NRC-09-0021, National Pollutant Discharge Elimination System (NPDES) Permit Renewal

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National Pollutant Discharge Elimination System (NPDES) Permit Renewal
ML091180356
Person / Time
Site: Fermi DTE Energy icon.png
Issue date: 04/21/2009
From: Rachel Johnson
Detroit Edison
To:
Document Control Desk, Office of Nuclear Reactor Regulation
References
FOIA/PA-2010-0209, NRC-09-0021
Download: ML091180356 (72)


Text

Fermi 2 6400 North Dixie Hwy., Newport, M1 48166 Detroit Edison April 21, 2009 NRC-09-0021 U. S. Nuclear Regulatory Commission Attention: Document Control Desk Washington D C 20555-0001

Reference:

Fermi 2 NRC Docket No. 50-341 NRC License No. NPF-43

Subject:

National Pollutant Discharge Elimination System (NPDES)

Permit Renewal This letter transmits a copy of the National Pollutant Discharge Elimination System (NPDES) application for renewal of permit number M10037028, in accordance with Fermi 2 Facility Operating License, NPF-43, Appendix B, Section 3.2. The application for renewal was submitted to the Michigan Department of Environmental Quality Water Division.

There are no commitments included in this letter.

Should you have any questions or require additional information, please contact me at (734) 586-5076.

Sincerely, Rodney W. Johnson Manager, Nuclear Licensing Enclosure cc: NRC Project Manager NRC Resident Office Reactor Projects Chief, Branch 4, Region III Regional Administrator, Region III C)C [

Supervisor, Electric Operators, Michigan Public Service Commission IMe4g, A DTE Energy Company

Enclosure 1 to NRC-09-0021 National Pollutant Discharge Elimination System (NPDES)

I Renewal Application for Permit Number M10037028

Michigan Department of Environmental Quality- Water Bureau WASTEWATER DISCHARGE PERMIT APPLICATION SECTION I - General Information Section I shall be completed by all permit applicants. Instructions Water Bureau Use Only Cashier Use Only: 37000-40535-9412-481000-00 for completing Section I, Pages 1 and 2, are on Page 2 of the Appendix. To submit additional information, see Page ii, Item 3. Receipt #:

PLEASE TYPE OR PRINT I Permit ID #:

1 NPDES PERMIT NUMBER IvIIUUo /uL*o Applicant Name DTE Energy Address Address 2 or P.O. Box One Energy Plaza Room 655 G.O.

City State ZIP Code Cý Detroit Michigan 48226 Telephone (with area code) FAX (with area code) Applicant Web Address 1(313) 235-8704 (313) 235-5018 www:dteenergy:cdm Facility Name 1 Fermi 2 Power Plant Facility Name 2

_ Facility Name 3 C,_

,4, Street Address (do not use a P.O. Box Number) c, 6400 North Dixie Highway City State ZIP Code Newport Michigan 48166 Telephone (with area code) FAX (with area code) Facility Web Address (734) 586-5263 First Name, Last Name Mary Hana * '

[ Application Contact Title Business E] Facility Contact Senior Engineer - Environmental DTE Energy Corporate Services, LLC 0- Discharge Monitoring Reports Address I Address 2 0 Storm Water Billing One Energy Plaza Room 655 G.O.

El Biosolids Billing City State ZIP Code

[ NPDES Annual Billing Detroit Michigan 48226 Telephone (with area code) FAX (with area code) e-mail address (313) 235-8704. (313) 235-5018 hanamj@dteenergy.com First Name Last Name Joseph Plona El Application Contact Title Business

'[ Facility Contact Site Vice President -Nuclear Power Plant DTE Energy - Fermi 2 Power Plant

[4 Discharge Monitoring Reports Address 1 Address 2 O 0l Storm Water Billing 6400 North Dixie Highway 210 Fermi 2 NOC

, El Biosolids Billing City State ZIP Code Ej NPDES Annual Billing Newport Michigan 148166 Telephone (with area code) FAX (with area code) e-mail address

_(734) 586-5910 (734) 586-4172 plonaj@dteenergy.com First Name Last Name Valerie Byrd El Application Contact Title Business El Facility Contact Senior Engineer - Environmental DTE Energy Corporate Services, LLC

[ Discharge Monitoring Reports Address 1 Address 2 El Storm Water Billing 6400 North Dixie Highway 200 Fermi 2 TAC El Biosolids Billing City State ZIP Code E] NPDES Annual Billing Newport Michigan 48166 Telephone (with area code) FAX (with area code) e-mail address 1 (734) 586-5577 (734) 586-4208 byrdv@dteehergy.com I EQP 4659-A (Rev. 01/2009) NP2

Michigan Department of Environmental Quality- Water Bureau WASTEWATER DISCHARGE PERMIT APPLICATION SECTION I - General Information PLEASE TYPE OR PRINT FACILITY NAME NPDES PERMIT NUMBER Fermi 2 Power Plant LMI0037028

5. PERMIT ACTION REQUESTED (Check one box only) - Instructions for this item are on Page 2 of the Appendix.

17 NEW USE: A proposed discharge.

17 EXISTING DISCHARGE that is currently unpermitted.

[ REISSUANCE of current permit.

El MODIFICATION of current permit. Attach a description of the proposed modification.

Note: Applications for New Use discharges, Existing Discharges that are currently unpermitted, and for either Reissuance or Modification that include an increased loading of pollutants to the receiving water are required to submit a Rule 98 Demonstration with the Application. See Item 6.

6. RULE 98 - ANTIDEGRADATION REQUIREMENTS - Instructions for this item are on Page 2 of the Appendix.

In accordance with Rule 323.1098 of the Michigan Water Quality Standards, the applicant is required to submit an Antidegradation Demonstration for any new or increased loading of pollutants to the surface waters of the state. An Antidegradation Demonstration must contain the information specified in Rule 1098, outlined in the Antidegradation section of the Appendix. For assistance in completing this item, contact the Permits Section.

Will this discharge be an increased loading of pollutants to the surface waters of the state? [] Yes, continue below. Z No.

El Antidegradation Demonstration provided. El Increased loading of pollutants is exempt from Antidegradation Demonstration as indicated below:

El A short-term (weeks to months) or temporary lowering of water quality.

El Bypasses that are not prohibited by regulations set forth in 40 CFR §122.41(m).

El Response actions undertaken to alleviate a release of pollutants into the environment that may pose an imminent and substantial danger to the public health or welfare.

El Discharges of pollutant quantities from the intake water at a facility if the intake and discharge are to the same body of water.

El Increases in flow, if the increase is within the design flow of the facility, it is not specifically authorized in the current permit, and there is no significant change expected in the characteristics of the wastewater collected.

El Intermittent increased loading related to wet-weather conditions.

El New or increased loading due to MDEQ-approved controls related to wet-weather conditions.

El Discharges authorized by Certificates of.Coverage and Notices of Coverage.

El Increased loadings within the authorized levels of a limit in an existing control document, except those loadings that result from actions by the permittee that would otherwise require submittal of an increased use request.

El Increased loadings of a pollutant which do not involve Bioaccumulative Chemicals of Concern (BCC) and which use less than 10 percent of the unused loading capacity that exists at the time of the request.

7 ADDITIONAL FACILITY LOCATION INFORMATION - Instructions for this item are on Page 2 of the Appendix.

Local Unit of Government (LUG) LUG e-mail address Frenchtown Charter Township comments@frenchtownchartertwp.org Township B County Monroe Frenchtown Town Range Section Y4 1/4, 141/4 Private (French)'Land Claim 16S R10E 21 Latitude Longitude L41 deg. 57'45" 83 deg. 15' 30"

8. CERTIFIED OPERATOR Does the facility have anMDEQ-certifiedoperator? 0 Yes El No Instructions for this item are on Page 2 of the Appendix.

First Name Last Name Gregory Mulleavy Certification Number Certification Classification(s)

W6115 A-id, A-lh, B-2a, B-2c Address 1 Address 2 6400 North Dixie Highway 110 AIB City SEate Zip Code Newport Michigan ý48166 Telep~hone Number Fax Number e-mail address 1(734) 586-5039J mulleavyg@dteenergy.com 2 EQP4659-A (Rev. 01/2009) ,

Michigan Department of Environmental Quality- Water Bureau WASTEWATER DISCHARGE PERMIT APPLICATION SECTION I - General Information PLEASE TYPE OR PRINT FACILITY NAME NPDES PERMIT NUMBER Fermi 2 Power Plant M10037028

9. OTHER ENVIRONMENTAL PERMITS Provide the information requested below for any other federal, state, or local environmental permits in effect or applied for at the time of submittal of this Application Form, including, but not limited to, permits issued under any of the following programs: Air Pollution Control, Hazardous Waste Management, Wetlands Protection, Soil Erosion add Sedimentation Control, and other NPDES permits. To submit additional information, see Page ii, Item 3.

Issuing Agency Permit or COC Number Permit Type 1

MDEQ, Air Quality Division 462-99B Permit to Install MDEQ, GLMD 45-58-009-P Part 325 G.L Sub. Lands Mofnoe Metropdlitani Water Polluitik- Cbntfdl Facilitv 1020 Industinl User discharge Office of Monroe County Drain Commissioner 4177 SESC Dept. of the Army, US Army Corps of Engineers 88-001-040-8 Department of the Army

10. WATER FLOW DIAGRAM AND NARRATIVE DESCRIPTION Provide a flow diagram (using 81/2" x 11" paper if possible) showing the wastewater flow through the facility (from intake through discharge),

including all processes, treatment units including any lagoons or ponds used for wastewater treatment or storage (identify treatment units that operate intermittently), and bypass piping, and include a narrative description that explains the diagram. Show all operations contributing wastewater and the locations of flow meters, chemical feeds, and monitoring and discharge points. The water balance shall show the daily average flow rates at the intake and discharge points, and approximate daily flow rates between treatment units, including influent and treatment rates. Use actual measurements whenever available, otherwise use the best estimate. Show all significant losses of water to products, atmosphere, and discharge. In addition, provide a flow diagram for any storm water discharges from secondary structures that are required by state or federal law, and for storm water runoff from any Site of Environmental Contamination, pursuant to Part 201 of the Michigan Act.' Do not send blueprints.

Municipal Facilities - Include a narrative that briefly describes the history of the wastewater treatment facility and collection system, including the initial construction, the facility improvements that have been made, future plans for upgrade, the location of all constructed emergency overflows, and other pertinent information.

Industrial and Commercial Facilities - The line diagram shall include all operations contributing wastewater, including process and production areas, sanitary flows, cooling water, and storm water runoff. Also include a narrative that provides a brief description of the nature of the business and the manufacturing processes.

ATTACH THIS INFORMATION TO THIS APPLICATION. PLEASE DO NOT BIND THIS INFORMATION.

11. MAP OF FACILITY AND DISCHARGE LOCATION Provide a detailed map on 81/2," x 11" paper showing the location of the existing or proposed facility, wastewater and biosolid treatment system(s), and wastewater monitoring and discharge points into receiving waters (including bypasses). Include the exact location of the wastewater monitoring and discharge point(s) and all areas through which the discharge flows (e.g., wetlands, open drains, storm sewers), if applicable, between the discharge point and the receiving water. If the discharge is to a storm sewer, label the storm sewer and show its flow path to the receiving water. Also include the location of any water supply intakes or wells, and groundwater monitoring wells. This map shall be a United States Geological Survey quadrangle (7.5 minute series) or other map of comparable detail, scale, and quality (which shows surface water bodies, roads, bathing beaches, and other pertinent landmarks). It is preferred that the minimum area this map shall encompass is approximately one mile beyond the property boundaries.

ATTACH THIS INFORMATION TO THIS APPLICATION.

3 EQP 4659-A (Rev. 01/2009)

Michigan Department of Environmental Quality- Water Bureau WASTEWATER DISCHARGE PERMIT APPLICATION SECTION I - General Information PLEASE TYPE OR PRINT FACILITY NAME NPDES PERMIT NUMBER Fermi 2 Power Plant M10037028

12. CONTRACT LABORATORIES THAT PROVIDE ANALYTICAL SUPPORT Provide the name and address of each contract laboratory or consulting firm that performed any analyses submitted as part of this Application. To submit additional information, see Page ii, Item 3.

Laboratory Name Laboratory Name TriMatrix Laboratories, Inc.

Street Address Street Address 5560 Corporate Exchange Court SE City State ZIP Code City State ZIP Code Grand Rapids Michigan 49512 Telephone (with area code) Fax (with area code) Telephone (with area code) Fax (with area code)

(616) 975-4500 (616) 942-7463 FAnalysis Performed Analysis Performed SEE ATTACHED ANALYSES Laboratory Name Laboratory Name Street Address Street Address City State City- State City State Telephone (with area code) Fax (with area code) Telephone (with area code) Fax (with area code)

Analysis Performed Analysis Performed

13. LIST ADJACENT PROPERTY OWNERS List the names and mailing addresses of all property owners for all properties adjacent to the facility, treatment systems, and discharge locations. For vacant lots or empty buildings, supply the owner's mailing address - NOT the lot or building property address. To submit additional information, see Page ii, item 3.

Name Acidness City State ZIP Code SEE ATTACHMENT V 4 EQP 4659-A (Rev. 01/2009)

Michigan Department of Environmental Quality- Water Bureau WASTEWATER DISCHARGE PERMIT APPLICATION SECTION I - General Information PLEASE TYPE OR PRINT FACILITY NAME FNPDES PERMIT NUMBER Fermi 2 Power Plant MI0037028

14. APPLICATION CERTIFICATION Rule 323.2114(1-4), promulgated under the Michigan Act, requires that this Application must be signed as follows:

A. For an organization, company, corporation, or authority, by a principal executive office, vice president, or higher.

B. For a partnership, by a general partner.

C. For a sole proprietor, by the proprietor.

D; For a municipal, state, or other public facility, by a principal executive officer or ranking elected official (such as the mayor, village president, city or village manager, or clerk).

Note: Ifthe signatory is not listed above, but is authorized to sign the Application, please provide documentation of that authorization.

"1certify under penalty of law that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fine and imprisonment for having knowledge of violations."

The last application for this facility was submitted on: March 31. 2004 I understand that my signature constitutes a legal agreement to comply with the requirements of the NPDES Permit. I certify under penalty of law that I possess full authority on behalf of the legal ownerlpermittee to sign and submit this application.

Joseph H. Plona Site Vice Pres. Fermi 2 Plant Print Name:

Title:

Signature: K! /-* ,. Date: _ -_____,--______

This completesSection I. Publicly-Owned Treatment Works (POTWs) discharging sanitary and industrial wastewater to the surface waters, and privately-owned treatment works discharging sanitary wastewater to the, surface waters should complete Section I1. Privately-owned treatment works include, but are not limited to, Mobile Home Parks, Campgrounds, Condominiums, Hotels and Motels, Nursing Homes, etc. All other applicants should complete Section III. If assistance is needed to complete this Application, contact the Permits Section.

Permit Application Submittal Checklist Please confirm the following before submitting the Application Form:

0l 1.Section I has been completed, including all diagrams, maps, and the treatment process narrative.

[3 2. The Application-has been signed as required above in Section 1.14. (A.-D.) or a copy of the letter authorizing the signatory to sign the letter has been included, as appropriate.

0 3.Section II or Section III has been completed, including any additional information or submissions.

0D 4.Section IV has been completed by any facility that dischairges storm water.

17 5.Section V has been completed by any facility that is a Concentrated Animal Feeding Operation (CAFO).

E0 6. A check or Money Order for the appropriate Application Fee has been made out to the "State of Michigan" and has been included with the Application submittal.

5 EOP 4659-A (Rev. 01/2009)

Michigan Department of EnvirOnmental Quality- Water Bureau WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater Section III is to be completed by all facilities classified as Industrial or Commercial facilities. Industrial and Commercial facilities include, but are not limited to, facilities that discharge or propose to discharge a wastewater generated by a production process, a service provided, or through a remediation project. Municipal and public facilities are not required to complete Section III (unless requesting authorization for discharge's other than sanitary wastewater).

A. Facility Information PLEASE TYPE OR PRINT FACILITY NAME I PDES PERMIT NUMBER Fermi 2 Power Plant M10037028

1. BUSINESS INFORMATION El No Change From Last Application A. Provide up to four Standard Industrial Classification (SIC) or North American Industry Classification System (NAICS) codes, in order of economic importance, which best describe the major products or services provided by this facility.

1.4911 2. 3. - 4.

B. Indicate ifthis facility is a primary industry (refer to Table 1 of the Appendix to determine if this facility is a primary industry).

[ Yes. This facility is a primary industry. Indicate the primary industry as identified in Table 1 of the Appendix: Steam Electric Power El No. This facility is not a primary industry.

C. Is this facility a Concentrated Animal Feeding Operation (CAFO)?

El Yes. Continue with Section III.B.11.

[ No.

2. WATER SUPPLY AND DISCHARGE TYPE El No Change From Last Application A. Identify all water sources entering the facility and treatment systems, and provide average flows. The volume may be estimated from water supply meter readings, pump capacities, etc. Provide the name of the source where appropriate (i.e., Grand River, Lake Michigan, City of Millpond). To submit additional information, see Page ii, Item 3.

Name and Location of Source Averaae Volume or Flow Rate Units Municipal Supply Frenchtown Township 25 MGY Surface Water Intake Lake Erie 55 MGD Private Well Other: Precipitation 5 MGD B. Identify water discharged by the facility and treatment systems, and provide average flows. If water is first used for ýone purpose and then is subsequently used for another purpose, indicate the type and amount of the last use. For example, if water is initially used for nbncontact cooling water and then for process water, indicate the amount of process water. The amount of water from sources should approximate the amount of water usage. If they are different, provide an explanation.

Average Flow Rate Units Averaae Flow Rate Units Process Wastewater 11,625 MGY Sanitary Wastewater 34,000 GPD Contact Cooling Water Regulated Storm Water 2.6 MGD Noncontact Cooling Water High Pressure Test Water Groundwater Cleanup Other: Dredge Basin 19 MGY Note: For A and B above, indicate units as MGD (million gallons per day), MGY (million gallons per year), GPD (gallons per day), or other appropriate unit:

I EQP 4659-C (Rev. 01/2009)

Michigan Department of Environmental Quality- Water Bureau WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information Complete a separate Section III.B. - Outfall Information (Pages 19-24) - for each outfall at the facility. Make copies of this blank section of the Application as necessary for additional outfalls.

PLEASE TYPE OR PRINT FACILITY NAME NPDES PERMIT NUMBER OUTFALL NUMBER Fermi 2 Power Plant M10037928 001

1. OUTFALL INFORMATION - Instructions for this item are on Page 3 of the Appendix. E] No Change From Last Application, Items A. - D.

Receiving Water Hydrologic Unit Code (HUC)

A.

Ottawa Stony 04100001.

County Township B.

Monroe Frenchtown Town Range Section 1/4 " 1/4, Private (French) Land Claim)

C.

T6S R10E 21 NE NW D, Latitude Longitude 41.964843 -83.254496 E. Type of Wastewater Discharged (check all that apply to this outfall): El No Change From Last Application, Item E.

El Contact Cooling El Groundwater Cleanup E] Hydrostatic Pressure Test El Noncontact Cooling Water 0 Process Wastewater El Sanitary Wastewater El Storm Water - not regulated E] Storm Water - regulated El Storm water subject to effluent guidelines (indicate under which category):

El Other - specify (see "Table 8 - Other Common Types of Wastewater" - in the Appendix)

F. What is the Maximum Design Flow Rate for this outfall: 45. El No Change From Last Application, Items F. - G.

G What is the Maximum Authorized Discharge Seasonal Dischargers __ MGY (Continue with Item H).

Flow for this outfall for the next five years?

Continuous Dischargers- 45.1 MGD (Continue with Item I).

H. Seasonal Discharge:

List the discharge periods (by month) and the volume discharged in the space provided below.

'From Through Actual Discharge Volume (MGD) Annual Total From Through Actual Discharge Volume (MGD)

From Through Actual Discharge Volume (MGD)

From, Through Actual Discharge Volume (MGD)

I. Continuous Discharge:

How often is there a discharge from this outfall (on average).? 24 Hours/Day 365 Days/Year Batch dischargers are required to provide the following additional information:

Is there effluent flow equalization? El Yes El No Batch Peak Flow Rate: Number of batches discharged per day: __

Minimum Average Maximum Batch Volume (gallons)

Batch Duration (minutes) 2 EQP 4659-C (Rev. 01/2009)

Michigan Department of Environmental Quality- Water Bureau WASTEWATER DISCHARGE -PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information PLEASE TYPE OR PRINT FACILITY NAME I NPDES PERMIT NUMBER OUTFALL NUMBER Fermi 2 Power PlantI M10037028 001

2. PROCESS STREAMS CONTRIBUTING TO OUTFALL DISCHARGE Ej No Change From Last Application Federal regulations require that different industries report different information, depending on the type of facility. The information below is used to determine the applicable federal regulations for this facility. An abbreviated list is in the Summary of Information to be reported by Industry Type section of the Appendix. Applicants are required to provide the name and the SIC or the NAICS code for each process at the facility. Facilities with production-based limits must report an estimated annual production rate for the next five years, or the life of the permit. If the wastestream is not regulated under federal categorical standards, the~applicant is required to report all pollutants which have the reasonable potential to be present in the discharge. To submit additional information, see Page ii, Item 3.

PROCESS INFORMATION A. Name of the process contributing to the discharge: Closed-cycle Cooling System Blowdown B. SIC or NAICS code: 4911 C. Describe the process and provide measures of production:

Blowdown from the plant's Closed-cycle Condenser Cooling System cooling tower blowdown. Maximum expected discharge = 45 MGD.

PROCESS INFORMATION A. Name of the process contributing to the discharge: Monitoring Point 001D - Processed Radwaste Wastewater B. SIC or NAICS code: 4911 C. Describe the process and provide measures of production:

Processed Radwaste wastewater from the plant floor drains and equipment drains. Maximum anticipated flow = 216,000 GPD PROCESS INFORMATION A. Name of the process contributing to the discharge: Monitoring Point 001 E - Chemical & non-chemical metal cleaning waste B. SIC or NAICS code: 4911 C. Describe the process and provide measures of production:

Treated chemical and/or non-chemical metal cleaning wastes from the condenser and heat exchanger cleaning. Maximum anticipated flow = 500,000 GPD.

PROCESS INFORMATION A. Name of the process contributing to the discharge: __

B. SIC or NAICS code:

C. Describe the process and provide measures of production:

PROCESS INFORMATION A. Name of the process contributing to the discharge: __

B. SIC or NAICS code:

C. Describe the process and provide measures of production:

3 EQP 4659-C (Rev. 01/2009)

Michigan Department of Environmental Quality- Water Bureau WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information PLEASE TYPE OR PRINT FACILITY NAME NPDES PERMIT NUMBER OUTFALL NUMBER Fermi 2 Power Plant M10037028 001

3. EFFLUENT CHARACTERISTICS - CONVENTIONAL POLLUTANTS - Instructions for this item are on Page 4 of the Appendix.

0 Check this box if additional information is included as an attachment. To submit additional information, see Page ii, Item 3.

Please Note: Rule 323.1062 allows the use of either EscherichiaCoi or Fecal Coliform Bacteria as an indicator that effluent has been disinfected. The MDEQ will use the indicator selected below in the permit issued based on this Application. [] Use Escherichia Co/i as an indicator of]disinfection. El Use Fecal Coliform Bacteria as an indicator of disinfection.

- 3/4Maimu . axmum. Number bma* R s the.-*: o nthly, .. . Daily of via DMRj' R ion;le Behind the Request - .- ,Parameter,. Concentrationi Concentration. , Units. Analyses Sample Type'.

El Biochemical Oxygen Demand - five day (BOD 5) mg/I El Grab El 24 Hr Comp 0l Chemical Oxygen Demand (COD) mg/I El Grab El 24 Hr Comp El Total Organic Carbon (TOC) mg/I El Grab El 24 Hr Comp El Ammonia Nitrogen (as N) mg/I El Grab El 24 Hr Comp El Total Suspended Solids mg/I El Grab E] 24 Hr Comp El NA Total Dissolved Solids mg/I El Grabom El.24 Hr Comp El NA Total Phosphorus (as P) mg/I El Grab

[1 24 Hr Comp El NA Fecal Coliform Bacteria (report geometric means) Maximum-7day counts/1 00ml Grab El NA Escherichia Coli (report geometric means) Maximum-7day counts/100 ml Grab z 'NA Total Residual Chlorine E] mg/I Grab El itg/l Minimum daily El Grab.

El NA Dissolved Oxygen O mg/I El 2rCo

[-1 24 Hr: Comp 0Minimum Maximum standard units ]Ga r z pH (report maximum and minimum of individual samples)

El 24 Hr Comp 0 Temperature, Summer El IF EO 'C El Grab E] ,24 Hr Comp

[]Temperature, Winter El OF El °C El Grab El 24 Hr Comp El NA Oil & Grease mg/I Grab 4 EQP 4659-C (Rev. 0 1/2009)

Michigan Department of Environmental Quality- Water Bureau WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information PLEASE TYPE OR PRINT FACILITY NAME I NPDES PERMIT NUMBER OUTFALL NUMBER Fermi 2 Power Plant M10037028 001 Note: For questions on this page, Tables 1-5 are found in the Appendix.

4. PRIMARY INDUSTRY PRIORITY POLLUTANT INFORMATION Existing primary industries that discharge process wastewater are required to submit the results of at least one permittee-collected effluent analysis for selected organic pollutants identified in Table 2 (as determined from Table 1, Testing Requirements for Organic Toxic Pollutants by Industrial Category), and all of the pollutants identified in Table 3. Existing primary industries are required to also provide the results of at least one permittee-collected effluent analysis for any other chemical listed in Table 2 known or believed to be present in the facility's effluent.

In addition, submit the results of all other effluent analyses performed within the last three years for any chemical listed in Tables 2 and 3.

New primary industries that propose to discharge process wastewater are required to provide an estimated effluent concentration for any chemical listed in Tables 2 and 3 expected to be present in the facility's effluent.

5. DIOXIN AND FURAN CONGENER INFORMATION Existing industries that use or manufacture 2,3,5-trichlorophenoxy acetic acid (2,4,5-T); 2-(2,3,5-trichlorophenoxy) propanoic acid, (Silvex, 2,3,5-TP); 2-(2,4,5-trichlorophenoxy) ethyl 2,2-dichloropropionate (Erbon); 0,0-dimethyl 0-(2,4,5-trichlorophenyl) phosphorothionate (Ronnel);

2,4,5-trichlorophenol (TCP); or h exachlorophrene (HCP), or knows or has reason to believe that 2,3,7,8-Tetrachlorodibenzo-p-dioxin (TCDD) is present in the facility's effluent, are required to submit the results of at least one effluent analysis for the dioxin and furan congeners listed in Table 6. All effluent analyses for dioxin and furan congeners shall be conducted using USEPA Method 1613.

In addition, submit the results of all other effluent analyses performedwithin the last three years for any dioxin and furan congener listed in Table 6.

New industries that expect to use or manufacture 2,3,5-trichlorophenoxy acetic acid 12,4,5-T); 2-(2,3;5-trichlorophenoxy) propanoic acid (Silvex, 2,3,5-TP); 2-(2,4,5-trichlorophenoxy) ethyl 2,2-dichloropropionate (Erbon); 0,0-dimethyl 0-(2,4,5-trichlorophenyl) phbsphorothionate (Ronnel);

2,4,5-trichlorophenol (TCP); or hexachlorophrene (HCP), or knows or has reason to believe that 2,3,7,8-Tetrachlorodibenzo-p-dioxin (TCDD) is present in the facility's effluent, shall provide estimated effluent concentrations for the dioxin and furan congeners listed in Table 6.

6. OTHER INDUSTRY PRIORITY POLLUTANT INFORMATION Existing secondary industries, or existing primary industries that discharge nonprocess wastewater, are required to submit the results of at least one effluent analysis for any chemical listed in Tables 2 and 3 known or believed to be present in the facility's effluent.

In addition, submit the results of all other effluent analyses performed within the last three years for any chemical listed in Tables 2 and 3.

New secondary industries, or new primary industries that propose to discharge nonprocess wastewater, are required to provide an estimated effluent concentfation for any chemical listed in Tables 2 and 3 expected to be present in the facility's effluent.

7. ADDITIONAL TOXIC AND OTHER POLLUTANT INFORMATION All existing industries, regardless of discharge type, are required to provide the results of at least one analysis for any chemical listed in Table 4 known or believed to be present in the facility's effluent, and a measured or estimated effluent concentration for any chemical listed in Table 5 known or believed to be present in the facility's effluent. In addition, submit the results of any effluent analysis performed within the last three'years for any chemical listed in Tables 4 and 5.

New industries, regardless of discharge type, are required to provide an estimated effluent concentration for any chemical listed in Tables 4 and 5 expected to be present in the facility's effluent.

8. INJURIOUS CHEMICALS NOTPREVIOUSLY REPORTED New or existing industries, regardless of discharge type, are required to provide a measured or estimated effluent concentration for any toxic or otherwise injurious chemicals known or believed to be present in the facility's effluent that have not been previously identified in this Application..

Quantitative effluent data for these chemicals that is less than five years old shall be reported.

NOTE: All effluent data submitted in response to questions 4, 5, 6, 7, and 8 above should be recorded on Page 23. To submit additional information, see Page ii, Item 3. If the effluent concentrations are estimated, place an "E in the "Analytical Method" column. The following fields shall be completed for each data row: Parameter, CAS No., Concentration(s), Sample Type, and Analytical Method. For analytical test requirements, see Page ii,,Item 5.

If Alternate Test Procedures have been approved for any parameter listed above (Items 4 through 8), see Page ii, Item 5 for additional instructions.

5 EQP 4659-C (Rev. 01/2009)

Michigan Department of Environmental Quality- Water Bureau WASTEWATER DISCHARGE PERMIT APPLICATION

-SECTION III - Industrial and Commercial Wastewater B. Outfall Information PLEASE TYPE OR PRINT FACILITY NAME NPDES PERMIT NUMBER OUTFALL NUMBER Fermi 2 Power Plant M10037028 001 Submitted SAMPLE DATE -

via DMR's PARAMETER CAS Conc. Conc. Conc. Conc. Sample- Analytical No. . (pg/I) (pg/I) (pg/I) (pg/I) Type Method E SEE ATTACHMENT VI El El El El El El El El El El El El El

[] .

El El El El El El El 6 EQP 4659-C (Rev. 01/2009)

Michigan Department of Environmental Quality- Water Bureau WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information PLEASE TYPE OR PRINT FACILITY NAME NPDES PERMIT NUMBER I OUTFALL NUMBER Fermi 2 Power Plant M10037028I 001

9. WATER TREATMENT ADDITIVES Water treatment additives include any material that is added to water used at the facility or to wastewater generated by the facility to condition or treat the water.

Approvals of water treatment additives are authorized by the MDEQ under separate correspondence. The issuance of an NPDES permit does not constitute approval of the water treatment additives that are included in this Application.

A. Are there water treatment additives in the discharge from this facility?

[ Yes.

F- No. Proceed to Item 10.

B. Have these water treatment additives been.previously approved?

[ Yes. Submit a list of the previously-approved water treatment additives and the date on which they were approved. The information listed in Item C., Items 1-8 shall be updated if it has changed since the previous approval.

El No. Continue with Item C.

C. Submit a list of water treatment additives that are or may be discharged from the facility. Applicants are required to submit the information listed below for each additive.

1. The water treatment additive Material Safety Data Sheet
2. The proposed water treatment additive discharge concentration
3. The discharge frequency (i.e., number of hours per day, week, etc.)
4. The outfall from which the water treatment additive is to be discharged 5.- The type of removal treatment, if any, that the water treatment additive receives prior to discharge
6. The water treatment additive function (i.e., microbiocide, flocculant, etc.)
7. A 48-hour LC50 or EC50 for a North American freshwater planktonic crustacean (either Ceriodaphniasp., Daphniasp., or Simocephalus sp.)
8. The results of a toxicity test for one other North American freshwater aquatic species (other than a planktonic crustacean) that meets a minimum requirement of Rule 323.1057(2)(a) of the Water Quality Standards. Examples of tests that would meet this requirement include a 96-hour LC50 for rainbow trout, bluegill, or fathead minnow.

The required toxicity information (described in Items 7 and 8 above) is currently available in the Water Bureau files for the water treatment additives listed on the MDEQ's Internet page. To access that information, go to http://www.michigan.gov/deq, click on "Site Map," at the bottom of the right column under Water Quality Monitoring, click on "Assessment of Michigan Waters." Under the Information heading, click on the "Water Treatment Additive List." If you intend to use one of the water treatment additives on this list, only the information in Items 1 through 6 above needs to be submitted to the Water Bureau.

Note: The availability of toxicity information for a water treatment additive does not constitute approval to discharge the water treatment additive.

10. WHOLE EFFLUENT TOXICITY (WET) TESTS Have any acute or chronic WET tests been conducted on any discharges or receiving water(s) in relation to facility discharges within the .last three years? If yes, identify the tests and summarize the results on a separate sheet, unless the test has been submitted to the MDEQ in the last three years. For assistance with WET testing, see "Whole Effluent Toxicity Test Guidance and Requirements" in the Appendix. N/A
11. CONCENTRATED ANIMAL FEEDING OPERATION (CAFO) INFORMATION. (See Section V - Concentrated Animal Feeding Operations.) To be completed by CAFOs only. For additional information, see "CAFO Guidance and Requirements" in the Appendix.

N/A This completesSection III. Return the completed Application (Sections I, Ill, IV, and V, and any attachments) to one of the addresses on Page ii of this Application. If assistance is needed to complete this Application, contact the Permits Section.

7 EQP 4659-C (Rev. 01/2009)

Michigan Department of Environmental Quality- Water Bureau WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information Complete a separate Section III.B. - Outfall Information (Pages 19-24) - for each outfall at the facility. Make copies of this blank section of the Application as necessary for additional outfalls.

PLEASE TYPE OR PRINT FACILITY NAME NPDES PERMIT NUMBER OUTFALL NUMBER Fermi 2 Power PlantT M10037028 009

1. OUTFALL INFORMATION - Instructions for this item are on Page 3 of the Appendix. El No Change From Last Application, Items A. - D.

Receiving Water Hydrologic Unit Code (HUC)

A.

Lake Erie via Swan Creek 04100001 County Township B.

Monroe Frenchtown Town Range Section 1/4 1/4, 1/4 Private (French) Land Claim)

C.

T6S R10E 21 NE NW Latitude Longitude D.

41.962590 -83.261856 E. - Type of Wastewater Discharged (check .all that apply to this outfall): El No Change From Last Application, Item E.

El Contact Cooling El Groundwater Cleanup E] Hydrostatic Pressure Test El Noncontact Cooling Water 0 Process Wastewater El Sanitary Wastewater El Storm Water - not regulated Z Storm Water - regulated 0 Storm water subject to effluent guidelines (indicate under which category): Steam Electric Power El Other - specify (see "Table 8 - Other Common Types of Wastewater" - in the Appendix)

F. What is the Maximum Design Flow Rate for this outfall: 0.7: El No Change From Last Application, Items F. - G.

G What is the Maximum Authorized Discharge Seasonal Dischargers _ .MGY (Continue with Item H).

Flow for this outfall for the next five years?

Continuous Dischargers 0.72 MGD (Continue with Item.).

H. Seasonal Discharge:

List the discharge periods (by month) and the volume discharged in the space provided below.

From Through Actual Discharge Volume (MGD) Annual Total From Through Actual Discharge Volume (MGD)

From Through Actual Discharge Volume (MGD)

From Through Actual Discharge Volume (MGD)

1. Continuous Discharge:

How often is there a discharge from this outfall (on average)? 7 Hours/Day 1.2 Days/Year Batch dischargers are required to provide the following additional information:

Is there effluent flow equalization? El Yes El No Batch Peak Flow Rate: __ Number of batches discharged per day: __

Minimum Average Maximum Batch Volume (gallons)

Batch Duration (minutes) 1 EQP 4659-C (Rev. 01/2009)

Michigan Department of Environmental Quality- Water Bureau WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information PLEASE TYPE OR PRINT FACILITY NAME NPDES PERMIT NUMBER I OUTFALL NUMBER Fermi 2 Power Plant IM10037028I 009

2. PROCESS STREAMS CONTRIBUTING TO OUTFALL DISCHARGE El No Change From Last Application Federal regulations require that different industries report different information, depending on the type of facility. The information below is used to determine the applicable federal regulations for this facility. An abbreviated list is in the Summary of Information to be reported by Industry Type section of the Appendix. Applicants are required to provide the name and the SIC or the NAICS code for each process at the facility. Facilities with production-based limits must report an estimated annual production rate for the next five years, or the life of the permit. If the wastestream is not regulated under federal categorical standards, the applicant is required to report all pollutants which have the reasonable potential to be present in the discharge. To submit additional information, see Page ii, Item 3.

PROCESS INFORMATION A. Name of the process contributing to the discharge: Miscellaneous Low Volume Wastes B. SIC or NAICS code: 4911 C. Describe the process and provide measures of production:

Low volume wastes consisting of chemically treated cooling system water and other equipment drains. Maximum anticipated volume = 800,000 GPY. *see note below*

PROCESS INFORMATION A. Name of the process contributing to the discharge: Chemical Metal Cleaning Wastes B. SIC or NAICS code: 4911 C. Describe the process and provide measures of production:

Chemical metal cleaning wastes from the cleaning of piping or heat exchangers. Maximum anticipated volume = 500,000 GPY PROCESS INFORMATION A. Name of the process contributing to the discharge: Non-chemical Metal Cleaning Wastes B. SIC or NAICS code: 4911 C. Describe the process and provide measures of production:

Non-chemical metal cleaning wastes from the cleaning of piping and heat exchangers. Maximum anticipated volume 500,000 GPY PROCESS INFORMATION A. Name of the process contributing to the discharge: Storm Water B. SIC or NAICS code: 4911 C. Describe the process and provide measures of production:

Storm water from transformer containment areas and general storm drains. Maximum anticipated volume = 450,000 GPY.

PROCESS INFORMATION A. Name of the process contributing to the discharge:

B. SIC or NAICS code:

C. Describe the process and provide measures of production:

  • NOTE: This outfall consists of a 3 chambered unit. The effluent is manually pumped from the chamber(s) as required*

2¸ EQP 4659-C (Rev. 01/2009)

Michigan Department of Environmental Quality- Water Bureau WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information PLEASE TYPE OR PRINT FACILITY NAME NPDES PERMIT NUMBER I OUTFALL NUMBER Fermi 2 Power Plant "I M10037028I 009

3. EFFLUENT CHARACTERISTICS - CONVENTIONAL POLLUTANTS - Instructions for this item are on Page 4 of the Appendix.

0 Check this box if additional information is included as an attachment. To submit additional information, see Page ii, item 3.

Please Note: Rule 323.1062 allows the use of either Escherichia Coil or Fecal Coliform Bacteria'as an indicator that.effluent has been disinfected. The MDEQ will use the indicator selected below in the permit issued based on this Application. El Use Escherichia Coil as an indicator of disinfection. El Use Fecal Coliform Bacteria as!an indicator of disinfection.

Biochemical Oxygen Demand - five day (BOD 5 ) Li Grab mg/i 17 24 Hr Comr El Chemical Oxygen Demand (COD) mg/I El Grab

-El24 Hr Comp mg/I El Grab El Total Organic Carbon (TOC) E] 24 Hr Comp El Ammonia Nitrogen (as N) mg/I El Grab

[] 24 Hr Comp Total Suspended Solids mg/I E] Grab 0

El 24 Hr Comp El NA Total Dissolved Solids mg/I El Grab E] 24HrComp El NA Total Phosphorus (as P) mg/i El Grab El 24 Hr Comp El NA Fecal Coliform Bacteria (reportLgeometric means) Maximum-7day counts/100m! Grab El NA Escherichia Coil (report geometric means) Maximum-7day counts/100 ml Grab 0 NA Total Residual Chlorine El mg/I Grab El NA Dissolved Oxygen Minimum daily mg/I El Grab

___ El 24 Hr Comp Minimum Maximum []Ga 0 pH (report maximum and minimum of individual samples) standard units El Grab

_E 24 Hr Comp 0 0 El Temperature, Summer ambient ambient El F El C El Grab El 24 Hr Comp El Grab El Temperature, Winter ambient ambient El OF El °C E] 24 Hr Comp 0 NA Oil & Grease mg/i Grab 3 EOP 4659-C (Rev. 0 1/2009)

Michigan Department of Environmental Quality- Water Bureau WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information PLEASE TYPE OR PRINT FACILITY NAME NPDES PERMIT NUMBER OUTFALL NUMBER Fermi 2 Power PlantI M10037028I 009 Note: For questions on this page, Tables 1-5 are found in the Appendix.

4. PRIMARY INDUSTRY PRIORITY POLLUTANT INFORMATION Existing primary industries that discharge process wastewater are required to submit the results of at least orne permittee-collected effluent analysis for selected organic pollutants identified in Table 2 (as determined from Table 1, Testing Requirements for Organic Toxic Pollutants by Industrial Category), and all of the pollutants identified in Table 3. Existing primary industries are required to also provide the results of at least one permittee-collected effluent analysis for any other chemical listed in Table 2 known or believed to be present in the facility's effluent.

In addition, submit the results of all other effluent analyses performed within the last three years for any chemical listed in Tables 2 and 3.

New primary industries that propose to discharge process wastewater are required to provide an estimated effluent concentration for any chemical listed in Tables 2 and 3 expected to be present in the facility's effluent.

5. DiOxiN ANb FURAN CONGENER INFORMATION Existing industries that use or manufacture 2,3,5-trichlorophenoxy acetic acid (2,4,5-T); 2-(2,3,5-trichlorophenoxy) propanoic acid, (Silvex, 2,3,5-TP); 2-(2,4,5-trichlorophenoxy) ethyl 2,2-dichloropropionate (Erbon); 0,0-dimethyl 0-(2,4,5-trichlorophenyl) phosphorothionate (Ronnel);

2,4,5-trichlorophenol (TCP); or hexachlorophrene (HCP), or knows or has reason to believe that 2,3,7,8-Tetrachlorodibenzo-p-dioxin (TCDD) is present in the facility's effluent, are required to submit the results of at least one effluent analysis for the dioxin and furan congeners listed in Table 6. All effluent analyses for dioxin and furan congeners shall be conducted using USEPA Method 1613.

In addition, submit the results of all other effluent analyses performed within the last three years for any dioxin and furan congener listed in Table 6.

New industries that expect to use or manufacture 2,3,5-trichlorophenoxy acetic acid (2,4,5-T); 2-(2,3,5-trichlorophenoxy) propanoic acid (Silvex, 2,3,5-TP); 2-(2,4,5-trichlorophenoxy) ethyl 2,2-dichloropropionate (Erbon); 0,0-dimethyl 0-(2,4,5-trichlorophenyl) phosphorothionate (Ronnel);

2,4,5-trichlorophenol (TCP); or hexachlorophrene (HCP), or knows or has reason to believe that 2,3,7,8-Tetrachlorodibenzo-p-dioxin (TCDD) is present in the facility's effluent, shall provide estimated effluent concentrations for the dioxin and furan congeners listed in Table 6.

6. OTHER INDUSTRY PRIORITY POLLUTANT INFORMATION Existing secondary industries, or existing primary industries that discharge nonprocess wastewater, are required to submit the results of at least one effluent analysis for any chemical listed in Tables 2 and 3 known or believed to be present in the facility's effluent.

In addition, submit the results of all other effluent analyses performed within the last three years for any chemical listed in Tables 2 and 3.

New secondary industries, or new primary industries that propose to discharge nonprocess wastewater, are required to provide an estimated effluent concentration for any chemical listed in Tables 2 and 3 expected to be present in the facility's effluent.

7. ADDITIONAL TOXIC AND OTHER POLLUTANT INFORMATION All existing industries, regardless of discharge type, are required to provide the results of at least one analysis for any chemical listed in Table 4 known or believed to be present in the facility's effluent, and a measured or estimated effluent concentration for any chemical listed in Table 5 known or believed to be present in the facility's effluent. In addition, submit the results of any effluent analysis performed within the last three years for any chemical listed in Tables 4 and 5.

New industries, regardless of discharge type, are required to provide an estimated effluent concentration for any chemical listed in Tables 4 and 5 expected to be present in the facility's effluent.

8. INJURIOUS CHEMICALS NOT PREVIOUSLY REPORTED New or existing industries, regardless of discharge type, are required to provide a measured or estimated effluent concentration for any toxic or otherwise injurious chemicals known or believed to be present in the facility's effluent that have not been previously identified in this Application.

Quantitative effluent data for these chemicals that is less than five years old shall be reported.

NOTE: All effluent data submitted in response to questions 4, 5, 6, 7, and 8 above should be recorded on Page 23. To submit additional information, see Page ii, Item 3. If the effluent concentrations are estimated, place an "E in the "Analytical Method" column. The following fields shall be completed for each data row: Parameter, CAS No., Concentration(s), Sample Type, and Analytical Method. For analytical test requirements, see Page ii, Item 5.

If Alternate Test Procedures have been approved for any parameter listed above (Items 4 through 8), see Page ii, Item 5 for additional instructions.

4 EQP 4659-C (Rev. 01/2009)

Michigan Department of Environmental Quality- Water Bureau WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information PLEASE TYPE OR PRINT FACILITY NAME NPDES PERMIT NUMBER OUTFALL NUMBER Fermi 2 Power Plant M10037028 009 Submitted SAMPLE DATE +

via DMR's P/RETER'- - CAS . Conc. Conc:. Conc. Conc..':' Sample.: Analytical.

- . . .. .,.. N- .. (pg/I) -(pg/) (pg/I) ' (pgi) Type Method El SEE ATTACHMENT VIII El El El El El El El El E]

El El El E]

El El El El El El El El El El El El El___[_ ____

_5 EQP 4659-C (Rev. 01/2009)

Michigan Department of Environmental Quality- Water Bureau WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information PLEASE TYPE OR PRINT FACILITY NAME I NPDES PERMIT NUMBER I OUTFALL NUMBER Fermi 2 Power PlantI M10037028 009

9. WATER TREATMENT ADDITIVES Water treatment additives include any material that is added to water used at the facility or to wastewater generated by the facility to condition or treat the water.

Approvals of water treatment additives are authorized by the MDEQ under separate correspondence. The issuance of an NPDES permit does not constitute approval of the water treatment additives that are included in this Application.

A. Are there water treatment additives in the discharge from this facility?

[ Yes.

El No, Proceed to item 10.

B, Have these water treatment additives been previously approved?

[ Yes. Submit a list of the previously-approved water treatment additives and the date on which they were approved. The information listed in Item C., Items 1-8 shall be updated if it has changed since the previous approval.

El No. Continue with Item C.

C. Submit a list of water treatment additives that are or may be discharged from the facility. Applicants are required to submit the information listed below for each additive.

1. The water treatment additive Material Safety Data Sheet
2. The proposed water treatment additive discharge concentration
3. The discharge frequency (i.e., number of hours per day, week, etc.)
4. The outfall from which the water treatment additive is to be discharged
5. The type of removal treatment, if any, that the water treatment additive receives prior to discharge
6. The water treatment additive function (i.e., microbiocide, flocculant, etc.)
7. A 48=hour LC50 or EC50 for a North American freshwater planktonic crustacean (either Ceriodaphnia sp., Daphnia sp., or Simocephalus sp:)
8. The results of a toxicity test for one other North American freshwater aquatic species (other than a planktonic crustacean) that meets a minimum requirement of Rule 323.1057(2)(a) of the Water Quality Standards. Examples of tests that would meet this requirement include a 96-hour LC50 for rainbow trout, bluegill, or fathead minnow.

The required toxicity information (described in Items 7 and 8 above) is currently available in the Water Bureau files for the water treatment additives listed on the MDEQ's Internet page. To access that information, go to http://www.michigan.gov/deq, click on "Site Map," at the bottom of the right column under Water Quality Monitoring, click on "Assessment of Michigan Waters." Under the Information heading, click on the "Water Treatment Additive List." If you intend to use one of the water treatment additives on this list, only the information in Items 1 through 6 above needs to be submitted to the Water Bureau.

Note: The availability of toxicity information for a water treatment additive does not constitute approval to discharge the water treatment additive.

10. WHOLE EFFLUENT TOXICITY (WET) TESTS Have any acute or chronic WET tests been conducted on any discharges or receiving water(s) in relation to facility discharges within the last three years? If yes, identify the tests and summarize the results on a separate sheet, unless the test has been submitted to the MDEQ in the last three years. For assistance with WET testing, see "Whole Effluent Toxicity Test Guidance and Requirements" in the Appendix.
  • SEE ATTACHMENT VIII
11. CONCENTRATED ANIMAL FEEDING OPERATION (CAFO) INFORMATION. (See Section V - Concentrated Animal Feeding Operations.) To be completed by CAFOs only. For additional information, see "CAFO Guidance and Requirements" in theAppendix.

6 EQP 4659-C (Rev. 01/20

Michigan Department of Environmental Quality- Water Bureau WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information Complete a separate Section III.B. - Outfall Information (Pages 19-24) - for each outfall at the facility. Make copies of this blank section of the Application as necessary for additional outfalls.

PLEASE TYPE OR PRINT FACILITY NAME NPDES PERMIT NUMBER I OUTFALL NUMBER Fermi 2 Power PlantI MI0037028 I 011

1. OUTFALL INFORMATION - Instructions for this item are on Page 3 of the Appendix. El No Change From Last Application, Items A. - D.

Receiving Water Hydrologic Unit Code (HUC)

A.

Lake Erie via Swan Creek -04100001 County Township B.

Monroe Frenchtown Town Range Section 1/4 114, 1/4Y Private (French) Land Claim)

C.

T6S R10E 21 NE NW Latitude Longitude b.

41.962590 -83.261856 E. Type of Wastewater Discharged (check all that apply to this outfall): [I No Change From Last Application, Item E.

El Contact Cooling El Groundwater Cleanup El Hydrostatic Pressure Test El Noncontact Cooling Water 0 Process Wastewater El Sanitary Wastewater El Storm Water - not regulated 0 Storm Water - regulated 0 Storm water subject to effluent guidelines (indicate under which category): Steam Electric Power Generation El Other - specify (see "Table 8 - Other Common Types of Wastewater" - in the Appendix) __

F. What is the Maximum Design Flow Rate for this outfall: 15 El No Change From Last Application, Items F. - G.

G What is the Maximum Authorized Discharge Seasonal Dischargers __ MGY (Continue with Item H).

Flow for this outfall for the next five years?

Continuous Dischargers 15 MGD (Continue with Item I).

H. Seasonal Discharge:

List the discharge periods (by month) and the volume discharged in the space provided below.

From Through Actual Discharge Volume (MGD) Annual Total From Through Actual Discharge Volume (MGD)

From Through Actual Discharge Volume (MGD)

From Through Actual Discharge Volume (MGD)

1. Continuous Discharge:

How often is there a discharge from this outfall (on average)? 24 Hours/Day 365 Days/Year Batch dischargers are required to provide the following additional information:

Is there effluent flow equalization? El Yes El No Batch Peak Flow Rate: __ Number of batches discharged per day:

Minimum Average Maximum Batch Volume (gallons)

Batch Duration (minutes)

I EQP 4659-C (Rev. 01/2009)

Michigan Department of Environmental Quality- Water Bureau WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information PLEASE TYPE OR PRINT FACILITY NAME NPDES PERMIT NUMBER OUTFALL NUMBER Fermi 2 Power Plant M10037028I 011O

2. PROCESS STREAMS CONTRIBUTING TO OUTFALL DISCHARGE Ej No Change From Last Application Federal regulations require that different industries report different information, depending on the type of facility. The information below is used to determine the applicable federal regulations for this facility. An abbreviated list is in the Summary of Information to be reported by Industry Type section of the Appendix. Applicants are required to provide the name and the SIC or the NAICS code for each process at the facility. Facilities with production-based limits must report an estimated annual production rate for the next five years, or the life of the permit. If the wastestream is not regulated under federal categorical standards, the applicant is required to report all pollutants which have the reasonable potential to be present in the discharge. To submit additional information, see Page ii, Item 3.

PROCESS INFORMATION A. Name of the process contributing to the discharge: Monitoring Point 011 C - Oily Waste Treatment B. SIC or NAICS code: 4911 C. Describe the process and provide measures of production:

Low volume waste consisting of the effluent from the treatment of oily waste water from floor, equipment and yard drains. Maximum anticipated flow 73,000 GPD. *NOTE - Currently Inactive*

PROCESS INFORMATION A. Name of the process contributing to the discharge: Service Water Screen Back Wash B. SIC or NAICS code: 4911 C. Describe the process and provide measures of production:

Intake screen and strainer backwash from general service pump house. Maximum anticipate flow 7.0 MGD.

PROCESS INFORMATION A. Name of the process contributing to the discharge: Storm Water B. SIC or NAICS code: 4911 C. Describe the process and provide measures of production:

Storm water from area near Fermi 1 Power plant main personnel parking lot. Maximum anticipated flow = 730,000 GPD.

PROCESS INFORMATION A. Name of the process contributing to the discharge: Fire Protection Flushwater B. SIC or NAICS code: 4911 C. Describe the process and provide measures of production:

Fire fighting system pressurization water blowoff. Maximum anticipated flow = 3.6 MGD.

PROCESS INFORMATION A. Name of the process contributing to the discharge: General Service Water Flow Control B. SIC or NAICS code: 4911 C. Describe the process and provide measures of production:

Fermi 1 Power Plant General Service Water System Blowoff. Maximum anticipated flow = 1.00 MGD 2 EQP 4659-C (Rev. 01/2009)

Michigan Department of, Environmental Quality- Water Bureau WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information PLEASE TYPE OR PRINT FACILITY NAME NPDES PERMIT NUMBER OUTFALL NUMBER Fermi 2 Power Plant M10037028 Oil

3. EFFLUENT CHARACTERISTICS - CONVENTIONAL POLLUTANTS - Instructions for this item are.on Page 4 of the Appendix.

0 Check this box if additional information is included as an attachment. To submit additional information, see Page ii, Item 3.

Please Note: Rule 323.1062 allows the use of either Escherichia Coil or Fecal Coliform Bacteria as an indicator thateffluent has been disinfected. The MDEQ will use the indicator selected belowin the permit issued based on this Application. E] Use Escherichia Coil as an indicator of disinfection. 0l Use Fecal Coliform Bacteria as an indicator of disinfection.

Li urao El Biochemical Oxygen Demand - five day (BODs) mg/I El 24 Hr Comp mg/I EGrab El Chemical Oxygen Demand (COD) 0 24 Hr Comp EU Total Organic Carbon (TOC) mg/I El Grab E] 24 Hr Comp mg/I EGrab U Ammonia Nitrogen (as N)

El 24 Hr Comp El Grab

[] 24 Hr Comp NA Total Dissolved Solids mg/I Grab mI 24 Hr Comp mg/I E Grab U NA Total Phosphorus (as P)

El 24 Hr Comp FU NA Fecal Coliform Bacteria (report geometric means) Maximum-7day counts/1 00ml Grab U NA Escherichia Coli (report geometric means) Maximum-7day counts/100 ml Grab EU NA NA Total Residual Chlorine Dissolved Oxygen Minimum daily El U

mg/I

__E_g/I mg/I E Grab Grab Nv 24 Hr Comp Minimum Maximum stnad nt Grabr pH (report maximum and minimum of individual samples) standard units El[ 24 Hr Comp 0

El Temperature, Summer ambient ambient U F E 0C 0 Grab E_ 24 Hr Comp U Temperature, Winter ambient ambient EU 0 F n 0C E Grab E] 24 Hr Comp 0 NA Oil & Grease mg/I Grab I ROP 46S9-C, (Rev. ni/q.nng)

Michigan Department of Environmental Quality- Water Bureau WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information PLEASE TYPE OR PRINT FACILITY NAME NPDES PERMIT NUMBER OUTFALL NUMBER Fermi 2 Power Plant M10037028I 011 Note: For questions on this page, Tables 1-5 are found in the Appendix.

4. PRIMARY INDUSTRY PRIORITY POLLUTANT INFORMATION Existing primary industries that discharge process wastewater are required to submit the results of at least one permittee-collected effluent analysis for selected organic pollutants identified in Table 2 (as determined from Table 1, Testing Requirements for Organic Toxic Pollutants by Industrial Category), and all of the pollutants identified in Table 3. Existing primary industries are required to also provide the results of at least one permittee-collected effluent analysis for any other chemical listed in Table 2 known or believed to be present in the facility's effluent.

In addition, submit the results of all other effluent analyses performed within the last three years for any chemical listed in Tables 2 and 3.

New primary industries that propose to discharge process wastewater are required to provide an estimated effluent concentration for any chemical listed in Tables 2 and 3 expected to be present in the facility's effluent.

5. DIOXIN AND *UPANq CONGiENE INFORMATION Existing industries that use or manufacture 2,3,5-trichlorophenoxy acetic acid (2,4,5-T); 2-(2,3,5-trichlorophenoxy) propanoic acid, (Silvex, 2,3,5-TP); 2-(2,4,5-trichlorophenoxy) ethyl 2,2-dichioropropionate (Erbon); 0,0-dimethyl 0-(2,4,5-trichlorophenyl) phosphorothionate (Ronnel);

2,4,5-trichiorophenol (TCP); or hexachlorophrene (HCP), or knows or has reason to believe that 2,3,7,8-Tetrachlorodibenzo-p-dioxin (TCDD) is present in the facility's effluent, are required to submit the results of at least one effluent analysis for the dioxin and furan congeners listed in Table 6. All effluent analyses for dioxin and furan congeners shall be conducted using USEPA Method 1613.

In addition, submit the results of all other effluent analyses performed within the last three years for any dioxin and furan congener listed in Table 6.

New industries that expect to use or manufacture 2,3,5-trichlorophenoxy acetic acid (2,4,5-T); 2-(2,3,5-trichlorophenoxy) propanoic acid (Silvex, 2,3,5-TP); 2-(2,4,5-trichlorophenoxy) ethyl 2,2-dichloropropionate (Erbon); 0,0-dimethyl 0-(2,4,5-trichlorophenyl) phosphorothionate (Ronnel);

2,4,5-trichlorophenol (TCP); or hexachlorophrene (HCP), or knows or has reason to believe that 2,3,7,8-Tetrachlorodibenzo-p-dioxin (TCDD) is present in the facility's effluent, shall provide estimated effluent concentrations for the dioxin and furan congeners listed in Table 6.

6. OTHER INDUSTRY PRIORITY POLLUTANT INFORMATION Existing secondary industries, or existing primary industries that discharge nonprocess wastewater, are required to submit the results of at least one effluent analysis for any chemical listed in Tables 2 and 3 known or believed to be present in the facility's effluent.

In addition, submit the results of all other effluent analyses performed within the last three years for any chemical listed in Tables 2 and 3.

New secondary industries, or new primary industries that propose to discharge nonprocess wastewater, are required to provide an estimated effluent concentration for any chemical listed in Tables 2 and 3 expected to be present in the facility's effluent.

7. ADDITIONAL TOXIC AND OTHER POLLUTANT INFORMATION All existing industries, regardless of discharge type, are required to provide the results of at least one analysis for any chemical listed in Table 4 known or believed to be present in the facility's effluent, and a measured or estimated effluent concentration for any chemical listed in Table 5 known or believed to be present in the facility's effluent. In addition, submit the results of any effluent analysis performed within the last three years for any chemical listed in Tables 4 and 5.

New industries, regardless of discharge type, are required to provide an estimated effluent concentration for any chemical listed in Tables 4 and 5 expected to be present in the facility's effluent.

8. INJURIOUS CHEMICALS NOT PREVIOUSLY REPORTED New or existing industries, regardless of discharge type, are required to provide a measured or estimated effluent concentration for any toxic or otherwise injurious chemicals known or believed to be present in the facility's effluent that have not been previously identified in this Application.

Quantitative effluent data for these chemicals that is less than five years old shall be reported.

NOTE: All effluent data submitted in response to questions 4, 5, 6, 7, and 8 above should be recorded on Page 23. To submit additional information, see Page ii, Item 3. If the effluent concentrations are estimated, place an "E in the "Analytical Method" column. The following fields shall be completed for each data row: Parameter, CAS No., Concentration(s), Sample Type, and Analytical Method. For analytical test requirements, see Page ii, Item 5.

If Alternate Test Procedures have been approved for any parameter listed above (Items 4 through 8), see Page ii, Item 5 for additional instructions.

4 EQP 4659-C (Rev. 01/2009)

Michigan Department of Environmental Quality- Water Bureau WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information -

PLEASE TYPE OR PRINT FACILITY NAME NPDES PERMIT NUMBER OUTFALL NUMBER Fermi 2 Power Plant M10037028 0i1 Submittedva MRs ....5*"" * , ,** *#: SAMPLE DATE + "

vi M' vi MRsPARANIETER> CAS ~ onic. coc ~Co;-,c-(4) Sariiple

-rpe'

~Ana!ýicAil El SEE ATTACHMENT iX El El El El 171 El El El El El El El El El El El El El.

El El El El El El El1 5 EQP 4659-C (Rev. 01/2009)

I Michigan Department of Environmental Quality- Water Bureau WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information PLEASE TYPE OR PRINT FACILITY NAME NPDES PERMIT NUMBER OUTFALL NUMBER Fermi 2 Power Plant M10037028I 011

9. WATER TREATMENT ADDITIVES Water treatment additives include any material that is added to water used at the facility or to wastewater generated by the facility to condition or treat the water.

Approvals of water treatment additives are authorized by the MDEQ under separate correspondence. The issuance of an NPDES permit does not constitute approval of the water treatment additives that are included in this Application.

A. Are there water treatment additives in the discharge from this facility?

0 Yes.

EO No. Proceed to Item 1.0.

B. Have these water treatment additives been previously approved?

E Yes. Submit a list of the previously-approved water treatment additives and the date on which they were approved: The information listed in Item C., Items 1-8 shall be updated if it has changed since the previous approval.

El No. Continue with Item C.

C. Submit a list of water treatment additives that are or may be discharged from the facility. Applicants are required to submit the information listed below for each additive.

1. The water treatment additive Material Safety Data Sheet
2. The proposed water treatment additive discharge concentration
3. The discharge frequency (i.e., number of hours per day, week, etc.)
4. The outfall from which the water treatment additive is to be discharged
5. The type of removal treatment, if any, that the water treatment additive receives prior to discharge
6. The water treatment additive function (i.e., microbiocide, flocculant, etc.)
7. A 48-hour LC50 or EC50 for a North American freshwater planktonic crustacean (either Ceriodaphniasp., Daphnia spj or Simocephalus sp;)
8. The results of a toxicity test for one other North American freshwater aquatic species (other than a planktonic crustacean) that meets a minimum requirement of Rule 323.1057(2)(a) of the Water Quality Standards. Examples of tests that would meet this requirement include a 96-hour LC50 for rainbow trout, bluegill, or fathead minnow.

The required toxicity information (described in Items 7 and 8 above) is currently ayailable in the Water Bureau files for the water treatment additives listed on the MDEQ's Internet page. To access that information, go to http://www.michigan.gov/deq, click on "Site Map," at the bottom of the right column under Water Quality Monitoring, click on "Assessment of Michigan Waters." Under the Information heading, click on the "Water Treatment Additive List." If you intend to use one of the water treatment additives on this list, only the information in Items 1 through 6 above needs to be submitted to the Water Bureau.

Note: The availability of toxicity information for a water treatment additive does not constitute approval to discharge the water treatment additive.

10. WHOLE EFFLUENT TOXICITY (WET) TESTS Have any acute or chronic WET tests been conducted on any discharges or receiving water(s) in relation to facility discharges within the last. three years? If yes, identify the tests and summarize the results on a separate sheet, unless the test has been submitted to the MDEQ in the last three years. For assistance with WET testing, see "Whole Effluent Toxicity Test Guidance and Requirements" in the Appendix.

N/A

11. CONCENTRATED ANIMAL FEEDING OPERATION (CAFO) INFORMATION. (See Section V - Concentrated Animal Feeding Operations.) To be completed by CAFOs only. For additional information, see "CAFO Guidance and Requirements" in the Appendix.

N/A 6 EQP 4659-C (Rev. 01/20

Michigan Department of Environmental Quality- Water Bureau WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information Complete a separate Section II.B. - Outfall Information (Pages 19-24) - for each outfall at the facility. Make copies of this blank section of the Application as necessary for additional outfalls.

PLEASE TYPE OR PRINT FACILITY NAME NPDES PERMIT NUMBER OUTFALL NUMBER 013 I MI0037028 Fermi 2 Power Plant

1. OUTFALL INFORMATION - Instructions for this item are on Page 3 of the Appendix. El No Change From Last Application, Items A. - D.

Receiving Water Hydrologic Unit Code (HUC)

A.

Lake Erie 04100001 County Township B.

Monroe Frenchtown Town Range Section ,/ 4, , Private (French) Land Claim)

C.

T6S R10E 21 SE NW Latitude Longitude D.

41.954244 -83.259636 E. Type of Wastewater Discharged (check all that apply to this outfall): El No Change From Last Application, Item E.

El Contact Cooling El Groundwater Cleanup El Hydrostatic Pressure Test El Noncontact Cooling Water E] Process Wastewater El Sanitary Wastewater El Storm Water - not regulated El Storm Water - regulated El Storm water subject to effluent guidelines (indicate under which category):

[ Other - specify (see "Table 8 - Other Common Types of Wastewater" - in the Appendix) Dredging Effluent F. What is the Maximum Design Flow Rate for this outfall: 5.5 E] No Change From Last Application, Items F. - G.

G What is the Maximum Authorized Discharge Seasonal Dischargers 450 MGY (Continue with Item H).

Flow for this outfall for the next five years?

Continuous Dischargers _ MGD (Continue with Item I).

H. Seasonal Discharge:

List the discharge periods (by month) and the volume discharged in the space provided below.

From Through Actual Discharge Volume (MGD) Annual Total From Through Actual Discharge Volume (MGD)

From Through Actual Discharge Volume (MGD)

From Through Actual Discharge Volume (MGD)

1. Continuous Discharge:

How often is there a discharge from this outfall (on average)? 24 Hours/Day 24 Days/Year Batch dischargers are required to provide the following additional information:

Is there effluent flow equalization? El Yes El No Batch Peak Flow Rate: Number of batches discharged per day: __

Minimum Average Maximum Batch Volume (gallons)

Batch Duration (minutes) 1 EQP 4659-C (Rev. 01/2009)

Michigan Department of Environmental Quality- Water Bureau WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information PLEASE TYPE OR PRINT FACILITY NAME NPDES PERMIT NUMBER OUTFALL NUMBER Fermi 2 Power Plant MI0037028I 013

2. PROCESS STREAMS CONTRIBUTING TO OUTFALL DISCHARGE El No Change From Last Application Federal regulations require that different industries report different information, depending on the type of facility. The information below is used to determine the applicable federal regulations for this facility. An abbreviated list is in the Summary of Information to be reported by Industry Type section of the Appendix. Applicants are required to provide the name and the SIC or the NAICS code for each process at the facility. Facilities with production-based limits must report an estimated annual production rate for the next five years, or the life of the permit. If the wastestream is not regulated under federal categorical standards, the applicant is required to report all pollutants which have the reasonable potential to be present in the discharge. To submit additional information, see Page ii, Item 3.

PROCESS INFORMATION A. Name of the process contributing to the discharge: Treatment of Dredge Spoils/Water Overflow B. SIC or NAICS code: 4911 C. Describe the process and provide measures of production:

Overflow from the settling of dredged materials from the lake bottom in the plant intake canal. Maximum anticipated flow 450 MGY.

PROCESS INFORMATION A. Name of the process contributing to the discharge: __

B. SIC or NAICS code:

C. Describe the process and provide measures of production:

PROCESS INFORMATION A. Name of the process contributing to the discharge:

B. SIC or NAICS code:

C. Describe the process and provide measures of production:

PROCESS INFORMATION A. Name of the process contributing to the discharge: __

B.' SIC or NAICS code:

C.. Describe the process and provide measures of production:

PROCESS !NFORMATION A. Name of the process contributing to the discharge:

B. SIC or NAICS code:

C. Describe the process and provide measures of production:

2 EQP 4659-C (Rev. 01/2009)

Michigan Department of Environmental Quality- Water Bureau WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information PLEASE TYPE OR PRINT FACILITY NAME NPDES PERMIT NUMBER I OUTFALL NUMBER Fermi 2 Power Plant M10037028I 013

3. EFFLUENT CHARACTERISTICS - CONVENTIONAL POLLUTANTS - Instructions for this item are on Page 4 of the Appendix.

0 Check this box if additional information is included as an attachment. To submit additional information, see Page ii, Item 3.

Please Note: Rule 323.1062 allows the use of either Escherichia Coil or Fecal Coliform Bacteria as an indicator that effluent has been disinfected. The MDEQ will use the indicator selected below in the permit issued based on this Application. E] Use EscherichiaCoil as an indicator of disinfection. El Use Fecal Coliform Bacteria as an indicator of disinfection.

E] Grab 17 Biochemical Oxygen Demand - five day (BOD 5 ) mg/I I-1 24 Hr Com#

El Chemical Oxygen Demand (COD) mg/I El Grab El 24 Hr Comp El Total Organic Carbon (TOC) mg/I El Grab El 24 Hr Comp El Ammonia Nitrogen (as N) mg/I El Grab El 24 Hr Comp 0 Total Suspended Solids mg/I El Grab El 24 Hr Comp Nl NA Total Dissolved Solids mg/I El Grab El 24 Hr Comp El NA Total Phosphorus (as P) mg/I El Grab El 24 Hr Comp El NA Fecal Coliform Bacteria (report geometric means) Maximum-7day counts/100ml Grab

'El NA Escherichia Coil (report geometric means) Maximum-7day counts/100 ml Grab El NA Total Residual Chlorine El mg/I Grab

_Elýg/l El NA Dissolved Oxygen R Minimum daily mg/I El Grab

_ El-- 24 Hr Comp 0Minimum pH (report maximum and minimum of individual samples) Maximum F1Ga units Elstandard Hr Comp 0

El Temperature, Summer ambient ambient El F [E °C E. Grab El 24 Hr Comp El Temperature, Winter ambient ambient El °F El °C El Grab El 24 Hr Comp El NA Oil & Grease mg/I Grab I F,0P 46.59-C. (Rev. 0 1 /9.009)

Michigan Department of Environmental Quality-Water Bureau WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information PLEASE TYPE OR PRINT FACILITY NAME NPDES PERMIT NUMBER OUTFALL NUMBER Fermi 2 Power PlantI M10037028 013 Note: For questions on this page, Tables 1-5 are found in the Appendix.

4. PRIMARY INDUSTRY PRIORITY POLLUTANT INFORMATION Existing primary industries that discharge process wastewater are required to submit the results of at least one permittee-collected effluent analysis for selected organic pollutants identified in Table 2 (as determined from Table 1, Testing Requirements for Organic Toxic Pollutants by Industrial Category), and all of the pollutants identified in Table 3. Existing primary industries are required to also provide the results of at least one permittee-collected effluent analysis for any other chemical listed in Table 2 known or believed to be present in the facility's effluent.

In addition, submit the results of all other effluent analyses performed within the last three years for any chemical listed in Tables 2 and 3.

New primary industries that propose to discharge.process wastewater are required to provide an estimated effluent concentration for any chemical listed in Tables 2 and 3 expected to be present in the facility's effluent.

5. DIOXIN AND FURAN CONGENER INFORMATION Existing industries that use or manufacture 2,3,5-trichlorophenoxy acetic acid (2,4,5-T); 2-(2,3,5-trichlorophenoxy) propanoic acid, (Silvex, 2,3,5-TP); 2-(2,4,5-trichlorophenoxy) ethyl 2,2-dichloropropionate (Erbon); 0,0-dimethyl 0-(2,4,5-trichlorophenyl) phosphorothionate (Ronnel);

2,4,5-trichlorophenol (TCP); or hexachlorophrene (HCP), or knows or has reason to believe that 2,3,7,8-Tetrachlorodibenzo-p-dioxin (TCDD) is present in the facility's effluent, are required to submit the results of at least one effluent analysis for the dioxin and furan congeners listed in Table 6. All effluent analyses for dioxin and furan congeners shall be conducted using USEPA Method 1613.

In addition, submif the results of all other effluent analyses performed within the last three years for any dioxin and furan congener listed in Table 6.

New industries that expect to use or manufacture 2,3,5-trichlorophenoxy acetic acid (2,4,5-T); 2-(2,3,5-trichlorophenoxy) propanoic acid (Silvex, 2,3,5-TP); 2-(2,4,5-trichlorophenoxy) ethyl 2,2-dichloropropionate (Erbon); 0,0-dimethyl 0-(2,4,5-trichlorophenyl) phosphorothionate (Ronnel);

2,4,5-trichlorophenol (TCP); or hexachlorophrene (HCP), or knows or has reason to believe that 2,3,7,8-Tetrachlorodibenzo-p-dioxin (TCDD) is present in the facility's effluent, shall provide estimated effluent concentrations for the dioxin and furan congeners listed in Table 6.

6. OTHER INDUSTRY PRIORITY POLLUTANT INFORMATION Existing secondary industries, or existing primary industries that discharge nonprocess wastewater, are required to submit the results of at least one effluent analysis for any chemical listed in Tables 2 and 3 known or believed to be present in the facility's effluent.

In addition, submit the results of all other effluent analyses performed within the last three years for any chemical listed in Tables 2 and 3.

New secondary industries, or new primary industries that propose to discharge nonprocess wastewater, are required to provide an estimated effluent concentration for any chemical listed in Tables 2 and 3 expected to be present in the facility's effluent.

7. ADDITIONAL TOXIC AND OTHER POLLUTANT INFORMATION All existing industries, regardless of discharge type, are required to provide the results of at least one analysis for any chemical listed in Table 4 known or believed to be present in the facility's effluent, and a measured or estimated effluent concentration for any chemical listed in Table 5 known or believed to be present in the facility'.s effluent. in addition, submit the results of any effluent analysis performed within the last three years for any chemical listed in Tables 4 and 5.

New industries, regardless of discharge type, are required to provide an estimated effluent concentration for any chemical listed in Tables 4 and 5 expecied to be present in the facility's effluent.

8. INJURIOUS CHEMICALS NOT PREVIOUSLY REPORTED New or existing industries, regardless of discharge type, are required to provide a measured or estimated effluent concentration for any toxic or otherwise injurious chemicals known or believed to be present in the facility's effluent that have not been previously identified in this Application.

Quantitative effluent data for these chemicals that is less than five years old shall be reported.

NOTE: All effluent data submitted in response to questions 4, 5, 6, 7, and 8 above should be recorded on Page 23. To submit additional information, see Page ii, Item 3. If the effluent concentrations are estimated, place an "E in the "Analytical Method" column. The following fields shall be completed for each data row: Parameter, CAS No., Concentration(s), Sample Type, and Analytical Method. For analytical test requirements, see Page ii, Item 5.

If Alternate Test Procedures have been approved for any parameter listed above (Items 4 through 8), see Page ii, Item 5 for additional instructions.

4 EQP 4659-C (Rev. 01/2009)

Michigan Department of Environmental Quality- Water Bureau WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information PLEASE TYPE OR PRINT FACILITY NAME NPDES PERMIT NUMBER OUTFALL NUMBER Fermi 2 Power Plant M10037028 013 Submitted SAMPLE DATE 4 CiS CM' C)riC. KCc.

CVonn& Ctonc.~ Conc.~ Sa-ple~ ~Analytir,-A

~No.>ý -- 4j~I y" -(jo/gJI),) (p/ Type hqd t.M El SEE ATTACHMENT X El El F1 El El El El El El El El El El 0l El El El

,[]

F--1 El El El El El El El El 5 EQP 4659-C (Rev. 01/2009)

Michigan Department of Environmental Quality- Water Bureau WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information PLEASE TYPE OR PRINT FACILITY NAME NPDES PERMIT NUMBER OUTFALL NUMBER Fermi 2 Power PlantI M10037028I 013

9. WATER TREATMENT ADDITIVES Water treatment additives include any material that is added to water used at the facility or to wastewater generated by the facility to condition or treat the water.

Approvals of water treatment additives are authorized by the MDEQ under separate correspondence. The issuance of'an NPDES permit does not constitute approval of the water treatment additives that are included in this Application.

A. Are there water treatment additives in the discharge.from this facility?

0 Yes.

El No; Proceed to Item 10.

B. Have these water treatment additives been previously approved?

Z Yes. Submit a list of the previously-approved water treatment additives and the date on which they were approved. The information listed in Item C., Items 1-8 shall be updated if it has changed since the previous approval.

El No. Continue with Item C.

C. Submit a list of water treatment additives that are or may be discharged from the facility. Applicants are required to submit the information listed below for each additive.

1. The water treatment additive Material Safety Data Sheet
2. The proposed water treatment additive discharge concentration
3. The discharge frequency (i.e., number of hours per day, week, etc.)
4. The outfall from which the water treatment additive is to be discharged
5. The type of removal treatment, if any, that the water treatment additive receives prior to discharge
6. The water treatment additive function (i.e., microbiocide, flocculant, etc.)
7. A 48=hour LC50 or EC50 for a North American freshwater planktonic crustacean (either Ceriodaphnia sp., Daphnia sp., or Simocephalus sp:)
8. The results of a toxicity test for one other North American freshwater aquatic species (other than a planktonic crustacean) that meets a minimum requirement of Rule 323.1057(2)(a) of the Water Quality Standards. Examples of tests that would meet this requirement include a 96-hour LC50 for rainbow trout, bluegill, or fathead minnow.

The required toxicity information (described in Items 7 and 8 above) is currently available in the Water Bureau files for the water treatment additives listed on the MDEQ's Internet.page. To access that information, go to http://www.michigan.gov/deq, click on "Site Map," at the bottom of the right column under Water Quality Monitoring, click on "Assessment of Michigan Waters." Under the Information heading, click on the "Water Treatment Additive List." If you intend to use one of the water treatment additives on this list, only the information in Items 1 through 6 above needs to be submitted to the Water Bureau.

Note: The availability of toxicity information for a water treatment additive does not constitute approval to discharge the water treatment additive.

10. WHOLE EFFLUENT TOXICITY (WET) TESTS Have any acute or chronic WET tests been conducted on any discharges or receiving water(s) in relation to facility discharges within the last three years? If yes, identify the tests and summarize the results on a separate sheet, unless the test has been submitted to the MDEQ in the last three years. For assistance with WET testing, see"Whole Effluent Toxicity Test Guidance and Requirements" in the Appendix.

N/A

11. CONCENTRATED ANIMAL FEEDING OPERATION (CAFO) INFORMATION. (See Section V - Concentrated Animal Feeding Operations.) To be completed by CAFOs only. For additional information, see "CAFO Guidance and Requirements" in the Appendix.

N/A 6 EQP 4659-C (Rev. 01/20

Michigan Department of Environmental Quality- Water Bureau WASTEWATER DISCHARGE PERMIT APPLICATION SECTION IV- Storm Water PLEASE TYPE OR PRINT FACILITY NAME 'NPDES PERMIT NUMBER Fermi 2 Power Plant I M10037028

1. STORM WATER DISCHARGES Facilities that discharge storm water must provide the followinginformation. (Please Note: The following discharges are also covered by storm water authoriz ation provided they are addressed in the facility's Storm Water Pollution Prevention Plan [SWPPP]): Discharges from fire hydrant flushing; potable water sources, including water line flushing; fire system test water; irrigation drainage; lawn watering; routine buil"ding wash down which does not use detergents or other compounds; pavement wash waters where spills or leaks of toxic or hazardous materials have not occurred (unless all spilled material has been removed) and where detergents are not used; air conditioning condensate; springs; uncontaminated grotund water; and foundation or footing drains where flows are not contaminated with process materials such as solvents. Unless otherwise specified, answer the following questions.

A. Is the storm water from this facility discharged to the waters of the state either directly or through another conveyance? Note: If storm water is discharged to a municipal wastewater treatment system or a privately-owned activated sludge treatment system, check the "No" box.

0 Yes.

El No.

B. Is the facility iden-tified in this application primarily engaged in an "industrial activity" as defined in 40 CFR 122.26(b)(14)?

l] Yes.

ElNo.

C. Are there any industrial activities or materials exposed to storm water at this facility? Storm water discharge requirements may be excluded from an NPDES permit when there are no industrial activities or materials exposed to storm water. To qualify, the applicant shall certify that the facility has met all the eligibility requirements to claim a condition of "no exposure". These requirements are found in the No-Exposure Certification form in the Appendix. This form is also available on the MDEQ's Internet Page. To access the form, go to http://www.michiqan.qov/dea. In the left column click on WATER, click on Surface Water, click on Storm Water, in the middle column click on Industrial Program, then click on No-Exposure Certification.

0 Yes.

El No. Complete the No-Exposure Certification form in the Appendix and submit it with this Application.

D. Does this facility have a current and up-to-date SWPPP?

0 Yes.

El No. Note: The applicant must complete this program element to receive storm water discharge authorization.

E. Has the facility implemented the nonstructural controls described in the SWPPP?

0 Yes.

0l No. Note: The applicant must complete this program element to receive storm water discharge authorization.

F. Have all the structural controls described in the SWPPP been constructed and put into operation?

0 Yes.

El No. Note: The applicant must complete this program element to receive storm water discharge authorization.

G. Does this facility have a certified industrial storm water operator who supervises the facility's storm water treatment and control measures included in the Storm Water Pollution Prevention Plan?

0 Yes. Valerie Byrd 107392 Storm Water Operator Name Certification Number El No. Note: The applicant must complete this program element to receive storm water discharge authorization.

H. Is any of the storm water discharged from (check all that apply):

0 Secondary containment structures that are required by state or federal law. On a separate page, provide a list of the materials that are stored in this area.

El Areas identified on Michigan's list of Sites of Environmental Contamination, pursuant to the Natural Resources and Environmental Protection Act, PA 451 of .1994, Part 201 (formerly 307).

I. The storm water from this facility discharges to the following receiving water(s): Lake Erie, Swan Creek Please note that applicants should provide any sample data taken of the storm water discharge as an attachment. To submit additional information, see Page ii, Item 3.

1'Fn~P 4659-C. rRev 0 1/2009)

Detroit Edison, Fermi 2 Personnel Certifications with State of Michigan, Department of Environmental Quality March 16, 2009 Attachment I NPDES Permit Application for Reissuance Fermi 2 Power Plant M10037028 Name Certificate.# A-la A-lb A-id A-'lh A-li A-lj A-2b B-lb B-2a B-2c Expiration Valerie S. Byrd 1 07392 X 2009 C 10174 X 2009 Kyle Bogle W6093 X X X X 2012 Steven K. W2460 X X X 2011 Labudda Gregory W6115 X X X X 2012 Mulleavy John Tansek W6149 X. X X X 2012 John M. W3579 X X X X X X 2011 Yokom

Attachment 11 Average rinaý, ~n~ V1rx i~~

7 NPDES Perrnit Annlicat ion for Reissuane* , 1.9x0 GPD To Lake Erie via SauthLa non Fe m 2 Po r Plant M[10037028 Lake Erie (Evaporation& Drift) 5.Sxi06 GPD 9.9x105 GPD 2,300 GPD Outfall 013 utfall 12 5.5 x 107 GPD (Evaporation& Drift)

Dredged] Fenni I Mat' Storm General **

Storage I Sewer Basin Systemn 200 GPD * - -- ~Service Water *

&TAC area -System (GSWS) Natural Draft CoolingTowers C owers Fenni I T Froin Ferhij 2 14,300 GPD (2)1 Power (Make-up) RHR Complex (2)

Plant Frenehtown I1I 106 GI'D Ferni I & 2 Flash City Water recirc during 1.2 ,l08 GPD Tank outages Sanitary 300

  • 25i 000 GPD System GP 6

4.8 X1 0 GPD Plant GSWS 115,200GPDi 1."055x lO GPD _. __ Ti aveling Ser een- Pump I 1 (Evaporation)

Internal [ Fermi & CWS Strainer Ba ckwash Potable Monroe County Auxilia ry Make-up (As needed) Circulating Sewer System Boiler Q 7,000 GPD Water Fermi 2 Plant Reservoir Auxilia ry Dernineralizer Systems.

Boiler -Reverse Osmosis

.GPD_ 0/C Fermi I Oily Currenlly inactive Waste System Waste fr om Fermi 2 (I'Oil, 4

Greasee t,) Rea, Reactor Bldg.g Fm Fermi 2 Processed Radwaste 7.2x10 GPD (currently inactive O01D Fermi I Stonn Sewer System Storm Sewer .

Dewatering SHoldinl g Groundwater System ROWaste.Sanitary RO ....  :, r2,000GPD Pond Sewer 3

7 2,00! 1,uuatt currently UU0, inactive 5.6x10 GPD Outfit 110 09 5 1 U Condenser Chem & Non- 5.0 x10 GPD 1.858 X106 Gpp Fermi I Overflow Canal 4.5 xl07 GPD Outfall 011 *_* Chemn Cleaning Waste To Lake Erie via _ _

Nuclear Operations 100 GPD To Lake Erie via 5,0001GPD- 004 Swan Cree Outfa 11 Canal 001-A to Lake Erie Center Groundwater to- 8,000:GPD- 007 Dewatering System Outfall 004 QuarryLakes 8,000:GPD- 005 Nuclear Operations Center Stornwater Runoff EF2_flow._2006 2 Modified 03132009 MJH

Attachment III NPDES Permit Application for Reissuance Fermi 2 Power Plant M10037028 Narrative Description Fermi 2 Power Plant is a 1,150-megawatt electric General Electric Boiling Water Reactor 4 Nuclear Power Plant. The Fermi 2 power block is situated in the Northeast Quartet of a 1,120-acre site that is located approximately 8 miles east-northeast of Monroe, Michigan.

The water sources for the Fermi 2 Power Plant are municipal water supplied by Frenchtown Township water and lake water withdrawn from Lake Erie.

Water discharges from the plant as a result of electric power generation and support processes include:

cooling tower blowdown, reverse osmosis wastes, chemical and non-chemical metal cleaning wastes, processed radwaste waste, low volume wastes, storm water runoff, treated oily wastewater, intake and strainer backwash water, firefighting system pressurization water, settled water from dredge material storage, and sanitary waste water.

Cooling tower blowdown, residual heat removal system service water, chemical and non-chemical metal cleaning wastes, and processed radwaste water are discharged from Outfall 001 to Lake Erie.

Storm water runoff, low volume wastes, and chemical and non-chemical metal-cleaning wastes are discharged from Outfall 009 to Lake Erie via Swan Creek.

Treated oily waste water, firefighting system pressurization water, intake screen and strainer backwash water, and storm water are discharged from Outfall 011 to Lake Erie via Swan Creek.

Settled water from the dredge material storage basin is discharged from Outfall 013 to Lake Erie.

Sanitary wastewater is composed of oil/water separator discharge water and plant domestic waste. This waste is collected in a holding tank and forwarded to the City of Monroe Municipal Waste Water Treatment Plant for treatment and disposal.

Attachment IV NPDES Permit Application for Reissuance - March 16, 2009 Fermi 2 Power Plant M10037028 C

'I iS 1<

  • 647
  • AN 23

2009 NPDES Permit Adjacent Property Owners Attachment V NPDES Permit Application for Renewal Fermi 2 Power Plant M10037028 March 16, 2009 Last Name First Name(s) Mail Address City St Zip Achinger Jeffery & Heather 5866 Pointe Aux Peaux Newport MI 48166 Baltrip Susan & Scott 5168 Pointe Aux Peaux Newport MI 48166 Alexander Michael & Julie 5944 Pointe Aux Peaux. Newport MI 48166 Barczewski James & Shelby 5701 Toll Rd Newport MI 48166 Bennett Alice 14848 Kingston Dr El Paso TX 79927 Bodenmiller Edward J (Catherine-Dec'd) 4771 Pointe Aux Peaux Newport MI 48166 Boerner Lauren & Kelly 5884 Pointe Aux Peaux Newport MI 48166 Bondy Eric & Robin 6211 Highland Newport MI 48166 Childress Charles & Barbara 6170 Leroux Newport MI 48166 Gonzales Shirley & Maria (C/O: Shirley) 3276 Chippewa Monroe MI 48162 Dellen William M 3466 Parkwood Monroe MI 48162 Drummonds Patricia 6148 Pointe Aux Peaux Newport MI 48166 MacDonald Muriel R 1017 Riverbank Lincoln Park MI 48146 Fix Bernice 6394 Leroux Newport MI 48166 Fix Kevin & Wendy L Rev Trust 5038.Post Rd Newport MI 48166 US Fish &Wildlife Services Bishop Henry Whipple Fed Bldg 1 Federal Dr St Paul MN 55111-4056 C/O Lois A Lawson I Popejoy Robert G PO Box 734 Punta Gorda FL 33591 Frenchtown Charter Township Supervisor 2744 Vivian Monroe MI 48162 Frenchtown Charter Township Water Tower 2744 Vivian Monroe MI 48162 Holmes Jimmy & Rebecca 6200 Langton Newport MI 48166 Jenkins Thomas 4828 Elm Newport MI 48166 Robertson Archie & Tina 5100 Pointe Aux Peaux Newport MI 48166 Kowalchuk Helen 20621 Wedgewood Grosse Pointe Woods MI 48236 Langton Valarian 6445 Leroux Newport MI 48166 Brazon Corey A 6267 Highland Newport MI 48166 Lyon Sand & Gravel Co 8800 Dix Ave Detroit MI 48209 Rorke Chasity & Homey Don III 5908 Pointe Aux Peaux Newport MI 48166 Manor, Gayle & Thelma Brooks, Kenneth & H 5920 Pointe Aux Peaux Newport MI 48166 Masserant Jerome & Janis 6255 Highland Newport MI 48166

2009 NPDES Permit Adjacent Property Owners Masserant Randy 6001 Toll Rd Newport MI 48166 Serokman John 4981 Pointe Aux Peaux Newport Ml 48166 McCarty Gordon 5300 Pointe Aux Peaux Newport MI 48166 McCarty Gordon 5194 Pointe Aux Peaux Newport MI 48166 Boles Timothy J 5182 Pointe Aux Peaux Newport MI 48166 MI Dept of Natural Resources Dept of Treasury PO Box 30722 Lansing Ml 48909 MI Nature Association 326 E Grand River Ave Williamston Ml 48895 Sterling David L 5838 Pointe Aux Peaux Newport Ml 48166 Moody Jason 6233 Highland Newport MI 48166 Moran Raymond & Linda 6511 Leroux Newport Ml 48166 Carmack Katherine & Robin 12600 Fessner Carleton MI 48117 Nowicki Viola 25000 Rubin Warren MI 48089 Peer Richard & Charlotte 5789 Newport South Newport MI 48166 Popejoy Robert G PO Box 734 Punta Gorda FL 33951 McDevitt Kay 2682 Nadeau Monroe MI 48162 Qassis Nabih & Juliet 37119 Muirfield Dr. Livonia Ml 48152 Sisung James & Holly 5701 Post Rd Newport MI 48166 US Fish & Wildlife Services Bishop Henry Whipple Fed Bldg 1 Federal Dr St Paul MN 55111-4056 C/O Lois A Lawson Squire Robert & Beth 5820 Pointe Aux Peaux Newport MI 48166 Styles Eleanor 6191 Highland Newport MI 48166 VanWashenova John & Delores 7982 South Newport Newport Ml 48166 VanWashenova Lawrence &Tina 2707 Steiner Monroe MI 48162 Tremblay Robert & Lou Ann 5152 Pointe Aux Peaux Newport MI 48166 Young David & Debra 4957 Raymond Newport MI 48166 International Transmission Co ITC Transmission 27175 Energy Way Novi MI 48377 Carmack Katherine & Robin 12600 Fessner Carlton MI 48117 Parker Orval 5121 Pointe Aux Peaux Newport MI 48166 Nothnagel Darlin Edward 4704 St. Clair St. Newport MI 48166 Ellison Michael & Laurie 4702 Long Newport Ml 48166 City of Monroe Water Works 120 E. First Monroe Ml 48161 Hathaway Rodney 13542 Venetian Monroe Ml 48161 MacDonald Muriel R 1017 Riverbank Lincoln Park Ml 48146 Newport Beach Marina Thomas Petty C/O:Towne MtgI 700 Tower Dr Ste#110 Troy MI 48098 US Fish & Wildlife Service Bishop Henry Whipple Fed Bldg 1 Federal Dr St Paul MN 55111-4056 C/O Lois A Lawson Flint Jerry A & Cindy L 6577 Leroux Newport Ml 48166

2009 NPDES Permit Adjacent Property Owners Daum Kevin F & Jaqueline E 6110 Leroux Newport MI 48166 Citimortgage 5280 Corporate Dr #1011 Frederick MD 21703-8351 Gonzalez Shirley & Maria (C/O: Maria) 3608 Navaho Monroe MI 48162 McPeek Charlie 4778 Superior Newport MI 48166 MR Investments LLC C/O Robert H Degraer 1555 Hollywood Drive Monroe MI 48162 McDevitt. Kay 2682 Nadeau Rd Monroe MI 48162 Stewart Virgil & Rosalie 4780 St. Clair Newport MI 481.66 Odom Phyllis C 132 Boyce Dr Brooklyn MI 49230 Brogan Christopher Lee 5670 Newport South Newport MI 48166 Rorke Chasity & Don Homey III 5908 Pointe-Aux Peaux Newport MI 48166 Gonzalez Maria & Shirley Gonzalez. 3276 Chippewa Monroe MI 48166 Kopsi_ Carl J 30020 Aspen Dr. Flat Rock, MI 48134 Deweys Stony Point Assoc Inc PO Box 66272 Newport MI 48166 Stringham, Roy D Ralston Lois C 6188 Highland Newport MI 48166 Ord David H & Bonnie L Trust 4720 Long St Newport MI 48166 Kennedy, Debra K Baker, Marilyn A &.Qualey, Jotbn J 4507 Goddard Newport MI 481.66 C/O: Debra Kennedy Diehl John H & Deborah L 4772 Long Newport MI 48166 Liedel Thomas & Anna 4802 Long Newport MI 48166 Lane Michael H PO Box 173 Wyandotte MI 48192 Seres Lonny & Linda 4834 Long Newport MI 48166 Monroe Frenchtown Raw Water Supply Co-Partnership 120 E. First St Monroe MI 48161 Long Est Summer Resort Assoc C/O Treasurer 4802 Long Newport MI 48166 McLaughlin Michael & Bridget 6108 Pointe Aux Peaux Newport MI 48166 Laskey Larry D 10623 Telegraph Carleton MI 48117 Yoas Lowell & Alice 6060 Pointe Aux Peaux Newport MI 48166 Flippin Todd D & Diana J 4690 N Lake Rd Newport MI 48166 Oliver Roxanne D 3938 Lakeshore Newport MI 48166 Day Christine R 16444 Trafalgar Dr Canton MI 48187

(a)

Attachment VI Application for Reissuance NPDES Permit Plant M10037028 Fermi 2 Power Outfall 001 Analyses

M-Aiix A;

ANALYTICAL REPORT Client: DTE Energy - EM&R Work Order: 0902360 Project: Permit Renewal - Fermi, 2009

Description:

Laboratory Services Client Sample ID: 001A Grab Day 1 Sampled: 02/18/09 11:16 Lab Sample ID: 0902360-02 Sampled By: E.Z., T.B.

Matrix: Waste Water Received: 02/19/09 18:50 Physical/Chemical Parameters by EPA/APHA/ASTM Methods Analytical Dilution Date QC Analyte Result RL Unit Factor Method Analyzed By Batch Chlorine, Total Residual (Field) <0.015 0.015 mg/L 1 USEPA 330.1 02/18/09 FLD 0902356 Oxygen, Dissolved (Field) 7.12 0.10 1 SM 4500-0 G 20th 02/18/09 FLD 0902356 pH (Field) 8.23 1.00 pH Units 1 SM 4500-H B 20th 02/18/09 FLD 0902356 Temperature °C (Field) 20.7 0.1 °C 1 SM 2550 B 20th 02/18/09 FLD 0902356 Page 3 of 40 This report shall not be reproduced except in full, vithout the written authorization of TrilVlatrix Laboratories, Inc.

Individual sample results relate only to the sample tested.

5560 Corporate Exchange Court SE - Grand Rapids, MI 49512 - (616) 975-4500 - Fax (616) 942-7463

ANALYTICAL REPORT Client: DTE Energy - EM&R Work Order: 0902360 Project: Permit Renewal - Fermi, 2009

Description:

Laboratory Services Client Sample ID: 001A Grab Day 2 Sampled: 02/19/09 11:00 Lab Sample ID: 0902360-03 Sampled By: E.Z., T.B.

Matrix: Waste Water Received: 02/19/09 18:50 Physical/Chemical Parameters by EPA/APHA/ASTM Methods Analytical Dilution Date QC Analyte Result RL Unit Factor Method Analyzed By Batch Chlorine, Total Residual (Field) <0.015 0.015 mg/L 1 USEPA 330.1 02/19/09 FLD 0902635 5.88 0.i0 mg/L 1 SM 4500-0 G 20th 02/19/09 FLD 0902356 Oxygen, Dissolved (Field) 1.00 pH Units 1 SM 4500-H B 20th 02/19/09 FLD 0902356 pH (Field) 8.51 0 1 Temperature *C (Field) 16.3 0.1 c SM 2550 B 20th 02/19/09 FLD 0902356

<2.0 2.0 ug/L 1 USEPA OIA-1677 02/25/09 VAS 0902420 Cyanide, Available

<5.00 5.00 mg/L 1 USEPA-1664A 02/26/09 LMA 0902384 HEM: Oil & Grease

<50.0 50.0 ug/L 1 USEPA-420.1 02/26/09 INR 0902394 Phenolics, Total Page 4 of 40 This report shall not be Indiridual except results reproducedsample without in full,relate thetowritten only the sample tested. of TriMatrix Laboratories, Inc.

authorization 5560 Corporate Exchange Court SE - Grand Rapids, MI 49512 - (616) 975-4500 - Fax (616) 942-7463

ANALYTICAL REPORT Client: DTE Energy - EM&R Work Order: 0902360 Project: Permit Renewal - Fermi, 2009

Description:

Laboratory Services Client Sample ID: 001A Grab VOC Composite Sampled: 02/19/09 11:00 Lab Sample ID: 0902360-04 Sampled By: E.Z., T.B.

Matrix: Waste Water Received: 02/19/09 18:50 Unit: ug/L Prepared: 02/25/09 By: JDM Dilution Factor: 1 Analyzed: 02/25/09 By: JDM QC Batch: 0902456 Analytical Batch: 9022632

  • Volatile Organic Compounds by EPA Method 624 Ani~lytfil Analyte Result CAS Number RL 107-02-8 Acrolein <5.0 5.0 107-13-1 Acrylonitrile <1.0 1.0 71-43-2 Benzene <i.0 1.0 75-27-4 Bromodichloromethane <1.0 1.0 75-25-2 Bromoform <1.0 1.0 74-83-9 Bromomethane <1.0 1.0 56-23-5 Carbon Tetrachloride <1.0 1.0 108-90-7 Chlorobenzene <1.0 1.0 75-00-3 Chloroethane <1.0 1.0 110-75-8 2-Chloroethyl Vinyl Ether <10 10 67-66-3 Chloroform <1.0 1.0 74-87-3 Chloromethane <1.0 1.0 124-48-1 Dibromochloromethane <1.0 1.0 75-34-3 1,1-Dichloroethane <1;0 1.0 107-06-2 1,2-Dichloroethane <1.0 1.0 75-35-4 1,1-Dichloroethene <1.0 1.0 542-75-6 1,3-Dichloropropene (Total) <2.0 2.0 156-60-5 trans-1,2-Dichloroethene <1.0 1.0 78-87-5 1,2-Dichioropropane <1.0 1.0 100-41-4 Ethylbenzene <1.0 1.0 75-09-2 Methylene Chloride <5.0 5.0 79-34-5 1,1,2,2-Tetrachloroethane <1.0 1.0 127-18-4 Tetrachloroethene <1.0 1.0 108-88-3 Toluene <1.0 1.0 71-55-6 1,1, 1-Trichloroethane <1.0 1.0 79-00-5 1, 1,2-Trichloroethane <1.0 1.0 79-01-6 Trichloroethene <1.0 1.0 75-01-4 Vinyl Chloride <1.0 1.0 Surrogates: 0 Recovery Control Limits Dibromofluoromethane 98 88-115 Continued on next page
  • See Statement of Data Qualifications Page 5 of 40 This report shall not be reproduced except in full, writhout the written authorization of TrilvIatrix Laboratories, Inc.

individual sample results relate only to the sample tested.

5560 Corporate Exchange Court SE

  • Grand Rapids, MI 49512 - (616) 975-4500
  • Fax (616) 942-7463

eboratone~. Inn.

ANALYTICAL REPORT Client: DTE Energy - EM&R Work Order: 0902360 Project: Permit Renewal - Fermi, 2009

Description:

Laboratory Services Client Sample ID: O01A Grab VOC Composite Sampled: 02/19/09 11:00 Lab Sample ID: 0902360-04 Sampled By: E.Z., T.B.

Matrix: Waste Water Received: 02/19/09 18:50 Unit: ug/L Prepared: 02/25/09 By: JDM Dilution Factor: 1 Analyzed: 02/25/09 By: JDM QC Batch: 0902456 Analytical Batch: 9022632

  • Volatile Organic Compounds by EPA Method 624 (Continued)

SiU-roatos (Cotirniaii9Y  % Recoe-ry ControlLimits 1,2-Pidhoroethane-d4 88 81-116 Toluene-d8 100 87-113 4-Bromofiuorobenzene 100 78-116

  • See Statement of Data Qualifications Page 6 of 40 This report shall not be reproduced except in full, without the written authorization of TriNMatrix Laboratories, Inc.

Individual sample results relate only to the sample tested.,

5560 Corporate Exchange Court SE - Grand Rapids, M1 49512 - (616) 975-4500 . Fax (616) 942-7463

iI.bxLtnnes JeL ANALYTICAL REPORT Client: DTE Energy - EM&R Work Order: 0902360 Project: Permit Renewal - Fermi, 2009

Description:

Laboratory Services Client Sample ID: O01A Composite Sampled: 02/19/09 11:00 Lab Sample ID: 0902360-07 Sampled By: E.Z., T.B.

Matrix: Waste Water Received: 02/19/09 18:50 Unit: ug/L Prepared: 02/27/09 By: DCG Dilution Factor: 1 Analyzed: 03/02/09 By: ASC QC Batch: 0902493 Analytical Batch: 9030318 Polychlorinated Biphenyls (PCBs) by EPA Method 608 Analytical CAS Number Anallyte Result RL 12674-11-2 PCB-1016 <0.21 0.21 11104-28-2 PCB-1221 <0.21 0.21 11141-16-5 PCB-1232 <0.21 0.21 53469-21-9 PCB-1242 <0.21 0.21 12672-29-6 PCB-1248 <0.21 0.21 11097-69-1 PCB-1254 <0.21 0.21 11096-82-5 PCB-1260 <0.21 0.21 Surrogates:  % Recovery ControlLimits Decach/orobipheny/ 91 45-134 Tetracbloro-m-xylene S9 27-126 Page 10 of 40 This report shall not be reproduced except in full, without the written authorization of TriNllatrix Laboratories, Inc.

IndiNidual sample results relate only to the sample tested.

5560 Corporate Exchange Court SE - Grand Rapids, MI 49512 - (616) 975-4500 - Fax (616) 942-7463

Labortodes, bLi&'..... .. .........

ANALYTICAL REPORT Client: DTE Energy - EM&R Work Order: 0902360 Project: Permit Renewal - Fermi, 2009

Description:

Laboratory Services Client Sample ID: 001A Composite Sampled: 02/19/09 11:00 Lab Sample ID: 0902360-07 Sampled By: E.Z., T.B.

Matrix: Waste Water Received: 02/19/09 18:50 Unit: ug/L Prepared: 02/26/09 By: DCG Dilution Factor: 1 Analyzed: 03/02/09 By: DMC QC Batch: 0902425 Analytical Batch: 9030346 Semivolatile Organic Compounds by EPA Method 625 Anavtiail CAS Number Analyte Result RL 83-32-9 Acenaphthene <5.4 5.4 208-96-8 Acenaphthylene <5.4 5A4 120-12-7 Anthracene <5.4 5.4 92-87-5 Benzidine <54 54 56-55-3 Benzo(a)anthracene <5.4 5.4 50-32-8 Benzo(a)pyrene <5.4 5.4 205-99-2 Benzo(b)fluoranthene <5.4 5.4 207-08-9 Benzo(k)fluoranthene <5.4 5.4 191-24-2 Benzo(g,h,i)perylene <5.4 5.4 101-55-3 4-Bromophenyl Phenyl Ether <5.4 5.4 85-68-7 Butyl Benzyl Phthalate <5.4 5.4 59-50-7 4-Chloro-3-methylphenol <5.4 5.4 111-91-1 Bis(2-chloroethoxy)methane <5.4 5.4

-111-44-4 Bis(2-chloroethyl) Ether <5.4 5.4 108-60-1 Bis(2-chloroisopropyl) Ether <5.4 5.4 91-58-7 2-Chloronaphthalene <5.4 5.4 95-57-8 2-Chlorophenol <5.4 5.4 7005-72-3 4-Chlorophenyl Phenyl Ether <5.4 5.4 218-01-9 Chrysene <5.4 5.4 53-70-3 Dibenz(a,h)anthracene <5.4 5.4 84-74-2 Di-n-butyl Phthalate <5.4 5.4 95-50-1 1,2-Dichlorobenzene <5.4 5.4 541-73-1 1,3-Dichlorobenzene <5.4 5.4 106-46-7 1,4-Dichlorobenzene <5.4 5.4 91-94-1 3,3 '-Dichlorobenzidine <22 22 120-83-2 2,4-Dichlorophenol <5.4 5.4 84-66-2 Diethyl Phthalate <5.4 5.4 105-67-9 2,4-Dimethylphenol <5.4 5.4 131-11-3 Dimethyl Phthalate <5.4 5.4 Continued on next page Page 11 of 40 This report shall not be reproduced except in full, without the written authorization of TriMatrix Laboratories, Inc.

Individual sample results relate only to the sample tested.

5560 Corporate Exchange Court SE - Grand Rapids, MI 49512 - (616) 975-4500 - Fax (616) 942-7463

ANALYTICAL REPORT Client: DTE Energy - EM&R Work Order: 0902360 Project: Permit Renewal - Fermi, 2009

Description:

Laboratory Services Client Sample ID: 001A Composite Sampled: 02/19/09 11:00 Lab Sample ID: 0902360-07 Sampled By: E.Z., T.B.

Matrix: Waste Water Received: 02/19/09 18:50 Unit: ug/L Prepared: 02/26/09 By: DCG Dilution Factor: 1 Analyzed: 03/02/09 By: DMC QC Batch: 0902425 Analytical Batch: 9030346 Semivolatile Organic Compounds by EPA Method 625 (Continued)

Aftalyrtical CAS Number Analyte Result RL 534-52-1 4,6-Dinitro-2-methylphenol <22 22' 51-28-5 2,4-Dinitrophenol <22 22 121-14-2 2,4-Dinitrotoluene <5.4 5.4 606-20-2 2,6-Dinitrotoluene <5.4 5.4 117-84-0 Di-n-octyl Phthalate <5.4 5.4 122-66-7 1,2-Diphenylhydrazine <5.4 5.4 117-81-7 Bis(2-ethylhexyl) Phthalate <5.4 5.4 206-44-0 Fluoranthene <5.4 5.4 86-73-7 Fluorene <5.4 5.4 118-74-1 Hexachlorobenzene <5.4 5.4 87-68-3 Hexachlorobutadiene <5.4 5.4 77-47-4 Hexachlorocyclopentadiene <5.4 5.4 67-72-1 Hexachloroethane <5.4 5.4 193-39-5 Indeno( 1;2;3-cd)pyrene <5.4 5.4 78-59-1 Isophorone <5.4 5.4 91-20-3 Naphthalene <5.4 5.4 98-95-3 Nitrobenzene <5.4 5.4 100-02-7 4-Nitrophenol <22 22 88-75-5 2-Nitrophenol <5.4 5.4 62-75-9 N-Nitroso-dimethylamine <5.4 5.4 86-30-6 N-Nitroso-diphenyJamine <5,4 5.4 621-64-7 N-Nitroso-di-n-propylamine <5.4 5.4 87-86-5 Pentachlorophenol <22 22 85-01-8 Phenanthrene <5.4 5.4 108-95-2 Phenol <5.4 5.4 129-00-0 Pyrene <5.4 5.4 120-82-1 1,2,4-Trichlorobenzene <5.4 5,4 88-06-2 2,4,6-Trichlorophenol <5.4 5.4 Surrogates:  % Recovery ControlLimits 2-Fluorophenol 67 20-70 Continued on next page Page 12 of 40 This report shall not be reproduced except in full, without the wwitten authorization of TriNlatrix Laboratories, Inc.

Individual sample results relate only to the sample tested.

5560 Corporate Exchange Court SE - Grand Rapids, MI 49512 - (616) 975-4500 - Fax (616) 942-7463

ANALYTICAL REPORT Client: DTE Energy - EM&R Work Order: 0902360 Project: Permit Renewal - Fermi, 2009

Description:

Laboratory Services Client Sample ID: O01A Composite Sampled: 02119/09 11:00 Lab Sample ID: 0902360-07 Sampled By: E.Z., T.B.

Matrix: Waste Water Received: 02/19/09 18:50 Unit: ug/L Prepared: 02/26/09 By: DCG Dilution Factor: 1 Analyzed: 03/02/09 By: DMC QC Batch: 0902425 Analytical Batch: 9030346 Semivolatile Organic Compounds by EPA Method 625 (Continued)

Surrogates(Coxtinlu'd):  % Revoe&Y CbhItrlLifits Phenol-d6 45 23-50 Nitrobenzene-d5 118 31-123 2-Fluorobiphenyl 91 25-113 2,4,6-Tribromophenol 97 30-121 o-Terphenyl 95 42-125 Page 13 of 40 This report shall not be reproduced except in full, without the written authorization of TriNIlatrix Laboratories, Inc.

Individual sample results relate only to the sample tested.

5560 Corporate Exchange Court SE - Grand Rapids, MI 49512 - (616) 975-4500 - Fax (616) 942-7463

11Malbm-oesn ANALYTICAL REPORT Client: DTE Energy - EM&R Work Order: 0902360 Project: Permit Renewal - Fermi, 2009

Description:

Laboratory Services Client Sample ID: O01A Composite Sampled: 02/19/09 11:00 Lab Sample ID: 0902360-07 Sampled By: E.Z., T.B.

Matrix: Waste Water Received: 02/19/09 18:50 Total Metals by EPA 200 Series Methods Analytical Dilution Date QC Analyte Result RL Unit Factor Method Analyzed By Batch Aluminum 0.60 0.050 mg/L USEPA-200.7 02/25/09 JMF 0902338 Antimony <1;0 1.0 ug/L 1 USEPA-200;8 02/25/09 MSM 0902337 Arsenic <1.0 1.0 ug/L 1 USEPA-200.8 02/25/09 MSM 0902337 Barium 31 5.0 ug/L 1 USEPA-200.8 02/25/09 MSM 0902337 Beryllium <1.0 1.0 ug/L USEPA-200.8 02/25/09 MSM 0902337 Boron 43 20 ug/L USEPA-200.8 02/25/09 MSM 0902337 Cadmium <0.20 0.20 ug/L USEPA-200.8 02/25/09 MSM 0902337 Chromium <10 10 ug/L USEPA-200.8 02/25/09 MSM 0902337 Cobalt <10 10 ug/L USEPA-200.7 03/03/09 KLV 0902338 Copper 5.4 1.0 ug/L USEPA-200.8 02/25/09 MSM 0902337 Iron 0.62 0.010 mg/L USEPA-200.7 02/25/09 JMF 0902338 Lead <1.0 1.0 ug/L USEPA-200.8 02/25/09 MSM 0902337 Magnesium 14 0.50 mg/L USEPA-200.7 02/25/09 JMF 0902338 Manganese 0.012 0.010 mg/L USEPA-200.7 02/25/09 JMF 0902338 Molybdenum <0.10 0.10 mg/L USEPA-200.7 02/25/09 JMF 0902338 Nickel <5.0 5.0 ug/L USEPA-200.8 02/25/09 MSM 0902337 Selenium <1.0 1.0 ug/L USEPA-200.8 02/25/09 MSM 0902337 Silver <0.50 0.50 ug/L USEPA-200.8 02/25/09 MSM 0902337 Thallium <1.0 1.0 ug/L USEPA-200.8 02/25/09 MSM 0902337 Tin <0.20 0.20 mg/L USEPA-200.7 02/25/09 JMF 0902338 Titanium <0.10 0.10 mg/L USEPA-200.7 02/25/09 JMF 0902338 Zinc 13 10 ug/L USEPA-200.8 02/25/09 MSM 0902337 Page 14 of 40 This report shall not be reproduced except in full, without the written authorization of TriMatrix Laboratories, Inc.

Individual sample results relate only to the sample tested.

5560 Corporate Exchange Court SE

  • Grand Rapids, M1 49512 - (616) 975-4500
  • Fax (616) 942-7463

4 Ti)a'1ix' ANALYTICAL REPORT Client: DTE Energy - EM&R Work Order: 0902360 Project: Permit Renewal - Fermi, 2009

Description:

Laboratory Services Client Sample ID: ý01A Composite Sampled: 02/19/09 11:00 Lab Sample ID: 0902360-07 Sampled By: E.Z., T.B.

Matrix: Waste Water Received: 02/19/09 18:50 Physical/Chemical Parameters by EPA/APHA/ASTM Methods Analytical Dilution Date QC Analyte , Result RL Unit Factor Method Analyzed By Batch BOD, (5-Day) 6.3 1.0 mg/L SM 5210 B 20th 02/20/09 CKD 0902276 Bromide 0.54 0.10 ASTM b 1246-95 02/27/09 VAS 0902512 mg/L mg!L Chemical Oxygen Demand 13 5.0 SM 5220 D 20th 02/23/09 CKD 0902310

  • Color (Apparent) 15.0 5.00 A.C.U. SM 2120 B 20th 02/20/09 CLD 0902294 Fluoride 0.37 0.10 mg/L SM4500-F C 20th 02/27/09 CKD 0902571 Hardness as CaC03 192 2 mg/L SM 2340 C 20th 03/03/09 CKD 0902612
  • Surfactants, MBAS 0.0365 0.0250 mg/L SM 5540 C 20th 02/20/09 CLB 0902301 Phosphorus, Total 0.192 0.0100 mg/L SM4500-P F 20th 02/23/09 INR 0902259 Residue, Dissolved @ 1800 C 320 50 mg/L SM 2540 C 20th 02/25/09 KNC 0902404 Residue, Suspended 11.1 4.5 mg/L SM 2540 D 20th 02/25/09 KNC 0902406 Sulfate 44 10 mg/L ASTMD516-90 (02) 02/26/09 GEH 0902515 Sulfide, Total <0.020 0.020 mg/L APHA 4500-S2 D 02/26/09 KNC 0902525
  • Sulfite <1.0 1.0 mg/L SM 4500-SO3 B 20th 02/20/09 GEH 0902339 Carbon, Total Organic 4.1 1.0 mg/L SM 5310 C 20th 02/27/09 LMA 0902550 Nitrogen, Ammonia 0.11 0.050 mg/L SM4500-NH3 G 20th 02/25/09 GEH 0902392 Nitroge-n, Nitrate+ Nitrite 1.3 0.10 mglL SM4500-NO3 F 20th 02/21/09 HLB 0902277 Nitrogen, Organic 0.54 0.50 mglL USEPA-351.2/4500-NH 03/03/09 GEH 0902604 Nitrogen, Total Kjeldahl 0.66 0.50 mg/L USEPA-351.2 02/25/09 CLB 0902309 Nitrogen, Inorganic 1.4 0.15 mg/L [CALC] 02/25/09 HLB [CALC]
  • See Statement of Data Qualifications Page 15 of 40 This report shall not be reproduced except in full, without the written authorization of TriMatrix Laboratories, Inc.

Individual sample results relate only to the sample tested.

5560 Corporate Exchange Court SE

  • Grand Rapids, Nff 49512 - (616) 975-4500 - Fax (616) 942-7463

ANALYTICAL REPORT Client: Detroit Edison - Fermi-2 Work Order: 0901361 Project: Mercury Analysis

Description:

Laboratory Services Client Sample ID: 001A Sampled: 01/27/09 11:40 Lab Sample ID: 0901361-01 Sampled By: E.Z,J.B.

Matrix: Wasie Water Received: 01/28/09 19:00 Total Metals by EPA 1600 Series Methods Analytical Dilution Date QC Analyte Result RL Unit Factor Method Analyzed By Batch Mercury 1.48 0.500 ng/L 1 USEPA-1631E 02/03/09 DWJ 0901578 Page 2 of 10 This report shall not be reproduced except in full, without the written authorization of Trinlvatrix Laboratories, Inc.

Individual sample results relate only to the sample tested.

5560Corporate Exchange Court SE - Grand Rapids, MI 49512 - (616) 975-4500 - Fax (616) 942-7463

01-W

'ý'

ý.

ANALYTICAL REPORT Client: Detroit Edison - Fermi-2 Work Order: 0901361 Project: Mercury Analysis

Description:

Laboratory Services Client Sample ID: 001A Duplicate Sampled: 01/27/09 11:40 Lab Sample ID: 0901361-02 Sampled By: EZ,JB Matrix: Waste Water Received: 01/28/09 19:00 Total Metals by EPA 1600 Series Methods Analytical Dilution Date QC Analyte Result RL Unit Factor Method Analyzed By Batch Mercury 1.53 0.500 ng/L 1 USEPA-1631E 02/03/09 DWJ 0901578 Page 3 of 10 This report shall not be reproduced except in full, without the written authorization of TriNlatrix Laboratories, Inc.

Individual sample results relate only to the sample tested.

5560 Corporate Exchange Court SE - Grand Rapids, M1 49512 - (616) 975-4500 - Fax (616) 942-7463

Attachment VI (b)

NPDES Permit Application for Reissuance Fermi 2 Plant M10037028 GSW Intake Analyses

ANALYTICAL REPORT Client: DTE Energy - EM&R Work Order: 0902360 Project: Permit Renewal - Fermi, 2009

Description:

Laboratory Services Client Sample ID: GSW Intake Grab Day 1 Sampled: 02/18/09 11:40 Lab Sample ID: 0902360-01 Sampled By: E.Z., T.B.

Matrix: Waste Water Received: 02/19/09 18:50 Physical/Chemical Parameters by EPA/APHA/ASTM Methods Analytical Dilution Date QC Analyte Result RL Unit Factor Method Analyzed By Batch Chlorine, Total Residual (Field) <0.015 0.015 mg/L 1 USEPA 330.1 02/18/09 FLD 0902356 Oxygen, Dissolved (Field) 4.32 0.10 mgiiL FLD 0902356 pH (Field). 8.03 1.00 pH Units 1 SM4500-H 5 20th 02/18/09 FLD 0902356 Temperature *C (Field) 3.0 0.1 oc 1 SM 2550 B 20th 02/18/09 FLD 0902356 Page 2 of 40 This report shall not be reproduced except in full, without the written authorization of TriMatrix Laboratories, Inc.

Individual sample results relate only to the sample tested.

5560 Corporate Exchange Court SE - Grand Rapids, MI 49512 - (616) 975-4500 - Fax (616) 942-7463

A.TriiYatrix.

ANALYTICAL REPORT Client: DTE Energy - EM&R Work Order: 0902360 Project: Permit Renewal - Fermi, 2009

Description:

Laboratory Services Client Sample ID: GSW Intake Grab Day 2 Sampled: 02/19/09 11:40 Lab Sample ID: 0902360-05 Sampled By: E.Z., T.B.

Matrix: Waste Water Received: 02/19/09 18:50 Physical/Chemical Parameters by EPA/APHA/ASTM Methods Analytical Dilution Date QC Analyte Result RL Unit Factor Method Analyzed By Batch Chlorine, Total Residual (Field) <0.015 0.015 mg/L 1 USEPA 330.1 02/19/09 FLD 0902635 Oxygen, Dissolved (Field) 6&47 010 mg/L 1 SM 4500-0 G 20th 02/19/09 FLD 0902356 pH (Field) 7.47 1.00 pH Units 1 SM4500-H B 20th 02/19/09 FLD 0902356 Temperature *C (Field) 2.3 0.1 0C ,i SM 2550 B 20th 02/19/09 FLD 0902356 Cyanide, Available <2.0 2.0 ug/L 1 USEPA OIA-1677 02/25/09 VAS 0902420 HEM: Oil & Grease <5.00 5.00 mg/L 1 USEPA-1664A 02/26/09 LMA 0902384 Phenolics, Total <50.0 50.0 ug/L 1 USEPA-420.1 02/26109 INR 0902394 Page 7 of 40 This report shall not be reproduced except in full, without the written authorization of TriMatrix Laboratories, Inc.

Individual sample results relate only to the sample tested.

5560 Corporate Exchange Court SE - Grand Rapids, MI 49512 (616) 975-4500 -Fax (616) 942-7463

A TniNatrix ANALYTICAL REPORT Client: DTE Energy - EM&R Work Order: 0902360 Project: Permit Renewal - Fermi, 2009

Description:

Laboratory Services Client Sample ID: GSW Intake Grab VOC Composite Sampled: 02/19/09 11:40 Lab Sample ID: 0902360-06 Sampled By: E.Z., T.B.

Matrix: Waste Water Received: 02/19/09 18:50 Unit: ug/L Prepared: 02/25/09 By: JDM Dilution Factor: 1 Analyzed: 02/25/09 By: 3DM QC Batch: 0902456 Analytical Batch: 9022632

  • Volatile Organic Compounds by EPA Method 624 Analytical CAS Number Analyte Result RL 107-02-8 Acrolein <5.0 5.0 107-13-1. Acrylonitrile <1.0 1.0 71-43-2 Benzene <1.0 1.0 75-27-4 Bromodichloromethane <1.0 1.0 75-25-2 Bromoform <1.0 1.0 74-83-9 Bromomethane <1.0 1.0 56-23-5 Carbon TetrachoDride <1.0 1.0 108-90-7 Chlorobenzene <1.0 1.0 75-00-3 Chioroethane <1.0 1.0 110-75-8 2-Chloroethyl Vinyl Ether <10 10 67-66-3 Chloroform <1.0 1.0 74-87-3 Chloromethane <1.0 1.0 124-48-1 Vibromochloromethane <1.0 1.0 75-34-3 1,1-Dichloroethane <1.0 1.0 1,2-Dichioroethane <-1.0 1.0 75-35-4 1,1-Dichloroethene <1.0 1.0 542-75-6 1,3-DichJoropropene (Total) <2.0 2.0 156-60-5 trans-1,2-Dichloroethene <1.0 1.0 78-87-5 1,2-Dichloropropane <1.0 1.0 100-41-4 Ethylbenzene <1.0 1.0 75-09-2 Methylene Chloride <5.0 5.0 79-34-5 1,1,2,2-Tetrachloroethane <1.0 1.0 127-18-4 Tetrachloroethene <1.0 1.0 108-88-3 Toluene <1.0 1.0 71-55-6 1,1,1-Trichioroethane <1.0 1.0 79-00-5 1,1,2-Trichloroethane <1.0 10 79-01-6 Trichiloroethene <1.0 1.0 75-01-4 Vinyl Chloride <1.0 1.0 surrogates.  % Recovery Control Limitf 00brmofluorometlhane 101 88-115 Continued on next page
  • See Statement of Data Qualifications Page 8 of 40 This report shall not be reproduced except in full, without the written authorization of TriMatrix Laboratories, Inc.

Individual sample results relate only to the sample tested.

5560 Corporate Exchange Court SE - Grand Rapids, MI 49512 - (616) 975-4500 - Fax (616) 942-7463

    • Labom=,In ANALYTICAL REPORT Client: DTE Energy - EM&R Work Order: 0902360 Project: Permit Renewal - Fermi, 2009

Description:

Laboratory Services Client Sample ID: GSW Intake Grab VOC Composite Sampled: 02/19/09 11:40 Lab Sample ID: 0902360-06 Sampled By: E.Z., T.B.

Matrix: Waste Water Received: , 02/19/09 18:50 Unit: ug/L Prepared: 02/25/09 By: JDM Dilution Factor: 1 Analyzed: 02/25109 By: JDM QC Batch: 0902456 Analytical Batch: 9022632

  • Volatile Organic Compounds by EPA Method 624 (Continued)

Surrogates (Continued):  %,/Recovery Controi Lmits 1,2-Dichloroethane-d4 97 81-116 Toluene-d8 100 87-113 4-Bromofiorobenzene 99 78-116

  • See Statement of Data Qualifications Page 9 of 40 This report shall not be reproduced except in full, without the written authorization of TriMatrix Laboratories, Inc.

Individual sample results relate only to the sample tested.

5560 Corporate Exchange Court SE - Grand Rapids, MI 49512 . (616) 975-4500 - Fax (616) 942-7463

ANALYTICAL REPORT Client: DTE Energy - EM&R Work Order: 0902360 Project: Permit Renewal - Fermi, 2009

Description:

Laboratory Services Client Sample ID: GSW Intake Composite Sampled: 02/19/09 11:40 Lab Sample ID: 0902360-08 Sampled By: E.Z., T.B.

Matrix: Waste Water Received: 02/19/09 18:50 Unit: ug/L Prepared: 02/27/09 By: DCG Dilution Factor: I Analyzed: 03/02/09 By: ASC QC Batch: 0902493 Analytical Batch: 9030318 Polychlorinated Biphenyls (PCBs) by EPA Method 608 Analytical CAS Number Analyte Result RL 12674-11-2 PCB-1016 <0.20 0.20 11104-28-2 PCB-1221 <0.20 0.20 11141-15-5 PCB-1232 <0.20 0.20 53469-21-9 PCB-1242 <0.20 0.20 12672-29-6 PCB-1248 <0.20 0.20 11097-69-1 PCB-1254 <0.20 0.20 1109&-82-5 PCB-1260 <0.20 0.20 Surrogates.. 0 Recovery ControlLimits Decakhlorobiphenyf 87 45-134 Tet'adV/oro-m-xy/ene 50 27-126 Page 16 of 40 This report shall not be reproduced except in full, without the written authorization of TriMatrix Laboratories, Inc.

Individual sample results relate only to the sample tested.

5560 Corporate Exchange Court SE - Grand Rapids, Mt 49512 * (616) 975-4500

  • Fax (616) 942-7463

ATratrix LaANoACieL REPOR ANALYTICAL REPORT Client: DTE Energy - EM&R Work Order: 0902360 Project: Permit Renewal - Fermi, 2009

Description:

Laboratory Services Client Sample ID: GSW Intake Composite Sampled: 02/19/09 11:40 Lab Sample ID: 0902360-08 Sampled By: E.Z., T.B.

Matrix: Waste Water Received: 02/19/09 18:50 Unit: ug/L Prepared: 02/26/09 By: DCG Dilution Factor: 1 Analyzed: 03/02/09 By: DMC QC Batch: 0902425 Analytical Batch: 9030346 Semivolatile Organic Compounds by EPA Method 625 Analytical CAS Number Analyte Result RL 83-32-9 Acenaphthene <5.0 5.0 208-96-8 Acenaphthylene <5.0 5.0 120-12-7 Anthracene <5.0 5,0 92-87-5 Benzidine <50 50 56-55-3 Benzo(a)anthracene <5.0 5.0 50-32-8 Benzo(a)pyrene <5.0 5.0 205-99-2 Benzo(b)fluoranthene <5.0 5.0 207-08-9 Benzo(k)fluoranthene <5.0 5.0 191-24-2 Benzo(g,h,i)perylene <5.0 5.0 101-55-3 4-Bromophenyl Phenyl Ether <5.0 5.0 85-68-7 Butyl Benzyl Phthalate <5.0 5.0 59-50-7 4-Chloro-3-methylphenol <5.0 5.0 111-91-1 Bis(2-chloroethoxy)methane <5.0 5.0 111-44-4 Bis(2-chloroethyl) Ether <5.0 5.0 108-60-1 Bis(2-chloroisopropyl) Ether <5.0 5.0 91-58-7 2-Chloronaphthalene <5.0 5.0 95-57-8 2-Chlorophenol <5.0 5.0 7005-72-3 4-Chlorophenyl Phenyl Ether <5.0 5.0 218-01-9 Chrysene <5.0 5.0 53-70-3 Dibenz(a,h)anthracene <5.0 5.0 84-74-2 Di-n-butyl Phthalate <5.0 5.0 95-50-1 1,2-Dichlorobenzene <5.0 5.0 541-73-1 1,3-Dichlorobenzene <5.0 5.0 106-46-7 1,4-Dichlorobenzene <5.0 5.0 91-94-1 3,3'-bichlorobenzdine <20 20 120-83-2 2,4-Dichlorophenol <5.0 5.0 84-66-2 Diethyl Phthalate <5.0 5.0 105-67-9 2,4-Dimethylphenol <5.0 5.0 131-11-3 Dimethyl Phthalate <5.0 5.0 Continued on next page Page 17 of 40 This report shall not be reproduced except in full, without the written authorization of TriMatrix Laboratories, Inc.

Individual sample results relate only to the sample tested.

5560 Corporate Exchange Court SE - Grand Rapids, Ml 49512., (616) 975-4500 - Fax (616) 942-7463

LaboAATiIAs, zi E.

ANALYTICAL REPORT Client: DTE Energy- EM&R Work Order: 0902360 Project: Permit Renewal - Fermi, 2009

Description:

Laboratory Services Client Sample ID: GSW Intake Composite Sampled: 02/19/09 11:40 Lab Sample ID:' 0902360-08 Sampled By: E.Z., T.B.

Matrix: Waste Water Received: 02/19/09 18:50 Unit: ug/L Prepared: 02/26/09 By: DCG Dilution Factor: 1 Analyzed: 03/02/09 By: DMC QC Batch: 0902425 Analytical Batch: 9030346 Semivolatile Organic Compounds by EPA Method 625 (Continued)

Anaaleecal CAS Number Analyte Result RL 534-52-1 4,6-Dinitro-2-methylphenol <20 20 51-28-5 2,4-Dirat-ophenol <20 20 121-14-2 2,4-Dinitrotoluene <5.0 5.0 606-20-2 2,6-Dinitrotoluene <5.0 5.0 117-84-0 Di-n-octyl Phthalate <5.0 5.0 122-66-7 1,2-Diphenylhydrazine <5.0 5.0.

117-81-7 Bis(2-ethylhexyl) Phthalate <5.0 5.0 206-44-0 Fluoranthene <5.0 5.0 86-73-7 Fluorene <5.0 5.0 118-74-1 Hexachlorobenzene <5.0 5.0 87-68-3 Hexachlorobutadlene <5.0 5.0 77-47-4 Hexachlorocydopentadiene <5.0 .5.0 67-72-1 Hexachloroethane <5.0 5.0 193-39-5 Indeno(1,2,3-cd)pyrene <5.0 5.0 74-59-1 <5.0 5.0 91-20-3 Naphthalene <5.0 5.0 98-95-3 Nitrobenzene <5.0 5.0 100-02-7 4-Nitrophenol <20 20 88-75-5 2-Nitrophenol <5.0 5.0 62-75-9 N-Nltroso-dimethylamine <5.0 5.0 86-30-6 N-Nitroso-dlphenylamine <5.0 5.0 621-64-7 N-Nltroso-di-n-propylarnine <5.0 5.0 87-86-5 Pentachlorophenol <20 20 85-01-8 Phenanthrene <5.0 5.0 108-95-2 Phenol <5.0 5.0 129-00-0 Pyrene <5.0 5.0 120-82-1 1,2,4-Trchlorobenzene <5.0 5.0 88-06-2 2,4,6-Trichlorophenol <5.0 5.0 Surrogates:  % Recovery ControlLimits 2-Fl.orophalo/ 44 20-70 Continued on next page Page 18 of 40 This report shall not be reproduced except in full, without the written authorization of TriMatrix Laboratories, Inc.

Individual sample results relate only to the sample tested.

5560 Corporate Exchange Court SE - Grand Rapids, MN49512 - (616) 975-4500 - Fax (616) 942-7463

4TiMattix ANALYTICAL REPORT Client: DTE Energy - EM&R Work Order: 0902360 Project: Permit Renewal - Fermi, 2009

Description:

Laboratory Services Client Sample ID: GSW Intake Composite Sampled: 02/19/09 11:40 Lab Sample ID: 0902360-08 Sampled By: E.Z., T.B.

Matrix: Waste Water Received: 02/19/09 18:50 Unit: ug/L Prepared: 02/26/09 By: DCG Dilution Factor: 1 Analyzed: 03/02/09 By: DMC QC Batch: 0902425 Analytical Batch: 9030346 Semivolatile Organic Compounds byCEPA Method 625 (Continued)

Surrogates(Continued):  % Recovery Controllimits Phenol-d6 36 23-50 N/trobenzene-d5 113 31-123 2-Fluorobiphenyl 84 25-113 2,4,6-Tbromophenof 64 30-121 o- Terphenyl 89 42-125 Page 19 of 40 This report shall not be reproduced except in full, without the written authorization of TriMatrix Laboratories, Inc.

Individual sample results relate only to the sample tested.

5560 Corporate Exchange Court SE

  • Grand Rapids, MN49512 * (616) 975-4500 - Fax (616) 942-7463

T t A L I Ra R ANALYTICAL REPORT Client: DTE Energy - EM&R Work Order: 0902360 Project: Permit Renewal - Fermi, 2009

Description:

Laboratory Services Client Sample ID: GSW Intake Composite Sampled: 02/19/09 11:40 Lab Sample ID: 0902360-08 Sampled By: E.Z., T.B.

Matrix: Waste Water Received: 02/19/09 18:50 Total Metals by EPA 200 Series Methods Analytical Dilution Date QC Analyte Result RL Unit Factor Method Analyzed By Batch Aluminum 0.15 0.050 mg/L USEPA-200.7 02/25/09 .MF 0902338 Antimony <i.0 1.0 ug/L USEPA-200.8 02/25/09 MSM 0902337 Arsenic <1.0 1.0 ug/L USEPA-200.8. 02/25/09 MSM 0902337 Barium 25 5.0 ug/L USEPA-200.8 02/25/09 MSM 0902337 Beryllilum <1.0 1.0 ug/L USEPA-200.8 02/25/09 MSM 0902337 Boron 30 20 ug/L USEPAk200.8 02/25/09 MSM 0902337 Cadmium <0.20 0.20 ug/L USEPA-200.8 02/25/09 MSM 0902337 Chromium <10 10 ug/L USEPA-200.8 02/25/09 MSM 0902337 Cobalt <10 10 ug/L USEPA-200.7 03/03/09 KLV 0902338 Copper 5.8 1.0 ug/L USEPA-200.8 02/25/09 MSM 0902337 Iron 0.16 0.010 mg/L USEPA-200.7 02/25/09 IMF 0902338 Lead <1.0 1.0 ug/L USEPA-200.8 02/25/09 MSM 0902337 Magnesium 9.8 0.50 mg/L USEPA-200.7 02/25/09 IMF 0902338 Manganese <0.010 0.010 mg/L USEPA-200.7 02/25/09 JMF 0902338 Molybdenum <0.10 0.10 mg/L USEPA-200.7 02/25/09 IMF 0902338 Nickel <5.0 5.0 ug/L LJSEPA-200.8 02/25/09 MSM 0902337 Selenium <1.0 1.0 ug/L USEPA-200.8 02/25/09 MSM 0902337 Silver <0.50 0.50 ug/L USEPA-200.8 02/25/09 MSMi 0902337 Thallium <1.0 1.0 ug/L USEPA-200.8 02/25/09 MSM 0902337 Tin <0.20 0,20 mg/L USEPA-200.7 02/25/09 JMF 0902338 Titanium <0.10 0.10 mgIL usEPA-200.7 02/25/09 JMF 0902338 Zinc - <10 10 ug/L USEPA-20D.8 02/25/09 MSM 0902337 Page 20 of 40 This report shall not be reproduced except in full, without the written authorization of TriMatrix Laboratories, Inc.

Individual sample results relate only to the sample tested.

5560 Corporate Exchange Court SE - Grand Rapids, M! 49512 - (616) 975-4500 - Fax (616) 942-7463

AAYiLaEPix ANALYTICAL REPORT Client: DTE Energy - EM&R Work Order: 0902360 Project: Permit Renewal - Fermi, 2009

Description:

Laboratory Services Client Sample ID: GSW Intake Composite Sampled: 02/19/09 11:40 Lab Sample ID: 0902360-08 Sampled By: E.Z., T.B.

Matrix: Waste Water Received' 02/19/09 18:50 Physical/Chemical Parameters by EPA/APHA/ASTM Methods Analytical Dilution Date QC Analyte Result RL Unit Factor Method Analyzed By Batch

  • BOD, (5-Day) 1.8 1.0 mg/L SM 5210 B 20th 02/20/09 CKD 0902276 Bromide 0.51 0.10 mg/L ASTM D 1246-95 02/27/09 VAS 0902512 Chemical Oxygen Demand 8.8 5.0 mg/L SM 5220 D20th 02/23/09 CKD 0902310
  • Color (Apparent) 10.0 5.00 A.C.U. SM 2120 B 20th 02/20/09 CLD 0902294 Fluoride 0.24 0.10 mg/L SM4500-F.C 20th 02/27/09 CKD 0902571 Hardness as CaCO3 143 2 mg/L SM 2340 C 20th 03/03/09 CKD 0902612
  • Surfactants, MBAS 0.0646 0.0250 mg/L SM 5540 C20th 02/20/09 CLB 0902301 Phosphorus, Total 0.0242 0,0100 mg/L SM4SO0-P F 20tM 02/23/09 INR 0902259 Residue, Dissolved @ 1800 C 230 5o mg/L SM 2540 C 20th 02/25/09 KNC 0902404 Residue, Suspended <3-3 3.3 mg/L SM 2540 D20th 02/25/09 KNC 0902406 Sulfate 28 5.0 mg/L ASTM D516-90 (02) 02/26/09 GEH 0902515 Sulfide, Total <0.020 0.020 mg/L APýA 4500-S2 D 02/26/09 KNC 0902525
  • Sulfte <1.0 1.0 mg/L SM 4500-S03 B20th 02/20/09 GEH 0902339 Carbon, Total Organic 2.9 1.0 mg/L SM 5310 C 20th 02/27/09 LMA 0902550 Nitrogen, Ammonia 0.21 0.050 mg/L SM4500-NH3 G 20th 02/25/09 GEH 0902392 Nitrogen, Nitrate+Nitrite 0.68 0.050 mg/L SM4500-NO3 F 20th 02121/09 HLB 0902277 Nitrogen, Organic <0.50 0.50 mgjL USEPA-3512145-0-NH 03/-073/-0§ 0902604 Nitrogen, Total Kjeldahl <0.50 0.50 ,..n/L US-PA-351.2 02/25/09 CLB 0902309 Nitrogen, Inorganic 0.89 0.10 mg/L 02/25/09 HLB [CALCI

[CALC]

  • See Statement of Data Qualifications Page 21 of 40 This report shall not be reproduced except in full, without the written authorization of TriMatrix Laboratories, Inc.

Individual sample results relate only to the sample tested.

5560 Corporate Exchange Court SE

  • Grand Rapids, M 49512 - (616) 975-4500 - Fax (616) 942-7463

Attachment VII FERMI 2 NPDES PERMITTED WATER TREATMENT ADDITIVES This list includes those WTA that are currently approved by the Surface Water Quality Assessment Section, Water Division, Michigan Department of Environmental Quality (Permit # M10037028) tIe ..... Pdt * *nv Dischar*

-v ge conentration sh e e. Apo vautt, Product FunctionV ýý,Aftim ttmu~i Discha~rge Frequency, Document adin Depositrol BL5307 :. ýe*l 6 mg*L .* . 5*.i.g/L 24 hr/d 7 d/wk* .. OnFile Letter dated 11/22/00'-

SDepositro1 BL5400 Del 0.31 mg/L 2 9L24 h rd 7dlwk 7OFile Letter dated 11/22/00 Depositrol'PY5204 Del 0.4mg/L. 10 mg/ 24 hr/d i7d/wk

.. On File

.,,.£ Letter dated 11/22/00 Depositrol PY5206 tDel 0.2 mig!L ~.i48mj/L:24rd 16 7idk On File Letter dated 11/22/0(0 Sodium Hypochlorite iK .B ,<30 ug/L 3*8 ug/b 'U>160 min/d 7 d/wk Permit Limitation Part I.A 1 Sodium -Sulfite Dh~gnto~~n~~i 1.5 times the,:stoicfiomnetric PermPermitLimitation amount of applied chlorine-/ Part .A:1,,

brominie oxidiant Bisulfite  :.Dehalogenatiom a- e ti I 1.5 times: the stoichiometric -. Permit Limiitationi S-- Part l.A.Le and .On*t

":-.n. of applied chlorineF**:-File letter* dated bromine oxidant 9/20/02

.Spectru sCT 1300. id Mlusii 3.2 ug/L* 3.32.u,/L See Permit : See Permit Permit Limitations Part [.A. land Spe~ctrus DTI400,'- Detox for(CT1300~hK~ . . Permit Limitations.

.Part I.A.2Ian Spectrus BD- 150:01 DepositICon1trol ~ 2 g/l 24rd3dyr . On File S,,.~. ~Letter

.~* ~.. dated 4/5/01 Flogard:MS6209 Corrosion Inh~ibitorm, A-110 ug/l 24 hr/d 30 d/yr On File I ~1 Letter dated 5/10/01 Mifai cdAL,.tfrO t~i~be 0...O ug1.*AS 24.hr/d ~ 7,d/wk' On File'

ýý-Prbe,'1,16:5 0) LtterDated-11/26/02 MuriAtic Acid/-! Scale Control ~V~¶04~g *~ 24 hr/d 7 d/wkOnFl Sulfuric Ac'id-- p 6590~Letter  :.. Dated 12/7/04:

Flogard MS6222 CorrosionIanhibitor. 1.5mg/L. -4 hr/d 30Od/yr On File:

- Lettei Daed 6/27/03 Aqa~thol K Aquatic Herbicide .1 ~ u/ 1. 24 lii- /d 5'd/yr On File Letter Dated.

  • R~ewardý Landsciipead Herbicide'j.~. -~~ 84 uglt 24 hrt /d 5 /r On Fil LteDated Aquatic Herbicide:.. .I.My2,20 CutrineýPlusýAlgacd H.....b-icideg.;A 2 h/ ~ m/y On File Letter Dated
  • - ~.~.~.. ~ - May 24, 2007

,SodiuniHypochlorite~ 7_3; 'roidj.~~ <30 8u/L8h/ d/yr It. Pri iiain-

-Polyflob AP 1.120C :

  • mg*L oag V.c'ru.T*13 0 0, 1 mg/La
7".7" ".

... 8,hr/d, Part I.A.5

,PeppsitroLBL5 40 '4idcyr' On

.. Deposit Cointri. .Letter datedFile 01 11/22/00 Spectrus BD Shr/d4 7d/yr 15 00:

  • On File 2;-0 119g/111 Letter dated Deposit Control . 6/.,1/03

, FlogardMS620 q " OnFile A.:-:;l+,.5 m.,uz:g/L Letter dated 6/17/03

-1.-)ugli -:, 8 hr/d

',4 d/yr On Filet 2

)i Letter dated

,;! D epositrol See8 hf/d 6/f7/03..

BL5E 47d/yr On File, Leposit Contro D0 0.1ug/L .See: Pet-r Letter dated 1'3 Ifr 6/17/03

++ + + +,.. Polyfloc

.+ :. AP 12 6 mng/L. it i:.:i;:*

0 -~ P~ageiInt)~ etigz~01m! 24 hr/d Letterdated Klaraid PC2700 7d/yr 120/04,

'44 lit-...

OnFile -

Letter.dated :1122100-24 hr/d,

  • Refer to permit S. *  ; ::: ,..* '.. +: Letter ".On File dated, for specifics ¶ 3.,4mg/L I,)22/00-,
    • Equates to on outfalls 001A No L-Jimt Letter dated.t tf22/00.

addition rate and 001B No Limitii.;

of 40 ml/minute On File'.

Current as of Letter dated tI18/01 March 12, 2009

Attachment VIII NPDES Permit Application for Reissuance Fermi 2 Power Plant M10037028 Outfall 009 Analyses, Pending The treatment system for Outfall 009 consists of a 3 chambered settling basin. At the time samples were to be obtained for the Fermi 2 NPDES Permit application, all chambers were ice covered. The MDEQ Permit Unit Chief advised that samples be obtained after the ice cover dissipates, as samples obtained for other permittees from ice covered treatment systems have been found to be not representative of the discharge under normal operations. Ice cover has recently dissipated from the surface of this treatment system.

Sampling and analyses are pending, and will be submitted as soon as results are available.

MI/DEQ/WB-08/052 MICHIGAN DEPARTMENT OF ENVIRONMENTAL QUALITY WATER BUREAU JUNE 2008 STAFF REPORT ACUTE TOXICITY ASSESSMENT OF DECO-FERMI-2 PLT OUTFALL 009 EFFLUENT NEWPORT, MICHIGAN MAY 13-15, 2008 NPDES PERMIT NO. M10037028 Staff of the Surface Water Assessment Section performed a Daphnia magna (D. magna) acute toxicity test on a grab/composite sample of the DECO-Fermi-2 Pit outfall 009 effluent from May 13-15, 2008. The facility was operating normally when the sample was collected.

Toxicity testing was performed according to the Great Lakes and Environmental Assessment Section Procedure 24 (procedure available upon request). The effluent samples did not contain quantifiable levels of total residual chlorine (level of quantification 0.02 milligrams per liter).*

Therefore, dechlorination was not necessary.

The facility discharges storm water runoff, low volume wastes, and chemical and nonchemical metal cleaning wastes from outfall 009 to Swan Creek via an overflow canal (discharge flow rate = 0.72 million gallons per day at the time of sampling). The allowable acute toxicity level for the effluent at the time of the test was 1.0 acute toxic unit (TUa).

SUMMARY

1. Test water quality parameters met test acceptability criteria (data available upon request).
2. The acute toxicity of the effluent to D. magna (0.0 TUa; Table 1) did not exceed an allowable level (1.0 TUa).
3. The D. magna control (21% mortality) failed to meet quality assurance/quality control criterion (<_10% mortality) for an acute toxicity test. However, there was no toxicity observed. Therefore, the effluent was not toxic to D. magna.

Test and Report by: Diana Butler, Laboratory Technician Surface Water Assessment Section Water Bureau Reviewed by: William Dimond, Aquatic Biology Specialist Surface Water Assessment Section Water Bureau

Table 1. Percent mortality of D. magna exposed to selected concentrations of DECO-Fermi-2 Pit outfall 009 effluent from May 13-15, 2008.

Percent Mortalit Effluent Concentration 24 Hour 48 Hour Control* 0 21 32 0 5 42 5 5 56 0 0 75 5 0 100 0 0

  • Control water was aerated carbon-filter Lansing City water.

2

Attachment IX NPDES Permit Application for Reissuance Fermi 2 Power Plant M10037028 Request for Waiver - Outfall 011 Analyses The Company requests a waiver for submittal of analytical data at the Fermi 2 Power Plant Outfall. 0 11 for the following reasons:

  • Monitoring is required at Outfall 011 only during times of oily wastewater discharge. This effluent has been re-routed to the Monroe Metropolitan Water Pollution Control Facility via Permit No. 1020 (City of Monroe)
  • The company retains the option to discharge via Outfall 011 if at any time discharge to the City of Monroe is no longer permitted. At that time, the company will notify the MDEQ and arrange to submit the required analytical information, to be obtained upon commencement of discharge via Outfall 011.

Attachment X NPDES Permit Application for Reissuance Fermi 2 Power Plant M10037028 Request for Waiver - Ouffall 013 Analyses The Company requests a waiver for submittal of analytical data at the Fermi 2 Power Plant Outfall 013 for the following reasons:

" Monitoring is only required at Outfall 013 during the infrequent discharge of dredged material effluent. The water treatment additives that enhance settling are previously approyed and do not

,require separate monitoring.

  • Total suspended solids (TSS) is the only parameter of concern for this monitoring point. This data is submitted as required during times of discharge on the Discharge Monitoring Report. There are no process wastewaters that are discharged via this monitoring point.

Attachment XI Detroit Edison: Fermi 2 Power Plant - 2009 NPDES Permit Application No. M10037028 Section IV, Item l.B. - Material Stored in Secondary Containment Structures

1. No. 2 Fuel Oil
2. Sodium Hypochlorite
3. Mineral Oil