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Effluent & Waste Disposal Semiannual Rept,Jan-June 1982
	ML20065A160
Person / Time
Site:	Three Mile Island
Issue date:	08/31/1982
From:	; GENERAL PUBLIC UTILITIES CORP.
To:	;
Shared Package
ML20065A156	List: ML20065A153; ML20065A160;
References
	NUDOCS 8209130153
	Download: ML20065A160 (61)
	v • d • e

1@MRog3nf /S@ EMfE 101@K43AL SEMIANFUAL REPORT ATTACHMENT I Page 1 1-Janusry/30-June (1982 Supplemental Information Facility TMI-Unit 1 License DPR 50-289

1. Regulatory Limits

a. Fission and activation gases:

b. Iodines: _

TMI-Unit 1 Tech Specs, Amendment No. 72

c. Particulates, half-lives > 8 days: based on 10 CFR 20 and 10 CFR 50 Limits.

d. Liquid effluents:

2. Maximum Permissible Concentrations Provide the MPCs used in determining allowable release rates or concentrations.

a. Fission and activation gases:

b. Iodines: -

10 CFR 20, Appendix B, Table II

c. Particulates, half-lives > 8 days:

d. Liquid effluents: _

A

3. Average Energy Provide the average energy (E) of the radionuclide mixture in releases of fission and activation gases, if applicable.

E = 3.82E-1

4. Measurements and Approximations of Total Radioactivity Provide the methods used to measure or approximate the total radioactivity in effluents and the methods used to determine radionuclide composition.

a. Fission and activation gases: GE(LI) spectrometry, Liquid Scintillation

b. Iodines: GE(LI) spectrometry

c. Particulates: GE(LI) Flow Proportional,

d. Liquid effluents: GE(LI) gpectrometrg GasSpeE!NES$ry,LiquidS

5. Batch Releases Provide the following information relating to batch releases of radioactive materials in liquid and gaseous effluents.

1st 0 ' 2nd Q

a. Liquid

l. Number of batch releases: 26 34

2. Total time period for batch releases: (min.) 19,028 15,061

3. Maximum time period for a batch release: (min.) 2,300 1,128

4. Average time period for batch releases: (min.) 732 , 443

5. Minimum time period for a batch release: (min.) 205 145

6. Average stream flow during periods of release 3.43E6 2.91E6 of effluent into a flowing stream: (CFM)

b. Gaseous

1. Number of batch releases: 16 23 l 2. Total time period for batch releases: (min.) 96,097 125,488

3. Maximum time period for a batch release: (min.) 30,905 39,886

4. Average time period for batch releases: (min.) 6,006 5,456

5. Minimum time period for a batch release: (min.) 510 508

6. Abnormal Releases 8209130153 820031 PDR ADOCK 05000289 R PDR

a. Liquid

1. Number of releases 2. Total activity releases: -none- -none-l

b. Gaseous i 1. Number of releases: -0 , 2. Total activity released: -" "*- * ~" "*~

ATTACHMENT I Page 2 TABLE 1A EFFLUENT AND WASTE DISPOSAL SEMIANNUAL REPORT (1982)

CASE 0US EFFLUENTS - SUMMATION OF ALL RELEASES Unit ,

Quarter 8 Est.Totali lst ) Quarter 2nd Error.% !

A. Fission & activation gases

1. Total release Ci j7.56E-3 j <l.00E-8 l 2.50 El l

2. Average release rate for period pCi/sec j9.51E-4 j N/A l

3. Percent of technical specification limit l % j

j B. Iodines

1. Total iodine - 131 Ci j<1.00E-8j<1.00E-8 l N/A l

2. Average release rate for period f.pC1/sec j N/A j N/A l

3. Percent; of technical specification limit l % } j l C. Particulates

1. Particulates with half-lives > 8 davs f Ci j7.53E-5 )3.72E-5 l2.50El !

2. Average release rate for period fpC1/sec j9.47E-6 j4.68E-6

3. Percent of technical specification limit ! * !

f

I 1 l

4. Gross alpha radioactivity & Ci 5.52 E-8 .i2.18 E-6 l D. Tritium

1. Total release f Ci j1.04E-4 j 6.78 E-5 l 2.50 El l

2. Average release rate for period kpCi/sec 1.33 E-5 j 8.53 E-6 !

j *

3. Percent of technical specification limit l % ! l Note: All less than (<) values are in pCi/cc.

% Tech Spec limits: Listed on Dose Summary Table

. _ _ _ _ - --. . . . . _ - _ - _ _ - = .-

ATTACHMENT I

.. , Page 3 I

) TABLE 1C EFFLUENT AND WASTE DISPOSAL SEMIANNUAL REPORT (1982)

GASEOUS EFFLUENTS - GROUND-LEVEL RELEASES Continuous Mode Batch Mode

. _ Unit .

Quarter . Quarter ,

Quarter <

Quarter i Nuclides Released 1st 2nd 1st 2nd

1. Fission gases krypton-85 Ci <1.00 E-8 <1.00 E-8 7.56 E-3 <1.00 E-8 i i krypton-85m Ci <1.00 E-8 <1.00 E-8 !<1.00 E-8 <1.00 E-8 krypton-87 Ci <1.00 E-8 <1.00 E-8 l<1.00E-8 <1.00 E-8 l krypton-88 Ci <1.00 E-8 <1.00 E-8 l<1.00:E-8 <1.00 E-8 j xenon-133 Ci <1.00 E-8 <1.00 E-8 l<1.00E-8 <1.00 E-8 l xenon-135 Ci <1.00 E-8 <1.00 E-8 !<1.00E-8 <1.'00 E-8 xenon-135m Ci <1.00 E-8 <1.00 E-8 <1.00 E-8 l<1.00E-8 xenon-138 Ci <1.00 E-8 <1.00 E-8 <1.00 E-8 !<1.00E-8 j Others (specify) Ci !

! Ci l l Ci l I unidentified Ci l Total for period Ci N/A N/A l 7.56 E-3 l N/A i

. 2. lodines l

l iodine-131 Ci <1.00E-12l<1.00E-8 l<1.00E-12 f<1.00E-8 I

iodine-133 Ci <1.00 E-10 <1.00E-10!<1.00E-8 !<1.00E-8 l

iodine-135 Ci <1.00 E-10 <1.00E-10!cl.00E-8 l<1.00E-8 Total for period Ci l N/A N/A l N/A l N/A l I

, 3. Particulates strontium-89 Ci 2.34 E-5 !1.31E-7 l l

strontium-90 Ci 6.20 E-6 ;<1.00 E-11 '

l cesium-134 Ci <1.00 E-11 <1.00 E-11 <1.00 E-8 <1.00 E-8 cesium-137 Ci <1.00 E-11 <1.00E-11!4.58E-5 l3.49E-5 l l barium-lanthanum-140 . Ci l <1.00E-11,<1.00E-11}<1.00E-8 f<1.00E-8 ,

i i

Note: All less than values (<) are in pC1/cc.

l

ATTACHMENT I Page 4 f

TABLE 2A l

EFFLUENT AND WASTE DISPOSAL SEMIANNUAL REPORT (1982)

LIQUID EFFLUENTS -SUMMATION OF ALL RELEASES Unit Quarter Quarter Est. Total 1st 2nd Error, %

A. Fission and activation products

1. Total release (not including tritium,

[

gases, alpha) Ci 9.98 E-3 4.73 E-3 2.50 El l l 2. Average diluted concentration during -period UCi/ml 7.62 E-10 2.99 E-10

3. Percent of applicable limit *

l l l B. Tritium

1. Total release l Ci l 4.22 E-1 l1.94EO !2.50El !

2. Average diluted concentration during period UC1/ml 8 3.22 E-8 1.23 E-7

3. Percent of applicable limit ; l *

l l l r

C. Dissolved and entrained gases

1. Total release l Ci l<l.00E-4l<l.00E-4 l N/A l

2. Average diluted concentration N/A N/A l during period pC1/ml !

3. Percent of applicable limit g N/A l l l N/A l D. Gross alpha radioactivity ll. Total Release Ci !<1.00 E-7 ! 1.46 E-6 l 2.50 El I

$. Volume of waste released (prior to dilution) ! liters! 5.09 E6 l 4.58 E6 l 1.00 El l

f. Volume of dilution water used during period. liters 2 1.31 E10 ) 1.58 E10l 1.00 El Note: All less than values (<) are in pCi/ml.

% Tech. Spec. Limits: Listed on Dose Summary Table.

TABLE 2B Page 5 EFFLUENT AND WASTE DISPOSAL SDilANNUAL REPORT (1982) e j , LIQUID EFFLUENTS CONTINUOUS MODE BATCH MODE Unit Quarter Quarter Quarter Quarter Nuclides Released 1st 2nd 1st 2nd strontium-89 Ci <5.00 E-8 <5.00 E-8 3.10 E-6 <5.00 E-8

strontium-90 Ci <5.00 E-8 l<5.00 E-8 l 7.52E-6l2.09E-5 cesium-134 Ci <5.00 E-7 l<5.00E-7 l 1.24E-3l6.32E-4 cesium-137 Ci <5.00 E-7 l<5.00E-7 l 7.23 E-3l 3.21 E-3 iodine-131 Ci <1.00E-6l<1.00E-6 l<1.00E-6l<l.00E-6

, cobalt-58 Ci l<5.00E-7l<5.00E-7 l<5.00E-7l<5.00E-7l cobalt-60 Ci l <5.00 E-7 l <5.00 E-7 l 1.16 E-3 l 6.31 E-4 l iron-59 Ci <5.00 E-7 l<5.00 E-7 l<5.00E-7l<5.00E-7l zine-65 '

Ci <5.00E-7l<5.00E-7l<5.00E-7l<5.00E-7l manganese-54 l Ci l <5.00 E-7 l <5.00 E-7 l 1.21E-5l<5.00E-7) chromium-51 l Ci l<5.00E-7l<5.00E-7l<5.00E-7l<5.00E-7l

=irconium-niobium-95 l Ci l <5.00 E-7 l <5.00 E-7 l <5.00 E-7 l <5.00 E-7 l molybdenum-99 l Ci l <5.00 E-7 l <5.00 E-7 l <5.00 E-7j <5.00 E-7 technetium-99m l Ci l <5.00 E-7 l <5.00 E-7 l <5.00 E-7l <5.00 E-7 ;

barium-lanthanum-140 l Ci l<5.00E-7l<5.00E-7l<5.00E-7l<5.00E-7j cerium-141 l Ci l <5.00 E-7 l <5.00 E-7 l <5.00 E-7j <5.00 E-7 j Other (specify) I C1 l<5.00E-7!<5.00E-7!<5.00E-7<5.00E-7f !

Iron-55 l Ci l<1.00E-6!<1.00E-6l 3.32 E-4I 2.32 E-8'

Antimony-125 l Ci l<5.00E-7 <5.00E-7l<5.00E-7I2.39E-4!

! Phosphorus-32 l Ci !<1.00E-6!<1.00E-6 <1.00E-6I<1.00E-6f l l Total for period (above) i Ci i N/A N/A l 9.98E-3l4.73E-3 xenon-133 l Ci !<1.00E-5 kl.00 E-5 I <1.00 E-4 ! <1.00 E-4l xenon-135 ) Ci j<1.00E-5 kl.00 E-5 j <1.00 E-4 j <1.00 E-4l Note: All less than (<) values are in pCi/ml.

All results of analyses by offsite vendors were not available in time for this report. Results will be supplied as soon as they are availabic and this table updated (if applicable) for Sr-89, Sr-90, P-32 and Fe-55 it. the 2nd quarter of 1982.

TAB 33 Se ATTACHMENT I EFFLUENT AND WASTE DISPOSAL SEMIANNUAL REPORT (1982) Page 6

, SOLID WASTE AND IRRADIATED FDU. SHIPMENTS A. Solid waste shipped off-site for burial or disposal (not irradiated fuel) i 6 MONTE EST. TOTAL

. ype waste l UNIT PERIOD ERROR, *

a. Spent resins, filter sludges, a m3 4.248 5'*

evaporator bottoms, etc.

Ci .927

b. Dry compressible waste, contmiminated m3 219.984 l 5 **

equipment, etc. ** C1 1.221 1

c. Irradiated components, control rods, m3 '

N/A etc. Ci !

d. Other (describe) c4 l N/A l Ci i I j 2. Estimate of major nuclide i j i i composition (by type of waste) I ' l

~

I a. Cod 60 i 4.47% i !

Cs-134 i i '

! 16.017 Cs-137 8 77.25% ' !

Sr-90/Y-90 8 0.63% each' !

b. Cs-137 i 32.17% i i Ea-137m i 30.40% . j i Cs-134 6 3.9% - I I Sr-90/Y-90 i 3.12% ea. i i i Co-60 t 24.64% . t

! c. N/A !

5 i 8 i !

l i I l

i i i l

.! d. N/A i i j I i i t

j i -

i I l

3. Solid Waste Disposition ;

i Number of Shipments Mode of Transportation i Destination .

I t 1 i Tractor / Trailer (van) iRichland, Washincton ;

! i 3 i Tractor / Flatbed t Richland. Washincton i 5 i Tractor / Trailer (van) i Earnwell. South Carolina i i 1 i Tractor / Flatbed IEarnwell, South Carolina .

i E. Irradiated Fuel Shipments (Disposition)

I l

, Nu=ber of Shipments fModeofTransportation l Destination i i

! None l

Shipped in 3 LSA liners, 172.3 cu. ft. each; solidified with cement 3

- Shipped in 227 LSA (Type A) steel drums. 7.5 ft /each and 62 LSA(Type A) steel boxes, 3

98 ft /each

I i

l ATTACIDfENT I I Page 7 TABLE 1 - Joint Frequency Tables for 1st Quarter (1982)

TABLE 2 - Joint Frequency Tables for 2nd Quarter (1982)

TABLE 3 - Joint Frequency Tables for Specific Release Periods During 1st Quarter (1982)

TABLE 4 - Joint Frequency Tables for Specific Release Periods During 2nd Quarter (1982) e

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Unit 1 - 1st Quarter 1902

SUMMARY

OF MAXIMUM INDIVIDUAL DOSES

, LAST ACCUMULATIONS FOR PERIODS N

January 1, 1982 to March 31, 1982

\y"e . Liquid Gaseous January 1, 1982 to March 31, 1982 O

$E Air January 1, 1982 to March 31, 1982

, DE Estimated Location % of Applicable Dose Age Dist Dir Applicable Limit Effluent Organ (mrem) Group (M) (Toward) Limit (nR)

1. Liquid Total Body 8.49E-02 Adult Receptor 1 2.8E 00 3.0

2. Liquid Liver 1.29E-01 Teen Receptor 1 1.3E 00 10.0 I 3. Noble Gas Air Dose 7.79E-09 363 ESE 7.8E-08 10.0 (Gamma-crad)

4. Noble Gas Air Dose 8.84E-07 363 ESE 4.4E-06 20.0 (Beta-mrad)

5. Noble cas T. Body 5.84E-09 All 630 ESE 1.2E-07 5.0

6. Skin 7.02E-07 All 630 ESE 4.7E-06 15.0 Noble Gas

7. Iodine & Skin 3.10E-04 Teen 630 ESE 2.lE-03 15.0 Particulates

SUMMARY

OF POPULATION DOSES LAST ACCUMULATIONS FOR PERIODS Liquid January 1, 1982 to March 31, 1982 Gaseous January 1, 1982 to March 31, 1982 Estimated Applicable Population Dose Effluent Organ (Person-rem)

8. Liquid Total Body 3.7E-02

9. Liquid Thyroid 2.5E-03

10. Gaseous Total Body 3.9E-04

11. Gaseous Bone, Lung 5.8E-04

Unit 1 - 2nd Quarter 1982

SUMMARY

OF MAXIMUM INDIVIDUAL DOSES

~ . LAST ACCUMULATIONS FOR PFRIODS yon . Liquid April 1, 1982 to June 30, 1982 0" Gascous April 1, 1982 to June 30, 1982

%E Air April 1, 1982 to June 30, 1982 NE % of Estimated Location Applicable Dose Age Dist Dir Applicable Limit Effluent Organ (mrem) Group (M) (Toward) Limit (nR)

1. Liquid Total Body 3.35E-02 Adult Receptor 1 1.lE 00 3.0

2. Liquid Liver 5.03E-02 Teen Receptor 1 5.0E-01 10.0 .

3. Noble Gas Air Dose 0.00 0 0 0 (Gamma-mrad)

4. Noble Gas Air Dose 0.00 0 0 0 (Beta-mrad)

5. Noble Gas T. Body 0.00 0 0 0

6. Noble Gas Skin 0.00 0 0 0

7. Iodine & Bone 1.58E-04 Child 630 ESE 1.lE-03 15.0 Particulates

SUMMARY

OF POPULATION DOSES LAST ACCUMULATIONS FOR PERIODS Liquid April 1, 1982 to June 30, 1982 Gaseous April 1, 1982 to June 30, 1982 Estimated Applicable Population Dose Effluent Organ (Person-rem)

8. Liquid Total Body 2.5E-02

9. Liquid Thyroid 1.0E-02

10. Gaseous Total Body 1.8E-03

11. Gaseous Liver, Skin 4.1E-03 W MW Mt *M P 8*TFT

ATTACEMENT II l

Page 1 4

~

CHANGES TO THE PROCESS CONTROL PROGRAM FOR i

RADI0 ACTIVE WASTE SOLIDIFICATION 1

i

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i

Background:

Originally, the TMI-1 Process Control Program (PCP) was included as part of the procedure for incontainer solidification (OP 1104-28A).

As of May, 1982, the PCP has been separated from this solidification

procedure, re-written, and issued as its own procedure (OP 1104-281).

I I The following provides the explanation for the changes in the content of the procedure for any applicable sections.

Procedure Changes and Explanations:

I a. Section 2.1.1 Concentrated Waste ( Evaporator Bottom) i This change reflects modifications in the method used to convey waste from the storage locations to the Hittman liner. Hard piping and use of the permanent waste recirculation pumps are

., now utilized instead of a progressive cavity pump and temporary

) line.

J

b. Section 2.2.1 Emulsifier Feed (Oily Waste Only) f Additional words have been added to indicate at which time

! emulsifiers will be added to a liner for oily waste solidifications.

Since the emulsifier is locally added, it is necessary for this addition to take place prior to the transfer of concentrated waste to eliminate the potential for airborne releases.

c. Section 2.4 Vent Air Filter Subsystem Changes in this section reflect the modifications to the liner off gas system. Previously, the liner was vented directly to j a bag / filter house located in the solidification building.

j Incorporation of a larger bag house with HEPA filter and the venting discharge to the TMI-1 Auxiliary Building, provides the mechanism to ensure that all off gas is contained within a filtered system and not released to the environment.

d. Note (Following Section 3.2.3.1)

The statement included in this note provides for testing of evaporator bottoms at ambient temperatures if the waste has been previously neutralized. Neutralization of the waste is required

, for conditioning waste prior to the addition of the cement and to

) prevent boric acid precipitation. TMI-1 does make it a practice i to neutralize waste while contained in the storage tanks. It is therefore possible that the sample of waste has an acceptable pH j and is properly conditioned for the solidification test.

i 2

, . - . , , - , - - - - - - , , . , , , . - - -._,.--,----,.n-,,. .

ATTACIDfENT II Page 2 CllANGES TO Tile PROCESS CONTROL PROGRAM FOR l RADIOACTIVE WASTE SOLIDIFICATION (continued)

e. Section 3.2.3.2 (Collection of Sampics)

The first sentence of this section has been reworded for clarification.

f. Section 4.1.1 (Waste Conditioning)

The content of Sections 4.1.1 and 4.1.2. have been exchanged. The new 4.1.1 provided additional guidance for neutralization of concentrated waste for conditioning of the waste prior to testing.

i

g. Section 4.1.2 (Waste Conditioning)

This revised item provided the required quidance for neutralization of bead and powdered resins prior to testing.

h. Section 4.1.4 (Waste Conditioning) j The specific information in this section has been modified to incorporate improvements to the Ilittman procedures. The Hittman procedures developed for incontainer solidification provides the basis for this PCP.

1. Section 4.1.5 (Waste Conditioning)

This section replaces 4.1.4.1 and subsequent sections. These sections are renumbered after restructuring. Additional information has also been included in this section for additional guidance of oily waste i to ensure proper ratios are used and consistent with burial requirements. The intent of the section is not changed.

J. Section 4.2.3 (Test Solidification)

The changes in the section incorporate changes to the Hittman procedures for test solidification. Two verification samples

, are now performed using different quantities of solidification agents (i.e. cement and metso). The two samples provide an upper and lower range of the ad mixtures and are used as a basis for determination of the ratios to be used for solidification.

k. Section 4.2.4 (Test Solidification)

See 4.2.3, (Item j. above)

1. Section 4.2.5 (Test Solidification)

See 4.2.3, (Item j. above)

_- - . - - =-_ - -

ATTACIIMENT II Page 3 i

CllANGES TO Tile PROCESS CONTROL PROGRAM FOR 3

RADIOACTIVE WASTE SOLIDIFICATION j (continued)

J

m. Section 4.2.6 (Test Solidification)

See 4.2.3, (Item j. above)

, n. Section 4.2.8 (Test Solidification)

The amount of time allowed for the samplea to harden have been changed from 30 minutes to 4 hours4.62963e-5 days 0.00111 hours 6.613757e-6 weeks 1.522e-6 months . This change is required to be consistent with the liittman procedures and provides additional time

for hardening of the verification samples, i

l

o. Section 4.5.2 (Alternate Solidification Parameters)

This section has been added to provide further guidance for

determination of the cause if a sample (s) fails to solidify.

p. Attachments (Data Sheets) i All of the previous data and calculation sheets have been changed l to reflect the methodology for the dual sample test verifications.

The new data sheets (again consistent with existing flittman l

procedures) are used for documentation of test verification.

The intent of these sheets has not been changed.

l I

i 1

l 2

l

ATTACIDIENT III Page 1

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'.D' O' T ' !"'{ Q p { {sf ( ,-) tgl[~ [ Qlg!j \/

1104-281 Revision 0 IMPORTANT TO SAFETY CONTibLt LkOPY FQR ENVIRONMENTAL IMPACT RELATED USE IS US1T 1.ONLY, THREE MILE ISLAND NUCLEAR STATION _ /

UNIT NO. 1 OPERATING PROCEDURE 1104-281 HITTMAN NUCLEAR AND DEVELOPMENTAL CORPORATION PROCESS CONTROL PROGRAM Incontainer Solidification Table of Effective Pages Page Revision Page Revision Page Revision Page Revision 1.0 0 26.0 0

! 2 . 0- 0 27.0 0 3.0 0 28.0 0 4.0 0 29.0 0 i 5.0 0 30.0 0 6.0 0 31.0 0 7.0 0 32.0 0 8.0 0 33.0 0

, 9.0 0 10.0 0 11.0 0 12.0 0 ,

13.0 0 i 14.0 0 i

15.0 0 l 16.0 0 17.0 0 18.0 0 19.0 0 20.0 0 21.0 0 22.0 0 23.0 0 24.0 0 25.0 0 i

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' tret E ~ p f) ~

Bif ' 7 9 2 Signature Date A

(A signature 7- 20 -8z-Date U

Document ID: 0212T

ATTACHMENT III Page 2 FOR USE IN UNIT I ONLY 1104-281 Revision 0 THREE MILE ISLAND NUCLEAR STATION UNIT N0.1 OPERATING PROCEDURE 1104-281 HITTMAN NUCLEAR AND DEVELOPMENT CORPOR Incontainer Solidification 1.0 PURPOSE The purpose of the Process Control Program (PCP) for incontainer solidi-fication is to provide a program which will assure a solidified product with no free liquid prior to transportation for disposal.

The program consists of diree major steps, which are:

a.

Procedures for collecting and analyzing samples; b.

Procedures for solidifying samples; c.

Criteria for process parameters for acceptance or rejection as solidified waste.

2.0 SYSTEM DESCRIPTION The systems described herein are designed to handleonthe of solidific liquids, evaporator bottoms, other concentrated ,liquids contaminated oil spent resin, filter sludge and other miscellaneous waste.

Concentrated liquids are processed at elevated temperatures as required e to k salts in solution.

The various operations are as described below.

2.1 Waste Feed System 2.1.1 Concentrated Waste (Evaporator Bottoms)

The waste feed system consists of permanent plant pump

~~ "-* and piping for the recirculation of concentrated evapora-tor b'otIo'ms from the concentrated waste storage tanks a permanent transfer piping terminating at the Hittman Building.

The concentrated waste being recirculated with the CWST transfer pumps (WDL-P-12 A/B) is diverted to pump waste to the Hittma- disposal liner.

1.0

ATTACHMENT III Page 3 FOR USE IN UNIT I ONLY 1104-281

. Revision 0 The pumps and the valve lineup is manually controlled and flow is discontinued when a predetermined level is reached in the liner.

2.1.2 Bead Resin and Powdered Resin The waste feed system consists of TMI-1 resin recircula-tion hoses attached to the resin disposal and dewater return connections on the outside wall of the Auxiliary Building. Resin may be directed either to the disposal liner or back to the resin tank via the dewater return

connection. The resin flow the liner is stopped when the i

resin slurry reaches a predetermined level. A dewatering pump operating during the fill cycle dewaters the liner

~

until loss of flow is detected. The dewater pump, a positive displacement air operated diaphragm pump, is stopped. The resin flow is restarted and continued until the predetermined level is reached. The dewater pump is resta rted. The fill and dewater procedure is repeated until the dewatering cycle no longer brings the resin

\

level down below the predetermined level. Based on liner size used, a predetermined quantity of water is added back into the liner through the dewatering element to I

-s- ..; 4 :

fluff Y

the bed to relieve any bed packing.

Liners used for powederd resin have special bottom designs to preclude plugging of the dewatering elements.

2.0

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ATTACID1ENT III Page 4 TOR USE IN UNIT l ONLY d, ,

2ol;289 2.1.3 Oily Waste Due to the low activity lewis associated with oil I wastes, the liners in which the oil is to be solidified i

can be filled by hand o r with a smal'1 pump. The line r is filled to a pmset level (dete nained visually). Tte quantity of evaporator bottons detenained by tte verifi-cation test is added as described in section 2.1.1.

2.2 Cement Feed Subsystem Cemnt and chemical additives am batch loaded into the shipping container, whe m the actual mixing occurs, by means of a screw co nveyo r. This subsystem consists of:

a. Cement toppe r with discha nje adapto r

b. Scmw feede r and drive moto r -

c. Container inlet val ve As a function of waste volume and container size, the appropriate annunt of cement and additives for a single batch are pru-loaded into the cement topper which, through the dischanje adapto r, meters the cement to tre screw feede r. Cement is conveyed through tie flexible semw feeder to the top of the container, whem it passes through the container inlet valve and falls by gravity into tie radwaste while the mixing blades are turning.

Dusting is minimized by pm-loading tre cement topper with a krown n ..: w . e . ..

volume of cement, as detenained by tre Waste Solidification Data Steet, and by tte use of a dust collecto r as a feature of the ent air filter subsystem (see 2.4).

3.0

ATTACIIMENT III Page 5 FOr, USE IN UNIT I ONLY yof;28;,

The cement container inlet valw and tre vent line are in integral part of the container fill lead assembly.

2.2.1 Eraulsifie r Feed (Oily Waste Only)

Liquid emulsifier is added using a small positiw dis-placement pump prio r to the addition of other liquid waste. The quantity of emulsifier required is detenained through ve rification testing.

2.3 Mixi ng a

Each liner is supplied with an internal mixing device designed to provide tie rough mixing of tie entire liner contents. A mixing moto r rao unted o n the top o f the li ne r p rio r to t he filli ng o pe ra-tion is sta rted prio r to the addition of cement. Mixing continues fo r appruximately twenty rainutes o r until the tacto r autoraatically trips off due to high resistance to mixing. The mixture will be completely firTa within 4 tours and be suitable fo r transpo rt.

2.4 Vent Ai r Filte r Subsystem The fill read also includes an elbowed vent line. The vent line is ha rd piped to the edge of the cask wfe re toses can be connected to allow tie air being vented f rom the cask to be conveyed ta tre ventilation system. The vent line on tre fill read is connected with flexible rose to a sealed 55 gallon drum used to detect an ina'dve rtent o w r flow of the line r. A liquid lewl sensor in the

- ,.u . . . . -

drum will activate an audible alana in the event that liquid enters the drum. The drum prewnts roisture intrusion into tie air filtration systera. The filtration system consists of flat fabric filters to remo ve pa rticulates (e specially cement dust) from the 4.0

ATTACilMENT III Page 6 e '-

QR I ig E ((Q IJls]lT i C)l4 LN

1104-281

, Revision 0 vent air. The vent air then goes through a HEPA and a charcoal filter before being discharged to the TMI-l Auxiliary Building. An auxiliary blower in the TM1-1 Auxiliary Buiding installed at the discharge of the vent line is installed to allow the vent line to be operated under a slight negative pressure.

3.0 COLLECTION AND ANALYSIS OF SAMPLES 3.1 General Requirements 3.1.1 As required by the Radiological Effluent Technical Specifications for PWR's and BWR's the PCP shall be used to verify the solifidication of at least one representa-tive test specimen from at least every tenth batch of each type of wet radioactive waste (e.g., evaporator

~

bottoms, boric acid solution,' sodium sulfate solutions, resin and precoat sludge).

3.1.2 For the purpose of the PCP a batch is defined as that quantity of waste required to fill a disposable liner to the waste level indicator.

3.1.3 If any test specimen fails to solidify, the batch under test shall be suspended until such time as additional test specimens can be obtained, alternative solidifica-tion parameters can be determined in accordance with the Process Control Program, and a subsequent. test verifies

.- _ _ sv. . -

solidification. Solidification of the batch may then be resumed using the alternate solidification parameters determined.

5.0 n

ATTACilMENT III Page 7 FC'R USE IN UNIT I ONLY 11a 281

. Revision 0 3.1.4 If the initial test specimen from a batch of waste fails to verify solidification then representative test speci-mens shall be collected from each consecutive batch of the same type of waste until the diree (3) consecutive initial test specimens demonstrate solidifications. The Process Control Program shall be modified as requires to assure solifidication of subsequent batches of waste.

3.1.5 For high activity wastes, such as spent resin or used precoat, where handling of samples could result in personnel radiation exposures which are inconsisent with the ALARA principle, representative non-radioactive samples will be tested. These samples should be as close to the actual waste and chemical properties as possible.

Typical unexpended mixed bed resin shall be used to simulate the spent bead resin and the appropriate mix of anion to cation powdered resin shall be used to simulate used precoat.

3.1.6 All Chemicals used to condition or solidify waste or simulated waste in solidification tests shall be repre-sentative of the actual chemicals to be used in full scale solidification. If chemicals of a different type

- or from a different manufacturer are used, the new material shall be tested to verify it produces a solid product prior to full scale solidification.

6.0

ATTACllMENT III i

Page 8

"'FOR USE IN UNIT I ONLY 1104-281 Revision 0 3.2 Collection of Samples 3.2.1 Radiological Protection 3.2.1.1 Comply with applicable Radiation Work Pemits.

3.2.1.2 Test samples which use actual waste shall be disposed of by solidification in the disposal liner.

3.2.1.3 A Waste Solidification Data Sheet will be maintained for each test sample solidified. Each Data Sheet will contain pertinent infomation on the test sample and the batch numbers of wastes solidified based on each test sample.

3.2.2 Waste Solidification Data Sheet TheWasteSolidificationDataSheetwillcontaInperti-nent infomation on the characteristics of the test sample solidified so as to verify solidification of subsequent batches of similar wastes without retesting.

3.2.2.1 a. The test sample data for concentrated waste will include, but not necessarily be limited to, the type of waste solidified, major constituents, percent solids, pH, volume of sample, amount of oil in sample and the ratio of the sample volume to the final volume of the solidification product.

b. The test sample data for spent resin and used

- : m .. r . ..

precoat will include, but not necessarily be limied to, the type of waste solidified, volume of sample

, and ratio of sample volume to the final volume of the solidified product.

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ATTACllMENT III Page 9

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FOR USE IN UNIT l ONLY 2o

,,l;28t o 3.2.2.2 Tre Waste Solidification Data Sheet will include the Batch Number, Batch Volume, and Data Solidified, for each batch v>1idified based on sample described.

i 3.2.3 0)llection of Samples 1

3.2.3.1 Evapo rato r bottoms shall be kept heated o r reteated to 130 7 p rio r to te sti ng .

NOTE: If the evapo rato r bottoms had previously been neutra- :

lized prio r to solidification to prewnt boric acid :

pr?cipitation the sample may be tested at ambient :

tempe ratu re s. :

3.2.3.2 Two samples shall be taken for analysis. One sample shall be compatible with the standard size sample used for the radioactivity analysis and the second for the cturaical analysi s. If the radioactivity levels are too high to penait full size samples to be taken then smaller samples shall be taken with tre results corrected acco rti-i ngly . Sample sizes shall be detennined by tre plant Radiological Control s staff.

3.2.3.3 Samples stould be drawn at least six tours prior to tre planned waste solidification procedure to allow adequate time to complete the required testing and verification of solidificatio n.

- ,- .3.R,3.4 The tank.containing the waste to be solidified stould be mixed by reci rculating tre tank contents fo r at least one volume change prio r to sampling to assure a representa-4 tive sample.

8. 0

-~ - . ,

ATTACHMENT III Page 10 OR USE Ux! UNIT I ONLY 21a-281 Re visio n 0 3.2.3.5 If the contents of mo re than one tank are to be solidi-fied in the same liner then representative samples of each tank stould be drawn. These samples stould be of such size that when mixed together they fona samples of standa ni size as presc ribed in Section 3.2.3.2. If the contents of a particular tank represents X percent of the total waste quantity to be solidified tien the sample of that tank stuuld be of such size to represent X percent of the composite samples.

4.0 TEST SOLIDIFICATION AND ACCEPTANCE CRITERIA 4.1 Waste Co nditioning 4.1.1 Fo r boric acid (up to 14 weight percent) prior to solidi-fication, tre pH of the sample stould be adjusted ts a range of 7.4 to 9.0 o r g reater than 11.6 with sodium hydroxide (NaOH) . The quantity of sodium tydroxide added shal1 be reco rded.

4.1.2 Fo r bead o r powde red resin, prio r to solidification the pH of the sample stould be adjusted to a range of 5 to 8 i f 11e tru Be ads a re used o r to a range o f 8 to 10 if they a re no t used . The quantity of sodium tydroxide used shall be reco rded.

4.1.3

- nn If foaming is apparent during the solidification testing

. :- s --

The quantity of anti-foaming agent required shall be reco rded.

9. 0

ATTACIDfENT III Page 11

' 'FOR USE IN UNIT I ONLY ito4-za Revision 0 4.1.4 If a floating oil film is present in quantities greater than 1 percent by volume, the oil should be broken up with Maysol or other emulsification agent. The quantity of emulsification agent added shall' be recorded.

4.1.5 If oily waste is to be solidified, an emulsifier shall be added to pretreat the waste sample as follows:

1. Allow one sample to stand undisturbed until the water / oil interface is clearly discernible and determine the percent by volume of the oil. If this volume is greater than 40 percent add a sufficient quantity of waste (or other aqueous liquid to be solidified) to reduce the percent of oil by volume to less than 40 percent. Use the Waste Calculation -

Data Sheet to determine the quantity of liquid to add. When the correct oil to water ratio is reached, measu,e and record the pH (pH paper may be used if a measurement cannot be made with a meter because of oil fouling).

2. Prior to the test sample solidification, the oily waste is treated with a predetermined quantity of emulsifier. For this application, Maysol 776 is used at a ratio of 1 part emulsifier to 5.1 parts

-- .a. -

oil by volume. The emulsifier has a density of one.

10 .0

ATTACIIMENT III Page 12

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TOR USE IN UNIT I ONLY 4 Lw;28;,,

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3. Af te r the emulsifie r is tro mughly mixed into the sample, a quantity of Metso Beads the weight of which is twice the weight of the emulsifier used, is mixed in thoroughly until the Metso Beads have completely dissolwd.

4.2 Test Solidification 4.2.1 Any sample to be solidified shall be pretreated as specified in Section 4.1.

4.2.2 Te st solidification sh)uld be conducted using a 1000 al.

disposal beake r o r simila r size containe r. Mixing stould be accomplished by stirring with a rigid stirmr until a tonogenous mixtu re is obtained, but in no case fo r 1 css than fiw (5) minute s. . -

4.2.3 Fo r the test solidification of resin, measure into two mixing wssels 90 ml of water each and add a sufficient quantity of dewaterud resin to yield a 390 mixture. The degree of compaction of the resin will detenaine tre volume o f re sin re qui md.

4.2.4 Fo r tre test solidification of precoat sludge, measure into two mixing vessels 300 gas of dewatered powdered resin each and add 100 gas of wate r.

4.2.5 Fo r the test solidification of Concentrated Waste

- n- :x e . . . . . .

(Evapo rato r B)ttoms), measu re into two mixing wssel s 400 ml of pH adjusted waste each.

11.0

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--.7 - ,__, -. , - - -

y _ -W - *"m ~

ATTACIDIENT III '

Page 13 )

l*h t USE l(4 Ui41T I O!x!W 1104-281 ,

, Revision 0 4.2.6 For the test solidification of Concentrated Waste and Oily Waste measure 320 ml of the waste to be solidified including the oily waste and pretreatment chemicals into the beaker. Measure out the required quantities of cement and Metso Beads as shown below. Volumes are for loose, uncompacted material.

Cement (grams) Metso Beads (grams)

Wa ste Sample A Sample B Sample A Sample B Bead Resin 189 236 19 24 Filters Sludge 230 260 46 52 Evaporator Bottoms 440 505 63 84.2

NOTE: Omit the following step if Metso Beads were pre- :

viously added. . : ,

4.2.7 Mix the cement and Metso Beads together and slowly add this mixture to the test sample while it is being stirred.

4.2.8 Af ter ten (10) minutes of mixing and a homogeneous mixture is obtained allow the waste to stand for a minimum of 4 hours4.62963e-5 days 0.00111 hours 6.613757e-6 weeks 1.522e-6 months .

4.3 Solidification Acceptability The following criteria define an acceptable solidification process and process parameters.

4.3.1 The sample solidification is considered acceptable if e .:..,.. .. r . . . . .

there is not visual or drainable free water.

12.0

ATTACIIMENT III Page 14

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FOR USE !N UNIT I ONLY 11a-281 Revision 0 4.3.2 The sample solidification is considered acceptable if upon visual inspection the waste appears 01at it would hold its shape if removed from the beaker and it resists penetration by a rigid stick.

4.4 Solidification Unacceptability 4.4.1 If the waste fails any of the criteria set forth in i

Section 4.3 the solidification will be termed unaccept-able and 6 new set of solidification parameters will need to be established under the procedures in Section 4.5.

4.4.2 If the test solidification is unacceptable then the same test procedure must be followed on each subsequent batch of the same type of waste until three consecutive test samples are solidified. -

4.5 Alternate Solidification Parameters I

4.5.1 If a test sample fails to provide acceptable solidifica-tion of waste the following procedures should be followed.

1. Mix equal volumes of dry cement and water to ensure 01at the problem if not a bad batch of cement.

2. Add additional caustic solution to raise the pH above 8.

3. If the waste (other than waste oil) is only par-tially solidified, use lower waste to cement and

- ~~ . . :. . . , :.. '

Metso ratios. Using the recommended quantities of cement and Metso Beads, reduce the waste sample volume 25 ml until die acceptability criteria of Section 4.3 are met.

I 13.0

,,,,r,

ATTACIBfENT-III 5 Page15"$<,, ,,;

?OR USE IN U-NIT l ONLY g;L '

If the waste oil mixture is or,1y partially solidi-

{

4. --

n fied try using lower waste to cement ratios. '. Reduce i ,

the quantity of waste by 20 ml and the emulsifier by 1 ml, (Tnis will result in a ilf @tlh[ higher concen-tration of emulsifier in the waste) and proceed with the test solidification. ' Contin'ue with 'fimilar y

~

reductions'until a satisfhetory product is achieved.

w .,

4.5.2 If the test sample fails to provide acce'ptable solidifi j . "+

<~ .

cation of waste following the actions of, Section C5.1

~

the following sample analysis snould be' perfqrmed. The

~

waste should fall within the acceptable range. s ,

= , .

I

.w 4

9q S

l

( 8-i

.~

li

) (

A.

f, 6

f g (

k

.r 14.0 'J -.

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a

!/* ATTACIDIENT III Page 16

' ~

iF.ORJ USE IN UNIT I ONLY 4

! vi;L8t,, o SA!PLE ANALYSIS i

Fo r Ib ric Acid .i.14 Weight Pe rcent (24000 ppm as B) pH 7.4 to 9.0 o r > 11.5 Pe rcent Bo ric Acid i 14 ppm. as Ib ro n i 24000 Oe te rge nts No appreciable foaming during agitation Oil (floating) < 1 pe rcent by volume fo r Be ad and Po wde red Re sin pH- >5 Dete rgente No appreciable foaming du ring agitatio n Oil (floating) < 1 pertent by volume -

Oily Waste Mixed with Evaporato r Bottoms pH >5 Pe rtent Bo ric Acid 1 14 (p rio r to mixing) ppa as Eb ru n 124000 (prior to mixing)

Oil 140 percent by volume i Dete rgents ib appreciable foaming du ring agitatio n l

l l

l w- .. :.m :. . --

e 15.0

~r - - . . - i,. ,. .

ATTACIDIENT III Page 17

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'FOR USE IN UNIT l ONLY ,Jof;28'

. O Batc h No . :

Sample No . :

Date:

WASTE SOLIDIFICATION DATA SHEET fo r 80 ric Acid Sample Volume, al: Sample A Sample B (1) pHl :

Quantity of 011 percent:

@antity o f Cement Added: Cement Ratio 2 : (No./ft3 Waste)

Sample A gas Sample A (2)

Sample B gms Sample B (3)

@antity of Additive 3 Adde d: Additive Ratio 4 : (No./ft3 Waste)

Sample A gas Sample A (4) .

Sample B gas Sample B (5)

Final Waste to Product Ratio: Sample A Sample B (6)

Product Acceptable: Sample A Ye s Ib (If no, refe r to Section 4.5 and proceed as directed)

Sampie B Ye s ib Radionu:lides Present: (Isotopes and Co ncentrations)

Additional batcies solidified based on this simple solidification:

Batch Batch Batch Batch Batc h Batc h

. No. .Vo l . ., Date. , No . Vo l . Date No. Vo l . Date 2 5 8 3 6 9 4 7 10 Test Solidifications Pe rfo rmed by: Date:

PCP Samples Appro wd by: Date:

16.0

ATTACHMENT III Page 18

' FOR USE IN UNIT I ONLY . 38'

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O NOTES 1 If pH adjustment is mquimd, note chemical used, quantity used and pH af te r adjustment.

2 Fo r the ratios giwn in Section 4.2.4, cement-to-waste ratios am 70.9 to 81 pounds cement per cubic foot of bo ric acid.

3 The additive used in this pmcess is antydmus sodium metasilicate as mfe mnced in the text.

4 Fo r the ratios giving in Section 4.2.4, additive-to-waste ratios am 10.1 to 13.5 pounds additie per cubic foot of bo ric acid.

O O pg ap -

p eng g see e

17.0

ATTACIDfENT III Page 19

?OR USE lN UNIT l ONLY n04-281 Revision 0 l

SOLIDIFICATION CALCULATION SHEET l 3 Waste Volume , ft - (1) 3 Cement Ratio, No./ft : Sample A (2A) j Sample B (2B)

Additive:

Additive Ratio, No./f t : Sample A: (3A)

Sample B: (38)

Cement Quantity 2 (1)I x (2A) = lbs. (4A)

I (1)I x (2B) = lbs. (4B) 2 Additive Quantity (1) x (3A) = lbs. (SA)

(1) x (3B) = lbs. (SB) 1 Tne quantity of waste to be solidified in a single liner cannot exceed the maximum waste volume listed on the attached Solidification Data Tables.

2 4A and SA define the minimum quantity of cement and additive respectively that must be mixed with the waste to assure solidification. When these quantities of materials are mixed, additional cement and additive are to be mixed until further mixing is not possible or the values in 4B and 5B are reached.

-- e --

s t

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! 18.0 e -mn n __ ,,-

ATTACIIMENT III Page 20

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FOR USE IN UNIT l ONLY -

1104-28:

Revision 0 Batch No.:

Sample No.:

Date:

WASTE SOLIDIFICATION DATA SHEET FOR OILY WASTE Volume percent Oils: percent (Maximum of 40 percent by volume)

Sample Volume, ml:

Major Composition of Non-oil Component:

Quantity of Emulsifier Added, ml:

pH:,

Quantity of Cement Added, gm: .

Quantity of Anhydrous Sodium Metasilicate Added, gm:

Final Product to Waste Ratio (Volumetric) percent ,

Product Acceptability: Acceptable Unacceptable If unacceptable note wny:

Radionuclides Present.

Isotopes and Concentrations

1. If the percent of oil in the sample exceeds the maximum allowable quantity the sample shall be diluted as required (See the Waste Calculation Data

. . Sheet).;._This new mixture,wil.1 be thoroughly mixed, tested for percent oil and a new sample taken from this mixture as per Section 4.2.3. The volume of dilutant required will be recorded.

19.0 c 1

ATTACHMENT III Page 21 70R USE IN UNlT l ONLY n04qss Revision 0 WASTE SOLIDIFICATION DATA SHEET FOR OILY WASTE l Complete Section A only if the initial samples shows oil in excess of 40 percent by volume, otherwise go to Section B.

SECTION A Step 1 Original samples volume ml. (1)

Volume pen:ent oil in sample 0. (as decimal fraction) (2)

Step 2 Sample volume (ml) multiplied by (2): =

(ml) X 0. = (ml) (3) i Step 3 Divide (3) by 0.4: + 0.4 = (4)

Step 4 Subtract original sample volume (1) from (4) to get quantity of liquid needed to dilute sample to 40 percent oil by volume:

(4) - (1) = ml (5)

SECTION B Step 1 Volume of waste in liner, gallons: (6)

(HN-100 liner contains 17.62 gallons / inch). The maximum allowable waste depth is 42 inches.

Step 2 If the volume percent oil is greater than 40 percent it is necessary to detennine the amount of liquid (i.e. water) that must be added to the liner to reduce the percent oil to less than 40 percent (If the fluid level in the liner is close to 42 inches such that the addition of any liquid would raise the fluid level above the 42 inches level proceed to Step 3).

Take the quantity of liquid (5), added to the test sample in Section A and divide it by the original sample volume (1).

Multiply this decimal fraction increase by the volume of fluid in the liner to obtain the quantity of liquid needed to dilute the contents of the liner to less than 40 percent oil by volume.

~ # ' '

T5)ini = 0.~ 'X'(6) gal = gal (7)

(1)ml 20.0

ATTACIDfENT III Page 22

'FOR USE IN UNIT l ONLY 1104-281 Revision 0 Calculate new fluid level in liner. Add (7) to (6) and divide by 17.62 gallons / inch and add this increased depth to the original fluid depth.

(6)+(7) gallons = inches (8) 17.62 gallons /incn (8)must not exceed 42 inches. If it does do not add any liquid to the liner but proceed to Step 3. If the fluid level (8) is less than or equal to 42" add the quantity of liquid calculated in (7) to the liner and proceed to Step 4.

Step 3 This step is to be completed only when the quantity of oil in the liner exceeds 40 percent by volume and diluting with water would raise the fluid level above 42 inches.

Multiply the original samples volume (1) by 0.4:

(1)(ml) X 0.4 = (9)

Subtract (9) from (3) above:

(3) - (9) = ml (10)

Divide (10) by the original sample volume (1) to obtain the -

decimal fractional decrease in sample oil volume to bring the percent oil down to 40 by volume.

(10) = 0. (11)

(1)

Multiply tne volume of waste in the liner (6) by this decimal fraction (11).

(6) X (11) = gallons (12)

This represents the quantity of oil that must be removed from the liner, and replaced by an equal volume of liquid waste, to bring the percent oil down below 40 percent by vol ume. To do this first allow the fluid in the liner to stand undisturbed for a period of 15 minutes and then tump oil out using a rubber hose extended into the liner to a level just below the top of the oil layer.

~ ~

S't'ep 4 ' I f'th' lab s"ampl'e shoWed' less than 40 percent oil by volume proceed without an additional sample and enter b: low the volume percent oil in the liner.

Vol. percent oil 0. (13) 21.0

. . . _ .m- , , , , , , ,,

ATTACllMENT III Page 23 7 i E IN UNIT l ONLY 1104-281 Revision 0 If liquid was added to dilute the oil (Step 2) or oil was removed (Step 3) mix the contents of the liner for 15 minutes and resample to confim the volume percent oil in the liner and enter below. (If not applicable enter N/A).

Resample Vol. percent oil 0. (14)

Measure the fluid level in the liner. Again this level must not exceed 42 inches.

Fluid level _ inches (15)

Calculate the quantity of oil in the liner by multiplying the fluid level (in inches) by the gallons per inch (17.62 gallons per inch) by the percent oil by volume from either (13) or (14).

gallons inches (15) X 17.62 inch X 0. (13 or 14) =

gallons (16)

Step 5 With the mixing motor "0N" add the emulsifier Maysol 776 at 1 part emulsifier to 5.1 parts oil by volume. To obtain the quantity of Maysol 776 required, divide the gallons of oil (16) by 5.1. -

(16) gallons = gallons of emulsifier (17) 5.1 gallons oil gallon emulsifier Continue mixing until the oil is completely mixed and the contents of the liner is a unifom milky white in appearance.

Record the mixing time.

minutes mixing Note that mixing times of up to 120 minutes may be required to completely emulsify some oils.

Step 6 For every gallon of fluid in the liner add 11.2 pounds of uncompacted cement. This is equivalent to 83.3 pounds of cement for every cubic foot of waste.

~

' f6'c'alculate"the'q05ntity of cement required multiply the fluid level (15) by 17.62 gallons per inch by 11.2 pounds cement per gallon of fluid.

(15) X 17.62 X 11.2 = pounds of cement (19) 22.0

ATTACIB!ENT III Page 24 TOR USE IN UNIT l ONLY Lol;28;,

Conve rt this to cubic feet o'floose cement by dividing (19) by 94 pounds per cubic foot.

(19) pounds = ft3 94 pounds per f t3 This is equivalent to the number of one f t3 bags re qui red .

Add the cement slowly while mixing continually until all the cement is added.

Step 7 Calculate the quantity of anhydrous sodium metasilicate to be added to the line r. F rom Sectio n 4.1.3, the wei g ht of the anhydrous sodium metasilicate is twice the weight of the emulsifie r. The density of the emulsifier is approximately equal to that of water, 62.4 pounds per cubic foot, (8.34 pounds per gallon). The refo re the antydrous sodium metasilicate will weigh twice as much as the emulsifie r.

pounds 2 X 8.34 gallon X (17) = po unds (18)

Add the Ibtso Beads slowly and continue mixing tte _

contents of the liner until all the antydrous sodium metasilicate has been added and the r:oto r trips due to high

resistance to mixing o r fo r 20 minutes after the last bag is adchd.

i l

vv- . .;-w :. . ~

23.0 t

r n - - ,

ATTACHMENT III Page 25

'?OR USE IN UNIT I ONLY o p,,f;28' , o Batc h No . :

Sample No . :

Date:

WASTE SOLIDIFICATION DATA SHEET fo r Powde red Resin Sample Volurae, ml: Sample A Sample B (1) pHl : Quantity of 011 pertent:

Otte r Majo r Constituents:

Quantity o f Cement Added: Cement Ratio 2 (No./f t3 Waste)

Sample A gas Sample A (2)

Sample B gms Sample B (3)

Quantity of Additive 3 Adde d: Additie Ratio 4 (No./f t3 Waste)

Sample A gms Sample I [4)

Sample B gas Sample B (5) l Pmduct Acceptable: Sample A Ye s ib (If no , re fe r to Sectio n 4.S and proceed as directed).

Sampie B Ye s tb Radionuclides Present: (Isotopes and Co ncentrations)

I Additional batetes solidified based on this simple solidification:

. Batch Ba tc h. ' Batch Batc h Batc h Batc h No. V51?'~ Date f4b '. ~ ~ Vo l . Date No. Vo l . Date 2 5 8 3 6 9 4 7 10 24.0

ATTACHMENT III l Page 26 j OR USE IN UNIT I ONLY tto4-281

~

Revision 0

. l FOOTNOTES t If pH adjust is required, note chemical used, quantity used and pH after adj ustment.

2 For the ratios given in Section 4.2.4, cement-to-waste ratios are 37.39 and 42.26 pounds per cubic foot of powdered resin. Note that the cement ratio for powdered resin is per cubic foot of waste; i.e., powdered resin plus water.

3 The additive used in this process is anhydrous sodium metasilicate as referenced in the text.

4 For the ratios given in Section 4.2.4, the additive-to-waste ratios are 7.47 and 8.45 pounds per cubic foot of powdered resin waste.

5 The following table shows the minimum and recomended mix ratios for a 300 gms sample size of 5 to 27 dry weight percent powdered resin:

Minimum Slurry Concentration, Cement Additive Cement Additive Dry Weight Percent (gms) (gms) (1b/f t3) (1b/ft3}

5-12 330 33.0 68.7 6.9 13-21 270 27.0 56.2 5.6 -

22-27 180 18.0 37.5 3.8 ,,

Recomended Cement Additive Cemen Additjve (gms) (gms) (1b/ftg) (1b/ft )

390 39.0 81.2 8.1 330 33.0 68.7 6.8 270 27.0 56.2 5.6

- . . :.m .. . -

e 25.0

1 ATTACIBIENT III Page 27

~FOF. USE IN UNIT i ONLY 8

. 2f;o'O v

SOLIDIFICATION CALCULATION SHEET l Waste Volume to be SlidifiedI-Cement Ratio, No./f t : Sample A (2A)

Sample B (28)

Additiw Ratio , No./f t : Sample A (3A)

Sample B (38) 2 Coment Quantity (1) X (2A) = lbs. (6A)

(1) X ( 28) = lbs. (68)

Additive Quantity 2 (1) X (3A) = lbs. (7A)

(1) X ( 38 ) = - lbs. (78 ) .

Quantity of Water to be added:

(1) X 2.36 = gallons (8)

Divide the Quantity of Water to be added (8) by the supply flowrate (9) to deternine tow long water siould be pumped to the disposal liner o r use a prepeasu red quantity of wate r.

(8) + gal / min (9) = minute s (10) 1 The quantity of waste to be solidifed in a single liner can not exceed tte maximum waste wlume listed on the attahed Solidification Data Table.

2 6A and 7A define the minimum quantity of cement and additie respectiwly that must be mixed with the waste to assure solidificatio n. When tiese quantities of materials are mixed, additional cement and additiw are to be mixed until fu rther mixing is not possible o r the values in 6B and 78 a re reac he d . _.,.. . -

26.0 t

ATTACHMENT III Page 28

, ~ .

~FOR tJSE IN UNIT l ONLY 1104-281 Revision 0 SOLIDIFICATION DATA TABLE POWDERED RESINS HN-600* HN-200**

Usable Liner Volume, f t3 65 57.

Max. Solidified Waste Vol. f t3 55.75 55.75 Max. Waste Vol. , f t3 42.4 42.4 Cement added at Max. Waste Vol.: Pounds 2532 2532 1 ft3 bags 26.9 26.9 Anhydrous Sodium Metasilicate Added at Max. Waste Vol.: Pounds 253 253 100 bags 2.5 2.5 Max. Radiation Level R/hr Contact 100 800

Based on 18" maximum deptn of filter sludge in-the liner and maximum - ,

cement and additive quantities. ,,

- Based on 34" maximum depth of filter sludge in the liner and maximum cement and additive quantities.

. . . .m . . --

27.0

ATTACHMENT III Page 29

" to

~FOR USE IN UNIT I ONLY .

,j;281 , ,

APPENDIX A CONCENTRATION OF POWDERED RESIN SLURRIES FOR PCP SOLIDIFICATION In o nde r fo r powdered resin slurry samples to be solidified in acco nfarre with this PCP, these samples must be concentrated to a higher weight percent so lid s. The simplest, easiest, and most accurate procedure to use is decanting, i.e. pouring off excess liquid until only a thin iner of liquid remains on the settled solids laye r. Dec anti ng i s to be pe rfo rmed af te r the sa:aple has been allowed to sit undisturbed for tw hours. The excess water is then poured off, being careful not to lose any solids. If the re is not eno ugh saaple to perfona tie PCP, the procedure is to be repeated until the required quantity i s obtained.

If the radiation level of the sample is too high for such handling, a decanting apparatus may be assembled much like that shown in Figure 1. The materials used depend upon availability and H.P. requireraents. This set up wuld allow fo r less physical handling of the sample by tre person perfo rming the test. The decant beaker siould ham the tube located at the 400 ral.

mark. A two to u r settli ng time i s re qui red. At that time, the stopcock (o r clamp) is opened to allow the liquid to drain off of the solids leer. If ro re than a thin laye r of water remains on the settled laye r, the sample will have to be decanted as described abo ve. Al so , if less than the required slurry quantity results, additional waste must be decanted in the same manner to the p re scrited arount.

Following this procedure will result in tre proper weight percent slurry as requi red by the PCP. H.P. requi rements will go ve rn which of the tw procedures stould be used.

i vv- ; ys. -

l 28.0

. S. .

i

71 ;

i O JJ t :-

l l' b__

t- CD i, .

I / FI

i. , -.

'T 1

., 4.,

C

/

Excess -l Liquid _

I

~

'o Settled . -

O O Waste /

~

thJ

! 1000 ml. Stopcock

. Decant Beaker '

1 1

to

, Rad ioa ct iv i Drain I

i l Figure 1. Decanting Apparatus Schematic w-CD ~

i

< O r nO

0) 1 WN o o) N>

Om ca R

, e OQ H 1 O (D >

O

{

i oE"2' w

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H H

t

ATTACHMENT III Page 31

~

FOR USE IN UNIT i ONLY tty;gt,o Batch No.:

Sample No.:

Date:

WASTE SOLIDIFICATION DATA SHEET for Bead Resin Sample Volume, ml: Sample A Sample B (1) pH(t)-

Quantity of 011 Percent:

Quantity of Cement Added: Cement Ratio 2 : (No./f t3 Waste)

Sample A gms Sample A (2A)

Sample B gms Sample B (28)

Quantity of Additive Added: Additive Ratio 3 : (No./ft3 Waste)

Sample A gms Sample A -

(3A) .

Sample B gms Sample B (3B)

Final Waste to Product Ratio: Sample A Sample B (4)

Product Acceptable: Sample A Yes No (If no, refer to Section 4.5 and proceed as directed).

Sample B Yes No Radionuclides Present: (Isotopes and Concentrations)

Additional batches solidified based on this sample solidification:

Batch Batch Batch Batch Batch Batch

-- - N o . . :Vol n . Date- .N o . Vol.- Date No. Vol. Date 2 5 8 3 6 9 4 7 10 PCP Perfortned by: Date:

Approved by: Date:

30.0

ATTACHMENT III Page 32

~ '

~FOR USE IN UNIT i ONLY yoj;281

. NOTES: i 1 pH is taken fo r info naation only. This may be useful in detennining additional steps to be taken in the event the sample solidificatfor: is unacceptable .

2 Fo r the ratios given is Section 4.2.4, cement-to-dewatemd msin ratios are 38 to 47.6 pounds of cement per cubic foot of dewatered resin for samples A and B respectiwly.

3 The weight of anhydmus sodium metasilicate is 10 percent of the ceraent 1 wei g ht. I l

O e

d-

/ Y

p-,~g,,',, , ,

e 31.0 a

[ ATTACHMEN III Page 33

~

~FOR USE IN UNIT I ONLY 22o4-281 Re vision 0 SOLIDIFICATION CALCULATION SHEET l

Re sin Volume ,: (1)

Cement Ratio , W./f t : Sample A (2A)

~

Sample B (28)

Additi ve:

Additive Ratio , No./f t : Sample A: (3A)

Sample B: (38)

Cement Quantity (1) x (2A) = lbs. (4A)

(1) x (2B ) = lbs. (4B)

Additive Quantity (1) x (3A) = lbs. (SA)

(1) x (38) = lbs. (58) ,

Quantity of Water to be added - gallons (Resin only):

(1) x 2.25 = (6)

Divide the Quantity of Water to be added (6) by the supply flowrate (7) to detenaine h3w long water stould be pumped to the disposal liner.

(6) + gal / min (7) = minute s (8) 1 The quantity of waste to be solidified in single liner canrot exceed the maximum resin volume listed on the attached Solidification Data Tables.

2 (4A) and (SA) define the minimum quantity of cement and additive respec-tively that must be mixed with the waste to assum solidification. When these quantities of materials am mixed, additional cement and additive am to be mixed until fu rther mixing is rot possible o r the values in (4B) and (SB) are mached.

c.- . . :. , - r ..

e 32.0 1

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