A04319, Rev 0 to CA04319, 8500 Gal 30% Ammonium Hydroxide CR Chemical Habitability
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, Engineering Services Process Overview EN 1-100 Revision 10 Page 105 of153 ATTACiniENT 19, CALCULATION COVER SIIEET INITIATION (Control Doc Type - DCALC) Page ./ of_ff
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'bCALC No.: r g a/3fg Revision No.: g '
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CALCULATION ENGINEERING O Civil D Instr & Controls g Nuc Engrg Dum -
O Electrical O Mechanical O Diesel Gen Project l
0 Life Cycle Mngmt O Reliability Engrg O Nuc FuelMngmt
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$t) Q( 36% /)&fid/fitsjf/1/ s/gd Co#DftL Jte) C/fD)/44f //Af/fj//Uf/' Unit O UNIT 1 O UNTT 2 gl COMMON - Proprietary or Safeguards Calculation O YES )5NO l Comments: jA' Vendor Calc No.: A'g REVISION No.: g/j; ] Vendor Name-. J//) Safety Class (Check one): ,kSR D AQ DNSR There are assumptions that require Verification during walkdown: AIT # f4 This calculation SUPERSEDES: ~j// REVIEW AND APPROVAL: - Responsible Engineer: [rf'[Mu . Date: y fr I Independent Reviewer: .Z)1j$mmowt/?e kW:- ==N Date: h//z/7f Approval: .),A.(htWAt,((( Date: 30 Mi336 l 9908230068 990017 PDR P ADOCK 05000317 PDR QQOFcIa m ' _- '
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ut04319 Rev.0 - l . Page 2 - l i 2. LIST OF EFFECTIVE PAGES , Page Latest . Page Latest ' Page Latest Page Latest Page Latest Rev Rev Rev Rev Rev i l 001 0 002 0 003 0 004 0 005 0 l 006 0 007 .0 008 0 009 0 010 0 i 011. 0 012 0 013 0 014 0 015 0 016 0 017 0 018 0 019 0 020 0 021 0 022 0 023 0 024 0 025 0 026 0 027 0 028 0 029 0- 030 0 L 031 0 032 0 033 0 034 0 035 0 036 0 037 0 038 0 039 0 040 0 041 0 042 0 043 0 044 0 045 0 l 046 0 047 0 048 0 049 0 050 0 051 0 052 0 053 0 i t i L l I i l I [. i
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-0 4-t CA04319 Rev.0
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- 3. REVIEWER COMMENTS Note that the NRC has stated that 300 ppm is an acceptable toxicity limit for ammonium hydroxide. This work assumes a toxicity limit of 500 ppm based on the following:
- (1) A TCLo of 408 ppm is the lowest concentration to which humans or animals have been 1 exposed for any given period of time that has produced any toxic effect. l (2) An IDLH of 500 ppm is defined as the maximum level from which one could escape within l 30 minutes without any impairing symptoms or irreversible health effects.
(3) The NRC value is overly conservative and is only a recommendation not a requirement. 00ther values may be used ifjustified.' 9 l l l 1 l l s i j
r 1 4 I i CA04319 Rev.0 Page 4
- 4. TABLE OF CONTENTS
- 01. C O VER S H E ET. . .. . . . . . .. . . . . . . . . . . . . . . . . . .. . . . . .. . . . . .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . . . . . . . .
- 02. LI ST O F EFFECTIVE PAG ES . ... . . ...... ........... . . .. ........ .. . .... . ... .. . . .. ... ....... .. .. .. . .. ... . . . . .. .. . .... ... . 2 03 . REVI EWER CO MM ENTS . ... .. ......... ... ............ ....... ... ... ... ............. .. ..... .. . .. .... . . ... . .. . .. . ... ... . . . . . 3
- 04. TAB LE OF CONTENTS .. ...... ... ....... .... .. ... .. . . ... . ........ .. ....... ....... .... . . .. . .... .. .. .... . . . . . . . . ... .. . . . . . .. 4
- 05. PURPOSE..................................................................................................................5 06.INPUTDATA............................................................................................................6
- 07. TEC HNIC AL AS S UMPTI ONS .. . . .. . .. ..... .... .... ... ... . .. . . ... . . ... ... . . . .. . . . .. .. .. .. . .. . . .. . . . . ... .. . . . . . . . . I 0 0 8 . RE F E REN C E S . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . . . . . . .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
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- 09. METH O D S O F AN ALY Sl S .. . . ... . .. .... . . . ... . .. .. .. .. . .. .. ... .. .. .. . ... ....... . .. . ... . . .... .. . . . .... . .. .. .. .. . . . I 3 1 0. C A L C U L ATI ON S . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
- 11. DOCUMENTATION OF COMPUTER CODES................... ........... . ............... ..... .....19 12.RESULTS..................................................................................................................20 1 3 . C ON C L U S I ON S . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . . . . . . . . . . . . . . 2 1 1 4. ATTA C H M ENTS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2 2 ATTACHMENT A: MSDS FOR AMMONIUM HYDROXIDE........................................ 22 ATTACHMENT B: ARCON96 RUN FOR AUX BLDG ROOF INLET............ ......... ... 37 ATTACHMENT C: ARCON96 RUN FOR WEST ROAD INLET PLENUM......... ... . . 40 i
l ATTACHMENT D: EXCEL SPREADSHEET l AMMONIUM HYDROXIDE - AUX BLDG ROOF INLET........... 43 l l ATTACHMENT E: EXCEL SPREADSHEET l AMMONIUM HYDROXIDE - WEST ROAD INLET........... ... .. . 47 ATTACHMENT F: TELEPHONE CONFERENCE MEMORANDUM.... .. ............ ....... 51 l ATTACHMENT G: CROSS SECTIONAL AREAS........ .... .. ..... . ........... ......... ......... . 52 L A ST PA G E OF REP ORT.. ..... .. .......... .... . .......... . .. . .. . . . .. . . ... . . . . . . ...... .... . .. .. .. .. . . ..... ... .. . .. .. . . .. . 5 3 I 1 I
F CA04319 Rev.0 Page5
- 5. PURPOSE 10CFR50 App.A GDC.19 (Ref.1) requires that a control room be provided, from which actions can be taken to operate the nuclear power plant safely under normal conditions and to maintain it in a safe condition under accident conditions. Release of hazardous chemicals can potentially result in the control room becoming uninhabitable. Thus the NRC requires each utility to assess the habitability of the control room during and after a postulated extemal release of hazardous chemicals based on the chemical toxicity limit, vaporization rate, and the relevant atmospheric dispersion coefficients (Ref.2). The explosion and flammability hazard of these chemicals must also be addressed (Ref.2).
CCNPP pro)oses to use a 30% ammonium hydroxide solution, which will be stored in an 8500 gal tank at tle tank farm. The chemical habitability of the control room after a chemical release involving ammonium hydroxide was determined based on in-house dispersion calculations and toxicity determinations for the current control room configuration with the inleakage points at the control room inlet and exhaust dampers and for the modified control room configuration with the inleakage points at the west road inlet plenum (Refs.3-4). Results indicate that this solution can be stored in the 8500 gal storage tank at the tank farm without constituting a toxicological or fire hazard to the control room following a worst case accident for both the current and modified control room configurations. The results of the toxicity calculations for a 30% Ammonium Hydroxide Solution are as follows: Peak Concentration Current Configuration No Recirculation 468 ppm With Recirculation 374 ppm Modified Configuration With Recirculation 184 ppm Toxicity Limit (IDLH) , 500 ppm j Note that under the current configuration with the control room in the recirculation mode within 20 minutes post-accident and under the modified configuration with the control room in a
?erpetual recirculation mode, the peak control room concentration under worst case conditions is !
.ess than TCLo, the lowest concentration to which humans or animals have been exposed for any l given period of time that has produced any toxic effect.
The current calculation incorporates many assumptions which make these results conservative. (1) A maximum concentration limit (IDLH) was utilized that could be tolerated for 30 minutes without physical incapacitation of an average human. The regulatorv requirements of Ref.2 ; dictate a maximum concentration limit that could be tolerated for 2 minutes without physical incapacitation of an average human. IDLH denotes Immediately Dangerous to Life and Health and is defined as the maximum level from which one could escape within 30 minutes without any impairing symptoms or irreversible health effects (Ref.5). (2) For the current configuration ' the maximum control room intake flowrate of 8300 cfm is utilized. This value is twice the normal operating value (Refs.6-8). (3) The control room volume conservatively neglects dead spaces in the control room ceiling and the volume of room A512. (4) The most conservative methodology is utilized: turbulent evaporation.
i l CA04319 Rev.0 Page 6
- 6. INPUT DATA The following input data is incorporated into this work:
(01) Chemical data for ammonium hydroxide: CAS number 1336-21-6 Refs.5,9,10 Chemical formula NH4 0H Refs.5,9,10 Toxicity Limit IDLH (ppm) 500. Refs.5.10 TCLo (ppm) 408. Ref.9 Odor threshold (ppm) 50 Ref.5 Volume fraction 0.30 Att.F Volume (gal) 8500 Att.F Specific gravity (gm/cc) 0.90 Refs.5,9,10 Vapor pressure (mm Hg) VP 720. Ref.10 ; Boiling point (Degrees C) TB 28 @27 C Ref.10 ' Molecular weight (gm/ mole) MB 35.06 Refs.9,10 Flash Point (Degrees F) Non-flammable Refs.5,9,10 Lower explosion limit (Vol%) 16 % Ref.10 i (02) Physical properties of air per Refs.13,14: 1 Molecular weight (gm/ mole) MA 28.97 Characteristic length in air (Angstroms) SIGA 3.711 Molecular energy of attraction / Boltzmann constant (K) E/KA 78.6 Mass density of air (gm/cc) RHOA 1.204E-03 Viscosity of Air (gm/cm-sec) MU l.83E-04 Universal Gas Constant (torr-cm3/gmole-K) R 6.24E+04 (03) The updated control room volume of 234157 ff was extracted from Ref.18. (04) Control room damper inflow for the current configuration is extracted from Refs. 7-8 and is defined as 8300 cfm or twice the maximum flowrate. (05) Control room inleakage for the modified configuration is extracted from Refs. 3-4 and is defined as 3000 cfm. (06) The Tank Farm-Control Room ARCON96 X/Q inputs were derived as follows (Att.B): (a) Number of meteorological data files: 3 Refs.B2,B10 (b) Meteorological data file names: CC1991. MET Refs.B2,B10 CC1992. MET Refs.B2,B10 CC1993. MET Refs.B2,B10 (c) Height oflower wind instrument (m): 10. Ref.B3 (d) Height of upper wind instrument (m): 60. Ref.B3 (e) Wind speed units type (l=m/s,2= mph,3= knots): 1 Refs.B2,B10 (f) Release type (l= ground,2= vent,3= elevated): 1
CA04319 Rev.0 Page 7 (g) Release height (m): 0. (h) Building area (m2)- 1155. . Att.G The cross sectional area calculations a[e analyzed in Att.G. The calculation of containment cross sectional area yields 12435.63 ft above the rooftop level of 91'6". The auxiliary building cross sectional area can N calculated to be 1938.93 ft2 . For a west-to-east wind directiog the total cross-sectional area of the auxiliary building and the two containments is 26810 f . For an capt-to-west wind direction, the total cross sectional area of the turbine . building is 27167 ft . For a north-to-south and south-to-north wind girection, the total cross ! sectional area of the containment and the tgrbine buildipg is 21016 ft . The cross-sectional area of a single containment of 12435.63 ft or 1155 m will conservatively be used.
- (i) Effluent vertical velocity (m/s): 0 (j) Stack or vent flow (m'/s): 0 (k) Stack or vent radius (m): 32.
r = SQRT(A/n) 2 2
= SQRT[(8500 gal)*(3785.422cc/ gal)/(1.cm)/n*(1.E-4m /cm )) j
= 32.00 m ;
l (1) Direction to source (deg): 333 Refs.B12,B14 l (m) Source window (deg): 90 Refs.B13-B14 ; (n) Distance from source to receptor (m): 135 Refs.B12,B14 (o) Intake height (m): 15.62 91.5' + 4.75' - 45' = 51.25' = 15.62 m where 91.5' is the height of the Auxiliary Building roof (Ref.B6),4.75' is the control room , exhaust height (Ref.B13), and 45' is ground level (Ref.B8). ' (p) Grade elevation difference (m): 0 Ref.B1 (q) Primary output file name: CHTFCR.OUT (r) JFT file name: CliTFCR.JFD (s) Surface roughness length (m): 0.1 Ref.B1 (t) Minimum wind speed (m/s): 0.5 Ref.Bl (u) Sector averaging constant: 4 Ref.Bl (v)llours in average: 1 2 4 8 12 24 96 168 360 720 Ref.B1 (w) Minimum number of hours: 1 2 4 8 11 22 87 152 324 648 Ref.Bl (x) llorizontal diffusion coefficient (m): 14.88 o y=r/2.15=32.00/2.15=14.88 m (Ref.B1)
p o CA04319 Rev.0 Page 8 (y) Vertical diffusion coefficient (m) 0. (z) Flag for expanded output: n Ref.Bl (07) Atmospheric dispersion coefficients from the Tank Farm to the Control Room: 0- 2 hrs 2.96E-04 sec/m3 2- 8 hrs 2.38E-04 sec/m3 8- 24 hrs 1.06E-04 sec/m3 24- 96 hrs 7.43E-05 sec/m3 l 96-720 hrs 6.10E-05 sec/m3 (Attachment B, Refs.B1, BIO, B15) (08) The Tank Farm-West Road Inlet ARCON96 X/Q inputs were derived as follows (Att.C): (a) Number of meteorological data files: 3 Refs.B2,B10 (b) Meteorological data file names: CC1991. MET Refs.B2,B10 CC1992. MET Refs.B2,B10 CC1993. MET Refs.B2,B10 (c) Height oflower wind instrument (m): 10. Ref.B3 i (d) Height of upper wind instrument (m): 60. Ref.B3 (e) Wind speed units type (l=m/s,2= mph,3= knots): 1 Refs.B2,B10 (f) Release type (l= ground, 2= vent, 3= elevated): 1 ) (g) Release height (m): 0. 2 (h) Building area (m ): 1155. Att.G The cross sectional area calculations age analyzed in Att.G. The calculation of containment cross sectional area yields 12435.63 ft above the rooftop level of 91'6". The auxiliary building cross sectional area can be calculated to be 1938.93 ft2, For a west-to-east wind directiog the total cross-sectional area of the auxiliary building and the two containments is 26810 ft . For an capt-to-west wind direction, the total cross sectional area of the turbine building is 27167 ft . For a north-to-south and south-to-north wind girection, the total cross , sectional area of the containment and the tgrbine buildipg is 21016 fl . The cross-sectional l area of a single containment of 12435.63 ft or 1155 m will conservatively be used. (i) Effluent vertical velocity (m/s): 0 (j) Stack or vent flow (m'/s): 0 (k) Stack or vent radius (m): 32. r = SQRT(A/n) 2 2
= SQRT[(8500 gal)*(3785.422cc/ gal)/(1.cm)/n*(l.E-4m /cm ))
= 32.00 m (1) Direction to source (deg): 354 Refs.B12,B14 1.
w,
- a. .
4 CA04319 Rev.0 Page 9
. (m) Source window (deg): 90 Refs.B13-B14 (ii) Distance from source to receptor (m): 172 Refs.B12,B14
- (o) Intake height (m): ' 9.14 -
The Auxiliary Bmiding roof above the control room and above A512 will be scaled tight. Most control room inleakage can then be assumed to originate at the Auxiliary Building
- inlet plenum on the west road side (ES199702144). Per Ref.B11, the inlet plenum is
' 54'x10' with a bottom elevation of 70'. Thus the intake height is 75'-45'=30'=9.14 m (p) Grade elevation difference (m): 0 Ref.B1 (q) Primary output file name: CHTFWR.OUT (r)JFT file name: CHTFWR.JFD (s) Surface roughness length (m): 0.1 Ref.B1 (t) Minimum wind speed (m/s): 0.5 Ref.Bl (u) Sector averaging constant: 4 Ref.B1 (v) Hours in average: 1 2 4 8 12 24 96 168 360 720 Ref.B1 -
(w) Minimum number of hours: 1 2 4 8 11'22 87 152 324 648 Ref.Bl (x) Horizontal diffusion coefficient (m): . 14.88 c y=r/2.15=32.00/2.15=14.88 m (Ref.B1) (y) Vertical diffusion coefficient (m) 0. (z) Flag for expanded output: n Ref.Bl (09) Atmospheric dispersion coefficients from the Tank Farm to the West Road Inlet: 0- 2 hrs 1.97E-04 sec/m3 - 2- 8 hrs 1.62E-04 sec/m3 8- 24 hrs 7.50E-05 sec/m3 ~ 24- 96 hrs 5.49E-05 sec/m3 96-720 hrs 4.37E-05 sec/m3 (Attachment C, Refs.B1, B10, B15)
.i
! I l' : u
w ;
- , ,s 1
CA04319 Rev.0 Page 10
- 7. TECHNICAL ASSUMPTIONS '
- The following technical assumptions were utilized in this work:
l
. (01) Per Attachment F, a 28% Ammonium Hydroxide Solution is stored in an ammonia storage j tank of 8500 gals capacity max. Q=8500. gals. j i
(02) Per Ref.15 in a postulated accident, it is assumed that the entire container of the toxic substance ruptures. ' (03) An average ambient atmospheric temperature of 20*C and pressure of 760 torr will be used l in this calculation. Variation in these parameters shows insignificant impact on the results (Ref.16). TA=20 PA=1 (04) The chemical s pill will be assumed to spread in a circular shape with the maximum radius determined by a spilI thickness of I cm per Ref.15. (05) Based on the characteristics of the chemicals, the following release mechanisms will be assumed: For the ammonium hydroxide solution, the mass transfer is the worst of three methodologies: diffusion in still air, laminar mass transfer, and turbulent mass transfer. (06) For laminar and turbulent mass flow, a wind speed of one meter /sec is assumed. This is consistent with the wind tunnel methodology and the CCNPP data of Ref.B3. Note that per Ref.17 (p.265), a flow with Reynold's Number less than 5E+05 is laminar. (07) The vapor pressure of the spilled material will be adjusted to the ambient conditions via the ideal gas law: VP(@T,) = VP(@Typ )
- T, / T,,
1 l l l l
CA04319 Rev.0 Page11
- 8. REFERENCES (01)" Control Room",10CFR50, Appendix A, General Design Criterion 19.
(02)" Assumptions for Evaluating the Habitability of a Nuclear Power Plant Control Room During a Postulated Hazardous Chemical Release", Regulatory Guide 1.78,6/74. (03)" Response to RAI: Accident Dose Analysis and Control Room Habitability Analysis for the MHA, FHA, and CEAEE", NRC-98-044. (04)" Response to RAI: Control Room Habitability Analyses and MSLB Analyses", NRC 018. (05)" Hazardous Chemicals Data Book", Second Edition, Edited by G. Weiss, Noyes Data Corporation. (06) "Offsite and Control Room Doses Following a LOCA", Bechtel Calculation M-89-33 Rev.3,7/9/91. (07) " Fan Performance Curve", BGE DWG 12782-35, Rev.0. (08)" Control Room Temperature During Normal and Emergency Recirculation Modes of Operation", Bechtel Calculation M-91-24,11/9/92. (09)" SAX's Dangerous Properties ofIndustrial Materials", Ninth Edition, Richard J. Lewis Sr. (10) MSDS for Ammonium Hydroxide, Attachment A. (11)"The Merck Index", Eleventh Edition,1989. (12) " CRC Handbook of Physics and Chemistry",66th Edition,1985-1986. (13) " Handbook of Chemical Property Estimation Methods, Environmental Behavior of Organic Compounds", W.Lyman, W.Reehl, and D.Rosenblatt, McGraw Hill 1982. (14)" Flow of Fluids through Valves, Fittings, and Pipe", Crane Technical Paper No.410,1988. (15)" Toxic Vapor Concentrations in the Control Room Following a Postulated Accidental Release", NUREG-0570,6/79. (16)"CCNPP Control Room Habitability Evaluation Due to a Postulated Spill of Ethanolamine", Bechtel Calculation M-94-16 Rev.0,11/10/94. l (17) " Heat Transfer", Seventh Edition, J.P.Holman. (18)"Modeling of the Control Room / Cable Spreading Room HVAC System Using GOTHIC Software", CA02725,1/8/97.
I l CA04319 Rev.0 - ' Page 12 (B1) " Atmospheric Relative Concentrations in Building Wakes", NUREd/CR-6331 R ev.1, 5/97. (B2) CCMAIL from Mark Abrams at PLG to G.E.Gryczkowski,3/5/97. (B3)" Wind Flows and Dispersion Conditions at Calvert Cliffs", Maria Gavrilas and Melissa Wieland, BG&E-EP1,9/85. (B4)" Atmospheric Dispersion Coefficient Calculations from the MSG and ADV to the Control Room", CA03533,1/17/97. (BS)" Auxiliary Building and Containment Structures Exterior Elevations East & West", BGE Drawing 62-047-E, Rev.6 ; (B6) " Auxiliary Building Roof Plan", BGE Drawing 62-043-E, Rev.12. I' (B7) " Containment Liner Plan, Elevation & Penetrations", BGE Drawing 61-740-E, Rev.19. (B8)" General East and South Elevations", BGE Drawing 62-006-E, Rev.4. l (B9) " Equipment Location Turbine Building Unit 1 Plan Floor El 12'0"", BGE Drawing 60-207-E Rev.11. 1 (B10)"ARCON96: Atmospheric Relative Concentrations in Building Wakes", CA03940, 8/21/97. (B11)" Heating and Ventilation System, Auxiliary Building, El. 69'0", Sections and Details", BGE Drawing 60-330-E, Rev.14. l (B12)" Wind Tunnel Modeling of CCNPP", CA00748 Rev.0,10/25/95 (B13)"ARCON95 X/Q Analysis", Bechtel Calculation M-97-02 Rev.0,5/8/97. (B14)"ARCON95 X/Q Analysis", Bechtel Calculation M-97-03 Rev.0,7/1/97. (B15) " Analytical Software Installation Test of ARCON96", CA03941, 8/21/97.
CA04319 Rev.0 Page 13
- 9. METHOD'bF ANALYSIS This work utilizes three separate methodologies to calculate mass transfer from the spill site to the control room.
(1) The first methodology is diffusion in still air for spills in closed areas and for liquids with high boiling points. The method of analysis utilizes the algorithms of Ref.15 to derive the toxic gas concentration inside the control room. (la) Calculation of the Diffusion Coefficient of an air / toxic gas system for dilute gases at low pressures per Ref.13 by the method of Wilke and Lee: 2 DAB = B'*TA"*MR"/(PA*SIGAB
- OMEGA) ~
. where -
2 DAB = Diffusion coeflicient (cm /sec) B' = 0.00217 - 0.00050 * (1/MA + 1/MB)" MA=' Molecular weight of air (gm/ mole) MB= Molecular weight of toxic gas (gm/ mole) MR= (MA+MB)/(MA*MB) = Molecular weight of binary gas (gm/ mole) TA = Air temperature (K) PA = Air pressure (atm) SIGAB == Characteristic length of molecule A interacting with molecule B (A) (SIGA+SIGB)/2 SIGA = Characteristic length of molecule A (A) SIGB = Characteristic length of molecule B (A) = 1.18*VB"
- VB = Lebas molal volume (cc/mol)
OMEGA = Collision integral The Lebas molal volume VB can be calculated as follows per Ref.13: VB = 14.8*(C) + 3.7*(H) + 7.4*(O) + 9.l *(O in Methyl Esters or Ethers)
+ 9.9'(O in Ethyl Esters or Ethers) + 11 *(O in Higher Esters or Ethers)
' + 12*(O in Acids) + 8.3*(O Joined to S, P, N) + 15.6*(N Double Bonded)
+ 10.5*(N in Primary Amines) + 12*(N in Secondary Amines) + 27*(Br)
+ 24.6*(Cl) + 8.7*(F) + 37*(I) + 25.6*(S) - 6.0*(3-Membered Ring)
- 8.5*(4-Membered Ring)- 11.5*(5-Membered Ring)- 15*(6-Membered Ring)
- 30* Naphthalene - 47.5' Anthracene + (Molecular weight / density)*(Element)
The collision OMEGA integrg+OMFg
= A/TS C/e +can bggplculatg E/e + G/e follows per Ref.13:
A= 1.06036 B= 0.15610 C= 0.19300 D= 0.47635 E= 1.03587 F= 1.52996 O= 1.76474 h H= 3.89411 TS = TA/(E/KAB) E/KAB = SQRT(E/KA
- E/KB)
E/KB = 1.15*(TB+273.15) i 4
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(Ib) Surface Area o a Spill P'er Ref.15 The rate of mass transfer of a licJuid into the atmosphere is directly proportional to the surface area of the spill. Ref.15 approximates the initial shape of the liquid body by a cylinder, with the height equal to the radius of the base. VO(m') = 'Q*QF*(0.003785422 m'/;;al)
- R0(m) .= . (V0/n)"' '
2 2-
' A0(m ) = x*R0 I
The liquid spreads q uickly by gravity to a thin pancake on the ground. Its surface area may be estimated by the fol owing equation: 2
'I(m), . x*(R02+2*t*(g*V0*(SG-RHOA)/(n*SG))")
where 1 SG = Density of the liquid (ga/cc) - 2 g= Gravitational constant = 9.81 m/sec t= Time (sec) The surface area, however, does not expand indefinitely as the above equation indicates. The maximum area of the spill in an unconfined space is estimated from the initial volume by assuming a spill thickness ofI cm. 2 AF(m ) = V0/0.01 (A(sec) = Time to maximum area
= (AF-A0)/SQRT(4
- n
- g
- V0 *(SG-RHOA)/SG)
The total mass of the liquid can be calculated as follows: M0_ = Q*QF*SG*3785.422 gm
- where .
Q == : Storage c,uantity (gal) - ,- QF_ = Volume fraction ofliquid or weight fraction of solid SG =- Specific gravity (gm/cc) (Ic) Vaporization Rate in Still Air: y When exposed to the atmosphere, liquids with boiling points above the ambient temperature will evaporate by diffusion into the air. The main driving force is the vapor pressure difference, i.e., concentration gradient, between the liquid phase and the air. The rate of a vapor diffusing into still air is computed from the Fickian diffusion equation in Ref.15 2 VR(gm/m -sec) = VP
- RHOV
- 10000. / p
- SQRT(DAB /(x*t))
~
where e
V~.
. v ..
1 CA04319 Rev.0 -
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) VP(torr) = - Vapor pressure of theliquid '
Xtorr) = Ambient atmospheric pressure (760 torr) RHOV(gm/cc) = Vapor density of the hquid t(sec) = 2 Time DAB (cm /sec) = Diffusion coefficient-The vapor density of the liquid RHOV is derived from Ref.14 as follows: '
. RHOV(lbm/cf) = 144*P'(psia)/(R*T(R))
RHOV(gm/cc) = 144*14.696/(1545/MB'T(R))*(.01601846 gm/cc/lbm/cf)
= MB(gm/ mole)
- 14.696*.01601846/(10.7292*T(R))
(1d) The vapor density outside'the control room can be calculated via 2 VD(gm/m3) = 2 VR(gm/m -sec)*AF(m )*X/Q(sec/m') The corresponding vapor density outside the control room in ppm is (Ref.13) PPM = = (24500/MB)
- VD(gm/m')
(le) The va following:dCen/dt por concentration
= 1
- Cgxy - A *inside
. Ccn the control room at time t can be calculated via the for t<tg Ccgi = CExt * (1. - exp(-A
- t))
for tg<t<t , Cen2 = Cgxy * {l. - exp[-A * (t-ta)]} + Cent
- exP[-A * (t-ta))
for t>t , . ' Ccu = Cn2
- exp[-A * (t-t )]
where 3 Ccn= - Control room concentration in gjn/m or ppm Cux7 = External concentration in gm/m or ppm
.A=. Fca / Vcn = Turnover constant in 1/ min at time t Fca = Control room ingress and egress flow rate at time t Vcn= Control room volume ,
t= ' Time (min) . ta = Time at which recirculation starts (min) t,= (mip)
= Time SG(gm/cc)at which
* (l.cm) / evaporetion
{VR(gm/m -sec) *of tox[cmsubstance (0.0001 ceaseg/cm ) * (60.sel
. (1f) The spill area, vaporization rate, and vapor density are time-dependent qu atities for difTusion m still air for spills in closed areas. The peak vapor density occurs at the time to maximum area (tA), which should be used under these cTnditions.
(2) The second methodology is mass transfer to forced convection for laminar flow per Ref.15,
.VD(gm/m3) = VFL'ADC*AF (1. - exp(-A
- t))
PPM = ' (24500/MB)*VD
, I I
~ -
c q C e-CA04319 Rev.0 Page 16 where ADC= ' Atmospheric dispersion coefficient (sec/m3) AF = Final spill area (m2) See 1b.
.MB = Toxic gas molecular weight (gm/ mole)
VFL = Laminar evaporation rate (gm/m2-sec)
=.
HDL*MB
- VP
- 10000/(R*(T(C)+273.15))
T(C) = Temperature in C at which VP is determined VP = Toxic gas vapor pressure (mmHg) TA = Ambient air temperature (C) R.=.. Universal gas constant = 62400 torr-cm3/gmole-K HDL- = Laminar mass transfg,coegjent (cm/sec)
=
0.664*(DAB /L)*Re Sc DAB = Diffusion coefficient (cm2/sec) See 1a. L= Characteristic I
= (4*V0*l.E6/x)gggth (cm)
V0=. Initial volume (m3)-See 1b. . Re= Reynolds number
=
L*VW*RHOA/MU VW = Wind velocity (cm/sec) RHOA = Mass density of air MU = Viscosity of air Sc = Schmidt number
=
MU/(DAB *RHOA) A= Fca / Vca = Turnover constant in 1/ min Fca = Control room ingress and egress flow rate Vca = Control room volume t= Time to maximum concentration = 10000.*SG/ VFL (3) The third methodology is mass transfer to forced convection for turbulent flow per Ref.15. VD(gm/m3) = VFT*ADC*AF (1. - exp(-A
- t))
PPM = (24500/MB)*VD where ADC = Atmospheric dispersion coeflicient (sec/m3) AF = Final spill area (m2) See 1b. MB = Toxic gas molecular weight (gm/ mole)
.VFT = Turbulent evaporation rate (gm/m2-sec)
=
HDT*MB'VP*10000./ R*(T(C)+273.15)) VP = _ Toxic gas vapor pressur(e (mmHg) _ TA = Ambient air temperature (C) R= Universal gas constant = 62400 torr-cm3/gmole-K HDT = Turbulent mass tranger cgcient (cm/sec)
=
0.037*(DAB /L)*Re Sc DAB = Diffusion coefficient (cm2/sec) See Ia. L= Characteristic I
= (4*VO*l.E6/n)gggth (cm)
V0 = Initial volume (m3)-See 1b. Re= Reynolds number
=
L*VW*RHOA/MU VW = Wind velocity (cm/sec)
L , ,. CA04319 Rev.0 Page 17-RHOA = Mass density ofair MU = Viscosity of air
' Sc = Schmidt number
=
. MU/(DAB'RHOA)
A=- Fca / Vca = Turnover constant in 1/ min Fca=. Control room ingress and egress flow rate
.Vcn= Control room volume t= Time to maximum concentration = 10000.*SG/VFT
. (04) Explosion and Flammability Limits:
Comparison of the maximum concentration of the relevant toxic chemical concentration inside the control room should yield a limiting value with which to compare against the explosion and flammability limits. l i i
)
F I: 1 L ' CA04319 Rev.0 l Page 18
- 10. CALCULATIONS 1 The chemical concentration of 30% ammonium hydroxide inside the control room for a chemical spill of 8500 gal in the tank farm is calculated via EXCEL spreadsheets captured in the following attachments using the methodologies of Section 9:
Attachment D: 30% Ammonium Hydroxide Solution for Current Control Room Configuration Attachment E: 30% Ammonium Hydroxide Solution for Modified Control Room Configuration l l l l l
CA04319 Rev.0 Page 19
- 11. DOCUMENTATION OF COMPUTER CODES This work employed the ARCON96 computer code, which was verified, benchmarked, and documented in Ref. BIO. The installation is documented in Ref.B15. ARCON96 implements a computational model for calculating atmospheric dispersion coefficients (X/Q's) in the vicinity ofbuildings.
1 l'
CA04319 Rev.0 - Page 20
- 12. RESULTS The results of the toxicity calculations for a 8500 gal chemical spill of 30% Ammonium Hydroxide Solution are as follows:
Peak Concentration Current Configuration No Recirculation 468 ppm With Recirculation 374 ppm Modified Configuration With Recirculation 184 ppm Toxicity Limit (IDLH) 500 ppm Note that under the current configuration with the control room in the recirculation mode within 20 minutes post-accident and under the modified configuration with the control room in a wrpetual recirculation mode, the peak control room concentration under worst case conditions is ess than TCLo, the lowest concentration to which humans or animals have been exposed for any given period of time that has produced any toxic effect. l l
CA04319 Rev.0 Page 21
.13. CONCLUSIONS Based on the spreadsheet results presented in Attachments D and E, use and storage of a 30%
Ammonium Hydroxide Solution at the tank farm in the 8500 gallon ammonia storage tank does i not present any control room habitability concerns at CCNPP. l The current chemical habitability calculation incorporates many assumptions which make these results conservative. (1)thout physical incapacitation of an average human. The regulatory req wi . dictate a maximum concentration limit that could be tolerated for 2 minutes without physical incapacitation of an average human. IDLH denotes Immedir.tely Dangerous to Life and Health and is defined as the maximum level from which one could escape within 30 minutes without any impairing symptoms or irreversible health effects (Ref.5). (2) For the cunent configuwtion the maximum control room intake flowrate of 8300 cfm is utilized. This value is twice the normal operating value. (Refs.6-8) (3) The control room volume conservatively neglects dead spaces in the control room ceiling and the volume ofroom A512. (4) The most conservative methodology is utilized: turbulent evaporation. Ammonium Hydroxide Solution will not pose a flammability or explosion hazard, since the solution is non-flammable and non-explosive per Refs.5,9 and 10.
)
CA04319 Rev.0 Page 22 I
- 14. ATTACHMENTS j ATTACHMENT A MSDS FOR AMMONIUM HYDROXIDE I
l l I {
F I g. o ff l L- J L C A0tl31'9 REV 0 - <- - - . P AGE 26 M l}-H-H uC O^R^C^Os e' CO'RCO CHEMICAL CORPORATION
- TYBURN ROAD & C,EDAR1ANE
- FAIRLESS HILT.S. PA. 19030
- 215/295 5006 l Manufacturers of Reagertt and Electronic Chemicals l l
lDENTET% (As Used on Label and Lost) Note: Blank ' spaces are not permitted. Tany kom is not appic' abk. or no l . Ammonium HYdTox1de 9Rnn ksfonneuon k annabk. Ce space mustbe meAed to indica'e that. C:ction i Manufacturet's Name Emergency Telephone Number _Corco Chemical Corporation . (2151 295e5006/Kon7 Address (Number. Street. City, State. and ZIP' Code) Telephone Number for Informaton , _Tyhurn Rd. E Cedar Lane l Date Prepared ' Fairless Hf11s. Penna.19030 10/14/_93_'.3 if7/75-3/92) 6.s iaturg.st2sepay taptenet)
~
. s. . kn . A. n.
'I S;ction 11 - Hazardous ingredients / identity Informatlon other umrts j Harardous Components (Specife Chemical identity: Common Name(s)) OSHA PEL ACGtH TLV Recommended % (optionat) -
Ammonium Hydroxide, NH40H 35 ppm 25 ppm 1D111 ~ l 27 ppm 18 mc/m3 500 ppm Common Names (Synonyms) Aqua Ammonia Indered n c- _ Ammonia Water CAR 1336 71 6. RTECS Rn 9675 000 Ammonin Aoueous - IIN 7679 - l Ammonia Solution - NA 2672
^ ~~
)
Ammonium Hydroxide Solution (DOT) DOT Corrosive Material l l l Section !!! - Physical / Chemical Characteristics 30% Solution Boding Point Spcofc Gravity (H 0 1) ~ l 280C. 830F 8 200C- - 0.9 Vapor Pressure [rnni'Ng')~ Mening Point 0 80 0 F 720 -72.2 0C -98 0F V!por Density (AIR = 1) Evaporation Rate 1.2 (Buy Acetate - 11 N/A Solubility en Water Miscible Appearance and Odor ... Colorless Liquid. Distiftet Odor. S:;ction IV - Fire and Explosion llazard Data l Flammable Limits LEL UEL Flash Point (Method Used) ,N/A (NH3 ) 16% 25% Ertinguistung Media Water Spray, Also water spray to cool flame exposed containers. ' Special Fire Fighting Procedures Stay upwind. Wear positive pressure self-contained breathing apparatus and full protective equipment. MeYtilg*"tSTeYo's#' c ition may cause emission of toxic f umes. Closed containers may c::plode in heat of fire. m a
E ., 0 ll e
,~ . a CA0I/31'9 REV0 l
P AGE 2f Section V - Reactivity Data - l asahday unsista condmons to Avoid . l Heat S Flame ,
- state - --
l Y Incompaiststy tuaterssis to 4vom l l Halosens. Gold. Aoua Repin. Acids. Dimethyl Sg1 Hvnnch1nvite fate, Silver, teachas. Acrolein, Copper, Mercury, Calciunir l Hazardous Decomposthon or Byproducis-l NH, . NG_. Hazardous May'Dccur ^ Condmons so Avoid . Polymentation g,,,_ pt,m, and thtam4nat 4 nn Wa Not Occur . X Sztlon VI- Health Hazard Data Route (s) of Entry. Inhalation? Skint ingestaan? Yes Yes Yes He:iin Hazards (Acute ana ctrone) Dnee4hiv fatal 4r 4nkni.A n ,- cue 11au.A vapar av+re=eiy irrit e+ 4ng _ f_4 n,i_i4 A cessene sovere-burns. Carcinogencur NTP?
- LARC Monographs? OSHA Regulated? I not reported not reported not as carcinosren j Sag ~ ns anti Symptoms oi Raposure ~
Eyn, Note, Throat irritation. Chest pain, Pulmonary Edema, Skin Burns. ~ Medeal Condehons l GeneraEr Aggravated by Exposure Skin, Eyes, Respiratory System. Person with Corneal Disease, l Glaucoma or chronic respiratory diseases may suffer increased risk. Emergency and First Aid Procedures ~ Eve. Skin - irr diate. continons water flush until medicn1 assistance arrives . l Inhalation - remove to fresh air. Ingestion-Call Physician!III l C ction Vil- Precautions for Safe Handling and Use stps so se Taen in cue Matenalis Relened or Spdied Eliminate ignition sources.. Wear self-contained
""^**d'I"5 apparatus and full protective equipment. Dilute spill with water. Tar.e l up with non-combustible absorbent and containerize for later disposal.
l w:ste oisposat Method To. be performed in compliance with all current Local, State 'and Federal Regulations. l Precautions to se Taken en Handhng and Storing l Avn4d vannr. Eeen ennt ainer cinc,d. nwnv frne hent .
- I Beware o'f contain'ers possible internal pre'ssure. ~ Store in a cool place, below 830F.
1: Other Psecautions i i Observe all label precautions whe6 handling " Empty" containers and possible residue there-in. ,. Ssction Vill - Control Measures Gispaatory Protection (Spec #yJype) Mat f-enntnined breathino annaratus e 250 ppm Vintdation Local Eshaust
' ~
Special Recommended uechancai tcenerTecommended , Protectwe Gloves /Eyg<ppctgce shicId splash goggles. Other Protective Clotheno or Equfptrwne Chemical resistant clothing, Eye wash, Safety showers. NN* s'$fel'9 Respect the mcterial. Wash after handling. Pege 2 . u s c e o eses.sti.57t/65f t) j
i b=:Johnsonatt.heyataseaszisase e es- 36 ez:ut 3 g ,
. , < . . . , . . . . , . ~
n C A0//319 REV O N PAGE W
/ ,
MATERIrL GAFETY DATA BWET Alfa Rasar A Johnson Watthey Company 1 30 Bond Street Ward HIII, WA 8;L885-0747 Emergency. Phone-(508) 521-6300 CHENTREC-(800) 14211-9800 , SECTION 1 IDENTIFICATION
- Product Code: 33285 Revision Date: 3/9/94 Product Name: Amonium hydroxide, ACS Synonyms: Aqua amonia Amon i n. wat er Ammonium hydrate Chemical Family: Base. -
CAS#: 7654-41-7 and 7732-18-5 . Molecular Formula: NHs in H2O 3 ......................................................................., i W SECTION 2 INGREDIENTS
~
l 1 4 Chemicolt Amo n i a . M CAS# % , PEL TLV l
%. 7664-41-7 30% 50ppn as NHa 25 ppm.as NHa -TWA
, 35 ppm as NHa-STEL Chemienir Water CAS# % PEL . TLV 7732-18-5 Balance . Not established Not established O .......................................................................
y) SECTION 3- PHYSICAL DATA
~
~
Boiiing Point: No data
% Volatiles: No data - -
Bolubility in Water : Soluble Speci fic Gravit y (H20=1): No data Freezing / Welting Point: No data Evaporation Rate (butyl acetate =1): No data Vapor Density (air =1): No data Vapor Pressure :No data Appearance anrJ' Odor: Clear, colorless liquid, odor of ammonia Other: No data SECTION 4-FIRE AND EXPLOSION HAZARD DATA
......................................................r................. .
Flash Point:(aF) No data Flamable Limits inAir,%byv[lume: Lower Not applicable Upper Not applicable . Autoignition Temperature: Not applicable
1 from: Johnson.!!atthm at --O 5085216350- ; - ' - - - --
- 1
; G 85-29-S6 .02:19 t ' ADI,,319 RE V O Page.2.. . 33285 ~~ , . . ,
PAGE 5
- Extinguishing Media: Nonflanmable' liquid. If materiai is involved in a small fire, use dry chemical or carbon dioxide extinguisher. On large fires, rise standard firefighting agents. Do not use halogenated extingulshing agents.
Special Fire Fighting Procedures: No'special firefightinh procedures needed, use normal procedures which include wearing NIOSH/MSHA apprt uud self-contain.ed breathing apparatus, flame and
' chemical resistant clothing; hats, boots and gloves. If without risk remove material from fire area. ;
SECTION 5-HEALTH DATR ,
..........~............................................................. i 1
USHA (PEL): Not est abl i shed i amuumum ACGIH (TLV): Not estabIished , A. ANIMAL T0XICITY - LDue: Oral-rat: 350 mg/kg-for solution less than 44% NHaand
. greater than 12%
LCso: Inhalat ion-human LCia: 5000 ppm-for so lut ion l ess t ha'n
'N% NHaand greater than 12%
Other: Eye irritation: rabbit; 44 ug, severe i rrit at i on- fo r solution iets t hen 44% and greater than 12% , B. EFFECTS OF EXPD90RE , ACUTE EFFECTS Ingest l o n': Concentrated NHa/H2O may' cause. corrosion of the
% mouth, esophagus and stomach wit:h perforation and peritonitir. Symptoms may. include pain in the mouth, chest and abdomen, constriction of the t hro at , with coughing, vomiting of blood or. passage of loose. stools with blood, and collapse. Breathing difficulty , convulsions and shock may occur. Brief exposure to 5000 ppm or ingest ion of 3-4ml may be fatal. Dilute solutions will have t he same ef fect s but less severe.
Skin
Contact:
Concentrated NHa/H2O may cause burns but dilute O solutions will have the same ef fects but less severe.
@ Eye
Contact:
Vapors may cause irritat lon. Splashes of concent rated solutions may cause severe pain and eye injuries such as glaucoma, - corneal scars, Iris atrophy and cataracts. Di lute so lut ions have' l ess severe effects. Inhalation: Vapors from concent rated NHa/H2O may cause irritat ion of the ' respiratory t ract. Symptoms may include coughing, sore throat and labored breat hing, laryngitis, tracheitis, pulmonary i edema, chest pains and pneumonit;is. Syst emi c irritant. Dilute J solutions have proportlonally less vapors and will have the same N effects but'Itsg severe. l Medical Conditions, if any, Aggravated by the Chemical: None known ! Other Health Hazards: None known j Most Llkely Routes of Entry: I ngest i o n, inhalation l Q , CHRONIC EFFECTS m Ingest I on: None known J Skin
Contact:
None known <- Eye
Contact:
None known ' Inhalation: None.known . Other: None known , l l
l
'I'ron: Johnson Itatthei af G 5005216350 . e7 6 65-ZS-36 62 eage .s,. .'aszes .. .
C A0/l31'9 REV 0 C. EMERdENCY AND FIR 9T AfD PROCEDUkEG Ingestion: PAGE 7/ Do not
/ lemon juice, induce vomiting. Give several glasses of watei or c
Do not give an'y thing by m'outh to an unconscious person.or mi l k t o dri nk Skin
Contact:
Remove contaminated clothing, flood skin with large
' amounts of water. If irritat f oriipersists seek tnedical 'attent ion.
] Eye
Contact:
Immediately. flush eyes, large amounts of wat'er for at. least 15 minutes. including under Call eyelids, ulth a physician. Inhalation: respiration or Remove oxygen as toneeded. fresh ni'r71f"not 'tfreathing give, ert i fi'cl a t
.e .
Obtain medical attention. ,
........*........q............p.'.................'...t..................
'S M
........................ECTION 5-REACTIVITY Incompatibility: Acids, ,icro g l ei ri, dimethyl sul fate, halocens, alkylene oxide, oxidizing agents, org_anic compounds, silver 'ompounds, heavy metals and their compou'nds, baron compounds, antimony, sulfu .
Hazardous Decomposit ton P.raductst NHs,.NOx Conditluns to Rvoid: Thermal dec.omposition. . Stability: Stable
- Hazardous Polymerization: Will not occur Other: No data
. . . . . . . . . . . . . SECTION . . . . . . 7-IfNVIR
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ONMENTAL INFORMATION M RCRA Code: D002 s
% TSCA Registered: Yes Spill and Leak Procedures; Weari,ng full protect ive equipment, .
'-~ I s p i l.1 u'ith dry ssnd or ver'miculite. Mix well and carefully transfer cover a container.
to Waste Disposal: Consult stat e, local or federal EPA regulat ions for proper disposal. O ........................................................................ SECTION 0-PROTE cf) ..................................CTION INFORMATION Vent i 1 at i o n Requ i rement s:. Laboratory fume hood -
~
Respiratory Protection: NIOSH/MSHA opproved respirat or wit h 'an armionia vapo r cart ridge. Use sel f-cont ained breathing apparatus emergency situations. for Protective Gloves: Rubber Eyn/ Face Protect ion: ANSI ap. proved safet y goggles wit h full face shield ' N .............-.
..n.......................................................
SECTION 9-SP
.................................ECIAL PRECAUTIONS I
Handlin'g and Storage: Keep container t ight ly closed. cool, dry, well-ventilated area. Store in a
'% Other Precautions: Lab coat and apron, Idash t horoughl y af t er use. .
.# flame and chemical res i st ant coveralis, eyewash capable and hygienic f ac i l i t i es f o r tidstri ng.
of systained flushing, safet y drench shower O
e
' *' l from: Johnson Ikttheu et O 5985216.350 .. O I eago 4. .33285.. .
C A0(31'9 RE V 0 i P A GE l# Q,, .........................'....................................... ,,,,,,, l SECTION 10-
.......................,TRANSPDRTATION INFORMATION-U.S. D.O.T.
n...................................,,,,
~
Per (HW181) . .
' Name und
Description:
- Ammonia solutions -
Hazard Class: 8 Packing Group: III . Identification Number:. UN2572 Labels Required:; ,Corros,Ive3j.!
.s 3 SECTION 11-CO
.............. ........................MMENTS .................................
numer Danger: Corrosive, burns e'yes,/ ungs, l sk in and t h'roat . I Onployers should use this information only es a suppl $unt to other infor ation i;athered by them, - should rd.e independent jedgergt of sultability of this infarration to ensure proper use and protect the health md safety of emplo2ces. This information is furnished without warranty, md a1y use of the product not in confonamca with t41s.1pterial Safety Data Sheet, or in axbination with aiy other product or prox.ss, is the. responsibility of the user. ! l e o N c . o Co g . N .. s
- s .
/
/
i l 1
Ub/2W1996 13:34 -215,7,447603. ., n. r re TA4ER INDUSTRIES-HQ .~. - CA0(31% REV 0
< dlATsRIA SAFETYDATASHEET PAGE d
~ AMMONIUM HYDROXfDE o ,
ATIONA i centem omrmanonsi IE!ED 9 TANNER INDUSTRIES,INC. DIVISIONS: [@ -%'#2. NATIONAL AMMONIA- NORTHEASTERN AMMONIA HAMLER INDUSTRIES - BOWER AMMONIA & CHEMICAL
~
6811 TAOONY ST., PHILADELPHIA, PA 19135 CORPORATE EMERGENCY TELEPHONE NUMBER:215 SSS-7530 CHEMTREC (CMA) 800 4 DESCRIPTION CHEMICAL NAME' AmmonrumHydroxecSotution l CAS REGISTRf NO. 1336-21-6 SYNOt#MS: MuaAmmone . . CHEMICAL FA dlLY: Anynona FORMULA: t%OH + H,0 Mq.WT: 35D5(NM.OH) COMPOSITION: 29.4% Dy weght of ammona gas dissotved 1 water. STATEMENT OF HEALTHIIAZARD HAZARD DESCRIPTION: Imtant and conushre to skh. eye.resptratyy tract and mucous membranes. May cause seme bums, eye'a'id lung thrurica. Sidn and tespiratory'felated 654a505 aggravated 17/ exposure. Not recoonaedby OSHA as . No!latedin the NationalTor m annualreport.. Not Ested as a catcriogen by the nterna al AgencyorResearch on Carx:er.
~
EXPOSURE LtO.!TS: Vapor - OSHA - 35 ppm,27 mghn3 STEL.15 rninutes 25 pprrt 18 mg/m3 PB. . ACG!H - 25 ppm,18 rng/m3 T1V. 8 hour TWA 35 ppm,27 mg/m3 STEL 1S minutes EMERGENCYTREATMENT EFFECTSOFC'VEREXPOSURE: Skin:locafirritation,burtt:, blister forma!! ort e: bums.ma eadtobtind'ess.Ingestiort n bumingpalninmoutttttroat. stomach. thorax.constrictionof throat.coug ,fonowe vomitingor6arthca.Piob-ablo lethat Ingestion dose is 3 4 m!. (1 ounce). Int)a!4t!Qtt idatiori, hea e severe lung congestion, eatnaam ouuy. co m ,uis m sh e i- . EMERGENCYAID:SMrt flush vdth copious amount of water whto removing contambated dothhg, shoes. Do not rub. or Rpply ch'Jront on affected area, ingestiott if Conscious,'give large amount of water to drink. Refer imme6ately to gs! clan.E Qush with copious amount of water for 15 tr*t Eyelids chould be held apart and away trom eyeban for gogn Inh tio remove to fresh air. Admiteter oxygen or arti6 cal respiration if necessary. SEEK NOTE TO FffYS! CLAN: Eye Inlury may appear as celayed phenomenort Putnonary edem: ~2y foaow chemical brorxtdtis. Supportive treatment with necessary ventlatory actions, inclV64ng oxyger, : ' warrant con-sideratiert PHYSICAt. DATA 80! LING PT.: 4H, v8Cors released on warming FREEZING PT; -77.7'C ( 100'F) VAPOR PR RE: @ 15.S*C: 420-475 mm Hg SPECIFIC GR ITY: 02974 at 60'F VAPOR DENSITY (Air =1) less than 1 - - SOLUBruTYINWATER Comp 6ete PERCENT VOLATILE:100% at 212*F .. EVAPORATION RATE (Abter 1): Semtar - APPEARANCE AND ODOR: Coloriess liquid ard puryant odor 4 F' IRE AND EXPLOslON HAZARD DATA Ft. ASH POINT; None Al.TTOlGNITION TEMP.: Not apprcat4e FLAMMABLE UMITS IN AIR: for edves ar' n monia. LE!; 16% UEl.: 25% EXTINGUISHING MEDIA Ndn'-combustible SPECLAL F1 HTING PROCEDURES: Not consiocred a fire hazard, but care should be taken to aWid exposure to procucthvoivocirifire.Ykarsplash proot pas chemes1 gloves and to avod contact as reeds 1 Coot firo , contahers, 9:Wes. respiratory pro:eccon,rubter i UNUSUAL AND EXPLOS!ON HAZARDS When heated. rnalenalwt give off ammorza paa, a stron0 irritant to eye. f respratory and rnotst skh. Closed contahers exposed to ertteme heat may develop pressure. Combustion of r released amrronia may form r2rogen oxides. -
/*
/
Revistors: Nov. 94 l L _J
05?29/1995. 13:34 2157447603 .TANIER INDUSTRIES-HQ
. C A0fl31'9 REV 0
- MATERIAL SAFETY DATA SHEET P AGE 30
, AMMONIUM HYDROXfDE(Corttinued)
CHEMICAL REACTIVITY STAS!UTV StaEtc at room temperature. Aqua ammorva' wit resst exomermesty wth aces. Releases arnmonsa vapor when heated. j CONDITIONST 3 AVOIO Avordincxingwithsulfuncacidc(Otherst.tngentneratacr.!s;mczngwithhypochicates(chionne bfcacf11. Othe halogens. sod:um hydrorde. Avod contact wth galvantZed surf aces, copper. Drass. brorue, alummum a!!oys.rnercuy, gotd. Ster. strong exceers. Avod heateg. .- ,, HAZARDOUSCECOMPOSITON PRODUCTS: Ammorua decomposden to hydrogen and twogen gases above 450'C (842'F1
- SPILL OR LEAK PROCEDURES STEPSTO BETnKEN: Wearrespiratoryprotectionandprotectreeclot .see PROTECTIVE EQUIPMENT Stop source st possibte.Sta) upwnd and use water spray to absorb the evolved gas, ilute win targe amount of water Contam spitl by d*ing. .
WASTE DISPOSAL Listed as hazardous substance under OWA (40 CFR I16.4. 40 CFR 117.3 Reportable Ouantity. Category C.1 000 N/454kg.). Comofy vatn att ators Sutably douted. product may be disposec of on agneuttural lanc as fertdcor. Keep sont from entenng strca, , or takes. , , SPECIAL PRotECTl0'NiND RHOCEDURES
~
RESPIRATORY PROTECTION: MSHA/NIOSH approved'resstatory protection vath. fun Iacepece for gas and vapor contaminarm effective for amrnongn hydroxde and able to te used for entry
- and escape n emergences. ~Refer 1029 CFR 1910.134 and ANSt: 7.ES.2 for reqwroment{ and Selectort VENTILATION: Local exhaust sufficicht to keep artymorvis gas to 25 ppm orless. Refer to 29 CRF 1910.134 ard ANSI.29.2 for rccu remr3 nts and selecton.
PROTECTIVE Contact. Cotton work EQUIPMENT: Splash-proof. clothes recornrnended Refer to 29 CRF Cas-tight ch'emical 1910.f32 to 1 10.136 safety coggles$ rubber gloves an for requirements SPECIAt. PRECAUTIONS HN4 DUNG > STORING. Keep in strong glass or plas' tic, tigh'ay closed containers. Store in coot (26.7'C/B0*F) and well ven!!ia area. WORKPLACE TECTIVE EQUIPMENT as discussed above sh6utd be near, but outs'de of agua ammonia area. Eyewash a safety shower in irrimediate vi(inity. See 29.'CFR 1910.141 tor workplace requirements. , OtSPOSAL: I ammonia is Ested as a hazardo(rs stbstance tnder FWPCA. See WASTE DISPOML ClasslSed as
. RCRA Haza'dous waste' d e to corrosivtty with designation D002 !! disposed of in original fomt PERSONAL: Asold unnecessary exposure. Use protective caugment as needed. Do not wear contact lenses.
LADELING. AND SHIPPING HAZARD CLAES 8 (Corrosive) PROPER SH!P'ING DEScalPTION: Ammon's Solutions (Arnmoritm Hydrodde),8 UN'>fr72. PG lit RO PLACARD Corosrve IDENTIFICATION NO:UN 2672
~
M0h%fMintROXIDE National Fir Hazardous Materials HEALTH '@ Protection soc. 3 0 , ideritification system FLAMMABILITY @ Hazard Ratng: COR ,yLabel:- REACTIVITY @' PEBSONAL PROTECTION E
'~
OTHER REGULATORY REQUIREMENTS Undef the ComprehenslWErrAronrnentatResponse.Compensaton,arduabEtyActof t980(C6TICLALT10ellt.Section 304,anyenviroynentalrcleaseof thischemicalequaltooroverthereportablequantityof1000lbs.mustbereportedpro-motly to the Nttional Response Center, Washington, D.C. (1000-424-68021 My consumer procuet containing 5% or more ammenh requires a POtSON labet under FHM(16 CFR 1500.129(1)k EPA Hazard Catagories -Immediate: Yet: Delayed. No: Fire:No: Sudden Rolease: No: Reactive: No . The in!ormation, data, and recommendations in this ma{crial safety data sheet relate only Io the specific material desfgnated herein and do tiot relate to trse in cornbination with arty other material or in any process. The informa tion, data; and recommendations set forth herein era bdeved by us to be accurnie. We mue no warranth l either expressed or implied, with respect thefeto and estume no liabit!ty la connechon with any uw of ad Information, data, and recommendations. _J
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GOO"OV5 JANUARi ?,1997 SECTION 1. - - - - - - - - - CHEMICAL IDENTIFICATION- - - - - - - - NAME- AMMONIUM HYDROXIDE,30% NH3 IN WATER 4f SECTION 2. - - - - - COMPOSITION /INFORMATION ON INGREDIENTS - -4Us --- CAS#: 1336-21-6 MF: H5NO EC NO: 215-647-6 e't - N SECTION 3. - - - - - - - - - - HAZARDS IDENTIFICATION - - - - - - - - - LABEL PRECAUTIONARY STATENENTS CORROSIVE CAUSES BURNS. HARMFUL BY INHALATION, IN CONTACT Wmi SKIN AND IF SWALLOWED. LACHRYMATOR. IN CASE OF ACCIDENT OR IF YOU FEEL UNWELL, SEEK hEDICAL ADVICE IMNEDIATELY (SHOW TIE LABEL WlERE POSSIBLE). IN CASE OF CONTACT WITH EYES, RINSE IMhEDIATELY WITH PLENTY OF WATER AND SEEK MEDICAL ADVICE. AFTER CONTACT WITH SKIN, WASilIMMEDIATELY WITH PLENTY OF WATER. WEAR SUITABLE PROTECTIVE CLOTHING, GLOVES AND EYE / FACE PROTECTION. REFRIGERATE BEFORE OPENING. PURITY BASED ON hETALS ANALYSIS. SECTION 4. - - - - - - - - - FIRST-AID MEASURES- - - - - - - - - - - IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES OR SKIN WITH COPIOUS AMOUNTS OF WATER FOR AT LEA 3T 15 MINUTES WHILE REMOVING CONTAMINATED CLOTHING AND SHOES. ASSURE ADEOUATE FLUSHING OF TIIE EYES BY SEPARATING THE EYELIDS
%TTH FINGERS.
IF SWALLOWED, WASil OUT MOUTH %TTH WATER PROVIDED PERSON IS CONSCIOUS. CALL A PHYSICIAN. IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. REMOVE AND WASH CONTAMINATED CLOTHING PROMI'TLY. SECTION 5. - - - - - - - - - FIRE FIGHTING hEASURES - - - - - - - - - - EXTINGUISHING MEDIA NONCOMBUSTIBLE. SPECIAL FIREFIGIITING PROCEDURES WEAR SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING TO PREVENT CONTACT WITH SKIN AND EYES. UNUSUAL FIRE AND EXPLOSIONS HAZARDS EMITS TOXIC FUMES UNDER FIRE CONDITIONS. SECTION 6. - - - - - - - ACCIDENTAL RELEASE hEASURES- - - - - - - - - SELF-CONTAINED BREATHING APPARATUS SHOULD BE WORN.
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MAYS CHEMICAL CO.,INC. CADIi319 REV O 875 ECst 112th Street PA6E N cago. it ms28 (773) 928-3644 EVACUA'IE AREA. ABSORB ON SAND OR VERMICUL11E AND PLACE IN CLOSED CONTAINERS FOR DISPOSAL. VEIRILA*IE AREA AND WASH SPILL SITE AFTER MATERIAL PICKUP IS COMPIEE' SECTION 7. - - - - - - - - - - HANDLING AND STORAGE- - - - - - - - - - -
.: REFERTO SECTION 8.
. ADDITIONAL INFORMATION NID col #ENT 20-30%
SECTION 8. ------ EXPOSURE CONTROLS / PERSONAL PROTECTION------ WEAR APPROPRIATE NIOSH/MSHA-APPROVED RESPIRATOR, CHEMICAL-RESISTANT
' GWVES, SAFETY GOGGLES, CTTHER PROTECTIVE CLOTHING.
SAFETY SHOWER AND EYE BATH. USE ONLYIN A CHEMICAL FUME HOOD. FACESHIELD (8-INCH MINIMUM) DO NOT BREATHE VAPOR. DO NOT GET IN EYES, ON SKIN, ON CLOTHING. AVOID PROLONGED OR REPEATED EXPOSURE. - WASH 1HOROUGHLY AFTERHANDLING. CORROSIVE.- TOXIC. LACHRYMATOR. KEEP TIGHILY CLOSED. REFRIGERATE BEFORE OPENING.
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SECTION 9. ------- PHYSICAL AND CHEMICAL PROPERTIES ------- APPEARANCE AND ODOR CLEAR COWRLESS LIQUID PHYSICAL PROPERTIES FLASHPOINT NONE SPECIFIC GRAVITY: 0.900 SECTION 10. - - - - - - - - -STABILITY AND REACTIVITY - - - - - - - - - INCOMPATIBILITIES ACIDS COPPER, COPPER ALIDYS GALVANIZED IRON ALUMINUM HAZARDOUS COMBUST 10N OR DECOMPOSITION PRODUCTS AMMONIA SECTION 11. - - - - - - - - - TOXICOLOGICAL INFORMATION - - - - - - - -
' ACUTE EFFECTS HARMFUL IF SWALLOWED, INHALED, OR ABSORBED THROUGH SKIN.
MATERIAL IS EX1T<EMELY DESTRUCTIVE TO TISSUE OF THE MUCOUS hEMBRANES
' AND UPPER RESPIRATORY TRACT, EYES AND SKIN. l INHALATION MAY BE FATAL AS A RESULT OF SPASM, INFLAMMATION AND EDEMA l OF THE LARYNX AND BRONCHI, CHEMICAL PNEUMONITIS AND PULMONARY EDEMA.
SYherOMS OF EXPOSURE MAY INCLUDE BURNING SENSATION, COUGHING, WHEEZING, LARYNGITIS, SHORTNESS OF BREATH, HEADACHE, NAUSEA AND VOMITING. RTECS #: BQ9625800 SECTION 12. - - - - - - - - - ECOLOGICAL INFORMATION - - - - - - - - - - DATA NOT YET AVAILABLE. r SECTION 13. - - - - - - - - - DISPOSAL CONSIDERATIONS - - - - - - - - - j FOR SMALL QUANTITIES: CAUTIOUSLY ADD TO A LARGE STIRRED EXCESS OF WATER. ADJUST THE PH TO NEUTRAL, SEPARATE ANY INSOLUBLE SOLIDS OR
' LIQUIDS AND PACKAGE THEM FOR HAZARDOUS-WASTE DISPOSAL. FLUSH THE
CA0(31'9 REV0 PASE 5.3 AQUEOUS SOLUTION DOWN THE DRAIN WIDI PLENTY OF WATER. THE HYDROLYSIS AND NEUTRALIZATION REACTIONS MAY GENERA *IE HEAT AND FUMES WHICH CAN BE CONTROLLED BY THE RATE OF ADDITION. j OBSERVE ALL FEDERAL, STATE AND LOCAL ENVIRONMENTAL REGULATIONS. SECTION I 4. - - - - - - - - - - TRANSPORT INFORMATION - - - - - - - - - CONTACT PURITAN PRODUCTS INC. FOR TRANSPORTATION INFORMATION. SECT 10N 15. - - - - - - - - - REGULATORY INFORMATION - - - - - - - - - - . EUROPEANINFORMATION ECINDEX NO: 007 001 0I-2 CORROSIVE R 34 CAUSES BURNS. R 37
~'.RITATING TO RESPIRATORY SYSTEM.
S7 KEEP CONTAINER TIGHTLY CLOSED. S 26 IN CASE OF CONTACT WITH EYES, RINSE IMMEDIATELY WITH PLENTY OF WATER AND SEEK MEDICAL ADVICE. S 45 IN CASE OF ACCIDENT OR IF YOU FEEL UNWELL, SEEK MEDICAL ADVICE IMMEDIATELY (SHOW THE LABEL WHERE POSSIBLE). SECTION I 6. - - - - - - - - - - OTHER INFORMATION- - - - - - - - - - - - ~ THE ABOVE INFORMATION IS BELIEVED TO BE CORRECT BUT DOES NOT PURPORT TO BE ALL INCLUSIVE AND SHALL BE USED ONLY AS A GUIDE. PURITAN PRODUCTS INC. SHALL NOT BE HELD LIABLE FOR ANY DAMAGE RESULTING FROM HANDLING OR FROM CONTACT WrIII'nIE ABOVE PRODUCT. NYS eht*** l
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- C A0(3'1'9 REV D i . . /.
210 ANmi0 AMM0 MUM 5EXAMTR'b CCBALTATE . P A 8E - p/ ANIT80
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' . HR's 3 ~"IN#$0 CAS:12124-901 HR: 3 AMMONIUM HEXANITRO COBALTATE / AMMONIUM HYDROSULRDE mf: CoH.,N,0,, ' mf: NH,HS mw: 589.1 j
nw: 51.11 ;
- OONSEN80if' REPORT 8; CobTanMisr6p6' 'Gn8s%e**PRDP: Pbd$ ret'dtystds. Mik,118' (150~atm), ds1:17 on the Community Right-To-Know List. , vap press: 400 mm @ 21.8*. ,
r,.ov rfI:i4 w:..'. .. r.u.v. * ' SAFETY PROFILE: ht UMitstanDE D 15soMidshDR6dLisf""." '" .
", _ sensitive. Upon da==plodes
,a@8aa. k e4 nits toxic fumes @ of250*. F:DBAlso D AMMoN isUMuYDaosUmDE.
impact ,(.:SYNSf'anatoN iari, i(Dor) D AMMomUM'
,,.- o MEacArrAN O AMMONIUM sUtFHYDRATE D MoNoAMMomUM
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NQ. See als' COBALT COMPOUNDS and NITRATBS. I stan6B D staNiE AMoNNY D MUE AMMoMU TOXICITY DATA WUH REFERiiiNCE ANJ000 CAS:184149.T hrs.3 ort-2nt LD50:168 mg/kg yns** AD A062 t3s AMMONIUM HYDROGEN. FLUORIDE ori mus'LDIo:80 ang/kg' Jhr. Tali N.1MA2 .
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DOT: UN 1727/UN 2817 - skn mus LDIn:2457 mg/kg"JFETAB %13A2 mf: F H,N mw: 57.06 !Pr mus LDio:10 mg/kg JPETAB %1MA2 PROP: White, colorless crystals. D:;1.51, mp: 126*, bp: vn mus 1.D 2 PET A
. 259*. Will etch glass Very sol in water; sitly sol in alc. Ivn-dog LDio:2 mg/kg JPEun id.tnA2 ska-rbt LD50:lli82 mg/kg JACTDZ [.712.92 SYNS: AC D AMMomUM FWoRIDE D AMMONIUM B!rwoRIDE scu-rbt LDIo:7500 pg/kg JFEnn 5tnA2 O AMuomUM DIFWoRIDE D AMMONIUM FWoa:DE comp.with lyn.rbt LDLo:1500 :1 JPETAB %IWA2 HYDROGEN FWoRIDE (t:0 0 AMMomUMHYDRoFWoxtDE D idr- bt LDlo 50 '
- JrEnn 76.tnA2 AMMONIUM HYDioGEN B! FLUORIDE D AMMONIUM HYDROGEN g gg DIFWoRIDE D AMMomUM HYDROGEN FWoRIDE.so!M(UN1727)
(dot) D AMMONIUM HYDROGEN FWoRmE.solmion (UN 2s17) Par,gpg gggg 343 ggjgg pgu, tnA2 (DOD CONSENSUS REPORTS: Reponed in EPA TSCA - Inventory. COICNSUS REPORTS: Reported in EPA TSCA Inventory. .. SAFETY PROFILE: Poison by ingestion, subcutaneous,
, and intravenous routes. Moderately toxic by skin con-O'SHA PEL: TWA 2.5 mg(F)/mi (El Pyroforic in air. See also SUIJIDES. When heated ACGIH TLV: TWA 2.5 mg(F)/m'. _- to decomposition it emits very toxic fumes of SO,, NO,,
NIOSH REL: (Fluorides, Inorganic) TWA 2.5 mg(F)/m' and NH,. Incompatible with zinc. DOT CLASSIFICATION: 8; Label: Corrosive (UN 1727); DOT Class: 8; Label: Corrosive, Poison (QN 2817) ANK260 CAS:1336-216 HR: 3 SAFETY PROFILE: Caustic p61 son and strong irritant by 0U HYDROXIDE all routes. See also HYDROFLUORIC ACID. When heated to decomposition it emits very toxic fumes of F , mf: H,N!HO inw: 35.06 NO., and NH,. PROP: Clear, colorless liquid solution of ammonia; very pungent odor. D: 0.90, mp: -77*. Sol in water. Soln contains not more than 44% ammonia. ANJ500 CAS:7803 63-6 HR: 2 -
- AMMONIUM HYDROGEN SULFATE SYNS: AMMoN A AQUEOUS O AMMoNIATATER 29% 0 AMMO- .
DOT: UN 2506 NtA s Wn Hs. Motos t=: nosss ammonia.wN 2672) mon mf: NH,HSO4 mw: 115.11 O AMMoNtA soWnoNs @35% IMm M ammonta WM 2M3) (dot) O AQUA AMMONIA PROP: White rhombic crystals; sol in water; insol in ' acetone. Mp: 146.9*, d: 1.78. TOXICITY DATA wmt REFERENCE eye rbt I mg/305 RNS SEV .TxCYAC 23.281.82
= SYNS: Ac D AMMon UM sUlJATE D AMMoN!()M ACID SULFATE eye rbt 750 pg SEV NotAA 29.1363A6 O AMMONIUM Sis 0LPAM D A56doeUUM MoNoHYDRooEN sUL. Inm& sal M kVplatC- ANYAA9 76.475.38 FATE D MoNoAMMoNIUM SULFATE d sUl5 URIC ACID.MoNoAM. mmo.ese 10 pl/ disc ANYAA9 76A75.58 MomuM SALT .
ort hmn LDio:45 mg/kg 34ztAo .95.69 ihl-hmn LClo:5000 ppm 34ztro 95.69
' CONSENSUS R PORTS: Reported In' EPA TSCA ihl hmn TClo:700 ppm: EYE JisMAs 61.2n.71 Inventory. Iht hmn TClo:408 ppm:lRR JisMAs 61.271.71 ort rat LD50:350 mg/kg JruTAn 23.259.41 DOT CLASSIFICATION: 8; Label: Corrosive ort cat LDIn:750 mg/kg NBAMAK4.1289.95 Ivn rbt LDIn:10 mg/kg HBAMAK 4.1289.35 SAFETY PROFILE: Moderately toxic by ingestion. I CONSENSUS REPORTS: Reported in EPA TSCA corrosive. See also SULFATES. Dangerous; when heated Inventory.
to decomposition it emits highly toxic fumes of sulfuric - acid and SO,. NHi, and NO,. NIOSH REL: (Ammonia) CL 50 ppm
I CA0tl31 REV 0 i
, , PAGE AMMOMUM AMGNESIUM ARSENATE ,Wa59 y ..
DOT CLASSiRCATJON: 8; Labch Corrosh'c (UN 2672); ANK750 DOT Class: 2.2;.Labeh Nonflammable Gas.(UN 2073) AMMONIUM IODATE HR: 3 mfi %1NO'8 mw: 192.94 SARITY PROFILE: A human.polson by 1 gestion. An experimental poison by-inhalattopand ngistlon. A PNOP: Colorless / crystals. D: 3.309 @ .21*. mp, 5l' 0' (decomp). Sitly sol in colli water' ; fnsorhi fiot water. ' severe eye.frritant. PUman sysiem!Drritant effects by ocular and in% tion routes,. Mutation data r ported. SAFEiY PROFILE: A pow'etful,itnstablioxidizer;.g . .; Incompatible vith acrolein, nitromethane, a le acid, heated to decomposition it emits very"toMle f6'rdes of 1-' ! chlomsulfonic acid, dimethyl sulfate, halogens, (Au + and NO, Has detonated upon contact with.a scoo ' aqua regla), hcl,-HF, HNOf,',oleum, $ lolactone' possibly due to contr.mination by ammonium periodat
- propylene oxide, AgNO,, Ag,0,'-(Ag,0:. C,H,OH) See also IODATES.
AgMnO , H,SO,. Dangerous; liquid can. Inflict burns, Ose' with adequate ventilation. Men heated to decomposi. tion it emits NH, and 'NO,' ANLOOO HR: 2 AMMONIUM IODDE H R: ,'l mh NH,! mw: 145 ANK500 . , AMMONIUM HYPOPHOSPHITE . PROP: Colorless, hygroscopic crystals. Mp: sub' & 551*, mf: H.NO,P mw: 83.03 bp: 220' (vac), d/2514 @ 25*. vap press: 1 mm @ 11 0.9 *. l* PROP: Mite granules or rhombic crystals. D: 1.634, mp: 200*, bp: decomp @ 240*. Sol in water, alc, NH,: Ir. sol in SAFETY PROFILE: .. . Moderately toxic. See also 10 acetone. , DIDES. Incompatible with BrF,: IF,; K. Men heated to SAFE 7Y PROFILE: M'en heated it can liberate highly decomposition it emits toxic fumes of I , NH,, and NO, i toxic and flammable PH,. See also PHOSPHINE. When heated to decomposition it can emit highly toxic fumes ANL100 CAS:57267-78-4 HR: 1 of PH,, PO,, NH,, add NO, AMMONIUM ISETH!ONATE ~ Inf: C,H,O,S.H,N mw: 142.17 - I ANK600 CAS:7783-18-8 HR: 2 SYOS:.ErnANEsULroNic Acid,z.frYDRoKY MMoN!UM sA1.T AMMONIUM HYPOSULFTE D 2.lfYDRoxYETilANEsULFomC ACID AMMoN!UM sRT mf: O,S,.2H,N mw: 148.22 TOXICIT( DATA wmi REFERENCE I PROP [ A solid. _.. . eye-rbt 100 nig I4LD ' rcroDI 20.573.82
, SYNS: AMMomuM TutosULFAH O DtAMMoNIUM nflosUt CONS'$f(SUS REPORTS: lieported in EPA TSCA Inventory.
FATE D TlitosUIJURIC ACID, DIAMMoNI M SALT TOXIC lTY DATA wmi REFERENCE SAFETY PRORLE: An eye irritant. Men heated to ort rat LD50:2890 mg/kg GUZAB 26(6),54.82 decomposition it emits toxic fumes of SO,, NH,, and NO, orl mus LD:>3 g/kg oTrzAs 26(6).54.82 ort gpg LD50:1098 mg/kg cTrzAn 26(6),54.82 ANL500 CAS:10169-00-3 HR: 2 CONSENSUS REPORTS: Reported . In EPA TSCA AMMON!UM LANTHANUM NITRATE Inventory. mf: H.N.la 7NO, nivi: 59103
! SAFETY PROFILE:Moderatelytoxicbyingestion When SYNS: LANTHANUM AMMoN!UM MTRATE ~
O MTRIC ACID. AMMO-heated to decomposition it emits toxic vapors of NH.- MUM,turrHANUM sAtT O Nmuc ActD.tnm{ ANUM AMMoN!UM and S0,. SET- < - TOXIC'ITY UATA wmi R'EFERENCE ANK6'50 CAS:27441-80 7 HR: 2 ort rat LD.50:3400 mg/kg .A! Hoax 1,637.50 l AMMONIUM IMIDODISULFONATE ipr rat LD50:625 mg/kg ArHoAx 1.637,50 mf: H,NO,S,.xH,N mw: 296.44 SAFETI PROFILE: Moderately toxic by ingestion and SYNS: AMMomUM IMIDom$ SULFATE,D AMdoNIUM IMIDosUL. Intraperitoneal routes. See also NITRATES. When heat-FoNATE D IMIDoDtsUt.rURIC add, AMstoNIUM SALT cd to decomposition it emits very torlC fumes of NH, TOXICITY DATA wmi REFERENCE ort rat LD50:3300 mg/kg GtsAAA 52(10),88.87 or!-mus LD50:2700 mg/kg cisAAA $2(10).88,87 ANL750 HR: 3 ort gpg LD50:2250 mg/kg G!sAAA 52(10),88.87 AMMONIUM MAGNESIUM ARSENATE
"" E^ ' " ' **; 09'4 CON'ENSUS S REPORTS: Reported in EPA TSCA .
Inventory. PROP: Colorless crys:als. Mp: decomp, d: 1.932 @ 15*.
'I ' *#"
SAFE 1Y PROFILE: Moderately toxic by ingestion. Wh f( heated to decomposition it emits toxic vapors of NH,- CONSENSUS REPORTS: Arsenic and its compounds ' and SO,. are on the Community Right To Know List. I
. e AMMONIUM HYDROXIDE CA0(31'S REV0 AMH
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CA04319 Rev.0 Page 37 ATTACHMENT B ARCON96 FILES FOR AUX BLDG ROOF INLET l l
p ! Program
Title:
ARCON96. CA0(319 REV 0 i I Developed For: U.'s.' Nuclear Regulatory Commission Office of Nuclear Reactor Regulation P A6E 18 il . Division of Reactor Program Management l Dats:
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June 25, 1997 11:00 a.m. MRC Contacts ' J. Y. Lee Phone: '(3 01) 415 1080 e-maile jyllenre. gov l J. J. Hayes ' Phone s . (301) 415 3167 - l e-mails jjhenrc. gov L. A Brown- Phones (301) 415 1232 l e-mails lab 2enre. gov Code Developer J. V. Ramsdell Phones (509) 372 6316
'e-mail: j.,ramsdellepnl. gov Code Documentations.NUREG/CR-6331 Rev. 1
'!he program was prepared for an agency of the United States Government. Neither the United States Covernment nor any agency thereof, nor any of their employees, makes any warranty, expressed or in: plied, or assumes any legal liability or responsibilities for any third party's use, or the results of such
' m e, et any portion of this program or represents that its use by such third party would not infringe privately owned rights.
. Program Run- 7/14/1998 at' 13:09:13 .
e****** ARCON INPUT ********** Number'cf Meteorological Data Files = 3 Meteorological Data File Names
]
CC1991. NET l CC1992. MET CC1993. MET Height of lower wind instrument (m) = 10.0 Height of upper wind instrument (m) = 60.0 Wind speeds entered as meters /second 1 Ground-level release 41 ease height (m) . . .0 Building Area (m"2) = 1155.0 Effluent vertical velocity (m/s) = .00 Vcnt or stack flow . (m*3/s) = .00 j Vint or stack radius (m) = 32.00 l
' Direction . intake to source (deg) = 333 Eind direction sector width (deg) = 90
, l'ind direction window (deg) = 288 - 018 l Dittance to intake (m) = 135.0 Intake height - (m) - = 15.6 Tarrain elevation difference (m) = .0-Output file names l CHTFCR.out. CMTrCR.jfd I Minimum Wind Speed (m/s) =-- .5 Surface roughness length (m) = .10 Sector averaging constant = 4.0 l Initial value of sigma y = 14.88 ! Initial value of sigma a = .00 Expanded output for code testing not selected Total number of hours of data processed = 26307 Hours.of missing data = 416. Mours direction in window = 7167 Hours elevated plume w/ dir. in window = . 0 Hours of calm winds - = 495 Hours direction not in window or calm = 18229 l- DISTRIBUTION SUlHARY DATA BY AVERAGING INTERVAL I AVER. PER, 1 2- 4 8 12 34 96 168 360 720 l I UPPER LIM. - 1. 00E-03 1.005-03 1.00E-03 1.00E-03 1.00E-03 1.00E-03 1.00E-03 1.005-03 1.00E 1.00E-03 1D8 LIM. -- 1. 00E-07 1.00E-07 1.00E-07 1.00E-07 1.00E-07 1.00E-07 1.00E-07 1.00E-07 1.00E-07 1.00E-07 l
- i. -e ABOVE RANGE 0. D. O. O. O. O. .O. D. O. O.
IN RANGE 7662. 9147. 11079. 13554. 15606. 19559. 25004. 25103. 25169. 24910. BRMIN RANGE 0. O. O. O. O. O. C. O. O. O. EERO 18229. 16678. 14628. 11932. 20062. 6025, 201. 1. C. O.
'r0TAL X/Os 25891. 25825. 25707. 25486, 25668. 25584. 25205. 25104. 25169. 24910.
4 NON EERO 29.59 35.42' 43.10 $3.18 60.80 76.45 99.20 100.00 100.00 100.00 95th PERCENTILE X/Q VALUES 2.96E-04 2.85E-04 2.73E-04 2.522 04 2.075-04 1.55E-04 9.45E-05 8.34E 05 7.28E-05 6.55E-05
'95% X/O for standard averaging interve'.s 0 to 2 hours 2.96E-04 $
2 8 to to 8 hoors 24 hours 2.38E-04 1.06E-04 C A0(319 REV 0 1 to 4 days 7.43E-05 4 to 30 days ' 6.10E-05 P A6E 37 MOURLY VALUE RANGE MAX X/Q MIN X/Q CENTERLINE 3.90E-04 3.45E-05 SECTOR-AVERAGE ' 2.45E-04. 2.16E-05 NORMAL PROGRAM COMPLETION i i i i I i
L-
. CA04319 Rev.0 Page 40 ATTACHMENT C /
ARCON96 FII.FS FOR WEST ROAD INLET PLENUM I I l i i
e . Program Title ARCON96.
~
Developed For U.S. Nuclear Regulatory Commission Office of Nuclear Reactor Regulation C AD//319 REV 0 Division of Reactor Program Management PASE Data: June 25, 1997 11:00 a.m. *
)
NRC Contacts: J. Y. Lee Phones (301) 415 1080 e-mails jyllenrc. gov J. J. Hayes Phones (301) 415 3167 e-amil: jjhenre. gov L. A Brown Phones (301) 415 1232 e-mails lab 2enrc. gov Code Developer: J. V. Ramsdell Phone: (509) 372 6316 e-mail j_ramsdellepnl . gov Code Documentation: NUREG/CR-6331 Rev. 1 The program was prepared for an agency of the United States Government. Neither the United States Government nor any agency thereof, not any of their employees, makes any warranty, expressed or implied, or assumes any legal liability or responsibilities for any third party's use, or the results of such u]3, of any portion of this program or represents that its use by such third party would not infringe privately owned rights. Program Run 7/14/1998 at 13:09:37
***** *
- ARCON INPtTf * * * *
- m e .
Number of Meteorological Data Files = 3 Meteorological Data File Names CC1991. MET CC1992. MET ~ CC1993. MET Height of lower wind instrument (m) = 10.0 Height of upper wind instrument (m) = 60.0 Cind speeds entered as meters /second cround-level release Release height (m) = .0 Cu11 ding Area (m*2) = 1155.0 Effluent vertical velocity (m/s) = .00 V;nt or stack flow (m*3/s) = .00 Vent or stack radius (m) = 32.00 Direction .. intake to source (deg) = 354 Cind direction sector width (deg) = 90 51nd direction window (deg) = 309 039 Distance to intake (m) = 172.0 Intake height (m) = 9.1 T;rrain elevation difference (m) = .0 Output file names QlTFWR.out CITFWR.jid Minimum Wind speed (m/s) . .5 Surface roughness length (m) = .10 Sector averaging constant = 4.0 Initial value of sigma y = 14.88 Iritial value of sigma z = .00 Expanded output for code testing not selected Total number of hours of data processed = 26307 Hours of missing data = 416 Hours direction in window = 7470-Hours elevated plume w/ dir, in window = 0 Hours of. calm winds = 495 Hours direction not in window or calm = 17926 DISTRIBITTION
SUMMARY
DATA BY AVERAGING INTERVAL AVER. PER. 1 2 4 8 12 24 96 168 360 720 UPPER LIM. 1.00E-03 1.00E-03 1.00E-03 1.00E-03 1.00E 03 1.00E-03 1.00E-Oh 1.00E-03 1.00E-03 1,00E-03 LOW LIM. 1.00E-07 1.00E-07 1.00E-07 1.00E-07 1.00E-07 1.00E-07 1.00E-07 1.00E 07 1.00E-07 1.00E-07 l c - ..
1 ABOVE RAb82E- 'O. O. O. D. O. D. O. O. - 0. O. IN RAIIGE 7965. 9453. 11343. 13855. 159M . 19755. 25017. 25101. 26169. 24910. 3E14381 RAIIGE 0. 0. O. O. O. O. O. O. D. O. EERO 17926. 16372. 14364. 11631. 9732. 5029. 188. 3. O. O. TU1'AL I/Os- 25891. 25425. 25707, 25486. '25660 25584. 25205. 25104. 25169. 24910. t W001 EERO ' 30.76 36.60 44.12 - 54.36 62.09 77.22 99.25 99.99 100.00 100.00 95th PERCENTILE X/Q VALUES 1.975-04 1.91E-04 1.84E-04 1.70E 1.41E-04 . dO4 1.07E 6.79E-05 5.97E-05 5.19E-05 .70E-05 954 X/Q for standard averaging intervals 0 to 2 hours 2.97E.04
.2 to 8 hours 1.62E-04 8 to 24 hours 7.508-05 CA431) n4va v U 1 to 4 days -
4 to 30 days 5.495-05 4.37E-05 gggg g
*MwL #
HOURLY VALUE RANGE - MAX X/Q MIN X/Q l CENTERLINE 2.668-04 2.44E-05 !- SECTOR-AVERAGE 1.67E-04 1.53E-05 W0ltMAL PROGRAM COMPLETION l l t
r: CA04319 Rev.0 Page 43 l
' ATTACHMENT D EXCEL SPREADSHEET AMMONIUM HYDROXIDE - AUX BtDG ROOF INLET l
I l I I l
AMM-HYD-8500-CR Wbl1 hf0 [p ff A ' B l C D E F G l 1 AMMONIUM HYDROXIDE 2 f
/
3 CHEMICAL NH40H 4 IDLH (PPM) IDLH 500 MSDS 5 ODOR THRCSHOLD (PPM) OT 50 6 STORAGE QTY (GAL) O 8500 7 STORAGE PURITY (FRACTION) QF 0.30 l 8 SPECIFIC GRAVITY (GM/CC) SG 0.9 ! 9 VAPOR PRESSURE (TORR-C-R-K) VP 7.20E+02 27 540.27 300.15 ] 10 BOILING POINT (C-K-R) TB 28 301.15 542.07 l 11 MOLECULAR WT (GM/ MOLE) MB 35.06
)
12 DIFFUSION COEFF (CM2/SEC) D 0 l 13 14 MOLECULAR WT AIR (GM/ MOLE) MA 28.97 15 MOL EN ATTR/BOLTZ CON AIR (K) E/KA 78.6 16 CHAR LENGTH AIR (A) SIGA 3.711 17 PRESSURE AIR (ATM-TORR-PSI) PA 1 760 14.696 18 TEMPERATURE AIR (C-K-R) TA 20 293.15 527.67 19 MASS DENSITY AIR (GM/CC) RHOA 1.20E-03 20 VISCOSITY OF AIR (G/CM-S) MU 1.83E-04 21 R(TORR-CM3/GMOLE-K) R 6.24 E+04 22 23 VOL-CR (CF) VCR 234157 24 Q-CR (CFM) FCR 8300 25 WIND VELOCITY (CM/SEC) VW 100 26 MAXIMUM TIME (MIN) Tmax 54.9436 54.9436 27 CONTROL ROOM FACTOR CRF 0.85738 CRF = 1.-exp(-FCR*Tmax.NCR) 28 29 LEBAS MOLAL VOLUME 30 C 14.8 0 0 31 H 3.7 5 18.5 32 0 7.4 1 7.4 33 O IN METHYL ESTERS & ETHERS 9.1 0 0 34 O IN ETHYL ESTERS & ETHERS 9.9 0 0 35 O IN HIGHER ESTERS & ETHERS 11 0 0 36 O IN ACIDS 12 0 0 37 O JOINED TO S, P N 8.3 0 0 38 N DOUBLE BONDED 15.6 0 0 39 N IN PRIMARY AMINES 10.5 1 10.5 40 N IN SECONDARY AMINES 12 0 0 41 BR 27 0 0 42 CL 24.6 0 0 43 F 8.7 0 0 44 1 37 0 0 45 S 25.6 0 0 46 3-MEMBERED RING -6.0 0 0 47 4-MEMBERED RING -8.5 0 0 48 5-MEMBERED RING -11.5 0 0 Page 1
I I , AMM-HYD-8500-CR hYbD & I A B C D E F G 49 6-MEMBERED RING -15.0 0 0 l 50 NAPHTHALENEj -30.0 0 0
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51 ANTHRACENE -47.5 0 0 52 OTHER 0.0 0 0 53 LEBAS MOLAL VOL VB'(CC/MOL) VB' 36.4 54 55 DIFFUSION COEFFICIENT: METHOD OF WILKE AND LEE 56 CHAR LENGTH B (A) SIGB 1.18*VB'^1/3= 3.9106 57 CHAR LENGTH A-B (A) SIGAB (SIGA+SIGB)/2= 3.8108 58 MOL EN ATTR/BOLTZ CON B (K) E/KB 1.15*(TB+273.15)= 346.3225 59 MOL EN AlTR/BOLTZ CON BA (K) E/KAB SQRT(E/KA*E/KB)= 164.9877 60 TSTAR T* TA/(E/KAB)= 1.7768 61 COLLISION INTEGRAL CONSTANT A 1.06036 62 B 0.15610 63 C 0.19300 64 D 0.47635 65 E 1.03587 66 F 1.52996 67 G 1.76474 68 H 3.89411 69 COLLISION INTEGRAL OMEGA A/T*^B +C/e^(T*D)+ Ele ^(T*F)+ Gle^(T*H) 1.1222E+00 70 B-PRIME B' O.00217-0.00050* SORT (1/MA+1/MB) = 2.0445E-03 71 MOLECULAR WElGHT MR (MA+MB)/(MA*MB) l l 6.3041E-02 72 DIFFUSION COEFF (CM2/SEC) D B'*TA^ 1.5'M R^0. 5/( PA*SI G AB ^2 *O M EG A)= 1.5809E-01
- 73 l l l 1.5809E-01 l 74 VAPOR DENSITY (GM/CC) RHOV MB*14.696*0.01601846/(10.72*TVP) 1.4250E-03 75 l l 76 INITIAL MASS (GM) MO Q*QF*SG'(3785.422 CC/ GAL) 8.6875E+06 77 VOLUME (M3) VO Q*QF*(3.785422E-3 M3/ GAL) = 9.6528E+00 78 SPILL RADIUS INITIAL (M) RO (V0/PI)^0.33333 = 1.4538E+00 79 SPILL AREA INITIAL (M2) AO Pl*RO^2 = 6.6398E+00 80 SPILL AREA FINAL (M2) AF VO/0.01 = 9.6528E+02 81 DELTA SPILL AREA (M2/SEC) DA SQ RT(4 *Pl*9.81 *VO*(S G-R H OA)/S G)) 3.4473E+01 82 TIME TO MAX AREA (SEC) tA (AF-AO)/DA = 2.7809E+01 83 CHARACTERISTIC LENGTH (CM) L SQRT(4*VO*1.E6/PI) 3.5058E+03 l 84 l 85 VAPOR DENSITY INSIDE CONTROL ROOM - DIFFUSION IN STILL AIR
, 86 TANK 87 ADC (S/M3) ADC 2.96E-04 88 TIME (SEC) T 1 10 27.8087 40 89 AREA (M2) A MIN (Pl*RO^2+T*DA,AF) 90 VAPORIZATION RATE (GM/M2-S) VR VP*RHOV*10000/760*SQRT(D/Pl/t) 91 VAPOR DEN INSIDE CR(GM/M3) VD VR*ADC*A , 92 PPM INSIDE CR PPM (24500/MB)*VD 93 94 CASES T ADC A VR VD __ PPM 95 1 2.96E-04 4.11E+01 3.03E+00 3.69E-02 2.58E+01 96 10 2.96E-04 3.51E+02 9.58E-01 9.96E-02 6.96E+01 l l I Page 2
AMM-HYD-8500-CR Cbd3tt49 hon A B C D l E F G 97 27.8087 2.96E-04 9.65E+02 5.74E-01 1.64E-01 1.15E+02 j 98 40.0000 2.96E-04 9.65E+02 4.79E-01 1.37E-01 9.56E+01 99 100 VAPOR DENSITY INSIDE CONTROL ROOM - FORCED CONVECTION 101 REYNOLD NUMBER RE L*VW*RHOA/MU 2.3015E+06 102 SCHMIDT NUMBER SC MU/(D*RHOA) 9.6354E-01 103 l 104 TURB MASS TRANS COEFF(CM/S) HDT 0.037*(D/L)*RE^0.8*SC^0.33333 2.0256E-01 105 TURB EVAP RATE (G/M2-S) VFT HDT*MB*VP*1.E4/(R*TVP) 2.7301E+00 106 VAPOR DEN INSIDE CR(GM/M3) VD VFT*ADC*AF*CRF 107 PPM INSIDE CR PPM (24500/MB)*VD 108 CASES ADC VD PPM 109 2.96E-04 6.69E-01 4.67E+02 110 111 LAM MASS TRANS COEFF(CM/S) HDL 0.664*(D/L)*RE^0.5'SC^0.33333 4.4866E-02 112 LAM EVAP RATE (G/M2-S) VFL HDL*MB*VP*1.E4/(R*TVP) 6.0470E-01 113 VAPOR DEN INSIDE CR(GM/M3) VD VFL *ADC*AF*CRF 114 PPM INSIDE CR PPM (24500/MB)*VD 115 CASES ADC VD PPM 116 2.96E-04 1.73E-01 1.21E+02 117 laminar turbulent 118 Time to peak (sec) = t=1/ER/.0001*SG 14883.50 3296.62 119 Time to peak (min) = 248.06 54.94 120 Time to peak (br) = 4.13 0.92 121 122 Turbulent Evaporation without Recirc Infow(cfm) 8300 8300 8300 8300 ADC l 123 Time (min) 20 54.94 60 120 2.96E-04 ! 124 PPM 276.82 467.35 390.67 46.58 125 126 Turbulent Evaporation with Recirc Inlow(cfm) 8300 3000 3000 3000 ADC 127 Time (min) 20 54.94 60 120 2.96E-04 128 PPM 276.82 373.64 350.20 162.36 l Page 3 L
r CA04319 Rev.0 Page 47 ATTACHMENT E EXCEL SPREADSHEET - AMMONIUM HYDROXIDE - WEST ROAD INLET
[ . . (M3M M* AMM-HYD-8500-WR kt-A B C D E F G 1 AMMONIUM HYDROXIDE 4 2 3 CHEMICAL NH40H 4 IDLH (PPM) IDLH 500 MSDS 5 ODOR THRESHOLD (PPM) OT 50 l 6 STORAGE QW (GAL) Q 8500 7 STORAGE PURITY (FRACTION) QF 0.30 l 8 SPECIFIC GRAVITY (GM/CC) SG 0.9 I I 9 VAPOR PRESSURE (TORR-C-R-K) VP 7.20E+02 27 540.27 300.15 10 BOILING POINT (C-K-R) TB 28 301.15 542.07 11 MOLECULAR WT (GM/ MOLE) MB 35.06 l 12 DIFFUSION COEFF (CM2/SEC) D 0 13 14 MOLECULAR WT AIR (GM/ MOLE) MA 28.97 3 15 MOL EN ATTR/BOLTZ CON AIR (K) E/KA 78.6 16 SIGA
)
CHAR LENGTH AIR (A) 3.711 17 PRESSURE AIR (ATM-TORR-PSI) PA 1 760 14.696 18 TEMPERATURE AIR (C-K-R) TA 20 293.15 527.67 19 MASS DENSITY AIR (GM/CC) RHOA 1.20E-03 20 VISCOSITY OF AIR (G/CM-S) MU 1.83E-04 21 R(TORR-CM3/GMOLE-K) R 6.24E+04 22 23 VOL-CR (CF) VCR 234157 24 Q-CR (CFM) FCR 3000 25 WIND VELOCITY (CM/SEC) VW 100 26 MAXIMUM TIME (MIN) Tmax 54.9436 54.9436 27 CONTROL ROOM FACTOR CRF 0.50536 CRF = 1.-exp(-FCR*TmaxWCR) 28 29 LEBAS MOLAL VOLUME 30 C 14.8 0 0 31 H 3.7 5 18.5 32 O 7.4 1 7.4 33 O IN METHYL ESTERS & ETHERS 9.1 0 0 34 O IN ETHYL ESTERS & ETHERS 9.9 0 0 35 O IN HIGHER ESTERS & ETHERS 11 0 0 36 O IN ACIDS 12 0 0 37 O JOINED TO S, P. N 8.3 0 0 38 N DOUBLE BONDED 15.6 0 0 39 N IN PRIMARY AMINES 10.5 1 10.5 40 N IN SECONDARY AMINES 12 0 0 41 BR 27 0 0 42 CL 24.6 0 0 ! 43 F 8.7 0 0 44 1 37 0 0 45 S 25.6 0 0 46 3-MEMBERED RING -6.0 0 0 j 47 4-MEMBERED RING -8.5 0 0 48 5-MEMBERED RING -11.5 0 0 Page 1 i
c%n ko AMM-HYD-8500-WR f4p N A B C D E F G 49 6-MEMBERED RING -15.0 0 0 4 50 NAPHTHALENE -30.0 0 0 51 ANTHRACENE -47.5 0 0 1 52 OTHER 0.0 0 0 53 LEBAS MOLAL VOL VB'(CC/MOL) VB' 36.4 54 55 DIFFUSION COEFFICIENT: METHOD OF WILKE AND LEE 56 CHAR LENGTH B (A) SIGB 1.18*VB'^1/3= 3.9106 57 CHAR LENGTH A-B (A) SIGAB (SIGA+SIGB)/2= 3.8108 58 MOL EN ATTR/BOLTZ CON B (K) E/KB 1.15*(TB+273.15)= 346.3225 59 MOL EN ATTR/BOLTZ CON BA(K) E/KAB SQRT(E/KA*E/KB)= 164.9877 60 TSTAR T* TA/(E/KAB)= 1.7768 61 COLLISION INTEGRAL CONSTANT A 1.06036 62 B 0.15610 63 C 0.19300 64 D 0.47635 65 E 1.03587 66 F 1.52996 67 G 1.76474 68 H 3.89411 69 COLLISION INTEGRAL OMEGA A/7*^B +C/e^(T*D)+ E/e^(T* F)+ Gle^(T*H) 1.1222E+00 ) 70 B-PRIME B' O.00217-0.00050*SQRT(1/MA+1/MB) = 2.0445E-03 j 71 MOLECULAR WEIGHT MR (MA+MB)/(MA*MB) l l 6.3041E-02 ' 72 DIFFUSION COEFF (CM2/SEC) D B'*TA^ 1. 5*M R^0. 5/( PA* SIG AB ^2 *O M E G A)= 1.5809E-01 73 l l l 1.5809E-01 74 VAPOR DENSITY (GM/CC) RHOV MB*14.696*0.01601846/(10.72*TVP) 1.4250E-03 75 l l 76 INITIA.L MASS (GM) MO Q*QF*SG*(3785.422 CC/ GAL) 8.6875E+06 77 VOLUME (M3) VO Q*QF'(3.785422E-3 M3/ GAL) = 9.6528E+00 78 SPILL RADIUS INITIAL (M) RO (V0/PI)^0.33333 = 1.4538E+00 79 SPILL AREA INITIAL (M2) AO Pl*RO^2 = 6.6398E+00 80 SPILL AREA FINAL (M2) AF VO/0.01 = 9.6528E+02 81 DELTA SPILL AREA (M2/SEC) DA SQ RT(4*Pl*9.81 *VO*(SG-R HOA)/SG)) 3.4473E+01 82 TIME TO MAX AREA (SEC) tA (AF-AO)/DA = ,' 7809E+01 83 CHARACTERISTIC LENGTH (CM) L SQRT(4*VO*1.E6/PI) 3.5058E+03 84 l 85 VAPOR DENSITY INSIDE CONTROL ROOM - DIFFUSION IN STILL AIR 86 TANK 87 ADC (S/M3) ADC 1.97E-04 88 TIME (SEC) T 1 10 27.8087 40 89 AREA (M2) A MIN (Pl*RO^2+T*DA,AF) 90 VAPORIZATION RATE (GM/M2-S) VR VP*RHOV*10000/760*SQRT(D/Pl/t) 91 VAPOR DEN INSIDE CR(GM/M3) VD VR*ADC*A L 92 PPM INSIDE CR PPM (24500/MB)*VD 93 94 CASES T ADC A VR VD PPM 95 1 1.97E-04 4.11E+01 3.03E+00 2.45E-02 1.71 E+01 96 10 1.97E-04 3 51E+02 9.58E-01 6.63E-02 4.63E+01 , I l Page 2 L
t CMW9 AM AMM-HYD-8500-VG f.ryc N A B C D E F 97 l G 27.8087 1.97E-04 9.65E+02 5.74 E-01 1.09E-01 7.63E+01 98 40.0000 1.97E-04 9.65E+02 4.79E-01 9.11E-02 99 6.3pE+01 l l 100 VAPOR DENSITY INSIDE CONTROL ROOM - FORCED CONVECTION 101 REYNOLD NUMBER RE L*VW'RH'OA/MU 2.3015E+06 102 SCHMIDT NUMBER SC MU/(D*RHOA) 9.6354E-01 103 l 104 TURB MASS TRANS COEFF(CM/S) HDT 0.037*(D/L)*RE^0.8*SC^0.33333 2.0256E 01 105 TURB EVAP RATE (G/M2-S) VFT HOT *MB*VP*1.E4/(R*TVP) I 2.7301E+00 106 VAPOR DEN INSIDE CR(GM/M3) VD VFT*ADC*AF*CRF I l 107 PPM INSIDE CR PPM (24500/MB)*VD j 108 CASES ADC VD PPM i 109 1.97E-04 2.62E-01 1.83E+02 l 110 l 111 LAM MASS TRANS COEFF(CM/S) HDL 0.664*(D/L)*RE^0.5*SC^0.333331 4.4866E-02 112 LAM EVAP RATE (G/M2-S) VFL HDL*MB*VP*1.E4/(R*TVP) I 6.0470E-01 113 VAPOR DEN INSIDE CR(GM/M3) VD VFL *ADC*AF*CRF i 114 PPM INSIDE CR PPM l (24500/MB)*VD i j 115 CASES ADC VD PPM ! 116 197E-04 1.10E-01 7.70E+01 1 117
! laminar turbulent 118 Time to peak (sec) = t=1/ER/.0001*SG I 14883.50 3296.62 119 Time to peak (min) = i 248.06 54.94 120 Time to peak (hr) = 7 4.13 0.92 121 :
122 Turbulent Evaporation with Recirc Inlow(cfm) 3000 3000 3000: 3000 ADC 123 Time (min) 20 54.94 60i 120 1.97E-04 124 PPM 82.00 183.34 171.84! 79.67 125 t 126 Turbulent Evaporation with Recirc Infow(cfm) 3000 3000 3000! 3000 ADC 127 Time (min) 20 54.94 60; 120 1.97E-04 128 PPM 82.00 183.34 171.84; 79.67 l l Page 3 l
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.... l CA04319 Rev.0 Page 51 ATTACHMENT F BALTIMORE GAS & ELECTRIC COMPANY TELEPHONE AND CONFERENCE MEMORANDUM DATE 04/01/98 BY: Gerard E. Grvezkowski PURCHASE ORDERNO REQN NO. TELEPHONE CALL g CONFERENCE O SOR NO WITH: Brian Klimt (Chemical Environmental Services) COMPANY: BGE
SUBJECT:
30% 8500 Gal Ammonium Hydroxide Chemical Habitability Analysis Brian requested that a control room chemical habitability analysis be performed for a 30% 8500 gal ammonium hydroxide solution stored at the tank farm. i l l l i
CA04319 Rev.0 Page 52 ATIACHMENT G CROSS SECTIONAL AREAS i l 1 l l l l \ l l l l
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CA0(31'9 REV 0 w-pt g =tiJV - PASE $3
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h G#4e acts 7 d=Mcgefugky'
=13]9?r 4 =133Jott = 2,3zyy, L=Y!bt67' cl' 227r ' ,
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S=/60 =(st.pgyj . _ g, t(,e . Acqs
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Ac= Oizd(Mc- ur)= 7/sz<-dt' Arm =JLY3CC3 jf~ du Ols'k*-1t'C")-(C6.() uar uas ea.y = (f38h.5 4'
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- ktim - Y g 6 ^ 2.G8/0,(9 }f ' -
RtM/d .fwuMG: l'-2w r71 Au =was Os8. anp re33-ftr)" .(pgp')= 27tc7,oc, ./t'- - Cs&N/wr.f' b TI!MWL A/L#t6: H-25 x 5 miy An = 0*z.ssi-rid woe am Or2.ic') = r;eoas ,)e' mm Acts = /Lt.IrU -lf' s. n.. ... ,. Apnt = 24oI&,ST,E'
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