBeryll iummg/L<00005 Cadmium mg/L<000200005000450005DissolvedCadmiummg /L<00020 Chromium mg/L003320100901DissolvedChromiummg /L<00050 Chloride mg/L180190 f80200NENE211NE Fluoride mg/L99 4NA!23 Lead mg/L<000200050045005DissolvedLead mg/L<000 2 0 Mercury mg/L<000020002000180002DissolvedMercury mg/L<00002 Nickel mg i L<000500100901DissolvedNickel mg/L<00050 Nitrate/NitriteasN mg/L39 10 9 10 Potassium mg/L28 NE606NEDissolvedPotassiummg /L 32 Selenium mg/L<000200050045005DissolvedSeleniummg /L<00020 Sulfate mg/L 130 NE133NETotalDissolvedSol idsmg/L 600 NE676NE Thallium mg/L<00005 0002000180002DissolvedThallium mg/L<00005Bromodichloromethanemg /L Bromoform mg/L Chloroform mg/LDibromochtoromethanemg /LTotalTrihatomethanesmg /L<00025010090t Tritium pCi/L<317<319<467<47020,0003 ,0001800020000 iodine-131 pCi/L<38 10090100 Ces i um-134 pCi/L<22 7567575 Cesium-137 pOi/L<22 11099110 Cobalt-60 pCi l L<21 200180200 Notes IJmhos/cm-m icromhospercent i meterAL-AlertLevelspecifiedInTable172-24ofthePermitAQLAquiferQualityLimitspecifiedinTable172 -24ofthePermitAWQSAquiferWaterQualityStandard tAL-IndicatorAlerlLevelspecifiedinTable172-10ofthePermit mg/L-milligramsperliterNE-Notestabl ished_nthePerm i t pCi/LpicocunesperliterP\APS-PVNGS\138949-2009AnnualMonandComplReport\Del t verable s\Reports_F_nal\Sect3on1Tables\20OgTable1A-2thru1A21WQxJsAPP-5Page3of20 APS-PVNGS:2009AnnualMonitoringandComplianceReport Ana lyt e A Q L pH NESpecConductance@25Cpmhos !cm 1,700 NEMonitoronlyNE Antimony mg/L<00040 0.006000540006DissolvedAntimonymg /L<00040 Arsenic mg/L00216 0.05NA0056D_ssolvedArsenic mg/L00181 Bar!urn mg/L<00040 218 2DissolvedBanum mg/L<00040 Boron mg/L13131414NENE164NEDissolvedBoron mg/L14!3!315 Beryllium mg/L<000t0 0004000360004DissolvedBeryl hummg/L<00010 Cadmium mg/L<00040 0.005000450006DissolvedCadmiummg /L<00040 Chromium mg/L<001000100901DissolvedChromiummg /L<00100 Chlonde mg/L330340320330NENE392NE Fluoride mg/L104 4NA151 Lead mg/L<000400050045005DissolvedLead mg/L<00040 Mercury mg/L<000020002000180002DissolvedMercury mg/L<00002 Nickel mg/L<001000100901DissolvedNickel mg/L<00100 Nitrate/NitriteasN mg/L<010 10 9!0 Potassium mg!L<20 NE288NEDissolvedPotassiummg /L<20 Selenium mg/L<000400050045005DissolvedSeleniummg /L<00040 Sulfate mg i L 140 NE169NETotalDi ssolvedSo!idsmg /L 710NE873N E Thallium mg/L<000100002000180002D_sso!vedThallium mg/L<00010Bromodichloromethanemg /L Bromoform mg/L C h lo r oform mg/LDibromochloromethanemg i L TotalTrihalomethanesmg /L<000250100901 Tri h um pCi/L<322<314<467<49120 ,00030001800020000 Iodine-131 pCi/L<38 10090100 Cesium-134 pCi/L<33 75 6 7576Cesium-f37 pCi/L<32t1099110 Cobalt-60 pCi/L<34 200180200 Notes pmhos lcmmicromhospercen t imeterAL-AlertLevelspecifiedinTable172-26ofthePerml (AQL-AquiferQualityLimitspecifiedinTable172-26ofthePerm{t AWQS-AquiferWaterQu alityStandardIAL-Indic atorAle rtLevelspecifiedinTable172-!0ofthePermit rag/L-milligramsperliterNE-NotestablishedinthePermit pQ/L-plcocunesperliterP,.APS-PVNGS',138949-2009AnnualMonandComplReport_,Deliverable s\Reports',Final_ ,Section1Tablesi2009TabletA-2thru1A -21WQxlsAPP-6Page4of20 APS-PVNGS:2009AnnualMonitoringandComplianceReport Analyt e AQL pH NESpecConductance@25Cpmhos /cm 840 NEMonitoronlyNE Antimony mg/L<001000006000540006DissolvedAntimony mg/L<00040 Arsenic mg/L00490005NA0053DissolvedArsemc mg/L00555 Banum mg/L00191 2182DissolvedBarium mg/L00133 Boron mg iL058063064059NENE073NEDissolvedBoron mg/L059058069057 Beryllium mg/L<000250004000360004DissolvedBeryllium mg/L<00010 Cadmium mg/L<001000005000450005DissolvedCadmium mg i L<00040 Chrom i um mg i L 006760100901DissolvedChrom t um mg/L 00669 Chloride mg/L120120120120NENE155NE Fluoride mg/L 12 4NA14 Lead mg/L<001000050045005DissolvedLead mg/L<00040 Mercury mg i L<000020002000180002DissolvedMercury mg/L<00002 Nickel mg/L<002500100901DissolvedNickel mg/L<00100 N_trate/NitriteasN mg/L40 10910 Potassium mg/L23 NE78NEDissolvedPotassium mg!L<20 Selenium mg/L<001000050045005DissolvedSetenium mg/L<00040 Sulfate mg/L 87 NE108NETotalDissolvedSolids mg/L 450 NE691NE Thallium mg/L<000250002000180002DissolvedThallium mg/L<00010Bromod_chloromethanemg /L Bromoform mg/L Chloroform mg/LDibromochloromethanemg /LTotalTnhalomethanes mg/L<000250100901 Tritium pCi/L<322<314<468<48920,0003.0001800020,000 Iodine-131 pCi/L<45 10090100 Cesium-134 pCi/L<18 7567575 Cesium-137 pCi/L<18t1099110 Cobalt-60 pCi/L<21 200180200 Notes _Jmhos/cm-micromhospercentimeterAL-AlertLevelspec tfiedinTable172-30ofthePermit AQL-AquiferQualityLimitspecifiedinTable172-30ofthePermtt AWQS-AquiferWaterQualityStandardIAL-Indicato[AlertLevelspecifiedinTablet72-10ofthePermpt
mg/L-milligramsperliter
NE-NotestablishedinthePermit pC t/L-plcocunesperhterP/APS-PVNGS\1389492009AnnualMort andComp LReport\Deliverabtes\Reports\Final\Sectlon1Tables\2OO9Table1A-2thru1A-21WQxlsAPP-7Page5of20 APS-PVNGS:2009AnnualMonitoringandComplianceReport Analyte A Q L pH NESpecConductance@25Cpmhos /cm1100 NEMonitoronlyNE Antimony mg/L<00020 0006000540006DissolvedAntimonymg /L<00020 Arsenic mg/L 002000050045005DtssolvedArsenic mg/L00202 Barium mg/L 00175 2182DissolvedBarium mg/L 0.0180 Boron mg/L088089098089086NENEtNEDissolvedBoron mg/L09208809810088 Beryllium mg/L<000050004000360004DissolvedBeryllium mg/L<00005 Cadmium mg/L<00020 0.005000450005DissolvedCadmiummg /L<00020 Chromium mg/L00180 0100901DissolvedChromiummg /L00182 Chloride mg iL190150170!70180NENE219NE Fluoride mg/L82 4NE9 Lead mg/L<000200050045005DissolvedLead mg/L<00020 Mercury mg/L<00002 0002000180002DissolvedMercury mg/L<00002 Nickel mg/L<000500100901DissolvedNickel mg/L<00050 Nitrate/NitriteasN mg/L2!10910 Potassium mg/L34 NE527NEDissolvedPotassiummg i L 34 Selenium mg/L<000200050045005DissolvedSeleniummg /L<00020 Sulfate mg/L t20 NE136NETotalDissolvedSolidsmg /L 640 NE665NE Thallium mg/L<00005 0002000180002DissolvedThallium mg i L<00005Bromodichloromethanemg /L Bromoform mg/L Chloroform mg/LDibromoohloromethanemg i LTotalTrihalomethanesmg /L<000250100901 Tritium pCi/L<320<326<314<491<48020,0003,00018,000200%Iodine-131 pCi/L<32 10090100 Cesium-134 pCi/L<18 7567575 Cesium-137 pCi/L<16 11099110 Cobalt-60 pCi/L<19 200180200 Notes: pmhos/cm-mlcromhospercentimeter AL-AlertLevelspecifiedinTable!72-14ofthePermit AQL-AquiferQua htyLimitspecifiedinTable!72-14ofthePermitAWQS-AquiferWaterQualityStandard IAL-IndicatorAlertLevelspecifiedinTable172-10ofthePermit mg iL-milligramsperliterNENotestablishedinthePermit pCi/L-p_cocur_esperliterP\APS-PVNGS',138949-2009AnnualMonandComplReport\Deliverable s\Reports\Flnal\Section1Tables\2009Table1A-2 thru1A-21WQxl s APP-8Page6of20 APS-PVNGS:2009AnnualMonitoringandComplianceReport Analyte AQL pHSpecConductance@25C p mhos/cm24000 NEMonitoronly--- Antimony mg!L<00200 000600054---'DissolvedAntimony mg/L<00200 Arsenic mg/L<00300 0050059 iDissolvedArsenic mg/L<00300 Barium mg/L 0103 218DissolvedBarium mg/L0093!Boron mg/L35403537NENE46-'DissolvedBoron mg/L35404139 Beryllium mg/L<00050000400036---Dissolved8erylhum mg!L<00050 Cadmium mg/L<00200000501DissolvedCadmium mg/L<00200 Chromium mg/L00250263'_019501009DissolvedChromium mg/L<0010<00500<00500 Chloride mg/L810080007,9008,000NENE9252---' Fluoride mg/L25 466--'Lead mg/L<002000050045---*DissolvedLead mg/L<00200 Mercur7 mg/L<00002000200018--DissolvedMercury mg/L<00002 Nickel mg/L0030051301071---_DissolvedNickel mg!L0061O527 Nitrate/NitriteasN mg/L 96 10130---_otass_um mg/L 45 NE49---'DissolvedPotassium mg/L 36 Selemum mg/L0036600501DissolvedSelenium mg/L<00200 Sulfate mg/L 1,400 NE1400---_TotalDissolvedSolids mg!L 15 , 000 NE 21 ,000---Thallium mg/L<000500002O0018___iDissolvedThallium mg i L<00050Bremodlchloromethanemg /L Bromoform mg!L Chloroform mg/LDibromochloromethanemg i LTotalTrihalomethanesmg i L<0002501009'Tntium pCi/L<320<314<471<491200003,0001800020000 Iodine-131 pCi/L<39 10090100 Cesium-134 pCi/L<21 7587575 Cesium-137 pCi/L<22 11099110 Cobalt-60 pCi/L<24 200180200 Not e s
- mhos'cm-micromhospercentimeterA-Reanalysisresultforchromiumwas0311mg
/LALAlertLevelspec ifiedinTable172-13ofthePermitAQLAquiferQualdyLimitspecifiedinTable172-13ofthePermit AW QS-AquderWaterQualityStandardiAL-IndicatorAlertLevelspecifiedinTable17 2-10ofthePerrmt
rng/L-milligramsperliterNE-NotestablishedinthePermit pCi!L-plcocudesperliterI-Forth_suppermostaquiferPOClocatedwestanddown -gradientofthegeneratingunitsAQLsareonlyestablishedforradionuc h desPAPS-PVNGS138949-2009AnnualMortandComplReport\DeliverablesiReports\Final',Sect ton1Tabi es_009Table1A-2thru1A-21WQxlsAPP-9Page7of20
APS-PVNGS:2009AnnualMonitoringandComplianceReport Ar_lyte AQL pH_/SpecConductance@25Cpmhos i cm 3600 NE Mo nitoronly---! Antimony mg/L<00040 000600054__1DissolvedAntimony mg!L<00040 Arsenic mg/L000710050045---_DissolvedArsenic mg/L<00060 Barium mg/L 0212 218--DissolvedBarium mg/L0204 Boron mg/L09710090099NENE12-- JDissolvedBoron mg lL101010096 BeryUium mg/L<00010000400036---'DissolvedBeryllbum mg/L<00010 Cadmium m g!L<00040 000500045---DissolvedCadmium mg/L<00040 Chromium m g/L02070103---DissolvedChromium mg/L<00100 Chloride mg/L10001.000950970NENE1300---' Fluodde mg/L38 446---1 Lead mg/L<000400050048 iDissolvedLead mg ,'L<00040 Mercury mg/L<00002000200018__iDissolvedMercury mg/L<00002 Nickel mg!L0046801011'DissolvedNicke! mg/L 00349 Nitrate/NitriteasN mg!L64 10 9---Potassium mg/L 12 NE12---DissolvedPotassium mg!L 13 Selemum mg/L<000400050045--DissolvedSelenium mg/L<00040 Sulfate mg/L6546 NE64---'TotalDissolvedSolidsmg /L 2000 NE2300 Thallium mg/L<00010000200018---DissolvedThallium mg/L<00010Bromodichloromethanemg /L Bromoform mg/L Chloroform mg/LDibromochloromethanemg /LTotalTrihalomethanesmg /L<0002501009 i Tritium pCi/L<320<314<471<491200003.0001800020000Iodine131 pCi/L<30 10090100 Cesium-134 pCi/L<19 75 6 7575 Cesium-137 pCi/L<17 11099110 Cobalt-60 pCi/L<19 200180200 Notes pmhos lcmmicromhospercen t ime t er_,L-AlertLevelspecifiedinTable172-12ofthePermit&QL-AquiferQualityLimitspecifiedinTable!72-12ofthePermit &WQS-AquiferWaterQualityS t andard IAL-IndicatorAlertLevelspecifiedinTable172-10ofthePermit mg/L-milligramsperliterNE-NotestablishedinthePermit pCi/L-pmocunesperIiter1-ForthisuppermostaquiferPOClocatedwestanddown -gradientofthegeneratingunitsAQLsareonlyestablishedforradionuc h desP_APS-PVNGS138949-2009AnnualMonandComp_Report'_D e l iverables/Reports'_Fmal!Section!Tables_0O9Table1A2th[u1A-21WQxisAPP-lOPage8of20 APS-PVNGS:2009AnnualMonitoringandComplianceReport Anal y t e AQL pH--/SpecConductance@25Cpmhos /cm 5700 NEMonitoro nly---_Antimony mg/L<000400006Reserved--JDissolvedAntimony mg!L<00040 Arsenic mg/L<00060005Reserved--DissolvedArsenic mg/L<00060 Barium mg/L0710 2Reserved---DissolvedBarium mg/L0594 Boron mg/L085089081092NENEReserved_iDissolvedBoronmglL086089095094 Beryllium mg/L<000100004Reserved---'DissolvedBeryllium mgfL<00010 Cadmium mg!L<000400005Reserved---DissolvedCadmium mg!L<00040 Chromium mg/L<0010001Reserved---_DissolvedChromium mg/L<00100 Chloride mg/L180017001,8001900NENEReserved--- Fluoride mg/L29 4Reservedi Lead mg/L00082005Reserved_i Diss olvedLead mg/L<00040 Mercury mg/L<000020002Reserved-- JDissolvedMercury mg/L<00002 Nickel mg!L00 2 5001 Reserved-Diss olvedNick e l mg/L00244 Nitrate/NitriteasN mg/L16 10 Reserved---_Potassium mg/L 21 NE Reserved-DissolvedPotassium mg/L 21 Selenium mg/L<00040005 Reserved---Diss olvedSelenium mg/L<00040 Sulfate mg/L 23 NE Reserved---TotalDissolvedSolidsmg /L3400 NE Reserved--'Thallium mg/L<00010 0002 Reserved_r Oiss olvedThallium mg/L<00010Bromodichlorornethanemg !L Bromoferm mg/L Chloroform mg/L Dibr omochloromethanemg&TotalTrihalomethanesmg /L<0002501Reserved--- Tritium pCdL<320<314<471<49120.0003000ReservedReserved Iodine-131 pCi/L<35 100ReservedReserved Cesium-134 pCi/L<22 75ReservedReserved Cesium-137 pCi/L<21 110ReservedReserved Cobalt-60 pCi/L<22 200ReservedReserved Notespmhosicm-micromhospercentimeterALAlertLevelspecifiedinTable172-11ofthePermitAQL-AquiferQuahtyLimitspecifiedinTable172-11ofthePermitAWQS-AquiferWaterQualityStandard IAL-IndicatorAlertLevelspec ifiedinTable17210ofthePerm{t mg!LmilligramsperliterNENotestablishedinthePermit pCi lL-pieocunesperliter1-ForthisuppermostaquiferPOCAQLswillonlybeestabhshedforradlonuclidesPAPS-PVNGS!138949-2009AnnualMenandComplReport',Deliv erab{es!Reports\Final',SectionITables, 2.OOgTable1A-2thru1A-21WQxtsAPP-12Page9of20 APS-PVNGS:2009AnnualMonitoringandComplianceReport Ana l yt e A Q L pHSpecConductance@25Cpmhos /cm NEMonitoronlyMonitorOnly Antimony mg/L 0006ReservedReservedDissolvedAntimonymg /L Arsenic mg/L 005ReservedRes ervedDissolvedArsenic mg/L Barium mg/L 2ReservedReservedDissolvedBanum mg/L_oron mg/L!9NENEReservedReservedDissolvedBoron mg/L1&Beryllium mg/L0004ReservedReservedDissolvedBeryllium mg;L Cadmium mg/L 0005ReservedReservedDissolvedCadmiummg /L Chromium mg/L0IReservedReservedDissolvedChromiummg /L Chloride mg/L140NENEReservedReserved Fluoride mg/L 4ReservedRes erved Lead mg/L005ReservedReservedDissolvedLead mg/L Mercury mg/L0002ReservedReservedDissolvedMercury mg/L Nickel mg/L01ReservedReservedDissolvedNickel mg/L Nitrate/NitriteasN mg/L t0ReservedReserved Potassium mg/L NEReservedReservedDissolvedPotassiummg /L Selenium mg/L 005ReservedReservedDBsotvedSeleniummg /L Sulfate mg/L NEReservedReservedTotalDissolvedSolidsmg/L NEReservedReserved Thallium mg/L0002ReservedReservedDissolvedThallium mg/LBromodichloromethanemg /L Bromoform mg/L Chloroform mg/L Dibromochl oromethane mg&TotalTrihalomethanesmg /L01ReservedReserved T ritium pOi/L<48620,000ReservedReservedReserved !odine-131 pOi/L 100ReservedReserved Cesium-134 pCi/L 75ReservedReserved Cesium-137 pCi/L 110ReservedReserved Cobalt-60 pOi/L 200ReservedReserved Notes pmhos lcm-micromhospercentimeterAL-,'Ner_LevelspecifiedinTable172-31ofthePermitAQL-AquiferQualityL_mitspecifiedinTable172-31ofthePermit AWQS-AquiferWaterQualityStandardIAL-indicatorAlertLevelspecifiedinTable172-10ofthePermit mg/LmilligramsperliterNENoteslablishedinthePermit pCi iL-p_cocunesperhterP\APS-PVNGS',138949-2009AnnualMonandComplReport\Dehverables\Reports\Flnal\Section1Tables/2009Table1A-2tflru1A-21WOxlsAPP -13Page10of20 APS-PVNGS:2009AnnualMonitoringandComplianceReport Analyte AQL pH NESpecConductance@25CtJmhos /cm NEMonitoronlyNE Antimony mg/L0006Reserved--DissolvedAntimony mg/L Arsenic mg/L005Reserved---'DissolvedArsenic mg/L Barium mg/L 2 R eserved---'DissolvedBabum mg/L Boron mg/L18NENER eservedNEDissolvedBoron mg/L18 Beryllium mg!L0004Reserved---'DissolvedBeryllium mg/L Cadmium mg/L0005Reserved--DissolvedCadmium mg/L Chromium mg/L01 Reserved--DissolvedChromium mg i L Chloride mg/L14000NENER eservedNE Ruorid e mg!L 4 Reserved---_Lead mg/L005 Reserved--)DissolvedLead mg/L Mercury mg/L0002 Reserved-DissolvedMercury mg/L Nickel mg/L01Reserved-DissolvedNickel mg!L Nitrate/NitriteasN mg/L 10Reserved--- Potassium mg l L NE Reser vedNEDissolvedPo tassium mg/L Setenium mg/L005 Reserved-DissolvedSelenium mg/L Sulfate mg&NEReservedNETote}DissolvedSolids mg)L NEReservedNE Thalhum mg!L 0002 Reserved---DissolvedThallium mg/LBTomodlchloromethenemg i L Bromoform mgiL Chloroform mg/LDibromochloromethanemg /LTotalTrihalomethanesmg /L01Reserved--- Tritium pCi/L,:47720000ReservedReservedReserved Iodine-13t pCi/L 100ReservedReserved Cesium-134 pCI/L 75ReservedReserved Cesium-137 pCi/L 110ReservedReserved Cobalt-60 pCi/L 200ReservedReserved Notes pmhos/cmmicromhospercentimeterAL-AlertLevelspecifiedinTable!72-32ofthePermitAQL-Aqu iferQuali tyLimdspecifiedinTable172_32ofthePe r mitAWQS-AquiferWaterQualifyStandard IAL-IndicatorAlertLevelspeclliedmTabie172-10ofthePermit
mg lLmilligramsperliterNENotestablishedinthePermit pCi/L-pieocuriesperlite[ 1-AQLswiflonlybeestablishedforrad_onucltdesPtAPS-PVNGS/138949-2 009AnnualMonandComplReport/Det werables_Reports/FinaliSectionITables'_009Table1A-2thru1A-21WQxlsAPP-14Page!!of20 ..................... _,_,:_r_u_umpl_epor_/uel werables_Reports/FinaliSectionITables'_00aTable1A-2thru1A -21WQxlsAPP-14Page!10f20 APS-PVNGS:2009AnnualMonitoringandCompliance R eport/_nal y te A QL pH NESpeoConductance@25Cpmhoalcm NE Moni toronlyINE Antimony mg l L0006Reserved-- 'D rssolvedAntimony mg/L Arsenic mg/L005 Reserved---DissolvedArsenic mg/L Barium mg/L 2 Reserved---DissolvedBarium mg/L Boron mg/L13NENEReservedNEDissolvedBoron mg/L13 Beryllium mg/L 0004Reserved--JDissolvedBeryllium mg/L Cadmium mg t L0005Reserved--'DissolvedCadmium mg/L Chromium mg/L01 Reserved---DissolvedChromium mg/L Chloride mg!L9.300NENEReservedNE Fluoride mg!L 4Reserved---'Lead mg[L005 Reserved---'DissolvedLead mg/L Mercury mg/L0002 Reserved---Dissolv edMercury mg/L Nickel mg/L0IReserved___T 'Dissolv edNicke r mg/LNitrateJNitrlteasN mg/L t0Reserved-- -Potassium mg i L NEReservedNE DissolvedPotassium mg/L Selenium mg/L005 Res erved--DissolvedSelenium mg/L Sulfate mg/L NEReservedNETotalDissolvedSolids mg/L NEReservedNE Thallium mg!L0002Reserved---'DissolvedThallium mg/L Bromod lchloromethan e mg f L Bromoform mg/L Chloroform mg/LDibromochloromethanemg /LTotalTrihalomethanesmg /L01Reserved-- Tritium pCi/L<47720000ReservedReservedReserved Iodine-t31 pCifL 100ReservedReserved Cesium-134 pCifL 75ReservedReserved Cesium-137 pCilL 110ReservedReserved Cobalt-60 pCi/L 200ReservedReserved Notes pmhos/cm-micromhosperc e ntimeterAL-AlertLevelspecifiedmTable172-33ofthePermitAQL-AquiferQualityLimitspecifiedinTable1 72-33ofth e PermitAWQS-AquiferWaterQualityStandard IAL-IndicatorAlertLevelspec d i edmTable1 72-10ofthePermit mg/L-milligramsperliter
NE-Notestabhshed mthePermit pQ/LpicocuriesperI_ter1-AQLswillon}ybeestablishedforradlonucl_desPAPS-PVNGS!1389492009AnnualMor_andComp J Report',D e hv erablesiReports_Fmal/Section1Tables_0O9Table1A-2thru1A21WQxlsAPP -15Page12of20 APS-PVNGS:2009AnnualMonitoringandComplianceReport Analyte AQL pH NA-AWSpecConductance@25Cpmhos /cm11000110001100011 .000NEMonitoronlyNA-AW Antimony mg iL<00100<00100<00100c0.0020000600054NAAWDissolvedAntimonymg /L<00100<00100<00100<00020 Arsenic mg/L006160060300352003740050145NA-AWDissolvedArsenic mg/L0044400477003040.0378 Barium mg/L0.0178002630016500151218NA-AWDissolvedBari u m mg/L00181002020.012400145 Boron mg/L65671375NE799799NA-AW D lssofvedBoron mg/L65656573 Beryllium mg/L<0.0025<00010<00025<00005000400036NA-AWDissolvedBeryllium mg/L<0.0025<00025<00025<00005 Cadmium mg/L<00100<00100<00100<0002000050043NA-AWDissolvedCadmiummg lL<00100<00100<00100c00020 Chromium mg/L0.0410<00250<00250<0005001009NA-AWDissolvedChromiummg lL<0.0250<00250c00250<00050 Chloride mg/L2,2002,1002,2002,300NE2.4912,491NA-AW Ftuoridemg/L7777876742"4I27NA-AW Leadmg/L<00100<00100<00100<000200.050045NA-AWDissolvedLead mg/L<00100<00100<00100c00020 Mercury mg/L<00002<00002<00002<00002000200035NA-AWDissolvedMercury mg lL<00002<00002<00002<00002 Nickel mglL00327<00250<00250<0005001009NA-AWDissolvedNickel mg/L<0.0250<00250<00250<00050 Nitra te/NilnteasNmglL67_'656266_10653NA-AW Potassiummg/L46453422FNE363NA-AWDissolvedPotassiummg /L42_43_16r'16_ S elenrummg/L00320034100292002570050061NA-AWDissolvedSelenrummg /L0029003280028300257 Sulfate mg/L117001,8001,70011800NE2,868NA-AWTotalDissolvedSolidsmg/L7,5006,8007,4007,600NE7,698NA-AW Thalliummg/L<00025<00025<00025<00005000200018NA-AWDissolvedTh a llium mg/L<00025<00025<00025<00005Bromodichloromethanemg /L E_rom ()for'm mg/L Chloroform mg l L Dibromochloromethan e mg/LTotalTdhalomethanesmg/L<00025<00025<00025<0002501009NA-AW T ntium pCi/L<322<314<467<49120000300018,000NA-AW ledme-131 pOi/L<50<46<30<2810090NA-AW Cesium-134pCitL<18<21<19<2475675NA-AW Cesium-137pCi/L<18<21<18<2211099NA-AW Cobalt-60 pCi tL<18<22<20<22200180NA-AW Notes pmhos/cm-m_cromhospetcentimeterA-Reanalysisresultformtrale initriteasNwas68mg /LAL-AlertLevelspeci fiedinTable172-27o1thePermitB-Reanalysisresultfordissolvedpotassiumwas38mg i L AQL-AquiferQuatityLimitspecif ied_nTable172-27o1thePermitC-Reanalysisresultfordissolvedpotassiumwas43mg /LAWQS-AquiferWaterQualityStandardDReanalysisresultfordissolvedpotassiumwas22rag&IAL-IndicatorAlertLevetspecifiedinTable172-10ofthePermitE-Reanalysisresultfornitrate/nitriteasNwas65mg /L mg iL-milligramsperILterF-Reanalysisresultforpotassiumwas40mg /L NA-AW-AQLsarenotapplicabletoalertwellsandPV-!4H_sanalertwellGReanalysisresultfordisso!vedpotassiumwas37mg /LNE-NotestablishedinthePermit pCi iL-picocuriesperliterPiAPS-PVNGS',138949-2009AnnualMortandComplReport\Deliverables\Reports\Final\Section1Tables\2009Table1A-2t tlru1A-21WQxlsPV-14HPage13of20*"-r.................n_' U l_lrIFId llO_CtlOn_l ao les\zuU£fable1A-2thr u1A-21WQxlsPV-14HPage13of 2 0 APS-PVNGS:2009AnnualMonitoringandComplianceReport An a lyt e A (:I L pH NA-AWSpecConductanc e@25C}Jmhos /cm 22,000 NE Moni torontyNA-AW Antimony mg/L<00200000600054NA-AWDissolvedAntimonymg /L<00020 Arsemc mg/L<00300 0.050045NA-AWDissolvedArsenic mg/L<00030 Barium mg/L003!218NA-AWDissolvedBarium mg/L 0.0052 Boron mg/L52B07156NE662662NA-AWDissolvedBoron mg/L58626460 Beryllium mg/L<00050000400036NAAWDissolvedBeryllium mg/L<00050 Cadmium mg/L<0.020000050086NA-AWDissolvedCadmiummg /L<00020 Chromium mg/L 0.089101009NA-AWDissolvedChromiummg /L<00050 Chtonde mg/L61005,6005 ,9005 ,900NE72207,220NA-AW Fluoride mg/L27 4617NA-AW Lead mg!L<00200 0.05015NA-AWDissolvedLead mg/L<00020 Mercury mg/L<00002000200018NAsAWDissolvedMercury mg/L<00002 Nickel mg/L010601009NA-AWDissolvedNickel mg/L 0.0131 Nitrate/NitriteasN mg/L 260 103399NA-AW Potassium mg/L1388 NE 8.8NA-AWDissolvedPotassiummg /L11_42 Selenium mg/L 0.0753 0050087NA-AWDissolvedSeleniummg /L 0.0063 Sutfate mg/L 2 , 400 NE 4 ,133NA-AWTotalDissolvedSolidsmg /L 15000 NE18,675NA-AW Thallium mg/L<00050 000200018NA-AWDissolvedThalli u m mg/L<00005 Bromodi c hlorometh anemg/L Bromoform mg/L Chloroform mg/LDibromochtoromethanemg/LTotalTrihalomethanesmg /L<00025 0.1009NA-AW Tiitium pQ/L<317<316<493<48020.000300018,000NA-AW Iodine-131 pQ/L<32 10090NA-AWCesium134 pCi/L<21 75675NA-AW Cesium-t37 pCi/L<23 11099NA-AW Cobalt-60 pCi/L<21 200180NA-AW Notes: pmhos icm-micromhospercentimeterA-Reanalysisresult10rdissolvedpotassiumwas12mg /LAL-AlertLevelspecifiedinTab le172-20ofthePermitAQL-AquiferQualityLimitspecifiedinTable!72-20ofthePerm i tAWQS-AquiferWaterQualityStandardIAL.-IndicatorAJertLevelspecifiedinTable172-10ofthePermit mg/L-mi lligramsperliter NA-AW-AQLsarenotapplicabletoalertwellsandPV-193A_sanalertwellNE-NotestablishedinthePermit pCi/L-picoc urtesperliterP_APSPVNGSI138949..2009AnnualMortandComplReport\Detiverables',Rep o rt s\Finar_Section1Tables\200 9Table1A-2thru1A-21WQxisPV-193APage14of20 APS-PVNGS:2009AnnualMonitoringandComplianceReport Ana lyte A QL pH NA-AWSpecConductance@25Cpmhos/cm3300036.00035,00036,000NEMonitoronlyNA-AW An bmony mg/L<00400<00400<00400<00400000600054NA-AWDissolvedAntimonymg /L<00400<00400<00400<00400 Arsenic mg/L<00600<00600<00600<006000.050045NA-AWDissolvedArsenic mg/L<00600<0.0600<0.0600<0.0600 Barium mg/L<00400<00400<00400<004002!8NA-AWD_ssolvedBariummg/L<0.040000!6<00400<00400 Boron mg/L20212323NE25482712NA-AWDissolvedBoron mg iL20222122 Bery!lium mg/L<00100<00100<00100<00100000400036NA-AWDissolvedBeryllium mg/L<00100<00100<00100<00100 Cadmiummg/L<0.0400<00400<00400<0,040000050148NA-AWDissolvedCadmiummg /L<0.0400<00400<00400<0.0400
Chromium mg/L<0100<0100<01000193010.133NA-AWDissolvedChromiummg/L<0.100<0100<0100<0,100
Chloride mg/L7,6008,3008,4009,100NE11,56011,560NA-AW FluoridemglL414348644447NA-AW Leadmg/L<00400<O0400<00400<004000050078NA-AWDissolvedLead mg/L<00400<0.0400<0.0400<0 .0400 Mercury mg/L<00002<00002<00002<0,0002000200024NAAWDissolvedMercury mg/L<0.0002<00002<00002<0.0002 Nickel mg/L<0100<0.100<0100<010001009NA-AWDissolvedNickel mg lL<0100<0100<0100<0!0 0Nitrate/NitriteasNmg/L200200190200103035NA-AW Potassiummg/L15t25021NE1333NA-AWDissolvedPotassiummg/L15A15_51'18E' Selenium mg/L00840!04<01000.1000.050327NA-AWDissolvedSeleniummg /L008700869<010000946 Sulfate mg/L7,6008,4007,9008,600NE9,515NA-AWTota!DissolvedSolidsmg/L280002700028,00029,000NE36,812NA-AW Thalliummg/L<00100<00100<00100<00100000200018NA-AWDissolvedThallium mg/L<00100<0.0100<0.0100<00100Bromodichloromethanemg /L Btomoform mg/L Chloroform mg/LDibromochloromethanemg /L TotalTnhalomethanesmg/L<00025<0,0025<00025<0.0025010.09NAAW TritiumpCi/L<322<319<467<47720.0003000!8,000NA-AW Iodine-131pCi/L<3.9<42<3.2<4.110090NA-AWCesium134 p Q/L<1.8<18<22<2375675NA-AW Cesium-137pCifL<18<17<19<2311099NAAW Cobalt-60 pQ/L<19<!9<2.2<23200180NA-AW Notes pmhos/cm-mieromhospercentimeterA-Reanalysisresultfordissolvedpot assiumwas15mg i LAL-AlertLevelspe cifiedinTable172-28ofthePermitB-Reanalysisresultfordissolvedpotassiumwas78mg /L AQL-AquiferQuatityLimitspecifiedinTable172-28ofthePermitCReanalysisresultfordissolvedpotassiumwas 72mg i LAWQS-AquiferWaterQualityStandard O-Reanalysisresultfo[dissolvedpotassiumwas10mg /L IA L.-IndicatorAlertLevelspecifiedinTabte172-10ofthePermit mg/L-milligramsperliterNA-AW-AQLsarenotapplic abletoalertwellsandPVq95A_sanalertwellNE-NotestablishedinthePermit pC d L-pJcocunesperliterP'_APSPVNGS',1389492009AnnualMonandComp!ReportlDeliverabl e si R eports\Fin al\Section!Tab l es\ e1A-2thru1A -21WQxlsPV-195APage15of20.................._',,_= t-'ufL_ueuveraDles/Ixeports \Final\Section!Tab l es\1A-2thru1A -21WQxlsPV-195APage15of20 APS-PVNGS:2009AnnualMonitoringandComplianceReport Analyte A Q L pH NA-AWSpecConductance@25CIJmhos /cm 9100 NEMonitoronlyNA-AW Antimony mg/L<00100000600054NA-AWDissolvedAntimonymg /L<00100 Arsenic mg!L<001500050045NAAWDissolvedArseni c mg i L<00150 Banum mg/L0047 218NA-AWDissolvedBarium mg/L00536 Boron mg iL37354134373936NE455455NA-AW DissolvedBoron mg/L36374243383637 Bery!lium mg/L<0.0025000400036NAAWDissolvedBerylliummg i L<00025 Cadm ium mg/L<00100000500045NAAWDissolvedCadmiummg /L<00100 Chromium mg/L0208'_0357_0I014NA-AWDissolvedChromiummg /L<00250<00250 Chlonde mg/L220021002.4002400E2800"2,700H2600_NE2,4712,471NA-AW Fluoride mg/L50 468NAAW Lead mg/L<001000050045NA-AWDissolvedLead mg/L<00100 Mercury mg/L<00002000200016NA-AWDissolvedMercury mg/L<00002 Nickel mg/L<002500!009NA-AWDissolvedNickel mg/L<00250 Nitrate/NitriteasN mg/L3741 10425NA-AW Potassium mg/L65_27 NE404NA-AWDissolvedPotassiummg /L57<20 Selenium mg i L<001000050045NA-AWDissolvedSelen_um mg/L<00100 Sulfate mg/L 640 NE701NA-AW TotalDissolvedSohdsmg/L53005600F NE4,782NA-AW Thallium mg/L<0002500020002NAAWDissolvedThallium mg/L<00025Bromodichloromethanemg /L Bromoform mg/L Chloroform mg!LDibromochloromethanemg i L TotalTrihalomethanes mg/L<0002501009NA-AW Tritium pCi/L<320<326<316<491<484<472<49420,0003,00018,000NA-AWIodine-13t pCi/L<42 10090NA-AW Cesium-134 pCi!L<18 75675NA-AWCesium137 pCi/L<16 11099NA-AW Cobalt-60 pCi/L<19 200180NA-AW Notes pmhos/cmmicromhosperc e nt t meterA-Reanalysisresultforchrom_umwas0193mg i LALAlertLevelspecifiedinTabl e172-16ofthePermitB-Reanalysisresultforpotassiumwas53mg /LAQL-AquiferQualityLimitspecifiedinTable172-16ofthePermitC-Reanalysisresultfortotaldissolvedsolidsw as5200mg l LAWQSAquiferWaterQualityStandardD-Reanalyslsresultforchromiumwas0167mg i LIAL-IndicatorAlertLevelspecified inTable172-10ofthePermitE-Reanalysisresultforchlondewas2300mg /L mg iL-milligr amsperliterF-Differetaliquotofsamplehads ameresultsNA-AW-AQLsarenotapplicabletoalertwellsandPV-198ARisanalertwellG-Reanalysisresultforchloridewas2800mg /LNE-NotestablishedinthePermitH-Reanalysisresultforchloridewas2800mg i L pCi/L-p_cocunesperliterI-Reanalysisresultfo rchloridewas2. 700mg/LPAPS-PVNGS\138949-2009AnnualMonandComplRepor t\Deliverables\ Reports\Final\Sect_on1Tables,2OO9Table1A-2thru1A-21WQxlsPV-198ARPage16of20
APS-PVNGS:2009AnnualMonitoringandComplianceReport Analy t e AQ L pH NA-AWSpecConductance@25CJmhos /crn2600026.0002500025 ,000NEMonitoronlyNA-AW Antimony mg/L<00100<00200<00200<00200000600054NA-AWDissolvedAntimonymg /L<00100<00200<00200<00200 Arsenic mg/L00163<00300<0.0300<003000050045NA-AWDissolvedArsenic mg/L<00150<00300<00300<00300 Barium mg/L00338003040045700311218NA-AWDissolvedBarium mg/L00297003350031200280 Boron mg/L1617!618NE29452945NA-AWDissolvedBoron mg/L16181820 Beryllium mg/L<00025<00050<0.0050<00050000400036NA-AWDissolvedBeryllium mg/L<0.0025<0.0050<00050<00050 C admium mg/L<00100<00200<0.0200<002000005004NA-AWDissolvedCadmiummg /L<00100<0.0200<0.0200<00200
Chromium mg/L0231<005000124007520.1009NA-AWDissolvedChromiummg /L<00250<00500<00500<00500
Ch!oride mg/L5 ,5005,5005,7005,600NE83128,312NA-AW Fluoride mg/L4847484484106NA-AW Lead mg/L<00100<00200<00200<002000050045NA-AWDissolvedLead mg/L<00100<00200<00200<00200 Mercury mg/L<00002<00002<00002<00002000200018NAAWDissolvedMercury mg/L<00002<00002<0.0002<00002 Nickel mg/L0.0906<005000.1290069601009NA-AWDissolvedN ickel mg/L00884<0050000911_:00645 Nitrate/NitnteasN mg/L2121171610244NA-AW Potassium mg/L3128!1!6NE1069NA-AWDissolvedPotassiummg /L30A33_14E'16E
Selenium mg/L002020036900537<002000050081NA-AWDissolvedSeleniummg /L002260.03290.0300<00200 Sulfate mg iL6 ,0005 ,9006 ,1006,200NE10,628NA-AWTotalD!ssolvedSolidsmg /L20,000200002000017,000NE23,129NA-AW Thallium mg/L<00025<00050<00050<0.0050000200018NA-AWDissolvedThallium mg/L<00025<00050<00050<00050Bromodichloromethanemg /L<000050 Bromoform mg/L<0.0010 Chloroform mg/L<000050 Dibromochl oromethane mg/L<0: 00050TotalTrthalomethanesmg /L<00025<00025<00025<0002501009NA-AW Tntium pCi/L<326<321<493<48020000300018,000NA-AW Iodine-!31 pCi/L<35<41<36<3310090NA-AW Cesium-134 pCi/L<23<22<18<2375675NA-AW Cesium-137 pCi/L<23<22<19<2311099NA-AW Cobalt-60 pCi/L<25<21<19<21200180NA-AW Notes pmhos icmm_cromhospercentimeterA-Reanalysisresultfordissolvedpotassiumwas35mg i LAL-AlertLevelspecifiedinTable172-15ofthePermitB-Reanalysisresultfordissolvedpotassiumwas23mg /LAQL-AquiferQualityDmitspeci fiedinTable172-15ofthePermitC-Reanalysisresultfordissolvednickelwas00848mg /LAWQS-AquiferWaterQualityStandardD-Reanalysisresultfordissolvedpotassiumwas84mg /L tAL-IndicatorAlertLevelspecifiedinTable172-10ofthePermitE-Reanalysisresultfordissolvedpotassiumwas15mg /L mg/L-milligramsperliterNA-AW-AQLsarenotapplicabletoalertwellsandPV-206A_sanalertwell NE-NotestablishedinthePermit pQ/L-picocunesperliterP,APS-PVNGS',!38949-2009AnnualMortandComplReport\Dellverab_es\Reports\Final\Section1Tables\2OO9Table1A -2thru1A21WQxlsPV206APage17of20 APS-PVNGS:2009AnnualMonitoringandComplianceReport Ana l yte AQL pH NA-AWSpecConductance@25CpmhosJcm 11000 NEMonloronlyNA-AW Antimony mg/L<00100000600054NA-AWDissolvedAntimonymg /L<00100 Arsenic mg/L 00987 0.050159NA-AWDissolvedArsenic mg/L 0.0986 Barium mg/L00532 2t8NA-AWDissolvedBarium mg/L0041 Boron mg/L67697071NE11581158NA-AWDissolvedBoron mg/L70696369 Beryllium mg/L<00025000400036NA-AWDissolvedBeryllium mg l L<0.0025 Cadmium mg/L<0010000050022NA-AWDissolvedCadmiummg /L<00100 Chromium mgJL<0025001009NA-AWDissolvedChromiummg /L<0.0250 Chloridemg;L2,0002,1002,1001 ,900NE27672.767NA-AW Fluonde mg/L118 4241NA-AW Lead mg./L<0.01000050045NA-AWDtssotvedLead mg/L<00100 Mercury mg/L<00002000200018NA-AWD_ssolvedMercury mg/L<00002 N_ckel mg/L<0025001009NAAWDissolvedNickel mg l L<00250N_traletNitriteasN mg/L 75 101245NA-AW Potassium mg/L<20 NE462NAAWDissolvedPotassiummg /L21 Setenium mgJL003910050048NA-AWDissolvedSeleniummg /L00402 Sulfate mg/L 1,700 NE2,355NAAWTotalDissolvedSolidsmg /L 6,600NE9,318NA-AW Thallium mg!L<0.0025000200018NA-AWDissolvedThallium mg/L<00025Bromodichloromethanemg /L Brom o form mg/L Chloroform mg/LDibromochloromethanemg /L TotalTrihalomethanesmg /L<0002501009NA-AW T rit ium pCi/L<317<319<467<47020,0003,00018.000NA-AW Iodine-131 pCi/L<48 10090NA-AW Cesium-134 pCi/L<t8 75675NA-AW Cesium-137 pCi/L<I7 11099NA-AW Cobalt-60 pCi/L<19 200180NAAW Notes: pmhos iem-micromhospe r centimeterALAlertLevelspecifiedinTable172-25ofthePermit
AQL-AquiferQualityLimitspecifiedinTable!72-25ofthePermit AWQS-AquiferWaterQualityStanda r dIAL-IndicatorAlertLevelspecifiedinTable172 -10o1thePermit
mg iL-milligramsperliter NA-AW-AQLsarenotapp hcabletoalertwellsandPV-34HisanalertwellNENotestablishedinthePermit pCi iL-p_cocuriesperliterP',APS-PVNGS',13894.9-2009AnnualMon andComplReport\Deliverables\Reports\Fma!\Secrion1Tables\2OOgTable1A-2thru1A-21WQxisPV-34HPage18of20 APS-PVNGS:2009AnnualMonitoringandComplianceReport Anal yte A (I L pH NA-AWSpecConductance@25Cpmhos /cm12.00013,000!2 , 000 13000 NEMonitoronlyNA-AW Antimony mg/L00066A<00100<00100<00100000600054NA-AWDissolvedAntimonymg /L<00040<00100<00100<00!00 Arsen i c mg/L00079<00150<00150<00!500050045NA-AWDissolvedArsenic mg/L00094<00150<00150<00150 Barium mg/L0.0236002100318 00221 218NA-AWDissolvedBarium mg/L00243002340031000220 Boron mg/L2834'36F33H2930NE3003NA -AWD_ssolvedBoron mg/L292933303330 Beryllium mg/L<00010<00025<00025<00025000400036NAAWDissolvedBeryllium mg/L<00010<00025<00025<00025 Cadmium mg/L<00040<00100<00100<00100000500045NA-AWDissolvedCadmiummg /L<00040<00100<00100 <00100 Chromium mg/L0041!00569<00250 <0.02500103NAAWD_ssolvedChromiummg /L<00100<00250<00250<00250 Chloride mg/L3,2003,1003,10029003000NE3,7553755NA-AW Fluoride mg/L282929 278 4443NA-AW Lead mg lL<00040<00!00<00100<001000050045NA-AWD_ssolvedLead mg/L<00040<00100<00100<00100 Mercury mg/L<00002<00002<00002 <00002 000200018NA-AWDissolvedMercury mg/L<00002<00002<00002<00002 Nickel mg/L00343005700043300260010197NAAW D issolvedNickel mg/L00649004860041900322 Nitrate/NitriteasN mg/L495050 49f0569NAAW Potassium mg/L74_11E3116_NE439NAAWDissolvedPotassiummg /L758828 16 Selenium mg/L0030200456E00476_ 0.03660050045NA-AWDissolvedSeleniummg iL00389003440041800411 Sulfate mg/L2,2002,2002200 2.100 NE2,745NA-AWTotalDissolvedSolidsmg /L8 ,4008,9008,700 8500 NE9656NAAW Th a llium mg/L<00010<00025<00025<00025 000200022NA-AWDissolvedThallium mg/L00012<00025<00025<00025Bromodichloromethanemg /L<000050 Bromoform mg!L<00010 Chloroform mg/L<000050Dibromochloromethanemg /L<000050 TotalTrihalomethanesmg /L<00025<00025<00025 <0002501009NA-AW Tritium pCi/L<326<316<493<480<49420.0003 ,00018000NA-AW Iodine-131 pCi/L<43<43<30 <32 10090NA-AW Cesium-t34 pCi/L<22<22<19 <22 75675NA-AW Cesium-187 pCi/L<21<21<20<23 11099NA-AW Cobalt-60 pCi/L<2I<20<20 <22 200180NA-AW Notes: pmhos/cmmicromhospercentimeterA-Reanalysisresultforantimonywas00052mg /LAL-AlertLevelspec rfiedinTable17217ofthePermitBReanalysisresultforpotassiumwas82mg /LAQLAqu iferQualityLimitspec ifiedinTable172-17ofthePermitC-Reanalys_sresultforboronwas29mg /LAWQS-AquiferWaterQualityStandardD-Reanalysisresultforpotassiumwas82mg /LIAL-Ind icatorAlertLevelspecifiedinTable172-10ofthePermitE-Reanalysisresultforseleniumw as00422mg/L mg/LmilhgramsperliterF-Re analysisresultforboronwas3.2mg /LNA-AW-AQLsarenotappt tcabletoalertwellsandPV-Q8is a n alertwellG-Reanalysisresultforseleniumwas00344mg /LNE-NotestablishedinthePermitH-Reanalysisresultforboronwas32mg /L pCi/L-picocur*esperliterI-Reanatysisresultforpotassiumwas!9mg /LP\APSPVNGS\138949-2009AnnualMonandComp JReport\Deliverables\Reports\Final\Sectlon1Tables\20O9Table1A-2tnru1A-21WQxlsPVQ8Page19of20 APS-PVNGS:2009AnnualMonitoringandComplianceReport Ana l yte AQL pH NA-AWSpecConductance@25Cpmhos /cm 17,000 NEMonitoronlyNA-AW Antimony mg/L<00200 0.00600054NA-AWDissolvedAntimonymg /L<00200 Arsenic mg/Lc003000050045NA-AWDissolvedArsenic mg/L<00300 Barium mg/L0105 2!8NA-AWDissolvedBarium mg/L00620 Boron mg/L13f41413NE222222NA-AWDissolvedBoron mg/L13121515 Beryllium mg/L<00010000400036NA-AWDissolvedBerylhummg /L<00050 Cadmium mg/L<00200000500045NA-AWDissolvedCadmiummg /L<00200 Chromium mg/L0081901009NA-AWDissolvedChromiummg /Lc00500 Chloride mg/L4.500510050004800NE5,8125812NA-AW Fluoride mg/L31 446NA-AW Lead mg/L<002000050045NAAWDissolvedLead rng/Lc00200 Mercury mg/L<00002 000200018NA-AWDissolvedMercury mg/L<00002 Nickel mg/L0073301009NAAWDissolvedNickel mg/L<00500 Nitrate/NitriteasN mg!L 27 1040.8NA-AW Potassium mg!L13_'NE 78NA-AWDissolvedPotassiummg /L 12 Selenium mg/L002920050045NA-AWDissolvedSeleniummg !L00234 Sulfate mg/L 1100 NE1342NA-AWTotalDissolvedSotidsmg /L 9, 7 00 NE14,284NA-AW Thallium mg/L<00050000200072NA-AWDissolvedThallium mg/L<00050Bromodichtoromethanemg /L Bromoform mg/L Chloroform mg/LDibromochloromethanemg /LTotalTnhalomethanesmg /L<0002501009NA-AW Tntium pCi/L<322<314<460<48920,0003 ,00018000NA-AW Iodine-131 pCi/L<49 10090NA-AW Cesium-134 pCi/L<23 75675NA-AWCesium137 pCi/L<22 11099NA-AW Cobalt-60 pCi/L<22 200180NA-AW Notes: IJmhos/cm-micromhospercentimeterAReanalysisresultforpotass tumwas61mg i L AL-AlertLevelspecifiedinTable172-29ofthePermitAQL-AquiferQualityLimitspecifiedinTable172-29ofthePermitAWQSAquiferWaterQualityStandardIAL-Indicato rAlertLevelspecifiedinTable172-10ofthePerm f t mg/L-m_lligramsperliterNA-AWAQLsarenotapplicabletoalertwellsandPV-R2ARisanalertwellNENotestablishedinthePermit pCi/L-p tcocurlesperliterPiAPS-PVNGS_138949-2009AnnualMortandComplR e pomDeli verables\Reports\Final\Sectton1Tables',2OO9Table1A-2thru1A-21WQxlsPV-R2ARPage20of20 1.GroundwaterMonitoring2009AnnualMonitoringandComplianceReportAPPNO,P-1003881.GROUNDWATERMONITORING B,, T I RENDSiNGR O U NDWATERC H EM I S T RYIn_cc(_rdancewithS ection14.4.1.A.l.boftheP ernlit,generalizedtrendsinindicatorparam etersaresummarizedinTable1B-l.Asthetableshows,theindicatorparametertritiumwasnotdetectedinanyof-thcwellss: m_pledduring20(19.Th egeneraltrendsf-ortherein:liningindicatorpar:tmetersboron:_ndchloridewereess entiallythesameascomp:tredtopreviousyears.I;or2009,th eonE"wellsampledthatexhibited_mincreasingtrend forBoronwasPV-34FI.kS'ellsthfltexhibitedanincreasingtrendforchloridewere ,\Pl).3,,\PP-4R,APP12,PV-I4fl,PV-193 A,PV19BAR,PV-34H,PV-QS,andPV-R2 AR.Chlorideconccntrati(msintheshallowaquif eratth ePVNGSsiteareknowntobehighandgenerffll.vhavebeenattributedtohistoricalagricultur_lactivitiesconductedatthesitepriortotheBuildingofthePVNGS. APS-PVNGS2009AnnualMonitoringandComplianceReport W e l l ID Tr it ium Bo r o n C h lor i deAPP-3Nochange-NDNotrend IncreasingAPP-4RNochange-NDNotrend IncreasingAPP-5Nochange-NDNotrendNotrendAPP-6Nochange-NDNotrendNotrendAPP-7Nochange-NDNotrendNotrendAPP-8Nochange-NDNotrendNotrendAPP-9Nochange-NDNotrend DecreasingAPP-10Nochange-NDNotrend DecreasingAPP-12Nochange-NDNotrend IncreasingAPP-13Nochange-NDNotrendNotrendAPP-14Nochange-NDNotrendNotrendAPP-15Nochange-NDNotrendNotrendPV-14HNochange-NDNotrend IncreasingPV-193ANochange-NDNotrend IncreasingPV-195ANochange-NDNotrend DecreasingPV-198ARNochange-NDNotrend IncreasingPV-206ANochange-NDNotrend DecreasingPV-34HNochange-ND Increasing IncreasingPV-Q8Nochange-NDNotrend IncreasingPV-R2ARNochange-NDNotrend Increasing Note._: ND-Notdetectedabovethe la bor a tory reportlhg/imit,P:_APS-PVNGS\138949-2009AnnualMonandComp!Repod\Deliverables\Reports\Final\Section1Tables\2009Table1B-1TrendsxlsPage1of1 1.GroundwaterMonitoring2009AnnualMonitoringandComplianceRepor tAPPNO.P-1003881.GROUNDWATERMONITORINGC,, N O ICA T OR PA R AMETERCONCEN T RA TIONC O N T OUR_AP S, ANDA LL E X CEEDANCES V ER I F I EDD U R I NG T HEONEoYEARRE P OR T ING P ERlO D Scc thm14.4.1.A.l.c()fthePermitrequeststhatannualreportsincludeindicat(_rparameterconcentrati(mcont(_urmaps.Sincethesiteiscomposedofmultiplelevelsofsaturationresultingfrominfiltration(_f e xcessirrigati(mwaterwhenthesitewasactiv elyfarmed,andbasedontheheter()gen eousnature(>fthesiteg e (>l(_g)', thereisahighdegreeofbothspatial_mdtemporalwtriabilit\ininorganicwaterquality.Thesecharacteri s tics rcsuhmh_calizedwaterlevelandwaterqualit T c(mditi(ms.Thewaterqualityresultsinparticulararenotamenabletocontouring,norwouldtheresultsbetechnicallymeaningful.Therefore,ratherthanprcparc c(mtourmaps(_findicatorparameterconcentrati(ms,selectedquarterlydataforboronandchloridetna\'ebeenpresented{}nI;igures2and3,respectively. ,\sshownont
- igure2,quarterl?
'boronconcentrationsintheregionalwells(APP-3andAPP-6)were1.3and1.4milligramsperliter(rag /L)throughout2()09.Quarterl)boronconcentra tionsinthePaloVerdeCla\aquift_rwellsin2(1()9rangedfr(ml{/.58to2.2rag /l_Fortheshallowaquiferwells,boronc(mccntrationsvariedfromlessthan1mg /LatAPP-12,andupto23mg /LatPV-195A.
- \ssh(_wn_mI
- igure3,quarterlychloridcconcentram msintlneregionalandPal(_VerdeClayaquiferwellswerewithinthesameorder(}fmagnituderangingfrom120to630mg
/l,.Chlorideconcentrationsintheshallowaquif_rwellsw_'reapproximatelyon e(}rderofmagnitudehigher,rangingfr(}m950mg /La tAPPllJ up u_14jill!!mg /l.atAPP-14.l.aborat{}rvanalyticalresultswerecomparedt_thewell-specific
- \LsandAQLsspecifiedinthePermit.l
- {_r 2()()9,11)wellshadatleast(meverifiedexceedanceofanAI
,Allverifiedexceedancesofgroundwaterqualitypermitlimits(Al.sand /()rAQLs)arepresentedinTable1C-1.
Z©_oooo_oooooo________ 0_O___l_--0000 .oo......_________________1___oo_oo__OOo oool o_o 0 000 0 O0 O0 O0 000_______oooooooooooo0oo__0____o g______Z0000 000_____"_"_"___!_____"__"___o'-......__'_c__c_"_"_______ooo___....00_O I 0 0 _o_______._____:_____o_____.______.___-__-o_-_o___o_ ,__o_r_]CD_CD--o_.__ooo rn_-_F-"-- 1,GroundwaterMonitoring2009AnnualMonitoringandComplianceReportAPPNO.P-1003881.GROUNDWATERMONITORING QU A R T ERLYSHALLOWGR OU N DWATER 'APSAND ANN U AL RE GIONAL G R O UND WATEREQUlP OTEN T t f AL rVIA P SCont_ursofth eshallowwaterleveldatahavebeencompletedforeachquarterof2()()9andarepres entedonFigures4through7.Contoursofwaterlevelsf(_rthePaloVerdeClayaquiferhavealsobeencompletedfi)reachquarterof2009andarepresentedonFigures8through11.Thegroundwaterelevationc(mt(mrswcrcdevelopedusingthecomputerprogramSurfer.Minorhanddrawneditshavebeenmadetocertainareasbasedonhistoricalwaterleveldataorinterpretation.Thisapproachisconsideredappropriateforthedataset utilized,andthewaterleveldataalsoreflectsthesubsurfaceheterogeneity.Ingeneral,theshallowwaterlevelelevationmapsfi)r20I)9remainconsistentwithhistoricalshallowgroundwaterelevationmaps.InSection14.4.1A.ldofthePermit,thecompletion{_faRegionalGroundwaterequip_tentiaimapisals(_ requested.Based<)nthenumberofwells,thewaterlevelcomplexitiescreatedfromhistoricalon-sitepumping,currentoff-sitepumping,anddifferentwellcompletiondepths,contouringoftheregi<malaquifer waterlevelelevationdatawasn<_tcompleted,norisitconsideredtcchnical h'advisable.Historically,based(m regionalaquif erwaterleveldatacollectedbothonandoffsite,ithasbeenshownthatregionalaquiferflow directionsaretothesouth /southwest.Thisflowdirectionissimilart_)thenaturalprePk"NGSgr<mndwatcrflowdirectionwiththecurrentflowgradientlargelycontrolledbypumpingintheCentennial\\'ashareat() thesouth/southwest ,andpumpingbyDukeEnergytothesouthofthePVN(;Sproperty.Thewaterlevelelevationdatacollectcdfortheregionalaquiferwells(APP-3,APP-6 ,andPV-216R)hasbeenpr<_videdinTable1,\1andp(_stedonFigure12.AsthedatapostedonFigure12indicates,thegeneralgr<_undwaterflowdirectionist(_thesouth /southwesttitpresent.H)-drographsf{)rthemonitoringwellslistedinTable17.234ofthePermitareprovidedinFigures13 thr_mgh54withtheexceptionofthefi4lowingwellsforthestatedreasons:,\PP-Iwasdrythroughout2009andhasbeendrysince2004.PV191Awasdr)through_ut2009andhasbeendrysince1985.'.PV2{)7Awasdr)"throughout20(19andhasbeendrysince1988. 1,GroundwaterMonitoring2009AnnualMonitoringandComplianceReportAPPNO.P-1003881.GROUNDWATERMONITORING P ROVIDE T DS ANDCHLORIDECONCEN T RA T ION CON T OUR MAPSF O R T HE SH ALL O W A Q U IFERON A B iE NN iALBASISSection14.4.1.
- \.l.eofthePermitrequeststhatannualreportsincludeTDSandchlorideconcentrationcontourmapsfortheshallowaquif eronabiennialbasis.Sincethesiteiscomposedofmultiplelevelsofsaturationresultingfrominfiltrationofexcessirrigationwaterwhenthesitewasactivehfarmed,andbasedontheheterogeneousnatureofthesitegeology,ther eisahighdegreeofbothspatialandtemporalvariahilitvininor,_amcwaterquality.Thesecharacteristicsresultinlocalizedwaterlevelandwaterqualityconditions.Thewaterqualibresultsinparticulararenotamenabletocontouring,norwouldtheresultsbetechnicallymeaningful.Therefore,ratherthanpreparecontourmapsofTDSandchlorideconcentrations,s e lect e dbiennialdataforTDSandchloridehavebeenpresentedonl;igures55and,3,respectiv e ly.BiennialTDSdatacollectedfromtheshallowaquiferwellsin2008anddiscr etionaryTDSdatacoll ectedfr(matheshallowaquif erw ellsin20il9areshownonI
- Jgure55.BiennialTDSconcentrationsintheshal h)waquiferwellsrangedfrom3,4()
()mg/l_atAPP12upto27()0()mg/LatPV-195A.;\sstatedinSection1.Cofthisreport,achlorideconcentrationmapisprovidedas Figure3.Thefigureincludesquarterlyresultsfortheshallowaquiferwells,Palo\"erdeClayaquiferwellsandtheregionalaquiferwells.In 2()()0,chlorideconcentrationsintheshallowaquiferwellsrangedfrom950mg /l.at:\PP1()upt(J14,()()()mg /l.atAPP14. 2,ImpoundmentMonitoring2009AnnualMonitoringandComplianceReportAPPNO.P-1003882.IMPOUNDMENTMONITORINGLCRSSUf 4 1 P MONlTOR)NGRESULTSTheleakc(41ectionandrecoxcrysystems(I,CRS)associatedwiththefacility'simpoundmentsaremonitoredonadailybasisfi )rthepres enceof fluid.TilefidlowingI,CRScomponentsaremonitorcdinaccordancewithTables17.23 , 17.2-5 ,17.28and17.2-0ofthePermit:Three_umpsatthe85-acreWSR
- Twosumps(northandsouthcollectionsumps)atthe45acreWSR;TwosumpsatEvaporationPond1;TwosumpsatEvaporationPond2Aand p,v (_sumpsatEvaporationPond2B
/2(Ibuttheseimpoundmentswereunderconstructionthr{mghout2009;andTwosumpsatEwtporationPond3Aandp,vosumpsat}'_vaporationPond3B.Thet (_taldaih'volumesofwaterpumpedbysumpsatthe45-acreWSRandl-{vaporationP (md1didnotexceedthe,\1_specifiedinthePermit.However,therewasoneexceedanceofanAI.basedonthevolumepumpedbySump2ofthe85-acreWSRonNovember24,2(109.Asstatedinthefive-daywrittenn ()tificati_,n letter,datedDecember3,2009,32,617gallonswerepumpedfromSump2onNovember24, 2009,whichexceedstb,e i\I Aof17,66(/gallonsperday.ThevolumepumpedbySump2didnotexceedthei\12of 577,655gallonsperday.MoreinformationonthisexceedanceisprovidedinSection2D. Evap (,rati,mP_md2wasemptythroughout2009.Therefore,nowaterwaspumpedbythesumpsassociatedwithEvaporationPond2.Dail)monit_ )ringwasconductedatbothsumpsatEvaporationPond3,\throughout200%dailym (mit (Jring ()fbothsumpsatEvaporationPond3BbeganonJune9,20{)9,whenthepondwasputint{ )service.Thet{_taldaih'volume ()fwaterpumpsbyEvaporationPond3A'sand3B'ssumpsdidnotexceedthe\l_s specifi edinthePermit.Asummarytablcofdailysumpmonitoringactivitiesconductedin2009isprovidedmTable2A-1.
z_E 0 C C C 0 C c!_oNNoN@N mx_@@N@ooooo _,_,__,__,_i°i°___ooo;oooooo'Oooooooooooom_______=ooooooooooooooooo_oooooooooo _g c%©> z_<_.E 0 ocococo N N__oi-__N___ooooooooooooooooooooooooooooo__oooo_,oooooooooo_oooooooooo_ommmc ocommc ocococococotommcommcomcoco u_coc o m_"_0 a 2____,_______ _g c I1)g_N_0 a_¢ z_,,o gnCOc'-13_m a_<_.E O O 7O r" C C O r" t-" o">,.-----Ooioc ,o_°ooooo_Ooo ,_ooooooooooooooooo,-_No°o°°°°°°i°°oo _=o,.o ,.ooo.,!oo°°o°o°°o°o°o°o°°°°o°o°o°NNN°°Nooo oo£_,:,o_,_o ,.o r-..-o o--,-_,._coco ,.oo ,..oco_,..---I, , ,--'_, i'o4'e-_-'o-_",---!..- -'0 o-'c4',,_-'c.4_'c4'_.-o- ',.--'0o-'c.__., o*<.,_*_..o-,_._._,.._.-,._*_,__._..4 , ,:,_.]*, ,_: ,i ,,_.<o'="_, o°o°oooo°oooooo°O°°Oo°°°o_° "_._C:'C)_OC',, I<:_OO E m_'_I_.._00000000000000000000000000000000"_ "-_8*m_g N_N_c CO o5 13_O_
GO z_0__GOc m0__o_E 0 o"o c c o c 0 c c Z00__oooooooooooooooo oooooo oooooo___00000000000000_0000000O0000000 ,_,--°:__.__.o_._._._._._._.___.o_._.o_-.oo_.o._.o_.o_-._'o_'04.......co............ m_.OooooOOooOoooo°°o°°oooo°ooooo ,,_-u__o___ooo_oooooooooooooooooooooooooo m g o_©7 13_
©o.z_COc13.._a_<_.E o 0"O*-113 C o C 0 c Cx__ooooooooooooooooo o c mN7 m g c©u 5 z_>a___E 0 0c__"_"-oooooooooooooooo __°oo_CM"-__ooooooooo,ooooooooooooooooooooowJ_r-,'"--
_o z_0_m 0..n E 0 o 2°'`'_r-_-_--'°00°°00ooooooo0oooooooooooo..$--__-__°°°°oooooooooooooooooooooooooo"__"h'_ZZZZZZZZZZZZZZZZZZZZZZZZZZZZZZ S_'_zz_'_zzzzzzzzzzzzzzzzzzzzz_,-_cao_or-___.....______CO'o_I.__ZZZZZZZZZZZZZZZZZZ_ 000030303030"30303'09 _____°°°°°°°_°°°°°°°°°N°°°°°°°°_°_oooo _o_=o_.==0oo_o ,oo_oooo°_oooooooooooooooooo 00 o 0_c k
z__c_E 0 C C 0 c 0 C C o_LO_O____,_,_,_,_,_,_,o,_,o,__,ooo,_,_,_,_,_,Q,o,_______m g% z_" s:>a.__nm_<_.Q-E o o O000000000 O00000000000 O00CCjO0O0_o o 2?o__°°°°°°°°°°°°°°°:°°°'°°°°°°°°°°_o_ °=ooooooooooooooooooooooooo_Oooooo-N_z>c k c b CL _g Nooooooooooooooo__ooooog_g N_N_z d_c_¢Ck z_>E o (D.__-___ooooooooo o oooooooooooooooooooo__°°2 e,l_0 oooooooo c__oo=__o_°0_oeooooo_o oooo_oo_ooo ooo.-- x__'_'_'_'_'_r_'_'_'_i_____ __'_'_'_1_ _________1_'_'_'_'_ __o_iooo;ooooo_ooooo_oo_'ooooo_oo,oo s N___oooooooooooo,ooooo'_,_o_ _--,=oo,__oooooooo g
_ocoo_z_>13__E o o_"I,L l000000000000000000000000000000C. oooo ooooooooooooooooooooooooooo_o 0000000000000000000000000000000 o rxlI_°°o0como0coo0cocococoo0o0o0cococ0cocoo_commmm e?___NNNNNNN_NNNNNNNNNNNNNNNNN_NNNNNN _N C 3 g (D m_°_=_°°°°°°°°°°°_°°°°°°°°°°°°°°°°°°_.o_< _@co t-_z_>c&o_0_ z_>_mc g E 0 C c C o C Cxm g c m©>N z_E 0"_0____00000 c 0_oooooooooo_oo___oooooooooo_oooooo_o__0o_=oo_ooooooo_oooooo_ o_____oooo_ooooo___zzzzzzzz________ _i oE_ooo_000000 ooooo o oooooooooooooo o_ooooo_ooooOO ____o_ooooooooooO o ,-@ 2ImpoundmentMonitoring2009AnnualMonitoringandComplianceReportAPPNOP-1003882.IMPOUNDMENTMONITORINGBSUM_, ,_AR_ESOFANA LYTlCALRESULTSWatersampleswerecollectedfromEvap()rationPond1atthefrequency'requiredbythePermitandanalyzedfortheparameterslistedinTable17.2-7ofthePermit.F()r2009,theannualsamplefromF_vap()rati(mPond1wascollectedon December15 ,2{)09.NoneoftheAl,sspecifiedinTable17.2-7wereexceededin20!19.Forradionuclides,weeklygrabsamplesfromI-
- _vaporationPond1werecompositedonaquarterlybasisand analyzedfortheindicatorparameterslistedinTable17.2-7ofthePermit.TritiumwasdetectedinallofthequarterlywatersamplesfromEvaporationPondl.Iodine-1 31wasdetectedin[
- _vaporationPond1quarterlywatersamplescollectedinJanuaryand July20{19.NoneoftheALsspecifiedinTable17.2-7wereexceededin2()()9.Summarytables_fthewaterqualitydatafor[{vaporationPond1for2009areprovidedinTables2B1and2B-2.\X'atersampleswerenotcollectedfromEvaporationPond2becauseitwasempty'fi}rre-lining.Thediss()lvedb(}ron,chloride,fluoride,anddiss{}lvedpotassiumconcentrationsdetectedintheEvap{}rationPond1samplecollectedin2{}09aresimilart{}previ()usyears.Tablesc{}mparin£2!}{!9waterqualitydatat(}historicalevaporationpondwaterqualitydataarepr(}videdasTables2B-3and2B-4.
APS-PVNGS:2009AnnualMonitoringandComplianceReportAlertLevel Analyte Units 1 2/1 5/09(Table17.2.7ofthePermit)Antimony(dissolved) m_/L<0.1NEArsenic(dissolved) mg i L<0.25 NEBeryllium(dissolved) mg/L<0.05 NE Boron mg/L33/36(D)NECadmium(dissolved) mg/L<0.05 NEChromium(dissolved) mg/L<0.15 NETotalAlkalinity mg/L 440 NE Chloride mg/L 41,000 NE Fluoride mg/L 27 NE pH SU 8.8<4,>11 Potassium mg/L2,300/2,500(D)NELead(dissolved) mg/L<0.05 NE Nickel m£t/L0.45/0.35(D)NE Nitrate/Nitrite mg/L 480 NESelenium(dissolved) mg/L<0.25 NE Sulfate mg/L 22,000 NE Thallium mg/L<0.05 NETotalDissolvedSolids mg/L t00,000 NETotalTrihalomethanes mg/L 0.017 NE Calcium mg/L820/810(D)NE Magnesium mg/L240/290(D)NE Sodium mg/L37,000/37,000(D)NECationAnionBalance %2.3 NE Notes:<-Lessthantheindicatedreportinglimit.(D)-Resultisfordissolvedmetal rag/L-milligramsperliterME-NotestablishedSU-StandardUnits P:_APS-PVNGS\138949-2009AnnualMon.andC ompl.Report\Deliverables\ R eports\F i n al\Section2Tables\2009Table2B-1and2B-2WQ.xlsTable2B-1EP1NonRadPage1of2
2.ImpoundmentMonitoring2009AnnualMoni toringandComplianceReportAPPNO.P-1003882.IMPOUNDMENTMONITORINGCSUrv_MAR YOFM A[N TE NANCE ANDRE PAIRAC T iViTiES Maintenance _ndrepair_tctivitiesfortheimpouncimcntsaredocumentedinthefacilitylogbo()kin_lccordancewiththePermit.5Ionthlvinspectionsofeachimpoundmentareconductedtoevaluateimpoundmentlinerintegrit y(tears,punctures,crflcks,deformities,orotherdamageduetosunlight,wind,weather,debris,vegetation,animals,orotheradverseconc{itions). ,-\tablesummarizingmaintenanc e_mdrepairactivitiesin2009isprovidedinTable2C-1. .....II: l_, x , , , l z_zo,_T'_I__,,7_1.1-.......
z_<_C D g:m#o__-g_o_g 2.ImpoundmentMonitoring2009AnnualMonitoringandComplianceReportAPPNO.P-100388 2.IMPOUNDMENTMONITORING
SUMMARY
OF THERESUL TSOFALLL INER L E A KAGEIngen eral,thesumpsassociatedwiththewaterstoragereservoirsandevaporationpondspumpedintermittentlythroughout2009.In2009,noneofthe ,'\l_swerecxceededatthe45-acre\\'SR,EvaporationPond1,andEvaporationPonds3Aand3B.However,thercwasoneexceedanceofanAI_basedonthevolumepumpedbySump2ofthe85-acreWSRonNovember24,2(109.Asstatedinthefive-daywrittennotificationletter,datedDecember3,2009,32,617gallonswerepumpedfromSump2onNovembcr24,2()(!9,whichexceedstheAI A_Jf17,660gallonsperday.Volumespumpedonsubsequentdayswerebelow the:\lJof17,66(!galhmsperday.APSbegandroppingthewaterlevelinthe85-acreWSR_mN_vember1 ,2(){)9,priortotheAI,1exceedance.The85acre\X'SRwasabout10percentfullonNovember24aswaterwastransferredtothe45-acreWSRbymeansofpumpst-loatingonbarges.Itisbelievedthatoneofthe bargesmadecontactwiththeliner,causingatearthatresultedintheincreasedf lowtoSump2.Thev_>lumcpurnpedb\Sump2didnotexceedtheAI,2of 577,655gallonsperday.AssummarizedonTable2C-1 ,maintenanceandrepairactivitiesoccurredatthe85-acrereservoirandKwlporationPond1duringthereportingperiod.Repairswcremadet<_allindicatedand_bscrvedliner defects.....il: u.1.,._,_, ,_1 L,.:Lvi_1=.... 2.ImpoundmentMonitoring2009AnnualMonitoringandComplianceReportAPPNO,P-1003882.IMPOUNDMENTMONITORING £.
SUMMARY
TA B LESOFA LLBASlN_iM P OUNDMEN T;AND RESE R V O I R D A TAWHICHA LLOWSDA T A TOBEREADILY COM PAR ED TO LE A K A GEA NDD I S CHARGEDUA L I T Y A L ERT L E V E LSA N D P RE V IOUS D A T A,\summarytableofmonthlyflowmeteringresultsfor2009isprovidedinTable2A-1.CumulativeinorganicandorganicdataforEvaporationPonds1and2areprovidedinTables2B3and2B-4.Theonlye ,;tablishedalertlevelsforevaporationpondwaterqualityaref_rpHandradionuclidesanddatahavenote::ceededthe,\ L s.AsummaryofflowstothewaterstoragereservoirsandtotheevaporationpondsisprovidedinTable2b_-1. [: 1 i[,l" ,'lil_l@1;t'2i: -]b
3.SludgeMonitoring2009AnnualMonitoringandComplianceReportAPPNO.P-1003883.SLUDGEMONITORING__,LtJDG_LANDFI LLMONITORINGANA L Y T ICA L RESULTSSludgefr(_mthe\\_RFisrecluJredto 1)m c h:-tracterizedthroughrepresentatives,wnplin_on:tsc n lJ-_mnu_[lb_tsis. In 2{)()9,\VR[;sludgesampleswerecollectedin]uricandOctoberandanalyzedfortheparameterslistedinTable17.2-4ofthePermit .Toxicity(;h:_racteristiel_eachingProcedure(TCI,P)metalswerenotdetectedabovethelab(_rator)reportinglimitsintheWRFsludgesamplescollectedin 2009,andnoneoftheALswereexceeded.,\summfuvt;_bleoftheIaboral(_rv_malvticalresultsfor\\RFsludges;lmplescollectedin2(/09ispr_ widedinTable3A1 .l:_l,l',,l_0F!{il',,i:i!_ APS-PVNGS2009AnnualMonitoringandComplianceReportAlertLevelUnits06 1 11/0 9 10 1 27 109(Table 17.2.4o fthePermit) pH SU 9.7 9.5<2,>12.5 Arsenic mg/L<1.0<1.0 5.0 Barium m_/L<5.0<5.0 100.0 Cadmium mg/L<0.50<0.50 1.0Chromium(total) mg/L<1.0<1.0 5.0 Lead m_i L<1.0<1.0 5.0 Mercury mg/L<0.0020<0.0020
0.2 Selenium
m_i L<0.50<0.50 1.0 Silver mg/L<1.0<t.0 5.0 Notes:MetalsanalyzedbyToxicityCharacteristicLeachingProcedure(TCLP).<-Lessthantheindicatedreportinglimit. mg/L-milligramsperliterSU-StandardUnitsP:/APS-PVNGS\138949-2009AnnualMonandCompl.Report\Deliverables\Reports\Final\Section3Tables\2009Table3A1xlsPage1of1 3.SludgeMonitoring2009AnnualMonitoringandComplianceReportAPPNO.P-1003883.SLUDGEMONITORING ,COOLINGTOW ERSL UDGEANALYTICALRESULT SCoolingtowersludgeisrequiredtobecharacterizedpriortodisposalintheSludgeDisposal Landfill,onaperdisposaleventbasis. Fourcoolingtowersludgesamples(canalandeachofthethreetowers)werecollectedfromeachunitin2009:'SamplesfromUnit1werecollectedinFebruary2009.In2009,anestimated216cubicyardsofcoolingtowersludgefromUnit1wasdisposed.SamplesfromUnit3werecollectedinAugust2009.In2009,anestimated326cubicyardsofcoolingtowersludgefromUnit3wasdisposed.SamplesfromUnit2werecollectedinDecember2009.CoolingtowersludgefromUnit2wasdisposedin2010;therefore,theestimatedvolumewillbeprovidedinthe2010AnnualMonitoringandCompliance Report.AllcoolingtowersludgesampleswereanalyzedfortheparameterslistedinTable17.2-4ofthePermit. TC LPmetalswerenotdetectedabovethelaborato Ureportinglimitsinthecoolingtowersludgesamplescollectedin2009,andnoneoftheALswereexceeded.Asumma ry,tableofthelaborato ry analy ticalresultsforcoolingtowersludgesamplescollectedin2009isprovidedinTable3B-1. [-" 1 i:*Wiil_l i'__t'Z L:-I I;PA': '5PV_GS:%i_d92909An'_aalk 'orargoLomPReportDelve_iDle_,ReDortsFi'- L:!Firla'AF -'S-PVNG{:Ar/% a!F_esorl2009soc
3.SludgeMonitoring2009AnnualMonitoringandComplianceReportAPPNO,P-1003883.SLUDGEMONITORINGCSUI_MARYOFANYExCEED ANCESOFPERMl °rL_M_TS F ORSLUDGEQUALITYNocxceedancesofpermitlimits6 )rsludgequalitywer eobservedduring2(){)9. 3.SludgeMonitoring2009AnnualMonitoringandComplianceReportAPPNO,P-1003883.SLUDGEMONITORING _:_,,DESCRIPTIONOFANYVlOLA!°_ONSOF'TNEARRA SPECIAL LICENSEFORS LUDGERAD i OiSOTOPE L_M_TSNoexcc_dances\vcreobservcdduring20{)9. 4.ComplianceStatus2009AnnualMonit oringandComplianceReportAPPNO.P-1003884.COMPLIANCESTATUS ,A,VOLUMEOFA LL,NON-STORf'v_WATERRELEASES '70_'_H_UNLINED£}fTCHKSORSE#JMKNTAT_ONBASINS Thcr c\vcr{:nonon-stormw
- t[crrcl c_sestoth cunlinedditch esorscdimcnt_tionb,gsinsin2009.
I r, l t ,l"_'ll_l_"i'l[l['il'_' i:4! 4.ComplianceStatus2009AnnualMonitoringandComplianceReportAPPNO.P-1003884.COMPLIANCESTATUS_,,SOURCEANDCHARAC_ER+ZATiONOFRELEASESTO BASINSSincethmcw e r e n()nonst ()rmwaterr el eas est ()th c un l in edd itches()rsed i mentat ionbasinsin21 1 ()9,watersampleswerenotc_>ll cctcdforcharacterizati (m.1:1I_*l','lllmm_i','[:tIt 4.ComplianceStatus2009AnnualMonitoringandComplianceReportAPPNO.P-1003884.COMPLIANCESTATUSC,(CON TINGENCYP LANACTIONS TAKENFORRE L EASES Sinc uthereweren <_nonst{_rmwat errel easest<_theunlinedditchesorsedim entationbasinsin 2t!(19,n_>conting encyplanactionsw eretak e n.n=jl,l,,, l,_t,__;ivi_Ii...... 4.ComplianceStatus2009AnnualMonitoringandComplianceReportAPPNO.P-1003884.COMPLIANCESTATUSOV_OLAT_ONSOFTNJSPERMITTherewerenoviolationsofthisp e rmit exceptforthecxc ccdanceof1ALsand /or,-\l.sasdescribedmSectionI.CofthisreportandlistedinTable1C-1. ['!t ,_,'_'lll_lll'_ IY L=..D. 4.ComplianceStatus2009AnnualMonitoringandComplianceReportAPPNO.P-1003884.COMPLIANCESTATUS_DENT_F_CATtONOFALERT LEVELS,AQLS,AQUIFER WA TERQUALITYSTANDARDS,ORDISCHARGE LIMITAT IONSTHAT'NAVESEENE XCEEDEDDUR ING°;H_I: RE P OR T ING PERIODANDADISCUSSIONOF THE TREN©INCONCENTRATIONSCOMPAREDTOTHE PREVIOUSREPORTINGPERIODSANDACTIONSTAKENTOCORREC '}_"THEEXCEEDEDLEVELSTinerewerenodischargesfromthcpermittedfacilitiesduringthereportingperiod.AssummarizedonTable2C1,rnaintenanccandrepairactivitiesoccurredatthe85-acrereservoirandEvaporationPondldurin_thereportingperiod.Repairsweremadetoallindicatedandobservedlinerdefects.,\sstatedinSccmms2 ,\and2D,ther ewasone.\1_exceedanceassociatedwiththeI,(IRSatd_e85-acre\X
- SRduringthereportingperiod.Asstatedinthefive-daywrittennotificationletter,datedDecember3,211119, 3_,6l,,gall,mswerepumpedfromSump2
()nN()vember24,2(1(19,whichexceedstheAI .Iof17,661gall_msperda\.Volumespumpedonsubsequentda\swerebelowtheAI Aof17,660gallonsperday.,.\PSbegandroppingthewaterlevelinthe85-acre\VSRonNovember1,20(19,priortotheAI Aexceedancc.The85acre\'('SRwasab_mt10percentfullonNovember24aswaterwastransferredtothe45-acre\VSRbymeans ()fpumpsfloating ,onbarges ,_.Itisbelievedthatoneofthebarges,.madecontactwiththeliner ,causingatearthatresultedintheincreasedflowtoSump2.ThevolumepumpedbySump2didnotexceedthe
- \1 2 (ff_..,,6n._gallonsper(tax.
- \leftlevelsforgroundwaterqualityatP()Candalertwellswereexceededin2(1(19.AsummaryofpermitlimitexceedancesrelatedtogroundwaterqualityixpresentedinTable1C1.Ingeneral,totalordissolvcd potassiumconcentrationsat,\PP-3,PVq4H,PV-195A,PV206A,andPV-Q8havevariedoverthepastt\w_
years.:\Is{,,thenitratc-nitritcasNconcentrationsatAPP-3andPV-14HandfluorideconcentrationsatPV195Ain2(1[19aresimilartoconcentrationsreportedfi_rthesewe llsin2008.These ,\I ,exceedanceswerenotassociatedwithdischargesfromthepermittedfacilities.Elevatedconcentrationsofboron,chloride,fluoride,nitratenitriteasN,potassium,andtotaldissolvedsolidsmaxbcattributedtopreviousagriculturallanduseand /orchangingsiteconditions(suchasadecreaseinwaterlevels).Forcxample,formanyshallowaquiferwells,waterlevelshavedecreased.Manyofth(_sewellsarcscreenedinasiltyclayunitandtheincreaseinpotassium(ametalcommonlyfoundinclayminerals)may againbeattributabletotheclayeyzonesthatmaybeintersectedaswaterlevelsdecrease.Inaddition,APShasnoticedvariationinconcentrationsforsomeparameters(suchaspotassium)thatc(_rrelatewiththelaboratoryusedand /(_rmeth (_dused.I_' (_rexample,EPAMeth(_d20{I.7,amethodusing inductively-coupledplasma,isgreatlyaffectedb}highsodiumandtotaldissolvedsolidsconcentrations.Potassiumandsodiumarebotheasilyionizableandthismaybecontributingtothevariabilityintheresults. EP,\Meth (Jd258.1whichisanatomicabsorptionmethodwasusedhistorically;however,currently,therearcnoAriz (ma-certifiedlaboratoriesforthismethod.Alternativeappropriatemethodsforpotassiumarebeinginvestigatedwithourcontractlaboratory.ItisuncertainwhetherornotthepotassiumexceedancesinmaybewithintheinherentvariabilityofEPAMethod20{I.7. 4.ComplianceStatus2009AnnualMonitoringandComplianceReportAPPNO.P-100388Whereelcvatedchromiumconcentrationsaredeterminedtobeassociatedwithpumpcorrosion,PVN(;Sc_mductscorrectiveactionstorcplaccthecorr_dcdpumps. I: u:,_,',,u_m_':"11_i,,,P4!_ 2009AnnualMonitoringandComplianceReportAPPNO.P-100388 FIGURES PVNGSW eftLocati o ns andAquife r Monito_e d....PVCayAquiferFIGURE1_,,'AbandonedWeISITEMAP_,oP'_NGoBounda[yPALOVEI-<DENUCLEAS_GEXEI_IATINGSTATI()NAI_IZONAPUB[,i(;SERVICES>GE_Pn_jeClSAPSP_' ¢_S1389497()_}9 !_rmuaMi)_ta_dUon2p[[kepor',GSA[-_Ck4APSF)GU_ES/"_8949FGOl%l_baps!?*;dL(,_s_Updal(_dM ay3POlO Appo-8 Da b_,'u 6 ,1208P_0_8 PV_, 20_A 2 i t0/20090_9 D a te_79,>L 5/7/20090.98 2/11/200916 7/23/20090,89 5/2t/2(}0917 10/28/2009086 8/4/2009161(i}i2 9 1200918 PV--195A D a t e m{_/L PVo198AR 3 1!1/200920 s_'_,'s O n:_379,17_;00.2f!1/200935,,,......_V4gSARII/I0_200923 5 i2 7/2009.4_,......7 i 22/2009;7,4....APP-15 10/15/200_37 D atemg/L 1", fn_1/4 ,20;,,_3.9 11/10/200913 12/1/200936 PV-Q8 D ate mg/L 2 1!!1200928 PV.4g3A5""_DatemglL APP-5 ,o/_8/_.,_0929 8/6/200936 2 1 27/200952 Datemg/'L'APP.,14 I0/8/200933 5 i 28/20096.0 2 1 27/20090 , 62 Dat e m_L 10 1 29/20092,9 8/4/20097I 6/10/20090,661I/10/2009!8 12/2 i200930 10/28/2009 56 9/16/2009059 11/5/20090,65 APP-13 Dat e mg ,'L APP-3 11/6/2009I9 D a te'_rag/,,.2 i 18 i2009i: 4 5!28/2009i4 PV°34H 8 i 6/2009_,4_v a_a t_o nDatem@iL PV-14H , O a t_, mg/L PondN o, 3B 10 1 29 i200913 2 1 27 1200967"" 6/10/200989 3/it/200965 9/!7/200970 6/15/200967 APP4RtI/6/200971 9/17/2009i3 Da t e mg/L 10 1 22 12009752/!9/2oo918 '5 128120092,0.......... 8/6/200922 APPo6 10!29/2009I7....Datem_'L 3/11/200913.......... 6 i 16/20091S: 9 1 17 i200914!............!0/22/2009!4 NOTE:PVNGSW eNLocationsandAquiferM o nit ore d mg/L=milligrampe_Lte_ .FIGURE2SELECTED2009....PVClayAquifer N_BORONCONCENTRATIOS ....PALOVERDENLI C I<EAR(}ENERATIN(I_S'['AI'{ON ARI ZONAPL[-K,I(SERVI(ES P 2 0)9,_\l_'uaf'4r>nandC;om_{_eI_or(!S,ARCMAPS[IGSIF_KSI_8949FiG02r_oor,r_xdLastk}c_datecMay5201( _i;iie_-ii, iiiii i:i: !:iii iiii ,,.....i!ii: £'<,_!ii_;!;__i_,_,_*.... (ki!i_!,_, APP=73/12,'2009120 9/80/20096/ 7/ °°9 112°20 Dat e mg/Lt1/19/2009120 1/5/20091000 APPo12 5/'L 2009 Dat e mg/l 7/9/2009I/I5/20091800 10/22/2009970 5 fU2009!700 AP_',,7 7/9/20091800........... 10/22/2009!900 }Datem_'L 3/i2/20094500 Datem/L 6/17/20095100;!/15/20098100....'i....,: 9/25/20095000 5/7/20098000_¢,_,,!1/19/20094800 7/9/20097900_*10/22/20098000 APPo8 D a t e m g, ,t%_,!/16/2009190 PVo206A 2 tt0/2009150"Datem/L 5/7/2009170 2/11/20095500 7/23/2009!70 5/21/20095500i0/28/2009180 8/4/20095700 10/29/20095600 PV 4 95A D ate m g/t_PV498AR;: '3/I1/20097600 Da te mg_,L 6/10/'20098300 I/!3/20092200 9/I7/2009_00 2/11/20092100...._,......... e__eS_,_11/10/20099100 5/27/20092400............ 7/22/200924 O0....L....I0/15/20092800_APP 4 5"Datem g/L 11/4/2009280011/!0/20099300 12/1/20092600_w-PVoQ8 Date m_/L PV 4 93A 2/11/20093200Datem APP=5 5/28/20093100 2 J 27/20096100Datemg/L APP 4 4 8/6/20093100 5/28/20095600 2/27/2009180 Dat e m g/L 1 8/29/20092900 8/4/20095900 6/10/20091901I/I0/200914000 12/2/20093000 10/28/20095900 9/16/2009180 11/5/2009200 APPo13 D ate mg/t , APPo3.................. 11/6/2009140Datem f_41 2/18/2009570 5/28/2009630 PV_34H 8/6/2009580_vo_: o_m_Dat e m/iPVol4H 10/29/2009570 P e_N e, , ,_2/27/20092000 D atemg/L.6/I0/20092100 3/11/20092200 9/17/20092100 6/15/20092100 11/6/20091900 9/17/20092200 APP4R 10/22/20092300 D atemg/t 2/19/2009550 5/28/2009550 8/6/2009600 APPo6 10/29/2009560 D ate m#%3/11 i2009330'6/16/2009340 9/I7/2009320 10/22/2009330 NOTE: P VNGS W e/Loc ationsandAquife r Monito re d mg iL=milligrampe_Lter@ShallowAquife_FIGURE3PVClayAquiferSELECTED2009 CH ibORI[)ECONCENTRATIONSRegionalAquifePAIOVERDENUCLEAI-IGENE[£ATtNGS'T'ATIO b_A RIZONAPUBMCSEi_IVICES .....i............._£>iSPO}_'CtSAPS -PVNGS_389492009A_ma%b!'_4qdCOr nOlRep0rtGIStARCt,ffA_:_S_GLR[S138949F!G03.Obi(}r}d8r_dk_stOp4afe(M_ /52010 F:eet0600S_200 2¢00PYc205A(WeltName) NOTES:837.2I(WaterLevelElevation)1Contou_lines9ene_ated(singSurfe_withminoeditsmadeusinghistodcadata2Water/evetetevatonsnfeet_SGroundwaterElevationComou_s-,_,,_ContoursDashedwhere:nferredJANUARY200.'9 SHALLOW AQUtFBR L:ROUND\VAT:_RELEY,AT:ONCONTOURS.h uOVER:)EN I;(.L t:_._<, QI{]NEI_ATII':GSTA 'FIONARI£ONA7:.;B[........S:£RVICE_:,::¢:_'GISProjecsA ,W_.PVNGS,38949i ?(309A'_:ua[tvlo:_ar:dComp/Repod(:KS/,A::CMAPSFK_:iF_ES!38,949FQ04V,_t.sha:o,200901JANmxdLastUpdated
- Ap:fi28,2, , Id Feet0600 1,200 2400P'vU205A(WetiName)
NO,_ES:83768(WatelLevelElevation)IContournesgeneratedusngSurfe!wthminoreditsmadeus{ngh{storcaldata_#_...."_'_\_jGroundwate__E,evationContours2Waterlevetelevationsinfeet '¢'_'__,_ContoursDashedwherehfretTedAPRIL2009 SHAL.LOW AQUIFERGROUNDWATEREEE_vATIONCONTOURLPASOVERDENU(13}_
- '}AI_:_([ENE}_ATINGSTATIONA}_IZ(bNAP UBLICSP}t_VICES P\C[S\R roiects APSPVNGS',,!38949
-2009Aw_ua!MoltandComp[Report\GISkARCMAPSFIGURES\!8949FiG05-WLsha!io,#200904APRmxdLastUpdatedA[:>[_.8°201>0 Feet06@I,200_;<o00 NOTES:pMo205A(WellName}!ContourlinesgeneratedusingSurf@'with837.22(WaterLeveI[ElevatioP,)minoreditsmadeusinghistoricaldata=(3roundwatur_E_evation Contours2_Waterteveteievations}nfeetJ"_%_jFabovemeans eaevel.3NA=MeasuFementnotavaiJabieF'IGURErb 4 p_'_e%_,,_,,ContoursDashedwhereinferred JUILY 2009 GROUNDWA TERE L EVA TIONCON T OURSPALOVERDEN_CI.EARQENERA'_{'INQS T A T ION}ikRIZOXA}L/BI,_I(}SF;RVIC[{:S>G!S!,ProjectsAPS-PVNGSq389492009AnnuaiMonandComplReport',GS_,ARCMAPS,FG,RESH38949FIG06-WLshaflov,-2@907JL__axdLasUpdatedApril2820t0 Feet06001200 2,400 b_OTf),S:PVc205A(We/Name}IConto_iir_esgeterated usingSu dewith837,07(WaterLeveElevation)m_noreditsmadeusinghistorcaidata2Waterlevelelevationsinfeet £_'s_abovemeansealeve X........,+GroundwaterElevatonContourss_A=Mea_u_emen_o_av_,ab,eFIGURE7_'_+,+ContoursDashedwhereInfer;edOCTOBER2009 (-" T SHALIL ,OWA}3UHS'ERGROUNDWATEREDEVAIIIONCONTOL,RS PAI.()\/_;"""_,t_DENL!CL_;}AIRGENERAT!NQSTATIONARIZONAPUI[_I_I(SE}_VI(fX}SP,GlS\g'ro_ects'APS-PV_,iGS138949200.9A_m ualMo_a_dCo_u:ARepol{\.GS_ARCMAPS\FI(_[IRES1389,19FiG07 t-WhshaHo_.2009!0OCTmxdlastUpdatedApril282010 Feet r_,600_'w ,
,-_,,,, 2,400EXPbAXA TION NO T ES;APP--5(WellName}1,contoul_iinesgeneratedsp,9Surfe_
'2Wate_levelelevationsinfeet776,78(WaterLevelElevation)Groundwater-ElevationContoursJANUARY2009PALOVERDE C L AY AQU I[: ERTT ,!GROUNDVvATERE iL_,YAIIONCONTOURS>A.,C)VE N[.)EN UCi,k_A}-t(}P}NERATN(,1SI'A1"()Ns_}<IZONAPUBi ,!("SER\'lCi4S::':'OS'Ptqects% t\PSRVNGS\1389492()Of}A!_iar,4o! >ridComp[Repo_lGIS\ARCr%lAPS\FK3URES\!38949W_deep200901-.ANnxd[atLpda{edb%y!4201O APPo,?841_36¢!i!;*K;}Feet0500!,200 2400 NOTES:1.Contot._rJinesgeneratedusn:Su_fer. APP5(WeftName) "2 ,Waterleveleievatonsinfeet77662(WaterLevetElevation}GroundwaterElevationConto_.rsAPRI[[_2009PA[_O%ERDa!,,C L,AYAQU i[FER CSROUN[DWAS'ERELEVA_[ON£,ON_rC L.,_RS_iAXO\,.'_RI)BNUC]£ARCtI 'XttIRArl:,_(DsrAI'I(}_',iARIZONAi-:L,_B]iCSBRV},CES
- '
- \G S P_oiect_W%PS-PVNGS13894926}09An!_u@MortsdCo_p(<por{',GS',ARCMAPS,F!GURES138949WLdeep200904APRmxdLas__.
'}da{eS:Ma_'142010 ..........Feet0(001 2 00 2, 400 NOTES:!Contot,rnesgeneratedusn!.}Surfer.APP-5(WetName)Waterevelelevatiop,snleti}'7687(WalerLevelElevation) 2.GroundwaterElevationContoursJ-U]_Y2009 PA L O VERDE C LAYAQUIFER ,-%,..._p_yGROUNDWA]ERE LE'vATIONCONTOURS}V\!,O\,L;RDb:__"LJ£t,/.kP'x"CENERA1.'INGSI.'ANONARIZONAP__B} ,I(S_......[,k\,I(.hb;P:GSPr@eck\A/_SPVNCS!38949?009Arcta_Molaidi;omplRepolf\G!S_AR;MAPS'FiGURES138949W_deep-2090; 'JUImxolastUpd_te- 'J:May142010 _.................Feet0600!200 240(}NOT[_:S:!CottournesgenerstedsngSu_fe_APP-5(WelI_'_xarne)2,Wate_eveleleva'_tior]ssinfeet776_57(WaterLevelEievaton)G_oundwaterElevationContours OCTOB_;}_t_£009PALOVERDECLAYA Q UIFE[_GRObNDWATERELE_ ._A']IONCONTOU_<S",)"/_)Y,,°"_/VEb_]}E?SbCI_. ,A,Gh}b;ERATINGSAT!ONA[<IZONAPUfq , I(SE[_VICESP\G!S'@ojecfs' i,,PS-PVN(_;S\138949-2)09Ans(;ai_o]aqdCo_-/ glel)(/!t',GS'_ARCMAPSF[OLJ[_FS!38949WISee g200910OCI_xci[sstJp:lae {:May14_2010
- 0 12f()b 0 q NOIE
- !Groundwatereew;tonsaeshownfoweliscompietedwith_theRegionaAqfen 2.Groundwater conto u rsarenotshown@RegionaiAquiferWe/Locations
_,-,_;-,GeneralDirectionofGroundwaterFlow RE.GIONALAQUIFERGROUNDWA'tTERELE",AFION S[AI.,OV[}i__.D[!fNL (i ,EAI_GENl£RA 'i'iN (}S'FA]]()NARIZONAPUL{LI(SE{VIC [/;SOi8::')__h,PP\/b]b!_!)}A_[<{, ru_{}>_)R,p:tGS_R(p_/APS_I(-,({88l{[S_:}QVVE{ivRgKaoxi (st{J)d_L e<, t_3 2010 ....%"_z_".oo,, ,,<:.:..m-4°o_.,,_¢/o¢<©.'Ooe,,_L ,,_!_o g ,7 o_g lS OO?l tt?lO t_>b oo.(Istu e'leet)uo!l e A al:lJ a l e M punoJ o _Z"=_Z eOo_/_/x_=__Z-o eOo_,,o%_, C eOo e/l¢/l" m.E (1)=__o°--I" Oo e/_¢/¢_: o" oo e/ex/o"_2 rrg)_.Q_.1 , I_cO_.___z c_(Ism e'leel)uo!:),eA al:ll e), e M punol!D
"o z.c: E["_>_o_.__zI___--__i____o_iiiii i-,_!i'<--_o i 1 ,-i i_..!i I i']oi=!I , i I 1i!, i_F Nl,i i ,', oo%_n(ISLUe':1.{)_)t)UOt:l.eA*13l e], e/w punol_)3;*
iE 0").°m , N ,,m O 0_R Imz 4" N O_©o o eL a."%.%,.__U-LL N o o"_00_/_,_./0¢_=r_o_'OOe,oe_" N d_(ISUJ e'_, aa t)uo!:l e^Ol:lJa l e M punoJo N D_
o_>a__Z-_o U__00_,¢_'/_o"_°°_/_'_,/o¢_-o%°i%°N%°d_13.(ISU J e'_, eet)uo_,e A el:lJ el e_pu no J o N*o 2
_z_.400_ldl t©*_->_i_=7=_E"_O0_l_l l____l_, 8{o u..Z%°e, D i g ff N,, , eOoe,,_e,,e g I_, I" ,.Z 0")(ISUJ il'leet)uo!l eA el:lJ elilM punoJ!D
Pvo?06A D a t e g 1/18 ,200819000 5 1 21/200920000 d PVd 98AR PV.,195A_/,"_e:;,-{}/: 5ae m g/L"/2{-}/20084600 36/200827000....6,0,-,0,:27000 5/27:20095300.....,..............................................,*'1 7 t"::;:: APP-!_D a te sK#/t 6 i 5:200920000 PVQ8 PV-193A Dat e::9v%Dater_£y L APP,,14 1/24/20088_00 2/I4/2008_000 D ate mgii 5/28/20098900 5/28/200915000 6/5:200935000 P'do44H D a t e m!>/t.2/20/2008:;'200 PV_34H 6/I!,/20096800:'o re:no.s_2//2006400 6/10/20096600 P VNGS We/: Loca ti o ns andAquit%:rM o:_i_o red NorE:@ShaI{owAquifer mg i L=mllg_ampe__:x FIGURE 55]u)<CCNCE.N_RAT]ONS}}:;ORSHALLOWAqL,IF L R WEI.,-L ,...!{K%I,,()VE F,D[_("'" ,-r v....._:,_,_t.l,_./\t (}[}X_I#,ATING o A1{"_}{i_: "AI:N()NqIblbk,SK%[VIC_S
- '([_P tj?c,AIS V.q(Stl:8_#_9)00
',)_axf(b_Z S PS9{D()()_dic_e,,;Las(U_dfMayi400 2009AnnualMonitoringandComplianceReportAPPNO,P-100388APPENDIXAANNUALRADIOLOGICALENVIRONMENTALOPERATINGREPORT -ia=J.c.l , , , J ,_._'1r__-jli t--................................................................................................................. NUCLEARGENERATINGSTATIONANNUALRADIOLOGICALENVIRONMENTALOPERATINGREPORT 2009(
Reference:
RCTSAI1643.LegacyItemNo.036843.01) D i g ita llysi gnedbyDrinovsky,LouisJDrinovsky,Louis,z33099_DN:c n=Drinovsky,LouisJ(Z33699) Rea son:Iamtheauthorofthis J(Z33699)d o.omen,Preparedby: D ate:2010.0.0210:24:39-07 'g0'D i g itallysignedbyBungard,JamesBungardJames P(Z180 1 2)DN: c n=Bu n g a rd , Jam e s P (Z 1 8012)P(Z18012)dooomeo, R e as on:Ih a v e r e vie we d th isReviewedby:Date2010040212:51:31-07'00 'Gaffney,J ohn,z3o4sg_°'g"°"Ys'_dby_a"°eY J_°_DN:cn=G affney.JohnP(Z36459) P(Z36459)Rea son:Iamappr ovingthisd....nt D ate:2910.940512:38:58-97 '0 0'Approvedby:Director,RadiationProtection TABLEOFCONTENTS 1.INTRODUCTION........................................................................................................................... 22.DESCRIPTIONOFTHEMONITORINGPROGRAM................................................................32.1.2009PVNGSI_A.DIOLOG1CALENVIRONMENTALMONITORINGPROGRAM...............................32.2.RADIOLOGICALENVIRONMENTALMONITORINGPROGRAMCHANGESFOR2009......................32.3.REMPDEVIATIONS /ABNORMALEVENTSSIJMMARY...............................................................4 2.4.SIGNIFICANTINVESTIGATIONREGAR DINGGROUNDWAFERPROTECTION...............................43.SAMPLECOLLECTIONPROGRAM........................................................................................123.1.WATER.................................................................................................................................... 123.2.VEGETATION........................................................................................................................... 123.3.MILK....................................................................................................................................... 123.4.AIR.......................................................................................................................................... 1 2 3.5.SLUDGEANDSEDIMENT.......................................................................................................... 134.ANALYTICALPROCEDURES.................................................................................................. 134.I.AIRPARTI CIILATE................................................................................................................... 134.2.AIRBORNERADII)IODINE......................................................................................................... 134.3.MILK....................................................................................................................................... 134.4.VEGETATION........................................................................................................................... 144.5.SLIrDGE /SEDIMENT................................................................................................................. 144.6.WATER.................................................................................................................................... 144.7.SoII.........................................................................................................................................155.NUCLEARINSTRUMENTATION............................................................................................155.1.GAMMASPECTROMEIER......................................................................................................... 155.2.LIQUIDSCINTILLA TIONSPECTROMETER................................................................................. 155.3.GASFLOWPROPORTIONALCOUNTER..................................................................................... 156.ISOTOPICDETECTIONLIMITSANDREPORTINGCRITERIA..........................................166.1.LOWERLIMITSOFDETECTION................................................................................................ 166.2.DATAREPORTINGCRITERIA................................................................................................... 166.3.LLDANDREPORTIN{_;CRITERIAOVERVIEW........................................................................... 177.INTERLABORATORYCOMPARISONPROGRAM...............................................................227.I.QI!ALITYCONTROLPROGRAM................................................................................................227.2.IN T ER{_'OMPARISONRESIrLTS.................................................................................................. 228.DATAINTERPRETATIONSANDCONCLUSIONS...............................................................258.1.AIRPARTICULATES................................................................................................................. 258.2.AIRBORNERADIOI()DINE......................................................................................................... 268.3.VEGETATION........................................................................................................................... 268.4.MILK....................................................................................................................................... 268.5.DRINKINGWATER................................................................................................................... 268.6.GROUNDWA TER..................................................................................................................... 26 P\,"NGSAN_',;UALRADI()LOGICALENVIRONMENTALOPERATINGREPORT-2009 ii TABLEOFCONTENTS8.7.SURFACEWATER.................................................................................................................... 26 8.8.SLUDGEANDSEDIMENT.......................................................................................................... 2 7 8.9.DATATRENDS......................................................................................................................... 2 79.THERMOLUMINESCENTDOSIMETER(TLD)RESULTSANDDATA..............................49 10.LANDUSECENSUS...................................................................................................................5510.1.INTRODUCTION ........................................................................................................................ 55 10.2.CENSUSRESULTS..................................................................................................................... 55 11.
SUMMARY
ANDCONCLUSIONS...........................................................................................57 1 2.REFERENCES..............................................................................................................................6 2P'_2NGSANNUALRAD1OLOGICALENVIRONMENTALOPEP_AT1NGREP{}RT-2 (109 iii LISTOFTABLES T ABLE2.1S AMPLECOLLECTIO N LOC ATIONS................................................................................6TABLE2,2SAMPLECOLLECTIONSCHED ULE..................................................................................7TABLE2.3S UMMARIESOFREMPDEVIATIONS /ABNORMALEVENTS......................................8TABLE6.10DCMREQ UIREDLOWERLIMITSOFDETECTION(APRIORI)...............................19TABLE62ODCMREQ UIREDREPORTINGLEVELS.......................................................................20TABLE6.3TYPICALMDAVAL UES....................................................................................................21 TABLE7.1INTERLABORATORYCOMPARISONRESULTS...........................................................23 TABLE8.1PARTICULATEGROSSBETAINAIR1ST-2NDQ UARTER.......................................28TABLE8.2PARTICULATEGROSSBETAINAIR3RD-4THQ UARTER.......................................29TABLE8.3GAMMAINAIRFILTERCOMPOSITES..........................................................................30TABLE8,4RADIOIODINEINAIR1ST-2NDQ UARTER.................................................................31TABLE8.5RADIOIODINEINAIR3RD-4THQ UARTER.................................................................32TABLE8.6VEGETATION......................................................................................................................33 TABLE8,7MILK.....................................................................................................................................34 TABLE8.8DRINKINGWATER.............................................................................................................35 TABLE8.9GROUNDWATER...............................................................................................................37TABLE8.10S URFACEWATER............................................................................................................38TABLE8.11SL U DGE/SEDIMENT........................................................................................................42 TABLE9.1TLDSITELOCATIONS.......................................................................................................50 TABLE9.22009ENVIRONMENTALTLDRESULTS.........................................................................52 TABLE10.12009LANDUSECENSUS.................................................................................................56TABLE11.1ENVIRONMENTALRADIOLOGICALMONITORINGPROGRAMANNUAL
SUMMARY
...58 P\LNGSANNUALRADIOLOGICALENVIRONMENTALOPEI L_.TINGREPORT-2 0O9 i x' LISTOFFIGURESFIGURE2.1REMPSAMPLESITES-MAP(0-10miles).................................................................10FIGURE2.2REMPSAMPLESITES-MAP(10 -35miles)...............................................................11FIGURE8.1HISTORICALGROSSBE TAINAIR(WEEKLYSYSTEMAVERAGES)...............45FIGURE8.2HIS TORICALGROSSBE TAINAIR(ANNUALSI TETOSITECOMPARISONS)COMPAREDTOPRE-OP.....................................................................................................................46FIGURE8.3GROSSBETAINDRINKINGWA TER........................................................................47FIGURE8.4EVAPORATIONPONDTRITIUMACTIVI TY............................................................48 FIGURE9.1NETWORKENVIRONMENTAL TLDEXPOSURERA TES......................................53FIGURE9.2ENVIRONMENTALTLDCOMPARISON-PRE-OPERATIONALVS2009............54 P\'.'NGSAN'NU ALRADIOLO(3I('A LENVIRONMENTALOPERATI NGREP()R T-2 009 Y ABSTRACTTheRadiologicalEnvironmentalMonitoringProgram(REMP)isanongoingprogramconductedbyArizonaPublicServiceCompany(APS)forthePaloVerdeNuclearGeneratingStation(PVNGS).VarioustypesofenvironmentalsamplesarecollectednearPVNGSandanalyzedforplantrelatedradionuclideconcentrations.During2009,thefollowingc a tegor iesofsampleswerecol lectedby APS:*Broadleafvegetation*Groundwater*Drinkingwater*Surfacewater*Airborneparticulateandradioiodine*Goatandcowmilk*SludgeandsedimentThermoluminescentdosimeters(TLDs)wereusedtomeasureenviro nmentalgammaradiati on.TheEnvironmentalTLDprogramisalsoconductedbyAPS.TheArizonaRadiationRegulatoryAgency(ARRA)performsradiochemistryanalysesonvariousduplicatesamplesprovidedtothembyAPS.SamplesanalyzedbyARRAincludeonsitesamplesfromtheReservoirs,EvaporationPonds,andtwo(2)deepwells.OffsitesamplesanalyzedbyARRAincludetwo(2)localresidentwells.ARRAalsoperformsairsamplingatseven(7)offsitelocationsidenticaltoAPSandmaintainsapproximatelyfifty(50)environmentalTLDmonitoringlocations,eighteen(18)ofwhichareduplicatesofAPSlocations.Acompari sonofpre-operationalandoperationaldataindicate snochanges toenvironmentalradiationlevels.Lowleveltritiumwasdiscoveredins ubsurfacewateronsite (notcon sideredpotable)in February2006atUnits2and3.Asignificantinvestigationwasinitiatedtodetermine thesourceofthewater, theexten toft hecondition ,andcorrectiveactions toprotectgroundwater.SeeSection2.4forfurt herdiscussion.(NOTE: R efer en c etoA PSthroughoutthisreportreferstoPVNGSpersonnel)P'_.'NGS ANNUALRADIOLOGICALENVIRONMENTALOPERATINGREPORT -2 009 1 O PERATI ONALRADIOL OGICALENVIRONMENT AL M O NITORING PR O GRAM1.IntroductionThisreportpresentstheresultsoftheoperation alradiologicalenvironmentalmonitoringpr o gramconductedbyArizonaPublicService Company(APS).TheRadiologicalEnvironmentalMonitoringProgram(REMP)wasestablishedforthePaloVerdeNuclearGeneratingStation (PVNGS)byAPSin1979.TheREMPisperformedinaccordancewiththefederalrequirements toprovideacompleteenvironmentalmonitoringprogramfornuclearreactors,andwithconcernformaintainingthequalityofthelocalenvironment.Theprogramcomplieswiththerequirements of10CFR50,AppendixI,PVNGSTechnicalSpecifications,andwiththeguidanceprovidedbytheUSNuclearRegulatoryCommission(USNRC)intheirRadiologicalAssessmentBranchTechnicalPositiononEnvironmentalMonitoring,Revision1,November1979(incorporatedintoNUREG1301).Thisreportcontainsthemeasurementsandfindingsfor2009.AllreferencesarespecificallyidentifiedinSection12.TheobjectivesoftheREMPareasfollows:1)todeterminebaselineradiationlevelsintheenvironspriortoplantoperationandtocomparethefindingswithmeasurementsobtainedduringreactoroperations:2)tomonitorpotentialradiologicalexposurepathwaystothepublic;and3)to determineradiologicalimpactsontheenvironmentcausedbytheoperationofPVNGS.ResultsfromtheREMPhelptoevaluatesourcesofelevatedlevelsofradioactivityintheenvironment(e.g.,atmosphericnucleardetonationsorabnormalplantreleases).ResultsofthePVNGSpre-operationalenvironmentalmonitoringprogramarepresentedmReference1.Theinitialcriticality ofUnit1occurredMay25,198 5.InitialcriticalityforUnits2and3wereApril18,1986 ,andOctober25,1987,respectively.PVNGSoperationalfindings(historical)arepresentedinReference2.P\._J (iSANNUALRADIOLOGICALENVIRONMENTAL ()PERATINGREPORT -2009 2 2.DescriptionoftheMo n itor ingProgramAPSandvendororganizationsperformedthepre -operationalradiologicalenvir o nmentalmonitoringprogram,whichbeganin1979.APSandvendorscontinuedtheprogramintotheoperationalphase. 2.1.2009PVNGSRadiologica lEnvironmentalMonitoringProgramTheassessmentprogramconsistsofrout inemeasurementsofenvironm entalgammaradiationandofradionuclideconcentrationsinmediasuchasair,groundwater,drinkingwater,surfacewater,vegetation,milk,sludge,andsediment.SampleswerecollectedbyAPSatthemonitoringsitesshowninFigures2.1and2.2.Thespecificsampletypes,samplinglocations,andsamplingfrequencies,assetforthinthe PVNGSOffsiteDoseCalculationManual(ODCM),Reference4,arepresentedinTables2.1,2.2and9.1.Additionalonsitesampling(outsidethescopeoftheODCM)isperformed tosupplementtheREMP.Allresultsareincludedinthisreport.Sampleanalyseswere performedbyAPSatthePVNGSCentral ChemistryLaboratory.ThislaboratoryislicensedbytheArizonaDepartmentofHealthServices(ADHS)toperformradiological
analyses.EnvironmentalgammaradiationmeasurementswereperformedbyAPSusingTLDsatfifty(50)locationsnearPVNGS.ThePVNGSDosimetryDepartmentisaccreditedbytheNationalVoluntaryLaboratoryAccreditationProgram(NVLAP)toperformionizingradiationdosimeteranalyses.Inadditiontomonitoringenvironmentalmedia,alandusecensusisperformedannuallytoidentifythenearestmilkanimals,residents,andgardens.Thisinformationisusedtoevaluatethepotentialdosetomembersofthepublicforthoseexposurepathwaysthatare indicated.2.2.RadiologicalEnvironmentalMonitoringProgramChangesfor2009AnnualsamplingofEvaporationPondsedimentwasdiscontinuedbasedonhistoricaldataandthepotentialtodamagethenewliners.ThissamplewasnotODCMrequired andanevaluationoftheriskvsbenefittocontinuedsamplingwasdocumentedintheCorrectiveActionProgrambyCRDR#3363010.TheLandUse Censusidentifiedanewcowmilklocationwithin5milesandthislocationwasaddedtothemonitoringprogram.EvaporationPond#3(dividedintosections3Aand3B)wasbuiltandplacedintoservice.WaterfromEvaporationPond#2waspumpedintothispond.EvaporationPond#2isemptyandisundergoingacompletelinerreplacement. P V_'NGSA NNI_ALIL&DIOLOGI('ALENV IRONMENTALOPE RATINGREP ORT-2 o 09 3 ThefollowingchangesimplementODCMRevision24andweremadeasaresultoftheannualLandUseCensus(reference CRDR#3337879);1.ReplacedtheLahti(ODCMSite#47),andWright(ODCMSite#52),vegetationsamplelocationswiththeBatdorflocation.DesignatedBatdorfasSite#47.>2.AddedtheRodriguez(cowandgoat)andDavis(goat)milksamplelocations.DesignatedRodriguezasSite#51andDavisasSite#52.3.RetainedtheHernandezgoatmilklocationasSite#54,butchangedstatusto supplemental.RefertoTable2.1foradescriptionofallcurrentsamplelocations(exceptTLDs).2.3.REMPDeviations /AbnormalEventsSummaryDuringcalendaryear2009,thereweresix(6)deviations /abnormaleventswithregardtothemonitoringprogram.RefertoTable2.3formoredetailandanycorrectiveactions taken.*TheairsamplesatSite#7Awereinvalidfrom9 /15through9 /22*TheairsamplesatSite#14Awereinvalidfrom11 /9through11 /17
- EvaporationPond#2wasemptytheentireyearforlinerreplacement*The1-131concentrationinwaterexceededtheactionlevelinEvaporationPond#1andbothReservoirs*TLDsatSite#36weremissinginthe3rd quarter*The4mquarterTLDresultsweredelayedformorethan60days2.4.SignificantInvestigationRegardingGroundWaterProtection (Fo l l o w-upfr ompastreports)
NOTE:AlthoughnotpartoftheREMP,thisinformationisbeingprovidedduetotheidentificationoflowleveltritiumintheonsiteenvirons(withintheRadiological ControlledArea)andheightenedsensitivitytocommunicatethepotentialtoaffectground water.OnFebruary15,2006PaloVerdepersonnelobservedwaterleakageintotheUnit2EssentialPipeDensityTunnelthroughthe'B'SprayPond(SP)supplylinepenetrationseal(documentedonSignificantCRDRNo.2869959).Lowleveltritiumwasidentifiedinthiswater.Ithasbeendeterminedthatthewaterwasnottheresultofleakagefromaplantsystem,butmorelikelyduetopreviousoperatingconditionscombinedwithprecipitation.TheinvestigationrevealedthatUnit3hadasimilarsituation.PVNGSinitiatedOE22651andfollow-upOE24237todescribetheincidentoflowleveltritiumatUnit3sincetheconcentrationexceededareportingthreshold.P\._GSANNUALRADIOLOGICALENVIRONNIENTA[OPERATINGREPORT-2O09 4 SeveralmonitoringwellshavebeeninstalledtomonitorthesubsurfacewaterandshallowaquiferatUnits1 ,2,and3.Thesewellsaresampledmonthlyandquarterlyforchemicalandradiologicalparameters.TheStateofArizonaAquiferProtectionPermit(Area-Wide)No.P-100388(APP)providesagreeduponmonitoringparametersandreportingthresholds.SampleresultsarereportedinthePVNGSAnnualRadioactiveEffluentReleaseReport(ARERR).PVNGShasimplementedagroundwaterprotectionprograminitiatedbytheNuclearEnergyInstitute(NEI).Thisinitiative,NEI07-07(IndustryGroundWaterProtection Initiative-FinalGuidanceDocument,August2007),providesaddedassurancethat groundwaterwillnotbeadverselyaffectedbyPVNGSoperations.TheStateofArizonaAPPprovidesspecificregulatorycriteriaforgroundwaterprotection.P\LN(iSANNUALRADIOLOGI('ALENVIR()NMEN TAL()PE RATINGREPORT-2 009 5 Table2.1SAMPLECOLLECTIONLOCATIONS SAMPLE SITE#S AMPLETYPELOCATIONLOCATIONDESCRIPTI O N.N 4 air El6 A PSOffic e 6 A*airSSE13OldUS80 7AairESE3ArlingtonSchool14AairNNE2371_tAve.andBuckeye-Salom e Rd.1 5 air NE2NESiteBoundary 1 7Aair E3351_Ave.21air$3SSit e Boundary 2 9 air WIWSiteBoundary35a ir NNW8 T onop a h40a ir N2 T r ansmissionRd 46 dr in k ing w a ter NNW8 W irthr e s i d enc e47vegeta tionNN E2(b)Batdorfresidence 4 8drinkingw aterSWI Berrymanresidence 4 9 drink ingwaterN2 Sand ovalresidence 51milk ESE2 (b)R od r i g u ez r es id e nce-g oatsandco ws52milkENE3(b)Davisresidence-goats 53*milk NE3 0 M artinresidence-goats 54milkNNE4Hemandezresidence -goats 55drinkingw aterSW3Gavetteresidence (supplemental) 57groundwat erONSITEWell27ddc 58groundw aterONSITEWell34 a bb 59surfacewaterONSITEEvaporationPond#1 6 0surfacewaterONSITE85acreReservoir61surfa cewaterONSITE45a creReservoir 62*vegetationENE26DuncanFamilyFarms63surfacewaterONSITEEvaporationPond# 264surfacewaterONSITEEvaporationPond#3 NOTES:*Designatesacontrolsite (a)Distancesanddirectionarefromthecenter -lineofUnit2containmentandroundedtothenearestmile (b)DenotesachangeinlocationoranewsamplelocationAirsamplesitesdesignatedwiththeletter'A"a resitesthathavethesamesitenumberasaTLDlocation,butarenotinthesamelocation(e.g.site# 6TLDlocationisdifferentfromsite#6Aairsamplelocation:site#4TLDlocationisthesameassite#4airsalnplelocation) P'_LNGSANNUALRADIOI.OGICALENVIRONMEN TALOPERATINGRE PORT-2009 6 Table2.2SAMP LE COLL E C TI O N SCH E D U L E ,%-JMPLEdlR AIRBORNE GRO{;NDDRINKING ,_,Y" RA Z q(" E 37 TE#PARII ('ULAIEMILKtL 4DI()IODINEVEGEI 3ITIONW.-ITERWATER I't N I'ER 4 W W 6A W W 7A W W 14A W W 15 W W 17A W W 21 W W 29 W W 35 W W 4O W W 46 W 47 M i AA 48 W 49 W 51 M/A A 52 M i AA 53 M i AA 54 M i AA 55 W 5v Q 5s Q 59 Q 6 o Q 61 Q 62 M/AA 63 Q 64 Q=WEEKLYM'AA=MON T H LYASAVAILABLEQ=QUAR T ERLYP'_LNGSANNUALRADIOLOGI('ALENVIR()NMENTAI.OPERATINGREPORT-2 0o9 7
T AB LE2.3SU MMARIESOFRE MPDE V I ATION S/ABNOR MAL E V E NT S Deviation/AbnormalEventActionstaken1.TheairsamplesatSite#7Awereinv alidfrom1.The airs amplepumpfailedduringth e 9/15through9 /22sampleperiod,resultingintheinabilitytodeterminetheactualsamplevolume.Thepumpwasreplacedandthesampleforthenextweekwasvalid.Nofurtheractions required.2.TheairsamplesatSite#14Awereinvalid2.Theairsamplepumpfailedduringthefromll/9through11 /17sampleperiod,resultingintheinabilitytodeterminetheactualsamplevolum e.Thepumpwasreplacedandthesampleforthenextweekwasvalid.Nofurtheractions required.3.EvaporationPond#2wasemptytheentire3.Thelinerisbeingreplaced.EvaporationyearforlinerreplacementPond#2wasemptyallyear.Whenwaterisaddedtothepondroutinesamplingwillstart.Noactionrequired.4.The1-131concentrationinwaterexceededthe4.CorrectiveActionProgramdocumentCRDRactionlevelinEvaporationPond#1andboth#3309449providestheevaluationconclusion Reservoirsthatradiopharmaceutical1-131isthecauseoftheelevated1 -131concentrations.Becausethe1-131isnottheresultofplanteffluents,n.__o_oSpecialReportingwasrequired.Providingtheinformationinthisreport meetstherequirementsofODCMSection 6.1,Actionb.andCRAI#3312804.Nofurtheractionsarerequired.5.T LDsatSite#36weremissinginthe3ra5.TheT LDsatthislocationweremovedacross quartertheroadasitwasdeterminedaschoolbusstopwasnowatthislocation.TheT L Dswerenotmissinginthe4_h quarter.Therefore,movingthemacrosstheroadhascorrectedtheproblem.Relocationofthese T LDswillbeconsiderediftheproblemrecurs.Nofurtheractions arerequiredatthis time.P'_LNGSANN U ALRADIOLOGICALENVIRONMENTALOPERATINGREPORT -2 009 8 T AB LE 2.3 SUMM ARI ES O F REMP DEV IA T IO N S/AB NO R M AL E VE NTS Deviation/AbnormalEvent{continued)Actionstaken{continued) 6.The4_h qua r te r TLDr e s ult s we redelayedfo r 6.Theen v i r on mentalTLDr e s ultsshoweda m o r e than60day slowbia sinthe 4 th quart e randaninve s ti g ati on intothecau sewa s c o nducted.Corr ec t i v e A cti on P r o gramdocument C R D R#3 4 39 2 1 5 wa s initia t ed tod o cu mentandc orr ectthei ss ue.P\L2qGSA NNI7A L RADI O LOGI('ALENVIR O NMEN T AL OPERATINGREP O R T-2 009 9 IFIGURE2.1PVNGSANNUALRADIOLOGICALENVIRONMENTALOPERATINGREPORT-2009 10 i , ,J ,_PV NG A NNU ALR A D IO L OG IC ALE NVI R O NMENT A L O PER A TIN G REP ORT-2 00 9 1 1 3.SampleCol lectionProgra mAPSpersonnelusingPVNGSprocedurescollectedallsamples.3.1.Wate r Week lysampleswerecollectedfromfour(4)residencewellsformonthlyandquarterlycomposites.Sampleswerecollectedinone-galloncontainersand500mlglass bottles.Thesampleswereanalyzedforgrossbeta,galmnaemittingradionuclidesandtritium.Quarterlygrabsampleswerecollectedfr omthe (45and85acre)Reservoirs,EvaporationPond#1,EvaporationPond#3A /3B ,andonsitewells34abband27ddc.EvaporationPond#2wasemptyforlinerreplacement.Sampleswerecollectedinone-galloncontainersand500mlglassbottles.Sampleswereanalyzedforgammaemittingradionuclidesand tritium.Trea tedsewageeffluentfromtheCityofPhoenixwassampledasaweeklycompositeattheonsiteWaterReclamationFacility(WRF),andanalyzedforgammaemittingradionuclides.Amonthlycompositewasanalyzedfortritium.3.2.VegetationVegetationsampleswerecollectedmon thly,asavailable,andwereanalyzedforgamma emi ttingradionuclides.3.3.Mi l kGoatandcowmilksampleswerecollectedmonthly,asavailable,andwereanalyzedforgammaemittingradionuclides,includinglowlevelI-131.3.4.AirAirparticulatefiltersandcharcoalcartridgeswerecollectedatten(10)sitesonaweeklybasis.Particulatefilterswereanalyzedforgrossbeta.Charcoalcartridgeswereanalyzed for1-131.Particulatefilterswerecompositedquarterly,bylocation ,andanalyzedforgammaemittingradionuclides.P\LNGSANNI_ALRADIOLO C,ICA LENVIRONMENTALOPERATINGREPORT-2009 12
3.5.SludgeandSedimentSludgesampleswereobtainedweek lyfromtheWRFwastecentrifuge(whenevertheplantwasoperational)andanalyzedforgammaemittingradionuclides .CoolingtowersludgewasanalyzedforgammaemittingradionuclidespriortodisposalintheWRFsludgelandfill.4.AnalyticalProceduresTheproceduresdescribedinthisreportarethoseusedbyAPStoroutinelyanalyzesamples.4.1.AirParticu l ate4.1.1.GrossBetaAglassfiberfiltersampleisplacedinastainlesssteelplanchetandcountedforgrossbetaactivityutilizingalowbackgroundgasflowproportionalcounter.4.1.2.GammaSpectroscopyTheglassfiberfiltersarecountedonamultichannelanalyzerequippedwithanHPGedetector.Theresultingspectrumisanalyzedbyacomputerforspecific radionuclides.4.2.AirborneRadioiodineThecharcoalcartridgeiscountedonamultichannelanalyzerequippedwithanHPGedetector.Theresultingspectrumisanalyzedbyacomputerforl-131.4.3.Mi l k4.3.1.GammaSpectroscopyThesampleisplacedinaplasticlnarinellibeakerandcountedonamultichannelanalyzerequippedwithanHPGedetector.Theresultingspectrumisanalyzedbyacomputerforspecificradionuclides.P\2NGSANNUALRADIOLOGICALENVIRONMENTALOPERATINGREPORT-2 OO9 13
4.4.Vegetation4.4.1.GammaSpectroscopyThesampleispureedinafoodprocessor,placedinaoneliterplasticmarinellibeaker,weighed,andcountedonanmltichannelanalyzerequippedwithanHPGedetector.Theresultingspectrumisanalyzedbyacomputerforspecific radionuclides.4.5.S l udge/Sediment4.5.1.GammaSpectroscopyThewetsampleisplacedinaone-literplasticmarinellibeaker ,weighed,andcountedonamultichannelanalyzerequippedwithanHPGedetector.Theresultingspectrumisanalyzedbyacomputerforspecificradionuclides.4.6.Water4.6.1.GammaSpectroscopyThesampleisplacedinaone-literplasticmarinellibeakerandcountedonamultichannelanalyzerequippedwithanHPGedetector.Theresultingspectrumisanalyzedbyacomputerforspecificradionuclides.4.6.2.TritiumThesampleisevaluatedtodeterminetheappropriatemethodofpreparationpriortocounting.Ifthesamplecontainssuspendedsolidsoristurbid,itmaybefiltered,distilled,and /orde-ionized,asappropriate.Eight(8)millilitersofsamplearemixedwithfifteen(15)millilitersofliquidscintillationcocktail.Themixtureisdarkadaptedandcountedfortritiumactivityusingaliquidscintillationcountingsystem.P'vLNGSANNUALI L_.DIOLOGICAI.ENVIR ()NMENTALOPERATINGREPOR[-2009 14
4.6.3.GrossBetaA200-250millilitersampleisplacedinabeaker.Five(5 )millilitersofconcentratednitric(HNO3)acidisaddedandthesampleisevaporateddowntoabouttwenty(20)milliliters.Theremainingsampleistransferredtoastainlesssteelplanchet.Thesampleisheatedtodrynessandcountedforgrossbetainagasflowproportionalcounter.4.7.Soil4.7.1.GammaSpectroscopyThesamplesaresieved,placedinaone-literplasticmarinellibeaker,andweighed.ThesamplesarethencountedonamultichannelanalyzerequippedwithanHPGedetector.Theresultingspectrumisanalyzedbyacomputerforspecific radionuclides.5.NuclearInstrumentation5.1.GammaSpectrometer TheCanberraGammaSpectrometerconsistsofaCanberraSystemequippedwithHPGedetectorshavingresolutionsof1.73keVand1.88keV(asdeterminedbyfullwidthhalfmaxwithanenergyof0.5keVperchannel)andrespectiveefficienciesof21.5%and38.4%(asdeterminedbythemanufacturerwithCo-60).TheCanberraSystemisusedfor allgammacounting.ThesystemusesCanberradevelopedsoftwaretosearch , identify ,andquantifythepeaksofinterest.5.2.LiquidScinti llationSpectrometerABeckmanLS-6500LiquidScintillationCounterisusedfortritiumdeterminations. T hesystembackgroundaveragesapproximately15-17cpmwithacountingefficiencyofapproximately40%usingaquenchedstandard.5.3.GasF l o wProportionalCounterTheTennelecS5Eisalowbackgroundgasflowproportionalcounterforgrossbetaanalysis.Thesystemcontainsanautomaticsamplechangercapableofcounting50samplesinsuccession.Averagebetabackgroundcountrateisabout1-2cpmwithabetaefficiencyofapproximately30%forCs-137.P'_.'NGSAN_N UAL R AD IOLOGICALENV I RONME NTALOPER ATINGREPO RT-2 0 0 9 15 6.IsotopicDetectionLimitsandReportingCriteria6.1.LowerLimitsofDetectionThelowerlimitsofdetection(LLD)andthemethodforcalculationarespecifiedinthe PVNGS ODCM,Reference4.The ODCMrequiredaprioriLLDsarepresentedin T able6.1.Forreference,aprioriLLDsareindicatedatthetopofdatatablesforsampleshavingrequired LLDvalues.6.2.DataReportingCriteriaAllresultsthataregreaterthantheMinimumDetectableActivity(MDA)(aposteriori LLD)arereportedaspositiveactivitywithitsassociated2_countingerror.AllresultsthatarelessthantheMDAarereportedaslessthanvaluesattheassociatedMDA.Forexample,iftheMDAis12pCi /liter,thevalueisreportedas<12.TypicalMDAvaluesarepresentedinTable6.3. Occasionally ,thePVNGSODCMaprioriLLDsmaynotbeachievedasaresultof:*Backgroundfluctuations*Unavoidablysmallsamplesizes*Thepresenceofinterferingradionuclides
- Selfabsorptioncorrections
- Decaycorrectionsforshorthalf-liferadionuclides*OtheruncontrollablecircumstancesIntheseinstances,thecontributingfact orswillbenotedinthetablewherethedataare presented.
Asummaryofdeviations /abnormaleventsispresentedin Table2.3andincludesadescriptionofanysampleresultsthatdidnotmeetaprioriLLDrequirements.P'_.N (ISANNUAI.RADIOLOGICALENVIRONMEN TALOPERATINGREPORT-2 0O9 16 6.3.LLDandReportingCriteria O verv i ewMakingareasonableestimateofthelimitsofdetectionforacountingprocedureoraradiochemicalmethodisusuallycomplicatedbythepresenceofsignificantbackground.It mustbeconsideredthatthebackgroundorblankisnotafixedvaluebutthataseriesof replicateswouldbenormallydistributed.Thedesirednetactivityisthedifferencebetweenthegrossandbackgroundactivitydistributions.Theinterpretationofthisdifference becomesaproblemifthetwodistributionsintersectasindicatedinthediagram. BACKGR O UND G R O SSIfasufficientnumberofreplicateanalysesarerun,itisexpectedthattheresultswouldfall inanormalGaussiandistribution.Standardstatisticsallowanestimateoftheprobabilityofanyparticulardeviationfromthemeanvalue.Itiscommonpracticetoreportthemean+/-oneortwostandarddeviationsastheresult.Inroutineanalysis,suchreplicationisnotcarriedout,anditisnotpossibletoreportaGaussianstandarddeviation.Withcounting
procedures , however ,itispossibletoestimateaPoissonstandarddeviationdirectlyfromthecount.Dataarecommonlyreportedasthemeasuredva lue+oneortwo P oissonstandarddeviations.Thereportedvaluesarethenconsideredtogivesomeindicationoftherangeinwhichthetruevaluemightbeexpectedtooccur .ALLDisthesma llestamountofsampleactivitythatwillyieldanetcountforwhichthereisconfidenceatapredeterminedlevelthatactivityispresent.LLDsarecalculatedvaluesforindividualradionuclidesbasedonanumberofdifferentfactorsincludingsamplesize,countingefficiencyandbackgroundcountrateoftheinstrument,thebackgroundandsamplecountingtime,thedecaytime,andthechemicalrecoveryoftheanalyticalprocedures.Aminimumdetectableactivityvalue(MDA)isthesmallestamountofactivity thatcanbedetectedinanactualsampleandusesthevaluesobtainedfromtheinstrumentandoutcomeoftheanalyticalprocess.Therefore ,theMDAvaluesmaydifferfromthecalculatedLLDvaluesifthesamplesizeandchemicalrecovery,decayvalues,ortheinstrumentefficiency , background ,orcounttimedifferedfromthoseusedintheLED calculation.P'_.'NGSANNUALRADIOLOGIC,_,LENVIR ONMENTALOPERATINGREPORT-2 009 17 ThefactorsgoverningthecalculationoftheLLDandMDAvaluesarediscussedbelow: I.SampleSize2.CountingEfficiencyThefund a menta lquantityinthenleasurementofar adioactivesubst anceisthenumberofdisintegrationsperunittime.Aswithmostphysicalmeasurementsinanalyticalchemistry,anabsolutemeasurementofthedisintegrationrateisseldompossible,ratheritisnecessarytocomparethesamplewithoneormorestandards.Thestandardsdeterminethecounterefficiencyth atmaythenbeusedtoconverts a mp lecountsperminute(cpm)to disintegrati onsperminute(dpm).3.Bac kgroundCountRateAnyc ounterwillshowacertaincountingratewithoutasampleinposition.Thisbackgroundcountingratecomesfromseveralsources:1)naturalenvironmentalradiationfromthesurroundingmaterials,2)cosmicradiation ,and3)thenaturalradioactivityinthecountermaterialitself.Thebackgroundcountingratewilldependontheamountsofthesetypesofradiationandthesensitivityofthecountertotheradiation.4.Ba c kgr o un dandSam pleC o unt ingT i meTheamountoftimedevotedtothecountingofthebackgrounddependsonthelevelofactivitybeingmeasured.Ingeneral,withlowlevelsamples,thistimeshouldbeaboutequaltothatdevotedtocountingasample.5.TimeInter v al b etween S a m ple CollectionandCountingDecaymeasurementsareusefulinidentifyingcert ainsh ort-livednuclides.Thedisintegrationconstantisoneofthebasiccharacteristicsofaspecificradionuclideandis readilydetermined,ifthehalf-lifeissufficientlyshort.ToensuretherequiredLLDsareachieved,appropriatedecaycorrectionvaluesareusedtoaccountforradioactivedecay duringtransittimeandsampleprocessing.P'_GSANNU ALI_DIOLOGICALENVIRONMENTALOPERATINGREPORT -2 009 18 Table6.10DCMREQUIREDLOWERLIMITSOFDETECTION(apriori)AIRBORNE ANALYSIS/WATERPARTICULATEorMILKVEGETATIONNUCLIDE{p Ci/liter)GAS(pCi/m 3t{p Ci/liter I (pCi/kg, w e t)GrossBet a 4 0.01 H-3 2000*Mn-54 15 Fe-59 30 Co-58,60 15 Z n-65 30 Zr-95 30 Nb-95 15 1-131 1"*0.07 1 60 Cs-134 15 0.05 15 60 Cs-137 18 0.06 18 80 Ba-140 60 60 La-140 15 15 NOTES:*Ifnodrinkingwaterpathwayexists,avalueof3000pCi /litermaybeused.**Ifnodrinkingwaterpathwayexists,avalueof15pCi /litermaybeused.Thislistdoesnotm eanthatonlythesenuclidesaretobedetectedandreported.Otherpeaksthataremeasurableandidentifiable,togetherwiththeabovenuclides ,shallalsobeidentifiedandreported.P\_GSANNUALRADIOLOGICALENVIRONMEN TALOPERATINGREPORT-2OO9 19 Table6.20DCMREQUIREDREP ORTINGLEVELS AIRBOR N E ANALYSIS/WATERPARTICULA TEMIL K VEGETA T ION N UC LIDEt p C i/i iter)orGASt p Ci/m3)_p C i/liter)(p Ci/k g,wet)H-3 20,000*Mn-54 1, 000 Fe-59 400 Co-58 1,000 Co-60 300 Z n-65 300 Z r/Nb-95 400 1-131 2**0.9 3 100Cs-134 30 10 60 1,000Cs-137 50 20 70 2,000 Ba/La-140 200 300 NOTES:*Fordrinkingw atersamp les.Thi sisa40CFRI41v a lu e.Ifnodrinkingwaterp athwayexists , avalueof30,000pCi /litermaybeused.**Ifnodrinkingwat erpathway exists,areportinglevelof20pCi /litermaybeused.Thevaluesinthistablearequ a rterly averagevalues,asstatedinth e ODCM.P\.'N(iSAN'NUALRADIOLOG1CALENVIRONMEN TALOPERATINGREPORT-2009 2O Table6.3TYPICALMDAVALUES A N ALY SI S/A IR B OR NE V EGET ATI O N NU CLIDEWATE RMILKPA R TI CULATEor(pC i/k g,wet)t pCi/l iter)(p C i/l iter)G A S (pCi/m3)GrossBeta2. 8 0.00 3 H-3 295 Mn-5 4 12 Fe-59 25 Co-58 12 Co-60 13 Zn-65 26 Zr-95 22 Nb-95 13 1-131 10 a 10.04u 49 CS-134 12 10.04b 47 CS-137 13 10.05b 51 Ba-140 40 3 L a-140 14 1 NOTES:a-lowlevel1-13 1isnotrequiredsinc ethereisnodrinkingw aterpathw a yb-Basedon433in3volume P'_2NGS A NNU AL RADIOLOGI(AL ENVIRONMENT ALOPERATINGRE PORT-20o9 21 7.InterlaboratoryComparisonProgram7.1.QualityControlPro gr amAPSmaintainsanextensiveQA /QCProgramtoprov ideassurancethatsamplesarecollected,handled,tracked,andanalyzedtospecifiedrequirements.ThisprogramincludesappropriateelementsofUSNRCRegulatoryGuide4.15,Quality AssuranceforRadiologicalMonitoringPrograms(NormalOperations)-EffluentStreamsandtheEnvironment,Rev.1.Includedintheprogramareproceduresforsamplecollection ,preparationandtracking,sampleanalysis,equipmentcalibrationandchecks ,andongoingparticipationinaninterlaboratorycomparisonprogram.Duplicate /replicatesamplesareanalyzedtoverifyanalyticalprecisionandsamplemethodology.Comprehensivedata reviewsareperformedincludingtrendingofdatawhereappropriate.During20 09,APSanalyzedthefollowingsampletypesundertheinterlaboratorycomparisonprogram;
- Beta/Gamma/inAirFilter*1-131inAir*BetainWater*GammainWater
- TritiuminWater*GammainMilk7.2.IntercomparisonResu l tsAPSparticipatesinacrosscheckprogramusingvendorsuppliedblindradionuclide
samp les.Resultsf orthe i nterlaborat oryc omparisonpr ogramarepresentedinTable 7.1.P\LNGSANNI_ALt L A.DIOLOGI('ALENVIRONMENTALOPERATINGREPORT-2 0o 9 T ABLE7.1I N TER LA BO R ATORYC OMPARI SONRE S U LTS S a mpleT ypeAn a l , vsi s T_'peNuclidePVNGS ValueCertifiedValue _PTAcc e ptanc e Limit 2 Results Gan u na Ba-13388 94.279.4-104Acc e pt(_'s-13482 88.672.7-97.5AcceptCs-13763 7063-79.7 Accept WATER Co-60108 11099-123 AcceptZn-65122 114 1(!3-136AcceptTritiumH-33831 42303610-4660AcceptGrossBeta 37 46.131.0-53.3AcceptERARAD-76PTS tudyR e s ult sGalmnaAm-241133 13 290.4-178Accept (_'s-134713 790584-907 AcceptCs-I37876 913776-1090Accept WATERCo-601240 1 2 30l(170-1450AcceptZn-656 2 3 631535-786Acceptl-ritiumH-39695 118007680-17400AcceptFILTERGamnmAm-24174.3 55.4 3 2.4-76.0AcceptCs-134766 865563-1070AcceptCs-137793 7 2 4544-951Accept Co-6054(1 490379-612AcceptZn-65229 185128-256Accept (ir ossBeta 89 80.749.7-I 18Accept ERA M RAD-0 1 0PTSt udyResultsGatmnaBa-13387 92.978.3-1(12Accept WA-[ERCs-13474 79.465.0-87.3AcceptCs-13752 54.649.1-62.9AcceptCo-60115 117 11)5-131Accepl Zn-65 9 2 99.589.6-119Accept Gross B eta 23.25 26.0 16.2-33.9AcceptERARAD-79PTStudyResults FI LTERGrossBeta 83.8 62.538.5-91.3AcceptGrossBela 74.7 67.439.4-98.9Accept ER A MR AD-011PTStud y R es ultsThecertifiedvaluesar everifiedtomeetcriteriaasestablishedbyNISTNWLAPinHandbooks150and150 -19 a ndtheUSEPAinNationalStandardsforWaterProficiencyJestingStudiesCriteriaDocument(December30,1998).:"AcceptanceLimits"havebeencalculatedpertherequirementsoftheUSEPAinNationalStandardsforWaterProficiencyTestingStudiesCriteriaDocument(Decem ber30.1998).PXLNGSANNUA L I_DIO L OGI(A L ENVIRONMENTAL ()PERAIINGRE P OR T-2oo9 23 T ABL E7.1I NTE RLAB O R A T O R Y C OMP AR I S ON R E S U L TS 1SampleAnalysisNuclideKnownPVNGSsigmaResolutionRatioAccept /Reject Typ e TypeValueValueError* MixedMilkGamma1-13139.938.51.8210.97AcceptE6683-111Ce-14115.1171.7101.12AcceptCr-5145.645.56.771.00AcceptCs-13421.620.81.2170.96AcceptCs-13726.1281.4201.07AcceptCo-5823.424.61.3191.05AcceptMn-5428.832.81.6211.14AcceptFe-5917.723,12.3101.31AcceptZn-6534.736.02.6141.04Accept Co-6033.235.91.6221.08AcceptAirUIodineCart.1-13195.71017 .3141.06IAccept II E6684-111*calculatedfrom P V N(ISva l ue ilsigmaerrorvalu eAcceptanceCriteria
- ResolutionRatio 4-7 0.5-2,0 8-15 0.6-1.66 16-50 0.75-1.3351-2000.80-1.25
>200 0.85-1.18"FromNRCInspectionManual,InspectionProcedure84 7 50 ,"RadioactiveWasteTreatment,AndEffluentAndEnvironmenta_Monitoring" P\L NGSAN NUALRADIOLOGICALENVI RONMENTALO P E RATINGRE P O RT-2oo9 2 4 8.DataInterpretationsandConclus i onsAssociatedwiththeanalytica lprocessarepotentialrandomandsystematicerrors.Systematicerrorscanbecausedbyinstrumentmalfunctions,incompleteprecipitation,backscattering,andself-absorption.Randomerrorsarebeyondthecontroloftheanalyst.Effortsaremadetominimizebothsystematicandrandomerrorsinthedatareported.Systematicerrorsareminimizedbyperformingreviewsthroughouttheanalysis.Forexample,instrumentsarecheckedroutinelywithradioactivesources,andrecoveryandself-absorptionfactorsbasedonindividualsampleanalysesareincorporatedintothecalculationequationswherenecessary.Randomerrorsarereducedbycomparingalldatatohistoricaldataforthesamesiteand performingcomparisonsbetweenanalyticalresultswhenavailable.Inaddition,whendatadonotappeartomatchhistoricalresults,analysesmaybererunonaseparatealiquotofthesampletoverifythepresenceoftheactivity.Theacceptanceofdataisdependentupontheresultsofqualitycontrolsamplesandispartofthedatareviewprocessforallanalyticalresults.The"plusorminusvalue"reportedwitheachanalyticalresultrepresentsthecountingerrorassociatedwiththeresultandgivesthe95%confidence(2_)intervalaroundthedata.Mostsamplescontainradioactivityassociatedwithnaturalbackground /cosmicradioactivity(e.g.K-40,Th-234,andBe-7).Grossbetaresultsfordrinkingwaterandairareduetonaturalbackground.Gammaemittingradionuclides,whichcanbeattributedtonaturalbackgroundsources,arenotindicatedinthisreport.Resultsandinterpretationofthedataforallofthesamplesanalyzedduring2009arepresentedinthefollowingsections.Assessmentofpre-operationalandoperationaldatarevealednochangesto
environment alr a diati onlevels.Theonly n wa surableimp actontheen_qronmentin2009w as thelowleveltriti umdiscoveredinsubsurfacewateronsiteintheRCAin2006 .SeeSection2 .4fi_r specifi c infi_rmation.8.1.AirParticu l atesWeeklygrossbetaresults,inquarterlyfonnat,arepresentedinTables8.1and8.2.Gross betaactivityatindicatorlocationsrangedfrom0.013to0.080pCi /m3.Theassociatedcountingerrorrangedfrom0.001to0.004pCi /m3.Meanquarterlyactivityisnormallycalculatedusingweeklyactivityoverathirteen(13)weekperiod.Alsopresentedinthe tablesaretheweeklymeanvaluesofallthesitesaswellasthepercentrelativestandard deviation(RSD%)forthedata. Thegrossbetaactivityisattributabletonatural(background)radioactivematerials.Thefindingsareconsistentwithpre-operational baselineandpreviousoperationalresults. TheresultsaresummarizedinTable11.1.Table8.3displaystheresultsofgammaspectroscopyonthequarterlycomposites.NoCs-134orCs-137wasobserved. P\LN (ISANNUALt L_DIOLOGICALENVIRONMENTALOPERATINGREPORT -2 009 2 5 8.2.A irborneRadio i odineTables8.4and8.5presentthequarterlyradioiodineresults.Noairborneradioiodinewasobservedinanyofthesamples.8.3.Vegetat i onTable8.6presentsgammaisotopicdataforthev egetationsamples. Nogamma e mittingradionuclideswereobservedinanyofthesamples.8.4.MilkTable8.7presentsgammaisotopicdataforthegoatmilksamples.Nogammaemittingradionuclideswereobservedinanyofthesamples.8.5.Dr i nking W aterSampleswereanalyzedforgrossbeta,tritium,andgammaemittingradionuclides.ResultsoftheseanalysesarepresentedinTable8.8.Notritiumorgammaemittingradionuclidesweredetectedinanysamples.Grossbetaactivityrangedfromlessthandetectabletoahighof5.5pCi /liter(Gavetteresidence,Augustcomposite).Thegrossbetaactivityisattributabletonatural(background)radioactivematerials.8.6.Ground W aterGroundwatersampleswereanalyzedfortritiumandgammaemittingradionuclides.ResultsobtainedfromtheanalysisofthesamplesarepresentedinTable8.9.Notritiumorgammaemittingradionuclideswereobservedinanyofthesamples.8.7.SurfaceWaterSurfacewatersamplesfromtheReservoirsandEvaporationPondswereanalyzedfortritiumandgammaemittingradionuclides.ThetwoReservoirscontainprocessedsewagewaterfromtheCityofPhoenixandareapproximately45and85acresinsize.ThethreeEvaporationPondsreceivemostlycirculatingwaterfrommainturbinecondensercoolingandareabout200-250acreseach.EvaporationPond#3wasconstructedin2008toallowforre-liningoftheolderponds.EvaporationPond#2waspumpedintoEvaporationPond#3(sections3Aand3B)andwillberelinedfirst .ResultsarepresentedinTable8.10.1-131wasobservedintheEvaporationPondsintwo(2)samples(15to20pCi /liter)andfour(4)oftheReservoirsamples(13to32pCi /liter).1-131inthesesurfacewater locationsisaresultofradiopharmaceuticalI-131inthePhoenixsewageeffluent.TritiumwasroutinelyobservedintheEvaporationPonds.Thehighestconcentrationin EvaporationPond#1was1224pCi /literandthehighestconcentrationinEvaporation P\LNGSANNUALRADIOLOGICALENVIRONMEN TALOPER ATINGREPORT-2 0O9 2 6 Pond#3was991pCi /liter.EvaporationPond#2wasemptytheen tireyearduetolinerreplacement.TritiumwasnotdetectedintheReservoirs.ThetritiumidentifiedintheEvaporationPondshasbeenattributedtopermittedplantgaseouseffluen treleasesandsecondaryplantliquiddischarges.WRFInfluent(Phoenixsewageeffluentcontainingradiopharmaceutical1-131)samplescollectedbytheWRFwereanalyzedforgammaemittingradionuclidesandtritium.Theresults,presentedinTable8.10,demonstratethat1-131wasobservedroutinely.Thehighest1-131concentrationwas74pCi !liter.Noneofthesamplesanalyzedindicatedthepresenceoftritium.Table8.10alsopresentsgammaspectroscopyandtritimnmeasurements ofsamplescollectedfromSedimentationBasin
- 2.Thisbasincollectsrainwaterfromsiterunoffandwasdryformostoftheyear.Notritiumorgammaemittingradionuclideswereobservedinthesamples.8.8.SludgeandSedi m ent 8.8.1.WRFCentrifugewastesludgeSludgesampleswereobtainedfromtheWRFcentrifugeandanalyzedbygammaspectroscopy.1-131activityinthesludgeisconsistentwithhistoricalvaluesand
, aspreviouslydiscussed,isduetoradiopharmaceuticalsintheWRFInfluent.1-131waspresentinallforty-nine(49)samplesrangingfrom387to1670pCi /kg.In-Illwasalsoidentifiedinthesludgein3ofthe49salnples.Thehighestconcentrationwas97pCi ikg.ItwaspreviouslyestablishedthatIn-I11isalsousedinthePhoenixareaasaradiopharmaceutical.ResultsforWRFcentrifugewastesludgecanbefoundinTable8.11.8.8.2.Coo lingTowers l udge Sludge/sedimentoriginatingfromtheUnit3CoolingTowersand /orCirculatingWatercanalswasdisposedofintheWRFsludgelandfillduring2009.SampleresultscanbefoundinTable8.11.8.9.DataTrendsFigures8.1-8.5presentdataingraphicalformat.Historicaldataaredisplayedforcomparisonwherepractical.P\LNGSAN2qUA L RADIO L OGI('A L ENVIRONMENTA LOPERATINGREPORT -2oo9 27
££_........ZVVVVVVVV<VVVVVVVV__ooc5ooooo zVVVVVVVV-:VVVVVVVV_;_r_,........z ,,_VVVVVVVV<*_00000000 -;I_ooo=o=oo_,.__.VVVVVVVV_:__vvvv vvvv<@vvvvvvvv./1m,_ddddddddvvvvvvvv<VVVVVVVV Zl , ,.,/\'v'_'VYVV'_VVV_VVVVVV'+VVVVVV_i_oooo_ooooo_ oooo_oo_o_ o z*_*_+____________ +_VVVV\iVV\:V',/V_d\i\/VV\/\/\/\iV\:V7"v',..,.;Z"7\1_dV\1VV\1VVVV\1VVV\i\/\:\, i\'V\/V"v__............. +_______--',,vv_°?'?_\,'\,vvvvvvvvvv,,,,,*-___...<ooo_,__.oooo_,oo -_l_VU\,'",/'v'Vk_k/V'vVV', Jv'vv\'_/'+VV'v'vV\"_I__I_ir,'-i_1 " w'h I..,,*-__t'"l--"d"r__t ri',_...............,_i__,__,_,____,___,__ >,, h,q_1._,,_,,__-_i tlr_"_i t_,,__,-_r I__________________ +V'+V\i\i\1V\;\1\!'dW V\iVVV\iV\:\JV_'V_+_,___--'l"_c_o_o_ooooc_____',,I,"_____--"____d_---Z]_\'\,'_,,,!t ,,Vvk ,v'vV__1_V'v'V '+V\'VVv_+V\;"":J"I"-_r__r, C el@rnr--__@-4:"1.r_,Q el@--@".__elQel.i,.,.Ill',-"V\ i x ,,'\vVv,,/V',/VVv'*-.Iv'v'V\ ,v'_.=','v\,+vv\/VV\;_" V'd'v"'d_,/'d\dV_V"v't,,, ,,_,/'vv\/'<V'VV©_l_rm e l__+1"_.l1._tmr'_"+1-t-_1.'1"tr,el r',',rm1."1-_z" ,=_"'+V_VV W_VV'vVvvY ,V\"'v'vVV<el el,Ao_4,_i--tG-__' ¢.d--<g__r-'lot_,-_,o.
TABLE8.6VEGETATI O N ODCMrequiredsamplesdenotedby*unitsarep C i/kg,wet<6 0<60<80 LO CATIONTYP E DATEC OLLE CTED1-131 Cs-134C s-137 B A T DOR F RESID E N C ENOSAMPL ES AVAI L AB LE (S i t e#47)*greencabbag e 16-Jan-09<60<54<67redcabbag e 1 6-Jan-09<47<58<69savoycabbage 16-Jan-09<46<57<45DUNCANgreencabbage 13-F eb-09<56<34<73 FA MILYredcabbage 13-Feb-09<52<41<67FARMSsavoycabbage 13-F eb-09<56<41<49 (S i t e#62)*savoycabbage 1 3-Mar-09<41<55<61redcabbage 13-Mar-09<43<58<74 greencabbage 13-Mar-09<46<49<54redcabbage 16-Apr-09<58<59<69savoycabbage 16-Apt-09<56<56<63greencabbage 16-Apt-09<56<49<14P_,'NGSAN NUALRADIOLOGIC ALENV IRONMENTALOPEK4,T IN(IREPORT-2 009 33 TABL E8.7M I L KODCMrequiredsamplesdenoted b y*unitsarepCi /liter SAM PLE D A TE<1<15<1 8<6(7)<15 LOCATIONCOLLECTED1-131Cs-134Cs-137Ba-140La-140 RODRIGUEZ 23-Oct-09<1<1<1<3<1 COW S 12-Nov-09<1<1<1<3<1 10-Dec-09<1<1<1<3<1 GOA TS (Si te#51 J*NOS A M PL ESA V AILABL E DAVIS GOATS NO S A M PL ES AVAILABL E (Si te#52)*23-Jan-09<1<1<1<3<127-Feb-09<1<1<1<3<120-Mar-09<1<1<1<3<124-Apr-09<1<1<1<3<1 M AR TI N 22-May-09<1<1<1<3<1 GOATS26-Jun-09<1<1<1<3<1 (Si t e#53)*24-Jul-09<1<1<1<3<12l-Aug-09<1<1<l<3<118-Sep-09<1<1<1<3<116-Oct-09<1<1<1<3<l12-Nov-09<1<1<1<3<111-Dec-09<1<1<1<3<113-Feb-09<1<1<1<3<1 H E R N A N DEZ 27-F eb-09<1<1<I<3<1 GOATS16-Apr-09<1<1<1<3<1(Site#5 4)15-Oct-09<1<1<1<3<106-Nov-09<1<1<1<3<1 P'v,'NGSANNUA[RADIOLOGICALENVIRONMENTALOPERATINGREPORT -2009 34 v_Vr--_VVVV,_VVV ,,o.r-q.__._!_.r-,!__._V _._VVV VVV_".,_VVVVVVVVVVVVVVVVVVVVVVVV z-,1:..a vVVVVVVVVVVVVVVVVVVVVVV7_-vvvvvvv'-78"T_?8"vT'Tvvvvvvvv_7vvvvv?T_'T?_'8_°°-°-- -_,_5TT'T_vvv_TS'S' <£[....=__"_vs"vvvvvvvv<TT__"TTS'_vvvv_'T_"8 >___O_VVVVVVVVVVVVVVVVVV V V VVVV_8,_?,-_-._"_v z_vvvvvvvvTTvvvTvvvvvvvvv%/VVVVVVVVVV I I ,_'_,__,pq_1,r-Ir"q I r_'-_'VVVVVV.,__',/_VVVVVVVVVVVVVVVVVVVV'v'VVV £--r',l,r'-I_1r'q_1_1_;I_1,r'-I '__VVVVVVVVVVVVVVVVVVVVVV,7__,'vvvvv_?'T?'Tvv,,_vvvvvvvvv -=vvvv ,'zvvvTTTTvv'_vvvvvvv =_$$$$$$$$$$$$$$$$$$$$$$$$ _'_
VVVV VVVV VVVV VVVV*VVV VVVVVVVVVVVV v VVV VVVV VVV VVVV _'_0_9I_'---_O0VVVVVVVV__a,,,ooooor---__ .-VVVVVVVVVVVVVVVVV_"V_,_.._.::a::,-..._tmv_vvvvvvvvvvvvvvvvvE__-'-',d>V(,_r_VVVVVVVVVVVVVVVVVV--rm,,_(_,_,_,=d.vvvvvTT?vvvvvvvvvv_a,- k)*--r%0-_*v.-_TTT..T-_T_vvvvvv=.___vvvvvvvvvvv_-_"-r__.-._--,vVvVVVVVvVvV_',.__,'_vv_oE-1_-_,'-_s_'<_'T_vvvv--='-"["-_vvvvvvvvvvvvvv--__t"'l t'_l t*"lt"l_0',,_vvvvv?vv?vvvvvv-_,=,v_vvvvvvvvo.vvug_V VVVV_..VVVVVV V_VVVVVV__,,°'°,s;.-+/-,z _-,'--_.__.--_E_._ ! _TT_"vTv_"v_vvvvT_"vvTvTT_"v_vTvvv °m_0_0I_V V Vavvv_vvv7vTv7vvvvvvvv .,.1v'T_vvvvvv4v d7S'78v7v'_v7vvT'vvvvvvvv sVVVVVVVVVVVVVVVV_'VVVV f V V_-6 8 TABL E8.11SLU D GE/SE D IM EN TODCMreq uiredsamples d e notedby*units are pC i/kg, w e t SAMPLE DATE L OCATIONCOLLECTED1-131Cs-13 4Cs-137In-111 6-Jan-091372+171<15<30 13-Jan-091670+344<21<27 20-Jan-091404+/-181<31<9 26-Jan-09651+/-100<24<26 3-Feb-09404+/-91<15<24 10-Feb-091(1512143<25<2782+/-40 17-Feb-091122+/-143<25<1997+/-43 24-Feb-091079+/-227<18<263 8+/-31 3-Mar-09866+215<144<177 10-Mar-09714+174<111<177 17-Mar-091301+259<141<148 24-Mar-091312+249<1 22<1753l-Mar-09895m22{)<143<179 WRF 7-Apr-09833+/-213<146<132 CENTRI F UGE 14-Apt-091201+238<13(i<169WASTESLUDGE28-Apt -09464+/-160<149<114 5-May-0 9664+/-186<134<176 12-May-091303+/-219<110<166 19-May-09831+/-253<135<144 26-May-09612+/-178<143<148 l-Jun-09499m214<101<134 9-Jun-09777+170<128<176 16-Jun-09912+/-242<138<163 22-Jun-09 1006+20l<115<148 29-Jun-091(t28+/-222<137<169 6-Jul-091377+/-278<135<153 13-Jul-09835+/-230<146<111"_"_9<135<151 20-Jul-0911_,.,+/-,_28-Ju!-09722+/-221<93<168 3-Aug-09909+216<96<135 10-Aug-091631+242<111<112 17-Aug-091003+229<146<98 24-Aug-09!636+/-316<146<166Note:Thesamp levo lumewas].oweredto250m linMarchandtheMDAsincreaseddue tothesmallervolume.PVNGSANNITALRADIOLOGICALENVIRONMENTALOPERATINGREP{)R] -2009 42 T ABL E 8.11 SL U DGE/SEDIM ENT ODCMr e quireds aml fle s denotedby*unitsarepCi/kg , w e t SAMPLE DATE LOCATION COLLECTED1-131Cs-134Cs-137In-Ill 1-Sep-091457+296<121<172 7-Sep-!)9876+/-2!7<142<135 15-Sep-09791+222<1 4(!<1(16 22-Sep-09829+184<142<113 29-Sep-09953+287<142<176 WRF 6-Oct-091032+214<145<156 CENTRIFUGE 13-Ocl-09 7 00+197<146<174WASTESLUDGE 20-Oct-09961+214<142<163 27-Oct-091109+/-241<86<134WRFshutdownform a in t enance 17-Nov-09387+124<115<168 23-Nov-09553+/-197<149<166 l-Dec-09469+/-167<96<108 8-Dec-09648+/-172<148<133 15-Dec-09741m167<127<161 21-Dec-09861+/-183<1(/5<13(I 28-Dec-091372-327<122<151PVNGSANNITALRADIOLOGICALENVIRONMENTALOPERATINGRE P_)RT-2O09 43 .3 eq_>_-0ooZo_,_-F 0_<_z<<__>___.=<<<VV w0_<>_
9.ThermoluminescentDosimeter(TLD)ResultsandData The e nviro nlnentalTLDusedatPVNGSisthePanasonicModel812D o sime ter.TheModel812isamulti-elementdosimeterColnbiningtwoelementsoflithiunaborateandtwoelementsofcalcimnsulfateundervariousfilters.TLDswereplacedinforty -ninelocationsfromonetothirty-fivemilesfromthePVNGS.TLDlocationsareshowninFigures2.1and2.2andaredescribedinTable9.1.T LDresultsfor2009arepresentedinTable9.2.Historicalenvironmentalgalmnaradiationresultsfor1985through2009arepresentedingraphicalformonFigure9.1(excludingtransitcontrolTLD#45).Figure9.2depictstheenvironmentalTLDresultsfrom2009ascomparedtothepre-operationalTLDresults(excludingsites#41,#43,and#46-50astheyweredeleted(andlaterassignedtoanewlocation)orhadnopre-opTLDatthelocationforcomparison).Thesitetositecomparisonsindicateadirectcorrelationwithrespecttopre-operationalresults.Itisevidentthattheoffsitedose,asmeasuredbyTLDs,hasnotchangedsincePaloVerdebecameoperational. P'v ,'NGSANNUALRADIOLOGICALENVIRONMENTA LOPERATINGREPORT-2009 49 TABLE9.1TLDSITELOCATIONS (dis tance sanddi rectionsa r e r ela t i v e t o U nit2 in m ile s)TL D SIT E LOCAT I O N LOC ATIOND E SCR I PTIO N 1 E 30Good y e ar 2 ENE2 4 S c ott-Libby S c ho ol 3 E21L i b e r tySc hool 4 E16Buc k ey e 5ESE11PaloVerd e School 6*SSE31APSGilaBendsubstation 7SE7OldUS80andArlingtonSchoolRd 8SSE4SouthernPacificPipelineRd. 9$5SouthernPacificPip elineRd.10SE5355 thAve.andElliotRd. 11ESE5339thAv e.andDobbinsRd. 12E5339thAve.andBuckey e-SalomeRd. 13N1Nsiteboundary 14NNE2NNEsit e boundary 15NE2NEsiteboundary,WRFaccessroad 16ENE2ENEsiteboundary 17 E2Esiteboundary 18ESE2ESEsiteboundary 19SE2SEsiteboundary 20SSE2SSEsiteboundary 21$3Ssiteboundary 22SSW3SSWsiteboundary 23W5NofElliotRd 24SW4NofElliotRd 25WSW5NofElliotRd 26SSW4SofElliotRd 27SW1SWsiteboundary 28WSWIWSWsiteboundary 29WIWsiteboundary 30WNWIWNWsiteboundary 31NWINWsiteboundary 32NNW1NNWsiteboundary 33NW4SofBuckeyeRd 34NNW5395thAve .andVanBurenSt. 35NNW8Tonopah 36N5WintersburgRd.andVanBurenSt. 37 NN E5363raAv e.andVanBur enSt.3 8 NE 5355t h Av e.andBuck e yeR d.39ENE5343rdAve.NofBroadwayRd. 40N2Wintersburg 41ESE3ArlingtonSchool 42N8Ruth FisherSchool P\'_'NGSAN'NI_!ALRADIOLO (iICALENVIRONMENTALOPE R A TIN G R EPO RT-2 009 5O TA BLE9.1TLDS ITELOCATIONS(distancesanddirectionsarerelativetoUnit2inmiles)TLDSITELO C ATION LO CATIONDES C RIPTION 43NE5WintersWellSchool 44*ENE35ElMirage 45**OnsiteCentralLaboratory(leadpig) 46ENE30LitchfieldParkSchool 47 E35 LittletonSchool 48E24JackrabbitTrail 49ENEI1PaloVerdeRd. 50WNW5SofBuckeye-SalomeRd.*Site#6andsite#44arethecontrollocations.**Site#45isthetransitcontrolTLD(storedinleadpig). P\.'NGSANNUALRADIOLOGICALENVIRONMENTALOPEtL4TINGRE PORT-2 009 51 TABLE9.22009 EN VIR ON M EN TAL T L D RES ULTS Units aremrem istdqtrTLDSi te#1 stQuarter2ndQuar ter3rdQuar ter4 thQuar terAvera g e I23.623.421.323 .022.8 221.822.120.420.621 .2 3 22.922.521.221.822.1 421.822.721.822.322.2 522.022.921.320.921.8 6(c o n n'ol)26226424.425.825 .7 724825123.024.624.4 823122921.722.022.4 927126526.227.026.7 I022423422.522.922.8 I I23i25422.723.023.6 1222723222.322.122.6 132372602 4.224.22 4.5 1424724223.624.224.2 1 523323622.422.823.0 1 621.121.320.821.5212 1723.424.323.124.0237 1823.12 2.82 2.122.5226 19 2 4.524.623.424.8 243 2023.824.12 2.723.3235 2 1 2 4.82 4.92 432 48247 2 225.325.1255256254 2 322.122.7205219218 2420.321.5212213211 25 22.021.9212221218 2 625.428.0251258261 2725.726.9251261260 2 824.426.6237253250 2 923.824.722223.623.6 3 024.725.723324.124.5 3 122.222.922322.422.5 3 223.924.724124.424.3 3 325826024.025.125.2 3427027525.225.926.4 3529631029.229.529.8 3 6246250missing23.524.4 3723923122.523.723.3 3826727526.026.026.6 39 23824022.121.722.9 4024824823.422.824.0 4127025726.625.826.3 4229.628329.228.729.0 4328.227726.525.827.1 44 (con t rol)19.720.619 .420.120.0 (t ransi t c o n t rol)6.25.85.55.6 5.8 4626.826.524.725.625.9 4 722.523.821.523 .522.8 4824.924.122.522.823.6 4 922.524.021.421.722.4._o19.218.518.618.218.6quarterTLDresul tsweredelayedduetoanidentifiedbiaswithresults.RefertodocumentCRDR
- 3439215.P\tNGSAN_NU ALRAD1OLO(}ICALENVIRONMENT A L O P ER A TINGREP(}R]-2009 5 2
+60-dasi60-q: IN:.__8 0-oaS z L 0_a_S L 0-JFIAI_(()_aaS_0-J r'I N_.o._-Z ,.__()_daS4__>-+IO-OaS[_i00"d_S<'00-jp.I A l ,£'66-d_S-486-a aS a_66-J_IAI>l'_I86"JPIA!k 6.dos L 6--ml A I 96-dQq96_Jt,iAl__6-dos S 6-JeIN__6-doS-4 U c6-°°S_6-o a S_6-J,HN 16-ooS[6-JP'IAI 06-ooS:_,()6-J_IAI 68-0_Si68-q;_I Z_88-ooS ,_88--1NN L S-OOS L g'JHN r_+98_00S_'_i98-'IFN c8-uoS S 8-JeBI Lv-000000 000 6_0_r O a 0 O0(0(N I Oq CqCqO W v-a!bp ls/Hm
10.LandUseCensus10.1.IntroductionInaccordancewiththePVNGSODCM,Section6.2,theannualLandUseCensuswasperformedwithinfivemilesofUnit2containmentinApril2009.Observationswere madeineach ofthe16meteorologicalsectorstod eterminethenearestmilkinganimals,residences,andgardensofgreaterthan500squarefeet.Thiscensuswascompletedbydrivingtheroadsandspeakingwithresidents.TheresultsoftheLandUseCensusarepresentedinTable10.1anddiscussedbelow.ThedirectionsanddistanceslistedareinsectorsandmilesfromtheUnit2containment.10.2.CensusResu l tsNearestResidentTherewere_ro(2)changesinne arestresidentstatus.Dosec a lcul ationsindicatedthehighestdosetobe0.229mrem.MilkAnimalTherewerefive (5)changesinmilkanimalstatus.Dosecalcul ationsindicatedthehighestdosetobe0.872mrem.VegetableGardensTherewerefour (4)ch angesinnearestg ardenst atus.Dosec a lcul ationsindicatedthehighestdosetobe0.332mrem.SeeT able10.1forasunmaaryofthespecificresultsandTable2.1forcurrentsample locations.P\.'NGSANNUALRAD1O L OGI (2ALENVIRONMENTALOPERATINGRE P OR T-2 009 55
TABLE1 0.12 009LANDUSECENSUS(Distancesanddirectionsa rerelati vetoUnit2inmiles)NEARESTNEARESTNEAREST CALCULATEDDOSESECTORRESIDENTG ARDENMILKANIMAL (to r ero)CHANGE (COW/GOAT)FROM2008 N1.55NONE2.6 9 Reside n t 39 2 E-0 2 GARDEN Milk3.50E-01MILKNNE1.522.23 2.0 5 Reside nt786E-02GAR D EN Ga r de n 3..,_E-01 M I LK M il k 7.60 E-0 1 NE 2.1 6 N O NE 3.9[Res ident1.1 4E-O1 M i lk 5.4 1 E-01ENE2.054.72 2.52 Residen t809E-02 RE SIDEN T G a rde n 1.00E-01 GA R DEN Mi lk 5.9 1 E-0 1 MI LK E 2.8 1 N ONEN ONERe sid en t 5.2 3E-02 E S E 1.89N O NE 1.9 5 Re si dent1.3 2 E-0!M I LK Mil k 8.7 2 E-0 1 S E 3.36 N ONE3.4 0 Re sid e nt 8.8 0 E-0 2 M IL K M i lk 5.3 0E-01 SSEN ONEN ONEN O NE N A S 4.6 7NONENONEReside nt2.29E-01RE SIDE NT SSW N O NE NONEN ONENA SW1.39 NONE N ONE R eside nt1.41E-0 1WSW0.75NONENONEResident 1.08E-O1W0.70NONE N ONE R esident 5.02E-02WNW2.67NONENONEResiden t 1.05E-02NW0.93NONENONE Resident3.71E-02NNW1.304.34NONEResident2 .91E-02GARDEN (iard e n 4.70E-02 COMMENT S:Dosecalculationsw e r eperformedusingtheG A SP ARcodeand200 8 met eorologicaldataandsou r ce ter m Dos ereportedforeachloca t io nisthetotalforallthreePVNGSUnitsa ndisthehighestindividualdos e id entified(organ,bone,totalbody,orskin). PX,,_q GS A NNUAL R ADIOL O GIC ALENVI RONMENTALOPEK_' [I N (i R EPO R T-2 009 56 11.S ummaryandConclusionsTheconclusionsarebasedonareviewoftheradioassayresultsandenvir onmentalgammaradiationmeasurementsforthe2009calendaryear.Wherepossible,thedatawerecomparedtopre-operationalsampledata.Allsampleresultsfor20 09arepresentedin Tables8.1-8.11anddonotincludeobservationsofnaturallyoccurringradionuclides,withtheexceptionofgrossbetainairandgrossbetaindrinkin¢water.Table11.1summarizestheODCMrequiredsamplesandisintheformatrequiredbytheNRCBTP o n E nvironme m a l Monitoring.1-131concentrationsidentifiedonoccasionintheEvaporationPonds,WRFInfluent,WRFCentrifugesludge,andReservoirsistheresultofoffsitesourcesandappearsintheeffluent sewagefromPhoenix .ThelevelsofI-131detectedintheselocationsareconsistentwithlevelsidentifiedinpreviousyears.TritiumconcentrationsidentifiedinsurfacewateronsitehavebeenattributedtoPVNGSpermittedgaseouseffluentreleasesandsecondaryplantreleases.Theseconcentrationsareconsistentwithhistoricalvalues.EnvironmentalradiationlevelsareconsistentwithmeasurementsreportedinpreviousPre-operationalandOperationalRadiologicalEnvironmentalannualreports ,References1and2.Theonly m easur ableimpactontheenviron mentin2009 wasthelowleveltritiumdiscovered h isubsurfiwewateronsiteinti leRadiologiealControlledAreah i 2006.SeeSection2 .4fi_r_wecif!cinformation .P\,'NGSAN NUALRADIOL()GICALENVIRONMENTALOPERATINGREPORT -2 009 57
u_L_Z ,r'l>.,.,-,_.__:<<:<<:<<<<<<<<<<<<<<<<z_,__=zzzzzzzzzzzzzzzzzzzz__-g-<--:--,.+Z__'_..j,j_j__,._._.j_j.j_._._ =Z_-_.JJ___.JJ.J_.__-__.J__*__.,VV_,/'VV'v'__R.',.'VVV'v'V'vV'_'VV<o<,.)_, D.oZZZZzZ2=ZzzzzzZzZzzzz< Z_'-<<<::<:<:<:::_:__<:<:<::<::<::_<<:'<<:<::<:_E__.-2_0-'_Z_m0<__ff ,_,-,__r,___r_r-i"_'v,/\,'v'v,: v o o<_"-_.._.2 W-o,._--7__"1"_,'__......+...,.__+++++++++=+__.c,__;__c_._
1 2.R e fe ren ce s1.Pre-Oper ationalRadiologicalMonitoringProgram,SummaryRep ort1979-19852.1985-2008AnnualRadi o l ogicalEnvir o nmen talOpera tingRepor ts,PaloVerdeNuclearGeneratingStati o n3.PaloVerdeNuc learGeneratingStati onTechnicalSpecificat ionsandTechnicalReference Manual4.Offs iteD o se C alcu lationManual,PVNGSUnits1,2,and35.Regulat oryGu ide4.1.Pr ogramsf orMonit oringRadi oactivityintheEnvir o ns ofNuclear P owerPlants6.Regulat oryGuide4.8,Env i r onmentalTechnica l Specificat ionsforNuc learP owerP l ant s 7.NRCRadi ologicalAssessmentBranchTechnicalP o siti o n onEnvironmentalM o nit o ring , Re vision1,N ovember1979 (Inc o rp oratedint oNUREG-13 0 1)8.NEI07-07,NuclearEnergyInstitute,IndustryGroundWaterProtectionInitiative-FinalGuidanceDocument,August2007 P\'_'NGSANNUALRADIOLOGICALENVIRONMENTALOPEt LaITINGREPOR T-2 009 62 2009AnnualMonitoringandComplianceReportAPPNO.P-100388APPENDIXBELECTRONICDATA(CDincludesPDFofentirereport) ................................................................................................................................ --I1: 1J:.],',,_i]_, e.]__, 2'#1!E---............................................................................. 2009AnnualMonitoringandComplianceReportAPPNO.P-100388APPENDIXCOTHERREQUIREDINFORMATIONAPPENDIXC1-VERTICALTRENDANALYSISAPPENDIXC2-ANALYTICALDATAOUTSIDEQA /QCORPERMITDETECTIONLIMITSAPPENDIXC3-
SUMMARY
OFALLWELLDATA(2009) ,,,rv........................................................................................................................-!:li,i ,Jn_llt'Tf:t!m- -.................................................................................................... 2009AnnualMonitoringandComplianceReportAPPNO.P-100388C1-VERTICALTRENDANALYSISSection14.4.1A.1oftheP ermitstat es"Usin gcross-sectionsof3-Dmodels ,ther eportshallassessdownwardconcentrationtrendsforindicatorparametersandAWQSconstituents,ifany,andshallconsidersuchtrendsincombinationwithtopographyoftheuppe rmostsurfaceoftheaquitard."InpreviousversionsofthePermit,indicatorparameteranalyticalresultsfromshallowaquiferAcolumnwellssuchasPV-14H,werecomparedwiththeanalyticalresultsfromnearbyshallowaquiferdeepBcolumnwellssuchasPV-14HB.(Typically,theAcolumnwellshavealongerscreenedintervalthantheBcolumnwells. ThedepthofthebottomoftheAandBcolumnwellsaregenerallythesame,buttheBcolumnwellshaveashorterscreenedintervalacrossthesameportionoftheaquifer.)ThereportedBcolumnindicatorparametervalueswerethencomparedwithAcolumnwellindicatorparametervaluesaspartoftheverticaltrendanalysis.LatermodificationsofthePerrmteliminatedtherequirementtosampletheshallowaquiferdeepBcolumnwells.Assuch,for2009therewerenoAandBcolumnwellpairssampledwhereverticaldifferencesingroundwaterqualitycouldbeevaluated,thereforeasimilardownwardconcentrationtrendanalysisforindicatorparameterscouldnotbeconducted.However,therewereshallowaquiferandnearbyPaloVerdeClayaquifermonitoringwellssampledinthreelocationsatthePVNGSsite.Thethreewellpairs,thescreenedintervalsmonitoredandtheboronandchlorideindicatorparameterresultsarepresentedinTableC-1.Ascanbeseenintheresults,itisevidentthatchlorideconcentrationsintheshallowandPaloVerdeClayaquifersdifferbyatleastoneorderofmagnitude, andaremuchhigherintheshallowaquifer.Boronconcentrationsforthetwoaquifersaresignificantlydifferent,alsogenerallymuchhigherintheshallowaquifer.ThisdatahelpsdemonstratethatduetothevetTheterogeneous,lowpermeability,free-grainedmaterialrepresentedbytheMiddleFine-GrainedUnit,vertical migrationofgroundwateratthesiteisverylimited.IIfI[.1" ,'1i_l l_[_k ,_,I: ll lP:APSPVNGS138949-2009Annualr'donandComplReporl_Delive_ables\ReportsFinalFinalAPS-PVNGSAnnualReport2009doc
APS-PVNGS2009AnnualMonitoringandComplianceReport SAMPLE(mI l L)Approx.PaloVerdeClayAQUITARDELEVATION LOCATION amsl)DATEBoron(feetamsl)888.6-843.62 /27/20096.72,000 729888.6-843.66 /10/20096.92,100888.6-843.69 /17/20097.02,100PV-34H888.6-843.611/6/20097.11900746.8-726.82 /27/20090.62180 729746.8-726.86 /10/20090.66190 746.8-726.89/16/20090.59180APP-5746.8-726.811 /5/20090.65200 I'....886.8-856.83 /12/20091.34,500 743886.8-856.86 /17/20091.45,100 886.8-856.89 /25/20091.45,000PV-R2AR886.8-856.811 /19/20091.34,800773.13-743.133 /12/20090.58120 743773.13-743.136 /17/20090.63120773.13-743.139 /30/20090.64120APP-7773.13-743.1311 /19/20090.59120897.3-847.32 /11/2009165,500 744897.3-847.35/21/2009175,500
897.3-847.38/4/2009165,700 PV-206A897.3-847.310/29/2009185,600 776.02-746.021 /16/20090.88190 744776.02-746 .022/10/20090.89150 776.02-746.025 /7/20090.98170
776.02-746.027 /23/20090.89170APP-8776.02-746.0210 /28/20090.86180 Notes:amsl=abovemeansealevel
mg/L=milligramsperliterPAAPS-PVNGS\138949-2009AnnualMon.andCompl.Report\Deliverables\Reports\FinaRAppendixC\2009TableC-1Ver ticalTrendsxlsPage1of1 2009AnnualMonitoringandComplianceReportAPPNO.P-100388C2-ANALYTICALDATAOUTSIDEQA /QCORPERMITDETECTIONLIMITSTableC-2presentsasummarytableofallanalyticaldatathatwasoutsidetheQA /QCorpermitdetection limits...................................................................................... --_i t,j_[,l,,jiIne_l__,z_dj ii_............................................................................P:APSPVrqGS138949-2009Annualr'donandComplReport,Delive_abies'Reporls' Finaf,FmatAPS-PVNGSAnnua!Reporl2009doc _-o*i<_.E 0 t)Z'o c<o_o ('4-_i___-___°°__o_o_°_°°_°°_°I_°_°_EE_"_"__'_'_'_E ZEE_'EEEEEEEEEEEEEEEEEEE _oo....oo ooooooo_ooooooooooooi......._,____ol__oooooo o o vvvvvvvv@I__"-°-°-°-00oo oNN_N_NNooo__oooo!o8N.....NNN_NNNNNNN_NN' g©7_g_g_ E O o" E o<Ob O O
("4_....o_oooloo I......................
_ooooo°o_o__oooooo°o,oq.o.o.olo__oooooooc_oc;c;c 5 c_c5c 5_!oc5c 5oc 5 c 5oooooooooooooooc_c:;c 5c_oc_c_ooc_c;c_lOc 5 c 51oc_o___°1....o......o.... I_.oN,N__o____o___o____0__o___
- ___1i___c5_5_ooc5o_o' O'_5"o'_5"o'c5"c_'o'o'c_'c;c5oo'_5oc:;ooc:;o_I,::_"oooc_c¢oo'o,oo oo_oooo_oooooo_ooooooooooooo_o_oooo oo_o o o<<<,<_<'_<<<<<<'_<<<<<<'___o_a_a_a_o_a_a.a_
c_a_0..0-_-I___.0__0_"_13__1;1_13_13_1_..n Q..13_1__1__0_13_13_1__O_nD_nnl3_n3_IL.ULU.ULULULULU_LULULULUWLULUL ULULULU_LUWlL U_L U ,0"i, g,,,,,,wwwww,,w,,,wwwwwww,,_5 a_ I EEEEEEEIEE_: 5c;c 5 o'o¢::;c;°ooooooo_;c;'___ 5c;¢:::;55": 5"5c;¢5c 5¢55"5"5" 55c;__o........ooDD........18 ,8°Ng....88.......Ng_8....°°°°°°°_'_ D___°_'i05o...................I_vvvvvvv£_>__-______>_ -_,--}__o___-__i_ godc:5_:::;_::_ 'd 0_::;'(::_c::;_5 "_::5_::;c:::;ooooooooo*:_ooo'J_:5d55 5"5'5o,o_.__.o°8o_oggggOoO8_ggg!wuauJ,,,,,, uJ ,,,_uJwwwww,,_,n_:___:__-ww ,,_J, ,.u o©a_6 _oooo E_,SS'SS5S7,'_,_oo__ooo__ooooo _J 1 z3 ,ooo__o: 5_ooooo.o.oo_oo;oooo o.q.q.olo.qo°S_go°o°o_c_,:: 5o<: 5ooc 5oooooooc5c: 5oooo D C 5_;C 5C;c::;_5_;c;o_ 5_oIooIoooooOOoooo_o_ooooOooo_o__ooOoO___Io__...........QQ,q,qQg...._°°°°_o_.......o__ -ooo_ooooooooovOOOOOoo°v° ?°,,v, ,vooooo?oo0.E___ooo_ooo_____.oo______o____,__-____.o_,___'__'___ ff;i__=___._, o_-_-__<,_,_g__,o_-<,',,o 5D&_<'_<_<<_"_<_'__!__'_1__uJuJLULUUJLUCI2LI AaJU J_U A UJ EN_sE ,N_N.........NNN_N_N5__N-5......°°°_1__o_l__i_oo_o______o__o_o___i.....__..........ooooo:Loi_o©N N E 0 0 5o_o zrr i E 0 (D g, o c©:s g g o cot¢<(-_.E 0 c)0 g==<Ob C) C)0,1 EEEEE ,dddJ_'_o°o°......o°_o°°°o°°o°°o°°o°°ooo______o_oooooo____gr_@@_-_:m@_o....o.q.QIo.QQo_o_@........oooo5c5F='5"_':5"_'_':_'__oooc:'°6c_:5oooooooooooc5"I"?odo°doo _-_vvvv vvvvv>i>>_,,.,_.>>>>>>>>_J___I_I_I_I.[J.LI.UJ JILlLLII._WLULLILUW m m©a_ l.y aloo________oooooooo o,;6o6" D'_": 5_: 5_o_;oo_5___o Ioo..........vvvvvvvvvv o......oo'_'_5"o_;oo: 5:55: 5_1:: 5"D'_'::;':: 5"__5'_'O'c 5 D_r_'D._D.."__r__-"_3_3-3_""3-3-:1_3_O_D-_._D_k_1.1.1U J_kl A_U J;_A J A_1.I A_UJ A UJ_1k,UU J ob _,'m r",, o'J..-IJJ ,.JJJ ,,-JJJJ..J--JJ,,--IJ.JJJJJ--JEEEEEEEEEEEE EEEEEi__o__oo__o_o_oOOooo_o__o......_ooooooooooooooo_oo_ooooooo_oo!oo_ooo_ooo_o__o_°.o_°.........o_°.o-°.o_°o_°.oO°.oo°o_°,o_° ,_: 5'oc;ooo'o',::: 5 6,:: 5 o ,:: 5oo'o',:: 5"o_5 ,:: 5 c;oooooooooo W ,....................V'odd_v°,,v 0 0_:____________i________,___o ,-__=.__io_-_.,-,._gs_-_o__-'_=-_o_-_#',____g_ &_1 o_°....................ii......................_ O'o'c;'o'o o'c;'o o O u5oc;c_'c 5"c 5'o'c 5'c;'¢5"o'o'¢5" c 5_'c;o"c 5'oo"o'oo'c;>_ oooooo oooo-_*-ooooo o_'_oooo_oo oo_oo_o=U JU_II..UI.JJU.Il&lI._ AUJ1.1.1LUU AUJ_.1k_lU J I._AkU_.1[.UUJI.Llk_l.1.1WU J_AkLl_k_lUJklJLU o_E N_¢N oooo......oooo__o__Ooooooo___oo__oo__o...._____o_____ o__oo.QqlQ.qQ.qlqQq.Q.Qq.q____d__NN_NN__ o_oooooo oooo-_-.--_o_o m NN oooooooooooe'°d'° 'dd°'°'dd'° N NN oooooooooooooooooooooodd'°e°'°e°'dd'°'e°'°'e O'd'de'd'd°§ %E o 0 o c oooooooo o oooc_oooo o oc_oo o ooo!°....o_o_°oo c_'c 5c_o'oc 5 c 51oc 5 c 50oc 5 c 5 1'c 5'c 5"c 5"o'o'0"c_c 5 c 5oc 50c 5oc 5'oc 5 c 5 o W oooo oOooi.....oOoO oOoOoOioo_0o_,_o_o_oooo,o.o........_o_oOg_OO_oo_ol_,__°_vO,_-__voo_vI0_0d'd'O'C_c S"O'd'd'd'Ovvvvvvddvc___vC_c 5°v_c__v°v°©¢0_0__.__-___>_o-_o__o___o>_____o_....---__!__.___=___I___ ........-__-_.__._.__,_.__-_.-____ ,__,_o o oo o"*o'o'o'o'o'o'o'o'o'o'o'o'ooolooooddo°oooooooo°ooo )o o o c_oooooooooooooooooooo ooooooooo<<<<<<_:_<<<<<<<<<<<<<<<< <<<<<<<, 9:_:_.9:.9:_:_<.=13-I_13.0-_.1_13._I__1-13_13.13._13__._1:1_I_1_0_13_1 21__.__5_,_,,,,,,,,,__i,,,___,,,LIJLLII.LILULIJLLILIJLULLILLILLILIJLLIIJ_lLULIJLIJLULIJLU__ g:i_o__1_1__I_o_1_ooI___'_'o_oo_o_o_o_o_o_o_o_o_o_o_o__o_o_oo__o___o co N i ,,.i_zzb_3D_,,m Dn_¢h oEEEEEE EIE Eooooo ooo_ooo0ooooc;oc;__!oo_NNNN°Nooooooo_,o_NN_v_oo,__OvOvOOvOvoo,o ,_,__B_2,_,___,_2,_°°oo'_........I__=_c a_N <-_.E o t)" F-0 E<$o cq O9I::: r->_E 0 (9 c#o c4
2009AnnualMonitoringandComplianceReportAPPNO.P-100388C3-
SUMMARY
OFALLWELLDATA(2009)PAP_-P\JG_1J894o2009An nualMonandCompiReport,Delivelables,Repor[s,FmalFinalAPS-PVNGSAnnuaiReport2009doc =o>__-_>__-___o_>_-___.__-_-_. ,,, ,, ,_>_._,, ,________OOOOOO_OOOOO1"__OOOOOOCOOOO(-)OOCO_GOOO¢,%N°Noo_o,ooooooooooooooooooo g_ooooooooooooooNo_o_No_°_°"_°"ooo°'°°°°°°°°'°°°°°°°°2__04___o4o4o4o4_o4_o4_,.0o0oc£_0ococo___0ocoeo0£_ooooco__eo_ooco_ G_m¥if_c_ z_013d&E...._o_oo__'_o_,-_,56____o°o°°io__o__o_ooo*oo°o5_.--:.-z_o__ooo00000_0",10"C I:_0 ooo°°v°o_o_,._oovo_o__6__5_6o__vvvvvvv c oo_o-->!_E"__>__ooooooo'_____N=__oooooo_ %ooN_NNoooN _NNNoooo oooo_!_ooo_i§__oooooooo_oo_ooo_-________,_o% o>__o__.___0>ZZ__god_EE!_.....___I...._I°<<<___<<<<<__<<<<<1<i<<<<<<_ Iooooo____ooo_o______oooooooooo______o_ooooooooo o 2oo_____1___°°° ¥Y b oC, o_,_z_o.n"&00_13_E 8 m oooo._O_o_00______'_000000I_-_o°oo_o.oo0000000 0{,--9-__vvv, ,vvvv__N_____vvv____.._o_o Z_o_0n"00,c°13_E*°°_o_o_o_o.,__o_'-°_oo___o__°00000__C,4 c_'-_oc 5°°°°ooc 5ooooooo-__o t"-,_o_oo____oovvvv oo_,_,_v,.,.,oo,..-dvvov Loo_o_04aiooo°vvvvvvv Ob 0 0 O4
03z_0_n" ,_[: 13._Eoo_'_oo"_o..__,:-404,:,4oo.o.o,:5o._ _00oo000*'-'__,._,.oo_o°___0oooovo_E°._ovvvvvvvvo_o_oOv <_t'_ooooo z_conr_,<D_-u:._o 1:3_."_: E'-_o____o_oo_____o_o__o.E°°oo.o_oS_o_o__o__o___o_°ooooo ,--,ooo--ojo__..__o<5oc5o,:5oo,::5oLoc5,::5"-:o--Oo<5,::5o.o-)=..ac5oc5<5II_B ioo__vvvvv__ _:vvvvv__-_ o>z.__0,--_0___5>,>:,i::5i5_..._Ee_.=E__n...._0__=_,_ .c::_:.=._,nlZ::u -_i5....=oo_olo_I]1&__-_..,o_.__,_, ,:___-__:'N"_oo__-'=1":-_: '_,°°._o.__1=/_ t'-.-I_-I'_O0O0O0COI'_O0_I'_COO0O0O0¢0CO00O0O0_CO_004_I'_ "=ggg_ddddggggldddd'ddd,,gd_-dd_ddoooo!<<<<<<<,_o_<<<<<<< I I%°°°--o,Iooo_o_oo_o ,o_o_°_o_o_o_o_o_o_o_o_o_o_o_000000000000o___,___oooooo°o°°oooo _.;_C D___ooE__,___"_"__'__,_,..o___,__,_,____, ,__,_!,_,_2o_o_o_,o_o_o_o_o_o_o_o_o_o_o_o_o_o_o_o_o_o_o_o_o°°°°°_ooo°_°_°°°°°°ooo_ooooooo oooo___o,,ooooooooooo ___oooooooo n_ co z_O_CO Eoc5.....ooN_o_o_c5°c5-__ooo__ovo_o°__vv__vvvvvvIvv°' ,°°o°v,---°_°o4._--v_m_3 O4 z_o E8o___0000 O0 00000_--d0._0.0 , 0.0_!ooooooooooooooooo________oo__o>zo__o____5_r____5_5_c_ o.---_d_'-'....d__>,"-'_g_*-==E"_="EE_d,=-_'_.------__=o___...._..___,_i._o_o___0_==....__oo____.= r_o_i,,.,..-r--.._r,.-.._cocoooco io_.r-.-_r-,.-oooococo Jooooo('_coco_oooo,: '-q,_"do_o_o_°_°_o_o__o_o_o_o_o__o__o_°_o_o_o_oo oooo_o_°__o_o_oOOOOOOOOoooOOO___ oooooooooo o moooooooooOOOOOOOOOOOOOOOOOOoooooo_____oo 13_m s c0_-oz_-o_n"_L3-._:=.Eo0o ooOOooo__ooO__ o_._r ,,.__/__vv o__OOv_v_vvvv_Ov_v_ovl;o_. coz__3-n"_&0'3c n<__E,n_C'.4oooo__ooo ooOo°o_o__"_o_O_oOOOOOO6oOOO°__°oO_ c__.---J c 5oc 5 c 5 c 5"c 5"c 5oc 5oc 5 c 5 c 5 c 5 c 5:c 5°o-gr, ,____v,,oNMv,,vI__°oovv__vvvvvv_c: 5vvvv<__oo 0_Ob 0 0 C,4 z_c I Evvv,vvv_vvvvv_vv_v_v__ ._>="=--._I I.__oo_oo____,__--fl=_.-__d__'s's'____==o____ooo ©ooo4r....,- -...coooooooo_oo_ i,_.r_,:::::,r..--i._.or---r---o,_oO_oOoOoOoOoO_oOoO_$oooooOoOoO_oOoO_o_oOoOoOo_'2___"_'2__:____<_<_<_<_'_________:'2°_ N" 6oo_o_o_o_o__°_°_o_o_,_o_°_°_°_°_o__,_o________ooooo00000000._oo oooooooooooo_ 0, ,_ooooooo_oooooo o 2oo_o_o___°_°_o_o_o_o_°_°_°_°_oooooooo_o_°_o__o°_°_°_oooo_o_o_o__ 00000_o_°ooooooooooooooooooooooooooo______,__>¥g
0 N%________oi__oooooooo°°°°°___________oo_______ooo_______________o__o__oo_ o 2 ooooooooooooooooo_ooo_OoN_o i m_N m 03z_-Q_n ," c:::<:-&E 8==,0404OqLOL.¢)04ooo__o_oo_,_,ooooooooQodooddooddodoOGO___VVV 0ooo_o°"!._vvv <o_ooo.c 5o°v N___-___>o_>'_>_,_-o-_ _:>'___.___-5>_, , 0'-"-.-=__=IE__:_c==" ,_________-,.-_-_,_,._=-.=,_____,,.,_ r---t-_om©8o$o__oOoo =_o_"_-"-_-_-"-_°°°°_°°°°°°°_-_oo , oooo°°,:: 5 ,:: 5 ,: 5doo,:: 5,--,5o,:: 5 ,:: 5d,:: 5,:::;,:: 5d,::: 5d,:: 5O0040410,4C'.40_000,00000000_' <<_<_'_<<<<<< _,,,,,,,,,,,,,,,:h,-,,-,,-,_-,-,,-,,-,o_,:,_o_,-,_U.l1._LL/L LJ_LLI L.LIkl ALLIUJI._L.LI_N$N°°°°°°oo ooooooo,oooooooooo0,.IJ0Ob0'304_ o 200000000000040404040404__',___,__ ,_o ,.o ,.__>:¢F-
oi.)z_-co n.n"o__o___._oO__oo°o___ooo,::5"_-,::5o___ooooo_-oo_oo_o_,_oOoo°d°_°_ _o'o'o'o'o ,::5 t'-0=-,___ooooo_._0ooo°v,__o_vo__o_ooooooo__:_,-04,-4o_""_"____ovvv,,,, Ob o o i '__-----__.-o 0_UJU.lLLIU-ICO _N_<_0"4)___(______i(_'_I--0000000(D00000 200000000oooooooooeooooooooooo°o°° -_____ooooooo°°°°°°,oo°o°ooo Q_m_n_b m x:
00, ,_z__, a.-ad___,(D00,oo=='" 8=_oo_o__o_iooOoooO___o__o_oooooooooooo_'__o_o°o_,:: 5o,::::ji<:::;eq__oc;,:: 5ooooooo,:: 5ooo0,1i"<l-_O0voov___vvvv°!vvvv_____,,v_oo <_t_oo<:go_oo eq Ob 0 0 c'J
z_E 8 E o__vvvv___vvvvv_vv_vv,_,-,-,,-,-,oooo,7_,_.._._.oo_ooo0ooocor_._coooco000ooooo0oIo0._0o.c£ ."!r,.-:.r,-.:o0oooo03co,_8oooooooooONoooo_oONNoO!_ %oooooooooo_o_1oN_°"°"'_$_.,oooooooo ooooooooo ooooo m 6 5 c o m_¥m
co z_-L;>_3-r__&13_*--!o_o4oo_o_o_,_o___oo_o_o___o__..__oo_ ,:: 5 c 5 c 5 c 5.......... c 5 o c 5 o oooo o cN-C__VVVVVVV0")_VVVVVVVVVVVCO____'_O_I0_0000_i_<_oooo 0 0 z__oa-.n"__&_c°E 0 G)000_0°o°°°°°iooo°°oo_o,,°°°°°°_'"_,--o_ _-CDo 0¢-Evvvvvv°°__vvvvvvvvvv°°vvvvvvvv Ob 0 o O 9 C O°_;__'o______--___1_--_.-____-___-o______________-___-_._._ _.o_.______-_-___=_,=_______ob--F--0(DI0©-ooo__oo_oo'o'ooo°oooo_ _°I..I ALLILLIU-IILlUJLIJ_UJ_GO _%_do__o_o_o_o_o_o__o__o_o_o_o_o_o_o___!o 0 00000000000(_ObO_ObO__ !Oh00000000000000000000 0 0 ooooo_o_o__o__o____°_o_o__o,oo_ooooooo__00 0 m_N¥_g<_m
Z_,: D 1:1_¸rY 1:3_¸<I::--E-"°__o__o_o_°_°__o__o_00_oo_o ,=5o,:: 5 ,:: 5 oo,=5_o4o t--N r--oo!v r--_vvvvo4vvv__--vvvvvvv'-_o°°__"_°°_°°-'v o o o4-.=,q8i:5EE-00COCqNN_O00O(D 00CO13CI 130 C)c::,ooioo_o,::: 5 c 5 o ,..o":-_oo_o_____ooo,:: 5 ,:: 5,:::;o,:: 5 u S<::<:.<:_o_o_o_°_°4°°°°°°_04C'4040"40"4C_IC'4,,,,, ,,,,,,,__,,,-,_;_,,,,,,_,,,,,,!,-,,-,_,-,__ -..--,-, 0_,-,,-,__,:,_,-,,,,,,,,,,Or)(/)LLIIU,JLLILLIU -IUJLLI"5o_o_o_o_oooo_o_o_o_o__o_o_ooIooo_o__o__oo__o__°_o_oOoOOooooo__o°°o_o,,_°ooooooooo_oooooOo_,_oOoooooo,ooooooOOOooOOO _,.0404C_I"'___________co_______p_n'___'13._o.<F_ z_-rl¢Y"03c El..EI_o-)_I-o._oo.ooooooooooodoooo_o°__o°oo_oo ......,:: 5.c__._oooooooc;oc_oooooooo-grY_lobt--.-_oooo.--:o4vvvvvv_,_vvvvvo 5covv_o o O4
CO o_o"o zS-nrr&c E 0 000 o oJ.ooooooou_oooo_ 0_.........oo,i_o,ioJ o c_ooo oooo o Io o o c-oo.o..__vvv_vv°°°__vvvvvv_vvv°1°vvvvvv,_>___I_o>z.__'_-_o,,,00..=___>._oEoo___,.,___________5$___-_-_=._I--!'--I,-- co z@0(K D_o 0 o_c_ooocDoooo....oooo o oc_oo L_o c o_vvvvv eocooor_r_vvvvvvL._v r 0o'_o_oooo___j-vvvvv_oooo__o o o I°l
co c0g z_n rY r-<__E o__ooIo__66_i_N__ t-O-_N o l f}VVVVVV00_ 0 t4:)"_1"00_Q_:),,_iZVVVVVV__i__i___-:.00VVVVVVV <I:_00_"<1" Ob 0 0¢"xl (/-j"b z_-t"--13_E 0 0*-oddd!dddddddIdddooNNN o4_vmm_ovvvvvvv,_o,._vvvvvv_o_vivv re Eg'F=g_'g'._........oo*<<_:,<:m,',',mmoooo___,o_____oooo oo________oo__oooooooooooooooooo o00 0 O000eooooooooo_ooo_oooooooooooo __0 z_-0_.n"_I1._5 Eo___oO_____._____-o_____._______-._-00000__0000oo_,-'xi ,-4 ," ,ic ,,io ,i_°°c5c5c5 I o Ic5"c5dc5o,::5o.c_c 5 c5oJo6_c 5 c5<_do_ov_,,v , , ,,vvv_ov_.vv ,,v , , ,,_1-_, , , , ,_v ,_o_o<_____o 0._-_"_______-_,EE...__::::._o.-,......=-_.-_--__1_o_"_°_°_°_ooo__o.....__.co.,_.cooooo o oooo oooooo 0 0 000LI..I_ILlLI..IU -I_oooo_o__oo_o_o_o__o_o__o_o_o_°__o___00 000__°°°o oo_o_o_o_B_Oooo°OOOOOOOOOOOOOOOOOOO _._._,_o________ 2oooooooOooooooooOooooooooOoooooo00 C_,000000C='00000 m I---F rsj z_o>o..rr"&c0_eu E'-"=-._°_o__oOoo,.o__5__oo__._oo oo°_,_'_"-____o.._...._o_,_g o ovv__oN_°°oo_<i c_<___:vmvvvvvv_:__-_m.___o_o-ggg-g*8;___--_"_"_ .2.__oi5EfE. E._:_oZzZ_o_o 3 03.c_t-o"E"_ooo__"__eOr'n[¢o0('-)cO0o--oocOo4 t---t-,-.oOco0 r'_"ododoo_ooooo_oo __..__..__o=o_ 2__<<<<<ww_w_w_w_ww_ -_nl°-O 9 Iooooooooo_oooooo,ooo_o___o" , o_oooooooooooooooOoo,,o,,_o,,o,,o,,__o°o___oo o o o o ooooooooooooooooo_°_°_°__°_°_c___o_°_°_°_ooo_00000000 a_n--m ad&'8 C f._c<__0.....ooo_o_-_'_oo"-=":._"__o_'_oo__-_oioJoo.o6,= 5ooooo,:: 56oioooooo,= 5ooo_.R¢.--_o_oovvvvvIvv__vvvvvvvv o I o I o o o___o______ I'_-_%%_:____,-___
z_u_Eo_ooooooo_o6oooo _"*_v ENN__v"_vvN__vvvvN_N=__v_v o_o z_c13_c_E 8 o._ooooooc5oc5"o'¢5"ooo_c°oc5c5o°oo r-emvvvovvvvv o_oo_o__o_!o.__vvvvvv_:vvvvv 0 0 O4
zS-m.r Y"<_.__E_u_'_c 5c5<50ooc;c_oooLooqo6_.__._" ,__o"__0o__co04__o:vvvvvvvvo°v*I_I'_Ob O O....8_____'_______.... _G%_oNN_o oooooo oooNNNN___N_ooooNoNNooooooN,NoooN _,_...._____N m co z_Q_r'F" E t--=cmvvvvvvcooovvvvo_ o_I_-imoOooo__VV0VVVVV__LO 0 0 CM '8 E 0 cvvvvv_vv_!_v_8° _o_r_____VVVV_0rirVVVV 0 0-=_&&_m@@o_==od-==E_E_E.........______-.___.__NN,£_ddddd'd'dddodoNN°NNNN°°N_NNNINNNooNN_oNNo_ ooo__oooo_ I___NNNNNNN_Noo ooooooNoo_o_NN°°°°°°°oo o___o_ooo_oo_oo_o_oo_ooo_oooo____m_<¥m ,__D_00000000000000000_00000000000000 --____I____Z n_n"_&co°EL.0_o_o__-"__°_!M°_____oo°_°_°__'o_°___o_o__°__°o°_ c_oc5c_c5c_c5oc5,::5,::5c5c5c5_°c5c:::;c5c5c5o6°4°4c5_c:5_o_c5oo o S r,,-_="__o Ob o_,vvv_oovvvvvvo0ovvvvvo__o_o_°o 0 0 co o_.r_&<_:__Eo_!_II_1°0000 i°N N_-_vvvvvvv_° o E_oovvvvo_o_oovvv _csc_csN_dvv N=>-_¥EE....___......_ ____o___i_°°
z_-0_n"c0oO_t'_E_oL__o_.__._o__._OoooOOooooo__oooo__o_@o_oooo__oo_o_ _Q...jc 5,::5,:: 5oo,:: 5oc 5 c 5 c 5 c 5 c 5c5c 5._-,:: 5 c 5 c 5_c 5vvv.-,___vvvvvv__ 0co(_100 8 i.t.,O__0:>0>_oeO_oO 0__._---___._._=,_ /._.....-g"_._.g*<<.<eece__,___.__._oI=oo_-_"5"_mmoooo__-_'_,zzza_nmmm_0oooo;!o-_-o_o_oooooo_o_o<....<_o'__--OlO/o,o_00_00000__- ooooo oooooo o°_°°_ooooooa__o_a_/_L_L___O_O__Z.__a_O_/n/no°°°°°°__°___°_ooo_o_o_o__oooooo/olooOooooooo I_100_"0000ObOb._.,_.__00,.i0404C., ,I04O__00000'00_o_o_o_o_o_o_o_o_!§o_o_o_o_o_o_o_o_o__ ooooo_oooooo_@_o _00000 O.000000000 0..,i_,4C,q0.4C..4_C_00000000'0000000 n co F-z_-5._rr&E r--,--,_o o"___vvvvvv___o_o°°°°°°__,o0oo, ,v,1vv_o__vv <ry co'LoL_oc 5 OD 0 0 z_,E 8 vvvvvo_0VVVVVVVV<__vvv___dd-_._._.______________-==__,_,_o ....-___.____,__=o........._o,o,o__<<<<_____<<_<<<<%o mN_00OO_¥
o_o._z_O_a d c<_.E*o_O_oo_"_oo___o_o_o__-_o_ o°o_°_Oo_*"_000-__r_o o-__°_oo00Lo IL_._¢t)vvvvvoo_0*_-_o_r.oo0 ,__vo__,vvvvvvvvo_,vvvv ,_Ob 0 0 C',,I
_o_,z , z_____-_-____._.=_,___."7EE:--.-z°°o-o ,..r_,,_,..s-'6_-__&_ooooo=o_-.,=-s.=-o,_,_-_I--t--I--I--:(,_)o..o9._(..)o000co_co0oo_o_h lhlh.t ,-:..ho°0cocornrnrnrnr--,5,=oo,._o=oo,5"°°_°dd°°_°°°°°°oi_oo -_o_<<<<<<<<<<<<< <<o<a_c k__a__wkuuJwwwt.uw_wwwwiu_t.ut.uco _% _dooooooooooooo_o_°_°_°_°_°_°_°__°_o_o_o_oooooooo o oooooooooooooooooooooooo oO ('4 ('q N o 2!o°ooooooooOooooooooOo_oooooOoooooOoo0000 00000000000 o__cocooooocococo0ooooocooococo_ocoqo_o-r__b m z_'8 E___od6oooo.oo_ooo.°o°oooooI________o_____vIvv_vv__!vvvv_ NEE¢0_00_<<<<____<<<<<<2_<<<<<_o loNNNNNNN'_NNNNNN __oooo___ooo_o oooo______0000000000000000000000______________oooo m_=g m z_'8_oo__,o..000 000 c 0__vvvvvv,vvovvv 0 0EEg--__mm omm_.......___,__EE"_"[EEcc__no o,.-,.-_0oooooooo_oo___o_ooooo_ooooooo__,...oooo %o oooooooo--__oooooooooooooooo g_oooooooooooooooooooooooooooooooooo000000(D000(D0000(D0000(D m_m¥7-_-x;
z_n.r__.&oE*-o_o_o__o_o_,_o,.Oiooo___,.o,.ooooo!.oo!.o°ooooooc_c_o°oooo,:dooo°oo_,_c_c;oc 5o6 E______vvvvvv._vv, ,vv_,I_-_,0!_,__i_o_0,}_o,_°-:_,_-:i_____-_1-__'_'__ 0___i_oooo_ oooo___oooo_<<_<____<<<<_%___!_oo_oo_oo__o_o_oo oooooooooooooooooooooooooooo_00o00o0000000000o00o000000oo_______ooooooooooooooooooooo o'd"d'o_!c_o____o°o°o° oO . o oo o oooo_"_______<<<<"_ '_'_°_°_____n____o_'<'_N"o*___cr___c_o'__'_o'_ i__ooooo°o°°o°o°o°__o"o_1ooo__o_o_o_oo_o__._.o,-,,,_o, , o00000 0e__ooooooo oooo O,4 m_%-r"<m_-° 03 z_>_Or)c 13_I o___o__ooo_o__oo,--,,o_o_°___o__o_o'_*.o____ooo°o° o°c:: 5°ooo°o°it::::;u';'°c:: 5oc: 5oc 5'°_ovv_oo,..o_vvvvo_v__vvvooi_____oo_ovoo_,_==_r=____5__=_S_ .__._,_,_F__....___o5r5__oo_.__________=
00,:>QFF"_.(3_'8 O0¢-t'l("I3--__o_oo_o_o...-J,: 5 c 5¢: 5 ,:: 5 c: 5 ,: 5!c 5o,:: 5<: 5o,:: 5 ,:: 5 ,:: 5-_, ,Y t-O--_.,....,___°=oo"_-__ovv_°¢_I°vvvvvvo"m rzvvvvv0_L¢)_._L¢)o*¢_ovvv_--('xl 0o<(r---0c5 Ob 0 0 0 , I
0'D 5_z_-Q-.__i c n.8_.o_ooo_._.oo_o_°o_'__o__0o_- O_o..._o°o_;ooc 5 c 5ooc 5____c 5 c 5 uoo_c 5 c 5o_.,_o_o o°_ooOo-,oO__o_o_Oovv_vvvv_Iv_._vv_,_,v___ooo_o o3z_-o._0d&'8 OC.I t-r_<__oo,5o,5o,5o,5,5o,5,5,5oo°_"o_°_°_'_o°° 0='-,_o_o,.oI_oo_-_vvvvv_°c_oo°o_.___vvvvvvcovvvvvob_ovvo Ob o 0______o_>>-_8>z._..m_ ---____o.--_0--....o<<<mmmmmmooooo__N_ '_]___NN_2 0oooNNoNNNNNood 'd'_'dd_ooooooo_OOOO_O<<<<<<<<_<<<<<_<<<_ -ooN$_,oNNNNNNN_N__$_$NN_NNNN g_ooNoooooooooo_NNNNNoo NmooNINNN___ oooooooo ooooo oo o0000000000____ooo£b m _s_°°________________Immmmmm______m___ co i_N_d__________I__o,oo_ooooooooooooooo_ooO_ooooooooooooooNNNNNNNNoo°_o o?°oooOoooOoOoooooooooo_oooooooo°NoOoooo ,oooooo°o°oo°o°-_ m__c o I a__b m z_'8_c c 0_vVv0_0VvVvVvvv_Nu...._-._V--v 0 0©_°_o_o__oo_o_o_o________ooooooooo_oo_o_o0")LLILI_ILLILLI %Ob0_,ObObooooo_o_o_o_o_o_o_ oo o_o_o_O_o_000000000 oooooo_o_o_o_o_o_o_°_°_°_o ioo_o_°_o_o_o_o_o_o_o_o_oo00__o_oooooo°ooo_ooo__o_000E____........................--_--_____o__b m z_->0-r¢__gm_c°121.._._i:-=o,--_-J 04 L O L_L O L O"--04C x ,l__L ,')14")L ,')__-__°oo°o.oo_oooooooooooooo__oo. .oo.gr, , c:__,_,_____vvvvvo'o_--,=:,__vVVV V V 0
o9 o_oz__oar_&8_1r<_oE o_=ooo_0oo__oo0o0 o_oo_o__o_oo o 5°°°°o°°°__0o_o0COCO14")__VVVVV_VVVV_VVVV z_c E_oo°o_6__ooo_Eoo__oo_vvvvvvvv_v_vvv__>>z___o_EE=&&_boo o__.......=00 0___:_____________ z_-_.0on.n" E 0 c:__.._ooooooLoo,::56o.,:: 5 c 5o___,::5,::5_.o_-. t'--_0000 t-O-_____vvvv_v"_vvv"-,.o_.o t'-o'-0L-o_.-o o c_;___-vv040VVVVVV ,_r,,," ooo_o_r"-Ob o 0 o4
_codddd°-_§___,_o_ooo_000 0 0_oo l,_._ddddNNNdddd'd_ NNN N NN_NNsN°°°°ooooooo___000 0000___ooo_°°0 0000_________oooooooiooooooo______________oo_oooooooooo_ m_<g z_13..Q£[3_'8 (,/i),:'-E°I=o:_ooo.___o_,*_o,,oo__0o....oooo4o4o_o°o°°4,:::5ooooc 5o_o,:::5,:::5ooo_"O_ooo_D_E o.,.o_vvv vvvvvvvv__.v_o____ovvVvv o o o4__==___-oI___-___>_7.._,,,o__or___>o_r'-,.-_>_.__u)"_rm--.-o._o....--,o,o==.=__._._oo_s__-___-='__=E I ,--I,--#©,_(-)cooo_oooo04r-.-r.--oooooooicq <<<<_,_ocOm%_o_o_o__o___o____o_o_o_o__o_°_°_oo_ ooooooooooooooooooo_'____i___o°_o_o_°_°_°_o_o_°_o_ooooooo,oo°_°_°"_o_o_o__o__°___°_o__°__oooooo__o_oooooooooooooooooooooooooo _"O4o4O4o404o40_ z_>i E*..00000_m_ooooooooo c 9_ViVV_-V V___V00V0___V 0 0_>_>___>__>_:>_>_=_i_>*-'>,>.:>:,_i::5._--m__,0i_'_(...)==_E d=-_=......_oo=_8_,__o=*E_==_8_.88-8oo=.=8__:_____....000rnrn0--nmm0t--__cO(.30___,_,_ <,__::mrmmnmrnI"-,.-_0I'-.--_0 130 130__1,3300cO{3000cO00b.__00::'"-:"_"_"___,_,___=ooo°_o__o_°_=o°o"o"_'o____o'_"_o"'_o"_o"_o_o_o_00000=____<<<<<LLII.ULLII.__LLI o o o o00o o_ooo__o,,°°_°°°°°°°°°°°°oo,,o,,_oo____o,,_ooooo_000: 000000000000(_0!000m000000000000000000000000000---I-oO c_n a__(D G Nooooo,oooooooooo o00000000I00000000000000000000m_mmm__mj__ E o oooNNNooooNNNN@N_NNNNNNN_oiOOOOOOOOOOOOOOOOOOOOOOOOOOOO m_N m g o m o_"6z_-n.rF_.I:L i o ,:., Q...00(NIf)I_00 e-l o___VVVVVVVVV E__ooooo°°__o_o__ivo°o__ooJeq_r-.-.o05c-Jc',,io, v
o_z_-r_.r_'8 EOO.__ooodddddddooooooo_o_°_N'Eo°_N.g r ,,=N°v!vvvv__o_vo°°___Ob o O I oj<-_o-___>oo__-_>z_ ,.___.__>_o-_r_"--c,_....._o.-__"-'.....EE-a>,:_c___EE. -IEE_EE_--c_z=___._.-E:_.-......._o.._o._'6 _u©__COO0cOO0O0O0_b.. -_O0O0¢0COO0CO00O0¢0_COO00,.II"-..-b_,_ "5000000 iO00 0 0 000 coN¢::::'00__00000000,_,00!00 _,00000:0000 N oooooooooioooooooooooooooooooo2_ b or)z_o._¢r&121._('__z.._c:5c:5,:5co__._,::5c 5c,o ,::: 5 6 ,5i ,:: 5 o ,:: 5oooooo0-__°°o°o°__°°,-.,qo,_o_o__,...vvvvvvvv_, ,_,-oo_vvvvv vo04o 5oo oq
z_I]..E o,.,.-Jc_cScS,.ocSc5cScSc5cSc_oo c_cc_cScS:__c_c_c_ 0I_-__co_o_vov_vvvv O_0 0 C_4
APS-PVNGS2009AnnualMonitoringandComplianceReport DAT E W ELLI D M E A S URED TY P E OF MEA S UR E M E NT APP-103/10/09 920.64 Dry DryQtrlyWQ 06/24/09 920.64 Dry DryQtrlyWQ 08/28/09 920.64 Dry DryQtrlyWQ 10/15/09 920.64 Dry DryQtrlyWQAPP-302/18/09 916,73 225.78 690.95QuarterlyIndicator 05/28/09 916.73 225.87 690.86QuarterlyIndicator 08 1 06/09916.73 227.65 689.08QuarterlyIndicator 11/03 t 09 916.73 228.97 687,76QuarterlyIndicatorAPP-4R02/19/09 917.08 161,60 755.48QuarterlyIndicator 05/27/09 917.08 161.31 755.77QuarterlyIndicator 08 1 05/09917.08 161.51 755.57QuarterlyIndicator 10/28/09 917.08 161.16 755.92QuarterlyIndicatorAPP-502/27/09 912 , 53 136.31 776.22QuarterlyIndicator 06/09/09 912.53 135.65 776.88QuarterlyIndicator 09/16!09 912.53 136.68 775 , 86QuarterlyIndicator 11/08/09 912.53 133.26 779.27QuarterlyIndicatorAPP-603/10/09 920.80 194.19 726.61QuarterlyIndicator 06/15/09 920.80 194.45 726.35QuarterlyIndicator 09 1 16/09920.80 195.40 725.40QuarterlyIndicator 10/2!/09 920 , 80 195.51 725.29QuarterlyIndicatorAPP-703/12/09 970.63!29.00 841.63QuarterlyIndicator 06/16/09 970.63!29.41 841.22QuarterlyIndicator 09/29/09 970.63 130 , 29 840.34QuarterlyIndicator1!/18/09 970.63 131.41 839.22QuarterlyIndicatorAPP-801/16/09 948.57 100.50 848.07QuarterlyIndicator 02/10/09 948.57 100.43848.14QuarterlyIndicator(repeatsample,samplererror) 05/07/09 948.57 100.61 847.96QuarterlyIndicator 07/23/09 948.57 100.90 847.67QuarterlyIndicator 10/28/09 948,57 101.25 847.32QuarterlyIndicatorAPP-901/15/09 952.00 93.72 858.48QuarterlyIndicator 05/06/09 952 , 00 93.92 858.28QuarterlyIndicator 07/08/09 952.00 94.15 858.05QuarterlyIndicator 07/21/09 952.00 94.10 858.10Verificationsamplingforchromium 10/21/09 952 , 00 94.34 857 , 86QuarterlyIndicatorPV_,PS-PVNGS\138949-2009AnnualMon.andCompl .Report\Deliverables\Reports\FinaRAppendixC\TableC-3bWaterLevels.xlsxPage1of9 APS-PVNGS2009AnnualMonitoringandComplianceReport DATEWELLID MEASUREDTYPEOFMEASUREMENTAPP-1001/14/09 956.27 114.55 841.92QuarterlyIndicator 05/06/09 956.27 115.15 841.32QuarterlyIndicator 06/08/09 956.27 115.34 841.13Verificationsamplingforsulfate 07/08/09 956.271!5.69 840.78QuarterlyIndicator 10/21/09 956.27!16.69 839.78QuarterlyIndicatorAPP-1103/10!09 950.27 71.45 879,02FromTransducer 08/27!09 950.27 71.85 878.62FromTransducer 10/16/09 950.27 72.15 878.32FromTransducer 12/16/09 950,27 72,25 878.22FromTransducerAPP-1201/15/09 957.83 130.29 827.54QuarterlyIndicator 05/06/09 957.83 130.55 827.28QuarterlyIndicator 07/08 109957.83 131.05 826.78QuarterlyIndicator 10/21 109957.83 131.75 826.08QuarterlyIndicatorAPP-1301/07 109920.69 87.83 832.86MonthlyAmbient 02/04 t 09 920.69 87.82 832.87MonthlyAmbient 03/05/09 920.69 87.94 832.75MonthlyAmbient 04/29/09 920.69 87 , 88 832.81MonthlyAmbient 05/20/09 920,69 87.98 832.71MonthlyAmbient 06/04/09 920.69 87.90 832.79MonthlyAmbient 07/14/09 920.69 87.95 832.74MonthlyAmbient 08/19/09 920.69 87.80 832,89MonthlyAmbient 11/05/09 920.69 87.61 833.08QuarterlyIndicatorAPP-1401/07/09 920.52 60.40 860.12MonthlyAmbient 02/04/09 920.52 60.08 860.44MonthlyAmbient 03/05/09 920.52 60.10 860.42MonthlyAmbient 04/29/09 920.52 60,13 860.39MonthlyAmbient 05/20/09 920.52 60.13 860.39MonthlyAmbient 06/04/09 920.52 60.15 860.37MonthlyAmbient 07/14/09 920.52 60.20 860.32MonthlyAmbient 08/19/09 920.52 60.30 860.22MonthlyAmbient 11/09/09 920.52 60.71 859.81QuarterlyIndicatorP:_APS-PVNGS\138949-2009AnnualMon.andCompl .Repod\Detiverables\Reports\F tnalL_ppendixC\TableC-3bWa terLevels.xlsxPage2of9 APS-PVNGS2009AnnualMonitoringandComplianceReport T OP O F C AS INGM E AS U REDDE PT H WA TE R DA T EWELLIDELEVATIONTOWATERELEVATIONTYPEOFMEASUREMENT MEA S URED,,(FTAMSL)(FTBMP},(FTAMSL)APP-1501/07/09 924.74 62.09 862.65MonthlyAmbient 02/04/09 924.74 61.88 862 , 86MonthlyAmbient 03/05/09 924.74 61,97 862.77MonthlyAmbient 04/29/09 924.74 61.95 862.79MonthlyAmbient 05/20/09 924.74 61.96 862.78MonthlyAmbient 06/04/09 924.74 61.99 862.75MonthlyAmbient 07/15/09 924.74 62.15 862.59MonthlyAmbient 08/19/09 924.74 61 , 95 862 , 79MonthlyAmbient 11/09/09 924.74 62 , 19 862.55QuarterlyIndicatorPV-14H03/11/09 922.01 57.96 864.05QuarterlyIndicator 06/15/09 922.01 58.08 863.93QuarterlyIndicator 09/17 109922.01 58.13 86'3.88Quarterlyindicator 10/22/09 922.01 58 , 10 863.91QuarterlyIndicatorPV-17403/05/09 955.75 59.76 895.99FromTransducer 06/18/09 955.756I.10 894.65FromTransducer 08/27/09 955.75 61.10 894.65FromTransducer 10/16/09 955.75 61.61 894.14FromTransducerPV-18303/11/09 951.70 60.0!891.69FromTransducer 06/18/09 951.70 60.55 891.I5FromTransducer 08/27/09 951.70 61.00 890.70FromTransducer 10/23/09 951.70 61.11 890.59FromTransducer PV-191A03/03/09 943.60 Dry DryQtrlyWQ 06/18/09 943.60 Dry DryQtrlyWQ 08/28/09 943,60 Dry DryQtrlyWQ 10/21/09 943.60 Dry DryQtrlyWQPV-192A03/03/09 943.31 95.68 847.63FromTransducer 06/18/09 943.31 95.75 847.56FromTransducer 08/28/09 943.31 95.81 847.50 From T ransducer 10/!6/09 943.31 95.88 847 , 43FromTransducerPV-193A02/27/09 943.71 79.63 864.08QuarterlyIndicator 05/27/09 943.71 79.48 864.23QuarterlyIndicator 08/03/09 943.71 79.55 864.16QuarterlyIndicator 10/28/09 943.71 79.11 864.60QuarterlyindicatorP_APS-PVNGS\138949 -2009AnnualMo rt.andCompl.Report\Deliverables\Reports\ginal_AppendixC\TabteC-3bWate r Levels.xlsxPage3of9 APS-PVNGS2009AnnualMonitoringandComplianceReport DATE WELLIDTYPEOF M EASURE M ENT M EASUREDPV-195A03/1!/09 921.71 48.80 872.91QuarterlyIndicator 06/23/09 921.71 48.99 872.72Quarterlyindicator 09/17/09 921.7!49.08 872.63QuarterlyIndicator 11/10/09 921.71 49.04 872.67QuarterlyIndicatorPV-198AR01 /13/09 931.48 75.78855.70Contingencymonthlyindicatorsamplingforchloride e xce edance 02/11/09 931.48 75.81 855.67 Quarter lyindicator 05/27/08 931.48 76.33 855.15Quarterlyindicator 07/22/09 931.48 76.59 854.89Quarterlyindicatorandverificationsamplingforboron,chloride,totaldissolvedsolids,potassium,andchromium. 10/14/09 931.48 76.85854.63Quarterlyindicatorandcontingencymonthlyindicatorsamplingforchlorideexceedance 11/04/09 931.48 76.83854.65Contingencymonthlyindicatorsamplingforchloride exceedancePV-205A03/24/09 907.23 69.94 837.29FromTransducer 08/28/09 907.23 69.92 837.31FromTransducer 10/15/09 907.23 70.00 837.23FromTransducerPV-206A02/10/09 947.91 82.30 86 5.61QuarterlyIndicator 05/20/09 947.91 82.56 865.35QuarterlyIndicator 08/03/09 947.91 82.81 865.10QuarterlyIndicator 10/28/09 947.91 82.96 864.95QuarterlyIndicatorPV-207A03/30/09 967.24 DryDryFromTransducer;Confirmedquarterlywithsounder 06/30/09 967.24 DryDryFromTransducer;Confirmedquarterlywithsounder 09/30/09 967.24 DryDryFromTransducer;Confirmedquarterlywithsounder 10/28/09 967.24 DryDryFromTransducer;Confirmedquarterlywithsounder 12/30/09 967.24 DryDryFromTransducer;ConfirmedquarterlywithsounderPV-216R03/17 /09 891.01 198.16 692.85FornitrateexceedanceinAPP-3 06/17/0989!.0I 199.33 691.68FornitrateexceedanceinAPP-3 08/20/09 891.01202.!5 688.86FornitrateexceedanceinAPP-3,WLrecheckedon9 /1/09:DTW@12:50=202.57ftbmp,TROLL=14.34fl!1/18/0989!.0!202.82 688.19FornitrateexceedanceinAPP-3PV-21H03/05/09 962.10 72.78 889.32FromTransducer 06/18/09 962.10 73.40 888.70 Fr omTransducer 08/27/09 962.10 73.64 888.46FromTransducer 10/16/09 962.10 73.82 888.28FromTransducerP:_APS-PVNGS\1389492009AnnualMonandCompLReport\Deliverables\Reports\Final_AppendixC\TableC
- 3bWaterLevels.xlsxPage4of9 APS-PVNGS2009AnnualMonitoringandComplianceReport T OP OFCAS I NG M EAS UR ED D EPTHWAT E R D A TEWELLIDELEVATIONTOWATERELEVATIONTYPEOFMEASUREMENT MEASURED(FTAMSL)(FTBM P}(FTAMS L)PV-24H01/06/09 947.00 59.63 887 , 37FromS o under 03/12/09 947.00NoreadingProbedryFromTransducer 06/23/09 947.00 59.85 887.15FromSounder 09/01/09 947.00NoreadingProbedryFromTransducerPV-24HB01/02/09 940.91 54.43 886.48FromTransducer 06 1 17/09940.91 54.80 886.11FromTransducer 08 t 28!09 940.91 55.03 885.88FromTransducer 10/!6!09 940.91 55.10 885.81FromTransducerPV-25HA01/02/09 942.10 60.11 881.99FromTransducer 06/17!09 942.10 60.69 881.41FromTransducer 08!27/09 942.10 61 , 18 880.92FromTransducer 10/23/09 942.10 61.24 880.86FromTransducerPV-28HB01/06/09 930,81 47.32 883.49FromTransducer 06/17!09 930.8!47.67 883.!4FromTransducer 08/27 t 09 930.81 48.38 882.43FromTransducer 10/23/09 930.81 48.71 882.10FromTransducerPV-29HB03/13/09 928,40 48,85 879.55FromTransducer 06/17/09 928.40 49.17 879.23FromTransducer 08/28/09 928.40 49.5!878.89FromTransducer 10/23/09 928.40 49.60 878.80FromTransducerPV-34H02/27/09 911,51 45.88 865.63QuarterlyIndicator 06/23/09 911.51 46.45 865.06QuarterlyIndicator 09/16/09 911,51 46.87 864.65QuarterlyIndicator 11/05/0991!.51 46.86 864.65QuarterlyIndicatorPV-Q501/08/09 938.31 58.12 880.19FromTransducer 03/13/09 938.31 58.44 879.87FromTransducer 06/18/09 938.31 5890 879.41FromTransducer 10/23/09 938.31 59.55 878 , 76FromTransducerP:LAPS-PVNGS\138949-2009AnnualMon.andCompLReport\Deliverables\Reports\Final_AppendixC\TableC-3bWaterLevels.xlsxPage5of9
! APS-PVNGS2009AnnualMonitoringandComplianceReport T OP OFC ASI NG M EAS UREDDE PT H W A T E R DATEWELLIDELEVATIONTOWATERELEVATIONTYPEOFMEASUREMENT MEASURED ,,(FT,AM SL)(FTBMP)(FTAMS L)PV-Q802/10/09 923,80 79.00 844.80QuarterlyInd i cator 05/27/09 923.80 78.97 844.83QuarterlyIndicator 08/05/09 923.80 78.97 844.83QuarterlyIndicator !0/07/09 923.80 79.07 844.73Verificationsamplingforboron 10/28/09 923.80 78.88 844.92QuarterlyIndicator 12/0!/09 923.80 79.07844.73Contingencymonthlyindicatorsamplingforboron exceedancePV-R2AR03/12/09 961.15 76.08 885.07Quarterlyindicator 06/17/09 961.15 76.55 884.60QuarterlyIndicator 09/24/09 961.15 77.35 883.80QuarterlyIndicator 11/18/0996t.15 77.70 883.45QuarterlyIndicatorPV-TR103!10/09 962,60 64.35 898.25FromTransducer 06/17/09 962,60 67 , 04 895.56FromTransducer 08/27/09 962.60 67.06 895.55FromTransducer !0/16!09 962.60 68.25 894.35FromTransducerU5-PTWB03/13 /09 930.81 45.50 885.31FromTransducer 06/18/09 930.81 45.65 885.16FromTransducer 08/28/09 930.8!46.05 884.76FromTransducer 10/23/09 930.81 46.34 884.47FromTransducerRPZ-la03/19/09 956.21 Dry DryFromTransducer 07/21/09 956.21 Dry DryFromTransducer 10 1 20/09956.21 Dry DryFromTransducerRPZ-lb03/19/09 956.20 52.35 903.85FromTransducer 07/2!/09 956.20 Dry DryFromTransducer !0/20/09 956.20 Dry DryFromTransducerRPZ-2a03/20/09 953.37 36.86 916.5!FromTransducer 07/21/09 953.37 37.85 915.52FromTransducer 10/20/09 953.37 Dry DryFromTransducer RPZ-2b03/19/09 953.42 56.65 896.77FromTransducer 06/26/09 953.42 57.74 895.68FromTransducer 07/21/09 953.42 58.01 895.41FromTransducer 10/20/09 953.42 58.65 894.77 ManualP_APS-PVNGS\1389492009AnnualMon.andCompl.Repod\Del werables\Reports\Final_AppendixC\TableC-3bWaterLevelsxlsxPage6of9 APS-PVNGS2009AnnualMonitoringandComplianceReport D A T EWELLID TYPE OFMEASU R EMENT MEASU R ED RP Z-3a03/17/09 953,96 30.50 923.46FromTransducer 07/21/09 953.96 30.69 923.27FromTransducer 10/17/09 953.96 30.79 923,17FromTransducerRPZ-3b03/17/09 953.96 52.18 901.78FromTransducer 07/21/09 953.96 53.20 900,76FromTransducer 10/20/09 953,96 53,79900.!7FromTransducer RPZ-4a03 1 17/09958.75 Dry DryFromTransducer 07/21/09 958.75 Dry DryFromTransducer 10/20/09 958.75 Dry DryFromTransducerRPZ-4b03/17/09 959.29 Dry DryFromTransducer 07/21!09 959.29 Dry DryFromTransducer 10/20/09 959,29 Dry DryFromTransducer RPZ-5a03 1 19/09964.23 30.23 934.00FromTransducer 07/21/09 964.23 30.60 933.63FromTransducer 10 t 20/09 964.23 30.76 933.47FromTransducerRPZ-5b03/19/09 963 , 92 57.69 906.23FromTransducer 07/21/09 963.92 57.65 906.27FromTransducer 10/20/09 963.92 57.67 906.25FromTransducerRPZ-6a03/19!09 956.33 29.52 926.81FromTransducer 07/21/09 956.33 29.68 926.65FtomTransducer 10/16/09 956,33 29.78 926.55FromTransducerRPZ-6b03/19/09 956.21 53.96 902.25FromTransducer 07/21/09 956.2!54.05 902.16FromTransducer 10/16/09 956.21 54.10 902 , 11FromTransducerRPZ-7a03/19/09 953.72 31.62 922.10FromTransducer 07/21/09 953.72 32.20 921.52FromTransducer 10/16/09 953.72 32.59 921.13FromTransducerRPZ-7b03/19/09 955.39 54.58 900.81FromTransducer 07/21/09 955.39 55,21 900.18FromTransducer 10/16/09 955.39 55.40 899.99FromTransducerP:LAPS-PVNGS\1389492009AnnualMon.andCompl.Report\De hverables\Reports\Final_,ppendixC\TableC-3bWaterLevels.xlsxPage7of9 APS-PVNGS2009AnnualMonitoringandComplianceReport TO P OF CA SING M E ASUREDDE P THW ATER DAT EWELLIDELEVATIONTOWATERELEVATIONTYPEO F MEASUREMENT MEASURED(FTAMS,I_)(FTBMP)(FTAMSL)RPZ-8a03/19/09 957.25 Dry DryFromTransducer 07/21/09 957.25 Dry DryFromTransducer 10/16/09 957r25 Dry DryFromTransducerRPZ-8b03 1 19 109957.27 Dry DryFromTransducer 07/21/09 957.27 Dry DryFromTransducer!0 1 16/09 957.27 Dry DryFromTransducerRPZ-9a03 t 19 t 09 958.74 Dry DryFromTransducer 07 1 2!I 09 958.74 Dry DryFromTransducer 10 1 16 109958.74 Dry DryFromTransducerRPZ-gb03/19/09 958.69 Dry DryFromTransducer 07 1 21 109958.69 Dry DryFromTransducer!0 1 16 109958.69 Dry DryFromTransducerPV-219C01 1 14 109943.00 Dry Dry Monthly 02 1 03/09943.00 Dry DryMonthly;abandonedinFebruary2009PV-220C01 1 14 109943.00 Dry Dry Monthly 02/03/09 943.00 Dry Dry Monthly 03 1 03/09943.00 Dry Dry Monthly 04/!6/09 943.00 Dry Dry Monthly 05/05 t 09 943.00 Dry Dry Monthly 06/02/09 943.00 Dry Dry Monthly 07/21/09 943.00 Dry Dry MonthlyPV-221C01 1 14 109944.00 Dry Dry Monthly 02/03/09 944.00 Dry Dry Monthly 03/03/09 944.00 Dry Dry Monthly 04/16/09 944.00 Dry Dry Monthly 05/05/09 944.00 Dry Dry Monthly 06/02/09 944.00 Dry Dry Monthly 07/21/09 944.00 Dry Dry MonthlyP_APS*PVNGS\138949-2009AnnualMon.andCompl.Report\Deliverables\Reports\Final\AppendixC\TableC-3bWaterLevels .xlsxPage8of9 APS-PVNGS2009AnnualMonitoringandCompliance Report DA TEWELLIDTYPEOFMEASUREMENT MEAS URED PV-222C01/14 1 09 943,00 Dry Dry Monthly 02/03/09 943.00 Dry Dry Monthly 03/03/09 943.00 Dry Dry Monthly 04/16/09 943.00 Dry Dry Monthly 05/05/09 943.00 Dry Dry Monthly 06/02/09 943,00 Dry Dry Monthly 07/21/09 943.00 Dry Dry MonthlyPV-223C01/14!09 943,00 Dry Dry Monthly 02/03/09 943.00 Dry Dry Monthly 03/03/09 943,00 Dry Dry Monthly 04/16/09 943.00 Dry Dry Monthly 05/05/09 943,00 Dry Dry Monthly 06/03/09 943.00 Dry Dry Monthly 07/21/09 943,00 Dry Dry Monthly Notes:DTW-DepthToWaterftamsl-feetabovemeansealevelflbmp-feetbelowmeasuringpointWL-WaterLevelWQ-WaterQualityP_APS-PVNGS\138949-2009AnnualMonandCompl.Report\Deli c erables\Reports\Final_AppendixC\TableC3bWaterLevels .xlsxPage9of9}}