A04557, Rev 0 to CA04557, 350 Gal 85% Ethanolamine CR Chemical Habitability

Rev 0 to CA04557, 350 Gal 85% Ethanolamine CR Chemical Habitability

ML20210V279
Person / Time
Site:	Calvert Cliffs
Issue date:	09/30/1998
From:	Gryczkowski J, Mihalcik J, Sommerville I BALTIMORE GAS & ELECTRIC CO.
To:
Shared Package
ML20210V122	List: A04319, Rev 0 to CA04319, 8500 Gal 30% Ammonium Hydroxide CR Chemical Habitability A04320, Rev 0 to CA04320, 5,000 Gal 35% Hydrochloric Acid CR Chemical Habitability A04541, Rev 0 to CA04541, 350 Gal 40% Dimethylamine CR Chemical Habitability A04542, Rev 0 to CA04542, 375 Gal 35% Hydrazine CR Chemical Habitability A04545, Rev 0 to CA04545, 700 Lbm Freon-22 CR Chemical Habitability A04552, Rev 0 to CA04552, 1,100 Tons 100% Benzene CR Chemical Habitability A04553, Rev 0 to CA04553, 55 Gal 100% Acetone CR Chemical Habitability A04554, Rev 0 to CA04554, 12,900 Gal 100% Sulfuric Acid CR Chemical Habitability A04555, Rev 0 to CA04555, Hydrogen Gas CR Chemical Habitability A04556, Rev 0 to CA04556, 1,100 Tons 100% Toluene CR Chemical Habitability A04557, Rev 0 to CA04557, 350 Gal 85% Ethanolamine CR Chemical Habitability A04558, Rev 0 to CA04558, 400 Gal 80% 5-Amino-Pentanol CR Chemical Habitability A04561, Rev 0 to CA04561, Nitrogen Gas CR Chemical Habitability A04571, Rev 0 to CA04571, 4 Tons Liquid Carbon Dioxide CR Chemical Habitability A04598, Rev 0 to CA04598, Halon CR Chemical Habitability ML20210V118
References
CA04557, NUDOCS 9908230087
Download: ML20210V279 (63)

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INITIATION (Control Doc Type - DCALC) j Page ./ ofM I

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Unit O UNIT 1 O UNTT2 jkf COMMON Proprietary or Safeguards Calculation O YES gNO Comments: M4 Vender Calc No.: NA REVISION No.: J/g

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Safety Class (Check one): D AQ DNSR KSR

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REVIEW AND APPROVAL:

I Responsible Engmeer: ( [, dd, Date: /p l Independent Reviewer: .Z'WMw's/ gJ/4[M[ ._/gg Date: 9-12 -9#

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CA04557 Rev.0 t

Page 2 k LIST OF EFFECTIVE PAGES Page Latest Page Latest Page Latest Page Latest Page Latest Rev Rev Rev Rev Rev 001 0 002 0 003 0 004 0 005 0 006 0 007 0 008 0 009 0 010 0 011 0 012 0 013 0. 014 0 015 0 016 0 017 0 018 0 019 0 020 0 021 0 022 0 023 0 024 0 025 0 026 0 027 0 028 0 029 0 030 0 031 0 032 0 033 0 034 0 035 0 036 0 037 0 038 0 039 0 040 0 041 0 042 0 043 0 -044 0 045 0 046 0 047 0 048 0 049 0 050 0 051 0 052 0 053 0 054 0 055 0 056 0 057 0 058 0 059 0 060 0 061 0 062 0 063 0 l

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CA04557 Rev.0 Page 3

3. REVIEWER COMMENTS i

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CA04557 Rev.0 Page 4

4. TABLE OF CONTENTS 01.COVERSHEET...................................................................................................................1

02. LI ST O F EFFECTIVE PAG ES.................. ................... .......... ....... .. ................... ................. 2 0 3. REVIEWER COMMENTS ...................................... .... ................. ...... ..... ............................ 3

- 04. TABLE OF CONTENTS .................................................. .... . ....... .. .. .. .... ............. ....... ........ . 4

05. PURPOSE............................................................................................................................5 06.INPUTDATA....................................................................................................................6

07. TECHNI CAL A S S UMPTI O N S ... ... . ........ ..... ... ............ ................ .. ... . . ..... ......... ......... . .... ... 1 1 0 8. REF E REN C E S . . . . . . . . . . . . . . .. . . ... . . . . . . . . . . . . . . . . . . .. . . . . .. . . . . . .. ... ... . . . . . . . . .. . . . . . . . . . . . . . . . . . . .

09. METH OD S OF ANALYS I S.. ..... .......... ...... ........ ..... ... ... .. ... .......... . . .. . .... . . ....... .. .. ...... .. .. . ... . 14 1 0. C AL C U L ATI ON S . . . . . . . . . . . . . . . . . . .. . . . . . . .. .. . . . . . . . . . . .. .. . . .. . .. .. .. . ... . . . . . . . . . .. . . .. . . .. . . . . . . . . .. . .

11. DOCUMENTATION OF COMPUTER CODES..................................... ........................ 20 12.RESULTS..........................................................................................................................21 1 3 . C ON C L U S I ON S . . . . . . . . . . . . . . .. . . . . . . . . . . . . . .. . . . . ... . . . . . . . .. ... . .. .. .. . . .. . . . . . . . . . . . .. . . .. . . . . . . . . . . . .. . ... . .

14. ATTA C HM ENTS . . . . . . . . . . . . . .. . . . . . . . . . . .. . . .. . . .. . . .... . .. . . . . .. . .. .. .. . .. .. . . . . . . . . . . .. . . . . . . . . . . . . . . . .. . . . . . . . . .

ATTACHMENT A: MSDS FOR ETHANOLAMINE................................. ..................... 23 ATTACHMENT B: ARCON96 RUNS FOR AUX DLDG ROOF INLET........................ 39 ATTACHMENT C: ARCON96 RUNS FOR WEST ROAD INLET PLENUM............... 46 ATTACHMENT D: EXCEL SPREADSHEET ETHANOLAMINE - AUX BLDG ROOF INLET........................... 53 ATTACHMENT E: EXCEL SPREADSHEET ETHANOLAMINE - WEST ROAD INLET.................... ............... 5 8 ATTACHMENT F: CROSS SECTION AL AREAS............ ...................... ...................... 62 L AST PAO E O F REPORT............................ ............ .... ...................... ..... . ... ... .. ......... . ....... .. 63

CA04557 Rev.0 Page 5

5. PURPOSE 10CFR50 App.A GDC.19 (Ref.1) requires that a control room be provided, from which actions can be taken to operate the nuclear power plant safely under normal conditions and to maintain it in a safe condition under accident conditions. Release of hazardous chemicals can potentially result in the control room becoming uninhabitable. Thus the NRC requires each utility to assess the habitability of the control room during and after a postulated external release of hazardous chemicals based on the chemical toxicity limit, vaporization rate, and the relevant atmospheric dispersion coefficients (Ref.2). The explosion and flammability hazard of these chemicals must also be addressed (Ref.2).

Currently, CCNPP utilizes morpholine and anunonia as secondary plant system pH control chemical additives. This calculation is performed in support of MCR-93-035-001-00, which addresses the acceptability of bringing Ethanokmine (ETA) as a new replacement / supplement additive for seconcary plant system pH control. ETA will be stored in 350 gal tote bms at the tank farm, warehouse, and north service building (Ref.19). The chemical habitability of the control room after a chemical release involving an 85% ETA solution was detehnined based on in-house dispersion calculations and toxicity determinations for the current control room configuration with the inleakage points at the control room inlet and exhaust dampers and for the modified control room configuration with the inleakage points at the west road inlet plenum (Refs.3-4). Results indicate that an 85% ETA solution can be stored at the tank farm, warehouse, and north service building without constituting a toxicological or fire hazard to the control room following a worst case accident for both the current and modified control room configurations.

The results of the toxicity calculations for an 85% ETA solution are as follows:

Peak Concentration (ppm)

Tank Farm Warehouse NSB CmTent Configuration No Recirculation 0.05 0.02 0.16 With Recirculation 0.05 0.02 0.16 Modified Configuration With Recirculation 0.04 0.02 0.05 Toxicity Limit (IDLH) 1000 1600 1000 Note that under the current and modified configurations, the peak control room concentrations under worst case conditions are much less than the IDLH toxicity limit, the maximum level from which one could escape within 30 minutes without any impairing symptoms or irreversible health effects. ETA will not pose a flammability or explosion hazard in the control room, since  ;

the peak concentration is a small fraction of the lower explosion limit of 5.5%. l l

The current calculation incorporates many assumptions which make these results conservative. I (1) A maximum concentration limit (IDLH).was utilized that could be tolerated for 30 minutes without physical incapacitation of an average human. The regulatory requirements of Ref.2 dictate a maximum concentration limit that could be tolerated for 2 minutes without physical incapacitation of an average human. IDLH denotes Immediately Dangerous to Life and Health and is defined as the maximum level from which one could escape within 30 minutes without any impairing symptoms or irreversible health effects (Ref.5). (2) For the current configuration the maximum control room intake flowrate of 8300 cfm is utilized. This value is twice the normal operating value (Refs.6-8). (3) The control room volume conservatively neglects dead spaces in the control room ceiling and the volume of room A512. (4) The most conservative methodology is utilized: turbulent evaporation.

CA04557 Rev.0 i'

Page 6 -

6. INPUT DATA The following input data is incorporated into this work: ,

(01) Chamical data for an 85% ETA solution:

CAS number . -141-43 Refs.5,9,10 Chemical fonnula ..

H7NO Refs.5,9,10 Toxicity LimitIDLH ( 1 Ref.5 Odorthreshold(ppm) ppm)

3. Ref.19 Volume fraction 0.85 Ref.19 Volume (gal) 350 Ref.19 Specific gravity (gm/cc) 1.016 Refs.5,9,10 Vaporpressure(mm Hg) VP 0.48@20 C Ref.10 Boiling point (Degrees C) TB 170 Refs.5,9,10 Molecular weight (gm/ mole) MB 61.0551 Refs.5,9,10 Lower explosion limit (Vol%) 5.5 Ref.10 (02) Physical properties of air per Refs.13,14:

Molecular weight (gm/ mole) MA 28.97 Characteristic length in air (Angstroms) SIGA 3.711 Molecular energy of attraction / Boltzmann constant (K) E/KA' 78.6 Mass density of air (gm/cc) RHOA 1.204E-03

- Viscosity of Air (gm/cm-sec) MU l.83E-04 Universal Gas Constant (torr-cm3/gmole-K) R 6.24E+04 (03) The updated control roo.n volume of 234157 ff was extracted from Ref.18.

(04) Control room damper inflow for the current configuration is extracted from Refs. 7-8 and is defined as 8300 cfm or twice the maximum flowrate.

(05) Control room inleakage for the modified configuration is extracted from Refs. 3-4 and is defined as 3000 cfm.

(06) The Tank Farm / Warehouse / North Service Building (NSB)-Control Room ARCON96 X/Q

' inputs were derived as follows (Att.B):

(a) Number of meteorological data files: 3 Refs.B2,B10 (b) Meteorological data file names: CC1991. MET Refs.B2,B10 CC1992. MET Refs.B2,B10 CC1993. MET Refs.B2,B10 (c) Height oflower wind instrument (m): 10. Ref.B3 (d) Height of upper wind instrument (m): 60. Ref.B3 (e) Wind speed units type (l=m/s,2= mph,3= knots): 1 Refs.B2,B10 (f) Release type (l= ground,2 vent,3= elevated): 1

,=

j i

l r .CA04557 Rev.0 l Page 7 j

'(g) Release height (m): 0. J (h) Building area (m2 ): 1155. . .

Att.F The cross sectional area calculations ap analyzed in Att.F. The calculation of containment cross sectional area yields 12435.63 ft above the rooftop level of 91'6". The auxiliary 2

building cross sectional area can be calculated to be 1938.93 ft . For a west-to-east wind directiog the total cross-sectional area of the auxiliary building and the two containments is .

i 26810 ft . For an eagt-to-west wind direction, the total cross sectional area of the turbine building is 27167 ft . For a north-to-south and south-to-north wind girection, the total cross

. sectional area of the containment and the pine buildipg is 21016 ft . The cross-sectional

' area of a single containment of 12435.63 ft or 1155 m will conservatively be used. i l

(i) Efiluent vertical velocity (m/s): 0 3

(j) Stack or vent flow (m /s): 0' j i

(k) Stack or vent radius (m): 6.49 r = SQRT(A/n) 2

= SQRT[(350 gal)*(3785.422cc/ gal)/(1.cm)/n*(1.E-4m fc,2))

= 6.49 m 1 (1) Direction to source (deg): 333 Tank Farm Refs.B12,B14 174 Warehouse Refs.B12,B14.

059 NSB Refs.B12,B14

. (m) Source window (deg): 90 Refs.Bl3-B14 l

-(n) Distance from source to receptor (m): 135 Tank Farm Refs.B12,B14 l 300 Warehouse Refs.B12,B14 1 M7 NSB Refs.B12,B14 l (o) Intake height (m): 15.62 i 91.5' + 4.75' - 45' = 51.25' = 15.62 m where 91.5' is the height of the Auxiliary Building roof (Ref.B6),4.75' is the control room  ;

exhaust height (Ref.B13), and 45' is ground level (Ref.B8).  !

(p) Grade elevation difference (m): 0 Ref.B1  !

1 (q) Primary output file name: CHTFCR.OUT Tank Farm CHWHCR.OUT Warehouse CHNSBCR.OUT NSB (r) JFT file name: CHTFCR.JFD Tank Farm CHWHCR.JFD Warehouse CHNSBCR.JFD NSB

- (s) Surface roughness length (m): 0.1 Ref.Bl ,

(t) Minimum wind speed (m/s): 0.5 Ref.B1 l

(u) Sector averaging constant: 4 Ref.B1 l

l b

CA04557 Rev.0 Page8 ,

' (v) Hours in average: 1 2 4 8 12 24 96 168 360 720 I Ref.B1 (w) Minimum number ofhours: . 1 2 4 8 11 22 87 152 324 648 Ref.B1 (x) Horizontal diffusion coefficient (m): 3.02 o y=r/2.15=6.49/2.15=3.12 m (Ref.B1)

(y) Vertical diffusion coefficient (m) 0.

(z) Flag for expanded output: .n Ref.Bl (07) Atmospheric dispersion coefficients from the Tank Farm / Warehouse /NSB to the Control Room:

Tank Farm Warehouse NSB 3

0- 2 hrs 3.33E-04 sec/m' 9.20E-5 sec/m 1.07E-3 sec/m' 3 3 3 2- 8 hrs 2.85E-04 sec/m 7.73E-5 sec/m 8.36E-4 sec/m 3 3 3 8- 24 hrs 1.27E-04 sec/m 3.21E-5 sec/m 3.73E-4 sec/m 3 3 2 24- 96 hrs 8.56E-05 sec/m 2.25E-5 sec/m - 2.51E-4 sec/m 3 3 96-720 hrs 7.23E-05 sec/m' l.88E-5 sec/m 1.81E-4 sec/m (Attachment B, Refs.B1, BIO, B15)

(08) The Tank Farm / Warehouse /NSB-West Road Inlet ARCON96 X/Q inputs were derived as follows (Att.C):

(a) Number of meteorological data files: -3 Refs.B2,B10 (b) Meteorological data file names: CC1991. MET Refs.B2,B10 CC1992. MET Refs.B2,B10 CC1993. MET Refs.B2,B10 (c) Height oflower wind instrument (m): 10. Ref.B3 (d) Height of upper wind instrument (m): 60. Ref.B3 (e) Wind speed units type (1=m/s,2= mph,3= knots): 1 Refs.B2,B10 l (f) Release type (l= ground,2= vent,3= elevated): 1

(g) Release height (m)

0. j 2

(h) Building area (m ): 1155. Att.F  !

The cross sectional area calculations analyzed in Att.F. The calculation of containment  !

cross sectional area yields 12435.63 above the rooftop level of 91'6". The auxiliary  !'

2 building cross sectional area can be calculated to be 1938.93 ft . For a west-to-east wind directiog the total cross-sectional area of the auxiliary building and the two containments is i 26810 ft . For an eagt-to-west wind direction, the total cross sectional area of the turbine l building is 27167 ft . For a north-to-south and south-to-north wind firection, the total cross ,

sectional area of the containment and the tybine buildipg is 21016 ft . The cross-sectional area of a single containment of 12435.63 ft or 1155 m will conservatively be used.

(i) Effluent vertical velocity (m/s): 0 l

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CA0k557 Rev.0'

- Page 9 3

(j) Stack or vent flow (m /s)

/0 i

(k) Stack or vent radius (m): 6.49 r = SQRT(A/x) 2

= SQRT[(350 gal)*(3785.422cc/ gal)/(1.cm)/n*(1.E-4m fc,2))

= 6.49 'm ,

\

(1) Direction to source (deg): 354 Tank Farm Refs.B12,B14 i 162 Warehouse Refs.B12,B14 i 050 NSB Refs.B12,B14 - j I

- (m) Source window (dcg); 90 Refs.B13-B14

- (n) Distance from source to receptor (m): 172 Tank Farm Refs.B12,B14 262 Warehouse Refs.B12,B14 ,

135 NSB Refs.B12,B14 i (o) Intake height (m): 9.14 The Auxiliary Building roof above the control room and above A512 will be sealed tight.

Most control room inleakage can then be assumed to originate at the Auxiliary Building

- inlet plenum on the west road side (ES199702144). Per Ref.Bl1, the inlet plenum is 54'x10' with a bottom elevation of 70'. Thus the intake height is 75'-45'=30'=9.14 m

.(p) Grade elevation' difference (m): 0 Ref.B1 (q) Primary output file name: CHTFWR.OUT Tank Farm CHWHWR.OUT Warehouse  :

CHNSBWR.OUT NSB  ;

_ (r) JFT file name: CHTFWR.JFD Tank Farm CHWHWR.JFD Warehouse CHNSBWR.JFD NSB (

(s) Surface roughness length (m): 0.1 Ref.Bl (t) Minimum wind speed (m/s): 0.5 Ref.Bl l (u) Sector averaging constant: 4 Ref.B1 (v) Hours in average: 1 2 4 8 12 24 96 168 360 720 Ref.B1

. (w) Minimum number of hours: 1 2 4 8 11 22 87 152 324 648 Ref.B1 (x) Horizontal diffusion coefficient (m): 3.02 o y=r/2.15=6.49/2.15=3.02 m (Ref.B1)

(y) Vertical diffusion coefYicient (m) 0.

(z) Flag for expanded output: n Ref.B1

r CA04557 Rev.0 Page 10 (09) Atmospheric dispersidn coefficients from the Tank Farm / Warehouse /NSB to the West Road Inlet:

Tank Farm Warehouse NSB 0- 2 hrs 2.15E-04 sec/m' l.10E-4 sec/m' 3.18E-4 sec/m 3

3 2- 8 hrs 1.85E-04 sec/m 8.73E-5 sec/m 3

2.61E-4 sec/m 3

8- 24 hrs 8.55E-05 sec/m 3

3.22E-5 sec/m 3

1.22E-4 sec/m 3 {

1 3 3 24- 96 hrs 6.20E-05 sec/m 2.25E-5 sec/m 8.32E-5 sec/m'96-720 hrs 4.93E-05 sec/m 3

1.93E-5 sec/m 3

5.94E-5 sec/m 3 l (Attachment C, Refs.B1, BIO, B15) i i

I

(

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i i

. CA04557 Rev.0 Page 11

7. TECHNICAL ASSUMPTIONS The following technical assumptions were utilized in this work:

(01) Per Ref.19, an 85% ETA Solution is stored in a tote bin of 350 gals capacity in the tank farm, warehouse, or north service building.

(02) Per Ref.15 in a postulated accident, it is assumed that the entire container of the toxic substance ruptures.

. (03) An average ambient atmospheric temperature of 30 C and pressure of 760 torr will be used in this calculation. Variation in these parameters shows insignificant impact on the results (Ref.16).TA=30 PA=1 (04) The chemical spill will be assumed to spread in a circular shape with the maximum radius determined by a spilI thickness of I cm per Ref.15.

(05) Based on the characteristics of the chemicals, the following release mechanisms will be assumed: For the ETA solution, the turbulent mass transfer is the worst of three methodologies:

diffusion in still air, laminar mass transfer, and turbulent mass transfer.

(06) For laminar and turbulent mass flow, a wind s peed of one meter /sec is assumed. This is consistent with the wind tunnel methodology and the CCNPP data of Ref.B3. Note that per Ref.17 (p.265), a flow with Reynold's Number less than 5E+05 is laminar.

(07) The vapor pressure of the spilled material will be adjusted to the ambient conditions via the ideal gas law:

VP(@T.) = VP(@T,,)

• T, / T,,

A

~

CA04557 Rev.0.

Page 12

8. REFERENCES (01)" Control Room",10CFR50, Appendix A, General Design Criterion 19.

(02) " Assumptions for Evaluating the Habitability of a Nuclear Power Plant Control Room

. During a Postulated Hazardous Chemical Release", Regulatory Guide 1.78,6/74.

(03) Res mnse to RAli Accident Dose Analysis and Control Room Habitability Analysis for the MHA, FF A, and CEAEE", NRC-98-044.

(04)" Response to RAI: Control Room Habitability Analyses and MSLB Analyses", NRC 018.

(05)" Hazardous Chemicals Data Book", Second Edition, Edited by G. Weiss, Noyes Data Corporation.

(06) "Offsite and Control Room Doses Following a LOCA", Bechtel Calculatiori M-89-33 Rev.3,7/9/91.

(07)" Fan Performance Curve", BGE DWG 12782-35, Rev.0.

(08) " Control Room Temperature During Normal and Emergency Recirculation Modes of Operation", Bechtel Calculation M-91-24,11/9/92.

(09)" SAX's Dangerous Properties ofIndustrial Materials", Ninth Edition, Richard J. Lewis Sr.

(10) MSDS for Ethanolamine, Attachment A.

(11) "The Merck Index", Eleventh Edition,1989.

(12)" CRC Handbook of Physics and Chemistry",66th Edition,1985-1986.

(13) " Handbook of Chemical Property Estimation Methods, Environmental Behavior of Organic Compounds", W.Lyman, W.Rechl, and D.Rosenblatt, McGraw Hill 1982.

(14) " Flow of Fluids through Valves, Fittings, and Pipe", Crane Technical Paper No.410,1988.

(15) " Toxic Vapor Concentrations in the Control Room Following a Postulated Accidental Release", NUREG-0570,6/79.

(16) "CCNPP Control Room Habitability Evaluation Due to a Postulated Spill of Ethanolamine",

Bechtel Calculation M-94-16 Rev.0,11/10/94.

(17) " Heat Transfer", Seventh Edition, J.P.Holman.

(18)"Modeling of the Control Room / Cable Spreading Room HVAC System Using GOTHIC ,

Softwam", CA02725,1/8/97.

l (19)"CCNPP Control Room Habitability Evaluation Due to a Postulated Spill of Ethanolamine",

Bechtel Calculation M-94-16,11/10/94. '

l l

CA04557 Rev.0 Page 13 (BI) " Atmospheric Relative Concentrations in Building Wakes", NUREG/Ck-6331 Rev.1, S/97.

- (B2) CCMAIL from Mark Abrams at PLG to G.E.Gryczkowski,3/5/97.

(B3)" Wind Flows and Dispersion Conditions at Calvert Cliffs", Maria Gavrilas and Melissa

- Wieland, BO&E-EP1,9/85.

(B4)" Atmospheric Dispersion Coefficient Calculations from the MSG and ADV to the Control Room", CA03533,1/17/97.

(BS)" Auxiliary Building and Containment Structures Exterior Elevations East &. West", BGE Drawing 62-047-E, Rev.6

. (B6) " Auxiliary Building Roof Plan", BGE Drawing 62-043-E, Rev.12.

(B7) " Containment Liner Plan, Elevation & Penetrations", BGE Drawing 61-740-E, Rev.19.

(BS) " General East and South Elevations", BGE Drawing 62-006-E, Rev.4.

(B9)" Equipment Location Turbine Building Unit 1 Plan Floor El 12'0"", BGE Drawing 60-207-E Rev.11.

(BIO)"ARCON96: Atmospheric Relative Concentrations in Building Wakes", CA03940, 8/21/97.

(B11) " Heating and Ventilation System, Auxiliary Building, El. 69'0", Sections and Details",

BGE Drawing 60-330-E, Rev.14.

(B 12) " Wind Tunnel Modeling of CCNPP", CA00748 Rev.0,10/25/95 (B13) "ARCON95 X/Q Analysis", Bechtel Calculation M-97-02 Rev.0, 5/8/97.

(B14)"ARCON95 X/Q Analysis", Bechtel Calculation M-97-03 Rev.0,7/1/97.

(B IS) " Analytical Software Installation Test of ARCON96", CA03941, 8/21/97.

CA04557 Rev.0 Page 14

9. METHOD OF ANALYSIS This work utilizes three separate methodologies to calculate mass transfer .from the spill site to the control room.

(1) The first methodology is diffusion in still air for spills in closed areas and for liguids with high boiling points. The method of analysis utilizes the algorithms of Ref.15 to derive the toxic gas concentration inside the control room.

(la) Calculation of the Diffusion Coefficient of an air / toxic gas system for dilute gases at low pressures per Ref.13 by the method of Wilke and Lee:

2 DAB = - B'*TA'#*MR"/(PA*SIGAB

• OMEGA) where 2

DAB = ' Diffusion coefficient (cm /sec)

B'=" 0.00217 - 0.00050 * (1/MA + 1/MB)" .

MA= Molecular weight of air (gm/ mole)

MB= Molecular weight of toxic gas (gm/ mole)

MR= (MA+MB)/(MA*MB) = Molecular weight of binary gas (gm/ mole)

TA = Air temperature (K)

PA = Air pressure (atm)

SIGAB = Characteristic length of molecule A interacting with molecule B (A)

=

(SIGA+SIGB)/2 SIGA = Characteristic length of molecule A (A)

SIGB = . Characteristic length of molecule B (A) = 1.18*VB" VB = Lebas molal volume (cc/mol)

OMEGA = Collision integral The Lebas molal volume VB can be calculated as follows per Ref.13:

VB = 14.8'(C) + 3.7*(H) + 7.4*(O) + 9.1*(O in Methyl Esters or Ethers)

+ 9.9'(O in Ethyl Esters or Ethers) + 11*(O in Higher Esters or Ethers)

' + 12*(O in Acids) + 8.3*(O Joined to S, P, N) + 15.6*(N Double Bonded)

+ 10.5*(N in Primary Amines) + 12*(N in Secondary Amines) + 27'(Br)

+ 24.6*(Cl) + 8.7*(F) + 37*(I) + 25.6*(S) - 6.0*(3-Membered Ring)

- 8.5*(4-Membered Ring) - 11.5*(5-Membered Ring) - 15*(6-Membered Ring)

- 30* Naphthalene - 47.5

• Anthracene + (Molecular weight / density)*(Elescent)

The collision= inted+OMFg 9 OMEGA ACS C/e +can Elebp3 plculatg,g

+ G/e follows per Ref.13:

'A = 1.06036 B= 0.15610 C= 0.19300 D= 0.47635 E= 1.03587 F= 1.52996 G= 1.76474' H=- 3.89411 TS = .TA/(E/KAB)

E/KAB = SQRT(E/KA

• E/KB)

E/KB = ' 1.15*(TB+273.15)

7_

,f

- CA04557 Rev.0 '

Page 15 (Ib) Surface' Area of a Spill Per Ref.15 l The rate of mass transfer of a licjuid into the atmosphere is directly proportional to the surface area of the spill. Ref.15 approxunates the initial shape of the liquid body by a cylinder, with the height equal to the radius of the base.

VO(m') = Q*QF*(0.003785422 m /3 gal) -

R0(m) = (V0/x)"

2 2 y c .' A0(m ) = - x*R0 The liquid spreads c uickly by gravity to a thin pancake on the ground. Its surface area may be estimated by the fol .owing equation:

2 2 A(m ) = x*(R0 +2*t*(g*V0*(SG-RHOA)/(x*SG))")

where SG = Density of the liquid (gm/cc)-

2 g= Gravitational constant = 9.81 m/sec t= Time (sec)

The surface area, however, does not expand indermitely as the above equation indicates. The maximum area of the spill in an uncontmed space is estimated from the initial volume by assuming a spill thickness ofI cm.

2 AF(m ) = V0/0.01 tA(sec) = -Time to maximum area

=

(AF-AO)/SQRT(4*x*g*V0*(SG RHOA)/SG)

The total mass of the liquid can be calculated as follows:

M0 = - Q*QF*SG*3785.422 gm where Q=- Storage cluantity (gal)

QF = Volume fraction ofliquid or weight fraction of solid SG = Specific gravity (gm/cc)

(Ic) Vaporization Rate in Still Air:

When exposed to the atmosphere, liquids with boiling points above the ambient temperature will evaporate by diffusion into the air. The main driving force is the vapor pressure difference, i.e.,

concentration gradient, between the lic vid phase and the air. The rate of a vapor diffusing into still air is computed from the Fickian c.iffusion equation in Ref.15 2

VR(gm/m -sec) = VP

• RHOV

• 10000. / p

• SQRT(DAB /(n't))

where 1

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1 CA04557 Rev.0 Page 16 4

Vapor pressure of the liquid - /

VP(torr) =

p(torr) = Ambient atmospheric pressure (760 torr)

RHOV(gm/cc) = Vapor density of the hquid t(sec)= 2 Time

' DAB (cm /sec) = Diffusion coeflicient The vapor density of the liquid RHOV is derived from Ref.14 as follows:

- RHOV(lbm/cf) = 144*P'(psiay(R*T(R))

RHOV(gm/cc) = 144* 14.696/(1545/MB*T(R))*(.01601846 gm/cc/lbm/cf)

= MB(gm/ mole)

• 14.696*.01601846/(10.7292*T(R))

where T(R) is the temperature in *R at which VP is determined.

(Id) The vapor density outside the control room can be calculated via 2

VD(gm/m') = VR(gm/m -sec)*AF(m2 )*X/Q(sec/m')

The corresponding vapor density outside the control room in ppm is (Ref.13)

PPM = (24500/MB)

• VD(gm/m')

(le) The vapor concentration inside the control room at time t can be calculated via the following: dCcg/dt = A

• Csxt - A

• Ccg for t<tg -Ccan = C ExT * (1. - exp(-A

• t))

for tg<t<t. Cca2 = CsxT * (1. - exp[-A * (t-ta)]} + Ccai

• cxP[-A * (t-ta)]

for t>t. Ccg3 = Ca2

• exP[-A * (t-t.)]

where 3

Cca = Control room concentration in gpt/m or ppm Csx7 = External concentration in gm/m or ppm A= Fca / Vca = Tumover constant in 1/ min at time t Fca = Control room ingress and egress flow rate at time t ,

Vca" Control room volume j t= Time (min) i ta = - ' Time at which recirculation starts (min) t= (mip)

= Time SG(gm/cc)at which

• (1.cm)evaporation of tox[c

/ {VR(gm/m -sec) substance

• (0.0001 m ceaseg/cm ) * (60.sec/ min)

(1f) The spill area,' vaporization rate, and vapor density are time-dependent quantities for diffusion m still air for spills in closed' areas. The peak vapor density occurs at the time to maximum area (tA), which should be used under these conditions.

(2) The second methodology is mass transfer to forced convection for laminar flow per Ref.15.

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7 CA04557 Rev.0 Page 17 VD(pn/m3) = VFL *ADC*AF (1. - exp(-A

• t)) )

PPM = ' (24500/MB)*VD where ADC = Atmospheric dispersion coefficient (sec/m3)

-AF = Final spill area (m2) See 1b.

MB =' Toxic gas molecular weight (gm/ mole) '

VFL = immia=r evaporation rate (gm/m2-sec)

=

HDL* MB

• VP* 10000./(R*(T(C)+273.15)) '

VP = ~ Toxic gas vaporpressure (mmHg).

TA = Ambient air temperature (C)

T(C)= Temperature in C at which VP is determined R= Universal gas constant = 62400 torr-cm3/gmole-K HDL , =

=

Laminar mass transfg*coegent (cm/sec) 0.664*(DAB /L)*Re Sc DAB = Diffusion coefficient (cm2/sec)- See 1a.

L= Characteristic I

=. -(4*V0*l.E6/n)gggth (cm)

V0= Initial volume (m3)-See Ib.

Re= Reynolds number

=- L*VW*RHOA/MU VW = . Wind velocity (cm/sec).

RHOA~ = Mass density of air MU.= Viscosity of air Sc = Schmidt number

=

MU/(DAB *RHOA)

A= Fca / Vcn = Tumover constant in 1/ min Fca = Control room ingress and egress flow rate Vca= _ Control room volume t= Time to maximum concentration = 10000.*SG/ VFL (3) The third methodology is mass transfer to forced convection for turbulent flow per Ref.15.

- VD(gm/m3) = VFT*ADC*AF (1. - exp(-A

• t))

PPM a (24500/MB)*VD where ADC = - Atmospheric dispersion coefficient (sec/m3)

AF = Final spill area (m2) See 1b.

MB-= Toxic gas molecular weight (gm/ mole) .

- VFT = Turbulent evaporation rate (gm/m2-sec)  !

=

. HDT*MB'VP*10000/(R*(T(C)+273.15)) i VP = Toxic gas vapor pressure (mmHg)

TA = Ambient air temperature (C)

T(C).= Temperature in C at which VP is detennined -

R= Universal gas constant = 62400 torr-cm3/gmole-K  ;

~ HDT = Turbulent mass tranger cgcient (cm/sec)

= 0.037'(DAB /L)*Re ,Sc ,

DAB = Diffusion coefficient (cm2/sec) See Ia. j

r.

CA04557 Rev.0 Page 18

~L'= Characteristic 4

= (4*V0*l.E6/n)gggth (cm) .

V0 =

Initial volume (m3)-See Ib.

Re= Reynolds number

=

L*VW'RHOA/MU VW = Wind velocity (cm/sec)

- RHOA = Mass density of air MU-= Viscosity of air Sc = Schmidt number

=

MU/(DAB *RHOA)

A= Fca / Vcn = Turnover constant in 1/ min Fca = Control room ingress and egress flow rate

-Vcx = Control room volume t=' Time to maximum concentration = 10000.*SG/VFT (04) Explosion and Flammability Limits:

Comparison of the maximum concentration of the relevant toxic chemical concentration inside the control room should yield a limiting value with which to compare against the explosi-an and flammability limits.

f

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CA04557 Rev.0 -

Page 19 l i

10. CALCULATIONS 1 1

The chemical concentration inside the control room for a chemical spill of.350 gal of an 85%

ETA solution in the tank farm / warehouse / north service building is calculated via EXCEL i spreadsheets captured in the following attachments using the methodologies of Section 9:

Attachment D: 85% ETA Solution for Current Control Room Configuration Attachment E: 85% ETA Solution for Modified Control Room Configuration l

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CA04557 Rev.0

• Page 20

11. DOCUMENTATION OF COMPUTER CODES /

This work employed the ARCON% computer code, which was verified, benchmarked, and documented in Ref.B10. The installation is documented in Ref.B15. ARCON96 implements a computational model for calculating atmospheric dispersion coefficients (X/Q's) in the vicinity ofbuildings.

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s CA04557 Rev.0

- Page 21 -

12. RESULTS J Curmntl chemie=y, CCNPP utilizes morpholine and ammonia as secondary plant system pH control 1 additives. This calculation is performed in support of MCR-93-035-001-00, which addresses the acceptability of bringin g Ethanolamine (ETA) as a new mplacement/ supplement additive for k_wm.sey I control. ETA will be stored in 350 gal tote bms at the tank farm, warehouse, plant system p and north service building (Ref.19). The chemical habitability of the control mom after a chemical release involving an 85% ETA solution was determined based on

'in-house dispersion calculations and toxicity determinations for the current control room configuration with the inleakage points at the control room inlet and exhaust dampers and for the modified control room configuration with the inleakage points at the west road inlet plenum (Refs.3-4). Results indicate that an 85% ETA solution can be stored at the tank farm. warehouse, and north service building without constituting a toxicological or fire hazard to the control room following a worst case accident for both the current and modified contml mom configurations.

The results of the toxicity calculations for an 85% ETA solution are as follows:

Peak Concentration (ppm)

Tank Fann Warehouse NSB Current Configuration. No Recirculation 0.05 0.02 0.16 With Recirculation 0.05 0.02 0.16 Modified Configuration With Recirculation 0.04 0.02 0.05 Toxicity Limit (IDLH) 1000 1000 1000

CA04557 Rev.0 Page 22 -

13. CONCLUSI6NS Under the current and modified configurations, the peak control room concentrations under worst case conditions are much less than the IDLH toxicity limit, the maximum level from which one  !

could escape within 30 minutes without any im; miring symptoms or irreversible health effects. I ETA will not pose a flammability or explosion iazard in the control room, since the peak  ;

concentration is a small fraction of the lower explosion limit of 5.5%.

The current chemical habitability calculation incorporates many assumptions which make these  !

results conservative.

. (1) A maximum concentration limit (IDLH) was utilized that could be tolerated for 30 minutes without physical incapacitation of an average human. The regulatory requirements of Ref.2 dictate a maximum concentration limit that could be tolerated for 2 minutes without physical incapacitation of an average human. IDLH denotes Immediately Dangerous to Life and Health ,

and is defined as the maximum level from which one could escape within 30 minutes without  !

any impairing symptoms or irreversible health effects (Ref.5).

(2) For the current configuration the maximum control room intake flowrate of 8300 cfm is utilized. This value is twice the normal operating value. (Refs.6-8) 1 (3) The control room volume conservatively neglects dead spaces in the control room ceiling and the volume ofroom A512.

(4) The most conservative methodology is utilized: turbulent evaporation.

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CA04557 Rev.0 Page 23

') 14. ATTACHMENTS ATTACHMENT A MSDS FOR ETHANOLAMINE i

I i

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MONOETHANOLAMINE CA04557 REV 0 ueA P A GE 28 Co.-e e-, Os, d C mee aire es-

s. nat nAr=0s a =As0 Assessui.T Com h8* ^ _ / *"8'*' s. Fineh point tasy CC. 3001 oC. fBee Haard ^ Handboekt

,menessaw.i . SJ Fassunehee thane an Aar.

_j ee e,. ~ e - ,- po.e m .it u

D e n,, e.e, sus A.pq

r. esen-.h.i. A e. .e. erre,.

s - ., eh.n . es, c **8' Av.e.ed eeneses

. e -o.r.h Ro. ad app.e.m

.eees, .. ..e e".e i u s II. NAZAA0 CLA$$tFICAfl0 ell g,g ,e,,.;ees

,,,,g, e use. .eoi per.ie,e A.e.nes , to .e iu Code a ees . ae-. tier.

me ens n e - m eensey tung heemi ene pneumon euntos egennes

.. . pee. re. Co e e --

Prospeth breatng vapps priseemd ItJ hA8 temand Asung ger gut weser e,is,i ,ies.

m in ,.dara r-u - C-e.-v ae.e.

,h,,,,,, s.t t nseen temperseme Dam asi evesame F t C. y.e.d e., _

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.es. u u e wee.,eme ur.ei, t-, em -

Fire 4 A e. , To.ipers. L=== sad *E-s - a De.am e e mo pos-e-.. . . . .a wees Pommon stansa teens, .. 3 cen==se Aomas Toscar. s CALL FOR MEDM AlD y. CNEMICAL REACTIVITY Assmour tenet.. .*

nessemi, LieutD On touD y.1 ReeeevNy Wim Wmw: 9e m Omm Chenmoede .. . 3

@,*'*"8*

r.: nesee ny mem Comnimi answeessa mis . 8 non ,e emneenwiped misewie .w shame - **"nem*

see enon .~.

'yN d*e*,* anes e,an eM Esem piene, or me. 73 stameny Detng Transport m etJ GIPPA Mamed Cassemessem. - . . . 0 F SWALLOWED and vicen a CON $000US. have vicasa pen water FA feeperatsmg Agente for Asies and M "

. aet ce, e pe,wi , Heelm Hader$ (BhmL. . 3 y,3 pas, geel putnem E^ -

E'*dI - I Exposure ,J win et . asaewir rvmooi .- .e esot eerwom f.F tecear Rous lheestant to preausig osta not eveemme ra mescovay oroup s .

e 11 PNTSICAL Afl0 CNEMiCAL P90PERTi[1 sto phymes teses et is C and t east Denomous to seuser Me m fugh concereshone Water ***'*"'"**"'"'*e=='aae* Lead now, ,,,

iu simseier weeht sies PoHution m,,,, ,,,m,.i,es,.,, e,e e,. ,wa,s,me,.en e e  :.e o.ee su i eum osame.,pe== ,, m,0.c . een 114 Poemstig Peant

1. RCSP045E TO Dt3CHAltGE & LAGEL 8. WAftR POLLvi10fl **"

,g, ,

e--- L C.e - ., .suese ,e- .e., e ...C . .,o Depose are sueh $J Cleam 9 F100 som/48 Iw/shanip/LCeeseek 31J CrInsel Preamfra esser 647 pas e 44 syn = 4 45 ten /nie 41 Waterfoot Tessely Date not evesmase 117 Sposes trevely:

4.9 Seetogsmal Osygen Demand le0Dk 1 Die et to C thead)

Fes,8 eers. (moor) 0%. S enya 6ss. 18J Leguld surense fanssem pese perenom 3D cays stJ LJeung Weest betergesasi Tenstem 1 CHEMILAL DE516hAfl0NS 4. 00$1RVASLI CNARACTEAISTICS ,,, gg,g ,,,",",

Et C4 Conosummty Claes ^ _ 4.1 phyeensi Some les ehdypedk Lead feet prenant SJ Pennian HOCheCHefese &S Ceser:Cokirteen 1111 Asse of Bressas seeses of Waper feask SJ eeD/ Ult Doespnseen Not essee 4J Oest: heesy _ essi poeiria l

1.4 DOT W tow 2491 1113 Lesent gemet et V,_

u cAS RegmWy hm telet 300 9tvt a 300 sevg =

e 37 x 10* #2e 1113 femme et Commussen -10.710 Savt

. -8000 eave -249 R 108 #tg L HgALTy llAZApps 9 SNIPPIIsc INF0AMATi0fl

'1 "# ""' "*""'

Et Perosnel Processee Bedpment FuS lace EPuset Segree. eye iseen Insely- 8.1 Greene et Pway: NF. 06% (15% esserk ta"s seest et asemass test)-it s'avt i

SJ tysnpeente regemeng * , ; Vapor sensass eyes and enes Leal sense loch s9sy le = -10 cavs = -.0A R 198 #he

, commercast 99+% 11to penal of T_ . _ 9eas permient maimb prest egnemse tact eksh and Syst 9J $lerage Tempe6 Aneueni jgJs Deggl of FesAss Osa nel eWORAR8e

&S Tremesent of Espeews OsGESTIOpt einste enneng tr pums larys volumes er eerm essi oness 3.3 beset A- . _ seeseememore ggJs g3ussig vekss: Dam am einestse (3 - . . _ per puest est a escess. $YES Ausi e. esser sur a esmet 15 nwi est a e4 veneeny Open 18J7 Reed Waper freeuws 0.01 pee esser. Osuel Gueh och weaur.

Le Thressneld Landt Wesus 3 ppm

&S Short feen Gmheletten Leims Does nel sweeshan M fenesty by bissemos Gross t. LDee = 0.5 le 5 g/kg pe0 EF Leam femmar Das nel einemmes I, 14 Seper fans) DHemnt T Wapare emme sameurone mensen eush that percomiel es one tegn eenceneseems _  : The eness a tenverary.

M LJedd er Seed hvitesd T _ _ Comme emerang et p. ese arW teHisyee twne en shon eseaws. may ones scenemy hume en long egoewe.

Ett Omar Timeshmee Deu neu amansas Ett EIUI Wesum 1.000 plan s.is : -. An i. P.m neem Den na e.sanne 412 Piems Temperatiart Deu aos evesense m

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A L-

CA04557 REV 0 1498 EEB100 N,N'-1,2-ETHANEDIYLBIS(N-(CARBOXYMETHYL) GLYCINE), DIPOTASSIUM SALT p [

TOXICITY DATA wiTH REFERENCE EEC600 CAS:141-43-5 ' HRt 3 orl mus LD50:342 mg/kg DCroDJ 3,249.80 ETHANOLAMINE ipr-mus LD50:50 mg/kg EjMCAS 17.235,82 DOT: UN 2491 ivn-mus LD50;56,200 pg/kg csl.Nx' Nxso2iol mf: C,H,NO mw: 61.10 CONSENSUS REPORTS: Reported in EPA TSCA PROP: Colorless, viscous, hygroscopic liquid with am-Inventory. monia-like odor. Bp: 170.5*, fp: 10.5*, flash p: 200*F (OC), d: 1.012 @ 25*/4*, vap press: 6 mm @ 60*, vap d:

SAFETY PROFILE: Poison by ingestion, intraperitoneal, 2.11. Misc in water and alc; sitly sol in benzene; sol in and intravenous routes. When heated to decomposition chloroform.

It emits very toxic fumes of SO. See also MERCAPTANS.

SYNS: AETHANOLAMIN (GERMAN) 0 2-AMINoAETHANOL (GER.

MAN) O 2 AMINoETANoLO (ITAltAN) O 2 AMINOETHANOL (hiAK)

EEB100 CAS:200194-7 HR: 1 O SAMINOETHE ALCOHOL 0 CoLAMINE D ETANOLAMINA (ITAL-N,N'-1,2-ETHANEDIYLBIS(N-(CARBOXYMETHYL) GLY. IAN) O SETHANOLAMINE D ETHANotAMINE.soludon (dot) O CINE), DIPOTASSIUM SALT UHROtAMINE D GLYCINot O SHYDRoxYETHYLAMINE O 2-HY.

mf: C,,HnN,0 2K mw: 368.46 DRoxYEmYtAMINE O MEA O MoNOAEmANO! AMIN (GERMAN)

O MONoETHANotAMINE O OLAMINE O THloFACo M 50 0 UsAF SYNS: ACETIC ACID,(ETHYLENEDINITRILo) TETRA.DIPoTAss!- EK-1597 UM SALT O DIPOTAss!UM ETHYLENEDIAMINETETRAACETATE D (E-THYLENEDINITRllo) TETRAACETATE DIPoTAss!UM SALT TOXICITY DATA WITH REFERENCE skn rbt 505 mg open MOD UCDs- In3n3 TOXICITY DATA wrTH REFERENCE eye rbt 763 pg SEV AjoPAA 29.1363,46 skn rbt 500 mg MLD FCToD7 20.563,82 cyt hmn:lyms 100 pmol /L BMAoA3 39.422,86 cye.rbt 100 mg FCToD7 20.573.82 sce hmn:lyms 1 mmol/L cVGEDx 2i(6) 29.s7 eye rbt 100 mg/30S RNS MLD rcioD7 20.573.82 ort rat TDLo:500 mg/kg (female 615D post):TER CONSENSUS REPORTS: Reported in EPA TSCA *

od D5() 1 0 mg/kg TxAPA9 42.417.77 I"***0'Y- ipr rat LD50:67 mg/kg EVssAV 2.289.68 SAFETY PROFILE: A skin and eye irritant. When heated scu rat LD50:1500 mg/kg GTPzAB 23(9J.55.79 to decomposition it emits toxic vapors of NQ. ivn rat LD50:225 mg/kg KBMEAL (4),44.68 ims-rat LD50:1750 mg/kg GTPzAD 23(9),55.79 ori mus LD50:700 mg/kg TPKVAL 4,81,62 EEB500 HR: 3 ipr mus LD50:50 mg/kg NT!s" AD277-68G ETHANE HEXAMERCARBIDE skn rbt LD50:1000 mg/kg UCDs~ ul3nz  !

mf: C,Hg,0,(Oli), mw: 1269.56 CONSENSUS REPORTS: Reported in EPA T5CA PROP: Yellowish white powder. Vap d: 44.6, explodes Inventory. '

@ 230*. Insol in water.

OSHA PEL: TWA 3 ppm; STEL 6 ppm CONSENSUS REPORTS: Mercury and its compounds ACGlH TLV: DVA 3 ppm; STEL 6 ppm are on the Commualty Right To Know List. j DFG MAK: 3 ppm (8 mg/m5) j DOT CLASSIFICATION: 8; Label: Corrosive SAFETY PROFILE: A poison. A dangerous explosion {

hazard. Explodes when shocked or heated to 230*C. SAFETY PROFILE: Poison by intraperitoneal route. '

Incompatible with oxidizing materials. When heated to Moderately toxic by ingestion, skin contact, subcuta-decomposition or on contact with acid or acid fumes, neous, intravenous, and intramuscular routes. A corro-below 230*C it emits highly toxic fumes of Hg. See also sive irritant to skin, eyes, and mucous membranes.

MERCURY COMPOUNDS, ORGANIC. Human mutation data reported. Flammable when ex-posed to heat or llame. A powerful base. Reacts violently with acetic acid; acetic anhydride; acrolein; acrylic acid; EEC000 CAS:594-44-5 HR: 3 acrylonitrile; cellulose; chlorosulfonic acid; epichloro.

ETHANESULFONYL CHLORIDE hydrin; hcl; HF; mesityl oxide; HNO,; oleum; H,SO,; S-mf: C,H,CIO,S mw: 128.58 propiolactone; vinyl acetate. To fight fire, use foam, PROP: Oil. D: 1.357, bp: 177.5*. Sitly sol (decomp) In alcohol foam, dry chemical. When heated to decomposi-water and alc; very sol in ether and CH,Cl,. tion it emits toxic fumes of NO,. See also AMINES.

SYNS: ETHYLsULFOCHLoRIDE O TL 77 For occupational chemical analysis use NIOSH: Ami- .

noethanol Compounds 2007; Aminoethanol Com- l TOXICITY DATA WITH REFERENCE pounds II 3509.

ihl mus LCLo:1220 mg/m'/10M NDRC" NDCrc.132.Aug,42 )

l CONSENSUS REPORTS: Reported in EPA TSCA EEC700 CAS:2002-24-6 HR: 1 Inventory. ETHANOLAMINE HYDROCHLORIDE SAFETY PROFILE: Moderately toxic by inhalation. mh C,H,NO ClH mw: 97.56 When heated to decomposition it emits very toxic fumes SYNS: FAMINoETHANOL HYDROCHLORIDE O 2 AMINOETHANOL of Cl and 50,. HYDROCHLORIDE O COtAMINE HYDROCHLORIDE O ETHANOL-

~

FRiN Fisher Scientific TO: Extension PAGES* 2 2 CA04557 REV O

• • • • MATERIAL SAFETY DATA SHEET **** PA6E 24 Ethanolamine l LOO- 1 4 Gu *i 08710

% 4 Is/D

• • • • SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION ****

MSDS Name: Ethanolamine Cr_talog Numbers:

M251 1, M251 9, M251-1, M251-9 Synonyms:

2-Aminoethanol, Monoethanolamine Company Identifieation: Fisher Scientific 1 Reagent Lane Fairlawn, NJ 07910 For information, call: 201-7 % -7100 Emergency Number: 201-796-7100 Fcr CHEMTREC assistance, call: 800-929-9300

• • • • SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****

+____________+____________________________________+_________+___________+

l CAS#  : Chemical Name  % Einecs# :

i 191-93-5lETH. 100 :205-983-3 :

+___.________+ ________________________________+_________+___________+

___'MOLAMINE Hazard Symbols: XI Risk Phrases: 36/37/38 20

• • • • SECTION 3 - HAZARDS IDENTIFICATION ****

EMERGENCY OVERVIEU Appearance: Colorless, viscous, hygroscopic. Flash Point: 85DC.

Terget Organs: Kidneys, central nervous system, liver.

Potential Health Effects Eye:

Causes severe eye irritation.

Causes eye burns.

Skin:

Causes moderate skin irritation.

May be absorbed through the skin in harmful amounts.

Ingestion:

Causes gastrointestinal tract burns.

Inhalation:

Inhalation of high concentrations may cause central nervous system effects characterized by headache, dizziness, unconsciousness and coma. -

Causes respiratory tract irritation.

Chronic:

May cause liver and kidney damage.

• • • • SECTION 9 - FIRST AID MEASURES ****

Eyes:

Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower ' lids.

Get medical aid immediately.

Skin:

Get medical aid.

Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.

Ingestion:

' Do NOT induce vomiting.

• Tr victI- i= cnneriniie and alar + niva P-4 c..n r. . ) . nr ;ik n, .u,

uo nut inauce voetting. -

If victic la conscious and alsrt, give 2-9 cupfulo cf milk er witsr.

Never nive anything by mouth to en unconscious person.

Get medical aid lemediately. CA04557 REV0 Inhaletlon: P A6E 87 Remove from exposure to fresh mir-immediately. If not breathing give artificial respiration. If breathing is difficult, give oxy, gen.

Get medical aid.

Notes to Physician:

Treat symptomatically and supportively.

• • • • SECTION 5 - FIRE FIGHTING MEASURES ****

General Information:

As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full

. protective gear.

Vapors mixed with air can explode when ignited.

Extinguishing Media:

In case of. fire, use water, dry chemical, chemical fone, or alcohol-resistant foam.

- Use water spray to cool fire exposed containers.

Autoignition Temperature: 780 Flash Point: 85gC (185.00gF) 3C (1,936.00RF)

Explosion Limits,1.ower: 5. 5 Upper: 17

• • • • SECTION 6 - ACCIDENTAL RELEASE MEASURES ****

General Information: Use proper personal protective equpiment as indicated in Section 8.

Spills / Leaks:

Absorb spill with inert material, (e.g., dry sand or earth) then place into a chemical wants container. Remove all sources o,f ignition.

• • • • SECTION 7 - HANDLING and STORAGE ****

Handling:

Remove contaminated clothing and wash before reuse.

Use with adequate ventilation.

Ground and bond containers when transferring material.

Do not get in eyes, on skin, or on clothing.

Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Do not pressurire, cut weld, braze, solder drill, flames.

grind,orexposesuchcontainerskoheat,sparksorope,n Keep container tightly closed.

Avoid ingestion and inhalation.

Storage: -

Keep away from heat and flame.

Keep away from sources of ignition.

Store.In a tightly closed container.

Store in a cool, dry, well-ventilated area away from incompatible substant:es.

• • • • SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****

Engineering Controls:

Use adequate general or local exhaust ventilation to keep airborne concentrations below the permiseible exposure 1imits.

+-___________________+_____________posure Ex Limits

1. Chem *.::a1 Name  :

______+___________________+_________________+

____________________;________ACGIH

NIOSH l0SHA - Final Pris

___________: __________________l_________________;

r

p

. m. . . aw. . .u m . , m .o ...... .....

i ETHAN0LAMINE !3 ppa ; 7.5 13 ppm THA; 8 !3. ppm THA; 6 mg/mi

' mg/m3; 6 ppm aq/m3 TWA; 6 ppm l3 TWA l

.l l STEL; 15 mg/m3 :STF1; 15 mg/m3 l l

-  : STEL i STEL  :

+-___________________+___________________#___________________+_________________,

OSHA Vacated PELs: '

ETHAN0LAMINE: CA04557 REVD 3 ppa TuA; 8 mg/m3 THA; 6 ppe STEL; 15 mg/m3 STEL PA6E 28 Personal Protective Equipment

. Eyes:

j Hear appropriate protective ey lasses or chemical  :

safety A's eye and face protect. ton goggles as described regulations by 1910.133.

in 29 CFR l Skin:

Hear appropriate gloves to prevent skin exposure. i Clothing:

Hear appropriate protective clothing to prevent skin exposure.

Respirators:  ;

Follow the OSHA respirator regulations found in 29CFR 1010.134. Always use a NIOSH-approved respirator when i necessary.  ;

• • • • SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****

Physical State: Liquid Appearance: Colorless, viscous, hygroscopic j Odor: Ammoniacal odor.

va 12.1 g IN-V por .98 mm Hg 8 20C por Pressure:

Density: 2.1 Evaporation Rate: )1 (butyl acetate:1)

Viscosity: 24 cP 20 C ,

I Balling Point: 1 l

[ Freering/ Melting Point:

Decomposition Temperature:

1 available.

Solubility: Miscible in water, i

f Specific Gravity / Density: 1.018 8 20C  ;

Molecular Formula: C2H7NO Moleculnr Meight: 61.0551

• • • • SECTION 10 - STABILITY AND REACTIVITY ****

' Chemical Stability:

Stable.

Conditions to Avoid:

Incompatible materials, ignition sources, acids, excess heat, strong i oxidants.

Incompatibilities with Other Materials:

Strong oxidizing agents, acids, and bases. It attacks some forms of plastics, rubber and coatings.

Hazardous Decomposition Products:

Nitrogen oxides, carbon monoxide, carbon dioxide.

Hazardous Polymerization: Has not been reported.

• • • • SECTION 11 - T0XICOLOGICAL INFORMATION ****

RTECS#:

CAS# 191-93-5: KJ5775000 LDSQ/LC50: .

CAS,# 191-43-5: Oral, _ mouse: LD50 : 700 mg/kg; Oral, rabbit: LD50 : 1

., a

^

CAS# 191-93-5: - Drs1, . mouse: LD50 : 700 mg/kg; Oral, rchbit: LD50 : 1 m ge/kg; Orol, rct: LD50 : 1720 mg/kg; Skin, rabbit: LD50  : I gn/kg.

Car c y: -

-Not 1isted by ACGIH, IARC,.NIOSH,_NTP, or OSHA. C A04557 RE

• • • • SECTION 12 - ECOLOGICAL INFORMATION **** P A6E 24

)

Ecotoxicity:

Not'available.

• • • • SECTION 13 - DISPOSAL CONSIDERATIONS ****

Dispose'of in a manner consistent with federal, state, and local regulations.

RCRA D-Series Naximum Concentration of Contaminants: Not listed.

RCRA D-Series Chronic Toxicity Reference Levels: Not listed.

RCRA F-Serles: Not 1isted.

RCRA P-Series: Not listed.

RCRA U-Series: Not listed.

Not listed as a material banned from land disposal according to RCRA.

• • • • SECTION 19 - TRANSPORT INFORMATION ****

US DOT .

Shipping Name: ETHAN0LAMINE Hazard Class: 8 UN Number: UN2991 Packing Group: III IND Shipping Name: ETHAN0LAMINE OR ETHAN0LAMINE SOLUTIONS Hazard Class: 8 UN Number: 2991 Pecking Group; 3 ..

IATA Shipping Name: ETHAN0LAMINE Hazard Class: 8 UN Number: 2991 Packing Group: 3 RID /ADR Shipping Name: ETHAN0LAMINE Dangerous Goods Code: 8(53C)

UN Number: 2491 Canedien TDG Shipping Name: ETHAN0LAMINE Hazard Class: 8 UN Number: UN2991

• • • • SECTION 15 - REGULATORY INFORMATION ****

A. Federal TSCA CAS# 191-93-5 is listed on the TSCA inventory.

Health & Safety Reporting List None of the chemicals are on the Health & Safety Reporting List.

Chemical Test Rules None of the chemicals in this product are under a Chemical Test Rule.

Section 12b None of the chemicals are listed under TSCA Section 12b.

TSCA Significant New Use Rule None of the chemicals in this material have a SNUR under TSCA.

CERCLA / SARA' I Section 302 (RQ)

None of the chemicals in this material have an RQ.

Section 302 (TPQ)

None of the chemicals in this product have a TPQ.

• c a :- m >

F None ef the chemicolo in this product hiva o TPO. CA04557 REV0 Section 313 No chemicalo cre reportable under Section 313. PASE 3o Clean Air Act:

This material does not'contain any hazardous air pollutants.

This material does not contain any Class 1 Ozone depletors.

This material does not contain any Class 2 Ozone depletors.

Clean Unter Act: -

None of the chemicals in this product a/o listed as Hazardous Substances under the CUA.

None of the chemicals in this product are listed as Priority Pollutants under the CUA.

None of the chemicals in this product are listed as Toxic Pollutants under the CUA.

OSHA:

None of the chemicals in this product 'are considered highly hazardous by OSHA.

B. State ETHANDLANINE can be found on the following state right to know lists:

California New Jersey, Florida, Pennsylvania, Minnesota, Massachuselts.

. California No Significant Risk Level:

None of the chemicals in this product are listed.

C. International Canada CAS# 141-43-5 is listed on Canada's DSL/NDSL List.

CAS# 191-93-5 is listed on Canada's' Ingredient Disclosure List.

European Labeling in Accordance with EC Directives Hazard Symbols: XI Risk Phrases:

R 36/37/38 Irritating to eyes, respiratory system and skin.

R 20 Harmful 'by inhalation.

Safety Phrases:

Exposure Limits:

DEL-ARAB Republic of Egypt:TWA 3 ppe (6 mg/m3). OEL-AUSTRALIA:TUA 3 pp a (8 mg/m3);STEL 6 ppa (15 mg/m3). OEL-BELGIUM:TWA 3 ppm (7.5 mg/m3);S TEL 6 ppa (15 mg/m3). OEL-DENMARK:TWA 6 ppa (6 mg/m3). OEL-FINLAND: TWA 3 ppm (7.5 mg/m3);STEL 6 ppa (15 mg/m3). DEL-FRANCE:TWA 3 ppm (8 mg/m  ;

3). OEL-GERMANY: TUA 3 ppm (8 mg/m3). OEL-JAPAN: TUA 3 ppm (7.5 mg/m3)

OEL-THE NETHERLANDS:TUA 3 ppa (8 mg/m3). OEL-THE PHILIPPINES: TIJA 3 ppm (6 mg/m3). DEL-RUSSIA:TWA 3 ppm;STEL 0.5 mg/m3; Skin. OEL-SUITZERLAND:

TWA 3 ppa (7.5 mg/m3);STEL 15 ppm (37.5 mg/m3). DEL-UNITED KINGDOM: TUA {

3 ppe (8 mg/m3);sTEL 6 ppm (15 mg/m3). DEL IN BULGARIA, COLOMBIA, JOR DAN, KOREA check ACGIH TLV. OEL IN NEW ZEALAND, SINGAPORE, VIETNAM che ek ACGI TLV

• • • • SECTION 16 - ADDITIONAL INFORMATION **** .-

Additlona1 Informatlon:

No additional information available.

NSDS Creation Date: June 13, 1995 The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes.

' CA04557 REV O PA8E ll Nde*3/Y

" -J.T. BAKER INC. 222 REO SCHOOL LANE, *HIL LIPSBURG, NJ - ' 08 86 5 M A T E R-1 A L SAF ETY 0A T A 5HEET 24-HOUR EMERGENCY TELEPHONE -- ( 908) 859-2151 CHEMTREC # ( 800) 424-9300 -- NATIONAL RESP 3NSE CENTER # (8003 424-8802

e. 12 M06 MONDETHANDLAMINE PAGE: 1 EFFECTIVE: 01/04/94 ISSUED: 01/15/94 J.T. BAKER INC., 2 22 R ED SCHOOL LANE, PHILLIPSBU1G, NJ 08865 IAAR 011934

......................................................=.....

SECfION I'- 6 % % ....

PRODUCT 'IDENTI:IC ATION a u w a' . da h'a va a,4 s. .'s .4,i sE. .,. 3 gifi

$ W = 4,s,us e . = = .. .. . . .= . z .. .. . . .. = = .. .. .. . . .. .. .. .. .

PRODUCT NAME: MON 0 ETH AN0L AMINE COMMON SYNONYMS: 2-AM IND ETH ANDL; BETA-AMINOETHAMOL; ETHAN0LAMINE; E THYLOL AMINE ; GLYCINOL; OLAMINE CHEMICAL FAMILY: AMINE ALCOHOLS l FORMULA: HOCH2C H2NH2 l FORMULA WT.: 61.08 CAS NO.: 141-43-5 NIOSH/RTECS NO.: KJ57T5000 PRODUCT USE: LABORATORY REAGENT PRGOUCT CODES: 9314  !

..======s....m...s.....z.m=s.....=======.=z==============...=.===.s=s.zzzse PREC$UTIONARY LABELING t a x x 4 : de u s e = = r.= g5 4 4. 'r u = g d,r. 3 dd

' $ ue.=,de r g s V = .2 d= = . ; u ss .s :4 4 = d .= == == ss .. . .s = = =

SAKER S'AF-T-OATA* IYS, TEM l HEALTH -

1 SLI3HT FLAMMABILITY -

2 MODERATE REACTIVITY -

2 MODERATE CONTACT -

3 SEVERE (C OR ROSIVE l LABOkATORY PROTECTIVE EQUIPMENT GOGGLES E SHIELO; LAB COAT E APRON; VENT HOOD;

• ROP ER GLOVE S; C LA SS B EXTINGUISHER i

U.S. PREC AUTION ARY L ABELING l l

DANGER COMSUSTIBLd. C AUSES BURNS. HARMFUL IF SWALLOWEO, I N H A LE 0, OR ABSORBE0 T HROUGH SKIN.

KEEP AWAY FROM HE AT, SPARKS, FLAME. DO NOT GET IN EYES, ON SKIN, ON CLOTHING.

AVOIO BREATHING V APOR. KEEP IN TIGHTLY CLOSED 00NT AINER. US E WITH A DEQU AT.E VENTILATION. WA SH THOROUGHLY AFTER HANDLING. IN C ASE OF FIRE, US E WA TER SPRAY, ALCOHOL FOAM, ORY CHEMIC AL, OR C ARBON DI3XIDE. FLUSH S PILL ARE A WITH WATER SPRAY.

CONTINUED ON PAGE: 2

/

CA04557 REV D J.T.B AKER INC. P A 6E JL-

• 222 RED SCHOOL -LANE, PHILLIPSBURG, NJ 08865 MATER IAL SAFETY 0A TA SHEET 24-HOUR EMERGENCY TELEPHONE -- (908) 859-2151 CHENTREC C ( 800) 424-9300 -- NATIONAL RESP 3NSE C ENTER c (800) 424-8802 6.J12 M06 MON 0ETHAN0LAMINE EFFECTIVE: 01/04/94 PAGE: i I SS UE D: 01/15/9d aos======================================================================s:=3 PREC'AUTIONARY LABELING (CONTINUED) j a -i= = s p4m m a h da,sgh gEgh ip3 sEsah,= =h i? 4 g'e s == == =~n s's h da is E= == Ga ksb Va s se h h*: j j

INTERNATIONAL LABELING HARMFUL BY INHALATION. IRRITATING TO EYES, RESPIRATORY SYSTEM AND SKIN. l AVOIO CONTACT HITH EYES. AFTER CONTACT WITH SKIN, WASH IMMEDIATELY WITH I PLENTY OF WATER. KEEP CONTAINER TIGHTLY CLOSEO.

SAF-T-DATA

• STORAGE COLOR CODE: RED (FLAMMABLEI as====================================== san ======suss========================= i

' SEdTION II - COMPONENTS

= va n z da s 4 4= =,a s u mj9

, 3 = =,s a d= is is ig ss'S 3 g i;s =,g

= = = = = == = = == = = 's = = ='s = = = == = = = = = s a s s = =

COMPONdNT CAS NO. WEIGHT %

MONOETHANOLAMINE OS HA/P EL ACGIH/TLV 141-43-5 93-100 3 PPM 3 PPM a s a = 2 e. i= s a 69 i = s g= 3 dge = = g d =,f g syld= V , = = s 5g ed =4 Mc =. d='ma s s 73 54 d. := h= == == =s s= =s s a n SECTIDN,III - PHY31DAL DATA ,

mass

mus===============,=====an==========s33s=============================

BUILING POINT: 171 C (339 F) VAPOR PRESSURE ( MMHG ) : 02 (AT 760 MM HG) (20 Cl MELTING POINT: 10 C (50 F) VASOR DENSITY ( AIR =1): 21 (AT 760 MM HG)

SPECIFIC GRAVITY: 1 02 EVaP3R ATION RATE: <0.1 (H20=1) {

(BUTYL ACETATE = 1)  !

l SOLUBILITYlH2O): COMPLETE (100%)  % #0LATILES BY VOLUME: 0 l (21 C)

PH: 12.1 ( 25% SOLUTION) 000R THRESHOLO ( P .P . M . ) : N/A PHYSIC AL ST ATE: LIQUID ._

COEFFICIENT WATER /0IL DISTRIBUTION: N/A l APF6ARANCE C ODOR: COLORLE SS LIQUID. AMMONI A 003R.

CONTINUED ON PAGE: 3

CA04557 REV0

~

. PAGEjl3 J.T. BAKER INC. - 222 RED SCHOOL LANE, PHILLIPSBURG, 'NJ '08865 MATER IA L SA FETY DA TA SHEET 24-HOUR EMERGENCY TELEPHONE -- ( 908) 859-2151 CHEMTREC # ( 800) 424-9300 -- NATIONAL RESP 3NSE CENTER # (800) 424-8802 F..s12 N06 MON 0ETHAN0LAMINE PAGE: 3 EFFECTIVE: 01/04/94 I SSUE D: 01/15/94 a da's.sa

'=m dt e . = 4 =aV a si s: : a :L = 2 =a === a da m'a z z. e= =2 Ee k'= = 3 ~ ba d='44 4: We *= = W= in 'de~= = == == =

^ "

" SEATf0M IV -# " FIR $ XND EXELOSION HAZ ARD DATA 0an======================,======,==================================,============.

FLASH POINT (CLOSE0 CUP): 84 C (185 F1 N:PA 704M R ATING: 2-2-0 AUTOIGNITION TEMPERATURE: 779 C (1436 F)

FLAMMABLE LIMITS: UPPER - 17  % LOWER - 55  %

FIRE EXTINQUISHING MEDI A USE WATER S P R AY, ALCOHOL FOAM, ORY CHEMIC AL OR CARBON DIDXIDE.

SPECIAL FIRE-FIGHTING PROCEDURES FIREFIGHTERS SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND SELF-CONTAINED SRE ATHING APP ARATUS WITH FULL FACEPIECE OPER A TED IN POSITIVE PRES SURE MODE. MOVE CONTAINERS FROM FIRE AREA IF IT ;AN BE 00NE WITHOUT RI SK. USE WATER TO KEEP FIRE-EXPOSED CONTAINERS COOL.

UNUSUAL FIRE C EXPLOSION HAZARDS VAPORS MAY FLO4 ALONG SURFACES TO DISTANT I3NITION SOURCES AND FL ASH BACK.

CLOSED CONT AINERS EXPOSED TO HEAT MAY EXPLOJE. CONTACT WITH STRONG OXIDIZERS MAY CAUSE FIRE. ..

T0XIC GASES PRODUCED AHMONIA, OXIDES OF NITROGEN, CARBON MONOXIDE, CARBON DIOXIDE E XP LOSI ON DATA-SENSITIVITY TO MECHANICAL IMPACT NONE IDENTIFIE0.

EXPLOSION DATA-SENSITIVITY TO STATIC OISCHARGE N3NE IDENTIFIED.

a us s u m a sa ,4 = . a i&12 5: 2_x.em:2=swazue 2r ~4. 32 == L is == sa uss= Winske'=e sa da s ~da mm e

' S*EUTYOh" Y ~ HE'ALYH' HilARD D AT A ass =============iz==============================sss===========s='==============

THRESH 0LO LIMIT VALUE (TLV/TWA): 7 5 MG/M ( 3 P PM ) ,

SHORT-TERM EXPOSURE LIMIT (STEL): 15 MG/M (6 PPMI PERMISSIBLE EXPOSURE LIMIT (PEL): 8 MG/M (3 PPM)

T0XICITY OF COMPONENTS ORAL RAT LOSO FOR MONDETHAN0LAMINE 2100 MG/KG CONTINUED ON PAGE: 4

CA04557 REV 0 J.T.8AKER INC. 222 RED SCHOOL LANE, DHILLIPSBURG,t NJ 08865 PABE)Y M A T E R-I A L SAFETY OA TA S H.E E T 24-HOUR EMERGENCY TELEPHONE -- ( 90 8) 859-2151 CHEMTREC # ( 800) 424-9300 -- NATIONAL RESP 3NSE C ENTER # -(800 5 424-8802 a J12 N06 MONDETHAN0LAMINE j PAGE: 4 EFFECTIVE: 01/04/94 I SSUE D: 01/15/94 0a=============================s==========='s==================================

' SECTION V ~ HEALTH HAZARD OATA (CONTINUEDI  !

m ags f zjiu = = = =,sha,=M as sc = gs;W page= == E{ scia Ea sgFy s,a d= E= Wr, Wa W4,EsE= Ec W= We ns,Ws's= &s i SKIN RAT LD50 FOR MONDETHANOLAMINE 1500 MG/KG INTRAPERITONEAL RAT LD50 FOR MON 0ETHAN0LAMINE 981 MG/KG INTRAVENOUS RAT LD50 FOR MONDETHANDLAMINE 800 MG/KG l CARCINOGENICITY: NTP: NO IARC: NO Z LIST: NO OSHA REG: NO l l

CARCINOGENICITY NONE IDENTIFIED.

REPRODUCTIVE EFF ECTS NONE IDENTIFIE0.

EFFECTS OF OVEREXPOSURE INHALATION: SEVERE IRRITATION OF RESPIRATORY SYSTEM SKIN CONTACT: SEVERE IRRITATION OR BURNS j EYE CONTACT: SEVERE IRRITATION OR BURNS SKIN ABSORPTION: MAY BE HARMFUL INGESTION: NAUSEA, VOMITING, G A STR0 INT E S T IN AL IRRITATION, BURNS TO MOUTH AND THROAT, CENTRAL VERVOUS SYSTEM DEPRESSION CHRONIC EFFECTS: KIDNEY DAMAGE, LIVEk DAMAGE TARGET ORGANS EYES, SKIN, RESPIRATORY SYSTEM, CENTR AL NERVOUS SYSTEM, LIVER, KIDNEYS MEDIC AL CONDITIONS GENER ALLY AGGRAVATED BY EXPOSURE DAMAGED SKIN, ASTHMA, PULMONARY DISEASE PRIMARY ROUTES OF dNTRY INHALATION, IN3ESTION, EYE CONTACT, SKIN C04T ACT, ABSORPTION , ,,

EMERGENCY AND FIRST AID PROCEDURES INGESTION: CALL A PHYSICIAN. IF SWALLOWED, 00 NOT INDUCE VOMITING. IF CONSCIOUS, GIVE WATER, MILK, 3R MILK OF MAGNESI A.

INHALATION: IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BtE ATHING IS DIFFICULT, GIVE OXYGEN.

CONTINUED ON PAGE: 5 l

l

CA04557 REV0 J.T. BAKER INC. 222 RED SCHOOL LANE, *HIL LI PS BURG,PAGE J[

~ NJ 08865 MATER IAL SAFETY DATA SHEET 24-HOUR EMERGENCY TELEPHONE -- ( 908) 859-2151 CHEMTREC 0 (800) 424-9300 -- NATIONAL RESP 3NSE CENTER # (800) 424-8802 6..s12 M06 EFFECTIVE: MONDETHANDLAMJNE PAGE: 5 01/04/94 I SSUE D: 0 1/15/94 a o '6 = c iu im mu s2 *3 =i

" ' ' =4: 4 = = = == ==: im'i Enim e=9sE=Eu i' nn e s's Es E =m4a ss~wa n= Em ""

is dae= ' ==

' W= =

"S$CTIdN*V" 'HEA[TA NA1 ado'DITX ( CONT'INUEO) n o s = = = = = = = = = = = = = ='= =, a = = = = = = = = = = = = = = = = = = = = = = = = 3 s m e = = s i n ks ie = = = = = = == = = = = 4: = = = = = = =

SKIN CONTACT: IN CASE OF CONTACT, IMMEDIATELY FLUSH SKIN WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES WHILE REMOVING CONT AMIN ATED i CLOTHING AND SHOES. WASH CLOTHING BEFORE RE-USE. I EYE CONTACT: IN CASE OF EYE CONTACT, IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES.

SARA / TITLE III HAZARD CATEGORIES AND LISTS l ACUTE: YES CHRONIC: YES FLAMMABILITY: YES PRESSJRE: NO REACTIVITY: NO l EXTREMELY HAZARDOUS SUBSTANCE: NO CERCLA HAZARDOUS SUBSTANCE: NO SARA 313 T0XIC CHEMICALS: NO TSCA INVENTORY: YES l

~

l

= U s = s = z = = t a = = s = = m 's' s = s = z = = = = = s - ~ ~ - s s = = = = s s = s s ='a s : s z e = = z z a z a s = m a = m m s a s s s s s s = = s s l SECTION VI'- RE ACTIVITY DAT A V

. a g :5 ss = 5= =y p igi ge g= = gd= n.3 - ?$4. = qin ig E= Ex ={= s i= ~4r ia lid s = = == = = == = = == = = == =

STABILITY: STABLE HAZ ARDOUS P3LYMERIZ ATION: WILL NOT OCCUR CONDITIONS TO AVOI3: HEAT, FLAME, OTHER SOUR;ES OF IGNITION INCOMPATIBLES: STRONG ACIDS, STRONG OXI3IZING AGENTS DECOMPOSITION PRODUCT S: AMMONI A, OXIDES OF NITR3 GEN , CARBON MONOX IDE, CARBON DIOXIDE

=o===============3==============3s=============23i=========================:  !

SECTION VII' 2 SPILE i DISPOSAL PRO ao$sgi,is===mi 7 ,

g ig'da,e s,i gi$ ig = = = = = = = = = = = = = = = = === === = === ===== === == ==C

= = =ED

~

= = =UR

= = =E

=S=

STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE .

WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING. SHU1 0FF IGNITION SOURCES; NO FLARES, SMOKING OR FL AME S IN ARE A. STOP L EAK IF YOU CAN 00 S0 WITHOUT RISK. USE WATER SPRA( TO REQUC E VA PORS. TAKE UP WITH SAND OR OTHER NON-COMBUSTIBLE ABSORBENT M ATERI AL AND PLACE INTO CONTAINER FOR LATER DISPOSAL. FLUSH AREA WITH WATER.

DISPOSAL PROCEDURE DISPOSE IN ACCORDANCE WITH ALL APPLIC ABLE FEDER AL, STATE, AND LOC AL ENVIRONMENTAL REGULATIONS.

CONTINUED ON PAGE: 6

CA04557 REV0 P ASE jf, J.T.B AKER INC . 222 RED SCHOOL LANE, PHILLIPSBURG, NJ 08865 '

MATER IAL 5AFETY OA TA SHEET 24-HOUR EMERGENCY TELEPHONE -- ( 90 8) 859-2151 CHEMTREC 0 (800) 424-9300 -- NATIONAL RESP 3NSE C ENTER # (800) 424-8802 J12 M06 / MON 0ETHAN0LAMINE PAGE: (

E FF ECTI VE: 01/04/94 I SS UE D: 01/15/98 an=============================ds================:===============m3s========:

SECTION VII - $PI'LL & OISPOSAL PR3CEDURES (CONTINUED) 4 d = d= =k de =gs =Wgeh'a$E m a m = Vs'e=Hgna== G=W{=~[iz En= E'sk G "== 96 2= w= ire == W= Gs E= si== E=i EPA HAZARDOUS WASTE NUMBER: D002 (CORROSI(E WASTE) as==============='====================

amass ==ss===============================:

sECTION VIII ~ "IRDOS'fRf AL PROT s s = 4 4=,sa E = Saigizyjda,WgE  : = = = = = = = == = == = = = == == =E C T I V E EQ UI PM E 5 ====m==========================:

VENTILATION: USE GENERAL OR LOCAL EXiAUST VENTILATION TO MEET TLV REQUIREMENTS.

RESPIRATORY PROTECTION: RESPIRATORY PROTECTION REQUIRED IF AIRBORNE CONCENTRATION EXCEEDS T.V. AT CONC'ENTRATIONS UP TO 150 PPM, A CHEMIC AL C ARTRIDGE RESPIRATOR WI TH AMMONIA / AMINE CARTRIDGE IS RECOMMENDED. ABOVE THIS LEVEL, A SELF-CONTAINED BRE ATHING APP AR ATUS IS ADVISED.

EYE / SKIN PROTECT ION: SAFETY GOGGLES AND FACE SHIELD, UNIFORM, PROTECTIVE SUIT, RUBBER GLOVES ARE RECOMMENDED.

========s's============== ========d:=============================

SECTION IX - STORAGE AND HANDLING PRECAUTIONS

= = = = = = = = = = = = = = = = = = =, = = = = = = = = = = = = = = = = = = = = d 'e = w- E, Fa is i si* a 7= d, 3 c a = = = = J e = =l= = 4 : 2 = ,

SAF-T-DATA

• STORAGE COLOR CODE: RED (FLAMMABLE)

STORAGE REQUIREMENTS KEEP CONTAINER TIGHTLY CLOSED. STORE IN A 030L, DRY, WEL L- VE NT IL AT ED ,

FLAMMABLE LIQUID STORAGE AREA OR C ABINET.

SPECI AL PRECAUTIONS PRODUCT MAY SOLIDIFY AT ROOM TEMPERATURE.

sas u mini a==

s==_ss'p=

SEC TION g'd

. X -as z a n = E'=i:Tais s=,Wp TNANS'P'ONTATYON 6A =I A ,42 Ga is ie r's e, =e du ks i= Ez' as 's, .es =

AND'AD')ITI ON AL I'NFORMATI ON

=================,==,se====,s===================================='s=============mi DOMESTIC (D.O.T.)

PROPER SHIPPING NAME: MON 0ETHAN0LAMINE HAZARD CLASS: 8 UN/NA: UN2491 P ACKAGING GROUP : II I LABELS: CORROSIVE CONTINUED ON PAGE: 7

_~

CA04557 REV0

. . P A6E jf7

~

J.T.B AKER INC. 222 RED SCHOOL LANE, PHILLIPSBURG, NJ 08865

, MATER IAL SAFETY DA TA SHEET 24-HOUR EMERGENCY TELEPHONE -- ( 90 89 859-2151 4 CHEMTREC # (8003 424-9300 -- NATIONAL RESP 3NSE C ENTER # (800) 424-8802 J12 M06 ) MON 0ETHAN0LAMINE PAGE: 7 EFF ECTI VE : 01/04/94 I SS UE D: 01/15/94 a s a s s = = = = = = = = = = = = as s s = = = = = = = = = = = = = = = = = = = = = = = = = m s : s m s s s s s s s s = = = = = = = = = = = =

SECTION X - TRANsPORYATION ' OATA AND ADDITIO1 AL INFORMATION (CONTINUEDI e a n == = = = = s a = sfs'g,%

3 sif=*a,.s?.;k's,akif aJa i ' sWs i'ps b Wa = = si Es, ills 949s as W=is=.~d: is'ds'da L E=k REGULATORY

REFERENCES:

49CFR IT2.101 INT ERNATION AL- ( I .M.D. )

PROPER SHIPPING NAME: ETHAN0LAMINE HAZARD CLASS: 8 I.M.D. PAGE: 81 69 UN: UN2491 MARINE PDLLUTANTS: NO P ACKAGING GROUP: III LABELS: CORROSIVE REGUL ATORY

REFERENCES:

49CFR PART 176; IMDG CODE AIR (I.C.A.O.)

PROPER SHIPPING NAME: ETHAN0LAMINE HAZARD CLASS: 8 UN: UN2491 P ACKAGING GROUP: III LABELS: CORROSIVE-REGULATORY

REFERENCES:

49CFR PART 175; ICAcess 4E BELIEVE THE TRANSPORT ATION D ATA AND REFERENCES CONT AINED HEREIN TO BE F ACTU AL AND THE OPINION OF QUALIFIED EXPERTS. THE DATA IS ME ANT AS A GUIDE TO THE OVERALL CL ASSIFIC ATION OF THE PRODUCT AND IS NOT PACKAGE SIZE SPECIFIC, NOR SHOULO IT BE TAKEN AS A WARRANTY OR REPRESENTATION FOR WHICH THE COMPANY ASSUMES LEGAL RESPON SIBILITY.s == T HE INFORMATION IS OFFERED S3LELY FOR YOUR CONSIDERATION, INVESTIGATION, AND VERIFIC ATION. ANY USE OF THE INFORMATION MUST BE DETERMINED BY THE USER TO BE IN ACCORD ANCE WITH AP PLIC ABLE FEDER AL, ST ATE, AND LOC AL LAWS AND REGULATIONS. SEE SHIPPER REQUIREMENTS 49CFR 171.2, CERTIFICATION 172.204, AND EMPLOY EE TRAINING 45 CFR 173 1(S).

U.S. CUSTOMS H ARMONIZ ATI ON NUMBER: 29221100008

~

o s a s s = = = s z a s a s s m a 'ss,m s s, s s a s a s = = = = = = = = = = = = = = = = = = = = = s'= s: : = = = = =s 'a m a s s s s s s s NOTE: WHEN HANDLING LIQUID PRODUCTS, SECONDARY PROTECTIVE CONT AINERS MUST BE USED FOR C ARRYING.

-N/A = NOT APPLICABLE, OR NOT AVAILABLE; N/E .5 NOT ESTABLISHED.-

THE INFORMATION IN THIS MATERI AL SAFETY DAT A SHEET MEETS THE J

RE'UIREMENTS OF THE UNITED STATES OCCUP ATIONAL SAFETY AND HEALTH ACT AND REGUL ATIONS PROMULGATED THEREUNDER (29 CFR 1910.1200 ET. SEQ. ) AN D TH E C ANADI AN WORKPLACE HAZARDOUS MATERI ALS INFORMATION SYSTEM. THIS DOCUMENT

• • INTENDED ONLY AS A GUIDE TO THE APPROPRI ATE PREC AUTIONARY HANDLING OF CONTINUED ON PAGE: 8 l

l

CA04557 REY 0

.\

P ASE J#

~

J.T. BAKER INC. 222 RED SCHOOL LANE, S HI L LI PS BURG, NJ 08865

.. MATER IAL SA FETY DATA SHEET 24-HOUR EMERGENCY TELEPHONE -- ( 908) 859-2151

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. J12 MO6 MONDETHAN0LAMINE PAGE: 8 EFFECTIVE: 01/04/94 ISSUED: 01/15/94 aar,muisiza aciqi g g ymasussad=iai3Ra

_ n=}gi= du ng is Es is n'a s= sg ?= &='su in ka ka wa ka su se zz i THE MATERI AL BY A PERSON TRAINED IN, OR SUPERVISED BY A PERSON TRAINED IN, CHEMIC AL HANDLING.

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" ISSUED BY VWR O2/19/94" I

1 l

1 CA04557 Rev.0 Page 39 ATTACHMENT B ARCON% RUNS FOR AUX BLDG ROOF INLET 4 l

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a .

Program Tit 19: ARCON96.

Developed Fors U.S. Nuclear Regulatory Commission CA04557 REV0 Office of Nuclear Reactor Regulation Division of Reactor Program Management PASE f'C' Data: June 25, 1997 11:00 a.m.

NRC Contacts: J. Y. Lee Phones (301) 415 1080 e-maili jyllenc. gov J. J. Hayes Phones (301) 415 3167 e-mails $jhanrc. gov L. A Brown Phones (301) 415 1232 e-mails lab 2enrc. gov Code Developer J. V. Ramsdell Phones (509) 372 6316 e-mail j,,ramsdellepnl. gov Code Documentation: NUREG/CR-6331 Rev. 1 The program was prepared for an agency of the United States Government. Neither the United States Government nor any agency thereof, nor any of their employees, makes any warranty, expressed or implied, or assumes any legal licbility or responsibilities for any third party's use, or the results of such u2 cf any portion of this program or represents that its use by such third party would not infringe privately owned rights.

Program Run 8/24/1998 at 07:22:41 eeees** ARCON INPUT * * *** m Number of Meteorological Data Files = 3 Meteorological Data File Names CC1991. MET CC1992. MET CC1993. MET H;1ght of lower wind instrument (m) = 10.0 H ight of upper wind instrument (m) = 60.0 tind speeds entered as meters /second Ground-level release R lease height (m) = .0 l Building Area (m"2)

• 1155.0 l Effluent vertical velocity (m/s) = .00 i V;nt or stack flow (m'3/s) = .00 V;nt or atack radius (m) = 6.49 Direction , intake to source (deg) = 333 Wind direction sector width (degl = 90 Cind direction window (deg) = 288 - 018 Distance to intake (m) = 135.0 Intake height (m) = 15.6 Terrain elevation difference (m) = .0 Output file names CHTFCR.out CHTrCR.j f d Minimum Wind Speed (m/s) = .5 Surface roughness length (m) = .10 Sector averaging constant = 4.0 Initial value of sigma y = 3.02 Initial value of sigma : = .00 Expanded output for code testing not selected Total number of hours of data processed = 26307 Hours of missing data = 416 Rours direction in window = 7167 Hours elevated plume w/ dir. in window = 0 Hours of calm winds = 495 Hours direction not in window or calm = 18229 DISTRIBUTION SUf94ARY DATA (<Y AVERAGING INTERVAL AVER. PER, 1 2 4 8 12 24 96 168 360 720 UPPER LIM. 1.00E-03 1.00E-03 1.00E-03 1.00E-03 1.00E-03 1.00E-03 1.00E-03 1.00E-03 1.00E-03 1.00E-03 LOW LIM. 1.00E-07 1.00E-07 1.00E-07 1.00E-07 1.00E-07 1.00E-07 1.00E-07 1.00E-07 1.00E-07 1.00E-07 m

L- ABOVE RANGE 0 O, O. O. O. D. O. O. D. O.

15 RANGE 7562. 9147. 11079. 13554. 15606. 19559, 25004. 25103. 25169. 24910.

EELON RANGE- D. O. O. - 0. O. O. O. O. O. D.

. 7.ERO ' 18229. 16678. 14628. 11932. 10062. 6025. 201. 1. O. O.

.'IUTAL X/Qs - 25891. 25825. 25707. 25446. 25668. 25584. 25205, 25104. 25169. 24910.

% NON EERO .29.59 35.42 43.10 53.18 ' 60.00 - 76.45- 99.20 100.00 100.00 100.00 95th PERCENTILE X/Q VALOBS - .

3.338-04 3.29E-04 '3.19E-04 2.97E-04 2.45E 1.83E-04 1.10E 04 9.84E-05 8.56E-05 7.73E-05 /

4 95% X/Q for standard averaging intervals O to 2 hours2.314815e-5 days <br />5.555556e-4 hours <br />3.306878e-6 weeks <br />7.61e-7 months <br /> 3.33E-04 CA04557 REV0 2 to 8 hours9.259259e-5 days <br />0.00222 hours <br />1.322751e-5 weeks <br />3.044e-6 months <br /> .2.85E-04 8 to 24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br /> - 1.275-04 A6E W 1 to 4 days 8.565-05'

= 4 to 30 days 7.23E-05 HOURLY VALUE RANGE MAN K/Q MIN K/Q

' CENTERLINE. 4.60E 04 4.24E-05 SECTOR-AVERAGE 2.88E-04 2.66E 05 NOTJ4AL PROGRAM COMPLETION

i e . .

Program Tit 10i ARCON96.

Developed For U.S. Nuclear Regulatory Commission Office of Nuclear Reactor Regulation Division of Reactor Program Management EV0 Datas June 25, 1997 11

00 a.m. P A S E d/ll-=

}

NRC Contacts: J. Y. Lee Phones (301) 415 1080 e-nails jyllenrc. gov J. J. Hayes Phones (301) 415 3167 e-maili jjhenrc. gov L. A Brown Phones (301) 415 1232 e-mails lab 2enre. gov Code Developers J. V. Ramsdell Phone (509) 372 6316 e-maili j ,ramsdellepnl. gov Code Documentations NUREG/CR-6331 Rev. 1 The program was prepared for an agency of the United States Government. Neither the United States Government nor any agency thereof, nor any of their empiryees, makes any warranty, expressed or implied, or assumes any legal ltrbility or responsibilities for any third party's use, or the results of such u;a, of any portion of this program or represents that its use by such third party would not infringe privately owned rights.

Progrim Run 8/24/1998 at 07:27:43 e*o*e** ARCON INPUT **********

Number of Meteorological Data Files = 3 Meteorological Data File Names CC1991. MET CC1992. MET CC1993. MET Height of lower wind instrument (m) = 10.0 Height of upper wind instrument (m) = 60.0 Cind speeds entered as meters /second Cround-level release R21 ease height (m) = .0 Building Area (m'2) = 1155.0 Effluent vertical velocity (m/s) = .00 V;nt or stack flow (m'3/s) = .00 V;nt or stack radius (m) = 6.49 Direction intake to source (deg) = 059 Cind direction sector width (deg) = 90 Cind direction window (deg) = 014 - 104 Distance to intake (m) = 67.0 Intake height (m) = 15.6 Tctrain elevation difference (m) = .0 Output file names CHNSBCR.out CHNSBCR. j f d Minimum Nind Speed (m/s) = .5 Surface roughness length (m) = .10 Sector averaging constant = 4.0 Initial value of sigma y = 3.02 Initial value of sigma : = .00 Expanded output for code testing not selected Total number of hours of data processed = 26307 Hours of missing data = 416 Hours direction in window = 5333 Hours elevated plume w/ dir, in window = 0 Kours of calm winds = 495 Hours direction not in window or calm = 20063 DISTRIBUTION

SUMMARY

DATA BY AVERAGING INTERVAL AVER. PER. 1 2 4 8 12 24 96 108 360 720 UPPER LIM. 1.00E-02 1.00E-02 1.00E-02 1.00E-02 1.00E-02 1.00E-02 1.00E-02 1.00E-02 1.00E-02 1.00E-02 LOW LIM. 1.00E-06 1.00E-06 1.00E-06 1.00E-06 1.00E-06 1.00E-06 1.00E-06 1.00E-06 1.00E-06 1.00E-06

ABOVE RANGE 0. . 0 . .. .O. D. D. D. ~ 0. O. O. O.

23 RAugE. 5828. 7130, 8854. 11232. .13252, 17178. 24362. 24911. 25169. 24910.

RE!AN RANGE 0. O. D. O. .O. O. O. O. O. C.

EERO '20063. 18695. '16853 14254. 12416. 8406. 843. '193. O. O.

W rAL X/Qs 25891, 25825. 25707. 25486 25668. 25584. 25205. 25104. 25169. 24910.

t as0N EERO 22.51 27.61 34.44 44.07 51.63 67.14 96 66 99.23 100.00 100.00 95th PERCENTILE X/Q VALUES.

1.075 03 1.045 03- 9,82E-04 8.95E-04 7.39E-04 / 5.47E-04 3.255-04 2.77E-04 2.26E-04 2.00E-04 '

956 X/Q'for standard averaging intervals 0 to 2 hours2.314815e-5 days <br />5.555556e-4 hours <br />3.306878e-6 weeks <br />7.61e-7 months <br /> 1.075 CA04557 REV0 3 to 8 hours9.259259e-5 days <br />0.00222 hours <br />1.322751e-5 weeks <br />3.044e-6 months <br />

'8 to 34 hours3.935185e-4 days <br />0.00944 hours <br />5.621693e-5 weeks <br />1.2937e-5 months <br /> 8.365 04 3.73E-04' f kl( h 1 to 4 days 2.515-04 4 to 30 days 1.815-04 NOURLY VALL4 RANGE MAX X/Q MIN X/Q CENTERLINE 1.4 9E-03 ' 1.392-04' SECTOR-AVERAGE 9.31E-04 8.68E 05 NORMAL PROGRAM COMPLETION J

I 1

• e Program Tit 10: ARCON96.

Developed For U.S. Nuclear Regulatory Commission C A04557 REV 0 Office of Nuclear Reactor Regulation Division of Reactor Program Management p g{ g/h a DatJe June 25, 1997 11:00 a.m.

J NRC Contacts: J Y. Lee Phones (301) 415 1080 e-mail jyllenre. gov J. J, Hayes Phone (301) 415 3167 e-maili jjhenrc. gov L. A Brown Phones (301) 415 1232 e-mails lab 2enre. gov Code Developer J. V. Ranadell Phone (509) 372 6316 e-mail j_ramsdellepnl. gov Code Documentations NUREG/CR-6331 Rev. 1 The program was prepared for an agency of the United States Government. Neither the United States Government nor any agency thereof, nor any of their employees, makes any warranty, expressed or implied, or assumes any legal liability or responsibilities for any third party's use, or the results of such ura, of any portion of this program or represents that its use by such third party would not infringe privately owned rights.

PrDgr:3 Run 8/24/1998 at 07:27:18 eeesese ARCON INPUT **********

Number of Meteorological Data Files = 3 Meteorological Data File Names CC1991. MET CC1992. MET CC1993. MET Height of lower wind instrument (m) = 10.0 H;ight of upper wind instrument (m) = 60.0 Cind speeds entered as meters /second Ground-level release RJ1 ease height (m) = .0 Cuilding Area (m*2) = 1155.0 Effluent vertical velocity (m/s) = .00 V;nt or stack flow (m"3/s) = .00 VInt or stack radius (m) = 6.49 Direction intake to source (deg) a 174 Cind direction sector width (deg) = 90 Cind direction window (deg) = 129 - 219 Dirtance to intake (m) = 300.0 Intake height (m) = 15.6 T;rrain elevation difference (m) = .0 Output file names CHWHCR.out CHWHCR.jfd Minimum Wind Speed (m/s) = .5 Surface roughness length (m) = .10 Sector averaging constant = 4.0 Initial value of sigma y = 3.02 Initial value of sigma a = .00 Expanded output for code testing not selected l Total number of hours of data processed = 26307 Hours of missing data = 416 Hours direction in window = 7071 Hours elevated plume w/ dir. in window a 0 Hours of calm winds = 495 Hours direction not in window or calm = 18325 DISTRIBUTION

SUMMARY

DATA BY AVERAGING INTERVAL AVER. PER. 1 2 4 8 12 24 96 168 360 720 1 UPPER LIM. 1.00E-03 1.00E-03 1.00E-03 1.00E-03 1.00E-04 1.00E-04 1.00E-04 1.00E-04 1.00E-04 1.00E-04 LOW LIM. 1.00E-07 1.00E-07 1.00E-07 1.00E-07 1.00E-08 1.00E-08 1.00E 08 1.00E-08 1.00E-08 1.00E-08 I

l t i

• e ABOVE RANGE 0. D. O. D. C. D. D. 0. C. O.

I'2 RANGE 7566. 9072. 10985. 13503. 15536. 19375. 24850. 25104. 25169. 24910.

CELOW RANGE 0. D. O. D. O. O. D. O. C. O.

EERO 18325, 16753. 14722. 11983. 10132. 6209, 355. O. O. 0.

TOTAL X/Qs 25891. 25825, 25707, 25486. 25668. 25584. 25205. 25104, 25169. 24910.

t NON ZERO 29.22 35.13 42.73 52.98 60.53 75.73 98.59 100.00 100.00 100.00 l

95th PERCENTILE X/Q VALUES

/ 9.20E-05 8.94E-05 8.65E-05 8.10E-05 6.65E-05 4 64E-05 2.90E-05 2.47E-05 2.20E-05 2.02E-05 954 X/Q for standard averaging intervals 0

2 to to 2 hours2.314815e-5 days <br />5.555556e-4 hours <br />3.306878e-6 weeks <br />7.61e-7 months <br /> 8 hours 9.20E-05 7.732-05 bk04557 REV D 8

1 to to 24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br /> 4 days 3.21E-05 2.252-05 PA6E f [

4 to 30 days 1.88E-05 HOURLY VALUE RANGE MAX X/Q MIN X/Q CENTERLINE 1.14E-04 1.05E-05 SECTOR-AVERAGE 7.15E-05 6.56E-06 NC2 MAL PROGRAM COMPLETION l

1 1

CA04557 Rev.0 Page 46 ATTACHMENT C ARCON96 RUNS FOR WEST ROAD INLET PLENUM I

I

Program Titles ARCON96.

Dev;1oped For U.S. Nuclear Regulatory Commission CA04557 REV0 Office of Nuclear Reactor Regulation $

Division of Reactor Program Management p g{

Dato June 25, 1997 11:00 a.m.

}

NRC Contacts: J. Y. Lee Phones (301) 415 1080 e-nail jyllenre. gov J. J. Hayes Phone (301) 415 3167 e-maili jjhenrc. gov L. A Brown Phones (301) 415 1232 e-mails lab 2enre. gov Dode Developer J. V. Ramadell Phones (509) 372 6316 e-mail: j_ramsdellepal. gov Cod) Documentation: NUREQ/CR-6331 Rev. 1 The program was prepared for an agency of the United States Government. Neither the United States Government nor any agency thereof, nor any of their employees, makes any warranty, expressed or implied, or assumes ary legal listility or responsibilities for any third party's use, or the reeuits of such uns, of any portion of this program or represents that its use by such third party would not infringe privately owned rights.

Progr:m Run 8/24/1998 at 07:24:54 eee**** ARCON INPUT **********

Number of Meteorological Data Files = 3 Meteorological Data File Names CC1991. MET CC1992. MET CC1993. MET H:ight of lower wind instrument (m) = 10.0 Hilght of upper wind instrument (m) = 60.0 Wind speeds entered as meters /second Ground-level release R31 ease height (m) = .0 Building Area (m"2) = 1155.0 Ef fluent vertical velocity (m/s) = .00 V nt or stack flow (m"3/s) . .00 Vint or stack radius (m) = 6.49 Direction intake to source (deg) = 354 Cind direction sector width (deg) = 90 Cind direction window (6ag) = 309 - 039 Distance to intake (m) = 172.0 Intake height (m) = 9.1 T;rrain elevation difference (m) = .0 Dutput file names CMTFWR.out CHTFWR.jfd Minimum Wind Speed (m/s) = .5 Surface roughness length (m) = .10 Sletor averaging constant = 4.0 Initial value of sigma y = 3.02 Initial value of sigma z = .00 Expanded output for code testing not selected Total number of hours of data processed = 26307 Hours of missing data = 416 Hours direction in window = 7470 Hours elevated pluwe w/ dir, in window a 0 Hours of calm winds = 495 Hours direction not in window or calm = 17926 DISTRIBUTION

SUMMARY

DATA BY AVERAGING INTERVAL AVER. FER. 1 2 4 8 12 24 96 168 360 720 UPPER LIM. 1.00E-03 1.00E-03 1.00E-03 1.00E-03 1.00E-03 1.00E-03 1.00E-03 1.00E 03 1.00E-03 1.00E-03 LOW LIM. 1.00E-07 1.00E-07 1.00E-07 1.00E-07 1.00E-07 1.00E-07 1.00E-07 1.00E 07 1.00E-07 1.00E-07

c .-

t 9 ABOVE RANGE 0. O. D. C. O. O. O. O, 0, 0, 12 RANGE 7965,- 9453, 11343. c13855. 15936. 19755. 25017. 25101. 25169. 24910.

' DEMNI RANGE 0. O. D. C. C. O. O. O. O. D.

EERO 17926, 16372. 14364, 11631. 9732. 5829. 188. 3. 0, 0, 1UFAL X/Qs 25891.~ 25825. 25707, 25486. 25668. 25584. 25205. 25104. 25169. 24910.-

t NON EERO 30.75 36.60 44.12 54.36 62.09 77.22 99.25 99.99- 100.00 100.00 t

95th'PERCBNTILE X/Q VALUES ~

2.15E-04 2,10E 2.05E-04 1.93E-04 1.60E-04 .21E-04 7,68E-05 6.76E.05 5.84E-05 5.30E-05

- 95% X/G for standard averaging intervals O to 2 hours2.314815e-5 days <br />5.555556e-4 hours <br />3.306878e-6 weeks <br />7.61e-7 months <br /> 2 to 8 hours9.259259e-5 days <br />0.00222 hours <br />1.322751e-5 weeks <br />3.044e-6 months <br /> 2.15E-04 1.85E-04 g g4557 REV0

..S to 24 houre 1 to 4 days 8.555-05 6.20E-05 ggQ fM 4 to 30 days 4.93E-05 ROURLY VALUE RANGE MAX X/Q MIN X/Q CENTERLINE 2.99E-04 2.88E-05 EECTOR-AVERAGE 1.87E-04 1.81E-05

-NORMAL PROGRAM COMPLETION l

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- Program Tit 13: 'ARCON96, CA04557.REV0 Developed Fors U.S Nuclear Regulatory Commission Office of Nuclear Reactor Regulation . PA6E 77 Division of Reactor Program Management

.: Date s, June 25 1997 11:00 a.m. +

)

NRC Contacts: J. Y.. Lee' Phone sl (301) 415 1080 e-mail jyllenre. gov J. J. Hayes' l Phones (301) 415 3167 e-mail jjbenrc. gov L. A Brown Phones (301) 415 1232 e-maili lab 2enre. gov

. Code Developer J. V. Ramsdell ? Phone s' (509)' 372 6316 l e-mails j_ramsdellepnl. gov

' Code Documentations,. NUREG/CR-6331 Rev, 1 The program was prepared for an agency of the United States Govornment. Neither the United States Government nor any agency thereof, nor any of their employees, makes any warranty, expressed or implied, or assumes any legal

'litbility or responsibilities for any third party's use, or the results of such u 3, of any portion of this program or represents that its use by such third party would not infringe privately owned rights, Progr m Run 8/24/1998 at 07:28:00

- eeeee .

• ARCON INPUT * * * * " * * *

• Number of Meteorological Data Files = 3 Meteorological Data File Names-CC1991. MET CC1992. NET -

CC1993. MET .

Height of lower wind instrument (m) .= 10.0

- H11ght of upper wind instrument . (m) = 60.0-

' Wind speeds entered as meters /second Ground-level release R31 ease height (m). ,

= .0

_Eui3 ding Area (m*2) = 1155.0 Effluent vertical velocity (m/s). = .00 Vent or. stack flow (m*3/s) =- -

.00-VInt or stack radius (m) = ._ 6 . 4 9 Direction ~ . intake to source (deg) = 050 Wind direction sector width (deg) = 90

" Wind direction window (deg) = 005 - 095 Distance to intake (m) = 135.0 Intake height' (m) = 9.1 Tarrain elevation difference (m)- = .0 Dutput fiJe names CHNSBWR out CHNSBWR.jfd Minimum wind Speed (m/s) = .5 Surface roughness length Im). . .10 SIctor. averaging constant = 4.0 Initial value of sigma y = 3.02 Initial value of sigma a = .00 Expanded output for code testing not selected Total number of hours of data processed = 26307 Hours of missing data . = 416 Hours direction in window = 5965-Hours elevated plume w/ dir. in window = 0 Hours of calm winds = 495 Hours direction not in window or calm = 19431 DISTRIBUTION Supt 4ARY DATA BY AVERAGING INTERVAL AVER, PER. 1 2 4 8 12 24 96 168 360 720 UPPER LIM. -1.00E-03 1.00E-03 1.00E-03 1.00E-03 1.00E-03 1.00E 03 1.00E-03 1.00E-03 1.00E-03 1.00E-03 LOW LIM. 1.00E-07 1.00E-07 1.00E-07 1.00E-07 1.005-07 1.002-07 1.00E-07 1.00E-07 1.00E-07 1.00E-07 p

• e ABOVE 9ANGE 0. O. D. O. D. O. O. O. O. D.

IJ RANGE 6460. 7712. 9395. 11745. 13756, 17618, 24509. 24994. 25169. 24910.

DEInf RANGE 0. O. O. D. O. D. D. O. O. O.

EERO 19431, 18113. 16312. 13741, 11912. 7966. 696. 110. O. O.

TOTAL X/Qs 25891. 25825. 25707. 25486. 25668. 25584. 25205. 25104. 25169. 24910.

t NON ZERO 24.95 29.86 36.55 46.08 53.59 68.86 97.24 99.56 100.00 100.00 95th PERCENTILE X/Q VALUES

/.18E-04 3.11E-04 2.99E-04 2.75E-04 2.29E-04 1.73E-04 1.06E-04 8.94E-05 7.57E-05 6.56E-05 95% X/Q for standard averaging intervals  !

O to 2 hours2.314815e-5 days <br />5.555556e-4 hours <br />3.306878e-6 weeks <br />7.61e-7 months <br /> 3.18E-04 CA01557 REV0 4

3 to 8 hours9.259259e-5 days <br />0.00222 hours <br />1.322751e-5 weeks <br />3.044e-6 months <br /> 2.61E-04 8

1 to to 24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br /> 4 days 1.22E-04 8.32E-05 PA6E 9 4 to 30 days 5.94E-05 HOURLY VALUE RANGE MAX X/Q MIN X/Q CENTERLINE 4.63E-04 4.31E-05 f SECTOR-AVERAGE 2.90E-04 2.70E-05 i NORMAL PROGRAM COMPLETION i

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}

Program'Titler lARCOM94.

' Developed'Pors U.S. Nuclear Regulatory Commission CA04557 REV0-office of Nuclear Reactor Regulation Division of Reactor Program Management p g g { '[f Data s - June 25)1997" 11:00 a.m.

NRC Contacts:- J, Y. Lee' Phone: (301)-415 1080 e-maili jyllenre. gov Ji J.= Hayes. . Phones (301) 415 3167 e-mails jjhenre. gov

- L. A Brown- Phones (301) 415 1232 e-mails lab 2enrc. gov Code Developer J. V. Ramsdell Phones (509) 372 6316 e-mails 3.,ransdellopal. gov Code Documentation ' NUREG/CR-6331 Rev. 1 The program was prepared'for an agency of the Uc.ited States Government. Neither th3 United States Government nor any agency thereof, nor any of their l tuployees, makes any warranty, expressed or implied,.or assumes any legal I 111bility or responsibilities for any third party's use, or the results of such use, of any portion of this program or represents that its use by such third party would not infringe privately owned rights.

Progrta Run 8/24/1998 at 07:27:29 eteee.* ARCON INPUT **********

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Cumber of Meteorological Data Files = 3 j Meteorological Data File Names j CC1991. MET l CC1992. MET >

CC1993. MET' Height of lower wind instrument (m)' = 10.0 H31ght of upper wind instrument' (m) = 60.0 Wind speeds entered as meters /second Cround-level release

'R31 ease height (m) = .0 Euilding Area (m"2) = 1155.0 Effluent vertical velocity (m/s) =_ .00

- Vint or stack flow-- (m*3/s) .. .00 vant or stack radius (m) = 6.49

= _ 162

' Wind Direction .. intake to source (deg)~'=

direction sector width (deg) _ 90

- Wind direction window (deg) = 117. 207

. Distance to intake (m) = 262.0 Intake height (m) = 9.1 Terrain elevation difference (r. = .D  !

l output file names CHWHWR.out CHWHWR,j f d Minimum Wind speed (m/s) = .5 Surface roughness length (m) = .10 Sector averaging constant = 4.0 ,

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Initial value of sigma y = 3.02

'Initini value of sigma z' .. .00 Expanded output for code testing not selected 1 Total number of hours of data processed = 26301 Hours of missing data -

416

. Hours direction in window = 5698 3 I

Hours elevated plume w/ dir in window =- 0 Hours of calm winds = 495 Hours direction not in window or calm = ' 19698 j DISTRIBUTION StDetARY DATA BY AVERAGING INTERVAL AVER. PER. 1 .2 4 8 12 24 96 168 360 720

' UPPER LIM. .1.00E 03' 1.00E 03 1.00E-03 1.00E 03 1.00E-03 1.002-03 1 002 03 1.00E 03 1.00E-03 1.00E-03 14W LIM. 1.00E-07 1.00E-07 1.00E 07 1.00E-07 1.00E-07 1.00E-07 1.00E-D7 1.00E-07 1.00E-07 1.00E-07 )

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a .

I ADOVE RANGE 0. O. -D. 0 .' 0, D. O. O. O. D.

j -23 2ANGE 6193.- 7584. 9475. 12141. 14358. 18559. 24524. --25030. 25169. 24f10.

DE14N RANGE 0. D. O. D. .O. O. O. O. C. O.

EERO 19698. 18241. 16232. '13345, 11310. 7025. 681. 14. O. D.

TOTAL X/Os' -25691. 25825. 25707. 25466. . 25668. 25584, 25205. 25104. 25169. 24910.

8 NON EERO .23,92- 29.37 -36.86 47.64 55.94 72,54 97.30 99.71 100.00 100.00 r 95th PERCENTILE X/Q VALUES 1.10E-04 1.06E-04 -1.01E-04 9.30E-05 7.57E-05 5.25E-05 3.00E-05 2.61E-05 2.30E-05 2.078-05 95% X/Q for standard averaging intervals j 0 to 2 hours2.314815e-5 days <br />5.555556e-4 hours <br />3.306878e-6 weeks <br />7.61e-7 months <br /> 3.10E-04 2 to 8 hours9.259259e-5 days <br />0.00222 hours <br />1.322751e-5 weeks <br />3.044e-6 months <br /> 8.73E.05 I

8 to 24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br /> 3.22E 05 A6ESL 1 to 4 days 2.25E-05 4 to.30 days 1.93E-05:

HOURLY VALUE RANGE MAX X/O MIN X/0 l . CENTERLINE 1.44E-04 1.44E-05 l ' SECTOR-AVERAGE 9.03E-05 9.035 NORMAL PROGRAM COMPLETION I

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t CA04557 Rev.0 Page 53 ATTACHMENT D EXCEL SPREADSHFFT ETHANOLAMINE - AUX BLDG ROOF INLET I

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ETA-350-CR CA04557 REV0 PA6E f A- B C D E F G 1 ETHANOLAMINE -

3 CHEMICAL C2H7NO 4 IDLH (PPM) lDLH 1000 6 ODOR THRESHOLD (PPM) OT 3 6 STORAGE QTY (GAL) Q 350 7 STORAGE PURITY (FRACTION) QF 0.85 8 SPECIFIC GRAVITY (GM/CC) SG 1.016 9 VAPOR PRESSURE (TORR-C-R-K) VP 0.48 20 527.67 293.15 10 BOILING POINT (C-K-R) TB 170 443.15 797.67 11 MOLECULAR WT (GM/ MOLE) MB 61.0551 12 DIFFUSION COEFF (CM2/SEC) D 0 13 14 MOLECULAR WT AIR (GM/ MOLE) MA 28.97 16 MOL EN ATTR/BOLTZ CON AIR (K) E/KA 78.6 g CHAR LENGTH AIR (A) SIGA 3.711 17 PRESSURE AIR (ATM-TORR-PSI) PA 1 760 14.696

?8 TEMPERATURE AIR (C-K-R) TA 30 303.15 545.67 19 MASS DENSITY AIR (GM/CC) RHOA 1.20E-03 20 VISCOSITY OF AIR (G/CM-S) MU 1.83E-04 21 R(TORR-CM3/GMOLE-K) R 6.24E+04 22 23 VOL-CR (CF) VCR 234157 24 Q-CR (CFM) FCR 8300 26 WIND VELOCITY (CM/SEC) VW 100 26 MAXIMUM TIME (MIN) Tmax 53737.34 53737.34 27 CONTROL ROOM FACTOR CRF 1.00000 CRF = 1.-exp(-FCR*Tmax.NCR) 28 29 LEBAS MOLAL VOLUME 30 C 14.8 2 29.6 31 H 3.7 7 25.9 32 O 7.4 1 7.4 33 O IN METHYL ESTERS & ETHERS 9.1 0 0 34 O IN ETHYL ESTERS & ETHERS 9.9 0 0 36 O IN HIGHER ESTERS & ETHERS 11 0 0 36 O IN ACIDS 12 0 0 37 O JOINED TO S, P N 8.3 0 0 38 N DOUBLE BONDED ~ 15.6 0 0 39 N IN PRIMARY AMINES 10.5 1 10.5 40 N IN SECONDARY AMINES 12 0 0 41 BR 27 0 0 42 CL- 24.6 0 0 43 F 8.7 0 0 44 1 37 0 0 46 S 25.6 0 0 46 3-MEMBERED RING -6.0 0 0 47 4-MEMBERED RING -8.5 0 0 48 5-MEMBERED RING -11.5 0 0 Page1

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ETA-350-CR CA04557 REV0 PA6E 6 A B C D E F G 49 6-MEMBERED RING -15.0 0 0 50 NAPHTHALENE -30.0 0 0 j 51 ANTHRACENE -47.5 0 0 52 OTHER 0.0 0 0 53 LEBAS MOLAL VOL VB'(CC/MOL) VB' 73.4 54 55 DIFFUSION COEFFICIENT: METHOD OF WILKE AND LEE 56 CHAR LENGTH B (A) SIGB 1.18*VB'^1/3= 4.9406 57 CHAR LENGTH A-B (A) SIGAB (SIGA+SIGB)/2= 4.3258 58 MOL EN ATTR/BOLTZ CON B (K) E/KB 1.15*(TB+273.15)= 509.6225 l 59 MOL EN ATTR/BOLTZ CON BA (K) E/KAB SQRT(E/KA*E/KB)= 200.1408 60 TSTAR T* TA/(E/KAB)= 1.5147 l 61 COLLISION INTEGRAL CONSTANT A 1.06036 62 B 0.15610 63 C 0.19300 64 D 0.47635 65 E 1.03587 66 F 1.52996 67 G 1.76474 68 H 3.89411 69 COLLISION INTEGRAL OMEGA A/T* ^ B + C/e^(T*D) + Ele ^(T* F)+ Gle^(T*H ) 1.1945E+00 70 B-PRIME B' O.00217-0.00050* SORT (1/MA+1/MB) = 2.0572E-03 71 MOLECULAR WEIGHT MR (MA+MB)/(MA*MB) l l 5.0897E-02 72 DIFFUSION COEFF (CM2/SEC) D B'*TA^1.5'MR^0.5/(PA*SIGAB^2* OMEGA)= 1.0959E-01 73 l l l 1.0959E-01 74 VAPOR DENSITY (GM/CC) RHOV MB*14.696*0.01601846/(10.72*TVP) 2.5409E-03 75 l l 76 INITIAL MASS (GM) MO Q*QF*SG'(3785.422 CC/ GAL) 1.1442E+06 77 VOLUME (M3) VO Q*QF'(3.785422E-3 M3/ GAL) = 1.1262E+00 78 SPILL RADIUS INITIAL (M) RO (V0/PI)^0.33333 = 7.1037E-01 79 SPILL AREA INITIAL (M2) AO Pl*RO^2 = 1.5853E+00 80 SPILL AREA FINAL (M2) AF VO/0.01 = 1.1262E+02 81 DELTA SPILL AREA (M2/SEC) DA SQ RT(4 *Pl*9.81 *VO*(SG-R H O A)/SG)) 1.1776E+01 82 TIME TO MAX AREA (SEC) tA (AF-AO)/DA = 9.4289E+00 83 CHARACTERISTIC LENGTH (CM) L SQRT(4*VO*1.E6/PI) 1.1974E+03 84 l 85 VAPOR DENSITY INSIDE CONTROL ROOM - DIFFUSION IN STILL AIR 86 TF NSB WH 87 ADC (S/M3) ADC 3.33E-04 1.07E-03 9.20E-05 88 TIME (SEC) T 1 9.4289 10 40 89 AREA (M2) A MIN (Pl*RO^2+T*DA,AF) 90 VAPORIZATION RATE (GM/M2-S) VR VP*RHOV*10000/760*SQRT(D/Pl/t) 91 VAPOR DEN INSIDE CR(GM/M3) VD VR*ADC*A 92 PPM INSIDE CR PPM (24500/MB)*VD 93 TF 94 CASES T' ADC 3 VR VD PPM 95 1 3.33E-04 1.34E+01 3.00E-03 1.33E-05 5.35E-03 96 9.4289 3.33E-04 1.13E+02 9.76E-04 3.66E-05 1.47E-02 Page 2

tA04557 REV0 ETA-350-CR PA6E %

A- B C D E F G 97 10.0000 3.33E-04 1.13E+02 9.48E-04 3.55E-05 1.43E-02 98 40.0000j 3.33E-04 1.13E+02 4.74E-04 1.78E-05 7.13E-03 99 NSB 100 1 1.07E-03 1.34E+01 3.00E-03 4.28E-05 1.72E-02 101 9.4289 1.07E-03 1.13E+02 9.76E-04 1.18E-04 4.72E-02 102 10.0000 1.07E-03 1.13E+02 9.48E-04 1.14E-04 4.58E-02 103 40.0000 1.07E-03 1.13E+02 4.74E-04 5.71E-05 2.29E-02 104 WH 105 1 9.20E-05 1.34E+01 3.00E-03 3.68E-06 1.48E-03 106 9.4289 9.20E-05 1.13E+02 9.76E-04 1.01E-05 4.06E-03 107 10.0000 9.20E-05 1.13E+02 9.48E-04 9.82E-06 3.94E-03 108 40.0000 9.20E-05 1.13E+02 4.74E-04 4.91E-06 1.97E-03 109 110 VAPOR DENSITY INSIDE CONTROL ROOM - FORCED CONVECTION 111 REYNOLD NUMBER RE L*VW*RHOA/MU 7.8611E+05 112 SCHMIDT NUMBER SC MU/(D*RHOA) 1.3899E+00 113 l 114 TURB MASS TRANS COEFF(CM/S) HDT 0.037*(D/L)*RE^0.8*SC^0.33333 1.9669E-01 115 TURB EVAP RATE (G/M2-S) VFT HDT*MB*VP*1.E4/(R*TVP) 3.1511E-03 118 VAPOR DEN INSIDE CR(GM/M3) VD VFT*ADC*AF*CRF 117 118 PPM INSIDE CR CASES PPM (24500/MB)*VD )

ADC VD PPM 119 TF 3.33E-04 1.18E-04 4.74E-02 120 NSB 1.07E-03 3.80E-04 1.52E-01 121 WH 9.20E-05 3.26E-05 1.31E-02 122 123 LAM MASS TRANS COEFF(CM/S) HDL 0.664*(D/L)*RE^0.5*SC^0.33333 6.0131 E-02 124 LAM EVAP RATE (G/M2-S) VFL HDL*MB*VP*1.E4/(R*TVP) 9.6336E-04 125 VAPOR DEN INSIDE CR(GM/M3) VD VFL'ADC*AF*CRF 126 PPM INSIDE CR PPM (24500/MB)*VD 127 CASES ADC VD PPM 128 _

TF 3.33E-04 3.61E-05 1.45E-02 129 NSB 1.07E-03 1.16E-04 4.66E-02 130 WH 9.20E-05 9.98E-06 4.01E-03 131 laminar turbulent 132 Time to peak (sec) = t=1/ERi.0001*SG 10546441 3224240.1 133 Time to peak (min) = 175774.0 53737.3 )

134 Time to peak (hr) = 2929.57 895.62 l 135 136 Turbulent Evaporation without Recirc intow(cfm) 8300 8300 8300 8300 ADC 137 TF Time (min) 20 53737.34 53767.34 53797.34 3.33E-04 l 138 PPM 0.02 0.05 0.02 0.01 l 139 Turbulent Evaporation without Recirc Inlow(cfm) 8300 8300 8300 8300 ADC I 140 NSB Time (min) 20 53737.34 53767.34 53797.34 1.07E-03 141 PPM 0.08 0.15 0.05 0.02 142 Turbulent Evaporation without Recirc Inlow(cfm) 8300 8300 8300 8300 ADC 143 WH Time (min) 20 53737.34 53767.34 53797.34 9.20E-05 144 PPM 0.01 0.01 0.00 0.00 l l

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ETA-350-CR CA04557 REV O P AGE (7 A B C D E F G 146 146 Turbulent Evaporation with Recire Inlow(cfm) 8300 3000 3000 3000 ADC 147 TF Time (min) 20 53737.34 53767.34 53797.34 3.33E-04 148 _

PPM 0.02 0.05 0.02 0.01 149 Turbulent Evaporation with Recirc Inlow(cfm) 8300 3000 3000 3000 ADC 160 NSB Time (min) 20 53737.?4 53767.34 53797.34 1.07E-03 161 PPM 0.08 0.15 0.05 0.02 162 Turbulent Evaporation with Recirc Inlow(cfm) 8300 3000 3000 3000 ADC 163 WH Time (min) 20 53737.34 53767.34 53797.34 9.20E-05 164 PPM 0.01 0.01 0.00 0.00 l

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J CA04557 Rev.0 .

Page 58 I

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ATTACHMENT E EXCEL SPREADSHFFT ETHANOLAMINE - WEST ROAD INLET j

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I ETA-350-WR CA04557 REY 0 PAGE $9 A B C D E F G 1 ETHANOLAMINE 2

3 CHEMICAL C2H7NO 4 IDLH (PPM) IDLH 1000 5 ODOR THRESHOLD (PPM) OT 3 6 STORAGE QTY (GAL) Q o

' SO 7 STORAGE PURITY (FRACTION) QF 0.85 8 SPECIFIC GRAVITY (GM/CC) SG 1.016 9 VAPOR PRESSURE (MM HG-C-R) VP 0.48 20 527.67 293.15 l 10 BOILING POINT (C-K-R) TB 170 443.15 797.67 11 MOLECULAR WT (GM/ MOLE) MB 61.0551 l 12 DIFFUSION COEFF (CM2/SEC) D 0 j 13 14 MOLECULAR WT AIR (GM/ MOLE) MA 28.97 l

15 MOL EN ATTR/BOLTZ CON AIR (K) E/KA 78.6 l

16 CHAR LENGTH AIR (A) SIGA 3.711 17 PRESSURE AIR (ATM-TORR-PSI) PA 1 760 14.696 18 TEMPERATURE AIR (C-K-R) TA 30 303.15 545.67 19 MASS DENSITY AIR (GM/CC) RHOA 1.20E-03 l 20 VISCOSITY OF AIR (G/CM-S) MU 1.83E-04 21 R(TORR-CM3/GMOLE-K) R 6.24E+04 22 l 23 VOL-CR (CF) VCR 234157 l 24 Q-CR (CFM) FCR 3000 l 25 WIND VELOCITY (CM/SEC) VW 100 26 MAXIMUM TIME (MIN) Tmax 53737.34 53737.34 27 CONTROL ROOM FACTOR CRF 1.00000 CRF = 1.-exp(-FCR*TmaxWCR) l 28 29 LEBAS MOLAL VOLUME 30 C 14.8 2 29.6 31 H 3.7 7 25.9 32 O 7.4 1 7.4 33 O IN METHYL ESTERS & ETHERS 9.1 0 0 I 34 O IN ETHYL ESTERS & ETHERS 9.9 0 0 35 O IN HIGHER ESTERS & ETHERS 11 0 0 l 36 OIN ACIDS 12 0 0 l 37 O JOINED TO S, P, N 8.3 0 0 38 f

N DOUBLE BONDED 15.6 0 0 i 39 N IN PRIMARY AMINES 10.5 1 10.5 40 N IN SECONDARY AMINES 12 0 0 l

l 41 BR 27 0 0 42 CL 24.6 0 0 43 F 8.7 0 0 .

44 1 37 0 0 l 45 S 25.6 0 0 46 3-MEMBERED RING -6.0 0 0 47 4-MEMBERED RING -8.5 0 0  ;

48 5-MEMBERED RING -11.5 0 0 Page 1 j l

1 CA04557 REV0 ETA-350-WR PA6E M i A B C D E F G 49 6-MEMBERED RING -15.0 0 0 50 NAPHTHALENE -30.0 0 0 51 ANTHRACENE -47.5 0 0 52 OTHER 0.0 0 0 53 LEBAS MOLAL VOL VB'(CC/MOL) VB' 73.4 l 54 55 DIFFUSION COEFFICIENT: METHOD OF WILKE AND LEE 56 CHAR LENGTH B (A) StGB 1.18*VB'^1/3= 4.9406 57 CHAR LENGTH A-B (A) SIGAB (SIGA+SIGS)/2= 4.3258 58 MOL EN ATTR/BOLTZ CON B (K) E/KB 1.15*(TB+273.15)= 509.6225 59 MOL EN ATTR/BOLTZ CON BA(K) E/KAB SQRT(E/KA*E/KB)= 200.1408 60 TSTAR T* TA/(E/KAB)= 1.5147 61 COLLISION INTEGRAL CONSTANT A 1.06036 62 B 0.15610 63 C 0.19300 64 D 0.47635 65 E 1.03587 66 F 1.52996 67 G 1.76474 68 H 3.89411 69 COLLISION INTEGRAL OMEGA A/T*^B +Cle^(T*D)+ Ele ^(T*F)+G/e^(T*H) 1.1945E+00 70 B-PRIME B' O.00217-0.00050*SQRT(1/MA+1/MB) = 2.0572E-03 71 MOLECULAR WEIGHT MR (MA+MB)/(MA*MB) l l 5.0897E-02 72 DIFFUSION COEFF (CM2/SEC) D B'*TA^ 1.5*M R^0. 5/(PA*SIGAB ^2 *OM EGA)= 1.0959E-01 73 l l l 1.0959E-01 74 VAPOR DENSIW (GM/CC) RHOV MB*14.696*0.01601846/(10.72*TVP) 2.5409E-03 75 l l 76 INITIAL MASS (GM) MO Q*QF*SG*(3785.422 CC/ GAL) 1.1442E+06 77 VOLUME (M3) VO Q*QF'(3.785422E-3 M3/ GAL) = 1.1262E+00 78 SPILL RADIUS INITIAL (M) RO (V0/PI)^0.33333 = 7.1037E-01 79 SPILL AREA INITIAL (M2) AO Pl*RO^2 = 1.5853E+00 80 SPILL AREA FINAL (M2) AF VO/0.01 = 1.1262E+02 81 DELTA SPILL AREA (M2/SEC) DA S Q RT(4

• Pl *9.81 *VO *(SG-R H OA)/S G)) 1.1776E+01 82 TIME TO MAX AREA (SEC) tA (AF-AO)/DA = 9.4289E+00 83 CHARACTERISTIC LENGTH (CM) L SQRT(4*VO*1.E6/PI) 1.1974E+03 ,

84 l 85 VAPOR DENSITY INSIDE CONTROL ROOM - DIFFUSION IN STILL AIR 86 TF NSB WH 87 ADC (S/M3) ADC 2.15E-04 3.18E-04 1.10E-04 88 TIME (SEC) T 1 9.4289 10 40 89 AREA (M2) A MIN (Pl*RO^2+T*DA,AF) 90 VAPORIZATION RATE (GM/M2-S) VR VP*RHOV*10000/760*SQRT(D/Pl/t) 91 VAPOR DEN INSIDE CR(GM/M3) VD VR*ADC*A 92 PPM INSIDE CR PPM (24500/MB)*VD 93 TF 94 CASES T ADC A VR VD PPM 95 1 2.15E-04 1.34E+01 3.00E-03 8.61 E-06 3.45E-03 96 9.4289 2.15E-04 1.13E+02 9.76E-04 2.36E-05 9.48E-03 Page 2

CA045E7 REV 0 ETA-350-WR PABE 6/

A B C D E F G l 97 10.0000 2.15E-04 1.13E+02 9.48E-04 2.29E-05 9.21 E-03' 98 40.0000 2.15E-04 1.13E+02 4.74E-04 1.15E-05 4.602.-0; 99 NSB 100 1 3.18E-04 1.34E+01 3.00E-03 1.27E-05 5.11E-03 101 9.4289 3.18E-04 1.13E+02 9.76E-04 3.50E-05 1.40E-02 102 10.0000 3.18E-04 1.13E+02 9.48E-04 3.39E-05 1.36E-02 103 40.0000 3.18E-04 1.13E+02 4.74 E-04 1.70E-05 6.81 E-03 104 WH 105 1 1.10E-04 1.34E+01 3.00E-03 4.41 E-06 1.77E-03 106 9.4289 1.10E-04 1.13E+02 9.76E-04 1.21E-05 4.85E-03 107 10.0000 1.10E-04 1.13E+02 9.48E-04 1.17E-05 4.71E-03 108 40.0000 1.10E-04 1.13E+02 4.74E-04 5.87E-06 2.36E-03 109 110 VAPOR DENSITY INSIDE CONTROL ROOM - FORCED CONVECTION 111 REYNOLD NUMBER RE L*VW"RHOA/MU 7.8611E+05 112 SCHMIDT NUMBER SC MU/(D*RHOA) 1.3899E+00 113 l 114 TURB MASS TRANS COEFF(CM/S) HDT 0.037*(D/L)*RE^0.8*SC^0.33333 1.9669E-01 115 TURB EVAP RATE (G/M2-S) .VFT HDT*MB*VP*1.E4/(R*TVP) 3.1511E-03 116 VAPOR DEN INSIDE CR(GM/M3) VD VFT*ADC*AF*CRF 117 PPM INSIDE CR PPM (24500!MB)*VD 118 CASES ADC VD PPM 119 TF 2.15E-04 7.63E-05 3.06E-02 120 NSB 3.18E-04 1.13E-04 4.53E-02 121 WH 1.10E-04 3.90E-05 1.57E-02 122 123 LAM MASS TRANS COEFF(CM/S) HDL 0.664*(D/L)*RE^0.5'SC^0.33333 6.0131 E-02 124 LAM EVAP RATE (G/M2-S) VFL HDL*MB*VP*1.E4/(R*TVP) 9.6336E-04 125 VAPOR DEN INSIDE CR(GM/M3) VD VFL *ADC*AF*CRF 126 PPM INSIDE CR PPM (24500/MB)*VD 127 CASES ADC VD PPM 128 TF 2.15E-04 2.33E-05 9.36E-03 129 NSB 3.18E-04 3.45E-05 1.38E-02 130 WH 1.10E-04 1.19E-05 4.79E-03 131 laminar turbulent 132 Time to peak (sec) = t=1/ER/.0001*SG 10546441 3224240.1 133 Time to peak (min) = 175774.0 53737.3 134 Time to peak (hr) = 2929.57 895.62 j 135 126 Turbulent Evaporation with Recirc Inlow(cfm) 3000 3000 3000 3000 ADC 137 TF Time (min) 20 53737.34 53767.34 53797.34 2.15E-04 138 PPM 0.01 0.03 0.02 0.01 139 Turbulent Evaporation with Recirc Inlow(cfm) 3000 3000 3000 3000 ADC 140 NSB Time (min) 20 53737.34 53767.34 53797.34 3.18E-04 141 PPM 0.01 0.05 0.03 0.02 142 Turbulent Evaporation with Recirc Intow(cfm) 3000 3000 3000 3000 ADC 143 WH Time (min) 20 53737.34 53767.34 53797.34 1.10E-04 144 PPM 0.00 0.02 0.01 0.01 Page 3

CA04557 Rev.0 Page 62 ATTACHMENT F /

CROSS SECTIONAL AREAS l

CA04557 REV D y ,,7 3 4;y.__ PA6E 63

' ' axes <

\;g A= 78,6667' anjy g

, hy i

' ) C = BGS~' 12sfB7

%r 151 ,%

• ne'c' w27 d=Mcge(apr/ey)

' e

=B.599r

& =B3Tkt* = 2,styyn ht, l=f 16 7 '

J < 21;c '

S*A* *ML.88Y/ .

l 4,t"

g. .

j unds  ;

Ai = Eb-cd)= 579fd3 Of' k=Gr?,dOMC-11,1)=7?Z2K~lt' Asm = JLY3CC3 N~

du:* Gu'k*-Wt)- (CG.I ) = (138,n 4'-

war u.)a ys.y bpf' * .E*ktrm- Yg6 = .268/0,/1jf'

~

R U M L .f w&D// G : E'nw Arg = 058,@33~1!r)* [T77 h= 27/G7,rg, /f'-

Attae arp .gry .

CoArf4 M/wy r h 9 L M h/L o rs: y -p 5 z S . ,4 Ars = Cusess Rrsp1 arps

-11.d -(trz.ir')

Mr.3,

= rseoas ,jr' -

Acrm = IlfJrC3 -lf'

,s ...

Apac ' 240IG'Lll'