ML101940097

E-Mail from Carla Bouligny (American Radiation Services Inc). to Wade Loo Regarding Laboratory Analysis Report for Water Samples Taken Near Harris Nuclear Plant

ML101940097
Person / Time
Site:	Harris
Issue date:	07/08/2009
From:	Bouligny C American Radiation Services
To:	Wade Loo NRC/RGN-II
References
FOIA/PA-2010-0209 ARS1-09-01568
Download: ML101940097 (17)

Text

Loo, Wade From: Carla Bouligny [CBouligny@amrad.com]

Sent: Wednesday, July 08, 2009 2:53 PM To: Loo, Wade

Subject:

Sample Results Attachments: ARS1-09-01568.pdf Sincerely, Carla Bouligny Project Manager/Chemist cbouligny @amrad.com ProjectManagers@amrad.com aIIRS iNTERNATIONAL 9 225.381.2991 Office A 225.381.2996 Fax Is/

1

I 2609 North River Road, Port Allen, Louisiana 70767 (800) 401-4277 -- FAX (225) 381-2996 INTERNATIONAL American Radiation Services, Inc.

Laboratory Analysis Report ARS1-09-01568 Preparedfor:

Nuclear Regulatory Commission (NRC)

Wade Loo USNRC Region 2 61 Forsyth St. S.W.

Suite 23T85 Atlanta, Ga 30303-8931 wade.loo@nrc.gov Phone: 404-562-4727 Fax: 404-562-4955 Project Manager R4ief Oit.ý sz(\V.

(7 N., kk.

Management ReV4w "rL 10-ý Notes: Amenrcan Radiation 8ervices, In assumes no liability for the use or iterpretation of any anaylical results provided other than the cost of the anlyosis itseWf.

Raproduotion of this report in less then full mquWes the written consent of the cbent.

Contact Person: Questions regarding this analytical report should be addressed to:

Project Manager ProjectManagers@amrad.com Phone: 225.381.2991 Fax: 225.381.2996 LELAP Cert# 01949 NELAP Cert# E87558 LELAP Cert# 01949 NELAP Cert# E97553

'A 2609 North River Road

• Port Allen, Louisiana 70767 AS1 INTERNATIONAL (800) 401-4277

• Fax (225) 381-2996 July 8, 2009 Nuclear Regulatory Commission Wade Loo 61 Forsyth St. S.W. Suite 23T85 Atlanta, Ga 30303-8931 Sample ID(S): BDL-MWI, BDL-MW2, BDL-MW3, BDL-MW5, BDL-MW6, BDL-MW8 ARS SDG: ARS 1-09-01568 Dear Mr. Loo; On May 21, 2009, ARS International received 6 aqueous sample(s) to be analyzed for Gamma Spectroscopy, 5 aqueous samples to be analyzed for Tritium, and 1 for Strontium-90.

The samples were processed and counted using the appropriate counting equipment and QA/QC for this type of analysis. Results of the analysis and QA/QC are attached in the data package.

The samples and QA/QCs were counted with a count time sufficient to meet quality control parameters for counting equipment were within acceptance criteria and statistical sound detection limits.

If you have any questions please do not hesitate to call at 225.381.2991 or email ProjectManagers@amrad.com.

Sincerely, Virgee'Mu11igan Laboratory Director ARS International

2609 North River Road 9 Port Allen, Louisiana 70767

• • INTERNATIONAL 1 (800) 401-4277 9 Fax (225) 381-2996 STARS COVER PAGE Statement of Work for Analytical Laboratories PROJECT SAMPLE IDENTIFICATION CROSS-REFERENCE TO ARS SAMPLE LABORATORY IDs SAMPLE ARS ID NUMBER(s) SAMPLE ID NUMBER(S)

BDL-MWI ARS1-09-01568-001 BDL-MW2 ARSI-09-01568-002 BDL-MW3 ARSI-09-01568-003 BDL-MW5 ARSI-09M1568-004 BDL-MW6 ARSI-09-01568-005 BDL-MW8 ARSI-09-01568-006 SAMPLE RECEIPT The samples were received in good condition. The samples were screened for radioactive contamination as per procedure ARS-062 "Sample Receiving".

ANALYTICAL METHODS The Gamma Spectroscopy determinations were performed using American Radiation Services procedure ARS-007/EPA 901.1, "Gamma Emitting Radionuclides in Water." The tritium analyses were performed using American Radiation Services procedure ARS-054, "Tritium In Water". ". The Strontium-90 analyses were performed using American Radiation Services procedure ARS-032, "Total- Strontium by Eichrom Resin Seperation."

ANALYTICAL RESULTS The result data that are flagged with "U" indicates that the activity is below the MDC.

For Strontium analyses, the LCS fell outside the acceptance criteria biased low; RER and DER didn't meet acceptance criteria due to low bias of LCS; however the LCSD is well within the acceptance criteria. The data is being reported per technical review.

2609 North River Road

• Port Allen, Louisiana 70767 VJ I It 4 1 (800) 4014277 " Fax (225)381-2996

• -* INTERNATIONAL American Radiation Services Project Manager/Laboratory Director's Comments:

"I certify that this sample data package is in compliance with SOW requirements, both technically and for completeness, other than the conditions detailed above. Release of the data contained in this sample data package and the computer-readable EDD, as applicable, submitted on diskette or by modem, has been authorized by the Laboratory Manager or the Manager's designee, as verified by the following signature."

"I certify that this electronic image and all hardcopiesproducedfrom this image accurately representthe data and is in compliance with the NRC specific requirements,both technically andfor completeness, other than the conditions detailedabove or in the sample datapackage narrative.Release, by submission through email, the data containedin this electronic image and the computer-readableEDD (as applicable), has been authorized by the laboratoryManager/TechnicalDirectoror the Manager's designee."

Laboratory Director, ARS International ignatre Title Date

__ 2609 North River Road, Port Allen, Louisiana 70767 1 (800) 401-4277 FAX (225) 381-2996 IN TERNATIONA L ARS Sample Delivery Group: ARS1-09-01568 Request or PO Number: N/A Client Sample ID: BDL-MWl ARS Sample ID: ARS1-09-01568-001 Sample Collection Date: 05/14/09 Date Received: 05/21/09 Sample Matrix: Aqueous Report Date: 07/06/09 Re, s is ErrO,+1,,2s DIoC , ,Analysis Analysis Analysis Analysis Tracer/Che.

A ption _ ResultS Ernor +/- 2Q Units Test Method Date/lme Technician Recovery H-3 187,989 1 111.800 182.529 90.162 - pCV/L ARS-054/EPA 905.0 06/14/09 22:01 BlS N/A NOTES:

Project Manager Revie Notes: American Radiation Services, Inc. assumes no liability for the use or Interpretation of any analytical results provided Other than the cost of the analysis itself. Reproduction of this report in less than full requires the written consent of the American Radiation Services, Inc.

LELAP Certificate# 01949 NELAP Certificate # E87S58

2609 North River Road, Port Mien, LouIsiana 70767 1 (600) 401-4277 FAX (225) 381-2996 INTERNATIONAL ARS Sample Delivery Group: ARS1-09-01568 Request or PO Number: N/A Client Sample ID: BDL-MW2 ARS Sample ID: ARS1-09-01568-002 Sample Collection Date: 05/14/09 Date Received: 05/21/09 Sample Matrix: Aqueous Report Date: 07/06/09 Analysis Description Analysis RESults +/-2 Analysis Error M- Cir u Analysis UnAt- An.is Test Method AnalysisI Date/ma Analysi Techntican Tracer/Chem Recovery MN-54 -0.494 1 2.533 3.930 1.965 U pCI/L ARS-006/EPA 901.1 06/11/09 18:17 JLA N/A CO-58 -0.062 i 2.019 3.460 1.730 U pCi/L i ARS-006/EPA 901.1 06/11/09 18:17 ILA N/A FE-59 -0.057 0.041 7.380 3.690 U pCi/L i ARS-006/EPA 901.1 06/11/09 18:17 ILA N/A CO-60 -1.984 11.974 4.510 2.255 U pCI/L I ARS-006/EPA 901.1 06/11/09 18:17 JLA N/A ZN-65 -0.161 6.005 8.920 4.460 U pC/L ARS-006/EPA 901.1 J 06/11/09 18:17 JA N/A NB-95 0.332 2.230 3.790 1.895 U PCI/L ARS-006/EPA 901.1 i 06/11/09 18:17 JLA N/A ZR-95 4.177 3.585 5.780 2.890 U pCI/L ARS-006/EPA 901.1 06/11/09 18:17 ILA N/A CS-134 1.375 2.209 3.670 1.835 U pCi/L ARS-006/EPA 901.1 j 06/11/09 18:17 JLA N/A CS-137 0,660 2.141 3.710 1.855 U pCi/L ARS-006/EPA 901.1 06/11/09 18:17 JLA N/A BA-140 -5.318 26.684 15.000 7.500 U PCI/ I ARS-006/EPA 901.1 06111/09 18:17 JLA N/A LA-140 0.776 2.715 4.680 2.340 U p0/I . ARSW006/EPA 901.1 06/11/09 18:17 JLA N/A H-3 520.944 I 127.666 184.586 91.178 p*/L I ARS-054/EPA 906.0 06/15/09 03:09 83S N/A NOTES:

Project Manager Review 0 U Notes: American Radiation Services, Inc. assumes no liability for the use or Interpretation of any analytical results provided other than the coastof the analysis itself. Reproduction of this report in lessthan full requires the written consent of the American Radiation Services, Inc.

LELAP Certificate# 01949 NELAP Certificate # E87558

2609 North River Road, Port a"en, Louisiana 70767 1 (800) 401-4277 FAX (225) 381-2996 INTERNATIONAL ARS Sample Delivery Group: ARS1-09-01568 Request or PO Number: N/A Client Sample ID: BDL-MW3 ARS Sample ID: ARS1-09-01568-003 Sample Collection Date: 05/14/09 Date Received: 05/21/09 Sample Matrix: Aqueous Report Date: 07/06/09 Analysis Analysis Analysis DLC u Analysis I Analysis Analysis Analysis Trocer/Chem

-- Description ReSults Error +/- 2 s M Units i Test Method Datirne Technician Recovery MN-54 0.011 2.576 4.360 1 2.180 U pCi/L ARS-006/EPA 901.1 06/11/09 18:18 JLA N/A CO-58 -0.390 8.380 3.970 i 1.985 U pCi/L ARS-006/EPA 901.1 TLA06/11/09 18:18 N/A I t 1 FE-S9 1.612 11 4.733 8.030 4.015 U pQ/L. ARS-006/EPA 901.1 06/11/09 18:18 JLA N/A CO-60 0.868 2.641 4.460 2.230 U pCI.L ARS-006/EPA 901.1 06/11/09 18:18 ]LA N/A ZN-65 -0.011 5.265 8.980 4.490 U pCi/L ARS-006/EPA 901.1 06/11/09 18:18 JLA N/A N-95. -2.627 205.030 4.390 2.195 U PCVL ARS-006/EPA 901.1 06/11/09 18:18 JLA N/A ZR-95 0.978 4.108 6.910 3.455 U PCIIL ARS-006/EPA 901.1 06/11/09 18:18 JLA N/A

,CS-134 0.659 2.844 4.780 2.390 U pCi/L ARS ,006/EPA 901.1 1 06/11/09 18:18 ILA N/A CS-137 0.190 2.829 4.770 2.385 U pCI/ I A -006/EPA 901.1 06/11/09 18:18 ILA N/A BA-140 1.314 10.033 17.000 8.500 U pCiLI ARS-006/EPA 901.1 06/11/09 18:18 ILA N/A LA-140 -3.700 8.290 6.300 3.150 U pCI/L ARS-006/EPA 901.1 06/11/09 18:18 JLA N/A SR-90 0.077 0.078 0.260 0.123 U pCI/L I ARS-O32,tEidno SRW-O1 06/16/09 16:33 BIS 83%

K-3 1056.951  ! 163.759 184.199 90.987 pCi/L ARS-054/EPA 906.0 06/15109 08:17 BIS i N/A NOTES:

Project Manager Review (I U Notes; American Radiation Services, Itn. assumes no liability for the use or interpretation of any analytical resutts provided other than the cost of the analysis itself. Reproduction of this report In less than full requires the written consent of the American Radiation Services, Inc.

LELAP Certificate# 01949 NELAP Certificate # E87558

- A 2609 North River Road, Port Allen, LouIsiana 70767 1 (800) 401-4277 FAX (225) 381-2996 INTERNATIONAL ARS Sample Delivery Group: ARS1-09-01568 Request or PO Number- N/A Client Sample ID: BDL-MW5 AS Sample ID: ARS1-09-01568-004 Sample Collection Date: 05/14/09 Date Received: 05/21/09 Sample Matrix: Aqueous Report Date: 07/06/09 Analysis Araysis Analysis DLC Qual Analysis Analysis I Analysis Descrilion Results JError +/- 2Is Units Test Method J Date/time Analysis Technican Tracer/Chem Recovery

.MN-54 0.000 2.598 4.420 2.210 U pC/L ARS-006/EPA 901.1 1 06/11/09 18'19 JLA N/A CO-58 -0.159 2.095 3.570 L 1.785 U pCL/L ARS-006/EPA 901.1 06/11/09 18:19 )LA N/A FE-59 -1.430 92.545 7.830 3.915 U PCI/L i ARS-006/EPA 901.1 06/11/09 18:19 JLA N/A CO-60 -1.109 14.557 4.330 2.165 U pCI/L ARS-006/EPA 901.1 06/11/09 18:19 ILA N/A ZN-65 -2.266 192.260 6.840 3.420 U pCiL ARS-006/EPA 901.1 06/11/09 18:19 ILA N/A NB-95 -1.091 12.628 4.030 2.015 U POiL ARS-006/EPA 901.1 06/11/09 18:19 ILA N/A ZR-95 CS-134 1.602 3.878 6.500 3.250 U pCi/L ARS-006/EPA 901.1 06/11/09 18:19 ILA T N/A

-0.589 23.569 4.250 2.125 U PCI/L ARS-006/EPA 901.1 06/11/09 18:19 JLA j N/A CS-137 1.191 2.672 4.580 2.290 U pCI/L ARS-006/EPA 901.1 06/11/09 18:19 ILA N/A BA-140 0.161 8.812 15.000 7.500 U PC/L i ARS-006/EPA 901 1 06/11/09 18:19 JLA N/A LA-140 -1.180 3.090 5.240 2.620 U pCI/L ARS!006/EPA 901.1 06/11/09 18:19 jLA N/A H-3 1096.201 166.624 183.758 90.769 pCi/L ARS-054/EPA 906.0 1BJS N/A I ______ ,______

NOTES:

Project Manager Review Notes: American Radiation Services, Inc assumes no liability for the use or Interpretation of any analytical results provided other than the cost of the analysis Itself. Reproducton of this report in kls thtanfull requires the written consent of the American Radiation Services, Inc.

LELAP Certificate# 01949 NELAP Certificate # E87558

2609 North River Road,~ Port Allen, LouisIana 70767 1 (800) 401-4277 FAX (225) 381-2996 INTERNATIONAL ARS Sample Delivery Group: ARS1-09-01568 Request or PO Number: N/A Client Sample ID: BDL-MW6 ARS Sample ID: ARS1-09-01568-005 Sample Collection Date: 05/14/09 Date Received: 05/21/09 Sample Matrix: Aqueous Report Date: 07/06/09 Analysis Analysis Analysis MDC DLC Qua Analysis nalys nalysis Analysis Tracer/Chem Desciption Results Error +/- 2 9 UnitS Test Method Date____ T Recavety MN-54 -2.917 4.386 4.140 2.070 U pCi/L ARS-006/EPA 901.1 06/11/09 18:20 ILA N/A CO-58 0.000 2.188 3.710 1 1.855 U pCI/L ARS-006/EPA 901.1 06/11/09 18:20 ILA N/A FE-59 -3.032 230.430 7.970 3.985 U pCI/L ARS-006/EPA 901.1 06/11/09 18:20 JLA N/A CO-60 0.136 2.317 4.010 2.005 U pCi/L ARS-006/EPA 901.1 06/11/09 18:20 ILA N/A ZN-65 -3.235 5.456 9.060 4.530 U pCI/L ARS-006/EP 901.1 06/11/09 18:20 JLA N/A NB-95 -0.553 4.165 3.990 1.995 U pCi/L ARS-006/EPA 901.1 06/11/09 18:20 JLA N/A ZR-95 1.448 3.931 6.580 i 3.290 U pCi/L ARS-006/EPA 901.1 08/11/09 18:20 ILA N/A CS.0.034 2.582 4.350 2.175 U pI/iL ARS-006/EPA 901.1 06/11/09 18:20 ILA N/A 0.04-.563435 CS-137 -0.785 20.065 4.190 2.095 U pCVL ARS-006/EPA 901.1 06/11/09 18:20 JLA N/A BA-140 1.091 8.802 15.100 7.550 U pCi/L ARS-006/EPA 901 1 06/11/09 18:20 ILA N/A LA-140 -2.123 8.978 5.720 2.860 U pCi/L ARS-006/EPA 901.1 06/11/09 18:20 JLA WA H.3 1552.790 204.344 182.822 90.307 pCI/L ARS-054/EPA 906.0 06/15/09 18:33 BJS WA

_ _- I _ _ _ _

NOTES:

Project Manager Review Notes: American Radiation Services, Inc. assumes no liability for the use or interpretatlon of any analytical results provided other than the cost of the analysis itself. Reproducion of this report in less than full requires the written consent of the American Radiation Services, Inc.

LELAP Certificate# 01949 NELAP Certificate # E87558

2609 North River Road,, Port Allen, Louisiana 70767 1 (800) 401-4277 FAX (225) 381-2996 INTERNATIONAL ARS Sample Delivery Group: ARS1-09-01568 Request or PO Number: N/A Client Sample ID: BDL-MW8 ARS Sample ID: ARS1-09-01568-006 Sample Collection Date: 05/14/09 Date Received: 05/21/09 Sample Matrix: Aqueous Report Date: 07/06/09 Analysis Description Analysis Results Analys.

Error ÷/- I2 s DLC Analysis . An~is Analyis Anaysis Tracer/Chem Mc Dc Qual Uis._ I Test Method Dalerm ecnca Recovery MN-54 1.083 T 2.195 3.670 1.835 U pCi/L, l ARS-006/EPA 901.1 06/12/09 17:24 JLA N/A CO-58 -0.105 1 1.965 3.370 1.685 U pCi/L ARS-006/EPA 901.1 1 06/12/09 17:24 ILA N/A FE-59 1.580 i 3.760 6.570 3.285 U pCi/L ARS-006/EPA 901.1 1 06/12/09 17:24 ILA N/A CO-60 -2.017 11.775 4,590 2.295 [ U pCI/L i ARS-006/EPA 901.1 06/12/09 17:24 JLA N/A ZN-65 -2.493 34.420 8.180 I 4.090 U pCI/LI ARS-006/EPA 901.1 06/12109 17:24 ILA N/A NB-95 -0.060 9.153 3.820 1.910 U pC/L ARS-006/EPA 901.1 06/12/09 17:24 ILA N/A ZR-95 3.194 3.111 5.040 2.520 U pCi/LI ARS-006/EPA 901.1 06/12/09 17:24 ILA N/A CS-134 -0.177 2.298 3.930 1.965 U pCi/L ARS-006/EPA 901.1 06/12/09 17:24 ILA N/A CS-137 0.335 2.225 3.880 1.940 U pCI/L I ARS-006/EPA 901.1 06/12/09 17:24 JILA N/A BA-140 1.471 8.824 15.100 7.550 U pCi/LI ARS-006/EPA 901.1 06/12/09 17:24 ILA N/A LA-140 -0.761 I 3.114 5.360 2.680 U pC/IL ARS-006/EPA 901.1 06/12/09 17:24 ILA N/A H-3 56,958 105.415 177.434 87.645 U pCI/Li ARS-054/EPA 906.0 06/15/09 23:41 BJS N/A NO NOTES:

i Project Manager Review UQ Notes: American Radiation Services, Inc. assumes no liability for the use or Interpretation of any analytical results provided other than the cost of the analysis itself. Reproduction of this report in less than full requires the written consent of the American Radiation Services, Inc.

LELAP Certificate* 01949 NELAP Certificate # E87558

2609 North River Road, Port Allen, Louisiana 70707 1 (800) 401-4277 FAX (225) 381-2996 1

QC Results Report Sample Delivery Group: ARSI 01568 Date Received: 05/21/09 Laboratory, Control Sam le Evaluation Analysis QiC Analyto Analysis cSU 1 (Is) MIDC Espacted Expected I~ Report Report Analysis Analysis Analysis Analysis Analysis Batch I Type Reslts Val. I Units Teat Method Dpe/Tlm" Technician I

ARSI1-B09-02160 LCS CO-60 24897.000 501.530 225.700 25394.583 pCl/g EPA 901.1 6/11/09 17:42 3LA 9j 5%-125%]

ARS1-B09-02160 LC$ CS-137 15371.000 367.090 140.100 15365.617 pCi/g EPA 901.1 6/11/09 17:42 JLA ARS1-B09-02160 LCS AM-241 34699.000 1259.900 276.700 34896.700 PON EPA 901.1 6/11/09 17:42 99 75%-125%I Blank Evaluation Analysis QC Analyte ymlyeis C (1 a) MDC Expected 1Report Analysis Analysis Analysi Batch Type Resu(ts Value Q Units Teat Method os/sJTime Tedmican ARS1-B09-02160 MBL CO-60 0.000 0.004 0.016 NA U PC/g EPA 901.1 6/11/09 17:42 JLA ARS1-B09-02160 MBL CS-137 0.000 0.005 0.017 NA U PONi/g EPA 901.1 6/11109 17:42 JLA ARS1-809-02160 MBL AM-241 -0.002 0.010 0.023 NA U PON/ EPA 901.1 6/11/09 17:42 JLA RER Duplicate Evaluation ___

Anlyl C Anolyslis Pault I CSU 1 (1 a) Ramat a csu 2 (18) Analsis Analsis Anaysis Anaysis RER Acm R on Q-ml Unit Tanpm~

Mehd DesTnt ehnca Batc Type Description *I TeTMthd DdoTm Tdn:*m*

ARSI-BO9-02160 LCSD CO-60 24897,000 501.530 25160.000 497.650 pCi/O EPA 901.1 6/11/09 17:42 JLA 0.26 <1 ARSI-509-02160 LCSD CS-137 15371.000 367.090 14664.000 326.430 PCVL/9 EPA 901.1 6/11/09 17:42 ILA 1.02 < 1 ARSI-B09-02160 LCSD AM-241 34699.000 1259.900 34685.000 12710.000 pCI/g EPA 901.1 6/11/09 17:42 JLA 0.00 < 1 DER Duplicate Evaluation __R I__.

Resylt Analysis Aas Andysis Analysis Analysis De atch Type Descrption m a S ) R 2 C 2 Units Tea Method Date/Time Tacdnidan Dr ARSI-B09-02160 LCSD CO-60 24897.000 501.530 25160.000 497.650 pCijg EPA 901.1 6/11/09 17:42 JLA 0.74 <3 ARS1-B09-02160 LCSO CS-137 15371.000 367.090 14664.000 326.430 pCi/g EPA 901.1 6/11/09 17:42 JLA 2.88 <3 ARS1-809-02160 LCSD AM-241 34699.000 1259.900 34685.000 12710.000 pCv0 EPA 901.1 6/11/09 17:42 JLA 0.00 <3 Project Manager Review U U Notes: American Radiation Services, Inc. assumes no liability for the use or interpretation of any analytical results prcvided other than the cost of the anailysi itself. Reproduction of this report in less than full requires the written consent of the LELAP Certificate* 01949 NELAP Certificate # E87558

2609 North River "oad, Port Allen, Louisiana 70767 1 (800) 401-4277 FAX (225) 381-2996 owSERVICES, INC.

QC Results Report Sample Delivery Group:

ARSI-09-01568 Date Received: 05/21/09 Laboratory Control Sample Evaluation _

Analysis Qc Annlrto Analysls cSu 1 (1.)

Batch Type n Results a I MDC Expected Value Report ulits Analysis Taat Method Anaulyals Dat/Tiame Analysis Technidan percent Recovary (%)

Acc ACCeptanoa ARS1-B09-02125 LCS Sr-g0 19.73 1 1.5 1 0.465 20.64 pCi/L ARS-032/EPA 905.0 6/16/09 16:33 BJS 96 75%-125%

Blank Evaluation Analysis QC Ann"yt1 Analysis CSU 1 (1 a) MDC Expected IRepeor RI Analysis Analysis Analysis Batch Type Re______Vnu a Units Teat Method Date/Time Te'ucldan ARS1-609-02125 J4BL Sr-90 0.106 0.14 0.474 NA pCO/L ARS-032/EPA 905.0 6/16/09 16:33 BJS RER Duplicate Evaluation Analys Ba t c h 1 I TQc yp e D AnalysisAnalysis n1

-m r ip t io n R es ult l I C 5U 1l( 1 ) Re s ult2 c s u 2 ( i s) Ibu a A -Ud yt - Ts t .D Analysis e/ i

]Analysis T c n ia R E lR A RER op n c~

e ARS1-B09-02125 LCSD Sr-g0 19.73 1.5 14.30 1.1 pCi/L ARS-032/EPA 905.0 6/16/09 16:33 BJS 2,07 DER Duplicate Evaluation DER AnalysAi Batch QC Type Analysis Description ResultI

) U 61 2 r 1 J -Analysis Uinits Analyniis Teat W4hod I Analysli Data/Tim Analysli Techlnician DaR AcDIncR ARS1-B09-02125 LCSD Sr-90 19.73 1.5 14.3 1.1 pCI/L ARS-032/EPA 905.0 6/16/09 16:33 J 35 1 5.76 3 Project Manager kRe'w Il Notes: American Radiation Services, Inc. assumes no liability for the use or interpretation of any analytical results provided other than the cost of the analysis itself. Reproduction of this report In less than full requires the written consent of the LELAP Certificate# 30658 NELAp Certificate # E87558

2609 North River Road, Port Allen, Louisiana 70767 AR 1 (800) 401-4277 FAX (225) 381-2996 4, INTERNATIONAL QC Results Report Sample Delivery Group: ARS1-09-01568 Date Received: 5/21/2009 Laboratory Control Sample Evaluation T An(lsMlyC CSU I pested Report Analysis Analysis Analysis Perclnt LCS Analysis ReSults Value l Units Test Method Date/Time Technician ReCOvey ()Aceptae Batch Type I_ _ _' I a"_ Meho I I _Range ARS1-809-02126 LCS H3 1360.904 187.652 182,341 1234.408 pCi/L ARS-054/EPA 906.0 6/14/09 1:28 BS 110 75%-125%

Blank Evaluation An &Aaye Analysi cu (8 Expec~ted Ier Andsis Analysis Analdysis Atyh Type IResults0 value Units Tet Method Date/lime Techsclut ARS1-009-02126 MBL H3 -4.944 108.695 184.804 NA pCi/L ARS-054/EPA 906.0 6/14/09 11:44 BS RER Duplicate Evaluation _

I Typ QC I [n An atys is Anatys BItd Typ Analysis I Result 1 csU 1 (1s) Result 2 IyCSU 2 (1 Iass i) unt Units M

Analys ToIst Methodis OIER Analysis Da~te/Time Analysis Teduildent RER Act petineft ARS1-509-02126 I LCS I H3 1360.904 187.652 1235.804 178.721 pC/L ARS-054/EPA 906.0 6/14/09 6:36 BS 034 1 DER Duplicate Evaluation T c ult I MU 1 (18) R esult'2 C 2 Is A[nalysis Anelysis Analysis Analysis DE A ER a tch I2Type DI _ __ Units Te=t Mto teTim TedMdoin ARS[o9-02126 LCS H3 1360.904 187,652 1235.804 178.721 PCVL ARS-054/EPA 906.0 6/14/09 6:36 BS 0.97 < 3 Project Manager Review Notes: American Radiation Services, Inc. assumes no liability for the use or Interpretation of any analytical results provided other than the cost of the analysis itself. Reproduction of this report in less than full requires the written consent of ARS LELAP Certificate# 01949 NELAP Certificate # E87558

RI S 1 (800)401-4277

• Fax (225) 381-2996 2609 North River Road 9 Port Allen, Louisiana 70767 ITERNATIONAL S?

Notes:

Comments:

1.0) Soil and Sludge analysis are reported on a wet basis or an as received basis unless otherwise indicated.

2.0) Data in this report are within the limits of uncertainty specified in the reference method unless otherwise specified.

3.0) Modified analysis procedures are procedures that are modified to meet the certain specifications. An example may be the use of a water method to analyze a solid matrix due to the lack of an officially recognized procedure for the analysis of the solid matrix.

Modified analyses are indicated by the subsequent addition of "m" to the procedure number (i.e. 900.OM).

4.0) Derived Air Concentrations and Effluent Release Concentrations are obtained from 10 CFR 20 Appendix B.

5.0) Total activity is actually total gamma activity and is determined utilizing the prominent gamma emitters from the naturally occurring radioactive decay chains and other prominent radioactive nuclides. Total activity may be lower than the actual total activity due to the extent of secular equilibrium achieved in the various decay chains at the time of analysis. The total activity is not representative of nuclides that emit solely alpha or beta particles.

6.0) Ra-228 is determined via secular equilibrium with its daughter, Actinium 228. (Gamma Spectroscopy only).

7.0) U-238 is determined via secular equilibrium with its daughter, Thorium 234. (Gamma Spectroscopy only).

8.0) All gamma spectroscopy was performed utilizing high purity germanium detectors (HPGe).

9.0) ARS makes every attempt to match sample density to calibrated density; however, in some cases, it is not practical or possible to do so and data results may be affected.

Method

References:

1.0) EPA 600/4-80-032; Prescribed Procedures for the Measurements of Radioactivity in Drinking Water, August 1980.

2.0) Standard Methods for Examination of Water and Waste Water, 1 8th, 1992.

3.0) EPA SW.846; Test Methods for Evaluating Solid Waste, Third Edition, (9/86). (Updated through 1995).

4.0) EPA 60014479-020; Methods for Chemical Analysis of Water and Waste, March 1983.

5.0) HASL 300 6.0) ARS-040; An LCSD is not reported with this process. The criteria for the LCSILCSD analysis for reproducibility have not been established for Low Level Tritium analysis. A prepared standard for Low Level Tritium has not been developed. As a result, the standard we use is based on the dilution of a verified conventional tritium standard. The volume required for Low Level Tritium analysis, in addition to the lack of an available Low Level Tritium standard, Introduce variability into the LCS/LCSD analysis that does not represent the actual sample analysis. The preferred measure for reproducibility'is to run a duplicate analysis of a sample.

Definitions:

1.0) ND Not detected above the detection limit (non-detect).

2.0) MDC (Minimum Detectable Concentration) minimum concentration of the analyte that ARS can detect utilizing the specific analysis 3.0) MBL Method Blank 4.0) DO Duplicate Original 5.0) DUP Method Duplicate 6.0) MS/MSD Matrix Spike/Matrix Spike Duplicate 7.0) S Spike 8.0) RS Reference Spike 9.0) *SC Subcontracted out to another qualified laboratory 10.0) NR Not Referenced 11.0) N/A Not Applicable 12.0) Reported as a calculated value 13.0) - False Positive due to interference from Bi-214 14.0) U Activity is below the MDC 15.0) LCSILCSD Laboratory Control Standard/Laboratory Control Standard Duplicate Notes: ARS International assumes no liability for the use or interpretation of any analytical results provided other than the cost of the analysis itself. Reproduction of this report in less than full requires the written consent of ARS Intemational.

LELAP Cert#30658 NELAP Carl# E87558

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