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| issue date = 05/02/2008
| issue date = 05/02/2008
| title = Survey Unit Release Record, EP Pph 109, Revision - Original - Part 2
| title = Survey Unit Release Record, EP Pph 109, Revision - Original - Part 2
| author name = Wood G L
| author name = Wood G
| author affiliation = US National Aeronautics & Space Admin (NASA), John H. Glenn Research Ctr at Lewis Field
| author affiliation = US National Aeronautics & Space Admin (NASA), John H. Glenn Research Ctr at Lewis Field
| addressee name =  
| addressee name =  
Line 18: Line 18:
=Text=
=Text=
{{#Wiki_filter:*
{{#Wiki_filter:*
* SECTION ATTACHMENT 68
* SECTION 7 ATTACHMENT 3 68 PAGES
*
 
* Attachment 3 Comments.
Attachment 3 Comments.
The graphic map in this attachment portrays the extent of core bores and excavations to support remediation of PH 109. Also included are the physical survey locations for the soil samples acquired to verify soil activity levels were less than DCGL at the conclusion of remediation activities in the various excavations.
The graphic map in this attachment portrays the extent of core bores and excavations to support remediation of PH 109. Also included are the physical survey locations for the soil samples acquired to verify soil activity levels were less than DCGL at the conclusion of remediation activities in the various excavations. The appropriate soil sample ID numbers can be discerned in the hexagon symbols on the map. The soil sample results are included in this attachment.
The appropriate soil sample ID numbers can be discerned in the hexagon symbols on the map. The soil sample results are included in this attachment.
 
*
0>--
* CO B-1 CO 6-2 .J  &#xa3;:0  ROOM 8 RPHO-l N c:i :L o: ROOM6 U\ FD3 VR 4-2 ROOM 7  ;<04; ROOM2B CO 2"\ /
* 0 ROOM 7 0>--                                                                            ~
FO 2 ROOM4  FD 4-2 VR
COl    /B ROOM 1 FD ROOM2B CO 2 " \ /
* 0 ROOM 1 COl /B FD 
FO 2
*
                                              ~S-010
* 1 PB08-00798 ORTEC g v -i (1087) npp32 G53w3.05 13-MAR-2008 14:30:38 page PBRF spectrum name: PB08-00798.An1 sample description PB08-00798; SR99-009; PPH; RM1; FD1; 3/13/08 spectrum Filename:
                                                            ~OOM3 U\FD3 JFD~
z:\Lab\SAMPLE 08\PB08-00798.An1 Acquisition information Start time: 1Y-Mar-2008 14:25:00 Live time: 300 Real time: 301 Dead time: 0.28 % Detector 10: 3 Detector system#3 DETECTOR (#131) Calibration Filename:
CO B-1 ROOM 8 VR 0-                                                                              &#xa3;:0
250ml #73678-773 (MC131) Sept07 Energy calibration created: Zero offset: Gain: Quadratic:
                                                                            ~~D~
Efficiency Calibration created: Type: uncertainty:
                ~ FD 4-2 CO 6-2 ROOM4 ROOM6
coeffi ci ents: Library Main analysis Library Match peak Analysis parameters Analysis engine: start channel: Stop channel: peak rejection level: peak search sensitivity:
                                      ~
sample Size: Activity scaling factor: Detection limit method: Random error: systematic error: Fracti-on Limit: Background width: o 05-sep-2007 16:56:38 0.565 key 0.247 key/channel 5.022E-08 kev/channel A 2 05-sep-2007 17:17:39 polynomial 1.204 % -0.304311
01---                              ;<04; VR 4-2                             .J RPHO-l N
-4.249899
c:i
-0.094002 0.005803 plumbrk 01.lib Library npp32 G53w3.05 155 ( 38.83keV ) 8144 ( 2014.22kev) 1.0000E+06/( 1.0000E+00*
:L n
4.5780E+02) 2.1844E+03 Nureg 4.16 1.0000000E+00 1.0000000E+00 0.000% best method (based on spectrum).
o:
Page 1 
* PB08-00798 ORTEC g v - i (1087) npp32 G53w3.05 13-MAR-2008 14:30:38 page     1 PBRF                             spectrum name: PB08-00798.An1 sample description PB08-00798; SR99-009; PPH; RM1; FD1; 3/13/08 spectrum Filename: z:\Lab\SAMPLE 08\PB08-00798.An1 Acquisition information Start time:                 1Y-Mar-2008 14:25:00 Live time:               300 Real time:               301 Dead time:                 0.28 %
*
Detector 10:                     3 Detector system
* PBRF ORTEC g v -i (l087) npp32 PB08-00798 G53w3.05 13-MAR-2008 14:30:38 Page Spectrum name: PB08-00798.An1 2 Half lives decay limit: Activity range factor: Min. step backg. energy 12.000 2.000 0.000 corrections Status Comments Decay correct to date: YES 11-Mar-2008 08:32:00 Decay during acquisition:
      #3 DETECTOR (#131)
NO Decay during collection:
Calibration Filename:
NO True coincidence correction:
250ml #73678-773 (MC131) Sept07 Energy calibration created:             05-sep-2007 16:56:38 Zero offset:         0.565 key Gain:               0.247 key/channel Quadratic:           5.022E-08 kev/channel A2 Efficiency Calibration created:             05-sep-2007 17:17:39 Type:               polynomial uncertainty:         1. 204 %
NO Peaked background correction:
coeffi ci ents:     -0.304311 -4.249899    0.669559
NO Absorption (Internal):
                                    -0.094002    0.005803 -0.000133 Library Files Main analysis library:      plumbrk 01.lib Library Match Width:        0.500 peak stripping:            Library based Analysis parameters Analysis engine:           npp32    G53w3.05 start channel:           155 (    38.83keV )
NO Geometry correction:
Stop channel:           8144 ( 2014.22kev) peak rejection level:     25.000%*
NO Random summing: NO Energy Normalized diff: SUM MARY 0F PEA K SIN RANGE Peak Area Uncert FWHM Corrctn Nuclide Brnch. Act. NuC Energy Factor Energy Ratio pCi/g 77 .16 60. 21. 82 0.62 8.259E-02 238.67 56. 18.73 0.97 6.195E-02 238.63 43.300 4.108E-01 PB212 352.09 59. 13.02 0.79 4.553E-02 351.93 37.600 6.779E-01 PB214 609.46 55. 13.48 0.54 2.830E-02 609.31 46.100 8.297E-01 BI214 661.40 22. 21. 32 0.59 2.639E-02 661.66 85.100 1. 928E-01 cs13 7 1173.14 55. 13.48 1. 30 1.656E-02 1173.24 99.974 6.544E-01 c060 1332.28 50. 14.14 0.31 1. 494E-02 1332.50 99.986 6.590E-01 c060 1460.62 108. *9.62 0.85 1.387E-02 1460.83 11. 000 1. 393E+01 K40 .J.. .J.. .1_ oJ* .I. J* .1_ J.J_ J* .J.. oJ.................. " ...... ************ U N IDE N T I FIE D PEA K SUM MAR Y peak Centroid Background Net Area Intensity Uncert FWHM Suspected Channel Energy Counts Counts Cts/Sec 2 sigma % kev Nuclide 310.28 77 .16 38. 60. 0.198 43.64 0.618 sM s -peak fails shape D -peak area L-Peak written from unknown C -Area < critical M -peak is close to a library This section based on library: plumbrk 01.lib o ORTEC g v -(1087) npp32 G53w3.05 13-MAR-2008 14:30:38 page PBRF spectrum name:
peak search sensitivity:   3 sample Size:               4.5780E+02 Activity scaling factor:   1.0000E+06/( 1.0000E+00*    4.5780E+02) 2.1844E+03 Detection limit method:    Nureg 4.16 Random error:              1.0000000E+00 systematic error:           1.0000000E+00 Fracti-on Limit:           0.000%
*'1:* ***** '1: -1: ,!; '1:
Background width:         best method (based on spectrum).
* 1. I DE N TI FI E D PEAK S UMMA R Y ** ** * *1: *"'1; * ** Nuclide peak Centroid Background Net Area Intensity Uncert FWHM channel Energy Counts Counts Cts/Sec 2 sigma % kev AM-241 0.00 59.54 O. O. 0.000 0.00 0.000 O. O. 0.000 0.00 0.000 TH-234 0.00 63.29 O. O. 0.000 0.00 0.000 TH-234 0.00 92.59 page 2 
o Page 1
*
 
* PB08-00798 EU-152 0.00 121.78 O. o. 0.000 0,00 0.000 EU-154 0.00 123. 07 O. o. 0.000 0.00 0.000 u-235 0.00 143.76 O. o. 0.000 0.00 0.000 u-235 0.00 185.71 O. O. 0.000 0.00 0.000 PB-212 964.40 238.67 18. 56. 0.187 37.46 0.969 EU-152 0.00 344.28 O. O. 0.000 0.00 0.000 PB-214 1423.63 352.09 O. 59. 0.197 26.04 0.7905 Ag-108m 0.00 433.94 O. O. 0.000 0.00 0.000 BI-214 2465.43 609.46 O. 55. 0.183 26.97 0.5405 Ag-108m 0.00 614.28 . O. O. 0.000 0.00 0.000 .. cs-137 2675.64 661.40 O. 22. 0.073 42.64 O.
ORTEC g v - i (l087) npp32
Ag-108m 0.00 722.91 O. O. 0.000 0.00 0.000 EU-154 0.00 723.30 O. O. 0.000 0.00 0.000 BI-212 0.00 727.33 O. O. 0.000 0.00 0.000 EU-154 0.00 1004.72 O. o. 0.000 0.00 .0. 000 CO-60 4745.62 1173 .14 O. 55. 0.183 26.97 1.2985 EU-154 0.00 1274.44 O. O. 0.000 0.00 0.000 co-60 5388.96 1332.28 O. 50. 0.167 28.28 0.3065 EU-152 0.00 1408.01 O. O. 0.000 0.00 0.000 K-40 5907.71 1460.62 O. 108. 0.360 19.25 0.8455 BI-214 7134.00 1764.13 O. O. 0.000 0.00 0.0005 5 -Peak fails shape D -Peak area A Derived peak 1: -!: 1: *-t: S UMMA R Y 0 F L I BRAR Y PEAK U S AGE -Nuclide -
* PB08-00798 G53w3.05 13-MAR-2008 14:30:38 Page                                2 PBRF                                                    Spectrum name: PB08-00798.An1 Half lives decay limit:                        12.000 Activity range factor:                          2.000 Min. step backg. energy                        0.000 corrections                                                    Status            Comments Decay correct to date:                              YES        11-Mar-2008 08:32:00 Decay during acquisition:                            NO Decay during collection:                            NO True coincidence correction:                        NO Peaked background correction: NO Absorption (Internal):                              NO Geometry correction:                                NO Random summing:                                    NO Energy Calibration Normalized diff:              0.1080 SUM MAR Y 0 F                          PEA K S I N          RAN G E Peak                        Area    Uncert FWHM          Corrctn      Nuclide Brnch.         Act.                       NuC Energy                                                    Factor      Energy    Ratio      pCi/g 77 .16                      60. 21. 82    0.62    8.259E-02 238.67                        56. 18.73      0.97    6.195E-02      238.63  43.300    4.108E-01                      PB212 352.09                        59. 13.02      0.79    4.553E-02      351.93  37.600    6.779E-01                      PB214 609.46                        55. 13.48      0.54    2.830E-02      609.31  46.100    8.297E-01                      BI214 661.40                        22. 21. 32    0.59    2.639E-02     661.66  85.100    1. 928E-01                    cs13 7 1173.14                          55. 13.48      1. 30  1.656E-02     1173.24  99.974    6.544E-01                     c060 1332.28                          50. 14.14      0.31    1. 494E-02   1332.50  99.986    6.590E-01                     c060 1460.62                        108. *9.62      0.85    1.387E-02     1460.83  11. 000  1. 393E+01                     K40
-------------
************ U N IDE N T I FIE D                                    PEA K        SUM MAR Y ................. " ...... ..
Peak Name Code ActlVlty Energy Activity Code MDA value pci/g kev pci/g pci/g COMMENTS K-40 N 1. 3934E+01 1460.83 1. 393E+01 ( 9.509E-01 9.62 G K co-60 F 6.5675E-01 1332.50 6.590E-01 ( 9.714E-02 14.14 G K 1173.24 6.544E-01  
                                                                                                  .J.. .J.. .1_ oJ* .I. J * .1_ J. J_ J * .J.. oJ.
?( 8.770E-02 13 .48 G K CS-137 I 1.9279E-01 661.66 6.458E-02 21.32 G K o U ORTEC 9 v -i (1087) npp32 G53w3,05 13-MAR-2008 14:30:38 Page PBRF Spectrum name:
peak Centroid Background Net Area                            Intensity    Uncert    FWHM Suspected Channel              Energy          Counts        Counts      Cts/Sec    2 sigma % kev        Nuclide 310.28                    77 .16          38.           60.     0.198    43.64    0.618                                  sM s - peak              fails shape tests.
Nuclide Ave activity Activity Code Peak MDA Comments PB-212 N 4.1077E-01 238.63 4.108E-01  
D - peak              area deconvoluted.
?( 1. 649E-01 18.73 G K PB-214 N 6.7792E-01 351.93 6.779E-01 ( 8.468E-02 13.02 G K BI-214 N 8.2966E-01 609.31 8.297E-01 ( 1.112E-01 13.48 GK 1764.49 O.OOOE+OO?
L - Peak            written from unknown list.
7.956E-01 0.00 G 1120.29 O.OOOE+OO  
C - Area              < critical level.
& 1.071E+00 152.75 ( -This peak used in the nuclide activity
M - peak              is close to a library peak.
* peak is too wide, but only one peak in library. peak is part of a multiplet and this area Page
This section based on library: plumbrk 01.lib o
*
ORTEC g v -                    (1087) npp32      G53w3.05 13-MAR-2008 14:30:38 page                                3 PBRF                                                    spectrum name: PB08-00798.Anl
* PB08-00798 negative during ? -peak is too @ -Peak is too wide at FW25M, but ok at % -Peak fails sensitivity $ peak identified, but first peak of this failed one or more qualification + -Peak activity higher than counting uncertainty peak activity lower than counting uncertainty -Peak outside analysis energy & -calculated peak centroid is not close enough to library energy centroid for positive P -peakbackground  
*'1:* *** * * '1: -1: ,!; '1:
} Peak is too close to another for the to be found directly.
* 1. I D E N T I F I E D         P EA K       S U M M A R Y ** ** * *1: *"'1; * *~; **
Nuclide codes: Peak T -Thermal Neutron Activation G-Gamma F -Fast Neutron Activation X-I -Fission Product P -Positron N -Naturally occurring Isotope S -
Nuclide peak                        Centroid Background Net Area            Intensity      Uncert FWHM channel Energy                 Counts           Counts     Cts/Sec 2 sigma % kev AM-241                        0.00      59.54              O.           O.     0.000      0.00                0.000 TH-234                        0.00      63.29              O.            O.      0.000      0.00              0.000 TH-234                        0.00      92.59              O.            O.      0.000      0.00              0.000 page 2
P -Photon Reaction D -
* PB08-00798 EU-152          0.00    121.78            O.           o.            0.000          0,00      0.000 EU-154          0.00    123. 07            O.            o.            0.000          0.00      0.000 u-235            0.00    143.76            O.            o.            0.000          0.00      0.000 u-235            0.00    185.71            O.            O.            0.000          0.00      0.000 PB-212        964.40    238.67          18.           56.             0.187        37.46      0.969 EU-152          0.00   344.28            O.           O.           0.000         0.00     0.000 PB-214        1423.63   352.09            O.         59.             0.197        26.04      0.7905 Ag-108m          0.00   433.94            O.           O.           0.000         0.00     0.000 BI-214        2465.43    609.46            O.         55.             0.183        26.97      0.5405 Ag-108m          0.00   614.28          . O.           O.           0.000         0.00     0.000       .
C -charged Particle Reaction K -Key M -No MDA Calculation A -Not in r R Coincidence Corrected  
cs-137        2675.64    661.40            O.         22.             0.073        42.64      O. 587s~
'---coincidence H -Halfl ife 1 i mi t o ORTEC g v -(1087) npp32 G53W3.05 13-MAR-2008 14:30:38 Page 5 PBRF spectrum name: PB08-00798.An1  
Ag-108m          0.00    722.91            O.           O.           0.000          0.00    0.000 EU-154          0.00   723.30            O.           O.           0.000         0.00     0.000 BI-212          0.00    727.33            O.           O.           0.000          0.00      0.000 EU-154          0.00   1004.72            O.           o.           0.000         0.00     .0. 000 CO-60        4745.62  1173 .14            O.         55.             0.183         26.97     1.2985 EU-154          0.00   1274.44            O.           O.           0.000         0.00     0.000 co-60        5388.96  1332.28            O.         50.             0.167        28.28      0.3065 EU-152          0.00   1408.01            O.           O.           0.000         0.00     0.000 K-40          5907.71  1460.62            O.       108.             0.360        19.25      0.8455 BI-214        7134.00   1764.13            O.           O.           0.000         0.00     0.0005 5 - Peak fails shape tests.
*-:.-1,7."1.
D - Peak area deconvoluted.
1,
A Derived peak area.
* 1, *' 1, SUM MAR Y oF NUCLI DES IN SAMPLE Time of Count Time Corrected uncertainty 2 Sigma Nuclide Activity Activity Counting Total MOA pci/g pci/g pci/g pci/g K-40 1.3934E+01 1.3934E+01 2.6816E+OO 2.7126E+OO 9.509E-01 co-60 6.5621E-01 6.5675E-01  
*-1(*1:*    S U MMA R Y        0 F  L  I BRA RY          P EAK U S AG E                    1: -!: 1: *-t:
: 1. 2833E-01 1. 2977E-01 9.707E-02 4.2438E-02 4.2439E-02 Ag-l0rl?cs-13 1. 9276E-01 1. 9279E-01 8.2205E-02 8.2399E-02 6.457E-02  
- Nuclide -      Ave~age      -------------     Peak - - - - - - - - - - - - -
);/'EU-15 . 1.1792E-01 1.1795E-01 B<, 1. 4004E-01 1.4011E-01 PB-212 & 4.1077E-01 4.1077E-01 1.5386E-0l  
Name       Code   ActlVlty       Energy     Activity Code MDA value pci/g           kev       pci/g               pci/g                   COMMENTS K-40         N   1. 3934E+01 1460.83 1. 393E+01     (     9.509E-01             9.62 G K co-60       F   6.5675E-01 1332.50 6.590E-01 (         9.714E-02             14.14 G K 1173.24 6.544E-01 ?(         8.770E-02           13 .48 G K CS-137           1.9279E-01 1.928E-0~
: 1. 5423E-01 1. 649E-01 ..PB-214 6.7792E-01 6.7792E-01  
I 661.66                     6.458E-02             21.32 G K o                                                   U ORTEC 9 v - i (1087) npp32       G53w3,05 13-MAR-2008 14:30:38 Page                             4 PBRF                                     Spectrum name: PB08-00798.An1 Nuclide       Ave activity     Energy      Activity   Code Peak MDA               Comments PB-212       N   4.1077E-01 238.63 4.108E-01 ?(         1. 649E-01           18.73 G K PB-214       N   6.7792E-01 351.93 6.779E-01     (     8.468E-02           13.02 G K BI-214       N   8.2966E-01 609.31 8.297E-01 ( 1.112E-01                     13.48 G  K 1764.49 O.OOOE+OO?           7.956E-01             0.00 G 1120.29 O.OOOE+OO & 1.071E+00                   152.75 G
: 1. 7651E-01 1.7763E-01 8.468E-02 BI-212 B< 1. 1889E+OO 1. 1889E+00 BI-214
( - This peak used in the nuclide activity average.
* 8.2966E-01 8.2966E-01 2.2374E-01 2.2548E-01 1.112E-01 RA-226 B< 1. 9488E+OO 1.9488E+OO TH-234 B< 1. 8498E+OO 1. 8498E+OO u-235 B< 4.9574E-01 4.9574E-01 AM-241 B< 1.4399E-01  
* peak is too wide, but only one peak in library.
: 1. 4399E-01 # -All peaks for activity calculation had bad Activity omitted from &-Activity omitted from total and all peaks had bad < -MOA value A -Activity printed, but activity < B -Activity < MOA and failed C -Area < Critical F -Failed fraction or key line H -Halflife limit Page 4
        - peak is part of a multiplet and this area went Page 3
*
 
* PB08-00798  
negative during deconvolution.
-----------------------------
PB08-00798
SUM MAR Y Total Activity ( 38.8 to 2014.2 kev) 8.4897500E-01 Total Decayed Activity ( 38.8 to 2014.2 kev) 8.4953296E-01 Analyzed project Reviewed by: __
          ?     -   peak is too narrow.
' 3 1008 R. Case Laboratory:
          @-       Peak is too wide at FW25M, but ok at FWHM.
PBRF Page 5
          %-       Peak fails sensitivity test.
*
          $         peak identified, but first peak of this nuclide failed one or more qualification tests.
* 1 PB08-00799 ORTEC g v -i (l087) npp32 G53W3.05 13-MAR-2008 14:35:55 Page PBRF spectrum name: PB08-00799.Anl sample description PB08-00799; SR99-010; PPH; RM2; FD2; 3/13/08 spectrum Filename:
          + -       Peak activity higher than counting uncertainty range.
z:\Lab\SAMPLE 08\PB08-00799.Anl Acquisition information Start time: Live ti me: . Real time: Dead time: Detector 1D: Detector system#2 DETECTOR (#130) calibration Filename:
peak activity lower than counting uncertainty range.
13-Mar-2008 14:29:50 300 301 [] COpy 250ml #73678-773 (Mc130)sept07 Energy Calibration Created: Zero offset: Gain: Quadratic:
                -   Peak outside analysis energy range.
Efficiency Calibration created: Type: uncertainty:
        &-         calculated peak centroid is not close enough to the library energy centroid for positive identlfication.
Coefficients:
P -       peakbackground subtraction
Library Main analysis Library Match Peak Analysis parameters Analysis engine: start channel: Stop channel: Peak rejection level: peak search sensitivity:
          }         Peak is too close to another for the activity to be found directly.
sample Size: Activity scaling factor: Detection limit method: Random error: systematic error: Fraction Limit: Background width: o 13-sep-2007 15:00:31 0.287 keY 0.251 keY/channel 2.324E-08 kev/channel A 2 13-Sep-2007 15:22:08 Po 1 ynomi a1 1.626 % -0.256697
Nuclide codes:                                   Peak codes:
-4.334323
T - Thermal Neutron Activation                   G -   Gamma Ray F - Fast Neutron Activation                     X -   x-Ray I - Fission Product                               P -   Positron Decay N - Naturally occurring Isotope                 S -   single-Escape P - Photon Reaction                             D-     Double-Escape C - charged Particle Reaction                   K - Key Line M - No MDA Calculation                           A - Not in Average R Coincidence Corrected                         '-- - coincidence Peak r
-0.092291 0.005686 pl umbrk 01.1 i bLibrary npp32 G53w3.05 155 ( 39.27kev )8144 ( 2049.92kev) 1.0000E+06/( 1.0000E+00*
H - Halfl ife 1i mi t exceeded o
4.2630E+02) 2.3458E+03 Nureg 4.16 1.0000000E+00 1.0000000E+00 0.000% best method (based on spectrum).
ORTEC g v -       (1087) npp32   G53W3.05 13-MAR-2008 14:30:38 Page               5 PBRF                                           spectrum name: PB08-00798.An1 1,
page 1 
* 1, *' 1,     SUM MAR Y         o F N U C L I DES             I N SAM P L E      *-:.-1,7."1.
*
Time of Count   Time Corrected uncertainty 2 Sigma Nuclide               Activity         Activity             Counting     Total         MOA pci/g           pci/g             pci/g         pci/g K-40           ~
* PB08-00799 PBRF ORTEC g v -i (1087) npp32 G53w3.05 13-MAR-2008 14:35:55 Spectrum name: PB08-00799.An1 Page 2 Half lives decay limit: Activity range factor: Min. step backg. energy 12.000 2.000 0.000 Corrections Status Comments Decay correct to date: YES 11-Mar-2008 08:35:00 Decay during acquisition: Decay during collection: True coincidence correction: Peaked background correction: Absorptinn (Internal): Geometry correction: Random summing: Energy Normalized diff: oJ.,)4 J,. oJ. J. SU M ivl ARY 0 F PEAKS IN RANGE '1,"1: f:
1.3934E+01     1.3934E+01       2.6816E+OO     2.7126E+OO 9.509E-01 co-60                   6.5621E-01     6.5675E-01       1. 2833E-01   1. 2977E-01 9.707E-02 Ag-l0rl?
* Peak Area Uncert FWHM Corrctn Nuclide Brnch. Act. Energy Factor Energy Ratio 77.07 57. 24.87 0.7 3 7.831E-02 238.69 81. 14.26 1.14 5.759E-02 238.63 43.300 6.864E-01 PB212 351. 98 80. 13.46 0.75 4.241E-02 351.93 37.600 1. 060E+00 PB214 609.15 50. 14.14 0.52 2.665E-02 609.31 46.100 8.600E-01 BI214 1461. 00 96. 10.21 1. 64 1. 362E-02 1460.83 11.000 1. 354E+01 K40 f,*
cs-13 4.2438E-02
* 1, **1: * '1: -1: 1: 1. UNI D E N TIFI ED PEAK SUMMA RY
: 1. 9276E-01 4.2439E-02
* 1: 1:  1.1: 1:
: 1. 9279E-01      8.2205E-02     8.2399E-02 6.457E-02
* 1: '!.. Peak Centroid Background Net Area Intensity uncert FWHM Suspected Channel Energy Counts Counts Cts/sec 2 sigma % keY Nuclide 305.31 77.07 48. 57. 0.190 49.75 0.732 PB-214 SM s -Peak fails shape D -Peak area L -peak written from unknown C -Area < Critical M -Peak is close to a library This section based on library: plumbrk01.lib ORTEC gv -1 (1087) npp32 G53w3.05 13-MAR-2008 14:35:55 page 3 PBRF Spectrum name: PB08-00799.An1
);/' EU-15               . 1.1792E-01     1.1795E-01 EU~15          B<,     1. 4004E-01     1.4011E-01 PB-212         &       4.1077E-01     4.1077E-01       1.5386E-0l     1. 5423E-01 1. 649E-01 PB-214         ..      6.7792E-01     6.7792E-01       1. 7651E-01   1.7763E-01 8.468E-02 BI-212         B<     1. 1889E+OO     1. 1889E+00 BI-214
"* 1: * '!( 1: 1. ** 1:'1.1.. i:1:
* 8.2966E-01     8.2966E-01       2.2374E-01     2.2548E-01 1.112E-01 RA-226         B<     1. 9488E+OO     1.9488E+OO TH-234         B<     1. 8498E+OO     1. 8498E+OO u-235           B<     4.9574E-01     4.9574E-01 AM-241         B<     1.4399E-01     1. 4399E-01
* IDE N T I F I E D PEAK SUMMA R Y ./:
          # - All peaks for activity calculation had bad shape.
          ~        Activity omitted from total
        & - Activity omitted from total and all peaks had bad shape.
          <     -MOA value printed.
A     - Activity printed, but activity < MOA.
B     - Activity < MOA and failed test.
C     - Area < Critical level.
F     - Failed fraction or key line test.
H     - Halflife limit exceeded Page 4
* PB08-00798
-----------------------------       SUM MAR Y           ---------------------------
Total Activity (   38.8 to 2014.2 kev) 8.4897500E-01 pci/g Total Decayed Activity (     38.8 to 2014.2 kev) 8.4953296E-01         pci/g Analyzed by:
project NAR Reviewed by: __   +ri--7~I'----::r"-""--                  ' 3 1008 R. Case Laboratory:   PBRF Page 5
* PB08-00799 ORTEC g v - i (l087) npp32 G53W3.05 13-MAR-2008 14:35:55 Page       1 PBRF                             spectrum name: PB08-00799.Anl sample description PB08-00799; SR99-010; PPH; RM2; FD2; 3/13/08 spectrum Filename: z:\Lab\SAMPLE 08\PB08-00799.Anl Acquisition information Start time:                 13-Mar-2008 14:29:50 Live ti me: .             300 Real time:               301 Dead time:                   0.39 %
Detector 1D:                     2 Detector system
      #2 DETECTOR (#130)
[] COpy calibration Filename:
250ml #73678-773 (Mc130)sept07 Energy Calibration Created:               13-sep-2007 15:00:31 Zero offset:           0.287 keY Gain:                   0.251 keY/channel Quadratic:             2.324E-08 kev/channel A2 Efficiency Calibration created:               13-Sep-2007 15:22:08 Type:                  Po 1ynomi a1 uncertainty:          1. 626 %
Coefficients:         -0.256697 -4.334323      0.664302
                                    -0.092291      0.005686 -0.000130 Library Files Main analysis library:      pl umbrk 01.1 i b Library Match width:        0.500 Peak stripping:              Library based Analysis parameters Analysis engine:             npp32    G53w3.05 start channel:           155 (      39.27kev )
Stop channel:           8144 ( 2049.92kev)
Peak rejection level:     25.000%
peak search sensitivity:     3 sample Size:                 4.2630E+02 Activity scaling factor:     1.0000E+06/( 1.0000E+00*    4.2630E+02) 2.3458E+03 Detection limit method:     Nureg 4.16 Random error:               1.0000000E+00 systematic error:           1.0000000E+00 Fraction Limit:             0.000%
Background width:           best method (based on spectrum).
o page 1
 
ORTEC g v - i (1087) npp32
* PB08-00799 G53w3.05 13-MAR-2008 14:35:55 Page                          2 PBRF                                                      Spectrum name: PB08-00799.An1 Half lives decay limit:                  12.000 Activity range factor:                    2.000 Min. step backg. energy                  0.000 Corrections                                                      Status              Comments Decay correct to date:                        YES        11-Mar-2008 08:35:00 Decay during acquisition:                    NO Decay during collection:                      NO True coincidence correction:                  NO Peaked background correction: NO Absorptinn (Internal):                        NO Geometry correction:                          NO Random summing:                              NO Energy Calibration Normalized diff:            0.0862 oJ.,)4 J,. oJ. J.
S U M ivl A R Y          0 F      P EAKS        I N RA NGE            '1,"1: f:
* 1.
Peak                          Area    Uncert FWHM        Corrctn      Nuclide Brnch.                   Act.         NUc Energy                                                    Factor      Energy    Ratio            pci/g 77.07                      57. 24.87    0.73    7.831E-02 238.69                        81. 14.26    1.14    5.759E-02      238.63    43.300        6.864E-01            PB212 351. 98                        80. 13.46    0.75    4.241E-02      351.93    37.600        1. 060E+00          PB214 609.15                        50. 14.14    0.52    2.665E-02      609.31    46.100        8.600E-01            BI214 1461. 00                           96. 10.21    1. 64  1. 362E-02    1460.83    11.000        1. 354E+01          K40 f,*
* 1, *
* 1: * '1: -1: 1: 1. UNI DE NT I F I ED                P EAK        S U M M A R Y
* 1: 1: 1. 1: 1:
* 1: '!..
                                                                                                              ~. ~:   ~:
Peak Centroid Background Net Area                           Intensity    uncert    FWHM Suspected Channel                    Energy        Counts        Counts      Cts/sec    2 sigma % keY                Nuclide 305.31                    77.07           48.            57.     0.190    49.75    0.732 PB-214                    SM s -        Peak        fails shape tests.
D-          Peak        area deconvoluted.
L -        peak        written from unknown list.
C-         Area        < Critical level.
M-         Peak        is close to a library peak.
This section based on library: plumbrk01.lib ORTEC g v -          1 (1087) npp32      G53w3.05 13-MAR-2008 14:35:55 page                          3 PBRF                                                      Spectrum name: PB08-00799.An1
"* 1: * '!( 1: 1. *
* 1:'1.1.. i:1:
* I D E NT I F I E D P E A K              S  U M M A R Y ./:
* 1:'k '1: 1:1: ** 1: -:."k "1.
* 1:'k '1: 1:1: ** 1: -:."k "1.
* Nuclide peak centroid Background Net Area Intensity Uncert FWHM channel Energy Counts Counts Cts/Sec 2 Sigma % keY AM-241 0.00 59.54 O. O. 0.000 0.00 0.000 O. O. 0.000 0.00 0.000 TH-234 0.00 63.29 TH-234 0.00 92.59 O. O. 0.000 0.00 0.000 EU-152 0.00 121.78 O. O. 0.000 0.00 0.000 EU-154 0.00 123.07 O. O. 0.000 0.00 0.000 U-235 0.00 143.76 O. O. 0.000 0.00 0.000 Page 2
* Nuclide                 peak           centroid Background Net Area             Intensity         Uncert FWHM channel Energy             Counts           Counts       Cts/Sec 2 Sigma % keY AM-241                           0.00     59.54             O.           O.     0.000           0.00           0.000 TH-234                          0.00      63.29            O.           O.     0.000           0.00           0.000 TH-234                           0.00     92.59             O.           O.     0.000           0.00           0.000 EU-152                           0.00     121.78             O.           O.     0.000           0.00           0.000 EU-154                           0.00     123.07             O.           O.     0.000           0.00           0.000 U-235                           0.00     143.76             O.           O.     0.000           0.00           0.000 Page 2
*
* PB08-00799 u-235 PB-212 EU-152 0.00 947.91 0.00 185.71 238.69 344.28 O. 15. O. O. 81. O. 0.000 0.270 0.000 0.00 28.53 0.00 0.000 1.135 0.000 PB-214 1398.30 351. 98 9. 80. 0.267 26.93 0.753s Ag-108m B1-214 0.00 2420.54 433.94 609.15 O. O. O. 50. 0.000 0.167 0.00 28.28 0.000 0.516s Ag-I08m cs-137 0.00 0.00 614.28 661.66 O. O. O. O. 0.000 0.000 0.00 0.00 0.000 0.000 Ag-108m EU-154 0.00 0.00 722.91 723.30 O. O. O. O. 0.000 0.000 0.00 0.00 0.000 0.000 B1-212 0.00 727.33 O. O. 0.000 0.00 0.000 EU-154 0.00 1004.72 O. O. 0.000 0.00 0.000 co-60 0.00 1173.24 O. O. 0.000 0.00 0.000 EU-154 0.00 1274.44 O. O. 0.000 0.00 0.000' co-60 0.00 1332.50 O. O. 0.000 0.00 0.000 EU-152 0.00 1408.01 O. O. 0.000 0.00 0.000 K-40 5805.24 1461. 00 O. 96. 0.320 20.41 1. 636 s -Peak fails shape D -Peak area A Derived peak SUM MAR Y o F LIB RAR Y PEA K USA GE ***** -Nuclide Average -------------
Peak Name Activlty Energy Activity Code MDA value pci/g kev pci/g pci/g COMMENTS K-40 N 1. 3539E+01 1460.83 1. 354E+Ol ( 1. 039E+00 10.21 G K PB-212 6.8636E-01 238.63 6.864E-01 ( 1'.759E-01 14.26 G K PB-214 1. 0601E+00 351.93 1.060E+00
@( 2.212E-01 13.46 G K 0 ORTEC g v -1 (l087) npp32 G53W3.05 13-MAR-2008 14:35:55 Page 4 PBRF Spectrum name: PB08-00799.Anl Nuclide activity Energy Activity Code Peak MDA Comments B1-214 8.6000E-01 609.318.600E-Ol ( 1.268E-01 14.14 G K 1764.49 O.OOOE+OO
% 8.569E-01 31.62 G 1120.29 O.OOOE+OO
% 6.215E-01 28.87 G ( -This peak used in the nuclide activity average. peak is too wide, but only one peak in
-peak is part of a multiplet and this area negative during ? -peak is too @ -peak is too wide at FW25M, but ok at % -peak fails sensitivity test. t.-peak identified, but first peak of this failed one or more qualification + -peak activity higher than


--peak activity lower than countlng uncertalnty = -peak outside analysis energy & -calculated peak is library energy centrold for posltlve Page 
u-235        0.00    185.71
* * \ ' PB08-00799 P peakbackground subtraction Peak is too close to another for the activity to be found directly.
* O.
Nuclide Peak codes: T -Thermal Neutron Activation F -Fast Neutron Activation I -Fission Product N -Naturally occurring Isotope P -photon Reaction C -charged Particle Reaction M No MDA Calculation R -Coincidence Corrected H -Halfl He l imi t exceeded G -Gamma Ray X -X-Ray P -Positron Decay S -Single-Escape D -Double-Escape K -Key Line A -Not in Average C -coincidence Peak Nuclide SUM MAR Y Time of Count Activity pci/g o F N U C L I Time Corrected Activity pci/g DES I N Uncertainty Counting pci/g SAM P L E 2 sigma Total pci/g '{-*-:.**
PB08-00799 O.      0.000
MDA ..K-40 1. 3539E+01 1.3539E+01 2.7636E+OO 2.7972E+00 1.039E+OO CO-60 B< 1. 0677E-01 1. 0686E-01 Ag-108mB<
* 0.00  0.000 PB-212      947.91    238.69          15.          81.        0.270    28.53  1.135 EU-152        0.00    344.28          O.            O.      0.000    0.00  0.000 PB-214    1398.30    351. 98          9.          80.        0.267    26.93  0.753s Ag-108m      0.00    433.94          O.            O.      0.000    0.00  0.000 B1-214    2420.54    609.15          O.          50.        0.167    28.28  0.516s Ag-I08m      0.00    614.28          O.            O.      0.000    0.00  0.000 cs-137        0.00    661.66          O.            O.      0.000    0.00  0.000 Ag-108m      0.00    722.91          O.            O.      0.000    0.00  0.000 EU-154        0.00    723.30          O.            O.      0.000    0.00  0.000 B1-212        0.00    727.33          O.            O.      0.000    0.00  0.000 EU-154        0.00    1004.72          O.            O.      0.000    0.00  0.000 co-60        0.00    1173.24          O.            O.      0.000    0.00  0.000 EU-154        0.00    1274.44          O.            O.      0.000    0.00  0.000' co-60        0.00    1332.50          O.            O.      0.000    0.00  0.000 EU-152        0.00    1408.01          O.             O.      0.000    0.00  0.000 K-40       5805.24    1461. 00          O.           96.       0.320    20.41  1. 636 s - Peak fails shape tests.
6.6716E-02 6.6717E-02 cs-137 B< 1. 3424E-01 1.3426E-01 EU-152 B< 1. 8601E-0l 1.8607E-01 EU-154 B< 1.7110E-01
D - Peak area deconvoluted.
: 1. 7118E-01 ,.PB-212 6.8636E-01 6.8636E-01 1.9581E-0l 1.9661E-01 1.759E-01 PB-214 & 1. 0601E+OO 1. 0601E+00 2.8545E-01 2.8745E-01 2.212E-01 B1-212 B< 1.2040E+OO
A Derived peak area, SUM MAR Y          o F    LIB R A R Y        PEA K        USA G E    *****
: 1. 2040E+00 0 ORTEC 9 v -1 (1087) npp32 G53w3.05 13-MAR-2008 14:35:55 Page PBRF spectrum name:
- Nuclide - Average            ------------- Peak -------------
B1-214 " 8.6000E-01 8.6000E-01 2.4324E-01 2.4520E-01 1.268E-01 RA-226 B< 2.3548E+00 2.3549E+00 TH-234 B< 1.8929E+00
Name    Code Activlty          Energy  Activity Code MDA value pci/g            kev    pci/g              pci/g          COMMENTS K-40      N    1. 3539E+01 1460.83 1. 354E+Ol    (    1. 039E+00   10.21 G K PB-212    N    6.8636E-01 238.63 6.864E-01     (    1'.759E-01   14.26 G K PB-214    N    1. 0601E+00 351.93 1.060E+00 @(      2.212E-01    13.46 G K 0
: 1. 8929E+OO u-235 B< 5.3764E-01 5.3764E-01 AM-241 B< 2.2330E-01 2.2330E-01 # -All peaks for activity calculation had bad *-Activity omitted from &-Activity omitted from total and all peaks had bad < -MDA value A -Activity printed, but activity < B -Activity < MDA and failed C -Area < Critical F -Failed fraction or key line H -Halflife limit
ORTEC g v -  1 (l087) npp32    G53W3.05 13-MAR-2008 14:35:55 Page            4 PBRF                                  Spectrum name: PB08-00799.Anl Nuclide  Ave activity      Energy    Activity    Code Peak MDA      Comments B1-214    N    8.6000E-01 609.318.600E-Ol ( 1.268E-01            14.14 G K 1764.49 O.OOOE+OO % 8.569E-01          31.62 G 1120.29 O.OOOE+OO % 6.215E-01          28.87 G
-----------------------------
( - This peak used in the nuclide activity average.
SUM MAR Y Total Activity ( 39.3 to 2049.9 kev) O.OOOOOOOE+OO pci/g Total Decayed Activity ( 39.3 to 2049.9 kev) O.OOOOOOOE+OO pci/g A.Analyzed by: project MAR 13 2008 Reviewed by: R.Case Laboratory:
peak is too wide, but only one peak in library.
PBRF page 4 
      - peak is part of a multiplet and this area went negative during deconvolution.
*
    ? - peak is too narrow.
* PB08-01265 ORTEC g v -1 (1087) npp32 G53w3.05 14-APR-2008 09:19:13 page 1 PBRF Spectrum name: PB08-01265.An1 sample description PB08-01265;SR99-52; PPH-RM3-FD3; 4/14/08 spectrum Filename:
    @ - peak is too wide at FW25M, but ok at FWHM.
z:\Lab\SAMPLE 08\PB08-01265.An1 Acquisition information Start time: 14-Apr-200808:18:54 Live time: 600 Real time: 604 Dead time: 0.70 % Detector 1D: 1 [J COpy Detector system#1 DETECTOR (#129) Calibration Filename:
    % - peak fails sensitivity test.            .
250ml #73678-773 (MC129) Jan08 , Energy calibration created: . Zero offset: Gain: Quadratic:
t.- peak identified, but first peak of this nuclide failed one or more qualification tests.
Efficiency calibration created: Type: uncertainty:
    + - peak activity higher than coun~ing uncert~inty range.
coefficients:
    - - peak activity lower than countlng uncertalnty range.
Library Files Main analysis library: Library Match Width: Peak stripping:
    = - peak outside analysis energy range.
Analysis parameters Analysis engine: Start channel: Stop channel: Peak rejection level: Peak search sensitivity:
    & - calculated peak centr~id is not.c~ose.enough.to ~he library energy centrold for posltlve ldentlflcatlon.
Sample Size: Activity scaling factor: Detection limit method: Random error: systematic error: Froaction Limit: Background width: o 09-Jan-2008
Page 3
-0.051 0.250
 
-8.299E-09 kev/channel A09-Jan-200809:15:56 polynomial 1.663 -0.338084
\ '
-4.099654
P - peakbackground subtraction
-0.082467 pl umbrk 01. 1i b Library npp32 G53w3.05 155 ( 38.73kev)8144 ( 2037.21kev) 25.000% 3 4.6250E+02 1.0000E+06/( 1.0000E+00*
* PB08-00799
4.6250E+02) 2.1622E+03 Nureg 4.16 1.0000000E+00
        }    Peak is too close to another for the activity to be found directly.
: 1. OOOOOOOE+OO best method (based on spectrum).
Nuclide Codes:                                  Peak codes:
page 1 
T - Thermal Neutron Activation                  G - Gamma Ray F - Fast Neutron Activation                    X - X-Ray I - Fission Product                            P - Positron Decay N - Naturally occurring Isotope                S - Single-Escape P - photon Reaction                            D - Double-Escape C - charged Particle Reaction                  K - Key Line M  No MDA Calculation                          A - Not in Average R - Coincidence Corrected                      C - coincidence Peak H - Halfl He l imi t exceeded SUM MAR Y             o F    N U C L I DES        I N SAM P L E    '{-*-:.**
* * ------------------------------------------------------------
Time of Count        Time Corrected    Uncertainty 2 sigma Nuclide        Activity            Activity          Counting    Total        MDA pci/g              pci/g           pci/g        pci/g K-40    ..     1. 3539E+01        1.3539E+01      2.7636E+OO    2.7972E+00 1.039E+OO CO-60 B<        1. 0677E-01         1. 0686E-01 Ag-108mB<      6.6716E-02          6.6717E-02 cs-137 B<      1. 3424E-01        1.3426E-01 EU-152 B<      1. 8601E-0l        1.8607E-01 EU-154 ,.B<    1.7110E-01          1. 7118E-01 PB-212          6.8636E-01          6.8636E-01      1.9581E-0l    1.9661E-01 1.759E-01 PB-214 &        1. 0601E+OO        1. 0601E+00    2.8545E-01    2.8745E-01 2.212E-01 B1-212 B<      1.2040E+OO          1. 2040E+00 0
PB08-01265 PBRF ORTEC g v -i (1087) npp32 G53W3.05 14-APR-2008 09:19:13 Spectrum name: PB08-01265.An1 Page 2 Half lives decay limit: Activity range factor: Min. step backg. energy 12:000 2.000 0.000 Corrections Status Comments Decay correct to date: YES 09-Apr-2008 09:17:00 Decay during acquisition:
ORTEC 9 v -    1  (1087) npp32        G53w3.05 13-MAR-2008 14:35:55 Page          5 PBRF                                      spectrum name: PB08-00799.An1 B1-214  "      8.6000E-01          8.6000E-01      2.4324E-01    2.4520E-01 1.268E-01 RA-226  B<      2.3548E+00          2.3549E+00 TH-234  B<      1.8929E+00          1. 8929E+OO u-235  B<      5.3764E-01         5.3764E-01 AM-241  B<      2.2330E-01          2.2330E-01
NO Decay during collection:
        # - All peaks for activity calculation had bad shape.
NO True coincidence correction:
        * - Activity omitted from total
NO Peaked background correction:
        &-  Activity omitted from total and all peaks had bad shape.
NO Absorption (Internal):
        < - MDA value printed.
NO Geometry correction:
A - Activity printed, but activity < MDA.
NO Random summing: NO Energy Normalized diff: *'1."1.1:* SU MMARY 0 F PEAKS I N RAN GE *'1.-/. *-I( peak Area Uncert FWHM Corrctn Nuclide Brnch. Act. Nuc Energy Factor Energy Ratio pci/g 74.78 125. 14.14 0.82 *8.364E-02 77 .18 180. 10.63 0.82 8.390E-02 185.78 75. 21. 93 0.90 7.485E-02 185.71 57.200 1. 706E-01 u235 186.21 3.590 2.722E+00 RA226 238.54 197. 9.64 0.97 6.443E-02 238.63 43.300 6.879E-01 PB212 295.13 98. 15.48 1. 07 5.498E-02 351.80 171. 9.17 0.98 4.767E-02 351.93 37.600 9.277E-01 PB214 609.16 115. 10.83 1.11 3.006E-02 609.31 46.100 8.083E-01 BI214 1120.51 30. 18.26 1. 25 1. 840E-02 1120.29 15.100 1.052E+00 BI214 1173.03 50. 16.95 0.34 1. 773E-02 1173.24 99.974 2.744E-01 c060 1332.63 39. 16.01 1.08 1. 598E-02 1332.50 99.986 2.381E-01 c060 1460.96 257. 6.24 1. 78 1. 481E-02 1460.83 11.000 1. 537E+01 K40
B - Activity < MDA and failed test.
C - Area < Critical level.
F - Failed fraction or key line test.
H - Halflife limit exceeded
      -----------------------------             SUM MAR Y ---------------------------
Total Activity (       39.3 to 2049.9 kev) O.OOOOOOOE+OO pci/g Total Decayed Activity (            39.3 to 2049.9 kev) O.OOOOOOOE+OO pci/g Analyzed by:        A.
PBRF                        project
                                  ,I;                          MAR 13 2008 Reviewed by:               /
Su                            R.Case Laboratory:      PBRF page 4
* PB08-01265 ORTEC g v -  1 (1087) npp32  G53w3.05 14-APR-2008 09:19:13 page      1 PBRF                              Spectrum name: PB08-01265.An1 sample description PB08-01265;SR99-52; PPH-RM3- FD3; 4/14/08 spectrum Filename: z:\Lab\SAMPLE 08\PB08-01265.An1 Acquisition information Start time:                  14-Apr-200808:18:54 Live time:                  600 Real time:                  604 Dead time:                    0.70 %
Detector 1D:                      1 Detector system
      #1 DETECTOR (#129)
[J    COpy Calibration Filename:
250ml #73678-773 (MC129) Jan08 Energy calibration created: .              09-Jan-2008 08:36:01 Zero offset:          -0.051 kev Gain:                  0.250 kev/channel Quadratic:            -8.299E-09 kev/channel A2 Efficiency calibration created:                09-Jan-200809:15:56 Type:                    polynomial uncertainty:            1. 663 %
coefficients:          -0.338084 -4.099654    0.610757
                                      -0.082467    0.004895-0.000109 Library Files Main analysis library:        pl umbrk 01. 1 i b Library Match Width:          0.500 Peak stripping:              Library based Analysis parameters Analysis engine:              npp32    G53w3.05 Start channel:              155 (    38.73kev)
Stop channel:              8144 ( 2037.21kev)
Peak rejection level:        25.000%
Peak search sensitivity:      3 Sample Size:                  4.6250E+02 Activity scaling factor:      1.0000E+06/( 1.0000E+00*    4.6250E+02) 2.1622E+03 Detection limit method:      Nureg 4.16 Random error:                1.0000000E+00 systematic error:            1. OOOOOOOE+OO .
Froaction Limit:              0.000%
Background width:            best method (based on spectrum).
o page 1
 
ORTEC g v - i (1087) npp32 PB08-01265 G53W3.05 14-APR-2008 09:19:13 Page                  2 PBRF                                            Spectrum name: PB08-01265.An1 Half lives decay limit:            12:000 Activity range factor:              2.000 Min. step backg. energy              0.000 Corrections                                            Status            Comments Decay correct to date:                  YES        09-Apr-2008 09:17:00 Decay during acquisition:                NO Decay during collection:                NO True coincidence correction:            NO Peaked background correction: NO Absorption (Internal):                  NO Geometry correction:                     NO Random summing:                         NO Energy Calibration Normalized diff:             0.0975
*'1."1.1:*       S U MMA R Y 0 F             P EAKS        I N   RAN G E * '1.-/. *-I(
peak                 Area   Uncert FWHM         Corrctn     Nuclide Brnch.           Act.       Nuc Energy                                           Factor     Energy     Ratio     pci/g 74.78             125. 14.14     0.82 *8.364E-02 77 .18             180. 10.63     0.82 8.390E-02 185.78                 75. 21. 93     0.90 7.485E-02         185.71 57.200     1. 706E-01 u235 186.21   3.590   2.722E+00 RA226 238.54               197. 9.64     0.97   6.443E-02     238.63 43.300     6.879E-01 PB212 295.13                 98. 15.48     1. 07   5.498E-02 351.80               171. 9.17     0.98   4.767E-02     351.93   37.600   9.277E-01         PB214 609.16               115. 10.83     1.11   3.006E-02     609.31   46.100   8.083E-01         BI214 1120.51                 30. 18.26     1. 25   1. 840E-02   1120.29   15.100   1.052E+00         BI214 1173.03                 50. 16.95     0.34   1. 773E-02   1173.24   99.974   2.744E-01       c060 1332.63                 39. 16.01     1.08   1. 598E-02   1332.50   99.986   2.381E-01         c060 1460.96                 257. 6.24     1. 78   1. 481E-02   1460.83   11.000   1. 537E+01       K40
* 1:1: 1: * *1:'1.***
* 1:1: 1: * *1:'1.***
* UN IDE NTI FI ED PEA K SUM MARY 1.'1: * '1. * *.,'; -k * * '!'. 1( peak centroid Background Net Area Intensity uncert FWHM Channel Energy Counts Counts cts/sec 2 sigma % keY Nuc ide 299.07 74.78 93. 125. 0.208 28.29 0.820 PB-214 D 308.64 77 .17 92. 180. 0.299 21.26 0.823 PB-214 D 742.67 185.78 51. 75. 0.125 43.86 0.900 U-235 sM 1179.71 295.13 33. 98. 0.163 30.95 1.075 PB-214 M s -Peak fails shape D -Peak area L -Peak written from unknown C -Area < critical M -Peak is close to a library This section based on library: plumbrk 01.lib o ORTEC g v -i (1087) npp32 G53W3.05 14-APR-2008 09:19:13 Page 3 PBRF Spectrum name: PB08-01265.An1 page 2
* U N IDE N T I F I E D              PEA K       SUM M A R Y 1.'1: * '1. * *.,'; -k * * '!'. 1(
*
peak centroid Background Net Area                     Intensity   uncert     FWHM sus~ected Channel             Energy     Counts         Counts     cts/sec   2 sigma % keY         Nuc ide 299.07             74.78           93.         125.       0.208     28.29   0.820   PB-214             D 308.64             77 .17         92.         180.       0.299     21.26   0.823   PB-214             D 742.67           185.78           51.           75.     0.125     43.86   0.900   U-235           sM 1179.71             295.13           33.           98.     0.163     30.95   1.075   PB-214             M s - Peak         fails shape tests.
* PB08-01265
D - Peak         area deconvoluted.
**************
L - Peak         written from unknown list.
1 DEN T 1 F 1 E D PEA K 5 U M MAR Y **************
C - Area         < critical level.
Nuclide Peak centroid Background Net Area Intensity Uncert FWHM channel Energy Counts Counts Cts/Sec 2 sigma % kev AM-241 0.00 59.54 O. O. . 0.000 0.00 0.000 TH-234 0.00 63.29 O. O. 0.000 0.00 0.000 TH-234 0.00 92.59 O. O. 0.000 0.00 0.000 EU-152 0.00 121. 78 O. O. 0.000 0.00 0.000 EU-154 0.00 123.07 O. O. 0.000 0.00 0.000 u-235 0.00 143.76 O. O. 0.000 0.00 0.000 u-235 0.00 185.71 O. O. 0.000 0.00 0.000 RA-226 0.00 186.21 O. O. 0.000 0.00 0.000 PB-212 953.56 238.54 49. 197. 0.328 19.27 0.965 EU-152 0.00 344.28 O. O. 0.000 0.00 0.000 PB-214 1406.21 351.80 15. 171. 0.284 18.33 0.977 Ag-108m B1-214 0.00 2434.89 433.94 609.16 O. 8. O. 115. 0.000 0.192 0.00 21.65 0.000 1.107s Ag-108m cs-137 0.00 0.00 614.28 661. 66 O. O. O. O. 0.000 0.000 0.00 0.00 0.000 0.000 Ag-108m EU-154 0.00 0.00 722.91 723.30 o. o. O. O. 0.000 0.000 0.00 0.00 0.000 0.000 B1-212 0.00 727.33 o. O. 0.000 0.00 0.000 EU-154 0.00 1004.72 o. O. 0.000 0.00 0.000 B1-214 4478.93 1120.51 O. 30. 0.050 36.51 1. 251s (0-60 EU-154 4688.88 0.00 1173.03 1274.44 4. O. 50. O. 0.083 0.000 33 .90 0.00 0.3435 0.000 CD-60 5326.92 1332.63 O. 39. 0.065 32.03 1. 0765 EU-152 0.00 1408.01 O. O. 0.000 0.00 0.000 K-40 5839.99 1460.96 O. 257. 0.428 12.48 1.782 5 -peak fails shape tests. D peak area deconvoluted.
M - Peak         is close to a library peak.
A Derived peak area. ***** 5UM MAR Y o F LIB RAR Y PEA K USA GE -Nuclide -
This section based on library: plumbrk 01.lib o
-------------
ORTEC g v - i (1087) npp32           G53W3.05 14-APR-2008 09:19:13 Page                 3 PBRF                                             Spectrum name: PB08-01265.An1 page 2
Peak Name code ActlVlty Energy Activity Code MDA value pci/g kev pci/g pci/g COMMENTS K-40 N 1.5366E+01 1460.83 1.537E+01 ( 4.407E-01 6.24 G K (0-60 I 2.5623E-01 1332.50 2.381E-01?( 4.500E-02 16.01 G K 1173.242.744E-01 ( 6.729E-02 16.95 G K o ORTEC g v -1 (1087) npp32 G53w3.05 14-APR-2008 09:19:13 Page 4 PBRF spectrum name: PB08-01265.An1 Nuclide Ave activity Energy Activity Code peak MDA Comments PB-212 N 6.8794E-01 238.63 6.879E-01 ( 1.234E-01 9.64 G K PB-214 N 9.2772E-01 351.93 9.277E-01 ( 1.139E-01 9.17 G K 81-214 N 8.0825E-01 609.318.083E-01 ( 1.117E-01 10.83 G K 1764.49 O.OOOE+OO  
 
& 5.640E-01 127.48 G page 3
************** 1 DEN T 1 F 1 E D PB08-01265 PEA K 5 U M MAR Y **************
*
Nuclide Peak       centroid Background Net Area             Intensity   Uncert FWHM channel Energy       Counts       Counts       Cts/Sec 2 sigma % kev AM-241       0.00     59.54           O.           O.     . 0.000     0.00   0.000 TH-234       0.00     63.29           O.           O.       0.000     0.00   0.000 TH-234       0.00     92.59           O.           O.       0.000     0.00   0.000 EU-152       0.00     121. 78           O.           O.       0.000     0.00   0.000 EU-154       0.00     123.07           O.           O.       0.000     0.00   0.000 u-235         0.00     143.76           O.           O.       0.000     0.00   0.000 u-235         0.00     185.71           O.           O.       0.000     0.00   0.000 RA-226       0.00     186.21           O.           O.       0.000     0.00   0.000 PB-212     953.56     238.54           49.       197.         0.328   19.27   0.965 EU-152       0.00     344.28           O.           O.       0.000     0.00   0.000 PB-214     1406.21     351.80           15.       171.         0.284   18.33   0.977 Ag-108m       0.00    433.94            O.            O.      0.000    0.00  0.000 B1-214     2434.89     609.16           8.       115.         0.192   21.65   1.107s Ag-108m       0.00     614.28           O.           O.       0.000    0.00  0.000 cs-137        0.00     661. 66          O.            O.      0.000    0.00  0.000 Ag-108m       0.00     722.91           o.           O.       0.000     0.00  0.000 EU-154        0.00     723.30            o.            O.      0.000     0.00  0.000 B1-212       0.00     727.33           o.           O.       0.000     0.00   0.000 EU-154       0.00   1004.72           o.           O.       0.000     0.00   0.000 B1-214     4478.93   1120.51           O.         30.         0.050   36.51   1. 251s (0-60     4688.88   1173.03           4.         50.         0.083   33 .90 0.3435 EU-154        0.00    1274.44            O.            O.      0.000    0.00  0.000 CD-60     5326.92   1332.63           O.         39.         0.065   32.03   1. 0765 EU-152       0.00   1408.01           O.           O.       0.000     0.00   0.000 K-40       5839.99   1460.96           O.       257.         0.428   12.48   1.782 5 - peak fails shape tests.
* PB08-01265 1120.29 1.052E+00  
D peak area deconvoluted.
+ 2.584E-01 18.26 G ( -Th;s peak used ;n the nucl;de act;v;ty average. Peak ;s too w;de, but only one peak in  
A Derived peak area.
-Peak part.of a and this area 'negatlve durlng deconvolutlon. ? -Peak is too @ -Peak is too wide at FW25M, but ok at % -peak fails sensitivity $-Peak identified, but first peak of this failed one or more qualification + -Peak activity higher than counting uncertainty --Peak activity lower than counting uncertainty -Peak outs;de analysis energy & -calculated peak centroid is not close enough to library energy centroid for positive P -Peakbackground  
*****   5 U M MAR Y         o F   LIB R A R Y         PEA K USA G E
} peak is too close to another for the to be found directly.
- Nuclide - Ave~age          ------------- Peak -------------
Nuclide codes: Peak T -Thermal Neutron Act;vation G -Gamma F -Fast Neutron Activation X -I -Fission Product P -positron N -Naturally occurring Isotope 5 -
Name    code ActlVlty          Energy    Activity Code MDA value pci/g             kev     pci/g             pci/g           COMMENTS K-40     N   1.5366E+01 1460.83 1.537E+01     (   4.407E-01     6.24 G K (0-60     I   2.5623E-01 1332.50 2.381E-01?(       4.500E-02   16.01 G K 1173.242.744E-01 (         6.729E-02   16.95 G K o
P -photon Reaction D -
ORTEC g v -   1 (1087) npp32     G53w3.05 14-APR-2008 09:19:13 Page           4 PBRF                                 spectrum name: PB08-01265.An1 Nuclide   Ave activity     Energy     Activity   Code peak MDA     Comments PB-212   N   6.8794E-01 238.63 6.879E-01     (   1.234E-01     9.64 G K PB-214   N   9.2772E-01 351.93 9.277E-01     (   1.139E-01     9.17 G K 81-214   N   8.0825E-01 609.318.083E-01 (         1.117E-01   10.83 G K 1764.49 O.OOOE+OO &       5.640E-01   127.48 G page 3
C -charged Particle Reaction K -Key M -NO MDA Calculation A -Not in R -coincidence corrected C -Coincidence H -Halflife 1 i mi t o ORTEC g v -; (1087) npp32 G53w3.05 14-APR-2008 09:19:13 page PBRF spectrum name:  
* PB08-01265 1120.29 1.052E+00 +       2.584E-01
***** 5UM MAR Y OF NUCLI DES IN 5 AMPLE Time of count Time Corrected uncertainty 2 Nuclide Activity Activ;ty counting Total pci/g pci/g pci/g K-40
* 18.26 G
* 1. 5366E+01 1.5366E+01  
( - Th;s peak used ;n the nucl;de act;v;ty average.
: 1. 9170E+00 i. 9798E+00 4.407E-01 co-60 2.5577E-01 2.5623E-01 5.9750E-02 6.0316E-02 4.492E-02 Ag-108mB<
Peak ;s too w;de, but only one peak in library.
5.4565E-02 5.4566E-02 cs-137 B< 4.0042E-02 4.0055E-02 EU-152 B< 1. 1165E-01 1. 1172E-01 EU-154 B< 1. 0086E-01 1. 0097E-01 PB-212
      - Peak ~s part.of a multiple~ and this area went
* 6.8794E-01 6.8794E-01  
        'negatlve durlng deconvolutlon.                 .
: 1. 3258E-01 1. 3376E-01 1. 234E-01 PB-214
    ? - Peak is too narrow.
* 9.2771E-01 9.2772E-01  
    @ - Peak is too wide at FW25M, but ok at FWHM.
: 1. 7009E-01 1. 7269E-01 1. 139E-01 BI-212 B< 1. 0880E+00 1. 0880E+00 BI-214 & 8.0825E-01 8.0825E-01  
  % - peak fails sensitivity test.
: 1. 7500E-01 1. 7743E-01 1.117E-01 RA-226 B< 1. 6310E+00 1. 6310E+00 TH-234 B< 1. 1517E+00 1.
    $ - Peak identified, but first peak of this nuclide failed one or more qualification tests.
u-235 B< 3.0181E-01 AM-241 B< 1. 7088E-01  
    + - Peak activity higher than counting uncertainty range.
# -All peaks for activity calculation had bad .. Activity omitted from & -Activity omitted from total and all peaks had bad < -MDA value Page 4
    - - Peak activity lower than counting uncertainty range.
*
      - Peak outs;de analysis energy range.
* A-printed, but activity < B -ActlVlty < MDA and failed c -Area < critical F -Failed fraction or key line H -Halflife limit  
  & - calculated peak centroid is not close enough to the library energy centroid for positive identlfication.
-----------------------------
P - Peakbackground subtraction
5 U M MAR Y Total Activity ( 38.7 to 2037.2 keV) 2.5577208E-Ol pci/g Total Decayed Activity ( 38.7 to 2037.2 kev) 2.5622919E-Ol pci/g Analyzed by: project APR 4 200B Reviewed by: R. Case Laboratory:
    }   peak is too close to another for the activity to be found directly.
PBRF page 5 ORTEC g v -i (1087) npp32 PBRF Sample description PB08-00794; SR99-005; PPH;
Nuclide codes:                             Peak codes:
* Page 1 Spectrum Filename:
T - Thermal Neutron Act;vation             G - Gamma Ray F - Fast Neutron Activation               X - X-Ray I - Fission Product                         P - positron Decay N - Naturally occurring Isotope           5 - single-Escape P - photon Reaction                       D - Double-Escape C - charged Particle Reaction               K - Key Line M - NO MDA Calculation                     A - Not in Average R - coincidence corrected                   C - Coincidence peak H - Halflife 1 i mi t exceeded o
z:\Lab\SAMPLE 08\PB08-00794.An1 Acquisition information Start time: Live time: Real time: Dead time: Detector ID: Detector system#2 DETECTOR (#130) Calibration Filename:
ORTEC g v - ; (1087) npp32       G53w3.05 14-APR-2008 09:19:13 page           5 PBRF                                   spectrum name: PB08-01265.An1
13-Mar-2008 15:20:00 1500 1505 [] COrY 250ml #73678-773 (MC130)Sept07 Energy Calibration created: Zero offset: Gain: Quadratic:
*****     5  U M MAR Y     OF     NUCLI DES             I N 5 AMP L E Time of count   Time Corrected uncertainty 2 Sigma Nuclide         Activity         Activ;ty         counting       Total           MDA pci/g           pci/g           pci/g           pc;/g K-40
Efficiency calibration Created: Type: uncertainty:
* 1. 5366E+01     1.5366E+01     1. 9170E+00     i. 9798E+00 4.407E-01 co-60           2.5577E-01     2.5623E-01     5.9750E-02       6.0316E-02   4.492E-02 Ag-108mB<       5.4565E-02     5.4566E-02 cs-137 B<       4.0042E-02     4.0055E-02 EU-152 B<       1. 1165E-01     1. 1172E-01 EU-154 B<       1. 0086E-01     1. 0097E-01 PB-212
coefficients:
* 6.8794E-01     6.8794E-01     1. 3258E-01     1. 3376E-01 1. 234E-01 PB-214
Library Main analysis . Library Match width: Peak stripping:
* 9.2771E-01     9.2772E-01     1. 7009E-01     1. 7269E-01 1. 139E-01 BI-212 B<       1. 0880E+00     1. 0880E+00 BI-214 &         8.0825E-01     8.0825E-01     1. 7500E-01     1. 7743E-01 1.117E-01 RA-226 B<       1. 6310E+00     1. 6310E+00 TH-234 B<       1. 1517E+00     1. 1517E+00 u-235 B<         3.0181E-01      3.0181E-01 AM-241 B<       1. 7088E-01    1.7088E-01
Analysis parameters Analysis engine: Start channel: Stop channel: Peak rejection level: peak search sensitivity:
  # - All peaks for activity calculation had bad shape.
sample Size: Activity scaling factor: Detection limit method: Random error: systematic error: Fraction Limit: Background width: o 13-sep-2007 15:00:31 0.287 keV 0.251 2.324E-08 kev/channel A13-Sep-2007 Pol ynomi 1.626 -0.256697
  .. Activity omitted from total
-4.334323
  & - Activity omitted from total and all peaks had bad shape.
-0.092291 0.005686 plumbrk 01.1ib Library npp32 G53w3.05 155 ( 39.27kev ) 8144 ( 2049.92kev) 25.000% 3 4.2840E+02 1.0000E+06/( 1.0000E+00*
  < - MDA value printed.
4.2840E+02) 2.3343E+03 Nureg 4.16 best method (based on spectrum).
Page 4
page 1
 
* * ------------------------------------------------------------
A  - Act~v~ty
ORTEC g v -i (1087) npp32 G53w3.05 13-MAR-2008 15:48:34 Page PBRF Spectrum name:
* PB08-01265 printed, but activity < MDA.
Half lives decay limit: Activity range factor: Min. step backg. energy Corrections Status Decay correct to date: YES 11-Mar-2008 Decay during acquisition: Decay during collection: True coincidence correction: Peaked background correction: Absorption (Internal): Geometry Random summing: Energy Normalized diff:
B - ActlVlty < MDA and failed test.
-!: * "/,"1.. "'/."1:1.
c - Area < critical level.
F - Failed fraction or key line test.
H - Halflife limit exceeded
-----------------------------     5 U M MAR Y       ---------------------------
Total Activity (    38.7 to 2037.2 keV) 2.5577208E-Ol pci/g Total Decayed Activity (     38.7 to 2037.2 kev) 2.5622919E-Ol pci/g Analyzed by:
project Reviewed by:                                        APR   4 200B R. Case Laboratory:   PBRF page 5
 
ORTEC g v - i (1087) npp32                                   Page  1 PBRF Sample description PB08-00794; SR99-005; PPH; RM4;{~~~
Spectrum Filename: z:\Lab\SAMPLE 08\PB08-00794.An1 Acquisition information Start time:                 13-Mar-2008 15:20:00 Live time:               1500 Real time:               1505 Dead time:                 0.36 %
Detector ID:                     2 Detector system
      #2 DETECTOR (#130)
Calibration
[] COrY Filename:
250ml #73678-773 (MC130)Sept07 Energy Calibration created:             13-sep-2007 15:00:31 Zero offset:           0.287 keV Gain:                 0.251 kev/channel Quadratic:             2.324E-08 kev/channel A2 Efficiency calibration Created:               13-Sep-2007 15:22:08 Type:                 Pol ynomi al uncertainty:           1. 626 %
coefficients:         -0.256697 -4.334323    0.664302
                                    -0.092291    0.005686 -0.000130 Library Files Main analysis library:      plumbrk 01.1ib
        . Library Match width:       0.500 Peak stripping:             Library based Analysis parameters Analysis engine:           npp32    G53w3.05 Start channel:           155 (    39.27kev )
Stop channel:           8144 ( 2049.92kev)
Peak rejection level:     25.000%
peak search sensitivity:   3 sample Size:               4.2840E+02 Activity scaling factor:   1.0000E+06/( 1.0000E+00*    4.2840E+02) 2.3343E+03 Detection limit method:     Nureg 4.16 Random error:               1.0000000E+00 systematic error:           1.0000000E+00 Fraction Limit:             0.000%
Background width:           best method (based on spectrum).
o page 1
 
ORTEC g v - i (1087) npp32
* PB08-00794 G53w3.05 13-MAR-2008 15:48:34 Page                        2 PBRF                                              Spectrum name: PB08-00794.An1 Half lives decay limit:              12.000 Activity range factor:                2.000 Min. step backg. energy                0.000 Corrections                                              Status            Comments Decay correct to date:                    YES        11-Mar-2008 08:15:00 Decay during acquisition:                  NO Decay during collection:                  NO True coincidence correction:              NO Peaked background correction: NO Absorption (Internal):                    NO Geometry correcti~n:                      NO Random summing:                            NO Energy calibration Normalized diff:            0.1333
*-!~* -!:
* S U M MA R Y 0 F              P EA KS        I N RAN G E          "/,"1.. "'/."1:1.
Peak                  Area    uncert FWHM        corrctn    Nuclide Brnch.                      Act. Nuc Energy                                            Factor      Energy      Ratio              pcijg 74.83                142. 18.95    0.92    7.837E-02 77 .05                192. 13.56    0.92    7.831E-02 186.04                  133. 19.28    0.79    6.693E-02    185.71    57.200                PBC<MDA u235 186.21      3.590        2.334E+00 RA226 238.70                  301. 7.95    1.06    5.759E-02    238.63    43.300        5.082E-01 ps212 295.34                  196. 10.80    1. 20  4.903E-02 352.03                  277 . 7.90    1. 06  4.240E-02    351.93    37.600        7.314E-01        PB214 609.50                  190. 9.85    0.92    2.665E-02    609.31    46.100*        6.504E-01        BI214 661. 68                113. 12.92    0.87    2.492E-02    661. 66    85.100        2.241E-01        cS137 1120.77                    74. 19.94    1.11    1. 660E-02  1120.29    15.100        1. 250E+00      BI214 1173.23                    50. 16.12    0.87    1. 604E-02  1173.24    99.974        1. 326E-01      c060 1333.26                    50. 18.65    0.30    1. 459E-02  1332.50    99.986        1.428E-01        c060 1461.01                  524. 4.37    1.71    1. 362E-02  1460.83    11. 000        1. 471E+01      K40 1764.77                    44. 15.08    0.94    1. 180E-02  1764.49    15.400        1. 018E+00      B1214
;.1:1:1:1: **
* 1:* 1:-/. U N IDE N T I F I E D              PEA K        SUM M A R Y -:.. -:.. **1.-1.. 1.. *1.. 1."1,"1,"
Peak Centroid Background Net Area                      Intensity    Uncert      FWHM Suspected Channel              Energy      Counts        Counts    CtsjSec    2 sigma % kev                    Nuclide 296.40                74.76        291.          142.      0.095    37.90    0.922 PB-214                  D 305.23                76.98        241.          192.      0.128    27 .12    0.924 PB-214                  D 1173.10              295.34            56.          196.      0.131    21. 60    1. 201 PB-214                M s - Peak          fails shape tests.
D - Peak          area deconvoluted.
L - Peak          written from unknown list.
C - Area          < Critical level.
M - Peak          is close to a library peak.
This section based on library: plumbrk 01.lib o
ORTEC g v - i (1087) npp32              G53w3.05 13-MAR-2008 15:48:34 Page                        3 PBRF                                              Spectrum name: PB08-00794.An1 page 2
* PB08-00794 "1: 1.-1. 1: 1.
* 1. 1: *
* 1, '* -1: '1: I DEN T I F I E D            P EA K        SUM MAR      Y **************
Nuclide                  Peak              Centroid    Background      Net Area        Intensity  Uncert FWHM Channel Energy                Counts          Counts          Cts/Sec 2 sigma % kev AM-241                            0.00        59.54              O.              O.      0.000    0.00    0.000 TH-234                            0.00        63.29              O.              O.      0.000    0.00    0.000 TH-234                            0.00        92.59              O.              O.      0.000    0.00    0.000 EU-152                            0.00        121. 78            O.              O.      0.000    0.00    0.000 EU-154                            0.00        123.07              O.              O.      0.000    0.00    0.000 u-235                            0.00        143.76              O.              O.      0.000    0.00    0.000 u-235                            0.00        185.71              O.              O.      0.000    0.00    0.000 RA-226                    738.56            186.04          127.          133.          0.089    38.57    0.7925 PB-212                    947.95            238.70            82.          301.          0.201    15.90    1.058 EU-152                            0.00        344.28              O.              O.      0.000    0.00    0.000 PB-214                  1398.50              352.03            47.          277 .        0.185    15.79    1.065 Ag-108m                          0.00        433.94              O.              O.      0.000    0.00    0.000 BI-214                    2421. 94            609.50            32.          190.          0.127    19.69    0.916s Ag-108m                          0.00        614.28              O.              O.      0.000    0.00    0.000 cS-137                    2629.33            661. 68          20.          113.          0.075    25.83    0.8715 Ag-108m                          0.00        722.91            "u .            O.      0.000    0.00    0.000 EU-154                          0.00        723.30            O.              O.      0.000    0.00    0.000 BI-212                          0.00        727.33            O.              O.      0.000    0.00    0.000 EU-154                          0.00        1004.72            O.              O.      0.000    0.00    0.000 BI-214                    4453.63            1120 ..77          20.            74.        0.050    39.89    1.1155 co-60                    4662.07            1173.23              4.            50.        0.034    32.24    0.8735 EU-154                          0.00        1274.44            O.              O.      0.000    0.00    0.000 co-60                    5297.81            1333.26            6.            50.        0.033    37.31    0.3045 EU-152                          0.00        1408.01            O.              O.      0.000    0.00    0.000 K-40                      5805.30            1461. 01            O.          524.          0.349    8.74    1.711 BI-214                  7011. 73            1764.77            O.            44.        0.029    30.15    0.9445 s - peak fails shape tests.
D - peak area deconvoluted.
A Derived peak area.
  *****. SUM MAR Y                                    o F    LIB R A R Y PEA K USA G E
- Nuclide - Ave~age                                    ------------- Peak -------------
Name              Code Actlvlty                        Energy    Activity Code MDA value pci/g                  kev      pci/g                pci/g          COMMENTS K-40                    N        1. 4707E+Ol 1460.83 1. 471E+01      (    2.069E-01    4.37 G  K co-60                    F        1. 3771E-01 1332.50 1. 428E-01      (    3.936E-02    18.65 G  K 1173.24 1. 326E-01      (    3.000E-02    16.12 G  K 0
ORTEC g v - i (1087) npp32                    G53w3.05 13-MAR-2008 15:48:34 Page              4 PBRF                                                          spectrum name: PB08-00794.An1*
Nuclide                  Ave activity                Energy      Activity      Code Peak MDA      Comments cs-137                  I        2.2413E-01 661.66 2.241E-01      .c    4.671E-02    12.92 G K PB-212                  N        5.0817E-01 238.63 5.082E-0l        (    7.559E-02    7.95 G K PB-214                  N        7.3142E-Ol Page 3
* PB08-00794 351.93 7.314E-01 ( 9.110E-02
* 7.90 G K BI-214    N    6.5040E-01 609.31 6.504E-01 (      9.951E-02      9.85 G K 1764.49 1. 018E+00 +      1. 705E-01    15.08 G 1120.29 1. 250E+00 +      3:908E-01    19.94 G RA-226    N    2.3339E+00 186.21 2.334E+00 *( 9.655E-01          19.28 G K
( - This peak used in the nuclide activity average.
Peak is too wide, but only one peak in library.
      - Peak is part of a multiplet and this area went negative during deconvolution.
  ? - Peak is too narrow.
  @ - Peak is too wide at FW25M, but ok at FWHM.
  % - Peak fails sensitivity tEst.
  $ - Peak identified, but first peak of this nuclide failed one or more qualification tests.
  + - peak activity higher than counting uncertainty range.
  - - Peak activity lower than counting uncertainty range.
      - Peak outside analysis energy range.
  & - Calculated peak centroid is not close enough to the library energy centroid for positive identlfication.
P - peakbackground subtraction
  }    Peak is too close to another for the activity to be found directly.
Nuclide codes:                            Peak Codes:
T - Thermal Neutron Activation            G - Gamma Ray F - Fast Neutron Activation                X X-Ray I - Fission Product                        P    Positron Decay N Naturally occurring Isotope              S    single-Escape P - photon Reaction                        D Double-Escape C - charged Particle Reaction              K Key Line M - NO MDA Calculation                    A Not in Average R Coincidence Corrected                    C Coincidence Peak H Halflife limit exceeded o
ORTEC g v -      (1087) npp32    G53w3.05 13-MAR-2008 15:48:34 page            5 PBRF                                  spectrum name: PB08-00794.An1
*****    SUM MAR Y        o  F    N U C L I DES        I N SAM P L E Time of Count    Time corrected    uncertainty 2 sigma Nuclide      Activity          Activity          counting      Total          . MDA pci/g            pci/g          pCi/g          pCi/g K-40    ~
: 1. 4707E+01      1. 4707E+01    1.2850E+00      1.3681E+OO    2.069E-01 co-60          1. 3760E-01      1. 3771E-01    3.3949E-02      3.4232E-02    3.932E-02 Ag-108mB<      2.9858E-02      2.9859E-02 cs-13i        2.2410E-01      2.2413E-01    5.7895E-02      5.8335E-02    4.670E-02 EU-152 B<      1.1821E-01      1. 1825E-0l EU-154 B<      7.3223E-02      7.3260E-02 PB-212  ~
5.08llE-01      5.08llE-01    8.0775E-02      8.1834E-02    7.559E-02 PB-214 ..      7.3141E-0l      7.3142E-01    1. 1551E-01    1. 1784E':-Ol 9.110E-02 81-212 B<      8.3351E-01      8.3351E-01 BI-214
* 6.5039E-01      6.5040E-01    1.2808E-01      1. 3020E-01  9.951E-02 RA-226 &      2.3339E+OO      2.3339E+OO    9.0014E-01      9.3380E-01    9.655E-01 page 4
 
TH-234 B<    7.3876E-Ol
* 7.3876E-Ol PB08-00794 u-235 B<      2.4401E-Ol    2.4401E-Ol AM-241 B<    1. 0412E-Ol    1. 0413E-Ol
  # - All peaks for activity calculation had bad shape.
* Activity omitted from total
  &-  Activity omitted from total and all peaks had bad shape.
  < - MDA value printed.
A-  Activity printed, but activity < MDA.
B - Activity < MDA and failed test.
C - Area < Critical level.
F - Failed fraction or key line test.
H-  Halflife limit exceeded
-----------------------------      5 U M MAR Y      ---------------------------
Total Activity (    39.3 to 2049.9 keV) 3.6169705E-Ol pci/g Total Decayed Activity (    39.3 to 2049.9 kev) 3.6184323E-Ol      pCi/g Analyzed by:
project Reviewed by:                                      MAR 13 2008 A. Case Laboratory:  PBRF Page 5
* PB08-01218 ORTEC g v -  1 (l087) npp32  G53w3.05 07-APR-2008 17:27:42 Page      1 PBRF                              Spectrum name: PB08-01218.An1 sample description PB08-01218; SR99-37; PPH RM 4; FD4-1B; 4/7/08 spectrum Filename: z:\Lab\SAMPLE 08\PB08-01218.An1 Acquisition information Start time:                  07-Apr-2008 17:21:54 Live time:                300 Real time:                301 Dead time:                  0.17 %
Detector 1D:                      3 Detector system
      #3 DETECTOR (#131) calibration Filename:
[j    COpy 250ml #73678-773 (MC131) Sept07 Energy calibration created:                05-Sep-2007 16:56:38 Zero offset:            0.565 kev Gain:                  0.247 kev/channel Quadratic:              5.022E-08 kev/channel A2 Efficiency calibration created:                05-Sep-2007 17:17:39 Type:                  polynomial uncertainty:            1. 204 %
Coefficients:          -0.304311 -4.249899    0.669559
                                      -0.094002    0.005803 -0.000133 Library Files Main analysis library:      pl umbrk 01.1 i b Library Match width:        0.500 Peak stripping:              Library based Analysis parameters Analysis engine:            npp32    G53w3.05 Start channel:            155 (    38.83kev )
Stop channel: .          8144 ( 2014.22kev)
Peak rejection level:      25.000%
peak search sensitivity:    3 sample Size:                4.6560E+02
        . Activity scaling factor:    1.0000E+06/( 1.0000E+00*    4.6560E+02) 2.1478E+03 Detection limit method:      Nureg 4.16 Random error:                1.0000000E+00 systematic error:            1. OOOOOOOE+OO Fraction Limit:              0.000%
Background width:            best method (based on spectrum).
o page 1
 
ORTEC g v - i (1087) npp32 PB08-01218 G53w3.05 07-APR-2008 17:27:42 Page                                          2 PBRF                                            Spectrum name: PB08-01218.An1 Half lives decay limit:          12.000 Activity range factor:            2.000 Min. step backg. energy          0.000 Corrections                                            Status              Comments Decay correct to date:                YES          02-Apr-2008 13:42:00 Decay during acquisition:            NO Decay during collection:              NO True coincidence correction:          NO Peaked background correction: NO Absorption (Internal):                NO Geometry correction:                  NO Random summing:                      NO Energy Calibration Normalized diff:            0.1988 1,"1,"1:"/,-1,-
S U MMA R Y 0 F            P EA KS        I N RAN G E          .) * .).-'* .J-.J.
peak                Area    uncert FWHM        Corrctn      Nuclide Brnch.                      Act.                  Nuc Energy                                          Factor      Energy    Ratio              pci/g 63.68            72. 23.25    0.82    7.980E-02        63.29    4.800        3.627E+00 TH234 77 .41            54. 24.00    0.88    8.257E-02 93.22            53. 23.03    1.17    8.166E-02        92.59    5.580        2.251E+00                        TH234 186.45              37. 23.09    0.87    7.184E-02      186.21    3.590        2.776E+00                        RA226 238.86              53. 17.19    1. 31  6.196E-02      238.63    43.300        3.822E-01                        ps212 351.95              64. 12.50    0.86    4.555E-02      351. 93  37.600        7.231E-01                        PB214 1460.52                127. 8.87    0.80    1. 387E-02    1460.83    11.000        1. 611E+01                        K40
*-f,. * * ""*'1;***** U N I D E N T I F I E D              P EA K        S U M M A R Y ...... " .. " " ....
J- -'~ -'- -'- -'-.). -,_ oJ. -'- -'. -,.-,_
                                                                                                                          ,~                " "
Peak Centroid Background Net Area                  Intensity    Uncert    FWHM suspected Channel              Energy    Counts        Counts      cts/sec    2 sigma % keY                    Nuclide 311.29          77 .41          38.            54.      0.180      48.01    0.876 s - peak        fails shape tests.
D  Peak        area deconvoluted.
L - Peak        written from unknown list.
C - Area        < Critical level.
This section based on library: plumbrk 01.lib o
ORTEC g v -    (1087) npp32      G53w3.05 07-APR-2008 17:27:42 Page                                        3 PBRF                                            Spectrum name: PB08-01218.An1
************** IDE N T I FIE D                        PEA K        SUM MAR Y **************
Nuclide peak                  Centroid Background Net Area            Intensity          Uncert FWHM Channel Energy      Counts          Counts      cts/Sec 2 sigma % keY AM-241                0.00      59.54            O.            O.      0.000            0.00                  0.000 TH-234              255.67      63.68            46.          72.        0.238        46.49                    0.821 TH-234              375.34      93.22            24.          53.        0.177        46.06                    1.173s EU-152                0.00    121.78            O.            O.      0.000            0.00                  0.000 EU-154                0.00    123.07            O.            O.      0.000            0.00                  0.000 page 2


==SUMMARY==
u-235          0.00  143.76
0 F PEAKS I N RAN GE Peak Area uncert FWHM corrctn Nuclide Brnch. Act. Nuc Energy Factor Energy Ratio pcijg 74.83 142. 18.95 0.92 7.837E-02 77 .05 192. 13.56 0.92 7.831E-02 186.04 133. 19.28 0.79 6.693E-02 185.71 57.200 PBC<MDA u235 186.21 3.590 2.334E+00 RA226 238.70 301. 7.95 1.06 5.759E-02 238.63 43.300 5.082E-01 ps212 295.34 196. 10.80 1. 20 4.903E-02 352.03 277 . 7.90 1. 06 4.240E-02 351.93 37.600 7.314E-01 PB214 609.50 190. 9.85 0.92 2.665E-02 609.31 46.100* 6.504E-01 BI214 661. 68 113. 12.92 0.87 2.492E-02 661. 66 85.100 2.241E-01 cS137 1120.77 74. 19.94 1.11 1. 660E-02 1120.29 15.100 1. 250E+00 BI214 1173.23 50. 16.12 0.87 1. 604E-02 1173.24 99.974 1. 326E-01 c060 1333.26 50. 18.65 0.30 1. 459E-02 1332.50 99.986 1.428E-01 c060 1461.01 524. 4.37 1.71 1. 362E-02 1460.83 11. 000 1. 471E+01 K40 1764.77 44. 15.08 0.94 1. 180E-02 1764.49 15.400 1. 018E+00 B1214 ;.1:1:1:1:
* O.
***1:* 1:-/. -:.. **1.-1.. 1.. *1.. 1."1,"1,"UN IDENTI FI ED PEA K  
PB08-01218 O.       0.000
* 0.00  0.000 u-235          0.00  185.71          O.            O.       0.000    0.00  0.000 RA-226      752.93    186.45          9.         37.       0.123  46.18  0.872 PB-'212    965.16    238.86        10.           53.       0.177  34.38  1. 311 EU-152        0.00    344.28          O.           O.       0.000    0.00  0.000 PB-214    1423.09    351.95          O.         64.       0.213  25.00  0.855s Ag-108m        0.00  433.94          O.             O.       0.000    0.00  0.000 B1-214        0.00    609.31         O.            O.       0.000    0.00  0.000 Ag-108m        0.00    614.28          O.             O.       0.000    0.00  0.000 cs-137        0.00    661.66         O.             O.       0.000    0.00  0.000 Ag-108m        0.00    722.91          O.             O.       0.000    0.00  0.000 EU-154        0.00    723.30          O.             O.       0.000    0.00  0.000 B1-212        0.00    727.33          O.             O.       0.000    0.00  0.000 EU-154        0.00  1004.72          O.             O.      0.000    0.00  0.000 B1-214        0.00  1120.29          O.          . O.       0.000    0.00   0.000 co-60          0.00  1173.24          O.             O.       0.000    0.00  0.000 EU-154        0.00  1274.44          O.             O.       0.000    0.00  0.000 co-60          0.00  1332.50          O.            O.      0.000    0.00  0.000 EU-152        0.00  1408.01          O.            O.      0.000    0.00  0.000 K-40      5907.31  1460.52          O.        127.        0.423  17.75  0.799s B1-214        0.00  1764.49          O.            O.      0.000    0.00  0.000 s - peak fails shape tests.
D - Peak area deconvoluted.
A Derived peak area.
  *****    SUM MAR Y        a F    LIB R A R Y PEA K USA G E
- Nuclide - Ave~age          ------------- Peak -------------
Name      code Actlvlty        Energy  Activity Code MDA value pci/g          kev    pci/g              pci/g          COMMENTS K-40        N  1.6111E+01 1460.83 1.611E+01?(        9.350E-01    8.87 G K PB-212      N  3.8225E-01 238.63 3.822E-01    (    1.258E-01  17.19 G K o
ORTEC 9 v - i (1087) npp32    G53W3.05 07-APR-2008 17:27:42 Page          4 PBRF                                spectrum name: PB08-01218.An1 Nuclide    Ave activity    Energy    Activity    Code peak MDA    Comments PB-214      N  7.2305E-Ol 351.93 7.231E-01    (    8.326E-02  12.50 GK RA-226      N  2.7761E+00 186.21 2.776E+00    (    1. 252E+00  23.09 G K TH-234      N  3:6275E+00 63.29 3.627E+00 ( 1. 732E+00        23.25 G K 92.59 2.251E+00 & 1. 085E+00        23.03 G K
( - This peak used in the nuclide activity average.
Peak is too wide, but only one peak in library.
      - Peak is part of a multiplet and this area went negative during deconvolution.
    ? - Peak is too narrow.
    @ - Peak is too wide at FW25M, but ok at FWHM.
    % - Peak fails sensitivity test.
    $ - Peak identified, but first peak of this nuclide page 3
 
,I
* PBOS-01218 failed one or more qualification tests.
      + -      peak activity higher than counting uncertainty range.
      - -      Peak activity lower than counting uncertainty range.
      =-        peak outside analysis energy range.
      &-        calculated peak centroid is not close enou~h to the library energy centroid for positive identlfication.
P -      peakbackground subtraction
      }        peak is too close to another for the activity to be found directly.
Nuclide codes:                                  peak codes:
T - Thermal Neutron Activation                  G - Gamma Ray F - Fast Neutron Activation                    X - x-Ray I - Fission Product                              P - Positron Decay N - Naturally occurring Isotope                S - single-Escape P - photon Reaction                            0 - Double-Escape rI.... -
charged particle Reaction              K - Key Line M - No MDA Calculation                          A - Not in Average R - Coincidence Corrected                        C - coincidence peak H - Hal fl i fe 1i mi t exceeded 5 U M MAR Y      OF    NUCLI DES            I N SAM P L    E Time of Count  Time Corrected uncertainty 2 sigma Nuclide              Activity        Activity          counting    Total          MDA pci/g          pci/g          pci/g        pci/g K-40        &        1.6111E+Ol    1.6111E+01    2.8593E+00    2.8980E+00    9.350E-01 CO-60 B<              9.5439E-02    9.5616E-02 Ag-I08mB<              4.1727E-02    4.1728E-02 C5-137 B<              6.3493E-02    6.3513E-02 o
ORTEC g v -      1 (l087) npp32  G53w3.05 07-APR-2008 17:27:42 Page          5 PBRF                                        spectrum name: PBOS-01218.Anl EU-152      B<        1.1594E-Ol    1.1602E-Ol EU-154      B<        1.2273E-01    1. 22S7E-Ol PB-212 PB-214      ....      3.8225E-01 7.2305E-01 3.8225E-01 7.2305E-01
: 1. 3141E-01
: 1. 8076E-01
: 1. 3178E-Ol
: 1. 8200E-Ol 1.258E-Ol 8.326E-02 BI-212      B<        8.8872E-01    8.8872E-Ol BI-214 RA-226      ..
B<        2.3972E-01 2.7761E+00 2.3972E-Ol 2.7761E+00    1. 2821E+00  1. 3157E+00  1. 252E+00 TH-234      ..        3.6275E+00    3.6275E+00    1. 6865E+00  1. 6891E+00  1. 732E+00 u-235        B<        4.1945E-Ol    4.1945E-01 AM-241      B<        1.8602E-Ol    1. 8603E-Ol
      # - All peaks for activity calculation had bad shape.
      ..      Activity omitted from total
      & - Activity omitted from total and all peaks had bad shape.
      < - MDA value printed.
A - Activity printed, but activity < MDA.
B - Activity < MDA and failed test.
C - Area < critical level.
F - Failed fraction or key line test.
H - Halflife limit exceeded
    -----------------------------              5 U M MAR Y ---------------------------
Total Activity (              38.8 to 2014.2 keV) O.OOOOOOOE+OO pci/g Total Decayed Activity (              38.8 to 2014.2 kev) O.OOOOOOOE+OO pci/g Analyzed by:          ~A rt!.~                    Page 4
* PB08-01218 oning Project Reviewed by:  _~~~..LJ-...~--=  _ _~A!.!.....!JPR 0*8 2008 Laboratory:  PBRF          R. Case Page 5
* PB08-01082 ORTEC g v - i (1087) npp32  G53w3.05 26-MAR-2008 16:29:47 Page      1 PBRF                            Spectrum name: PB08-01082.An1 sample description PB08-01082; SR99-14; PPH-RM4; FD-4-2; 3/26/08 Spectrum Filename: z:\Lab\SAMPLE 08\PB08-01082.An1 Acquisition information Start time:                  26-Mar-2008 16:19:45 Live time:                300 Real time:                301 Dead time:                  0.19 %
Detector 1D:                    3 Detector system
      #3 DETECTOR (#131)
Calibration Filename:
250ml #73678-773 (MC131) Sept07 ro COpy Energy Calibration Created:              05-Sep-2007 16:56:38 Zero offset:          0.565 kev Gain:                  0.247 kev/channel Quadratic:            5.022E-08 kev/channel A2 Efficiency Calibration Created:              05-Sep-2007 17:17:39 Type:                  Polynomial Uncertai nty:          1. 204 %
Coeffi ci ents :      -0.304311 -4.249899    0.669559
                                    -0.094002    0.005803 -0.000133 Library Files Main analysis library:      plumbrk OI.lib Library Match width:        0.500 peak stripping:            Library based Analysis parameters Analysis engine:            npp32    G53w3.05 Start channel:            155 (    38.83kev )
Stop channel:            8144 ( 2014.22kev)
Peak rejection level:      25.000%
Peak search sensitivity:    3 sample size:                4.2770E+02 Activity scaling factor:    1.0000E+06/( 1.0000E+00*    4.2770E+02) 2.3381E+03 Detection limit method:    Nureg 4.16 Random error:              1. OOOOOOOE+OO systematic error:          1.0000000E+00 Fraction Limit:            0.000%
Background width:          best method (based on spectrum).
o page 1
 
ORTEC g v - i (1087) npp32
* PB08-01082 G53w3.05 26-MAR-2008 16:29:47 Page                                2 PBRF                                                        Spectrum name: PB08-01082.An1 Half lives decay limit:                    12.000 Activity range factor:                      2.000 Min. step backg. energy                      0.000 Corrections                                                        Status              Comments Decay correct to date:                          YES        18-Mar-2008 15:18:00 Decay during acquisition:                        NO Decay during collection:                        NO True coincidence correction:                    NO Peaked background correction: NO Absorption (Internal):                          NO Geometry correction:                            NO Random summing:                                  NO Energy Calibration Normalized diff:              0.1381 SUM MAR Y                  0 F      PEA K S I N          RAN G E        *****
Peak                          Area      Uncert FWHM          Corrctn      Nuclide Brnch.              Act.                  NUc Energy                                                      Factor      Energy    Ratio    pcijg 77 .00                        98. 22.48      0.54    8.260E-02 238.88                          57. 16.36      0.75    6.191E-02      238.63    43.300  4.475E-01                      PB212 352.26                          51. 16.98      0.95    4.551E-02      351. 93  37.600  6.272E-01                      PB214 609.46                          45. 14.91      1. 09  2.830E-02      609.31    46.100  7.266E-01                      BI214 1461.03                              97. 10.15      1. 29  1. 387E-02    1460.83    11.000  1.340E+01                      K40
************ U N IDE N T I FIE D                                        PEA K        SUM MAR Y ************
peak Centroid Background Net Area                              Intensity    Uncert    FWHM Suspected Channel                      Energy        Counts        Counts      Ctsjsec    2 sigma % kev              Nuclide 309.61                    77.00            75.            98.      0.327      44.97    0.543                                  sM s - Peak                fails shape tests.
D
* peak                area deconvoluted.
L - Peak                written from unknown list.
C - Area                < Critical level.
M - Peak                is close to a library peak.
This section based on library: plumbrk 01.lib o
ORTEC g v -                  (1087) npp32      G53w3.05 26-MAR-2008 16:29:47 Page                                3 PBRF                                                          spectrum name: PB08-01082.An1
-,':,';-);;:*"1;;;-;,-;;-1:'1:'1:'1:-;,
I D E NT I F I E D P E A K              S U M M A R Y -f,-"1: ,*-1: "1,"1:-!;-;:-,':'1: "!;-,',"-;:*
Nuclide                  peak            Centroid    Background      Net Area    Intensity    Uncert FItJHM channel Energy              Counts          Counts      CtsjSec 2 sigma % kev AM-241                            0.00      59.54              O.            O.      0.000      0.00                0.000 TH-234                            0.00      63.29              O.            O.      0.000      0.00                0.000 TH-234                            0.00      92.59              O.            O.      0.000      0.00                0.000 EU-152                            0.00      121. 78            O.            O.      0.000      0.00                0.000 EU-154                            0.00      123.07              O.            O.      0.000      0.00                0.000 u-235                            0.00      143.76              O.            O.      0.000      0.00                0.000 Page 2
 
U-235        0.00    185.71
* O.
PB08-01082 O.      0.000
* 0.00  0.000 PB-212      965.25    238.88          10.          57.        0.190    32.73  0.747s EU-152        0.00    344.28            O.            O.      0.000    0.00  0.000 PB-214    1424.32    352.26            6.          51.        0.170    33.96  0.945 Ag-108m      0.00    433.94            O.            O.      0.000    0.00  0.000 BI-214    2465.45    609.46            O.          45.        0.150    29.81  1. 087s Ag-108m      0.00    614.28            O.            O.      0.000    0.00  0.000 cS-137        0.00    661. 66          O.            O.      0.000    0.00  0.000 Ag-108m      0.00    722.91            O.            O.      0.000    0.00  0.000 EU-154        0.00    723.30            O.            O.      0.000    0.00  0.000 BI-212        0.00    727.33            O.            O.      0.000    0.00  0.000 EU-154        0.00  1004.72            O.            O.      0.000    0.00  0.000 co-60        0.00  1173 . 24          O.            O.      0.000    0.00  0.000 EU-154        0.00  1274.44            O.            O.      0.000    0.00  0.000 co-60        0.00  1332.50            O.            O.      0.000    0.00  0.000 EU-152        0.00  1408.01            O.            O.      0.000    0.00  0.000 K-40      5909.36  1461. 03          O.          97.        0.323    20.31  1.287s s - peak fails shape tests.
D - peak area deconvoluted.
A Derived peak area.
  ~~~~h    SUM MAR Y          a F    LIB R A R Y        PEA K USA G E
- Nuclide - Ave~age            ------------- Peak -------------
Name    code Actlvlty          Energy  Activity Code MDA value pci/g            kev    pci/g            pci/g          COMMENTS K-40      N    1. 3396E+01 1460.83 1.340E+01    (    1.018E+00    10.15 G K PB-212    N    4.4753E-01 238.63 4.475E-01    (    1. 370E-01  16.36 G K PB-214    N    6.2724E-01 351.93 6.272E-01 ?(      1. 737E-01  16.98 G K 0
ORTEC g v - i (l087) npp32      G53w3.05 26-MAR-2008 16:29:47 page          4 PBRF                                  Spectrum name: PB08-01082.An1 Nuclide  Ave activity      Energy    Activity  Code Peak MDA      Comments BI-214    N    7.2659E-01 609.31 7.266E-01 ( 1.190E-01          14.91 G K 1764.49 O.OOOE+OO % 8.516E-01          35.36 G 1120.29 O.OOOE+OO & 9.768E-01        321.46 G
( - This peak used in the nuclide activity average.
    -    peak is too wide, but only one peak in library.
      - peak is part of a multiplet and this area went negative during deconvolution.
    ? - peak is too narrow.
    @ - peak is too wide at Fw2SM, but ok at FWHM.
    % - peak fails sensitivity test.
    $ - peak identified, but first peak of this nuclide failed one or more qualification tests.
    + - peak activity higher than counting uncertainty range.
peak activity lower than counting uncertainty range.
      - peak outside analysis energy range.
    & - calculated peak centr~id is not.c!ose.enough.to ~he library energy centrold for POSltlve ldentlflcatlon.
Page 3
 
P - peakbackground subtraction
* PB08-01082
        }          peak is too close to another for the activity to be found directly.
Nuclide Codes:                                  Peak Codes:
T - Thermal Neutron Activation                  G - Gamma Ray F - Fast Neutron Activation                      X - X-Ray I - Fission Product                              P - Positron Decay N - Naturally occurring Isotope                  S - single-Escape P - Photon Reaction                              D - Double-Escape C - Charged Particle Reaction                    K - Key Line M - No MOA Calculation                          A - Not in Average R - Coincidence Corrected                        C - coincidence Peak H - Ha lfl i fe 1 i mi t exceeded 1: 1, .:: 1:
S U MMA R y      0 F    NUC L I 0 E S        I N  S A MP L E      .)* .)* .J* .) * .)_
~':
Time of Count    Time Corrected uncertainty      2 Sigma Nuclide                  Activity        Activity          counting      Total              MDA pci/g          pci/g          pCi/g          pCi/g K-40              ~.      1. 3396E+01    1. 3396E+01    2.7203E+OO      2.7485E+OO  1.018E+00 co-60 B<                  1. 0390E-01    1.0420E-01 Ag-108mB<                  4.5425E-02      4.5427E-02 cs-137 B<                  6.9119E-02      6.9154E-02 EU-152 B<                  1. 4944E-01    1. 4961E-01 EU-154 B<                  1. 4888E-01    1.4914E-01 PB-212 ~:                  4.4753E-01      4.4753E-01    1.4647E-01      1.4692E-01  1.370E-01 PB-214 &                  6.2724E-01      6.2724E-01    2.1302E-01      2.1382E-01  1.737E-01 BI-212 B<                  1. 3928E+OO    1.3928E+OO o
ORTEC 9 v - i (1087) npp32      G53w3.05 26-MAR-2008 16:29:47 page                        5 P8RF                                            spectrum name: PB08-01082.An1 BI-214            ~.
7.2658E-01      7.2659E-01    2.1663E-01      2.1801E-01  1. 190E-01 RA-226 B<                  2.2173E+OO      2.2173E+00 TH-234 B<                  1. 5680E+OO    1.5680E+00 u-235 B<                  4.1374E-01      4.1374E-01 M~-241 8<                  2.2357E-01      2.2357E-Ol
        # -        All peaks for activity calculation had bad shape.
        ~          Activity omitted from total
      &-          Activity omitted from total and all peaks had bad shape.
        <      -  MDA value printed.
A      -  Activity printed, but activity < MOA.
B      -  Activity < MDA and failed test.
C      -  Area < critical level.
F      -  Failed fraction or key line test.
H      -  Halflife limit exceeded A R Y Total Activity (                  38.8 to                                  pCi/g Total Decayed Activity (                                            O.OOOOOOOE+OO  pci/g Analyzed by:
Reviewed by:
2GOB Laboratory:                PBRF Page 4
* PB08-00797 ORTEC g v -  1 (l087) npp32                                  page    1 PBRF sample description PB08-00797; SR99-008; PPH;  RM4;\~~~~
spectrum Filename: z:\Lab\SAMPLE Acquisition information Start time:                  13-Mar-2008 14:23:27 Live time:                300 Real time:                301 Dead time:                  0.39 %
Detector TO:                      2 Detector system
      #2 DETECTOR (#130)
Calibration Filename:
Dc          p 250ml #73678-773 (MC130)Sept07 Energy Calibration Created:                13-Sep-2007 15:00:31 zero offset:            0.287 kev Gain:                  0.251 kev/channel Quadratic:              2.324E-08 kev/channel A2 Efficiency calibration created:                13-Sep-2007 15:22:08 Type:                  polynomial uncertainty:            1. 626 %
coeffi ci ents :      -0.256697 -4.334323    0.664302
                                    -0.092291    0.005686 -0.000130 Library Files Main analysis library:      plumbrk 01.1ib Library Match Width:        0.500 peak stripping:              Library based Analysis parameters Analysis engine:            npp32    G53w3.05 Start channel:            155 (    39.27kev )
Stop channel:            8144 ( 2049.92kev) peak rejection level:      25.000%
peak search sensitivity:    3 sample size:                4.4440E+02 Activity scaling factor:    1.0000E+06/( 1.0000E+00*    4.4440E+02) 2.2502E+03 Detection limit method:      Nureg 4.16 Random error:                1.0000000E+00 systematic error:            1. OOOOOOOE+OO Fraction Limit:              0.000%
Background width:            best method (based on spectrum).
o page 1
 
ORTEC g v - i (1087) npp32 PB08-00797 G53w3.05 13-MAR-2008 14:29:02 Page            2 PBRF                                Spectrum name: PB08-00797.An1 Half lives decay limit:      12.000 Activity range factor:          2.000 Min. step backg. energy        0.000 corrections                                Status            Comments Decay correct to date:            YES        11-Mar-2008 08:22:00 Decay during acquisition:          NO Decay during collection:          NO True coincidence correction:      NO Peaked background correction: NO Absorption (Internal):            NO Geometry correction:              NO Random summing:                    NO Energy calibration Normalized diff:          0.0999 SUM MAR Y 0 F            PEA K S I N        RAN G E        *****
Peak        Area    Uncert FWHM      Corrctn    Nuclide Brnch.          Act. NUc Energy                                Factor      Energy    Ratio    pci/g 186.14          45. 23.92    0.33 6.693E-02      186.21    3.590  3.825E+00    RA226 238.58          76. 13.86    1. 01 5.760E-02      238.63    43.300  6.178E-01    PB212 351.88          53. 19.31    0.68 4.242E-02      351.93    37.600  6.780E-01    PB214 609.62          42. 15.43    1. 26 2.665E-02      609.31    46.100  6.930E-01    BI214 661.70          77. 12.45    0.59 2.492E-02      661.66    85.100  7.329E-01    CS137 1173 .15          25. 20.00    0.34 1. 604E-02    1173 .24  99.974  3.164E-01    c060 1331.67          17. 24.25    0.25 1. 459E-02    1332.50    99.986  2.364E-Ol    c060 1460.75          91. 10.48    0.67 1. 362E-02    1460.83    11.000  1.231E+01    K40 No unknown peaks passed sensitivity test.
This section based on library: plumbrk 01.lib
************** IDE N T I FIE D PEA K                  SUM MAR Y **************
Nuclide Peak        Centroid Background Net Area        Intensity    Uncert FWHM Channel Energy      Counts        Counts      Cts/Sec 2 sigma % key AM-241        0.00      59.54          O.          O.      0.000      0.00    0.000 TH-234        0.00      63.29          O.          O.      0.000      0.00    0.000 TH-234        0.00      92.59          O.          O.      0.000      0.00    0.000 EU-152        0.00    121.78          O.          O.      0.000      0.00    0.000 EU-154        0.00    123.07          O.          O.      0.000      0.00    0.000 u-235        0.00    143.76          O.          O.      0.000      0.00    0.000 u-235        0.00    185.71          O.          O.      0.000      0.00    0.000 RA-226      738.96    186.14        17.          45.      0.151    47.83    0.329s PB-212      947.48    238.58        10.          76.      0.253    27.73    LOBs EU-152        0.00    344.28          O.          O.      0.000      0.00    0.000 PB-214    1397.90    351.88        13.          53.      0.178    38.63    0.682s o
ORTEC g v -    (1087) npp32  G53W3.05 13-MAR-2008 14:29:02 page            3 PBRF                                spectrum name: PB08-00797.An1 Nuclide    Channel    Energy  Background    Net area  Cnts/sec      Uncert    FWHM Ag-108m      0.00    433.94          O.          O.      0.000      0.00    0.000 BI - 214  2422 . 38  609.62          O.          42.      0.140    30.86    1. 258 Ag-108m      0.00    614.28          O.          O.      0.000      0.00    0.000 Page 2
 
c5-13 7                    2629.41 661.70          3.
PB08-00797
: 77.            0.256
* 24.90    0.591s Ag-108m                      0.00    722.91          O.            O.            0.000        0.00    0.000 EU-154                        0.00    723.30          O.            O.            0.000        0.00    0.000 81-212                        0.00    727.33          O.            O.            0.000        0.00    0.000 EU-154                        0.00    1004.72          O.            O.            0.000        0.00    0.000 co-60                      4661. 74  1173.15          O.          25.            0.083        40.00    0.340s EU-154                        0.00    1274.44          O.            O.            0.000        0.00    0.000 co-60                      5291. 50  1331.67          O.          17.            0.057        48.51    0.252s EU-152                        0.00    1408.01          O.            O.            0.000        0.00    0.000 K-40                      5804.26    1460.75          O.          91.            0.303        20.97    0.673s s - Peak fails shape tests.
D - Peak area deconvoluted.
A Derived peak area.
oJ * ..L .J~ ..J# oJ.
S U  M MAR Y      0  F  L I B RA RY          P EA K U S A GE                  -h-t,."'!.**
- Nuclide -                    Ave~a~e      -------------    Peak - - - - - - - - - - - - -
Name                    Code  ActlVlty        Energy  Activity Code MDA value pci/g            kev    pci/g                pci/g                  COMMENTS K-40                      N    1.2311E+01 1460.83 1,231E+01?(        9.971E-01            10.48 G K co-60                    F    2.7640E-01 1332.50 2.364E-O(';J 1.025E-01                  24.25 G K 1173.24 3.164E-0~ 9.327E-02                      20.00 G K cs-137                    I    7.3295E-01 661.667.329E-01      (    1.072E-01            12.45 G K PB-212                    N    6.1776E-01 238.63 6.178E-01 *(      1.418E-01            13.86 G K PB-214                    N    6.7796E-01 351.93 6.780E-01    (    2.453E-01            19.31 G K B1 - 214                  N    6.9298E-01 609.31 6.930E-01 (        1.216E-01            15.43 G K 1764.49 O.OOOE+OO %        8.220E-01            50.00 G 1120.29 O.OOOE+OO %        5;961E-01            26.73 G RA-226                    N    3.8248E+OO 186.21 3.825E+00    (    1.834E+00            23,92 G K ORTEC g v -  1  (1087) npp32  G53w3.05 13-MAR-2008 14:29:02 page                            4 PBRF                                                Spectrum name: PB08-00797.An1
( - This peak used in the nuclide activity average.
peak is too wide, but only one peak in library.
                  - peak is part of a multiplet and this area went negative during deconvolution.
          ? - peak is too narrow.
          @ - peak is too wide at FW25M, but ok at FWHM.
          % - Peak fails sensitivity test.
          $ - peak identified, but first peak of this nuclide failed one or more qualification tests.
          + - peak actlvlty hlgher than coun~lng uncert~lnty range.
          - - peak activlty lower than countlng uncertalnty range.
peak outslde analysis energy range.
Page 3
* PB08-00797
    & - Calculated peak centroid is not close enough to the library energy centroid for positive identlfication.
P - peakbackground subtraction
    }    Peak is too close to another for the activity to be found directly.
Nuclide Codes:                              Peak Codes:
T - Thermal Neutron Activation            G - Gamma Ray F - Fast Neutron Activation                X - X-Ray I - Fission product                        P - Positron Decay N - Naturally occurring Isotope            S - Single-Escape P - Photon Reaction                        0 - Double-Escape C - charged particle Reaction              K - Key Line M - No MDA calculation                    A - Not in Average R - Coincidence Corrected                  C - Coincidence Peak H - Halflife 1i mi t exceeded
  *****      SUM MAR Y        0 F    NUC L I DE S          I N S AMP L E        .J. oJ. J * .J * .J.
Time of Count  Time COf'rected uncertainty 2 sigma Nuclide        Activity        Activity          counting        Total            MDA pci/g          pci/g            pci/g            pci/g K-40            1.2311E+01    1.2311E+01      2.5811E+00      2.6108E+00  9.971E-01 co-60            2.7618E-01    2.7640E-01      8.6891E-02        8.7338E-02  1. 024E-01
~ Ag-108            4.6802E-02    4.6802E-02 cs-137          7.3284E-01    7.3295E-01      1. 8251E-01      1. 8400E-01 1. 072E-01 EU-152  B<      1,8271E-01    1. 8277E-01 EU-154  B<      1. 4495E-01    1. 4502E-01 PB-212  &        6.1776E-01    6.1776E-01      1. 7128E-01      1. 7202E-01 1.418E-01 PB-214  ~
6.7796E-01    6.7796E-01      2.6189E-01      2.6278E-01  2.453E-01 BI-212  _.B<    1.6534E+00    1.6534E+00 BI-214          6.9297E-01    6.9298E-01      2.1386E-01        2.1531E-01  1. 216E-01
          ".      3.8248E+00    3.8248E+00      1. 8295 E+OO      1.8743E+00  1.834E+00 RA-226 TH-234  B<      1. 8569E+00    1. 8569E+00 u-235  B<      3.8817E-01    3.8817E-01 AM-241  B<      1.9880E-01    1.9880E-01 0
ORTEC g v -    1 (1087) npp32  G53w3.05 13-MAR-2008 14:29:02 Page                        5 PBRF                                  Spectrum name: PB08-00797.An1
    # -  All peaks for activity calculation had bad shape.
h    Activity omitted from total
    & - Activity omitted from total and all peaks had bad shape.
    < - MDA value printed.
A - Activity printed, but actlvlty < MDA.
B - Activity < MDA and failed test.
C - Area < critical level.
F - Failed fraction or key line test.
H - Halflife limit exceeded
  -----------------------------        SUM MAR Y            ---------------------------
Total Activity (        39.3 to 2049.9 kev) 1.0090208E+00 pCi/g Total Decayed Activity (        39.3 to 2049.9 kev) 1.0093489E+00 pci/g Analyzed by:          A PBRF D        sioning projef1AR M    1 3 2008 Reviewed by:
R. CaSA Page 4
* PB08-00797 Laboratory: PBRF Page 5
* PB08-01083 ORTEC g v -      (1087) npp32  G53w3.05 26-MAR-2008 16:42:13 Page      1 PBRF                                Spectrum name: PB08-01083.An1 sample description PB08-01083; SR99-15; PPH-RM4; FD-4-3B; 3/26/08 spectrum Filename: z:\Lab\SAMPLE 08\PB08-01083.An1 Acquisition information Start time:                    26-Mar-2008 16:27:02 Live time:                  300 Real time:                    302 Dead time:                      0.69 %
Detector TO:                        1 Detector system
      #1 DETECTOR (#129)
[] COpy Calibration Filename:
250ml #73678-773 (MC129) Jan08 Energy calibration Created:                  09-Jan-2008 08:36:01 Zero offset:            -0.051 kev Gain:                    0.250 kev/channel Quadratic:              -8.299E-09 kev/channelA2 Efficiency Calibration created:                  09-Jan-200809:15:56 Type:                    Polynomial uncertainty:              1. 663 %
Coefficients:            -0.338084 -4.099654    0.610757
                                        -0.082467    0.004895 -0.000109 Library Files Main analysis library:          plumbrk 01.lib Library Match Width:            0.500.
Peak stripping:                Library based Analysis parameters Analysis engine:                npp32    G53W3.05 Start channel:              155 (      38.73kev)
Stop channel:              8144 ( 2037.21kev) peak rejection level:          25.000%
Peak search sensitivity:        3 sample size:                    4.4360E+02 Activity scaling factor:        1.0000E+06/( 1.0000E+00*  4.4360E+02) 2.2543E+03 Detection limit method:        Nureg 4.16 Random error:                  1.0000000E+00 systematic error:              1.0000000E+00 Fraction Limit:                0.000%
Background width:              best method (based on spectrum).
o Page 1
 
ORTEC g v - i (10S7) npp32 PB08-01083 G53w3.05 26-MAR-2008 16:42:13 Page            2 PBRF                                Spectrum name: PB08-01083.An1 Half lives decay limit:      12.000 Activity range factor:        2.000 Min. step backg. energy        0.000 Corrections                              Status            Comments Decay correct to date:            YES        18-Mar-2008 15:30:00 Decay during acquisition:        NO Decay during collection:          NO True coincidence correction:      NO Peaked background correction: NO Absorption (Internal):            NO Geometry correction:              NO
        . Random summing:                  NO Energy Calibration Normalized diff:        0.0443 SUM MAR Y 0 F          PEA K S I N        RAN G E Peak        Area  uncert FWHM      Corrctn    Nuclide Brnch.        Act. NuC Energy                                Factor    Energy    Ratio    pCi/g 238.62        74. 14.50    0.45 6.441E-02      238.63  43.300  5.388E-01    PB212 351.81        57. 15.79    1. 07 4.765E-02      351.93  37.600  6.461E-01    PB214 609,26        49. 14.29    1. 24 3.006E-02      609.31  46.100  7.181E-0l    BI214 1460.79        116. 9.28    0.76 1.481E-02      1460.83  11.000  1.446E+01    K40 No unknown peaks passed sensitivity test.
This section based on library: plumbrk 01.lib
************** IDE N T I FIE D            PEA K      SUM MAR Y **************
Nuclide    peak    centroid  Background    Net Area    Intensity    Uncert FWHM Channel Energy    Counts        Counts      Cts/sec 2 sigma % kev AM-241        0.00    59.54          O.          O.      0.000      0.00    0.000 TH-234        0.00    63.29          o.          o.      0.000      0.00    0.000 TH-234        0.00    92.59          O.          O.      0.000      0.00    0.000 EU-152        0.00  121.78          O.          O.      0.000      0.00    0.000 EU-154        0.00  123.07          O.          O.      0.000      0.00    0.000 U-235        0.00  143.76          O.          O.      0.000      0.00    0.000 u-235        0.00  185.71          O.          O.      0.000      0.00    0.000 RA-226        0.00  186.21          O.          O.      0.000      0.00    0.000 PB-212      953.86  238.62          13.          74.      0.247    29.00    0.448s EU-152        0.00  344.28          O.          O.      0.000      0.00    0.000 PB-214    1406.28  351.81          6.          57.      0.190    31. 58    1. 066 Ag-108m      0.00  433.94          O.          O.      0.000      0.00    0.000 BI-214    2435.29  609.26          O.          49.      0.163    28.57    1. 241 Ag-108m      0.00  614.28          O.          O.      0.000      0.00    0.000 cs-137        0.00  661.66          O.          O.      0.000      0.00    0.000 o
ORTEC g v -    (1087) npp32    G53w3.05 26-MAR-2008 16:42:13 page            3 PBRF                                spectrum name: PBOS-01083.An1 Nuclide    channel  Energy  Background    Net area  Cnts/sec    Uncert    FWHM Ag-108m      0.00  722.91          O.          O.      0.000      0.00    0.000 EU-154        0.00  723.30          O.          O.      0.000      0.00    0.000 BI-212        0.00  727.33          O.          o.      0.000      0.00    0.000 page 2
 
EU-154        0.00  1004.72
* O.
PB08-01083 O.      0.000
* 0.00      0.000 co-60        0.00  1173.24          O.            O.      0.000          0.00      0.000 EU-154        0.00  1274.44          O.            O.      0.000          0.00      0.000 co-60        0.00  1332.50          O.            O.      0.000          0.00      0.000 EU-152        0.00  1408.01          O.            O.      0.000          0.00      0.000 K-40      5839.29  1460.79          O.        116.        0.387        18.57      0.765s s - peak fails shape tests.
D - Peak area deconvoluted.
A Derived peak area.
S U  M MAR Y      o F    LIB R A R Y        PEA K USA G E
- Nuclide    Ave~age      ------------- Peak Name    Code  ActlVlty      Energy  Activity code MDA value pci/g          kev    pci/g            pCi/g                COMMENTS K-40      N    1. 4462E+Ol 1460.83 1.446E+01 ---:"---=--.:...,~=-=---=-==-----_::....:....:=-=---=-.:..:.----------
( 9.189E-Ol            9.28 G K PB-212    N    5.3885E-Ol 238.63 5.388E-01    (    1.421E-01      14.50 G K PB-214    N    6.4609E-Ol 351.93 6.461E-01    (    1.601E-01      15.79 G K BI-214    N    7.1812E-01 609.31 7.181E-01 ( 1.080E-01            14.29 G K 1764.49 O.OOOE+OO % 8.118E-Ol            183.33 G 1120.29 O.OOOE+OO % 5.388E-01            25.82 G
( - This peak used in the nuclide activity average.
  "    peak is too wide, but only one peak in library.
      - Peak is part of a multiplet and this area went negative during deconvolution.
  ? - peak is too narrow.
  @  peak is too wide at FW25M, but ok at FWHM.
  %  peak fails sensitivity test.
  $ - peak identified, but first peak of this nuclide failed one or more qualification tests.
  + - peak activity higher than counting uncertainty range.
  - - peak activity lower than counting uncertainty range.
      - peak outside analysis energy range.
  & - calculated peak centroid is not close enough to the library energy centroid for positive identlfication.
ORTEC g v - i (1087) npp32    G53w3.05 26-MAR-2008 16:42:13 page                  4 PBRF                                Spectrum name: PB08-01083.Anl P - peakbackground subtraction
  } - Peak is too close to another for the activity to be found directly.
Nuclide codes:                          Peak codes:
T Thermal Neutron Activation            G - Gamma Ray F    Fast Neutron Activation            X - X-Ray I    Fission Product                    P - positron Decay N Naturally occurring Isotope            5 - single-Escape P    photon Reaction                    D - Double-Escape C charged particle Reaction            oK - Key Line M NO MDA calculation                    A - Not in Average page 3
 
R - Coincidence Corrected
* PB08-01083 C - Coincidence Peak H - Halflife limit exceeded SUM MAR Y            o F N U eLI DES I N            SAM P L E Time of Count      Time Corrected uncertainty    2 Sigma Nuclide          Activity          Activity          Counting    Total        MDA pci/g            pci/g          pci/g        pci/g K-40    ".        1. 4462E+01      1.4462E+01    2.6856E+00    2.7256E+00 9.189E-01 eo-60 B<          9.3659E-02        9.3930E-02 Ag-108mB<        5.2525E-02        5.2527E-02 e5-137 B<        6.2613E-02        6.2644E-02 EU-152 B<        1.1639E-01        1.1652E-01 EU-154 B<        1. 5062E-01      1.5089E-01 PB-212 "'        5.3885E-01        5.3885E-01    1. 5629E-01  1.5691E-01 1.421E-01 PB-214 ".        6.4608E-01        6.4609E-01    2.0403E-01    2.0509E-01 1.601E-01 BI-212 B<        8.7465E-01        8.7465E-01 BI-214  '1(  - - 7 :-lbT1F\Y:'-  -rTIIT2E="U-'
RA-226  B<        2.4956E+OO        2.4957E+OO TH-234  B<        1.6156E+00        1.6156E+00 u-235  B<        3.071lE-01        3.0711E-01 AM-241  B<        2.1461E-01        2.1461E-0l
  # - All peaks for activity calculation had bad shape.
  . Activitv omitted from total
  & - Activity omitted from total and all peaks had bad shape.
  < - MDA value printed, A - Activity printed, butactlvlty < MDA.
B - Activity < MDA and failed test.
e - Area < critical level.
F - Failed fraction or key line test.
H - Halflife limit exceeded
-----------------------------            SUM MAR Y ---------------------------
Total Activity (          38.7 to 2037.2 kev) O.OOOOOOOE+OO pci/g Total Decayed Activity (            38.7 to 2037.2 kev) O.OOOOOOOE+OO pCi/g Analyzed by:          A,"
project Reviewed by:                                        ~AR  l A. Case o
ORTEe 9 v -        (1087) npp32    G53w3.05 26-MAR-2008 16:42:13 Page      5 PBRF                                      spectrum name: PB08-01083.An1 Laboratory:      PBRF page 4
* PB08-01283 ORTEC g v - i (1087) npp32  G53w3.05 15-APR-2008 15:50:44 Page      1 PBRF                            Spectrum name: PB08-01283.An1 sample description PB08-01283; SR99-56; PPH - RM8 - FD8-1; 4/15/08 spectrum Filename: z:\Lab\SAMPLE 08\PB08-01283.An1 Acquisition information Start time:                15-Apr-2008 15:41:43 Live time:                300 Real time:
Dead time:
Detect-o r 10:
301 0.17 %
[J    COpy Detector system
      #3 DETECTOR (#131)
Calibration Filename:
2S0ml #73678-773 (MC131) Sept07 Energy Calibration Created:              05-Sep-2007 16:56:38 Zero offset:          0.565 kev Gain:                0.247 kev/channel Quadratic:            5.022E-08 kev/channel A2 Efficiency Calibration Created:              05-sep-2007 17:17:39 Type:                  Po 1ynomi a1 uncertainty:          1. 204 %
coefficients:        -0.304311 -4.249899    0.669559
                                    -0.094002    0.005803 -0.000133 Library Files Main analysis library:      pl umbrk 01.1 i b Library Match Width:        0.500 Peak stripping:            Library based Analysis parameters Analysis engine:            npp32    G53w3.05 Start channel:            155 (    38.83kev )
Stop channel:            8144 ( 2014.22kev)
Peak rejection level:      25.000%
Peak search sensitivity:    3 sample Size:                4.8520E+02 Activity scaling factor:    1.0000E+06/( 1.0000E+00*    4.8520E+02) 2.0610E+03 Detection limit method:    Nureg 4.16 Random error:              1.0000000E+00 Systematic error:          1. OOOOOOOE+OO Fraction Limit:            0.000%
Background width:          best method (based on spectrum).
o page 1
 
ORTEC g v - i (1087) npp32
* PB08-01283 G53w3.05 15-APR-2008 15:50:44 Page                              2 PBRF                                                              spectrum name: PB08-01283.An1 Half lives decay limit:                      12.000 Activity range factor:                          2.000 Min. step backg. energy                        0.000 corrections                                                              Status              Comments Decay correct to date:                            YES        14-Apr-2008 11:23:00 Decay during acquisition:                          NO Decay during collection:                          NO True coincidence correction:                      NO peaked background correction: NO Absorption (Internal):                            NO Geometry correction:                              NO Random summing:                                    NO Energy Calibration Normalized diff:                0.2766
  '1~*"'1: 1: 1:
S U MMA R Y 0 F                      P EAK S        I N  RANGE          1:1:**1,"
peak                            Area      uncert FWHM            Corrctn      Nuclide Brnch.              Act.                NUc Energy                                                            Facto r      Energy    Ratio        pcijg 77.24                            44. 24.24        0.92    8.258E-02 238.69                              80. 13.81        0.99    6.195E-02      238.63    43.300      5.537E-01                  PB212 351. 94                            57. 19.85        0.59    4.555E-02      351. 93  37.600      6.216E-01                  PB214 609.06                              51. 14.00        0.88    2.830E-02      609.31    46.100      7.259E-01                  BI214 1460.23                                127. 8.87        1. 39  1. 387E-02    1460.83    11.000      1.546E+01                  K40
* 1; 1: 1: i: "1: 1: 1: "/,'1:"/:
* UNI D ENT          T J.. F I ED          P  EA K      S U M M A R Y 1,- 1: "1.: '1: 1: * -/: -;. * -1.
1~                            ~.
Peak Centroid Background Net Area                                    Intensity    Uncert      FWHM suspected channel                        Energy        Counts          Counts      CtsjSec    2 Sigma % kev            Nuclide 310.61                        77.24            27.              44.      0.148    48.47    0.924                                  M s - peak                    fails shape tests.
D - Peak                    area deconvoluted.
L - peak                    written from unknown list.
C - Area                      < Critical level.
M - Peak                    is close to a library peak.
This section based on library: plumbrk OI.lib o
ORTEC g v - i (1087) npp32                          G53w3.05 15-APR-2008 15:50:44 page                              3 PBRF                                                              spectrum name: PB08-01283.An1 1: 1: 1:  "* 1: 1: 1: 1: 7. 1: 1; 1: * -/: I D E N T I F I E D P E A K                S U M M A R Y -:: -t: '* * "'1: "* * -:. -1:
* 1.. 1: 1: -1:
Nuclide peak                                centroid Background Net Area                Intensity        Uncert FWHM channel Energy              Counts            Counts      ctsjsec L.... sigma % kev AM-241                              0.00      59.54                O.            O.      0.000        0.00            0.000 TH-234                              0.00      63.29                O.            O.      0.000        0.00            0.000 TH-234                              0.00      92.59                O.            O.      0.000        0.00            0.000 EU-152                              0.00      121. 78              O.            O.      0.000        0.00            0.000 EU-154                              0.00      123.07                O.            O.      0.000        0.00            0.000 u-235                                0.00      143.76                O.            O.      0.000        0.00            0.000 Page 2
 
u-235        0.00    185.71
* O.
PB08-01283 O.      0.000
* 0.00          0.000 PB-212      964.47    238.69          14.          80.          0.267      27.61          0.994 EU-152        0.00    344.28          O.              O.      0.000      0.00          0.000 PB-214    1423.03    351. 94        17.          57.          0.191      39.71          0.5895 Ag-108m      0.00    433.94          O.              o.      0.000      0.00          0.000 BI-214    2463.81    609.06          O.          51.          0.170      28.01          0.8755 Ag-108m      0.00    614.28          O.              O.      0.000      0.00          0.000 cs-137    2675.78    661. 43          4.          24.          0.080      50.00'          1.026s' Ag-108m      0.00    722.91          O.              O.      0.000      0.00          0.000 EU-154        0.00    723.30          O.              O.      0.000      0.00          0.000 BI-212        0.00    727.33          O.              O.      0.000      0.00          0.000 EU-154        0.00    1004.72          O.              O.      0.000      0.00          0.000 co-60        0.00    1173.24          O.              O.      0.000      0.00          0.000 EU-154        0.00    1274.44          O.              O.      0.000      0.00          0.000 co-60        0.00    1332. SO          O.              O.      0.000      0.00          0.000 EU-152        0.00    1408.01          O.              O.      0.000      0.00          0.000 K-40      5906.14    1460.23          O.        127.          0.423  .---1-7--.--1--5--1---.---3-945- .
s - Peak fails shape tests.
D - Peak area deconvoluted.
A Derived peak area,
  *****    SUM MAR Y          o F    LIB R A R Y          PEA K USA G E
- Nuclide - Ave~age            ------------- Peak -------------
Name    Code Actlvlty          Energy  Activity Code MDA value pci/g            kev    pci/g              pci/g              COMMENTS K-40      N    1. 5460E+Ol                          ,.
1460.83 1.546E+01    \.. 8.972E-01    8.87 G        K CS-137    I    1.9842E-01 661.66 1. 984E-OG          9.946E-02    25.00 G K PB-212    N    5.5367E-01 238.63 5.537E-01 ?(        1. 394E-Ol  13.81 G K 0
ORTEC 9 v -  1  (1087) npp32    G53w3.05 15-APR-2008 15:50:44 page                          4 PBRF                                  spectrum name: PB08-01283.An1 Nuclide    Ave activity      Energy    Activity  code Peak MDA        Comments PB-214    N    6.2157E-01 351.93 6.216E-Ol ?(        2.356E-Ol    19.85      G K BI-214    N    7.2588E-01 609.31 7.259E-01?( 1.049E-01            14.00 G K 1764.49 O.OOOE+OO % 7.507E-Ol          111.80 G 1120.29 O.OOOE+OO % 8.179E-01            95.12 G
( - This peak used in the nuclide activity average.
    - - Peak is too wide, but only one peak in library.
      - Peak is part of a multiplet and this area went negative during deconvolution.
    ? - Peak is too narrow.
    @ - Peak is too wide at FW25M, but ok at FWHM.
    % - Peak fails sensitivity test.
    $ - Peak identified, but first peak of this nuclide failed one or more qualification tests.
    + - Peak activity higher than coun~ing uncert~inty range.
    - - Peak activity lower than countlng uncertalnty range.
Page 3
 
                      - peak outside analysis energy range.
PB08-01283
              & - Calculated peak centroid is not close enough to the library energy centroid for positive identlfication.
P - peakbackground subtraction
              }          Peak is too close to another for the activity to be found directly.
Nuclide Codes:                                    Peak Codes:
T - Thermal Neutron Activation                    G - Gamma Ray F - Fast Neutron Activation                      X - X-Ray I - Fission Product                              P - Positron Decay N - Naturally occurring Isotope                  S - single-Escape P - Photon Reaction                              D - Double-Escape C - Charged particle Reaction                      K - Key Line M - No MDA Calculation                            A - Not in Average R - Coincidence Corrected                        C - Coincidence Peak H - Halfl ife 1 i mi t exceeded oJ **h~. oJ * .J#
S U MMA R y      0 F    NUC L I n E S
                                                                  !J        I N  S A r.1 P L E    -t;.J,....~.**
Time of Count    Time Corrected uncertainty      2 sigma Nuclide                    Activity        Activity          Counting      Total              MDA pci/g          pci/g          pci/g          pci/g K-40                .c
: 1. 5460E+01    1.5460E+01    2.7438E+00      2.7810E+00    8.972E-01 co-60 B<                    9.1584E-02      9.1623E-02 Ag -108Jlf1R'              5.3398E-02      5.3398E-02
  . /CS-1W                        1. 9841E-01    1. 9842E-01    9.9212E-02      9.9382E-02    9,945E-02 JO EU-b <                        1.4040E-01      1.4042E-01 I      EU-154 B<                  1. 1376E-01    1. 1379E-01 0
ORTEC g v - i (l087) npp32      G53w3.05 15-APR-2008 15:50:44 Page                  5 PBRF                                              Spectrum name: PB08-01283.An1 PB-212              &      5.5367E-01      5.5367E-01    1. 5289E-01    1. 5356E-01  1.394E-01 PB-214              &      6.2156E-01      6.2157E-01    2.4680E-01      2.4747E-01    2.356E-01 BI-212              B<      1. 0046E+00    1. 0046E+00 BI-214              &      7.2588E-01      7.2588E-01    2.0329E-01      2.0475E-01    1.049E-01 RA-226              B<      1.4202E+00      1. 4202E+00 TH-234              B<      1. 6149E+00    1. 6149E+00 u-235              B<      4.9162E-01      4.9162E-01 AM-241              B<      1.8240E-01      1. 8240E-01
              # -          All peaks for activity calculation had bad shape.
              "          Activity omitted from total
              &-          Activity omitted from total and all peaks had bad shape.
              <      -    MDA value printed.
A      -    Activity printed, but activity < MDA.
B      -    Activity < MDA and failed test.
C      -    Area < Critical level.
F      -    Failed fraction or key line test.
H      -    Halflife limit exceeded
        -----------------------------                    SUM MAR Y          ---------------------------
Total Activity (                  38.8 to 2014.2 keY) 1.9840866E-01 pci/g Total Decayed Activity (              I 38.8 to 2014.2 keY) 1.9842345E-01        pci/g Analyzed by:                    y.
Reviewed by:
 
Supervisor PB08-01283 Laboratory: PBRF page 5
* PB08-01284 ORTEC g v - i (1087) npp32  G53w3.05 15-APR-2008 15:54:45 Page      1 PBRF                            Spectrum name: PB08-01284.An1 sample description PB08-01284; SR99-57; PPH  RM8 - FD8-2; 4/15/08 spectrum Filename: z:\Lab\SAMPLE 08\PB08-01284.An1 Acquisition information Start time:                  15-Apr-2008 15:48:59 Live time:                300 Real time:                302 Dead time:                  0.60 %
Detector IO:                      1 Detector system
      #1 DETECTOR (#129) calibration Filename:
250ml #73678-773 (MC129) Jan08 Energy Calibration created:              09-Jan-2008 08:36:01 zero offset:        -0.051 kev Gain:                  0.250 kev/channel Quadratic:          -8.299E-09 kev/channel A2 Efficiency Calibration Created:              09-Jan-2008 09:15:56 Type:                  polynomial uncertainty:          1. 663 %
coeffi ci ents:      -0.338084 -4.099654      0.610757
                                    -0.082467      0.004895 -0.000109 Library Files Main analysis library:      plumbrk 01.lib Library Match width:        0.500 Peak stripping;              Library based Analysis parameters Analysis engine:            npp32    G53w3.05 Start channel:            155 (      38.73kev)
Stop channel:            8144 ( 2037.21kev)
Peak rejection level:      25.000%
Peak search sensitivity:    3 sample Size:                5.0470E+02 Activity scaling factor:    1.0000E+06/( 1.0000E+00*    5.0470E+02) =
L 9814E+03 Detection limit method:      Nureg 4.16 Random error;              1.0000000E+00 systematic error:            1.0000000E+00 Fraction Limit:            0.000%
Background width:          best method (based on spectrum).
o page 1
 
ORTEC g v - i (1087) npp32
* PB08-01284 G53w3.05 15-APR-2008 15:54:45 page                          2 PBRF                                                          Spectrum name: PB08-01284.An1 Half lives decay limit:                      12.000 Activity range factor:                          2.000 Min. step backg. energy                      0.000 Corrections                                                          Status              Comments Decay correct to date:                            YES        14-Apr-2008 11:14:00 Decay during acquisition:                          NO Decay during collection:                          NO True coincidence correction:                      NO peaked background correction: NO Absorption (Internal):                            NO Geometry correction:                              NO Random summing:                                  NO Energy calibration Normalized diff:                0.1373 SUM MAR Y 0 F                        PEA K S I N          RAN G E peak                          Area        Uncert FWHM        Corrctn      Nuclide Brnch.          Act.                  Nuc Energy                                                          Factor      Energy    Ratio    pci/g 74.77                            45. 21. 06    0.82  8.366E-02 77.26                            56. 18.22      0.82  8.392E-02 238.46                              57. 16.36      0.42  6.444E-02      238.63    43.300  3.648E-01 PB212 294.94                              36. 18.74      0.80  5.501E-02 351.92                              72. 11.79      1.33  4.765E-02      351. 93  37.600  7.173E-01                ps214 608.97                              38. 16.22      0.83  3.006E-02      609.31    46.100  4.895E-01                BI214 1120.08                                18. 23.57      0.50  1. 840E-02    1120.29    15.100  1.157E+00                BI214 1460.79                                97. 10.15      0.60  1. 481E-02    1460.83    11.000  1.063E+01                K40
************ U N IDE N T I FIE D                                          PEA K        SUM MAR Y peak Centroid Background Net Area                                Intensity    Uncert    FWHM suspected Channel                      Energy          Counts        Counts      Cts/sec    2 sigma % kev          Nuclide 299.02                    74.86                23.          45.      0.151      42.12    0.820 PB-214                        D 308.99                    77.36                23.          56.      0.185      36.44    0.823 PB-214                        D 1178.97                      294.94                  2.          36.      0.118      37.48    0.798 PB-214                        M s - Peak                fails shape tests.
D - Peak                area deconvoluted.
L - peak                written from unknown list.
C - Area                < Critical level.
M - peak                is close to a library peak.
This section based on library: plumbrk 01.1ib o
ORTEC g v -                  1 (l087) npp32      G53w3. as 15-APR-2008 15: 54: 45 Page                        3 PBRF                                                          spectrum name: PB08-01284.Anl
* "i. 1.
* of; * * "1: * "1: * * '1: 7-, I D E N T I F I E D        P EA K      S U M M A R Y * ;( ;: * "1, "1: * * * "'1. * -/: "1, "'1.
Nuclide peak                                Centroid Background Net        Area    Intensity    Uncert FWHM channe 1 Energy                Counts          Counts      Cts/sec 2 sigma % kev AM-241                          0.00          59.54            O.            O.      0.000      0.00            0.000 page 2
 
TH-234        0.00      63.29
* O.
PB08-01284 O.      0.000
* 0.00    0.000 TH-234        0.00      92.59          O.            O.      0.000    0.00    0.000 EU-152        0.00    121. 78          O.            O.      0.000    0.00    0.000 EU-154        0.00    123.07          O.            O.      0.000    0.00    0.000 u-235        0.00    143.76          O.            O.      0.000    0.00    0.000 u-235        0.00    185.71          O.            O.      0.000    0.00    0.000.
RA-226        0.00    186.21          O.            O.      0.000    0.00    0.000 PB-212      953.25    238.46          10.          57.        0.190  32.73    0.421s EU-152        0.00    344.28          O.            O.      0.000    0.00    0.000 PB-214    1406.71    351.92          O.          72.        0.240  23.57    1.334s Ag-108m      0.00    433.94          O.            O.      0.000    0.00    0.000 BI-214    2434.11    608.97          O.          38.        0.127  32.44    0.834s Ag-108m      0.00    614.28          O.            O.      0.000    0.00    0.000 cs-137        0.00    661.66          O.            O.      0.000    0.00    0.000 Ag-108m      0.00    722.91          O.            O.      0.000    0.00    0.000 EU-154        0.00    723.30          O.            O.      0.000    0.00    0.000 6I-212        o 00    727 33          0            0        a 000    a 00    o 000 EU-154        0.00    1004.72          O.            O.      0.000    0.00    0.000 BI-214    4477.22    1120.08          O.          18.        0.060  47.14    0.500s co-60        0.00    1173.24          O.            O.      0.000    0.00    0.000 EU-154        0.00    1274.44          r.
: v.            O.      0.000    0.00    0.000 co-60        0.00    1332.50          O.            O.      0.000    0.00    0.000 EU-152        0.00    1408.01          O.            O.      0.000    0.00    0.000 K-40      5839.32    1460.79          O.          97.        0.323  20.31    0.597s s - peak fails shape tests.
D - peak area deconvoluted.
A Derived peak area.
  ~~~~~    SUM MAR Y          o F    LIB R A R Y PEA K USA G E
- Nuclide - Ave~age            ------------- Peak -------------
Name 'Code Actl Vl ty            Energy  Activity Code MDA value pci/g            kev    pci/g            pCi/g          COMMENTS K-40      N    1.0629E+01 1460.83 1. 063E+01  (    8.076E-01  10.15 G K PB-212    N    3.6481E-01 238.63 3.648E-01 ?(      1. 117E-01  16.36 G K PB-214    N    7.1731E-01 351.93 7.173E-01 @(      7.342E-02  1l.79GK 0
ORTEC g v -  1  (l087) npp32    G53w3.05 15-APR-2008 15:54:45 Page          4 PBRF                                  Spectrum name: PB08-01284.An1 Nuclide  Ave activity      Energy    Activity  code Peak MDA    Comments BI-214    N    4.8948E-01 609.31 4.895E-01 ( 9.493E-02        16.22 G  !(
1764.49 O.OOOE+OO % 6.791E-01        30.15 G 1120.29 1.157E+00 +      4.736E-01  23.57 G
( - This peak used in the nuclide activity average.
    ~    Peak is too wide, but only one peak in library.
      - Peak is part of a multiplet and this area went negative during deconvolution.
    ? - peak is too narrow.
    @ - peak is too wide at FW25M, but ok at FWHM.
    % - Peak fails sensitivity test.
Page 3
* PB08-01284
    $ - Peak identified, but first peak of this nuclide failed one or more qualification tests.
  + - Peak activity higher than counting uncertainty range.
    - - Peak activity lower than counting uncertainty range.
      - Peak outside analysis energy range.
  & - calculated peak centroid is not close enough to the library energy centroid for positive identlfication.
P - peakbackground subtraction
  }    Peak is too close to another for the activity to be found directly.
Nuclide codes:                          Peak codes:
T - Thermal Neutron Activation          G - Gamma Ray F - Fast Neutron Activation            X - X-Ray I - Fission Product                      P - Positron Decay N  Naturally occ~rring Isotope          S - single-Escape p - photon R@Eict;on                    0    Double E!;Cape C - charged Particle Reaction            K  Key Line M - NO MDA calculation                  A - Not in Average R - Coincidence Corrected                C - Coincidence Peak H - Halfl ife limit exceeded
*****    SUM MAR Y        o F    N U C L I DES        I N SAM P L E Time of Count  Time Corrected    uncertainty 2 sigma Nuclide      Activity        Activity          counting      Total        iv1DA pci/g          pci/g          pci/g          pci/g K-40    k      1. 0629E+01    1.0629E+01    2.1)85E+00      2.1854E+00  8.076E-01 co-60 B<      8.2320E-02    8.2356E-02 Ag-108mB<      3.6585E-02    3.6585E-02 cs-137 B<      5.5033E-02    5.5037E-02 EU-152 B<      1. 1230E-01    1.1232E-01 EU-154 B<      8.3781E-02    8.3803E-02 PB-212 &      3.6481E-01    3.6481E-01    1.1939E-01      1.1977E-01  1.117E-01 PB-214 &      7.1731E-01    7.1731E-0l    1. 6907E-01    1.7064E-01  7.342E-02 BI-212 B<      8.4396E-01    8.4396E-01 o
ORTEC g v - i (1087) npp32    G53w3.05 15-APR-2008 15:54:45 Page          5 PBRF                                spectrum name: PB08-01284.An1 81-214  .      4.8948E-01    4.8948E-0l    1. 5881E-0l    1.5979E-01  9.493E-02 RA-226  B<    1.6841E+00    1. 6841E+00 TH-234  B<    1. 4415E+00    1. 4415E+00 U-235  B<    4.6609E-01    4.6609E-01 AM-241  B<    1.6849E-01    1. 6849E-Ol
  # - All peaks for activity calculation had bad shape .
  .. - Activity omitted from total
  & - Activity omitted from total and all peaks had bad shape.
  < - MDA value printed.
A - Activity printed, but activity < MDA.
B - Activity < MDA and failed test.
C - Area < Critical level.
F - Failed fraction or key line test.
H - Halflife limit exceeded
_____________________________      SUM MAR Y          ---------------------------
Total Activity (      38.7 to 2037.2 keV) O.OOOOOOOE+OO pci/g Total Decayed Activity (      38.7 to 2037.2 kev) O.OOOOOOOE+OO pci/g Page 4
 
*1 Analyzed by:
A~
* P808-01284 Reviewed by:
Laboratory:  PBRF  R.~
page 5
* PB08-01335 ORTEC g v -      (1087) npp32  G53W3.05 21-APR-2008 17:12:45 Page      1 PBRF                                Spectrum name: PB08-01335.An1 sample description PB08-01335; SR99-81; PPH RM 8 HD8-1; 4/21/08 spectrum Filename: z:\Lab\SAMPLE 08\PB08-01335.An1 A~quisition  information Start time:                      21-Apr-2008 16:00:21 Live time:                  300 Real time:                    301 Dead time:                      0.27 %
Detector ID:                          3 Detector system
      #3 DETECTOR (#131)
[] COpy Calibration Filename:
2S0ml #73678-773 (MC131) Sept07 Energy Calibration Created:                  05-Sep-2007 16:56:38 Zero offset:              0.565 kev Gain:                    0.247 kev/channel Quadratic:                5.022E-08 kev/channel A2 Efficiency Calibration Created:                  05-sep-2007 17:17:39 Type:                    polynomial uncertainty:              1. 204 %
Coefficients:            -0.304311 -4.249899    0.669559
                                        -0.094002    0.005803 -0.000133 Library Files Main analysis library:          plumbrk 01.lib Library Match Width:            0.500 Peak stripping:                Library based Analysis parameters Analysis engine:                npp32    G53w3.05 Start channel:              155 (      38.83kev )
Stop channel:              8144 ( 2014.22kev)
Peak rejection level:          25.000%
Peak search sensitivity:        3 sample Size:                    4.6620E+02 Activity scaling factor:        1.0000E+06/( 1.0000E+00*    4.6620E+02) 2.1450E+03 Detection limit method:        Nureg 4.16 Random error:                  1.0000000E+00 systematic error:              1.0000000E+00 Fraction Limit:                0.000%
Background width:              best method (based on spectrum).
o Page 1
 
ORTEC g v - i (l087) npp32 PB08-01335 G53w3.05 21-APR-2008 17:12:45 Page            2 PBRF                                Spectrum name: PB08-01335.An1 Half lives decay limit:        12.000 Activity range factor:          2.000 Min. step backg. energy        0.000 Corrections                                Status            Comments Decay correct to date:              YES        17-Apr-2008 08:34:00 Decay during acquisition:          NO Decay during collection:            NO True coincidence correction:        NO peaked background correction: NO Absorption (Internal):              NO Geometry correction:                NO Random summing:                    NO Energy calibration Normalized diff:          0.0642 SUM MAR Y 0 F            PEA K S I N          RAN G E peak        Area    Uncert FWHM        Corrctn    Nuclide Brnch.          Act. Nuc Energy                                Factor      Energy    Ratio    pci/g 238.67        85. 14.31    1. 03 6.196E-02      238.63    43.300  6.123E-01    PB212 352.11        57. 14.81    1. 37 4.555E-02      351.93    37.600  6.394E-Ol    PB214 609.28        56. 13.36    1. 34 2.830E-02      609.31  46.100    8.295E-01    81214 1460.99      138. 8.51    1. 45 1. 387E-02    1460.83  11.000    1. 748E+01  K40 NO unknown peaks passed sensitivity testo This section based on library: plumbrk 01.lib
  ************** IDE N T I FIE D            PEA K      SUM MAR Y **************
Nuclide    Peak    Centroid  Background    Net Area    Intensity      Uncert FWHM channel Energy    Counts          Counts      Cts/sec 2 sigma % keY AM-241        0.00    59.54          o.            O.      0.000      0.00    0.000 TH-234        0.00    63.29          O.            O.      0.000      0.00    0.000 TH-234        0.00    92.59          O.            O.      0.000      0.00    0.000 EU-152        0.00    121. 78          O.            O.      0.000      0.00    0.000 EU-154        0.00    123.07          O.            O.      0.000      0.00    0.000 u-235        0.00    143.76          O.            O.      0.000      0.00    0.000 u-235        0.00    185.71          O.            o.      0.000      0.00    0.000 PB-212      964.39    238.67          14.          85.      0.283      28.62    1. 027 EU-152        0.00    344.28          O.            O.      0.000      0.00    0.000 PB-214    1423.71    352.11          4.          57.      0.189      29.61    1.372 Ag-108m      0.00    433.94          O.            O.      0.000      0.00    0.000 BI-214    2464.73    609.28          O.          56.      0.187      26.73    1. 338 Ag-108m      0.00    614.28          O.            O.      0.000      0.00    0.000 cs-137        0.00    661. 66          O.            O.      0.000      0.00    0.000 Ag-108m      0.00    722.91          O.            O.      0.000      0.00    0.000 o
ORTEC g v - i (1087) npp32      G53w3.05 21-APR-2008 17:12:45 Page              3 PBRF                                spectrum name: PB08-01335.An1 Nuclide    Channel    Energy  Background      Net area  Cnts/sec      Uncert    FWHM EU-154        0.00    723.30          O.            O.      0.000      0.00    0.000 BI-212        0.00    727.33          O.            O.      0.000      0.00    0.000 EU-154        0.00  1004.72          O.            O.      0.000      0.00    0.000 page 2


==SUMMARY==
co-60            0.00  1173.24
-:Peak Centroid Background Net Area Intensity Uncert FWHM Channel Energy Counts Counts CtsjSec 2 sigma % kev 296.40 74.76 291. 142. 0.095 37.90 0.922 PB-214 D 305.23 76.98 241. 192. 0.128 27 .12 0.924 PB-214 D 1173.10 295.34 56. 196. 0.131 21. 60 1. 201 PB-214 M s -Peak fails shape D -Peak area L-Peak written from unknown C -Area < Critical M -Peak is close to a library This section based on library: plumbrk 01.lib o ORTEC g v -i (1087) npp32 G53w3.05 13-MAR-2008 15:48:34 Page PBRF Spectrum name:
* O.
page 2 
PB08-01335 O.     0.000
*
* 0.00   0.000 EU-154           0.00   1274.44          O.           O.     0.000   0.00   0.000 co-60             0.00   1332.50          O.           O.     0.000   0.00   0.000 EU-152           0.00   1408.01         O.           O.     0.000   0.00   0.000 K-40           5909.21  1460.99          O.         138.       0.460  17.03  1. 454s s - Peak fails shape tests.
* PB08-00794 "1: 1.-1. 1: 1. *1. 1: **1, '* -1: '1: I DEN TI FI ED PEAK SUM MAR Y ************** Peak Centroid Background Net Area Intensity Uncert FWHM Channel Energy Counts Counts Cts/Sec 2 sigma % kev AM-241 0.00 59.54 O. O. 0.000 0.00 0.000 TH-234 0.00 63.29 O. O. 0.000 0.00 0.000 TH-234 0.00 92.59 O. O. 0.000 0.00 0.000 EU-152 0.00 121. 78 O. O. 0.000 0.00 0.000 EU-154 0.00 123.07 O. O. 0.000 0.00 0.000 u-235 0.00 143.76 O. O. 0.000 0.00 0.000 u-235 0.00 185.71 O. O. 0.000 0.00 0.000 RA-226 738.56 186.04 127. 133. 0.089 38.57 0.7925 PB-212 947.95 238.70 82. 301. 0.201 15.90 1.058 EU-152 0.00 344.28 O. O. 0.000 0.00 0.000 PB-214 1398.50 352.03 47. 277 . 0.185 15.79 1.065 Ag-108m 0.00 433.94 O. O. 0.000 0.00 0.000 BI-214 2421. 94 609.50 32. 190. 0.127 19.69 0.916s Ag-108m 0.00 614.28 O. O. 0.000 0.00 0.000 cS-137 2629.33 661. 68 20. 113. 0.075 25.83 0.8715 Ag-108m 0.00 722.91 " u. O. 0.000 0.00 0.000 EU-154 0.00 723.30 O. O. 0.000 0.00 0.000 BI-212 0.00 727.33 O. O. 0.000 0.00 0.000 EU-154 0.00 1004.72 O. O. 0.000 0.00 0.000 BI-214 4453.63 1120 ..77 20. 74. 0.050 39.89 1.1155 co-60 4662.07 1173.23 4. 50. 0.034 32.24 0.8735 EU-154 0.00 1274.44 O. O. 0.000 0.00 0.000 co-60 5297.81 1333.26 6. 50. 0.033 37.31 0.3045 EU-152 0.00 1408.01 O. O. 0.000 0.00 0.000 K-40 5805.30 1461. 01 O. 524. 0.349 8.74 1.711 BI-214 7011. 73 1764.77 O. 44. 0.029 30.15 0.9445 s -peak fails shape D -peak area A Derived peak *****. SUM MAR Y oF LIBRARY PEA K USAGE -Nuclide  
D - Peak area deconvoluted.
-------------
A Derived peak area.
Peak Name Actlvlty Energy Activity Code MDA value pci/g kev pci/g pci/g COMMENTS K-40 N 1. 4707E+Ol 1460.83 1. 471E+01 ( 2.069E-01 4.37 G K co-60 F 1. 3771E-01 1332.50 1. 428E-01 ( 3.936E-02 18.65 G K 1173.24 1. 326E-01 ( 3.000E-02 16.12 G K 0 ORTEC g v -i (1087) npp32 G53w3.05 13-MAR-2008 15:48:34 Page 4 PBRF spectrum name: PB08-00794.An1* Ave activity Energy Activity Code Peak MDA Comments I 2.2413E-01 661.66 2.241E-01 .c 4.671E-02 12.92 G K N 5.0817E-01 238.63 5.082E-0l ( 7.559E-02 7.95 G K PB-214 N 7.3142E-Ol Page 3 
1:1:1d:,"    S U  M MAR Y     o  F  LIB R A R Y        PEA K USA G E
*
- Nuclide         Ave~age      ------------- peak Name       code    ActlVlty      Energy   Activity code MDA value pCi/g           keV    pCi/g             pci/g         COMMENTS K-40           N   1. 7484E+01 1460.83 1.748E+01 I(     9.338E-01   8.51GK PB-212        N    6.1225E-01 238.63 6.123E-01   (   1.451E-01 14.31 G K PB-214         N   6.3938E-01 351.93 6.394E-01   (   1.400E-01  14.81 G K 81-214       N     8.2953E-01 609.31 8.295E-Ol ( 1.092E-01        13.36 G K 1764.49 O.OOOE+OO % 7.813E-01         30.15 G 1120.29 O.OOOE~OO % 5.490E-01         40.82 G
* PB08-00794 351.93 7.314E-01 ( 9.110E-02 7.90 G K BI-214 N 6.5040E-01 609.31 6.504E-01 ( 9.951E-02 9.85 G K 1764.49 1. 018E+00 + 1. 705E-01 15.08 G 1120.29 1. 250E+00 + 3:908E-01 19.94 G RA-226 N 2.3339E+00 186.21 2.334E+00
( - This peak used ln the nuclide activity average.
*( 9.655E-01 19.28 G K ( -This peak used in the nuclide activity average. Peak is too wide, but only one peak in  
peak is too wide, but only one peak in library.
-Peak is part of a multiplet and this area negative during ? -Peak is too @ -Peak is too wide at FW25M, but ok at % -Peak fails sensitivity $ -Peak identified, but first peak of this failed one or more qualification + -peak activity higher than counting uncertainty --Peak activity lower than counting uncertainty -Peak outside analysis energy & -Calculated peak centroid is not close enough to library energy centroid for positive P -peakbackground  
        - peak is part of a multiplet and this area went negative during deconvolution.
} Peak is too close to another for the to be found directly.
    ? - Peak is too narrow.
Nuclide codes: Peak T -Thermal Neutron Activation G -Gamma F -Fast Neutron Activation X I -Fission Product P Positron N Naturally occurring Isotope S P -photon Reaction D C -charged Particle Reaction K Key M -NO MDA Calculation A Not in R Coincidence Corrected C Coincidence H Halflife limit o ORTEC g v -(1087) npp32 G53w3.05 13-MAR-2008 15:48:34 page 5 PBRF spectrum name: PB08-00794.An1
    @ - Peak is too wide at FW25M, but ok at FWHM.
***** SUM MAR Y oF NUCLI DES IN SAMPLE Time of Count Time corrected uncertainty 2 sigma Nuclide Activity Activity counting Total . MDA pci/g pci/g pCi/g pCi/g K-40  1. 4707E+01 1. 4707E+01 1.2850E+00 1.3681E+OO 2.069E-01 co-60 1. 3760E-01 1. 3771E-01 3.3949E-02 3.4232E-02 3.932E-02 Ag-108mB<
    % - Peak fails sensitivity test.
cs-13i 2.9858E-02 2.2410E-01 2.9859E-02 2.2413E-01 5.7895E-02 5.8335E-02 4.670E-02 EU-152 B< 1.1821E-01
    $ - peak identified, but first peak of this nuclide failed one or more qualification tests.
: 1. 1825E-0l EU-154 B< 7.3223E-02 7.3260E-02 PB-212  5.08llE-01 5.08llE-01 8.0775E-02 8.1834E-02 7.559E-02 PB-214 .. 7.3141E-0l 7.3142E-01
    + - Peak activity higher than counting uncertainty range.
: 1. 1551E-01 1. 1784E':-Ol 9.110E-02 81-212 B< 8.3351E-01 8.3351E-01 BI-214
        - Peak activity lower than counting uncertainty range.
* 6.5039E-01 6.5040E-01 1.2808E-01
        - Peak outside analysis energy range.
: 1. 3020E-01 9.951E-02 RA-226 & 2.3339E+OO 2.3339E+OO 9.0014E-01 9.3380E-01 9.655E-01 page 4 
    & - calculated peak centroid is not close enough to the library energy centroid for positive identlfication.
*
P - peakbackground subtraction o
* PB08-00794 TH-234 B< 7.3876E-Ol 7.3876E-Ol u-235 B< 2.4401E-Ol 2.4401E-Ol AM-241 B< 1. 0412E-Ol 1. 0413E-Ol #-All peaks for activity calculation had bad shape.* Activity omitted from & -Activity omitted from total and all peaks had bad < -MDA value A -Activity printed, but activity < B -Activity < MDA and failed C -Area < Critical F -Failed fraction or key line H -Halflife limit
ORTEC g v - i (1087) npp32      G53w3.05 21-APR-2008 17:12:45 page        4 PBRF                                    spectrum name: PB08-01335.Anl
-----------------------------5 U M MAR Y Total Activity ( 39.3 to 2049.9 keV) 3.6169705E-Ol Total Decayed Activity ( 39.3 to 2049.9 kev) 3.6184323E-Ol Analyzed by: project MAR 13 2008 Reviewed by: A. Case Laboratory:
    } - Peak is too close to another for the activity to be found directly.
PBRF Page 5 
Nuclide Codes:                              peak codes:
*
T       Thermal Neutron Activation           G - Gamma Ray F       Fast Neutron Activation             X - X-Ray I       Fission Product                     P - Positron Decay N Naturally occurring Isotope               S - single-Escape P       photon Reaction                     o - Double-Escape C charged particle Reaction                 K - Key Line M No MDA Calculation                         A - Not in Average R Coincidence corrected                     C - Coincidence Peak page 3
* 1 PB08-01218 ORTEC g v -1 (l087) npp32 G53w3.05 07-APR-2008 17:27:42 Page PBRF Spectrum name: PB08-01218.An1 sample description PB08-01218; SR99-37; PPH RM 4; FD4-1B; 4/7/08 spectrum Filename:
z:\Lab\SAMPLE 08\PB08-01218.An1 Acquisition information Start time: Live time: Real time: Dead time: Detector 1D: Detector system#3 DETECTOR (#131) calibration Filename:
07-Apr-2008 17:21:54 300 301 [j 250ml #73678-773 (MC131) Sept07 Energy calibration created: Zero offset: Gain: Quadratic:
Efficiency calibration created: Type: uncertainty:
Coefficients:
Library Main analysis Library Match Peak Analysis parameters Analysis engine: Start channel: Stop channel: . Peak rejection level: peak search sensitivity:
sample Size: . Activity scaling factor: Detection limit method: Random error: systematic error: Fraction Limit: Background width: o 05-Sep-2007 16:56:38 0.565 kev 0.247 kev/channel 5.022E-08 kev/channel A 2 05-Sep-2007 17:17:39 polynomial 1.204 % -0.304311
-4.249899
-0.094002 0.005803 pl umbrk 01.1 i b Library npp32 G53w3.05 155 ( 38.83kev )8144 ( 2014.22kev) 1.0000E+06/( 1.0000E+00*
4.6560E+02) 2.1478E+03 Nureg 4.16 1.0000000E+00
: 1. best method (based on page 1 
*
* PB08-01218 ORTEC g v -i (1087) npp32 G53w3.05 07-APR-2008 17:27:42 Page 2 PBRF Spectrum name: PB08-01218.An1 Half lives decay limit: 12.000 Activity range factor: 2.000 Min. step backg. energy 0.000 Corrections Status Comments Decay correct to date: YES 02-Apr-2008 13:42:00 Decay during acquisition:
NO Decay during collection:
NO True coincidence correction:
NO Peaked background correction:
NO Absorption (Internal):
NO Geometry correction:
NO Random summing: NO Energy Normalized diff: 1,"1,"1:"/,-1,-
.)* .).-'* .J-.J.SUMMA RY 0 F PEAKS I N RAN G peak Area uncert FWHM Corrctn Nuclide Brnch. Act. Energy Factor Energy Ratio 63.68 72. 23.25 0.82 7.980E-02 63.29 4.800 3.627E+00 TH234 77 .41 54. 24.00 0.88 8.257E-02 93.22 53. 23.03 1.17 8.166E-02 92.59 5.580 2.251E+00 TH234 186.45 37. 23.09 0.87 7.184E-02 186.21 3.590 2.776E+00 RA226 238.86 53. 17.19 1. 31 6.196E-02 238.63 43.300 3.822E-01 ps212 351.95 64. 12.50 0.86 4.555E-02 351. 93 37.600 7.231E-01 PB214 1460.52 127. 8.87 0.80 1. 387E-02 1460.83 11.000 1. 611E+01 K40 J- -'--'--'-.). -,_ oJ. -'--'. -,.-,_*-f,. **""*'1;***** UNI DENTI FI ED PEAK


==SUMMARY==
H - Halflife limit exceeded
...... " .. "" .... "" Peak Centroid Background Net Area Intensity Uncert FWHM suspected Channel Energy Counts Counts cts/sec 2 sigma % keY Nuclide 311.29 77 .41 38. 54. 0.180 48.01 0.876 s -peak fails shape tests. D Peak area deconvoluted. L -Peak written from unknown C -Area < Critical level. list. This section based on library: plumbrk 01.lib o ORTEC g v -(1087) npp32 G53w3.05 07-APR-2008 17:27:42 Page 3 PBRF Spectrum name: PB08-01218.An1
* PB08-01335
**************
    ..J * .J * .J ...... .J.
IDE N T I FIE D PEA K SUM MAR Y **************
S UMMA RY                      0 F      N UC L I 0 E S              T
Nuclide peak Centroid Background Net Area Intensity Uncert FWHM Channel Energy Counts Counts cts/Sec 2 sigma % keY AM-241 0.00 59.54 O. O. 0.000 0.00 TH-234 255.67 63.68 46. 72. 0.238 46.49 TH-234 375.34 93.22 24. 53. 0.177 46.06 EU-152 0.00 121.78 O. O. 0.000 0.00 EU-154 0.00 123.07 O. O. 0.000 0.00 0.000 page 2 
                                                                                                      .L N      S A MP L E  .J * .J * .J* .J * .J.
*
Time of Count                  Time Correc'ted uncertainty                    2 Sigma Nuclide                          Activity                        Activity                Counting            Total            MDA pci/g                      pci/g                pci/g                pci/g K-40                      &        1. 7484E+01                    1. 7484E+01          2.9767E+00            3.0205E+00 9.338E-01 co-60 B<                          9.5316E-02                    9.5464E-02 Ag-108mB<                          4.1674E-02                    4.1674E-02 cs-137 B<                          6.3411E-02                    6. 3428E -02 EU-152 B<                          1. 2712E-01                    1. 2720E-01 EU-154 B<                        1. 4340E-01                    1.4353E-01 PB-212 ..                         6.1225E-01                      6.1225E-01          1.7526E-01            1.7597E-01 1.451E-01 PB-214                    J.
* PB08-01218 u-235 0.00 143.76 O. O. 0.000 0.00 0.000 u-235 0.00 185.71 O. O. 0.000 0.00 0.000 RA-226 752.93 186.45 9. 37. 0.123 46.18 0.872 PB-'212 965.16 238.86 10. 53. 0.177 34.38 1. 311 EU-152 0.00 344.28 O. O. 0.000 0.00 0.000 PB-214 1423.09 351.95 O. 64. 0.213 25.00 0.855s Ag-108m 0.00 433.94 O. O. 0.000 0.00 0.000 B1-214 0.00 609.31 O. O. 0.000 0.00 0.000 Ag-108m 0.00 614.28 O. O. 0.000 0.00 0.000 cs-137 0.00 661.66 O. O. 0.000 0.00 0.000 Ag-108m 0.00 722.91 O. O. 0.000 0.00 0.000 EU-154 0.00 723.30 O. O. 0.000 0.00 0.000 B1-212 0.00 727.33 O. O. 0.000 0.00 0.000 EU-154 0.00 1004.72 O. O. 0.000 0.00 0.000 B1-214 0.00 1120.29 O. . O. 0.000 0.00 0.000 co-60 0.00 1173.24 O. O. 0.000 0.00 0.000 EU-154 0.00 1274.44 O. O. 0.000 0.00 0.000 co-60 0.00 1332.50 O. O. 0.000 0.00 0.000 EU-152 0.00 1408.01 O. O. 0.000 0.00 0.000 K-40 5907.31 1460.52 O. 127. 0.423 17.75 0.799s B1-214 0.00 1764.49 O. O. 0.000 0.00 0.000 s -peak fails shape D -Peak area A Derived peak ***** SUM MAR Y aF LIBRARY PEA K USAGE -Nuclide
6.3937E-01                    6.3938E-01          1. 8933E-01          1.9025E-01 1.400E-01 81-212 B<                        1. 1157E+00                     1.1157E+00 81 - 214                  J.
-------------
8.2952E-01                      8.2953E-01          2.2170E-01            2.2345E-01 1.092E-01 RA-226 B<                        1.5096E+00                      1.5096E+00 TH-234 B<                        1. 2364E+00                     1. 2364E+00 u-235 B<                          5.0761E-01                    5.0761E-01 AM-241 B<                        1.9806E-01                      1.9806E-01
Peak Name Actlvlty Energy Activity Code MDA value pci/g kev pci/g pci/g COMMENTS K-40 N 1.6111E+01 1460.83 1.611E+01?( 9.350E-01 8.87 G K PB-212 3.8225E-01 238.63 3.822E-01 ( 1.258E-01 17.19 G K o ORTEC 9 v -i (1087) npp32 G53W3.05 07-APR-2008 17:27:42 Page 4 PBRF spectrum name: PB08-01218.An1 Nuclide activity Energy Activity Code peak MDA Comments PB-214 7.2305E-Ol 351.93 7.231E-01 ( 8.326E-02 12.50 GK RA-226 2.7761E+00 186.21 2.776E+00 ( 1. 252E+00 23.09 G K TH-234 3:6275E+00 63.29 3.627E+00 ( 1. 732E+00 23.25 G K 92.59 2.251E+00  
              # - All peaks for activity calculation had bad shape.
& 1. 085E+00 23.03 G K ( -This peak used in the nuclide activity average. Peak is too wide, but only one peak in
                ..           Activity omitted from total
-Peak is part of a multiplet and this area negative during ? -Peak is too @ -Peak is too wide at FW25M, but ok at % -Peak fails sensitivity $ -Peak identified, but first peak of this page 3 
              & - Activity omitted from total and all peaks had bad shape.
* * ,I PBOS-01218 failed one or more qualification + -peak activity higher than counting uncertainty --Peak activity lower than counting uncertainty = -peak outside analysis energy & -calculated peak centroid is not close to library energy centroid for positive P -peakbackground
              < - MDA value printed.
} peak is too close to another for the to be found directly.
A - Actlvity printed, but actlvity < MDA.
Nuclide codes: peak T -Thermal Neutron Activation G -Gamma F -Fast Neutron Activation X -I -Fission Product P -Positron N -Naturally occurring Isotope S -
B - Activity < MDA and failed test.
-P photon Reaction 0 -Double-Escape r I.... -charged particle Reaction K -Key M -No MDA Calculation A -Not in R -Coincidence Corrected C -coincidence H-Hal fl i fe 1 i mi t 5 UM MAR Y OF NUCLI DES I N SAMPL E Time of Count Time Corrected uncertainty 2 sigma Nuclide Activity Activity counting Total MDA pci/g pci/g pci/g pci/g K-40 & 1.6111E+Ol 1.6111E+01 2.8593E+00 2.8980E+00 9.350E-01 CO-60 B< 9.5439E-02 9.5616E-02 Ag-I08mB<4.1727E-02 4.1728E-02 C5-137 B< 6.3493E-02 6.3513E-02 o ORTEC g v -1 (l087) npp32 G53w3.05 07-APR-2008 17:27:42 PBRF spectrum name:
C - Area <- Critical 'level.
EU-152 B< 1.1594E-Ol EU-154 B< 1.2273E-01
F            Failed fraction or key line test.
: 1.
H - Halflife limit exceeded
..PB-212 3.8225E-01 3.8225E-01
    -----------------------------                                            SUM MAR Y ---------------------------
: 1. 3141E-01 1. 3178E-Ol 1.258E-Ol..PB-214 7.2305E-01 7.2305E-01
Total Activity (                                    38.8 to 2014.2 kev) O.OOOOOOOE+OO pci/g Total Decayed Activity (                                          38.8 to 2014.2 kev) O.OOOOOOOE+OO pci/g Ana 1 yzed by:                    ----.::~=___.----=-~.C>l-..L..l.,..L!>-4~,..,e--:-:--------:----..,------
: 1. 8076E-01 1. 8200E-Ol 8.326E-02 BI-212 B< 8.8872E-01 8.8872E-Ol BI-214 B< 2.3972E-01 2.3972E-Ol
project Reviewed by:                                                                                    APR 2 2 200B supervisor R. Case Laboratory:                      PBRF Page 4
..RA-226 2.7761E+00 2.7761E+00
* PB08-01280 ORTEC g v -  1  (l087) npp32  G53w3.05 15-APR-2008 15:49:44 Page      1 PBRF                                Spectrum name: PB08-01280.Anl sample description PB08-01280; SR99-54; PPH-RM8- HD8-2; 4/15/08 spectrum Filename: z:\Lab\SAMPLE 08\PB08-01280.Anl Acquisition information Start time:                    15-Apr-2008 15:39:55 Live time:                  300 Real time:                  302 Dead time:                    0.53 %
: 1. 2821E+00 1. 3157E+00 1. 252E+00 ..TH-234 3.6275E+00 3.6275E+00
Detector ID:                        2 Detector system
: 1. 6865E+00 1. 6891E+00 1. 732E+00 u-235 B< 4.1945E-Ol 4.1945E-01 AM-241 B< 1.8602E-Ol
      #2 DETECTOR (#130)                                    [j  COpy Calibration Filename:
: 1. 8603E-Ol # -All peaks for activity calculation had bad .. Activity omitted from & -Activity omitted from total and all peaks had bad < -MDA value A -Activity printed, but activity < B -Activity < MDA and failed C -Area < critical F -Failed fraction or key line H -Halflife limit
250ml #73678-773 (MC130)sept07 Energy Calibration created:                  13-sep-2007 15:00:31 zero offset:              0.287 kev Gain:                    0.251 kev/channel Quadratic:                2.324E-08 kev/channel A2 Efficiency Calibration created:                  13-sep-2007 15:22:08 Type:                     polynomial uncertai nty:             1. 626 %
-----------------------------5 U M MAR Y Total Activity ( 38.8 to 2014.2 keV) O.OOOOOOOE+OO pci/g Total Decayed Activity ( 38.8 to 2014.2 kev) O.OOOOOOOE+OO pci/g Analyzed by:
Coeffi ci ents:         -0.256697 -4.334323    0.664302
Page 4 5 
                                      -0.092291    0.005686 -0.000130 Library Files Main analysis library:        plumbrk 01.lib Library Match width:          0.500 Peak st ri ppi ng:            Library based Analysis parameters Analysis engine:              npp32    G53w3.05 Start channel:              155 (     39.27kev )
*
Stop channel:              8144 ( 2049.92kev)
* PB08-01218 oning Project Reviewed by:
Peak rejection level:         25.000%
__
Peak search sensitivity:      3 sample size:                  4.6380E+02 Activity scaling factor:      1.0000E+06/( 1.0000E+00*    4.6380E+02) 2.1561E+03 Detection limit method:        Nureg 4.16 Random error:                  1.0000000E+00 systematic error:              1.0000000E+00 Fraction Limit:                0.000%
0*8 Laboratory:
Background width:              best method (based on spectrum).
PBRF R. Case Page 
o page 1
*
* 1 ORTEC g v -i (1087) npp32 G53w3.05 26-MAR-2008 16:29:47 Page PBRF Spectrum name: PB08-01082.An1 sample description PB08-01082; SR99-14; PPH-RM4; FD-4-2; 3/26/08 Spectrum Filename:
z:\Lab\SAMPLE 08\PB08-01082.An1 Acquisition information Start time: 26-Mar-2008 16:19:45 Live time: 300 Real time: 301 Dead time: 0.19 % Detector 1D: 3 Detector system#3 DETECTOR (#131) ro Calibration Filename:
250ml #73678-773 (MC131) Sept07 Energy Calibration Created: Zero offset: 05-Sep-2007 16:56:38 0.565 kev Gain: Quadratic:
0.247 kev/channel 5.022E-08 kev/channel A 2 Efficiency Calibration Created: Type: Uncertai nty: Coeffi ci ents : 05-Sep-2007 17:17:39 Polynomial
: 1. 204 % -0.304311
-4.249899 0.669559 -0.094002 0.005803 -0.000133 Library Files Main analysis library: Library Match width: peak stripping:
plumbrk OI.lib 0.500 Library based Analysis parameters Analysis engine: Start channel: Stop channel: Peak rejection level: Peak search sensitivity:
sample size: Activity scaling factor: npp32 G53w3.05 155 ( 38.83kev ) 8144 ( 2014.22kev) 25.000% 3 4.2770E+02 1.0000E+06/( 1.0000E+00*
2.3381E+03 4.2770E+02)
Detection limit method: Nureg 4.16 Random error: 1. OOOOOOOE+OO systematic error: Fraction Limit: 1.0000000E+00 0.000% Background width: best method (based on spectrum).
o page 1 
*
* PB08-01082 ORTEC g v -i (1087) npp32 G53w3.05 26-MAR-2008 16:29:47 Page 2 PBRF Spectrum name: PB08-01082.An1 Half lives decay limit: Activity range factor: Min. step backg. energy Corrections Status Comments Decay correct to date: YES 18-Mar-2008 15:18:00 Decay during acquisition:
NO Decay during collection:
NO True coincidence correction:
NO Peaked background correction:
NO Absorption (Internal):
NO Geometry correction:
NO Random summing: NO Energy Normalized diff: SUM MAR Y0 F PEA K SIN RAN G E ***** Peak Area Uncert FWHM Corrctn Nuclide Brnch. Act. NUc Energy Factor Energy Ratio pcijg 77 .00 98. 22.48 0.54 8.260E-02 238.88 57. 16.36 0.75 6.191E-02 238.63 43.300 4.475E-01 PB212 352.26 51. 16.98 0.95 4.551E-02 351. 93 37.600 6.272E-01 PB214 609.46 45. 14.91 1. 09 2.830E-02 609.31 46.100 7.266E-01 BI214 1461.03 97. 10.15 1. 29 1. 387E-02 1460.83 11.000 1.340E+01 K40 ************ U N IDE N T I FIE D PEA K SUM MAR Y ************
peak Centroid Background Net Area Intensity Uncert FWHM Suspected Channel Energy Counts Counts Ctsjsec 2 sigma % kev Nuclide 309.61 77.00 75. 98. 0.327 44.97 0.543 sM s -Peak fails shape D
* peak area L -Peak written from unknown C -Area < Critical M -Peak is close to a library This section based on library: plumbrk 01.lib o ORTEC g v -(1087) npp32 G53w3.05 26-MAR-2008 16:29:47 Page PBRF spectrum name: -f,-"1: ,*-1: "1,"1:-!;-;:-,':'1:
"!;-,',"-;:*
-,':,';-);;:*"1;;;-;,-;;-1:'1:'1:'1:-;, I D E N T I FI E D PEA K S UMM AR Y Nuclide peak Centroid Background Net Area Intensity Uncert FItJHM channel Energy Counts Counts CtsjSec 2 sigma % kev AM-241 0.00 59.54 O. O. 0.000 0.00 0.000 TH-234 0.00 63.29 O. O. 0.000 0.00 0.000 0.000 TH-234 0.00 92.59 O. O. 0.000 0.00 EU-152 0.00 121. 78 O. O. 0.000 0.00 0.000 EU-154 0.00 123.07 O. O. 0.000 0.00 0.000 0.00 143.76 O. O. 0.000 0.00 0.000 u-235 Page 2 
*
* PB08-01082 U-235 0.00 185.71 O. O. 0.000 0.00 0.000 PB-212 965.25 238.88 10. 57. 0.190 32.73 0.747s EU-152 0.00 344.28 O. O. 0.000 0.00 0.000 PB-214 1424.32 352.26 6. 51. 0.170 33.96 0.945 Ag-108m BI-214 0.00 2465.45 433.94 609.46 O. O. O. 45. 0.000 0.150 0.00 29.81 0.000 1. 087s Ag-108m cS-137 0.00 0.00 614.28 661. 66 O. O. O. O. 0.000 0.000 0.00 0.00 0.000 0.000 Ag-108m EU-154 0.00 0.00 722.91 723.30 O. O. O. O. 0.000 0.000 0.00 0.00 0.000 0.000 BI-212 0.00 727.33 O. O. 0.000 0.00 0.000 EU-154 0.00 1004.72 O. O. 0.000 0.00 0.000 co-60 0.00 1173 . 24 O. O. 0.000 0.00 0.000 EU-154 0.00 1274.44 O. O. 0.000 0.00 0.000 co-60 0.00 1332.50 O. O. 0.000 0.00 0.000 EU-152 0.00 1408.01 O. O. 0.000 0.00 0.000 K-40 5909.36 1461. 03 O. 97. 0.323 20.31 1.287s s -peak fails shape D -peak area A Derived peak SUM MAR Y a F LIB RAR Y PEA K USA G E -Nuclide
-------------
Peak Name Actlvlty Energy Activity Code MDA value pci/g kev pci/g pci/g COMMENTS K-40 N 1. 3396E+01 1460.83 1.340E+01 ( 1.018E+00 10.15 G K PB-212 4.4753E-01 238.63 4.475E-01 ( 1. 370E-01 16.36 G K PB-214 6.2724E-01 351.93 6.272E-01
?( 1. 737E-01 16.98 G K 0 ORTEC g v -i (l087) npp32 G53w3.05 26-MAR-2008 16:29:47 page 4 PBRF Spectrum name: PB08-01082.An1 Nuclide activity Energy Activity Code Peak MDA Comments BI-214 7.2659E-01 609.31 7.266E-01 ( 1.190E-01 14.91 G K 1764.49 O.OOOE+OO
% 8.516E-01 35.36 G 1120.29 O.OOOE+OO
& 9.768E-01 321.46 ( -This peak used in the nuclide activity
-peak is too wide, but only one peak in
-peak is part of a multiplet and this area negative during ? -peak is too @ -peak is too wide at Fw2SM, but ok at % -peak fails sensitivity $ -peak identified, but first peak of this failed one or more qualification + -peak activity higher than counting uncertainty peak activity lower than counting uncertainty -peak outside analysis energy &-calculated peak is not.c!ose.enough.to library energy centrold for POSltlve Page 
*
* PB08-01082 P peakbackground subtraction peak is too close to another for the activity to be found directly.
Nuclide Peak Codes: T Thermal Neutron Activation G -Gamma Ray F Fast Neutron Activation X -X-Ray I Fission Product P -Positron Decay N Naturally occurring Isotope S -single-Escape P Photon Reaction D -Double-Escape C Charged Particle Reaction K -Key Line M No MOA Calculation A -Not in Average R Coincidence Corrected C -coincidence Peak H Ha lfl i fe 1 i mi t exceeded .)* .)* .J* .)* .)_ 1: 1,.:: 1: S UMMAR y 0F NUC LI 0 ES I N SA MP LE Time of Count Time Corrected uncertainty 2 Sigma Nuclide Activity Activity counting Total MDA pci/g pci/g pCi/g pCi/g K-40  1. 3396E+01 1. 3396E+01 2.7203E+OO 2.7485E+OO 1.018E+00 co-60 B< 1. 0390E-01 1.0420E-01 Ag-108mB<
4.5425E-02 4.5427E-02 cs-137 B< 6.9119E-02 6.9154E-02 EU-152 B< 1. 4944E-01 1. 4961E-01 EU-154 B< 1. 4888E-01 1.4914E-01 PB-212  4.4753E-01 4.4753E-01 1.4647E-01 1.4692E-01 1.370E-01 PB-214 & 6.2724E-01 6.2724E-01 2.1302E-01 2.1382E-01 1.737E-01 BI-212 B< 1. 3928E+OO 1.3928E+OO o ORTEC 9 v -i (1087) npp32 G53w3.05 26-MAR-2008 16:29:47 page 5 P8RF spectrum name: PB08-01082.An1 BI-214 7.2658E-01 7.2659E-01 2.1663E-01 2.1801E-01
: 1. 190E-01 RA-226 B< 2.2173E+OO 2.2173E+00 TH-234 B< 1. 5680E+OO 1.5680E+00 u-235 B< 4.1374E-01 4.1374E-01 8< 2.2357E-01 2.2357E-Ol #-All peaks for activity calculation had bad  Activity omitted from & -Activity omitted from total and all peaks had bad < -MDA value A -Activity printed, but activity < B -Activity < MDA and failed C -Area < critical F -Failed fraction or key line H -Halflife limit ARY Total Activity ( 38.8 to Total Decayed Activity ( O.OOOOOOOE+OO Analyzed by: Reviewed by: 2GOB Laboratory:
PBRF Page 4 1
* ORTEC g v -1 (l087) npp32 page PBRF sample description PB08-00797; SR99-008; PPH; spectrum Filename:
z:\Lab\SAMPLE Acquisition information Start time: 13-Mar-2008 14:23:27 Live time: 300 Real time: 301 Dead time: 0.39 % Detector TO: 2 Detector system#2 DETECTOR (#130) Dc p Calibration 250ml #73678-773 PB08-00797 Energy Calibration Created: zero offset: Gain: Quadratic:
Efficiency calibration created: Type: uncertainty:
coeffi ci ents : Library Main analysis Library Match peak Analysis parameters Analysis engine: Start channel: Stop channel: peak rejection level: peak search sensitivity:
sample size: Activity scaling factor: Detection limit method: Random error: systematic error: Fraction Limit: Background width: o 13-Sep-2007 15:00:31 0.287 kev 0.251 kev/channel 2.324E-08 kev/channel A 2 13-Sep-2007 15:22:08 polynomial 1.626 % -0.256697 -4.334323
-0.092291 0.005686 plumbrk 01.1ib Library npp32 G53w3.05 155 ( 39.27kev )8144 ( 2049.92kev) 1.0000E+06/( 1.0000E+00*
2.2502E+03 Nureg 4.16 1.0000000E+00
: 1. OOOOOOOE+OO 0.000%
best method (based on spectrum).
page 1 
*
* PBRF ORTEC g v -i (1087) npp32 PB08-00797 G53w3.05 13-MAR-2008 14:29:02 Spectrum name: PB08-00797.An1 Page 2 Half lives decay limit: Activity range factor: Min. step backg. energy 12.000 2.000 0.000 corrections Status Comments Decay correct to date: YES 11-Mar-2008 08:22:00 Decay during acquisition:
NO Decay during collection:
NO True coincidence correction:
NO Peaked background correction:
NO Absorption (Internal):
NO Geometry correction:
NO Random summing: NO Energy Normalized diff: SUM MAR Y 0 F PEA K SIN RAN GE ***** Peak Area Uncert FWHM Corrctn Nuclide Brnch. Act. NUc Energy Factor Energy Ratio pci/g 186.14 45. 23.92 0.33 6.693E-02 186.21 3.590 3.825E+00 RA226 238.58 76. 13.86 1. 01 5.760E-02 238.63 43.300 6.178E-01 PB212 351.88 53. 19.31 0.68 4.242E-02 351.93 37.600 6.780E-01 PB214 609.62 42. 15.43 1. 26 2.665E-02 609.31 46.100 6.930E-01 BI214 661.70 77. 12.45 0.59 2.492E-02 661.66 85.100 7.329E-01 CS137 1173 .15 25. 20.00 0.34 1. 604E-02 1173 .24 99.974 3.164E-01 c060 1331.67 17. 24.25 0.25 1. 459E-02 1332.50 99.986 2.364E-Ol c060 1460.75 91. 10.48 0.67 1. 362E-02 1460.83 11.000 1.231E+01 K40 No unknown peaks passed sensitivity test. This section based on library: plumbrk 01.lib **************
IDE N T I FIE D PEA K SUM MAR Y **************
Nuclide Peak Centroid Background Net Area Intensity Uncert FWHM Channel Energy Counts Counts Cts/Sec 2 sigma % key AM-241 0.00 59.54 O. O. 0.000 0.00 0.000 TH-234 0.00 63.29 O. O. 0.000 0.00 0.000 TH-234 0.00 92.59 O. O. 0.000 0.00 0.000 EU-152 0.00 121.78 O. O. 0.000 0.00 0.000 EU-154 0.00 123.07 O. O. 0.000 0.00 0.000 u-235 0.00 143.76 O. O. 0.000 0.00 0.000 u-235 0.00 185.71 O. O. 0.000 0.00 0.000 RA-226 PB-212 EU-152 738.96 947.48 0.00 186.14 238.58 344.28 17. 10. O. 45. 76. O. 0.151 0.253 0.000 47.83 27.73 0.00 0.329s LOBs 0.000 PB-214 1397.90 351.88 13. 53. 0.178 38.63 0.682s o PBRF ORTEC g v -(1087) npp32 G53W3.05 13-MAR-2008 14:29:02 spectrum name: PB08-00797.An1 page 3 Nuclide Channel Energy Background Net area Cnts/sec Uncert Ag-108m 0.00 433.94 O. O. 0.000 0.00 BI -214 2422 .38 609.62 O. 42. 0.140 30.86 1. Ag-108m 0.00 614.28 O. O. 0.000 0.00 Page 2 
*
* PB08-00797 c5-13 7 2629.41 661.70 3. 77. 0.256 24.90 0.591s Ag-108m 0.00 722.91 O. O. 0.000 0.00 0.000 EU-154 0.00 723.30 O. O. 0.000 0.00 0.000 81-212 0.00 727.33 O. O. 0.000 0.00 0.000 EU-154 0.00 1004.72 O. O. 0.000 0.00 0.000 co-60 4661. 74 1173.15 O. 25. 0.083 40.00 0.340s EU-154 0.00 1274.44 O. O. 0.000 0.00 0.000 co-60 5291. 50 1331.67 O. 17. 0.057 48.51 0.252s EU-152 0.00 1408.01 O. O. 0.000 0.00 0.000 K-40 5804.26 1460.75 O. 91. 0.303 20.97 0.673s s -Peak fails shape D -Peak area A Derived peak oJ* ..L  ..J# oJ. F -h-t,."'!.**SU M MAR Y 0 LI B RAR Y P EAK U SAGE -Nuclide -
-------------
Peak Name Code ActlVlty Energy Activity Code MDA value pci/g kev pci/g pci/g COMMENTS K-40 N 1.2311E+01 1460.83 1,231E+01?( 9.971E-01 10.48 G K co-60 F 2.7640E-01 1332.50 2.364E-O(';J 1173.24 1.025E-01 9.327E-02 24.25 G K 20.00 G K cs-137 I 7.3295E-01 661.667.329E-01 ( 1.072E-01 12.45 G K PB-212 N 6.1776E-01 238.63 6.178E-01
*( 1.418E-01 13.86 G K PB-214 N 6.7796E-01 351.93 6.780E-01 ( 2.453E-01 19.31 G K B1 -214 N 6.9298E-01 609.31 6.930E-01 ( 1.216E-01 15.43 G K 1764.49 O.OOOE+OO
% 8.220E-01 50.00 G 1120.29 O.OOOE+OO
% 5;961E-01 26.73 G RA-226 N 3.8248E+OO 186.21 3.825E+00 ( 1.834E+00 23,92 G K ORTECgv -1 (1087) npp32 G53w3.05 13-MAR-2008 14:29:02 PBRF Spectrum name: ( -This peak used in the nuclide activity average. peak is too wide, but only one peak in
-peak is part of a multiplet and this area negative during ? -peak is too @ -peak is too wide at FW25M, but ok at % -Peak fails sensitivity $ -peak identified, but first peak of this failed one or more qualification + -peak actlvlty hlgher than


--peak activlty lower than countlng uncertalnty peak outslde analysis energy Page 4 
ORTEC g v - i (1087) npp32
* * & -Calculated peak centroid is not close enough to library energy centroid for positive P -peakbackground
* PB08-01280 G53w3.05 15-APR-2008 15:49:44 Page                      2 PBRF                                                      Spectrum name: PB08-01280.An1 Half lives decay limit:                   12.000 Activity range factor:                      2.000 Min. step backg. energy                    0.000 Corrections                                                      Status            Comments Decay correct to date:                          YES        14-Apr-2008 11:32:00 Decay during acquisition:                      NO Decay during collection:                        NO True coincidence correction:                    NO Peaked background correction: NO Absorption (Internal):                          NO Geometry correction:                            NO Random summing:                                NO Energy calibration Normalized diff:            0.1987 SUM MAR Y 0 F                     PEA K S I N           RAN G E *****
} Peak is too close to another for the to be found directly.
Peak                          Area      uncert FWHM        Corrctn      Nuclide Brnch.        Act.              NUC Energy                                                      Factor      Energy    Ratio    pCi/g 238.65                            80. 13.07    1.17    5.760E-02      238.63  43.300  6.231E-01 PB212 351. 90                          45. 17.43    1. 24  4.241E-02      351.93  37.600  5.522E-01 PB214 582.97                            29. 22.90    0.60    2.764E-02 608.92                            41. 15.62    1.13    2.665E-02      609.31  46.100  6.482E-01             BI214 1172.94                              38. 16.22    0,82    1.604E-02     1173.24  99.974  4.606E-Ol            c060 1332.15                              48. 14.43    0.44    1. 459E-02    1332.50  99.986  6.394E-01           C060 1460.39                              105. 9.76    1. 69  1. 362E-02    1460.83  11.000  1.361E+01             K40
Nuclide Codes: Peak T -Thermal Neutron Activation G -Gamma F -Fast Neutron Activation X -I -Fission product P -Positron N -Naturally occurring Isotope S -
************ U N IDE N T I FIE D                                      PEA K        SUM MAR Y Peak Centroid Background Net Area                              Intensity    Uncert    FWHM Suspected Channel                      Energy        counts      Counts      Cts/sec    2 sigma % kev        Nuclide 2316.46                      582.97            3.            29.     0.096    45.81    0.600 TL-208                s s    -     Peak          fails shape tests.
P -Photon Reaction 0 -
D    -     peak          area deconvoluted.
C -charged particle Reaction K -Key M -No MDA calculation A -Not in R -Coincidence Corrected C -Coincidence H -Halflife 1 i mi t .J. oJ. J* .J* .J.***** SUM MAR Y 0 F N U C LI DE S I N SAMPLE Time of Count Time COf'rected uncertainty 2 sigma Nuclide Activity Activity counting Total MDA pci/g pci/g pci/g pci/g K-40 co-60 Ag-108 cs-137 EU-152 B< EU-154 B< PB-212 & PB-214 BI-212 _.B< BI-214 RA-226 ". TH-234 B< u-235 B< AM-241 B< 0 ORTEC PBRF 1.2311E+01 2.7618E-01 4.6802E-02 7.3284E-01 1,8271E-01
L    -     Peak          written from unknown list.
: 1. 4495E-01 6.1776E-01 6.7796E-01 1.6534E+00 6.9297E-01 3.8248E+00
C   -   Area           < critical level.
: 1. 8569E+00 3.8817E-01 1.9880E-01 g v -1 (1087) 1.2311E+01 2.5811E+00 2.6108E+00 9.971E-01 2.7640E-01 8.6891E-02 8.7338E-02
This section based on library: plumbrk 01.lib D
: 1. 024E-01 4.6802E-02 7.3295E-01
ORTEC g v -                 1 (1087) npp32    G53w3.05 15-APR-2008 15:49:44 page                      3 PBRF                                                        Spectrum name: PB08-01280.An1
: 1. 8251E-01 1. 8400E-01 1. 072E-01 1. 8277E-01 1. 4502E-01 6.1776E-01  
* '1. 1.
: 1. 7128E-01 1. 7202E-01 1.418E-01 6.7796E-01 2.6189E-01 2.6278E-01 2.453E-01 1.6534E+00 6.9298E-01 2.1386E-01 2.1531E-01  
* 1: *" * -/: '1: 1;1: * -/:
: 1. 216E-01 3.8248E+00
* I D E N T I F I E D      P EA K      S U M M A R Y *1:*'1:'1:"1:1:1:'1;*::1:'1:-1:-:.
: 1. 8295 E+OO 1.8743E+00 1.834E+00
Nuclide                    peak          Centroid Background Net Area          Intensity    uncert FWHM channel Energy          Counts          Counts      Cts/sec 2 sigma % kev AM-241                            0.00      59.54            O.            O.      0.000      0.00          0.000 TH-234                            0.00      63.29            O.            O.      0.000      0.00          0.000 TH-234                            0.00      92.59            O.            O.      0.000      0.00          0.000 EU-152                          0.00      121.78            O.            O.      0.000      0.00          0.000 EU-154                          0.00      123.07            O.           O.     0.000      0.00          0.000 Page 2
: 1. 8569E+00 3.8817E-01 1.9880E-01 npp32 G53w3.05 13-MAR-2008 14:29:02 Page Spectrum name: PB08-00797.An1 # -All peaks for activity calculation had bad shape. h Activity omitted from total & -Activity omitted from total and all peaks had bad shape. < -MDA value printed.A -Activity printed, but actlvlty < MDA. B -Activity < MDA and failed test. C -Area < critical level. F -Failed fraction or key line test. H -Halflife limit exceeded -----------------------------
SUM MAR Y Total Activity ( 39.3 to 2049.9 kev) 1.0090208E+00 pCi/g Total Decayed Activity ( 39.3 to 2049.9 kev) 1.0093489E+00 pci/g A PBRF D Analyzed by: sioning projef1AR M 1 3 2008 Reviewed by: R. CaSA Page 4 5 
*
* PB08-00797 Laboratory:
PBRF Page  
*
* 1 ORTEC g v -(1087) npp32 G53w3.05 26-MAR-2008 16:42:13 Page PBRF Spectrum name: PB08-01083.An1 sample description PB08-01083; SR99-15; PPH-RM4; FD-4-3B; 3/26/08 spectrum Filename:
z:\Lab\SAMPLE 08\PB08-01083.An1 Acquisition information Start time: 26-Mar-2008 16:27:02 Live time: Real time: Dead time: 0.69 Detector TO: Detector system#1 DETECTOR (#129) [] COpy Calibration Filename:
250ml #73678-773 (MC129) Jan08 Energy calibration Created: Zero offset: Gain: Quadratic:
Efficiency Calibration created: Type: uncertainty:
Coefficients:
Library Files Main analysis library: Library Match Width: Peak stripping:
Analysis parameters Analysis engine: Start channel: Stop channel: peak rejection level: Peak search sensitivity:
sample size: Activity scaling factor: Detection limit method: Random error: systematic error: Fraction Limit: Background width: o 09-Jan-2008 08:36:01 -0.051 kev 0.250 kev/channel
-8.299E-09 kev/channelA2 09-Jan-200809:15:56 Polynomial
: 1. 663 % -0.338084
-4.099654
-0.082467 0.004895 plumbrk 01.lib Library npp32 G53W3.05 155 ( 38.73kev)8144 ( 2037.21kev) 1.0000E+06/( 1.0000E+00*
4.4360E+02) 2.2543E+03 Nureg 4.16 1.0000000E+00 1.0000000E+00 0.000% best method (based on spectrum).
Page 1 
*
* PB08-01083 PBRF ORTEC g v -i (10S7) npp32 G53w3.05 26-MAR-2008 16:42:13 Spectrum name: PB08-01083.An1 Page 2 Half lives decay limit: Activity range factor: Min. step backg. energy 12.000 2.000 0.000 Corrections Status Comments Decay correct to date: YES 18-Mar-2008 15:30:00 Decay during acquisition:
NO Decay during collection:
NO True coincidence correction:
NO Peaked background correction:
NO Absorption (Internal):
NO Geometry correction:
NO . Random summing: NO Energy Normalized diff: SUM MAR Y 0 F PEA K SIN RAN G E Peak Area uncert FWHM Corrctn Nuclide Brnch. Act. NuC Energy Factor Energy Ratio pCi/g 238.62 74. 14.50 0.45 6.441E-02 238.63 43.300 5.388E-01 PB212 351.81 57. 15.79 1. 07 4.765E-02 351.93 37.600 6.461E-01 PB214 609,26 49. 14.29 1. 24 3.006E-02 609.31 46.100 7.181E-0l BI214 1460.79 116. 9.28 0.76 1.481E-02 1460.83 11.000 1.446E+01 K40 No unknown peaks passed sensitivity test. This section based on library: plumbrk 01.lib **************
IDE N T I FIE D PEA K SUM MAR Y **************
Nuclide peak centroid Background Net Area Intensity Uncert FWHM Channel Energy Counts Counts Cts/sec 2 sigma % kev AM-241 0.00 59.54 O. O. 0.000 0.00 0.000 TH-234 0.00 63.29 o. o. 0.000 0.00 0.000 TH-234 0.00 92.59 O. O. 0.000 0.00 0.000 EU-152 0.00 121.78 O. O. 0.000 0.00 0.000 EU-154 0.00 123.07 O. O. 0.000 0.00 0.000 U-235 0.00 143.76 O. O. 0.000 0.00 0.000 u-235 0.00 185.71 O. O. 0.000 0.00 0.000 RA-226 0.00 186.21 O. O. 0.000 0.00 0.000 PB-212 953.86 238.62 13. 74. 0.247 29.00 0.448s EU-152 0.00 344.28 O. O. 0.000 0.00 0.000 PB-214 Ag-108m BI-214 Ag-108m cs-137 1406.28 0.00 2435.29 0.00 0.00 351.81 433.94 609.26 614.28 661.66 6. O. O. O. O. 57. O. 49. O. O. 0.190 0.000 0.163 0.000 0.000 31. 58 0.00 28.57 0.00 0.00 1. 066 0.000 1. 241 0.000 0.000 o PBRF ORTEC g v -(1087) npp32 G53w3.05 26-MAR-2008 16:42:13 spectrum name: PBOS-01083.An1 page 3 Nuclide channel Energy Background Net area Cnts/sec Uncert Ag-108m 0.00 722.91 O. O. 0.000 0.00 EU-154 0.00 723.30 O. O. 0.000 0.00 O. o. 0.000 0.00 0.000 BI-212 0.00 727.33 page 2 
*
* PB08-01083 EU-154 0.00 1004.72 O. O. 0.000 0.00 0.000 co-60 0.00 1173.24 O. O. 0.000 0.00 0.000 EU-154 0.00 1274.44 O. O. 0.000 0.00 0.000 co-60 0.00 1332.50 O. O. 0.000 0.00 0.000 EU-152 0.00 1408.01 O. O. 0.000 0.00 0.000 K-40 5839.29 1460.79 O. 116. 0.387 18.57 0.765s s -peak fails shape tests. D -Peak area deconvoluted.
A Derived peak area. SU M MAR Y oF LIB RAR Y PEA K USAGE -Nuclide
-------------
Peak Name Code ActlVlty Energy Activity code MDA value pci/g kev pci/g pCi/g COMMENTS K-40 N 1. 4462E+Ol 1460.83 1.446E+01 ( 9.189E-Ol 9.28 G K PB-212 N 5.3885E-Ol 238.63 5.388E-01 ( 1.421E-01 14.50 G K PB-214 N 6.4609E-Ol 351.93 6.461E-01 ( 1.601E-01 15.79 G K BI-214 N 7.1812E-01 609.31 7.181E-01 (1764.49 O.OOOE+OO
% 1.080E-01 8.118E-Ol 14.29 G K 183.33 G 1120.29 O.OOOE+OO
% 5.388E-01 25.82 G ( -This peak used in the nuclide activity average. " peak is too wide, but only one peak in library. -Peak is part of a multiplet and this area went negative during deconvolution. ? -peak is too narrow. @ peak is too wide at FW25M, but ok at FWHM. % peak fails sensitivity test. $ -peak identified, but first peak of this nuclide failed one or more qualification tests. peak activity higher than counting uncertainty+ -range. --peak activity lower than counting uncertainty range. -peak outside analysis energy range.& -calculated peak centroid is not close enough to the library energy centroid for positive identlfication.
ORTEC g v -i (1087) npp32 G53w3.05 26-MAR-2008 16:42:13 page 4 PBRF Spectrum name: PB08-01083.Anl P -peakbackground subtraction } -Peak is too close to another for the activity to be found directly.
Nuclide codes: Peak codes: T Thermal Neutron Activation G -Gamma Ray F Fast Neutron Activation X -X-Ray I Fission Product P -positron Decay N Naturally occurring Isotope 5 -single-Escape P photon Reaction D -Double-Escape C charged particle Reaction oK -Key Line M NO MDA calculation A -Not in Average page 3 
*
* PB08-01083 R -Coincidence Corrected C -Coincidence Peak H -Halflife limit exceeded SUM MAR Y oF NU eLI DES I N SAM PLE Time of Count Time Corrected uncertainty 2 Sigma Nuclide Activity Activity Counting Total MDA pci/g pci/g pci/g pci/g K-40 ". 1. 4462E+01 1.4462E+01 2.6856E+00 2.7256E+00 9.189E-01 eo-60 B< 9.3659E-02 9.3930E-02 Ag-108mB<
5.2525E-02 5.2527E-02 e5-137 B< 6.2613E-02 6.2644E-02 EU-152 B< 1.1639E-01 1.1652E-01 EU-154 B< 1. 5062E-01 1.5089E-01 PB-212 "' 5.3885E-01 5.3885E-01
: 1. 5629E-01 1.5691E-01 1.421E-01
".PB-214 6.4608E-01 6.4609E-01 2.0403E-01 2.0509E-01 1.601E-01 BI-212 B< 8.7465E-01 8.7465E-01 BI-214 '1( --7 :-lbT1F\Y:'--rTIIT2E="URA-226 B< 2.4956E+OO 2.4957E+OO TH-234 B< 1.6156E+00 1.6156E+00 u-235 B< 3.071lE-01 3.0711E-01 AM-241 B< 2.1461E-01 2.1461E-0l # -All peaks for activity calculation had bad shape. . Activitv omitted from total & -Activity omitted from total and all peaks had bad shape. < -MDA value printed, A -Activity printed, butactlvlty
< MDA. B -Activity < MDA and failed test. e -Area < critical level. F -Failed fraction or key line test. H -Halflife limit exceeded -----------------------------
SUM MAR Y Total Activity ( 38.7 to 2037.2 kev) O.OOOOOOOE+OO pci/g Total Decayed Activity ( 38.7 to 2037.2 kev) O.OOOOOOOE+OO pCi/g Analyzed by: A," project  l Reviewed by: A. Case o ORTEe 9 v -(1087) npp32 G53w3.05 26-MAR-2008 16:42:13 Page PBRF spectrum name:
Laboratory:
PBRF page 4 
*
* ORTEC g v -i (1087) npp32 G53w3.05 15-APR-2008 15:50:44 Page 1 PBRF Spectrum name: PB08-01283.An1 sample description PB08-01283; SR99-56; PPH -RM8 -FD8-1; 4/15/08 spectrum Filename:
z:\Lab\SAMPLE 08\PB08-01283.An1 Acquisition information Start time: 15-Apr-2008 15:41:43 Live time: 300 Real time: 301 Dead time: 0.17 % [J COpy Detect-o r 10: :> Detector system#3 DETECTOR (#131) Calibration Filename:
2S0ml #73678-773 (MC131) Sept07 Energy Calibration Created: Zero offset: Gain: Quadratic:
Efficiency Calibration Created: Type: uncertainty:
coefficients:
Library Main analysis Library Match Peak Analysis parameters Analysis engine: Start channel: Stop channel: Peak rejection level: Peak search sensitivity:
sample Size: Activity scaling factor: Detection limit method: Random error: Systematic error: Fraction Limit: Background width: o 05-Sep-2007 16:56:38 0.565 kev 0.247 kev/channel 5.022E-08 kev/channel A 2 05-sep-2007 17:17:39 Po 1 ynomi a1 1.204 % -0.304311 -4.249899
-0.094002 0.005803 pl umbrk 01.1 i bLibrary npp32 G53w3.05 155 ( 38.83kev )8144 ( 2014.22kev) 1.0000E+06/( 1.0000E+00*
4.8520E+02) 2.0610E+03 Nureg 4.16 1.0000000E+00
: 1. best method (based on page 1 
*
* PBRF ORTEC g v -i (1087) npp32 PB08-01283 G53w3.05 15-APR-2008 15:50:44 Page spectrum name: PB08-01283.An1 2 Half lives decay limit: Activity range factor: Min. step backg. energy 12.000 2.000 0.000 corrections Status Comments Decay correct to date: Decay during acquisition:
Decay during collection:
True coincidence correction:
YES NO NO NO 14-Apr-2008 11:23:00 peaked background correction:
Absorption (Internal):
Geometry correction:
Random summing: NO NO NO NO Energy Normalized diff:
1: 1: 1:1:**1,"S UMMARY 0 F PE A K S I N RAN G peak Area uncert FWHM Corrctn Nuclide Brnch. Act. Energy Facto r Energy Ratio 77.24 44. 24.24 0.92 8.258E-02 238.69 80. 13.81 0.99 6.195E-02 238.63 43.300 5.537E-01 PB212 351. 94 57. 19.85 0.59 4.555E-02 351. 93 37.600 6.216E-01 PB214 609.06 51. 14.00 0.88 2.830E-02 609.31 46.100 7.259E-01 BI214 1460.23 127. 8.87 1. 39 1. 387E-02 1460.83 11.000 1.546E+01 K40 *1; 1: 1: i: "1: 1: 1: "/,'1:"/:
* UNI DE N T T FI ED P E A K S U MMA R Y  1,-1: "1.: '1: 1: * -/: -;..  * -1.J.. Peak Centroid Background Net Area Intensity Uncert FWHM suspected channel Energy Counts Counts CtsjSec 2 Sigma % kev Nuclide 310.61 77.24 27. 44. 0.148 48.47 0.924 M s -peak fails shape D -Peak area L-peak written from unknown C -Area < Critical M -Peak is close to a library This section based on library: plumbrk OI.lib o ORTEC g v -i (1087) npp32 G53w3.05 15-APR-2008 15:50:44 page PBRF spectrum name:
1: 1: 1: "* 1: 1: 1: 1: 7.1: 1;1: * -/: I DENT I F I E D PE A K S UMM A R Y -:: -t: '* * "'1: "* * -:.. -1: *1.. 1: 1: -1: Nuclide peak centroid Background Net Area Intensity Uncert FWHM ....channel Energy Counts Counts ctsjsec sigma % kev L AM-241 0.00 59.54 O. O. 0.000 0.00 0.000 O. O. 0.000 0.00 0.000 TH-234 0.00 TH-234 0.00 92.59 O. O. 0.000 0.00 EU-152 0.00 121. 78 O. O. 0.000 0.00 EU-154 0.00 123.07 O. O. 0.000 0.00 u-235 0.00 143.76 O. O. 0.000 0.00 Page 
*
* PB08-01283 u-235 0.00 185.71 O. O. 0.000 0.00 0.000 PB-212 964.47 238.69 14. 80. 0.267 27.61 0.994 EU-152 0.00 344.28 O. O. 0.000 0.00 0.000 PB-214 1423.03 351. 94 17. 57. 0.191 39.71 0.5895 Ag-108m BI-214 0.00 2463.81 433.94 609.06 O. O. o. 51. 0.000 0.170 0.00 28.01 0.000 0.8755 Ag-108m cs-137 0.00 2675.78 614.28 661. 43 O. 4. O. 24. 0.000 0.080 0.00 50.00' 0.000 Ag-108m EU-154 0.00 0.00 722.91 723.30 O. O. O. O. 0.000 0.000 0.00 0.00 0.000 0.000 BI-212 0.00 727.33 O. O. 0.000 0.00 0.000 EU-154 0.00 1004.72 O. O. 0.000 0.00 0.000 co-60 0.00 1173.24 O. O. 0.000 0.00 0.000 EU-154 0.00 1274.44 O. O. 0.000 0.00 0.000 co-60 0.00 1332. SO O. O. 0.000 0.00 0.000 EU-152 0.00 1408.01 O. O. 0.000 0.00 0.000 K-40 5906.14 1460.23 O. 127. 0.423 .---1-7--.--1--5--1---.---3-945-. s -Peak fails shape D -Peak area A Derived peak ***** SUM MAR Y oF LIB RAR Y PEA K USAGE -Nuclide
-------------
Peak Name Actlvlty Energy Activity Code MDA value pci/g kev pci/g pci/g COMMENTS K-40 N 1. 5460E+Ol 1460.83 1.546E+01
\.. ,. 8.972E-01 8.87 G K CS-137 1.9842E-01 9.946E-02 25.00 G K 1. 984E-OG PB-212 5.5367E-01 238.63 5.537E-01
?( 1. 394E-Ol 13.81 G K 0 ORTEC 9 v -1 (1087) npp32 G53w3.05 15-APR-2008 15:50:44 page 4 PBRF spectrum name: PB08-01283.An1 Nuclide activity Energy Activity code Peak MDA Comments PB-214 6.2157E-01 351.93 6.216E-Ol
?( 2.356E-Ol 19.85 GK BI-214 7.2588E-01 609.31 7.259E-01?( 1.049E-01 14.00 G K 1764.49 O.OOOE+OO
% 7.507E-Ol 111.80 G 1120.29 O.OOOE+OO
% 8.179E-01 95.12 G ( -This peak used in the nuclide activity average. --Peak is too wide, but only one peak in
-Peak is part of a multiplet and this area negative during ? -Peak is too @ -Peak is too wide at FW25M, but ok at % -Peak fails sensitivity $ -Peak identified, but first peak of this failed one or more qualification + -Peak activity higher than


--Peak activity lower than countlng uncertalnty Page 3 
u-235           0.00           143.76
* *
* O.
-peak outside analysis energy & -Calculated peak centroid is not close enough to library energy centroid for positive P -peakbackground
PB08-01280 O.       0.000
} Peak is too close to another for the to be found directly.
* 0.00   0.000 u-235           0.00           185.71                 O.           O.       0.000     0.00   0.000 PB-212       947.76           238.65                 8.         80.       0.267   26.14   1.173s EU-152         0.00           344.28                 O.           O.       0.000     0.00   0.000 PB-214       1397.98           351.90                 4.         45.       0.151   34.86   1.238s Ag-108m         0.00           433.94                 O.           O.       0.000     0.00   0.000 B1 - 214     2419.63           608.92                 O.         41.       0.137   31. 23 1.132 Ag-108m         0.00           614.28                 O.           O.       0.000     0.00   0.000 c5-137         0.00           661.66                 O.           O.       0.000     0.00   0.000 Ag-108m         0.00           722.91                 O.           O.       0.000     0.00   0.000 EU-154         0.00           723.30                 O.           O.       0.000     0.00   0.000 BI-212         0.00           727.33                 O.           O.       0.000     0.00   0.000 EU-154         o. 00       1004. 72                 O.           O.       0.000     0.00   0.000 co-60       4660.92         1172.94                   O.         38.       0.127   32.44   0.818s EU-154         0.00       1274.44                   O.           O.       0.000     0.00   0.000   .
Nuclide Codes: Peak T -Thermal Neutron Activation G -Gamma F -Fast Neutron Activation X -I -Fission Product P -Positron N -Naturally occurring Isotope S -
co-60       5293.40       1332.15                   O.         48.       0.160   28.87   0.441s/
P -Photon Reaction D -
Ell 152         o o.oL-1J.,..<4,"-,O~8>--v-OJ.------V-.--------Y~-____\J...._\Aru__-__\,l,_.Wd___Y__riA~------
C -Charged particle Reaction K -Key M -No MDA Calculation A -Not in R -Coincidence Corrected C -Coincidence H -Halfl ife 1 i mi t oJ** oJ* .J# n
K-40         5802.82       1460.39                   O.       105.         0.350   19.52   1.690 s - Peak fails shape tests.
!J S U MMA R y 0 F NU C L I E S I N S A r.1 P L E Time of Count Time Corrected uncertainty 2 sigma Nuclide Activity Activity Counting Total MDA pci/g pci/g pci/g pci/g .c K-40 1. 5460E+01 1.5460E+01 2.7438E+00 2.7810E+00 8.972E-01 co-60 B< 9.1584E-02 9.1623E-02 Ag -108Jlf1R' 5.3398E-02 5.3398E-02 . /CS-1W 1. 9841E-01 1. 9842E-01 9.9212E-02 9.9382E-02 9,945E-02 JO EU-b < 1.4040E-01 1.4042E-01 I EU-154 B< 1. 1376E-01 1. 1379E-01 0 ORTEC g v -i (l087) npp32 G53w3.05 15-APR-2008 15:50:44 Page 5 PBRF Spectrum name: PB08-01283.An1 PB-212 & 5.5367E-01 5.5367E-01
D - Peak area deconvoluted.
: 1. 5289E-01 1. 5356E-01 1.394E-01 PB-214 & 6.2156E-01 6.2157E-01 2.4680E-01 2.4747E-01 2.356E-01 BI-212 B< 1. 0046E+00 1. 0046E+00 BI-214 & 7.2588E-01 7.2588E-01 2.0329E-01 2.0475E-01 1.049E-01 RA-226 B< 1.4202E+00
: 1. 4202E+00 TH-234 B< 1. 6149E+00 1. 6149E+00 u-235 B< 4.9162E-01 4.9162E-01 AM-241 B< 1.8240E-01
: 1. 8240E-01 # -All peaks for activity calculation had bad " Activity omitted from & -Activity omitted from total and all peaks had bad < -MDA value A -Activity printed, but activity < B -Activity < MDA and failed C -Area < Critical F -Failed fraction or key line H -Halflife limit
-----------------------------
SUM MAR Y Total Activity ( 38.8 to 2014.2 keY) 1.9840866E-01 pci/g Total Decayed Activity ( 38.8 to 2014.2 keY) 1.9842345E-01 pci/g y. I Analyzed by: Reviewed by: 
*
* PB08-01283 Supervisor Laboratory:
PBRF page 5 
*
* ORTEC g v -i (1087) npp32 PBRF sample description PB08-01284; SR99-57; PPH spectrum Filename:
z:\Lab\SAMPLE Acquisition information Start time: Live time: Real time: Dead time: Detector IO: 1 Detector system#1 DETECTOR (#129) calibration Filename:
250ml #73678-773 (MC129) Energy Calibration created: zero offset: Gain: Quadratic:
Efficiency Calibration Created: Type: uncertainty:
coeffi ci ents: Library Files Main analysis library: Library Match width: Peak stripping; Analysis parameters Analysis engine: Start channel: Stop channel: Peak rejection level: PB08-01284 G53w3.05 15-APR-2008 15:54:45 Page 1 Spectrum name: PB08-01284.An1 RM8 -FD8-2; 4/15/08 15-Apr-2008 0.60 % Jan08 09-Jan-2008 08:36:01 -0.051 kev 0.250 kev/channel
-8.299E-09 kev/channel A 2 09-Jan-2008 09:15:56 polynomial 1.663 % -0.338084
-4.099654
-0.082467 0.004895 plumbrk 01.lib Library npp32 G53w3.05 155 ( 38.73kev) 8144 ( 2037.21kev) 25.000%
Peak search sensitivity:
3 sample Size: 5.0470E+02 Activity scaling factor: 1.0000E+06/( 1.0000E+00*
5.0470E+02)
= L 9814E+03 Detection limit method: Nureg 4.16 Random error; 1.0000000E+00 systematic error:
Fraction Limit: Background width: best method (based on spectrum).
o page 1 
*
* PBRF ORTEC g v -i (1087) npp32 PB08-01284 G53w3.05 15-APR-2008 15:54:45 Spectrum name: PB08-01284.An1 page 2 Half lives decay limit: Activity range factor: Min. step backg. energy 12.000 2.000 0.000 Corrections Status Comments Decay correct to date: Decay during acquisition:
Decay during collection:
True coincidence correction:
YES NO NO NO 14-Apr-2008 11:14:00 peaked background correction:
Absorption (Internal):
Geometry correction:
Random summing: NO NO NO NO Energy calibration Normalized diff: 0.1373 peak Energy SUM MAR Y 0 Area Uncert F PEA K SIN RAN G E FWHM Corrctn Nuclide Brnch. Factor Energy Ratio Act. pci/g Nuc 74.77 45. 21. 06 0.82 8.366E-02 77.26 56. 18.22 0.82 8.392E-02 238.46 57. 16.36 0.42 6.444E-02 238.63 43.300 3.648E-01 PB212 294.94 36. 18.74 0.80 5.501E-02 351.92 608.97 72. 38. 11.79 16.22 1.33 0.83 4.765E-02 3.006E-02 351. 93 609.31 37.600 46.100 7.173E-01 ps214 4.895E-01 BI214 1120.08 18. 23.57 0.50 1. 840E-02 1120.29 15.100 1.157E+00 BI214 1460.79 97. 10.15 0.60 1. 481E-02 1460.83 11.000 1.063E+01 K40 ************
U N IDE N T I FIE D PEA K SUM MAR Y peak Centroid Background Net Area Intensity Uncert FWHM suspected Channel Energy Counts Counts Cts/sec 2 sigma % kev Nuclide 299.02 74.86 23. 45. 0.151 42.12 0.820 PB-214 D 308.99 77.36 23. 56. 0.185 36.44 0.823 PB-214 D 1178.97 294.94 2. 36. 0.118 37.48 0.798 PB-214 M s -Peak fails shape D -Peak area L-peak written from unknown C -Area < Critical M -peak is close to a library This section based on library: plumbrk 01.1ib o ORTEC g v -1 (l087) npp32 G53w3. as 15-APR-2008 15: 54: 45 Page 3 PBRF spectrum name: PB08-01284.Anl
* "i. 1.
* of; * * "1: * "1: * * '1: I D E N T I Nuclide peak Centroid channe 1 Energy F I E D P E A K Background Net Area Counts Counts S U M M A R Y *;( ;: * "1, "1: * ** "'1. *-/: "1, "'1. Intensity Uncert FWHM Cts/sec 2 sigma % kev AM-241 0.00 59.54 O. O. 0.000 0.00 0.000 page 2 
*
* PB08-01284 TH-234 0.00 63.29 O. O. 0.000 0.00 0.000 TH-234 0.00 92.59 O. O. 0.000 0.00 0.000 EU-152 0.00 121. 78 O. O. 0.000 0.00 0.000 EU-154 0.00 123.07 O. O. 0.000 0.00 0.000 u-235 0.00 143.76 O. O. 0.000 0.00 0.000 u-235 0.00 185.71 O. O. 0.000 0.00 0.000. RA-226 0.00 186.21 O. O. 0.000 0.00 0.000 PB-212 953.25 238.46 10. 57. 0.190 32.73 0.421s EU-152 0.00 344.28 O. O. 0.000 0.00 0.000 PB-214 1406.71 351.92 O. 72. 0.240 23.57 1.334s Ag-108m 0.00 433.94 O. O. 0.000 0.00 0.000 BI-214 2434.11 608.97 O. 38. 0.127 32.44 0.834s Ag-108m 0.00 614.28 O. O. 0.000 0.00 0.000 cs-137 0.00 661.66 O. O. 0.000 0.00 0.000 Ag-108m 0.00 722.91 O. O. 0.000 0.00 0.000 EU-154 0.00 723.30 O. O. 0.000 0.00 0.000 6I-212 o 00 727 33 0 0 a 000 a 00 o 000 EU-154 0.00 1004.72 O. O. 0.000 0.00 0.000 BI-214 4477.22 1120.08 O. 18. 0.060 47.14 0.500s co-60 0.00 1173.24 O. O. 0.000 0.00 0.000 r.EU-154 0.00 O. 0.000 0.00 0.000 v. co-60 0.00 1332.50 O. O. 0.000 0.00 0.000 EU-152 0.00 1408.01 O. O. 0.000 0.00 0.000 K-40 5839.32 1460.79 O. 97. 0.323 20.31 0.597s s -peak fails shape D -peak area A Derived peak SUM MAR Y oF LIBRARY PEA K USAGE -Nuclide
-------------
Peak Name Actl Vl ty Energy Activity Code MDA value pci/g kev pci/g pCi/g COMMENTS K-40 N 1.0629E+01 1460.83 1. 063E+01 ( 8.076E-01 10.15 G K PB-212 3.6481E-01 238.63 3.648E-01
?( 1. 117E-01 16.36 G K PB-214 7.1731E-01 351.93 7.173E-01
@( 7.342E-02 1l.79GK 0 ORTEC g v -1 (l087) npp32 G53w3.05 15-APR-2008 15:54:45 Page 4 PBRF Spectrum name: PB08-01284.An1 Nuclide activity Energy Activity code Peak MDA Comments BI-214 4.8948E-01 609.31 4.895E-01 ( 9.493E-02 16.22 G !( 1764.49 O.OOOE+OO
% 6.791E-01 30.15 G 1120.29 1.157E+00
+ 4.736E-01 23.57 G ( -This peak used in the nuclide activity average. Peak is too wide, but only one peak in
-Peak is part of a multiplet and this area negative during ? -peak is too @ -peak is too wide at FW25M, but ok at % -Peak fails sensitivity Page 3 
* * $ -Peak identified, but first peak of this nuclide failed one or more qualification tests. + -Peak activity higher than counting uncertainty range. --Peak activity lower than counting uncertainty range. -Peak outside analysis energy range.& -calculated peak centroid is not close enough to the library energy centroid for positive identlfication. P -peakbackground subtraction
} Peak is too close to another for the activity to be found directly.
Nuclide codes: Peak codes: T -Thermal Neutron Activation F -Fast Neutron Activation I -Fission Product N Naturally Isotope p -photon R@Eict;on C -charged Particle Reaction M -NO MDA calculation R -Coincidence Corrected G -Gamma Ray X -X-Ray P -Positron Decay S -single-Escape 0 Double E!;Cape K Key Line A -Not in Average C -Coincidence Peak H -Halfl ife limit exceeded ***** SUM MAR Y oF NUCLI DES IN SAMPLE Time of Count Time Corrected uncertainty 2 sigma Nuclide Activity Activity counting Total iv1DA pci/g pci/g pci/g pci/g k K-40 1. 0629E+01 1.0629E+01 2.1)85E+00 2.1854E+00 8.076E-01 co-60 B< 8.2320E-02 Ag-108mB<3.6585E-02 cs-137 B< 5.5033E-02 EU-152 B< 1. 1230E-01 EU-154 B< 8.3781E-02 PB-212 & 3.6481E-01 3.6481E-01 1.1939E-01 1.1977E-01 1.117E-01 PB-214 & 7.1731E-01 7.1731E-0l
: 1. 6907E-01 1.7064E-01 7.342E-02 BI-212 B< 8.4396E-01 8.4396E-01 o ORTEC g v -i (1087) npp32 G53w3.05 15-APR-2008 15:54:45 Page PBRF spectrum name:
..81-214 4.8948E-01 4.8948E-0l
: 1. 5881E-0l 1.5979E-01 9.493E-02 RA-226 B< 1.6841E+00
: 1. 6841E+00 TH-234 B< 1. 4415E+00 1. 4415E+00 U-235 B< 4.6609E-01 4.6609E-01 AM-241 B< 1.6849E-01
: 1. 6849E-Ol # -All peaks for activity calculation had bad shape .. -Activity omitted from & -Activity omitted from total and all peaks had bad < -MDA value A -Activity printed, but activity < B -Activity < MDA and failed C -Area < Critical F -Failed fraction or key line H -Halflife limit
_____________________________
SUM MAR Y Total Activity ( 38.7 to 2037.2 keV) O.OOOOOOOE+OO Total Decayed Activity ( 38.7 to 2037.2 kev) O.OOOOOOOE+OO Page 4 
* * *1  P808-01284 Analyzed Reviewed Laboratory:
PBRF page 5 
*
* 1 ORTEC g v -(1087) npp32 G53W3.05 21-APR-2008 17:12:45 Page PBRF Spectrum name: PB08-01335.An1 sample description PB08-01335; SR99-81; PPH RM 8 HD8-1; 4/21/08 spectrum Filename:
z:\Lab\SAMPLE 08\PB08-01335.An1 information Start time: 21-Apr-2008 16:00:21 Live time: 300 Real time: 301 Dead time: 0.27 % Detector ID: 3 Detector system [] #3 DETECTOR (#131) Calibration Filename:
2S0ml #73678-773 (MC131) Sept07 Energy Calibration Created: Zero offset: 05-Sep-2007 16:56:38 0.565 kev Gain: Quadratic:
0.247 kev/channel 5.022E-08 kev/channel A 2 Efficiency Calibration Created: Type: uncertainty:
Coefficients:
05-sep-2007 17:17:39 polynomial
: 1. 204 % -0.304311 -4.249899 0.669559 -0.094002 0.005803 -0.000133 Library Files Main analysis library: Library Match Width: Peak stripping:
plumbrk 01.lib 0.500 Library based Analysis parameters Analysis engine: Start channel: Stop channel: Peak rejection level: Peak search sensitivity:
sample Size: Activity scaling factor: npp32 G53w3.05 155 ( 38.83kev ) 8144 ( 2014.22kev) 25.000% 3 4.6620E+02 1.0000E+06/( 1.0000E+00*
2.1450E+03 4.6620E+02)
Detection limit method: Nureg 4.16 Random error: 1.0000000E+00 systematic error: Fraction Limit: 1.0000000E+00 0.000% Background width: best method (based on spectrum).
o Page 1 
*
* PBRF ORTEC g v -i (l087) npp32 PB08-01335 G53w3.05 21-APR-2008 17:12:45 Spectrum name: PB08-01335.An1 Page 2 Half lives decay limit: Activity range factor: Min. step backg. energy 12.000 2.000 0.000 Corrections Status Comments Decay correct to date: YES 17-Apr-2008 08:34:00 Decay during acquisition:
NO Decay during collection:
NO True coincidence correction:
NO peaked background correction:
NO Absorption (Internal):
NO Geometry correction:
NO Random summing: NO Energy Normalized diff: SUM MARY 0F PEA K SIN RANGE peak Area Uncert FWHM Corrctn Nuclide Brnch. Act. Nuc Energy Factor Energy Ratio pci/g 238.67 85. 14.31 1. 03 6.196E-02 238.63 43.300 6.123E-01 PB212 352.11 57. 14.81 1. 37 4.555E-02 351.93 37.600 6.394E-Ol PB214 609.28 56. 13.36 1. 34 2.830E-02 609.31 46.100 8.295E-01 81214 1460.99 138. 8.51 1. 45 1. 387E-02 1460.83 11.000 1. 748E+01 K40 NO unknown peaks passed sensitivity testo This section based on library: plumbrk 01.lib **************
IDE N T I FIE D PEA K SUM MAR Y **************
Nuclide Peak Centroid Background Net Area Intensity Uncert FWHM channel Energy Counts Counts Cts/sec 2 sigma % keY AM-241 0.00 59.54 o. O. 0.000 0.00 0.000 TH-234 0.00 63.29 O. O. 0.000 0.00 0.000 TH-234 0.00 92.59 O. O. 0.000 0.00 0.000 EU-152 0.00 121. 78 O. O. 0.000 0.00 0.000 EU-154 0.00 123.07 O. O. 0.000 0.00 0.000 u-235 0.00 143.76 O. O. 0.000 0.00 0.000 u-235 0.00 185.71 O. o. 0.000 0.00 0.000 PB-212 964.39 238.67 14. 85. 0.283 28.62 1. 027 EU-152 0.00 344.28 O. O. 0.000 0.00 0.000 PB-214 1423.71 352.11 4. 57. 0.189 29.61 1.372 Ag-108m 0.00 433.94 O. O. 0.000 0.00 0.000 BI-214 2464.73 609.28 O. 56. 0.187 26.73 1. 338 Ag-108m 0.00 614.28 O. O. 0.000 0.00 0.000 cs-137 0.00 661. 66 O. O. 0.000 0.00 0.000 Ag-108m 0.00 722.91 O. O. 0.000 0.00 0.000 o ORTEC gv -i (1087) npp32 G53w3.05 21-APR-2008 17:12:45 Page 3 PBRF spectrum name: PB08-01335.An1 Nuclide Channel Energy Background Net area Cnts/sec Uncert EU-154 0.00 723.30 O. O. 0.000 0.00 O. 0.000 0.00 0.000 BI-212 0.00 727.33 O. EU-154 0.00 1004.72 O. O. 0.000 0.00 0.000 page 2 
*
* PB08-01335 co-60 0.00 1173.24 O. O. 0.000 0.00 0.000 EU-154 0.00 1274.44 O. O. 0.000 0.00 0.000 co-60 0.00 1332.50 O. O. 0.000 0.00 0.000 EU-152 0.00 1408.01 O. O. 0.000 0.00 0.000 K-40 5909.21 1460.99 O. 138. 0.460 17.03 1. 454s s -Peak fails shape D -Peak area A Derived peak 1:1:1d:," SU M MAR Y o F LIB RA RY PEA K USAGE -Nuclide
-------------
peak Name ActlVlty Energy Activity code MDA value pCi/g keV pCi/g pci/g COMMENTS K-40 N 1. 7484E+01 1460.83 1.748E+01 I( 9.338E-01 8.51GK PB-212 6.1225E-01 238.63 6.123E-01 ( 1.451E-01 14.31 G K PB-214 6.3938E-01 351.93 6.394E-01 ( 1.400E-01 14.81 G K 81-214 8.2953E-01 609.31 8.295E-Ol ( 1.092E-01 13.36 GK 1764.49 O.OOOE+OO
% 7.813E-01 30.15 G 1120.29
% 5.490E-01 40.82 G -This peak used ln the nuclide activity average. peak is too wide, but only one peak in
-peak is part of a multiplet and this area negative during ? -Peak is too @ -Peak is too wide at FW25M, but ok at % -Peak fails sensitivity $ -peak identified, but first peak of this failed one or more qualification tests. -Peak activity higher than counting uncertainty -Peak activity lower than counting uncertainty -Peak outside analysis energy & -calculated peak centroid is not close enough to the library energy centroid for positive identlfication. P -peakbackground subtraction o ORTEC g v -i (1087) npp32 G53w3.05 21-APR-2008 17:12:45 page 4 PBRF spectrum name: PB08-01335.Anl } -Peak is too close to another for the to be found Nuclide Codes: peak T Thermal Neutron Activation G -Gamma F Fast Neutron Activation X -I Fission Product P -Positron N Naturally occurring Isotope S -
P photon Reaction o -
C charged particle Reaction K -Key M No MDA Calculation A -Not in R Coincidence C -Coincidence Peak page 3 
.' H -Halflife limit
* exceeded PB08-01335
* ..J * .J * .J...... .J. Nuclide S U M M A R Y Time of Count Activity pci/g 0 F N U C L I Time Correc'ted Activity pci/g 0 E S T N.L uncertainty Counting pci/g S A M P L 2 Sigma Total pci/g E .J * .J * .J* .J* .J. MDA K-40 & 1. 7484E+01 1. 7484E+01 2.9767E+00 3.0205E+00 9.338E-01 co-60 B< 9.5316E-02 9.5464E-02 Ag-108mB<
4.1674E-02 4.1674E-02 cs-137 B< 6.3411E-02
: 6. 3428E-02 EU-152 B< 1. 2712E-01 1. 2720E-01 EU-154 B< 1. 4340E-01 1.4353E-01
..PB-212 6.1225E-01 6.1225E-01 1.7526E-01 1.7597E-01 1.451E-01 J.PB-214 6.3937E-01 6.3938E-01
: 1. 8933E-01 1.9025E-01 1.400E-01 81-212 B< 1. 1157E+00 1.1157E+00 J.81-214 8.2952E-01 8.2953E-01 2.2170E-01 2.2345E-01 1.092E-01 RA-226 B< 1.5096E+00 1.5096E+00 TH-234 B< 1. 2364E+00 1. 2364E+00 u-235 B< 5.0761E-01 5.0761E-01 AM-241 B< 1.9806E-01 1.9806E-01 # -All peaks for activity calculation had bad .. Activity omitted from & -Activity omitted from total and all peaks had bad < -MDA value A -Actlvity printed, but actlvity < B -Activity < MDA and failed C -Area <-Critical F Failed fraction or key line H -Halflife limit
-----------------------------
SUM MAR Y Total Activity ( 38.8 to 2014.2 kev) O.OOOOOOOE+OO pci/g Total Decayed Activity ( 38.8 to 2014.2 kev) O.OOOOOOOE+OO pci/g Ana 1 y zed by: project APR 22 200B Reviewed by: supervisor R. Case Laboratory:
PBRF Page 4 
*
* ORTEC g v -1 (l087) npp32 G53w3.05 15-APR-2008 15:49:44 Page 1 PBRF Spectrum name: PB08-01280.Anl sample PB08-01280; SR99-54; PPH-RM8-HD8-2; spectrum Filename:
z:\Lab\SAMPLE 08\PB08-01280.Anl Acquisition Start time: 15-Apr-2008 Live time: Real time: Dead time: 0.53 Detector ID: Detector #2 DETECTOR [j COpy 250ml #73678-773 Energy Calibration created: 13-sep-2007 15:00:31 zero offset: 0.287 kev Gain: 0.251 kev/channel Quadratic:
2.324E-08 kev/channel A 2 Efficiency Calibration created: 13-sep-2007 15:22:08 Type: polynomial uncertai nty: 1. 626 % Coeffi ci ents: -0.256697
-4.334323 0.664302 -0.092291 0.005686 -0.000130 Library Main analysis library: plumbrk Library Match width: Peak st ri ppi ng: Library Analysis Analysis engine: npp32 Start channel: 155 ( 39.27kev Stop channel: 8144 (
Peak rejection level: Peak search sensitivity: sample size:
Activity scaling factor: 1.0000E+06/( 1.0000E+00*
Detection limit method: Nureg Random error:
systematic error:
Fraction Limit: Background width: best method (based on spectrum).
o page 1 
*
* PBRF ORTEC g v -i (1087) npp32 PB08-01280 G53w3.05 15-APR-2008 15:49:44 Spectrum name: PB08-01280.An1 Page 2 Half lives decay limit: Activity range factor: Min. step backg. energy 12.000 2.000 0.000 Corrections Status Comments Decay correct to date: Decay during acquisition:
Decay during collection:
True coincidence correction:
YES NO NO NO 14-Apr-2008 11:32:00 Peaked background correction:
Absorption (Internal):
Geometry correction:
Random summing: NO NO NO NO Energy calibration Normalized diff: 0.1987 Peak Energy SUM MAR Y 0 Area uncert F PEA K SIN RAN FWHM Corrctn Nuclide Factor Energy G E ***** Brnch. Act. Ratio pCi/g NUC 238.65 80. 13.07 1.17 5.760E-02 238.63 43.300 6.231E-01 PB212 351. 90 45. 17.43 1. 24 4.241E-02 351.93 37.600 5.522E-01 PB214 582.97 29. 22.90 0.60 2.764E-02 608.92 41. 15.62 1.13 2.665E-02 609.31 46.100 6.482E-01 BI214 1172.94 38. 16.22 0,82 1.604E-02 1173.24 99.974 4.606E-Ol c060 1332.15 48. 14.43 0.44 1. 459E-02 1332.50 99.986 6.394E-01 C060 1460.39 105. 9.76 1. 69 1. 362E-02 1460.83 11.000 1.361E+01 K40 ************ U N IDE N T I FIE D PEA K SUM MAR Y Peak Centroid Background Net Area Intensity Uncert FWHM Suspected Channel Energy counts Counts Cts/sec 2 sigma % kev Nuclide 2316.46 582.97 3. 29. 0.096 45.81 0.600 TL-208 s s -Peak fails shape D -peak area L -Peak written from unknown C -Area < critical This section based on library: plumbrk 01.lib D ORTECgv -1 (1087) npp32 G53w3.05 15-APR-2008 15:49:44 page PBRF Spectrum name: S U MMA RY *1:*'1:'1:"1:1:1:'1;*::1:'1:-1:-:.
* '1. 1.
* 1: *"* -/: '1: 1;1: * -/:
* I DEN T I F I ED P EA K peak Centroid Background Net Area Intensity uncert channel Energy Counts Counts Cts/sec 2 sigma % AM-241 0.00 59.54 O. O. 0.000 0.00 TH-234 0.00 63.29 O. O. 0.000 0.00 O. O. 0.000 0.00 0.000 TH-234 0.00 EU-152 0.00 121.78 O. O. 0.000 0.00 EU-154 0.00 123.07 O. O. 0.000 0.00 Page 2 
*
* PB08-01280 u-235 0.00 143.76 O. O. 0.000 0.00 0.000 u-235 0.00 185.71 O. O. 0.000 0.00 0.000 PB-212 947.76 238.65 8. 80. 0.267 26.14 1.173s EU-152 0.00 344.28 O. O. 0.000 0.00 0.000 PB-214 1397.98 351.90 4. 45. 0.151 34.86 1.238s Ag-108m 0.00 433.94 O. O. 0.000 0.00 0.000 B1 -214 2419.63 608.92 O. 41. 0.137 31. 23 1.132 Ag-108m 0.00 614.28 O. O. 0.000 0.00 0.000 c5-137 0.00 661.66 O. O. 0.000 0.00 0.000 Ag-108m 0.00 722.91 O. O. 0.000 0.00 0.000 EU-154 0.00 723.30 O. O. 0.000 0.00 0.000 BI-212 0.00 727.33 O. O. 0.000 0.00 0.000 EU-154 o.00 1004. 72 O. O. 0.000 0.00 0.000 co-60 4660.92 1172.94 O. 38. 0.127 32.44 0.818s EU-154 0.00 1274.44 O. O. 0.000 0.00 0.000 . co-60 5293.40 1332.15 O. 48. 0.160 28.87 0.441s/ Ell 152 o K-40 5802.82 1460.39 O. 105. 0.350 19.52 1.690 s -Peak fails shape tests. D -Peak area deconvoluted.
A Derived peak area.
A Derived peak area.
5 UM MAR Y o F LIB RARY PEA K USA GE -Nuclide -
~~~k~      5 U M MAR Y                     o F   LIB R A R Y PEA K USA G E
-------------
- Nuclide - Ave~a~e                          ------------- Peak -------------
Peak Name Code Actlvlty Energy Activity Code MDA value pCi/g kev pCi/g pci/g COMMENTS K-40 N 1. 3611E+01 1460.83 1.361E+01 ( 9.553E-01 9.76 G K co-60 F 6.3943E-01 1332.50 6.394E-D 9.818E-02 14.43 G K 1173.24 4.606E--8.933E-02 16.22 G K PB-212 N 6.2307E-01 238.63 6.231E-01  
Name     Code Actlvlty                       Energy   Activity Code MDA value pCi/g                         kev     pCi/g             pci/g           COMMENTS K-40       N   1. 3611E+01 1460.83 1.361E+01   (   9.553E-01     9.76 G K co-60       F   6.3943E-01 1332.50 6.394E-D 9.818E-02             14.43 G K 1173.24 4.606E-   -     8.933E-02   16.22 G K PB-212     N   6.2307E-01 238.63 6.231E-01 *(     1. 238E-01   13.07 G K o
*( 1. 238E-01 13.07 G K o ORTEC 9 v -i (1087) npp32 G53w3.05 15-APR-2008 15:49:44 page 4 PBRF Spectrum name: PB08-01280.An1 Nuclide Ave activity Energy Activity Code Peak MDA Comments PB-214 N 5.5216E-01 351.93 5.522E-01  
ORTEC 9 v - i (1087) npp32                   G53w3.05 15-APR-2008 15:49:44 page         4 PBRF                                               Spectrum name: PB08-01280.An1 Nuclide     Ave activity                   Energy   Activity   Code Peak MDA     Comments PB-214     N   5.5216E-01 351.93 5.522E-01 *(     1.417E-01   17.43 G K BI-214     N   6.4818E-01 609.31 6.482E-01?( 1.165E-01         15.62 G K 1764.49 O.OOOE+OO % 1.199E+00         127.48 G 1120.29 O.OOOE+OO % 7.998E-01         27.91 G
*( 1.417E-01 17.43 G K BI-214 N 6.4818E-01 609.31 6.482E-01?( 1.165E-01 15.62 G K 1764.49 O.OOOE+OO  
( - This peak used in the nuclide activity average.
% 1.199E+00 127.48 G 1120.29 O.OOOE+OO  
    - - Peak is too wide, but only one peak in library.
% 7.998E-01 27.91 G ( -This peak used in the nuclide activity average. --Peak is too wide, but only one peak in  
      - Peak is part of a multiplet and this area went negative during deconvolutipn.
-Peak is part of a multiplet and this area negative during ? -Peak is too @ -Peak is too wide at FW25M, but ok at % -Peak fails sensitivity $ -Peak identified, but first peak of this failed one or more qualification Page
    ? - Peak is too narrow.
* * ,. + -Peak higher than counting uncertainty peak actlvlty lower than counting uncertainty = -Peak outside analysis energy & -calculated peak centroid is not close enough to library energy centroid for P -peakbackground  
    @ - Peak is too wide at FW25M, but ok at FWHM.
} peak is too close to another for the to be found directly.
    % - Peak fails sensitivity test.
Nuclide Codes: Peak T -Thermal Neutron Activation G -Gamma F Fast Neutron Activation X I Fission Product P Positron N Naturally occurring Isotope S P photon Reaction D C charged Particle Reaction K Key NO MDe. calclllation  
    $ - Peak identified, but first peak of this nuclide failed one or more qualification tests.
: e. Not In R coincidence Corrected C -Coincidence H Halflife limit  
Page 3
* PB08-01280
    + - Peak act~vity higher than counting uncertainty range.
peak actlvlty lower than counting uncertainty range.
    = - Peak outside analysis energy range.
    & - calculated peak centroid is not close enough to the library energy centroid for positiveidentlfication.
P - peakbackground subtraction
    }   peak is too close to another for the activity to be found directly.
Nuclide Codes:                           Peak Codes:
T - Thermal Neutron Activation           G - Gamma Ray F   Fast Neutron Activation             X X-Ray I   Fission Product                     P     Positron Decay N Naturally occurring Isotope             S     single-Escape P   photon Reaction                     D Double-Escape C charged Particle Reaction               K Key Line
    ~    NO MDe. calclllation                 e. Not In ~verage R   coincidence Corrected               C - Coincidence Peak H   Halflife limit exceeded


==SUMMARY==
==SUMMARY==
o F NUCLI DES I N SAMPLE Time of Count Time Corrected uncertainty 2 sigma Nuclide Activity Activity counting Total MDA pci/g pci/g pci/g pCi/g ,r K-40 1.3611E+01  
o F   N U C L I DES         I N SAM P L E Time of Count   Time Corrected     uncertainty 2 sigma Nuclide       Activity         Activity           counting     Total         MDA pci/g           pci/g           pci/g         pCi/g K-40           1.3611E+01     1. 3611E+01     2.6565E+00     2.6918E+00 9.553E-01 6.3943E-Ol         8459E-Ol   1.8571E-01 9.814E-02
: 1. 3611E+01 2.6565E+00 2.6918E+00 9.553E-01 CO-60 6.3916E-Ol 6.3943E-Ol 1, 8459E-Ol 1.8571E-01 9.814E-02 Ag-108mB<
,r CO-60 Ag-108mB<
4.4844E-02 4.4844E-02 CS-137 B< 9.2305E-02 EU-152 B< 1. 2503E-01 1.
CS-137 B<
EU-154 B< 1.2256E-01 ORTEC g v -i (1087) npp32 G53w3.05 15-APR-2008 15:49:44 page 5 PBRF spectrum name: PB08-01280.An1 PB-212 & 6.2307E-01 6.2307E-01  
EU-152 B<
: 1. 6288E-01 1. 6367E-01 1. 238E-01 PB-214 & 5.5216E-01 5.5216E-01  
6.3916E-Ol 4.4844E-02 9.2305E-02
: 1. 9250E-01 1. 9330E-01 1. 417E-01 BI-212 B< 1. 0874E+00 1.0874E+00 BI-214 & 6.4818E-01 6.4818E-01 2.0246E-01 2.0380E-01 1.165E-01 RA-226 B< 2.0126E+00 2.0126E+00 TH-234 B< 1. 8427E+00 1. 8427E+00 u-235 B< 4.9901E-0l 4.9901E-01 AM-241 B< 2.1333E-01 2.1334E-Ol # -All peaks for activity calculation had bad shape.
: 1. 2503E-01 4.4844E-02 9.2312E-02
* Activity omitted from & -Activity omitted from total and all peaks had bad < -MOA value A -Activity printed, but activity < B -Activity < MDA and failed C -Area < critical F-fraction or key line H -Halflife limit
: 1. 2505E-0l 1,
_____________________________
EU-154 B<     1.2256E-01      1.2259E-01 ORTEC g v - i (1087) npp32     G53w3.05 15-APR-2008 15:49:44 page         5 PBRF                                 spectrum name: PB08-01280.An1 PB-212 &     6.2307E-01     6.2307E-01     1. 6288E-01   1. 6367E-01 1. 238E-01 PB-214 &     5.5216E-01     5.5216E-01     1. 9250E-01   1. 9330E-01 1. 417E-01 BI-212 B<     1. 0874E+00     1.0874E+00 BI-214 &     6.4818E-01     6.4818E-01     2.0246E-01     2.0380E-01 1.165E-01 RA-226 B<     2.0126E+00     2.0126E+00 TH-234 B<     1. 8427E+00     1. 8427E+00 u-235   B<     4.9901E-0l     4.9901E-01 AM-241 B<     2.1333E-01     2.1334E-Ol
SUM MAR Y Total Activity ( 39.3 to 2049.9 kev) 6.3915920E-Ol pci/g Total Decayed Activity ( 39.3 to 2049.9 kev) 6.3942903E-01 pci/g Analyzed by: missioning project Page 4
    # - All peaks for activity calculation had bad shape.
*
* Activity omitted from total
* Reviewed by: --fTl-r-<
    & - Activity omitted from total and all peaks had bad shape.
1 5 ". upervi sor R. Case Laboratory:
    < - MOA value printed.
PBRF page  
A - Activity printed, but activity < MOA.
*
B - Activity < MDA and failed test.
* 1 PB08-01l84 ORTEC 9 v 1 (1087) npp32 GS3w3. 03 APR 2008 13:37:56 Page PBRF Spectrum name: PB08-01184.An1 sample description PB08-01184; sR99-26; PPH RM 8; HD-8-3; 4/3/08 spectrum Filename:
C - Area < critical level.
z:\Lab\SAMPLE 08\PB08-01184.An1 Acquisition information Start time: Live time: Real time: Dead time: Detector 10: Detector system#1 DETECTOR (#129) Calibration Filename:
F - Fail~d fraction or key line test.
250ml #73678-773 (MC129) Energy Calibration Created: Zero offset: Gain: Quadratic:
H - Halflife limit exceeded
Efficiency calibration Created: Type: uncertainty:
_____________________________       SUM MAR Y ---------------------------
coefficients:
Total Activity (      39.3 to 2049.9 kev) 6.3915920E-Ol pci/g Total Decayed Activity (       39.3 to 2049.9 kev) 6.3942903E-01 pci/g Analyzed by:
Library Files Main analysis library: Library Match width: Peak stripping:
missioning project Page 4
Analysis parameters Analysis engine: Start channel: Stop channel: peak rejection level: Peak search sample Activity scaling Detection limit Random systematic Fraction Background 03-Apr-2008 0.64 % 1 ro COpy Jan08 09-Jan-2008 08:36:01 -0.051 kev 0.250 kev/channel
* PB08-01280 Reviewed by: --fTl-r-<--t,L-~I-.L--:::=-----=-          ~A'-!!..P-ll.. 1 5 2008
-8.299E-09 kev/channel A 2 09-Jan-2008 09:15:56 polynomial 1.663 % -0.338084
                  ". upervi sor Laboratory:  PBRF              R. Case page 5
-4.099654
* PB08-01l84 ORTEC 9 v     1 (1087) npp32 GS3w3. 03 APR 2008 13:37:56 Page   1 PBRF                               Spectrum name: PB08-01184.An1 sample description PB08-01184; sR99-26; PPH RM 8; HD-8-3; 4/3/08 spectrum Filename: z:\Lab\SAMPLE 08\PB08-01184.An1 Acquisition information Start time:                   03-Apr-2008 13:24:43 Live time:                 300 Real time:                 302 Dead time:                   0.64 %
-0.082467 0.004895 plumbrk 01.lib Library npp32 G53w3.05 155 ( 38.73kev)8144 ( 2037.21kev) 1.0000E+06/C 1.0000E+00*
Detector 10:                       1 Detector system ro COpy
4.2810E+02) 2.3359E+03 Nureg 4.16 1.0000000E+00 1.0000000E+00 0.000% best method (based on spectrum).
      #1 DETECTOR (#129)
Page 1 
Calibration Filename:
*
250ml #73678-773 (MC129) Jan08 Energy Calibration Created:               09-Jan-2008 08:36:01 Zero offset:          -0.051 kev Gain:                   0.250 kev/channel Quadratic:             -8.299E-09 kev/channel A2 Efficiency calibration Created:               09-Jan-2008 09:15:56 Type:                   polynomial uncertainty:           1. 663 %
* PBRF ORTEC g v -i (1087) npp32 PB08-01184 GS3w3.0S 03-APR-2008 13:37:56 Spectrum name: PB08-01184.An1 Page 2 Half lives decay limit: Activity range factor: Min. step backg. energy 12.000 2.000 0.000 Corrections Status Comments Decay correct to date: Decay during acquisition:
coefficients:         -0.338084 -4.099654    0.610757
Decay during collection:
                                    -0.082467    0.004895 -0.000109 Library Files Main analysis library:       plumbrk 01.lib Library Match width:         0.500 Peak stripping:               Library based Analysis parameters Analysis engine:             npp32    G53w3.05 Start channel:             155 (    38.73kev)
True coincidence correction:
Stop channel:             8144 ( 2037.21kev) peak rejection level:       25.000%
YES NO NO NO 26-Mar-2008 14:50:00 Peaked background correction:
Peak search sensitivity:      3 sample Size:                  4.2810E+02 Activity scaling factor:      1.0000E+06/C 1.0000E+00*    4.2810E+02) 2.3359E+03 Detection limit method:      Nureg 4.16 Random error:                 1.0000000E+00 systematic error:             1.0000000E+00 Fraction Limit:              0.000%
Absorption (Internal):
Background width:            best method (based on spectrum).
Geometry correction:
Page 1
Random summing: NO NO NO NO Energy Calibration Normalized diff: 0.1268 SUM MARY 0F PEA K SIN RANGE ***** peak Area uncert FWHM Corrctn Nuclide Brnch. Act. NUc Energy Factor Energy Ratio pci/g 77.23 63. 18.87 0.82 8.390E-02 238.43 70. 14.87 0.79 6.445E-02 238.63 43.300 5.307E-01 PB212 295.14 41. 18.65 0.65 5.498E-02 351. 90 54. 16.49 1. 06 4.765E-02 351.93 37.600 6.401E-01 PB214 609.30 59. 13 _02 1.07 3,006E-02 609.31 46.100 8.960E-Ol BI214 661.89 41. 15.62 1. 05 2.809E-02 661.66 85.100 3.611E-01 cs137 1173.31 59. 13.02 0.84 1. 773E-02 1173.24 99.974 7.026E-01 c060 1332.85 48. 14.43 0.33 1.598E-02 1332.50 99.986 6.339E-01 c060 1461.13 99. 10.05 1. 33 1. 481E-02 1460.83 11.000 1. 279E+01 K40 ************ U N IDE N T I FIE D PEA K SUM MAR Y ************
 
peak centroid Background Net Area Intensity Uncert FWHM suspected Channel Energy Counts Counts Cts/sec 2 sigma % kev Nuclide 308.84 77 .19 39. 63. 0.211 37.74 0.823 PB-214 D 1179.76 295.14 5 . 41. 0.137 37.31 0.646 PB-214 sM s -peak fails shape D -peak area L -Peak written from unknown C -Area < Critical M -peak is close to a library This section based on library: plumbrk 01.lib o ORTEC g v -1 (1087) npp32 G53w3.05 03-APR-2008 13:37:56 page PBRF spectrum name:
ORTEC g v - i (1087) npp32 PB08-01184 GS3w3.0S 03-APR-2008 13:37:56 Page            2 PBRF                                    Spectrum name: PB08-01184.An1 Half lives decay limit:            12.000 Activity range factor:              2.000 Min. step backg. energy            0.000 Corrections                                    Status            Comments Decay correct to date:                  YES        26-Mar-2008 14:50:00 Decay during acquisition:              NO Decay during collection:                NO True coincidence correction:            NO Peaked background correction: NO Absorption (Internal):                  NO Geometry correction:                    NO Random summing:                        NO Energy Calibration Normalized diff:              0.1268 SUM MAR Y 0 F              PEA K S I N          RAN G E      *****
**************
peak        Area    uncert FWHM          Corrctn      Nuclide Brnch.        Act. NUc Energy                                    Factor      Energy    Ratio    pci/g 77.23          63. 18.87      0.82    8.390E-02 238.43          70. 14.87      0.79    6.445E-02      238.63  43.300  5.307E-01 PB212 295.14          41. 18.65      0.65    5.498E-02 351. 90        54. 16.49      1. 06  4.765E-02      351.93  37.600  6.401E-01  PB214 609.30          59. 13 _02    1.07    3,006E-02     609.31  46.100  8.960E-Ol  BI214 661.89          41. 15.62      1. 05  2.809E-02     661.66  85.100  3.611E-01   cs137 1173.31          59. 13.02      0.84    1. 773E-02   1173.24  99.974  7.026E-01  c060 1332.85          48. 14.43      0.33    1.598E-02    1332.50  99.986  6.339E-01  c060 1461.13          99. 10.05      1. 33  1. 481E-02   1460.83  11.000  1. 279E+01 K40
IDE N T I FIE D PEA K SUM MAR Y **************
************ U N IDE N T I FIE D                    PEA K        SUM MAR Y ************
Nuclide Peak centroid Background Net Area Intensity uncert FWHM channel Energy Counts Counts Cts/sec 2 sigma % kev 0.00 0.000 AM-241 0.00 59.54 O. O. 0.000 page 2 
peak centroid Background Net Area              Intensity    Uncert    FWHM suspected Channel      Energy    Counts        Counts      Cts/sec    2 sigma % kev      Nuclide 308.84      77 .19          39.           63.     0.211    37.74    0.823 PB-214      D 1179.76    295.14            5.           41.      0.137    37.31    0.646 PB-214    sM s - peak  fails shape tests.
*
D - peak  area deconvoluted.
* TH-234 TH-234 EU-152 EU-154 u-235 u-235 RA-226 0.00 0.00 0.00 0.00 0.00 0.00 0.00 63.29 92.59 121. 78 123.07 143.76 185.71 186.21 O. O. o. O. O. O. O. O. O. o. O. O. O. O. 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.000 0.000 0.000 0.000 0.000 0.000 0.000 PB-212 953.10 238.43 11. 70. 0.234 29.75 0.786 EU-152 0.00 344.28 O. O. 0.000 0.00 0.000 PB-214 1406.63 351. 90 8. 54. 0.182 32.98 1.062 Ag-108m B1 214 0.00 2435.43 433.94 609.30 O. O. O. 59. 0.000 0.197 0.00 26.04 0.000 1. 070 Ag-108m CS-137 0.00 2645.64 614.28 661. 89 O. O. O. 41. 0.000 0.137 0.00 31. 23 0.000 1. 051s Ag-108m EU-154 0.00 0.00 722.91 723.30 O. O. O. O. 0.000 0.000 0.00 0.00 0.000 0.000 81-212 0.00 727.33 O. O. 0.000 0.00 0.000 EU-154 0.00 1004.72 O. O. 0.000 0.00 0.000 co-60 4690.00 1173.31 O. 59. 0.197 26.04 EU-154 0.00 1274.44 O. O. 0.000 0.00 0.000 co-60 5327.81 1332.85 O. 48. 0.160 28.87 o.334EU-152 0.00 1408.01 O. O. 0.000 0.00 0.000 K-40 5840.65 1461.13 O. 99. 0.330 20.10 1.334s B1-214 7052.00 1764.10 O. O. 0.000 0.00 O.OOOs s D Peak fails shape tests. Peak area deconvoluted.
L - Peak  written from unknown list.
C - Area  < Critical level.
M - peak  is close to a library peak.
This section based on library: plumbrk 01.lib o
ORTEC g v -    1 (1087) npp32      G53w3.05 03-APR-2008 13:37:56 page            3 PBRF                                      spectrum name: PB08-01184.An1
************** IDE N T I FIE D                  PEA K        SUM MAR Y **************
Nuclide    Peak     centroid    Background      Net Area   Intensity    uncert FWHM channel Energy        Counts          Counts      Cts/sec 2 sigma % kev AM-241        0.00      59.54              O.           O.     0.000      0.00    0.000 page 2
 
TH-234          0.00    63.29
* O.
PB08-01184 O.      0.000
* 0.00  0.000 TH-234          0.00    92.59            O.            O.       0.000     0.00  0.000 EU-152          0.00   121. 78          o.            o.       0.000    0.00    0.000 EU-154         0.00   123.07            O.           O.       0.000    0.00   0.000 u-235          0.00   143.76             O.           O.       0.000    0.00  0.000 u-235          0.00  185.71            O.           O.       0.000    0.00    0.000 RA-226          0.00  186.21            O.           O.       0.000   0.00    0.000 PB-212        953.10    238.43          11.          70.        0.234  29.75    0.786 EU-152          0.00    344.28            O.            O.      0.000   0.00   0.000 PB-214      1406.63    351. 90          8.          54.       0.182  32.98    1.062 Ag-108m        0.00   433.94            O.           O.       0.000   0.00    0.000 B1  214    2435.43  609.30            O.         59.       0.197  26.04    1. 070 Ag-108m        0.00   614.28             O.           O.       0.000   0.00   0.000 CS-137      2645.64  661. 89            O.         41.       0.137  31. 23  1. 051s Ag-108m         0.00   722.91            O.           O.       0.000   0.00   0.000 EU-154          0.00   723.30            O.           O.       0.000   0.00   0.000 81-212          0.00   727.33            O.           O.       0.000   0.00    0.000 EU-154          0.00 1004.72             O.           O.       0.000   0.00   0.000 co-60       4690.00 1173.31             O.         59.       0.197   26.04   0.838Y-EU-154         0.00 1274.44             O.           O.       0.000   0.00   0.000 co-60       5327.81 1332.85             O.         48.       0.160   28.87   o. 334 s.-----
EU-152         0.00 1408.01             O.           O.       0.000   0.00   0.000 K-40         5840.65 1461.13             O.         99.       0.330   20.10   1.334s B1-214       7052.00 1764.10             O.           O.       0.000   0.00   O.OOOs s     Peak fails shape tests.
D  Peak area deconvoluted.
A Derived peak area.
A Derived peak area.
SUM MAR Y o F LIB RAR Y PEA K USA GE -Nuclide -
  ~~~~~      SUM MAR Y         o F     LIB R A R Y       PEA K USA G E
-------------
- Nuclide - Ave~a~e            ------------- Peak -------------
Peak Name Code Actlvlty Energy Activity Code MOA value pci/g kev pci/g COMMENTS K-40 N 1.2790E+01 1460.83 1.279E+01 ( 9.521E-01 10.05 G K co-60 I 6.6824E-01 1332.50 6 339E>OG 9.733E-02 14.43 G K 0 1173.24 7.026E-0 ? 8.777E-02 13.02 G K 0 ORTEC 9 v -(l087) npp32 G53w3.05 03-APR-2008 13:37:56 Page 4 PBRF Spectrum name: PB08-01184.An1 Nuclide Ave activity Energy Activity Code peak MDA Comments cs-137 I 3.6111E-01 661. 66 3.611E-01 ( 6.491E-02 15.62 G K PB-212 N 5.3069E-01 238.63 5.307E-01 ( 1.353E-01 14.87 G K PB-214 N 6.4012E-01 351.93 6.401E-01 ( 1. 817E-01 16.49 G K BI-214 N 8.9598E-01 609.31 8.960E-01  
Name     Code Actlvlty           Energy   Activity Code MOA value pci/g           kev     pci/g             pci/g          COMMENTS K-40         N   1.2790E+01 1460.83 1.279E+01     (   9.521E-01   10.05 G K co-60       I   6.6824E-01 1332.50 6 339E>OG 9.733E-02 0                            14.43 G K 1173.24 7.026E-0 ?         8.777E-02   13.02 G K 0
?( 1. 119E-01 13.02 G K 1764.49 O.OOOE+OO  
ORTEC 9 v -     (l087) npp32     G53w3.05 03-APR-2008 13:37:56 Page           4 PBRF                                   Spectrum name: PB08-01184.An1 Nuclide     Ave activity     Energy     Activity   Code peak MDA     Comments cs-137       I   3.6111E-01 661. 66 3.611E-01   (   6.491E-02   15.62 G K PB-212       N   5.3069E-01 238.63 5.307E-01     (   1.353E-01   14.87 G K PB-214       N   6.4012E-01 351.93 6.401E-01     (   1. 817E-01 16.49 G K BI-214       N   8.9598E-01 609.31 8.960E-01 ?( 1. 119E-01       13.02 G K 1764.49 O.OOOE+OO ?         8.006E-01   0.00 G 1120.29 O.OOOE+OO % 5.583E-01           26.73 G
? 8.006E-01 0.00 G 1120.29 O.OOOE+OO  
( - This peak used in the nuclide activity average.
% 5.583E-01 26.73 G -This peak used in the nuclide activity Page
Page 3
*
* PB08-01l84 Peak is too wide, but only one peak in library.
* PB08-01l84 Peak is too wide, but only one peak in Peak lS part of a multlplet and thlS area negative during 7_ Peak is too @ Peak is too wide at FW25M, but ok at % Peak fails sensitivity $ -Peak identified, but first peak of this failed one or more qualification tests. +-Peak activity higher than counting uncertainty Peak activity lower than counting uncertainty Peak outside analysis energy & -calculated peak centroid is not close enough to the library energy centroid for positive P peakbackground  
Peak lS part of a multlplet and thlS area went negative during deconvolution.
} Peak is too close to another for the to be found directly.
7    _
Nuclide codes: Peak T -Thermal Neutron Activation G -Gamma -Fast Neutron Activation X -I -Fission product P -positron N -Naturally occurring Isotope S -
Peak is too narrow.
P -photon Reaction D -
            @       Peak is too wide at FW25M, but ok at FWHM.
C -charged Particle Reaction K -Key M -No MDA Calculation A -Not in R -Coincidence Corrected C -Coincidence H -Halfl i fe 1 i mi t o ORTEC 9 v -(1087) npp32 G53w3.05 03-APR-2008 13:37:56 Page 5 PBRF spectrum name: PB08-01184.An1  
            %       Peak fails sensitivity test.
'1: 7: '1: -!:-!: S UMMA R Y 0 F NU CLI DE S I N SAMP L E Time of Count T-ime Corrected Unce rtai nty 2 sigma Nuclide Activity Activity counting Tota 1 MOA pcijg pcijg pcijg pcijg 1;K-40 1.2790E+01  
            $ -     Peak identified, but first peak of this nuclide failed one or more qualification tests.
: 1. 2790E+01 2.5708E+OO 2.6036E+OO 9.521E-01 6.6633E-01 6.6824E-01  
            + -     Peak activity higher than counting uncertainty range.
: 1. 2989E-01 1. 3166E-01 9.705E-02 Ag-108' < 7.0402E-02 7.0404E-02 (5-137 3.6093E-Ol 3.6111E-01 1.1279E-01 1.1339E-01 6.488E-02 EU-152 B< 1. 3240E-01 1. 32 54E-01 EU-154 B< 1.2312E-01  
Peak activity lower than counting uncertainty range.
: 1. 2333E-01 _c PB-212 5.3069E-01 5.3069E-01 1.5787E-01  
Peak outside analysis energy range.
: 1. 5847E-01 1.353E-01 PB-214 " 6.4011E-01 6.4012E-01 2.1109E-01 2.1209E-01  
            &-       calculated peak centroid is not close enough to the library energy centroid for positive identlfication.
: 1. 817E-01 BI-212 B< 2.0762E+00 2.0762E+00 BI-214 & 8.9597E-01 8.9598E-0l 2.3329E-01 2.3554E-01 1.119E-01 RA-226 B< 2.4288E+00 2.4288E+00 TH-234 B< 1. 7419E+00 1.7419E+00 u-235 B< 3.8942E-01 3.8942E-01 AM-241 B< 1. 9544E-01 1. 9545E-01 # -All peaks for activity calculation had bad shape. Activity omitted from total & -Activity omitted from total and all peaks had bad shape. < -MDA value printed.A -Activity printed, but activity < MOA. B -Activity < MDA and failed test. Page 4
P       peakbackground subtraction
*
            }       Peak is too close to another for the activity to be found directly.
* C -Area < Critical F -Failed fraction or key line H Halfllfe Ilmlt  
Nuclide codes:                                   Peak Codes:
-----------------------------
T - Thermal Neutron Activation                   G - Gamma Ray
SUM MAR Y Total Activity ( 38.7 to 2037.2 kev) 1.0272623E+00 pci/g Total Decayed Activity ( 38.7 to 2037.2 kev) 1.0293509E+00 pci/g 2D08 project Reviewed by: Analyzed by: fi Laboratory:
                  - Fast Neutron Activation                   X - x-Ray I - Fission product                               P - positron Decay N - Naturally occurring Isotope                   S - single-Escape P - photon Reaction                               D - Double-Escape C - charged Particle Reaction                     K - Key Line M - No MDA Calculation                           A - Not in Average R - Coincidence Corrected                         C - Coincidence peak H - Halfl i fe 1 i mi t exceeded o
PBRF A.Case page 5
ORTEC 9 v -       (1087) npp32     G53w3.05 03-APR-2008 13:37:56 Page                 5 PBRF                                             spectrum name: PB08-01184.An1
*
    '1.-1:'1:"'1:*
* 1 PB08-0l214 ORTEC g v -1 (1087) npp32 G53w3.05 07-APR-2008 17:09:37 page PBRF spectrum name: PB08-01214.An1 sample description PB08-01214; SR99-32; PPH RM 8 FD8-3 / C08-1; 4/7/08 spectrum Filename:
S U MMA R Y       0 F     NUC L I D E S         I N S A MP L E     '1: 7: '1: -!:-!:
z:\Lab\sAMPLE 08\PB08-01214.An1 Acquisition information Start time: Live time: Real time: Dead time: Detector 1D: Detector system#1 DETECTOR (#129) Calibration Fi 1 ename : 250ml #73678-773 (MC129) Energy calibration created: zero offset: Gain: Quadratic:
Time of Count   T-ime Corrected Unce rtai nty 2 sigma Nuclide                 Activity         Activity           counting     Tota 1           MOA pcijg           pcijg           pcijg         pcijg K-40             1;      1.2790E+01       1. 2790E+01     2.5708E+OO   2.6036E+OO 9.521E-01
Efficiency Calibration created: Type: uncertainty:
  ~CO-60~
Coefficients:
~'\  Ag-108' <
Library Files Main analysis library: Library Match Width: peak stripping:
6.6633E-01 7.0402E-02 6.6824E-01 7.0404E-02
Analysis parameters Analysis engine: Start channel: Stop channel: peak rejection level: peak search sensitivity:
: 1. 2989E-01   1. 3166E-01 9.705E-02 J    (5-137                    3.6093E-Ol       3.6111E-01     1.1279E-01   1.1339E-01 6.488E-02 EU-152           B<       1. 3240E-01     1. 32 54E-01 EU-154           B<
sample size: Activity scaling factor: Detection limit method: Random error: systematic Fraction Limit: Background width: o 07-Apr-2008 0.63 % 1 ro COpy JanOS 09-Jan-2008 08:36:01 -0.051 kev 0.250 kev/channel
_c 1.2312E-01       1. 2333E-01 PB-212                   5.3069E-01       5.3069E-01     1.5787E-01   1. 5847E-01 1.353E-01 PB-214           "       6.4011E-01       6.4012E-01     2.1109E-01   2.1209E-01 1. 817E-01 BI-212           B<       2.0762E+00       2.0762E+00 BI-214           &       8.9597E-01       8.9598E-0l     2.3329E-01   2.3554E-01 1.119E-01 RA-226           B<       2.4288E+00       2.4288E+00 TH-234           B<       1. 7419E+00     1.7419E+00 u-235           B<       3.8942E-01       3.8942E-01 AM-241           B<       1. 9544E-01     1. 9545E-01
-8.299E-09 kev/channel A 2 09-Jan-200809:15:56 polynomial 1.663 % -0.338084
          # - All peaks for activity calculation had bad shape.
-4.099654
Activity omitted from total
-0.082467 0.004895 plumbrk 01.1ib Library npp32 G53w3.05 155 ( 38.73kev)8144 ( 2037.21kev) 1.0000E+06/( 1.0000E+00*
          & - Activity omitted from total and all peaks had bad shape.
4.5040E+02) 2.220ZE+03 Nureg 4.16 1.0000000E+00 1.0000000E+00 0.000% best method (based on spectrum).
            < - MDA value printed.
page 1 
A - Activity printed, but activity < MOA.
*
B - Activity < MDA and failed test.
* PB08-01214 ORTEC g v -i (1087) npp32 G53w3.05 07-APR-2008 17:09:37 Page 2 PBRF Spectrum name: PB08-01214.An1 Half lives decay limit: Activity range factor: Min. step backg. energy Corrections Status Comments Decay correct to date: YES 31-Mar-2008 13:30:00 Decay during acquisition: Decay during collection: True coincidence correction: Peaked background correction: Absorption (Internal): Geometry correction: Random summing: Energy Normalized diff: SUM MAR Y 0 F PEA K SIN RAN GE ***** Peak Area Uncert FWHM Corrctn Nuclide Brnch. Act. Nuc Energy Factor Energy Ratio pci/g 77.22 43. 24.71 0.95 8.390E-02 238.68 68. 20.18 0.86 6.440E-02 238.63 43.300 4.865E-01 PB212 295.18 35. 24.42 0.47 5.498E-02 351.98 74. 15.31 0.73 4.765E-02 351.93 37.600 8.317E-01 PB214 609.42 53. 14.76 1. 46 3.006E-02 609.31 46.100 7.602E-01 BI214 1120.10 22. 21. 32 0.75 1. 840E-02 1120.29 15.100 1.584E+00 BI214 1461. 37 134. 8.64 1. 48 1. 481E-02 1460.83 11.000 1.645E+01 K40 .'* ..! * ..J * .J-.J* .J .J* .J ..J * ..J.",," ,." "" ..************ U N IDE N T I FIE D PEA K SUM MAR Y Peak Centroid Background Net Area Intensity Uncert FWHM suspected Channel Energy Counts Counts Cts/sec 2 sigma % kev Nuclide 308.83 77.22 29. 43. 0.142 49.41 0.947 PB-214 sM 1179.92 295.18 11. 35. 0.118 48.84 0.473 PB-214 sM s -peak fails shape o -peak area L -peak written from unknown C -Area < critical M -Peak is close to a library This section based on library: plumbrk 01.lib o ORTEC g v -1 (1087) npp32 G53w3.05 07-APR-2008 17:09:37 Page PBRF spectrum name:  *"1:  7; ******** I D ENTI F I E 0 P E AK S UMM A R Y "1:*** * **1:*1.***
Page 4
* Nuclide peak centroid Background Net Area Intensity uncert . FWHM Channel Energy Counts Counts Cts/sec 2 sigma % kev O. O. 0.000 0.00 0.000 AM-241 0.00 TH-234 0.00 63.29 O. O. 0.000 0.00 TH-234 0.00 92.59 O. O. 0.000 0.00 Page 
 
*
C - Area < Critical level.
* EU-152 0.00 121.78 O. O. 0.000 0.00 0.000 EU-154 0.00 123.07 O. O. 0.000 0.00 0.000 u-235 0.00 143.76 O. O. 0.000 0.00 0.000 U-235 0.00 185.71 O. O. 0.000 0.00 0.000 RA-226 0.00 186.21 O. O. 0.000 0.00 0.000 PB-212 954.09 238.68 31. 68. 0.226 40.35 0.859 EU-152 0.00 344.28 O. O. 0.000 0.00 0.000 PB-214 1406.94 351. 98 12. 74. 0.248 30.62 0.731s Ag-108m 0.00 433.94 O. O. 0.000 0.00 0.000 B1-214 2435.91 609.42 2. 53. 0.176 29.52 1. 457 Ag-108m 0.00 614.28 O. O. 0.000 0.00 0.000 cS-137 0.00 661. 66 O. O. 0.000 0.00 0.000 Ag-108m 0.00 722 .91 O. O. 0.000 0.00 0.000 EU-154 0.00 723.30 O. O. 0.000 0.00 0.000 61-212 0.00 727.33 O. O. 0.000 0.00 0.000 EU-154 0.00 1004.72 O. O. 0.000 0.00 0.000 B1-214 4477 .27 1120.10 O. 22. 0.073 42.64 0.750s co-60 0.00 1173.24 O. O. 0.000 0.00 0.000 EU-154 0.00 1274.44 O. O. 0.000 0.00 0.000 co-60 0.00 1332.50 O. O. 0.000 0.00 0.000 EU-152 0.00 1408.01 O. O. 0.000 0.00 0.000 K-40 5841. 63 1461. 37 O. 134. 0.447 17.28 1. 480s s -Peak fails shape o -Peak area A Derived peak -----SUM MAR Y o F LIB RAR Y PEA K USA G E -Nuclide Ave\age -------------
PB08-01184 F - Failed fraction or key line test.
peak Name ACtlvlty Energy Activity Code MDA value pci/g kev pci/g pci/g COMMENTS K-40 N 1.6454E+01 1460.83 1. 645E+01 ( 9.050E-01 8.64 GK PB-212 4.8649E-01 238.63 4.865E-01 ( 2.060E-01 20.18 GK PB-214 8.3170E-01 351.93 8.317E-01 ( 2.067E-01 15.31 GK 0 ORTEC g v -i (1087) npp32 G53w3.05 07-APR-2008 17:09:37 Page 4 PBRF spectrum name: PB08-01214.Anl Nuclide activity Energy Activity Code Peak MDA Comments B1-214 7.6020E-01 609.31 7.602E-01 ( 1.419E-01 14.76 GK 1764.49 O.OOOE+OO  
H Halfllfe Ilmlt exceeded
% 7.610E-01 28.87 G 1120.29 1.584E+00  
-----------------------------   SUM MAR Y       ---------------------------
+ 5.306E-01  
Total Activity (   38.7 to 2037.2 kev) 1.0272623E+00 pci/g Total Decayed Activity (   38.7 to 2037.2 kev) 1.0293509E+00   pci/g Analyzed by:     fi P~                  project Reviewed by:
: 21. 32 G ( -This peak uied. in the nuclide activity average. Peak is too wide, but only one peak in  
2D08 Laboratory:   PBRF                         A.Case page 5
-Peak is part of a multiplet and this area negative during ? -Peak is too @ -Peak is too wide at FW25M, but ok at % -Peak fails sensitivity $ -peak identified, but first peak of this failed one or more qualification page
* PB08-0l214 ORTEC g v -   1 (1087) npp32 G53w3.05 07-APR-2008 17:09:37 page     1 PBRF                               spectrum name: PB08-01214.An1 sample description PB08-01214; SR99-32; PPH RM 8 FD8-3 / C08-1; 4/7/08 spectrum Filename: z:\Lab\sAMPLE 08\PB08-01214.An1 Acquisition information Start time:                   07-Apr-2008 17:00:36 Live time:                 300 Real time:                 302 Dead time:                   0.63 %
* * + -peak act:v:ty higher than uncertainty Peak actlvlty lower than countlng uncertainty -Peak outside analysis energy & -calculated peak centroid is not close enough to library energy centroid for positive P -peakbackground  
Detector 1D:                       1 Detector system
} Peak is too close to another for the to be found directly.
      #1 DETECTOR (#129)
Nuclide Codes: Peak T -Thermal Neutron Activation G -Gamma F -Fast Neutron Activation X -I -Fission Product P -Positron N -Naturally occurring Isotope S -
Calibration Fi 1ename :
P -photon Reaction D -
250ml #73678-773 (MC129) JanOS ro COpy Energy calibration created:               09-Jan-2008 08:36:01 zero offset:          -0.051 kev Gain:                   0.250 kev/channel Quadratic:             -8.299E-09 kev/channel A2 Efficiency Calibration created:               09-Jan-200809:15:56 Type:                   polynomial uncertainty:           1. 663 %
C -Charged Particle Reaction K -Key M -NO MDA calculation A -Not in R -Coincidence Corrected C -Coincidence H -Halflife limit "1:"!: *-1:* 1:* '1: S U MM A R y 0 F N U C LID ES IN SA tv1 PLE Time of Count Time Corrected uncertainty 2 Sigma Nuclide Activity Activity Counting Total MDA pCi/g pci/g pci/g pci/g K-40 .. 1. 6454E+01 1.6454E+01 2.8428E+00 2.8917E+OO 9.050E-01 co-60 B< 9.2245E-02 9.2482E-02 Ag-108mB<4.0995E-02 4.0996E-02 cs-137 B< 6.1667E-02 6.1695E-02 EU-152 B< 1. 3572E-01 1. 3586E-01 EU-154 B< 1.1052E-01 1.1070E-01 PB-212 4.8649E-01 4.8649E-0l 1.9631E-01 1.9671E-Ol 2.060E-01 PB-214 8.3169E-01 8.3170E-01 2.5465E-01 2.5606E-Ol 2.067E-01.c BI-212 B< 9.7242E-01 9.7242 E-Ol o ORTEC 9 v -i (1087) npp32 G53w3.05 07-APR-2008 17:09:37 page PBRF Spectrum name: BI-214 7.6019E-01 7.6020E-01 2.2444E-Ol 2.2612E-Ol  
Coefficients:         -0.338084 -4.099654    0.610757
: 1. 419E-Ol RA-226 B< 1.8209E+00 1.8209E+00 TH-234 B< 1. 4530E+00 1.4530E+00 u-235 B< 3.1325E-Ol 3.1325E-Ol AM-241 B< 1. 8638E-01 1.8638E-01 # -All peaks for activity calculation had bad shape.* Activity omitted from &-Activity omitted from total and all peaks had bad < -MDA value A -Activity printed, but activity < B -Activity < MDA and failed C -Area < Critical F -Failed fraction or key line H -Halflife limit
                                      -0.082467    0.004895 -0.000109 Library Files Main analysis library:       plumbrk 01.1ib Library Match Width:         0.500 peak stripping:               Library based Analysis parameters Analysis engine:             npp32    G53w3.05 Start channel:             155 (    38.73kev)
_____________________________
Stop channel:             8144 ( 2037.21kev) peak rejection level:       25.000%
SUM MAR Y Total Activity ( 38.7 to 2037.2 keY) O.OOOOOOOE+OO Total Decayed Activity ( 38.7 to 2037.2 keY) O.OOOOOOOE+OO Analyzed by: ecommissioning project page 4
peak search sensitivity:     3 sample size:                 4.5040E+02 Activity scaling factor:     1.0000E+06/( 1.0000E+00*    4.5040E+02) 2.220ZE+03 Detection limit method:       Nureg 4.16 Random error:                 1.0000000E+00 systematic error~            1.0000000E+00 Fraction Limit:               0.000%
* * "
Background width:            best method (based on spectrum).
Reviewed by:
o page 1
--:;;;' ----.nJAeR.J) 8 200a Laboratory:
 
PBRF A. Case page 5
PBRF ORTEC g v - i (1087) npp32
*
* PB08-01214 G53w3.05 07-APR-2008 17:09:37 Page                                2 Spectrum name: PB08-01214.An1 Half lives decay limit:              12.000 Activity range factor:                2.000 Min. step backg. energy                0.000 Corrections                                                Status            Comments Decay correct to date:                    YES        31-Mar-2008 13:30:00 Decay during acquisition:                  NO Decay during collection:                  NO True coincidence correction:              NO Peaked background correction: NO Absorption (Internal):                    NO Geometry correction:                      NO Random summing:                            NO Energy Calibration Normalized diff:            0.1090 SUM MAR Y            0 F      PEA K S I N          RAN G E      *****
* ATTACHMENT 1
Peak                    Area    Uncert FWHM          Corrctn      Nuclide Brnch.        Act.                       Nuc Energy                                                Factor      Energy    Ratio    pci/g 77.22                  43. 24.71      0.95    8.390E-02 238.68                    68. 20.18      0.86    6.440E-02      238.63  43.300  4.865E-01 PB212 295.18                    35. 24.42      0.47    5.498E-02 351.98                    74. 15.31     0.73    4.765E-02      351.93  37.600  8.317E-01                      PB214 609.42                    53. 14.76      1. 46  3.006E-02      609.31  46.100  7.602E-01                      BI214 1120.10                      22. 21. 32    0.75    1. 840E-02   1120.29  15.100  1.584E+00                      BI214 1461. 37                    134. 8.64      1. 48  1. 481E-02    1460.83  11.000  1.645E+01                      K40
-------------DQA Check Sheet Design # EP PPH-109 I Revision # Original I I Survey Unit # EP Preliminary Data Answers to the following questions should be fully documented in the Survey Yes No N/A Release Record Have surveys been performed in accordance with survey instructions in the Survey Design? X _. Is the instrumentation MDC for structure static measurements below the DCGL w for Class 1 and 2 X survey units, or below 05 DCGL w for Class 3 survey 3 Is the instrumentation MDC for embedded/buried piping static measurements below the DCGL w X Was the instrumentation MDC for structure scan measurements, soil scan measurements, embedded/buried piping scan measurements below the DCGL w. or, if not, was the need for X static measurements or soil samples addressed in the survey design? Was the instrumentation MDC for volumetric measurements and smear analysis < 10% DCGL w ? X Were the MDCs and assumptions used to develop them appropriate for the instruments and techniques X used to perform the survey? Were the survey methods used to collect data proper for the types of radiation involved and for the X media being 8 Were "Special Methods" for data collection properly applied for the survey unit under X 9 Is the data set comprised of qualified measurement results collected in accordance with the X design, which accurately reflects the radiological status of the Graphical Data 1 Has a posting plot been X XHas a histogram (or other frequency plot) been created? XHave other graphical data tools been created to assist in analyzing the data? Data Analysis XAre all sample measurements below the DCGL w (Class 1 & 2), or 05 DCGL w (Class 3)? XIs the mean of the sample data < DCGL w? If elevated areas have been identified by scans and/or sampling, is the average activity in each X elevated area < DCGLEMC (Class 1), < DCGL w (Class 2), or <0.5 DCGL w (Class 3)? XIs the result of the Elevated Measurements Test < 1.0? 5 Is the result of the statistical test (5+ for Sign Test or W r for WRS Test) ::: the critical X -Comments:
************ U N IDE N T I FIE D                                PEA K        SUM MAR Y      .'* ..! * ..J * .J-.J * .J
See Section 5 of this Survey Unit Release Record FSS/Characterization Engineer (prinUsign)
                                                                                                                          .J * .J
Date 1.5)?/tJJ l<...) l' "I':::'&L I , /I 5/b4r Date['"I. Casl ,/ t..FSS/ Characterization Manager (prinUsign)  v Fonn CS-09/2 Rev 0 Page 1 of 1 
                                                                                                                                    ..J * ..J.
*
Peak Centroid Background Net Area                        Intensity    Uncert    FWHM suspected Channel                Energy      Counts        Counts      Cts/sec    2 sigma % kev      Nuclide 308.83                77.22           29.           43.     0.142    49.41    0.947 PB-214                            sM 1179.92                295.18            11.           35.     0.118    48.84    0.473 PB-214                            sM s -        peak      fails shape tests; o -        peak      area deconvoluted.
* SECTION ATTACHMENT 1}}
L -        peak      written from unknown list.
C -      Area      < critical level.
M-        Peak      is close to a library peak.
This section based on library: plumbrk 01.lib o
ORTEC g v -          1 (1087) npp32      G53w3.05 07-APR-2008 17:09:37 Page                                3 PBRF                                                  spectrum name: PB08-01214.An1
~: *"1: 7:~: 7; * * * * * * *
* I D E N T I F I E 0        P EA K      S U M M A R Y "1:*** * ** 1:*1.***
* Nuclide peak                      centroid Background Net Area             Intensity     uncert . FWHM Channel Energy         Counts           Counts     Cts/sec 2 sigma % kev AM-241                      0.00    59.54              O.           O.     0.000      0.00                0.000 TH-234                      0.00    63.29              O.           O.     0.000      0.00                0.000 TH-234                      0.00    92.59              O.            O.      0.000      0.00                0.000 Page 2
 
EU-152 EU-154 0.00 0.00 121.78 123.07
* O.
PB08-01214 O.     0.000
* 0.00  0.000 O.            O.      0.000    0.00   0.000 u-235        0.00   143.76            O.           O.     0.000     0.00   0.000 U-235        0.00   185.71          O.             O.     0.000     0.00   0.000 RA-226        0.00   186.21          O.             O.     0.000     0.00   0.000 PB-212      954.09  238.68          31.           68.       0.226    40.35    0.859 EU-152        0.00   344.28          O.             O.     0.000     0.00   0.000 PB-214    1406.94  351. 98        12.           74.       0.248    30.62    0.731s Ag-108m      0.00   433.94          O.             O.     0.000     0.00   0.000 B1-214    2435.91  609.42          2.           53.       0.176    29.52    1. 457 Ag-108m      0.00   614.28           O.             O.     0.000     0.00   0.000 cS-137        0.00  661. 66          O.             O.     0.000      0.00  0.000 Ag-108m       0.00   722 .91          O.             O.     0.000     0.00   0.000 EU-154        0.00  723.30          O.             O.     0.000      0.00  0.000 61-212        0.00   727.33          O.             O.     0.000     0.00   0.000 EU-154        0.00 1004.72          O.             O.     0.000     0.00   0.000 B1-214    4477 . 27 1120.10          O.           22.       0.073    42.64    0.750s co-60        0.00  1173.24          O.            O.      0.000      0.00  0.000 EU-154       0.00 1274.44          O.             O.     0.000     0.00   0.000 co-60        0.00 1332.50          O.             O.     0.000     0.00   0.000 EU-152        0.00 1408.01          O.             O.     0.000     0.00   0.000 K-40      5841. 63 1461. 37          O.         134.       0.447    17.28    1. 480s s - Peak fails shape tests.
o - Peak area deconvoluted.
A    Derived peak area.
  -----    SUM MAR Y        o F    LIB R A R Y        PEA K USA G E
- Nuclide - Ave\age          ------------- peak -------------
Name     Code ACtlvlty         Energy   Activity Code MDA value pci/g           kev     pci/g             pci/g           COMMENTS K-40       N   1.6454E+01 1460.83 1. 645E+01   (   9.050E-01   8.64 G K PB-212     N    4.8649E-01 238.63 4.865E-01     (   2.060E-01   20.18 G K PB-214     N    8.3170E-01 351.93 8.317E-01     (   2.067E-01   15.31 G K 0
ORTEC g v - i (1087) npp32     G53w3.05 07-APR-2008 17:09:37 Page           4 PBRF                               spectrum name: PB08-01214.Anl Nuclide   Ave activity     Energy     Activity   Code Peak MDA     Comments B1-214     N    7.6020E-01 609.31 7.602E-01 ( 1.419E-01         14.76 G  K 1764.49 O.OOOE+OO % 7.610E-01         28.87 G 1120.29 1.584E+00 +       5.306E-01   21. 32 G
( - This peak uied. in the nuclide activity average.
Peak is too wide, but only one peak in library.
      - Peak is part of a multiplet and this area went negative during deconvolution.
    ? - Peak is too narrow.
    @ - Peak is too wide at FW25M, but ok at FWHM.
    % - Peak fails sensitivity test.
    $ - peak identified, but first peak of this nuclide failed one or more qualification tests.
page 3
* PB08-01214
        + - peak act:v:ty higher than coun~ing uncertainty range.
Peak actlvlty lower than countlng uncertainty range.
            - Peak outside analysis energy range.
        & - calculated peak centroid is not close enough to the library energy centroid for positive identlfication.
P - peakbackground subtraction
        }     Peak is too close to another for the activity to be found directly.
Nuclide Codes:                               Peak Codes:
T - Thermal Neutron Activation               G - Gamma Ray F - Fast Neutron Activation                 X - X-Ray I - Fission Product                         P - Positron Decay N - Naturally occurring Isotope             S - single-Escape P - photon Reaction                         D - Double-Escape C - Charged Particle Reaction               K - Key Line M - NO MDA calculation                       A - Not in Average R - Coincidence Corrected                   C - Coincidence Peak H - Halflife limit exceeded "1:"!: *-1:*       S U MMA R y     0 F   NU C L I DE S      I N S A tv1 P L E    1:* '1: -1:""1.
Time of Count  Time Corrected uncertainty 2 Sigma Nuclide               Activity       Activity         Counting     Total           MDA pCi/g         pci/g         pci/g           pci/g K-40           ..     1. 6454E+01   1.6454E+01     2.8428E+00     2.8917E+OO 9.050E-01 co-60 B<               9.2245E-02     9.2482E-02 Ag-108mB<               4.0995E-02     4.0996E-02 cs-137 B<               6.1667E-02     6.1695E-02 EU-152 B<               1. 3572E-01   1. 3586E-01 EU-154 B<               1.1052E-01     1.1070E-01 PB-212 ~,              4.8649E-01     4.8649E-0l     1.9631E-01     1.9671E-Ol 2.060E-01 PB-214         .c      8.3169E-01     8.3170E-01     2.5465E-01     2.5606E-Ol 2.067E-01 BI-212 B<               9.7242E-01     9.7242 E-Ol o
ORTEC 9 v - i (1087) npp32       G53w3.05 07-APR-2008 17:09:37 page                 5 PBRF                                         Spectrum name: PB08-01214.Anl BI-214         ~.
7.6019E-01     7.6020E-01     2.2444E-Ol     2.2612E-Ol 1. 419E-Ol RA-226         B<       1.8209E+00     1.8209E+00 TH-234         B<       1. 4530E+00   1.4530E+00 u-235         B<       3.1325E-Ol     3.1325E-Ol AM-241         B<       1. 8638E-01   1.8638E-01
        # - All peaks for activity calculation had bad shape.
* Activity omitted from total
        & - Activity omitted from total and all peaks had bad shape.
        < - MDA value printed.
A - Activity printed, but activity < MDA.
B - Activity < MDA and failed test.
C - Area < Critical level.
F - Failed fraction or key line test.
H - Halflife limit exceeded
_____________________________               SUM MAR Y         ---------------------------
Total Activity (              38.7 to 2037.2 keY) O.OOOOOOOE+OO pci/g Total Decayed Activity (               38.7 to 2037.2 keY) O.OOOOOOOE+OO pci/g Analyzed by:
ecommissioning project page 4
 
                        ~
PB08-01214 Reviewed by:  ---:;J,J,~>Lf--7A'--:;;;'~~A~            ----.nJAeR.J) 8 200a l~~
Laboratory:   PBRF                         A. Case page 5
 
SECTION?
ATTACHMENT 4 1 PAGE
 
DQA Check Sheet Design              EP PPH-109          I Revision #
I      Original I
Survey Unit   #                                                             EP PPH-109 Preliminary Data Review' Answers to the following questions should be fully documented in the Survey Unit Yes   No   N/A Release Record
: i. Have surveys been performed in_. accordance with survey instructions in the Survey Design?                 X
: 2. Is the instrumentation MDC for structure static measurements below the DCGL w for Class 1 and 2 X
survey units, or below 05 DCGL w for Class 3 survey units?
3    Is the instrumentation MDC for embedded/buried piping static measurements below the DCGL w ?                X 4    Was the instrumentation MDC for structure scan measurements, soil scan measurements, and embedded/buried piping scan measurements below the DCGL w. or, if not, was the need for additional                      X static measurements or soil samples addressed in the survey design?
5    Was the instrumentation MDC for volumetric measurements and smear analysis < 10% DCGL w ?                   X
: 6. Were the MDCs and assumptions used to develop them appropriate for the instruments and techniques X
used to perform the survey?
: 7. Were the survey methods used to collect data proper for the types of radiation involved and for the X
media being surveyed?
8     Were "Special Methods" for data collection properly applied for the survey unit under review?              X 9     Is the data set comprised of qualified measurement results collected in accordance with the survey X
design, which accurately reflects the radiological status of the facility?
Graphical Data Review 1   Has a posting plot been created?                                                                                        X 2    Has a histogram (or other frequency plot) been created?                                                                 X
: 3. Have other graphical data tools been created to assist in analyzing the data?                                           X Data Analysis
: 1. Are all sample measurements below the DCGL w (Class 1 & 2), or 05 DCGL w (Class 3)?                               X
: 2. Is the mean of the sample data < DCGL w?                                                                   X
: 3. If elevated areas have been identified by scans and/or sampling, is the average activity in each X
elevated area < DCGLEMC (Class 1), < DCGL w (Class 2), or <0.5 DCGL w (Class 3)?
: 4. Is the result of the Elevated Measurements Test < 1.0?                                                     X 5   Is the result of the statistical test (5+ for Sign Test or W r for WRS Test) ::: the critical value?                    X Comments: See Section 5 of this Survey Unit Release Record FSS/Characterization Engineer (prinUsign)
                                                          &L        l<...) l' "I':::'   I;/1Aj~
                                                                                          , /I Date 1.5)? /tJJ I
FSS/ Characterization Manager (prinUsign)                  ['"I. Casl              ,/  k~    t..            Date  5/b4r v  . L.
Fonn CS-09/2 Rev 0 Page 1 of 1
 
SECTION 7 ATTACHMENT 5 1 DISC}}

Latest revision as of 01:54, 13 March 2020

Survey Unit Release Record, EP Pph 109, Revision - Original - Part 2
ML081690611
Person / Time
Site: Plum Brook
Issue date: 05/02/2008
From: Wood G
US National Aeronautics & Space Admin (NASA), John H. Glenn Research Ctr at Lewis Field
To:
NRC/RGN-III
Shared Package
ML081330527 List:
References
EP-PPH-109
Download: ML081690611 (72)
v • d • e


Text

  • SECTION 7 ATTACHMENT 3 68 PAGES

Attachment 3 Comments.

The graphic map in this attachment portrays the extent of core bores and excavations to support remediation of PH 109. Also included are the physical survey locations for the soil samples acquired to verify soil activity levels were less than DCGL at the conclusion of remediation activities in the various excavations. The appropriate soil sample ID numbers can be discerned in the hexagon symbols on the map. The soil sample results are included in this attachment.

0>--

  • 0 ROOM 7 0>-- ~

COl /B ROOM 1 FD ROOM2B CO 2 " \ /

FO 2

~S-010

~OOM3 U\FD3 JFD~

CO B-1 ROOM 8 VR 0- £:0

~~D~

~ FD 4-2 CO 6-2 ROOM4 ROOM6

~

01---  ;<04; VR 4-2 .J RPHO-l N

c:i

L n

o:

  • PB08-00798 ORTEC g v - i (1087) npp32 G53w3.05 13-MAR-2008 14:30:38 page 1 PBRF spectrum name: PB08-00798.An1 sample description PB08-00798; SR99-009; PPH; RM1; FD1; 3/13/08 spectrum Filename: z:\Lab\SAMPLE 08\PB08-00798.An1 Acquisition information Start time: 1Y-Mar-2008 14:25:00 Live time: 300 Real time: 301 Dead time: 0.28 %

Detector 10: 3 Detector system

  1. 3 DETECTOR (#131)

Calibration Filename:

250ml #73678-773 (MC131) Sept07 Energy calibration created: 05-sep-2007 16:56:38 Zero offset: 0.565 key Gain: 0.247 key/channel Quadratic: 5.022E-08 kev/channel A2 Efficiency Calibration created: 05-sep-2007 17:17:39 Type: polynomial uncertainty: 1. 204 %

coeffi ci ents: -0.304311 -4.249899 0.669559

-0.094002 0.005803 -0.000133 Library Files Main analysis library: plumbrk 01.lib Library Match Width: 0.500 peak stripping: Library based Analysis parameters Analysis engine: npp32 G53w3.05 start channel: 155 ( 38.83keV )

Stop channel: 8144 ( 2014.22kev) peak rejection level: 25.000%*

peak search sensitivity: 3 sample Size: 4.5780E+02 Activity scaling factor: 1.0000E+06/( 1.0000E+00* 4.5780E+02) 2.1844E+03 Detection limit method: Nureg 4.16 Random error: 1.0000000E+00 systematic error: 1.0000000E+00 Fracti-on Limit: 0.000%

Background width: best method (based on spectrum).

o Page 1

ORTEC g v - i (l087) npp32

  • PB08-00798 G53w3.05 13-MAR-2008 14:30:38 Page 2 PBRF Spectrum name: PB08-00798.An1 Half lives decay limit: 12.000 Activity range factor: 2.000 Min. step backg. energy 0.000 corrections Status Comments Decay correct to date: YES 11-Mar-2008 08:32:00 Decay during acquisition: NO Decay during collection: NO True coincidence correction: NO Peaked background correction: NO Absorption (Internal): NO Geometry correction: NO Random summing: NO Energy Calibration Normalized diff: 0.1080 SUM MAR Y 0 F PEA K S I N RAN G E Peak Area Uncert FWHM Corrctn Nuclide Brnch. Act. NuC Energy Factor Energy Ratio pCi/g 77 .16 60. 21. 82 0.62 8.259E-02 238.67 56. 18.73 0.97 6.195E-02 238.63 43.300 4.108E-01 PB212 352.09 59. 13.02 0.79 4.553E-02 351.93 37.600 6.779E-01 PB214 609.46 55. 13.48 0.54 2.830E-02 609.31 46.100 8.297E-01 BI214 661.40 22. 21. 32 0.59 2.639E-02 661.66 85.100 1. 928E-01 cs13 7 1173.14 55. 13.48 1. 30 1.656E-02 1173.24 99.974 6.544E-01 c060 1332.28 50. 14.14 0.31 1. 494E-02 1332.50 99.986 6.590E-01 c060 1460.62 108. *9.62 0.85 1.387E-02 1460.83 11. 000 1. 393E+01 K40
                        • U N IDE N T I FIE D PEA K SUM MAR Y ................. " ...... ..

.J.. .J.. .1_ oJ* .I. J * .1_ J. J_ J * .J.. oJ.

peak Centroid Background Net Area Intensity Uncert FWHM Suspected Channel Energy Counts Counts Cts/Sec 2 sigma % kev Nuclide 310.28 77 .16 38. 60. 0.198 43.64 0.618 sM s - peak fails shape tests.

D - peak area deconvoluted.

L - Peak written from unknown list.

C - Area < critical level.

M - peak is close to a library peak.

This section based on library: plumbrk 01.lib o

ORTEC g v - (1087) npp32 G53w3.05 13-MAR-2008 14:30:38 page 3 PBRF spectrum name: PB08-00798.Anl

  • '1:* *** * * '1: -1: ,!; '1:
  • 1. I D E N T I F I E D P EA K S U M M A R Y ** ** * *1: *"'1; * *~; **

Nuclide peak Centroid Background Net Area Intensity Uncert FWHM channel Energy Counts Counts Cts/Sec 2 sigma % kev AM-241 0.00 59.54 O. O. 0.000 0.00 0.000 TH-234 0.00 63.29 O. O. 0.000 0.00 0.000 TH-234 0.00 92.59 O. O. 0.000 0.00 0.000 page 2

  • PB08-00798 EU-152 0.00 121.78 O. o. 0.000 0,00 0.000 EU-154 0.00 123. 07 O. o. 0.000 0.00 0.000 u-235 0.00 143.76 O. o. 0.000 0.00 0.000 u-235 0.00 185.71 O. O. 0.000 0.00 0.000 PB-212 964.40 238.67 18. 56. 0.187 37.46 0.969 EU-152 0.00 344.28 O. O. 0.000 0.00 0.000 PB-214 1423.63 352.09 O. 59. 0.197 26.04 0.7905 Ag-108m 0.00 433.94 O. O. 0.000 0.00 0.000 BI-214 2465.43 609.46 O. 55. 0.183 26.97 0.5405 Ag-108m 0.00 614.28 . O. O. 0.000 0.00 0.000 .

cs-137 2675.64 661.40 O. 22. 0.073 42.64 O. 587s~

Ag-108m 0.00 722.91 O. O. 0.000 0.00 0.000 EU-154 0.00 723.30 O. O. 0.000 0.00 0.000 BI-212 0.00 727.33 O. O. 0.000 0.00 0.000 EU-154 0.00 1004.72 O. o. 0.000 0.00 .0. 000 CO-60 4745.62 1173 .14 O. 55. 0.183 26.97 1.2985 EU-154 0.00 1274.44 O. O. 0.000 0.00 0.000 co-60 5388.96 1332.28 O. 50. 0.167 28.28 0.3065 EU-152 0.00 1408.01 O. O. 0.000 0.00 0.000 K-40 5907.71 1460.62 O. 108. 0.360 19.25 0.8455 BI-214 7134.00 1764.13 O. O. 0.000 0.00 0.0005 5 - Peak fails shape tests.

D - Peak area deconvoluted.

A Derived peak area.

  • -1(*1:* S U MMA R Y 0 F L I BRA RY P EAK U S AG E 1: -!: 1: *-t:

- Nuclide - Ave~age ------------- Peak - - - - - - - - - - - - -

Name Code ActlVlty Energy Activity Code MDA value pci/g kev pci/g pci/g COMMENTS K-40 N 1. 3934E+01 1460.83 1. 393E+01 ( 9.509E-01 9.62 G K co-60 F 6.5675E-01 1332.50 6.590E-01 ( 9.714E-02 14.14 G K 1173.24 6.544E-01 ?( 8.770E-02 13 .48 G K CS-137 1.9279E-01 1.928E-0~

I 661.66 6.458E-02 21.32 G K o U ORTEC 9 v - i (1087) npp32 G53w3,05 13-MAR-2008 14:30:38 Page 4 PBRF Spectrum name: PB08-00798.An1 Nuclide Ave activity Energy Activity Code Peak MDA Comments PB-212 N 4.1077E-01 238.63 4.108E-01 ?( 1. 649E-01 18.73 G K PB-214 N 6.7792E-01 351.93 6.779E-01 ( 8.468E-02 13.02 G K BI-214 N 8.2966E-01 609.31 8.297E-01 ( 1.112E-01 13.48 G K 1764.49 O.OOOE+OO? 7.956E-01 0.00 G 1120.29 O.OOOE+OO & 1.071E+00 152.75 G

( - This peak used in the nuclide activity average.

  • peak is too wide, but only one peak in library.

- peak is part of a multiplet and this area went Page 3

negative during deconvolution.

PB08-00798

? - peak is too narrow.

@- Peak is too wide at FW25M, but ok at FWHM.

%- Peak fails sensitivity test.

$ peak identified, but first peak of this nuclide failed one or more qualification tests.

+ - Peak activity higher than counting uncertainty range.

peak activity lower than counting uncertainty range.

- Peak outside analysis energy range.

&- calculated peak centroid is not close enough to the library energy centroid for positive identlfication.

P - peakbackground subtraction

} Peak is too close to another for the activity to be found directly.

Nuclide codes: Peak codes:

T - Thermal Neutron Activation G - Gamma Ray F - Fast Neutron Activation X - x-Ray I - Fission Product P - Positron Decay N - Naturally occurring Isotope S - single-Escape P - Photon Reaction D- Double-Escape C - charged Particle Reaction K - Key Line M - No MDA Calculation A - Not in Average R Coincidence Corrected '-- - coincidence Peak r

H - Halfl ife 1i mi t exceeded o

ORTEC g v - (1087) npp32 G53W3.05 13-MAR-2008 14:30:38 Page 5 PBRF spectrum name: PB08-00798.An1 1,

  • 1, *' 1, SUM MAR Y o F N U C L I DES I N SAM P L E *-:.-1,7."1.

Time of Count Time Corrected uncertainty 2 Sigma Nuclide Activity Activity Counting Total MOA pci/g pci/g pci/g pci/g K-40 ~

1.3934E+01 1.3934E+01 2.6816E+OO 2.7126E+OO 9.509E-01 co-60 6.5621E-01 6.5675E-01 1. 2833E-01 1. 2977E-01 9.707E-02 Ag-l0rl?

cs-13 4.2438E-02

1. 9276E-01 4.2439E-02
1. 9279E-01 8.2205E-02 8.2399E-02 6.457E-02

);/' EU-15 . 1.1792E-01 1.1795E-01 EU~15 B<, 1. 4004E-01 1.4011E-01 PB-212 & 4.1077E-01 4.1077E-01 1.5386E-0l 1. 5423E-01 1. 649E-01 PB-214 .. 6.7792E-01 6.7792E-01 1. 7651E-01 1.7763E-01 8.468E-02 BI-212 B< 1. 1889E+OO 1. 1889E+00 BI-214

  • 8.2966E-01 8.2966E-01 2.2374E-01 2.2548E-01 1.112E-01 RA-226 B< 1. 9488E+OO 1.9488E+OO TH-234 B< 1. 8498E+OO 1. 8498E+OO u-235 B< 4.9574E-01 4.9574E-01 AM-241 B< 1.4399E-01 1. 4399E-01
  1. - All peaks for activity calculation had bad shape.

~ Activity omitted from total

& - Activity omitted from total and all peaks had bad shape.

< -MOA value printed.

A - Activity printed, but activity < MOA.

B - Activity < MOA and failed test.

C - Area < Critical level.

F - Failed fraction or key line test.

H - Halflife limit exceeded Page 4

  • PB08-00798

SUM MAR Y ---------------------------

Total Activity ( 38.8 to 2014.2 kev) 8.4897500E-01 pci/g Total Decayed Activity ( 38.8 to 2014.2 kev) 8.4953296E-01 pci/g Analyzed by:

project NAR Reviewed by: __ +ri--7~I'----::r"-""-- ' 3 1008 R. Case Laboratory: PBRF Page 5

  • PB08-00799 ORTEC g v - i (l087) npp32 G53W3.05 13-MAR-2008 14:35:55 Page 1 PBRF spectrum name: PB08-00799.Anl sample description PB08-00799; SR99-010; PPH; RM2; FD2; 3/13/08 spectrum Filename: z:\Lab\SAMPLE 08\PB08-00799.Anl Acquisition information Start time: 13-Mar-2008 14:29:50 Live ti me: . 300 Real time: 301 Dead time: 0.39 %

Detector 1D: 2 Detector system

  1. 2 DETECTOR (#130)

[] COpy calibration Filename:

250ml #73678-773 (Mc130)sept07 Energy Calibration Created: 13-sep-2007 15:00:31 Zero offset: 0.287 keY Gain: 0.251 keY/channel Quadratic: 2.324E-08 kev/channel A2 Efficiency Calibration created: 13-Sep-2007 15:22:08 Type: Po 1ynomi a1 uncertainty: 1. 626 %

Coefficients: -0.256697 -4.334323 0.664302

-0.092291 0.005686 -0.000130 Library Files Main analysis library: pl umbrk 01.1 i b Library Match width: 0.500 Peak stripping: Library based Analysis parameters Analysis engine: npp32 G53w3.05 start channel: 155 ( 39.27kev )

Stop channel: 8144 ( 2049.92kev)

Peak rejection level: 25.000%

peak search sensitivity: 3 sample Size: 4.2630E+02 Activity scaling factor: 1.0000E+06/( 1.0000E+00* 4.2630E+02) 2.3458E+03 Detection limit method: Nureg 4.16 Random error: 1.0000000E+00 systematic error: 1.0000000E+00 Fraction Limit: 0.000%

Background width: best method (based on spectrum).

o page 1

ORTEC g v - i (1087) npp32

  • PB08-00799 G53w3.05 13-MAR-2008 14:35:55 Page 2 PBRF Spectrum name: PB08-00799.An1 Half lives decay limit: 12.000 Activity range factor: 2.000 Min. step backg. energy 0.000 Corrections Status Comments Decay correct to date: YES 11-Mar-2008 08:35:00 Decay during acquisition: NO Decay during collection: NO True coincidence correction: NO Peaked background correction: NO Absorptinn (Internal): NO Geometry correction: NO Random summing: NO Energy Calibration Normalized diff: 0.0862 oJ.,)4 J,. oJ. J.

S U M ivl A R Y 0 F P EAKS I N RA NGE '1,"1: f:

  • 1.

Peak Area Uncert FWHM Corrctn Nuclide Brnch. Act. NUc Energy Factor Energy Ratio pci/g 77.07 57. 24.87 0.73 7.831E-02 238.69 81. 14.26 1.14 5.759E-02 238.63 43.300 6.864E-01 PB212 351. 98 80. 13.46 0.75 4.241E-02 351.93 37.600 1. 060E+00 PB214 609.15 50. 14.14 0.52 2.665E-02 609.31 46.100 8.600E-01 BI214 1461. 00 96. 10.21 1. 64 1. 362E-02 1460.83 11.000 1. 354E+01 K40 f,*

  • 1, *
  • 1: * '1: -1: 1: 1. UNI DE NT I F I ED P EAK S U M M A R Y
  • 1: 1: 1. 1: 1:
  • 1: '!..

~. ~: ~:

Peak Centroid Background Net Area Intensity uncert FWHM Suspected Channel Energy Counts Counts Cts/sec 2 sigma % keY Nuclide 305.31 77.07 48. 57. 0.190 49.75 0.732 PB-214 SM s - Peak fails shape tests.

D- Peak area deconvoluted.

L - peak written from unknown list.

C- Area < Critical level.

M- Peak is close to a library peak.

This section based on library: plumbrk01.lib ORTEC g v - 1 (1087) npp32 G53w3.05 13-MAR-2008 14:35:55 page 3 PBRF Spectrum name: PB08-00799.An1

"* 1: * '!( 1: 1. *

  • 1:'1.1.. i:1:
  • I D E NT I F I E D P E A K S U M M A R Y ./:
  • 1:'k '1: 1:1: ** 1: -:."k "1.
  • Nuclide peak centroid Background Net Area Intensity Uncert FWHM channel Energy Counts Counts Cts/Sec 2 Sigma % keY AM-241 0.00 59.54 O. O. 0.000 0.00 0.000 TH-234 0.00 63.29 O. O. 0.000 0.00 0.000 TH-234 0.00 92.59 O. O. 0.000 0.00 0.000 EU-152 0.00 121.78 O. O. 0.000 0.00 0.000 EU-154 0.00 123.07 O. O. 0.000 0.00 0.000 U-235 0.00 143.76 O. O. 0.000 0.00 0.000 Page 2

u-235 0.00 185.71

  • O.

PB08-00799 O. 0.000

  • 0.00 0.000 PB-212 947.91 238.69 15. 81. 0.270 28.53 1.135 EU-152 0.00 344.28 O. O. 0.000 0.00 0.000 PB-214 1398.30 351. 98 9. 80. 0.267 26.93 0.753s Ag-108m 0.00 433.94 O. O. 0.000 0.00 0.000 B1-214 2420.54 609.15 O. 50. 0.167 28.28 0.516s Ag-I08m 0.00 614.28 O. O. 0.000 0.00 0.000 cs-137 0.00 661.66 O. O. 0.000 0.00 0.000 Ag-108m 0.00 722.91 O. O. 0.000 0.00 0.000 EU-154 0.00 723.30 O. O. 0.000 0.00 0.000 B1-212 0.00 727.33 O. O. 0.000 0.00 0.000 EU-154 0.00 1004.72 O. O. 0.000 0.00 0.000 co-60 0.00 1173.24 O. O. 0.000 0.00 0.000 EU-154 0.00 1274.44 O. O. 0.000 0.00 0.000' co-60 0.00 1332.50 O. O. 0.000 0.00 0.000 EU-152 0.00 1408.01 O. O. 0.000 0.00 0.000 K-40 5805.24 1461. 00 O. 96. 0.320 20.41 1. 636 s - Peak fails shape tests.

D - Peak area deconvoluted.

A Derived peak area, SUM MAR Y o F LIB R A R Y PEA K USA G E *****

- Nuclide - Average ------------- Peak -------------

Name Code Activlty Energy Activity Code MDA value pci/g kev pci/g pci/g COMMENTS K-40 N 1. 3539E+01 1460.83 1. 354E+Ol ( 1. 039E+00 10.21 G K PB-212 N 6.8636E-01 238.63 6.864E-01 ( 1'.759E-01 14.26 G K PB-214 N 1. 0601E+00 351.93 1.060E+00 @( 2.212E-01 13.46 G K 0

ORTEC g v - 1 (l087) npp32 G53W3.05 13-MAR-2008 14:35:55 Page 4 PBRF Spectrum name: PB08-00799.Anl Nuclide Ave activity Energy Activity Code Peak MDA Comments B1-214 N 8.6000E-01 609.318.600E-Ol ( 1.268E-01 14.14 G K 1764.49 O.OOOE+OO % 8.569E-01 31.62 G 1120.29 O.OOOE+OO % 6.215E-01 28.87 G

( - This peak used in the nuclide activity average.

peak is too wide, but only one peak in library.

- peak is part of a multiplet and this area went negative during deconvolution.

? - peak is too narrow.

@ - peak is too wide at FW25M, but ok at FWHM.

% - peak fails sensitivity test. .

t.- peak identified, but first peak of this nuclide failed one or more qualification tests.

+ - peak activity higher than coun~ing uncert~inty range.

- - peak activity lower than countlng uncertalnty range.

= - peak outside analysis energy range.

& - calculated peak centr~id is not.c~ose.enough.to ~he library energy centrold for posltlve ldentlflcatlon.

Page 3

\ '

P - peakbackground subtraction

  • PB08-00799

} Peak is too close to another for the activity to be found directly.

Nuclide Codes: Peak codes:

T - Thermal Neutron Activation G - Gamma Ray F - Fast Neutron Activation X - X-Ray I - Fission Product P - Positron Decay N - Naturally occurring Isotope S - Single-Escape P - photon Reaction D - Double-Escape C - charged Particle Reaction K - Key Line M No MDA Calculation A - Not in Average R - Coincidence Corrected C - coincidence Peak H - Halfl He l imi t exceeded SUM MAR Y o F N U C L I DES I N SAM P L E '{-*-:.**

Time of Count Time Corrected Uncertainty 2 sigma Nuclide Activity Activity Counting Total MDA pci/g pci/g pci/g pci/g K-40 .. 1. 3539E+01 1.3539E+01 2.7636E+OO 2.7972E+00 1.039E+OO CO-60 B< 1. 0677E-01 1. 0686E-01 Ag-108mB< 6.6716E-02 6.6717E-02 cs-137 B< 1. 3424E-01 1.3426E-01 EU-152 B< 1. 8601E-0l 1.8607E-01 EU-154 ,.B< 1.7110E-01 1. 7118E-01 PB-212 6.8636E-01 6.8636E-01 1.9581E-0l 1.9661E-01 1.759E-01 PB-214 & 1. 0601E+OO 1. 0601E+00 2.8545E-01 2.8745E-01 2.212E-01 B1-212 B< 1.2040E+OO 1. 2040E+00 0

ORTEC 9 v - 1 (1087) npp32 G53w3.05 13-MAR-2008 14:35:55 Page 5 PBRF spectrum name: PB08-00799.An1 B1-214 " 8.6000E-01 8.6000E-01 2.4324E-01 2.4520E-01 1.268E-01 RA-226 B< 2.3548E+00 2.3549E+00 TH-234 B< 1.8929E+00 1. 8929E+OO u-235 B< 5.3764E-01 5.3764E-01 AM-241 B< 2.2330E-01 2.2330E-01

  1. - All peaks for activity calculation had bad shape.
  • - Activity omitted from total

&- Activity omitted from total and all peaks had bad shape.

< - MDA value printed.

A - Activity printed, but activity < MDA.

B - Activity < MDA and failed test.

C - Area < Critical level.

F - Failed fraction or key line test.

H - Halflife limit exceeded

SUM MAR Y ---------------------------

Total Activity ( 39.3 to 2049.9 kev) O.OOOOOOOE+OO pci/g Total Decayed Activity ( 39.3 to 2049.9 kev) O.OOOOOOOE+OO pci/g Analyzed by: A.

PBRF project

,I; MAR 13 2008 Reviewed by: /

Su R.Case Laboratory: PBRF page 4

  • PB08-01265 ORTEC g v - 1 (1087) npp32 G53w3.05 14-APR-2008 09:19:13 page 1 PBRF Spectrum name: PB08-01265.An1 sample description PB08-01265;SR99-52; PPH-RM3- FD3; 4/14/08 spectrum Filename: z:\Lab\SAMPLE 08\PB08-01265.An1 Acquisition information Start time: 14-Apr-200808:18:54 Live time: 600 Real time: 604 Dead time: 0.70 %

Detector 1D: 1 Detector system

  1. 1 DETECTOR (#129)

[J COpy Calibration Filename:

250ml #73678-773 (MC129) Jan08 Energy calibration created: . 09-Jan-2008 08:36:01 Zero offset: -0.051 kev Gain: 0.250 kev/channel Quadratic: -8.299E-09 kev/channel A2 Efficiency calibration created: 09-Jan-200809:15:56 Type: polynomial uncertainty: 1. 663 %

coefficients: -0.338084 -4.099654 0.610757

-0.082467 0.004895-0.000109 Library Files Main analysis library: pl umbrk 01. 1 i b Library Match Width: 0.500 Peak stripping: Library based Analysis parameters Analysis engine: npp32 G53w3.05 Start channel: 155 ( 38.73kev)

Stop channel: 8144 ( 2037.21kev)

Peak rejection level: 25.000%

Peak search sensitivity: 3 Sample Size: 4.6250E+02 Activity scaling factor: 1.0000E+06/( 1.0000E+00* 4.6250E+02) 2.1622E+03 Detection limit method: Nureg 4.16 Random error: 1.0000000E+00 systematic error: 1. OOOOOOOE+OO .

Froaction Limit: 0.000%

Background width: best method (based on spectrum).

o page 1

ORTEC g v - i (1087) npp32 PB08-01265 G53W3.05 14-APR-2008 09:19:13 Page 2 PBRF Spectrum name: PB08-01265.An1 Half lives decay limit: 12:000 Activity range factor: 2.000 Min. step backg. energy 0.000 Corrections Status Comments Decay correct to date: YES 09-Apr-2008 09:17:00 Decay during acquisition: NO Decay during collection: NO True coincidence correction: NO Peaked background correction: NO Absorption (Internal): NO Geometry correction: NO Random summing: NO Energy Calibration Normalized diff: 0.0975

  • '1."1.1:* S U MMA R Y 0 F P EAKS I N RAN G E * '1.-/. *-I(

peak Area Uncert FWHM Corrctn Nuclide Brnch. Act. Nuc Energy Factor Energy Ratio pci/g 74.78 125. 14.14 0.82 *8.364E-02 77 .18 180. 10.63 0.82 8.390E-02 185.78 75. 21. 93 0.90 7.485E-02 185.71 57.200 1. 706E-01 u235 186.21 3.590 2.722E+00 RA226 238.54 197. 9.64 0.97 6.443E-02 238.63 43.300 6.879E-01 PB212 295.13 98. 15.48 1. 07 5.498E-02 351.80 171. 9.17 0.98 4.767E-02 351.93 37.600 9.277E-01 PB214 609.16 115. 10.83 1.11 3.006E-02 609.31 46.100 8.083E-01 BI214 1120.51 30. 18.26 1. 25 1. 840E-02 1120.29 15.100 1.052E+00 BI214 1173.03 50. 16.95 0.34 1. 773E-02 1173.24 99.974 2.744E-01 c060 1332.63 39. 16.01 1.08 1. 598E-02 1332.50 99.986 2.381E-01 c060 1460.96 257. 6.24 1. 78 1. 481E-02 1460.83 11.000 1. 537E+01 K40

  • 1:1: 1: * *1:'1.***
  • U N IDE N T I F I E D PEA K SUM M A R Y 1.'1: * '1. * *.,'; -k * * '!'. 1(

peak centroid Background Net Area Intensity uncert FWHM sus~ected Channel Energy Counts Counts cts/sec 2 sigma % keY Nuc ide 299.07 74.78 93. 125. 0.208 28.29 0.820 PB-214 D 308.64 77 .17 92. 180. 0.299 21.26 0.823 PB-214 D 742.67 185.78 51. 75. 0.125 43.86 0.900 U-235 sM 1179.71 295.13 33. 98. 0.163 30.95 1.075 PB-214 M s - Peak fails shape tests.

D - Peak area deconvoluted.

L - Peak written from unknown list.

C - Area < critical level.

M - Peak is close to a library peak.

This section based on library: plumbrk 01.lib o

ORTEC g v - i (1087) npp32 G53W3.05 14-APR-2008 09:19:13 Page 3 PBRF Spectrum name: PB08-01265.An1 page 2

                            • 1 DEN T 1 F 1 E D PB08-01265 PEA K 5 U M MAR Y **************

Nuclide Peak centroid Background Net Area Intensity Uncert FWHM channel Energy Counts Counts Cts/Sec 2 sigma % kev AM-241 0.00 59.54 O. O. . 0.000 0.00 0.000 TH-234 0.00 63.29 O. O. 0.000 0.00 0.000 TH-234 0.00 92.59 O. O. 0.000 0.00 0.000 EU-152 0.00 121. 78 O. O. 0.000 0.00 0.000 EU-154 0.00 123.07 O. O. 0.000 0.00 0.000 u-235 0.00 143.76 O. O. 0.000 0.00 0.000 u-235 0.00 185.71 O. O. 0.000 0.00 0.000 RA-226 0.00 186.21 O. O. 0.000 0.00 0.000 PB-212 953.56 238.54 49. 197. 0.328 19.27 0.965 EU-152 0.00 344.28 O. O. 0.000 0.00 0.000 PB-214 1406.21 351.80 15. 171. 0.284 18.33 0.977 Ag-108m 0.00 433.94 O. O. 0.000 0.00 0.000 B1-214 2434.89 609.16 8. 115. 0.192 21.65 1.107s Ag-108m 0.00 614.28 O. O. 0.000 0.00 0.000 cs-137 0.00 661. 66 O. O. 0.000 0.00 0.000 Ag-108m 0.00 722.91 o. O. 0.000 0.00 0.000 EU-154 0.00 723.30 o. O. 0.000 0.00 0.000 B1-212 0.00 727.33 o. O. 0.000 0.00 0.000 EU-154 0.00 1004.72 o. O. 0.000 0.00 0.000 B1-214 4478.93 1120.51 O. 30. 0.050 36.51 1. 251s (0-60 4688.88 1173.03 4. 50. 0.083 33 .90 0.3435 EU-154 0.00 1274.44 O. O. 0.000 0.00 0.000 CD-60 5326.92 1332.63 O. 39. 0.065 32.03 1. 0765 EU-152 0.00 1408.01 O. O. 0.000 0.00 0.000 K-40 5839.99 1460.96 O. 257. 0.428 12.48 1.782 5 - peak fails shape tests.

D peak area deconvoluted.

A Derived peak area.

- Nuclide - Ave~age ------------- Peak -------------

Name code ActlVlty Energy Activity Code MDA value pci/g kev pci/g pci/g COMMENTS K-40 N 1.5366E+01 1460.83 1.537E+01 ( 4.407E-01 6.24 G K (0-60 I 2.5623E-01 1332.50 2.381E-01?( 4.500E-02 16.01 G K 1173.242.744E-01 ( 6.729E-02 16.95 G K o

ORTEC g v - 1 (1087) npp32 G53w3.05 14-APR-2008 09:19:13 Page 4 PBRF spectrum name: PB08-01265.An1 Nuclide Ave activity Energy Activity Code peak MDA Comments PB-212 N 6.8794E-01 238.63 6.879E-01 ( 1.234E-01 9.64 G K PB-214 N 9.2772E-01 351.93 9.277E-01 ( 1.139E-01 9.17 G K 81-214 N 8.0825E-01 609.318.083E-01 ( 1.117E-01 10.83 G K 1764.49 O.OOOE+OO & 5.640E-01 127.48 G page 3

  • PB08-01265 1120.29 1.052E+00 + 2.584E-01
  • 18.26 G

( - Th;s peak used ;n the nucl;de act;v;ty average.

Peak ;s too w;de, but only one peak in library.

- Peak ~s part.of a multiple~ and this area went

'negatlve durlng deconvolutlon. .

? - Peak is too narrow.

@ - Peak is too wide at FW25M, but ok at FWHM.

% - peak fails sensitivity test.

$ - Peak identified, but first peak of this nuclide failed one or more qualification tests.

+ - Peak activity higher than counting uncertainty range.

- - Peak activity lower than counting uncertainty range.

- Peak outs;de analysis energy range.

& - calculated peak centroid is not close enough to the library energy centroid for positive identlfication.

P - Peakbackground subtraction

} peak is too close to another for the activity to be found directly.

Nuclide codes: Peak codes:

T - Thermal Neutron Act;vation G - Gamma Ray F - Fast Neutron Activation X - X-Ray I - Fission Product P - positron Decay N - Naturally occurring Isotope 5 - single-Escape P - photon Reaction D - Double-Escape C - charged Particle Reaction K - Key Line M - NO MDA Calculation A - Not in Average R - coincidence corrected C - Coincidence peak H - Halflife 1 i mi t exceeded o

ORTEC g v - ; (1087) npp32 G53w3.05 14-APR-2008 09:19:13 page 5 PBRF spectrum name: PB08-01265.An1

          • 5 U M MAR Y OF NUCLI DES I N 5 AMP L E Time of count Time Corrected uncertainty 2 Sigma Nuclide Activity Activ;ty counting Total MDA pci/g pci/g pci/g pc;/g K-40
  • 1. 5366E+01 1.5366E+01 1. 9170E+00 i. 9798E+00 4.407E-01 co-60 2.5577E-01 2.5623E-01 5.9750E-02 6.0316E-02 4.492E-02 Ag-108mB< 5.4565E-02 5.4566E-02 cs-137 B< 4.0042E-02 4.0055E-02 EU-152 B< 1. 1165E-01 1. 1172E-01 EU-154 B< 1. 0086E-01 1. 0097E-01 PB-212
  • 6.8794E-01 6.8794E-01 1. 3258E-01 1. 3376E-01 1. 234E-01 PB-214
  • 9.2771E-01 9.2772E-01 1. 7009E-01 1. 7269E-01 1. 139E-01 BI-212 B< 1. 0880E+00 1. 0880E+00 BI-214 & 8.0825E-01 8.0825E-01 1. 7500E-01 1. 7743E-01 1.117E-01 RA-226 B< 1. 6310E+00 1. 6310E+00 TH-234 B< 1. 1517E+00 1. 1517E+00 u-235 B< 3.0181E-01 3.0181E-01 AM-241 B< 1. 7088E-01 1.7088E-01
  1. - All peaks for activity calculation had bad shape.

.. Activity omitted from total

& - Activity omitted from total and all peaks had bad shape.

< - MDA value printed.

Page 4

A - Act~v~ty

  • PB08-01265 printed, but activity < MDA.

B - ActlVlty < MDA and failed test.

c - Area < critical level.

F - Failed fraction or key line test.

H - Halflife limit exceeded

5 U M MAR Y ---------------------------

Total Activity ( 38.7 to 2037.2 keV) 2.5577208E-Ol pci/g Total Decayed Activity ( 38.7 to 2037.2 kev) 2.5622919E-Ol pci/g Analyzed by:

project Reviewed by: APR 4 200B R. Case Laboratory: PBRF page 5

ORTEC g v - i (1087) npp32 Page 1 PBRF Sample description PB08-00794; SR99-005; PPH; RM4;{~~~

Spectrum Filename: z:\Lab\SAMPLE 08\PB08-00794.An1 Acquisition information Start time: 13-Mar-2008 15:20:00 Live time: 1500 Real time: 1505 Dead time: 0.36 %

Detector ID: 2 Detector system

  1. 2 DETECTOR (#130)

Calibration

[] COrY Filename:

250ml #73678-773 (MC130)Sept07 Energy Calibration created: 13-sep-2007 15:00:31 Zero offset: 0.287 keV Gain: 0.251 kev/channel Quadratic: 2.324E-08 kev/channel A2 Efficiency calibration Created: 13-Sep-2007 15:22:08 Type: Pol ynomi al uncertainty: 1. 626 %

coefficients: -0.256697 -4.334323 0.664302

-0.092291 0.005686 -0.000130 Library Files Main analysis library: plumbrk 01.1ib

. Library Match width: 0.500 Peak stripping: Library based Analysis parameters Analysis engine: npp32 G53w3.05 Start channel: 155 ( 39.27kev )

Stop channel: 8144 ( 2049.92kev)

Peak rejection level: 25.000%

peak search sensitivity: 3 sample Size: 4.2840E+02 Activity scaling factor: 1.0000E+06/( 1.0000E+00* 4.2840E+02) 2.3343E+03 Detection limit method: Nureg 4.16 Random error: 1.0000000E+00 systematic error: 1.0000000E+00 Fraction Limit: 0.000%

Background width: best method (based on spectrum).

o page 1

ORTEC g v - i (1087) npp32

  • PB08-00794 G53w3.05 13-MAR-2008 15:48:34 Page 2 PBRF Spectrum name: PB08-00794.An1 Half lives decay limit: 12.000 Activity range factor: 2.000 Min. step backg. energy 0.000 Corrections Status Comments Decay correct to date: YES 11-Mar-2008 08:15:00 Decay during acquisition: NO Decay during collection: NO True coincidence correction: NO Peaked background correction: NO Absorption (Internal): NO Geometry correcti~n: NO Random summing: NO Energy calibration Normalized diff: 0.1333
  • -!~* -!:
  • S U M MA R Y 0 F P EA KS I N RAN G E "/,"1.. "'/."1:1.

Peak Area uncert FWHM corrctn Nuclide Brnch. Act. Nuc Energy Factor Energy Ratio pcijg 74.83 142. 18.95 0.92 7.837E-02 77 .05 192. 13.56 0.92 7.831E-02 186.04 133. 19.28 0.79 6.693E-02 185.71 57.200 PBC<MDA u235 186.21 3.590 2.334E+00 RA226 238.70 301. 7.95 1.06 5.759E-02 238.63 43.300 5.082E-01 ps212 295.34 196. 10.80 1. 20 4.903E-02 352.03 277 . 7.90 1. 06 4.240E-02 351.93 37.600 7.314E-01 PB214 609.50 190. 9.85 0.92 2.665E-02 609.31 46.100* 6.504E-01 BI214 661. 68 113. 12.92 0.87 2.492E-02 661. 66 85.100 2.241E-01 cS137 1120.77 74. 19.94 1.11 1. 660E-02 1120.29 15.100 1. 250E+00 BI214 1173.23 50. 16.12 0.87 1. 604E-02 1173.24 99.974 1. 326E-01 c060 1333.26 50. 18.65 0.30 1. 459E-02 1332.50 99.986 1.428E-01 c060 1461.01 524. 4.37 1.71 1. 362E-02 1460.83 11. 000 1. 471E+01 K40 1764.77 44. 15.08 0.94 1. 180E-02 1764.49 15.400 1. 018E+00 B1214

.1
1:1:1: **
  • 1:* 1:-/. U N IDE N T I F I E D PEA K SUM M A R Y -:.. -:.. **1.-1.. 1.. *1.. 1."1,"1,"

Peak Centroid Background Net Area Intensity Uncert FWHM Suspected Channel Energy Counts Counts CtsjSec 2 sigma % kev Nuclide 296.40 74.76 291. 142. 0.095 37.90 0.922 PB-214 D 305.23 76.98 241. 192. 0.128 27 .12 0.924 PB-214 D 1173.10 295.34 56. 196. 0.131 21. 60 1. 201 PB-214 M s - Peak fails shape tests.

D - Peak area deconvoluted.

L - Peak written from unknown list.

C - Area < Critical level.

M - Peak is close to a library peak.

This section based on library: plumbrk 01.lib o

ORTEC g v - i (1087) npp32 G53w3.05 13-MAR-2008 15:48:34 Page 3 PBRF Spectrum name: PB08-00794.An1 page 2

  • PB08-00794 "1: 1.-1. 1: 1.
  • 1. 1: *
  • 1, '* -1: '1: I DEN T I F I E D P EA K SUM MAR Y **************

Nuclide Peak Centroid Background Net Area Intensity Uncert FWHM Channel Energy Counts Counts Cts/Sec 2 sigma % kev AM-241 0.00 59.54 O. O. 0.000 0.00 0.000 TH-234 0.00 63.29 O. O. 0.000 0.00 0.000 TH-234 0.00 92.59 O. O. 0.000 0.00 0.000 EU-152 0.00 121. 78 O. O. 0.000 0.00 0.000 EU-154 0.00 123.07 O. O. 0.000 0.00 0.000 u-235 0.00 143.76 O. O. 0.000 0.00 0.000 u-235 0.00 185.71 O. O. 0.000 0.00 0.000 RA-226 738.56 186.04 127. 133. 0.089 38.57 0.7925 PB-212 947.95 238.70 82. 301. 0.201 15.90 1.058 EU-152 0.00 344.28 O. O. 0.000 0.00 0.000 PB-214 1398.50 352.03 47. 277 . 0.185 15.79 1.065 Ag-108m 0.00 433.94 O. O. 0.000 0.00 0.000 BI-214 2421. 94 609.50 32. 190. 0.127 19.69 0.916s Ag-108m 0.00 614.28 O. O. 0.000 0.00 0.000 cS-137 2629.33 661. 68 20. 113. 0.075 25.83 0.8715 Ag-108m 0.00 722.91 "u . O. 0.000 0.00 0.000 EU-154 0.00 723.30 O. O. 0.000 0.00 0.000 BI-212 0.00 727.33 O. O. 0.000 0.00 0.000 EU-154 0.00 1004.72 O. O. 0.000 0.00 0.000 BI-214 4453.63 1120 ..77 20. 74. 0.050 39.89 1.1155 co-60 4662.07 1173.23 4. 50. 0.034 32.24 0.8735 EU-154 0.00 1274.44 O. O. 0.000 0.00 0.000 co-60 5297.81 1333.26 6. 50. 0.033 37.31 0.3045 EU-152 0.00 1408.01 O. O. 0.000 0.00 0.000 K-40 5805.30 1461. 01 O. 524. 0.349 8.74 1.711 BI-214 7011. 73 1764.77 O. 44. 0.029 30.15 0.9445 s - peak fails shape tests.

D - peak area deconvoluted.

A Derived peak area.

- Nuclide - Ave~age ------------- Peak -------------

Name Code Actlvlty Energy Activity Code MDA value pci/g kev pci/g pci/g COMMENTS K-40 N 1. 4707E+Ol 1460.83 1. 471E+01 ( 2.069E-01 4.37 G K co-60 F 1. 3771E-01 1332.50 1. 428E-01 ( 3.936E-02 18.65 G K 1173.24 1. 326E-01 ( 3.000E-02 16.12 G K 0

ORTEC g v - i (1087) npp32 G53w3.05 13-MAR-2008 15:48:34 Page 4 PBRF spectrum name: PB08-00794.An1*

Nuclide Ave activity Energy Activity Code Peak MDA Comments cs-137 I 2.2413E-01 661.66 2.241E-01 .c 4.671E-02 12.92 G K PB-212 N 5.0817E-01 238.63 5.082E-0l ( 7.559E-02 7.95 G K PB-214 N 7.3142E-Ol Page 3

  • PB08-00794 351.93 7.314E-01 ( 9.110E-02
  • 7.90 G K BI-214 N 6.5040E-01 609.31 6.504E-01 ( 9.951E-02 9.85 G K 1764.49 1. 018E+00 + 1. 705E-01 15.08 G 1120.29 1. 250E+00 + 3:908E-01 19.94 G RA-226 N 2.3339E+00 186.21 2.334E+00 *( 9.655E-01 19.28 G K

( - This peak used in the nuclide activity average.

Peak is too wide, but only one peak in library.

- Peak is part of a multiplet and this area went negative during deconvolution.

? - Peak is too narrow.

@ - Peak is too wide at FW25M, but ok at FWHM.

% - Peak fails sensitivity tEst.

$ - Peak identified, but first peak of this nuclide failed one or more qualification tests.

+ - peak activity higher than counting uncertainty range.

- - Peak activity lower than counting uncertainty range.

- Peak outside analysis energy range.

& - Calculated peak centroid is not close enough to the library energy centroid for positive identlfication.

P - peakbackground subtraction

} Peak is too close to another for the activity to be found directly.

Nuclide codes: Peak Codes:

T - Thermal Neutron Activation G - Gamma Ray F - Fast Neutron Activation X X-Ray I - Fission Product P Positron Decay N Naturally occurring Isotope S single-Escape P - photon Reaction D Double-Escape C - charged Particle Reaction K Key Line M - NO MDA Calculation A Not in Average R Coincidence Corrected C Coincidence Peak H Halflife limit exceeded o

ORTEC g v - (1087) npp32 G53w3.05 13-MAR-2008 15:48:34 page 5 PBRF spectrum name: PB08-00794.An1

          • SUM MAR Y o F N U C L I DES I N SAM P L E Time of Count Time corrected uncertainty 2 sigma Nuclide Activity Activity counting Total . MDA pci/g pci/g pCi/g pCi/g K-40 ~
1. 4707E+01 1. 4707E+01 1.2850E+00 1.3681E+OO 2.069E-01 co-60 1. 3760E-01 1. 3771E-01 3.3949E-02 3.4232E-02 3.932E-02 Ag-108mB< 2.9858E-02 2.9859E-02 cs-13i 2.2410E-01 2.2413E-01 5.7895E-02 5.8335E-02 4.670E-02 EU-152 B< 1.1821E-01 1. 1825E-0l EU-154 B< 7.3223E-02 7.3260E-02 PB-212 ~

5.08llE-01 5.08llE-01 8.0775E-02 8.1834E-02 7.559E-02 PB-214 .. 7.3141E-0l 7.3142E-01 1. 1551E-01 1. 1784E':-Ol 9.110E-02 81-212 B< 8.3351E-01 8.3351E-01 BI-214

  • 6.5039E-01 6.5040E-01 1.2808E-01 1. 3020E-01 9.951E-02 RA-226 & 2.3339E+OO 2.3339E+OO 9.0014E-01 9.3380E-01 9.655E-01 page 4

TH-234 B< 7.3876E-Ol

  • 7.3876E-Ol PB08-00794 u-235 B< 2.4401E-Ol 2.4401E-Ol AM-241 B< 1. 0412E-Ol 1. 0413E-Ol
  1. - All peaks for activity calculation had bad shape.
  • Activity omitted from total

&- Activity omitted from total and all peaks had bad shape.

< - MDA value printed.

A- Activity printed, but activity < MDA.

B - Activity < MDA and failed test.

C - Area < Critical level.

F - Failed fraction or key line test.

H- Halflife limit exceeded

5 U M MAR Y ---------------------------

Total Activity ( 39.3 to 2049.9 keV) 3.6169705E-Ol pci/g Total Decayed Activity ( 39.3 to 2049.9 kev) 3.6184323E-Ol pCi/g Analyzed by:

project Reviewed by: MAR 13 2008 A. Case Laboratory: PBRF Page 5

  • PB08-01218 ORTEC g v - 1 (l087) npp32 G53w3.05 07-APR-2008 17:27:42 Page 1 PBRF Spectrum name: PB08-01218.An1 sample description PB08-01218; SR99-37; PPH RM 4; FD4-1B; 4/7/08 spectrum Filename: z:\Lab\SAMPLE 08\PB08-01218.An1 Acquisition information Start time: 07-Apr-2008 17:21:54 Live time: 300 Real time: 301 Dead time: 0.17 %

Detector 1D: 3 Detector system

  1. 3 DETECTOR (#131) calibration Filename:

[j COpy 250ml #73678-773 (MC131) Sept07 Energy calibration created: 05-Sep-2007 16:56:38 Zero offset: 0.565 kev Gain: 0.247 kev/channel Quadratic: 5.022E-08 kev/channel A2 Efficiency calibration created: 05-Sep-2007 17:17:39 Type: polynomial uncertainty: 1. 204 %

Coefficients: -0.304311 -4.249899 0.669559

-0.094002 0.005803 -0.000133 Library Files Main analysis library: pl umbrk 01.1 i b Library Match width: 0.500 Peak stripping: Library based Analysis parameters Analysis engine: npp32 G53w3.05 Start channel: 155 ( 38.83kev )

Stop channel: . 8144 ( 2014.22kev)

Peak rejection level: 25.000%

peak search sensitivity: 3 sample Size: 4.6560E+02

. Activity scaling factor: 1.0000E+06/( 1.0000E+00* 4.6560E+02) 2.1478E+03 Detection limit method: Nureg 4.16 Random error: 1.0000000E+00 systematic error: 1. OOOOOOOE+OO Fraction Limit: 0.000%

Background width: best method (based on spectrum).

o page 1

ORTEC g v - i (1087) npp32 PB08-01218 G53w3.05 07-APR-2008 17:27:42 Page 2 PBRF Spectrum name: PB08-01218.An1 Half lives decay limit: 12.000 Activity range factor: 2.000 Min. step backg. energy 0.000 Corrections Status Comments Decay correct to date: YES 02-Apr-2008 13:42:00 Decay during acquisition: NO Decay during collection: NO True coincidence correction: NO Peaked background correction: NO Absorption (Internal): NO Geometry correction: NO Random summing: NO Energy Calibration Normalized diff: 0.1988 1,"1,"1:"/,-1,-

S U MMA R Y 0 F P EA KS I N RAN G E .) * .).-'* .J-.J.

peak Area uncert FWHM Corrctn Nuclide Brnch. Act. Nuc Energy Factor Energy Ratio pci/g 63.68 72. 23.25 0.82 7.980E-02 63.29 4.800 3.627E+00 TH234 77 .41 54. 24.00 0.88 8.257E-02 93.22 53. 23.03 1.17 8.166E-02 92.59 5.580 2.251E+00 TH234 186.45 37. 23.09 0.87 7.184E-02 186.21 3.590 2.776E+00 RA226 238.86 53. 17.19 1. 31 6.196E-02 238.63 43.300 3.822E-01 ps212 351.95 64. 12.50 0.86 4.555E-02 351. 93 37.600 7.231E-01 PB214 1460.52 127. 8.87 0.80 1. 387E-02 1460.83 11.000 1. 611E+01 K40

  • -f,. * * ""*'1;***** U N I D E N T I F I E D P EA K S U M M A R Y ...... " .. " " ....

J- -'~ -'- -'- -'-.). -,_ oJ. -'- -'. -,.-,_

,~ " "

Peak Centroid Background Net Area Intensity Uncert FWHM suspected Channel Energy Counts Counts cts/sec 2 sigma % keY Nuclide 311.29 77 .41 38. 54. 0.180 48.01 0.876 s - peak fails shape tests.

D Peak area deconvoluted.

L - Peak written from unknown list.

C - Area < Critical level.

This section based on library: plumbrk 01.lib o

ORTEC g v - (1087) npp32 G53w3.05 07-APR-2008 17:27:42 Page 3 PBRF Spectrum name: PB08-01218.An1

                            • IDE N T I FIE D PEA K SUM MAR Y **************

Nuclide peak Centroid Background Net Area Intensity Uncert FWHM Channel Energy Counts Counts cts/Sec 2 sigma % keY AM-241 0.00 59.54 O. O. 0.000 0.00 0.000 TH-234 255.67 63.68 46. 72. 0.238 46.49 0.821 TH-234 375.34 93.22 24. 53. 0.177 46.06 1.173s EU-152 0.00 121.78 O. O. 0.000 0.00 0.000 EU-154 0.00 123.07 O. O. 0.000 0.00 0.000 page 2

u-235 0.00 143.76

  • O.

PB08-01218 O. 0.000

  • 0.00 0.000 u-235 0.00 185.71 O. O. 0.000 0.00 0.000 RA-226 752.93 186.45 9. 37. 0.123 46.18 0.872 PB-'212 965.16 238.86 10. 53. 0.177 34.38 1. 311 EU-152 0.00 344.28 O. O. 0.000 0.00 0.000 PB-214 1423.09 351.95 O. 64. 0.213 25.00 0.855s Ag-108m 0.00 433.94 O. O. 0.000 0.00 0.000 B1-214 0.00 609.31 O. O. 0.000 0.00 0.000 Ag-108m 0.00 614.28 O. O. 0.000 0.00 0.000 cs-137 0.00 661.66 O. O. 0.000 0.00 0.000 Ag-108m 0.00 722.91 O. O. 0.000 0.00 0.000 EU-154 0.00 723.30 O. O. 0.000 0.00 0.000 B1-212 0.00 727.33 O. O. 0.000 0.00 0.000 EU-154 0.00 1004.72 O. O. 0.000 0.00 0.000 B1-214 0.00 1120.29 O. . O. 0.000 0.00 0.000 co-60 0.00 1173.24 O. O. 0.000 0.00 0.000 EU-154 0.00 1274.44 O. O. 0.000 0.00 0.000 co-60 0.00 1332.50 O. O. 0.000 0.00 0.000 EU-152 0.00 1408.01 O. O. 0.000 0.00 0.000 K-40 5907.31 1460.52 O. 127. 0.423 17.75 0.799s B1-214 0.00 1764.49 O. O. 0.000 0.00 0.000 s - peak fails shape tests.

D - Peak area deconvoluted.

A Derived peak area.

- Nuclide - Ave~age ------------- Peak -------------

Name code Actlvlty Energy Activity Code MDA value pci/g kev pci/g pci/g COMMENTS K-40 N 1.6111E+01 1460.83 1.611E+01?( 9.350E-01 8.87 G K PB-212 N 3.8225E-01 238.63 3.822E-01 ( 1.258E-01 17.19 G K o

ORTEC 9 v - i (1087) npp32 G53W3.05 07-APR-2008 17:27:42 Page 4 PBRF spectrum name: PB08-01218.An1 Nuclide Ave activity Energy Activity Code peak MDA Comments PB-214 N 7.2305E-Ol 351.93 7.231E-01 ( 8.326E-02 12.50 GK RA-226 N 2.7761E+00 186.21 2.776E+00 ( 1. 252E+00 23.09 G K TH-234 N 3:6275E+00 63.29 3.627E+00 ( 1. 732E+00 23.25 G K 92.59 2.251E+00 & 1. 085E+00 23.03 G K

( - This peak used in the nuclide activity average.

Peak is too wide, but only one peak in library.

- Peak is part of a multiplet and this area went negative during deconvolution.

? - Peak is too narrow.

@ - Peak is too wide at FW25M, but ok at FWHM.

% - Peak fails sensitivity test.

$ - Peak identified, but first peak of this nuclide page 3

,I

  • PBOS-01218 failed one or more qualification tests.

+ - peak activity higher than counting uncertainty range.

- - Peak activity lower than counting uncertainty range.

=- peak outside analysis energy range.

&- calculated peak centroid is not close enou~h to the library energy centroid for positive identlfication.

P - peakbackground subtraction

} peak is too close to another for the activity to be found directly.

Nuclide codes: peak codes:

T - Thermal Neutron Activation G - Gamma Ray F - Fast Neutron Activation X - x-Ray I - Fission Product P - Positron Decay N - Naturally occurring Isotope S - single-Escape P - photon Reaction 0 - Double-Escape rI.... -

charged particle Reaction K - Key Line M - No MDA Calculation A - Not in Average R - Coincidence Corrected C - coincidence peak H - Hal fl i fe 1i mi t exceeded 5 U M MAR Y OF NUCLI DES I N SAM P L E Time of Count Time Corrected uncertainty 2 sigma Nuclide Activity Activity counting Total MDA pci/g pci/g pci/g pci/g K-40 & 1.6111E+Ol 1.6111E+01 2.8593E+00 2.8980E+00 9.350E-01 CO-60 B< 9.5439E-02 9.5616E-02 Ag-I08mB< 4.1727E-02 4.1728E-02 C5-137 B< 6.3493E-02 6.3513E-02 o

ORTEC g v - 1 (l087) npp32 G53w3.05 07-APR-2008 17:27:42 Page 5 PBRF spectrum name: PBOS-01218.Anl EU-152 B< 1.1594E-Ol 1.1602E-Ol EU-154 B< 1.2273E-01 1. 22S7E-Ol PB-212 PB-214 .... 3.8225E-01 7.2305E-01 3.8225E-01 7.2305E-01

1. 3141E-01
1. 8076E-01
1. 3178E-Ol
1. 8200E-Ol 1.258E-Ol 8.326E-02 BI-212 B< 8.8872E-01 8.8872E-Ol BI-214 RA-226 ..

B< 2.3972E-01 2.7761E+00 2.3972E-Ol 2.7761E+00 1. 2821E+00 1. 3157E+00 1. 252E+00 TH-234 .. 3.6275E+00 3.6275E+00 1. 6865E+00 1. 6891E+00 1. 732E+00 u-235 B< 4.1945E-Ol 4.1945E-01 AM-241 B< 1.8602E-Ol 1. 8603E-Ol

  1. - All peaks for activity calculation had bad shape.

.. Activity omitted from total

& - Activity omitted from total and all peaks had bad shape.

< - MDA value printed.

A - Activity printed, but activity < MDA.

B - Activity < MDA and failed test.

C - Area < critical level.

F - Failed fraction or key line test.

H - Halflife limit exceeded

5 U M MAR Y ---------------------------

Total Activity ( 38.8 to 2014.2 keV) O.OOOOOOOE+OO pci/g Total Decayed Activity ( 38.8 to 2014.2 kev) O.OOOOOOOE+OO pci/g Analyzed by: ~A rt!.~ Page 4

  • PB08-01218 oning Project Reviewed by: _~~~..LJ-...~--= _ _~A!.!.....!JPR 0*8 2008 Laboratory: PBRF R. Case Page 5
  • PB08-01082 ORTEC g v - i (1087) npp32 G53w3.05 26-MAR-2008 16:29:47 Page 1 PBRF Spectrum name: PB08-01082.An1 sample description PB08-01082; SR99-14; PPH-RM4; FD-4-2; 3/26/08 Spectrum Filename: z:\Lab\SAMPLE 08\PB08-01082.An1 Acquisition information Start time: 26-Mar-2008 16:19:45 Live time: 300 Real time: 301 Dead time: 0.19 %

Detector 1D: 3 Detector system

  1. 3 DETECTOR (#131)

Calibration Filename:

250ml #73678-773 (MC131) Sept07 ro COpy Energy Calibration Created: 05-Sep-2007 16:56:38 Zero offset: 0.565 kev Gain: 0.247 kev/channel Quadratic: 5.022E-08 kev/channel A2 Efficiency Calibration Created: 05-Sep-2007 17:17:39 Type: Polynomial Uncertai nty: 1. 204 %

Coeffi ci ents : -0.304311 -4.249899 0.669559

-0.094002 0.005803 -0.000133 Library Files Main analysis library: plumbrk OI.lib Library Match width: 0.500 peak stripping: Library based Analysis parameters Analysis engine: npp32 G53w3.05 Start channel: 155 ( 38.83kev )

Stop channel: 8144 ( 2014.22kev)

Peak rejection level: 25.000%

Peak search sensitivity: 3 sample size: 4.2770E+02 Activity scaling factor: 1.0000E+06/( 1.0000E+00* 4.2770E+02) 2.3381E+03 Detection limit method: Nureg 4.16 Random error: 1. OOOOOOOE+OO systematic error: 1.0000000E+00 Fraction Limit: 0.000%

Background width: best method (based on spectrum).

o page 1

ORTEC g v - i (1087) npp32

  • PB08-01082 G53w3.05 26-MAR-2008 16:29:47 Page 2 PBRF Spectrum name: PB08-01082.An1 Half lives decay limit: 12.000 Activity range factor: 2.000 Min. step backg. energy 0.000 Corrections Status Comments Decay correct to date: YES 18-Mar-2008 15:18:00 Decay during acquisition: NO Decay during collection: NO True coincidence correction: NO Peaked background correction: NO Absorption (Internal): NO Geometry correction: NO Random summing: NO Energy Calibration Normalized diff: 0.1381 SUM MAR Y 0 F PEA K S I N RAN G E *****

Peak Area Uncert FWHM Corrctn Nuclide Brnch. Act. NUc Energy Factor Energy Ratio pcijg 77 .00 98. 22.48 0.54 8.260E-02 238.88 57. 16.36 0.75 6.191E-02 238.63 43.300 4.475E-01 PB212 352.26 51. 16.98 0.95 4.551E-02 351. 93 37.600 6.272E-01 PB214 609.46 45. 14.91 1. 09 2.830E-02 609.31 46.100 7.266E-01 BI214 1461.03 97. 10.15 1. 29 1. 387E-02 1460.83 11.000 1.340E+01 K40

                        • U N IDE N T I FIE D PEA K SUM MAR Y ************

peak Centroid Background Net Area Intensity Uncert FWHM Suspected Channel Energy Counts Counts Ctsjsec 2 sigma % kev Nuclide 309.61 77.00 75. 98. 0.327 44.97 0.543 sM s - Peak fails shape tests.

D

  • peak area deconvoluted.

L - Peak written from unknown list.

C - Area < Critical level.

M - Peak is close to a library peak.

This section based on library: plumbrk 01.lib o

ORTEC g v - (1087) npp32 G53w3.05 26-MAR-2008 16:29:47 Page 3 PBRF spectrum name: PB08-01082.An1

-,':,';-);;:*"1;;;-;,-;;-1:'1:'1:'1:-;,

I D E NT I F I E D P E A K S U M M A R Y -f,-"1: ,*-1: "1,"1:-!;-;:-,':'1: "!;-,',"-;:*

Nuclide peak Centroid Background Net Area Intensity Uncert FItJHM channel Energy Counts Counts CtsjSec 2 sigma % kev AM-241 0.00 59.54 O. O. 0.000 0.00 0.000 TH-234 0.00 63.29 O. O. 0.000 0.00 0.000 TH-234 0.00 92.59 O. O. 0.000 0.00 0.000 EU-152 0.00 121. 78 O. O. 0.000 0.00 0.000 EU-154 0.00 123.07 O. O. 0.000 0.00 0.000 u-235 0.00 143.76 O. O. 0.000 0.00 0.000 Page 2

U-235 0.00 185.71

  • O.

PB08-01082 O. 0.000

  • 0.00 0.000 PB-212 965.25 238.88 10. 57. 0.190 32.73 0.747s EU-152 0.00 344.28 O. O. 0.000 0.00 0.000 PB-214 1424.32 352.26 6. 51. 0.170 33.96 0.945 Ag-108m 0.00 433.94 O. O. 0.000 0.00 0.000 BI-214 2465.45 609.46 O. 45. 0.150 29.81 1. 087s Ag-108m 0.00 614.28 O. O. 0.000 0.00 0.000 cS-137 0.00 661. 66 O. O. 0.000 0.00 0.000 Ag-108m 0.00 722.91 O. O. 0.000 0.00 0.000 EU-154 0.00 723.30 O. O. 0.000 0.00 0.000 BI-212 0.00 727.33 O. O. 0.000 0.00 0.000 EU-154 0.00 1004.72 O. O. 0.000 0.00 0.000 co-60 0.00 1173 . 24 O. O. 0.000 0.00 0.000 EU-154 0.00 1274.44 O. O. 0.000 0.00 0.000 co-60 0.00 1332.50 O. O. 0.000 0.00 0.000 EU-152 0.00 1408.01 O. O. 0.000 0.00 0.000 K-40 5909.36 1461. 03 O. 97. 0.323 20.31 1.287s s - peak fails shape tests.

D - peak area deconvoluted.

A Derived peak area.

~~~~h SUM MAR Y a F LIB R A R Y PEA K USA G E

- Nuclide - Ave~age ------------- Peak -------------

Name code Actlvlty Energy Activity Code MDA value pci/g kev pci/g pci/g COMMENTS K-40 N 1. 3396E+01 1460.83 1.340E+01 ( 1.018E+00 10.15 G K PB-212 N 4.4753E-01 238.63 4.475E-01 ( 1. 370E-01 16.36 G K PB-214 N 6.2724E-01 351.93 6.272E-01 ?( 1. 737E-01 16.98 G K 0

ORTEC g v - i (l087) npp32 G53w3.05 26-MAR-2008 16:29:47 page 4 PBRF Spectrum name: PB08-01082.An1 Nuclide Ave activity Energy Activity Code Peak MDA Comments BI-214 N 7.2659E-01 609.31 7.266E-01 ( 1.190E-01 14.91 G K 1764.49 O.OOOE+OO % 8.516E-01 35.36 G 1120.29 O.OOOE+OO & 9.768E-01 321.46 G

( - This peak used in the nuclide activity average.

- peak is too wide, but only one peak in library.

- peak is part of a multiplet and this area went negative during deconvolution.

? - peak is too narrow.

@ - peak is too wide at Fw2SM, but ok at FWHM.

% - peak fails sensitivity test.

$ - peak identified, but first peak of this nuclide failed one or more qualification tests.

+ - peak activity higher than counting uncertainty range.

peak activity lower than counting uncertainty range.

- peak outside analysis energy range.

& - calculated peak centr~id is not.c!ose.enough.to ~he library energy centrold for POSltlve ldentlflcatlon.

Page 3

P - peakbackground subtraction

  • PB08-01082

} peak is too close to another for the activity to be found directly.

Nuclide Codes: Peak Codes:

T - Thermal Neutron Activation G - Gamma Ray F - Fast Neutron Activation X - X-Ray I - Fission Product P - Positron Decay N - Naturally occurring Isotope S - single-Escape P - Photon Reaction D - Double-Escape C - Charged Particle Reaction K - Key Line M - No MOA Calculation A - Not in Average R - Coincidence Corrected C - coincidence Peak H - Ha lfl i fe 1 i mi t exceeded 1: 1, .:: 1:

S U MMA R y 0 F NUC L I 0 E S I N S A MP L E .)* .)* .J* .) * .)_

~':

Time of Count Time Corrected uncertainty 2 Sigma Nuclide Activity Activity counting Total MDA pci/g pci/g pCi/g pCi/g K-40 ~. 1. 3396E+01 1. 3396E+01 2.7203E+OO 2.7485E+OO 1.018E+00 co-60 B< 1. 0390E-01 1.0420E-01 Ag-108mB< 4.5425E-02 4.5427E-02 cs-137 B< 6.9119E-02 6.9154E-02 EU-152 B< 1. 4944E-01 1. 4961E-01 EU-154 B< 1. 4888E-01 1.4914E-01 PB-212 ~: 4.4753E-01 4.4753E-01 1.4647E-01 1.4692E-01 1.370E-01 PB-214 & 6.2724E-01 6.2724E-01 2.1302E-01 2.1382E-01 1.737E-01 BI-212 B< 1. 3928E+OO 1.3928E+OO o

ORTEC 9 v - i (1087) npp32 G53w3.05 26-MAR-2008 16:29:47 page 5 P8RF spectrum name: PB08-01082.An1 BI-214 ~.

7.2658E-01 7.2659E-01 2.1663E-01 2.1801E-01 1. 190E-01 RA-226 B< 2.2173E+OO 2.2173E+00 TH-234 B< 1. 5680E+OO 1.5680E+00 u-235 B< 4.1374E-01 4.1374E-01 M~-241 8< 2.2357E-01 2.2357E-Ol

  1. - All peaks for activity calculation had bad shape.

~ Activity omitted from total

&- Activity omitted from total and all peaks had bad shape.

< - MDA value printed.

A - Activity printed, but activity < MOA.

B - Activity < MDA and failed test.

C - Area < critical level.

F - Failed fraction or key line test.

H - Halflife limit exceeded A R Y Total Activity ( 38.8 to pCi/g Total Decayed Activity ( O.OOOOOOOE+OO pci/g Analyzed by:

Reviewed by:

2GOB Laboratory: PBRF Page 4

  • PB08-00797 ORTEC g v - 1 (l087) npp32 page 1 PBRF sample description PB08-00797; SR99-008; PPH; RM4;\~~~~

spectrum Filename: z:\Lab\SAMPLE Acquisition information Start time: 13-Mar-2008 14:23:27 Live time: 300 Real time: 301 Dead time: 0.39 %

Detector TO: 2 Detector system

  1. 2 DETECTOR (#130)

Calibration Filename:

Dc p 250ml #73678-773 (MC130)Sept07 Energy Calibration Created: 13-Sep-2007 15:00:31 zero offset: 0.287 kev Gain: 0.251 kev/channel Quadratic: 2.324E-08 kev/channel A2 Efficiency calibration created: 13-Sep-2007 15:22:08 Type: polynomial uncertainty: 1. 626 %

coeffi ci ents : -0.256697 -4.334323 0.664302

-0.092291 0.005686 -0.000130 Library Files Main analysis library: plumbrk 01.1ib Library Match Width: 0.500 peak stripping: Library based Analysis parameters Analysis engine: npp32 G53w3.05 Start channel: 155 ( 39.27kev )

Stop channel: 8144 ( 2049.92kev) peak rejection level: 25.000%

peak search sensitivity: 3 sample size: 4.4440E+02 Activity scaling factor: 1.0000E+06/( 1.0000E+00* 4.4440E+02) 2.2502E+03 Detection limit method: Nureg 4.16 Random error: 1.0000000E+00 systematic error: 1. OOOOOOOE+OO Fraction Limit: 0.000%

Background width: best method (based on spectrum).

o page 1

ORTEC g v - i (1087) npp32 PB08-00797 G53w3.05 13-MAR-2008 14:29:02 Page 2 PBRF Spectrum name: PB08-00797.An1 Half lives decay limit: 12.000 Activity range factor: 2.000 Min. step backg. energy 0.000 corrections Status Comments Decay correct to date: YES 11-Mar-2008 08:22:00 Decay during acquisition: NO Decay during collection: NO True coincidence correction: NO Peaked background correction: NO Absorption (Internal): NO Geometry correction: NO Random summing: NO Energy calibration Normalized diff: 0.0999 SUM MAR Y 0 F PEA K S I N RAN G E *****

Peak Area Uncert FWHM Corrctn Nuclide Brnch. Act. NUc Energy Factor Energy Ratio pci/g 186.14 45. 23.92 0.33 6.693E-02 186.21 3.590 3.825E+00 RA226 238.58 76. 13.86 1. 01 5.760E-02 238.63 43.300 6.178E-01 PB212 351.88 53. 19.31 0.68 4.242E-02 351.93 37.600 6.780E-01 PB214 609.62 42. 15.43 1. 26 2.665E-02 609.31 46.100 6.930E-01 BI214 661.70 77. 12.45 0.59 2.492E-02 661.66 85.100 7.329E-01 CS137 1173 .15 25. 20.00 0.34 1. 604E-02 1173 .24 99.974 3.164E-01 c060 1331.67 17. 24.25 0.25 1. 459E-02 1332.50 99.986 2.364E-Ol c060 1460.75 91. 10.48 0.67 1. 362E-02 1460.83 11.000 1.231E+01 K40 No unknown peaks passed sensitivity test.

This section based on library: plumbrk 01.lib

                            • IDE N T I FIE D PEA K SUM MAR Y **************

Nuclide Peak Centroid Background Net Area Intensity Uncert FWHM Channel Energy Counts Counts Cts/Sec 2 sigma % key AM-241 0.00 59.54 O. O. 0.000 0.00 0.000 TH-234 0.00 63.29 O. O. 0.000 0.00 0.000 TH-234 0.00 92.59 O. O. 0.000 0.00 0.000 EU-152 0.00 121.78 O. O. 0.000 0.00 0.000 EU-154 0.00 123.07 O. O. 0.000 0.00 0.000 u-235 0.00 143.76 O. O. 0.000 0.00 0.000 u-235 0.00 185.71 O. O. 0.000 0.00 0.000 RA-226 738.96 186.14 17. 45. 0.151 47.83 0.329s PB-212 947.48 238.58 10. 76. 0.253 27.73 LOBs EU-152 0.00 344.28 O. O. 0.000 0.00 0.000 PB-214 1397.90 351.88 13. 53. 0.178 38.63 0.682s o

ORTEC g v - (1087) npp32 G53W3.05 13-MAR-2008 14:29:02 page 3 PBRF spectrum name: PB08-00797.An1 Nuclide Channel Energy Background Net area Cnts/sec Uncert FWHM Ag-108m 0.00 433.94 O. O. 0.000 0.00 0.000 BI - 214 2422 . 38 609.62 O. 42. 0.140 30.86 1. 258 Ag-108m 0.00 614.28 O. O. 0.000 0.00 0.000 Page 2

c5-13 7 2629.41 661.70 3.

PB08-00797

77. 0.256
  • 24.90 0.591s Ag-108m 0.00 722.91 O. O. 0.000 0.00 0.000 EU-154 0.00 723.30 O. O. 0.000 0.00 0.000 81-212 0.00 727.33 O. O. 0.000 0.00 0.000 EU-154 0.00 1004.72 O. O. 0.000 0.00 0.000 co-60 4661. 74 1173.15 O. 25. 0.083 40.00 0.340s EU-154 0.00 1274.44 O. O. 0.000 0.00 0.000 co-60 5291. 50 1331.67 O. 17. 0.057 48.51 0.252s EU-152 0.00 1408.01 O. O. 0.000 0.00 0.000 K-40 5804.26 1460.75 O. 91. 0.303 20.97 0.673s s - Peak fails shape tests.

D - Peak area deconvoluted.

A Derived peak area.

oJ * ..L .J~ ..J# oJ.

S U M MAR Y 0 F L I B RA RY P EA K U S A GE -h-t,."'!.**

- Nuclide - Ave~a~e ------------- Peak - - - - - - - - - - - - -

Name Code ActlVlty Energy Activity Code MDA value pci/g kev pci/g pci/g COMMENTS K-40 N 1.2311E+01 1460.83 1,231E+01?( 9.971E-01 10.48 G K co-60 F 2.7640E-01 1332.50 2.364E-O(';J 1.025E-01 24.25 G K 1173.24 3.164E-0~ 9.327E-02 20.00 G K cs-137 I 7.3295E-01 661.667.329E-01 ( 1.072E-01 12.45 G K PB-212 N 6.1776E-01 238.63 6.178E-01 *( 1.418E-01 13.86 G K PB-214 N 6.7796E-01 351.93 6.780E-01 ( 2.453E-01 19.31 G K B1 - 214 N 6.9298E-01 609.31 6.930E-01 ( 1.216E-01 15.43 G K 1764.49 O.OOOE+OO % 8.220E-01 50.00 G 1120.29 O.OOOE+OO % 5;961E-01 26.73 G RA-226 N 3.8248E+OO 186.21 3.825E+00 ( 1.834E+00 23,92 G K ORTEC g v - 1 (1087) npp32 G53w3.05 13-MAR-2008 14:29:02 page 4 PBRF Spectrum name: PB08-00797.An1

( - This peak used in the nuclide activity average.

peak is too wide, but only one peak in library.

- peak is part of a multiplet and this area went negative during deconvolution.

? - peak is too narrow.

@ - peak is too wide at FW25M, but ok at FWHM.

% - Peak fails sensitivity test.

$ - peak identified, but first peak of this nuclide failed one or more qualification tests.

+ - peak actlvlty hlgher than coun~lng uncert~lnty range.

- - peak activlty lower than countlng uncertalnty range.

peak outslde analysis energy range.

Page 3

  • PB08-00797

& - Calculated peak centroid is not close enough to the library energy centroid for positive identlfication.

P - peakbackground subtraction

} Peak is too close to another for the activity to be found directly.

Nuclide Codes: Peak Codes:

T - Thermal Neutron Activation G - Gamma Ray F - Fast Neutron Activation X - X-Ray I - Fission product P - Positron Decay N - Naturally occurring Isotope S - Single-Escape P - Photon Reaction 0 - Double-Escape C - charged particle Reaction K - Key Line M - No MDA calculation A - Not in Average R - Coincidence Corrected C - Coincidence Peak H - Halflife 1i mi t exceeded

          • SUM MAR Y 0 F NUC L I DE S I N S AMP L E .J. oJ. J * .J * .J.

Time of Count Time COf'rected uncertainty 2 sigma Nuclide Activity Activity counting Total MDA pci/g pci/g pci/g pci/g K-40 1.2311E+01 1.2311E+01 2.5811E+00 2.6108E+00 9.971E-01 co-60 2.7618E-01 2.7640E-01 8.6891E-02 8.7338E-02 1. 024E-01

~ Ag-108 4.6802E-02 4.6802E-02 cs-137 7.3284E-01 7.3295E-01 1. 8251E-01 1. 8400E-01 1. 072E-01 EU-152 B< 1,8271E-01 1. 8277E-01 EU-154 B< 1. 4495E-01 1. 4502E-01 PB-212 & 6.1776E-01 6.1776E-01 1. 7128E-01 1. 7202E-01 1.418E-01 PB-214 ~

6.7796E-01 6.7796E-01 2.6189E-01 2.6278E-01 2.453E-01 BI-212 _.B< 1.6534E+00 1.6534E+00 BI-214 6.9297E-01 6.9298E-01 2.1386E-01 2.1531E-01 1. 216E-01

". 3.8248E+00 3.8248E+00 1. 8295 E+OO 1.8743E+00 1.834E+00 RA-226 TH-234 B< 1. 8569E+00 1. 8569E+00 u-235 B< 3.8817E-01 3.8817E-01 AM-241 B< 1.9880E-01 1.9880E-01 0

ORTEC g v - 1 (1087) npp32 G53w3.05 13-MAR-2008 14:29:02 Page 5 PBRF Spectrum name: PB08-00797.An1

  1. - All peaks for activity calculation had bad shape.

h Activity omitted from total

& - Activity omitted from total and all peaks had bad shape.

< - MDA value printed.

A - Activity printed, but actlvlty < MDA.

B - Activity < MDA and failed test.

C - Area < critical level.

F - Failed fraction or key line test.

H - Halflife limit exceeded

SUM MAR Y ---------------------------

Total Activity ( 39.3 to 2049.9 kev) 1.0090208E+00 pCi/g Total Decayed Activity ( 39.3 to 2049.9 kev) 1.0093489E+00 pci/g Analyzed by: A PBRF D sioning projef1AR M 1 3 2008 Reviewed by:

R. CaSA Page 4

  • PB08-00797 Laboratory: PBRF Page 5
  • PB08-01083 ORTEC g v - (1087) npp32 G53w3.05 26-MAR-2008 16:42:13 Page 1 PBRF Spectrum name: PB08-01083.An1 sample description PB08-01083; SR99-15; PPH-RM4; FD-4-3B; 3/26/08 spectrum Filename: z:\Lab\SAMPLE 08\PB08-01083.An1 Acquisition information Start time: 26-Mar-2008 16:27:02 Live time: 300 Real time: 302 Dead time: 0.69 %

Detector TO: 1 Detector system

  1. 1 DETECTOR (#129)

[] COpy Calibration Filename:

250ml #73678-773 (MC129) Jan08 Energy calibration Created: 09-Jan-2008 08:36:01 Zero offset: -0.051 kev Gain: 0.250 kev/channel Quadratic: -8.299E-09 kev/channelA2 Efficiency Calibration created: 09-Jan-200809:15:56 Type: Polynomial uncertainty: 1. 663 %

Coefficients: -0.338084 -4.099654 0.610757

-0.082467 0.004895 -0.000109 Library Files Main analysis library: plumbrk 01.lib Library Match Width: 0.500.

Peak stripping: Library based Analysis parameters Analysis engine: npp32 G53W3.05 Start channel: 155 ( 38.73kev)

Stop channel: 8144 ( 2037.21kev) peak rejection level: 25.000%

Peak search sensitivity: 3 sample size: 4.4360E+02 Activity scaling factor: 1.0000E+06/( 1.0000E+00* 4.4360E+02) 2.2543E+03 Detection limit method: Nureg 4.16 Random error: 1.0000000E+00 systematic error: 1.0000000E+00 Fraction Limit: 0.000%

Background width: best method (based on spectrum).

o Page 1

ORTEC g v - i (10S7) npp32 PB08-01083 G53w3.05 26-MAR-2008 16:42:13 Page 2 PBRF Spectrum name: PB08-01083.An1 Half lives decay limit: 12.000 Activity range factor: 2.000 Min. step backg. energy 0.000 Corrections Status Comments Decay correct to date: YES 18-Mar-2008 15:30:00 Decay during acquisition: NO Decay during collection: NO True coincidence correction: NO Peaked background correction: NO Absorption (Internal): NO Geometry correction: NO

. Random summing: NO Energy Calibration Normalized diff: 0.0443 SUM MAR Y 0 F PEA K S I N RAN G E Peak Area uncert FWHM Corrctn Nuclide Brnch. Act. NuC Energy Factor Energy Ratio pCi/g 238.62 74. 14.50 0.45 6.441E-02 238.63 43.300 5.388E-01 PB212 351.81 57. 15.79 1. 07 4.765E-02 351.93 37.600 6.461E-01 PB214 609,26 49. 14.29 1. 24 3.006E-02 609.31 46.100 7.181E-0l BI214 1460.79 116. 9.28 0.76 1.481E-02 1460.83 11.000 1.446E+01 K40 No unknown peaks passed sensitivity test.

This section based on library: plumbrk 01.lib

                            • IDE N T I FIE D PEA K SUM MAR Y **************

Nuclide peak centroid Background Net Area Intensity Uncert FWHM Channel Energy Counts Counts Cts/sec 2 sigma % kev AM-241 0.00 59.54 O. O. 0.000 0.00 0.000 TH-234 0.00 63.29 o. o. 0.000 0.00 0.000 TH-234 0.00 92.59 O. O. 0.000 0.00 0.000 EU-152 0.00 121.78 O. O. 0.000 0.00 0.000 EU-154 0.00 123.07 O. O. 0.000 0.00 0.000 U-235 0.00 143.76 O. O. 0.000 0.00 0.000 u-235 0.00 185.71 O. O. 0.000 0.00 0.000 RA-226 0.00 186.21 O. O. 0.000 0.00 0.000 PB-212 953.86 238.62 13. 74. 0.247 29.00 0.448s EU-152 0.00 344.28 O. O. 0.000 0.00 0.000 PB-214 1406.28 351.81 6. 57. 0.190 31. 58 1. 066 Ag-108m 0.00 433.94 O. O. 0.000 0.00 0.000 BI-214 2435.29 609.26 O. 49. 0.163 28.57 1. 241 Ag-108m 0.00 614.28 O. O. 0.000 0.00 0.000 cs-137 0.00 661.66 O. O. 0.000 0.00 0.000 o

ORTEC g v - (1087) npp32 G53w3.05 26-MAR-2008 16:42:13 page 3 PBRF spectrum name: PBOS-01083.An1 Nuclide channel Energy Background Net area Cnts/sec Uncert FWHM Ag-108m 0.00 722.91 O. O. 0.000 0.00 0.000 EU-154 0.00 723.30 O. O. 0.000 0.00 0.000 BI-212 0.00 727.33 O. o. 0.000 0.00 0.000 page 2

EU-154 0.00 1004.72

  • O.

PB08-01083 O. 0.000

  • 0.00 0.000 co-60 0.00 1173.24 O. O. 0.000 0.00 0.000 EU-154 0.00 1274.44 O. O. 0.000 0.00 0.000 co-60 0.00 1332.50 O. O. 0.000 0.00 0.000 EU-152 0.00 1408.01 O. O. 0.000 0.00 0.000 K-40 5839.29 1460.79 O. 116. 0.387 18.57 0.765s s - peak fails shape tests.

D - Peak area deconvoluted.

A Derived peak area.

S U M MAR Y o F LIB R A R Y PEA K USA G E

- Nuclide Ave~age ------------- Peak Name Code ActlVlty Energy Activity code MDA value pci/g kev pci/g pCi/g COMMENTS K-40 N 1. 4462E+Ol 1460.83 1.446E+01 ---:"---=--.:...,~=-=---=-==-----_::....:....:=-=---=-.:..:.----------

( 9.189E-Ol 9.28 G K PB-212 N 5.3885E-Ol 238.63 5.388E-01 ( 1.421E-01 14.50 G K PB-214 N 6.4609E-Ol 351.93 6.461E-01 ( 1.601E-01 15.79 G K BI-214 N 7.1812E-01 609.31 7.181E-01 ( 1.080E-01 14.29 G K 1764.49 O.OOOE+OO % 8.118E-Ol 183.33 G 1120.29 O.OOOE+OO % 5.388E-01 25.82 G

( - This peak used in the nuclide activity average.

" peak is too wide, but only one peak in library.

- Peak is part of a multiplet and this area went negative during deconvolution.

? - peak is too narrow.

@ peak is too wide at FW25M, but ok at FWHM.

% peak fails sensitivity test.

$ - peak identified, but first peak of this nuclide failed one or more qualification tests.

+ - peak activity higher than counting uncertainty range.

- - peak activity lower than counting uncertainty range.

- peak outside analysis energy range.

& - calculated peak centroid is not close enough to the library energy centroid for positive identlfication.

ORTEC g v - i (1087) npp32 G53w3.05 26-MAR-2008 16:42:13 page 4 PBRF Spectrum name: PB08-01083.Anl P - peakbackground subtraction

} - Peak is too close to another for the activity to be found directly.

Nuclide codes: Peak codes:

T Thermal Neutron Activation G - Gamma Ray F Fast Neutron Activation X - X-Ray I Fission Product P - positron Decay N Naturally occurring Isotope 5 - single-Escape P photon Reaction D - Double-Escape C charged particle Reaction oK - Key Line M NO MDA calculation A - Not in Average page 3

R - Coincidence Corrected

  • PB08-01083 C - Coincidence Peak H - Halflife limit exceeded SUM MAR Y o F N U eLI DES I N SAM P L E Time of Count Time Corrected uncertainty 2 Sigma Nuclide Activity Activity Counting Total MDA pci/g pci/g pci/g pci/g K-40 ". 1. 4462E+01 1.4462E+01 2.6856E+00 2.7256E+00 9.189E-01 eo-60 B< 9.3659E-02 9.3930E-02 Ag-108mB< 5.2525E-02 5.2527E-02 e5-137 B< 6.2613E-02 6.2644E-02 EU-152 B< 1.1639E-01 1.1652E-01 EU-154 B< 1. 5062E-01 1.5089E-01 PB-212 "' 5.3885E-01 5.3885E-01 1. 5629E-01 1.5691E-01 1.421E-01 PB-214 ". 6.4608E-01 6.4609E-01 2.0403E-01 2.0509E-01 1.601E-01 BI-212 B< 8.7465E-01 8.7465E-01 BI-214 '1( - - 7 :-lbT1F\Y:'- -rTIIT2E="U-'

RA-226 B< 2.4956E+OO 2.4957E+OO TH-234 B< 1.6156E+00 1.6156E+00 u-235 B< 3.071lE-01 3.0711E-01 AM-241 B< 2.1461E-01 2.1461E-0l

  1. - All peaks for activity calculation had bad shape.

. Activitv omitted from total

& - Activity omitted from total and all peaks had bad shape.

< - MDA value printed, A - Activity printed, butactlvlty < MDA.

B - Activity < MDA and failed test.

e - Area < critical level.

F - Failed fraction or key line test.

H - Halflife limit exceeded

SUM MAR Y ---------------------------

Total Activity ( 38.7 to 2037.2 kev) O.OOOOOOOE+OO pci/g Total Decayed Activity ( 38.7 to 2037.2 kev) O.OOOOOOOE+OO pCi/g Analyzed by: A,"

project Reviewed by: ~AR l A. Case o

ORTEe 9 v - (1087) npp32 G53w3.05 26-MAR-2008 16:42:13 Page 5 PBRF spectrum name: PB08-01083.An1 Laboratory: PBRF page 4

  • PB08-01283 ORTEC g v - i (1087) npp32 G53w3.05 15-APR-2008 15:50:44 Page 1 PBRF Spectrum name: PB08-01283.An1 sample description PB08-01283; SR99-56; PPH - RM8 - FD8-1; 4/15/08 spectrum Filename: z:\Lab\SAMPLE 08\PB08-01283.An1 Acquisition information Start time: 15-Apr-2008 15:41:43 Live time: 300 Real time:

Dead time:

Detect-o r 10:

301 0.17 %

[J COpy Detector system

  1. 3 DETECTOR (#131)

Calibration Filename:

2S0ml #73678-773 (MC131) Sept07 Energy Calibration Created: 05-Sep-2007 16:56:38 Zero offset: 0.565 kev Gain: 0.247 kev/channel Quadratic: 5.022E-08 kev/channel A2 Efficiency Calibration Created: 05-sep-2007 17:17:39 Type: Po 1ynomi a1 uncertainty: 1. 204 %

coefficients: -0.304311 -4.249899 0.669559

-0.094002 0.005803 -0.000133 Library Files Main analysis library: pl umbrk 01.1 i b Library Match Width: 0.500 Peak stripping: Library based Analysis parameters Analysis engine: npp32 G53w3.05 Start channel: 155 ( 38.83kev )

Stop channel: 8144 ( 2014.22kev)

Peak rejection level: 25.000%

Peak search sensitivity: 3 sample Size: 4.8520E+02 Activity scaling factor: 1.0000E+06/( 1.0000E+00* 4.8520E+02) 2.0610E+03 Detection limit method: Nureg 4.16 Random error: 1.0000000E+00 Systematic error: 1. OOOOOOOE+OO Fraction Limit: 0.000%

Background width: best method (based on spectrum).

o page 1

ORTEC g v - i (1087) npp32

  • PB08-01283 G53w3.05 15-APR-2008 15:50:44 Page 2 PBRF spectrum name: PB08-01283.An1 Half lives decay limit: 12.000 Activity range factor: 2.000 Min. step backg. energy 0.000 corrections Status Comments Decay correct to date: YES 14-Apr-2008 11:23:00 Decay during acquisition: NO Decay during collection: NO True coincidence correction: NO peaked background correction: NO Absorption (Internal): NO Geometry correction: NO Random summing: NO Energy Calibration Normalized diff: 0.2766

'1~*"'1: 1: 1:

S U MMA R Y 0 F P EAK S I N RANGE 1:1:**1,"

peak Area uncert FWHM Corrctn Nuclide Brnch. Act. NUc Energy Facto r Energy Ratio pcijg 77.24 44. 24.24 0.92 8.258E-02 238.69 80. 13.81 0.99 6.195E-02 238.63 43.300 5.537E-01 PB212 351. 94 57. 19.85 0.59 4.555E-02 351. 93 37.600 6.216E-01 PB214 609.06 51. 14.00 0.88 2.830E-02 609.31 46.100 7.259E-01 BI214 1460.23 127. 8.87 1. 39 1. 387E-02 1460.83 11.000 1.546E+01 K40

  • 1; 1: 1: i: "1: 1: 1: "/,'1:"/:
  • UNI D ENT T J.. F I ED P EA K S U M M A R Y 1,- 1: "1.: '1: 1: * -/: -;. * -1.

1~ ~.

Peak Centroid Background Net Area Intensity Uncert FWHM suspected channel Energy Counts Counts CtsjSec 2 Sigma % kev Nuclide 310.61 77.24 27. 44. 0.148 48.47 0.924 M s - peak fails shape tests.

D - Peak area deconvoluted.

L - peak written from unknown list.

C - Area < Critical level.

M - Peak is close to a library peak.

This section based on library: plumbrk OI.lib o

ORTEC g v - i (1087) npp32 G53w3.05 15-APR-2008 15:50:44 page 3 PBRF spectrum name: PB08-01283.An1 1: 1: 1: "* 1: 1: 1: 1: 7. 1: 1; 1: * -/: I D E N T I F I E D P E A K S U M M A R Y -:: -t: '* * "'1: "* * -:. -1:

  • 1.. 1: 1: -1:

Nuclide peak centroid Background Net Area Intensity Uncert FWHM channel Energy Counts Counts ctsjsec L.... sigma % kev AM-241 0.00 59.54 O. O. 0.000 0.00 0.000 TH-234 0.00 63.29 O. O. 0.000 0.00 0.000 TH-234 0.00 92.59 O. O. 0.000 0.00 0.000 EU-152 0.00 121. 78 O. O. 0.000 0.00 0.000 EU-154 0.00 123.07 O. O. 0.000 0.00 0.000 u-235 0.00 143.76 O. O. 0.000 0.00 0.000 Page 2

u-235 0.00 185.71

  • O.

PB08-01283 O. 0.000

  • 0.00 0.000 PB-212 964.47 238.69 14. 80. 0.267 27.61 0.994 EU-152 0.00 344.28 O. O. 0.000 0.00 0.000 PB-214 1423.03 351. 94 17. 57. 0.191 39.71 0.5895 Ag-108m 0.00 433.94 O. o. 0.000 0.00 0.000 BI-214 2463.81 609.06 O. 51. 0.170 28.01 0.8755 Ag-108m 0.00 614.28 O. O. 0.000 0.00 0.000 cs-137 2675.78 661. 43 4. 24. 0.080 50.00' 1.026s' Ag-108m 0.00 722.91 O. O. 0.000 0.00 0.000 EU-154 0.00 723.30 O. O. 0.000 0.00 0.000 BI-212 0.00 727.33 O. O. 0.000 0.00 0.000 EU-154 0.00 1004.72 O. O. 0.000 0.00 0.000 co-60 0.00 1173.24 O. O. 0.000 0.00 0.000 EU-154 0.00 1274.44 O. O. 0.000 0.00 0.000 co-60 0.00 1332. SO O. O. 0.000 0.00 0.000 EU-152 0.00 1408.01 O. O. 0.000 0.00 0.000 K-40 5906.14 1460.23 O. 127. 0.423 .---1-7--.--1--5--1---.---3-945- .

s - Peak fails shape tests.

D - Peak area deconvoluted.

A Derived peak area,

- Nuclide - Ave~age ------------- Peak -------------

Name Code Actlvlty Energy Activity Code MDA value pci/g kev pci/g pci/g COMMENTS K-40 N 1. 5460E+Ol ,.

1460.83 1.546E+01 \.. 8.972E-01 8.87 G K CS-137 I 1.9842E-01 661.66 1. 984E-OG 9.946E-02 25.00 G K PB-212 N 5.5367E-01 238.63 5.537E-01 ?( 1. 394E-Ol 13.81 G K 0

ORTEC 9 v - 1 (1087) npp32 G53w3.05 15-APR-2008 15:50:44 page 4 PBRF spectrum name: PB08-01283.An1 Nuclide Ave activity Energy Activity code Peak MDA Comments PB-214 N 6.2157E-01 351.93 6.216E-Ol ?( 2.356E-Ol 19.85 G K BI-214 N 7.2588E-01 609.31 7.259E-01?( 1.049E-01 14.00 G K 1764.49 O.OOOE+OO % 7.507E-Ol 111.80 G 1120.29 O.OOOE+OO % 8.179E-01 95.12 G

( - This peak used in the nuclide activity average.

- - Peak is too wide, but only one peak in library.

- Peak is part of a multiplet and this area went negative during deconvolution.

? - Peak is too narrow.

@ - Peak is too wide at FW25M, but ok at FWHM.

% - Peak fails sensitivity test.

$ - Peak identified, but first peak of this nuclide failed one or more qualification tests.

+ - Peak activity higher than coun~ing uncert~inty range.

- - Peak activity lower than countlng uncertalnty range.

Page 3

- peak outside analysis energy range.

PB08-01283

& - Calculated peak centroid is not close enough to the library energy centroid for positive identlfication.

P - peakbackground subtraction

} Peak is too close to another for the activity to be found directly.

Nuclide Codes: Peak Codes:

T - Thermal Neutron Activation G - Gamma Ray F - Fast Neutron Activation X - X-Ray I - Fission Product P - Positron Decay N - Naturally occurring Isotope S - single-Escape P - Photon Reaction D - Double-Escape C - Charged particle Reaction K - Key Line M - No MDA Calculation A - Not in Average R - Coincidence Corrected C - Coincidence Peak H - Halfl ife 1 i mi t exceeded oJ **h~. oJ * .J#

S U MMA R y 0 F NUC L I n E S

!J I N S A r.1 P L E -t;.J,....~.**

Time of Count Time Corrected uncertainty 2 sigma Nuclide Activity Activity Counting Total MDA pci/g pci/g pci/g pci/g K-40 .c

1. 5460E+01 1.5460E+01 2.7438E+00 2.7810E+00 8.972E-01 co-60 B< 9.1584E-02 9.1623E-02 Ag -108Jlf1R' 5.3398E-02 5.3398E-02

. /CS-1W 1. 9841E-01 1. 9842E-01 9.9212E-02 9.9382E-02 9,945E-02 JO EU-b < 1.4040E-01 1.4042E-01 I EU-154 B< 1. 1376E-01 1. 1379E-01 0

ORTEC g v - i (l087) npp32 G53w3.05 15-APR-2008 15:50:44 Page 5 PBRF Spectrum name: PB08-01283.An1 PB-212 & 5.5367E-01 5.5367E-01 1. 5289E-01 1. 5356E-01 1.394E-01 PB-214 & 6.2156E-01 6.2157E-01 2.4680E-01 2.4747E-01 2.356E-01 BI-212 B< 1. 0046E+00 1. 0046E+00 BI-214 & 7.2588E-01 7.2588E-01 2.0329E-01 2.0475E-01 1.049E-01 RA-226 B< 1.4202E+00 1. 4202E+00 TH-234 B< 1. 6149E+00 1. 6149E+00 u-235 B< 4.9162E-01 4.9162E-01 AM-241 B< 1.8240E-01 1. 8240E-01

  1. - All peaks for activity calculation had bad shape.

" Activity omitted from total

&- Activity omitted from total and all peaks had bad shape.

< - MDA value printed.

A - Activity printed, but activity < MDA.

B - Activity < MDA and failed test.

C - Area < Critical level.

F - Failed fraction or key line test.

H - Halflife limit exceeded

SUM MAR Y ---------------------------

Total Activity ( 38.8 to 2014.2 keY) 1.9840866E-01 pci/g Total Decayed Activity ( I 38.8 to 2014.2 keY) 1.9842345E-01 pci/g Analyzed by: y.

Reviewed by:

Supervisor PB08-01283 Laboratory: PBRF page 5

  • PB08-01284 ORTEC g v - i (1087) npp32 G53w3.05 15-APR-2008 15:54:45 Page 1 PBRF Spectrum name: PB08-01284.An1 sample description PB08-01284; SR99-57; PPH RM8 - FD8-2; 4/15/08 spectrum Filename: z:\Lab\SAMPLE 08\PB08-01284.An1 Acquisition information Start time: 15-Apr-2008 15:48:59 Live time: 300 Real time: 302 Dead time: 0.60 %

Detector IO: 1 Detector system

  1. 1 DETECTOR (#129) calibration Filename:

250ml #73678-773 (MC129) Jan08 Energy Calibration created: 09-Jan-2008 08:36:01 zero offset: -0.051 kev Gain: 0.250 kev/channel Quadratic: -8.299E-09 kev/channel A2 Efficiency Calibration Created: 09-Jan-2008 09:15:56 Type: polynomial uncertainty: 1. 663 %

coeffi ci ents: -0.338084 -4.099654 0.610757

-0.082467 0.004895 -0.000109 Library Files Main analysis library: plumbrk 01.lib Library Match width: 0.500 Peak stripping; Library based Analysis parameters Analysis engine: npp32 G53w3.05 Start channel: 155 ( 38.73kev)

Stop channel: 8144 ( 2037.21kev)

Peak rejection level: 25.000%

Peak search sensitivity: 3 sample Size: 5.0470E+02 Activity scaling factor: 1.0000E+06/( 1.0000E+00* 5.0470E+02) =

L 9814E+03 Detection limit method: Nureg 4.16 Random error; 1.0000000E+00 systematic error: 1.0000000E+00 Fraction Limit: 0.000%

Background width: best method (based on spectrum).

o page 1

ORTEC g v - i (1087) npp32

  • PB08-01284 G53w3.05 15-APR-2008 15:54:45 page 2 PBRF Spectrum name: PB08-01284.An1 Half lives decay limit: 12.000 Activity range factor: 2.000 Min. step backg. energy 0.000 Corrections Status Comments Decay correct to date: YES 14-Apr-2008 11:14:00 Decay during acquisition: NO Decay during collection: NO True coincidence correction: NO peaked background correction: NO Absorption (Internal): NO Geometry correction: NO Random summing: NO Energy calibration Normalized diff: 0.1373 SUM MAR Y 0 F PEA K S I N RAN G E peak Area Uncert FWHM Corrctn Nuclide Brnch. Act. Nuc Energy Factor Energy Ratio pci/g 74.77 45. 21. 06 0.82 8.366E-02 77.26 56. 18.22 0.82 8.392E-02 238.46 57. 16.36 0.42 6.444E-02 238.63 43.300 3.648E-01 PB212 294.94 36. 18.74 0.80 5.501E-02 351.92 72. 11.79 1.33 4.765E-02 351. 93 37.600 7.173E-01 ps214 608.97 38. 16.22 0.83 3.006E-02 609.31 46.100 4.895E-01 BI214 1120.08 18. 23.57 0.50 1. 840E-02 1120.29 15.100 1.157E+00 BI214 1460.79 97. 10.15 0.60 1. 481E-02 1460.83 11.000 1.063E+01 K40
                        • U N IDE N T I FIE D PEA K SUM MAR Y peak Centroid Background Net Area Intensity Uncert FWHM suspected Channel Energy Counts Counts Cts/sec 2 sigma % kev Nuclide 299.02 74.86 23. 45. 0.151 42.12 0.820 PB-214 D 308.99 77.36 23. 56. 0.185 36.44 0.823 PB-214 D 1178.97 294.94 2. 36. 0.118 37.48 0.798 PB-214 M s - Peak fails shape tests.

D - Peak area deconvoluted.

L - peak written from unknown list.

C - Area < Critical level.

M - peak is close to a library peak.

This section based on library: plumbrk 01.1ib o

ORTEC g v - 1 (l087) npp32 G53w3. as 15-APR-2008 15: 54: 45 Page 3 PBRF spectrum name: PB08-01284.Anl

  • "i. 1.
  • of; * * "1: * "1: * * '1: 7-, I D E N T I F I E D P EA K S U M M A R Y * ;( ;: * "1, "1: * * * "'1. * -/: "1, "'1.

Nuclide peak Centroid Background Net Area Intensity Uncert FWHM channe 1 Energy Counts Counts Cts/sec 2 sigma % kev AM-241 0.00 59.54 O. O. 0.000 0.00 0.000 page 2

TH-234 0.00 63.29

  • O.

PB08-01284 O. 0.000

  • 0.00 0.000 TH-234 0.00 92.59 O. O. 0.000 0.00 0.000 EU-152 0.00 121. 78 O. O. 0.000 0.00 0.000 EU-154 0.00 123.07 O. O. 0.000 0.00 0.000 u-235 0.00 143.76 O. O. 0.000 0.00 0.000 u-235 0.00 185.71 O. O. 0.000 0.00 0.000.

RA-226 0.00 186.21 O. O. 0.000 0.00 0.000 PB-212 953.25 238.46 10. 57. 0.190 32.73 0.421s EU-152 0.00 344.28 O. O. 0.000 0.00 0.000 PB-214 1406.71 351.92 O. 72. 0.240 23.57 1.334s Ag-108m 0.00 433.94 O. O. 0.000 0.00 0.000 BI-214 2434.11 608.97 O. 38. 0.127 32.44 0.834s Ag-108m 0.00 614.28 O. O. 0.000 0.00 0.000 cs-137 0.00 661.66 O. O. 0.000 0.00 0.000 Ag-108m 0.00 722.91 O. O. 0.000 0.00 0.000 EU-154 0.00 723.30 O. O. 0.000 0.00 0.000 6I-212 o 00 727 33 0 0 a 000 a 00 o 000 EU-154 0.00 1004.72 O. O. 0.000 0.00 0.000 BI-214 4477.22 1120.08 O. 18. 0.060 47.14 0.500s co-60 0.00 1173.24 O. O. 0.000 0.00 0.000 EU-154 0.00 1274.44 r.

v. O. 0.000 0.00 0.000 co-60 0.00 1332.50 O. O. 0.000 0.00 0.000 EU-152 0.00 1408.01 O. O. 0.000 0.00 0.000 K-40 5839.32 1460.79 O. 97. 0.323 20.31 0.597s s - peak fails shape tests.

D - peak area deconvoluted.

A Derived peak area.

~~~~~ SUM MAR Y o F LIB R A R Y PEA K USA G E

- Nuclide - Ave~age ------------- Peak -------------

Name 'Code Actl Vl ty Energy Activity Code MDA value pci/g kev pci/g pCi/g COMMENTS K-40 N 1.0629E+01 1460.83 1. 063E+01 ( 8.076E-01 10.15 G K PB-212 N 3.6481E-01 238.63 3.648E-01 ?( 1. 117E-01 16.36 G K PB-214 N 7.1731E-01 351.93 7.173E-01 @( 7.342E-02 1l.79GK 0

ORTEC g v - 1 (l087) npp32 G53w3.05 15-APR-2008 15:54:45 Page 4 PBRF Spectrum name: PB08-01284.An1 Nuclide Ave activity Energy Activity code Peak MDA Comments BI-214 N 4.8948E-01 609.31 4.895E-01 ( 9.493E-02 16.22 G  !(

1764.49 O.OOOE+OO % 6.791E-01 30.15 G 1120.29 1.157E+00 + 4.736E-01 23.57 G

( - This peak used in the nuclide activity average.

~ Peak is too wide, but only one peak in library.

- Peak is part of a multiplet and this area went negative during deconvolution.

? - peak is too narrow.

@ - peak is too wide at FW25M, but ok at FWHM.

% - Peak fails sensitivity test.

Page 3

  • PB08-01284

$ - Peak identified, but first peak of this nuclide failed one or more qualification tests.

+ - Peak activity higher than counting uncertainty range.

- - Peak activity lower than counting uncertainty range.

- Peak outside analysis energy range.

& - calculated peak centroid is not close enough to the library energy centroid for positive identlfication.

P - peakbackground subtraction

} Peak is too close to another for the activity to be found directly.

Nuclide codes: Peak codes:

T - Thermal Neutron Activation G - Gamma Ray F - Fast Neutron Activation X - X-Ray I - Fission Product P - Positron Decay N Naturally occ~rring Isotope S - single-Escape p - photon R@Eict;on 0 Double E!;Cape C - charged Particle Reaction K Key Line M - NO MDA calculation A - Not in Average R - Coincidence Corrected C - Coincidence Peak H - Halfl ife limit exceeded

          • SUM MAR Y o F N U C L I DES I N SAM P L E Time of Count Time Corrected uncertainty 2 sigma Nuclide Activity Activity counting Total iv1DA pci/g pci/g pci/g pci/g K-40 k 1. 0629E+01 1.0629E+01 2.1)85E+00 2.1854E+00 8.076E-01 co-60 B< 8.2320E-02 8.2356E-02 Ag-108mB< 3.6585E-02 3.6585E-02 cs-137 B< 5.5033E-02 5.5037E-02 EU-152 B< 1. 1230E-01 1.1232E-01 EU-154 B< 8.3781E-02 8.3803E-02 PB-212 & 3.6481E-01 3.6481E-01 1.1939E-01 1.1977E-01 1.117E-01 PB-214 & 7.1731E-01 7.1731E-0l 1. 6907E-01 1.7064E-01 7.342E-02 BI-212 B< 8.4396E-01 8.4396E-01 o

ORTEC g v - i (1087) npp32 G53w3.05 15-APR-2008 15:54:45 Page 5 PBRF spectrum name: PB08-01284.An1 81-214 . 4.8948E-01 4.8948E-0l 1. 5881E-0l 1.5979E-01 9.493E-02 RA-226 B< 1.6841E+00 1. 6841E+00 TH-234 B< 1. 4415E+00 1. 4415E+00 U-235 B< 4.6609E-01 4.6609E-01 AM-241 B< 1.6849E-01 1. 6849E-Ol

  1. - All peaks for activity calculation had bad shape .

.. - Activity omitted from total

& - Activity omitted from total and all peaks had bad shape.

< - MDA value printed.

A - Activity printed, but activity < MDA.

B - Activity < MDA and failed test.

C - Area < Critical level.

F - Failed fraction or key line test.

H - Halflife limit exceeded

_____________________________ SUM MAR Y ---------------------------

Total Activity ( 38.7 to 2037.2 keV) O.OOOOOOOE+OO pci/g Total Decayed Activity ( 38.7 to 2037.2 kev) O.OOOOOOOE+OO pci/g Page 4

  • 1 Analyzed by:

A~

  • P808-01284 Reviewed by:

Laboratory: PBRF R.~

page 5

  • PB08-01335 ORTEC g v - (1087) npp32 G53W3.05 21-APR-2008 17:12:45 Page 1 PBRF Spectrum name: PB08-01335.An1 sample description PB08-01335; SR99-81; PPH RM 8 HD8-1; 4/21/08 spectrum Filename: z:\Lab\SAMPLE 08\PB08-01335.An1 A~quisition information Start time: 21-Apr-2008 16:00:21 Live time: 300 Real time: 301 Dead time: 0.27 %

Detector ID: 3 Detector system

  1. 3 DETECTOR (#131)

[] COpy Calibration Filename:

2S0ml #73678-773 (MC131) Sept07 Energy Calibration Created: 05-Sep-2007 16:56:38 Zero offset: 0.565 kev Gain: 0.247 kev/channel Quadratic: 5.022E-08 kev/channel A2 Efficiency Calibration Created: 05-sep-2007 17:17:39 Type: polynomial uncertainty: 1. 204 %

Coefficients: -0.304311 -4.249899 0.669559

-0.094002 0.005803 -0.000133 Library Files Main analysis library: plumbrk 01.lib Library Match Width: 0.500 Peak stripping: Library based Analysis parameters Analysis engine: npp32 G53w3.05 Start channel: 155 ( 38.83kev )

Stop channel: 8144 ( 2014.22kev)

Peak rejection level: 25.000%

Peak search sensitivity: 3 sample Size: 4.6620E+02 Activity scaling factor: 1.0000E+06/( 1.0000E+00* 4.6620E+02) 2.1450E+03 Detection limit method: Nureg 4.16 Random error: 1.0000000E+00 systematic error: 1.0000000E+00 Fraction Limit: 0.000%

Background width: best method (based on spectrum).

o Page 1

ORTEC g v - i (l087) npp32 PB08-01335 G53w3.05 21-APR-2008 17:12:45 Page 2 PBRF Spectrum name: PB08-01335.An1 Half lives decay limit: 12.000 Activity range factor: 2.000 Min. step backg. energy 0.000 Corrections Status Comments Decay correct to date: YES 17-Apr-2008 08:34:00 Decay during acquisition: NO Decay during collection: NO True coincidence correction: NO peaked background correction: NO Absorption (Internal): NO Geometry correction: NO Random summing: NO Energy calibration Normalized diff: 0.0642 SUM MAR Y 0 F PEA K S I N RAN G E peak Area Uncert FWHM Corrctn Nuclide Brnch. Act. Nuc Energy Factor Energy Ratio pci/g 238.67 85. 14.31 1. 03 6.196E-02 238.63 43.300 6.123E-01 PB212 352.11 57. 14.81 1. 37 4.555E-02 351.93 37.600 6.394E-Ol PB214 609.28 56. 13.36 1. 34 2.830E-02 609.31 46.100 8.295E-01 81214 1460.99 138. 8.51 1. 45 1. 387E-02 1460.83 11.000 1. 748E+01 K40 NO unknown peaks passed sensitivity testo This section based on library: plumbrk 01.lib

                            • IDE N T I FIE D PEA K SUM MAR Y **************

Nuclide Peak Centroid Background Net Area Intensity Uncert FWHM channel Energy Counts Counts Cts/sec 2 sigma % keY AM-241 0.00 59.54 o. O. 0.000 0.00 0.000 TH-234 0.00 63.29 O. O. 0.000 0.00 0.000 TH-234 0.00 92.59 O. O. 0.000 0.00 0.000 EU-152 0.00 121. 78 O. O. 0.000 0.00 0.000 EU-154 0.00 123.07 O. O. 0.000 0.00 0.000 u-235 0.00 143.76 O. O. 0.000 0.00 0.000 u-235 0.00 185.71 O. o. 0.000 0.00 0.000 PB-212 964.39 238.67 14. 85. 0.283 28.62 1. 027 EU-152 0.00 344.28 O. O. 0.000 0.00 0.000 PB-214 1423.71 352.11 4. 57. 0.189 29.61 1.372 Ag-108m 0.00 433.94 O. O. 0.000 0.00 0.000 BI-214 2464.73 609.28 O. 56. 0.187 26.73 1. 338 Ag-108m 0.00 614.28 O. O. 0.000 0.00 0.000 cs-137 0.00 661. 66 O. O. 0.000 0.00 0.000 Ag-108m 0.00 722.91 O. O. 0.000 0.00 0.000 o

ORTEC g v - i (1087) npp32 G53w3.05 21-APR-2008 17:12:45 Page 3 PBRF spectrum name: PB08-01335.An1 Nuclide Channel Energy Background Net area Cnts/sec Uncert FWHM EU-154 0.00 723.30 O. O. 0.000 0.00 0.000 BI-212 0.00 727.33 O. O. 0.000 0.00 0.000 EU-154 0.00 1004.72 O. O. 0.000 0.00 0.000 page 2

co-60 0.00 1173.24

  • O.

PB08-01335 O. 0.000

  • 0.00 0.000 EU-154 0.00 1274.44 O. O. 0.000 0.00 0.000 co-60 0.00 1332.50 O. O. 0.000 0.00 0.000 EU-152 0.00 1408.01 O. O. 0.000 0.00 0.000 K-40 5909.21 1460.99 O. 138. 0.460 17.03 1. 454s s - Peak fails shape tests.

D - Peak area deconvoluted.

A Derived peak area.

1:1:1d:," S U M MAR Y o F LIB R A R Y PEA K USA G E

- Nuclide Ave~age ------------- peak Name code ActlVlty Energy Activity code MDA value pCi/g keV pCi/g pci/g COMMENTS K-40 N 1. 7484E+01 1460.83 1.748E+01 I( 9.338E-01 8.51GK PB-212 N 6.1225E-01 238.63 6.123E-01 ( 1.451E-01 14.31 G K PB-214 N 6.3938E-01 351.93 6.394E-01 ( 1.400E-01 14.81 G K 81-214 N 8.2953E-01 609.31 8.295E-Ol ( 1.092E-01 13.36 G K 1764.49 O.OOOE+OO % 7.813E-01 30.15 G 1120.29 O.OOOE~OO % 5.490E-01 40.82 G

( - This peak used ln the nuclide activity average.

peak is too wide, but only one peak in library.

- peak is part of a multiplet and this area went negative during deconvolution.

? - Peak is too narrow.

@ - Peak is too wide at FW25M, but ok at FWHM.

% - Peak fails sensitivity test.

$ - peak identified, but first peak of this nuclide failed one or more qualification tests.

+ - Peak activity higher than counting uncertainty range.

- Peak activity lower than counting uncertainty range.

- Peak outside analysis energy range.

& - calculated peak centroid is not close enough to the library energy centroid for positive identlfication.

P - peakbackground subtraction o

ORTEC g v - i (1087) npp32 G53w3.05 21-APR-2008 17:12:45 page 4 PBRF spectrum name: PB08-01335.Anl

} - Peak is too close to another for the activity to be found directly.

Nuclide Codes: peak codes:

T Thermal Neutron Activation G - Gamma Ray F Fast Neutron Activation X - X-Ray I Fission Product P - Positron Decay N Naturally occurring Isotope S - single-Escape P photon Reaction o - Double-Escape C charged particle Reaction K - Key Line M No MDA Calculation A - Not in Average R Coincidence corrected C - Coincidence Peak page 3

H - Halflife limit exceeded

  • PB08-01335

..J * .J * .J ...... .J.

S UMMA RY 0 F N UC L I 0 E S T

.L N S A MP L E .J * .J * .J* .J * .J.

Time of Count Time Correc'ted uncertainty 2 Sigma Nuclide Activity Activity Counting Total MDA pci/g pci/g pci/g pci/g K-40 & 1. 7484E+01 1. 7484E+01 2.9767E+00 3.0205E+00 9.338E-01 co-60 B< 9.5316E-02 9.5464E-02 Ag-108mB< 4.1674E-02 4.1674E-02 cs-137 B< 6.3411E-02 6. 3428E -02 EU-152 B< 1. 2712E-01 1. 2720E-01 EU-154 B< 1. 4340E-01 1.4353E-01 PB-212 .. 6.1225E-01 6.1225E-01 1.7526E-01 1.7597E-01 1.451E-01 PB-214 J.

6.3937E-01 6.3938E-01 1. 8933E-01 1.9025E-01 1.400E-01 81-212 B< 1. 1157E+00 1.1157E+00 81 - 214 J.

8.2952E-01 8.2953E-01 2.2170E-01 2.2345E-01 1.092E-01 RA-226 B< 1.5096E+00 1.5096E+00 TH-234 B< 1. 2364E+00 1. 2364E+00 u-235 B< 5.0761E-01 5.0761E-01 AM-241 B< 1.9806E-01 1.9806E-01

  1. - All peaks for activity calculation had bad shape.

.. Activity omitted from total

& - Activity omitted from total and all peaks had bad shape.

< - MDA value printed.

A - Actlvity printed, but actlvity < MDA.

B - Activity < MDA and failed test.

C - Area <- Critical 'level.

F Failed fraction or key line test.

H - Halflife limit exceeded

SUM MAR Y ---------------------------

Total Activity ( 38.8 to 2014.2 kev) O.OOOOOOOE+OO pci/g Total Decayed Activity ( 38.8 to 2014.2 kev) O.OOOOOOOE+OO pci/g Ana 1 yzed by: ----.::~=___.----=-~.C>l-..L..l.,..L!>-4~,..,e--:-:--------:----..,------

project Reviewed by: APR 2 2 200B supervisor R. Case Laboratory: PBRF Page 4

  • PB08-01280 ORTEC g v - 1 (l087) npp32 G53w3.05 15-APR-2008 15:49:44 Page 1 PBRF Spectrum name: PB08-01280.Anl sample description PB08-01280; SR99-54; PPH-RM8- HD8-2; 4/15/08 spectrum Filename: z:\Lab\SAMPLE 08\PB08-01280.Anl Acquisition information Start time: 15-Apr-2008 15:39:55 Live time: 300 Real time: 302 Dead time: 0.53 %

Detector ID: 2 Detector system

  1. 2 DETECTOR (#130) [j COpy Calibration Filename:

250ml #73678-773 (MC130)sept07 Energy Calibration created: 13-sep-2007 15:00:31 zero offset: 0.287 kev Gain: 0.251 kev/channel Quadratic: 2.324E-08 kev/channel A2 Efficiency Calibration created: 13-sep-2007 15:22:08 Type: polynomial uncertai nty: 1. 626 %

Coeffi ci ents: -0.256697 -4.334323 0.664302

-0.092291 0.005686 -0.000130 Library Files Main analysis library: plumbrk 01.lib Library Match width: 0.500 Peak st ri ppi ng: Library based Analysis parameters Analysis engine: npp32 G53w3.05 Start channel: 155 ( 39.27kev )

Stop channel: 8144 ( 2049.92kev)

Peak rejection level: 25.000%

Peak search sensitivity: 3 sample size: 4.6380E+02 Activity scaling factor: 1.0000E+06/( 1.0000E+00* 4.6380E+02) 2.1561E+03 Detection limit method: Nureg 4.16 Random error: 1.0000000E+00 systematic error: 1.0000000E+00 Fraction Limit: 0.000%

Background width: best method (based on spectrum).

o page 1

ORTEC g v - i (1087) npp32

  • PB08-01280 G53w3.05 15-APR-2008 15:49:44 Page 2 PBRF Spectrum name: PB08-01280.An1 Half lives decay limit: 12.000 Activity range factor: 2.000 Min. step backg. energy 0.000 Corrections Status Comments Decay correct to date: YES 14-Apr-2008 11:32:00 Decay during acquisition: NO Decay during collection: NO True coincidence correction: NO Peaked background correction: NO Absorption (Internal): NO Geometry correction: NO Random summing: NO Energy calibration Normalized diff: 0.1987 SUM MAR Y 0 F PEA K S I N RAN G E *****

Peak Area uncert FWHM Corrctn Nuclide Brnch. Act. NUC Energy Factor Energy Ratio pCi/g 238.65 80. 13.07 1.17 5.760E-02 238.63 43.300 6.231E-01 PB212 351. 90 45. 17.43 1. 24 4.241E-02 351.93 37.600 5.522E-01 PB214 582.97 29. 22.90 0.60 2.764E-02 608.92 41. 15.62 1.13 2.665E-02 609.31 46.100 6.482E-01 BI214 1172.94 38. 16.22 0,82 1.604E-02 1173.24 99.974 4.606E-Ol c060 1332.15 48. 14.43 0.44 1. 459E-02 1332.50 99.986 6.394E-01 C060 1460.39 105. 9.76 1. 69 1. 362E-02 1460.83 11.000 1.361E+01 K40

                        • U N IDE N T I FIE D PEA K SUM MAR Y Peak Centroid Background Net Area Intensity Uncert FWHM Suspected Channel Energy counts Counts Cts/sec 2 sigma % kev Nuclide 2316.46 582.97 3. 29. 0.096 45.81 0.600 TL-208 s s - Peak fails shape tests.

D - peak area deconvoluted.

L - Peak written from unknown list.

C - Area < critical level.

This section based on library: plumbrk 01.lib D

ORTEC g v - 1 (1087) npp32 G53w3.05 15-APR-2008 15:49:44 page 3 PBRF Spectrum name: PB08-01280.An1

  • '1. 1.
  • 1: *" * -/: '1: 1;1: * -/:
  • I D E N T I F I E D P EA K S U M M A R Y *1:*'1:'1:"1:1:1:'1;*::1:'1:-1:-:.

Nuclide peak Centroid Background Net Area Intensity uncert FWHM channel Energy Counts Counts Cts/sec 2 sigma % kev AM-241 0.00 59.54 O. O. 0.000 0.00 0.000 TH-234 0.00 63.29 O. O. 0.000 0.00 0.000 TH-234 0.00 92.59 O. O. 0.000 0.00 0.000 EU-152 0.00 121.78 O. O. 0.000 0.00 0.000 EU-154 0.00 123.07 O. O. 0.000 0.00 0.000 Page 2

u-235 0.00 143.76

  • O.

PB08-01280 O. 0.000

  • 0.00 0.000 u-235 0.00 185.71 O. O. 0.000 0.00 0.000 PB-212 947.76 238.65 8. 80. 0.267 26.14 1.173s EU-152 0.00 344.28 O. O. 0.000 0.00 0.000 PB-214 1397.98 351.90 4. 45. 0.151 34.86 1.238s Ag-108m 0.00 433.94 O. O. 0.000 0.00 0.000 B1 - 214 2419.63 608.92 O. 41. 0.137 31. 23 1.132 Ag-108m 0.00 614.28 O. O. 0.000 0.00 0.000 c5-137 0.00 661.66 O. O. 0.000 0.00 0.000 Ag-108m 0.00 722.91 O. O. 0.000 0.00 0.000 EU-154 0.00 723.30 O. O. 0.000 0.00 0.000 BI-212 0.00 727.33 O. O. 0.000 0.00 0.000 EU-154 o. 00 1004. 72 O. O. 0.000 0.00 0.000 co-60 4660.92 1172.94 O. 38. 0.127 32.44 0.818s EU-154 0.00 1274.44 O. O. 0.000 0.00 0.000 .

co-60 5293.40 1332.15 O. 48. 0.160 28.87 0.441s/

Ell 152 o o.oL-1J.,..<4,"-,O~8>--v-OJ.------V-.--------Y~-____\J...._\Aru__-__\,l,_.Wd___Y__riA~------

K-40 5802.82 1460.39 O. 105. 0.350 19.52 1.690 s - Peak fails shape tests.

D - Peak area deconvoluted.

A Derived peak area.

~~~k~ 5 U M MAR Y o F LIB R A R Y PEA K USA G E

- Nuclide - Ave~a~e ------------- Peak -------------

Name Code Actlvlty Energy Activity Code MDA value pCi/g kev pCi/g pci/g COMMENTS K-40 N 1. 3611E+01 1460.83 1.361E+01 ( 9.553E-01 9.76 G K co-60 F 6.3943E-01 1332.50 6.394E-D 9.818E-02 14.43 G K 1173.24 4.606E- - 8.933E-02 16.22 G K PB-212 N 6.2307E-01 238.63 6.231E-01 *( 1. 238E-01 13.07 G K o

ORTEC 9 v - i (1087) npp32 G53w3.05 15-APR-2008 15:49:44 page 4 PBRF Spectrum name: PB08-01280.An1 Nuclide Ave activity Energy Activity Code Peak MDA Comments PB-214 N 5.5216E-01 351.93 5.522E-01 *( 1.417E-01 17.43 G K BI-214 N 6.4818E-01 609.31 6.482E-01?( 1.165E-01 15.62 G K 1764.49 O.OOOE+OO % 1.199E+00 127.48 G 1120.29 O.OOOE+OO % 7.998E-01 27.91 G

( - This peak used in the nuclide activity average.

- - Peak is too wide, but only one peak in library.

- Peak is part of a multiplet and this area went negative during deconvolutipn.

? - Peak is too narrow.

@ - Peak is too wide at FW25M, but ok at FWHM.

% - Peak fails sensitivity test.

$ - Peak identified, but first peak of this nuclide failed one or more qualification tests.

Page 3

  • PB08-01280

+ - Peak act~vity higher than counting uncertainty range.

peak actlvlty lower than counting uncertainty range.

= - Peak outside analysis energy range.

& - calculated peak centroid is not close enough to the library energy centroid for positiveidentlfication.

P - peakbackground subtraction

} peak is too close to another for the activity to be found directly.

Nuclide Codes: Peak Codes:

T - Thermal Neutron Activation G - Gamma Ray F Fast Neutron Activation X X-Ray I Fission Product P Positron Decay N Naturally occurring Isotope S single-Escape P photon Reaction D Double-Escape C charged Particle Reaction K Key Line

~ NO MDe. calclllation e. Not In ~verage R coincidence Corrected C - Coincidence Peak H Halflife limit exceeded

SUMMARY

o F N U C L I DES I N SAM P L E Time of Count Time Corrected uncertainty 2 sigma Nuclide Activity Activity counting Total MDA pci/g pci/g pci/g pCi/g K-40 1.3611E+01 1. 3611E+01 2.6565E+00 2.6918E+00 9.553E-01 6.3943E-Ol 8459E-Ol 1.8571E-01 9.814E-02

,r CO-60 Ag-108mB<

CS-137 B<

EU-152 B<

6.3916E-Ol 4.4844E-02 9.2305E-02

1. 2503E-01 4.4844E-02 9.2312E-02
1. 2505E-0l 1,

EU-154 B< 1.2256E-01 1.2259E-01 ORTEC g v - i (1087) npp32 G53w3.05 15-APR-2008 15:49:44 page 5 PBRF spectrum name: PB08-01280.An1 PB-212 & 6.2307E-01 6.2307E-01 1. 6288E-01 1. 6367E-01 1. 238E-01 PB-214 & 5.5216E-01 5.5216E-01 1. 9250E-01 1. 9330E-01 1. 417E-01 BI-212 B< 1. 0874E+00 1.0874E+00 BI-214 & 6.4818E-01 6.4818E-01 2.0246E-01 2.0380E-01 1.165E-01 RA-226 B< 2.0126E+00 2.0126E+00 TH-234 B< 1. 8427E+00 1. 8427E+00 u-235 B< 4.9901E-0l 4.9901E-01 AM-241 B< 2.1333E-01 2.1334E-Ol

  1. - All peaks for activity calculation had bad shape.
  • Activity omitted from total

& - Activity omitted from total and all peaks had bad shape.

< - MOA value printed.

A - Activity printed, but activity < MOA.

B - Activity < MDA and failed test.

C - Area < critical level.

F - Fail~d fraction or key line test.

H - Halflife limit exceeded

_____________________________ SUM MAR Y ---------------------------

Total Activity ( 39.3 to 2049.9 kev) 6.3915920E-Ol pci/g Total Decayed Activity ( 39.3 to 2049.9 kev) 6.3942903E-01 pci/g Analyzed by:

missioning project Page 4

  • PB08-01280 Reviewed by: --fTl-r-<--t,L-~I-.L--:::=-----=- ~A'-!!..P-ll.. 1 5 2008

". upervi sor Laboratory: PBRF R. Case page 5

  • PB08-01l84 ORTEC 9 v 1 (1087) npp32 GS3w3. 03 APR 2008 13:37:56 Page 1 PBRF Spectrum name: PB08-01184.An1 sample description PB08-01184; sR99-26; PPH RM 8; HD-8-3; 4/3/08 spectrum Filename: z:\Lab\SAMPLE 08\PB08-01184.An1 Acquisition information Start time: 03-Apr-2008 13:24:43 Live time: 300 Real time: 302 Dead time: 0.64 %

Detector 10: 1 Detector system ro COpy

  1. 1 DETECTOR (#129)

Calibration Filename:

250ml #73678-773 (MC129) Jan08 Energy Calibration Created: 09-Jan-2008 08:36:01 Zero offset: -0.051 kev Gain: 0.250 kev/channel Quadratic: -8.299E-09 kev/channel A2 Efficiency calibration Created: 09-Jan-2008 09:15:56 Type: polynomial uncertainty: 1. 663 %

coefficients: -0.338084 -4.099654 0.610757

-0.082467 0.004895 -0.000109 Library Files Main analysis library: plumbrk 01.lib Library Match width: 0.500 Peak stripping: Library based Analysis parameters Analysis engine: npp32 G53w3.05 Start channel: 155 ( 38.73kev)

Stop channel: 8144 ( 2037.21kev) peak rejection level: 25.000%

Peak search sensitivity: 3 sample Size: 4.2810E+02 Activity scaling factor: 1.0000E+06/C 1.0000E+00* 4.2810E+02) 2.3359E+03 Detection limit method: Nureg 4.16 Random error: 1.0000000E+00 systematic error: 1.0000000E+00 Fraction Limit: 0.000%

Background width: best method (based on spectrum).

Page 1

ORTEC g v - i (1087) npp32 PB08-01184 GS3w3.0S 03-APR-2008 13:37:56 Page 2 PBRF Spectrum name: PB08-01184.An1 Half lives decay limit: 12.000 Activity range factor: 2.000 Min. step backg. energy 0.000 Corrections Status Comments Decay correct to date: YES 26-Mar-2008 14:50:00 Decay during acquisition: NO Decay during collection: NO True coincidence correction: NO Peaked background correction: NO Absorption (Internal): NO Geometry correction: NO Random summing: NO Energy Calibration Normalized diff: 0.1268 SUM MAR Y 0 F PEA K S I N RAN G E *****

peak Area uncert FWHM Corrctn Nuclide Brnch. Act. NUc Energy Factor Energy Ratio pci/g 77.23 63. 18.87 0.82 8.390E-02 238.43 70. 14.87 0.79 6.445E-02 238.63 43.300 5.307E-01 PB212 295.14 41. 18.65 0.65 5.498E-02 351. 90 54. 16.49 1. 06 4.765E-02 351.93 37.600 6.401E-01 PB214 609.30 59. 13 _02 1.07 3,006E-02 609.31 46.100 8.960E-Ol BI214 661.89 41. 15.62 1. 05 2.809E-02 661.66 85.100 3.611E-01 cs137 1173.31 59. 13.02 0.84 1. 773E-02 1173.24 99.974 7.026E-01 c060 1332.85 48. 14.43 0.33 1.598E-02 1332.50 99.986 6.339E-01 c060 1461.13 99. 10.05 1. 33 1. 481E-02 1460.83 11.000 1. 279E+01 K40

                        • U N IDE N T I FIE D PEA K SUM MAR Y ************

peak centroid Background Net Area Intensity Uncert FWHM suspected Channel Energy Counts Counts Cts/sec 2 sigma % kev Nuclide 308.84 77 .19 39. 63. 0.211 37.74 0.823 PB-214 D 1179.76 295.14 5. 41. 0.137 37.31 0.646 PB-214 sM s - peak fails shape tests.

D - peak area deconvoluted.

L - Peak written from unknown list.

C - Area < Critical level.

M - peak is close to a library peak.

This section based on library: plumbrk 01.lib o

ORTEC g v - 1 (1087) npp32 G53w3.05 03-APR-2008 13:37:56 page 3 PBRF spectrum name: PB08-01184.An1

                            • IDE N T I FIE D PEA K SUM MAR Y **************

Nuclide Peak centroid Background Net Area Intensity uncert FWHM channel Energy Counts Counts Cts/sec 2 sigma % kev AM-241 0.00 59.54 O. O. 0.000 0.00 0.000 page 2

TH-234 0.00 63.29

  • O.

PB08-01184 O. 0.000

  • 0.00 0.000 TH-234 0.00 92.59 O. O. 0.000 0.00 0.000 EU-152 0.00 121. 78 o. o. 0.000 0.00 0.000 EU-154 0.00 123.07 O. O. 0.000 0.00 0.000 u-235 0.00 143.76 O. O. 0.000 0.00 0.000 u-235 0.00 185.71 O. O. 0.000 0.00 0.000 RA-226 0.00 186.21 O. O. 0.000 0.00 0.000 PB-212 953.10 238.43 11. 70. 0.234 29.75 0.786 EU-152 0.00 344.28 O. O. 0.000 0.00 0.000 PB-214 1406.63 351. 90 8. 54. 0.182 32.98 1.062 Ag-108m 0.00 433.94 O. O. 0.000 0.00 0.000 B1 214 2435.43 609.30 O. 59. 0.197 26.04 1. 070 Ag-108m 0.00 614.28 O. O. 0.000 0.00 0.000 CS-137 2645.64 661. 89 O. 41. 0.137 31. 23 1. 051s Ag-108m 0.00 722.91 O. O. 0.000 0.00 0.000 EU-154 0.00 723.30 O. O. 0.000 0.00 0.000 81-212 0.00 727.33 O. O. 0.000 0.00 0.000 EU-154 0.00 1004.72 O. O. 0.000 0.00 0.000 co-60 4690.00 1173.31 O. 59. 0.197 26.04 0.838Y-EU-154 0.00 1274.44 O. O. 0.000 0.00 0.000 co-60 5327.81 1332.85 O. 48. 0.160 28.87 o. 334 s.-----

EU-152 0.00 1408.01 O. O. 0.000 0.00 0.000 K-40 5840.65 1461.13 O. 99. 0.330 20.10 1.334s B1-214 7052.00 1764.10 O. O. 0.000 0.00 O.OOOs s Peak fails shape tests.

D Peak area deconvoluted.

A Derived peak area.

~~~~~ SUM MAR Y o F LIB R A R Y PEA K USA G E

- Nuclide - Ave~a~e ------------- Peak -------------

Name Code Actlvlty Energy Activity Code MOA value pci/g kev pci/g pci/g COMMENTS K-40 N 1.2790E+01 1460.83 1.279E+01 ( 9.521E-01 10.05 G K co-60 I 6.6824E-01 1332.50 6 339E>OG 9.733E-02 0 14.43 G K 1173.24 7.026E-0 ? 8.777E-02 13.02 G K 0

ORTEC 9 v - (l087) npp32 G53w3.05 03-APR-2008 13:37:56 Page 4 PBRF Spectrum name: PB08-01184.An1 Nuclide Ave activity Energy Activity Code peak MDA Comments cs-137 I 3.6111E-01 661. 66 3.611E-01 ( 6.491E-02 15.62 G K PB-212 N 5.3069E-01 238.63 5.307E-01 ( 1.353E-01 14.87 G K PB-214 N 6.4012E-01 351.93 6.401E-01 ( 1. 817E-01 16.49 G K BI-214 N 8.9598E-01 609.31 8.960E-01 ?( 1. 119E-01 13.02 G K 1764.49 O.OOOE+OO ? 8.006E-01 0.00 G 1120.29 O.OOOE+OO % 5.583E-01 26.73 G

( - This peak used in the nuclide activity average.

Page 3

  • PB08-01l84 Peak is too wide, but only one peak in library.

Peak lS part of a multlplet and thlS area went negative during deconvolution.

7 _

Peak is too narrow.

@ Peak is too wide at FW25M, but ok at FWHM.

% Peak fails sensitivity test.

$ - Peak identified, but first peak of this nuclide failed one or more qualification tests.

+ - Peak activity higher than counting uncertainty range.

Peak activity lower than counting uncertainty range.

Peak outside analysis energy range.

&- calculated peak centroid is not close enough to the library energy centroid for positive identlfication.

P peakbackground subtraction

} Peak is too close to another for the activity to be found directly.

Nuclide codes: Peak Codes:

T - Thermal Neutron Activation G - Gamma Ray

- Fast Neutron Activation X - x-Ray I - Fission product P - positron Decay N - Naturally occurring Isotope S - single-Escape P - photon Reaction D - Double-Escape C - charged Particle Reaction K - Key Line M - No MDA Calculation A - Not in Average R - Coincidence Corrected C - Coincidence peak H - Halfl i fe 1 i mi t exceeded o

ORTEC 9 v - (1087) npp32 G53w3.05 03-APR-2008 13:37:56 Page 5 PBRF spectrum name: PB08-01184.An1

'1.-1:'1:"'1:*

S U MMA R Y 0 F NUC L I D E S I N S A MP L E '1: 7: '1: -!:-!:

Time of Count T-ime Corrected Unce rtai nty 2 sigma Nuclide Activity Activity counting Tota 1 MOA pcijg pcijg pcijg pcijg K-40 1; 1.2790E+01 1. 2790E+01 2.5708E+OO 2.6036E+OO 9.521E-01

~CO-60~

~'\ Ag-108' <

6.6633E-01 7.0402E-02 6.6824E-01 7.0404E-02

1. 2989E-01 1. 3166E-01 9.705E-02 J (5-137 3.6093E-Ol 3.6111E-01 1.1279E-01 1.1339E-01 6.488E-02 EU-152 B< 1. 3240E-01 1. 32 54E-01 EU-154 B<

_c 1.2312E-01 1. 2333E-01 PB-212 5.3069E-01 5.3069E-01 1.5787E-01 1. 5847E-01 1.353E-01 PB-214 " 6.4011E-01 6.4012E-01 2.1109E-01 2.1209E-01 1. 817E-01 BI-212 B< 2.0762E+00 2.0762E+00 BI-214 & 8.9597E-01 8.9598E-0l 2.3329E-01 2.3554E-01 1.119E-01 RA-226 B< 2.4288E+00 2.4288E+00 TH-234 B< 1. 7419E+00 1.7419E+00 u-235 B< 3.8942E-01 3.8942E-01 AM-241 B< 1. 9544E-01 1. 9545E-01

  1. - All peaks for activity calculation had bad shape.

Activity omitted from total

& - Activity omitted from total and all peaks had bad shape.

< - MDA value printed.

A - Activity printed, but activity < MOA.

B - Activity < MDA and failed test.

Page 4

C - Area < Critical level.

PB08-01184 F - Failed fraction or key line test.

H Halfllfe Ilmlt exceeded

SUM MAR Y ---------------------------

Total Activity ( 38.7 to 2037.2 kev) 1.0272623E+00 pci/g Total Decayed Activity ( 38.7 to 2037.2 kev) 1.0293509E+00 pci/g Analyzed by: fi P~ project Reviewed by:

2D08 Laboratory: PBRF A.Case page 5

  • PB08-0l214 ORTEC g v - 1 (1087) npp32 G53w3.05 07-APR-2008 17:09:37 page 1 PBRF spectrum name: PB08-01214.An1 sample description PB08-01214; SR99-32; PPH RM 8 FD8-3 / C08-1; 4/7/08 spectrum Filename: z:\Lab\sAMPLE 08\PB08-01214.An1 Acquisition information Start time: 07-Apr-2008 17:00:36 Live time: 300 Real time: 302 Dead time: 0.63 %

Detector 1D: 1 Detector system

  1. 1 DETECTOR (#129)

Calibration Fi 1ename :

250ml #73678-773 (MC129) JanOS ro COpy Energy calibration created: 09-Jan-2008 08:36:01 zero offset: -0.051 kev Gain: 0.250 kev/channel Quadratic: -8.299E-09 kev/channel A2 Efficiency Calibration created: 09-Jan-200809:15:56 Type: polynomial uncertainty: 1. 663 %

Coefficients: -0.338084 -4.099654 0.610757

-0.082467 0.004895 -0.000109 Library Files Main analysis library: plumbrk 01.1ib Library Match Width: 0.500 peak stripping: Library based Analysis parameters Analysis engine: npp32 G53w3.05 Start channel: 155 ( 38.73kev)

Stop channel: 8144 ( 2037.21kev) peak rejection level: 25.000%

peak search sensitivity: 3 sample size: 4.5040E+02 Activity scaling factor: 1.0000E+06/( 1.0000E+00* 4.5040E+02) 2.220ZE+03 Detection limit method: Nureg 4.16 Random error: 1.0000000E+00 systematic error~ 1.0000000E+00 Fraction Limit: 0.000%

Background width: best method (based on spectrum).

o page 1

PBRF ORTEC g v - i (1087) npp32

  • PB08-01214 G53w3.05 07-APR-2008 17:09:37 Page 2 Spectrum name: PB08-01214.An1 Half lives decay limit: 12.000 Activity range factor: 2.000 Min. step backg. energy 0.000 Corrections Status Comments Decay correct to date: YES 31-Mar-2008 13:30:00 Decay during acquisition: NO Decay during collection: NO True coincidence correction: NO Peaked background correction: NO Absorption (Internal): NO Geometry correction: NO Random summing: NO Energy Calibration Normalized diff: 0.1090 SUM MAR Y 0 F PEA K S I N RAN G E *****

Peak Area Uncert FWHM Corrctn Nuclide Brnch. Act. Nuc Energy Factor Energy Ratio pci/g 77.22 43. 24.71 0.95 8.390E-02 238.68 68. 20.18 0.86 6.440E-02 238.63 43.300 4.865E-01 PB212 295.18 35. 24.42 0.47 5.498E-02 351.98 74. 15.31 0.73 4.765E-02 351.93 37.600 8.317E-01 PB214 609.42 53. 14.76 1. 46 3.006E-02 609.31 46.100 7.602E-01 BI214 1120.10 22. 21. 32 0.75 1. 840E-02 1120.29 15.100 1.584E+00 BI214 1461. 37 134. 8.64 1. 48 1. 481E-02 1460.83 11.000 1.645E+01 K40

                        • U N IDE N T I FIE D PEA K SUM MAR Y .'* ..! * ..J * .J-.J * .J

.J * .J

..J * ..J.

Peak Centroid Background Net Area Intensity Uncert FWHM suspected Channel Energy Counts Counts Cts/sec 2 sigma % kev Nuclide 308.83 77.22 29. 43. 0.142 49.41 0.947 PB-214 sM 1179.92 295.18 11. 35. 0.118 48.84 0.473 PB-214 sM s - peak fails shape tests; o - peak area deconvoluted.

L - peak written from unknown list.

C - Area < critical level.

M- Peak is close to a library peak.

This section based on library: plumbrk 01.lib o

ORTEC g v - 1 (1087) npp32 G53w3.05 07-APR-2008 17:09:37 Page 3 PBRF spectrum name: PB08-01214.An1

~: *"1: 7:~: 7; * * * * * * *

  • I D E N T I F I E 0 P EA K S U M M A R Y "1:*** * ** 1:*1.***
  • Nuclide peak centroid Background Net Area Intensity uncert . FWHM Channel Energy Counts Counts Cts/sec 2 sigma % kev AM-241 0.00 59.54 O. O. 0.000 0.00 0.000 TH-234 0.00 63.29 O. O. 0.000 0.00 0.000 TH-234 0.00 92.59 O. O. 0.000 0.00 0.000 Page 2

EU-152 EU-154 0.00 0.00 121.78 123.07

  • O.

PB08-01214 O. 0.000

  • 0.00 0.000 O. O. 0.000 0.00 0.000 u-235 0.00 143.76 O. O. 0.000 0.00 0.000 U-235 0.00 185.71 O. O. 0.000 0.00 0.000 RA-226 0.00 186.21 O. O. 0.000 0.00 0.000 PB-212 954.09 238.68 31. 68. 0.226 40.35 0.859 EU-152 0.00 344.28 O. O. 0.000 0.00 0.000 PB-214 1406.94 351. 98 12. 74. 0.248 30.62 0.731s Ag-108m 0.00 433.94 O. O. 0.000 0.00 0.000 B1-214 2435.91 609.42 2. 53. 0.176 29.52 1. 457 Ag-108m 0.00 614.28 O. O. 0.000 0.00 0.000 cS-137 0.00 661. 66 O. O. 0.000 0.00 0.000 Ag-108m 0.00 722 .91 O. O. 0.000 0.00 0.000 EU-154 0.00 723.30 O. O. 0.000 0.00 0.000 61-212 0.00 727.33 O. O. 0.000 0.00 0.000 EU-154 0.00 1004.72 O. O. 0.000 0.00 0.000 B1-214 4477 . 27 1120.10 O. 22. 0.073 42.64 0.750s co-60 0.00 1173.24 O. O. 0.000 0.00 0.000 EU-154 0.00 1274.44 O. O. 0.000 0.00 0.000 co-60 0.00 1332.50 O. O. 0.000 0.00 0.000 EU-152 0.00 1408.01 O. O. 0.000 0.00 0.000 K-40 5841. 63 1461. 37 O. 134. 0.447 17.28 1. 480s s - Peak fails shape tests.

o - Peak area deconvoluted.

A Derived peak area.

SUM MAR Y o F LIB R A R Y PEA K USA G E

- Nuclide - Ave\age ------------- peak -------------

Name Code ACtlvlty Energy Activity Code MDA value pci/g kev pci/g pci/g COMMENTS K-40 N 1.6454E+01 1460.83 1. 645E+01 ( 9.050E-01 8.64 G K PB-212 N 4.8649E-01 238.63 4.865E-01 ( 2.060E-01 20.18 G K PB-214 N 8.3170E-01 351.93 8.317E-01 ( 2.067E-01 15.31 G K 0

ORTEC g v - i (1087) npp32 G53w3.05 07-APR-2008 17:09:37 Page 4 PBRF spectrum name: PB08-01214.Anl Nuclide Ave activity Energy Activity Code Peak MDA Comments B1-214 N 7.6020E-01 609.31 7.602E-01 ( 1.419E-01 14.76 G K 1764.49 O.OOOE+OO % 7.610E-01 28.87 G 1120.29 1.584E+00 + 5.306E-01 21. 32 G

( - This peak uied. in the nuclide activity average.

Peak is too wide, but only one peak in library.

- Peak is part of a multiplet and this area went negative during deconvolution.

? - Peak is too narrow.

@ - Peak is too wide at FW25M, but ok at FWHM.

% - Peak fails sensitivity test.

$ - peak identified, but first peak of this nuclide failed one or more qualification tests.

page 3

  • PB08-01214

+ - peak act:v:ty higher than coun~ing uncertainty range.

Peak actlvlty lower than countlng uncertainty range.

- Peak outside analysis energy range.

& - calculated peak centroid is not close enough to the library energy centroid for positive identlfication.

P - peakbackground subtraction

} Peak is too close to another for the activity to be found directly.

Nuclide Codes: Peak Codes:

T - Thermal Neutron Activation G - Gamma Ray F - Fast Neutron Activation X - X-Ray I - Fission Product P - Positron Decay N - Naturally occurring Isotope S - single-Escape P - photon Reaction D - Double-Escape C - Charged Particle Reaction K - Key Line M - NO MDA calculation A - Not in Average R - Coincidence Corrected C - Coincidence Peak H - Halflife limit exceeded "1:"!: *-1:* S U MMA R y 0 F NU C L I DE S I N S A tv1 P L E 1:* '1: -1:""1.

Time of Count Time Corrected uncertainty 2 Sigma Nuclide Activity Activity Counting Total MDA pCi/g pci/g pci/g pci/g K-40 .. 1. 6454E+01 1.6454E+01 2.8428E+00 2.8917E+OO 9.050E-01 co-60 B< 9.2245E-02 9.2482E-02 Ag-108mB< 4.0995E-02 4.0996E-02 cs-137 B< 6.1667E-02 6.1695E-02 EU-152 B< 1. 3572E-01 1. 3586E-01 EU-154 B< 1.1052E-01 1.1070E-01 PB-212 ~, 4.8649E-01 4.8649E-0l 1.9631E-01 1.9671E-Ol 2.060E-01 PB-214 .c 8.3169E-01 8.3170E-01 2.5465E-01 2.5606E-Ol 2.067E-01 BI-212 B< 9.7242E-01 9.7242 E-Ol o

ORTEC 9 v - i (1087) npp32 G53w3.05 07-APR-2008 17:09:37 page 5 PBRF Spectrum name: PB08-01214.Anl BI-214 ~.

7.6019E-01 7.6020E-01 2.2444E-Ol 2.2612E-Ol 1. 419E-Ol RA-226 B< 1.8209E+00 1.8209E+00 TH-234 B< 1. 4530E+00 1.4530E+00 u-235 B< 3.1325E-Ol 3.1325E-Ol AM-241 B< 1. 8638E-01 1.8638E-01

  1. - All peaks for activity calculation had bad shape.
  • Activity omitted from total

& - Activity omitted from total and all peaks had bad shape.

< - MDA value printed.

A - Activity printed, but activity < MDA.

B - Activity < MDA and failed test.

C - Area < Critical level.

F - Failed fraction or key line test.

H - Halflife limit exceeded

_____________________________ SUM MAR Y ---------------------------

Total Activity ( 38.7 to 2037.2 keY) O.OOOOOOOE+OO pci/g Total Decayed Activity ( 38.7 to 2037.2 keY) O.OOOOOOOE+OO pci/g Analyzed by:

ecommissioning project page 4

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PB08-01214 Reviewed by: ---:;J,J,~>Lf--7A'--:;;;'~~A~ ----.nJAeR.J) 8 200a l~~

Laboratory: PBRF A. Case page 5

SECTION?

ATTACHMENT 4 1 PAGE

DQA Check Sheet Design EP PPH-109 I Revision #

I Original I

Survey Unit # EP PPH-109 Preliminary Data Review' Answers to the following questions should be fully documented in the Survey Unit Yes No N/A Release Record

i. Have surveys been performed in_. accordance with survey instructions in the Survey Design? X
2. Is the instrumentation MDC for structure static measurements below the DCGL w for Class 1 and 2 X

survey units, or below 05 DCGL w for Class 3 survey units?

3 Is the instrumentation MDC for embedded/buried piping static measurements below the DCGL w ? X 4 Was the instrumentation MDC for structure scan measurements, soil scan measurements, and embedded/buried piping scan measurements below the DCGL w. or, if not, was the need for additional X static measurements or soil samples addressed in the survey design?

5 Was the instrumentation MDC for volumetric measurements and smear analysis < 10% DCGL w ? X

6. Were the MDCs and assumptions used to develop them appropriate for the instruments and techniques X

used to perform the survey?

7. Were the survey methods used to collect data proper for the types of radiation involved and for the X

media being surveyed?

8 Were "Special Methods" for data collection properly applied for the survey unit under review? X 9 Is the data set comprised of qualified measurement results collected in accordance with the survey X

design, which accurately reflects the radiological status of the facility?

Graphical Data Review 1 Has a posting plot been created? X 2 Has a histogram (or other frequency plot) been created? X

3. Have other graphical data tools been created to assist in analyzing the data? X Data Analysis
1. Are all sample measurements below the DCGL w (Class 1 & 2), or 05 DCGL w (Class 3)? X
2. Is the mean of the sample data < DCGL w? X
3. If elevated areas have been identified by scans and/or sampling, is the average activity in each X

elevated area < DCGLEMC (Class 1), < DCGL w (Class 2), or <0.5 DCGL w (Class 3)?

4. Is the result of the Elevated Measurements Test < 1.0? X 5 Is the result of the statistical test (5+ for Sign Test or W r for WRS Test) ::: the critical value? X Comments: See Section 5 of this Survey Unit Release Record FSS/Characterization Engineer (prinUsign)

&L l<...) l' "I':::' I;/1Aj~

, /I Date 1.5)? /tJJ I

FSS/ Characterization Manager (prinUsign) ['"I. Casl ,/ k~ t.. Date 5/b4r v . L.

Fonn CS-09/2 Rev 0 Page 1 of 1

SECTION 7 ATTACHMENT 5 1 DISC

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