ML17058A954

Rev 4 to Administrative Procedure AP-3.7.1, Unit 2 Radwaste Process Control Program

ML17058A954
Person / Time
Site:	Nine Mile Point
Issue date:	03/06/1991
From:	Mccormick M NIAGARA MOHAWK POWER CORP.
To:
Shared Package
ML17058A955	List: ML17058A954 ML17058A956 ML18038A369
References
AP-3.7.1, NUDOCS 9109090104
Download: ML17058A954 (74)

Text

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pbp NIAGARA MOHAWK POWER CORPORATION NINE MILE POINT NUCLEAR STATION ADMINISTRATIVE PROCEDURE

~AP-..1 VI I WA TE P

Approved By:

M. J.

McCormick Plant an ger, Unit 2 Date Effective Date:

NOT TO BE USED AFTER SUBJ ECT TO PERIODIC REVIEW 9t0S 0SO>oe 9>0S2S PDR ADOCK 050004i0 R

PDR

LI FE IVEPAE 2

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Page 1

AP-3.7.1 Rev 04

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~TISH

~PA 1.0 PURPOSE..

2.0 SCOPE

3.0 REFERENCES

AND COMMITMENTS

4. 0 DEFINITIONS

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5. 0 RESPONSIBILITIES 6.0 PROCEDURE 6.1

6.2 System Description

Asphalt Volume Reduction System.....................

11 6.3 Administrative Controls..

18 7.0 ATTACHMENTS.

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21 Attachment 1:

Unit 2 Radwaste Process Control Program Implementing Procedures..

22 :

Attachment 3: : :

Attachment 6:

Attachment 7: :

Solid Waste Sources,...

24 System Flow Schematic.

Operator Worksheet Temperature Profile Log.

Barnwell Hanifest.....,.............

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31 US Ecology Manifest....

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33 Process Control Flowpath............,.............,.

26 Page ii AP-3.7.1 Rev 04

1. 0 PllJPggg 1; 1 To describe the methods for processing, packaging and transportation of low-level radioactive waste and provide assurance of complete solidification of various radioactive "wet wastes" in accordance with app'licable NRC regulations and guidelines.

1.2 To satisfy the Nuclear Regulatory Commission's Low-Level Waste and Uranium Recovery Projects Branch (WNLU) requirement and establish process parameters within which the Werner IE Pfleiderer Corporation Volume Reduction System (NPC-VRS) must be operated to ensure complete solidification.

1.3 Haste process under this program using asphalt as the media is limited to Class A Waste.

tgTE:

Conformance with NHLU requirements provides assurance that the requirements identified in 10CFR61, Sub Part D,

Technical Requirements for Land Disposal Facilities and Final Waste Classification and Waste Form Technical Position

Papers, which requires that Class A Waste shall be a free standing monolith with

<.05

% free standing liquid.

2.0

/CD 2.1 bi i t 2.2 This procedure applies to the Unit 2 Radwaste Process Control Program for solidification and transportation of radioactive waste.

Ob ect ve 2.2.1 2.2.2 2.2.3 2.2.4 2.2.5 2.2.6 To satisfy the Nuclear Regulatory Commission's Low-Level Haste and Uranium Recovery Projects Branch (NMLU) requirements.

To establish process parameters within which the Werner and Pfleiderer Corporation Volume Reduction System (WPC-VRS) shall operate to ensure complete solidification of waste.

To ensure compliance with Federal regulations for the packaging and transportation of radioactive materials.

To ensure Radwaste Operators are trained and qualified in the operation of radioactive waste processing equipment, To ensure Chemistry Technicians are trained and qualified in the sampling and analysis of wet radioactive waste.

To ensure Radiation Protection Technicians are trained and qualified in radiological controls monitoring of radioactive waste shipments.

Page 1

AP-3.7.1 Rev 04

3.0 3;1 REFE N

San rs i

s 3.1.1-3.1.2 3.1.3 3.1.4 3.1.5 3.1.6 3.1.7 3.1.8 3.1.9 3.1.10 ANSI/ANS 55.1,

1979, American National Standard for Solid Radioactive Waste Processing System for Light Water Cooled Reactor Plants 10CFR20,311, Transfer for Disposal and Manifest 10CFR20.311.d.3, Transfer for Disposal and Manifest

10CFR61, Sub Part D, Technical Requirements for Land Disposal Facilities and Final Waste Classification and Haste Form Technical Position Papers 10CFR61,55, Waste Classification 10CFR61.56, Waste Characteristics

10CFR71, Packaging and Transportation of Radioactive Material 49CFR173.1.b, Transportation 49CFR173.425, Transport Requirements for Low Specific Activity (LSA) Radioactive Materials NUREG-0123, Standard Radiological Effluent Technical Specifications for Boiling Water Reactors 3.1.11 NUREG-0800, a.

Section 11.2, Standard Review Plan for Liquid Waste Management Systems b.

Section 11.4, Standard Review Plan for Solid Waste Management Systems 3.1.12 32 R

1 r

3.2.1 Resource Conservation and Recovery Act (RCRA) of 1976 (Ref.

Corporate Guide to Hazardous Haste Disposal and Spill Reporting)

I idel in Regulatory Guide 1.143, Rev. 0, Design Guidance for Radioactive Waste Management

Systems, Structures, and Components Installed in Light Hater Cooled Nuclear Power Plants Page 2

AP-3.7.1 Rev 04

33 Li n

3.3.1 QATR-1, Quality Assurance Program Topical Report for Nine Mi.le Point Nuclear Station Operations, Section 17.0, Quality Assurance Records 3.3.2 ni 2 T hn n:

a.

Section 3.11.3.a, Solid Radioactive Wastes b.

Section 3.11.3.b, Solid Radioactive Wastes c.

Section 4.11.3.a, Solid Radioactive Wastes d.

Section 4.11.3.b, Solid Radioactive Wastes e.

Section 6.5.2.11, Review and Audit, Technical Review and Control Activities f.

Section 6.5.3.8.i, Review and Audit, Safety Review and Audit Board 3.4 g.

Section 6.9.1.8, Semi-Annual Radioactive Effluent Release Report h.

Section 6.13, Process Control Program

~ld 3.4.1 3.4.2 3.4.3 3.4.4 3.4.5 3.4.6 3.4.7 3.4.8 3.4.9 3.4.10 AP-2.0, Production and Control of Procedures AP-7.2, Control of Material Storage Areas AP-9.0, Administration of Training AP-10.1, Management of Station Records N2-CSP-14, Solid Radwaste Chemical Surveillance at Unit 2 NZ-OP-41, Asphalt Solidification Operating Procedure N2-NTP-13, Nuclear Department Training Manual N2-WHP-l, Required Documents Concerning Packaging and Shipping of Radioactive Wastes N2-HHP-2, Paperwork for a Radioactive Haste Shipment N2-WHP-4, Cask Loading Procedure 3.4.11 N2-HHP-8B, Flatbed Loading Procedure Page 3

AP-3.7.1 Rev 04

3.5 3.4.12 N2-WHP-9, Asphalt Solidification 3.4.13 N2-WHP-9A, Operating Procedure Vendor Solidification 3.4.14 N2-WHP-9B, Process Control LN Cement Solidification 3.4.15 N2-WHP-10A, Process Control Oil/Cement Solidification Procedure 3.4.16 N2-WHP-10B, Cement/Oil Solidification Procedure 3.4.17 NZ-WHP-11, Process Control Dry Solid Waste 3.4.18 N2-WHP-12, Solid Dry Waste Collection and Compaction 3.4.19 N2-WHP-14, Solidified Liner Inspection Program 3.4.20 NTP-l, Training and Continued Training of Chemistry and Radiochemistry Technicians 3.4.21 NTP-13, Training and Continued Training of Radwaste Operators 3.4.22 NTP-14, Training and Continued Training of Radiation Protection Technicians 3.4.23 S-RPIP-7.1, Movement and Storage of Radioactive Material on Site 3.4.24 S-RPIP-7.2, Receipt of Radioactive Material 3.4.25 S-RPIP-7.3, Determination of Shipment Type 3.4.26 S-RPIP-7 ',

Cask Shipments 3.4.27 S-RPIP-7.5, Van/Flatbed Shipments 3.4.28 S-RPIP-7.6, Activated Materials Shipments 3.4.29 S-RPIP-7.7, Non-Waste Radioactive Shipments 3.4.30 S-RPIP-7.8, Shipping Documents 3.4.31 AP-3.3.1, Site Alara Program g~h-Pqf<KqX~

3.5.1 3.5.2 South Carolina Department of Health and Environmental Control, Radioactive Material License

097, as amended State of Washington Radioactive Material License No.

WN-I019-2, as amended Page 4

AP-3.7.1 Rev 04

3.5.3 Herner and Pfleiderer Corporation Topical Report No.

WPC-VRS-OOl, November

1976, Rev.

1, May 1978, Appendix B, Solid Content 3.5.4.

NRC Special Nuclear Material License No. 12-13536-02, as

amended, for Barnwell, SC 3.5.5 NRC Special Nuclear Material License No.

16-19204-01, as

amended, for Richland, WA 3.6 3.5,6 Nuclear Regulatory Commission Branch Technical Position on Waste Classification and Waste

Form, May 1983 I

Sequence

~Nmb r NCTS NumluNr D

r i n

None 4.0 DE I ITIONS 4.1 "A" Ha e

4.2 Waste usually segregated from other waste classes at the disposal site.

The physical form and characteristics shall meet the minimum requirements of 10CFR61.56, Waste Characteristics.

1 "8"

Wa Haste meeting more rigorous waste form requirements to ensure stability after disposal.

Class B waste form shall meet both the minimum and stability requirements of 10CFR61.56, Waste Characteristics.

4.3 Waste meeting Class B standards and requiring additional measures at the disposal facility to prevent inadvertent intrusion.

5.0 B

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N The General Superintendent, Nuclear Generation shall review and approve changes to the Unit 2 Radwaste Process Control Program in accordance with Unit 2 Technical Specification, Section 6.5.2.11, Review and Audit, Technical Review and Control Activities.

Page 5

AP-3.7.1 Rev 04

5.2 S

The Station Superintendent shall ensure the Unit 2 Radwaste Process Control Program provides for the health and safety of the general public as it applies to Radwaste Management.

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The Supervisor Radwaste Operations shall:

5.3.1 5.3.2 Implement the Radwaste Process Control Program.

Interface with the Unit Supervisor Chemistry and Radiochemistry on matters concerning radwaste processing and

disposal, as required.

5.3.3 Interface with the Manager Radiation Protection on matters concerning radwaste processing and disposal, as required.

5.3.4 Supervise activities related to radwaste collection, processing, packaging,

storage, transportation, and disposal.

5.3.5 5.3.6 Review Radwaste Process Control Program implementing procedures to ensure validity of technical content and compliance with applicable Federal and State Regulations, Technical Specifications, Company Policies, and the Station Operating License.

Ensure compliance with Federal and State Regulations governing the transportation and disposal of radioactive material.

5.3.7 Ensure Radwaste Operators complete required training and qualification and maintain proficiency, as required.

5.4 Un u

v The Unit Supervisor Chemistry and Radiochemistry shall:

5.4.1 5.4.2 5.4.3 Interf'ace with the Supervisor Radwaste Operations on matters concerning radwaste processing and disposal, as required.

Ensure Chemistry Technicians complete required training and qualification and maintain proficiency, as required.

Ensure Chemistry Technicians calculate and determine Haste-to-Asphalt flow rates and contents in accordance with established procedures.

Page 6

AP-3.7.1 Rev 04

5.5 The Manager Radiation Protection shall:

5..5.1-Interface with the Supervisor Radwaste Operations on matters concerning radwaste processing and disposal, as required.

5.6 5.5 '

mi tr Ensure Radiation Protection Technicians complete required training and qualification and maintain proficiency, as required' a

5.7 Chemistry and Radiochemistry Technicians shall perform analysis of radioactive waste samples.

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ia 5.8 Radiation Protection Technicians shall perform radiological controls monitoring on radwaste shipments.

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Radwaste Operators shall perform operations associated with radwaste processing.

6.0

~PRO ED RE 6.1 emD c i n

6.1.1 The Solid Waste Management System (SWMS),

implemented by the procedures identified in the Unit 2 Radwaste Process Control Program Implementing Procedures (Attachment

1) collects, reduces the volume, solidifies, and packages wet and dry types of radioactive waste in preparation for shipment off-site to a licensed burial site.

C.

Types of solid waste sources are identified in Solid Haste Sources (Attachment 2).

Radwaste Process Control Flowpath (Attachment

3) and System Flow Schematic (Attachment 4) are provided for the Unit 2 SHMS.

d.

The Solid Waste Management System accepts dry solid trash which is, when physically possible, compacted with a trash compactor.

Page 7

AP-3.7.1 Rev 04

(Cont) e.

Bead resins or powdered resins are dewatered in high integrity containers or processed along with evaporator bottoms through the extruder evaporator.

f.

When required, Unit 2 will use the services of a vendor to solidify waste.

Ex r r/

a.

The extruder/evaporator is a one-step volume reduction and solidification process.

b.

Two screws inside the twin screw extruder/evaporator convey the waste/asphalt mixture along the length, continually shearing and mixing the waste/asphalt.

c.

The screw speed can be regulated to control the evaporating capacity and residence time of the waste.

d.

The extruder/evaporator discharges a homogeneous mixture of asphalt and waste containing

~N free standing water.

The solid radwaste system uses the extruder/ evaporator to process waste fed from two inputs; the evaporator bottoms tank or the waste sludge tank.

The waste is mixed with asphalt in the extruder.

Only one waste feed path can be processed at a time f.

Operation of the extruder/evaporator is detailed in N2-0P-41, Asphalt Solidification Operating Procedure.

Ev r

B a.

The evaporator bottoms tank and lines are electrically heat traced to prevent crystallization of waste salts.

b.

The contents of the tank are fed to the extruder/

evaporator via a transfer pump that supplies redundant metering pumps.

c.

The waste flow rate is controlled manually by adjusting the flow rates on the metering pumps.

1 T

The contents of the waste sludge tank are fed to the extruder/evaporator by a separate system from the evaporator bottoms feed system.

This system has redundant waste sludge metering pumps.

Page 8

AP-3.7.1 Rev 04

(Cont)

C.

The waste sludge tank is supplied by waste from three sources:

the radwaste filters, the floor drain filter, and the spent resin tank.

The waste flow rate is controlled manually by adjusting the flow rates on the metering pumps.

d.

The waste sludge tank has the ability for decantation.

A decant pump takes a suction off the sludge tank and discharges to the spent resin tank.

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El The contents of the asphalt tank is fed to the extruder/evaporator via redundant recirculation

pumps, strainers, and metering pumps.

The asphalt flow rate is automatically adjusted to yield the proper ratio of asphalt to solids.

The asphalt tank and lines are continuously steam heated to keep the asphalt in a liquid state for ease in pumping.

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As the waste/asphalt mixture moves through the extruder/evaporator, the mixture is heated by steam from the electric radwaste boiler.

b.

e.

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The boiler is a skid mounted boiler system whi ch uses electricity for steam production.

The boiler is a closed

system, therefore, most of the water used for steam is returned to the boiler as condensate via the boiler feedwater system.

The boiling vessel is capable of supplying 14004/hr of steam at 233 psig and 400 F.

The steam applied to the extruder is used in six separate heating zones for moisture evaporation.

Each zone has a separate temperature controller for optimum operating conditions.

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n P r a.

Three devolatization ports along the extruder allow for water vapor to separate from the product and enter the three steam domes.

Page 9

AP-3.7.1 Rev 04

6.1.7 (Cont) 6.1.8 C.

A predetermined amount (4 gal.) of demineralized water is used, which dissolves and boils out salt sediment at the devolatization port.

The vapors are condensed in the steam domes using turbine building closed loop cooling and drained to the distillate collection system.

The distillate collection system is a recirculating system used to continuously filter and cool the condensate from the extruder/evaporator steam domes.

The condensate is recirculated from the distillate collection tank through the distillate pumps, roughing filter, and the distillate cooler, then routed back to the collection tank.

6.1.9 c

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V n The level controller maintains collection tank level and system flow.

1 i

n m

a.

A forced circulation ventilation system is incorporated into this system.

b.

The system consists of a vent hood over the extruder/

evaporator turntable, a fan which draws air from the plant ventilation system across the extruder/evaporator turntable, and liner cool down areas.

6. 1. 10

~~r The extruder/evaporator product empties into 50 cubic feet liners.

The liners are placed on the fill station turntable.

The operator indexes (turns) the turntable via a control switch, placing a liner under the discharge chute of the extruder/evaporator.

The turntable holds three liners.

When the liner level reaches a predetermined

level, a high level alarm sounds to inform the operator it is time to index the container.

Page 10 AP-3.7.1 Rev 04

6. 1. 10 (Cont) d.

Liners are indexed without shutting down the extruder/evaporator.

Using control switches, the

operator, via a pneumatic carrier, extends a drip pan under the extruder/evaporator discharge chute.

The.

operator then indexes the turntable.

e.

Once the new liner is in place under the extruder/

evaporator discharge

chute, the pneumatically operated carrier is withdrawn.

f.

During this withdrawal operation, the drip pan is removed from the carrier by a stationary arm as the carrier retracts past the arm and drops the drip pan into the new liner.

6.1.11

~r ~n 6.2 a.

Full liners are removed from the turntable to the cooldown area via a radio controlled/operated crane.

b.

After cooldown is completed, the liners are moved by crane to the storage area using a ceiling grid coordinated system for placement of the liner.

c.

When the liners are to be shipped, the liners are moved to the capping station and capped just before shipment then loaded for transportation to the burial location.

~Ah lt V lum d

m 6.2.1 6.2.2 Radwaste Operators shall ensure proper equipment is available before beginning radwaste processing.

Radwaste Operators may process wastes through the extruder/evaporator when the following equipment is operable:

a.

Closed circuit television system at the asphalt loading stations b.

Calibrated temperature profile monitoring instrumentation c.

Operational asphalt and waste metering equipment d.

Solid radwaste sampling stations.

Pr Pr Radwaste Operators shall control the following variables to ensure the final waste product is a free standing monolith with essentially 59 free standing water:

a.

Asphalt type Page ll AP-3.7.1 Rev 04

(Cont) b.

Waste chemical species being incorporated into the asphalt matrix/water content c.

Ratio of waste-to-asphalt d.

Process temperature e.

Additional process variables such as pH, that do

~N T affect the ability of the waste product to form a solid free standing monolith upon cooling A

1 T

Radwaste Operators shall:

a.

Use an oxidized petroleum-based

asphalt, conforming to ASTH-D-312-71, Type III requirements with the following properties:

1.

Has a low residual volatile content 2.

Has a high molecular weight 3.

At room temperature, or ambient conditions, is a

free standing monolith 4.

Specify Witco Pioneer 221, or an equivalent asphalt

.ggg:

Consult Werner and Pfleiderer Corporation if an alternate asphalt material is to be used.

b.

Ensure verification of asphalt type is conducted per NZ-CSP-14, Solid Radwaste Chemical Surveillance at Unit 2.

h Radwaste Operators shall ensure:

Testing is performed to determine the oil content and physical properties of the waste to be solidified per N2-CSP-14, Solid Radwaste Chemical Surveillance at Unit 2.

b.

Adherence to the Werner and Pfleiderer limit of 1.0%%d oil and organic contaminants in the waste feed stream for process control.

Page 12 AP-3.7.1 Rev 04

6.2.5 Type and relative quantity (waste-to-asphalt) of waste chemicals being incorporated in the asphalt matrix has a direct influence on the properties of the final product:

l.

Encapsulation of inorganic salts and solids typically "stiffen" and harden the waste product.

2.

Encapsulation of organic liquids typically softens the waste product.

a

-A Radwaste Operators shall use the following waste-to-asphalt ratios:

~N T :

Optimum values depend on type and quantity of contaminants present.

a.

Evaporator Concentrates 40/60 to 50/50 b.

Spent Resins - 45/55 to 50/50 c.

Filter Sludge 40/60 to 50/50

MOOT, When the ratio of waste-to-asphalt is increased above the range specified

above, the end product viscosity will increase and may exhibit a grainy texture.

This could lead to "pyramiding" of the product in the container, thereby decreasing the container filling efficiency.

6.2.6 W

1 Fl w

a.

Radwaste Operators shall set the initial proportion of waste-to-asphalt flow based on Chemistry Department calculations.

b.

The Chemistry Department shall determine the solids content of the waste feed by sampling.

c

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The Chemistry Department shall:

1.

Determine the proper feed control settings in accordance with N2-CSP-14, Solid Radwaste Chemical Surveillance at Unit 2, for flow rate calculations.

2.

Calculate flow rates based on the information supplied in Werner and Pfleiderer Corporation Topical Report No.

WPC-VRS-001, November

1976, Rev.

1, Hay 1978 Appendix B Solid Content.

Page 13 AP-3.7.1 Rev 04

(Cont) d.

Radwaste Operators shall visually confirm the proper ratios are being maintained on the Solid Radwaste Control Panel.

l.

A closed circuit televi'sion camera may be used to view the discharge from the extruder/evaporator.

2.

The television monitor located in the control room allows observation of the physical consistency as the product is discharged into the container.

Pr Tm r

r Radwaste Operators shall:

a.

Ensure a proper temperature profile is maintained along the length of the extruder/evaporator to provide adequate evaporative (process) capacity.

b.

Ensure free water is gg discharged from the machine.

QN )~TE 1.

Low temperature alarms are provided to alert the operator to a low temperature off-normal condition which could lead to the discharge of free water.

2.

Low temperature alarms are typically based on a +10 F deviation from setpoint.

The above can be adjusted up to z25/ (+75'F) of the instrument range.

C.

Adhere to the following (approximate) temperature profiles:

Evaporator Concentrates:

Zone 1

165'F Zone 2

265'F Zone 3

300'F Zone 4

330'F Zone 5/6 375'F Zone 7

350 F.

Page 14 AP-3.7.1 Rev 04

(Cont) 2.

Spent Resins, Filter Sludge:

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Zone 1

165'F

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Zone 2

265'F

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Zone 3

285'F

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Zone 4

300'F

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Zone 5/6 285'F

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Zone 7

230'F.

d.

Log temperature profiles every two hours during equipment operating run time.

Hi The Supervisor Radwaste Operations shall ensure:

a.

High Integrity Containers (HIC) are used for dewatering to satisfy the stability requirements.

b.

Each HIC is accompanied by a certificate of compliance.

c.

Dewatering procedures based on an NRC approved vendor process control program or "Topical Report" are part of N2-WHP-4, Cask Loading Procedure.

d.

Documentation of adherence to procedures are maintained as records.

n min i 1 The Supervisor Radwaste Operations shall ensure:

a.

Contaminated oils are stored in containers at designated areas within the plant.

b.

A vendor with an approved process control program acceptable at the selected burial site is used to solidify the oil.

c.

N2-WHP-10A, Process Control Oil/Cement Solidification Procedure, is used for operating the portable oil solidification system.

d.

NZ-WHP-108, Cement/Oil Solidification Procedure, is used to sample production level.

Page 15 AP-3.7.1 Rev 04

m rr R

w Pr The Supervisor Radwaste Operations shall ensure:

a.

The vendor is NRC approved and has demonstrated a

commitment to 10CFR61, Sub Part D, Technical Requirements for Land Disposal Facilities and Final Waste Classification and Waste Form Technical Position Papers stability requirements

b.

The vendor has completed Class B and C waste testing or has provided a schedule of completion.

c.

The vendor has an approved procedure to process Class A

waste (Dewatering, Solidification).

d.

Vendor procedures are acceptable if:

1.

Vendor procedures are reviewed and approved in accordance with AP-2.0, Production and Control of Procedures.

2.

A production sample level process control procedure is implemented.

3.

The vendor is provided samples in accordance with N2-0P-41, Asphalt Solidification Operating Procedure, and N2-CSP-14, Solid Radwaste Chemical Surveillance at Unit 2.

Dr iv H

The Supervisor Radwaste Operations shall ensure:

The proper and safe steps are performed to collect and prepare low specific activity (LSA) DAH in accordance with N2-HHP-12, Solid Dry Waste Collection and Compaction.

b.

Items most directly influencing the quality of the end product are identified and controlled in accordance with N2-HHP-11, Process Control Dry Sol,id Haste.

c.

DAW is examined for liquids or items that would compromise the integrity of the package or violate the burial site license and/or criteria before compacting is removed or separated.

d.

DAH is shipped in containers meeting the transport requirements of 49CFR173.425, Transport Requirements for Low Specific Activity (LSA) Radioactive Materials.

Page 16 AP-3.7.1 Rev 04

(Cont) e.

Waste precluded from disposal in LSA boxes or drums due to radiation limits is disposed of in liners in accordance with N2-WHP-4, Cask Loading Procedure.

SsKlkUJ39 Radwaste Operators and the Chemistry Department shall ensure:

a

~

b.

The evaporator bottoms tank (TklO) and the waste sludge tank (Tk8) are isolated from further input when preparing to process waste and a batch number is assigned in accordance with the Operator Worksheet (Attachment 5).

The evaporator bottoms tank (TklO) is recirculated to ensure a homogeneous mixture.

The waste sludge tank (Tk8) is agitated to ensure a

homogeneous mixture.

A sample is obtained from the tank(s) to be processed in accordance with N2-0P-41, Asphalt Solidification Operating Procedure and N2-CSP-14, Solid Radwaste Chemical Surveillance at Unit 2.

e.

The sample from the tank(s) to be processed is analyzed and the sample data sheet form in N2-CSP-14, Solid Radwaste Chemical Surveillance at Unit 2, is completed.

The Chemistry Department shall determine the chemical and radionuclide content of each sample.

Completion of the Operator Worksheet (Attachment 5).

Completion of the Temperature Profile Log (Attachment

6) during processing.

After obtaining feed rate data from the Chemistry Department,.

the given feed rates for introduction into the extruder/evaporator are selected, If batch processing is interrupted, the Radwaste Operator shall isolate the source tank until processing can resume.

ifi i

n a

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The Unit 2 Radwaste Process Control Program assures that wastes determined acceptable for near surface disposal are properly classified.

Page 17 AP-3.7.1 Rev 04

6.2.13 (Cont) b.

Haste classification is performed consistent with the guidance provided in the Branch Technical Position pertaining to Waste Classification and is based upon the concentration of certain radionuclides in the waste form as given in 10CFR61.55, Waste Classifica-tion, and 10CFR61.56, Waste Characteristics.

The methods used by Unit 2 and the frequency for determining the radionuclide concentration of the final waste form are conducted in accordance with N2-CSP-14, Solid Radwaste Chemical Surveillance at Unit 2.

c.

The Supervisor Radwaste Operations shall ensure:

1.

The minimum waste characteristic requirements identified in 10CFR61.56, Waste Characteristics, are satisfied by implementation of S-RP-6, The Packaging and Transportation of Radioactive Material.

2.

The radionuclide concentration determination methods and frequency are conducted in accordance with N2-CSP-14, Solid Radwaste Chemical Surveillance at Unit 2.

6. 3

~hm1 n t d.

The Unit Supervisor Chemistry and Radiochemistry and Manager Radiation Protection shall ensure classification of waste is performed in accordance with S-RPIP-7.3, Determination of Shipment Type.

v n rol The Manager, Nuclear gA, Operations has the authority to stop work when significant conditions adverse to quality exist and require corrective action.

6.3.1 Qgy i A

r A Pr r~i~ir:

a.

Ongoing review, monitoring, and audit functions.

b.

Performance of audits, under the cognizance of the SRAB, of the Process Control Program and implementing procedures for processing and packaging of radioactive waste at least once every 24 months as required by Unit 2 Technical Specification 6.5.3.8.i, Review and Audit, Safety Review and Audit Board.

c.

Compliance with the waste classification and characterization requirements of 10CFR61.55, Waste Classification and 10CFR61.56, Waste Characteristics.

Page 18 AP-3.7.1 Rev 04

(Cont) d.

Quality Assurance Inspectors performing radwaste inspections have documented training in Department of Transportation and NRC radwaste regulatory requirements.

e.

Quality Assurance review of vendor procedures.

f.

Quality Assurance review of vendor programs to ensure compliance with 10CFR71, Packaging and Transportation of Radioactive Materials, Quality Assurance requirements.

Tr i in Pr r

i in Pr r

r ir a.

Radwaste Operator qualification by completion of the Radwaste Operations Unit 2 Plant Training Program with:

l.

An average grade of 80 percent or above.

2.

On-the-job training in conjunction with classroom instruction to ensure each radwaste operator maintains an acceptable level of skill and familiarity associated with radwaste controls and operational procedures.

3.

Training in accordance with NTP-13, Training and Continued Training of Radwaste Operators.

b.

Training of Radwaste Operators

includes, but is

~N T limited to, familiarity with the following radwaste components or related systems:

1.

Liquid-drains, collection tanks with subsystems, waste and regeneration evaporators, and seal water 2.

Solid-Extruder/evaporator and associated support systems 3.

LWS-Computer operation and interfaces 4.

Waste handling procedures for packaging and shipping of radioactive materials 5.

Condensate demineralizer system 6.

Spent fuel and phase separators subsystem 7.

Steam supplies C.

Chemistry and Radiochemistry Technicians are trained in accordance with NTP-l, Training and Continued Training of Chemistry and Radiochemistry Technicians.

Page 19 AP-3.7.1 Rev 04

(Cont) d.

Radiation Protection Technicians are trained in accordance with NTP-14, Training and Continued Training of Radiation Protection Technicians.

e.

A formal classroom Radwaste Training Program is scheduled based on the needs of Radwaste Operations personnel.

~NTE This training may be covered in a continuous cycle or as part of the normal rotating shift schedule.

Retraining of Radwaste Operator personnel on an annual basis identifies individual needs for retraining.

1.

Personnel demonstrating a significant deficiency in a given area of knowledge and proficiency are placed in a remedial training program as directed by the Supervisor Radwaste Operations.

2.

Successful completion of the accelerated training program is evaluated by a written and/or oral examination as directed by the Supervisor Radwaste Operations.

The Requalification Training Program covers a fundamental review of system modifications, revisions or changes to procedures, and changes or experiences in the nuclear industry.

g.

Training records:

l.

Are maintained for audit and inspection purposes.

2.

Are considered permanent records.

3.

Shall meet the applicable requirements of QATR-l, Quality Assurance Program Topical Report for Nine Mile Point Nuclear Station Operations, Section 17.0, Quality Assurance

Records, AP-9.0, Administration of Training, and AP-10.1, Management of Station Records.

D n

e n i a.

Station management shall evaluate QA program audits of waste classification records to satisfy the requirements of 10CFR20.3ll.d.3, Transfer for Disposal and Manifests.

Page 20 AP-3,7.1 Rev 04

6.3.3 (Cont)

C.

Personnel shall forward changes affecting operating procedures to Nuclear-QA for review in parallel with the NMPC Operations review as required.

Site Records Management shall maintain waste management records in accordance with the appropriate administrative procedures'.3.4 Li n

-ini i d

h n

e Uni 2

w e Pr 6.3.5 Th Are submitted to the Commission by the method and containing the information as required by Technical Specification 6.13, Process Control Program.

Become effective upon review and acceptance by the SORC.

rvi r

R dwa r

i n

hall re:

Shipping manifests are completed and tracked to satisfy the requirements of 10CFR20.311, Transfer for Disposal and Manifests, in accordance with Waste Handling Procedures.

c

~

Radwaste Management monitors the status of the manifests in accordance with N2-WHP-2, Paperwork for a Radioactive Waste Shipment.

Temporary storage of solid radioactive material awaiting shipment in an area other than a designated area is done in accordance with AP-7.2, Control of Material Storage Areas.

7.0 Attachment 1:

Unit 2 Radwaste Process Control Program Implementing Procedures Attachment 2:

Solid Waste Sources Attachment 3:

Process Control Flowpath Attachment 4:

System Flow Schematic Attachment 5:

Operator Worksheet Attachment 6:

Temperature Profile Log Attachment 7:

Barnwell Manifest Attachment 8:

US Ecology Manifest Page 21 AP-3.7.1 Rev 04

W Hn 1'i N2-WHP-1 N2-WHP-2 N2-WHP-3 N2-WHP-4 N2-WHP-6 N2-WHP-7 ATTACHMENT 1

UNIT 2 RADWASTE PROCESS CONTROL PROGRAM

.I~L~QQ59.~(KKQ555 (Sheet 1 of 2)

Required Documents Concerning Packaging and Shipping of Radioactive Wastes Paperwork for a Radioactive Waste Shipment Cask Handling Procedure Cask Loading Procedure Van Handling Procedure Van Loading Procedure N2-WHP-8A Flatbed Handling Procedure N2-WHP-8B Flatbed Loading Procedure N2-WHP-9 N2-WHP-9A Asphalt Solidification Cement Solidification Procedure N2-WHP-9B Process Control LN Cement Solidification N2-WHP-10A Process Control Oil/Cement Solidification Procedure N2-WHP-10B Cement/Oil Solidification Procedure N2-WHP-11 Process Control Dry Solid Waste N2-WHP-12 Solid Dry Waste Collection and Compaction N2-WHP-14 Solidified Liner Inspection Procedure

)on Pr S-RPIP-7.1 Movement and Storage of Radioactive Material on Site S-RPIP-7.2 Receipt of Radioactive Material S-RPIP-7.3 Determination of Shipment Type S-RPIP-7.4 Cask Shipments S-RPIP-7.5 Van/Flatbed Shipments Page 22 AP-3.7.1 Rev 04

ATTACHMENT 1

UNIT 2 RADWASTE PROCESS CONTROL PROGRAM 2FJM~

(Sheet 2 of 2) i i

Pr i

Pr (Cont)

S-RPIP-7.6 Activated Materials Shipments S-RPIP-7.7 Non-Waste Radioactive Shipments S-RPIP-7.8 Shipping Documents hm r

P r

N2-CSP-14 Solid Radwaste Chemical Surveillance at Unit 2 li A

r Pr QAP-10.03 QAD Surveillance Activities for Operations QAP-10.30 QAD Inspection Activities QAP-15.01 Control of Nonconforming Items

- QAP-18.10 QAD Audits N2-OP-40 N2-OP-41 Liquid Radwaste Operating Procedures Asphalt Solidification Operating Procedure AP-10.1 AP-3.3 AP-3.3.2 AP-3.3.3 Management of Station Records Radiation Protection Program Radiation Work Permit Radiation Worker Conduct Page 23 AP-3.7.1 Rev 04

ATTACHMENT 2 WW~

(Sheet 1 of 2)

.0

~AW 1.

1 Mechanical radwaste filters filter resin and crud (backwash material) from the waste collector sub-system.

1.2 When a filter reaches a pre-determined differential pressure, the filter backwashes the material into the backwash

tank, which is then pumped to the spent resin tank.

2.0 W

LIZE 2.

1 The radwaste demi neralizers are used as an ionic exchange media for processing high quality water from the waste collector tanks.

2.2 When determined the resin can QQ longer be regenerated, the depleted resin is pumped to the spent resin tank.

3.0 D

NERA IZ 3.1 3.2 4.0 The condensate demineralizers remove soluble and insoluble impurities from the condensate water to maintain reactor feedwater purity.

After it is determined these resins can gQ longer be regenerated, the depleted resins are pumped to the spent resin tank.

F FILTE 4.1 The floor drain filter contributes to solid waste because the filter uses diatomaceous earth to process liquid waste of low quality. Input to the filter is from the floor drain system and the regeneration waste tank.

4.2 5.0 When the filter reaches a pre-determi ned pressure drop the filter backwashes to the waste sludge tank for processing through the extruder/evaporator.

PENT E

P E

R These tanks receive the exhausted powdered filter media (resins) from the fuel pool cleanup system which is subsequently pumped to the spent resin tank.

6.0 These separator tanks receive exhausted powdered filter media (resins) from the water cleanup system which is subsequently pumped to the spent resin tank.

Page 24 AP-3,7.1 Rev 04

ATTACHMENT 2 L1 (Sheet 2 of 2) 7 '

8.0 Oil from sources within Unit 2 that become contaminated are stored in containers to be solidified by a vendor with an approved procedure.

MATB D

8.1 Compactible low level trash is processed and compacted in a hydraulically operated box compactor.

8.2 Shoe covers,

trash, contaminated paper from the chemistry lab, and similar materials are included in this category.

9.0 F

0 E

L 10.0 Solid items with high dose rates are handled on a case-by-case

basis, being disposed of by methods acceptable to the burial site.

10.1 The waste evaporator processes low quality waste from the floor drain collector system

and, as an option, waste from the waste discharge tanks.

10.2 The waste evaporator is designed to concentrate the waste to a 25'/.

solid concentration.

The concentrates are then discharged to the evaporator bottoms tank for processing through the extruder/evaporator.

11.0 N

NT EVAP 11.1 The regenerant waste evaporator receives regeneration solutions from the condensate demineralizer system and radwaste demineralizer resin regeneration system as well as the radwaste regeneration sump.

11.2 The regenerant waste evaporator is designed to concentrate to a 25/. by weight solid concentration of sodium sulfate.

11.3 The concentrates are then discharged to the evaporator bottoms tank to be processed through the extruder/evaporator.

12.0 E

TRAE N

12.1 Exhausted resin from the condensate demineralizer, the radwaste demineralizer, RWCU phase separator, the spent fuel pool phase separator, and the radwaste filter backwash tanks are sluiced to the spent resin storage tank.

12.2 The waste from the spent resin storage tank is pumped to the waste sludge tank for processing through the extruder/evaporator.

Page 25 AP-3.7.1 Rev 04

~l

ATTACHHENT 3 E

L NPT Start N2-OP-41 M2 CSP 11 N2 wHP 08 N2 WHP 108 Isola>> and Mx Sample Was>>

Form Chemical Analysts Pre Red Asphalt Sampled N2 CSP.tl tt2 OP-41 M2 WHP 0 N2 WHP 08 k?.WHP OA N2 WHPA N2 Wlto 08 N2 WHP 11 N2 WHP 12 Process Was>> Form 8 RPIP-7.1 S RPIP-7.3 N2 WHP 0 S-RPIP 7

4 N2 CSP 1 ~

S-RPIP-7

~ 3 Classlry. Label and Store Waste Form To Stereos P. T.

or Shrp lor tXsposal N2 WHP 2 8 RPIP 7. 8 Prepare Mantrest N2 WHP 2 N2 WHP.2 8-RPIP-7 '

S-RPIP-7.6 S-RPIP-7.4 8 RPIP-7.8 S-RPIP-7.5 Ship Waste Form N2 WHP.2 Close Fee t3n Was>>

Form Waste Reooesd At Crsposst Sr>>

tneesd0ate Itstosat St>>

N2 WHP.2 N2 WHP.2 tt needed, teams tlstr to N3t.c.

Page 26 AP-3.7.1 Rev 04

ATTACHMENT 4 Y TEM HEM T Reactor Water Clean Up Phase Separator Spent Fuel Phase Separator Condensate Radwaste DemtnoraNzers Radwasto Domlnorallzofs Spent Tank Waste Evaporator Radwaste Filters Evap.

Bonoms Tank Waste Sludge Tank Waste iud P

Waste Sktdgo Motoring Roor Drain Filter Steam Domes R.T Tank Distillate Collection To Roor Drain FLT Eve poratof Borklms Metering Bonoms Vent

~phal Tank be OII Pumps Lube OII Filter Tank EXTIRQERrEVAPORATOR FIII Station Cool Down Area 0

Asphalt Metering Asphalt DA.W.

Storage DAW. Canpacar ~ ~LS A

Solid Waste Storage Page 27 AP-3.7.1 Rev 04

6'.2 Operator Worksheet Batch Number ATTACHMENT 5 WO E

(Sheet 1 of 2)

FIGURE I Date A batch is considered (1)

A Sampled Sludge TK, or (2) a sampled Evaporator Bottoms Tank with no waste being added to the tank during the processing of that batch.

ggg:

Batch number will consist of; BA (Batch Asphalt), year, and a four-digit successive

number, (beginning with 0001).

JL- ~0 Unit Year Batch Number b.

Type of Waste Waste Resin Filter Media Concentrate 1.

Waste Temperature 2.

Rad Level 3.

Specific Gravity 4.

pH 5.

/ Oil 6.

'/ Solid 7.

Activity oF M/Ci/ml c.

QA to verify chemistry results and flow settings prior to starting E/E QA Date d.

Feed Flow Settings l.

Asphalt feed flow settings 2.

Waste feed flow settings Radioactive materials classification 1.

Radioactive materials LSA 2.

Other Page 28 AP-3.7.1 Rev 04

ATTACHMENT 5

~E~

(Sheet 2 of 2)

FIGURE I (Cont) 6.4.2 (Cont) f.

Waste container labeled in respect to S-RPIP-7.3 1.

Labels with the appropriate data will be supplied to the Radwaste Operator by the Radiation Protection Department/

Chemistry Department.

2.

The operator must label container, g.

Radioactive waste classification 1.

Class A Waste 2.

Class B Waste 3.

Class C Waste h.

Was container labeled in respect to S-RPIP-7.3 1.

The Radwaste Operator will label the container with labels he received from the Radiation Protection Department.

i.

Temperature Profile the radwaste operator must monitor the temperature profile while processing waste.

The profile must be logged every 2 hours2.314815e-5 days <br />5.555556e-4 hours <br />3.306878e-6 weeks <br />7.61e-7 months <br /> of operations.

In addition, the operator must include liner numbers that were solidified in that batch, and record time it took to fill each container of a particular batch.

See

a. (Figure II).

NIITg:

After completion of the Operator Worksheet and temperature profile log, a copy will be returned to the Radiation Protection Department and the original returned to Radwaste Supervision for permanent records.

The radwaste operator wi 11 retain a copy in the Radwaste Control Room.

Page 29 AP-3.7.1 Rev 04

f~

ly

ATTACHMENT 6 THP P

FIGURE II a.

Temperature Profile Log Record of Temperature in Degree 'F every two hours of Run Time for a particular batch.

TYPE OF HASTE BATCH 0 START TINE Bead Resin-Precoat Filtercake w/Powered Resin-Hixed Resin and F

Precoat Filtercake w/Diatomaceous Earth-Evaporator Concentrates D

in 2

H r

200 280 320 350 300 190 200 280 320 350 350 280 f r H

r A

r H

r r

1 H

r r

2 H

r 4

r f

1 Hor M

r r

4 H

r b.

Did temperature profile remain within limits?

JNNTK.:

The temperature profile should be monitored constantly but must be logged every second hour of Run Time.

Page 30 AP-3.7.1 Rev 04

r

ATTACHMENT 7 L

A F

T (Sheet 1 of 2)

(I) GENERA'FOR'AME FACIUTY ADDRESS CITY STATE BARNWELLWASTE MANAGEMENTFACILITY Operated by CHEM NUCLEAR SYSTEMS. INC.

PO Box 726. BarnweE, Sooth Carolina 29812 (803) 259 1781 RADIOACTIVESHIPMENT MANIFESTFORM (2A) AADCACTIVE WASTE TRANSPORTATCN PERMIT NO, IS>

CARRIER TELEPHONE ADDRESS StnpptNG DATE SHIPMFNl'YPE SNIPM(KFSUIFFAC((XIOSUA(

CASK IOENTIFCAFION NO.

USA mR tv CONTACT PHONE (

)

EMERGENCY RESPONSE CONTACT.

PHONE (

(2) BILL TO:

(c) USF THIS IOMBER ON SIOPMENT LD.NUMBER A(LCONTINUA1ION PAGES OB) NUMBEROF GENERATORS PAGE OF SIOPMENT NO.

LINEA SERIAL NO.

LFNER lYPE DATE (9) TOTALFOR EACHCLASS PROPER StapptNQ NAMEa HAZARDCLASS (PER a9 CFII 122 101)

(O.

NUMBER Ford Ikxct Packages SICPMENT TOTALS ACTFVI)~VIOCFA20 0 II)

Source (Pounds)

(9)

'TQTALsNM Notcpo Grams SS Pkt nnsorcevo stow n o s osoocov4o trnwur n o t. nwrooco>> rroronrr osrorvvo tro>>not n o s ~ llosoocovo crown>>

Aosoocsvorronroctnnoo

• os Roroocov ~ Uooon l ooorcevo ttrronrl, nt o ~ oscoorvo ttotwwl tarte t~

tens I2 tactor 0 carters urrts II (12) WASTE DESCRIPTION (10) pHvscAL FORM Date (SSB) (

)Yes (

) No TNS waste(s) mull he disposed In South Caroana Dtpartn>>nl ot Health and Enwronmontal Control Approved stnrchrrv overpass(s) Io rhett statratr rorhnrtmtnts.

(11) (

I Ves (

) No THIS VEHICLE IS CONSIGNED EXCLUSIVE USE. LOADINOAND UNLOADINGMUST BE ACCOMPLISHED BY CONSIGNOR 011 CONSGNEE OR HIS DESIGNATEDAGENT.

(I9) IMPQRTANT: Thts ts lo corslr Ihal the SF>>vo nan>>d matonats <<o prop<<IF cassrs<<L des<<o<<L packs)od.

mcus ed, and Mt>>t<<L and <<e In proptr concHvtn I<< lransponason ccoocsnuo lo p>> apptcatse routshone ot 9>> Depanmonl ot Fr<<nponason, Trtaum C.IS Tcde 1129 (11)

NUMBERANDlYPE OF CONTA9IERS CNSI USE ONLY (9)

(I0)

MSIIMUMWASTE SOUDIFCATION PACKAGE es FAL AGENT (M)

(19)

(19 A)

CHEMCAL NAMEANO Ss OF WASTE FORM CLASS FOAM CHE(ATINQAGENT(St QAUQAS QB QC (19) <<ssAcatsm Is h<<etrr made lo Iha scrdh carosna tpanmont ot Heath and Envsonn>>ntd c&40Il>>t ess strpment ot tow trvrt rasoacth>> waste has t>>en Inspected H accodace wah 9>> r<<tutroments ot south carotna Aacsoacsve Mattnv Ucense No oilas amend<<L and Ihe Nucle<<Rapist<<Y comncsst<<l ~ Ltc<<no No. I2 199)s.ot as amendtd. Snd Iho ostctrvt Bavnvvsa sne Dnoosd Crtt<<ta wktvn sa hours prtor lo ttppnonL and tenner c<<shcason Is made that 9>> kwptctkm Forested no Soma ot noneompiance wah SA Fpacatao Iews. rules and reoutaacvvh DISPOSAL SITE COPY Form No. CNS.201 Ttde and Qoanttatton (I 90) stat>> rlucvconon ntvlnsa sot Tehphor>> Ncx (

)

ron rst we our clos ronu Q TNs matondmeets aa )cense r<<artren>>rts.

Q TNS mat<>ed ot at cocdaavN wkh Icense Q~.

Date Aud>>nsod Synature Ov<<pack SrN Ov<<pack Ud SrN Forksfl Q P<<MN>>IQ Antvd Date waste Crass code Trench NO.

Waste Crass Code P<<tonnd Erposure Page 31 AP-3.7.1 Rev 04

,C r l~

~e

ATTACHMENT 7.

A (Sheet 2 of 2)

GErfERASOR rfAME BARNWELLWASTE MANAGEMENTFACILITY Operated by: CHEM.NUCLEAR SYSTEMS, INC.

CONTINUATIONSHEET USE Tlfra NUMSER OM SRSTSRkf ID. SARRKR ACL COrfrfffUATIONPAGES PAGE OF OO ITCSAfOf MJClCC ACHTTTIS OTI OI CCHHARA I%CLOS OR

~OITTTIS IICII COAIAATIA CIATACAA OII IOAH AAO

~TAAR ~ n Of CAAIATHC AOI~TI OR HASTI aSCnflfn Off

~TAITS SffOAA IOHI IACAfAA CIASS Hcfnfl Ofl Oll COTTIATACA COATIAITCA HlCITS TCXIAAf If,nl II SOffAOS I ~ HfffA OR IAAfill HAHTHOS IRC0 PAGE tOTALS DISPOSAL SITE COPY Page 32 AP-3.7.1 Rev 04

ATTACHMENT 8 Y

T (Sheet 1 af 2)

Elf CfICAATCAAAK AIXNCSS CONTACI UStAttAsI ~

STATt Zt

~IIONE Det>>CNT ~

AEV SOI RADIOACTIVEWASTE SHIPMENT & DISPOSAL MANIFEST US Ecccotf. SIL lSECOIEEgy KEICkIIr>>A '~~

EXECUTIVEOFFICEE 1602) 426 7160 P.Q. BOX 7246 a LOUISVILLE,KENTUCKY40207 IN ACENTSAOcCA AEOAESS tool IOf lcl CONDCNtDTO ISfcoloyl, IAI OO SOAPS Q~~~

Ac<<W ra 41st NollltlII

~ 0 ooays wa INFTOAllh so cc 0 asser Nvykof IoloslIIOI Calf PACK 5lalt CONTecuatcph p"'+ 1 p 1 3 2 3 0 DTKA CONTACT DI PAL DCKNAIcNAAoc510 ADCAESS CITT

~UACNASS OACCA ~

MATE 01T CONTACT

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STATE IICK DAoetAUSCAtftest ~

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~ Of tCCCAOES AIKIAIAKC OVANIllyNANC le Carl

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1400KI vo 14NAOI Raococsw Makrot 0 0 ~.

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