ML063400434

Final Status Survey Final Report Phase IV, Appendix A3, Survey Unit Release Record 9106-0003, Discharge Canal

ML063400434
Person / Time
Site:	Haddam Neck File:Connecticut Yankee Atomic Power Co icon.png
Issue date:	11/13/2006
From:	Newson C Connecticut Yankee Atomic Power Co
To:	NRC/FSME
References
9106-0003
Download: ML063400434 (226)

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Bok4 f1 Final Status Survey Final Report Phase IV Appendix A3 Survey Unit Release Record 9106-0003, Discharge Canal November 2006

CYAPCO FINAL STATUS SURVEY RELEASE RECORD DISCHARGE CANAL SURVEY UNIT 9106-0003 Prepared By:  %-LZ X Date: /a- 2 5,'-o1 Reviewed By: Date: //"/3 FS gineer Approved By: Date:____

Technical Support Manager Revision 0

DISCHARGE CANAL SURVEY UNIT 9106-0003 RELEASE RECORD TABLE OF CONTENTS

1. SURVEY UNIT DESCRIPTION ................................................................. 3

2. CLASSIFICATION BASIS ...................................................................... 3

3. DATA QUALITY OBJECTIVES (DQO) .................................................... 5

4. SURVEY DESIG N ..................................................................................... 8

5. SURVEY IMPLEMENTATION ................................................................ 10

6. SURVEY RESULTS ............................................................................... 11

7. QUALITY CONTROL ............................................................................. 13

8. INVESTIGATIONS AND RESULTS ...................................................... 14

9. REMEDIATION AND RESULTS ............................................................. 14

10. CHANGES FROM THE FINAL STATUS SURVEY PLAN .................... 14

11. DATA QUALITY ASSESSMENT (DQA) ................................................. 14

12. A NO MA LIES ........................................................................................... 15

13. CO NCLUSIO N ....................................................................................... 15

14. ATTACHM ENTS ..................................................................................... 16 14.1 Attachment 1 - Figures (6 pages including cover) 14.2 Attachment 2 - Sample and Statistical Data (194 pages including covers)

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DISCHARGE CANAL SURVEY UNIT 9106-0003 RELEASE RECORD SURVEY UNIT DESCRIPTION Survey Unit 9106-0003 (Discharge Canal) is designated as Final Status Survey (FSS) Class 2 and consists of approximately 8,292 m 2 ( 2.05 acres) of water covered sediment in an area located approximately 0.28 miles from the reference coordinate system benchmark used at the Haddam Neck Plant (HNP)

(see Attachment 1, Figure 1). The Discharge Canal is a man-made mile long waterway that runs parallel to, and ultimately communicates with the Connecticut River. The Discharge Canal is subdivided into fifteen (15) survey units which includes two (2) permanent wetland areas for FSS purposes. With "called north" oriented with the north to south flow of the Connecticut River, the survey unit is bounded as follows: Discharge Canal Survey Unit 9106-0002 is to the north, land surface area Survey Unit 9521 is to the east, Discharge Canal Survey Unit 9106-0004 is to the south and Survey Area 9520 is to the west. The survey unit comprises the canal sediments to the deeper of three (3) feet or the original construction depth. It extends up the canal banks to the mean high water level.

The reference coordinates associated with this survey unit are E010 through E015 by S084 through S092 (refer to License Termination Plan Section 5.4.4).

The reference coordinates provide the maximum dimensions of a rectangle containing this survey unit. Some areas contained in this rectangle may not be part of this survey unit. The boundary of the survey unit was defined using a Global Positioning System (GPS) based on the Connecticut State Plane System North American Datum (NAD) 1927.

2. CLASSIFICATION BASIS The survey unit was classified in accordance with Procedure RPM 5.1-10, "Survey Unit Classification." The historical information, scoping analyses and characterization results provided sufficient data to designate Survey Unit 9106-0003 as Class 2 in April 2006.

The "Classification Basis Summary" conducted for this survey unit consisted of:

a) A review of the 10CFR50.75 (g) (1) database, b) A review of the "Initial CharacterizationReport" and the "Historic Site Assessment (HSA) Supplement, "

c) Historic and current survey records review, d) Visual inspections and a "walkdown."

e) Formal or informal interviews with cognizant personnel.

A review of the 10CFR50.75(g)(1) database report identifies a number of events that may have impacted this survey unit. Several events indicated the potential for plant related contamination in the survey unit. These included a number of primary side system to secondary side system leakage events, contamination Revision 0 3 Revision 0 3

DISCHARGE CANAL SURVEY UNIT 9106-0003 RELEASE RECORD found to be present in secondary side systems and components, and unmonitored spills that drained to the discharge canal. In 1986, samples were taken from the legacy dredge spoils removed in 1979 dredged spoils area and from recently dredged canal sediment. The sample analyses indicated that the concentrations of Cs-137, Co-60 and other radionuclides were a small fraction of the DCGLs for those nuclides that could be identified by gamma spectroscopy. (refer to NE-86-RA- 1142 dated 11-13-86). None of the available historical information reviewed would support a conclusion that any residual activity in this survey unit was present at concentrations greater than the respective DCGLs.

Additional information was provided by several historical documents, including the "Results of Scoping Survey", (completed 9/1/98), the "Historical Site Assessment", and the HSA Supplement (dated 6-30-00). These documents presented the results of several sediment samples taken in 1997. These sample results indicated concentrations of 0.5 pCi/g for Co-60, 0.024 pCi/g for Cs-134 and 0.722 pCi/g for Cs-137.

A review of the "Initial andSupplemental CharacterizationReports" as well as the previous "Classification Basis Summaries" provided no additional information pertinent to classification.

Characterization was performed by Site Closure personnel in April and May of 2004 to obtain the necessary data of sufficient data quality for final status survey (FSS) planning purposes. Fifteen (15) samples were initially obtained by biased sampling throughout the area. The samples were analyzed off-site using gamma spectroscopy. Hard-to-Detect analyses were also conducted on two (2) of the fifteen (15) samples. The only plant-related dosimetrically significant radionuclides identified in the samples were Cesium- 137 and Cobalt-60 (refer to Table 1).

Table I - Basic

'Statitical Qntitiýsfor* Cs-137 and Co-60 fromn the ChrceiainSte Minimum Value: -6.28E-03 -1.47E-02 Maximum Value: 4.44E-01 1.49E+00 Mean: 9.06E-02 1.59E-01 Median: 3.30E-02 7.46E-03 Standard Deviation: 1.32E-01 3.85E-01 NOTE: The Operational DCGLs are 5.38 pCi/g for Cs-137, 2.59 pCi/g for Co-60; these are used in conjunction with the unity rule to achieve 17 mrem/yr TEDE The FSS Engineer performed a visual inspection and walkdown during May 2006 to assess the physical condition of the survey unit, evaluate access points and travel paths and identify potentially hazardous conditions.

Based upon the historical information and the results of radiological surveys performed during characterization, it was concluded that there was a low Revision 0 4

DISCHARGE CANAL SURVEY UNIT 9106-0003 RELEASE RECORD probability for residual radioactivity to be present in this survey unit in concentrations greater than the Operational DCGLs justifying a final survey unit classification of Class 2 (refer to Section 3).

3. DATA QUALITY OBJECTIVES (DQO)

FSS design and planning is based on the Data Quality Objective (DQO) process as described by the LTP, Procedure RPM 5.1-11, "Preparationof Final Status Survey Plan," and the "Multi-Agency Radiation Survey and Site Investigation Manual" (MARSSIM). A summary of the main features of the DQO process are provided herein.

The DQO process incorporates hypothesis testing and probabilistic sampling distributions to control decision errors during data analysis. Hypothesis testing is a process based on the scientific method that compares a baseline condition to an alternate condition. The baseline condition is technically known as the null hypothesis. Hypothesis testing rests on the premise that the null hypothesis is true and that sufficient evidence must be provided for rejection. In designing the survey plan, the underlying assumption, or null hypothesis was that residual activity in the survey unit exceeded the release criteria. Rejection of the null hypothesis would satisfy the release criteria objective of the FSS.

The primary objective of the Final Status Survey Plan (FSSP) was to demonstrate that the level of residual radioactivity in Survey Unit 9106-0003 did not exceed the release criteria specified in the LTP and that the potential dose from residual radioactivity is As Low As Reasonably Achievable (ALARA).

A fundamental precursor to survey design is to establish a relationship between the release criteria and some measurable quantity. This is done through the development of Derived Concentration Guideline Levels (DCGLs). The DCGLs represent the concentration of radioactivity above background, equivalent to a dose-based release criterion and is presented in terms of surface or mass activity concentrations. Chapter 6 of the LTP describes in detail the modeling used to develop the DCGLs for soil (called Base Case Soil DCGL),

for existing groundwater radioactivity and for future groundwater radioactivity that will be contributed by building foundations and footings.

As described in detail in the LTP, the dose model applied to the discharge canal presumes that the canal sediments are dredged to a depth of three (3) feet and spread for the planting of crops per the Resident Farmer Scenario.

Consequently, the soil DCGLs are directly applied to the canal sediment media which are sampled by coring to a nominal depth of three (3) feet.

The DCGLs presented in Chapter 6 of the LTP were developed for exposures from three (3) components, that is, residual radioactivity in soil, existing groundwater radioactivity, and future groundwater radioactivity from the burial of concrete foundations or footings from site buildings containing Revision 0 5 Revision 0 5

DISCHARGE CANAL SURVEY UNIT 9106-0003 RELEASE RECORD residual radioactivity. Equation 1 shows the mathematical relationship between the three (3) components and the total dose.

Equation 1:

HTotal=HSoil (sediment) + HExisting GW + HFuture GW The total dose under the LTP criteria is twenty-five (25) mrem/yr TEDE from all three components. The allowable total dose under the Connecticut Department of Environmental Protection (CTDEP) radiological remediation standard for Connecticut Yankee (CY) is nineteen (19) mrem/yr TEDE. To satisfy both the LTP and CY CTDEP criteria, the dose from soil must be reduced when using the existing and future groundwater dose values discussed above.

This survey unit is affected by existing groundwater (reference CY memo ISC 06-024). The dose contribution from existing groundwater is bounded to be less than two (2) mrem/yr TEDE, based on field data.

This survey unit is not considered impacted by future groundwater radioactive contamination, as there are no concrete foundations or footings remaining within the groundwater saturated zone in the area (reference CY memo ISC 06-024). The dose contributions from future groundwater, the third component is, therefore, zero (0) mrem/yr TEDE.

Equation 2:

19 mrem/yr~otaj= 17 mrem/yrsoi1+2 mrem/yrExisting GW+O mrem/yrFuture GW The allowable dose for soil in this survey unit is seventeen (17) mrem/yr TEDE as shown by Equation 2 above. The concentration of residual radioactivity resulting in seventeen (17) mrem/yr TEDE is designated as the Operational DCGL, and has been established for the radionuclides of concern as provided in Table 2 Note: The survey design used a much smaller value for investigation than the Operational DCGL provided by Table 2 to conservatively account for the contribution to the total dose from existing and future groundwater which had not been established at the time of planning the FSS.

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DISCHARGE CANAL SURVEY UNIT 9 106-0003 RELEASE RECORD 1-1-.5 4.1 bU-t-O 2.80E+02 1.65E+01 C-14 5.66E+00 3.85E+00 2.26E-01 Mn-54 1.74E+01 1.18E+O1 6.96E-0I Fe-55 2.74E+04 1.86E+04 1.1OE+03 Co-60 3.81E+00 2.59E+00 1.52E-01 Ni-63 7.23E+02 4.92E+02 2.89E+O1 Sr-90 1.55E+00 1.05E+00 6.20E-02 Nb-94 7.12E+00 4.84E+00 2.85E-01 Tc-99 1.26E+O1 8.57E+00 5.04E-01 Ag- 108m 7.14E+00 4.86E+00 2.86E-01 Cs-134 4.67E+00 3.18E+00 1.87E-01 Cs-137 7.91E+00 5.38E+00 3.16E-01 Eu-152 1.01E+01 6.87E+00 4.04E-01 Eu-154 9.29E+00 6.32E+00 3.72E-01 Eu-155 3.92E+02 2.67E+02 1.57E+01 Pu-238 2.96E+01 2.01E+O1 1.18E+00 Pu-239/240 2.67E+01 1.82E+01 1.07E+00 Pu-241 8.70E+02 5.92E+02 3.48E+O I Am-241 (5) 2.58E+01 1.75E+01 1.03E+00 Cm-243/244 2.90E+01 1.97E+01 1.16E+00 (1) Bold indicates those radionuclides considered to be Hard to Detect (HTD)

(2) The Base Case Soil DCGLs for soil are specified by the LTP in Chapter 6 and are equivalent to twenty-five (25) mrem/yr TEDE (3) The Operational DCGL is equivalent to seventeen (17) mrem/yr TEDE (4) The required MDC is equivalent to one (1) mrem/yr TEDE (5) Americium-241 can be analyzed by gamma and alpha spectroscopy and is considered to be Easy to Detect (ETD). The preferred result is the alpha spectroscopy's when both analyses are performed.

Another important facet of the DQO process is to identify the radionuclides of concern and determine the concentration variability. Characterization was performed in April and May of 2004 as discussed in Section 2. Cesium-137 and Cobalt-60 were found to be the predominate radionuclides of concern. The basic statistical quantities (i.e., mean, standard deviation, median) for Cs-137 and Co-60 are provided in Table 1.

As part of the DQOs applied to laboratory processes, analysis results were reported as actual calculated results. Results reported as less than Minimum Detectable Concentration (<MDC) were not accepted for FSS. Sample report Revision 0 7

DISCHARGE CANAL SURVEY UNIT 9106-0003 RELEASE RECORD summaries included unique sample identification, analytical method, radionuclide, result, and uncertainty to two (2) standard deviations, laboratory data qualifiers, units, and the required and observed MDC.

4. SURVEY DESIGN The level of effort associated with planning a survey is based on the complexity of the survey and nature of the hazards. To assist the FSS Engineers when preparing survey plans for FSS, guidance is provided in Procedure RPM 5.1-11, "Preparationof Final Status Survey Plans". By design, the FSSP meets the ALARA criteria for soils as specified in Chapter 4 of the LTP.

Characterization was performed by Site Closure personnel in April and May 2004 to determine existing conditions and obtain radiological data for Final Status Survey (FSS). The DQO process determined that Cs-137 and Co-60 would be the radionuclides of concern (refer to Section 3). The sum of fractions or unity rule would be used with the individual Operational DCGLs because multiple radionuclides (Cs-137 and Co-60) were considered in the survey design. Other radionuclides identified during FSS would be evaluated to ensure adequate survey design and compliance with the unity rule.

Surrogate DCGLs were not required for this survey unit based on process knowledge from FSS of nearby adjacent areas and via screening under LTP Section 5.4.7.2, "Gross Activity DCGLs". Radionuclide screening or de-selection is a process where an individual radionuclide or aggregate may be considered insignificant and eliminated from the FSS. The criteria for de-selection are concentrations less than 5% for individual radionuclides and less than 10% for aggregates.

The Elevated Measurement Comparison (EMC) did not apply to this survey unit since the survey unit is a Class 2 and discrete, elevated areas of contamination were not expected.

The Sign Test was selected as the non-parametric statistical test. The use of the Sign Test did not require the selection or use of a background reference area, which simplified survey design and implementation. This approach was conservative since it included background Cs-137 as part of the sample set.

The number of soil samples for FSS was determined in accordance with Procedure RPM 5.1-12, "Determination of the Number of Samples for Final Status Survey. " The Lower Bound of the Gray Region (LBGR) was set in accordance with Procedure RPM 5.1-11 to 0.5 to maintain the relative shift (A/a) in the range of 1 and 3. The resulting relative shift was 1.9. A Prospective Power Curve was generated using COMPASS, a software package developed under the sponsorship of the United States Nuclear Regulatory Commission (USNRC) for implementation of the MARSSIM in support of the decommissioning license termination rule (10 CFR 20, Subpart E). The result of the COMPASS computer run showed adequate power for the survey design.

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DISCHARGE CANAL SURVEY UNIT 9106-0003 RELEASE RECORD Survey design specified sixteen (16) sediment samples for non-parametric statistical testing.

The grid pattern and locations of the soil samples were determined using Visual Sample Plan (VSP) in accordance with Procedure RPM 5.1-14, "Identifying, and Marking Surface Sample Locations for Final Status Survey. " Visual Sample Plan was created by Pacific Northwest National Laboratory (PNNL) for the United States Department of Energy. A systematic triangular grid pattern with a random starting point was selected for sample design, which is appropriate for a Class 2 area.

Sample locations were identified using AutoCAD-LT, a commercially available plotting software package with coordinates consistent with the Connecticut State Plane System. These coordinates were integrated with a GPS to locate sample locations in the field. Sample Measurement Locations for the design are listed with the GPS coordinates in Table 3.

STable 3 -Sampl~eWasurment Locations N~ith Associated (,PS Coordinates M=D~signation* .......... =l Northng L asting 9106-0003-OOIF 235918.25 669524.39 9106-0003-002F 235918.25 669605.02 9106-0003-003F 235848.42 669484.07 9106-0003-004F 235848.42 669564.70 9106-0003-005F 235848.42 669645.33 9106-0003-006F 235848.42 669725.96 9106-0003-007F 235778.60 669605.02 9106-0003-008F 235778.60 669685.64 9106-0003-009F 235778.60 669766.27 9106-0003-OIOF 235778.60 669846.90 9106-0003-011 F 235778.60 669927.53 9106-0003-012F 235778.60 670008.16 9106-0003-013F 235708.77 669806.59 9106-0003-014F 235708.77 669887.22 9106-0003-015F 235708.77 669967.85 9106-0003-016F 235708.77 670048.47 There was to be one (1) sediment core to be taken as a judgmental sample. The location was selected based on its proximity to the outfall of a culvert which drains from a low-lying area along the Independent Spent Fuel Storage Installation (ISFSI) haul road.

Although Procedure RPM 5.1-11 specifies that 5% of the samples must be selected for HTD analysis, four (4) sediment samples were analyzed for HTDs, exceeding the percentage required. Two (2) samples for statistical testing were randomly selected for HTD radionuclide analysis using the Microsoft Excel "RAND" function. In addition, two (2) samples, which were determined to contribute the greatest dose based on gamma only analyses were also selected Revision 0 9

DISCHARGE CANAL SURVEY UNIT 9106-0003 RELEASE RECORD for HTD analyses. This number of HTD analyses exceeded the 5%

requirement. Each sample was sent off-site for a full suite analysis of the HTD radionuclides specified in Table 2.

The implementation of quality control measures as referenced by Procedure RPM 5.1-24, "Split Sample Assessment for Final Status Survey, " included the collection of two (2) sediment samples for "split sample" analysis by the off-site laboratory. These locations were selected randomly using the Microsoft Excel "RAND" function. The number of quality control samples exceeded the 5%

requirement.

Section 5.7.3.2.6 of the LTP specifies that scanning is not required for the FSS of the Discharge Canal. Table 4 provides a synopsis of the survey design.

Survey Unit d on AutoUAD-LI and Visual Area Sample Plan calculations Type I and Type 2 errors were 0.05, Number of 16 sigma was 0.257 the LBGR was set to 0.5 Measurements to maintain Relative Shift in the range of I and 3, Relative Shift was 1.9 Grid Spacing 24.5 Based on triangular grid Design DCGL 3.16 pCi/g Cs-137 To achieve 10 mrem/yr TEDE 1.52 pCi/g Co-60 Operational 5.38 pCi/g Cs-137 To achieve 17 mrem/yr TEDE (2)to demonstrate compliance with DCGL 2.59 pCi/g Co-60 Equation 2 of this Release Record Scan Coverage N/A The LTP exempts this area Sediment Investigation 5.38 pCi/g Cs-137 The Operational DCGL meets the LTP Level 2.59 pCi/g Co-60 criteria for a Class 2 survey unit (1) The survey design used a much smaller value for investigation than the Operational DCGL provided by Table 2 as the total dose from existing and future groundwater had not been established at the time of planning the FSS (2) The allowable dose for soil in this survey unit is seventeen (17) mrem/yr TEDE as the total dose from existing and future groundwater has been established (reference CY memo ISC 06-024)

5. SURVEY IMPLEMENTATION Final status survey field activities were conducted under Work Plan and Inspection Record (WP&IR) 2006-0021. The WP&IR package included a detailed FSSP, job safety analysis, job planning checklist and related procedures for reference. Daily briefings were conducted to discuss the expectations for job performance and the safety aspects of the survey. The "Daily Survey Journal" was used to document field activities and other information pertaining to the FSS.

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DISCHARGE CANAL SURVEY UNIT 9106-0003 RELEASE RECORD Using GPS coordinates, sample measurement locations were identified in NAD 1927 coordinates that were supplied to the sampling vendor, Ocean Survey Inc. (OSI) of Old Saybrook, Connecticut. Discharge Canal sampling was accomplished using direct push technology to collect composite samples of bottom and average high water mark sediments. Sediment cores from the Discharge Canal were obtained by OSI using a vibrating corer that is platform mounted on a sampling vessel. The core barrel was a three (3) inch diameter thin-walled aluminum tube which also serves as a core liner (ten (10) feet or less). A core catcher was available to prevent the sample from sliding out of the bottom of the tube. Vessel positioning and the determination of sample locations will be accomplished using a global positioning system (GPS) interfaced with a navigation and data logging system.

After extraction, water was drained from above the sample by drilling holes above the sediment. The liner was cut, capped, sealed, labeled and turned over from the Ocean Surveys, Inc. to site personnel who processed and controlled the samples under Chain-of-Custody (COC). Rinsing of the barrel and associated equipment was performed between sampling events. New aluminum tubes were used to prevent cross-contamination of subsequent samples.

The sixteen (16) sediment samples were collected and packaged in accordance with Haddam Neck Plant (HNP) Procedure RPM 5.1-3, "Collection of Sample Media for Final Status Survey" and FSS design. Samples were controlled, transported, stored, and transferred to the off-site laboratory using Chain-of-Custody (COC) protocol in accordance with Procedure RPM 5.1-5, "Chain of Custodyfor FinalStatus Survey Samples ".

Four (4) samples (9106-0003-004F, 9106-0003-008F, 9106-0003-0014 and 9106-0003-015F) were selected for HTD radionuclide analysis by the off-site laboratory. Two (2) of these samples (008F and 014F) were selected at random. The others were selected based on being the most dosimetrically significant samples from spectroscopic gamma analyses.

One (1) biased sediment sample (9106-0003-017F) was collected and analyzed by the offsite laboratory for gamma spectroscopy.

The implementation of survey specific quality control measures included the collection of two (2) split samples at locations 9106-0003-004F and 9106-0003-01OF for "split sample" analysis by the off-site laboratory.

6. SURVEY RESULTS The off-site laboratory employed for the radiological analyses of samples was General Engineering Laboratories (GEL) - Charleston, South Carolina. The laboratory analyzed the sixteen (16) samples taken for non-parametric statistical testing and the associated duplicates using gamma spectroscopy. Gamma Revision 0 I1I Revision 0 11

DISCHARGE CANAL SURVEY UNIT 9106-0003 RELEASE RECORD spectroscopy analysis was performed to the required MDC. Gamma spectroscopy results identified some radionuclides meeting the acceptance criteria for detection (i.e., a result greater than two standard deviations uncertainty). All could be de-selected or excluded using the 5% and 10% rule described in Section 4.

Cesium-137 was identified in fourteen (14) and Co-60 was identified in eleven (11) of the sixteen (16) samples.

None of the samples exceeded the Operational DCGL. Gamma spectroscopy sample analysis did not require further investigation. A summary of the sample results is provided in Table 5.

I Tabile 2;- Summary ot'Svdinieit Sam ple Results

.'am'p&Num-r:' 71 1C-j3 Co-60 Fraction of tbe Operational Do" I-~'

Sapl umeP'i' 00 Nuclides of Unity

>p/  ?~I concern (Sign Test) (2) 9106-0003-001 F 1.28E-0 I 1.07E-01 1.1 IE-01 1.48E-01 9106-0003-002F 4.37E-02 1.89E-02 2.63E-02 6.35E-02 9106-0003-003F 3.93E-02 2.45E-02 2.86E-02 6.58E-02 9106-0003-004F 2.92E-01 7.43E-01 5.81 E-01 5.95E-01 9106-0003-005F 2.101E-01 1.36E-01 1.56E-01 1.93E-01 9106-0003-006F 1.05E-01 1.86E-02 4.55E-02 8.27E-02 9106-0003-007F 2.64E-02 2.90E-02 2.74E-02 6.47E-02 9106-0003-008F 2.46E-01 1.09E-01 1.50E-01 2.41E-01 9106-0003-009F 3.18E-0 I 4.45E-01 3.93E-01 4.3 1E-01 9106-0003-01 OF 2.04E-01 2.28E-01 2.15E-01 2.52E-01 9106-0003-012F 4.27E-02 1.45E-02 2.31 E-02 6.03E-02 9106-0003-013F 1.96E-02 2.41 E-02 2.21 E-02 5.93E-02 9106-0003-014F 2.91 E-0I 4.33E-01 3.77E-01 4.09E-01 9106-0003-015F 2.57E-01 8.05E-01 6.11 E-01 6.22E-01 9106-0003-016F 3.52E-04 2.02E-02 1.34E-02 5.06E-02 9106-0003-018F 1.90E-01 1.85E-01 1.82E-01 2.19E-01 (1) The Operational DCGLs from Table 2 are 5.38 pCi/g for Cs-137 and 2.59 pCi/g for Co-60; these are used in conjunction with the unity rule to achieve 17 mrem/yr TEDE (2) This column is the sum of the DCGL unity fraction from identified radionuclides of concern and HTD isotope (Pu-241) exceeding the 5%/10% rule for one or more FSS samples. For those samples not measured for HTD isotopes, an average calculated value of 6.1% of the DCGL was added to each sample.

The sample location designations of Table 5 are not sequentially inclusive because of the necessity to relocate some samples due to the accessibility of the original sample locations. Sample number 9106-0003-01 IF could not be sampled due to an obstruction. Therefore sample number 9106-0003-018F was added as a replacement sample. Sample number 9106-0003-017F was a biased sample location; not part of the non-parametric design.

The off-site laboratory also processed four (4) samples for HTD analysis as required by the sample plan. The requested analyses included alpha Revision 0 12

DISCHARGE CANAL SURVEY UNIT 9106-0003 RELEASE RECORD spectroscopy, gas proportional counting, and liquid scintillation depending on the radionuclide and the measurement method. All analyses met the required MDC. Four (4) of the HTD radionuclides met the accepted criteria for detection (i.e., a result greater than two standard deviations uncertainty) in more than one (1) sample. Each of the positive results for HTD radionuclides could be de-selected based on the 5% and 10% rules, except for Pu-241. These results are presented in Table 6.

<pC/g' I 1*Qprational DCG L 9106-0003-004F 8.31 0.014 9106-0003-008F 54.2 0.092 9106-0003-014F 19.0 0.032 9106-0003-015F 6.63 0.011 (1) The Operational DCGL from Table 2 is 592 pCi/g for Pu-241.

One (1) biased sample was collected at a location selected by FSS Supervision based on professional judgment and observation. Gamma spectroscopy analysis was performed by the off-site laboratory to the required MDC. The sample was at 0.8% of the Operational DCGL. No further action or investigations were required (see Table 7).

STable 7 - Biased Sample Results"'

s-.. Co-60 .. Fraction of t*]e

• mSample Number - *g !i* operational O

~

p~i/g> ~ilgDCGLP 9106-0003-017F 0.OOE+00 2.08E-02 0.008 (1) The Operational DCGLs from Table 2 are 5.38 pCi/g for Cs-137 and 2.59 pCi/g for Co-60 and are used in conjunction with the unity rule to achieve 17 mrem/yr TEDE

7. QUALITY CONTROL The off-site laboratory processed the split samples and performed gamma spectroscopy analysis. Two (2) of the samples were selected for analysis, which exceeds the 5% minimum required by the LTP. The data were evaluated using USNRC acceptance criteria specified in Inspection Procedure 84750 as detailed in HNP Procedure RPM 5.1-24, "Split Sample Assessment for Final Status Survey. " There was acceptable agreement between the field split results for both of the "split sample" pairs tested.

The sample analysis vendor, General Engineering Laboratories (GEL) -

Charleston, South Carolina, maintained quality control and quality assurance plans as part of normal operation. Refer to Attachment 2 for data and data quality analysis results.

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DISCHARGE CANAL SURVEY UNIT 9106-0003 RELEASE RECORD

8. INVESTIGATIONS AND RESULTS Sample investigation levels were not exceeded for this unit, consequently none were performed.

9. REMEDIATION AND RESULTS Historically, no radiological remedial action as described by MARSSIM Section 5.4 was performed in this survey unit prior to or as a result of the FSS. Health Physics TSD BCY-HP-0078, "ALARA Evaluation of Soil Remediation in Support of Final Status Survey, " determined that remediation beyond that required to meet the release criteria to be unnecessary and that the remaining residual radioactivity in soil was ALARA.

10. CHANGES FROM THE FINAL STATUS SURVEY PLAN The survey was designed to ten (10) mrem/yr TEDE which was conservative and necessary at the time of FSS planning. It is no longer required as the total dose from existing and future groundwater has been established. The dose for soil used to demonstrate compliance with the LTP and CTDEP criteria is seventeen (17) mrem/yr TEDE as discussed in Section 2 of this Release Record.

11. DATA QUALITY ASSESSMENT (DQA)

The DQO sample design and data were reviewed in accordance with Procedure RPM 5.1-23, "Data Quality Assessment. " The sample design had adequate power as indicated by the Retrospective Power Curve. The Sign Test was performed on the data and compared to the original assumptions of the DQOs.

The evaluation of the Sign Test results indicates that the survey unit passes the unrestricted release criterion, thus, the null hypothesis is rejected.

Documentation was complete and legible. Surveys and sample collection were consistent with the DQOs and were sufficient to ensure that the survey unit was properly designated as Class 2.

The preliminary data review consisted of calculating basic statistical quantities (e.g., mean, median, standard deviation). The standard deviation of the sample results was below the design value used. This is represented by a favorable shift in the retrospective power curve as shown in Attachment 2f. This would indicate the retrospective power exceeds the prospective power, indicating that the design sample population was adequate. The mean and median values are well below the Operational DCGL when used in conjunction with the unity rule.

Therefore, the survey unit meets the unrestricted release criterion with adequate power as required by the DQOs.

Revision 0 14

DISCHARGE CANAL SURVEY UNIT 9106-0003 RELEASE RECORD The range of the data, about 2.98 standard deviations, was not unusually large.

The difference between the mean and median was 5.5% of the standard deviation which indicates limited skewness in the data. The data was represented graphically through posting plots, a frequency plot, and a quantile plot. The frequency plot shows some positive skewness as confirmed by the calculated skew of 1.2.

All data, assessments, and graphical representations are provided in Attachment 2.

12. ANOMALIES An anomaly was encountered at one non-parametric sample location which could not be sampled due to an obstruction. The sample (9106-0003-01 IF) was replaced with another randomly generated location (9106-0003-018F). This is noted in the field notes and other documentation associated with this survey unit.

In addition, one HTD radionuclide was reported in concentrations exceeding the 5% and 10% rule for de-selection. Therefore, the individual Operational DCGLs for Pu-239 was included into sample analyses in conjunction with the unity rule to ensure adequate survey design in accordance with the DQOs. The result of the COMPASS computer run showed adequate power and maintained the original sixteen (16) sediment samples for non-parametric statistical testing.

13. CONCLUSION Survey Unit 9106-0003 has met the final DQOs of the FSS. The ALARA criteria for soils as specified in Chapter 4 of the LTP were achieved. Elevated Measurement Comparison and remediation was not required.

The sample data passed the Sign Test. The null hypothesis was rejected.

Graphical representation of data indicates some positive skewness that is probably due to the differences in terrain and the collection of runoff. The Retrospective Power Curve generated using COMPASS shows adequate power was achieved. The survey unit was properly designated as Class 2.

The dose contribution from soil is 4.3 mrem/yr TEDE based on the average concentration of the samples used for non-parametric statistical sampling.

This survey unit is affected by existing groundwater (reference CY memo ISC 06-024). Therefore, the dose contribution from existing groundwater is two (2) mrem/yr TEDE.

This survey unit is not considered impacted by future groundwater radioactive contamination, as there are no concrete foundations or footings containing residual radioactive material within the groundwater saturated zone in the area (reference CY memo ISC 06-024). The dose contribution from future groundwater, the third dose component, is therefore 0 mrem/yr TEDE.

Revision 0 15

DISCHARGE CANAL SURVEY UNIT 9106-0003 RELEASE RECORD The average total dose from residual radioactivity in this survey unit, including exposures from the three (3) components as described in Section 3, that is, residual radioactivity in soil, existing groundwater radioactivity, and future groundwater radioactivity from the burial of concrete foundations or footings from site buildings containing residual radioactivity, will not exceed 6.3 mrem/yr Total Effective Dose Equivalent (TEDE).

14. ATTACHMENTS 14.1 Attachment 1 - Figures 14.2 Attachment 2 - Sample and Statistical Data Revision 0 16 Revision 0 16

DISCHARGE CANAL SURVEY UNIT 9106-0003 RELEASE RECORD Attachment 1 Figures (5 pages)

A 141 Connecticut Yankee Atomic Power Company Fig*u 1 Site MapWith Reference To Survey Unit 9106-0003

Sample Loation 9 qf Pond 5

1 18 4 0 30 60 Feet 3

Connecticut Yankee Atomic PowerCompany 9106-0003 FinalStatus Survey Sample Locations

Note.

0.318 Clmdum-137 zesidts aw given inpCilg.

0.19 6

& n

'W Pond 0 30 60

,i IFeet 9106-0003 FinalStatus Survey Cesium-137 PostingPlot

Sample Location NOTE.-

Cobalt-60 0.445 raguk, are given in 0.136 pcilg 9 000.185 'l Pond 0.743

DISCHARGE CANAL SURVEY UNIT 9106-0003 RELEASE RECORD Attachment 2a Sample Data (186 Pages)

Table of Contents G eneral Narrative .................................................................. 1 Chain of Custody and Supporting Documentation ........... 4 Radiological Analysis .......................................................... I Sample Data Summary ...................................................... 22 Q uality C ontrol D ata ........................................................... 64

General Narrative 1

CASE NARRATIVE For CONNECTICUT YANKEE RE: Sediment PO# 002332 Work Order: 162335 SDG: MSR #06-0652 June 2, 2006 Laboratory Identification:

General Engineering Laboratories, LLC Mailing Address:

P.O. Box 30712 Charleston, South Carolina 29417 Express Mail Delivery and Shippin2 Address:

2040 Savage Road Charleston, South Carolina 29407 Telephone Number:

(843) 556-8171 Summary:

Sample receipt The sample(s) for this Project arrived at General Engineering Laboratories, LLC, (GEL) in Charleston, South Carolina on May 5, 2006. All sample containers arrived without any visible signs of tampering or breakage. The chain of custody contained the proper documentation and signatures.

The laboratory received the following sample(s):

Sample ID Client Sample ID 162335001 9106-0003-001F 162335002 9106-0003-002F 162335003 9106-0003-003F 162335004 9106-0003-004F 162335005 9106-0003-004FS 162335006 9106-0003-005F 162335007 9106-0003-006F GENERAL ENGINEERING LABORATORIES, LLC a Member of THE GEL GROUP, INC.

P.O. Box 30712 - Charleston, SC 29417

• 2040 Savage Road (29407)

Phone (843) 556-8171 - Fat(843) 766-1178

• www.gel.com

Sample ID Client Sample ID 162335008 9106-0003-007F 162335009 9106-0003-009F 162335010 9106-0003-OIOF 162335011 9106-0003-O1OFS 162335012 9106-0003-012F 162335013 9106-0003-013F 162335014 9106-0003-015F 162335015 9106-0003-016F 162335016 9106-0003-017F 162335017 9106-0003-018F 162335018 9106-0003-008F 162335019 9106-0003-014F Items of Note:

There are no items of note.

Case Narrative:

Sample analyses were conducted using methodology as outlined in General Engineering Laboratories (GEL) Standard Operating Procedures. Any technical or administrative problems during analysis, data review, and reduction are listed below by analytical parameter.

Analytical Request:

Seventeen sediment samples were analyzed for FSSGAM.

Two sediment samples were analyzed for FSSALL.

Internal Chain of Custody:

Custody was maintained for the sample(s).

Data Package:

The enclosed data package contains the following sections: Case Narrative, Chain of Custody and Supporting Documentation and all analytical fractions.

I certify that this data package is in compliance with the SOW, both technically and for completeness, for other than the conditions detailed above. Release of the data contained in this hard copy data package has been authorized by the Laboratory Manager or a designee, as verified by the following signature.

Cheryl Jones Project Manager GENERAL ENGINEERING LABORATORIES, LLC a Member of THE GEL GROUP,INC.

P.O. Box 30712

• Charleston, SC 29417

• 2040 Savage Road (29407)

Phone (843) 556-8171 ° Fax (843) 766-1178 . www.gel.com 3

Chain of Custody and Supporting Documentation 4

Health Physics Procedure GPP-GGGR-R5104-003 -Attachment B-CY-001 Major Health Physics Procedure GPP-GGGR-R5 104-003-Attachment B-CY-00 1 Major Connecticut Yankee Atomic Power Company 362 Injun Hollow Road, East Hampton, CT 06424 Project Name: Haddam Neck Decommissic Contact Name & Phone:

Jack McCarthy 860-267-2556 Ext. 3024 Analytical Lab (Name, City, State)

General Engineering Laboratories 2040 Savage Road. Charleston SC. 29407 843 556 8171. Attn. Cheryl Jones Comment

.. "P -vation Priority: Z 30 D.E] 14 D. n] 7 D.

Comment, Preservation Samples Shipped Via:

Z Fed Ex LI uPs n] Hand

1) Relinquished By C1 Other

3) Relinquished By Bill of Lading #

7-t12O-%?,a- 0261

Health Physics Procedure GPP-GGGR-R5104-003-Attachment B-CY-00 I Major Connecticut Yankee Atomic Power Company Chain of Custody Form No. 2006-00312 362 Injun Hollow Road, East Hampton, CT 06424  ! V .f .2 860-267-2556 ,u#--.-,.--.u I(9 3 '

Project Name: ]Haddam Neck Decommissioning Analyses Requested ýL'ý" Use Oly"'

Contact Name & Phone: Cmmient:,.

Jack McCarthy 860-267-2556 Ext. 3024 Analytical Lab (Name, City, State) ,1 *,

General Engineering Laboratories

• 2040 Savage Road. Charleston SC. 29407 843 556 8171. Attn. Cheryl Jones Co V V)

Priority: [ 30 D. LI 14 D. EJ 7 D. Container J

Sample Size-Media Type &Type Sample Designation Date Time Code Code Code Comment, Preservation ¢lab S aipie*I.

p 9106-0003-OO1F 4/24/06 14:13 SE C BP X Transferred from COC2006-00221 .7 .

9106-0003-002F 4/24/06 14:39 SE C BP X Transferred from COC2006-00221 ci! 9106-0003-003F 4/24/06 15:01 SE C BP X Transferred from COC2006-00221 9106-0003-004F 4/25/06 08:41 SE C BP X Transferred from COC2006-00223 ,

9106-0003-004FS 4/25/06 08:41 SE C BP X Transferred from COC2006-00223 :,

9106-0003-005F 4/25/06 09:21 SE C BP X Transferred from COC2006-00223 ,.

9106-0003-006F 4/25/06 09:46 SE C BP X Transferred from COC2006-00223 .> .

/t 9106-0003-007F 4/25/06 10:28 SE C BP X Transferred from COC2006-00223 9106-0003-008F 4/25/06 11:15 SE C BP X Transferred from COC2006-00223 NOTES: PO #: 002332 MSR #: 0 6 -° ¢ SSWP# NA Z LTP QA El Radwaste QA El Non QA Samples Shipped Via: :ptanal Con'tainer:

Combined samples 9106-0003-003F taken on 4/25/06 @08:19 and 9106-0003-003FB taken on 4/25/06 @ 08:19 in order to have sufficient sample for counting. Z El UPS FedLI s Exu: < 'I--..*. .Deg, iTemp.*,

... ," l,7.,,.-:,.**<*:**.C-ElHand Cus d~y' Sealed?

___

__ __ __

__ __ ___

__Y-0-1 NE t

1) Relinquished By Date/Time 2) ec ived By Date Time Custo'dy S1 Intact?

S- /13.10 , d n6 Other ,

3) Relinquished By Date/Time 4) Received By Date/Time __.______________

Bill of Lading #-

5) Relinquished By Date/Time 6) Received By Date/Time . *2 0- 0 J/?;0O- 0 2 40 . ....<

Connecticut Yankee Statement of Work for Analytical Lab Services CY-ISC-SOW-001

/ Figure 1. Sample Check-in List.

Date/Time Received: iEA 10(, 9 SDG#: 6,K 0 M~~ &2 Work Order Number: . (D'Z3 3 b7 Shipping Ccntainer ID:. "lcllW ' ",

'

- ) 7-- I Chain of Custody#

O1.-'4c)* 9Q L(p Y.00"31 9 OO ( -oo31

1. Custody Seals. ori shipping container intact? *Yes t j No

2. Custody Seals dated and signed? Yesj[ No

3. Chain-of-Custody record present? Yes No [ ]

4. Cooler temperature . c9 ,\

5. Vermiculite/packing materials is: Wet [I Dry ]') fn Fr 6.' Number of samples in shipping container: [ io3,e n Eq I rh*71"n el.

7. Sample holding times exceeded? Yes [ No

10. Were any anomalies identified in sample receipt? Yes ' ] No

• 1. .Description of anomalies (include sample numbers):

Sample Custodian/Laboratory: .(2 Irv; (4 C'M Dat:. -)

Telephoned to: On By .

7

SAMPLE RECEIPT & REVIEW FORM IF PMuse only I (a2 33 IClient:

Date Received:

Received By:

reN ' 5

'4 QL4 6 40 6l PM(A) Review (ensure non-counftorM ng items are resolved prior to signing):

SDG/ARCOC/Work Order:

____________________

Sample Receipt Criteria Comments/Qualifiers (Required for Non-Conforming Items) 1 Shipping containers received intact Circle Applicable: seals broken damaged container leaking container other (describe) and sealed?

Samples requiring cold Circle Coolant # ice bags blue ice dry ice none 2 preservation within (4 +/- 2 C)?

Record preservation method. /" Per r)L-t5 Chain of custody documents included with shipment?

4 Sample containers intact and Circle Applicable: seals broken damaged container leaking container other (describe) sealed?

5 Samples requiring chemical Sample ID's, containers affected and observed pH:

preservation at proper pH?

Sample ID's and containers affected:

6 VOA vials free of headspace (defined as < 6mm bubble)?

Are Encore containers present?

7 (If yes, immediately deliver to VOA laboratory) 8 Samples received within holding Id'S and tests affected:

time?

9 Sample ID's on COC match ID's Sample ID's and containers affected:

on bottles?

10IDate & time on COC match date Sample ID's affected:

& time on bottles?

1Number of containers received Sample ID's affected:

match number indicated on COC?

COC form is properly signed in 12 relinquished/received sections?

-"Air Bill ,Tracking #'s, & d. to I Additional Comments "z--. ,

. * " RSO RAD Receipt #

SrG~ * *If > x2 area background is observed on samples identified as "non-Spt z regulated/non-radioactive", contact the Radiation Safety group for further

_ __ investigation.

A Radiological Classification?7. Maximum Counts Observed*: t) 6P ju B PCB Regulated? Comments:

Shipped as DOT1Hazardous C Material? If yes, contact Waste Hazard Class Shipped:

Manager or ESH Manager. I UN#:

PM (or PMA) review of Hazard classification: Initials /._, _- Date:

r r 8 (./

RADIOLOGICAL ANALYSIS 1

Radiochemistry Case Narrative Connecticut Yankee Atomic Power Co. (YANK)

Work Order 162335 Method/Analysis Information Product: Alphaspec Am241, Cm, Solid ALL FSS Analytical Method: DOE EML HASL-300, Am-05-RC Modified Prep Method: Ash Soil Prep Dry Soil Prep GL-RAD-A-021 Method: Dry Soil Prep Analytical Batch Number: 530940 Prep Batch Number: 527706 Dry Soil Prep GL-RAD-A-021 Batch Number: 527705 Sample ID Client ID 162335018 9106-0003-008F 162335019 9106-0003-014F 1201095113 Method Blank (MB) 1201095114 162335018(9106-0003-008F) Sample Duplicate (DUP) 1201095115 162335018(9106-0003-008F) Matrix Spike (MS) 1201095116 Laboratory Control Sample (LCS)

SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-01 1 REV# 14.

Calibration Information:

Calibration Information All initial and continuing calibration requirements have been met.

Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).

Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.

2

Quality Control (QC) Information:

Blank Information The blank volume is representative of the sample volume in this batch.

Designated QC The following sample was used for QC: 162335018 (9106-0003-008F).

QC Information All of the QC samples met the required acceptance limits.

Technical Information:

Holding Time All sample procedures for this sample set were performed within the required holding time.

Preparation Information All preparation criteria have been met for these analyses.

Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis.

Miscellaneous Information:

NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. A nonconformance report (NCR) was not generated for this SDG.

Manual Integration No manual integrations were performed on data in this batch.

Additional Comments Additional comments were not required for this sample set.

Qualifier information Manual qualifiers were not required.

Method/Analysis Information 3

Product: Alphaspec Pu, Solid-ALL FSS Analytical Method: DOE EML HASL-300, Pu- 11-RC Modified Prep Method: Ash Soil Prep Dry Soil Prep GL-RAD-A-021 Method: Dry Soil Prep Analytical Batch Number: 530942 Prep Batch Number: 527706 Dry Soil Prep GL-RAD-A-021 Batch Number: 527705 Sample ID Client ID 162335018 9106-0003-008F 162335019 9106-0003-014F 1201095121 Method Blank (MB) 1201095122 162335018(9106-0003-008F) Sample Duplicate (DUP) 1201095123 162335018(9106-0003-008F) Matrix Spike (MS) 1201095124 Laboratory Control Sample (LCS)

SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-01 I REV# 14.

Calibration Information:

Calibration Information All initial and continuing calibration requirements have been met.

Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).

Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.

Quality Control (QC) Information:

Blank Information The blank volume is representative of the sample volume in this batch.

Designated QC The following sample was used for QC: 162335018 (9106-0003-008F).

QC Information All of the QC samples met the required acceptance limits.

4

Technical Information:

Holding Time All sample procedures for this sample set were performed within the required holding time.

Preparation Information All preparation criteria have been met for these analyses.

Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis.

Miscellaneous Information:

NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. A nonconformance report (NCR) was not generated for this SDG.

Manual Integration No manual integrations were performed on data in this batch.

Additional Comments Additional comments were not required for this sample set.

Qualifier information Manual qualifiers were not required.

Method/Analysis Information Product: Liquid Scint Pu241, Solid-ALL FSS Analytical Method: DOE EML HASL-300, Pu- 11-RC Modified Prep Method: Ash Soil Prep Dry Soil Prep GL-RAD-A-021 Method: Dry Soil Prep Analytical Batch Number: 530943 Prep Batch Number: 527706 Dry Soil Prep GL-RAD-A-021 Batch Number: 527705 5

Sample ID Client ID 162335018 9106-0003-008F 162335019 9106-0003-014F 1201095125 Method Blank (MB) 1201095126 162335018(9106-0003-008F) Sample Duplicate (DUP) 1201095127 162335018(9106-0003-008F) Matrix Spike (MS) 1201095128 Laboratory Control Sample (LCS)

SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-035 REV# 8.

Calibration Information:

Calibration Information All initial and continuing calibration requirements have been met.

Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).

Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.

Quality Control (QCQ Information:

Blank Information The blank volume is representative of the sample volume in this batch.

Designated QC The following sample was used for QC: 162335018 (9106-0003-008F).

QC Information All of the QC samples met the required acceptance limits.

Technical Information:

Holding Time All sample procedures for this sample set were performed within the required holding time.

Preparation Information All preparation criteria have been met for these analyses.

Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis.

Miscellaneous Information:

NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from 6

referenced SOP or contractual documents. A nonconformance report (NCR) was not generated for this SDG.

Manual Integration No manual integrations were performed on data in this batch.

Additional Comments Additional comments were not required for this sample set.

Qualifier information Manual qualifiers were not required.

Method/Analysis Information Product: Gamma,Solid-FSS GAM & ALL FSS Analytical Method: EML HASL 300, 4.5.2.3 Prep Method: Dry Soil Prep Analytical Batch Number: 528196 Prep Batch Number: 527705 7

Sample ID Client ID 162335001 9106-0003-001F 162335002 9106-0003-002F 162335003 9106-0003-003F 162335004 9106-0003-004F 162335005 9106-0003-004FS 162335006 9106-0003-005F 162335007 9106-0003-006F 162335008 9106-0003-007F 162335009 9106-0003-009F 162335010 9106-0003-OIOF 162335011 9106-0003-01OFS 162335012 9106-0003-012F 162335013 9106-0003-013F 162335014 9106-0003-015F 162335015 9106-0003-016F 162335016 9106-0003-017F 162335017 9106-0003-018F 162335018 9106-0003-008F 162335019 9106-0003-014F 1201088599 Method Blank (MB) 1201088600 162335001(9106-0003-00 IF) Sample Duplicate (DUP) 1201088601 Laboratory Control Sample (LCS)

SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-013 REV# 11.

Calibration Information:

Calibration Information All initial and continuing calibration requirements have been met.

Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).

Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.

Ouality Control (0C) Information:

Blank Information The blank volume is representative of the sample volume in this batch.

Designated QC The following sample was used for QC: 162335001 (9106-0003-001F).

QC Information 8

All of the QC samples met the required acceptance limits.

Technical Information:

Holding Time All sample procedures for this sample set were performed within the required holding time.

Preparation Information All preparation criteria have been met for these analyses.

Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis.

Miscellaneous Information:

NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. A nonconformance report (NCR) was not generated for this SDG.

Additional Comments Additional comments were not required for this sample set.

Qualifier information 9

Qualifier Reason Analyte Sample Data rejected due to high Full-Width UI Bismuth-214 1201088599 Half-Maximum.

Cesium- 137 162335016 Manganese-54 162335019 UI Data rejected due to interference. Europium- 155 162335018 UI Data rejected due to low abundance. Cesium- 134 162335002 162335003 162335004 162335006 162335007 162335009 162335010 162335011 162335012 162335015 162335016 162335019 Cobalt-60 162335011 Radium-226 1201088599 Method/Analysis Information Product: GFPC, Sr90, solid-ALL FSS Analytical Method: EPA 905.0 Modified Prep Method: Ash Soil Prep Dry Soil Prep GL-RAD-A-021 Method: Dry Soil Prep Analytical Batch Number: 535512 Prep Batch Number: 527706 Dry Soil Prep GL-RAD-A-021 Batch Number: 527705 10

Sample ID Client ID 162335018 9106-0003-008F 162335019 9106-0003-014F 1201105909 Method Blank (MB) 1201105910 162335018(9106-0003-008F) Sample Duplicate (DUP) 1201105911 162335018(9106-0003-008F) Matrix Spike (MS) 1201105912 Laboratory Control Sample (LCS)

SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-004 REV# 10.

Calibration Information:

Calibration Information All initial and continuing calibration requirements have been met.

Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).

Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.

Quality Control (QC) Information:

Blank Information The blank volume is representative of the sample volume in this batch.

Designated QC The following sample was used for QC: 162335018 (9106-0003-008F).

QC Information All of the QC samples met the required acceptance limits.

Technical Information:

Holding Time All sample procedures for this sample set were performed within the required holding time.

Preparation Information All preparation criteria have been met for these analyses.

Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis.

Chemical Recoveries All chemical recoveries meet the required acceptance limits for this sample set.

11

Miscellaneous Information:

NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. A nonconformance report (NCR) was not generated for this SDG.

Additional Comments Additional comments were not required for this sample set.

Qualifier information Manual qualifiers were not required.

Method/Analysis Information Product: Liquid Scint Tc99, Solid-ALL FSS Analytical Method: DOE EML HASL-300, Tc-02-RC Modified Analytical Batch Number: 531704 Sample ID Client ID 162335018 9106-0003-008F 162335019 9106-0003-014F 1201096867 Method Blank (MB) 1201096868 162583001(NOL-02-02-005-F-S) Sample Duplicate (DUP) 1201096869 162583001(NOL-02-02-005-F-S) Matrix Spike (MS) 1201096870 Laboratory Control Sample (LCS)

SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-005 REV# 13.

Calibration Information:

Calibration Information All initial and continuing calibration requirements have been met.

Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).

Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.

12

Quality Control (QC) Information:

Blank Information The blank volume is representative of the sample volume in this batch.

Designated QC The following sample was used for QC: 162583001 (NOL-02-02-005-F-S).

QC Information All of the QC samples met the required acceptance limits.

Technical Information:

Holding Time All sample procedures for this sample set were performed within the required holding time.

Preparation Information All preparation criteria have been met for these analyses.

Sample Re-prep/Re-analysis Sample 162335018 (9106-0003-008F) was recounted due to high MDA.

Miscellaneous Information:

NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. A nonconformance report (NCR) was not generated for this SDG.

Additional Comments Additional comments were not required for this sample set.

Qualifier information Manual qualifiers were not required.

Method/Analysis Information Product: Liquid Scint Fe55, Solid-ALL FSS Analytical Method: DOE RESL Fe-1, Modified Prep Method: Ash Soil Prep Dry Soil Prep GL-RAD-A-021 Method: Dry Soil Prep Analytical Batch Number: 535483 Prep Batch Number: 527706 Dry Soil Prep GL-RAD-A-021 Batch Number: 527705 13

Sample ID Client ID 162335018 9106-0003-008F 162335019 9106-0003-014F 1201105872 Method Blank (MB) 1201105873 162335018(9106-0003-008F) Sample Duplicate (DUP) 1201105874 162335018(9106-0003-008F) Matrix Spike (MS) 1201105875 Laboratory Control Sample (LCS)

SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-040 REV# 3.

Calibration Information:

Calibration Information All initial and continuing calibration requirements have been met.

Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).

Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.

Quality Control (QC) Information:

Blank Information The blank volume is representative of the sample volume in this batch.

Designated QC The following sample was used for QC: 162335018 (9106-0003-008F).

QC Information All of the QC samples met the required acceptance limits.

Technical Information:

Holding Time All sample procedures for this sample set were performed within the required holding time.

Preparation Information All preparation criteria have been met for these analyses.

Sample Re-prep/Re-analysis Samples were reprepped due to low/high carrier/tracer yield.

14

Miscellaneous Information:

NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. A nonconformance report (NCR) was not generated for this SDG.

Additional Comments Additional comments were not required for this sample set.

Qualifier information Manual qualifiers were not required.

Method/Analysis Information Product: Liquid Scint Ni63, Solid-ALL FSS Analytical Method: DOE RESL Ni-1, Modified Prep Method: Ash Soil Prep Dry Soil Prep GL-RAD-A-021 Method: Dry Soil Prep Analytical Batch Number: 527978 Prep Batch Number: 527706 Dry Soil Prep GL-RAD-A-021 Batch Number: 527705 Sample ID Client ID 162335018 9106-0003-008F 162335019 9106-0003-014F 1201088147 Method Blank (MB) 1201088148 162335018(9106-0003-008F) Sample Duplicate (DUP) 1201088149 162335018(9106-0003-008F) Matrix Spike (MS) 1201088150 Laboratory Control Sample (LCS)

SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-022 REV# 8.

Calibration Information:

Calibration Information All initial and continuing calibration requirements have been met.

15

Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).

Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.

Quality Control (Q0 Information:

Blank Information The blank volume is representative of the sample volume in this batch.

Designated QC The following sample was used for QC: 162335018 (9106-0003-008F).

QC Information All of the QC samples met the required acceptance limits.

Technical Information:

Holding Time All sample procedures for this sample set were performed within the required holding time.

Preparation Information All preparation criteria have been met for these analyses.

Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis.

Miscellaneous Information:

NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. The following NCR was generated for this SDG:

NCR 321720 was generated due to Container scanning event for custody missed. 1. The analyst did not scan the samples 162335018 and 162335019 into the batch prior to analysis, however the samples did remain in their custody at all times. The error has been corrected and the analyst has been instructed on the proper scanning procedures. 1. Reporting results.

Additional Comments Additional comments were not required for this sample set.

Qualifier information Manual qualifiers were not required.

Method/Analysis Information 16

Product: LSC, Tritium Dist, Solid-HTD2,ALL FSS Analytical Method: EPA 906.0 Modified Analytical Batch Number: 531705 Sample ID Client ID 162335018 9106-0003-008F 162335019 9106-0003-014F 1201096877 Method Blank (MB) 1201096878 162583001(NOL-02-02-005-F-S) Sample Duplicate (DUP) 1201096879 162583001(NOL-02-02-005-F-S) Matrix Spike (MS) 1201096880 Laboratory Control Sample (LCS)

SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-002 REV# 11.

Calibration Information:

Calibration Information All initial and continuing calibration requirements have been met.

Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).

Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.

Quality Control (QC) Information:

Blank Information The blank volume is representative of the sample volume in this batch.

Designated QC The following sample was used for QC: 162583001 (NOL-02-02-005-F-S).

QC Information All of the QC samples met the required acceptance limits.

Technical Information:

Holding Time All sample procedures for this sample set were performed within the required holding time.

Preparation Information All preparation criteria have been met for these analyses.

17

Sample Re-prep/Re-analysis Sample 1201096877 (MB) was recounted due to high MDA.

Miscellaneous Information:

NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. A nonconformance report (NCR) was not generated for this SDG.

Additional Comments Additional comments were not required for this sample set.

Qualifier information Manual qualifiers were not required.

Method/Analysis Information Product: Liquid Scint C14, Solid AII,FSS Analytical Method: EPA EERF C-01 Modified Analytical Batch Number: 534837 Sample ID Client ID 162335018 9106-0003-008F 162335019 9106-0003-014F 1201104384 Method Blank (MB) 1201104385 162335019(9106-0003-014F) Sample Duplicate (DUP) 1201104386 162335019(9106-0003-014F) Matrix Spike (MS) 1201104387 Laboratory Control Sample (LCS)

SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-003 REV# 8.

Calibration Information:

Calibration Information All initial and continuing calibration requirements have been met.

Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).

18

Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.

Quality Control (Q0 Information:

Blank Information The blank volume is representative of the sample volume in this batch.

Designated QC The following sample was used for QC: 162335019 (9106-0003-014F).

QC Information All of the QC samples met the required acceptance limits.

Technical Information:

Holding Time All sample procedures for this sample set were performed within the required holding time.

Preparation Information All preparation criteria have been met for these analyses.

Sample Re-prep/Re-analysis Samples 1201104385 (9106-0003-014F), 162335018 (9106-0003-008F) and 162335019 (9106-0003-014F) were recounted due to high MDAs. Samples were reprepped due to low/high recovery.

Miscellaneous Information:

NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. A nonconformance report (NCR) was not generated for this SDG.

Additional Comments Additional comments were not required for this sample set.

Qualifier information Manual qualifiers were not required.

Certification Statement Where the analytical method has been performed under NELAP certification, the analysis has met all of the requirements of the NELAC standard unless otherwise noted in the analytical case narrative.

Review Validation:

GEL requires all analytical data to be verified by a qualified data validator. In addition, all data designated for CLP or CLP-like packaging will receive a third level validation upon completion of the 19

data package.

The following data validator verified the information presented in this case narrative:

Reviewer/Date: (- V,ý'46 20

General Engineering Laboratories NCR Report No.: 321720 Form GEL-NCR Revision No.:

Rev. 06/05 COMPANY -WIDE NONCONFORMANCE REPORT Mo.Day Yr. Division: Quality Criteria: Type:

01-JUN-06 Radiochemistry Specifications Process Instrument Type: Test I Method: Matrix Type: Client Code:

BIOASSAY LSC DOE RESL Ni-1, Modified Solid YANK Batch ID: Sample Numbers:

527978 See Below Potentially affected work order(s)(SDG): 162335(MSR#06-0652)

Application Issues:

Container scanning event for custody missed Specification and Requirements NRG Disposition:

Nonconformance

Description:

1. The analyst did not scan the samples 162335018 and 162335019 into 1. Reporting results.

the batch prior to analysis, however the samples did remain in their custody at all times. The error has been corrected and the analyst has been instructed on the proper scanning procedures.

Originator's Name: Data Validator/Group Leader:

Melanie Aycock 01-JUN-06 Heather Anderson 08-JUN-06 Quality Review:

Director:

Page 1 21

SAMPLE DATA

SUMMARY

22

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Report for YANKOO Connecticut Yankee Atomic Power Co.

Client SDG: MSR#06-0652 GEL Work Order: 162335 The Qualifiers in this report are defined as follows:

• A quality control analyte recovery is outside of specified acceptance criteria

• • Analyte is a surrogate compound U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

UI Gamma Spectroscopy--Uncertain identification ND The analyte concentration is not detected above the reporting limit.

The above sample is reported on a dry weight basis except where prohibited by the analytical procedure.

Where the analytical method has been performed under NELAP certification, the analysis has met all of the requirements of the NELAC standard unless qualified on the Certificate of Analysis.

This data report has been prepared and reviewed in accordance with General Engineering Laboratories, LLC standard operating procedures. Please direct any questions to your Project Manager, Cheryl Jones.

Reviewed by 23

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.corn Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: June 7, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0003-001F Proiect: YANK01204 Sample ID: 162335001 Client ID: YANKOO Matrix: Soil Vol. Recv.:

Collect Date: 24-APR-06 Receive Date: 05-MAY-06 Collector: Client Moisture: 15.7%

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS Actinium-228 0.640 +/-0.149 0.0501 +/-0.149 0.106 pCi/g MJHI 05/31/06 1021 528196 1 Americium-241 U 0.00555 +/-0.0707 0.0612 +/-0.0707 0.126 pCi/g Bismuth-212 0.351 +/-0.281 0.0993 +/-0.281 0.211 pCi/g Bismuth-214 0.462 +/-0.0847 0.0266 +/-0.0847 0.0557 pCi/g Cesium-134 U 0.00674 +/-0.0184 0.0164 +/-0.0184 0.0346 pCi/g Cesium-137 0.128 +/-0.0361 0.0135 +/-0.0361 0.0285 pCi/g Cobalt-60 0.107 +/-0.0311 0.0144 +/-0.0311 0.0312 pCi/g Europium-152 U 0.00641 +/-0.043 0.0342 +/-0.043 0.0713 pCi/g Europium-154 U -0.015 +1-0.0505 0.0422 +/-0.0505 0.0909 pCi/g Europium-155 U 0.0713 +/-0.0618 0.0381 +/-0.0618 0.0785 pCi/g Lead-212 0.670 +/-0.0714 0.0212 +/-0.0714 0.0439 pCi/g Lead-214 0.562 +/-0.0771 0.0248 +/-0.0771 0.0517 pCi/g Manganese-54 U -0.0119 +/-0.0207 0.0145 +/-0.0207 0.0307 pCi/g Niobium-94 U 0.0123 +1-0.0151 0.0139 +1-0.0151 0.0292 pCi/g Potassium-40 10.9 +/-0.996 0.131 +/-0.996 0.285 pCi/g Radium-226 0.462 +/-0.0847 0.0266 +/-0.0847 0.0557 pCi/g Silver-108m U 0.0049 +/-0.0138 0.0123 +/-0.0138 0.0258 pCi/g Thallium-208 0.229 +/-0.0399 0.0131 +/-0.0399 0.0277 pCi/g The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 05/07/06 1536 527705 The following Analytical Methods were performed Method Description I EML HASL 300, 4.5.2.3 Notes:

The Qualifiers in this report are defined as follows

• A quality control analyte recovery is outside of specified acceptance criteria

< Result is less than value reported

> Result is greater than value reported 24

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: June 7, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0003-00IF Project: YANKO 1204 Sample ID: 162335001 Client ID: YANK001 Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd A The TIC is a suspected aldol-condensation product BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.

25

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.corn Certificate of Analysis Company : Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: June 7, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0003-002F Project: YANK01204 Sample ID: 162335002 Client ID: YANKOO Matrix: Soil Vol. Recv.:

Collect Date: 24-APR-06 Receive Date: 05-MAY-06 Collector: Client Moisture: 24.9%

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS Actinium-228 0.816 +/-0.163 0.0714 +/-0.163 0.153 pCi/g MJH1 05/31/06 1021 528196 1 Americium-241 U -0.00658 +/-0.123 0.0837 +/-0.123 0.172 pCi/g Bismuth-212 0.668 +/-0.340 0.141 +/-0.340 0.302 pCi/g Bismuth-214 0.737 +/-0.107 0.0333 +/-0.107 0.0707 pCi/g Cesium-134 UUI 0.00 +/-0.0349 0.0284 +/-0.0349 0.0597 pCi/g Cesium-137 0.0437 +/-0.0291 0.0186 +/-0.0291 0.0396 pCi/g Cobalt-60 U 0.0189 +/-0.0258 0.0235 +/-0.0258 0.0509 pCi/g Europium-152 U -0.03 +/-0.0655 0.0538 +/-0.0655 0.112 pCi/g Europium-154 U -0.0149 +/-0.0654 0.0546 +/-0.0654 0.120 pCi/g Europium-155 U 0.0749 +/-0.080 0.0496 +/-0.080 0.102 pCi/g Lead-212 1.06 +/-0.0751 0.0297 +/-0.0751 0.0615 pCi/g Lead-214 0.789 +/-0.0858 0.0373 +/-0.0858 0.0779 pCi/g Manganese-54 U -0.0111 +/-0.0254 0.0206 +/-0.0254 0.0439 pCi/g Niobium-94 U 0.0103 +/-0.0214 0.0189 +/-0.0214 0.0399 pCi/g Potassium-40 12.5 +/-0.989 0.148 +/-0.989 0.334 pCi/g Radium-226 0.737 +/-0.107 0.0333 +/-0.107 0.0707 pCi/g Silver-108m U 0.00613 +/-0.0206 0.0174 +/-0.0206 0.0366 pCi/g Thallium-208 0.340 +/-0.0571 0.0182 +/-0.0571 0.0387 pCi/g The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 05/07/06 1536 527705 The following Analytical Methods were performed Method Description EML HASL 300, 4.5.2.3 Notes:

The Qualifiers in this report are defined as follows:

• A quality control analyte recovery is outside of specified acceptance criteria Result is less than value reported Result is greater than value reported 26

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Certificateof Analvsis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: June 7, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0003-002F Project: YANKO 1204 Sample ID: 162335002 Client ID: YANK001 Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd A The TIC is a suspected aldol-condensation product BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.

27

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: June 7, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0003-003F Proiect: YANKO 1204 Sample ID: 162335003 Client ID: YANKOO 1 Matrix: Soil Vol. Recv.:

Collect Date: 24-APR-06 Receive Date: 05-MAY-06 Collector: Client Moisture: 12.6%

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS Actinium-228 0.691 +/-0.118 0.0423 +/-0.118 0.0912 pCi/g MJH1 05/31/06 1022 528196 1 Americium-241 U 0.0567 +/-0.087 0.0631 +/-0.087 0.130 pCi/g Bismuth-212 0.546 +/-0.249 0.102 +/-0.249 0.218 pCi/g Bismuth-214 0.557 +/-0.0675 0.0257 +/-0.0675 0.0542 pCi/g Cesium-134 UUI 0.00 +/-0.027 0.0184 +/-0.027 0.0387 pCi/g Cesium-137 0.0393 +/-0.0252 0.0139 +/-0.0252 0.0293 pCi/g Cobalt-60 U 0.0245 +/-0.0188 0.018 +/-0.0188 0.0385 pCi/g Europium-152 U 0.0141 +/-0.0403 0.0369 +/-0.0403 0.0769 pCi/g Europium-154 U -0.0796 +/-0.0517 0.0374 +/-0.0517 0.0818 pCi/g Europium-155 U 0.0703 +/-0.0578 0.0397 +/-0.0578 0.0816 pCi/g Lead-212 0.715 +/-0.0498 0.0219 +/-0.0498 0.0453 pCi/g Lead-214 0.693 +/-0.0729 0.0281 +/-0.0729 0.0583 pCi/g Manganese-54 U 0.00312 +/-0.0175 0.0153 +/-0.0175 0.0323 pCi/g Niobium-94 U -0.00416 +/-0.0165 0.0123 +/-0.0165 0.026 pCi/g Potassium-40 9.93 +/-0.658 0.110 +/-0.658 0.246 pCi/g Radium-226 0.557 +/-0.0675 0.0257 +/-0.0675 0.0542 pCi/g Silver-108m U -0.0208 +/-0.015 0.0121 +/-0.015 0.0253 pCi/g Thallium-208 0.197 +/-0.037 0.0139 +/-0.037 0.0293 pCi/g The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 05/07/06 1536 527705 The following Analytical Methods were performed Method Description I EML HASL 300, 4.5.2.3 Notes:

The Qualifiers in this report are defined as follows

• A quality control analyte recovery is outside of specified acceptance criteria

< Result is less than value reported

> Result is greater than value reported 28

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: June 7, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0003-003F Project: YANK01204 Sample ID: 162335003 Client ID: YANKOOI Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd A The TIC is a suspected aldol-condensation product BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.

29

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificatie of Annlvqi, Company: Connecticut Yankee Atomic Power Address: 362 lnjun Hollow Rd East Hampton, Connecticut 06424 Report Date: June 7, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0003-004F Proiect: YANKO 1204 Sample ID: 162335004 Client ID: YANK001 Matrix: Soil Vol. Recv.:

Collect Date: 25-APR-06 Receive Date: 05-MAY-06 Collector: Client Moisture: 20.9%

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS Actinium-228 0.743 +/-0.177 0.0741 +/-0.177 0.157 pCi/g MJH1 05/31/06 1022 528196 1 Americium-241 U 0.080 +/-0.0848 0.0694 +/-0.0848 0.143 pCi/g Bismuth-212 0.561 +/-0.246 0.143 +/-0.246 0.303 pCi/g Bismuth-214 0.467 +/-0.0843 0.0338 +/-0.0843 0.0712 pCi/g Cesium-134 UUI 0.00 +/-0.0421 0.0235 +/-0.0421 0.0495 pCi/g Cesium-137 0.292 +/-0.050 0.0179 +/-0.050 0.0379 pCi/g Cobalt-60 0.743 +/-0.0722 0.0177 +/-0.0722 0.0386 pCi/g Europium-152 U -0.0383 +/-0.0535 0.0426 +/-0.0535 0.0893 pCi/g Europium-154 U 0.0175 +/-0.0552 0.0481 +/-0.0552 0.105 pCi/g Europium-155 U 0.0679 +/-0.050 0.0475 +1-0.050 0.098 pCi/g Lead-212 0.744 +/-0.0622 0.0253 +/-0.0622 0.0525 pCi/g Lead-214 0.632 +/-0.0994 0.0331 +/-0.0994 0.069 pCi/g Manganese-54 U -0.00494 +/-0.0237 0.0193 +/-0.0237 0.0409 pCi/g Niobium-94 U 0.0149 +/-0.019 0.0178 +/-0.019 0.0374 pCi/g Potassium-40 10.5 +/-0.878 0.149 +/-0.878 0.332 pCi/g Radium-226 0.467 +/-0.0843 0.0338 +/-0.0843 0.0712 pCi/g Silver-108m U -0.0156 +/-0.0165 0.0137 +/-0.0165 0.0288 pCi/g Thallium-208 0.239 +/-0.0385 0.0155 +/-0.0385 0.0329 pCi/g The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 05/07/06 1536 527705 The following Analytical Methods were performed Method Description I EML HASL 300, 4.5.2.3 Notes:

The Qualifiers in this report are defined as follows:

• A quality control analyte recovery is outside of specified acceptance criteria

< Result is less than value reported

> Result is greater than value reported 30

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: June 7, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0003-004F Project: YANKO 1204 Sample ID: 162335004 Client ID: YANKOOI Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd A The TIC is a suspected aldol-condensation product BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.

31

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company : Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: June 7, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0003-004FS Project: YANK01204 Sample ID: 162335005 Client ID: YANKOO0 Matrix: Soil Vol. Recv.:

Collect Date: 25-APR-06 Receive Date: 05-MAY-06 Collector: Client Moisture: 24.4%

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Gamma Spec Analysis GammaSolid-ESS GAM & ALL FSS Actinium-228 0.904 +/-0.210 0.0771 +/-0.210 0.162 pCi/g MJHI 05/31/06 1023 528196 1 Americium-241 U -0.0871 +/-0.147 0.0818 +/-0.147 0.167 pCi/g Bismuth-212 U 0.233 +/-0.344 0.161 +/-0.344 0.336 pCi/g Bismuth-214 0.577 +/-0.095 0.033 +/-0.095 0.069 pCi/g Cesium-134 U 0.0183 +/-0.0318 0.0242 +/-0.0318 0.0505 pCi/g Cesium-137 0.314 +/-0.046 0.0197 +/-0.046 0.0412 pCi/g Cobalt-60 0.984 +/-0.103 0.019 +/-0.103 0.0409 pCi/g Europium-152 U -0.025 +/-0.0537 0.0467 +/-0.0537 0.0968 pCi/g Europium- 154 U -0.0144 +/-0.0724 0.0606 +/-0.0724 0.129 pCi/g Europium-155 U 0.0585 +/-0.0663 0.052 +/-0.0663 0.106 pCi/g Lead-212 0.872 +/-0.0947 0.0264 +/-0.0947 0.0544 pCi/g Lead-214 0.636 +/-0.102 0.0326 +/-0.102 0.0677 pCi/g Manganese-54 U -0.0163 +/-0.0262 0.0211 +/-0.0262 0.0443 pCi/g Niobium-94 U 0.0151 +/-0.0212 0.0187 +/-0.0212 0.039 pCi/g Potassium-40 12.7 +/-1.23 0.163 +/-1.23 0.356 pCi/g Radium-226 0.577 +/-0.095 0.033 +/-0.095 0.069 pCi/g Silver-108m U 0.0178 +/-0.0154 0.0166 +/-0.0154 0.0345 pCi/g Thallium-208 0.271 +/-0.0547 0.0184 +/-0.0547 0.0384 pCi/g The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 05/07/06 1536 527705 The following Analytical Methods were performed Method Description 1 EML HASL 300, 4.5.2.3 Notes:

The Qualifiers in this report are defined as follows

• A quality control analyte recovery is outside of specified acceptance criteria

< Result is less than value reported

> Result is greater than value reported 32

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: June 7, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0003-004FS Proiect: YANK01204 Sample ID: 162335005 Client ID: YANKOO Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd A The TIC is a suspected aldol-condensation product BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.

33

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analyvis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: June 7, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0003-005F Proiect: YANKO 1204 Sample ID: 162335006 Client ID: YANK001 Matrix: Soil Vol. Recv.:

Collect Date: 25-APR-06 Receive Date: 05-MAY-06 Collector: Client Moisture: 19.4%

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS Actinium-228 0.810 +/-0.183 0.0752 +/-0.183 0.159 pCi/g MJH1 05/31/06 1023 528196 1 Americium-241 U 0.0234 +/-0.036 0.0312 +/-0.036 0.0638 pCi/g Bismuth-212 0.648 +/-0.358 0.164 +/-0.358 0.344 pCi/g Bismuth-214 0.637 +/-0.112 0.0383 +/-0.112 0.080 pCi/g Cesium-134 UUI 0.00 +/-0.0379 0.0262 +/-0.0379 0.0547 pCi/g Cesium- 137 0.210 +/-0.0415 0.0214 +/-0.0415 0.0447 pCi/g Cobalt-60 0.136 +/-0.0507 0.0187 +/-0.0507 0.0404 pCi/g Europium-152 U -0.0439 +/-0.0596 0.0513 +/-0.0596 0.106 pCi/g Europium-154 U -0.0179 +/-0.0729 0.0616 +/-0.0729 0.131 pCi/g Europium-155 U 0.0147 +/-0.0557 0.051 +/-0.0557 0.105 pCi/g Lead-212 0.757 +/-0.0591 0.0304 +/-0.0591 0.0627 pCi/g Lead-214 0.714 +/-0.0897 0.038 +/-0.0897 0.0788 pCi/g Manganese-54 U 0.00687 +/-0.026 0.0227 +/-0.026 0.0476 pCi/g Niobium-94 U -0.0014 +/-0.0222 0.0194 +/-0.0222 0.0406 pCi/g Potassium-40 11.2 +/-0.854 0.194 +/-0.854 0.418 pCi/g Radium-226 0.637 +/-0.112 0.0383 +/-0.112 0.080 pCi/g Silver-108m U --0.00275 +/-0.0221 0.0191 +/-0.0221 0.0397 pCi/g Thallium-208 0.273 +/-0.0491 0.0204 +/-0.0491 0.0427 pCi/g The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 05/07/06 1536 527705 The following Analytical Methods were performed Method Description I EML HASL 300, 4.5.2.3 Notes:

The Qualifiers in this report are defined as follows

• A quality control analyte recovery is outside of specified acceptance criteria

< Result is less than value reported

> Result is greater than value reported 34

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: June 7, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0003-005F Project: YANK01204 Sample ID: 162335006 Client ID: YANK001 Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd A The TIC is a suspected aldol-condensation product BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.

35

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: June 7, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0003-006F Proiect: YANK01204 Sample ID: 162335007 Client ID: YANK001 Matrix: Soil Vol. Recv.:

Collect Date: 25-APR-06 Receive Date: 05-MAY-06 Collector: Client Moisture: 27.9%

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Gamma Spec Analysis Gamma,Solid-FSS GAAM & ALL FSS Actinium-228 0.808 +/-0.189 0.0619 +/-0.189 0.132 pCi/g MJH1 05/31/06 1112 528196 1 Americium-241 U -0.0509 +/-0.111 0.0797 +/-0.111 0.164 pCi/g Bismuth-212 0.562 +/-0.324 0.130 +/-0.324 0.276 pCi/g Bismuth-214 0.562 +/-0.106 0.0306 +/-0.106 0.0645 pCi/g Cesium-134 UUI 0.00 +/-0.0388 0.0232 +/-0.0388 0.0487 pCi/g Cesium-137 0.105 +/-0.0477 0.0187 +/-0.0477 0.0393 pCi/g Cobalt-60 U 0.0186 +/-0.0229 0.0204 +/-0.0229 0.0441 pCi/g Europium-152 U -0.0255 +/-0.0547 0.043 +/-0.0547 0.0896 pCi/g Europium-154 U 0.0125 +/-0.068 0.0575 +/-0.068 0.124 pCi/g Europium-155 U 0.0834 +/-0.0936 0.0445 +/-0.0936 0.0917 pCi/g Lead-212 0.894 +/-0.0948 0.0256 +/-0.0948 0.0529 pCi/g Lead-214 0.686 +/-0.102 0.0313 +/-0.102 0.0652 pCi/g Manganese-54 U 0.0168 +/-0.0254 0.0173 +/-0.0254 0.0367 pCi/g Niobium-94 U -0.00862 +/-0.0187 0.0149 +/-0.0187 0.0315 pCi/g Potassium-40 14.6 +/-1.33 0.110 +/-1.33 0.252 pCi/g Radium-226 0.562 +/-0.106 0.0306 +/-0.106 0.0645 pCi/g Silver-108m U 0.00453 +/-0.0169 0.0146 +/-0.0169 0.0307 pCi/g Thallium-208 0.285 +/-0.0542 0.0162 +/-0.0542 0.0342 pCi/g The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 05/07/06 1536 527705 The following Analytical Methods were performed Method Description I EML HASL 300, 4.5.2.3 Notes:

The Qualifiers in this report are defined as follows

• A quality control analyte recovery is outside of specified acceptance criteria

< Result is less than value reported

> Result is greater than value reported 36

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: June 7, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0003-006F Proiect: YANKO 1204 Sample ID: 162335007 Client ID: YANKOO I Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd A The TIC is a suspected aldol-condensation product BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier

• QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.

37

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - vww.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: June 7, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0003-007F Project: YANKO 1204 Sample ID: 162335008 Client ID: YANK001 Matrix: Soil Vol. Recv.:

Collect Date: 25-APR-06 Receive Date: 05-MAY-06 Collector: Client Moisture: 10.9%

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS Actinium-228 0.517 +/-0.112 0.0452 +/-0.112 0.0971 pCi/g MJHI 05/31/06 1149 528196 1 Americium-241 U 0.000336 +/-0.0951 0.0786 +/-0.0951 0.163 pCi/g Bismuth-212 0.382 +/-0.238 0.090 +/-0.238 0.193 pCi/g Bismuth-214 0.481 +/-0.0661 0.025 +/-0.0661 0.0528 pCi/g Cesium-134 U 0.0215 +/-0.0213 0.018 +/-0.0213 0.038 pCi/g Cesium-137 U 0.0264 +/-0.0204 0.0141 +/-0.0204 0.0298 pCi/g Cobalt-60 U 0.029 +/-0.0355 0.0161 +/-0.0355 0.0347 pCi/g Europium-152 U 0.0144 +/-0.0384 0.034 +/-0.0384 0.0712 pCi/g Europium-154 U 0.0132 +/-0.0495 0.0434 +/-0.0495 0.0938 pCi/g Europium-155 U 0.0317 +/-0.0496 0.0411 +/-0.0496 0.0848 pCi/g Lead-212 0.628 +/-0.0457 0.0187 +/-0.0457 0.039 pCi/g Lead-214 0.510 +/-0.0692 0.0242 +/-0.0692 0.0508 pCi/g Manganese-54 U -0.00489 +/-0.0168 0.0139 +/-0.0168 0.0296 pCi/g Niobium-94 U 0.00332 +/-0.0141 0.0124 +/-0.0141 0.0262 pCi/g Potassium-40 9.43 +/-0.672 0.129 +/-0.672 0.283 pCi/g Radium-226 0.481 +/-0.0661 0.025 +/-0.0661 0.0528 pCi/g Silver-108m U 0.000625 +/-0.0127 0.0115 +/-0.0127 0.0243 pCi/g Thallium-208 0.176 +/-0.0378 0.0115 +/-0.0378 0.0246 pCi/g The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 05/07/06 1536 527705 The following Analytical Methods were performed Method Description I EML HASL 300, 4.5.2.3 Notes:

The Qualifiers in this report are defined as follows:

• A quality control analyte recovery is outside of specified acceptance criteria

• Result is less than value reported

> Result is greater than value reported 38

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: June 7, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0003-007F Proiect: YANKO 1204 Sample ID: 162335008 Client ID: YANKOO Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd A The TIC is a suspected aldol-condensation product BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.

39

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.corn Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: June 7, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 91 06-0003-009F Project: YANK01204 Sample ID: 162335009 Client ID: YANKOO Matrix: Soil Vol. Recv.:

Collect Date: 25-APR-06 Receive Date: 05-MAY-06 Collector: Client Moisture: 17.9%

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Gamma Spec Analysis Gammna,Solid-FSSGAM & ALL FSS Actinium-228 0.719 +/-0.154 0.0493 +/-0.154 0.105 pCi/g MJH1 05/31/06 1150 528196 1 Americium-241 U 0.0062 +/-0.0182 0.0173 +/-0.0182 0.0355 pCi/g Bismuth-212 U 0.229 +/-0.253 0.114 +/-0.253 0.239 pCi/g Bismuth-214 0.434 +/-0.0714 0.0244 +/-0.0714 0.0515 pCi/g Cesium-134 UUI 0.00 +/-0.0227 0.0193 +/-0.0227 0.0405 pCi/g Cesium-137 0.318 +/-0.0367 0.0145 +/-0.0367 0.0305 pCi/g Cobalt-60 0.445 +/-0.0475 0.0139 +/-0.0475 0.0303 pCi/g Europium-152 U 0.013 +/-0.0375 0.0335 +/-0.0375 0.0697 pCi/g Europium-154 U 0.0143 +/-0.054 0.0469 +/-0.054 0.100 pCi/g Europium-155 U 0.0386 +/-0.0411 0.0284 +/-0.0411 0.0585 pCi/g Lead-212 0.666 +/-0.0419 0.0209 +/-0.0419 0.0431 pCi/g Lead-214 0.507 +/-0.0629 0.0244 +/-0.0629 0.0508 pCi/g Manganese-54 U -0.0112 +/-0.0181 0.0146 +/-0.0181 0.031 pCi/g Niobium-94 U -0.00588 +/-0.0152 0.0128 +/-0.0152 0.0269 pCi/g Potassium-40 10.9 +/-0.688 0.133 +/-0.688 0.291 pCi/g Radium-226 0.434 +/-0.0714 0.0244 +/-0.0714 0.0515 pCi/g Silver-108m U -0.00469 +/-0.0128 0.0115 +/-0.0128 0.0241 pCi/g Thallium-208 0.196 +/-0.0361 0.0123 +/-0.0361 0.026 pCi/g The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 05/07/06 1536 527705 The following Analytical Methods were performed Method Description I EML HASL 300, 4.5.2.3 Notes:

The Qualifiers in this report are defined as follows

• A quality control analyte recovery is outside of specified acceptance criteria

< Result is less than value reported

> Result is greater than value reported 40

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: June 7, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0003-009F Proiect: YANK01204 Sample ID: 162335009 Client ID: YANK001 Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd A The TIC is a suspected aldol-condensation product BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.

41

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company : Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: June 7, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0003-01OF Project: YANKO 1204 Sample ID: 162335010 Client ID: YANK001 Matrix: Soil Vol. Recv.:

Collect Date: 25-APR-06 Receive Date: 05-MAY-06 Collector: Client Moisture: 15.8%

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS Actinium-228 0.848 +/-0.169 0.0514 +/-0.169 0.103 pCi/g MJHl 05/31/06 1243 528196 1 Americium-241 U -0.00399 +/-0.0658 0.0526 +/-0.0658 0.105 pCi/g Bismuth-212 0.626 +/-0.223 0.110 +/-0.223 0.219 pCi/g Bismuth-214 0.658 +/-0.0977 0.0271 +/-0.0977 0.0542 pCi/g Cesium-134 UUI 0.00 +/-0.0242 0.0187 +/-0.0242 0.0374 pCi/g Cesium-137 0.204 +1-0.0415 0.0166 +/-0.0415 0.0332 pCi/g Cobalt-60 0.228 +/-0.0508 0.0151 +/-0.0508 0.0302 pCi/g Europium-152 U 0.0348 +1-0.0545 0.0416 +1-0.0545 0.0831 pCi/g Europium-154 U 0.032 +/-0.058 0.0511 +/-0.058 0.102 pCi/g Europium-155 U 0.0754 +/-0.0616 0.043 +/-0.0616 0.086 pCi/g Lead-212 0.881 +/-0.0859 0.0248 +/-0.0859 0.0497 pCi/g Lead-214 0.840 +/-0.100 0.029 +/-0.100 0.058 pCi/g Manganese-54 U -0.00224 +/-0.0189 0.0164 +/-0.0189 0.0329 pCi/g Niobium-94 U 0.00778 +/-0.0157 0.0143 +/-0.0157 0.0286 pCi/g Potassium-40 12.4 +/-1.01 0.102 +/-1.01 0.203 pCi/g Radium-226 0.658 +/-0.0977 0.0271 +/-0.0977 0.0542 pCi/g Silver-108m U 0.00435 +/-0.0158 0.0141 +/-0.0158 0.0282 pCi/g Thallium-208 0.267 +/-0.0454 0.015 +/-0.0454 0.030 pCi/g The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 05/07/06 1536 527705 The following Analytical Methods were performed Method Description I EML HASL 300, 4.5.2.3 Notes:

The Qualifiers in this report are defined as follows

• A quality control analyte recovery is outside of specified acceptance criteria

< Result is less than value reported

> Result is greater than value reported 42

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: June 7, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0003-OIOF Project: YANKO 1204 Sample ID: 162335010 Client ID: YANKOOl Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd A The TIC is a suspected aldol-condensation product BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.

43

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: June 7, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0003-010FS Project: YANKO 1204 Sample ID: 162335011 Client ID: YANKOOl Matrix: Soil Vol. Recv.:

Collect Date: 25-APR-06 Receive Date: 05-MAY-06 Collector: Client Moisture: 15.5%

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Gamma Spec Analysis GammaSolid-FSS GAM & ALL FSS Actinium-228 0.731 +/-0.148 0.0534 +/-0.148 0.113 pCi/g MJH1 05/31/06 1722 528196 1 Americium-241 U -0.0861 +/-0.0773 0.0637 +/-0.0773 0.131 pCi/g Bismuth-212 0.464 +/-0.253 0.116 +/-0.253 0.245 pCi/g Bismuth-214 0.736 +/-0.101 0.0282 +/-0.101 0.0589 pCi/g Cesium-134 UUI 0.00 +/-0.0312 0.0199 +/-0.0312 0.0416 pCi/g Cesium-137 0.169 +/-0.0358 0.0153 +/-0.0358 0.0321 pCi/g Cobalt-60 UUI 0.00 +/-0.0404 0.0303 +/-0.0404 0.063 pCi/g Europium-152 U 0.00825 +/-0.0439 0.0397 +/-0.0439 0.0823 pCi/g Europium-154 U -0.0128 +/-0.0532 0.0448 +/-0.0532 0.0961 pCi/g Europium-155 U 0.0139 +/-0.0539 0.045 +/-0.0539 0.0923 pCi/g Lead-212 0.841 +/-0.0842 0.0226 +/-0.0842 0.0467 pCi/g Lead-214 0.851 +/-0.102 0.0272 +/-0.102 0.0565 pCi/g Manganese-54 U -0.0134 +/-0.020 0.0165 +/-0.020 0.0348 pCi/g Niobium-94 U 0.0167 +/-0.0157 0.0146 +/-0.0157 0.0306 pCi/g Potassium-40 11.3 +/-0.982 0.143 +/-0.982 0.310 pCi/g Radium-226 0.736 +/-0.101 0.0282 +/-0.101 0.0589 pCi/g Silver-108m U - -0.00529 +/-0.0156 0.0134 +/-0.0156 0.028 pCi/g Thallium-208 0.266 +/-0.0396 0.0142 +/-0.0396 0.0298 pCi/g The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 05/07/06 1536 527705 The following Analytical Methods were performed Method Description I EML HASL 300, 4.5.2.3 Notes:

The Qualifiers in this report are defined as follows

• A quality control analyte recovery is outside of specified acceptance criteria

< Result is less than value reported

> Result is greater than value reported 44

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: June 7, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0003-010FS Project: YANKO 1204 Sample ID: 162335011 Client ID: YANK001 Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd A The TIC is a suspected aldol-condensation product BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.

45

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Cs~rfri~ofe tt.t ttttt.tt, af flhIUR t~t A ns1hrece V OZ~

Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: June 7, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0003-012F Proiect: YANKO 1204 Sample ID: 162335012 Client ID: YANK001 Matrix: Soil Vol. Recv.:

Collect Date: 25-APR-06 Receive Date: 05-MAY-06 Collector: Client Moisture: 10.5%

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS Actinium-228 0.944 +/-0.128 0.0471 +/-0.128 0.101 pCi/g MJH1 05/31/06 1723 528196 1 Americium-241 U -0.108 +/-0.105 0.0811 +1-0.105 0.168 pCi/g Bismuth-212 0.686 +/-0.178 0.110 +/-0.178 0.233 pCi/g Bismuth-214 0.573 +/-0.0696 0.0259 +/-0.0696 0.0546 pCi/g Cesium-134 UUI 0.00 +/-0.0249 0.0192 +/-0.0249 0.0404 pCi/g Cesium-137 0.0427 +/-0.0245 0.0126 +/-0.0245 0.0269 pCi/g Cobalt-60 U 0.0145 +/-0.0186 0.017 +/-0.0186 0.0367 pCi/g Europium-152 U -0.00296 +/-0.0424 0.0362 +/-0.0424 0.0757 pCi/g Europium-154 U -0.0379 +/-0.0639 0.0431 +/-0.0639 0.0935 pCi/g Europium-155 U 0.0158 +/-0.0486 0.0466 +/-0.0486 0.0958 pCi/g Lead-212 0.871 +/-0.0541 0.0223 +/-0.0541 0.0462 pCi/g Lead-214 0.606 +/-0.0738 0.0284 +/-0.0738 0.0592 pCi/g Manganese-54 U 0.0177 +/-0.0179 0.0163 +/-0.0179 0.0344 pCi/g Niobium-94 U-0.000997 +/-0.0157 0.0134 +/-0.0157 0.0283 pCi/g Potassium-40 10.3 +/-0.691 0.135 +/-0.691 0.298 pCi/g Radium-226 0.573 +/-0.0696 0.0259 +/-0.0696 0.0546 pCi/g Silver-108m U -0.00211 +/-0.0133 0.0119 +/-0.0133 0.0251 pCi/g Thallium-208 0.287 +/-0.036 0.0127 +/-0.036 0.027 pCi/g The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 05/07/06 1536 527705 The following Analytical Methods were performed Method Description I EML HASL 300, 4.5.2.3 Notes:

The Qualifiers in this report are defined as follows

• A quality control analyte recovery is outside of specified acceptance criteria

< Result is less than value reported

> Result is greater than value reported 46

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: June 7, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0003-012F Project: YANKO1204 Sample ID: 162335012 Client ID: YANKOO Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd A The TIC is a suspected aldol-condensation product BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier

• QC Samples were not spiked with this compound

^ RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.

47

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: June 7, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0003-013F Project: YANKO 1204 Sample ID: 162335013 Client ID: YANKOO Matrix: Soil Vol. Recv.:

Collect Date: 25-APR-06 Receive Date: 05-MAY-06 Collector: Client Moisture: 35.4%

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS Actinium-228 0.950 +/-0.267 0.0693 +/-0.267 0.150 pCi/g MJHI 05/31/06 1724 528196 1 Americium-241 U -0.0155 +/-0.124 0.0897 +/-0.124 0.185 pCi/g Bismuth-212 0.769 +/-0.384 0.196 +/-0.384 0.414 pCi/g Bismuth-214 0.689 +/-0.128 0.0464 +/-0.128 0.0975 pCi/g Cesium-134 U 0.0358 +/-0.0353 0.0295 +/-0.0353 0.0622 pCi/g Cesium-137 U 0.0196 +/-0.0262 0.023 +/-0.0262 0.0488 pCi/g.

Cobalt-60 U 0.0241 +/-0.0353 0.0265 +/-0.0353 0.0573 pCi/g Europium-152 U -0.0728 +/-0.0763 0.0585 +/-0.0763 0.122 pCi/g Europium- 154 U 0.0364 +/-0.0868 0.0759 +/-0.0868 0.164 pCi/g Europium- 155 U 0.0211 +/-0.0691 0.0597 +/-0.0691 0.123 pCi/g Lead-212 1.22 +/-0.0914 0.0359 +/-0.0914 0.0741 pCi/g Lead-214 0.763 +/-0.131 0.0439 +/-0.131 0.0915 pCi/g Manganese-54 U -0.00992 +/-0.0283 0.0226 +/-0.0283 0.0482 pCi/g Niobium-94 U 0.00629 +/-0.0335 0.0206 +/-0.0335 0.0436 pCi/g Potassium-40 19.6 +/-1.23 0.227 +/- 1.23 0.499 pCi/g Radium-226 0.689 +/-0.128 0.0464 +/-0.128 0.0975 pCi/g Silver-108m U -0.019 +/-0.0249 0.0189 +/-0.0249 0.0397 pCi/g Thallium-208 0.339 +/-0.0682 0.0232 +/-0.0682 0.0489 pCi/g The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 05/07/06 1536 527705 The following Analytical Methods were performed Method Description I EML HASL 300, 4.5.2.3 Notes:

The Qualifiers in this report are defined as follows:

• A quality control analyte recovery is outside of specified acceptance criteria

< Result is less than value reported

> Result is greater than value reported 48

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: June 7, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0003-013F Project: YANK01204 Sample ID: 162335013 Client ID: YANK001 Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd A The TIC is a suspected aldol-condensation product BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.

49

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: June 7, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0003-015F Project: YANKO 1204 Sample ID: 162335014 Client ID: YANK001 Matrix: Soil Vol. Recv.:

Collect Date: 26-APR-06 Receive Date: 05-MAY-06 Collector: Client Moisture: 19.9%

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Gamma Spec Analysis GammaSolid-FSS GAM & ALL FSS Actinium-228 0.682 +/-0.213 0.0694 +/-0.213 0.147 pCi/g MJH1 05/31/06 1724 528196 1 Americium-241 U -0.0444 +/-0.0952 0.076 +/-0.0952 0.156 pCi/g Bismuth-212 0.651 +/-0.327 0.143 +/-0.327 0.304 pCi/g Bismuth-214 0.446 +/-0.0833 0.0339 +/-0.0833 0.0714 pCi/g Cesium-134 U 0.0335 +/-0.0326 0.0241 +/-0.0326 0.0507 pCi/g Cesium-137 0.257 +/-0.0479 0.0172 +/-0.0479 0.0365 pCi/g Cobalt-60 0.805 +/-0.0828 0.0204 +/-0.0828 0.0442 pCi/g Europium-152 U -0.0503 +/-0.0545 0.0447 +/-0.0545 0.0934 pCi/g Europium-154 U 0.00444 +/-0.0697 0.0591 +/-0.0697 0.127 pCi/g Europium-155 U 0.0251 +/-0.0558 0.0498 +/-0.0558 0.102 pCi/g Lead-212 0.741 +/-0.0638 0.0269 +/-0.0638 0.0556 pCi/g Lead-214 0.638 +/-0.0878 0.0329 +/-0.0878 0.0687 pCi/g Manganese-54 U 0.00149 +/-0.0272 0.023 +/-0.0272 0.0482 pCi/g Niobium-94 U -0.00431 +/-0.0214 0.0181 +/-0.0214 0.038 pCi/g Potassium-40 11.3 +/-0.805 0.141 +/-0.805 0.315 pCi/g Radium-226 0.446 +/-0.0833 0.0339 +/-0.0833 0.0714 pCi/g Silver-108m U -0.00188 +/-0.0197 0.0165 +/-0.0197 0.0346 pCi/g Thallium-208 0.246 +/-0.0422 0.020 +/-0.0422 0.042 pCi/g The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 05/07/06 1536 527705 The following Analytical Methods were performed Method Description I EML HASL 300, 4.5.2.3 Notes:

The Qualifiers in this report are defined as follows

• A quality control analyte recovery is outside of specified acceptance criteria

< Result is less than value reported

> Result is greater than value reported 50

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: June 7, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0003-015F Project: YANKO 1204 Sample ID: 162335014 Client ID: YANKOO Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd A The TIC is a suspected aldol-condensation product BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

UIl Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.

51

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: June 7, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0003-016F Project: YANKO 1204 Sample ID: 162335015 Client ID: YANK001 Matrix: Soil Vol. Recv.:

Collect Date: 26-APR-06 Receive Date: 05-MAY-06 Collector: Client Moisture: 15.4%

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS Actinium-228 0.485 +/-0.112 0.0433 +/-0.112 0.0936 pCi/g MJH1 05/31/06 1725 528196 1 Americium-241 U 0.0196 +/-0.0623 0.0518 +/-0.0623 0.107 pCi/g Bismuth-212 0.348 +/-0.142 0.115 +/-0.142 0.243 pCi/g Bismuth-214 0.403 +/-0.0668 0.0219 +/-0.0668 0.0467 pCi/g Cesium-134 UJUI 0.00 +/-0.0237 0.0173 +/-0.0237 0.0367 pCi/g Cesium-137 U 0.000352 +/-0.0154 0.0133 +/-0.0154 0.0283 pCi/g Cobalt-60 U 0.0202 +/-0.020 0.0142 +/-0.020 0.0312 pCi/g Europium-152 U -0.0118 +/-0.0424 0.0314 +/-0.0424 0.0661 pCi/g Europium-154 U 0.0276 +/-0.060 0.0374 +/-0.060 0.0822 pCi/g Europium-t55 U 0.00266 +/-0.037 0.0351 +/-0.037 0.0726 pCi/g Lead-212 0.488 +/-0.0437 0.0199 +/-0.0437 0.0414 pCi/g Lead-214 0.390 +/-0.0686 0.0231 +/-0.0686 0.0487 pCi/g Manganese-54 U 0.00955 +1-0.015 0.0134 +/-0.015 0.0287 pCi/g Niobium-94 U 0.0164 +/-0.0146 0.0136 +/-0.0146 0.0287 pCi/g Potassium-40 8.00 +/-0.691 0.118 +/-0.691 0.264 pCi/g Radium-226 0.403 +/-0.0668 0.0219 +/-0.0668 0.0467 pCi/g Silver-108m U 0.0079 +/-0.0126 0.0109 +/-0.0126 0.023 pCi/g Thallium-208 0.170 +/-0.0404 0.0119 +/-0.0404 0.0253 pCi/g The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 05/07/06 1536 527705 The following Analytical Methods were performed Method Description I EML HASL 300, 4.5.2.3 Notes:

The Qualifiers in this report are defined as follows

• A quality control analyte recovery is outside of specified acceptance criteria

< Result is less than value reported

> Result is greater than value reported 52

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 lnjun Hollow Rd East Hampton, Connecticut 06424 Report Date: June 7, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0003-016F Proiect: YANKO 1204 Sample ID: 162335015 Client ID: YANKOO I Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd A The TIC is a suspected aldol-condensation product BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

Ul Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.

53

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: June 7, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0003-017F Proiect: YANK01204 Sample ID: 162335016 Client ID: YANKOO Matrix: Soil Vol. Recv.:

Collect Date: 26-APR-06 Receive Date: 05-MAY-06 Collector: Client Moisture: 18.5%

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS Actinium-228 1.25 +/-0.253 0.0616 +/-0.253 0.131 pCi/g MJHl 05/31/06 1726 528196 1 Americium-241 U 0.0391 +/-0.146 0.0859 +/-0.146 0.176 pCi/g.

Bismuth-212 0.847 +/-0.246 0.131 +/-0.246 0.277 pCi/g Bismuth-214 0.880 +/-0.115 0.0333 +/-0.115 0.0697 pCi/g Cesium-134 UUI 0.00 +/-0.0443 0.0252 +/-0.0443 0.0525 pCi/g Cesium-137 UUI 0.00 +/-0.0357 0.0203 +/-0.0357 0.0424 pCi/g Cobalt-60 U 0.0208 +/-0.0239 0.0217 +/-0.0239 0.0464 pCi/g Europium-152 U -0.0194 +/-0.053 0.0462 +/-0.053 0.0958 pCi/g Europium-154 U 0.00332 +/-0.0714 0.0609 +/-0.0714 0.130 pCi/g Europium-155 U 0.069 +/-0.0628 0.0529 +/-0.0628 0.108 pCi/g Lead-212 1.24 +/-0.122 0.0279 +/-0.122 0.0573 pCi/g Lead-214 1.02 +/-0.130 0.0335 +/-0.130 0.0694 pCi/g Manganese-54 U 0.00696 +/-0.0258 0.0191 +/-0.0258 0.0404 pCi/g Niobium-94 U 0.00448 +/-0.0306 0.0178 +/-0.0306 0.0372 pCi/g Potassium-40 13.2 +/- 1.27 0.163 +/-1.27 0.356 pCi/g Radium-226 0.880 +/-0.115 0.0333 +/-0.115 0.0697 pCi/g Silver-108m U -0.00197 +/-0.0175 0.0152 +/-0.0175 0.0317 pCi/g Thallium-208 0.413 +/-0.0528 0.0186 +/-0.0528 0.0389 pCi/g The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 05/07/06 1536 527705 The following Analytical Methods were performed Method Description I EML HASL 300, 4.5.2.3 Notes:

The Qualifiers in this report are defined as follows

• A quality control analyte recovery is outside of specified acceptance criteria

< Result is less than value reported

> Result is greater than value reported 54

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: June 7, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0003-017F Project: YANKO 1204 Sample ID: 162335016 Client ID: YANK001 Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd A The TIC is a suspected aldol-condensation product BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier

• QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.

55

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company : Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: June 7, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0003-018F Proiect: YANKO 1204 Sample ID: 162335017 Client ID: YANKOO0 Matrix: Soil Vol. Recv.:

Collect Date: 26-APR-06 Receive Date: 05-MAY-06 Collector: Client Moisture: 19.6%

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS Actinium-228 0.397 +/-0.164 0.0734 +/-0.164 0.154 pCi/g MJH1 05/31/06 1727 528196 1 Americium-241 U 0.000262 +/-0.0286 0.0275 +/-0.0286 0.0564 pCi/g Bismuth-212 U 0.309 +/-0.280 0.158 +/-0.280 0.330 pCi/g Bismuth-214 0.360 +/-0.081 0.0367 +/-0.081 0.0766 pCi/g Cesium-134 U 0.0232 +/-0.0253 0.0233 +/-0.0253 0.0487 pCi/g Cesium-137 0.190 +/-0.0405 0.0196 +/-0.0405 0.0411 pCi/g Cobalt-60 0.185 +/-0.0516 0.0201 +/-0.0516 0.043 pCi/g Europium-152 U -0.00454 +/-0.0526 0.047 +/-0.0526 0.0976 pCi/g Europium-154 U 0.0156 +/-0.0628 0.0554 +/-0.0628 0.118 pCi/g Europium-155 U 0.0431 +/-0.0437 0.0435 +/-0.0437 0.0893 pCi/g Lead-212 0.516 +/-0.0495 0.0279 +/-0.0495 0.0574 pCi/g Lead-214 0.420 +/-0.0794 0.035 +/-0.0794 0.0725 pCi/g Manganese-54 U6.390E-06 +/-0.0235 0.0204 +/-0.0235 0.0429 pCi/g Niobium-94 U 0.00578 +/-0.0201 0.018 +/-0.0201 0.0377 pCi/g Potassium-40 9.25 +/-0.728 0.167 +/-0.728 0.362 pCi/g Radium-226 0.360 +/-0.081 0.0367 +/-0.081 0.0766 pCi/g Silver-108m U 0.0022 +/-0.0189 0.0167 +/-0.0189 0.0348 pCi/g Thallium-208 0.133 +/-0.0506 0.0203 +/-0.0506 0.0424 pCi/g The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 05/07/06 1536 527705 The following Analytical Methods were performed Method Description 1 EML HASL 300, 4.5.2.3 Notes:

The Qualifiers in this report are defined as follows

• A quality control analyte recovery is outside of specified acceptance criteria

< Result is less than value reported

> Result is greater than value reported 56

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: June 7, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0003-018F Proiect: YANKO 1204 Sample ID: 162335017 Client ID: YANK001 Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd A The TIC is a suspected aldol-condensation product BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value isestimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.

57

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: June 7, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0003-008F Proiect: YANKO 1204 Sample ID: 162335018 Client ID: YANK001 Matrix: Soil Vol. Recv.:

Collect Date: 25-APR-06 Receive Date: 05-MAY-06 Collector: Client Moisture: 15%

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Alpha Spec Analysis Alphaspec Am241, Cm, Solid ALL FSS Americium-241 U 0.00731 +/-0.0284 0.00 +/-0.0284 0.0777 pCi/g LCWl 05/18/06 1606 530940 1 Curium-242 U 0.0241 +/-0.0639 0.0361 +/-0.064 0.158 pCi/g Curium-243/244 U 0.00 +/-0.0563 0.00 +/-0.0563 0.0778 pCi/g Alphaspec Pu, Solid-ALL FSS Plutonium-238 U --0.0741 +1-0.155 0.193 +/-0.155 0.467 pCi/g LCWI 05/18/06 1605 530942 2 Plutonium-239/240 U -( 0.00243 +/-0.133 0.143 +/-0.133 0.367 pCi/g Liquid Scint Pu241, Solid-ALL FSS Plutonium-241 54.2 +/-15.0 11.0 +/-15.9 22.6 pCi/g LCWI 06/03/06 0928 530943 3 Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS Actinium-228 0.615 +/-0.163 0.0558 +/-0.163 0.120 pCi/g MJH1 05/31/06 1727 528196 4 Americium-241 U -( 0.00706 +/-0.0254 0.0245 +/-0.0254 0.0503 pCi/g Bismuth-212 0.528 +/-0.246 0.144 +/-0.246 0.306 pCi/g Bismuth-214 0.501 +/-0.095 0.0294 +/-0.095 0.0624 pCi/g Cesium- 134 U 0.0293 +/-0.0241 0.0224 +/-0.0241 0.0473 pCi/g Cesium-137 0.246 +/-0.0396 0.0178 +/-0.0396 0.0377 pCi/g Cobalt-60 0.109 +/-0.0365 0.0172 +/-0.0365 0.0377 pCi/g Europium- 152 U ().00648 +/-0.0436 0.0405 +/-0.0436 0.0847 pCi/g Europium-154 U 0.0147 +/-0.0577 0.0508 +/-0.0577 0.110 pCi/g Europium- 155 UUI 0.00 +/-0.0588 0.0358 +/-0.0588 0.0739 pCi/g Lead-212 0.470 +/-0.047 0.0218 +/-0.047 0.0453 pCi/g Lead-214 0.460 +/-0.0751 0.0294 +/-0.0751 0.0615 pCi/g Manganese-54 U -( ).00378 +/-0.0226 0.0189 +/-0.0226 0.0402 pCi/g Niobium-94 U -( ).00262 +/-0.0191 0.0163 +/-0.0191 0.0345 pCi/g Potassium-40 9.51 +/-0.714 0.143 +/-0.714 0.319 pCi/g Radium-226 0.501 +/-0.095 0.0294 +/-0.095 0.0624 pCi/g Silver-108m U -0.012 +/-0.0156 0.0134 +/-0.0156 0.0284 pCi/g Thallium-208 0.204 +/-0.0408 0.0165 +/-0.0408 0.0349 pCi/g Rad Gas Flow Proportional Counting GFPC,Sr90, solid-ALL FSS Strontium-90 U 0.010669 +/-0.00923 0.00862 +/-0.00923 0.0179 pCi/g BXF1 06/06/062314 535512 5 Rad Liquid Scintillation Analysis LSC, Tritium Dist, Solid-HTD2,ALL FSS Tritium U 5.45 +/-6.31 5.08 +/-6.31 10.6 pCi/g NXPI 05/28/060219 531705 7 Liquid Scint C14, Solid AII, FSS 58

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: June 7, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0003-008F Proiect: YANKO 1204 Sample ID: 162335018 Client ID: YANKOO Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Liquid Scintillation Analysis Liquid Scint C14, SolidAllFSS Carbon-14 U 0.0788 +/-0.115 0.0953 +1-0.115 0.194 pCi/g ATH2 06/05/06 1937 534837 8 Liquid Scint Fe55, Solid-ALL FSS Iron-55 U -15.8 +/-16.9 13.2 +/-17.0 27.8 pCi/g AFI 06/05/06 1553 535483 10 Liquid Scint Ni63, Solid-ALL FSS Nickel-63 U 0.0786 +/-2.26 1.89 +/-2.26 3.93 pCi/g SLNI 05/30/06 1451 527978 12 Liquid Scint Tc99, Solid-ALL FSS Technetium-99 U -0.0613 +/-0.256 0.217 +/-0.256 0.445 pCi/g SXEI 05/31/06 0914 531704 13 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Ash Soil Prep Ash Soil Prep, GL-RAD-A-021B MXP2 05/08/06 0826 527706 Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 05/07/06 1536 527705 The following Analytical Methods were performed Method Description I DOE EML HASL-300, Am-05-R C Modified 2 DOE EML HASL-300, Pu-I I-RC Modified 3 DOE EML HASL-300, Pu-I I-RC Modified 4 EML HASL 300, 4.5.2.3 5 EPA 905.0 Modified 6 EPA 905.0 Modified 7 EPA 906.0 Modified 8 EPA EERF C-01 Modified 9 EPA EERF C-01 Modified 10 DOE RESL Fe-I, Modified 11 DOE RESL Fe-I, Modified 12 DOE RESL Ni-I, Modified 13 DOE EML HASL-300, Tc-02-RC Modified Surrogate/Tracer recovery Recovery% Acceptable Limits Americium-243 Alphaspec Am241, Cm, Solid ALl 106 (15%-125%)

Plutonium-242 Alphaspec Pu, Solid-ALL FSS 91 (15%-125%)

Carrier/Tracer Recovery Liquid Scint Pu241, Solid-ALL FS 94 (25%-125%)

59

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: June 7, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0003-008F Project: YANK01204 Sample ID: 162335018 Client ID: YANKOOI Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 73 (25%- 125%)

Carrier/Tracer Recovery Liquid Scint Fe55, Solid-ALL FS 91 (15%-125%)

Carrier/Tracer Recovery Liquid Scint Ni63, Solid-ALL FS 85 (25%-125%)

Carrier/Tracer Recovery Liquid Scint Tc99, Solid-ALL FS 62 15%- 125%)

Notes:

The Qualifiers in this report are defined as follows

• A quality control analyte recovery is outside of specified acceptance criteria

< Result is less than value reported

> Result is greater than value reported A The TIC is a suspected aldol-condensation product BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.

60

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Cprtifieatp of Annlvqiq Company: Connecticut Yankee Atomic Power Address : 362 lnjun Hollow Rd East Hampton, Connecticut 06424 Report Date: June 7, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0003-014F Project: YANKO 1204 Sample ID: 162335019 Client ID: YANK001 Matrix: Soil Vol. Recv.:

Collect Date: 25-APR-06 Receive Date: 05-MAY-06 Collector: Client Moisture: 16%

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Alpha Spec Analysis Alphaspec Am241, Cm, Solid ALL FSS Americium-241 U 0. 0626 +/-0.101 0.00 +/-0.102 0.115 pCi/g LCWI 05/18/06 1606 530940 1 Curium-242 U 0.047 +/-0.0921 0.00 +/-0.0924 0.127 pCi/g Curium-243/244 U 0.00 +/-0.0834 0.00 +/-0.0834 0.115 pCi/g AIphaspec Pu, Solid ALL FSS Plutonium-238 U -0. 0512 +/-0.167 0.197 +/-0.168 0.476 pCi/g LCW1 05/18/06 1605 530942 2 Plutonium-239/240 U -0. 0658 +/-0.043 0.104 +/-0.0437 0.291 pCi/g Liquid Scint Pu241, Solid-ALL FSS Plutonium-241 U 19.0 +/-13.1 10.4 +/-13.2 21.5 pCi/g LCW1 06/03/06 0959 530943 3 Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS Actinium-228 ().885 +/-0.165 0.0474 +/-0.165 0.0994 pCi/g MJHI 05/31/06 1728 528196 4 Americium-241 U 0.0 0545 +/-0.0921 0.0757 +/-0.0921 0.156 pCi/g Bismuth-212 ( ).476 +/-0.227 0.107 +/-0.227 0.223 pCi/g Bismuth-214 ( ).559 +/-0.0801 0.0249 +/-0.0801 0.0518 pCi/g Cesium-134 UUI 0.00 +/-0.0239 0.0171 +/-0.0239 0.0356 pCi/g Cesium-137 0).291 +/-0.0402 0.0132 +/-0.0402 0.0275 pCi/g Cobalt-60 01.433 +/-0.0574 0.0112 +/-0.0574 0.0242 pCi/g Europium-152 U -0. 0381 +/-0.0372 0.0325 +/-0.0372 0.0675 pCi/g Europium-154 U -0. 0112 +/-0.0452 0.037 +/-0.0452 0.0787 pCi/g Europium-155 U 01.080 +/-0.0686 0.0431 +/-0.0686 0.0885 pCi/g Lead-212 01.927 +/-0.0855 0.0203 +/-0.0855 0.042 pCi/g Lead-214 01.733 +/-0.0906 0.0247 +/-0.0906 0.0512 pCi/g Manganese-54 UU1 0.00 +/-0.0409 0.013 +/-0.0409 0.0272 pCi/g Niobium-94 U 0. 0126 +/-0.0136 0.0118 +/-0.0136 0.0246 pCi/g Potassium-40 15.3 +/-1.40 0.101 +/-1.40 0.218 pCi/g Radium-226 C1.559 +/-0.0801 0.0249 +/-0.0801 0.0518 pCi/g Silver-108m U -0.0' 0262 +/-0.013 0.0115 +/-0.013 0.024 pCi/g Thallium-208 01.333 +/-0.0443 0.0119 +/-0.0443 0.025 pCi/g Rad Gas Flow Proportional Counting GFPC,Sr90, solid-ALL FSS Strontium-90 U-0.00i 0963 +/-0.0092 0.00897 +/-0.0092 0.0187 pCi/g BXFI 06/06/06 2315 535512 5 Rad Liquid Scintillation Analysis LSC, Tritium Dist, Solid-HTD2,ALL FSS Tritium U 9.53 +/-7.00 5.52 +/-7.00 11.5 pCi/g NXPI 05/28/06 0251 531705 7 Liquid Scint C14, Solid AIlFSS 61

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.corn Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: June 7, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0003-014F Project: YANKO 1204 Sample ID: 162335019 Client ID: YANKOOI Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Liquid Scintillation Analysis Liquid Scint CJ4, SolidA, FSS Carbon-14 U 0.' +/-0.110 0.0919 +/-0.110 0.187 pCi/g ATI-12 06/05/06 2038 534837 8 Liquid Scint Fe55, Solid-ALL FSS Iron-55 U 1.69 +/-16.2 12.1 +/-16.2 25.3 pCi/g AF1 06/05/06 1610 535483 10 Liquid Scint Ni63, Solid-ALL FSS Nickel-63 U - -0.34 +/-2.43 2.05 +/-2.43 4.25 pCi/g SLNI 05/30/06 1507 527978 12 Liquid Scint Tc99, Solid-ALL FSS Technetium-99 U 0 .179 +/-0.268 0.219 +/-0.268 0.453 pCi/g SXEI 05/30/06 2109 531704 13 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Ash Soil Prep Ash Soil Prep, GL-RAD-A-021B MXP2 05/08/06 0826 527706 Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 05/07/06 1536 527705 The following Analytical Methods were performed Method Description I DOE EML HIASL-300, Am-05-RC Modified 2 DOE EML HASL-300, Pu-I 1-RC Modified 3 DOE EML HASL-300, Pu- I -RC Modified 4 EML HASL 300, 4.5.2.3 5 EPA 905.0 Modified 6 EPA 905.0 Modified 7 EPA 906.0 Modified 8 EPA EERF C-01 Modified 9 EPA EERF C-01 Modified 10 DOE RESL Fe-I, Modified 11 DOE RESL Fe-I, Modified 12 DOE RESL Ni-I, Modified 13 DOE EML HASL-300, Tc-02-RC Modified Surrogate/Tracer recovery Test Recovery% Acceptable Limits Americium-243 Alphaspec Am241, Cm, Solid ALL 66 (15%-125%)

Plutonium-242 Alphaspec Pu, Solid-ALL FSS 95 (15%-125%)

Carrier/Tracer Recovery Liquid Scint Pu241, Solid-ALL FS 101 (25%-125%)

62

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: June 7, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0003-014F Project: YANK01204 Sample ID: 162335019 Client ID: YANK001 Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 60 (25%-125%)

Carrier/Tracer Recovery Liquid Scint Fe55, Solid-ALL FS 86 (15%-125%)

Carrier/Tracer Recovery Liquid Scint Ni63, Solid-ALL FS 83 (25%-125%)

Carrier/Tracer Recovery Liquid Scint Tc99, Solid-ALL FS 69 (15%-/125%)

Notes:

The Qualifiers in this report are defined as follows:

• A quality control analyte recovery is outside of specified acceptance criteria

• Result is less than value reported

> Result is greater than value reported A The TIC is a suspected aldol-condensation product BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.

63

I, QUALITY CONTROL DATA 64

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com QC Summary Reuort Date: June 7, 2006 Client : Connecticut Yankee Atomic Power Page 1 of 9 362 Injun Hollow Rd East Hampton, Connecticut Contact: Mr. Jack McCarthy Workorder: 162335 Parmname NOM Sample Qual QC Units RPD% REC% Range Anist Date Time Rad Alpha Spec Batch 530940 QC1201095114 162335018 DUP Americium-241 U 0.00731 U 0.0412 pCi/g 140 (0%- 100%) ,CWI 05/18/06 16:06 Uncert: +/-0.0284 +/-0.144 TPU: +/-0.0284 +/-0.144 Curium-242 U 0.0241 U 0.00 pCi/g 0 (0%- 100%)

Uncert: +/-0.0639 +/-0.179 TPU: +/-0.064 +/-0.179 Curium-243/244 U 0.00 U -0.0198 pCi/g 200 (0%- 100%)

Uncert: +/-0.0563 +/-0.0389 TPU: +/-0.0563 +/-0.039 QC1201095116 LCS Americium-241 12.7 11.5 pCi/g 91 (75%-125%)

Uncert: +/-1.12 TPU: +/-1.97 Curium-242 U 0.00 pCi/g Uncert: +/-0.0559 TPU: +/-0.0559 Curium-243/244 15.5 13.4 pCi/g 85 (75%-125%)

Uncert: +/-1.21 TPU: +/-2.24 QC1201095113 MB Americium-241 U -0.0214 pCi/g Uncert: +/-0.0615 TPU: +/-0.0617 Curium-242 U -0.00758 pCi/g Uncert: +/-0.0149 TPU: +/-0.0149 Curium-243/244 U -0.00753 pCi/g Uncert: +/-0.0148 TPU: +/-0.0148 QC1201095115 162335018 MS Americium-241 13.3 U 0.00731 11.9 pCi/g 90 (75%-125%)

Uncert: +/-0.0284 +/-1.21 TPU: +/-0.0284 +/-2.09 Curium-242 U 0.0241 U 0.00 pCi/g Uncert: +/-0.0639 +/-0.0689 TPU: +/-0.064 +/-0.0689 Curium-243/244 16.3 U 0.00 15.5 pCi/g 95 (75%-125%)

Uncert: +/-0.0563 +/-1.38 TPU: +/-0.0563 +/-2.61 Batch 530942 QC1201095122 162335018 DUP Plutonium-238 U -0.0741 U -0.0202 pCi/g 114 (0%- 100%) -CWI 05/18/06 16:14 65

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.corn QC Summary Workorder: 162335 Page 2 of 9 Parmname NOM Sample Qual QC Units RPD% REC% Range Anist Date Time Rad Alpha Spec Batch 530942 Uncert: +/-0.155 +/-0.0595 TPU: +/-0.155 +/-0.0595 Plutonium-239/240 U -0.00243 U 0.0157 pCi/g 273 (0%- 100%)

Uncert: +/-0.133 +/-0.0841 TPU: +/-0.133 +/-0.0842 QC1201095124 LCS Plutonium-238 0.128 pCilg (75%-125%)

Uncert: +/-0.125 TPU: +/-0.126 Plutonium-239/240 11.7 11.8 pCi/g 101 (75%-125%)

Uncert: +/-1.21 TPU: +/-1.72 QC1201095121 MB Plutonium-238 U -0.0523 pCi/g 05/18/06 16:05 Uncert: +/-0.0953 TPU: +/-0.0955 Plutonium-239/240 U -0.0933 pCi/g Uncert: +/-0.101 TPU: +/-0.101 QC1201095123 162335018 MS Plutonium-238 u -0.0741 U 0.070 pCi/g (75%- 125%) 05/18/06 16:14 Uncert: +/-0.155 +/-0.0961 TPU: +/-0.155 +/-0.0964 Plutonium-239/240 12.3 U -0.00243 10.5 pCi/g 85 (75%-125%)

Uncert: +/-0.133 +/-1.06 TPU: +/-0.133 +/-1.49 Batch 530943 QC1201095126 162335018 DUP Plutonium-241 54.2 36.3 pCi/g 40 (0% - 100%) LCW I 06/03/06 11:01 Uncert: +/-15.0 +1-15.1 TPU: +/-15.9 +/-15.6 QC1201095128 LCS Plutonium-241 330 303 pCi/g 92 (75%-125%) 06/03/06 12:04 Uncert: +/-22.1 TPU: +/-37.4 QC1201095125 MB Plutonium-241 U 14.0 pCi/g 06/03/06 10:30 Uncert: +/-13.6 TPU: +/-13.6 QC1201095127 162335018 MS Plutonium-241 331 54.2 320 pCi/g 80 (75%-125%) 06/03/06 11:32 Uncert: +1-15.0 +/-23.3 TPU: +/-15.9 +/-40.0 Rad Gamma Spec Batch 528196 QC1201088600 162335001 DUP Actinium-228 0.640 0.681 pCi/g 6 (0%-100%) MJHI 05/31/06 17:31 Uncert: +/-0.149 +/-0.118

+/-0.118 66

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com QC Summary Workorder: 162335 Page 3 of 9 Parmname NOM Sample Qual QC Units RPD% REC% Range Anist Date Time Rad Gamma Spec Batch 528196 TPU: +/-0.149 Americium-241 U 0.00555 U -0.00939 pCi/g 779 (0% - 100%)

Uncert: +/-0.0707 +/-0.0817 TPU: +/-0.0707 +/-0.0817 Bismuth-212 0.351 0.356 pCi/g I (0%- 100%)

Uncert: +/-0.281 +/-0.181 TPU: +/-0.281 +/-0.181 Bismuth-214 0.462 0.418 pCi/g 10 (0%- 100%)

Uncert: +/-0.0847 +/-0.066 TPU: +/-0.0847 +/-0.066 Cesium- 134 U 0.00674 U 0.00496 pCi/g 30 (0%- 100%)

Uncert: +/-0.0184 +/-0.0191 TPU: +/-0.0184 +/-0.0191 Cesium-137 0.128 0.131 pCi/g 3 (0%- 100%)

Uncert: +/-0.0361 +/-0.0298 TPU: +/-0.0361 +/-0.0298 Cobalt-60 0.107 0.108 pCi/g I (0%- 100%)

Uncert: +/-0.0311 +/-0.0327 TPU: +/-0.0311 +/-0.0327 Europium- 152 U 0.00641 U -0.00259 pCi/g 471 (0%- 100%)

Uncert: +/-0.043 +/-0.0383 TPU: +/-0.043 +/-0.0383 Europium- 154 U -0.015 U 0.00694 pCi/g 544 (0%- 100%)

Uncert: +/-0.0505 +/-0.0476 TPU: +/-0.0505 +/-0.0476 Europium- 155 U 0.0713 U 0.033 pCi/g 74 (0%- 100%)

Uncert: +/-0.0618 +/-0.0524 TPU: +/-0.0618 +/-0.0524 Lead-212 0.670 0.640 pCi/g 5 (0%- 20%)

Uncert: +/-0.0714 +/-0.048 TPU: +/-0.0714 +/-0.048 Lead-214 0.562 0.561 pCi/g 0 (0% - 20%)

Uncert: +/-0.0771 +/-0.0698 TPU: +/-0.0771 +/-0.0698 Manganese-54 U -0.0119 U 0.00582 pCi/g 584 (0% - 100%)

Uncert: +/-0.0207 +/-0.0176 TPU: +/-0.0207 +/-0.0176 Niobium-94 U 0.0123 U 0.00253 pCi/g 132 (0%- 100%)

Uncert: +/-0.0151 +/-0.0135 TPU: +/-0.0151 +/-0.0135 Potassium-40 10.9 10.5 pCi/g 4 (0%- 20%)

Uncert: +/-0.996 +/-0.705 TPU: +/-0.996 +/-0.705 Radium-226 0.462 0.418 pCi/g 10 (0%- 100%)

Uncert: +/-0.0847 +/-0.066 TPU: +/-0.0847 +/-0.066 Silver-I 08m U 0.0049 U -0.001 pCi/g 303 (0%- 100%)

Uncert: +/-0.0138 +/-0.0125 67

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com QC Summary Workorder: 162335 Page 4 of 9 Parmname NOM Sample Qual QC Units RPD% REC% Range Anist Date Time Rad Gamma Spec Batch 528196 TPU: +/-0.0138 +/-0.0125 Thallium-208 0.229 0.214 pCi/g 7 (0%- 100%)

Uncert: +/-0.0399 +/-0.0444 TPU: +/-0.0399 +/-0.0444 QC1201088601 LCS Actinium-228 U 0.109 pCi/g 05/31/06 17:32 Uncert: +/-0.571 TPU: +/-0.571 Americium-241 23.4 21.1 pCi/g 90 (75%-125%)

Uncert: +/-2.42 TPU: +/-2.42 Bismuth-212 U -0.0642 pCi/g Uncert: +/-1.13 TPU: +/-1.13 Bismuth-214 U 0.196 pCi/g Uncert: +/-0.247 TPU: +/-0.247 Cesium- 134 U -0.013 pCi/g Uncert: +/-0.147 TPU: +/-0.147 Cesium- 137 9.65 10.2 pCi/g 105 (75%-125%)

Uncert: +/-0.895 TPU: +/-0.895 Cobalt-60 15.1 15.8 pCi/g 104 (75%-125%)

Uncert: +/-1.18 TPU: +/-1.18 Europium- 152 U -0.084 pCi/g Uncert: +/-0.302 TPU: +/-0.302 Europium- 154 U 0.416 pCi/g Uncert: +/-0.330 TPU: +/-0.330 Europium- 155 U -0.213 pCi/g Uncert: +/-0.356 TPU: +/-0.356 Lead-212 U 0.105 pCi/g Uncert: +/-0.180 TPU: +/-0.180 Lead-214 U 0.00264 pCi/g Uncert: +/-0.222 TPU: +/-0.222 Manganese-54 U -0.0501 pCi/g Uncert: +/-0.138 TPU: +/-0.138 Niobium-94 U 0.0389 pCi/g Uncert: +/-0.131 TPU: +/-0.131 Potassium-40 U 1.82 pCi/g 68

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.corn QC Summary Workorder: 162335 Page 5 of 9 Parmname NOM Sample Qual QC Units RPD% REC% Range AnIst Date Time Rad Gamma Spec Batch 528196 Uncert: +/-1.28 TPU: +/-1.28 Radium-226 U 0.196 pCi/g (75%-125%)

Uncert: +/-0.247 TPU: +/-0.247 Silver- 108m U -0.0876 pCi/g Uncert: +/-0.113 TPU: +/-0.113 Thallium-208 U 0.0613 pCi/g Uncer: +/-0.173 TPU: +/-0.173 QC1201088599 MB Actinium-228 U 0.0748 pCi/g 06/02/06 09:20 Uncert: +/-0.0533 TPU: +/-0.0533 Americium-241 U -0.0415 pCi/g Uncert: +/-0.0619 TPU: +/-0.0619 Bismuth-212 U 0.0557 pCi/g Uncert: +/-0.0788 TPU: +/-0.0788 Bismuth-214 UUI 0.00 pCi/g Uncert: +/-0.0342 TPU: +/-0.0342 Cesium- 134 U 0.00114 pCi/g Uncert: +/-0.00936 TPU: +/-0.00936 Cesium-137 U 0.00771 pCi/g Uncert: +/-0.0187 TPU: +/-0.0187 Cobalt-60 U 0.0159 pCi/g Uncert: +/-0.0128 TPU: +/-0.0128 Europium- 152 U 0.00686 pCi/g Uncert: +/-0.0288 TPU: +/-0.0288 Europium- 154 U -0.0183 pCi/g Uncert: +/-0.0274 TPU: +/-0.0274 Europium- 155 U -0.00693 pCi/g Uncert: +/-0.0229 TPU: +/-0.0229 Lead-212 U 0.00357 pCi/g Uncert: +/-0.0163 TPU: +/-0.0163 Lead-214 U 0.00987 pCi/g Uncert: +/-0.0198 TPU: +/-0.0198 69

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.corn QC Summary Workorder: 162335 Page 6 of 9 Parmname NOM Sample Qual QC Units RPD% REC% Range Anist Date Time Rad Gamma Spec Batch 528196 Manganese-54 U 0.00383 pCi/g Uncert: +/-0.00944 TPU: +/-0.00944 Niobium-94 U -0.00371 pCi/g Uncert: +/-0.00901 TPU: +/-0.00901 Potassium-40 U 0.0777 pCilg Uncert: +/-0.178 TPU: +/-0.178 Radium-226 UUI 0.00 pCilg Uncert: +/-0.0342 TPU: +/-0.0342 Silver-108m U 0.000939 pCilg Uncert: +/-0.00928 TPU: +/-0.00928 Thallium-208 U 0.0147 pCilg Uncert: +/-0.0161 TPU: +/-0.0161 Rad Gas Flow Batch 535512 QC1201105910 162335018 DUP Strontium-90 U 0.00669 U 0.012 pCi/g 0 (0% - 100%) BXFI 06/06/06 23:16 Uncert: +/-0.00923 +/-0.00902 TPU: +/-0.00923 +/-0.00902 QC1201105912 LCS Strontium-90 1.43 1.19 pCi/g 83 (75%-125%) 06/07/06 10:08 Uncert: +/-0.081 TPU:. +/-0.0854 QC1201105909 MB Strontium-90 U 0.0107 pCi/g 06/06/06 23:16 Uncert: +/-0.00663 TPU: +/-0.00664 QC1201105911 162335018 MS Strontium-90 1.54 U 0.00669 1.54 pCi/g 100 (75%-125%) 06/07/06 10:08 Uncert: +/-0.00923 +/-0.107 TPU: +/-0.00923 +/-0.115 Rad Liquid Scintillation Batch 527978 QCI201088148 162335018 DUP Nickel-63 U 0.0786 U -2.09 pCi/g (0% - 100%) SLNI 05/30/06 15:39 Uncert: +/-2.26 +/-2.31 TPU: +/-2.26 +/-2.31 QC1201088150 LCS Nickel-63 129 119 pCi/g 92 (75%-125%) 05/30/06 16:12 Uncert: +/-5.38 TPU: +/-6.06 QC1201088147 MB Nickel-63 U -1.23 pCi/g 05/30/06 15:23 70

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com QC Summary Workorder: 162335 Page 7 of 9 Parmname NOM Sample Qual QC Units RPD% REC% Range Anist Date Time Rad Liquid Scintillation Batch 527978 Uncert: +/-2.03 TPU: +/-2.03 QC1201088149 162335018 MS Nickel-63 134 U 0.0786 122 pCi/g 91 (75%-125%) 05/30/06 15:55 Uncert: +/-2.26 +/-5.70 TPU: +/-2.26 +/-6.37 Batch 531704 QC1201096868 162583001 DUP Technetium-99 U 0.161 U 0.239 pCi/g .0 (0% - 100%) SXEI 05/31/06 00:27 Uncert: +/-0.254 +/-0.273 TPU: +/-0.255 +/-0.273 QC1201096870 LCS Technetium-99 12.5 11.1 pCi/g 89 (75%-125%) 05/31/06 01:00 Uncert: +/-0.474 TPU: +/-0.545 QC1201096867 MB Technetium-99 U 0.163 pCi/g 05/31/06 00:11 Uncert: +/-0.214 TPU: +/-0.214 QC1201096869 162583001 MS Technetium-99 13.1 U 0.161 11.6 pCi/g 89 (75%-125%) 05/31/06 00:44 Uncert: +/-0.254 +/-0.583 TPU: +/-0.255 +/-0.649 Batch 531705 QC1201096878 162583001 DUP Tritium U 1.17 U 6.01 pCi/g 0 (0% - 100%) NXP I 05/28/06 09:10 Uncert: +/-4.09 +/-4.70 TPU: +/-4.09 +/-4.70 QC1201096880 LCS Tritium 41.4 44.8 pCi/g 108 (75%-125%) 05/28/06 10:14 Uncert: +/-5.68 TPU: +/-5.73 QC1201096877 MB Tritium U 0.0641 pCi/g 06/03/06 05:11 Uncert: +/-0.533 TPU: +/-0.533 QC1201096879 162583001 MS Tritium 45.7 U 1.17 52.3 pCi/g 114 (75%-125%) 05/28/06 09:42 Uncert: +/-4.09 +/-6.44 TPU: +/-4.09 +/-6.50 Batch 534837 QC1201104385 162335019 DUP Carbon- 14 U 0.0228 U 0.0418 pCi/g (0%- 100%) ATH2 06/05/06 22:40 Uncert: +/-0.110 +/-0.121 TPU: +/-0.110 +/-0.121 QC1201104387 LCS Carbon- 14 6.66 6.52 pCi/g 98 (75%-125%) 06/04/06 08:22 Uncert: +/-0.238 TPU: +/-0.259 71

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com QC Summary Workorder: 162335 Page 8 of 9 Parmname NOM Sample Qual QC Units RPD% REC% Range AnIst Date Time Rad Liquid Scintillation Batch 534837 QC1201104384 MB Carbon- 14 U 0.0371 pCi/g 06/04/06 06:04 Uncert: +/-0.125 TPU: +/-0.125 QC1201104386 162335019 MS Carbon- 14 7.13 U 0.0228 7.04 pCi/g 99 (75%-125%) 06/04/06 07:36 Uncert: +/-0.110 +/-0.249 TPU: +/-0.110 +/-0.272 Batch 535483 QC1201105873 162335018 DUP Iron-55 U -15.8 U 0.079 pCi/g 0 (0%- 100%) AFI 06/05/06 17:00 Uncert: +/-16.9 +/-20.4 TPU: +/-17.0 +/-20.4 QC1201105875 LCS Iron-55 485 492 pCi/g 101 (75%-125%) 06/05/06 17:33 Uncert: +/-39.7 TPU: +/-61.9 QC1201105872 MB Iron-55 U 5.04 pCi/g 06/05/06 16:43 Uncert: +/-22.8 TPU: +/-22.8 QC1201105874 162335018 MS Iron-55 655 U -15.8 628 pCi/g 96 (75%-125%) 06/05/06 17:16 Uncert: +/-16.9 +/-39.8 TPU: +/-17.0 +/-71.2 Notes:

The Qualifiers in this report are defined as follows:

A quality control analyte recovery is outside of specified acceptance criteria Result is less than value reported Result is greater than value reported A The TIC is a suspected aldol-condensation product BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A

RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL Preparation or preservation holding time was exceeded 72

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com QC Summary Workorder: 162335 Page 9 of 9 Parmname NOM Sample Qual QC Units RPD% REC% Range Anist Date Time h

N/A indicates that spike recovery limits do not apply when sample concentration exceeds spike conc. by a factor of 4 or more.

• • Indicates analyte is a surrogate compound.

^ The Relative Percent Difference (RPD) obtained from the sample duplicate (DUP) is evaluated against the acceptence criteria when the sample is greater than five times (5X) the contract required detection limit (RL). In cases where either the sample or duplicate value is less than 5X the RL, a control limit of +/- the RL is used to evaluate the DUP result.

For PS, PSD, and SDILT results, the values listed are the measured amounts, not final concentrations.

Where the analytical method has been performed under NELAP certification, the analysis has met all of the requirements of the NELAC standard unless qualified on the QC Summary.

73

General Narrative Page 1 of 105

CASE NARRATIVE For CONNECTICUT YANKEE RE: Soil PO# 002332 Work Order: 168404 SDG: MSR #06-0652, 06-0675, 06-0687, 06-0688, 06-0707, 06-0743, 06-0755 August 15, 2006 Laboratory Identification:

General Engineering Laboratories, LLC Mailing Address:

P.O. Box 30712 Charleston, South Carolina 29417 Express Mail Delivery and Shipping Address:

2040 Savage Road Charleston, South Carolina 29407 Telephone Number:

(843) 556-8171 Summary:

Sample receipt The sample(s) for this Project arrived at General Engineering Laboratories, LLC, (GEL) in Charleston, South Carolina on May 5, May 9, May 12, May 17, May 26, June 2, June 8, 2006. All sample containers arrived without any visible signs of tampering or breakage. The chain of custody contained the proper documentation and signatures.

The laboratory received the following sample(s):

Sample ID Client Sample ID 168404001 9106-0002-007F 168404002 9106-0002-01 IF 168404003 9106-0003-004F 168404004 9106-0003-015F 168404005 9106-0004-005F 168404006 9106-0004-015F 168404007 9106-0005-01 OF 168404008 9106-0005-014F 168404009 9106-0006-005F GENERAL ENGINEERING LABORATORIES, LLC a Member of THE GEL GROUP,INC.

P.O. Box 30712

• Charleston, SC 29417

• 2040 Savage Road (29407)

Page 2 of 105 Phone (843) 556-8171

• Fax (843) 766-1178

• www.gel.com

168404010 9106-0008-006F 168404011 9106-0008-008F 168404012 9106-0009-002F 168404013 9106-0009-017F 168404014 9106-0010-001F 168404015 9106-0010-012F Items of Note:

At the request of Dale Randall on July 20, 2006, GEL analyzed the above samples according to the spreadsheet in the attached email.

Case Narrative:

Sample analyses were conducted using methodology as outlined in General Engineering Laboratories (GEL) Standard Operating Procedures. Any technical or administrative problems during analysis, data review, and reduction are listed below by analytical parameter.

Analytical Request:

Seven soil samples were reanalyzed for FSSALL, except gamma and Sr-90.

Four soil samples were reanalyzed for FSSALL, except gamma and Ni-63.

Two soil samples were reanalyzed for FSSALL, except gamma.

Two soil samples were reanalyzed for FSALL, except gamma, Sr-90 and Ni-63.

Internal Chain of Custody:

Custody was maintained for the sample(s).

Data Package:

The enclosed data package contains the following sections: Case Narrative, Chain of Custody and Supporting Documentation and all analytical fractions.

I certify that this data package is in compliance with the SOW, both technically and for completeness, for other than the conditions detailed above. Release of the data contained in this hard copy data package has been authorized by the Laboratory Manager or a designee, as verified by the following signature.

Cheryl Jones Project Manager GENERAL ENGINEERING LABORATORIES, LLC a Member of THE GEL GROUP,INC.

P.O. Box 30712

• Charleston, SC 29417 - 2040 Savage Road (29407)

Phone (843) 556-8171

• Fax (843) 766-1178

• www.gel.com Page 3 of 105

Additional HTD analyses

Subject:

Additional HTD analyses 16 8, LI o (4, (

From: "Dale Randall" <randall @cyapco.com>

Date: Thu, 20 Jul 2006 11:04:54 -0400 To: "Cheryl Jones" <cj@gel.com>

CC: "Clyde Newson" <Newson@CYAPCO.com>, "John McCarthy" <McCarthy@ CYAPCO .com>

Cheryl:

Per our earlier discussion, attached is a list of samples that we would like to have analyzed to the FSSALL protocol. I have included a list of test protocols performed on each sample to date. Once you have had an opportunity to determine our options for each sample please call or e-mail me at your convenience.

Thank You, Dale (860) 267-3133 Content-Description: GEL FSSALL analyses request.xls GEL FSSALL analyses request.xls! Content-Type: application/vnd.ms-excel Content-Encoding: base64 I oflI Page 4 of 105 812/2006 7:04 PM

.1l,

'C x x x x x x x x

xx x xx x x x X x X x X X "x x x CXIX xXIXx x x x "x xxx x Xxlx x xI Cx x Xx x x 'Cxx xI

'x xx x X1 x'C X x xx x x x x x x x x x'x x x x x x X XC x . ..

E x x x x' x 'C x x x x x 'C x x x x x x z

0 0

0)

LLu-LLLLLLLLLLLLLLLLLLLLLLLLL 00 U- C9 99 9 9 9 o~~~~tU)) 0 C)- C) '0 C)n \

a~ - CsJ

-0 0. .- 0-o- 0000 ) 0-M000000000000000

.2 cli C\j m mCl) c~l LOLL COC qC)C) 0 0) 0u 00000 N 000000 , c mC o 2.)c C) O ot c) ' -1 ragec 0o IUD

Chain of Custody and Supporting Documentation Page 6 of 105

16 5 CIO (ý Health Physics Procedure GPP-GGGR-R5 104-003 -Attachment B-CY-001 Major CD Connecticut Yankee Atomic Power Company Chain of Custody Form No. 2006-00371 362 Injun Hollow Road, East Hampton, CT 06424 Project Name: Haddam Neck Decommissioning Analyses Requested Lab Use Only Contact Name & Phone: Comments:

Jack McCarthy 860-267-2556 Ext. 3024 Analytical Lab (Name, City, State)

General Engineering Laboratories 2040 Savage Road. Charleston SC. 29407 Cn3 r. OA 843 556 8171. Attn. Cheryl Jones r 4 Priority: 9 30 D. [114 D. [17 D. Container Sample Size- ,..

Media Type &Type "

Sample Designation Date Time Code Code Code Comment, Preservation Lab Sample ID 9106-0002-OO1F 5/17/06 10:42 SE C BP X X Transferred from COC 2006-00357 9106-0002-002F 5/18/06 09:43 SE C BP x Transferred from COC 2006-00361 9106-0002-003F 5/18/06 10:14 SE C BP X X Transferred from COC 2006-00361 9106-0002-004F 5/18/06 10:39 SE C BP X X Transferred from COC 2006-00361 9106-0002-005F 5/18/06 12:49 SE C BP X X Transferred from COC 2006-00364 9106-0002-006F 5/18/06 13:14 SE C BP X x -.-.- Transferred from COC 2006-00364 9106-0002-006FS 5/18/06 13:14 SE C BP x X Transferred from COC 2006-00364 9106-0002-007F 5/18/06 13:37 SE C BP x X Transferred from COC 2006-00364 9106-0002-008F 5/18/06 14:04 SE C BP x X Transferred from COC 2006-00364 NOTES: PO #: 002332 MSR #: 06- SSWP# NA Z LTP QA F1 Radwaste QA [ Non QA Samples Shipped Via: Internal 0[5 Fed Ex Container

' UPS Temp.:

Deg. C E0 Hand Custody Sealed?

I Date/Time 2) ivd By Date/Time Custody Seal eJ 3. M- C\ ) C. Other Intact?

elinquished B.. Date/Time 4) Received By Date/Time BillofLaing___710YD NO

5) Relinquished By -Date/Time" Bill of Lading #

7q0'? '7///YS6

6) Received By "Date/Time 5,7/ &)

Health Physics Procedure GPP-GGGR-R5 104-003-Attachment B-CY-00 1 Major Connecticut Yankee Atomic Power Company Chain of Custody Form No. 2006-00372 0*

362 Injun Hollow Road, East Hampton, CT 06424 860-267-2556

-Project Name: Haddam Neck Decommissioning Analyses Requested Lab Use Only Contact Name & Phone: Comments:

Jack McCarthy 860-267-2556 Ext. 3024 Analytical Lab (Name, City, State)

General Engineering Laboratories 2040 Savage Road. Charleston SC. 29407 843 556 8171. Attn. Cheryl Jones rA 4 Priority: Z 30D. El 14 D. [U17 D. Container Sample Size-Media Type &Type C-Sample Designation Date Time Code Code Code -r-n-e-e- Comment, Preservation Lab Sample I2 9106-0002-009F 5/18/06 14:28 SE C BP x Transfeed from COC 2006-00364 9106-0002-01OF 5/18/06 14:50 SE C BP x x Transferred from COC 2006-00364 9106-0002-01 IF 5/19/06 08:10 SE C BP X x Transferred from COC 2006-00365 9106-0002-012F 5/19/06 08:31 SE C BP x x Transferred from COC 2006-00365 9106-0002-013F 5/19/06 09:00 SE C BP x x Transferred from COC 2006-00365 9106-0002-014F 5/19/06 09:58 SE C BP X x Transferred from'COC 2006-00365 9106-0002-014FS 5/19/06 09:58 SE C BP X Transferred from COC 2006-00365 9106-0002-015F 5/19/06 10:29 SE C BP x x Transferred from COC 2006-00365 9106-0002-016F 5/19/06 13:19 SE C BP x X Transferred from COC 2006-00365 NOTES: PO #: 002332 MSR #: 06- SSWP# NA [D LTP QA [] Radwaste QA ED Non QA Samples Shipped Via: Internal

,E Fed Ex Container UPS Temp.:

Deg. C

[ Hand Custody 1 'Relinm'she* Sealed?

j Date/Time 2) Re ived By Datime Custody Seal 2 ~ved- _ _Inat___ E] Other Intact?

3)*'elinqu ished BY

• Date/Time - 4) Received By Date/Time Bill...Lading# Y N

5) Relinquished By Date/Time 6) Received By Bill of Lading #

7909 Date/Time //46"j *5t*

Connecticut Yankee Statement of Work for Analytical Lab Services .CY-ISC-SOW-OO1 Figure 1. Sample Check-in List Date/Time Received 90 SDG#:

Work Order Number: Co, Lt.{-C'".

Shipping Ccntainer ID') O  %" t

[5.5 4'1 /0 Chain of Custody# f0 (0 C" 9/

1. Custody Seals ori shipping container intact?.- Yes No [ ]

2. Custody Seals dated and signed? Yes No[J.

3. Chain-of-Custody record present? Yes []No' A4. Cooler temperature

5. Vermiculite/packing materials is:. Wet [ Dry 1lO t "

tC~iA

6. -Numberof samples in shipping container: ,. _ _ _ "_' _"

7.= .

. exc'eeded?

Sample holding _times_. 'Yes [1No*.

8. Samples have.

tape *_azard labels K. scustody seals - appropriate sample labels

9. Samples arei

)(--in good condition Jeaking

.broken ---- have air bubbles

10. Were any anomalies identified in sample receipt? yes. No)(

• .I 1 Description of anomalies, (include sample numbers):

Sample.Custodian/Laboratory: Date.. "0(4o Telephoned to: . .On By Page 9 ofO.105

Connecticut Yankee " " CYISCS Statement of Work for Analytical Lab Services C. . CY-ISC-SOW-OOl Figure 1. Sample Check-in List, DatefTimne Received -',- &4.9 SDG#: L-(

Work Order Number: l f' Shipping C4:htainer ID.p L i~ T Cano Cutdy #QD I. Custody Seals. or; shipping container intact? -Yes. No []

2. Custody Seals dated and signed? Yes No [No

3. Chain-of-Custody record preent? Yes ~~No[

4. Cooler temperaturc .

5. Vermiculite/packing materials is: 'Wet [ I Dry

~,Lue+

6.: Number of samples in shipping container _

7. Sample holding times exceeded? Yes [ No

8. Sam have:

__ape,hazard labels custody seals .appropriate sample labels

9. Samples are-

_)L in good condition leaking broken -have air bubbles

10. Were any anomalies identified in sample receipt? Yes [1 No

11. *Descriptionof anomalies (include sample numbers):

Sample Custodian/Laboratory: ,i" ;1p .4, .Date" Telephoned to: On By.

Page 10 of 105

SAMPLE RECEIPT & REVIEW FORM JTORIO"PM use only tn7Tk t -

Order:

ISDG/ARCOC/Work CliCt prior to signing);

JM(A) Review(esre non(confoflitig items ar resolyed Date Received:

Received By:

Sample Receipt Criteria CommentslQualifiers (Required for Non-Conforming Items) container o.her (dcribe)

Circle Applicable: seals broken damaged container Shipping containers received intact 7.

1 and sealed?

ice bass blue ice / dry ice none other describe)

Circle Coolant #

Samples requiring cold 2 preservation within (4 +1- 2 C)?

Record preservation method.

Chain of custody documents .

included with shipment?

Circe'^pplcab .: sbroken damaged container itakingeontainnr o (de*jb,)

Sample containers intact and 4 sealed? , _ _ _ ..._. ... .. ...

kSa If Mls. containers affected and observed p"-

5 Samples requiring chemical preservation at proper pH? ........ __.___

VOA vials free of beadspace Sample ID's and containers affected:

6 (defined as < 6mm bubble)?7.___.

Are Encore containers present?

7 (If yes, immediately deliver to

!VOAlaborator) ____ "--_-d- _ _____ _

8 Samples received wi holding Id's and tests affected time?

9 Sample ID's COC match ID's Sample ID's and containers affectedt:

on bottles?___

0Date &me on COC match date Sample ID's affected:

& tirP6 on bottles?

i Nutber of containers received Sample ID's affcted:

match number indicated on COC?

COC form is properly signed in 12 relinguished/reccived sections? ___ 0__&______2_004_e on____ _.

&

14 Air Bill ,Tracking #'s, Additional Comments

. , > RSO RAD Receipt #

Suspected Hazard Information  !*fS> x2 area background is observed on samples identified as "non-ud ' regulatedlnon-radioactive', contact the Radiation Safety group for further

[

___ __ *___ investigation.

rRadiological Classification? Maxiimum Counts Observed* (P47 B CB Regulateid? Cl Omments:

Sipdas DpI' Hazardous C If yes, contact Waste

.eral? Hazard Class Shipped:

= UN#:

Manager or ESH Manager.

-PM (or PMA) review of Hazard class~ftkation- ntal:Z Page II of 105

. lG/4 SAMPLE RECEIPT & REVIEW F ORM

4rOgl PM use only I ,t

,- ,, ' - ' (,J _ .. ,.-,-, ,,.,n-,.-. I(.. 4'ZZO I

Date Received:: (, -:;4 Ofo PM(A) Reflvi

-ateR Review re on-conor r are resolvedl prior to signing):

Received By: -

Sample Receipt Criteria Comments/Qualifie rs equired for Non-Conforming Items)

Circle Applicable: seals broke damaged container leaking container other (describe)

Shipping containers received intact and sealed? ... .. . ._._._._,_ _ _ _ __.

Circ Coolant # blue ice dry ice none other describe)

Samples requiring cold 7Yiags 2 preservation within (4 +/- 2 C)? /

Record preservation method.

Chain of custody documents included with shipment?

Sample containers intact and pplicable: seals broken damaged container leaking container other (describe) sealed?

Samples requiring chemical, 7.

ample IU's. containers affected and observed pH:

preservation at proper pH? I... .

VOA vials free of headspace Sample ID's and containes affected:

(defined as < 6mm bubble)?

Are Encore containers present?

7 (If yes, immediately deliver to VO A laboratory) .... _ __..... ... . ... ...

Samples received within holdin id's and tests affected.

8lime?

9 Sample ID's on COC ma c lD's Sample ID's and containers affected:

on bottles?__ _ _ _ __ _

Date & time on COC tch date Sample ID'S affected:

& time on bottles?

Number of containe received Sample ID's affected:

match number indic.ted COC form is propirly signed in 4"-

1 relinguished/recgived sections? 1ccc Z OCG Air Bill ,Tracking #'s, &

Additional Comments

=

• RSRAD Receipt #___________

C4 *If > x2 area background is observed on samples identified as Ron-Suspected Hazard InformationU c- . regulated/non-radioactive". contact the Radiation Safety group for further

• !E investigation.

A Radiological Classification? [ 1/ Maximum. Counts Observed*.' r ..

BPCB Regulated? Comments:

shipped as DZY' azardous I Material? If yes, contact Waste Hazard Class Shipped:

PM (or PMA) review of Hazard classification:

Page 12 of 105 0

Health Physics Procedure GPP-GGGR-R5104-003 -Attachment B-CY-00 I Major

~Chain of Custody Form No. 2006-00312 Connecticut Yankee Atomic Power Company

2. 362 Injun Hollow Road, East Hampton, CT 06424 !SZ :9'6 j9 4 I.933- '/

W860-267-2556 %___________________I'___

0 Project Name: Haddam Neck Decommissioning Analyses Requested Lab Use Only.,

J Contact Name & Phone: Corents:

Jack McCarthy 860-267-2556 Ext. 3024 Analytical Lab (Name, City, State)

General Engineering Laboratories 2040 Savage Road. Charleston SC, 29407 843 556 8171. Attn. Cheryl Jones Priority: 0 30 D. E] 14 D. El 7 D. Container Sample Size-Media Type &Type Sample Designation Date Time Code Code Code Comment, Preservation Lab Sample 1D 9106-0003-OOIF 4/24/06 14:13 SE C BP x Transferred from COC2006-00221 p" 9106-0003-002F 4/24/06 14:39 SE C BP x Transferred from COC2006-00221

"'9106-0003-003F 4/24/06 15:01 SE C BP x Transferred from COC2006-00221 9106-0003-004F 4/25/06 08:41 SE C BP x Transferred trom COC2006-00223 9106-0003-004FS 4/25/06 08:41 SE C BP X Transferred from COC2006-00223 9106-0003-005F 4/25/06 09:21 SE C BP X Transferred from COC2006-00223 9106-0003-006F 4/25/06 09:46 SE C BP X transferred from COC2006-00223 9106-0003-007F 4/25/06 10:28 SE C BP X Transferred from COC2006-00223 9106-0003-008F 4/25/06 11:15 SE C BP X Transferred from' COC2006-00223 NOTES: PO #: 002332 MSR #: 0 6 -c - " SSWP# NA [ LTP QA El Radwaste QA E Non QA Samples Shipped Via: nitern'lal.Cotiner Combined samples 9106-0003-003F taken on 4/25/06 @08:19 and 9106-0003-003FB taken on 4/25/06 @ 08:19 in order to have sufficient sample for counting. Z Fed Ex n.:ip" : . Deg&C,;

[ Hand Custody Sealed?7,.

1) Relinquished By Date/Time 2)/ec ived By / DateiTime CiStbdy lSeql Intk.t?

' gh ,(, . .5-4Y. / J.' 3 0 (1 ,W),*eAu(d tlt 5/ */f 1GiII Other

3) Relinquished By Date/Time 4) Received By .. Date/Time _ _ __ _ YF. .

Bill of Lading  :

5) Relinquished By Date/Time 6) Received By Date/Time .- 92O- '52C- 52 4.

Health Physics Procedure GPP-GGGR-R5104-003-Attachment B-CY-00 1 Maj or Chain C of Custody Form No. 2006-003 13 CD Connecticut Yankee Atomic Power Company 362 Injun Hollow Road, East Hampton, CT 06424 .,

960-267-2556 -', -35V.

Project Name: Haddam Neck Decommissioning Analyses Requested Contact Name & Phone: its.: . . ..

Jack McCarthy 860-267-2556 Ext. 3024 Analytical Lab (Name, City, State)

General Engineering Laboratories 00 2040 Savage Road. Charleston SC. 29407 0 n 843 556 8171. Attn. Cheryl Jones (n Priority: 30 D.l 14D.[-7D. Container .'; '. . '

Sample Size-Media Type &Type Sample Designation Date Time Code Code Code - - --- - Comment, Preservation S:i i TV ..-

9106-0003-009F 9106-0003-010F 4/25/06 13:00 SE C BP X Transferred from COC 2006-00236 4/25/06 13:23 SE C BP X -- - ransfertedfromCOC2006-00236 9106-0003-01OFS 4/25/06 13:23 SE C BP X Transferred from COC 2006-00236 okc 00~ 9106-0003-01"2F 4/25/06 15:12 SE C BP X Transferred from COC 2006-00236 9106-0003-013F 4/25/06 14:21 SE C BP X Transferred from COC 2006-00236 w, 00l 9106-0003-014F 4/25/06 14:48 SE C BP X Trandferred from COC 2006-00236 . "

9106-0003-015F 4/26/06 08:16 SE C BP x Transferred from COC 2006-00237

, 01 0e.AiOO.O1 iW Ar/9 v/A* 001+/-1 I ~P. lqP ran*l'sicreldg IomO 2*k/. 6/-t*, 1 91600307F42/0 9:8 S C B I Transferred from COC 2006-00237 I ':.<

0 -9106-0003-018F 4/26/06 4/26/06 08:59 08:59 I SE SE I1 C c BP xI I T ansferred from COC 2006-00A3 I 0&

NOTES: PO #:002332 MSR #: 06- SSWVP# NA Z LTP QA E! Radwasfe. nA E] Non QA Samples Shipped Via:

gpj"jC a] g

[ Fed Ex 11UPS LI Hand 1~i~sod 4 'De~l~tc mYL p ND

1) Relinquished By Datwiime 2) eceived By DateiTime 3)1Rlinquseo ae e4 cD El Other

3) Relinquished By Date/Time 4) Received By b /T

°Dafe/Time Bill of Lading #

092O-S0120-02/

Connecticut Yankee Statement of Work for Analytical Lab Services CY-ISC-SOW-OO 1 Figure 1. Sample Check-in List Date/Time Received:_ .* 6 SDG#:____A t{ fo6-o~

Work Order Number:- (.'Z- 3 5 ShippingCctntainer ID: AC'lX*. 0 'i(. 017--1ChainofCustody# 1(25" -

kO0-40) 0.(.) (

1. Custody Seals od shipping container intact?., *yes.[ No

2. Custody Seals dated and signed7 Yes [NNo

3. Chain-of-Custody record present? Yes No [ ]

.4. Cooler temperature .C-

5. Vermiculite/packing materials is: Wet Dryti

6. Number of samples in shipping container :y [.

7. Sample holding times exceeded? Yes [ I No A

.8 Sainp~les V tape -- hazard labels

ýZ custody seals appropriate sample labels

9. Samples are:'

good condition -Ieaking

-. broken .have air bubbles

10. Were any anomalies identified in sample receipt? Yes [ ] No 1I., .Description of anomalies (include sample numbers):

Sample. Custodian/Laboratory:j[Ld(L* C-4c, a Telephoned to: On -By___

Page15of1 5 -1

SAMPLE RECEIPT & REVIEW FORM PM use Gely i (023!

Received By:

... d . R 5PM(A)

(2. ,QirV- " cc_

Review (ensure non-onforuing items are resolved prior to signing):

I 1

[

Sample Receipt Criteria Z Comments/Qualifiers (Required for Non-Conforming Items)

SShipping containers received intact Circle Applicable: seals broken damaged container leaking container other (describe)

Iand sealed?

I0---=,,,,4"_

Samples requiring cold Circlc Coolant # ice bags blue ice dry ce none 2 preservation within (4 +/- 2 C)?

Record preservation method. _ __ _ _r_, P__

e_ n__-H_ "

Chain of custody documents included with shipment? _,_

Sample containers intact and Circle Applicable: seals ibrken damaged container leaking container other (describe) sealed?

5 Samples requiring chemical Sample ID's. containers aftected and obsmved pH:

reservation at ro r H? I 6 VOA vials free of headspace Sample ID's and containers affected:

(defined as < 6mm bubble)?._..

Are Encore containers present?

7 (If yes, immediately deliver to VOA laboratory) 8Samples received within holding Id's and tests affected.

time? I 9 Sample ID's on COC match ID's Sample ID's and containers affected:

on bottles?

Date & time on COC match date Sample ID's affected:

& time on bottles?

Sample ID's affected:

Number of containers received match number indicated on COCI COC form is properly signed in relinquished/received sections?

14 Air Bill ,Tracking #'s, & d

a. ' 'q .2 6 02-(..

Additional Comments I b 2 (4 0

-V RSO RAD Receipt #__

Information *If > x2 area background is observed on samples identified as 'non-SH Q regulated/non-radioacrve", contact the Radiation Safety group for further

__ investigation.

rA Radiological Classification? Maximum Counts Observed*:

B PCB Regulated? Comments:

Shipped as DUI Hazarous C Material? If yes, contact Waste Hazard Class Shipped:

Manager or ESH Manager. UN#:

PM (or PMA) review of Hazard classification: Initials Date:

Page 16 of 105 C/ 0 1

Health Physics Procedure GPP-GGGR-R5104-003-Attachment B-CY-001 Major Connecticut Yankee Atomic Power Company 362 Injun Hollow Road, East Hampton, CT 06424 Contact Name & Phone:

Jack McCarthy 860-267-2556 Ext. 3024 Analytical Lab (Name, City, State)

General Engineering Laboratories 2040 Savage Road. Charleston SC. 29407 843 556 8171. Attn. Cheryl Jones Priority: [0 30 D.E] 14 D. [] 7 D.

Samples Shipped Via:

ED Fed Ex El uPs E3 Hand

[I Other Bill of Lading #

Health Physýs. PriiýIedure GPP-GGGR-R5104-003-Attachment B-CY-001 Major Chain of Custody Form No. 2006-00337 CQn1 1 pi.p4 Yankee Atomic Power Company

6triZjun Hollow Road, East Hampton, CT 06424 0

860-267-2556 C Y- I - I- I Project.Name: Haddam Neck Decommissioningv Analyses Requested I

Contact Name & Phone:

I.

Jack McCarthyI 860-267-2556 Ext. 3024 Analytical Lab (Name, City, State)

General Engineering Laboratories 0I-2040 Savage Road. Charleston SC. 29407 0/

843 556 8171. Attn. Cheryl Jones Priority: M 30 D. [] 14 D. U 7 D. Container Sample Size-Media Type &Type Sample Designation Date Time~ Code Cormment PreservationI DaeCd oe Code 9I06-0004-008.F.. 5/04/06 08:58 SE C BP x x Transferred from COC 2006-00320 9106-0004-009P,,, 5/04/06 08:23 SE C BP X X Transferred from COC 2006-00320 9106-0004-010 ., 5/03/06 15:11 SE C BP x X Transferred from COC 2006-00317 9106-0004-01OFS -' 5/03/06 15:11 SE C BP X X Transferred from COC 2006-00317 9106-0004-011IF,- 5/03/06 13:08 SE C BP x x Transferred from COC 2006-00317 9106-0004-012F¢/ 5/03/06 13:33 SE C BP x x Transferred from COC 2006-00317 9106-0004-013F-" 5/03/06 13:54 SE C 13P X X Transferred from COC 2006-00317 9106-0004-014F. 5/03/06 14:43 SE C BP X x Transferred from COC 2006-00317 9106-0004-015F , 5/03/06 14:18 SE C BP X X Transferred from COC 2006-00317 I.

NOTES: PO #: 002332 MSR #: 06- a04 p SSWP# NA SLTP QA E] Radwaste QA E] Non QA Samples Shipped Via: IL

[ Fed Ex El ups El Hand 1)Relinquished Iy Date/Time 2) R ived y Date/Time E[ Other I

3) Relinquished By Date/Time ed By Date/Time Bill of Lading #

I. . .

Connecticut Yankee Statement of Work for Analytical Lab Services cY-ISC-SOW-001 Figure 1. Sample Check-in List Date/Time Received: ,'- /1. o.f* 6 ' ,' , 0-CY-ISC-SOW-O01 SDG#: /14t fLO O - O , *e Work Order Number: -( *3 21 1 Shipping Container ID: 7*-M1 Z3 1 Chain of Custody# 0oo .- 6013"1

1. Custody Seals on shipping container intact? Yes No []

2. Custody Seals dated and signed? Yes No []

3. Chain-of-Custody record present? Yes No (]

4. Cooler temperature

/

5. Venniculite/packing materials is: Wet If Dry [ ]

6. Number of samples in shipping container:

7. Sample holding times exceeded? Yes [] No

8. Samples have:

_tape -hazard labels

_.r custody seals _ _appropriate sample labels

9. Samples are:

_ in good condition _..__leaking broken have air bubbles

10. Were any anomalies identified in sample receipt? Yes No []

11. Description of anomalies (include sample numbers):

Sample Custodian/Laboratory: , I Lýc..,-b.,'. Date: . . o , 9. o Telephoned to: On By Page 45 of 56 Page 19 of 105

Connecticut Yankee Staiement of Work for Analytical Lab Services CY-ISC-SOW-00O Figure 1. Sample Chc.k-in List.

Date/TimeReceived.: /Jr)DIRP "

SDG#: /JS~~(

Work Order Number:.____________________

• , - X 3b9= 5 8 ebq .

Shipping Cdatainer ID: _t" Chain of Custody# AD)O( - no 1.. Custody Seals od shipping container intact? -Yes ] No j4)

2. Custody Seals dated and signed? Yes[ ] ..No *c?

3. Chain-of-Custody rc~ord present?

Yes ' No [1

4. Cooler ýemperature_,_ _ _ _ __ _ "

5. vermiculite/packing materials is: wet E4Diy t*]

6.: *Number ofsamples in shipping container

",_-_"_._ __

7. Sample holding timeS,.exceeded?

• . * -Yes e. [ ]No 8.Samiples have:--

2Qtape-hazard labels A..ý2custody seals .. appropriate sample labels

9. Samples ar.e:

--- n good conditiono- Jeokig--

"--haveair bubbles

10. Were any aomali esidentified in sample receipt? Y - N

" Yes/ No.[ J* .

ll..~~~Dte I,"*":..

Sarnple Custoianw hl~ .(~ Dtra/2I(

Telephoned to-__ _ ____________

.*. , . .....

..

...

........

...........

Page 20 of 105

SAMPLE RECEIPT & REVIEW FORM CONTINUATION FORM AedL2.voL...: CO&-* &4 cpro:+(t n(Ke (a- 5 G5 (00 -sv II bLL5f ec, p.-5 CLrpU 06 ts-54 6( , i** '""

Co ,* (F,~~

AJ 1i~_ _ __ _ _ _ _ _

Page 21 of 105 1!1! 1

0 SAMPLE RECEIPT & REVIEW FORM a,

PM use only Client: C41 *'*.-Le. SDG/ARCOC/Work Order: /4' -z3z.

Date Received: * -/. o PM(A) Review (ensure non-conforming items are resolved prior to signing):

Received By:- k&,h- - O-- . .

Sample Receipt Criteria A Comments/Qualiniers (Required for Non-Conforming Items)

Shipping containers received intact Cirie Applicable: seals broken damaged container leaking container other (describe) and sealed? , ,

Samples requiring cold Circle Coolant # ice bags blue ice dry ice rom other describe) 2 preservation within (4 +/- 2 C)?

Record preservation method. __

Chain of custody documents included with shipment? ad 4 Sample containers intact and Circle A icssok dg cone , F oe(dsb) sealed?  : 21t(a oe OoO0-t a1 "

5 Samples requiring chemical Sample M's. containers affected and observed pH:

preservation at proper pH? __

VOA vials free of headspace Sample ID's and containers affected:

(defined as < 6rmm bubble)? _

Are Encore containers present?

7 (If yes, immediately deliver to

_VOA laboratory)x

.

8Samples received within holding Id's and tests affected:..

9 Sample ID's on COC match ID's ll nple ID's and contaiaew affected-on bottles?

10 Date & time on COC match date m ID's af ....

& time on bottles? __....

I1 Number of containers received Samp I's affce:

match number indicated on COC?

12 COC form is properly signed in relinquished/received sections? A.o'- i(-od. #5 k el Air Bill ,Tracking #'s, &

Additional Comments Suspected Hazard Information

• x2 area background is observed on wamples identified as 'aon-

.regulatedthon-radioactive, contact te Radiation Safety group for.further

! Radiological Classificatio= Vd B PCB. Regulat

-~~~ .7:- 7 "com,,enwtS:*_ ... X '

c Material? If yes, contact Waste r Cls Shipped:

Manager or ES Manager. y UN#:

P? Pff4}yqw of Hazard classification: Initials A. Date: -- z.

(.1

0 SAMPLE RECEIPT & REVIEW FORM iPM use only IClient: +/lJ(Y n o " SD1/ARCOCIWork Order: /6Z 2.2.

Date Received: =71 PM(A) Review (esure now onfoar hemsare resolved prim to ii:

Received By: C r7}e vr 1 CA-1 I_____

Sample Receipt Criteria Comments/Qualifiers (Required for Non*Conforming Items) other {describe)

Circle Applicable: seals broken damaged comainer leaking comnaier I Shipping containers received intact and sealed? . .... Cooant __icebags blueice dry_ce______ therdescibe Samples requiring cold Circi Coola # ice bas blue ice dry ice edbr descriic) 2 preservation within (4 +/- 2 C)?

- Record preservation method.

Vq '-,

Chain of custody documents O S. C"X E> V tA-included with shipment?._ coomnse 4 Sample containers intact and i W"cc: stts"I edamaged comaim leaking omier sealed? M15 c3 '

Samples requiring chemical Sam* ID's. containers affected a=W observed pH:

preservation at proper pH? I _, _... . _ ..

__...... ... _'

VOA vials free of headspace le ID's and containers atieced:

6 (defined as < 6mm bubble)? _

Are Encore containers present?

7 (If yes, immediately deliver to VOA laboratory)___ _______.

8amples received within holding Id'j and tests aftned:

time?

Sample ID's on COC match ID's ample ID's and co-aines affected:

on bottles?

Date & time on COC match date ampe ID's affemed:

& time on botles?

Number of containers received smple ID's affected:

match number indicated on COC?

COC form is properly signed in Ctks "L vwrv invoCt 12relinquished/received sections?

14Air Bill ,Tracking #s, & qu~SheA Additional Comments l RSORADReceipt __'

~j ~*If> x2 area- background is observed on samples identified as "non-Suspected Hazard Information .

z reguIated/non-radioactive, contact the Radiation Safety group for further

__ a___d

____,____ investigation.

A Radiological Classification? Maximum Counts Observed..* ... '  : .A. e B PCB Regulatvd? omments:

IShpped as OT1 Hazardous Ci Material? If yes, contact Waste I Hazard Class Shipped:

IManager or ESH Manager.- IUNI:

PM (or PMA) review of Hazard classification: Initials Date: -

Page 2 rF I z -f

Health Physics Procedure GPP-GGGR-R5104-003 -Attachment B-CY-001 Major HelhPyisPoidr P-GRR I 0-0 Atahet IIYO1 ao Connecticut Yankee Atomic Power Company 362 Injun Hollow Road, East Hampton, CT 06424 860-267-2556 Contact Name & Phone:

Jack McCarthy 860-267-2556 Ext. 3024 Analytical Lab (Name, City, State)

General Engineering Laboratories 2040 Savage Road. Charleston SC. 29407 843 556 8171. Attn. Cheryl Jones Priority: Ig 30 D.[] 14 D. [] 7 D.

Date

[] Other Bill of Lading #

1q7'719iS tI/3ISZ

- Connecticut Yankee Statement of Work for Analytical Lab Services .CY-ISC-SOW-O01 Figure 1. Sample Check-in List.

Date/Time Received: 0 SDG#: A Work Order Number: \-,2- 'A "[.

Shipping Container ID: - " L41-3 Chain of Custody #. & - 006 g/ Oc 19 I. Custody Seals ori shipping container intact? YesP4f No[]

2. Custody Seals dated and signed? Yes 4No [ ]"

3. Chain-of-Custody record present? Yes J No []

4. Cooler temperature Ik9 ./, 1 "

5. Vermiculite/packing materials is: Wet [WIDry , J

6. Number ofsamnplw in shipping container: I"

7. Sample holding times exceeded? Yes [ ] No

8. Sampleshave:

-hazard labels

_zcustody seals -appropriate sample labels

9. Samples are.: I 9.Smpe aein good condition' .. ,/*leakin, (Ssi* e4 .S)

• broken -have air bubbles

10. Were any anomalies identified in sample receipt? Y No I . Description of anomalies (incude e numbers):

Sample CustodiantLaboratory: Date: C2d ' O"I?1)

Telephoned to: On By,._"

Page 25 of 105

SAMPLE RECEIPT & REVIEW FORM r

FIM use only Client: SDG/ARCOCIWork Order: IG7vf85 Date Received:

Received By: _._I-PM(A) Review (ensure non-confornuig items are resolved prior to signing):

(I-Sample Receipt Criteria ZO Comments/Qualifiers (Required for Non-Conforming Items)

Shipping containers received intact Circle Applicable: seals broken damaged container leaking container other (describe) a sealed?

Samp- requiring cold Circle Coolant # ice bags blue ice dry ice none other describe) 2 preservati within (4 +/- 2 C)?

Record reserv n method.

3 Chain of custody do nts i included with shipment?t? ..

4 Sample containers intact and Circle Applitable: seals broken damaged container leaking continer other (describe)

,sealed?

S Samples requiring chemical Sample ID's. containers affected and observed pH:

preservation at proper pH?

6 VOA vials free of headspace Sample ID's and containers affected:

--(defined as < 6ram bubble..)?

jAre Encore containers present?

7 (If yes, immediately deliver to VOA laboratory)

Samples received within holding Id's and e afct.e o

_ time? --

Sample ID's on COC match ID's Sample ID's and containers affected:

on bottles?

Date & time on COC match date Sample ID's affected:

- & time on bottles?

Sample ID's affected:

Number of containers received match number indicated on COG?

12 COC form is properly signed in relinquished/received sections?

14 Air Bill ,Tracking #'s, & F41 -5'T. 9! 5 4 2 -- 1 C--

/7 Additional Comments 4210'tO38 m c.-

V 0 RSO RAD Receipt #

Suspected Hazard Information o " Qnon-

- lf> x2 area backgrounda is observed on samples identified as

-- u* reuae/nnrdatv contact the Radiation Safety group for hffrter 04 iZ ,invesigation.

A Radiological Classification? - Maximun Counts Observed*:

B PCB Regulated? /00 ommnts_

Shipped as DOT Hazardous H C Material? If yes, contact Waste Hazard Class Shipped:

Manager or ESH Manager.

PM (or PMA) review of Hazard classification: Initials Date: 715 77 I-aur, /-U 01 1 Vj U,

Health Physics Procedure GPP-GGGR-R5104-003-Attachment B-CY-001 Major Connecticut Yankee Atomic Power Company 362 Injun Hollow Road, East Hampton, CT 06424 "Project Name: Haddam Neck Decommissk

ýZontact Name & Phone:

Jack McCarthy 860-267-2556 Ext. 3024 Analytical Lab (Name, City, State)

General Engineering Laboratories 2040 Savage Road. Charleston SC. 29407 843 556 8171. Attn. Cheryl Jones Priority: Z 30 D.E] 14 D. [I 7 D.

Samples Shipped Via:

[ Fed Ex El uPs El Hand

[] Other Bill of Lading #

• 92o- 7.1o- ,

Connecticut Yankee Statement of Work for Analytical Lab Services , CY-ISC-SOW-O01 Figure 1. Sample Check-in List.

Date/Time Received-: . cr!Z(D SDG#A k . . -

Work SippingOrder Number._ /_________________

Cdhtainer ID):- S9,"

Sipn CCchýt-ai*nef Chain of Custody'# SQ (C 'V ' /

I. Custody Scals ojinshipping container intact?.... -Yes t No V(-

2. Custody Seats dated and. signed? Yes H No

3. Chain-of-Custody record present?

Yes (P)No []

-4. Cooler.te.perature I C">

5. Vermiculite/packing materials is: - Wet o) Dry J, ]

6.: Number ofsamples in shipping container; 5 t (c n" *-

7. Sample holding times exceeded? Yes [] No

.8. Samples have:

~tepe-hazard labels

'custody seats ... appropriate -sample labels

9. Samples are.

-0n good co,,dition -leaking

- haye air bubbl.s

10. Were any anomalies identif .- YesJ[ ] No

11. .Description of anomalies.(include sample numbers):

Sanilek Custodian/Laboratory: /A . -a e /~

Telephoned to:__________________"

-

Page 28 of 105

oSAMPLE RECEIPT & REVIEW FORM PMuseanly Client:SDG/ARCOCIWork Order: tG7832. /,1-&5-0 Date Received: A Rev- m-emresolved prior to sigaiag):

io.-coflisi Received BY: C cdrk I Sample Receipt Criteria [ Comments/Qualimers (Required for Non-Coaforming items) ircle Applicable: seals btokcn damaged conzainer inaking coe*ainer oie (describe)

Shipping containers received intact I and s caled ? ...*

ICE;;

Samples requiring cold Circle Coolan# ice bags blue ie dry ie Q!( odiudescribe) 2 preservation within (4 +/- 2 C)?

Record preservation method. .....

Chain of custody documents included with ship*ment?

CO U S c bu.'* e.pp*: baO(A dim container leaking

/. danged sa tmqka "Wcontinere OX _,l p'~

Od)C(dc ,,/ ~

Sample containers intact and sealed?

Samples requiring chemical mple ID's. containers a: S preservation at proper pH? ,r, VOA vials free of headspace Sam& ID's and coamin affected:

(defined as < 6mn bubble)?

Are Encore containers present?

7 (If yes, immediately deliver to VOA laboratory) .. ..

id's and wte affected:

8 Samples received within holding time?

9 Sample ID's on COC match ID's Suiple ID's and comainers affected:

on bottles? I Date & time on COC match date SampIe WS UffeCte:

& time on bottles? , _,

mp* I'S afect:

Number of containers received match number indicated on COC?

COC form is properly signed in C3VU Cd'L LU vL~Ac ut*i relinquished/received sections?___

3 Air Bill ,Tracking #'s, & . C.*c+/-,y)u,_d-3 () 1L.&L" Additional Comments C V V iRSO RAD Receipt_#

• > x2 area background is observed on samples identified as"non-

• If Sregulated/non-radioactive, contact the Radiation Safety group for further

__investigation.

A jRadiological Classification? Maximum Counts Observed':

P CP*IRcgulated? Comments:

jShippe -aI Hazardous NC[Material? If yes, contact Waste I Hazard Class Shipped:

_Manager or ESH Manager. UN#

PM (or PMA) review of Hazard classitication: Initials ,, ý , Date: 7(71 .10 rage 2-9 of 10U a

1. -- ,1 M

9 SAMPLE RECEIPT & REVIEW FORM CONTINUATION FORM VAAlk 16,7- 9-3 2, 1(, Z 95-0

-Fid F Y--Fa-To*-W co)-

O-W "41= f: cri&-LL*rvn

__ q__q_ _ COLO)?) no0"n OOas 0e053A

--- -- UoII &OOto - 0(35 H ) 5*v

[o

-- - (lo,5S

• OO* 550 ( o )

• iv.

-~ok - op 3-i (q0 lVL b-s~ed codce-i h ad m_.'

5fr c*!,n~ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _

CrL4~ro J~

a iL U i1 _ _ _ _ _ _ _

Page 30 of 105

'I '"P

Health Physics Procedure GPP-GGGR-R5104-003 -Attachment B-CY-001 Major Connecticut Yankee Atomic Power Company Chain of Custody Form No. 2006-00367 362 Injun Hollow Road, East Hampton, CT 06424 0 860-267-2556 .. .... .. . .

Project Name: Haddam Neck Decommissioning Analyses Requested Lab Use Only Contact Name & Phone: Comments:

Jack McCarthy 860-267-2556 Ext. 3024 Analytical Lab (Name, City, State)

General Engineering Laboratories 2040 Savage Road. Charleston SC. 29407 843 556 8171. Attn. Cheryl Jones W 4 4 Priority: 2] 30 D. [] 14 D. 0 7 D. Container Sample Size-Sample Designation Date Time Type &Type Comment, Preservation SamleDeigatin at Tme Lab Sample ID Code Code Code II 9106-0008-001F 5/05/06 11:13 SE C BP X X x Transferred from COC #2006-00324 9106-0008-003F 5/5/06 13:35 SE C BP x x x Transferred from COC #2006-00325 9106-0008-004F 5/5/06 13:51 SE C BP x x x Transferred from COC #2006-00325 9106-0008-005F 5/5/06 14:17 SE C BP X X X Transferred from COC #2006-00325 9106-0008-006F 5/5/06 14:36 SE C BP x x x Transferred from COC # 2006-00325 9106-0008-006FS 5/5/06 14:36 SE C BP X X X " Transferred from COC # 2006-00325 9106-0008-007F 5/5/06 15:03 SE C BP X Transferred from COC # 2006-00325 9106-0008-002F 5/5/06 13:10 SE C BP X x x Transferred from COC # 2006-00325 4 i-f------------~-t-t-t-t I NOTES: PO #: 002332 MSR #: 06- 07'"3 SSWP# NA SLTP QA El Radwaste QA E] Non QA Samples Shipped Via: Internal Container Fed Ex F Temp.: __ Deg. C EUPS L]Hand Custody Sealed?

Yo NO

1) elinqu Qhe Date/Time 2), ived " ate/Time Custody Seal Intact?

El Other

3) Winquished By \ Date/Time 4) Redeive y V '"/ Ibate/Time YO NO Bill of Lading #

Rfl2? 5541//(2_

Health Physics Procedure GPP-GGGR-R5104-003 -Attachment B-CY-001 Major HeathPhyic Prceur GP-GGR-5 0400-Atacmet BCYO0 Mjo Chain of Custody Form o Connecticut Yankee Atomic Power Company 362 Injun Hollow Road, East Hampton, CT 06424 860-267-2556 - -. ..

Project Name: Haddam Neck Decommissioning Analyses Requested Lab Use Only Contact Name & Phone: Comments:

Jack McCarthy 860-267-2556 Ext. 3024 Analytical Lab (Name, City, State)

General Engineering Laboratories 2040 Savage Road. Charleston SC. 29407 Q 843 556 8171. Attn. Cheryl Jones z Priority: 0 30 D. [] 14 D. ED 7 D, Container Sample Size-Media Type &Type '"

Sample Designation Date Time Code Code Code Comment, Preservation Lab Sample ID 9106-0008-008F 5/08/06 08:01 SE C BP x x x Transferred from COC # 2006-00327 010 9106-0008-009F 5/08/06 08:32 SE C BP x x x Transferred from COC # 2006-00327 Oil 9106-0008-OIOF 5/08/06 09:09 SE C BP X x x Transferred from COC # 2006-00327 1l 9106-0008-01OFS 5/08/06 09:09 SE C BP X X X Transferred from COC # 2006-00327

)I 9106-0008-01IF 5/08/06 09:30 SE C BP x x x Transferred from COC # 2006-00327 10 9106-0008-012F 5/08/06 09:53 SE C BP X Transferred from COC #2006-00327

)1 9106-0008-013F 5/08/06 10:16 SE C BP X x X Transferred from COC # 2006-00327 9106-0008-014F 5/08/06 9106-0008-01F 5/08/06 110:47 1047 SE C BP X x x Transferred from COC # 2006-00327 SE C BP, X ___________

NOTES: PO #: 002332 MSR #: 06-61q3 SSWP#NA SLTP QA fl Radwaste QA El Non QA Samples Shipped Via: Internal Container CK Fed Ex Temp.: -4 1 Deg. C l] UPS l Hand Custody Sealed?

YCD N)T

1) Relinquished By Date/Time 2) Received By Date/Time Custody Seal Intact?

S-iqs5/2ti4)(0 By bt Ul Other

3) Relinquished By Date/Time 4) Received By Date/Time Yli7ND Bill of Lading #

j~,~7L~1 ~/

Connecticut Yankee Sta~tement of Work for Analytical Lab Services -CY-ISC-SOW-001 Figure 1. Sample Check-in List Date/Time Received: 4OQ u CptoC SDG#:

Work Order Number:

Shipping CcitainerlD:'q~r 6 t I J Chain ofCstody# ')OO..DuO&3(ofl

1. Custody Seals owi shipping container intact? -Yes ['rNo I I

2. Custody Seals dated and signed? Yes* [ No [<

3. Chain-of-Custody record present? Yes C.00o I I

4. Cooler temperature

5. Vermiculite/packing materials is: Wet [ , Dry A",]

/AIi 6" Number of samples in shipping container: ".;

7. Sample holding times exceeded? Yes [] No [4'

8. Samples have:

-thazard labels

_ _custodly seals _/appropriate sample labels

9. Samples are:' - *

/"'in. good co~ndton leking

-broken -have air bubbles

10. Were any anomalies identified in sample receipt? Yes [ No 11.,. .Description of anomalies.(include sample numbers):

Telephoned to:__ _ By on___.__*__ "..._.._,._ -_

Page 33 of 105

SAMPLE RECEIPT & REVIEW FORM

• ber of contimners received i number indicated on COC? I form is properly signed in S::W --

O RAD R=cipt I

> x2 am background is observed on samples idenmiied as non--

ilated/non-radiactive', contact the Radiation Saty,group for further Observed*: no tv-ý 7a,

-p kl

[azard Class Shipped:

NI:

Initials I2& 26 Date:

-

Page 34 of 105

0 SAMPLE RECEIPT & REVIEW FORM

.r PM urn oly SClient: Y an keSIDG/ARCOC/Work Order: Ap37 //.

Date Received: 1W Review (ensure noncounrorming iteus are resoved prior to signing):

,PM(A)

Received By: C fui6k 1 .I Sample Receipt Criteria CommentslQualiflers (Required for Non-Confonming Items)

Shipping containers received intact Circle Applicable: s-als brken damaged container leaking container other (describe) and sealed? __

Samples requiring cold Circle Cooant # ice bags blue ice dry ice odief describe) 2 preservation within (4 +/- 2 C)?

Record preservation method. .21 '

Chain of custody documents included with shipment?

Sample containers intact and Circle Applicable: seals broken damaged conairner leaking continer other (describe) sealed? __ _ _ _ _ _ _ _ _ __ _ _ _ _ _ _ _ _ _ __ _ _ _ _ _ _ _ _ _

Samples requiring chemical Sample ID's. containers affected and observed pH:

preservation at proper pH?

VOA vials free of headspace Sample ID's and containers affected:

6 (defined as < 6mm bubble)?

Are Encore containers present?

7 (If yes, immediately deliver to VOA laboratory) 1 Id's a sew afected; Samples received within holding 8 time? V' SSample ID's on COG match ID's samPleID'sanicotiners affected:

on bottles? __

Smtuple ID's affected:

10 Date & time on COC match date

& time on bottles?

Number of containers received Sample ID's affected:

match number indicated on COC?

COC form is properly signed in *o4-j " I 1q&1/wjk'*

relinquished/received sections?

o r1 Lace "e

14Air Bill ,Tracking #'s, &

Additional Comments T RSO RAD Receipt #

'4ti *If> x2 area background is observed on samples i&dmfied as "nan-Suspected Hazard Information ,40 VD 2p regulated/non-radioactive*.

r3 contact ca the Radiation Safety group for fiurther

• 1%, in ves tigati on .

A I KaG oiogIC2i CLassltcation? p.

-¶ I1*~ jMaximum Counts Observed*: V; CyPH-i LI Comments:

B PCB Regulated?

[Shipped as DOI Hazardous n Hazard Class Shipped:

CMaterial? If yes, contact Waste Manager or ESH Manager. UND:

PM (or PMA) review of Hazard classification:

Page 35 of 105

Ito3 7q IV Connecticut Yankee Statement of Work for Analytical Lab Services CY-ISC-SOW-001 Figure 1. Sample Check-in List Date/Time Received: t,(. (¢ Og"b SDG#:

Work Order Number:

Shipping Cctntainer ID: -79 2 5 <4 I I 7 Chain of Custody # " *t Q U4C, I. Custody Seals o0 shipping container intact?. Yes j"'o

2. Custody Seals dated and signed? Yes L o [ -

3. Chai;k-of-Custody record present? Yes [,4o [1

4. Cooler temperature . ZI'

5. Vermiculite/packing materials is: Wet ý,,]ry []

6' Number of samples in shipping container: (9 t 1 h k'

7. Sample holding times exceeded? Yes.[ ] No

8. Samples have:

t.pe -hazard labels

.cuStody seals -_appropriatesample labels

9. Samples are:

.Jin good condition leaking

-broken .have air bubbles 10.

11.

Were any anomalies identified in sample receipt?

Description of anomalies (include sample numbers):

OW Yes []No Sample. Custodian/Laboratory: e C" b Date:. -Y - ,

Telephoned to: On By Page 36 of 105

.. 'r11.

GPP-GGGR-R5104 -00 3-Attach rnen t B-CY-001 Major Health Physics Procedure

/.tj gvo J HeltPoedreIJJ Pyic ~4 GPGGR-5 0-03 Atahmn BCY0 IMao Chain of Custody Form No. 2006-00380 CD Connecticut Yankee Atomic Power Company 362 Injun Hollow Road, East Hampton, CT 06424

Project Name: Haddam Neck Decommissioning Analyses Requested -abUseOnly Contact Name & Phone: Comments:

Jack McCarthy 860-267-2556 Ext. 3024 Analytical Lab (Name, City, State)

General Engineering Laboratories 2040 Savage Road. Charleston SC. 29407 0 843 556 8171. Attn. Cheryl Jones C/_ Z Priority: Z 30 D.E] 14 D. E 7 D. Container Sample Size-Media Type &Type C P Sample Designation Date Time Code Code Code Comment, Preservation Lab Sample ID

,i 9106-0009-016F 5/15/06 13:28 SE C BP x x Transferred from COC 2006-00352 502.9106-0009-016FS 5/15/06 13:28 SE C BP x x Transferred from COC 2006-00352 9106-0009-017F 5/15/06 14:03 SE C BP X x Transferred from COC 2006-00352 9106-0009-01IF 5/15/06 08:05 SE C BP x Transferred from COC 2006-00351 p 9106-0009-013F 5/15/06 08:35 SE C BP X X Transferred from COC 2006-00351 9106-0009-013FS 5/15/06 08:35 SE C BP X x Transferred from COC 2006-00351 DII 9106-0009-014F 5/15/06 08:59 SE C BP x Transferred from COC 2006-00351 9106-0009-015F 5/15/06 09:36 SE C BP X X Transferred from COC 2006-00351 i i i- P i ----------- 4- i I

1. J A L L ~

NOTES: PO#: 002332 MSR#: 06-0/S SSWP#NA Z LTPQA LI Radwaste QA tL_.Non QA Samples Shipped Via: Internal Container

[ Fed Ex Temp.: ___ Deg. C El uPs Hand Hl Custody Sealed?

YO NI

1) Relinquised By Date/Time j2) Re Date/Time Custody Seal Intact?

r-16-06 9O0 El Other

-~~= V- LyI-

-

3) Relinquished By Date/Time 4) Reeivet By Date/Time Y []7 N 7 I

I I Bill of Lading #

Health Physics Procedure I//"Irf

- I - -- I GPP-GGGR-R5104-003 -Attachment B-CY-001 Major 00 Connecticut Yankee Atomic Power Company Chain of Custody Form No. 2006-00381 362 Injun Hollow Road, East Hampton, CT 06424 00 860-267-2556 Project Name: Haddam Neck Decommissioning Analyses Requested Lab Use Only Contact Name & Phone: Comments:

Jack McCarthy 860-267-2556 Ext. 3024 Analytical Lab (Name, City, State)

General Engineering Laboratories

• 2040 Savage Road. Charleston SC, 29407 .

843 556 8171. Attn. Cheryl Jones r, , Z 30 D. [] 14 D. [17 D. Container Priority:

Sample Size-Media Type &Type Sample Designation Date Time Code Code Code Comment, Preservation Lab Sample ID 9106-0009-OO1F 5/11/06 13:22 SE C BP X X Transferred from COC 2006-00347 9106-0009-002F 5/11/06 13:46 SE C BP X X Transferred from COC 2006-00347 9106-0009-003F 5/11/06 14:06 SE C BP X X Transferred from COC 2006-00347 Ott 9106-0009-004F 5/11/06 14:30 SE C BP X X Transferred from COC 2006-00347 9106-0009-005F 5/11/06 14:55 SE C BP X X Transferred from COC 2006-00347 oil- 9106-0009-007F 5/12/06 07:44 SE C BP X X Transferred from COC 2006-00348 9106-0009-008F 5/12/06 08:16 SE C BP X x Transferred from COC 2006-00348 9106-0009-009F 5/12/06 08:35 SE C BP X X Transferred from COC 2006-00348 9106-0009-OIOF 5/12/06 09:07 SE C BP X X Transferred from COC 2006-00348 NOTES: PO #: 002332 MSR #: 06- SSWP# NA E LTP QA [] Radwaste QA 0l Non QA Samples Shipped Via: Internal Container

[ Fed Ex Temp.: _ Deg. C

~UPS 0 Hand Custody Sealed?

YO NO

1) Relinquished By Date/Time 2) Rec* ed y Custody Seal Intact?

Date/Time

-] Other

3) Relinquished By Date/Time 4) Receivedby Y0 Date/Time ND Bill of Lading #

tqzf /N/ zy2"2x

Connecticut Yankee Statement of Work for Analytical Lab Services .CY-ISC-SOW-001 Figure 1. Sample Check-in List Datefrime Received: (2 - 0 00 "0 SDG#: rL- ,-o . 0o X Work Order Number:

Shipping C'tainer IDI, Cctntaincr

- /' Chain ID: of Custody# "CMO -12,°'

1. Custody Seals. oti shipping container intact? -Yes D4] No [

2. Custody Seals dated and signed? Yes [ .No

3. Chain-of-Custody record present? Yes f No []

.4. Cooler temperature i0 ,, "6

5. Vermiculite/packing materials is: Wet [] Dry

6. Number of samples in shipping container: .... __

7. Sample holding times exceeded? Yes No []

8. Samples have:

tape _____hazard labels X _custody seals -.__appropriate sample labels

9. Samples are:

-,A-in good condition . leaking

-broken -- have air bubbles

10. Were any anomalies identified in sample receipt? Yes [' No

-II *..Descriptionof anomalies (include sample numbers): ..

Sample Custodian/Laboratory:- Date.: 6 , ' 06 Telephoned to: On By "

Page 39 of 105

Health Physics Procedure GPP-GGGR-R5104-003-Attachment B-CY-001 Major Connecticut Yankee Atomic Power Company Chain of Custody Form No. 2006-00349 362 Injun Hollow Road, East Hampton, CT 06424 860-267-2556 Project Name: Haddam Neck Decommissioning Analyses Requested Lab Use Only Contact Name & Phone: Comments:

Jack McCarthy 860-267-2556 Ext. 3024 Analytical Lab (Name, City, State)

General Engineering Laboratories 2040 Savage Road. Charleston SC. 29407 V) Cn* ",

843 556 8171. Attn. Cheryl Jones rn d z Priority: Z 30 D. E 14 D. [] 7 D. Container media Type &Type Sample Desigation Date Time Code Code Code Comment, Preservation Lab Sample ID a 9106-0010-OOIF 5/04/06 10:49 SE C BP X X Transferred from COC 2006-00321 0 9106-0010-002F 5/04/06 11:12 SE C BP X X Transferred from COC 2006-00321 01t 9106-0010-004F 5/04/06 12:48 SE C BP X X Transferred from COC 2006-00321 9106-0010-006F 5/04/06 13:34 SE C BP X x Transferred from COC 2006-00321 9106-0010-007F 5/04/06 13:21 SE C BP X X Transferred from COC 2006-00321 0 -9106-0010-009F 5/04/06 14:01 SE C BP X X Traferred from COC 2006-00321 b 9106-0010-00F 5/04/06 14:21 SE C BP X X Transferred from COC 2006-00321 eJ;J 9106-0010-012F 5/04/06 14:44 SE C BP X X Transferred from COC 2006-00321

-o 9106-0010-013F 5/04/06 15:06 SE C BP X Transferred from COC 2006-00321 II NOTES: PO #: 002332 MSR#: 06- 0707 SSWP#NA 9 LTP QA [] Radwaste QA El Non QA Samples Shipped Via: internal Container

[ Fed Ex Temp.: /7Deg. C EUPS El Hand CustodyySealed?

1) RelinquisheoBy Date/Ti e 2) Received y Date/Time Custody Seal Intact?

El Other 1)Relinquished By Datefime 4) Received By Date/Time Y Q- o Bill of Lading -

3q04- 3 1

Connecticut Yankee CY-ISC-SOW-O0L Statement of Work for Analytical Lab Services Figure 1. Sample Check-in List q qf" 5"/ °6 *o Date/Time Received:

SDG#: n 1r-0707

... M1V_ 2 Work Order Number:

311) 55 ?. Chain of Custody # 60 39 .

Shipping Cdntainer ID: ,O1

1. Custody Seals ori shipping container intact? -Yes I)(1 No [ ]

2. Custody Seals dated and signed? Yes [] No []

3. Chain-of-Custody record present? Yes D] No [ ]

4. Cooler temperature '7 9 C

5. Vermiculite/packing materials is: Wet ] Dry t\ I

6. Number of samples in shipping container: ___

7. Sample holding times exceeded? Yes I3No 1*

8. Samples have:

- tape -hazard labels

.-. custody seals -appropriate sample labels

9. Samples are:

4_._in good condition .1jleaking

-broken -have air bubbles

10. Were any anomalies identified in sample receipt? Yes [ ] No j

11. - Description of anomalies (include sample numbers):

Sample CustodianjLaboratoxy: Date: -)6 3_--O G Telephoned to: On By "

Page 41 of 105

SAMPLE RECEIPT & REVIEW FORM 00

ýP1roRV&t" PM use only Client: ad-At, 44 ------- SDG/ARCCWok Order:

Date Received: 5- PM(A) Review ( o 0 g items are resolved prior to signing):

Received By:

Sample Receipt Criteria .

• Com ents/Quaiiers (Required for Non-Conforming Items) damaged container leaking container other (describe)

Shipping containers received intact Z Circle Applicable: seals broken 1and sealed?

Samples requiring cold Circle Coolant # ice bags blue ice dry ice jiie.) other describe) 2 preservation within (4 +/- 2 C)? V/

Record preservation method.

3Chain of custody documents included with shipment?

4 Sample containers intact and Circle Applicable: seals broken damaged container leaking container C other (describe) sealed? -'/

5 Samples requiring chemical Sample ID's. containers affected and observed pH:

_ reservation at proper pH? .....

6 VOA vials free of headspace Sample ID's and containers affected:

(defined as < 6mm bubble)?

Are Encore containers present?

7 (If yes, immediately deliver to

-VOA laboratory) _________________________

Id's and tests affected:

8 Samples received within holding 8 time? IA Sample ID's on COC match ID's Sample ID's and containers affected:

on bottles?

10 Date & time on COC match date Sample ID's affected:

& time on bottles? ___

11 Number of containers received Sample ID's affected:

match number indicated on COC?

12 COC form is properly signed in relinquished/received sections?

Air Bill ,Tracking #'s, &

1Additional Comments RAD Receipt #

> V IRSO x2 area background is observed on samples identified as "non-CI S*If H

Sup e Hd Iregulated/non-radioactive", contact the Radiation Safety group for further

___________________4_ 1 i investigation.

A Radiological Classification? Maximum Counts Observed*:

V Comments:

• P'B Regulated?

fShpped as DOI Hazardous

• Material? If yes, contact Waste Hazard Class Shipped:

Manager or ESH Manager.I N#:

PM (or PMA) review of Hazard classification: Initials Date:

Z Z Page 42 of 105

List of current GEL Certifications as of 15 August 2006 E State Certification Alaska UST-062 Arizona AZ0668 Arkansas 88-0651.

-: - CLIA 42D0904046 California 0115 ICA -

Colorado GenEngLabs Connecticut PH-0169 Dept. of Navy NFESC 413 EPA WG-1I5J Florida/NELAP E.87156 Georgia E87156 (FLINELAP)

Idaho N/A Illinois 200029 Indiana C-SC-01 Kansas E- 10332

-- Kentucky 90129 Maryland Massachusetts 270 M-S1CO2

-H Michigan 9903 Nevada SC002 New Jersey

-_ _Z--.---

---

_-5-b New York North Carolina 233 North Carolina Drinking W 45709 North Dakota R-158 Oklahoma 9904 Pennsylvania 68-485

-SouthCarolina 10120001/10585001/10120002 Tennessee 02934 Texas TX213-2006A U.S. Dept. of Agriculture S-52597 US Army Corps of Engineer N/A Utah Vermont 8037697376 GEL N/A

---.

1

~~~~1 Virginia 00151 Washington C223 Page 43 of 105

RADIOLOGICAL ANALYSIS Page 44 of 105

Radiochemistry Case Narrative Connecticut Yankee Atomic Power Co. (YANK)

Work Order 168404 Method/Analysis Information Product: Alphaspec Am241, Cm, Solid ALL FSS Analytical Method: DOE EML HASL-300, Am-05-RC Modified Prep Method: Ash Soil Prep Dry Soil Prep GL-RAD-A-021 Method: Dry Soil Prep Analytical Batch Number: 555696 Prep Batch Number: 554650 Dry Soil Prep GL-RAD-A-021 Batch Number: 554649 Sample ID Client ID 168404001 9106-0002-007F 168404002 9106-0002-01 IF 168404003 9106-0003-004F 168404004 9106-0003-015F 168404005 9106-0004-005F 168404006 9106-0004-015F 168404007 9106-0005-OIOF 168404008 9106-0005-014F 168404011 9106-0008-008F 168404012 9106-0009-002F 168404013 9106-0009-017F 168404014 9106-0010-OO1F 168404015 9106-0010-012F 1201153129 Method Blank (MB) 1201153130 168340011(9304-01-005C) Sample Duplicate (DUP) 1201153131 168340011(9304-01-005C) Matrix Spike (MS) 1201153132 Laboratory Control Sample (LCS)

SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-01 1 REV# 14.

Page 45 of 105

Calibration Information:

Calibration Information All initial and continuing calibration requirements have been met.

Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).

Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.

Quality Control (QC) Information:

Blank Information The blank volume is representative of the sample volume in this batch.

Designated QC The following sample was used for QC: 168340011 (9304-01-005C).

QC Information All of the QC samples met the required acceptance limits.

Technical Information:

Holding Time All sample procedures for this sample set were performed within the required holding time.

Preparation Information All preparation criteria have been met for these analyses.

Sample Re-prep/Re-analysis Sample 168404003 (9106-0003-004F) was recounted due to high MDA.

Miscellaneous Information:

NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. A nonconformance report (NCR) was not generated for this SDG.

Manual Integration No manual integrations were performed on data in this batch.

Additional Comments Additional comments were not required for this sample set.

Qualifier information Manual qualifiers were not required.

Method/Analysis Information Page 46 of 105

Product: Alphaspec Am241, Cm, Solid ALL FSS Analytical Method: DOE EML HASL-300, Am-05-RC Modified Prep Method: Ash Soil Prep Dry Soil Prep GL-RAD-A-021 Method: Dry Soil Prep Analytical Batch Number: 557837 Prep Batch Number: 554650 Dry Soil Prep GL-RAD-A-021 Batch Number: 554649 Sample ID Client ID 168404009 9106-0006-005F 168404010 9106-0008-006F 1201158316 Method Blank (MB) 1201158317 168404009(9106-0006-005F) Sample Duplicate (DUP) 1201158318 168404009(9106-0006-005F) Matrix Spike (MS) 1201158319 Laboratory Control Sample (LCS)

SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-01 I REV# 14.

Calibration Information:

Calibration Information All initial and continuing calibration requirements have been met.

Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).

Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.

Ouality Control (OC) Information:

Blank Information The blank volume is representative of the sample volume in this batch.

Designated QC The following sample was used for QC: 168404009 (9106-0006-005F).

QC Information Page 47 of 105

All of the QC samples met the required acceptance limits.

Technical Information:

Holding Time All sample procedures for this sample set were performed within the required holding time.

Preparation Information All preparation criteria have been met for these analyses.

Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis.

Miscellaneous Information:

NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. A nonconformance report (NCR) was not generated for this SDG.

Manual Integration No manual integrations were performed on data in this batch.

Additional Comments Additional comments were not required for this sample set.

Qualifier information Manual qualifiers were not required.

Method/Analysis Information Product: Alphaspec Pu, Solid-ALL FSS Analytical Method: DOE EML HASL-300, Pu- 11-RC Modified Prep Method: Ash Soil Prep Dry Soil Prep GL-RAD-A-021 Method: Dry Soil Prep Analytical Batch Number: 555697 Prep Batch Number: 554650 Dry Soil Prep GL-RAD-A-021 Batch Number: 554649 Page 48 of 105

Sample ID Client ID 168404001 9106-0002-007F 168404002 9106-0002-01 IF 168404003 9106-0003-004F 168404004 9106-0003-015F 168404005 9106-0004-005F 168404006 9106-0004-015F 168404007 9106-0005-OIOF 168404008 9106-0005-014F 168404009 9106-0006-005F 168404010 9106-0008-006F 168404011 9106-0008-008F 168404012 9106-0009-002F 168404013 9106-0009-017F 168404014 9106-0010-001F 168404015 9106-0010-012F 1201153133 Method Blank (MB) 1201153134 168340011(9304-01-005C) Sample Duplicate (DUP) 1201153135 168340011(9304-01-005C) Matrix Spike (MS) 1201153136 Laboratory Control Sample (LCS)

SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-01 1 REV# 14.

Calibration Information:

Calibration Information All initial and continuing calibration requirements have been met.

Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).

Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.

Quality Control (OC Information:

Blank Information The blank volume is representative of the sample volume in this batch.

Designated QC The following sample was used for QC: 168340011 (9304-01-005C).

QC Information All of the QC samples met the required acceptance limits.

Page 49 of 105

Technical Information:

Holding Time All sample procedures for this sample set were performed within the required holding time.

Preparation Information All preparation criteria have been met for these analyses.

Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis.

Miscellaneous Information:

NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. A nonconformance report (NCR) was not generated for this SDG.

Manual Integration No manual integrations were performed on data in this batch.

Additional Comments Additional comments were not required for this sample set.

Qualifier information Manual qualifiers were not required.

Method/Analysis Information Product: Liquid Scint Pu241, Solid-ALL FSS Analytical Method: DOE EML HASL-300, Pu- I1-RC Modified Prep Method: Ash Soil Prep Dry Soil Prep GL-RAD-A-021 Method: Dry Soil Prep Analytical Batch Number: 555698 Prep Batch Number: 554650 Dry Soil Prep GL-RAD-A-021 Batch Number: 554649 Page 50 of 105

Sample ID Client ID 168404001 9106-0002-007F 168404002 9106-0002-01 IF 168404003 9106-0003-004F 168404004 9106-0003-015F 168404005 9106-0004-005F 168404006 9106-0004-015F 168404007 9106-0005-OIOF 168404008 9106-0005-014F 168404009 9106-0006-005F 168404010 9106-0008-006F 168404011 9106-0008-008F 168404012 9106-0009-002F 168404013 9106-0009-017F 168404014 9106-0010-001F 168404015 9106-0010-012F 1201153137 Method Blank (MB) 1201153138 168340011(9304-01-005C) Sample Duplicate (DUP) 1201153139 168340011(9304-01-005C) Matrix Spike (MS) 1201153140 Laboratory Control Sample (LCS)

SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-035 REV# 8.

Calibration Information:

Calibration Information All initial and continuing calibration requirements have been met.

Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).

Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.

Quality Control (QC) Information:

Blank Information The blank volume is representative of the sample volume in this batch.

Designated QC The following sample was used for QC: 168340011 (9304-01-005C).

QC Information All of the QC samples met the required acceptance limits.

Page 51 of 105

Technical Information:

Holding Time All sample procedures for this sample set were performed within the required holding time.

Preparation Information All preparation criteria have been met for these analyses.

Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis.

Miscellaneous Information:

NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. A nonconformance report (NCR) was not generated for this SDG.

Manual Integration No manual integrations were performed on data in this batch.

Additional Comments Additional comments were not required for this sample set.

Qualifier information Manual qualifiers were not required.

Method/Analysis Information Product: GFPC, Sr90, solid-ALL FSS Analytical Method: EPA 905.0 Modified Prep Method: Ash Soil Prep Dry Soil Prep GL-RAD-A-021 Method: Dry Soil Prep Analytical Batch Number: 556350 Prep Batch Number: 554650 Dry Soil Prep GL-RAD-A-021 Batch Number: 554649 Page 52 of 105

Sample ID Client ID 168404003 9106-0003-004F 168404004 9106-0003-015F 168404012 9106-0009-002F 168404013 9106-0009-017F 168404014 9106-0010-001F 168404015 9106-0010-012F 1201154644 Method Blank (MB) 1201154645 168404003(9106-0003-004F) Sample Duplicate (DUP) 1201154646 168404003(9106-0003-004F) Matrix Spike (MS) 1201154647 Laboratory Control Sample (LCS)

SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-004 REV# 10.

Calibration Information:

Calibration Information All initial and continuing calibration requirements have been met.

Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).

Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.

Quality Control (QC) Information:

Blank Information The blank volume is representative of the sample volume in this batch.

Designated QC The following sample was used for QC: 168404003 (9106-0003-004F).

QC Information All of the QC samples met the required acceptance limits.

Technical Information:

Holding Time All sample procedures for this sample set were performed within the required holding time.

Preparation Information All preparation criteria have been met for these analyses.

Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis.

Page 53 of 105

Chemical Recoveries All chemical recoveries meet the required acceptance limits for this sample set.

Miscellaneous Information:

NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. A nonconformance report (NCR) was not generated for this SDG.

Additional Comments Samples 1201154644 (MB), 1201154645 (9106-0003-004F), 1201154646 (9106-0003-004F),

1201154647 (LCS), 168404003 (9106-0003-004F), 168404004 (9106-0003-015F), 168404012 (9106-0009-002F), 168404013 (9106-0009-017F), 168404014 (9106-0010-001F) and 168404015 (9106-0010-012F) were dried and reweighed due to low matrix spike/laboratory control sample recovery.

Qualifier information Manual qualifiers were not required.

Method/Analysis Information Product: Liquid Scint Tc99, Solid-ALL FSS Analytical Method: DOE EML HASL-300, Tc-02-RC Modified Analytical Batch Number: 554580 Page 54 of 105

Sample ID Client ID 168404001 9106-0002-007F 168404002 9106-0002-01 IF 168404003 9106-0003-004F 168404004 9106-0003-015F 168404005 9106-0004-005F 168404006 9106-0004-015F 168404007 9106-0005-OIOF 168404008 9106-0005-014F 168404009 9106-0006-005F 168404010 9106-0008-006F 168404011 9106-0008-008F 168404012 9106-0009-002F 168404013 9106-0009-017F 168404014 9106-0010-OO1F 168404015 9106-0010-012F 1201150561 Method Blank (MB) 1201150562 168340012(9304-02-003C) Sample Duplicate (DUP) 1201150563 168340012(9304-02-003C) Matrix Spike (MS) 1201150564 Laboratory Control Sample (LCS)

SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-005 REV# 13.

Calibration Information:

Calibration Information All initial and continuing calibration requirements have been met.

Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).

Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.

Quality Control (QC) Information:

Blank Information The blank volume is representative of the sample volume in this batch.

Designated QC The following sample was used for QC: 168340012 (9304-02-003C).

QC Information All of the QC samples met the required acceptance limits.

Page 55 of 105

Technical Information:

Holding Time All sample procedures for this sample set were performed within the required holding time.

Preparation Information All preparation criteria have been met for these analyses.

Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis.

Miscellaneous Information:

NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. A nonconformance report (NCR) was not generated for this SDG.

Additional Comments Additional comments were not required for this sample set.

Qualifier information Manual qualifiers were not required.

Method/Analysis Information Product: Liquid Scint Fe55, Solid-ALL FSS Analytical Method: DOE RESL Fe-1, Modified Prep Method: Ash Soil Prep Dry Soil Prep GL-RAD-A-021 Method: Dry Soil Prep Analytical Batch Number: 555722 Prep Batch Number: 554650 Dry Soil Prep GL-RAD-A-021 Batch Number: 554649 Page 56 of 105

Sample ID Client ID 168404001 9106-0002-007F 168404002 9106-0002-01 IF 168404003 9106-0003-004F 168404004 9106-0003-015F 168404005 9106-0004-005F 168404006 9106-0004-015F 168404007 9106-0005-OIOF 168404008 9106-0005-014F 168404009 9106-0006-005F 168404010 9106-0008-006F 168404011 9106-0008-008F 168404012 9106-0009-002F 168404013 9106-0009-017F 168404014 9106-0010-OO1F 168404015 9106-0010-012F 1201153222 Method Blank (MB) 1201153223 168340012(9304-02-003C) Sample Duplicate (DUP) 1201153224 168340012(9304-02-003C) Matrix Spike (MS) 1201153225 Laboratory Control Sample (LCS)

SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-040 REV# 3.

Calibration Information:

Calibration Information All initial and continuing calibration requirements have been met.

Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).

Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.

Quality Control (QC) Information:

Blank Information The blank volume is representative of the sample volume in this batch.

Designated QC The following sample was used for QC: 168340012 (9304-02-003C).

QC Information All of the QC samples met the required acceptance limits.

Page 57 of 105

Technical Information:

Holding Time All sample procedures for this sample set were performed within the required holding time.

Preparation Information All preparation criteria have been met for these analyses.

Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis.

Miscellaneous Information:

NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. A nonconformance report (NCR) was not generated for this SDG.

Additional Comments Additional comments were not required for this sample set.

Qualifier information Manual qualifiers were not required.

Method/Analysis Information Product: Liquid Scint Ni63, Solid-ALL FSS Analytical Method: DOE RESL Ni-1, Modified Prep Method: Ash Soil Prep Dry Soil Prep GL-RAD-A-021 Method: Dry Soil Prep Analytical Batch Number: 555723 Prep Batch Number: 554650 Dry Soil Prep GL-RAD-A-021 Batch Number: 554649 Page 58 of 105

Sample ID Client ID 168404001 9106-0002-007F 168404002 9106-0002-01 IF 168404003 9106-0003-004F 168404004 9106-0003-015F 168404005 9106-0004-005F 168404006 9106-0004-015F 168404007 9106-0005-OIOF 168404008 9106-0005-014F 168404009 9106-0006-005F 1201153226 Method Blank (MB) 1201153227 168340012(9304-02-003C) Sample Duplicate (DUP) 1201153228 168340012(9304-02-003C) Matrix Spike (MS) 1201153229 Laboratory Control Sample (LCS)

SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-022 REV# 8.

Calibration Information:

,Calibration Information All initial and continuing calibration requirements have been met.

Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).

Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.

Quality Control (QC) Information:

Blank Information The blank volume is representative of the sample volume in this batch.

Designated QC The following sample was used for QC: 168340012 (9304-02-003C).

QC Information All of the QC samples met the required acceptance limits.

Technical Information:

Holding Time All sample procedures for this sample set were performed within the required holding time.

Preparation Information All preparation criteria have been met for these analyses.

Page 59 of 105

Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis.

Miscellaneous Information:

NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. A nonconformance report (NCR) was not generated for this SDG.

Additional Comments Additional comments were not required for this sample set.

Qualifier information Manual qualifiers were not required.

Method/Analysis Information Product: LSC, Tritium Dist, Solid-HTD2,ALL FSS Analytical Method: EPA 906.0 Modified Analytical Batch Number: 554582 Sample ID Client ID 168404001 9106-0002-007F 168404002 9106-0002-01 IF 168404003 9106-0003-004F 168404004 9106-0003-015F 168404005 9106-0004-005F 168404006 9106-0004-015F 168404007 9106-0005-01OF 168404008 9106-0005-014F 168404009 9106-0006-005F 168404010 9106-0008-006F 168404011 9106-0008-008F 168404012 9106-0009-002F 168404013 9106-0009-017F 168404014 9106-0010-OO1F 168404015 9106-0010-012F 1201150569 Method Blank (MB) 1201150570 168340011(9304-01-005C) Sample Duplicate (DUP) 1201150571 168340011(9304-01-005C) Matrix Spike (MS) 1201150572 Laboratory Control Sample (LCS)

Page 60 of 105

SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-002 REV# 12.

Calibration Information:

Calibration Information All initial and continuing calibration requirements have been met.

Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).

Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.

Quality Control (QCQ Information:

Blank Information The blank volume is representative of the sample volume in this batch.

Designated QC The following sample was used for QC: 168340011 (9304-01-005C).

QC Information All of the QC samples met the required acceptance limits.

Technical Information:

Holding Time All sample procedures for this sample set were performed within the required holding time.

Preparation Information All preparation criteria have been met for these analyses.

Sample Re-prep/Re-analysis Sample 168404010 (9106-0008-006F) was recounted due to high MDA.

Miscellaneous Information:

NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. A nonconformance report (NCR) was not generated for this SDG.

Additional Comments Additional comments were not required for this sample set.

Page 61 of 105

Qualifier information Manual qualifiers were not required.

Method/Analysis Information Product: Liquid Scint C14, Solid AII,FSS Analytical Method: EPA EERF C-01 Modified Analytical Batch Number: 554583 Sample ID Client ID 168404001 9106-0002-007F 168404002 9106-0002-01IF 168404003 9106-0003-004F 168404004 9106-0003-015F 168404005 9106-0004-005F 168404006 9106-0004-015F 168404007 9106-0005-OIOF 168404008 9106-0005-014F 168404009 9106-0006-005F 168404010 9106-0008-006F 168404011 9106-0008-008F 168404012 9106-0009-002F 168404013 9106-0009-017F 168404014 9106-0010-001F 168404015 9106-0010-012F 1201150573 Method Blank (MB) 1201150574 168404003(9106-0003-004F) Sample Duplicate (DUP) 1201150575 168404003(9106-0003-004F) Matrix Spike (MS) 1201150576 Laboratory Control Sample (LCS)

SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-003 REV# 8.

Calibration Information:

Calibration Information All initial and continuing calibration requirements have been met.

Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).

Page 62 of 105

Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.

Quality Control (0Q0 Information:

Blank Information The blank volume is representative of the sample volume in this batch.

Designated QC The following sample was used for QC: 168404003 (9106-0003-004F).

QC Information All of the QC samples met the required acceptance limits.

Technical Information:

Holding Time All sample procedures for this sample set were performed within the required holding time.

Preparation Information All preparation criteria have been met for these analyses.

Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis.

Miscellaneous Information:

NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. A nonconformance report (NCR) was not generated for this SDG.

Additional Comments Additional comments were not required for this sample set.

Qualifier information Manual qualifiers were not required.

Certification Statement Where the analytical method has been performed under NELAP certification, the analysis has met all of the requirements of the NELAC standard unless otherwise noted in the analytical case narrative.

Review Validation:

GEL requires all analytical data to be verified by a qualified data validator. In addition, all data designated for CLP or CLP-like packaging will receive a third level validation upon completion of the data package.

Page 63 of 105

The following data validator verified the information presented in this case narrative:

Reviewer/Date: (& 1§46e% Z*e46 Page 64 of 105

SAMPLE DATA

SUMMARY

Page 65 of 105

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Report for YANKOO Connecticut Yankee Atomic Power Co.

Client SDG: 168404 GEL Work Order: 168404 The Qualifiers in this report are defined as follows:

• A quality control analyte recovery is outside of specified acceptance criteria

• • Analyte is a surrogate compound U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

ND The analyte concentration is not detected above the detection limit.

The above sample is reported on a dry weight basis except where prohibited by the analytical procedure.

Where the analytical method has been performed under NELAP certification, the analysis has met all of the requirements of the NELAC standard unless qualified on the Certificate of Analysis.

This data report has been prepared and reviewed in accordance with General Engineering Laboratories, LLC standard operating procedures. Please direct any questions to your Project Manager, Cheryl Jones.

Reviewed by Page 66 of 105

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: August 21, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0002-007F Project: YANK01204 Sample ID: 168404001 Client ID: YANKOO Matrix: SE Vol. Recv.:

Collect Date: 18-MAY-06 Receive Date: 02-JUN-06 Collector: Client Moisture: 20.9%

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Alpha Spec Analysis Alphaspec Am241, Cm, Solid ALL FSS Americium-241 U 0.0762 +/-0.102 0.00 +/-0.102 0.0956 pCi/g BXLI 08/11/06 1336 555696 1 Curium-242 U 0.00 +/-0.0995 0.00 +/-0.0995 0.138 pCi/g Curium-243/244 U -0.00853 +/-0.0717 0.0405 +/-0.0717 0.177 pCi/g Alphaspec Pu, Solid-ALL FSS 0.444 pCi/g Plutonium-238 U 0.199 +/-0.228 0.181 +/-0.229 BXLI 08/11/06 1633 555697 2 Plutonium-239/240 U 0.0341 +/-0.129 0.120 +/-0.129 0.323 pCi/g Liquid Scint Pu241, Solid-ALL FSS Plutonium-241 U 10.0 +/-6.64 5.08 +/-6.72 10.7 pCi/g BXL1 08/16/06 1220 555698 3 Rad Liquid Scintillation Analysis LSC, Tritium Dist, Solid-HTD2,ALL FSS Tritium U 4.17 +/-6.67 5.28 +/-6.67 11.4 pCi/g DFA1 08/09/06 1128 554582 4 Liquid Scint C14, SolidAlLFSS Carbon-14 U 0.0813 +/-0.0797 0.0634 +/-0.0797 0.132 pCi/g ATH2 08/09/06 0324 554583 5 Liquid Scint Fe55, Solid-ALL FSS Iron-55 U 9.90 +/-48.1 32.0 +/-48.1 65.9 pCi/g MXPI 08/12/06 1633 555722 6 Liquid Scint Ni63, Solid-ALL FSS Nickel-63 U 7.02 +/-6.39 5.18 +/-6.40 10.6 pCi/g MXPI 08/11/06 0738 555723 7 Liquid Scint Tc99, Solid-ALL FSS Technetium-99 U 0.139 +/-0.213 0.173 +/-0.213 0.360 pCi/g EGD1 08/11/06 2027 554580 8 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 08/03/06 1534 554649 The following Analytical Methods were performed Method Description I DOE EML HASL-300. Am-05-RC Modified DOE EML HASL-300, Pu-I I-RC Modified 2

DOE EML HASL-300, Pu-I I-RC Modified 3

4 EPA 906.0 Modified Page 67 of 105

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: August 21, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0002-007F Project: YANKO 1204 Sample ID: 168404001 Client ID: YANKOO Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd 5 EPA EERF C-01 Modified 6 DOE RESL Fe-I, Modified 7 DOE RESL Ni-I, Modified 8 DOE EML HASL-300, Tc-02-RC Modified Surrogate/Tracer recovery Recovery% Acceptable Limits Americium-243 Alphaspec Am241, Cm, Solid ALL 80 (15%-125%)

Plutonium-242 Alphaspec Pu, Solid-ALL FSS 100 (15%-125%)

Carrier/Tracer Recovery Liquid Scint Pu241, Solid-ALL FS 98 (25%-125%)

Carrier/Tracer Recovery Liquid Scint Fe55, Solid-ALL FS 75 (15%-125%)

Carrier/Tracer Recovery Liquid Scint Ni63, Solid-ALL FS 76 (25%-125%)

Carrier/Tracer Recovery Liquid Scint Tc99, Solid-ALL FS 74 (15%-125%)

Notes:

The Qualifiers in this report are defined as follows:

• A quality control analyte recovery is outside of specified acceptance criteria

< Result is less than value reported

> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.

Page 68 of 105

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: August 21, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0002-01 IF Project: YANKO 1204 Sample ID: 168404002 Client ID: YANK001 Matrix: SE Vol. Recv.:

Collect Date: 19-MAY-06 Receive Date: 02-JUN-06 Collector: Client Moisture: 17.4%

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Alpha Spec Analysis Alphaspec Am241, Cm, Solid ALL FSS Americium-241 U 0.120 +/-0.154 0.0683 +/-0.155 0.251 pCi/g BXLI 08/11/06 1336 555696 1 Curium-242 U -0.0146 +/-0.122 0.0692 +/-0.123 0.303 pCi/g Curium-243/244 U -0.0103 +/-0.0861 0.0487 +/-0.0862 0.213 pCi/g Alphaspec Pu, Solid-ALL FSS Plutonium-238 U 0.0121 +/-0.125 0.127 +/-0.125 0.344 pCi/g BXLI 08/11/06 1633 555697 2 Plutonium-239/240 U 0.0254 +/-0.0675 0.0381 +/-0.0675 0.167 pCi/g Liquid Scint Pu241, Solid-ALL FSS Plutonium-241 U 6.72 +/-7.02 5.56 +/-7.05 11.7 pCi/g BXLI 08/16/06 1237 555698 3 Rad Liquid Scintillation Analysis LSC, Tritium Dist, Solid-HTD2,ALL FSS Tritium U -0.521 +/-7.03 5.94 +/-7.03 12.8 pCi/g DFA1 08/09/06 1143 554582 4 Liquid Scint C14, SolidAllFSS Carbon-14 U 0.023 +/-0.0828 0.0685 +/-0.0828 0.143 pCi/g ATH2 08/09/06 0426 554583 5 Liquid Scint Fe55, Solid-ALL FSS Iron-55 U 3.93 +/-47.7 31.9 +/-47.7 65.7 pCi/g MXPI 08/12/06 1649 555722 6 Liquid Scint Ni63, Solid-ALL FSS Nickel-63 U 7.52 +/-5.81 4.68 +/-5.81 9.60 pCi/g MXPI 08/11/06 0825 555723 7 Liquid Scint Tc99, Solid-ALL FSS Technetium-99 U 0.173 +/-0.203 0.164 +/-0.203 0.341 pCi/g EGD1 08/11/06 2043 554580 8 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 08/03/06 1534 554649 The following Analytical Methods were performed Method Description 1 DOE EML HASL-300, Am-05-RC Modified 2 DOE EML HASL-300, Pu-I I-RC Modified 3 DOE EML HASL-300, Pu-I I-RC Modified 4 EPA 906.0 Modified 5 EPA EERF C-01 Modified Page 69 of 105

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: August 21, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0002-01IF Project: YANK01204 Sample ID: 168404002 Client ID: YANK001 Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd 6 DOE RESL Fe-I, Modified 7 DOE RESL Ni-I, Modified 8 DOE EML HASL-300, Tc-02-RC Modified Surrogate/Tracer recovery Test Recovery% Acceptable Limits Americium-243 Alphaspec Am241, Cm, Solid ALL 76 (15%-125%)

Plutonium-242 Alphaspec Pu, Solid-ALL FSS 100 (15%-125%)

Carrier/Tracer Recovery Liquid Scint Pu241, Solid-ALL FS 88 (25%-6125%)

Carrier/Tracer Recovery Liquid Scint Fe55, Solid-ALL FS 72 (15%-/125%)

Carrier/Tracer Recovery Liquid Scint Ni63, Solid-ALL FS 76 (25%-125%)

Carrier/Tracer Recovery Liquid Scint Tc99, Solid-ALL FS 79 (15/-,125%)

Notes:

The Qualifiers in this report are defined as follows:

• A quality control analyte recovery is outside of specified acceptance criteria

< Result is less than value reported

> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.

Page 70 of 105

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: August 21, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0003-004F Project: YANK01204 Sample ID: 168404003 Client ID: YANKOO Matrix: SE Vol. Recv.:

Collect Date: 25-APR-06 Receive Date: 05-MAY-06 Collector: Client Moisture: 23.5%

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Alpha Spec Analysis Alphaspec Am241, Cm, Solid ALL FSS Americium-241 U -0.027 +/-0.117 0.153 +/-0.117 0.488 pCi/g BXLI 08/13/06 0819 555696 1 Curium-242 U 0.112 +/-0.315 0.245 +1-0.315 0.781 pCi/g Curium-243/244 U 0.0217 +/-0.206 0.205 +/-0.206 0.594 pCi/g Alphaspec Pu, Solid-ALL FSS 0.176 Plutonium-238 U 0.061 +/-0.189 +/-0.189 0.449 pCi/g BXL1 08/11/06 1633 555697 2 Plutonium-239/240 U 0.0551 +/-0.103 0.0584 +/-0.103 0.215 pCi/g Liquid Scint Pu241, Solid-ALL FSS Plutonium-241 U 8.31 +/-5.73 4.40 +/-5.78 9.25 pCi/g BXLI 08/16/06 1253 555698 3 Rad Gas Flow Proportional Counting GFPC,Sr90, solid-ALL FSS Strontium-90 U -0.00343 +/-0.0203 0.0172 +/-0.0203 0.036 pCi/g BXFI 08/14/06 0834 556350 4 Rad Liquid Scintillation Analysis LSC, Tritium Dist, Solid HTD2,ALL FSS Tritium U 0.603 +/-8.25 6.87 +/-8.25 14.8 pCi/g DFAI 08/09/06 1159 554582 5 Liquid Scint C14, SolidAllFSS Carbon-14 U 0.0937 +/-0.0813 0.0642 +/-0.0813 0.134 pCi/g ATH2 08/09/06 0529 554583 6 Liquid Scint Fe55, Solid-ALL FSS Iron-55 U 7.68 +/-51.2 34.2 +/-51.2 70.4 pCi/g MXPI 08/12/06 1706 555722 7 Liquid Scint Ni63, Solid ALL FSS Nickel-63 U 5.74 +/-7.12 6.58 +/-7.13 13.6 pCi/g MXP1 08/11/06 0912 555723 8 Liquid Scint Tc99, Solid-ALL FSS Technetium-99 U -0.0643 +/-0.198 0.169 +/-0.198 0.351 pCi/g EGD1 08/11/06 2059 554580 9 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 08/03/06 1534 554649 The following Analytical Methods were performed Method Description 1 DOE EML HASL-300, Am-05-RC Modified 2 DOE EML HASL-300, Pu-l1 -RC Modified Page 71 of 105

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Cprtifir-tit nf Ann]vsie J-Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: August 21, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0003-004F Proiect: YANK01204 Sample ID: 168404003 Client ID: YANK001 Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd 3 DOE EML HASL-300, Pu-I 1-RC Modified 4 EPA 905.0 Modified 5 EPA 906.0 Modified 6 EPA EERF C-01 Modified 7 DOE RESL Fe-I, Modified 8 DOE RESL Ni-I, Modified 9 DOE EML HASL-300, Tc-02-RC Modified Surrogate/Tracer recovery Test Recovery% Acceptable Limits Americium-243 Alphaspec Am241, Cm, Solid ALl 42 (15%/o-125%)

Plutonium-242 Alphaspec Pu, Solid-ALL FSS 92 (15%-125%)

Carrier/Tracer Recovery Liquid Scint Pu241, Solid-ALL FS 113 (25%-/125%)

Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 59 (25%-125%)

Carrier/Tracer Recovery Liquid Scint Fe55, Solid-ALL FS 71 (15%-125%)

Carrier/Tracer Recovery Liquid Scint Ni63, Solid-ALL FS 83 (25%-.125%)

Carrier/Tracer Recovery Liquid Scint Tc99, Solid-ALL FS 76 (15%-125%)

Notes:

The Qualifiers in this report are defined as follows

• A quality control analyte recovery is outside of specified acceptance criteria

< Result is less than value reported

> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

U! Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded Page 72 of 105

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: August 21, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0003-004F Project: YANKO 1204 Sample ID: 168404003 Client ID: YANKOO Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd The above sample is reported on a dry weight basis.

Page 73 of 105

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: August 21, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0003-015F Project: YANK01204 Sample ID: 168404004 Client ID: YANK001 Matrix: SE Vol. Recv.:

Collect Date: 25-APR-06 Receive Date: 05-MAY-06 Collector: Client Moisture: 22.5%

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Alpha Spec Analysis Alphaspec Am241, Cm, Solid ALL FSS Americium-241 U 0.0456 +1-0.155 0.139 +/-0.155 0.387 pCi/g BXLI 08/11/06 1434 555696 1 Curium-242 U 0.113 +/-0.181 0.0733 +/-0.182 0.321 pCi/g Curium-243/244 U 0.180 +/-0.239 0.181 +/-0.240 0.472 pCi/g Alphaspec Pu, Solid-ALL FSS 0.118 Plutonium-238 U 0.0196 +/-0.121 +/-0.121 0.324 pCi/g BXL1 08/11/06 1633 555697 2 Plutonium-239/240 U 0.0326 +/-0.0639 0.00 +/-0.064 0.0884 pCi/g Liquid Scint Pu241, Solid-ALL FSS Plutonium-241 U 6.63 +/-6.19 4.86 +/-6.22 10.2 pCi/g BXLI 08/16/06 1309 555698 3 Rad Gas Flow Proportional Counting GFPC,Sr90, solid-ALL FSS Strontium-90 U 0.00477 +/-0.0216 0.0179 +/-0.0216 0.0375 pCi/g BXF1 08/14/06 0834 556350 4 Rad Liquid Scintillation Analysis LSC, Tritium Dist, Solid-HTD2,ALL FSS Tritium U 1.03 +/-7.06 5.85 +/-7.06 12.6 pCi/g DFA1 08/09/06 1215 554582 5 Liquid Scint C14, SolidAllFSS Carbon-14 0.156 +/-0.0912 0.0699 +/-0.0913 0.146 pCi/g ATH2 08/09/06 0632 554583 6 Liquid Scint Fe55, Solid-ALL FSS Iron-55 U -9.99 +/-42.7 28.7 +/-42.7 59.2 pCi/g MXP I 08/12/06 1722 555722 7 Liquid Scint Ni63, Solid-ALL FSS Nickel-63 U 0.939 +/-10.1 10.3 +/-10.1 21.6 pCi/g MXPI 08/11/06 1001 555723 8 Liquid Scint Tc99, Solid-ALL FSS Technetium-99 U 0.237 +/-0.213 0.170 +/-0.213 0.353 pCi/g EGDI 08/11/06 2115 554580 9 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 08/03/06 1534 554649 The following Analytical Methods were performed Method Description I DOE EML HASL-300, Am-05-RC Modified 2 DOE EML HASL-300, Pu-I I-RC Modified Page 74 of 105

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: August 21, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0003-015F Project: YANKO 1204 Sample ID: 168404004 Client ID: YANKOO Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd 3 DOE EML HASL-300, Pu-I 1-RC Modified 4 EPA 905.0 Modified 5 EPA 906.0 Modified 6 EPA EERF C-01 Modified 7 DOE RESL Fe-I, Modified 8 DOE RESL Ni-I, Modified 9 DOE EML HASL-300, Tc-02-RC Modified Surrogate/Tracer recovery Recovery% Acceptable Limits Americium-243 Alphaspec Am241, Cm, Solid ALL 78 (15%-I125%)

Plutonium-242 Alphaspec Pu, Solid-ALL FSS 94 (15%-125%)

Carrier/Tracer Recovery Liquid Scint Pu241, Solid-ALL Fý 101 (25%-125%)

Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 58 (25%-I125%)

Carrier/Tracer Recovery Liquid Scint Fe55, Solid-ALL FS 75 (15%-125%)

Carrier/Tracer Recovery Liquid Scint Ni63, Solid-ALL FS 62 (25%- 125%o)

Carrier/Tracer Recovery Liquid Scint Tc99, Solid-ALL FS 75 (15%-125%)

Notes:

The Qualifiers in this report are defined as follows

• A quality control analyte recovery is outside of specified acceptance criteria

< Result is less than value reported

> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding.time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded Page 75 of 105

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: August 21, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0003-015F Project: YANKO 1204 Sample ID: 168404004 Client ID: YANK001 Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd The above sample is reported on a dry weight basis.

Page 76 of 105

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.corn Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: August 21, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0004-005F Project: YANKO 1204 Sample ID: 168404005 Client ID: YANKOO Matrix: SE Vol. Recv.:

Collect Date: 03-MAY-06 Receive Date: 12-MAY-06 Collector: Client Moisture: 15.4%

Parameter Qualifier R esult Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Alpha Spec Analysis Alphaspec Am241, Cm, Solid ALL FSS Americium-241 U -( 0.036 +/-0.123 0.157 +/-0.123 0.437 pCi/g BXLI 08/11/06 1434 555696 1 Curium-242 U -0. 0169 +/-0.033 0.080 +/-0.0331 0.350 pCi/g Curium-243/244 U -0. 0129 +/-0.227 0.247 +/-0.227 0.619 pCi/g Alphaspec Pu, Solid-ALL FSS Plutonium-238 U -0. 0217 +/-0.163 0.181 +/-0.163 0.444 pCi/g BXLI 08/11/06 1633 555697 2 Plutonium-239/240 U -0. 0708 +/-0.0791 0.128 +/-0.0795 0.337 pCi/g Liquid Scint Pu241, Solid-ALL FSS Plutonium-241 U 9.52 +/-6.00 4.57 +/-6.07 9.61 pCi/g BXLI 08/16/06 1326 555698 3 Rad Liquid Scintillation Analysis LSC, Tritium Dist, Solid-HTD2,ALL FSS Tritium U ().854 +/-5.88 4.87 +/-5.88 10.5 pCi/g DFAI 08/09/06 1231 554582 4 Liquid Scint C14, Solid All,FSS Carbon-14 (1.347 +/-0.097 0.0674 +/-0.0972 0.141 pCi/g ATH2 08/09/06 0734 554583 5 Liquid Scint Fe55, Solid-ALL FSS Iron-55 U - -1.57 +/-46.0 30.7 +/-46.0 63.2 pCi/g MXPI 08/12/06 1738 555722 6 Liquid Scint Ni63, Solid-ALL FSS Nickel-63 U 6.39 +/-7.62 7.40 +/-7.62 15.5 pCi/g MXPI 08/11/06 1017 555723 7 Liquid Scint Tc99, Solid-ALL FSS Technetium-99 U 0.0198 +/-0.187 0.156 +/-0.187 0.324 pCi/g EGDI 08/11/06 2131 554580 8 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 08/03/06 1534 554649 The following Analytical Methods were performed Method Description I DOE EML HASL-300, Am-05-RC Modified 2 DOE EML HASL-300, Pu-I I-RC Modified 3 DOE EML HASL-300, Pu-I I-RC Modified 4 EPA 906.0 Modified 5 EPA EERF C-01 Modified Page 77 of 105

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: August 21, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0004-005F Project: YANK01204 Sample ID: 168404005 Client ID: YANK001 Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd 6 DOE RESL Fe-I, Modified 7 DOE RESL Ni-I, Modified 8 DOE EML HASL-300, Tc-02-RC Modified Surrogate/Tracer recovery Test Recovery% Acceptable Limits Americium-243 Alphaspec Am241, Cm, Solid ALL 65 (15%-/125%)

Plutonium-242 Alphaspec Pu, Solid-ALL FSS 95 (15%-125%)

Carrier/Tracer Recovery Liquid Scint Pu241, Solid-ALL Fý 105 (25%-125%)

Carrier/Tracer Recovery Liquid Scint Fe55, Solid-ALL FS 78 (15%-125%)

Carrier/Tracer Recovery Liquid Scint Ni63, Solid-ALL FS 80 (25%-125%)

Carrier/Tracer Recovery Liquid Scint Tc99, Solid-ALL FS 80 (15%- 125%)

Notes:

The Qualifiers in this report are defined as follows:

• A quality control analyte recovery is outside of specified acceptance criteria

< Result is less than value reported

> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.

Page 78 of 105

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: August 21, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0004-015F Proiect: YANK01204 Sample ID: 168404006 Client ID: YANK001 Matrix: SE Vol. Recv.:

Collect Date: 03-MAY-06 Receive Date: 12-MAY-06 Collector: Client Moisture: 26.5%

Parameter Qualifier Resuit Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Alpha Spec Analysis Alphaspec Am241, Cm, Solid ALL FSS Americium-241 U 0.( 0823 +/-0.203 0.178 +/-0.203 0.469 pCi/g BXLI 08/11/06 1434 555696 1 Curium-242 U -0.( 0154 +/-0.0301 0.0729 +/-0.0302 0.319 pCi/g Curium-243/244 U -0.( )994 +/-0.251 0.300 +/-0.251 0.713 pCi/g Alphaspec Pu, Solid-ALL FSS Plutonium-238 U 0.( 1466 +/-0.213 0.210 +/-0.213 0.521 pCi/g BXLI 08/11/06 1633 555697 2 Plutonium-239/240 U -0 .142 +/-0.108 0.191 +/-0.109 0.483 pCi/g Liquid Scint Pu24l, Solid-ALL FSS Plutonium-241 U 6.64 +/-6.53 5.16 +/-6.57 10.8 pCi/g BXL1 08/16/06 1342 555698 3 Rad Liquid Scintillation Analysis LSC, Tritium Dist, Solid-HTD2,ALL FSS Tritium U -2.9 +/-7.59 6.60 +/-7.59 14.2 pCi/g DFAI 08/09/06 1247 554582 4 Liquid Scint C14, SolidAllFSS Carbon- 14 U 0.01352 +/-0.0868 0.0713 +/-0.0868 0.149 pCi/g ATH2 08/09/06 0837 554583 5 Liquid Scint Fe55, Solid-ALL FSS Iron-55 U 1.88 +/-46.8 31.3 +/-46.8 64.4 pCi/g MXP I 08/12/06 1754 555722 6 Liquid Scint Ni63, Solid-ALL FSS Nickel-63 U 3.88 +/-7.46 7.40 +/-7.46 15.5 pCi/g MXPI 08/11/06 1033 555723 7 Liquid Scint Tc99, Solid-ALL FSS Technetium-99 U 0.01894 +/-0.198 0.163 +/-0.198 0.338 pCi/g EGD I 08/11/06 2147 554580 8 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 08/03/06 1534 554649 The following Analytical Methods were performed Method Description I DOE EML HASL-300, Am-05-RC Modified 2 DOE EML HASL-300, Pu-l l-RC Modified 3 DOE EML HASL-300, Pu-I 1-RC Modified 4 EPA 906.0 Modified 5 EPA EERF C-01 Modified Page 79 of 105

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: August 21, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0004-015F Project: YANK01204 Sample ID: 168404006 Client ID: YANKOO Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd 6 DOE RESL Fe-I, Modified 7 DOE RESL Ni-I, Modified 8 DOE EML HASL-300, Tc-02-RC Modified Surrogate/Tracer recovery Recovery% Acceptable Limits Americium-243 Alphaspec Am241, Cm, Solid ALL 72 (15%-125%)

Plutonium-242 Alphaspec Pu, Solid-ALL FSS 72 (15%/-125%)

Carrier/Tracer Recovery Liquid Scint Pu241, Solid-ALL FS 94 (25%-6125%)

Carrier/Tracer Recovery Liquid Scint Fe55, Solid-ALL FS 73 (15%-125%)

Carrier/Tracer Recovery Liquid Scint Ni63, Solid-ALL FS 80 (25%-125%)

Carrier/Tracer Recovery Liquid Scint Tc99, Solid-ALL FS 78 (15%-125%)

Notes:

The Qualifiers in this report are defined as follows

• A quality control analyte recovery is outside of specified acceptance criteria

< Result is less than value reported

> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.

Page 80 of 105

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: August 21, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0005-01OF Project: YANKO 1204 Sample ID: 168404007 Client ID: YANKOO Matrix: SE Vol. Recv.:

Collect Date: 02-MAY-06 Receive Date: 09-MAY-06 Collector: Client Moisture: 56.2%

Parameter Qualifier R esult Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Alpha Spec Analysis Alphaspec Am241, Cm, Solid ALL FSS Americium-241 U -( 0.128 +/-0.0939 0.142 +/-0.0942 0.385 pCi/g BXL1 08/11/06 1434 555696 1 Curium-242 U -0. 0115 +/-0.128 0.147 +/-0.128 0.450 pCi/g Curium-243/244 U -0. 0333 +/-0.122 0.149 +/-0.122 0.401 pCi/g Alphaspec Pu, Solid-ALL FSS Plutonium-238 U 0. 0548 +/-0.169 0.158 +/-0.170 0.403 pCi/g BXLI 08/11/06 1633 555697 2 Plutonium-239/240 U 0.0195 +/-0.121 0.117 +/-0.121 0.322 pCi/g Liquid Scint Pu241, Solid-ALL FSS Plutonium-241 U 10.4 +/-6.89 5.27 +/-6.97 11.1 pCi/g BXL1 08/16/06 1358 555698 3 Rad Liquid Scintillation Analysis LSC, Tritium Dist, Solid-HTD2,ALL FSS Tritium U 0.00 +/-6.86 5.76 +/-6.86 12.4 pCi/g DFAI 08/09/06 1303 554582 4 Liquid Scint C14, SolidAllFSS Carbon-14 U 0. 0636 +/-0.0801 0.0644 +/-0.0801 0.135 pCi/g ATH2 08/09/06 1017 554583 5 Liquid Scint Fe55, Solid-ALL FSS Iron-55 U 36.1 +/-44.1 28.7 +/-44.1 59.0 pCi/g MXPI 08/12/06 1811 555722 6 Liquid Scint Ni63, Solid-ALL FSS Nickel-63 U 7.26 +/-10.2 10.0 +/-10.2 20.9 pCi/g MXPI 08/11/06 1049 555723 7 Liquid Scint Tc99, Solid-ALL FSS Technetium-99 U - -0.05 +/-0.199 0.169 +/-0.199 0.351 pCi/g EGD1 08/11/06 2203 554580 8 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 08/03/06 1534 554649 The following Analytical Methods were performed Method Description I DOE EML HASL-300, Am-05-RC Modified 2 DOE EML HASL-300, Pu-I I-RC Modified 3 DOE EML HASL-300, Pu-I I-RC Modified 4 EPA 906.0 Modified 5 EPA EERF C-01 Modified Page 81 of 105

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: August 21, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0005-010F Project: YANKO 1204 Sample ID: 168404007 Client ID: YANKOO Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd 6 DOE RESL Fe-I, Modified 7 DOE RESL Ni-I, Modified 8 DOE EML HASL-300, Tc-02-RC Modified Surrogate/Tracer recovery Recovery% Acceptable Limits Americium-243 Alphaspec Am241, Cm, Solid ALL 85 (15%-125%)

Plutonium-242 Alphaspec Pu, Solid-ALL FSS 91 (.15%-125%)

Carrier/Tracer Recovery Liquid Scint Pu241, Solid-ALL FS 92 (25%-125%)

Carrier/Tracer Recovery Liquid Scint Fe55, Solid-ALL FS 81 (15%-125%)

Carrier/Tracer Recovery Liquid Scint Ni63, Solid-ALL FS 64 (25%- 125%)

Carrier/Tracer Recovery Liquid Scint Tc99, Solid-ALL FS 77 (15%-125%)

Notes:

The Qualifiers in this report are defined as follows:

• A quality control analyte recovery is outside of specified acceptance criteria

< Result is less than value reported

> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.

Page 82 of 105

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: August 21, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0005-014F Proiect: YANKO 1204 Sample ID: 168404008 Client ID: YANK001 Matrix: SE Vol. Recv.:

Collect Date: 02-MAY-06 Receive Date: 09-MAY-06 Collector: Client Moisture: 32.3%

Parameter Qualifier R esult Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Alpha Spec Analysis Alphaspec Am241, Cm, Solid ALL FSS Americium-241 U 0.0 0591 +/-0.219 0.231 +/-0.219 0.608 pCi/g BXLI 08/11/06 1434 555696 1 Curium-242 U --0.04 +1-0.0554 0.134 +/-0.0557 0.494 pCi/g Curium-243/244 U 0. 0634 +/-0.261 0.249 +/-0.261 0.646 pCi/g Alphaspec Pu, Solid-ALL FSS Plutonium-238 U -0. 0694 +/-0.106 0.160 +/-0.106 0.434 pCi/g BXL1 08/11/06 1633 555697 2 Plutonium-239/240 U -0. 0287 +/-0.098 0.127 +/-0.0981 0.369 pCi/g Liquid Scint Pu241, Solid-ALL FSS Plutonium-241 U 4.68 +/-8.01 6.48 +/-8.02 13.6 pCi/g BXLI 08/16/06 1415 555698 3 Rad Liquid Scintillation Analysis LSC, Tritium Dist, Solid-HTD2,ALL FSS Tritium U 6.02 +/-6.38 4.90 +/-6.38 10.6 pCi/g DFAI 08/09/06 1319 554582 4 Liquid Scint C14, SolidAllFSS Carbon-14 U 0.0892 +/-0.0827 0.0655 +/-0.0827 0.137 pCi/g ATH2 08/09/06 1424 554583 5 Liquid Scint Fe55, Solid-ALL FSS lron-55 U 19.8 +/-46.3 30.6 +/-46.3 62.9 pCi/g MXPI 08/12/06 1827 555722 6 Liquid Scint Ni63, Solid-ALL FSS Nickel-63 U 5.41 +/-7.91 7.77 +/-7.91 16.2 pCi/g MXPI 08/11/06 1106 555723 7 Liquid Scint Tc99, Solid-ALL FSS Technetium-99 U -( ).134 +/-0.192 0.167 +/-0.192 0.346 pCi/g EGD1 08/11/06 2218 554580 8 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 08/03/06 1534 554649 The following Analytical Methods were performed Method Description I DOE EML HASL-300, Am-05-RC Modified 2 DOE EML HASL-300, Pu- I -RC Modified 3 DOE EML HASL-300, Pu-I I-RC Modified 4 EPA 906.0 Modified 5 EPA EERF C-01 Modified Page 83 of 105

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: August 21, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0005-014F Project: YANKO 1204 Sample ID: 168404008 Client ID: YANKOO Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd 6 DOE RESL Fe-I, Modified 7 DOE RESL Ni-I, Modified 8 DOE EML HASL-300, Tc-02-RC Modified Surrogate/Tracer recovery Recovery% Acceptable Limits Americium-243 Alphaspec Am241, Cm, Solid ALL 50 (15%-125%)

Plutonium-242 Alphaspec Pu, Solid-ALL FSS 61 (15%-125%)

Carrier/Tracer Recovery Liquid Scint Pu241, Solid-ALL FS 74 (25%-I125%)

Carrier/Tracer Recovery Liquid Scint Fe55, Solid-ALL FS 76 (15%-125%)

Carrier/Tracer Recovery Liquid Scint Ni63, Solid-ALL FS 76 (25%--125%)

Carrier/Tracer Recovery Liquid Scint Tc99, Solid-ALL FS 75 (15%-1125%)

Notes:

The Qualifiers in this report are defined as follows

• A quality control analyte recovery is outside of specified acceptance criteria

< Result is less than value reported

> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.

Page 84 of 105

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.corn Certificate of Analysis Company : Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: August 21, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0006-005F Project: YANK01204 Sample ID: 168404009 Client ID: YANKOOI Matrix: SE Vol. Recv.:

Collect Date: 28-APR-06 Receive Date: 12-MAY-06 Collector: Client Moisture: 16.5%

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Alpha Spec Analysis Alphaspec Am241, Cm, Solid ALL FSS Americium-241 U -0.0851 +/-0.136 0.106 +/-0.136 0.390 pCi/g BXLI 08/16/06 0949 557837 1 Curium-242 U -0.0253 +/-0.0495 0.120 +/-0.0496 0.525 pCi/g Curium-243/244 U -0.0479 +/-0.0542 0.131 +/-0.0545 0.443 pCi/g Alphaspec Pu, Solid-ALL FSS Plutonium-238 U 0.0183 +/-0.113 0.110 +/-0.113 0.303 pCi/g BXLI 08/11/06 1633 555697 3 Plutonium-239/240 U 0.00122 +/-0.0662 0.0694 +/-0.0662 0.221 pCi/g Liquid Scint Pu241, Solid-ALL FSS Plutonium-241 U 4.43 +/-5.83 4.67 +/-5.85 9.82 pCi/g BXLI 08/16/06 1431 555698 4 Rad Liquid Scintillation Analysis LSC, Tritium Dist, Solid-HTD2,ALL FSS Tritium U -2.02 +/-6.67 5.76 +/-6.67 12.4 pCi/g DFAI 08/09/06 1335 554582 5 Liquid Scint C14, SolidAllFSS Carbon- 14 0.142 +/-0.0798 0.061 +/-0.0799 0.127 pCi/g ATH2 08/09/06 1719 554583 6 Liquid Scint Fe55, Solid-ALL FSS Iron-55 U 12.6 +/-47.6 31.7 +/-47.6 65.3 pCi/g MXPI 08/12/06 1843 555722 7 Liquid Scint Ni63, Solid-ALL FSS Nickel-63 U 7.70 +/-9.56 9.31 +/-9.56 19.5 pCi/g MXPI 08/11/06 1122 555723 8 Liquid Scint Tc99, Solid-ALL FSS Technetium-99 U -0.00659 +/-0.185 0.156 +/-0.185 0.323 pCi/g EGD1 08/11/06 2234 554580 9 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 08/03/06 1534 554649 The following Analytical Methods were performed Method Description I DOE EML HASL-300, Am-05-RC Modified 2 DOE EML HASL-300, Am-05-RC Modified 3 DOE EML HASL-300, Pu-I I-RC Modified 4 DOE EML HASL-300, Pu-I I-RC Modified 5 EPA 906.0 Modified Page 85 of 105

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: August 21, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0006-005F Project: YANK0 1204 Sample ID: 168404009 Client ID: YANKOO Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd 6 EPA EERF C-01 Modified 7 DOE RESL Fe-I, Modified 8 DOE RESL Ni-1, Modified 9 DOE EML HASL-300, Tc-02-RC Modified Surrogate/Tracer recovery Recovery% Acceptable Limits Americium-243 Alphaspec Am241, Cm, Solid ALL 76 (15%-125%)

Plutonium-242 Alphaspec Pu, Solid-ALL FSS 93 (15%-125%)

Carrier/Tracer Recovery Liquid Scint Pu241, Solid-ALL Fý 105 (25%-125%)

Carrier/Tracer Recovery Liquid Scint Fe55, Solid-ALL FS 72 (15%-t125%)

Carrier/Tracer Recovery Liquid Scint Ni63, Solid-ALL FS 64 (25%/.-125%)

Carrier/Tracer Recovery Liquid Scint Tc99, Solid-ALL FS 81 (15%-125%)

Notes:

The Qualifiers in this report are defined as follows

• A quality control analyte recovery is outside of specified acceptance criteria

< Result is less than value reported

> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.

Page 86 of 105

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.corn Certificate of Analysis Company : Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: August 21, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0008-006F Proiect: YANK01204 Sample ID: 168404010 Client ID: YANK001 Matrix: SE Vol. Recv.:

Collect Date: 05-MAY-06 Receive Date: 26-MAY-06 Collector: Client Moisture: 34.8%

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Alpha Spec Analysis Alphaspec Am241, Cm, Solid ALL FSS Americium-241 U 0.129 +/-0.195 0.0758 +/-0.196 0.332 pCi/g BXL1 08/16/06 0949 557837 1 Curium-242 U 0.103 +/-0.202 0.00 +/-0.203 0.280 pCi/g Curium-243/244 U -0.0161 +/-0.0316 0.0766 +/-0.0317 0.335 pCi/g Alphaspec Pu, Solid-ALL FSS Plutonium-238 U -0.0276 +/-0.0711 0.0967 +/-0.0712 0.275 pCi/g BXLI 08/11/06 1633 555697 3 Plutonium-239/240 U 0.00359 +/-0.113 0.118 +/-0.113 0.317 pCi/g Liquid Scint Pu241, Solid-ALL FSS Plutonium-241 14.9 +/-6.37 4.64 +/-6.51 9.75 pCi/g BXLI 08/16/06 1447 555698 4 Rad Liquid Scintillation Analysis LSC, Tritium Dist, Solid-HTD2,ALL FSS Tritium U 0.00 +/-6.06 5.09 +/-6.06 10.7 pCi/g DFAI 08/10/06 2150 554582 5 Liquid Scint C14, SolidAlFSS Carbon-14 U 0.107 +/-0.0846 0.0664 +/-0.0846 0.139 pCi/g ATH2 08/09/06 1822 554583 6 Liquid Scint Fe55, Solid-ALL FSS Iron-55 U 15.1 +/-41.4 27.5 +/-41.4 56.6 pCi/g MXPI 08/12/06 1900 555722 7 Liquid Scint Tc99, Solid-ALL FSS Technetium-99 U 0.258 +/-0.225 0.179 +/-0.225 0.373 pCi/g EGDI 08/11/06 2251 554580 8 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 08/03/06 1534 554649 The following Analytical Methods were performed Method Description 1 DOE EML HASL-300, Am-05-RC Modified 2 DOE EML HASL-300, Am-05-RC Modified 3 DOE EML HASL-300, Pu-I I-RC Modified 4 DOE EML HASL-300, Pu-I 1-RC Modified 5 EPA 906.0 Modified 6 EPA EERF C-01 Modified 7 DOE RESL Fe-I, Modified Page 87 of 105

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel com Certificate of Analysis Company : Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: August 21, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0008-006F Project: YANK01204 Sample ID: 168404010 Client ID: YANK001 Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd 8 DOE EML HASL-300, Tc-02-RC Modified Surrogate/Tracer recovery Recovery% Acceptable Limits Americium-243 Alphaspec Am241, Cm, Solid ALL 77 (15%-1I25%)

Plutonium-242 Alphaspec Pu, Solid-ALL FSS 94 (15°/7-125%)

Carrier/Tracer Recovery Liquid Scint Pu241, Solid-ALL FS 103 (25%-125%)

Carrier/Tracer Recovery Liquid Scint Fe55, Solid-ALL FS 72 (15%-125%)

Carrier/Tracer Recovery Liquid Scint Tc99, Solid-ALL FS 71 (15%-/125%)

Notes:

The Qualifiers in this report are defined as follows

• A quality control analyte recovery is outside of specified acceptance criteria

< Result is less than value reported

> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.

Page 88 of 105

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: August 21, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0008-008F Project: YANK01204 Sample ID: 168404011 Client ID: YANKOO0 Matrix: SE Vol. Recv.:

Collect Date: 08-MAY-06 Receive Date: 26-MAY-06 Collector: Client Moisture: 35.7%

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Alpha Spec Analysis Alphaspec Am241, Cm, Solid ALL FSS Americium-241 U 0.0969 +/-0.192 0.152 +/-0.193 0.426 pCi/g BXLI 08/11/06 1434 555696 1 Curium-242 U -0.0482 +/-0.142 0.132 +/-0.142 0.446 pCi/g Curium-243/244 U -0.0576 +/-0.202 0.240 +/-0.203 0.603 pCi/g Alphaspec Pu, Solid-ALL FSS Plutonium-238 U -0.0397 +/-0.096 0.125 +/-0.096 0.328 pCi/g BXLI 08/11/06 1633 555697 2 Plutonium-239/240 U -0.0315 +/-0.114 0.137 +/-0.114 0.353 pCi/g Liquid Scint Pu241, Solid-ALL FSS Plutonium-241 11.5 +/-6.72 5.08 +/-6.80 10.7 pCi/g BXLI 08/16/06 1504 555698 3 Rad Liquid Scintillation Analysis LSC, Tritium Dist, Solid-HTD2,ALL FSS Tritium U 0.00 +/-5.92 4.97 +/-5.92 10.7 pCi/g DFAI 08/09/06 1407 554582 4 Liquid Scint C14, SolidAllFSS Carbon-14 U -0.0238 +/-0.0745 0.0636 +/-0.0745 0.133 pCi/g ATH2 08/09/06 1924 554583 5 Liquid Scint Fe55, Solid-ALL FSS lron-55 U -10.7 +/-40.9 27.5 +/-40.9 56.8 pCi/g MXPI 08/12/06 1916 555722 6 Liquid Scint Tc99, Solid-ALL FSS Technetium-99 U 0.0956 +/-0.211 0.174 +/-0.211 0.361 pCi/g EGDI 08/11/06 2307 554580 7 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 08/03/06 1534 554649 The following Analytical Methods were performed Method Description 1 DOE EML HASL-300, Am-05-RC Modified 2 DOE EML HASL-300, Pu-1 I-RC Modified 3 DOE EML HASL-300, Pu-I I-RC Modified 4 EPA 906.0 Modified 5 EPA EERF C-01 Modified 6 DOE RESL Fe-I, Modified Page 89 of 105

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: August 21, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0008-008F Project: YANK01204 Sample ID: 168404011 Client ID: YANKOO I Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd 7 DOE EML HASL-300, Tc-02-RC Modified Surrogate/Tracer recovery Recovery% Acceptable Limits Americium-243 Alphaspec Am241, Cm, Solid ALL 65 (15%-I125%)

Plutonium-242 Alphaspec Pu, Solid-ALL FSS 98 (15%-125%)

Carrier/Tracer Recovery Liquid Scint Pu241, Solid-ALL FS 96 (25%-125%)

Carrier/Tracer Recovery Liquid Scint Fe55, Solid-ALL FS 76 (15%-.125%)

Carrier/Tracer Recovery Liquid Scint Tc99, Solid-ALL FS 74 (15%-125%)

Notes:

The Qualifiers in this report are defined as follows:

• A quality control analyte recovery is outside of specified acceptance criteria

< Result is less than value reported

> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.

Page 90 of 105

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company : Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: August 21, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0009-002F Project: YANKO 1204 Sample ID: 168404012 Client ID: YANK001 Matrix: SE Vol. Recv.:

Collect Date: 11-MAY-06 Receive Date: 08-JUN-06 Collector: Client Moisture: 33%

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Alpha Spec Analysis Alphaspec Am241, Cm, Solid ALL FSS Americium-241 U -0.00144 +1-0.155 0.166 +/-0.155 0.458 pCi/g BXLI 08/11/06 1434 555696 1 Curium-242 U 0.0192 +/-0.145 0.135 +/-0.145 0.455 pCi/g Curium-243/244 U 0.013 +/-0.268 0.281 +/-0.268 0.687 pCi/g Alphaspec Pu, Solid-ALL FSS Plutonium-238 U -0.00587 +/-0.0493 0.0279 +/-0.0494 0.122 pCi/g BXL1 08/11/06 1632 555697 2 Plutonium-239/240 U 0.0186 +/-0.0492 0.0278 +/-0.0493 0.122 pCi/g Liquid Scint Pu241, Solid-ALL FSS Plutonium-241 13.6 +/-6.90 5.13 +/-7.01 10.8 pCi/g BXLI 08/16/06 1520 555698 3 Rad Gas Flow Proportional Counting GFPC, Sr90, solid-ALL FSS Strontium-90 U 0.0151 +/-0.0146 0.0114 +/-0.0146 0.0242 pCi/g BXFI 08/14/06 0834 556350 4 Rad Liquid Scintillation Analysis LSC, Tritium Dist, Solid-HTD2,ALL FSS Tritium U 4.12 +/-8.36 6.70 +/-8.36 14.5 pCi/g DFAI 08/09/06 1422 554582 5 Liquid Scint C14, Solid Al1,FSS Carbon- 14 U 0.046 +/-0.0755 0.0613 +/-0.0755 0.128 pCi/g ATH2 08/09/06 2027 554583 6 LiquidScint Fe55, Solid-ALL FSS Iron-55 U 12.9 +/-40.6 26.8 +/-40.6 55.2 pCi/g MXPI 08/12/06 1932 555722 7 Liquid Scint Tc99, Solid-ALL FSS Technetium-99 U 0.078 +/-0.203 0.168 +/-0.203 0.348 pCi/g EGDI 08/11/06 2323 554580 8 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 08/03/06 1534 554649 The following Analytical Methods were performed Method Description I DOE EML HASL-300, Am-05-RC Modified 2 DOE EML HASL-300, Pu-I 1-RC Modified 3 DOE EML HASL-300, Pu- 11-RC Modified 4 EPA 905.0 Modified Page 91 of 105

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: August 21, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0009-002F Project: YANK0 1204 Sample ID: 168404012 Client ID: YANK001 Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd 5 EPA 906.0 Modified 6 EPA EERF C-01 Modified 7 DOE RESL Fe-I, Modified 8 DOE EML HASL-300, Tc-02-RC Modified Surrogate/Tracer recovery Recovery% Acceptable Limits Americium-243 Alphaspec Am241, Cm, Solid ALL 61 (15%-125%)

Plutonium-242 Alphaspec Pu, Solid-ALL FSS 98 (15%-125%)

Carrier/Tracer Recovery Liquid Scint Pu241, Solid-ALL FS 94 (25%-/125%)

Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 69 (25%-/125%)

Carrier/Tracer Recovery Liquid Scint Fe55, Solid-ALL FS 81 (15%-125%)

Carrier/Tracer Recovery Liquid Scint Tc99, Solid-ALL FS 75 (15%-125%)

Notes:

The Qualifiers in this report are defined as follows:

• A quality control analyte recovery is outside of specified acceptance criteria

< Result is less than value reported

> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.

Page 92 of 105

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: August 21, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0009-017F Project: YANKO 1204 Sample ID: 168404013 Client ID: YANK001 Matrix: SE Vol. Recv.:

Collect Date: 15-MAY-06 Receive Date: 08-JUN-06 Collector: Client Moisture: 28.4%

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Alpha Spec Analysis Alphaspec Am241, Cm, Solid ALL FSS Americium-241 U 0.0755 +/-0.242 0.230 +/-0.243 0.574 pCi/g BXL1 08/11/06 1434 555696 1 Curium-242 U 0.0957 +/-0.220 0.171 +/-0.220 0.509 pCi/g Curium-243/244 U -0.073 +/-0.214 0.256 +/-0.214 0.627 pCi/g Alphaspec Pu, Solid-ALL FSS Plutonium-238 U - 0.00629 +/-0.0529 0.0299 +/-0.0529 0.131 pCi/g BXL1 08/11/06 1632 555697 2 Plutonium-239/240 U 0.0262 +/-0.0513 0.00 +/-0.0514 0.0709 pCi/g Liquid Scint Pu241, Solid-ALL FSS Plutonium-241 13.3 +/-6.66 4.95 +/-6.77 10.4 pCi/g BXLI 08/16/06 1536 555698 3 Rad Gas Flow Proportional Counting GFPC,Sr90, solid-ALL FSS Strontium-90 U 0.0205 +/-0.0151 0.0116 +1-0.0151 0.0246 pCi/g BXFI 08/14/06 0833 556350 4 Rad Liquid Scintillation Analysis LSC, Tritium Dist, Solid-HTD2,ALL FSS Tritium U 0.583 +/-7.98 6.65 +/-7.98 14.4 pCi/g DFAI 08/09/06 1438 554582 5 Liquid Scint C14, SolidAllFSS Carbon-14 U 0.0271 +/-0.0759 0.0625 +/-0.0759 0.131 pCi/g ATH2 08/09/06 2129 554583 6 Liquid Scint Fe55, Solid-ALL FSS Iron-55 U -61.9 +1-150 102 +/-150 210 pCi/g MXPI 08/12/06 1949 555722 7 Liquid Scint Tc99, Solid-ALL FSS Technetium-99 U 0.0628 +/-0.200 0.165 +/-0.200 0.343 pCi/g EGDI 08/11/06 2338 554580 8 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 08/03/06 1534 554649 The following Analytical Methods were performed Method Description I DOE EML HASL-300, Am-05-RC Modified 2 DOE EML HASL-300, Pu- 11-RC Modified 3 DOE EML HASL-300, Pu-l I-RC Modified 4 EPA 905.0 Modified Page 93 of 105

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: August 21, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0009-017F Project: YANKO1204 Sample ID: 168404013 Client ID: YANKOOI Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd 5 EPA 906.0 Modified 6 EPA EERF C-01 Modified 7 DOE RESL Fe-I, Modified 8 DOE EML HASL-300, Tc-02-RC Modified Surrogate/Tracer recovery Test Recovery% Acceptable Limits Americium-243 Alphaspec Am241, Cm, Solid ALL 64 (15°/-125%)

Plutonium-242 Alphaspec Pu, Solid-ALL FSS 91 (15%-/125%)

Carrier/Tracer Recovery Liquid Scint Pu241, Solid-ALL FS 96 (25%-0125%)

Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 72 (25%-125%)

Carrier/Tracer Recovery Liquid Scint Fe55, Solid-ALL FS 73 (15%-125%)

Carrier/Tracer Recovery Liquid Scint Tc99, Solid-ALL FS 79 (15%-125%)

Notes:

The Qualifiers in this report are defined as follows:

• A quality control analyte recovery is outside of specified acceptance criteria

• Result is less than value reported

> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.

Page 94 of 105

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.corn Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: August 21, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0010-00IF Project: YANKO 1204 Sample ID: 168404014 Client ID: YANKOO Matrix: SE Vol. Recv.:

Collect Date: 04-MAY-06 Receive Date: 17-MAY-06 Collector: Client Moisture: 27.3%

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Alpha Spec Analysis Alphaspec Am241, Cm, Solid ALL FSS Americium-241 U 0.00677 +/-0.227 0.238 +/-0.227 0.628 pCi/g BXL1 08/11/06 1434 555696 1 Curium-242 U 0.0854 +/-0.167 0.00 +/-0.168 0.231 pCi/g Curium-243/244 U 0.0361 +/-0.242 0.241 +/-0.242 0.634 pCi/g Alphaspec Pu, Solid-ALL FSS Plutonium-238 U 0.173 +/-0.181 0.143 +/-0.182 0.331 pCi/g BXLI 08/11/06 2250 555697 2 Plutonium-239/240 U -0.0342 +/-0.0865 0.0951 +/-0.0866 0.235 pCi/g Liquid Scint Pu241, Solid-ALL FSS Plutonium-241 13.0 +/-6.44 4.78 +/-6.54 10.0 pCi/g BXL1 08/16/06 1553 555698 3 Rad Gas Flow Proportional Counting GFPC,Sr90, solid-ALL FSS Strontium-90 U -0.0128 +/-0.0141 0.0125 +/-0.0141 0.0262 pCi/g BXFI 08/14/06 0833 556350 4 Rad Liquid Scintillation Analysis LSC, Tritium Dist, Solid-HTD2,ALL FSS Tritium U 0.548 +/-7.50 6.25 +/-7.50 13.5 pCi/g DFAI 08/09/06 1454 554582 5 Liquid Scint C14, SolidAllFSS Carbon-14 U 0.0555 +/-0.0809 0.0655 +/-0.0809 0.137 pCi/g ATH2 08/09/06 2232 554583 6 Liquid Scint Fe55, Solid-ALL FSS Iron-55 U -18.1 +/-47.6 32.3 +/-47.6 66.6 pCi/g MXPI 08/12/06 2005 555722 7 Liquid Scint Tc99, Solid-ALL FSS Technetium-99 U 0.134 +/-0.205 0.167 +/-0.205 0.347 pCi/g EGD1 08/11/06 2354 554580 8 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 08/03/06 1534 554649 The following Analytical Methods were performed Method Description 1 DOE EML HASL-300, Am-05-RC Modified 2 DOE EML HASL-300, Pu-I I-RC Modified 3 DOE EML HASL-300, Pu-11-RC Modified 4 EPA 905.0 Modified Page 95 of 105

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: August 21, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0010-OOIF Project: YANK01204 Sample ID: 168404014 Client ID: YANK001 Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd 5 EPA 906.0 Modified 6 EPA EERF C-01 Modified 7 DOE RESL Fe-I, Modified 8 DOE EML HASL-300, Tc-02-RC Modified Surrogate/Tracer recovery Test Recovery% Acceptable Limits Americium-243 Alphaspec Am241, Cm, Solid ALl 50 (15%-125%)

Plutonium-242 Alphaspec Pu, Solid-ALL FSS 85 (15%-125%)

Carrier/Tracer Recovery Liquid Scint Pu24 1, Solid-ALL FS 99 (25%-/125%)

Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 74 (25°%o- 125%)

Carrier/Tracer Recovery Liquid Scint Fe55, Solid-ALL FS 70 (15%-125%)

Carrier/Tracer Recovery Liquid Scint Tc99, Solid-ALL FS 75 (15/-,125%)

Notes:

The Qualifiers in this report are defined as follows:

• A quality control analyte recovery is outside of specified acceptance criteria

< Result is less than value reported

> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.

Page 96 of 105

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: August 21, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0010-012F Project: YANK01204 Sample ID: 168404015 Client ID: YANK001 Matrix: SE Vol. Recv.:

Collect Date: 04-MAY-06 Receive Date: 17-MAY-06 Collector: Client Moisture: 28.1%

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Alpha Spec Analysis Alphaspec Am241, Cm, Solid ALL FSS Americium-241 U 0.110 +/-0.184 0.140 +/-0.184 0.386 pCi/g BXLI 08/11/06 1434 555696 1 Curium-242 U -0.0547 +/-0.141 0.192 +/-0.141 0.544 pCi/g Curium-243/244 U -0.126 +/-0.184 0.245 +/-0.185 0.597 pCi/g Alphaspec Pu, Solid-ALL FSS Plutonium-238 U -0.00157 +/-0.126 0.122 +/-0.126 0.291 pCi/g BXLI 08/11/06 2250 555697 2 Plutonium-239/240 U 0.0867 +/-0.0869 0.0406 +/-0.0872 0.128 pCi/g Liquid Scint Pu241, Solid-ALL FSS Plutonium-241 U 8.31 +/-6.16 4.77 +/-6.21 10.0 pCi/g BXLI 08/16/06 1609 555698 3 Rad Gas Flow Proportional Counting GFPC,Sr90, solid-ALL FSS Strontium-90 U -0.00771 +/-0.0144 0.0124 +/-0.0144 0.0263 pCi/g BXF1 08/14/06 0833 556350 4 Rad Liquid Scintillation Analysis LSC, Tritium Dist, Solid-HTD2,ALL FSS Tritium U 0.896 +/-6.17 5.11 +/-6.17 11.0 pCi/g DFA1 08/09/06 1510 554582 5 Liquid Scint C14, SolidAllFSS Carbon-14 U 0.0162 +/-0.0763 0.0633 +/-0.0763 0.132 pCi/g ATH2 08/09/06 2334 554583 6 Liquid Scint Fe55, Solid ALL FSS Iron-55 U 23.3 +/-49.3 32.5 +/-49.3 67.0 pCi/g MXP1 08/12/06 2021 555722 7 Liquid Scint Tc99, Solid-ALL FSS Technetium-99 U 0.0577 +/-0.206 0.171 +/-0.206 0.354 pCi/g EGD1 08/12/06 0010 554580 8 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 08/03/06 1534 554649 The following Analytical Methods were performed Method Description I DOE EML HASL-300, Am-05-RC Modified 2 DOE EML HASL-300, Pu-I I-RC Modified 3 DOE EML HASL-300, Pu-I I-RC Modified 4 EPA 905.0 Modified Page 97 of 105

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: August 21, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0010-012F Proiect: YANK01204 Sample ID: 168404015 Client ID: YANK001 Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd 5 EPA 906.0 Modified 6 EPA EERF C-01 Modified 7 DOE RESL Fe-I, Modified 8 DOE EML HASL-300, Tc-02-RC Modified Surrogate/Tracer recovery Test Recovery% Acceptable Limits Americium-243 Alphaspec Am241, Cm, Solid ALl 81 (15°/-125%)

Plutonium-242 Alphaspec Pu, Solid-ALL FSS 91 (15%-125%)

Carrier/Tracer Recovery Liquid Scint Pu241, Solid-ALL FS 99 (25%-125%)

Carrier/Tracer Recovery GFPC, SrO0, solid-ALL FSS 68 (250/6-125%)

Carrier/Tracer Recovery Liquid Scint Fe55, Solid-ALL FS 74 (15/-,125%)

Carrier/Tracer Recovery Liquid Scint Tc99, Solid-ALL FS 75 (15%-0125%)

Notes:

The Qualifiers in this report are defined as follows:

• A quality control analyte recovery is outside of specified acceptance criteria

< Result is less than value reported

> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.

Page 98 of 105

QUALITY CONTROL DATA Page 99 of 105

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com QC Summary Revort Date: August 21, 2006 Client: Connecticut Yankee Atomic Power Page 1 of 6 362 Injun Hollow Rd East Hampton, Connecticut Contact: Mr. Jack McCarthy Workorder: 168404 Parmna.mn NAMVI *mnlp I*,,*l A')C l1nif* RPrbO/,. RF-C 0/6 Ran e Anist Date Time Parmname NOM Sam le tlual nc Units RPD%

Rad Alpha Spec Batch 555696 QC1201153130 168340011 DUP Americium-241 U -0.000522 U 0.0578 pCi/g 204 (0%- 100%) BXLI 08/11/06 14:34 Uncert: +/-0.0385 +/-0.278 TPU: +/-0.0385 +/-0.279 Curium-242 U 0.00 U -0.0405 pCi/g 200 (0%- 100%)

Uncert: +/-0.0756 +/-0.0562 TPU: +/-0.0756 +/-0.0565 Curiumn-243/244 U -0.0177 U -0.0517 pCi/g 98 (0%- 100%)

Uncert: +/-0.0764 +/-0.257 TPU: +/-0.0765 +/-0.257 QC1201153132 LCS Americium-241 12.8 12.8 pCi/g 100 (75%-125%)

Uncert: +/-1.84 TPU: +/-2.70 Curium-242 U -0.0328 pCi/g Uncert: +/-0.0454 TPU: +/-0.0457 Curium-243/244 15.5 14.3 pCi/g 92 (75%-125%)

Uncert: +/-1.94 TPU: +/-2.92 QC1201153129 MB Americium-241 U 0.0471 pCi/g Uncert: +/-0.157 TPU: +/-0.157 Curium-242 U -0.0469 pCi/g Uncert: +/-0.0459 TPU: +/-0.0464 Curium-243/244 U -0.00385 pCi/g Uncert: +/-0.210 TPU: +/-0.210 QC1201153131 168340011 MS Americium-241 13.3 U -0.000522 12.0 pCi/g 91 (75%-125%)

Uncert: +/-0.0385 +/-1.38 TPU: +/-0.0385 +/-2.08 Curium-242 U 0.00 U 0.0427 pCi/g Uncert: +/-0.0756 +/-0.0837 TPU: +/-0.0756 +/-0.0839 Curium-243/244 16.1 U -0.0177 15.9 pCi/g 99 (75%-125%)

Uncert: +/-0.0764 +1-1.58 TPU: +/-0.0765 +/-2.61 Batch 555697 QC1201153134 168340011 DUP Plutonium-238 U -0.0155 U 0.0237 pCi/g 956 (0% - 100%) BXLI 08/11/06 22:51 Page 100 of 105

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com QC Summary Workorder: 168404 Page 2 of 6 Parmname NOM Samole Oual OC Units RPD% REC% Range Anist Date Time Rad Alpha Spec Batch 555697 Uncert: +/-0.0215 +/-0.0465 TPU: +/-0.0216 +/-0.0466 Plutonium-239/240 U 0.0414 U -0.0489 pCi/g 2410 (0%- 100%)

Uncert: +/-0.0934 +/-0.124 TPU: +/-0.0935 +/-0.124 QC1201153136 LCS Plutonium-238 U 0.155 pCi/g (75%-1 25%)

Uncert: +/-0.141 TPU: +/-0.142 Plutonium-239/240 11.8 11.5 pCi/g 98 (75%-125%)

Uncert: +/-0.856 TPU: +/-1.32 QCI201153133 MB Plutonium-238 U 0.0552 pCi/g 08/11/06 22:50 Uncert: +/-0.186 TPU: +/-0.186 Plutonium-239/240 U -0.0978 pCi/g Uncert: +/-0.0892 TPU: +/-0.0899 QC1201153135 168340011 MS Plutonium-238 U -0.0155 U 0.0539 pCi/g (75%-125%) 08/11/06 22:51 Unceri: +/-0.0215 +/-0.112 TPU: +/-0.0216 +/-0.112 Plutonium-239/240 12.3 U 0.0414 10.3 pci/g 84 (75%-125%)

Uncert: +/-0.0934 +/-0.796 TPU: +/-0.0935 +/-1.19 Batch 555698 QC1201153138 168340011 DUP Plutonium-241 U 7.28 U 10.1 pCi/g 0 (0% - 100%) BXL I 08/16/06 16:41 Unceri: +/-6.30 +/-6.39 TPU: +/-6.35 +/-6.46 QC1201153140 LCS Plutonium-241 137 145 pCi/g 106 (75%-125%) 08/16/06 17:14 Uncert: +/-12.5 TPU: +/-19.9 QC1201153137 MB Plutonium-241 U 8.57 pCi/g 08/16/06 16:25 Uncert: +/-6.93 TPU: +/-6.98 QC1201153139 168340011 MS Plutonium-241 138 U 7.28 142 pCi/g 103 (75%-125%) 08/16/06 16:58 Uncert: +/-6.30 +/-12.4 TPU: +/-6.35 +/-19.7 Batch 557837 QC1201158317 168404009 DUP Americium-241 U -0.0851 U 0.167 pCi/g 616 (0%- 100%) BXLI 08/16/06 09:49 Uncert: +/-0.136 +/-0.220 TPU: +/-0.136 +/-0.221 Curium-242 U -0.0253 U 0.241 pCi/g 247 (0%- 100%)

Page 101 of 105

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com QC Summary Workorder: 168404 Page 3 of 6 Parmname NOM Sam pLe _Qual QC Units RPD% REC% Range Anlst Date Time Rad Alpha Spec Batch 557837 Uncert: +/-0.0495 +/-0.334 TPU: +/-0.0496 +/-0.335 Curium-243/244 U -0.0479 U 0.0761 pCi/g 879 (0%- 100%)

Unceri: +/-0.0542 +/-0.149 TPU: +/-0.0545 +/-0.149 QC1201158319 LCS Americium-241 24.5 25.4 pCi/g 104 (75%-125%)

Uncert: +/-2.47 TPU: +/-4.16 Curium-242 U 0.0477 pCi/g Uncert: +/-0.127 TPU: +/-0.127 Curium-243/244 29.7 27.0 pCi/g 91 (75%-125%)

Uncert: +/-2.54 TPU: +/-4.38 QCI2O1158316 MB Americium-241 U 0.234 pCi/g Uncert: +/-0.275 TPU: +/-0.277 Curium-242 U 0.00 pCi/g Uncert: +/-0.152 TPU: +/-0.152 Curium-243/244 U -0.0551 pCi/g Uncert: +/-0.0624 TPU: +/-0.0628 QC1201158318 .168404009 MS Americium-241 26.4 U -0.0851 29.1 pCi/g 110 (75%-125%)

Uncert: +/-0.136 +/-2.97 TPU: +/-0.136 +/-5.01 Curium-242 U -0.0253 U 0.126 pCi/g Uncert: +/-0.0495 +/-0.247 TPU: +/-0.0496 +/-0.248 Curium-243/244 32.4 U -0.0479 31.7 pCi/g 98 (75%-125%)

Uncert: +/-0.0542 +/-3.12 TPU: +/-0.0545 +/-5.39 Rad Gas Flow Batch 556350 QC1201154645 168404003 DUP Strontium-90 U -0.00343 U -0.00637 pCi/g 0 (0% - 100%) BXFI 08/14/06 08:33 Uncert: +/-0.0203 +/-0.0152 TPU: +/-0.0203 +/-0.0152 QC1201154647 LCS Strontium-90 1.56 1.30 pCi/g 83 (75%-125%)

Uncert: +/-0.0563 TPU: +/-0.0881 QCI201154644 MB Strontium-90 U 0.0176 pCi/g Uncert: +/-0.018 TPU: +/-0.018 Page 102 of 105

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com QC Summary Workorder: 168404 Page 4 of 6 Parmname NOM Samole Oual QC Units RPD% REC% Range Anist Date Time Rad Gas Flow Batch 556350 QC1201154646 168404003 MS Strontium-90 1.58 U -0.00343 1.29 pCi/g 82 (75%-125%)

Uncert: +/-0.0203 +/-0.0535 TPU: +/-0.0203 +/-0.0813 Rad Liquid Scintillation Batch 554580 QC1201150562 168340012 DUP Technetium-99 U 0.0338 U 0.266 pCi/g 0 (0%- 100%) EGDI 08/12/06 00:42 Uncert: +/-0.192 +/-0.226 TPU: +/-0.192 +/-0.226 QC1201150564 LCS Technetium-99 13.1 13.6 pCi/g 103 (75%-125%) 08/12/06 01:14 Uncert: +/-0.496 TPU: +/-0.599 QC1201150561 MB Technetium-99 U 0.0311 pCi/g 08/12/06 00:26 Uncert: +/-0.177 TPU: +/-0.177 QC1201150563 168340012 MS Technetium-99 13.0 U 0.0338 12.0 pCi/g 92 (75%-125%) 08/12/06 00:58 Uncert: +/-0.192 +/-0.523 TPU: +/-0.192 +/-0.602 Batch 554582 QC1201150570 168340011 DUP Tritium U 1.77 U 1.62 pCi/g 0 (0% - 100%) DFA1 08/09/06 15:42 Uncert: +/-8.20 +/-7.47 TPU: +/-8.20 +/-7.47 QC1201150572 LCS Tritium 68.3 76.2 pCi/g 111 (75%-125%) 08/09/06 16:14 Uncert: +/-14.0 TPU: +/-14.1 QC0201150569 MB Tritium U 0.586 pCi/g 08/09/06 15:26 Uncert: +/-8.01 TPU: +/-8.01 QC1201150571 168340011 MS Tritium 61.3 U 1.77 61.8 pCi/g 101 (75%-125%) 08/09/06 15:58 Uncert: +/-8.20 +/-12.2 TPU: +/-8.20 +/-12.3 Batch 554583 QC1201150574 168404003 DUP Carbon-14 U 0.0937 I1 0.0422 pCi/g 0 (0% - 100%) ATH2 08/10/06 01:39 Uncert: +/-0.0813 +/-0.075 TPU: +/-0.0813 +/-0.0751 QC1201150576 LCS Carbon- 14 7.27 7.14 pCi/g 98 (75%-125%) 08/10/06 03:00 Uncert: +/-0.508 TPU: +/-0.520 QC1201150573 MB Page 103 of 105

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com QC Summary Workorder: 168404 Page 5 of 6 Parmname NOM Sample Qual QC Units RPD% REC% Range Anist Date Time Rad Liquid Scintillation Batch 554583 Carbon- 14 U -0.0315 pCi/g Uncert: +/-0.0776 TPU +/-0.0776 QC1201150575 168404003 MS Carbon-14 15.1 U 0.0937 13.8 pCi/g 92 (75%-125%) 08/10/06 02:43 Uncert: +/-0.0813 +/-1.00 TPU +/-0.0813 +/-1.03 Batch 555722 QC1201153223 168340012 DUP Iron-55 U -26.5 U 5.83 pCi/g 0 (0% - 100%) viXP1 08/12/06 20:54 Uncert: +/-65.1 +/-36.9 TPU +/-65.1 +/-36.9 QC1201153225 LCS Iron-55 641 660 pCi/g 103 (75%-125%) 08/12/06 21:27 Uncert: +/-56.2 TPU +/-67.2 QC1201153222 MB Iron-55 U 18.2 pCi/g 08/12/06 20:38 Uncert: +/-39.6 TPU +/-39.6 QC1201153224 168340012 MS Iron-55 717 U -26.5 688 pCi/g 96 (75%-125%) 08/12/06 21:11 Uncert: +/-65.1 +/-60.2 TPU: +/-65.1 +/-71.6 Batch 555723 QC1201153227 168340012 DUP Nickel-63 U 3.79 U 6.68 pCi/g 0 (0% - 100%) vAXPI 08/11/06 11:55 Uncert: +/-5.39 +/'-7.43 TPU: +/-5.40 +//-7.43 QCI201153229 LCS Nickel-63 512 479 pCi/g 94 (75%-125%) 08/11/06 12:27 Uncert: +/'-22.4 TPU: +/'-27.1 QC1201153226 MB Nickel-63 U 15.7 pCi/g 08/11/06 11:38 Uncert: +/-9.92 TPU: +/-9.93 QC1201153228 168340012 MS Nickel-63 530 U 3.79 511 pCi/g 96 (75%-125%) 08/11/06 12:11 Uncert: +/-5.39 +/-23.5 TPU: +/-5.40 +/-28.7 Notes:

The Qualifiers in this report are defined as follows:

A quality control analyte recovery is outside of specified acceptance criteria

< Result is less than value reported Result is greater than value reported Page 104 of 105

GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com QC Summary Workorder: 168404 Page 6 of 6 Parmname NOM Sample Qual QC Units RPD% REC% Range Anist Date Time A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded N/A indicates that spike recovery limits do not apply when sample concentration exceeds spike conc. by a factor of 4 or more.

• • Indicates analyte is a surrogate compound.

A The Relative Percent Difference (RPD) obtained from the sample duplicate (DUP) is evaluated against the acceptence criteria when the sample is greater than five times (5X) the contract required detection limit (RL). In cases where either the sample or duplicate value is less than 5X the RL, a control limit of +/- the RL is used to evaluate the DUP result.

For PS, PSD, and SDILT results, the values listed are the measured amounts, not final concentrations.

Where the analytical method has been performed under NELAP certification, the analysis has met all of the requirements of the NELAC standard unless qualified on the QC Summary.

Page 105 of 105

DISCHARGE CANAL SURVEY UNIT 9106-0003 RELEASE RECORD Attachment 2b Split Sample Assessment Forms (2 Pages)

Connecticut Yankee Decommissioning Project Health 24265-000-GPR-GGGR-R5124-000 Attachment A Physics Procedure Split Sample Assessment Form Survey Area 9106 Survey 0003 Survey Discharge Canal

1. Unit #: Unit Name:

Sample Plan or WPIR#: 2006-021 SML #: 9106-0003-004 Sample

Description:

Comparison of split samples collected from sample measurement location #04 and analyzed using gamma spectroscopy by an off-site vendor laboratory. The standard sample was 9106-0003-004F the comparison sample was 9106-0003-004FS.

STANDARD COMPARISON Radionuclide Activity Standard Resolution Agreement Activity Standard Comparison Acceptable (Y/N)

Value Error Range Value Error Ratio Cs-137 2.92E-01 2.50E-02 12 0.6- 1.66 3.14E-01 2.30E-02 1.08 Y Co-60 7.43E-01 3.61E-02 21 0.75- 1.33 9.84E-01 5.15E-02 1.32 Y Comments/Corrective Actions: N/A Table is provided to show acceptance criteria used to assess split samples.

Resolution I Agreement Range 4 7 0.50 2.00 8 15 0.60 1.66 16 50 0.75 1.33 51 200 0.80 1.25

> 200 0.85 1.18 Performed By:

WPIR - Work Plan and Inspection Record SML - Sample Measurement Location designation Page I of I

Connecticut Yankee Decommissioning Project Health 24265-000-GPR-GGGR-R5124-000 Attachment A Physics Procedure Split Sample Assessment Form Survey 9106 Survey 0003 Survey Unit Discharge Canal Area#: IUnit #: Name:

Sample Plan or WPIR#: 2006-0021 SML #: 9106-0003-010 Sample

Description:

Comparison of split samples collected from sample measurement location #10 and analyzed using gamma spectroscopy by an off-site vendor laboratory. The standard sample was 9106-0003-OIOF. the comparison sample was 9106-0003-010FS.

STANDARD COMPARISON Radionuclide Activity Standard Resolution Agreement Activity Standard Comparison Acceptable (Y/N)

Value Error Range Value Error Ratio Cs-137 2.04E-01 2.08E-02 10 0.6- 1.66 1.69E-01 1.79E-02 0.83 Y Co-60 2.28E-01 2.54E-02 9 0.6- 1.66 0.OOE+00 2.02E-01 0.00 N K-40 1.24E+01 5.05E-01 25 0.75- 1.33 1.13E+01 4.91E-01 0.91 Y Comments/Corrective Actions: Since Co-60 has a likelyhood to Table is provided to show acceptance criteria used be present in the sample matrix in particulate form, one would to assess split samples.

not neccassarily expect it to be homogenuously mixed from processing of the sample-split aliqot. Since both Cs-137 and K- Resolution Agreement Range 40 were also found to be present at an acceptable level of 4 7 0.50 2.00 agreement, no further action is warranted. 8 15 0.60 1.66 16 50 0.75 1.33 51 200 0.80 1.25

> 200 0.85 1.18 Performed By: Date: Reviewed By: Date:

7-/3-06 WPIR - Work Plan and Inspection Record SML - Sample Measurement Location designation Page I of I

DISCHARGE CANAL SURVEY UNIT 9106-0003 RELEASE RECORD Attachment 2c Preliminary Data Forms (1 Page)

Health Physics Procedure GPP-GGGR-R512 1-001 Attachment B, Rev. CY-00 I MAJOR Health Physics Procedure GPP-GGGR-R5 121-001 Attachment B, Rev. CY-00 1 MAJOR Preliminary Data Review Form - Samples for the Sign Test Survey Unit: 9106- 0003 Survey Unit Name: Discharge Canal Classification: 2 Survey Media: Soil Type of Survey: Final Status Survey Type of Measurement: Radionuclide Specific Number of Measurements: 15 Operational DCGL: 1 BASIC STATISTICAL QUANTITIES Cs-137 Co-60 Minimum Value: 3.52E-04 1.45E-02 Maximum Value: 3.18E-01 8.05E-01 Mean: 1.48E-01 2.1OE-01 Median: 1.28E-01 1.07E-01 Standard Deviation: 1.16E-0 1 2.70E-0 I RADIONUCLIDE CONCENTRATION (pCi/g)

NUMBER Cs-137 Co-60 Identified? Identified?

9106-0003-001F 1.28E-01 1.07E-01 Y Y 9106-0003-002F 4.37E-02 1.89E-02 Y N 9106-0003-003F 3.93E-02 2.45E-02 Y Y 9106-0003-004F 2.92E-01 7.43E-01 Y Y 9106-0003-005F 2.10E-01 1.36E-01 Y Y 9106-0003-006F 1.05E-01 1.86E-02 Y N 9106-0003-007F 2.64E-02 2.90E-02 Y N 9106-0003-008F 2.46E-01 1.09E-01 Y Y 9106-0003-009F 3.18E-01 4.45E-01 Y Y 9106-0003-OIOF 2.04E-01 2.28E-01 Y Y 9106-0003-012F 4.27E-02 1.45E-02 Y N 9106-0003-013F 1.96E-02 2.41 E-02 N N 9106-0003-014F 2.91 E-01 4.33E-01 Y Y 9106-0003-015F 2.57E-01 8.05E-01 Y Y 9106-0003-016F 3.52E-04 2.02E-02 N Y Performed By: Date: 7 Independent Review: i~A~~r Date:

DISCHARGE CANAL SURVEY UNIT 9106-0003 RELEASE RECORD Attachment 2d Graphical Representation of Data (4 Pages)

. .1 Health Physics Procedure GGGR-R5123-Rev.CY-001 Attachment C Quantile Plot For Cesium - 137 Survey Unit: 9106-0003 Survey Unit Name: Discharge Canal Mean: 1.48E-01 pCi/g Cs-137 Rank Percentage 3.52E-04 1 3%

1.96E-02 2 9%

2.64E-02 3 16%

3.93E-02 4 22 %

4.27E-02 5 28 %

4.37E-02 6 34 %

1.05E-01 7 41%

1.28E-01 8 47 %

1.90E-01 9 53 %

2.04E-01 10 59 %

2.10E-01 11 66 %

2.46E-01 12 72 %

2.57E-01 13 78 %

2.91 E-01 14 84 %

2.92E-01 15 91 %

3.18E-01 16 97 %

Prepared By: Date: >ý 13 -Oz Reviewed By: Date: 7/3/4-jj

Health Physics Procedure GGGR-R5123-Rev.CY-001 Attachment C Quantile Plot For Cobalt - 60 Survey Unit: 9106-0002 Survey Unit Name: Discharge Canal Mean: 2.07E-01 pCi/g 7OOE-01 6.OOE-01 O5.OOE-01 0 4.00E-01 "

3.00E-01 o 2.00E-01-: --------------------------------------------

0.OOE+00 -. -

0 20 40 60 80 100 Percentage Co-60 Rank Percentage 1.46E-03 1 3 %

2.13E-02 2 10 %

5.07E-02 3 17 %

8.07E-02 4 23  %

1.18E-01 5 30  %

1.19E-01 6 37 %

1.21E-01 7 43%

1.45E-01 8 50 %

1.51E-01 9 57 %

2.31 E-01 10 63 %

2.38E-01 11 70 %

2.88E-01 12 77 %

3.70E-01 13 83 %

5.26E-01 14 90 %

6.39E-01 15 97 %

Prepared By: 5 6,Z Date: 7- Z Reviewed By: Date: 12* 6

Health Physics Procedure GGGR-R5123-Rev.CY-001 Attachment C Frequency Plot For Cesium - 137 Survey Unit: 9106-0003 Survey Unit Name: Discharge Canal Mean: 0.148 pCi/g 7-6 5-a4-

"*2-0 0.05 0.1 0.15 0.2 0.25 0.3 Upper End Value (pCi/g)

Upper End Observation Observation Value Frequency Frequency 0.05 6 38%

0.1 2 13%

0.15 1 6%

0.2 3 19%

0.25 3 19%

0.3 1 6%

Total 16 100%

Prepared By: /Aý) tý7AK V / Date:-//- 7-04 Reviewed By: Date: //3/e6

Health Physics Procedure GGGR-R5123-Rev.CY-001 Attachment C Frequency Plot For Co - 60 Survey Unit: 9106-0003 Survey Unit Name: Discharge Canal Mean: 0.210 pCi/g 8

7 6

5 C) 4 3

LL. 2 1 , .

0- Ii IK 0.10 0.20 0.30 0.40 0.50 0.60 0.70 0.80 Upper End Value (pCi/g)

Upper End Observation Observation Value Frequency Frequency 0.10 7 44%

0.20 4 25%

0.30 1 6%

0.40 0 0%

0.50 2 13%

0.60 0 0%

0.70 1 6%

0.80 1 6%

Total 16 100%

Prepared By: Date: -

Reviewed By: Date: 2;'/5'-2

DISCHARGE CANAL SURVEY UNIT 9106-0003 RELEASE RECORD Attachment 2e Sign Test Calculation (1 Page)

Health Physics Procedure GPP-GGGR-R5]2 1-000 Attachment A, Rev. CY-00 I MAJOR Sign Test Calculation Sheet For Multiple Radionuclisdes SU Number: 9106-0003 Survey Unit Name: Discharge Canal WP&IR#: 2006-021 Classification : 2 ITYPE I (a error):0.051 TYPE I (3 error):0.05 i Radionuclides: Cs-137 Co-60 Survey Design DCGL (pCi/g): 3.16 1.52 Weighted Sum (Ws)

Results Cs-137 Results Co-60 Results Pu-241 (includes Pu-241 DCGL-Result Sign component) 1.28E-01 1.07E-01 2.20E+01 1.48E-01 8.52E-01 4.37E-02 1.89E-02 2.20E+01 6.35E-02 9.36E-01 3.93E-02 2.45E-02 2.20E+01 6.58E-02 9.34E-01 2.92E-01 7.43E-01 8.3 1E+00 5.95E-01 4.05E-01 2.1OE-01 1.36E-01 2.20E+01 1.93E-01 8.07E-01 1.05E-01 1.86E-02 2.20E+01 8.27E-02 9.17E-01 2.64E-02 2.90E-02 2.20E+01 6.47E-02 9.35E-01 2.46E-0 I 1.09E-01 5.42E+01 2.41E-01 7.59E-01 3.18E-01 4.45E-01 2.20E+01 4.3 1E-01 5.69E-0 I 2.04E-01 2.28E-01 2.20E+0 1 2.52E-01 7.48E-01 4.27E-02 1.45E-02 2.20E+0 I 6.03E-02 9.40E-0 1 1.96E-02 2.41 E-02 2.20E+0 1 5.93E-02 9.41E-01 2.91E-01 4.33E-01 1.90E+01 4.09E-01 5.91E-01 2.57E-01 8.05E-01 6.63E+00 6.22E-0 I 3.78E-01 3.52E-04 2.02E-02 2.20E+0 I 5.06E-02 9.49E-0 1 1.90E-01 1.85E-01 2.20E+01 2.19E-01 7.8 1E-01 Number of Positive Differences (S+): 16 Critical Value: II Survey Unit: Meets Acceptance Criterion Performed By: -/,?_ Date: /- -0 Z Independent Review: &48::,ýý2 Date: 1/i /3/oc Page 1 of I

DISCHARGE CANAL SURVEY UNIT 9106-0003 RELEASE RECORD Attachment 2f COMPASS DQA Surface Soil Report with Retrospective Power Curve (4 Pages)

DQA Surface Soil Report Assessment Summary Site: 9106-0003 Planner(s): Dale Randall Survey Unit Name: Discharge Canal 9106-0003 Report Number: 1 Survey Unit Samples: 16 Reference Area Samples: 0 Test Performed: Sign Test Result: Not Performed Judgmental Samples: 0 EMC Result: Not Performed Assessment

Conclusion:

Reject Null Hypothesis (Survey Unit PASSES)

Retrospective Power Curve 1

0.9 __Jil-vi

-

4-0.8 U

0.7 0.6 0.5

-a "

0.4 Ia-Id 0.3 0.2 0.1 0

0.0 0.2 0.4 0.6 0.8 1.0 1.2 Unity Rule Sum-ef-Rails, includiug background

- - Prospective Power 1-beta 1 .... Actual Power

,- LBGR - - Estimated Power DCGL ---- Retrospective Power COMPASS v11.0.0 1012412006 Page I

DQA Surface Soil Report Survey Unit Data NOTE: Type = "S"indicates survey unit sample.

Type = "R" indicates reference area sample.

Sample Number Type Co-60 (pCi/g) Cs-I 37 (pC ig) 9106-0003-001 F S 0.11 0.13 9106-0003-002F S 0.02 0.04 9106-0003-003F S 0.02 0.04 9106-0003-004F S 0.74 0.29 9106-0003-005F S 0.14 0.21 9106-0003-006F S 0.02 0.1 9106-0003-007F S 0.03 0.03 9106-0003-008F S 0.11 0.25 9106-0003-009F S 0.44 0.32 9106-0003-01 OF S 0.23 0.2 9106-0003-012F S 0.01 0.04 9106-0003-013F S 0.02 0.02 9106-0003-0115F S 0.8 0.26 9106-0003-016F S 0.02 0 9106-0003-018F S 0.18 0.19 9106-0003-014F S 0.43 0.29 Modified Data (Unity Rule SOR)

NOTE: Type = "S"indicates survey unit sample.

Type = "R" indicates reference area sample.

Sample Number Type Sum-of-Ratios (SOR) 9106-0003-001 F S 0.11 9106-0003-002F S 0.03 9106-0003-003F S 0.03 9106-0003-004F S 0.58 9106-0003-005F S 0.16 9106-0003-006F S 0.05 9106-0003-007F S 0.03 9106-0003-008F S 0.15 9106-0003-009F S 0.39 9106-0003-01 OF S 0.21 9106-0003-012F S 0.02 9106-0003-013F S 0.02 9106-0003-015F S 0.61 9106-0003-016F S 0.01 9106-0003-018F S 0.18 9106-0003-014F S 0.38 COMPASS vl.0.0 1012412006 Page 2

U4 DQA Surface Soil Report Basic Statistical Quantities Summary Statistic Survey Unit Background DQO Results Sample Number 16 N/A N=15 Mean (SOR) 0.19 N/A 0.13 Median (SOR) 0.13 N/A N/A Std Dev (SOR) 0.20 N/A 0.26 High Value (SOR) 0.61 N/A N/A Low Value (SOR) 0.01 N/A N/A vl.0.0 1012412006 Page 3 COMPASS v1.0.0 COMPASS 1012412006 Page 3