ML19308D117

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RO-77-17:on 770207,while Preparing to Enter Mode 4,sodium Hydroxide Was Introduced Into Rcs,Due to Cycling BSV-36 W/ Valves DHV-41,DHV-4 & DHV-3 Open.Caused by Inadequacy in SP-342.SP Revised
ML19308D117
Person / Time
Site: Crystal River 
Issue date: 03/01/1977
From: Stewart W
FLORIDA POWER CORP.
To:
Shared Package
ML19308D100 List:
References
CS-77-38, NUDOCS 8002270604
Download: ML19308D117 (3)


Text

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Re-l 7 n9 eo Ql dundant systems were available. This was not a repetitive occurrence.

Surveillance l 7 89 80 hl Procedures have been revised to prevent introduction of NaOH into the DH System.

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Supplementary Information gv 1.

Report No.:

50-302/77-17 2.

Facility:

Crystal River Unit 3 3a.

Report Date:

1 March 1977 3h.

Occurrence Date:

7 February 1977 4.

Identification of Occurrence:

In Mode 5, while preparing to enter Mode 4, Decay Heat Removal in recircu-lation, sodium hydroxide was introduced into the Reactor Coolant System due to cycling BSV-36 with valves DHV-41, DHV-4, and DHV-3 open.

5.

Conditions Prior to Occurrence:

On 7 February 1977, during routine operations while in' Mode 5 (Cold Shut-f' down), Train "A" of the Decay Heat Removal System was being used to recircu-late the Reactor Coolant System and the Reactor Coolant System was being filled from the "C" Bleed Tank.

6.

Description of Occurrence:

In preparation to enter Mode 4 (Hot Shutdown), Reactor Coolant System filling and recirculation was discontinued by closing DHV-5, and "A" Decay Heat Pump was lef t on recirculation, in order to cycle valves BSV-36 and BSV-37 as re-quired by SP-342, Building Spray System Valve Check.

When BSV-36 was cycled. sodium bydroxide was iatroduced into the Reactor Coolant System from the sodium ha aroxide tank via open valves DHV-41, DHV-4, and DHV-3.

Recirculation and filling were resumed and a Boron analysis indicated a con-centration of 305 ppmB. Actual' Boron concentration (approximately 1500 ppm) was masked by sodium hydroxide.

Filling was immediately terminated and source range instrumentation was closely monitored with no inersase in count rate.

After a second Boron analysis, it was realized that sodium hydroxide had been introduced into the Reactor Coolant. System.

7.

Designation of Apparent Cause of Occurrence:

The cause of this occurrence was procedural inadequacy in that no precautions in the Surveillance Procedure noted that BSV-36 should not be cycled with the Decay Heat Removal System in Reactor Coolant System recirculation mode.

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8.

Ana]ysis:

Initial concern that a Boron dilution had occurred was found to be un-justified. The alkaline sodium hydroxide masked the Boric Acid in the titration analysis. Boron concentration remained at approximately 1500 ppm. There are no specifications for sodium hydroxide content in the Reactor Coolant System below 2500 F.

The system temperature was approximately ambient. The chloride and fluoride content of the water in the sodium hydroxide tank were sufficiently high to.cause a violation of Technical Specification 3.4.7.

Engineecing evaluation indicates that, because of the low system temperature and the pH remaining above 7, chloride contamination in the range of 1.0 ppm which was experienced is not of significant concern. The level.was returned to less than.05 ppa using the makeup and purification demineralizers.

Redundant systems (both Decay Heat and Boron addition) were available and operable. No hazard was presented to the Plant or public as a result of this occurrence.

9.

Corrective Action:

i Cleanup was initiated via the cation demineralizer system. Procedures have been revised to preclude recurrence.

Final sodium content after 7-cleanup was less than.1 ppm.

10.

Failure Data:

J No previous failures of this type have occurred.

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