Text

Reporting Related to the National Pollutant Discharge Elimination System (NPDES) Permit Id# FL0000159-014-IW1S
	ML14225A010
Person / Time
Site:	Crystal River
Issue date:	08/07/2014
From:	Wunderly B; Duke Energy Carolinas, Duke Energy Corp
To:	; Document Control Desk, Office of Nuclear Reactor Regulation
References
	3F0814-03
	Download: ML14225A010 (109)
	v • d • e

Crystal River Nuclear Plant 15760 W. Power Line Street ENERGY. Crystal River, FL 34428 Docket 50-302 Operating License No. DPR-72 Environmental Protection Plan (Non-Radiological)

Technical Specifications Appendix B - Part II August 7, 2014 3F0814-03 U.S. Nuclear Regulatory Commission Attn: Document Control Desk Washington, DC 20555-0001

Subject:

Crystal River Unit 3 - Reporting Related to the National Pollutant Discharge Elimination System (NPDES) Permit ID# FL0000159-014-IW1S

Dear Sir:

Duke Energy Florida, Inc., hereby provides a copy to the Nuclear Regulatory Commission (NRC) of a revision to the NPDES Permit to include operation of the proposed Citrus County Combined Cycle Project and changing the pH monitoring and compliance point for existing Crystal River Unit 3 (CR-3) Outfall I-FG during times when pH water quality-based effluent limits are met in discharge from this internal outfall. This submittal is required by the CR-3 Facility Operating License, Appendix B - Part II, Environmental Protection Plan (Non-Radiological)

Technical Specifications, Section 3.2, Reporting Related to the NPDES Permit.

Specifically, Section 3.2.4., states, "The NRC shall be notified of changes to the effective NPDES Permit proposed by the licensee by providing NRC with a copy of the proposed change at the same time it is submitted to the permitting agency."

This letter establishes no regulatory commitments.

If you have any questions regarding this report, please contact Mr. Doug Yowell, Lead Environmental Specialist at (727) 820-5228.

Sincq~y Blair P. Wunderly Plant Manager Crystal River Nuclear Plant BPW/ff

Attachment:

Citrus County Combined Cycle Project -Application for Revision to the Crystal River Energy Complex NPDES Permit (Facility ID: FL0000159) xc: NRR Project Manager Regional Administrator, Region I Cce

DUKE ENERGY FLORIDA, INC.

CRYSTAL RIVER UNIT 3 DOCKET NUMBER 50-302 / LICENSE NUMBER DPR-72 REPORTING RELATED TO THE NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPDES) PERMIT ID#

FLOO001 59-014-1Wl S ATTACHMENT CITRUS COUNTY COMBINED CYCLE PROJECT -

APPLICATION FOR REVISION TO THE CRYSTAL RIVER ENERGY COMPLEX NPDES PERMIT (FACILITY ID:

FL0000159)

AUGUST 2014

tDUKE Citrus Combined Cycle Project V.ENERGY. Site Certification Application I,::1Z:A Appendices 10.2.2 NPDES Application/Permits The Crystal River Energy Complex (CREC) is currently authorized to operate under two National Pollutant Discharge Elimination System (NPDES) permits: No. FL0000159 was issued for Units 1, 2, and 3 (see Appendix 10.6.3), and No. FL0036366 for Units 4 and 5.

For the Citrus Combined Cycle (CCC) Project, Duke Energy Florida, Inc. (DEF), is seek-ing a revision of the existing NPDES industrial wastewater facility permit No. FL0000159 for CREC Units 1, 2, and 3 to include the CCC Project and associated changes in the facility water balance and wastewater discharge plans. The industrial wastewater facility or activity permit application (Florida Department of Environmen-tal Protection [FDEP] Forms 1 and 2CS) and supporting information for the requested permit revision are provided in this appendix. The permit application has also been submitted separately to the FDEP Industrial Wastewater Section, Power Plant NPDES Permitting.

"f *1,:. .*! } i*. )*] * *,:'.{'."*. . ' * .* ".\ ~l ';:; {'. ," . * 'R":'.

WASTEWATER FACILITY OR ACTIVITY PERMIT APPLICATION FORM 1 GENERAL INFORMATION I IDENTIFICATION NUMIBER:

Facility ID FL0000159 II CHARACTERISTICS:

INSTRUCTIONS: Complete the questions below to determine whether you need to submit any permit application forms to the Department of Environmental Protection. If you answer "yes" to any questions, you must submit this form and the supplemental form listed in the parenthesis following the question. Mark "X" in the blank in the third column if the supplemental form is attached. If you answer "no" to each question, you need not submit any of these forms. You may answer "no" if your activity is excluded from permit requirements. See Section B of the instructions. See also, Section C of the instructions for definitions of the terms used here.

SPECIFIC QUESTIONS YES NO FORM ATTACHED A. Is this facility a domestic wastewater facility which results in a discharge to surface or ground waters? X B. Does or will this facility (either existing or proposed) include a concentrated animal feeding operation or aquatic animal X production facility which results in a discharge to waters?

C. Does or will this facility (other than those describe in A. or B.)

discharge process wastewater., or non-process wastewater regulated by X 2CS effluent guidelines or new source performance standards, to surface waters?

D. Does or will this facility (other than those described in A. or B.) X (Separate COC) discharge process wastewater to ground waters?

E. Does or will this facility discharge non-process wastewater, not regulated by effluent guidelines or new source performance standards, to X surface waters?

F. Does or will this facility discharge non-process wastewater to ground waters? X (Separate COC)

G. Does or will this facility discharge stormwater associated with industrial activity to surface waters?

H. Is this facility a non-discharging/closed loop recycle system? X I. Is this facility a public water system whose primary purpose is the production of potable water for public consumption and which discharges demineralization concentrate to surface water or X groundwater?

III NAME OF FACILITY: (40 characters and spaces)

Crystal River Units 1, 2, 3 I-1 Y \GDP-I4\DUKETCCC\CATE)EP(.200 ) I DOCX-0725 14 DEP Foini 62-620.910(0)

(Eff-elise .Jty7, 2006 Revised JuMy30, 2010)

Facility ID FL0000159 IV FACILITY CONTACT: (A. 30 characters and spaces)

A. Name and Title (Last, first, & title) B. Phone (area code & no.)

Yowell, Douglas W. 727-820-5228 V FACILITY MAILING ADDRESS: (A. 30 characters and spaces; B. 25 characters and spaces)

A. Street or P.O. Box: P.O. Box 14042, PEF-903 B. City or Town: St. Petersburg I State: FL IZip Code: 33733 VI FACILITY LOCATION: (A. 30 characters and spaces; B. 24 characters and spaces; C. 3 spaces (if known); D. 25 characters and spaces; E. 2 spaces; F. 9 spaces)

A. Street, Route or Other Specific Identifier: 15760 West Power Line Street B. County Name: Citrus C. County Code (if known): 017 D. City or Town: Crystal River E. State: FL I F. Zip Code: 34428 VII SIC CODES: (4-digit, in order of priority)

]. Code #: 4911 (Specify) Electric Svc. 2. Code #: (Specify)

3. Code #: (Specify) 4. Code #: (Specify)

VIII OPERATOR INFORMATION: (A. 40 characters and spaces; B. I character; C. I character (if other, specify);

D. 12 characters; E. 30 characters and spaces; F. 25 characters and spaces; G. 2 characters; H. 9 characters)

A. Name: Duke Energy Florida, Inc. B. Is the name in VIII A. the owner?

[Yes [-]No

.... :ttts. of bper...:

. * .(code) (specify) D. Phone No.:

F = Federal; S - Sta Ite, P =*. Private ,;

.. g.PUtility

.a. tlt 3 25 15 8 352-501-5682 0 Other;. M =Publi.c (other than F :or S).;..

E. Street or P. 0. Box: 15760 West Power Line Street F. City or Town: Crystal River G. State: FL I H. Zip Code: 34428 IX INDIAN LAND: Is the facility located on Indian lands? El Yes E No 1-2 Y.\GDP- 14\DUKE\CCC\SCA\FDEP62OI _)I DOCX--o72514 DEP FoP0n,62-620.910(1)

(Efectie July 7,2006 Revised JWly30, 2010)

Facility ID FL0000159 X EXISTING ENVIRONMENTAL PERMITS:

A. NPDES Permit No. B. UIC Permit No. C. Other (specify) D. Other (specify)

FLOOOO 159; NiA COC PA 77-09P FLA I 18753 - DWW MSGP FLR05H479 XI MAP: Attach to this application a topographic map of the area extending to at least one mile beyond property boundaries. The map must show the outline of the facility, the location of each of its existing and proposed intake and discharge structures, each of its hazardous waste treatment, storage, or disposal facilities, and each well where it injects fluids underground. Include all springs, rivers and other surface water bodies in the map area. See instructions for precise requirements.

See Form 2CS; See Narrative and Figures in Attachment I XII NATURE OF BUSINESS (provide a brief description)

Crystal River Energy Complex is an electrical power generation plant.

The revision is to add the Citrus Combined Cycle (CCC) Project to the existing NPDES Permit FLOOOO 159.

CCC is a two-unit natural gas-fired combined cycle generator.

XIII CERTIFICATION (see instructions)

I certify under penalty of law that I have personally examined and am familiar with the information submitted in this application and all attachments and that, based on my inquiry of those persons immediately responsible for obtaining the information contained in the application, I believe that the information is true, accurate and complete.

I am aware that there are significant penalties for submitting false information, including the possibility of fine and imprisonment.

R. Alexander Glenn A. Name (type or print) B. Sign-re State President Florida Official Title (type or print) 1-3 V',GDP.!4,DUIK.CCC'I5CA ThDEP620(

I I.DOCX-.072514 ODI' Form61-670.910(1) 4Eff-d-J.Joy 7, 2M0 Re.iwd July30,2010)

FORM 2CS WASTEWATER APPLICATION FOR PERMIT TO DISCHARGE PROCESS WASTEWATER FROM NEW OR EXISTING INDUSTRIAL WASTEWATER FACILITIES TO SURFACE WATERS Facility I.D. Number: FLO000159 Please print or type information in the appropriate areas.

I OUTFALL LOCATION For each outfall, list the X,Y coordinates and the name of the receiving water.

(latitude/longitude to the nearest 15 seconds)

A. Outfall B. Latitude C. Longitude No. (List) Deg. Min. Sec. Deg. Min. Sec. D. Name of Receiving Water D-XXX 28 57 33.2 82 41 54.01 To the site discharge canal and thence to the Gulf of Mexico I-XXI 28 58 7.1 82 40 24.92 Internal Outfall to D-XXX I-XX2 28 58 7.1 82 40 19.07 Internal Outfall to D-XXX NA - - - - - - Intentionally left blank NA ..... Intentionally left blank NA ...... Intentionally left blank NA ...... Intentionally left blank II OUTFALL DESIGN A. Outfall B. Design Configuration and C. D. E. Elevation F. Receiving No. (List) Construction Materials Distance Diameter of Discharge Water Depth from shore Invert (MSL) at POD (MSL)

D-XXX Concrete headwall, baffle, and overflow weir that 0 NA -11.29 -13.29 discharges onto a concrete apron and riprap Internal Outfal I-XX I HDPE or equivalent NA 30" Outfall Internal Outfal I-XX2 HDPE or equivalent NA 30" Outfall NA .

NA NA DEP Forrn(2-(,2( 910()51 2CS- IY\D-1DUECCCAF P2) CSDC Y \GDP-14\DUKENCCC\SCA\FDEP62o(l)-2CS -9S4 DOCX-072i14

Facility I.D. Number: FL-0000159 III RECEIVING WATER INFORMATION For each surface water that will receive effluent, supply the following information:

A. Name of Receiving Water B. Check One C. D. Type of Classification Receiving Water Fresh Salt or Brackish (See Ch.62-302, F.A.C.) (canal, river, lake, etc.)

Crystal Bay/Gulf of Mexico (WBID 8039) El 0 Class II Gulf El El El El E. Minimum 7-day 10-year low flow of the receiving water at each outfall (if appropriate).

NA - tidal waters F. Identifly and describe the flow of effluent from each outfall to a major body of water. A suitably marked map or aerial photograph may be used.

Cooling water will be withdrawn from the existing CREC intake canal, while cooling tower blowdown will be discharged via the existing discharge canal. See Attachment 1, Figures I and 2.

G. Do you request a mixing zone under Rule 62-4.244, F.A.C.? If yes, for what parameters or pollutants?

No IV FLOWS, SOURCES OF POLLUTION, AND TREATMENT TECHNOLOGIES A. Attach a line drawing showing the water flow through the facility. Indicate sources of intake water, operations contributing wastewater to the effluent, and treatment units labeled to correspond to the more detailed descriptions in Item B. Construct a water balance on the line drawing by showing average flows between intakes, operations, treatment units, and outfalls. If a water balance cannot be determined (e.g., for certain mining activities), provide a pictorial description of the nature and amount of any sources of water and any collection or treatment measures.

See Attachment I, Figures 3-5 and supporting narrative in Attachment 2.

B. For each outfall, provide a description of:

I. All operations contributing wastewater to the effluent; including process wastewater, sanitary wastewater, cooling water, and stormwater runoff;

2. The average flow contributed by each operation and

3. The treatment received by the wastewater.

Use the space on the next page. Continue on additional sheets, if necessary.

DEP Form 62.620 910(5) 2CS..2 Y:\GDP- I4\DU1KE\CCC\SCA\FDEP6200 ) 'CS DOCX-11725 14 EITecOe N.,en-ber '9. 194.

IV B. Contd. Facility I.D. Number: FLOO00159 (I) (2) Operation(s) Contributing Flow (3) Treatment Outfall No. (a) Operation (list) (b) Avg. Flow (a) Description (b) List Code from (List) & Units Table 2CS- I D-XXX Cooling tower discharge 27.4 MGD Mixing, discharge to surface water 1-0 4-A Flow augmentation to reduce chlorides 54.9 MGD Flow augmentation to reduce chlorides 1-0 concentrations concentrations I-XXI Internal Outfall CCC Blowdown #1 13.7 MGD Disinfection 2-F Dechlorination 2-E I-XX2 Internal Outfall CCC Blowdown #2 13.7 MGD Disinfection 2-F Dechlorination 2-E DEPFomi61-6,20910(5) 2CS-3 2CS-3 2CSDOCX-)172514 Y.\GDP-1I4\DUKE\CCC\SCA\FDEP"'20(1I Effect.,e No, emb,r 29. 1-)94

IV Contd. Facility I.D. Number: FL0000159 C. Except for stoni runoff, leaks, or spills, are any of the discharges described in Items Il-A or B intermittent or seasonal?

ED Yes (complete the following table) E No (go to D. below)

(3) Frcquency (4) Flow (I) Outfall (2)Operation(s) (a) Days per (b) Months (a) Flow Rate (b) Total Volume No. (List) Contributing Flow(Lis) Week per Yr. (in ngd) (specify with units) (c) Duration (specify avg.) (speciav Long Temr Ag Nlax Dail. Long Tem, Ag Ma\ Dad) (in days)

I I ~avg.) III

+ + 4 4- * + +

D. Describe practices to be followed to ensure adequate wastewater treatment during emergencies such as power loss and equipment failures causing shutdown of pollution abatement equipment of the proposed/permitted facilities.

Power generating facilities are interconnected to the electrical grid, and, therefore have a reliable backup power supply. However, in the unlikely event of complete power loss, the cooling tower circulating water pumps for internal Outfalls I-XX1 and I-XX2 would cease to operate, thereby preventing a discharge to Outfall D-XXX.

E. List the method(s) and location(s) of flow measurement.

Flow from Internal Outfalls I-XXI and I-XX2 will be measured continuously via bubble-tube type flow meters, ultrasonic level indicator/weir, or equivalent at the blowdown flow point from each cooling tower.

V PRODUCTION A. Does an effluent guideline limitation promulgated by EPA under Section 304 of the Clean Water Act apply to your facility?

E Yes (complete Item V-B) [] No (go to Section VI)

B. Are the limitations in the applicable guideline expressed in terms of production (or other measure of operation)?

El Yes (complete Item V-C) Z No (go to Section VI)

C. If you answered "yes" to Item V-B, list the quantity which represents an actual measurement of your level of production, expressed in the terms and units used in the applicable effluent guideline, and indicate the affected outfalls.

1. AVERAGE DAILY PRODUCTION 2. Affected Outfalls

a. Quantity per Day b. Units of Measure c. Operation. Product. Materials, Etc. (specify) (list outfall nos.)

N/A DEPIoF- 6,2-62091f)5S) 2CS-4 ).\GDP-14\OLIKE\CCC\SCA\FDEPW'21)(

I2CS DOCX-o72514 WIen,ýoN., e-hbe21..11194

Facility I.D. Number: FL0000159 VI IMPROVEMENTS A. Are you now required by any Federal, State or local authority to meet any implementation schedule for the construction, upgrading or operation of wastewater treatment equipment or practices or any other environmental programs which may affect the discharges described in this application? This includes, but is not limited to, permit conditions, administrative or enforcement order, enforcement compliance schedule letter, stipulations, court orders, and grant or loan conditions.

E Yes (complete the following table) 0 No (go to Item VI-B)

I. Identification of Condition, 2. Affected Outfalls 3. Brief Description 4. Final Compliance Date Agreement, Etc a. No. b. Source of Discharge of Project a. Required B. Projected See Attachment 2 B. OPTIONAL: You may attach additional sheets describing any additional water pollution control programs (or other environmental projects which may affect your discharges) you now have underway or which you plan. Indicate whether each program is now underway or planned, and indicate your actual or planned schedules for construction.

L] Mark "X" if description of additional control programs is attached.

VII INTAKE AND EFFLUENT CHARACTERISTICS A, B, & C: See instructions before proceeding--Complete one set of tables for each outfall -- Annotate the outfall number in the space provided. NOTE: Tables VII-A, VII-B, and VII-C are included on separate sheets number VII-I through VII-9.

See Attachment 2 for narrative on intake and effluent characteristics and Attachment 3 for Antidegradation Demonstration.

D. Use the space below to list any of the pollutants listed in Table 2CS-3 of the instructions, which you know or have reason to believe is discharged or may be discharged from any outfall. For every pollutant you list, briefly describe the reasons you believe it to be present and report any analytical data in your possession.

1. Pollutant 2. Source 1. Pollutant 2. Source N/A DEPFormA2-620)911)15) 2CS-5 Y \GDP-I4\DUKE\CCC\SCA\FDEP62(.2)(

2CSDOCX-.-172S14 ElfmcdreN., enbe, 29. 1994

Facility I.D. Number: FL0000159 VIII POTENTIAL DISCHARGES NOT COVERED BY ANALYSIS Is any pollutant listed in Item VII-C a substance or a component of a substance which you currently use or manufacture as an intermediate or final product or by-product?

DYES (list all such pollutants below) E NO (go to IX)

IX BIOLOGICAL TOXICITY TESTING DATA Do you have any knowledge or reason to believe that any biological test for acute or chronic toxicity has been made on any of your discharges or on a receiving water in relation to your discharge within the last 3 years?

M YES (identify the test(s) and describe their purposes below) D NO (go to Section X)

Acute and/or chronic WET testing performed in conjunction with treatment of the Unit 3 heat decay system using Betz CT 1300 Testing performed by Hydrosphere Research, 11842 Research Circle, Alachua, Florida 32615.

FL-NELAP Cert. # EE82295 In addition, chronic WET testing has been performed on cooling tower blowdown for Units 4 and 5 (NPDES No. FL0036366)

X CONTRACT ANALYSIS INFORMATION Were any of the analyses reported in Item VII performed by a contract laboratory or consulting firm?

0 YES (list the name, address, telephone number, and certification number of, and pollutants analyzed by each such laboratory or firm below) El NO (go to Section XI)

A. Name B. Address C. Telephone D. Pollutants Analyzed (list)

(area code & no.)

Pace Analytical Services, Inc. 8 East Tower Circle, (386) 672 5668 All parameters (excluding fecal coliform, FL DOH No E83079 Ormond Beach, FL 32174 low-level mercury, and rads.)

Pace Analytical Services, Inc. 1209 Tech Blvd., Suite 207 627-0003 Fecal coliform FL DOH No. E84973 Tampa, FL 33619 Pace Analytical Services, Inc. 1638 Roseytown Road, Suite 2-3-4 FL DOH No. E87683 Greensburg, PA 15601 (724) 850-5600 Gross alpha, gross beta, Total Ra and Ra 226 Pace Analytical Services, Inc. 1241 Bellevue Street, Suite 9 920) 469-2436 Low-level mercury FL DOH No. E87948 Green Bay, WI 54302 DEPForm62-620 910(5) 2CS-6 ZCSDOCN-072514I

)'\GDP- I 4\DLIKE\CCC\SCA\FDEP620(1 Effeclie No, ember -9. 1994

Facility I.D. Number: FL0000159 XI CONNECTION TO REGIONAL POTW A. Indicate the relationship between this project and area regional planning for wastewater treatment. List steps to be taken for this industrial wastewater facility to become part of an area-wide wastewater treatment system.

NA XII-A CERTIFICATIONS FOR NEW OR MODIFIED FACILITIES This is to certify the engineering features of this, pollution control project have been designed by me and found to be in conformity with sound engineering principles, applicable to the treatment and disposal of pollutants characterized in the permit application. There is reasonable assurance, in my professional judgment, that the pollution control facilities, when properly maintained and operated, will discharge an effluent that complies with all applicable statutes of the State of Florida anlikqrlAd iqf the Department. It is also agreed that the undersigned, if authorized by the owner, will furnish the appl"Vs*seo e '* for the proper maintenance and operation of the pollution control facilities and, if applicable,

1. ý- , , ,-#

'47 %ý- - * ý-M 0 - Environmental Consulting & Technology. Inc.

Company Name Address 3701 Northwest.98t4 Street Gainesville. Florida 32606 Florida Registration No.: 30688 Telephone No:: (352) 332 - 0444 Date August 1, 2014 I certify under penalty of law that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system or those persons directly responsible for gathering the information, the information, submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that.there are significant penalties for submitting false information, including the possibility of fine and imprisonment for knowing violations.

R- Alexander Glenn, State President Florida Name & Official Title (Please type or print) Signature (727) 820- 5587 No. Dt S Telephone No. (area code & No.) Date Signed DEP F"Tr.6.2-6220910(5) 2CS-7 DCI' 6Z~20 91(3)

%,MP CS.7Y 14 UKVCCC1SCAf1CWEI62V< S VOCX 1_2C -'17Ml I Eff.u.c N-=tx, 21. 1IY4

XII-B CERTIFICATIONS FOR PERMIT RENEWALS This is to certify the engineering features of this pollution control project have been examined by me and found to be in conformity with sound engineering principles, applicable to the treatment and disposal of pollutants characterized in the permit application. There is reasonable assurance, in my professional judgment, that the pollution control facilities, when properly maintained and operated, will discharge an effluent that complies with all applicable statutes of the State of Florida and the rules of the Department.

Not applicable.

Signature Company Name Address Name (please type)

(Affix Seal) Florida Registration No.:

Telephone No::

Date I certify under penalty of law that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fine and imprisonment for knowing violations.

Name & Official Title (Please type or print) Signature Telephone No. (area code & No.) Date Signed DEPForm62-620 9100() 2CS-8 Y:\GDP-14\DLIKE\CCC\SCA\FDEP62Oi)

I )CS DOCX-t)72(, 4 Elfooti-eNoenh,er29. 11194

Facilit, ID. Number: FL0000159 Outfall No. Intake PLEASE PRINT OR TYPE ONLY: You nay report some or all of this information on separate sheets instead of completing these pages. Use the same format.

SEE INSTRUCTIONS.

VII. INTAKE AND EFFLUENT CHARACTERISTICS PART A - You must orovide the results ofat least one analysis for every nollutant in this table. Comnlete one table for each outfall. See instructions for additional details.

I 1 3 Units 4 Intake toptional)

Pollutant dNo o a Concention b Mass Asa A Value b No or Anal,'ss _ _ _2) b_Mas I Toerm Mass Anal%scs aQhbonssEsssmtll <2 nmg/L O"ýp~n Drea'd M b Chemical O,-ge[

Demand (COD) c Total Organic 82 120 f m sglL ng/L Carbon I-OC'i d Total Suspended 1'4 S.9/L Solids JTSS) 1 c Toda Ninogen (asN) _

f Tul Phhosp- (as 1s)4 LilI

____ I(H(I 61II,

<o1)12 gAnona A as N) h Flos - acrual or Value Value eroieloed i Flo -design is pH Min 7 52 49 STANDARD UNITS

_______I I Mr 8 50 1Min 1ýý M&A ' _ _ _ L________

I 2

PART B - Mark "X" in column 2a for each potIutant you know or have reason aobelieve is present. Mark "X" in column 2b for each poltutant you believe to be absent. tfyou mark column a for any pollttant which is limited either directly. or indirectty but espressly, in an effluent limitations guideline, you must provide the results ofat least one analysis for that pollutant. For other pollutants for which you mark column 2a. you must provide quantitative data or an explanation of their presence in your discharge Complete one table for each outfall. See the instructons for additonal details and requirements 2 Mark "X" 3 E'fluent 4 Unit, 5 tota.ike.OlOtrna I Poltutant and CAS a be- b be a Maiosuo Dall b5 MSat 3.da, Value c Long Tonn Ag d No or a Cono b Mass a Long Tmn1Avg b No of No (lfa\ ilabtc) lios'd licted Valu e (if o\-ila.obt ValutLiflaailable) Anatbses Value Analyses Pretsre absent (1 Cone I2) Mass (t) Coic Q2) Mass ItConc I (2t Mass (I iCone (2) Mass a Bromide 124949-67-9) 0 0 374 t mg/L b Chlorine.

Totat Restdual E < . I mL c Color 0 0 45 u I PCU d Fecal Coliform 0 0 <2 CFU/100 mL c Fluoride

,1,698448-m81)- < 50 I mg/L f Nmtatn-Nitritl LasNI 0 El[ 0900 0.313 4 mg/L VII-I Y GI)I'-I-4DUKcF CCcOSCAA'I'I;I't.2)II II 2CS 0 tICX--I)723'5I DER Form 62-620.910(5t2CS. Effective November 29. 1994

Item VII-B Contd. Facility ID. Number FL0000159 Outfall No. Intake 2 Mark "" 3 Eftouent 4 Units 5 Intake (optional)

I Pollutantand CAS a he- b be- a Maomuom Dail, Value b Mao 30-da, Value c Long Term A, g Value d No of a Cone b Mass a Long Term A, g Value b No of No (if a-ailablo) Iheod Iherd (if asailablc) ifaailablo) Anal, ns Anal., os present absent (I)Cone 12) Mass (((Cone (2) Mass (I) Cooe (2Mass (]) Cone (2) Mass j Nittogon. Total Onganie(asN) 0 E" 0.74 t mg/L h Oiland grease ] < 1.3 t mg/L i Phosphonts. Total 0 0 0i 0.061 4 tg/L (as P) (7723-144))

(1 Alpha. Total 0 ] 3 72 (1!- I 041 I pCi/L (2) Beta. Total 0 El I pCi/L (3) Radium. Total 0 El 0 I 15) 1 pCi/L (4) Radium 226. Total [ 624 095 I pCi/L 0 "624) pi/

k Sulfate (a. SO')

(1401o-79-8) 0 1,600 I mg/L I Sulfide lasSl 0 0 < 1.0 1 mg/L I m g !L 2 k5- 5 -3(

S14 0 El < 0

" Surfacants IQ El 0.38 I mg/L o Alatinunt. Total 17429-90-51 0 [ 0.094 I) I mg/L p Barium. Total

,7440-39-3) []

0] 0.012 I mg/L q Boron. Total (7440-42-M) 0 0l 3.3 I mng/L n Cohalt. Total (7440-48-4) 02 El < 0.005 I mg/L s]Ito. Total (7439-894r1 0l 0 0.16 I mg/L Maagnesium. Total (7439-95-4) 03 EL 898.0 I mg/L SMolN.hbdcnum. Total 17439.98-7) 0 E] 0.0074 (I) I mg/L

% M an gan ese. Total 00 2 -.

743-9-5<0.025 te Tin. Total (744. .31-1 [ Li < 0.025 I mg/L x7Titanium. Total 7440l-32-61 0 El < 0.025 I mg/L VII-2 "lDPl. 14;DUKPCCCISCAWFDEIM42U(

YV t _CS Iu ýCX-072514 DER Form 62-620.91 (5I2CS, Effective November 20. 1994

Facility ID. Number: FL0000159 Outfall No. Intake PART C - If you are a primary industry and this outfall contains process wsastewater, refer to Table 2c-2 in the instructions to determone which of the GC/MS fractions you must test for. Mark "X" in column 2a for alt GC/MS fractions that apply to your industry and for ALL toxic metals, cyaoides, and total phenols If you are not required to mark column 2a (secondary industries, non-process wastewater outfalls, and non-required GC/NTSfractions), mark "X" in column 2b for each pollutant you know or have reason to believe is present. Mark "X" in column 2c for each pollutant you believe is absent. If you mark column 2a for any pollutant, you must provide the results of at least one analysis for that pollutant. If you mark column 2b for any pollutant, you must provide the results of at least one anlysis for that pollumat if you know or have reason to believe it will be discharged in concentrations of 10 ppb or greater. If you mark column 2b for acrolein. acrylonitrile, 2,4,dinitrophenol, or 2-methyl-4.6 dinitrophenol, you must provide the results of at least one analysis for each of these pollutants which you know or haoe reason to believe that you discharge in concentrations of 100 ppb or greater. Otherwise, for pollutants for swhichyou mark column2b, You must either submit at least one analysis or briefly describe the reasons the pollutant is expected to be discharged. Note that there are 7 pages to this part: please review each carefully. Complete one table lall 7 pages) for each outfall. See instructions for additionat details and requirements.

2 Mark"X" 3 Effiuet 4 Units 5 Intakcoptional)

I Pollutantand CAS a hb he- T he- a Maximum DailyValue b Mal 311-dav Value c LongTenmAsg Value d No of a Cone b Mass a LongTermAvg Valun b No of No ifasailablel renting osend bstiierd "lla ailahlO ifaahle Astutseno Anal sns required J j sll~one ([) Cone l2ihus (tass IlCene (2, Il)Cone l(2tMas M ETA LS . C YA N IDE:AAN N,

Dts U' T . LPNE n OLS . o,g. . . :... . . . . . ,4 s:..

.v . . :- : ". ,,- . -. " . :" . : * :: * * "::2v2 . ;lO " ':, "

I Aoiimony.Total (7440i-36-4i) 0 0 s5.0 I ug/L 2M Arsenic.Tout<

(7723.14-0) 0 0 0 <5.0 I ag/L 3M BtsoIllium.Total (7440-41 -70 0 I < 0.25 1 ugn.

4M Cadmium.Total (7440-13-9) <0.50 I ug/L 5W Chromium.Total I oWL (744i1-47-3) 1 El < 2.5 6M Copper. Total (74405-51l) 0 046 I gL 7M Lead. Total (7439-92-1) 0 0 0 <2.5 I ug/L IMMhercur'. Total (7439-97-r.) 0 0 0 0.000911 1 ug/L 9hMNickel.Totat (7441-2-0) 0 <2.5 ug/L

'IM Selcnium.Total 17782-49-2) < 7.5 1 ue/L (IiM Silter. Total (74-4l-22-4) 0 0 0 <0.25 I ug/L 12M Thallium. Total t74410-28-4) 0 0 0 < 2.5 I ug/L 13MIZinc.Total 1744"i-6,6-6t 0 0 0 < 10.0 1 ug/L 14MCyanide.Total (57-12-5) ED 0] [ < 50 I ug/L 15M Phenols.Total t < 50 ug/L chlorodibenzo-P-Diaoxin -

11117(1-1121-6 r o o o ____i ___ __ ___ __ W IV Acrolnin r i-[ ] [ <u I. _ 1 u__

(117-02-8) b 0 2V Acr,'lonitrile (107-0."h [] 11 1 < ,. o ./*C Vll-3 Y 61)W.IIDJKI CCC SCAt IITI:k2vtI (I2CS t*X '72514 DER Form 62-620.910(5)2CS, Effective November 29.1994

Facility ID. Number: FL0000159 Outfall No. Intake 2I Mark X 3 E<luent 4 Unts5 I 5 ntake (optional)

I Ibb- I JI I PolilwantandCAS a o- aMits DadsýValuc I Ma- 111-da,Valuo c LongTenn Ag Vao8 d No of oCooc b Mass aLong Tenn A\, Value No of No (ofa-aIable) I sngo I ýhesd hioned ifaailable) (,fanailabl) I Analyses Analyses roqoisod p .

a..... on )2)Mass 1Cone Con I Mass 1 Con 12) M(ss

.... 2) Mass CC ýLFRAMTIN &VOI2ATJL1EPCMPOUýNP.(be!

3V1-43-2)

(7 Bentoene ] [] [ 0.50 1 .,/L 4V Bis (Chlorosthyh 1 0 Ether(542-8-1) 5V BrooorZ<00l (75-25-2) 0 0 Li <050 I ugL 6V Carbon Telsashlorid<

(56-23-5) 0 E Li < O t ug/L 7V Chlorobencon 0.40 (10Ig-90-7) < I ug/L 8V Chlorodi-bronsoelhsan (1124-8-1) i < 0.25 I ug/L 9V ChlosoethanoW (744)0)3) < 0 61 ugL I41V2.Chloro-othylvinIl Ether (I 0-75-8 1 0 0 EL < 5.0 I ug/L (IIIV Chlororoonn (07-8&3) 0 <0.50ug/L 12V Diehloso-bronomeshanc (75-24-4) 0 0 R < 0.31 I ugoL 13V Diehloro- 7 dluoramoetne (75- 1-8) 0 0 i < 0.50 1 ug/L 14V I.I-Dichloromthan0 05L I 0 M l I0.5 (75-34-3) 15V 1.2-Dichloroelhane (1{11716-2) < 0.50 u/L (16V 00t<.0enW <. 0-5Di0hloso (75-35-4) 1 ug/L 17V I.2.-Dichkolonqo*o

( 7)6,07.5) 0 0 Li < 0.50 I OWLt ISV .- D5 op < 0.50 I ugWL 1

(542-7_ý) M 0 < 0 50 19V Ethylbenzeno (100-41-4) 0 0 [] <0.50 I ugWL 2))V Methyl Bromide (74-83-9) El 10 50 I ug/L 21 V MethyI Chloride (74-87-3) 0 0 J < 0.50 I ug/L 22V Mclhylene Chloride (74-98-2) 0 El < 2.5 I ug/L 23V I.I.2.2-Totra-chlorOclhane (79-34-51) 0 Li <0.17 I ugWL 24V Teraohl~osochylene (127-18-4) 0 0 L < 0.50 I ug/L VII-4 1: CCC SCAI'j :j)1,21)i)2LS I.N CX-072 14 Y'GIP- 14,1 K DER Form 62-620.910(5)2CS, Effectine November 29. 1994

Facility ID. Number: FL000159 Outfall No. Intake 2 Mark "X" 3 Effuent 4 Unns 5 Iroake optional)

I Pollutant and CAS a b be- u ho- a Maximum Daily Value I Ma, 30-day Value a Long fenn Asg VaLe d No of a Cone h Mans a Long Teni An g Value I No of No (ifarailable) testing liered hrved (ifasailable) (ifarailablel Aaal'ses Analyses required prcscn absent

(((Cone (2) M onCe 1(2)MPs (((Conc Mass (Cone (2(Mass

((22 s ZCCNMS FRACTION -,VOL FTILE COl FOUNDStol f ebifs' 2d) __

25V Toluene (10(8-88-3) 0 0 U <050 1 ug/L 26V 1.2-Trans-Diou*n*lnt(*I,-MS()

27V l.I 2-Tritm* r 0 0 E < 0.50 I 00/1 (71-556a) 0 0 U < 0.50 I ug/L 28V l.1.2-Trub-ftoc (91 ý-) 0 < 0.50 I ugIL 29V Triehlornelhvlene (794 1-6) Z0 El < 0.50 ug/L 30(V Trichloro-fluoreon ne (75-69-4) 0 0 U <0 66 1 ug[L 31V Vinyl 174)1-41 .] Chlodgde [] [] 0.53 ] ulg[L IA 2-Chlurophennl 0 0 U <78I a/

(95-57-8) < 0.78 1 ug[L 2A 2.4-Diehlorophennl (121-113-2) 0 2] 0 < 0.64 1 ug/L 3A 2.4-Dimethrlphenol (005-67-9) 0 U < 1.8 I ug/L 4A 4.6-Dioiiro-O-Cresol (534-53-1h 0 0 U < 1.5 1 ug/L 5A 2.4-Diniropbenol < 1.0 I ug/L (51-20-5I 0 0 nA 2-Nitrophenol 88_-75-5,) 0 0 <0 93 1 ug[L 7AI(((-012-7) 4-Nitrophenol 0] 0] [ < 1.2 8A P-Chlor.-M-Cresol (50-5(7) 0 0 U < 0.71 1 ug/L 9A Penlachlorophenol (97-87-S5 0 03 El < 0.76 1 ug/L (IiA Phenol (8(18-95-2) 0 0 U <0.62 I A 2.4.5-Triehloro-phenol (88-06-2) 0 0 U < 0.79 I ug/L l B Aeeoaphbheoe (63-32-9( ] [ T u

] <0018

<0 1gI u/

2B Acenaphtylene < I ug (208-96'-8) ] [ ] <007I u/

3B Anthracene (120-12-7) [] -1 < 0.018 1 ugfL 4B B n/idine (924(7-5) 0 t <088 I ug/L V11-5 Y\'II.III'-I 1041: CCC NCA<I'll',,2ntI j2C.'r IrCX-072514 DER Form 62-620.<l0(5)2CS, Effective November 29. 1994

Facility ID. Number: FLOO00159 Outfall No. Intake 2 Mark X" 3 Effuc.n 4 Units 5 Intake(optional)

I Pollusanrid CAS 6 be-b c be- a NMaximunr Dail, Value b Max 30(-dai"Value c Long Tonn Ag Value d No of a Cone b Mass Long Tenm Asg Value b No of No iifsa-lablo testing licrcd licncd lifa ailablc) hifau abl)o Anal., sos Arin sOs required present absent (I)Corc (25 Mass H]sConlc 2) Mass 1i Colc (2) Mass () Cone (2) Mass SB Benz.o(,) Anthracene0 Bo (56-55-3) 6B Bcnz.o n)yP, yrenc El

[r <0.013 I ug/L (10-32-8) < 0.021 1 u/L 7B 3.4-BIacan.,- sd 0-99L-2) 0 03 El <0.016 1 ug/L 8B Benzo (ghi) Pen'eIne (191-24-2) 9B [c*nzo (k) FhKrvhe( 0 0 El <0.016 I ug/L 9 n5)- s0 0 0 E < 0.022 1 ug/L IO(BBis (2g )< I ug/L Melhane ( 11-91-1) 01El 3.0

<3.

EIB Bis (2-,heloruehls5 ther I01-44-4) 0 0 El <0.86 l ug/L 12B Bus (24nl2n*wpspi Ether (102-60-I ) 0 El < 0.84 I ug/L 13B Bis 2-155'1hea51) [

Phhlaulasc0 17-81-757I <0.92 14B 4-Broarophlsnyl Phcnyl Ethor (SIl-55-3) 0 0 < 0 77 1 ug/L 15B Buty BcnIsl Phthalate (84-68-7) 0 0 El <0.83 I ug[L 16B 2-Chlosonalidleu (91.-07) 0 0 El < 0.92 I uagL 17B 4-Chlomophsnyl 0 0 <0.72 PhcnNI Ethlr 57555-72-3) I uo/L 5I5BChrscus1n

,218-Mt-9) 0 0 El <0.0(5 I ug/L 59B Dibosnlo 500.Ih Anthracene (3.7-.-3) 0 0 El <0.010 I ug/i 20B 1.2-D lukhloreolru 0-[ L < 0.78 1 ug/L 21ts 1624c oEb.l (541-73-1 0 <0.87 5 uOWL 2-B 1.4-Dichlornlien-ns 55i.4e [] 65 L <0088 0 1 u/I 23B 33-D"ichasetnd

-- 0] El <0 79 5 uag/

24B Dicdr'l Phthalate

(&-.0,(621 0 0 El < 0.59 I ug/L 25B DimcnhylPhlhalate (131-11-3))] [] [ < 0.73 1 ug/L 260 Di-N-Butys Phalahle (84-74-2) I] [] Li < 0.47 1 ugWL 27B 2.4-Dinitrotolucnc 1021-14-21 0 0 El <0.615 ugWL 20B 2.6-Diniirotolacnc (W ((20u-2) 0 0 El < 0.73 1 ugWL VII-6 Y 'GDP-.41DU5JKF CCC.SCA1[FDEP,2o( I _2CSID2CX--072514 DER Form 62-620.910(5)2CS, Effective November 29. 1994

Facility ID.Number: FL0000159 Outfall No. Intake 2 Mark "X" 3 Eflfuent 4 Units 5 Intake optitonal)

I Pollutant and CAS a p bo- c be- a Maxiumt Dailt Value b Max 31-day Value c Lang Tern Avg Value d No of a Cone b Mass a Long Term Aug Value b No of No (ifavailable) testing tieed littd (foatauablo) (if auoilablo) Anal, ses Atalyses required present absent litCons (21Mass 11) Ceoc 121Ma IllCone (2)Mass 298 Dt-N-Octvl PhIhalate (117-84-l 0 0 0 ug/L 308 12-D*lho*elhyIaaann tan4v'ooxll¢)l22.a7) ] 0 0 < 0 76 I ug/L 31B Fluoratnhenc (2n6-44-0) 0 < 0 t.012 I ug/L 32B Fluorene (86-73-7) <001 I I u/L 33B HIcxuhlerobnzene

'118-74-1) 0 0 0 < 0.92 I ug/L 34B H.oxtolsltrel2alks 35B H-xfl Itq (77-474) IItvalue 0 0 0 < 1.5 I ug/L 36B Hexaehloroethanre (07-72-1) 0 0 0 <0.82 I ug/L 37B Indono 11.2.3-tO 0 Pvrene(193-39-1) E ] < 0.018 1 ug/L 39B Isophoron0 (78-59-1l M El < 0 84 1 ug/L 39B Naplhtdleoec 19l-20-3) 0 0 0 <0.015 I ug/L 4t0B Nitrobnenoese

(,8-95-9) 0 0 l < 13 I ug/L 41 B N-NMsED su<11Ekrne (62-75-9) 0 0 0 < 1..

42B N-Nitrosodi-N-Prepvlamineiit2l-64-7) 0 0 0 < 1.1 I ug/IL 43B N-Nitro-sodiphenylantiee 1--StllO 0 0 0 <0.57 u 44B Phetanthrtne 185411-8) 0 0 <(1.016 I ug/L 49B Preenc 12'l-tol-l0l 0] 0 0.0097 I ug/L 46B 124-Trichkslonas, Ic 75h-89-9._

IP Aldrin (3-00-2) 2P -BHC(319-84-6)1 0 5 0 3P -BHC (319-85-7) 0 0 0 4P -BHC [] [] []

5P -BHC,(319-8,6-9) 0] [] [

VII-7 I 21) Ltt<

Y 'CDP-W4'DUSKEICCOSCAIFDEIt,2011 Icx-725 W DER Form 62-620 910(5)2CS, Effective November 29, 1994

Facility ID. Number: FL0000159 Outfall No. Intake 2 Mark X" 3 Effuent 4 Uoas 5 Intake (optional)

I Pollulanr and CAS a b be- c be- a Maomonn Daily Value b Mon 30-day Value c Long Term A%g Value d No of a Cone b Mass a Long Teem Ang Value b No of No (i available) tsing lieocd licoed if na'ilable) (ifanailable) Analoes AnaIl*os required present absent

'I)Cone (2) Macn 1) Cooe (2) Mass (1")Conc (2) Mann I Cooe (2) Mans P Chlordaoce(7-74-9) - El El 7P 4.4'-DDT (50-29-3 0 0 0 8P 4.4'.DDE (72-55-9) ] []

9P 4.4'-DDD (72-54-1) 0] E] 0 HIP DOildrino(,0-57-1) [ [ 0 II P -Eadosulfao u o 0

( I15-21-7) 12P -PEdonelfon 115-29-7) 13P Endosulfan Sullflc 1031-117-X5) 0l 0 0 14P Endnn i72-2n-81 o o o lIP Endein Adehyd, 0 (7421-92-41 loP Heplacbloe

( 76-14-K) cl cl E 17P HepwoehlorEpocde 11I124-57-3, El 01 0D IHPPCB-1242 (s34(,9- I) [ 0 E0 (19P PCB-1254 1,9*7-69,-1) El C] EI 20)PPCB-1221 (111114-2H-2) E 0 0E 21P PCB-1232 (11,4H,-5) 0 1 11 22P PCB-1249 (12,72-29-)6) E0 0 23P PCB-12611 24P PCB-I(Ih, (121,74-11-2) 25P Tocaphcne (X--01-35-21 E 0 0 VII-8 Y [1)['-141

)11KE'CCCSCAI )fP,42ur(I _2C ) CX--)72514 DER Form c2-h2.)1(H5)2CS. Effectice Nocember 29. 1914

Facility ID. Number: FL0000159 Outfall No. D-XXX PLEASE PRINT OR TYPE ONLY: You may report some or all of this information on separate sheets instead of completing these pages. Use the same format.

SEE INSTRUCTIONS.

VII. INTAKE AND EFFLUENT CHARACTERISTICS PART A - You must provide the results ofat least one analysis for every pollutant in this table. Complete one table for each outfall. See instructions for additional details.

I 1 3 Units 14 Intakemoptionah1 Pollutant ran D [mhmdKaf <2 d No of Anal.sesx a Concentration ing/l, J b Te 2 "Cn ass Analr ,

b Chemical Oygen 1)00004 1 mg/L Demand(COD)

. Total Organic b97 I mrg---

Carbon (TOCO d Total Suspended 28 67 I mg/L Solids (TSS) e TtdNm (mN) It15 g[L f TotalPheTpl (asP) 008 1 nIIn8L Aomeonra(as N) 002 1In/l h Flow -actual or Value Value 109 3 (Projected - see Value 82 3 (Projected see MGD Value projected Narrative Fi 41 Narratie Fig 3) i Flow - doin Value Value Value \Value j Speirc Cendcvio" Valho 38088 31 Valoe Value I umbos/cm Value k Temperature (winter) Value Value Value 'C Value I Temperature Isumnmer) Value 35 3 Value Valor 25 2 calculated C Value mn pit Mis 8 la7se Min ]7 STANDARD UNITS--

PART B - Mark "W' in column 2a for each polluiant you know or have reason to believe is present. Mark "X" in column 2b for each pollutant vou believe to be absent. Ifyou mark column 2a for any pollutant which is limited either directly, or indirectly but expressly, l an effluent limilations guideline, you must provide the results of at least one analysis for that pollutant. For other pollutanrs for which you mark column 2a. you must provide quantitative dara or an explanation ofrheir presence in your discharge Complete one table for each outfall See Ihe instructions for additonal details and requirements.

2 Mark "X" 3 Etflouni 4 Units 5 Intake option)'

I Pollulanl and CAS a be- b be a Maximum Daily b Max 3ntlay Value c Long Ter, Avg d No of a Conae Mass a Long Temi Avg b No of No tifasailable) lieoed lihcsd Value ofr a ilablec) Value (ifavailable) Analyses Volue Anal scs present absenl (1) Cone (2) Mass (I Cone (2) Mass (I1Core 2, Mass I) Cone 12) Mass a Bromide (24949-67-9) 0 0 40.60 I mg/L b Chlorine.

Total Residual 0 0 0.07 1 mg/L c Color 0 0 31.67 I PCU cal.Colifor67 CFU/100 r Ftuoride U(,tiI-4g-g) 0] 3.60 1 f(asN NilEate-Nitriro 0] 0 0.32 I mg/L.

VII-9 Y D['-i41DtIJKECCCSCAItDEPa,21I 2CXS teCX--I725 4 DER Form 62-620 Ql0(5)2CS, Effective November 29. 1094

Item VII-B Contd. Facility ID. Number FL0000159 Outfall No. D-XXX 2 Mark "X 3 Effnt 4 Units 5 lntaketoplional)

I PollumaoiandCAS a be- b be- a Maximum Daily Value b Max 30-day Value c Long Tero Asg Value d No or a Cone b Mass a LongTenm Aog Value I No of No (if-aailable) liesed lieoed if asadlable) Iifavailable) Analyses Analhses presens absenl 1I1Cone (2 Mass- (I) C... (2) Mass (1) Cone Mass IlICore (2lMass (2) g Nitrogen. Tolal Organic as N) 0.22 mg/L h Oti and grease 0 0.43 1 mg/L i Phosphorus. Tolal (as P) (7723-14-4) 005 1 mg/L

' .. I>. /ti+ **" _ _"__"

......... ......... . ........... 55..... . .

(I)Alpha. Total 0 0 3.51 I pCiIL

12) Beta. Total 0 0 73.33 I pCi/L (3) Radium. Total 0 0 1.45 I pCI/L (4) Radium 226. Total 0 0 0.97 I pCi/L k Sulfate (as SO,) Z 186664 I mg/L 114808-79-81 I Sulfide las S) 0 0 <0.70 I mg/L as Solfito (asSO))

114265-15-3") ED L <7.33 I mg/L n Surfataunis z 0 0.32 I mg/L o Aluminum. Tolal (7429-90-5) 0 0] 0.08 I mg/L p Bronum. Tolal (7440-39-3) [] Li 001 I mg/L q Boron. Total (7440-42.8) [ Li 222 I mg/L

' Cobalt. Towl 174410-48-41) 0 0l 0.01 I mg/L s lron. Total (7439-89-6) 0 0 0 16 I mg/L I Maagnesium. Total (7439-95-4) 0 0 1065.32 u Molvbdenum. Total (7439-98-7) 0 0 0.03 1 mg/L v Mangaeses. Totala0 I og/.

7439-96-5) 0 0 0.01m to Tin. Toal (7441)-31-51 02 0l 0.58 I nng/L x Tilaniuni. Total 74411-32-6) 0 0 <0.02 I mg/L V1I-1O CCCSCA IDI':L*,20t Y 'GI)P-14.)OlUKI:' I _2CSINICJX-1725I DER Form 62-620.910(5)2CS. Effective November 29, 1994

Facility ID. Number: FL0000159 Outfall No. D-XXX PART C - If you are a primary industry and this outfall contains process wastewater. refer to Table 2c-2 in the instructions to determine which of the GC/ItS fractions you must test for. Mtark"N" colucunm 2a for all GU/MS fractions that apply to your industry and for ALL toxic metals. cyanides. and total phenols. Ifyou we not required to mark column 2a (secondary industries. non-process wasrewater ouffalls, and non-required GCL/NSfractions), mark "X" in column 2b for each pollutant you know or have reason to believe is present. Mark "X" in coluom 2c for each pollotant you believe is absent Ifyou mark column 2a for any polluant.

you must provide the results of at least one analysis for thatpollutant. If you mark column 2b for any pollutant. you must provide the results of at least one anlysis for that pollumat if you know or have reason to belteve it will be discharged in concentrations of 10 ppb or greater If you mark column 2b for acrolein, acrylonitrile, 24.dinirrophenol. or 2-methyl-4,6 drnitrophenol. you must provide the results of at least one analysis for each of these pollutants which you know or have reason to believe that you discharge in concentrations of 100 ppb or greater. Otherswise. for pollutants for which you mark column2b. you must etther submit at least one analysis or bnefly describe the reasons the pollutant is expected to be discharged. Note thatthereare 7 pages to this part: please review each carefultly. Complete one table (all 7 pages) for each outfatl. See instructions for additional detatls and requrremests.

2 Mark "N" 3 Effucnt 4 Units 5 Intake (optional)

I Pollutantand CAN No (if aailable) a tasting he lioed e

liusud MaximunDal Van b Mnt-d Vatue a LongTermAvg Value (ifasailablel (ifasailablel d No of Anal, a Cone fI b Mass LongTermAvg Value b No of Aalyses requir penn nt absent t 1) C_

t,Cona t2ttulan UlCona - I,121 las J i

,) .... Il

_ _ ]

j....

Starr _on_____, ,__ __,__°_

IM Antimony.Total (744o1-3W- ))0 0 0 <3.33 I pg/L 2M Arsenni.Total (7723-14-10) [ 0 0 <3.33 I pg/L 3M BursIlium.Total 17440-4i-7) ED 23 0 <0.17 I pg/L 4M Cadmium.Total 17441-43-9) 0 0 0 <0.33 I pg/L 5M Chromium. Total 0 0 0 <167 1744i7T)7-3< I pgIL Copper.ntal t74.roppeiotl 6Mi (744,-0-Mi-)3.71 0] 0] 0 3.07 I pg/L Pf 7M Lead.Total 0 0 0 <1,67 I (7439-92-I1 8M Mercut*. Total (7439-97-6) 0 0 0 0.0012 1 pgL IM Nickel.Total

)

(744t0-n2-024 0 0 <1.67 1 pg/L tI'M Selcnium.Total 17782-49-2) 0 0 0 <5.00 1 ug/L I IM Silver. Total i7440-22.4) 0 0 0 <0.17 1 vg/L 12NMThallium. Total (7440-2-" 0 03 1.67

<tg/L 13MZinc.Total (74401-66-6) 0 0 0 <6.67 I Pt/L 14MCsanide. Total I rg/L P/

(57-12-5) 0 11 0 <.4I 151 Phenols.Total 0 0 0 <3.34 I pg/L 2.3.7.8-Tecua-chtloro.dib-n-P-Dioxin (17641-111.6)

[]0 0-

,II7-o2-O) 2V Acrsylonitrile 1107 1)

[]

0 I o]

0

<6.88

<3.87 I pg/L VII-I I Y t < - 11.tUK CCCcSCAttID:t02<)2CSIA

'IDI-lPI it ICX--072t5 DER Form 62-620.910(5)2CS, Effective November 29, 1994

Facility ID. Number: FL0000159 Outfall No. D-XXX 2 Mark "X" 3 Effaclt 4 Unils i In ake (oplional)

I PollulanIand CAS a bba- eb-ho aMaxntoua Dail) Value b Ma\ 30-day,Voie e LongTen Aeg Valac d No of a Cernc b Mass a Long Tons,Ag Value I No of No tfaealablo nesting finevd licvd (itfavalalc) 1i. avaeilOb)l Ana'ses Anal, sos raqaired present abset_______________

G'CM YRA~rlo*..,3'OI

.,.t COMP1nOUNDS. ri¢ os - Ms ,), Con" (2...

. . core 2..Ma.s...."... . (2) Ma"s 3V Bonoene .

(71-43-2) 0 U 0.37/L 4V Bis tChlorometh'l) Ether (542-88-1) Z E0 5+ Bromooforun Eg/I. I (75-25-2) <0.97g/L 6V Carbon Teclrahloride Eag0I4 I (56-23-5 <0.41)g/L 7V Chlooebenze0n I1,-8.90-7) 0 El 0.28 1 HgL 8V Chlorodi-bromosmelhane0124-8-1) 0 <0 22g/L 9V Chlooelharge (74-00-3) <0 54 /l (oV2-Chloro-ethyl)s-81 I pg/L Etn1t-580 0 U <3.46 PgI 11V Chloroforn <g/

(67-86-3) 12V Dichloro- 0 0 U <0.38 pg/LI bromomnethane(75-24-4) 0 0 U <0.24 I Pg/L 13V Dichloro- pg/I dith-uetor , (-75-71-8) 0 <0.58 g/L Z (g/I.

14V I.I-Dichloromthane (75-34-3) <0.37g/L 15V 1.2-Dichloroethanc 037

)t)7-06-2) ED E] E] I ag/L 16V 1.1-Dichloothko 0lene <0.3 (7-35-4) z E 11 .g/L 17V .L,2-D~d~kn, 1o, 0 0 U <0.35 i1 g/I 18V 1.3-Dichlrop rie

U 0 02-7: <0 38 I pg/L I9V Ethylbcnecnc 4

(1)l0.414) 0 U <0.38 1 Pg[L 200VMoth5* Bromitde <0 74_83-9) 0 0 El Ug/, .53 21V Meth, IChloride (74-87-3) <0 49 1 L 22V Methilene Chloride (74-98-2) < 1.71 ] igfb 23V (.I .2-Ttrt-ehlornothast (79-34-5) 0S <0 Pg/L 24V Tetrachloroclhy lene 1127-18-41 I pg/I.

VII-12 1DIDI2K

<<C1 [1)1,2f1"i 2,CS[n ICX--072314 SCAFI<

DER Form 62-620.910(5)2CS. Effective Nooember 20. 1994

Facility ID. Number: FL0000159 Outfall No. D-X,'X 2 Mark "X" 3 EIThetn 4 Units 5 Intake optioal)

I PollataistandCAS a 1be- e- a MtaxitnastDaila Valee b Maix tIn-dasVelon LangTenoAvg Values No or aCo b Mann a Long Teno A, g Valso b No oP No (iloilablot tossing lic ed lieted tiatailablel ifasailablex Analyses Analss neqetned present absent I 1 ___ JICons 2 Mann ilCene 121Moss l))Cone 12tlss G21Mass [

CC/MS FRA(frIONI;.VOLATILE-COMPOUNDJ *nohead .. .."... . .. . . 4924,0, 2 .2. t >** . ,

2V Tlaent11o8-88-31 0 0 El 0 37 I pg/IL 26V 1.2-Trans-Dith ,bnelnlaset05lr.,-5l 0 0 E <043 I g/IL 27V I. 2-Tndikwuclonc (71-55-C, 0 0 El <0.36 I pg/L 28V I.1.2-Tlsksnoearnr I7hxet) 0 0s E <0.41 I g/IL 29V Trichlnoecthylene (79,, 1-6) 0 0 E <0.37 1 pg/L 30V Trichloro- 0 fluoromethane (75--69-4 0 0 El <2.51 31V Vinyl Chloride (754114) [] [ ] <1.48 9*/t, IA 2-Chlorophenol (95-57-81 0 0 El 0

<0.85 pg/L 2A 2.4-Dishlonophenol (12,t-B3-2) 0 D E C1 -g/e

<0.70 3A 2.4-Dimethylphenol <I 3 I pg/I (1115-67-9) 0 0 El 4A 4.(-Dtnitro-O-Crncsol <.00 I (534-53-I) 0 E 2 pg/L 5A 2.4-Dinitrophenol 151-21-I 0 0 El <6 20 I pg/L

A 2-Nitrophenol 88-75-5) 0 005 1 gL 7A 4-Nitroplhenol (l100-02-7) <5.8 I pg/L 8A P-Chloro-M-Cresol 059-50l-7) 0 0 1 I ag 9A Pentachloronphenlo (87-.80*5) 0 El <1.51 I pg/L.

]itA Phenol lltt-95-2) 0 0 El <075 I pg/L ILA2.4.5-Tnichlorn-phenol(98-06-21 0 0 El <I 19 I pg/1 IB Aeeaaphthsne (63-32-91 0 0 El <0.35 I pg/L 2B Accnaphtylene El <0.34 I ag/L (20l-t81)(0)V 3B Anthlaccnc <035 (120-12-7) " El El -g[L 4B Bcneidine 92-87-s) 0 0 El <3392 I ag/L VII-13 I-GDP-StlltlDUKI'CCtC(CAIEItI:'ýlteIt2CSLaC<-0721514 DER Form 62-520.9101512CS, Effecttve Noventber 29, 1994

Facility ID. Number: FLOOOO 159 Outfall No. D-XXX 2 Mark "X" 3 Effuent 4 LlUis 5 Iniake(oplional)

I Polluan oand CAS a b be- c be- a Maximum Daily Value b Max 30-day Value c Long Term Ag Value d No of a Cono b Mss a Long Term Ag Value b No of No ,ifuuilabcli testing livsd lised (ilravsoblcI lirusorloblel Anolsnos Analyses required present absent rI)Cons (21Mo n I1iCone (2)Mass

) 11)Conc (2) Mss (I) Cone O2i Mass 5B Beo-o (o) Anthracene (56-55-3) 0 03 0 <0 34 I g/L 6B Ben.o (a) P, rena (50-32-.) 0 0 0 <0 35 I pg/L 7B 3.4-B1on-flooanhosne lV50-'- 0] 0 <034 I u1g/11 8B B&n.o (ghi) Pern enc (191-24-2) 0] 0 <0 34 ] g]L 0

9B Bosno (0) tRuorabenelnnneliT- 0 (F-9 o13 <3 0 35pg/L tauBB' (2-'ls*..soI Melhanc Il1-91-1)

I IlB Bin12-t'hhssrsi.othsI 0 0 0 <2.60 pg/L EIhrBI 4) 0 0 <1 57 I pg/L 12B Bis (24M-fp*teo Eser (ul2-41-lI 0) 0 E E <0.89 I pg/L 13B Bis(2-h1:'thih 1<1 I<

Plsihalato (I 17-01-7) F) 0 <1.61 14B 4-BsosopbsenyI 0 <L PhensI Ether (1) 1-55-3) z 3 <0.85g 15B Bsuts Benon1Plholase 0 0] <1 55 (94-68-7) 3 16,B 2-Chle-plult<095 I (91-5*-7) 0 I] 0pg9L 17B 4-Chlorophenl 0 <11 I1 PhensI Ether (711)5.72-3) lOB Chsrse e <034 (218-0-l9i 0-19B D0bcsnz (,,.h)

Anihaces (l53-70)-3) E 0 E <0 35 1 lg[L 2i0B 1.2-Dibdne n o/L p] sc <0.0 I 21B 13-Dichtlonlonsce 15-1-73-hli 0 0 <091 1 pg/L 2B .4-Dielilodbteitrope

('1-0-7( 0] []0 0 <0 92 ] g/L 23B 33-Dichlomrnsidrne 092-94-1i 0 0 0 <13.86 I "g/,

24B Diethyl Phthilale 0H4446-2) 0 0 0 <0.73 I 1 sg/L 25B Dinithyl Phohhloto (131-11-3) 0 0 0 <2 15 I pg/L 26B Di-N-Bussl Phlhalte<

(04-74-2) 0 0 0 <198 I pg/L 27B 2.4-Dtilrntonsiotuene gIL 1121-14-2) <0.74pg/L 28B 2'.-sDusisouolueiII h9l1s-2(l-2( 0] 0] [ l1 2/

VII-14 YV

'1)-1'. 4UK E"CCCcSCAIFDEPr20i II 2CSI 1CX-072514 DER Form 62-620.910(5)2CS, Eflectise November 29, 1994

Facility ID. Number: FLOO00159 Outfall No. D-XXX 2 Mark "X" 3 Effueni 4 Units 5 Intake (optional)

I Pollutant and CAS a b be- c be- a ManximnumDarN Value b Mbas 3-r-dta Value a Long Teno Avg Value d No of a Cone b Mass a Long Teem Ar g Value b No of No (ilaarlabla) testing lice'ed liered (ifavailable) ilfarailable) Analyses Analyses required present absent l I lCene 12r Mann rlI)Cene (2i Mass rIl)Cone l2l Mass (Ir)Cene (2) M~ann 29B Di-N-OctsI Phlielar.

017-l1--r 0 0 l i.oo I WgL 3oB 12-Diph ra'.aar I pg/In

/,ao-a.,srr,122-&o71 0 0 0 <1.17, 31B Fluoraneann (206-.44-0) 121 [] <0.34 I Pg/L 32B Fluorene (8673-7) 0 0 0 <0.34 I lg/L 33B Hexachlorobnne.<9 1118-74-1) 0 0 0 <0.95 I lsg/L 34B ilomblansh (8748-3) 0 0 < 1.80 I ag/L 35B *Lb tt [ 2 (7747-4) 0 0 <200 I pg/I 36B Hexachloroethane (67-72-1l 0D 09 El <1.55 1 ag/L 37B Indeno(I.23-cd)

Pyrene (193-39-51 0 0 0 <0.35 1 ag/L 38B IIophognc (78-59-1) 0 0 0 <0.89 1 Pg/L 39B Naphthalene (91-20-3) 0 0 03 <0.34 I Pg/L 40B Nirobebnnee 198-95-9) 0D 0 01 <1.53 I Pg/L 41B N-N n-tins dranlsin (62-75-91 0 0D 0] <1.733 Pg/L 42B N-Nitrosodi-N- I1.g3 Prop) lamme (621-64-7) 0 Erg/L 0 0 <1.73 I 43B N-Nitro-sodrphene lanene W03r-9 0 0 0 <1.38 I ,pg/I.

44B Pbenanthrbne

(,45.n,-8) 0 0 0 <0.34 I pg/I.

45B PFrene(129-1(-1r) 03 03 0 <0 34 I PYg/L 4r0 124-T10-K es1) nor 0 1 0 0 <0.97 I g/L IP Aldin (3,9-00-2) El 0 S 2P -BHC (319-84-6) F-I [] E 3P -BHC 319-85-7) 0 5 0 4P -BHC (58-89-9) 11 01 0

5P -B0HC(319-86-81 1] 0 VII-15 5 D Y 'P-r141 DUKECCCI CA<DEPe20Lr_2C S LKrCX-e72 514 DER Form 62-620.910(5)2CS, Effeclive November 29, 1994

Facility ID. Number: FLO000159 Outfall No. D-X XX 2 MarknX" 3 EI(uent 4 Units 5 hlake loptional)

I Pollutanta nd CAS a b be- c be- 3 Maximuom Daily Value b Moas30.-day Value c Long Tem A%g Value d No of a Cooe b Mass a Long Teno Ag Value b No of No (ifavanable) testing lisved Ieoed (ifavailable) (ifavailable) Analyses Analo sos requited proent absent (h Cone (2)Mass Conc

(() (2)Mass (ICone {2) Mass (1 Conc (2)Mass 6P Chlordane (57-74-9) c E3 0D 7P 4.4'-DDT (50-29-3) ol o1 03 8P 4.4'-DDE (72-55-9) El El 0 9P 4.4'-DDD(72-54-8) [ El 0 (OP Dieldnn (60-57.11 El El 0 P -Endosulfan II (115-29-7) El El 0 12P -Endosulfoo

( 115-29-7) El El 0 13P Endosulfan Sulfate (1031-(.7-81 0 01

[]

14P Endno(72-21t-8) [] El 02 15P EndrinAldehsdo ] c (7421-92-4) 16P Hepsachlor S76-44-8) 17P Hspsachlor Epoxide (1024-57-3)

(OP PCB-1242 (53469-21-9) El El 0 19P PCB-1254 (II(97-69-I) El El 0 2(IP PCB-1221

( 1104-28-2) El El 0 IIP PCB-1232

((1141-16-5) El El 0 22P PCB-1248 (12672-29-6) El El 0 23P PCB-12(2)

(110-982-5) El El 0 24P PCB-1016 (12674-11-2) El El 0 25P, 1.31-2)

(801 TEoxaphen [] [] 0[111]

VI1-16 V '(1;DI-IS Y14D KHCCCSCAq'WIIDn2Ot I) 2CS 1.CX--72514 DER Fonrm 62-620.910{5)2CS. Effective Noveober 29. 1994

Facility ID. Number: FL0000159 Outfall No. I-XXI PLEASE PRINT OR TYPE ONLY: You may report some or all oflhis information on separate sheets instead of completing these pages. Use the same format.

SEE INSTRUCTIONS.

VII. INTAKE AND EFFLUENT CHARACTERISTICS PART A - You must provide the results ofat least one analysis for every pollutant in this table. Complete one table for each outfall. See instructions for additional details.

3 Uniis 1_4 Intake (optional)

Pollutant d No or a Concenlrafion b Mass a L Avg b No or Anh sess s one Tes 2) Mass AbN

<2 oig/L b Chemical Oxygen 160 I1g/

Demand (COD) c Total Organicr V 4 V eg/L Carbon (roc) d Total Suspended 54 1 g/L Solids (TSS) c TotalN-itangnasNi 06d6 1 gl/L f Tot'alMph- I F) o(118111 I pt/L gI Ammonia (as N) 00 '1 1 VJdL h Flo,, - actual or Value 13 71 Value Value MGD Value proclmed i F .. -design Value Value Value Value j Sp-f'dkConduoairt Value 44g8011 E2aLu Value 1Ulnbos/ent Value k Temperature (W\inter) Value Value Value °C Value I Temperature (surnerel in pH Value 35 9 Mi. 8 1M. 8 Value Min I Ma.s Value 2112 calculuted STANDARD UNITS Value PART B - Mark "X" n column 2a for each pollutint you know or have reason to believe is present. Mark "X" in column 2b for each pollutant you believe to be absent. If you mark column 2a for any pollutant which is limited either directly. or indirectly but expressly, in an el]uent linmiattons guideline, you must provide the results of at least one analysis for that pollutant. For other pollutanis for which you mark column 2a. you must provide quantitative data or an explanation of their presence in your discharge. Complete one table for each outfall See the instructions for addilonal details end requirements 2 Mark "X" 3 Effluent 4 Units 5 Intake optionaIt I Pollutant and CAS a be- b be a Maximum Dailt b Max 3niday Value c Long Term Aig d No of a Cone b Mass a Long Te Avg b No of No ifuvaitlable) liesed lihvsd Value lit suailablel Value if available) Analises Value Analyses present absent (1 Cone (21 Mass l1) Core (21 Mass (IlICorc (2) Mass (I) Cone (2) Mass a Bromide (24949-67-9)1 0 47 I mg/L b Chlorine.

Total Residual 00.01 I mg/L c Color 0 5 I PCU SFeceal ColiIo CFLI/100 r Fluotide

(,914-4t-81 0] C 0.8 I mgiL lasNlr0e-Nil3r31 NI 0] 0 0.33(11 I nmg/L VII-17 Y 71l<140-,1IIKI: CCtcSCArtltN,2Ul,I, 2CSta ICX-I72514 DER Form 62-620.91115)2CS, Effective November 29, 1994

Item VII-B Contd. Facility ID. Number FL0000159 Outfall No. '-XXI 2 Mark "X" I Effucnt 4 Units 5 Intake (optional)

I Pollutant and CAS be- b bo- a MaximuomDail, Value b Max 30-da" Value c Long Tern Ag Valuc d No of a Cone b Mass a Long Term Ag Value b No or No (ifavailabtc) licced 00504 of-ilaablc) ofoaailablo Anols sos Analyses present absent (1)Colic (2) Mass (I) Couc (2) Moss (lICore 2) Mass Cone

(() (2) Mass g Nitrogen. Total Organic (as N) 0 EU 0.66 1 mg/L h Oil and grease 0 l 1 .3 t mg/L i Phosphorus, Total (as P) (7723-14-41 0 - 0.018((I) mgfL

."uo.'.',o,,..

" =,.... ..

,-- -1/4. . := ;..i* ... " " * .a..,... 950:-4'*4:,

(I) Alpha. Total 3. I I.pCi/L (2) Beat. Total 0 Ul 220 I pCi/L (3)Radioms.Total 0 U IpC/L (4) Radium 226. Total 0 1 pCi/L k Sulfate (as SOA)

(148508-79-8) E[ [0 2400 I g[L I Sulfide (as S) [] [] <0. I I mg/L osSufite (asSO,,)

(14265-45-3) E0 U 2 mgL

" Surfa0tants E 0.209 1 mg/L o Aluminum. Total (7429-90-5) 0 U <0.05 I mg/L p Baium. Total (7440-39-3) [] El 0.02 1 mg/L q Boron. Total (7440-42-8) 0 U <0.05 1 gfL I Cobalt. Total (7440-418-4) 0 U 0.019() I mg/L s (ros.Total (7439-99-6) 0 15 mgL tMaagnctiut.. Total

74M39-954" 1400 1 mg/L u Molybdenum. Total (7439-98-7) 0 U 0.071 1 mg/L v Manganese. Total (7439-9(-5) H E <0.000 I mg/L ss Tin. Total (744;-31-5) 0] El 1.7 1 mg/L x Titasium. Total (7440-32-0) 0 U <0.01 I m&/L

\I((-18 Y 'Gt)P-14t.IJUKFE.CCCISCAIF)Elt20t U_2C9SLY)CX--07251-DER Form 62-620 910(5)2CS, Effective November 29. 1994

Facility ID. Number: FL0000159 Outfall No. I-XX1 PART C - If you are a primary industry and this outfall contains process wastewater. refer to Table 2c-2 in the instructions to determine which of the GC/MS fractions you must test for. Mark "Y" in column 2a for all GC/MS fractions that apply to your industry and for ALL toxic metals, cyanides, and total phenols. Ifyou are not required to mark column 2a (secondary industries, non-process vasewwaterourfalls, and non-required OC/MetSfractions), mark NX in column 2b for each pollutant you know or have reason to believe is present. Mark "X" in column 2c for each pollutant you beliese is absent. If you mark column 2a for any pollutant, you must provide the results of at least one analysts for that pollutant. If you mark column 2b for any pollutant, you must provide the results of at least one anlysis for that pollumat if you know or have reason to believe it will be discharged in concentrations of 10 ppb or greater. If you mark coluom 2b for acrolein, acrylonitrile. 2,4,dioirophenol, or 2-ntethyl-4.6 dinitrophenol, you must provide the results of at least one analysis for each of these pollutants which you know or have reason to believe that you discharge in concentrations of 100 ppb or greater. Otherwise. for pollutants for which you mark column2b. you must either submit at least one analysis or briefly describe the reasons the pollutant is expected to be discharged. Note that there are 7 pages to this part; please review each carefully. Complete one table (all 7 pages) for each ouofall. See instructrons for additional details and requrremenrs.

2 Mark "N" 3 Effuent 4 Units 5 rntakeloptional)

I Pollutanl and CAS a b be- c be- a Matimum Daily Value b M.an 30-day Value u Long Ten Aig Value d No of a Conc h Muss a Lone Tumi Ag Value b No of No if lzvibahtol tesling lieced ielied lifauailabluc) ifuvailahle) Analyses[ Analyse eeqormd present absernt I It) Coc I t Stus 1lCone: 121- Con, (1mI) (2(SlmJ_____ _____[ I (oe1-ttn MiETALS, CANIDE.>AN`40rsT.AZLPHENOLS . . .'ct.

IN! Aniinony. Total (744)0,-3)) ] 0] 01 00031 1g/L (1) 2M Arsenic. Tooal (7723-14-il) 0 0 0 0.0021 (I) 1 lg/L 3M Bes aitiu.ToilI 17440)-41-7) 0 0 0 <.0001 I pg/L 4M1 Cadmium. Total (7440i-43-9)1 0 0 <0.001 I pg/L sM Chromiam. Total (7440-47-3) ED E0 0 <0.004 I lag/L 6M Copper. Total (7440-51-s) 0 0 0 0.0025(I)

I Ig/L 7M Load. Total (7439-92-1 0 0 0 <0.005 I pg/L HM Mercun. Total z (7439-97-c) 0 0 0.007/L 9M Nickel. Total 174401-02-n) Z 0] 0.0029(l) lg/L IOM Selcnium. Tomal (7702-49-2) Z I 0] 0.014 I g/L I iM Siher. Total

,744)-22-4) 0 0 0.013 I pg/L 12M Thalliur. Total C7440.-29-i) 0-0 E] ] 000161() I jug/L 13M 7 Zinc. Total

( 440)-6r)-,-) 0 0 0 0.019 1 pg/L 14M Cyanide. Total t57-12-5) 00.0050 0g0L 15M Phenols. Total 5 Q 0.006(1) I L e hlormdiheneo-P-Diosin c.3.7 _ITe-I (171,4.0)1-6)_

5 5 -

I 0<0.63 t107-n)2-8) 1 pg/L 2V Aurvlonitrile 0o7-13-1 I3 ] [] [ <16Ivr 16 a/

VII-19 Y "'an'-

I141DU K CCC1SCA1FD)EI'1,',20(I)2CS Ilx)CX--0725M DER Form 62-620.910(5)2CS. Effective November 29, 1994

Facility ID. Number: FLOO00159 Outfall No. I-XXI 2 Mark )c 3 Elluenm 44 UnitS Urals I 7 0)060)optiooOi) 5 intake (optional)

I No Pollutaolrt oodCAS (iroavilf blo) inng bosi roqoirod j I b beh-lio cd pr...on I liosod ho-

. .b.ro. ( ,Co~o, 1 2 ,Mos L j a MaxinmomDoris Valoe 1 Mo. 30-d.., Val",

o -if oc voilablo)

I ,o1s I Long,of

, oo Tern

,aialA~g ble) Value 1 2,M d No or Anals

_o_

es

_,_ ]-

a Cone

] b Moss

_Cooc o Long TcrnoA, g Valor 1 (M , o b No or Analyse, CC/IS FR AMION VO ATILE COd ROUN DS. oih~ I*~662i ~ v: 2 . -4 3V Benoone (71-43-2) 0D 0 El <0.10 4V Bis Chlorometh%IhEther (542-M-*) 0 .4 5V BlOOfom 1 gL (75-25-2) 0 0 E 1.9

(:V Carbon Tetrachloride (56-23-5) 0] 0] E E <0.22 I p/

7V Chlorobcnzene (108-90-7) 0 0 0 <0.04 l P]L BV Chlorodi.

brontornoehano 0 24-8-I) 0 0 El <0. 15 I pg/L 9V Chloroothanc (744)0-3) 0 0 El <0.39 I pg/L

(<V 2-Chloro-o,hI,in, I Ether (I IW-75-8) 0 0 <0.39 I pg/L I(,7-06-3)

IV Chloroformn 0] 0] E <0.14 II p/

12V Dichloro-bromoo-thano (75-24-4) 0 0IJ <0.13 I "g/L 13V Dichloro-dfithlh-,d. (75-71-0()

,14V I .l-Dichlormethane 0 El <0.74 0l I

1 75-4-3IrIn

)2 0 El <0.1 I pgIL 15V 1.2-DichloroelhaIoe 1017-16-2) 0 <0.12 g/L I(,V I.I-Dichhoootlene<01 75-35-4 <0.14 Pg/L 17V I.2.-Dich~k-pq-onr l <0 (7v 7.-) El [] El <0 06 1 Pg/L

_742-7_-,1 0 0 El <0.14 1 ag/L 19V Ethilbenono0 101-41-41 <0.1I yg/L 20V Methyl Broomido (74-83-9) 0 0 El <0.58 I g/L 21V Mothy)Chloride l<g/I (74-87-3) 0 0 <0.47 Pg/L 22V Moth le neChlo rde 174-98-2) 0 0 El <0.13 I Pg/L 23V 1.l.2.2-Toto-ehloroethaoe (79-34-51 0 0 E <0.12 ] Pg/L 24V Tetrmchloroothslene El <0 -

127-18-4) 0 0 VII-20 1G DP-14,DtJKICCCSCA'IIISIS.725(

Y I _265lO.'CX--0l'2 (4 DER Form 62-620.910(5)2CS, Effective November 29, 1094

Facility ID. Number: FL0000159 Outfall No. I-XXl 2 Mark "X" 3 Effuent 4 Unis 5 Intake (optional)

Tb IpollutantandCAS No tifalarble) a testingI lieted required o-present b-hcsdI absen i aMasiosorn DaidsValube 1 n2)d~V~o if asarabt) ogTn s (faarlable)

Value d No f a Coo nalrrsashAnalyses b Mas. a Long Tono ASg Value b No of c "2) .t)Cone Mss (2)Mts (1))Cono 2HMass (lICorc 1 (2)Masn I pg/L 25V Toluenn (100-08-3) 0 0 El <0.10 26V 1.2-Trans. [ 0 U <0.30 1 Pag/L 27V I.I.2.Tsidskrslame 0 0 U <0.09 1 pg/L (71-55..6,)

29V I.I.2-Trik.oo 0] 0 M <0.23 1 Pg/L C'/9.(x1-5) 29V Trichloroethvclrni 0 021 E <0.12 I Yg/L 179-I1"()1 3OV Trichloro- 0 0 El <0.21 I pg/L florsomsthane(75-69-4) 31V Vinyl Chloride 0 0 U <0.38 I Pg/L (7-411-4)

IA 2-Chlomoplsnol 0 0 U <t I pg/I 1'95-517-8)/

2A 2.4-Dichlorophenol (120-83-2) El E]

[ <1 I lag/L 3A 2.4-Dineilhylphenol 0 (105-67-9) 0 _ F3 El <1 I Pg/L 4A 4.(6Diniro-O-Crsol (3.4-.33-1 ) 0

[] Z] E <3 1 )ag/

5A 2.4-Dinitrophonol 0 0 E <15 1 (51-28-5) <g/L 6A 2-Nirophcnol (08-75-5) <1 I g/L 7A 4-Nitrophcnol (WI0-02-7) <15 I Pg/L 8A P-Chloro-M-Cresol (59-511-71 Pg/L 9A Pcntachlorophenol (07-86-5) 0 C1 <3 I +*/t I:A Phenol (108-95-2) 0 0 U <I I pg/L I IA 2.4.5-Trihioro- < g phenol(88-0,-2) 0 02 <2 I g/L

,-+' . .+ t*mm+B t+: .: .t,.*., * **-,.. . .......

IB Acennphthent 2U9) 0,03 < I I Pg/L 2B Accnaphs'lcnn (208-96-8) 0 0 o < III Pf ogl 3B Anth-ecnc (120)-12-7) [ ] 1] ug]L 4B BOo,..dine 92-07-_*) 0 < too 00 VII-21 Y GI'. (4'DIsJKICCCISCATI]:](s20 II)_2CS[0 CX--72i I4 DER Form 62-620.910(5)2CS, Effective Novoember 29. 1994

Facility ID. Number: FL0000159 Outfall No. I-XX I 2 Mark "X" 3 Elfucnt 4 Units 5 [.take(optional)

I Pollutant and CAS a b be- c be- a MaxinmumDaily Value b Max 30-day Value c Long TenonAg Value d No of a Cone b Mass a Long Tenet Acg Value b No of No ltfatailablo) testing liceed heted tif atailabloe (if ainailableo Analysen Analyses roquired present absent I) Cone (2) Mass (I) Cone (2) Mass () Cone (2) Mass (1)Cone 7 2) Mass 35 Ben/o (a) Anthacene 0 0 - t pag/L (56-55-3) 6B Ben,. (a) P rne0 (5)1-32-g) 0 0]l 7B 3.4-Bnt-Da-dn-ho (2,1-9,21) < I g XB Benzo (ghi) Pen'lenc (191-24-21 0 0 <

9B Bet.o (k) F-lcaa*he l(I)7-1131Bis(20-*o -9da) __ 0 Li < I I li.

Methane (11lIl-91-I) 1I B Bin (2-dhlortcn l)

Ethe, (111-44--41) 0" 0 L <3 I PYg/L Pzhenls (2B Bint2.60--I (20-flaneaonlg Ether I I( 2-60-1)E3I 0] 0] L <' I pg/i.

Af 13B Bts (2-Elh, 3h-l)

Phihalate (117481-7) 0 0 Li <3 I pag/I.

(4B 4-Boounophensl <I Phenol t)hert(lII-55-3< IIi pg/L 15B But5-)BencI Phthdalate (84.tiA-7)( 0 23 L <3 1 16B 2-Chk-ýonqa 01.5-58-7) 0 0 L <I I pg/Li 17B 4-Chlorophenyl Ph..yl Ethen (700-.721-3) S E < I pg,/L IB Ch-see (218-0l-91 [] ,] t] < I I "g/L 198 Dibonofa h)

Anthracene (53-710-3) 0 0 Li < I pLg/i 20B 1.2-Dthaob-295-5t-Il 0 0 Li < I ig/t 21B 13-Dichlon*bnc 0 <I I lag/L 1541-73-1)M< pgi

-B 1.4-Dchlorobacnon la(n.1-7/' 0 0] L <I I Lag/i.

23B 33-Drhdor dinr 152--0 123 0 <40 1 pg/i.

248 Diedhvl Phthalate (84.tit-21 0] 0] L <(I I (.g/L.

25B Dimthylo Phthalate (131-11-3) 0 ] Li <S I pg/.L 26B Di-N-Bum.I Phthalat5 (84-74-21 0 0 LI g 27B 2.4-Dtitnotoluene (121-14-2) 0 0 < ig/L 208 2,,1Dinitnotoluene "t.-2(-2) 0 0 0 <2 I Pg/L VII-22 Y1 011

I DIJIUK I CCC SCA I'D PfUI,

'I'o 2CSI I ICN--n72 4 DER Form 62-620.9I0( 5)2CS, Effective Novenmber 29, 1994

Facility ID. Number: FLOOOO 159 Otufall No. 1-3cc 1 2 Mark "X" 3 Eflfuent 4 Units 5 Intake(optional)

I Pollutant and CAS a b be- c be- a Maxonuni Duil; Value b Man 30-day Value c Long Tcrt Ang Value d No of a Cone b Mass a Long Tnmn Ang Value b No of No irfaniluble) testing licted lit*ed (if aailallel (ifuibble) Anal] ses Anal> seo required present absent (1) Cone (2)lMass (h Con- (2) Mass (I ICone 12) Mass (I Conc (2) Mass 29B Di-N-Oclvl Phithalante (117-94-In) 2 0 [] <1 I pg/L 30B 12-Di[p*l1122-U-SI7

,,enAur*,tnnno Ihdnubae 0] 0] 0 <2 I pg/L 31B Fluoranthicne O2lt-44-11) 0 0 0 < I I pg/L 32B Fluorenc (86-73-7) 0 0 0 <1 I pg/L 33B Hexachlorobens*no (118-74-1) 34B aclrbtin 0 0 0 <I I Pg/

87W*,,-OI3 I pg/L 35B I-L"-it .1 lx (77-47-4) 36B Heachl-o <3

< 1] 1] 1 pg/L thaned (67-72-1) 3 0 0 0 <3 I pg/L 37B lndonotI.2. -,d)

Psrcne 193-39-5) 03 0 <E I pg/L 38B Isophorone0 178-59-1) 0 0 El <1 I g/I 39B Naphthlalene (91-21)-3) 0 0 0 << I ag/L 40B Nilsobcnhcne (98-95-9) 0 0 0 <2 I Pg/IL 41B N-Nit-linsutls. ine (6i2-759*) 0] 0 0 <3 I Pg/L 42B N-Nitrnsndi-N-Psnpvlaminc (621-64-7) M0 0 <3 I pYg/L 43B N-Nitro-sodiphesvlaninc (t*3ý(n ) 0 0 0 <3 I ag/IL 44B Phsnaonlhisno (854)1-81 0 0 El < I I pg/L 45B Pmsroen 1129-110-1( 0 0 El <1 I pg/L 41,B 124-Triab roe d(cc'-

[] )[] 1" <II pg/I.

IP Aldrin(3(010-1-2) 1:1 0] [

2P -BHC (319-n4-61, c[ 0 0 3P -BHC I*99-85-7I c ol 0D 4P -BHC 5s-809-91 [] 0 0 3P -BHC(319-8(il) El 0 0 VII-23 Y '(tDl- t.atDUs:E'CCCISCArDtEPi,.2a it 2CSD iCX--072514 DER Form 62-620.910)5)2CS, Effectine November 29, 1994

Facility ID. Number: FL0000159 Outfall No. I-",I 2 Mark "V" 3 Effuenc 4 Units 5 Intake (optional)

I Pollulas and CAS a b be- c bc- a Maximum Daily Value b MaN 321-dayValue e Long Tono Asg Value d No of a Cone b Mass a Long Tomo A%'gValue b No of No (If asailabla) esming hcoed hcocd (if availab6e) (if-aaiLable) Ana,,ses Anaelyes required prescn absent

'l)Conc (2) Mass tIICoic (2) Mass (I) Cone (2) Mass (0 Coon (2) Mass (6P Chlordane (57-74-9) 11 11 S 7P 4.4'-DDT (511-29-3) o El 0 HP 4,4'-DDE (72-55-9) El El 0 9P 4.4'-DDD (72-54-8) ol o] 0 (OP Dieldrin(60-57-1) El El 0 I IP -Endosulfan (1)15-29-7) El El Z 12P -Endonsufan (I15-29-7) El El 0 13P EndosulfannSulfate 11141-7-9) [El El 0

]4P Endrin (72-20-8) 1 ElD 15P Endrin Aldehyde El 0 (7421-92-4) 16P Heptachlr0 (76*-4-8)

I7P Hcptlcllor Epoxide (11024-57-3) El 1:1 0 lNO PCB-1242 [ ] [

(S3,169-21-9) 19,P PCB-1254 [ [ [

1097-69-1 El 2)P PCB-1221 I l 0",-+28-2)

) 0 0 2IP PCB-1232 (11141-16-5) 0l El 0 22P PCB-124H (12672-29-6) El El 0 23P PCB-12( [

(1196-82-5* El El 24P PCB-11116El l 0 (12674-11-2) 25P Tox.phene (89011-35-2)

Y 'COP-(1DUtKE'CCCISCAM1DI:PO20(I ) 2CNDIKCX--072514 DER Form 62-620 910(5)2CS. Effective November 29, 1994

Facility ID. Number: FL0000159 Outfall No. I-XX2 PLEASE PRINT OR TYPE ONLY: You may report some or all of this information on separate sheets instead of completing these pages. Use the same format.

SEE INSTRUCTIONS.

VII. INTAKE AND EFFLUENT CHARACTERISTICS PART A - You must provide the results ofat least one analysis for every pollutant in this table. Complete one table for each outlfall. See instructions for additional details.

I uen 1 3 Units 1 4 Inake oplional)

Pollutant e Annual Ai Value d No of a Coo tIon I1)Coroe 2 Mas Asnaiscs C oncern rati I b Mass a %g alu 12 r_________

12Aoloc ___sh

_c b No of a Cats.a_ Bd*xmid mng'L 0uss Dmslda&TM0 b Chemical Onsgen 160 1 g/L Demand (COD)

. Total Organic 45 I mg/L Carbon (TOCI d Total Suspended 54 I mg/L Solids (TSS) e Ttd Nitrogen(asN) 0166 I mo/L f Totalphosphrucas) Ii M01(1() I g/L a A-onia (as N) <o 1 I mg/L h Flow - actual or Value 13 71 Value Value Value mgIL projoctcd i Flos,, design Value Valoe Value Value mng[L j SpecificCcduclhani Value 44900) Value Value I urrhos/cm Value sfL k Temperature (inter) Value Value Value °C Value I Teroperature (summer) Value 35 9 Value Value 28 2 calculated C Value so pH Min 8 NAn8 Min IMa. _ STANDARD UNITS PART B - Mark "X" in column 2a for each pollutant you know or have reason to believe is present. Mark "X" in column 2b for each pollutant you believe to be absent. Ifyou mark column 2a for any pollutant which is limited either directly. or indirectly but expressly. in an effluent hlmilations guideline, you must provide the results of at least one analysis for that pollutant. For other pollutants for which you ntark coluon 2a. you must provide quantitative data or onexplanation of Iheir presence in your discharge. Complete one table for each outfall. Seethe tmstmcnlons for additonal details and requirements.

2 Mark "X 3 Effluent 4 Units 5 Isiaketoptlona)

I Pollutant mid CAS a be- b be a Masmum Daily b Mhas311-dayValue c Long Tenm Avg d No of a Cone b Mass a Long Ters Aug b No of No (ifauailable) hood lirvod Value (if available) Value (ifasailablr) Anals Value Aalyses presrnt abst IIDCon (2) Mass (I) Cone (21 Mass (l) Conme (Mass _1__ Cone (2) Mass a Bromide 124949-.67-9) [ 47 I mg/L b Chlorine.

Total Residual [ <0.01 I mg/L c Color 123 E 5 I PCU d Fecul Colifoso [ o <I CFUI/1O0 ml o Fluoride,,

t I 9)4.x4 [u 0.8 I mg/L I(asnN)

NiC1a3(-Ni1rile ] 0] 0.33 i)1 I sogI VI1-25 Y VIl-- 14UKI CCcOSCA FDEiH201 ii 2CSIA ICX-0725 4 DER Form 62-620 910(5)2CS, Effective November 29. 1904

Item VII-B Contd. Facility ID. Number FL0000159 Outfall No. l-XX2 2 Mar "X" 3 Effueon 4 Units 5 Intake (optional)

I Polluamt and CAS a be- b be- a Maximum Daily Value b M4ax311-dayValue c Long Term Avg Value d No of a Cone b Mass a Long Term An g Value b No of No (ifailable) lited teind (ifuN ailablet (ifailublbe Analyses Atinlses present absent (I) Conc (2) Mus (1) Coe (2)Mass ((Cone Mass (2) (( (Cone (2j Mass g Nitrogen. Total Organic (as N) 0 0 0.66 I mg/L I Oilandgrease 0 0 <1 3 I mg/L i Phosphoruns.Touta jMpon ,jg, x.:..::

(as P) (7723-14-mt 0 0 , * **

0.01(t) ":t *. ... . . .. .. .. -

mg/L. i (i) Alpha. Total 0 3. pCi/L (2) Btoa. Total [ 220 t pCiL (3) Radium. Total 0I I pCi/L (4) Radium 226. Total 0 0 I I pCi/L (2400I S1ulat08-79-8) mg/L I Sulfide (anS 0 <S.I I mg/L o Sulfio (as SO,)

(1426545-3) 2 mgL

Surfacunos 0 ID 0.209 I mg/L o Almninum. Total (7429-910-5) <0.05 I mgfL p Bariunm.Total (74401-39-3) El

,. 0.02 mng/L q Boron. Total

,7440t42-8) 0 0 <0.05 1 mg/L r Cobalt. Total 7440-49-4) 0 0 0.019(1) I mg/L s Iron. Touta (7439-89-6) ] .] 0.15 I nng/L SMugonsium. Total (7439-95-4) 0 0 1400 1 mgfL u Mohýbdenum. Total (7439-90-Ti 0 [ 0.071 I mg/L (Mnanganese. Total 7439-96-5t 0 [] <0.001 I mg/L

wnTin. Total 74431-51 [ 1.7mgl x Tiluniurn. Total 74401-32-6, 0 EJ <0.01)

VII-26 Y GDP-141D)UKI?CCC'%CAAt:I I20112CSDXtX--072514 DER Form 62-620.910(5)2CS, Effective November 29, 1994

Facility ID. Number: FL0000159 Outfall No. I-NY'N2 PART C - If you are a primary industry and this outfall contains process wastewater. refer to Table 2c-2 in the instructions to determine which of the GC/NS fractions you must test for. Mark "X" in column 2a for all GC/MS fractions that apply to your industry and for ALL toxic metals, cyaeides, and total phenols If you are not required to mark column 2a (secondary industries, non-process wastewater ourfalls, and non-required GCIMS fractions), mark "Y" in column 21 for each pollutant you know or have reason to believe is present. Mark "Y" in column 2c for each pollutant you believe is absent. If you mark colunm 2a for any pollutant.

you must provide the results of at least one analysis for that pollutant. If you mark column 21 for any pollutant, you must provide the results of at least one anlysis for that pollutnat if you know or have reason to believe it will be discharged in concentrations of 10 ppb or greater. If you mark column 2b for acrolein, acrylontrile. 24,dinitrophenol, or 2-methyl-4.6 dinitrophenol, you must provide the results of at least one analysis for each of these pollutants which you know or have reason to believe thatyou discharge in concentrations of 100 ppb or greater. Otherswise, for pollutants for which you mark column2b, you must either submit at least one analysis or briefly descnbe the reasons the pollutant is expected to be discharged. Note that there are 7 pages to this part: please review each carefully. Complete one table (all 7 pages) for each outfall. Seeinstructions for additional details andreqairemeors 2 Mark"N" 3 Effst 4 Units 5 Intake(optionalt Poll..tantandCAS a bbe- chba-1 a Masiemum DailvValue b Mtax311-day Value n LongTermiAsg Value d No of aCona h ... . LoiugTemiAsg Valun b No of No ifavaitable) testing liemed icnsd c (f usable) oif-aailabl.) Anals.ses Aasly-ss required prescnt ahsunt [o )

___I___ I)Cnc titu2 ss

(________________ t(ll ttim tnConscJtlttas,_____s , IiCona

( It -tanss AMI00TAL'APrYAN1DE

- OS ,".: : :. ... .. ,......... .. ... , :.. , " . ..:<?Qt. .

IM Antimom.Total t1) ig/l 17441t-36-0) 0.0031 1 2M Arsenni.Totl (7723-14-1)) 0 0D E:1 00021 (1) I ag/L 3M Beryllium. Total 074411-7) 0 0 E <0.0001 I ag/L 4M Cadmium.Total 1744i-43-9)tg/L <0.001 I 5M Chromium.Total i7440-47-3) 0 0l I I <0 004 I pg/L 6M Copper. Total (7441i-50-t)tg/L 0.002501 7M Lead. Total (7439-92-It 0 0 E5 <0.005 I ag/L 8M Merciua. Tout 7439-97-61 0 0 51 00017 I ag/L 9M Nickel.Total t7440i)2-024!. 0 0 E 0002911) 1 g/L tiM Selenium.Total 0I g/1 1778249-2)

It Nt Sih'src Total 0 5 .1 1 (7440-22-4) 0 0 5 0.013 1 WIL 12MThalium. Total 17440-284j 0 0 5 00016(11) 1 Pg1 13M Zinc.Total I ug/U (744o6)0I Pg/

14M Csanide. Total t57-12-5t 0 0 5J <0.505 1 pg/L 1tt Phenols.Total I I/L g0.006(l) 2.3. 7.5-Tutna-chlorodibenuzo-P-Dioxin

( 7641-11-6i1 5 5 0 IV0 <.6h (10_7-12-8) I ag/U 2V Aerylonitrile (107-13-h ] [ ] ] <1

<. pg/

VII-27 Y CO7-v14s Wi1ny CCCSa E

'IscQsTiliIIU D

Im)Cv-072514 DER Form 62-620.91015)2CS, Effective November 29, 19c4

Facility ID. Number: FL0000 159 Ouffall No. I-XX2

.( ((loon) 4 UoI(s S InhaLe5.59)100011 i2 Mark "X" 3 Eminent 4 Units i 5inta*ke (optional)

Pollao ondCAS a b be- c be- a Maiunoo Daily Valuc b Max 3)y-day Value c Log Tner Ang Value d No of a Cone b Mass a Long Tonn Ag Value b No of No .1faladble) testingI lic~ed licked (ifa ilable) oifavi able) AnlssAnalyse required presen l ahbsent

1) Cono 1 (2) Mass (1) Cone [ (2) Moss fIConl ) Mass __., Cono 7) Mass 1

CI.S* RACTION -VOLATILE COMPOUNDrS*(-onoed.. .. . .... .

3V Benoene (71-13-2) [] [ - <0.10 I Ig/L 4V Bis (Chloronethb 1)Ether (542-88-I) 0 0 0 5V Bronorooon 1.9 (75-25-2) [. [ [] . I ((g/L 6V Carbon Tetrachloride 0.22 (56.23-5) [] [ ] 0 I ((glL 7V Chlorobenze0.

(1(1-9-) ] [] [ <0.04 II pg/Li 0

9)7)

-3 XV Chlorodi-hronoelhane (124-8-11 0 0 EJ <0.15 1 pg/L 9V Chloroothanc 74-300-) 12 0D E <0.39 I I(g/L IOV 2-Chloro-chyl*, iyl Eiher (I (0-73.-) 0 0 0 <0.39 I pg/L I IV Chloroform (67,S6-31 0 0 0 <0.14 I lg/L t12V Dichloro-broomel""hae (75-24-4() 0 0 <0 3 I ((giL 13V Dichloro.

dfluernehd,e (75-71(-8) <0.74 1I pg]L 14V 1.1-Dichloroclhane (77.34.3) 0 01 <0.12 I (pg/L 15V E.2-D<chlorothan (107-06.2) [] 14 U <0.12 I ag/1 (16V I.(I-Dickhnoolrleo <0.o141 75-3341) 0 0 pg/C 17V 1.2.-D r o sn-(7")7-5) ED 00 Li <0.06 I ig/L 18V 1.3'Dicldhnrcpn*n cr 3M42.7-*) 000 [L <0.14 1 pg/L 19V Eth, Ibenzene (100(4.1-4*4 ( 0 0.13 1 pg/L 20)V hlethyl Bromide (74,S3-9) <0.58 I pg/L 21 V Meth)I Chloride (74-87-3) Z. <0.47 1 .gL 22V Meh (loone Chloride (74-98-2) <0.13 1 23V .1.2.2-T1na-chlionothano 79-34-,) 0 0 0 <0 12 I pg/L 24V Teleachlorocthylenc <0.16 1 (hg/b

( 127-18-4) ______<.1___/

VII-28 -y'3 )UKI<CCK p.14%1- SCA'F:I)pIs,,i01e l)_2(C9l+C£X--72 314 DER Form 621-20.c10(5)2CS. Effective November 29. 1994

Facility ID. Number: FLO(OO 159 Outfall No. l-XX2 2 Mark "X" 3 Effuent 4 Units 5 Intake(optional)

I NoPollutar and CAS (ifasailablo) aMsdig b be-liccd clic'od be- a Maxinuio DariValue b Max 3(1-day Value (ifasailable) a Long Ters Arg Value olfa'ailablel dAlsso1Analysos No of a Cone b Mass a Long Tenn Ag Value b No of roquirod prosnt requiredpresent absont abn t(I)nConc $2)Ms

[

I____________

toncr (2) Mass (IICone (2$Mass _

_)Coor ________ 2 2Mass 25V Toluene (1108-88-3) 0 0 0 <o0.10t rg/L 26V 1.2-Trans-

. 0 0 0 <0.30 pgL 27V 1.12-Trtiotro 00 .$ /

(7$554-5 0 <0.09 Mg/L 2v I.t,2-T8V iohldsrrso [ <0.23 I ag/L 29V TriChloToethylene (79-6t-,) z ID 0.12 1 g/L 30V Trichloro-fluoromehiane (75-69-4) 0] 0 <0.21 pag/L 31V Vinyl Chloride <038 f /L IA 2-Crhlorophenol 0 0 0 <I 1 pg/L

$95-S7-0) 2A 2.4-Dichlorophenol (120-)3-2) 1 Pg/L 3A 2.4-DimrlhoIphcnol (105-*7-9) 0 0<] I F ,

4A 41JoDinitro-O-Cresol 0 pg/b (534-53-1) Il <3 5A 2.4-Dinitrophenol (51-20.3)

.2 0 <-5 $ ag/b 6A 2-Niurophonol <1 pg/b (08-75-5) 7AllnM-02-7) 4-Niorophenol ] [ 0g/L

] <5I1 p/

8A P-Chloro-M-Crosol (59-50-7) Li <t I pg/L 9A Poniachlorophrnol (87-8&5)6<3 g/L

(((APtrennt (I((8-93-21 0 0 <I pg/IL I IA 2.4.5-Trithloro-phenol (80-06-2) 0 0S 0 <2 $ "ag/

I B Aeenaphthene<I (r;3-32-9) 0 0 0 <t $ ag/bL 2B Acenaphtylene o <

(208-96-8) 0 I Yg/b 3B A0<hraeene < I p/b 4-c' nzg7-idin[ [ < 100 1 gL VII-29 Y 'GDP-]4kDUKi:

iCCCSCAFDE(I,',2( I)2CS Ia 1CX-O72514 DER Form 62-620.910(5)2CS, Effective November 29, 1994

Facility ID. Number: FL0000159 Outfall No. I-XX2 uMar"X" 3 Eaein 4 Units 5 Intakc(oplional)

I Pollutant and CAS a b ie- c be- a Maximum Dail, Value b NJax 3St-dl Value c Long Term Ag Valen d No of a Cone b Mass a Long Tern Avg Valne In No of No tifau'ailable) testing lieted licncd (if availablet oravaable) Analyses Anailses required present absent (I)Cone (2) Mass (I)Cone (2) Mass (I} Cone (2)

SMns (I) Cone (2) Mass 5B Benzo (I)Anlhracene (56-55-3) 0 0 Pg/L 6B Be-o (,ot Psroan I pg 050-32-8) 1 p/

7B 3.4-B-1-lutalh~en SB )Q ED-onelco~ts El C3 I I Pg/I.

hB Benzo (ghoi Penlene (191-24-21 0 03 0 <I I Pg/L 9B Benro (k) Elu-nselhne

,Xý[] (2017- ] <1 I pg/L lOB Bis 24-*,)rtiee.(

Methane it 1-1n-I9 1] 0 O <I I pg/L I IB Bis (2S¢hloroedthI) 0 0 c <3 pg/I Ether (I 11-44-41 12B BisI I2pg/L Ether (1(2-611- 0 Pg/L 13B Bis (2.Ett4tlh. bE Phthaiate (I 17-817) []<3 1 g/L 14B 4-Bromophenyl Phenvl Ether(IOI.-55-3* 0 0D E <I I pg/L 15B Butyl Bon*l Phithalate (84-68-7) 0 <3 1 WL 91B 2 El < I I pg/IL 091-SB,-S70 17B 4-Chlorophenyl Phittt Ether (7t00-72-3) 0 2 1 pg/L IOB Chntscnn

(,18-01-9) 0 E0 <g/.

19B Dibtnzo (a,.h) it El E < I I Pg/L Anthracene (53-7tt-3) 211B 1.2-Dihcb

) 0 0 El ,I I pg/I.

21B 1.3-Dichtlorob n

(-141-7.;-It 0 E e 1 22B 1.4-Dicldorobsniten I

(I (P-V,71( 0 0 El 23B 3*-Ditcsebeidhne JI-91-tI 0 0 El <40 I Pg/L 24B DicthyIlPhthalatE, 25B Dimeth, Pithalote 0 0 El <I I Pg/L 2IB Di- (h I(-5)~

(131-11-3)< ~t 1 PY 26B Di-N-But'l Ptihalate (94-74-2) 0 El <0 L 27B 2.4-Dinittololaunepg (1']-14-1t El/ < I I SOB 2.6-Dinituol-on.

(,o6-20-2) 0 0 E <2 VII-30 Y tiP. 14IJK CCCnSCA'FDEI'020I 2S I *CX-t72514 DER Form 62-6i0.910(5)2CS. Effective November 29, 1994

Facility ID. Number: FLO000159 Outfall No. I-XX2 2 Mark "X" 3 Effuoni 4 Unas 5 Inlak optionalh l

I Pollutant and CAS a b be- c be- a MatximuntDailb Value b Ma. 3(1-day Value c Long Term Avg Value d No of a Cone b Mans a Long Torm Ang Value b No of No tifa'ailable) teing lie'ed lioned if available) (ifavailableo Analyses Anal> sen required present absent (I) Cone 121 M-os 1)Cone (2) Mss (I Cone (2) Mas ()Cone Mass 12.)

29B Di-N-ctyl Ptuhalat e 1t117-84-(l) 0 0] 0 <tII I u/

30B E <2 I pg/L 318 Flaurnitnene 32,I,Bit.--, c ] [ p*g/L 32B Fluornn W8,v73-7) 0 0 0 <1 I pg/L 338 Heachlorobcnzeo e (110-74-1) 0 0 0 <I t pg/L 34B Hc.naehkbebtaLoe (874&,83) [] [] <3 1 "g/t.

35B f-.afh (77-47-4) ipo.)d 0E0 <3 I ag/L 36B Hexachloroedhan 0 (67-72-1; <3 1 pg/L 37B Indeno(I.23-c10 PFrunc(193-39-5) 0 El <] I pg/L 38B lsophorone <I I pg/U (78-59-1) 0 0 39B Naphthalene (91-20-3) 0 0 <I I pg/U 40B Nilroben-ene (9-9'-9) 0 0 <2 I pg/L 418BN9-Mitronrndnhoitnue (62-75-9) 0 0 0 <3 I pg/L 42B N-Nttnroot-N-Pro.pIamtine (621-64-7) 0 0 0 <3 I pg/L 43B N-N<tur-sodiphenvlatuine (1-30-t) 0 0 0 <s I Pg/U 44B Phenauthrbne (8-54(-01. 0 0 < I I pg/L 45B Prnne 1294-0-0 0 0 0 <1 I pg/L 4 124-Ttdk.*n

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, 14,IJKI: CC 'SCAF lDEI20e tI2<CS1.)CX-6-e72514 DER Form er2-620 910(5)2CS, Effective November 29, 0394

Facility ID. Number: FLOOOO 159 Outfall No. I-XX2 2 Mark W 3 Effuent 4 Units 5 Intake (oplional)

I PollutantandCAS a b be- o be- a MaximnuoDaiy Value b Mao 30-d&-Value c Long Toms Ag Value d No of a Cone b Mass a Long Tons Ag Value b No of No fCoailablel testing (,,ed liesed (if osoiloble) (iorotilable) Anas sos Analyses required present absent (I) Conc (21 Mass (I) Conc (21 Mass (II) Con (2) Mass (()Cooe (2) Mass (P Chlordane (57-74-91 [ [ 0 7P 4.4'-DDT (50-29-3) El El 0 8P 4.4'-DDE (72-55-9) El El 0 9P 4.4'.DDD (72-54-8) [] 0l 0 (0P Dieldrin (60-57-1) o El 0

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((P PCB-1242 (5346,9-21-9) El El 0 19P PCB-1254 1110)7-69-1) El El 0 211PPCB-1221 (1 )I(4-28-2) El El 0 21P PCB-1232 (11141-16.5) El E 0 22P PCB-1248 (12672-29-6) El El 0 23P PCB-124 j (II9O-82A*- El El 0 24P PCB-1(16 (12674-11-2) 0l El 0 25P Tosophcne W111.(-35-2) El El 0 V11-32 Y 'GDP.14rEUKEICCCSCAIF*EPo20111 2CS [ICX-0725 a DER Form 62-620.910(5)2CS. Effective November 29, 1994

Attachment 1 - Narrative Summary This is an application to revise the National Pollutant Discharge Elimination System (NPDES) permit for Duke Energy Florida, Inc's (DEF's) Crystal River Units 1, 2, and 3 NPDES Permit No. FL-0000159 (Figure 1) to include operation of the proposed Citrus Combined Cycle (CCC) Project. DEF is currently seeking certification of the CCC Pro-ject under the Florida Electrical Power Plant Siting Act (PPSA) (Sections 403.501 through 518, Florida Statutes [F.S.], and Chapter 62-17, Florida Administrative Code

[F.A.C.]). The requested revisions to the existing NPDES permit are limited to:

" Using the existing cooling water intake system bays from the recently re-tired Crystal River Unit 3 (Figure 2) to serve the CCC Project.

" Adding two internal outfalls for cooling tower blowdown from the CCC's two cooling towers (located in Figure 2).

" Adding a new surface water outfall to the existing Crystal River Energy Complex (CREC) discharge canal (located in Figure 2) to discharge cooling tower blowdown in accordance with this application.

Renaming existing Outfall D-093 to reflect that this screen washwater out-fall is associated with the CCC intake flows.

Changing the pH monitoring and compliance point for existing Crystal Riv-er Unit 3 Outfall I-FG during times when pH water quality-based effluent limits are met in discharge from this internal outfall.

No other changes to the existing NPDES permit relative to CREC Units 1, 2, and 3 are requested. Permitting of some other wastewater facilities associated with the CCC Pro-ject, including a proposed percolation pond system for disposal of contact stormwater, industrial wastewaters, and a septic tank or on-Site package plant for sanitary wastewaters, will be accomplished through a site certification application (SCA) under the PPSA. Construction stormwater permit coverage will be through an NPDES multisector general construction permit, with notices of intent filed under separate cover.

This narrative will summarize the nature of surface water intake and wastewater dis-charges of the proposed CCC Project as they relate to relevant aspects of the NPDES permit.

OVERVIEW Operation of the CCC Project will require the use of seawater withdrawn from the exist-ing CREC intake canal. The primary uses of seawater will be for condenser cooling (i.e.,

for cooling tower makeup water) and for managing chlorides concentrations in the cool-ing tower blowdown. The commingled cooling tower blowdown will be discharged to surface waters via the existing discharge canal. The primary uses of groundwater will be for plant process/service water and potable water needs, with no wastewater discharges to surface waters. Information concerning groundwater use is included in this application to AM- Al-Y\GDP- I)_2CS_ATTSDOCN-I)725 14 14\DUKE\CCC\SCA\FDEP62U(

provide a comprehensive water balance. In its application for site certification under the PPSA, DEF is seeking certification of inlet chiller systems to cool inlet air to the combus-tion turbine generators during periods of high temperature. At this time, DEF does not anticipate constructing the chiller system, but such a system may be included as the final design as the Project progresses or postconstruction, should a chiller system be deter-mined to be be needed, effective, and practicable. This NPDES permit application pre-sents information inclusive of construction and operation of such a system.

Figures 3 through 5 present process flow diagrams depicting the water flow through the proposed CCC facility. The quantities of water used in different plant systems will vary with plant operating conditions, as well as with ambient meteorological conditions (e.g.,

air temperature and relative humidity). The water balance diagrams in the three figures are presented to show the estimated annual average and peak water use under different operating conditions:

Figure 3, annual average daily seawater/groundwater use.

Figure 4, peak month daily seawater use.

Figure 5, peak month daily groundwater use.

The annual average water balance depicted in Figure 3 is based on annual average ambi-ent conditions and assumed annual average operating conditions of 1,830 hours0.00961 days 0.231 hours 0.00137 weeks 3.15815e-4 months without duct firing, 4,000 hours0 days 0 hours 0 weeks 0 months with duct firing, and 2,930 hours0.0108 days 0.258 hours 0.00154 weeks 3.53865e-4 months of summer direct firing with inlet air chillers. The peak monthly seawater use in Figure 4 is based on 100-percent load with duct firing under maximum ambient conditions (i.e., 98.5 degrees Fahrenheit ['F]

dry bulb temperature). The peak month groundwater use in Figure 5 is based on 100-percent load with duct firing and 40'F ambient temperature. If the chiller system is not constructed, the chiller condensate supply used to augment service water shown in Figures 3 and 4 and Table 1 would be unavailable and would be replaced by groundwa-ter. Table 1 provides a summary of the major flows for both power blocks combined in the three water balances.

AI-2 ','\GDP. I4\DUKE\C'CC\SCA\FDEPI,2O(1I)_2CSATlS DOCN-O72S14

Table 1. Summary of Major Flows/Uses in the Water Balances Water Use (gpm)

Annual Peak Seawater Peak Average (Figure 4) Groundwater Water Flow/Use (Figure 3) (Figure 5)

Seawater Cooling tower makeup 24,764 32,874 19,560 Augmentation water for cooling tower/ blowdown 38,106 50,616 30,094 Total withdrawal 62,870 83,490 49,654 Cooling tower evaporation 5,716 7,592 4,514 Total discharge 57,156 75,916 45,136 Groundwater Plant process/sanitary water 84 20 138 Potable water 1 1.1 1 Total withdrawal 85 21 138 Chiller condensate reuse (optional) 112 334 0 Total discharge to percolation pond 106 118 114 Sources: Burns & McDonnell, 2014. ECT, 2014.

WATER SUPPLY AND DISCHARGE As shown in Table I, use of seawater for cooling tower makeup and augmentation water for cooling tower blowdown, with a total peak combined flow of 83,490 gallons per mi-nute (gpm) (120.2 million gallons per day [MGD]), are by far the largest plant water uses for the CCC Project. Cooling tower makeup water is required to replace water lost through evaporation in the cooling process and the discharge of blowdown to effectively manage water quality in the cooling towers. Seawater will also be used to manage the chlorides concentrations in the cooling tower blowdown (elevated due to evaporation) to meet applicable marine surface water quality standards.

The cooling tower makeup and augmentation water will be withdrawn from the existing CREC intake canal through the existing intake structure of the retired Crystal River Unit 3. Although not shown in the water balances, a small quantity of seawater will be periodically withdrawn from the intake structure bays as wash water for the traveling screens. Screen wash water will be returned to the intake canal after removal of debris.

The peak flow of combined cooling tower makeup and augmentation water flow (120.2 MGD) for the proposed CCC Project is significantly less than historical withdraw-als when Crystal River Unit 3 was operational. Prior to its shutdown and ultimate perma-nent retirement, the once-through cooling water design withdrawal for Unit 3 was 979.2 MGD. Currently, Unit 3 is permitted to withdraw up to approximately 43.5 MGD of noncontact cooling water for utilization in the Unit 3 heat decay, spent fuel pool heat exchanger system. Actual flows have averaged approximately 16 to 18 MGD over the past several months. The current design withdrawals from the intake canal for once-through cooling water for Crystal Units I and 2 are 446.4 and 472.3 MGD, respectively.

AI1-3 AI-Y\(DP-14\DLIKE\CCC\SCA\FDEP(,2U)(I) 2CSAT-rS DOC.X-07251-4

DEF is currently planning on retiring Units I and 2 in coordination with the commercial operation of the CCC Project; therefore, these cooling water withdrawals will also cease in the future. The proposed CCC cooling water system will be compliant with the final Section 3 16(b) rule as described in the following paragraphs.

MINIMIZATION AND REUSE DEF has evaluated the facility's water use in an integrated fashion and reduced its overall water withdrawals by employing a closed-cycle recirculating cooling system as well as combined cycle generation technology. The closed-cycle cooling system will consist of mechanical draft, evaporative cooling towers supplied with seawater for makeup to avoid use of freshwater as well as to take advantage of the existing intake canal and existing cooling water intake system associated with Crystal River Unit 3. Use of closed-cycle cooling and combined cycle generation, including consideration of the water used to manage chlorides concentrations, will reduce facility cooling water demand by 93 percent relative to an open-cycle facility of the same electrical output. Use of closed-cycle cool-ing is also a basis of compliance for new units] at existing facilities as defined in U.S.

Environmental Protection Agency's (EPA's) 2014 316(b) existing facilities intake rule, which aims to reduce adverse environmental impacts associated with impingement and entrainment of aquatic organisms.

DEF has carefully considered opportunities for water reuse, either from inside the plant itself or from outside the plant, and water conservation to minimize the use of groundwa-ter. In conjunction with the Southwest Florida Water Management District, DEF is cur-rently implementing a project to use all reclaimed water available from the city of Crystal River to offset some groundwater use for Crystal River Units 4 and 5. No other practical sources of reclaimed water are available in the region. Similarly, potential storage and reuse of stormwater on the Site is impractical due to the size of the Site and constraints posed by wetlands and other land features. If an air chiller system is constructed, chiller condensate will be reused in the process/service water systems and as makeup water for the chiller cooling towers.

MINIMIZATION OF POTENTIAL WATER QUALITY IMPACTS DEF has taken several measures to reduce the potential for impacts to water quality in-cluding:

" Use of closed-cycle cooling and combined cycle generation to reduce water demand for cooling. Together, surface water intake will be reduced by 93 percent relative to similar steam electric generating plants that use open-cycle cooling.

" Use of flow augmentation to limit the increase in chlorides concentration to 10 percent prior to discharge to surface waters to comply with Florida Sur-face Water Quality Standards. A co-benefit is that the augmentation water 1 The CCC Project will be considered a new unit at an existing facility according to the definitions in the final 3 16(b) existing facilities rule.

Al-4 I j2CSATTS DOCX--11725 Y\ODP- I4\DUKE\CCC\SCA\FDEP('O2(

YI- 14

will also reduce the concentrations of other cooling tower blowdown con-stituents, including those derived from concentration of seawater or from addition by the plant.

Use of combined cycle generation and closed-cycle cooling substantially re-duces the thermal loading to the environment. This reduction is manifested in reduced flows as well as reduced effluent temperatures. Use of augmenta-tion water to manage chlorides concentrations will also reduce effluent tem-perature. DEF estimates that the maximum effluent temperature, conserva-tively estimated, will be well below the thermal limitation in the existing NPDES permit.

" The CCC Project will be operated in compliance with applicable state and federal regulations, including effluent limitation guidelines, water quality-based effluent limitations, and Florida's antidegradation policy.

Chemical metal cleaning wastes will be containerized and disposed of off-Site consistent with local, state, and federal regulations.

" Industrial process wastewater will be disposed of to an appropriately sized and constructed percolation pond system, and treated sanitary wastewater will be disposed of to a subsurface treatment system or on-Site package plant under separate regulatory approvals.

SECTION 316 COMPLIANCE/THERMAL WATER QUALITY STANDARDS Use of combined cycle generation and closed-cycle cooling substantially reduces the thermal loading to the environment. This reduction is manifested in reduced cooling wa-ter flows, as well as reduced effluent temperatures. Mixing cooling tower blowdown with ambient seawater to limit chloride concentrations in the blowdown will also reduce efflu-ent temperature. DEF estimates that the maximum effluent temperature, conservatively estimated, will be well below the existing thermal limitation in the NPDES permit. The size of the thermal plume will not increase beyond existing conditions. Also, with the re-tirement of Unit 3, the thermal plume has been further reduced. DEF requests that the ex-isting 316(a) variance and monitoring point for same remain applicable. As shown in the following Table 2, the thermal discharge will remain an existing heat source in accord-ance with Rule 62-302.520(1), (3)(d), F.A.C., and Section 403.08852, F.S.

AI1-5 AI5\GjDP-14\DUIE\CCC\SCA\FDEP62"( I1 2CS ATTSDOCX-11725 14

Table 2. CREC Unit Operations-Effluent Thermal Loading Generator Output* Heat Rejection Rate Heat Load Added to Discharge Canal Unit (MW electric) (MW thermal) Btu/hr %

CREC 1 373.95 485.03 1.66E+09 16.80 CREC 2 520.82 674.06 2.30E+09 23.35 CREC 3 880.02 1,727.40 5.91E+09 59.84 Total CREC Units 1,774.79 2,886.49 9.87E+09 100.00 CCC 1 362 545.5 3.86E+07 0.39 CCC 2 362 545.5 3.86E+07 0.39 Total CCC 724 1,091.0 7.72E+07 0.78

Generator output for CCC I and 2 are for steam cycle only.

Sources: DEF, 2014.

Burns & McDonnell, 2014.

ECT, 2014.

316(b) INFORMATION DEF has evaluated the facility's water use in an integrated fashion and reduced its overall water withdrawals by employing a closed-cycle recirculating cooling system, as well as combined cycle generation technology. The closed-cycle cooling system will consist of mechanical draft, evaporative cooling towers supplied with seawater for makeup. Use of seawater is planned to avoid use of freshwater for cooling purposes as well as to take ad-vantage of the existing intake canal and existing cooling water intake structure at Crystal River Unit 3. Use of closed-cycle cooling and combined cycle generation, including con-sideration of the chlorides flow augmentation water, will reduce facility cooling water demand by 93 percent relative to an open-cycle facility of the same electrical output and will result in a commensurate reduction in adverse environmental impacts associated with impingement and entrainment of aquatic organisms.

Use of closed-cycle cooling is deemed the best technology available (BTA) for compli-ance with both impingement and entrainment reduction requirements for new units at ex-isting facilities as defined in EPA's 2014 final intake rule applicable to new units at exist-ing facilities (40 CFR § 125.94(e)). As an added measure to reduce impingement, the in-take structure will be configured to achieve an intake velocity of less than or equal to 0.5 foot per second (fps), considered the BTA for impingement for existing intakes in the final 316(b) rule for existing facilities.

ANTIDEGRADATION provides a demonstration that the proposed discharge is consistent with Florida's Antidegradation Policy set forth in Rule 62-302.300, F.A.C., as well as permit-ting requirements under Rule 62-4.242(1).

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" Existing Outfall CREC Property Boundary CCC Site FIGURE 2.

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Attachment 2 - Form 2CS Additional Information FORM 2CS, SECTION IV-WASTEWATER DESCRIPTION The following describes the contributory wastewater streams and wastewater treatment employed at the two CCC units. Refer to Figures 3 through 5 in Attachment I for the process flow diagram and water balances. Additional descriptions of chemical usage and chemicals that have the potential to be discharged via the permitted outfalls are also pro-vided.

Internal Outfalls I-XX1 and 1-XX2 consist of noncontact, closed-cycle cooling tower blowdown from the two CCC cooling tower basins. Water discharged from these cooling tower basins will be commingled with seawater from the intake while in transit to a new outfall, Outfall D-XXX, which, in turn, is discharged via the CREC discharge canal.

The two CCC units have the ability to inject oxidizing biocides to control biofouling within the mechanical draft cooling towers. In addition to sodium hypochlorite, various sodium bromide products (or a mixture of sodium hypochlorite and sodium bromide) may be used. To comply with limits for total residual oxidants, a dechlorination/de-bromination product, such as sodium bisulfite or sodium metabisulfite, is added at a stoi-chiometric ratio to ensure compliance with the total residual oxidants limits. Table 3 pro-vides usage rates for these chemicals. Attachment 4 provides material safety data sheets.

Table 3. Projected Treatment Chemical Use in the Cooling Towers Daily Use (gallons)

Chemical Average Maximum Sodium hypochlorite (12.5%)

Intake feed 2,174 2,415 Cooling tower feed 444 444 Sodium bromide (42.8%)

Intake feed 157 245 Cooling tower feed 32 45 Surfactant 7.1 9.5 Sodium bisulfite Variable* Variable*

Dosage rate will vary with oxidant demand in source water and flow rate Sources: DEF, 2014.

ECT, 2014.

A2-1 A2l Y:\GDP-I-4\DUKE\CCC\SCA\FDEP6(,2mI)-2CS-ATTS DOCX-072514

In addition to biocide treatment in the cooling towers, at times, a Florida Department of Environmental Protection (FDEP)-approved surfactant is used to increase the effective-ness of the biocide treatments and as a silt dispersant. Consistent with federal effluent guidelines for the steam electric sector, only one cooling tower is treated at any one time.

FORM 2CS, SECTION VI-IMPROVEMENTS Revised Administrative Order No. AO-024-TL (revised Order) was issued with the cur-rent NPDES permit on April 7, 2014. Item 111.29 of the revised Order requires that CREC prepare a feasibility study report to comply with the final regulations for Section 3 16(b) for operation of the existing units at CREC. EPA's final intake rule was signed by the EPA Administrator on May 19, 2014, and has been released in prepublication form.

FDEP has stated its intent to modify the revised Order for consistency with the study re-quirements and schedule in the final rule once it is published.

Based on the prepublication version of the final rule, the new CCC generation units are defined as new units at an existing facility. As discussed in Attachment 1, the design of new CCC cooling water intake system will be compliant with the rule's requirements for such units as the use of closed-cycle recirculating cooling towers represents BTA for compliance with both impingement and entrainment reduction requirements (40 CFR § 125.94(e)(1)). Information submittals required under 40 CFR § 122.21(r) for operation of the proposed CCC Project must be submitted no later than 180 days prior to the commencement of cooling water withdrawals at the new units (40 CFR § 125.95(b)).

Item 111.32 of the revised Order requires that CREC prepare a modified biological plan of study and schedule to study the protectiveness of the existing Section 316(a) thermal var-iance given the retirement of Unit 3. As stated in Attachment 1, the discharge from the CCC Project will achieve the existing thermal limits for the CREC permit and thus will be protective of the balanced indigenous population in the receiving water body. A ther-mal plan of study was submitted to FDEP on July 3, 2014, that included a phased ap-proach for physical and biological sampling of the CREC thermal discharge.

FORM 2CS, SECTION VII-INTAKE AND EFFLUENT CHARACTERISTICS Data provided in Part VII of the application were calculated using sampling data from the intake canal taken from DEF's NPDES permit renewal application for Units 1, 2 and 3 submitted to FDEP on February 28, 2013, and data for cooling tower blowdown from Units 4 and 5 taken from DEF's NPDES permit renewal application for Units 4 and 5 submitted to FDEP on January25, 2010. Constituents in the tables for Section VI1, Part B, marked as "believed present" are due to their presence in the ambient seawater at the point of intake, which are then passed through to the discharge.

The cooling tower blowdown from the CCC Project will be similar to that of Units 4 and 5, given that both sets of towers use the same source waters and similar water treatment chemicals (Table 3). Cooling tower blowdown from the CCC Project will also be subject to flow augmentation to manage chlorides concentration using seawater from the intake A2-2 A22 Y:\GDP-I14\DUKE\CCC\SCA\FDEP62O(il)-2CSATTS DOCX-Co72514

canal. The intake and blowdown data described in the previous paragraphs were mathe-matically composited using the projected augmentation ratios from the water balance to predict the final effluent characterization for Outfall D-XXX.

When analytical results were below the method detection limit, the result was reported as less than the calculation result.

Estimation of effluent temperature (Table 4) is based on modeling of cooling tower blowdown temperature based on the operation of the CCC units and ambient meteorolog-ical conditions. The record of inlet temperature for CREC Units 1, 2, and 3 was used to assign a temperature for the augmentation water. The ratio of augmentation water to cool-ing tower blowdown was used to develop a flow-weighted temperature of the mixed streams under annual average conditions as well as maximum summertime temperatures.

Table 4. Projected Effluent Temperatures Parameter Average Maximum Inputs Intake canal temperature basis Average Maximum Intake canal temperature ('F) 74.6 94.9 Cooling tower blowdown ('F) 82.8 96.6 Flow augmentation rate (gpm) 38,026 29,026 Cooling tower blowdown rate (gpm) 19,010 18,868 Estimate Effluent temperature to effluent canal ('F) 77.3 95.6 Sources: Burns & McDonnell, 2014.

ECT, 2014.

The summertime maximum temperature likely represents an overestimate, as the maxi-mum observed inlet temperature (94.9'F) is only one of two observations made between July 2005 and March 2014 that exceeded 92'F. In addition, the cooling tower blowdown and mixed blowdown/augmentation water will be transported in subsurface pipes for sev-eral thousand feet prior to discharge. This will allow for heat transfer from the effluent to subsurface soils. This heat dissipation is not accounted for in the calculation of the max-imum summer temperature. Furthermore, compliance with the thermal limits is at the point of discharge into Crystal Bay (monitoring location Eff-3D), which is approximately 1.5 miles downstream of the proposed outfall into the discharge canal. Additional heat dissipation into the atmosphere will occur during transit in the discharge canal. For these reasons, the calculated maximum effluent temperatures and the overall thermal loading into the receiving water body are conservative.

A2-3 A23

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Attachment 3 - Antidegradation Demonstration The discharge from the proposed CCC Project will not result in degradation of water quality or impairment in any of the designated uses in the receiving body of water. The operation of the CCC Project, in combination with the retirement of Crystal River Unit 3 in 2013 and the planned retirement of Crystal River Units I and 2 in conjunction with the CCC Project becoming operational, will result in a net benefit to aquatic resources through reductions in cooling water use and thermal loading.

An SCA has been submitted to the state that addresses the potential effects of the con-struction and operation of the CCC Project. The benefits of the Project are also described in the SCA. While the CCC Project is not expected to result in degradation of water qual-ity, the following information is provided to demonstrate that the proposed discharge is consistent with the antidegradation policy set forth in Rule 62-302.300, F.A.C., and meets the antidegradation permitting requirements in Rules 62-4.242(1)(b) and (d), F.A.C.

ANTIDEGRADATION PROVISIONS Section 403.088(2)(b), F.S. provides that if a proposed discharge does not reduce the quality of the receiving water below the classification established for it, FDEP "may issue an operation permit if it finds that such degradation is necessary or desirable under feder-al standards and under circumstances which are clearly in the public interest."

Rule 62-4.242(1), F.A.C. provides:

(b) In determining whether a proposed discharge which results in water quality degradation is necessary or desirable under federal standards and under cir-cumstances which are clearly in the public interest, the department shall consider and balance the following factors:

1. Whether the proposed project is important to and is beneficial to the public health, safety, or welfare (taking into account the policies set forth in Rules62-302.300, F.A.C., and, if applicable,62-302.700, F.A.C.); and

2. Whether the proposed discharge will adversely affect conservation of fish and wildlife, including endangered or threatened species, or their habitats; and

3. Whether the proposed discharge will adversely affect the fishing or water-based recreational values or marine productivity in tile vicinity of the proposed discharge; and A3-1 \GDP- 14\UKE\CCC\SCA\FDEP620(1I)-2CS-ATTS DOCX-0725 14

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4. Whether the proposed discharge is consistent with any applicable Sur-face Water Improvement and Management Plan that has been adopted by a Water Management District and approved by the Department.

(d) For industrial wastewater facilities, proposing new or expanded surface wa-ter discharges, in addition to paragraph (b) above, in order for the new or expanded industrial wastewater discharge to be necessary or desirable Linder federal standards and under circumstances which are clearly in the public in-terest, the permit applicant:

1. Must demonstrate that use of other discharge locations, land applica-tion, or recycling at off-Site locations that would avoid the degradation of water quality is not economically and technologically reasonable; and

2. Shall submit a signed statement under penalty of law that a waste min-imization and source reduction analysis was completed consistent with best management practices appropriate for the type of facility or dis-charge proposed as identified in paragraph 62-620.100(3)(m), F.A.C.,

40 CFR 122.44(k), and Guidance Manual for Developing Best Man-agement Practices (BMP), U.S. Environmental Protection Agency, Of-fice of Water, Washington, DC, EPA 833-B-93-004, October 1993.

Rule 62-302.300(6), F.A.C., confirms that "private activities conducted for private pur-poses may.. .be in the public interest." These elements of the antidegradation rule are ad-dressed in the following paragraphs.

RULE 62-4.242(1)(B), F.A.C.

1. The CCC Project is important and beneficial to the public health, safety, and welfare of the region by providing reliable and cost-effective electric power.

DEF has an obligation to provide sufficient, adequate, and efficient electric service in its service territory (Section 366.03, F.S.). Through its integrated resource planning process, DEF has determined the need for additional gen-erating capacity by 2018. The CCC Project is the most cost-effective option for customers and provides systemwide reliability, ensures regulatory com-pliance, and meets DEF's 2018 in-service construction timeline. On May 27, 2014, DEF filed a petition for a determination of need for the CCC Project with the Florida Public Service Commission (PSC). The PSC is the sole fo-rum for a determination of the need for an electrical power plant (Sec-tion 403.5 19, F.S.).

2. The proposed discharge will not adversely affect conservation of fish and wildlife, including endangered or threatened species, or their habitats.

A3-2 A32 Y:\GDP- 14\DUKE\CCC\SCA\FDEP6'(,2)-

2CSA~rS DOCX-I)725 .4

3. The proposed discharge will not adversely affect the fishing or water-based recreational values or marine productivity in the vicinity of the proposed discharge.

The conclusions articulated in previous Items 2 and 3 are supported by the following:

The effects of the existing cooling water intakes and thermal discharges from CREC have been studied extensively over the several decades. In Sep-tember 1988, EPA granted a Section 316(a) variance from thermal effluent limitations to CREC after a determination that the variance was adequately protective of a balanced indigenous population in the receiving body of wa-ter. At the same time, EPA determined that CREC's helper cooling towers, seasonal flow reductions, and mitigation efforts constituted BTA for protec-tion of adverse environmental impacts under the Clean Water Act Sec-tion 316(b) requirements. The potential for adverse effects to federally-listed species also were carefully evaluated by the relevant agencies. Their deter-minations either concluded that there would not be substantial impacts or re-sulted in control plans approved by the agencies.

" The CCC Project's use of a closed-cycle recirculating cooling system will result in significant reductions in cooling water withdrawals, which will produce commensurate reductions in adverse environmental effects. As not-ed in the following paragraphs, the CCC Project will use seawater to man-age chlorides concentrations in the cooling tower blowdown. The rate of cooling water withdrawn from the existing intake canal (including augmen-tation water for chlorides) will be reduced by approximately 93 percent compared to a facility with the same output that employs once-through cool-ing. When considered on the basis of electricity output (i.e., million gallons per day per megawatt [MGD/MW]), the generation provided by Units 1, 2, and 3 require 1.03 MGD/MW. In contrast, the proposed CCC Project will use cooling tower makeup and chloride dilution water at a rate of 0.07 MGD/MW, an overall 93-percent reduction relative to a facility of the same output that uses once-through cooling, thus producing a commensurate decrease in impingement and entrainment rates.

" The use of closed-cycle recirculating cooling systems is identified in the fi-nal Section 316(b) existing facilities rule as BTA for new units at existing facilities (40 CFR 125.94[e][1]). The existing Unit 3 intake bays will be ret-rofitted with intake screens with a design through-screen velocity of less than 0.5 fps, considered BTA for mitigation of impingement mortality ef-fects from existing cooling water intakes (40 CFR § 125.94(c)(2)).

" The CCC Project will greatly reduce thermal loading to the aquatic envi-ronment relative to open-cycle systems. The current NPDES permit sets a maximum discharge temperature at the point of discharge into Crystal Bay of 96.5°F as a 3-hour average for compliance with the 316(a) thermal vari-ance. The cooling tower design for the new CCC units will result in a cool-ing tower blowdown temperature that is lower than this final discharge limit, A3-3 A3-Y\GDP-I-4DLIKETCC\SCA\FDEP62O(MU2CSATTS DOCX-072514

conservatively estimated using the maximum seawater intake and ambient air temperatures to yield a maximum effluent temperature of 95.6°F. Fur-ther, heat dissipation will occur through the below-ground discharge pipe prior to entering the discharge canal and within the discharge canal prior to entering Crystal Bay at the temperature monitoring compliance point. The temperature of the proposed discharge will therefore easily meet thermal limits set by the current 316(a) thermal variance. Evaporative cooling towers operate by using the latent heat of water evaporation to cool recirculating water. The facility also uses the waste heat from the combustion process to generate steam and electricity, reducing the cooling demand. For these rea-sons, the thermal load associated with cooling tower blowdown is far lower than that of a similarly-sized plant that employs once-through cooling.

" The effluent from the CCC Project will comply with applicable ambient wa-ter quality standards. As described previously, the CCC Project will use am-bient seawater from the existing intake canal to manage chlorides concentra-tions in the blowdown prior to discharge to ensure that the concentration of chlorides is not increased by more than 10 percent relative to the source wa-ter. This will have the additional beneficial effect of reducing the tempera-ture of the cooling tower blowdown.

" The CCC Project will intermittently use sodium hypochlorite and/or sodium bromide to control biofouling in the cooling towers, consistent with the 40 CFR 423 effluent guidelines for the steam electric generating sector.

Dechlorination will be performed during this procedure.

No other toxic chemicals will be introduced into the cooling tower blow-down, which is expected to be similar in quality to the blowdown from the existing Units 4 and 5 cooling towers. Semiannual toxicity testing of the Unit 4 and 5 blowdown conducted under conditions of the current NPDES permit for those units has shown no issues with toxicity.

There are no applicable surface water improvement and management (SWIM) plans adopted by a Water Management District and approved by FDEP that would be impacted by the project. The closest approved plan is for Crystal River/Kings Bay . located south of the Project. The Project boundary lies northwest of the SWIM plan's management boundary and lies outside both the surface watershed and groundwater recharge area.

RULE 62-4.242(l)(D), F.A.C.

I. Discharge of cooling tower blowdown via the existing CREC discharge ca-nal is the most cost-effective and least environmentally disturbing discharge alternative due the presence of existing infrastructure and close proximity.

2 Crystal River/Kings Bay Surface Water Improvement and Management (SWIM) Plan, Final Approved Plan July 10, 2000. Southwest Florida Water Management District, Resource Management Department, Surface Water Improvement and Management Section.

A3-4 AY:\GDP-4 14\DUKE\CCC\SCA\FDEP6201f) 2CS ATTSDOCX-072i14

Land application and off-Site reuse of the cooling tower blowdown is not feasible due to the use of salt water cooling towers and the resulting high dissolved solids content of the cooling blowdown. Process wastewaters will be discharged to an on-Site percolation pond to limit the potential for water quality degradation. As noted in Attachment I to this application, every op-portunity for flow reduction and reuse on-Site was incorporated into the Pro-ject design.

2. DEF certifies that a waste minimization and source reduction analysis was completed consistent with BMPs to control or abate the discharge of pollu-tants as identified in paragraph 62-620.100(3)(m), F.A.C., and 40 CFR § 122.44(k).

In summary, the proposed CCC Project is in the public interest, because it helps ensure that DEF can provide reliable and cost-effective electric service in its service territory.

The Project will result in substantial reductions in cooling water withdrawals and thermal discharges, minimize adverse environmental impacts due to impingement and entrain-ment, and will result in additional protection to threatened and endangered species. The Project will not result in degradation of water quality or reduction in any of the designat-ed uses in the receiving water body. Finally, the Project will be designed with waste 3 min-imization and source reduction features consistent with approved BMP guidance.

DEF is providing the following statement in accordance with Rule 62-4.242(i)(d)2, Flor-ida Administrative Code (F.A.C.):

[A] waste minimization and source reduction analysis was completed con-sistent with best management practices appropriate for the type of facility or discharge proposed, as identified in paragraph 62-620.100(3)(m),

F.A.C., 40 CFR 122.44(k), and Guidance Manual for Developing Best Management Practices, U.S. Environmental Protection Agency, Office of Water., Washington, DC, EPA 833-B-93-004, October 1993.

3 Guidance Manual for Developing Best Management Practices, U.S. Environmental Protection Agency, Office of Water, Washington, DC, EPA 833-B-93-004, October 1993 A3-5 Y\GDP-I-I\DUKE\CCC\SCA\FDEP6201 Y- I) 2C5ArTS DOCX-1,7'i 14

- Material Safety Data Sheets A4-1 Y\GDP-I4\DLIKE\CCC\SCA\FDEPA,2)( I)_2CSAVIS DOCN-(172514 Y4-

Material Safety Data Sheet Material Name: Sodium Metabisulphite or Sodium Metabisulfite ID: C1-143

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Section 1 - Chemical Product and Company Identification Chemical Name: Sodium MetabisuIlphite (Technical, Photo and Food Grades) or Sodium Metabisulfite Product Use: For Commercial Use Synonyms: Disulfurous acid, Disodium salt, Fertisilo; Pyrosulfurous acid. disodium salt; Sodium disulfite; Disodium pyrosulfite; Sodium pyrosulfite.

Supplier Information Chem One Ltd. Phone: (713) 896-9966 8017 Pinemont Drive, Suite 100 Fax: (713) 896-7540 Houston, Texas 77040-6519 Emergency # (800) 424-9300 or (703) 527-3887 General Comments: FOR COMMERCIAL USE ONLY; NOT TO BE USED AS A PESTICIDE.

NOTE: Emergency telephone numbers are to be used only in the event of chemical emergencies involving a spill, leak, fire, exposure, or accident involving chemicals. All non-emergency questions should be directed to customer service.

Section 2 - Composition / Information on Ingredients ***

CAS # Component Percent 7681-57-4 Sodium Metabisulfite > 95%

Component Related Regulatory Information This product may be regulated, have exposure limits or other information identified as the following: Sulfites.

Component Information/Information on Non-Hazardous Components This product is considered hazardous under 29 CFR 1910.1200 (Hazard Communication).

Section 3 - Hazards Identification ***

Emergency Overview Sodium Metabisulfite is a white crystal or white/yellow powder form. May cause severe allergic reaction in asthmatics and sulfite sensitive individuals. May be harmful if swallowed. May cause eye, skin and respiratory tract irritation. This product is not flammable. Thermal decomposition of this product produces irritating vapors and toxic gases (e.g. sulfur dioxide), which may increase fire hazard due to the flammability of sulfur dioxide. Emergency responders should wear proper personal protective equipment for the releases to which they are responding.

Hazard Statements WARNING! CAUSES SKIN AND EYE IRRITATION. HARMFUL IF INHALED. MAY CAUSE ALLERGIC SKIN OR RESPIRATORY REACTION. Keep from contact with clothing. Do not taste or swallow. Do not get on skin or in eyes. Avoid breathing dusts or particulates. Avoid prolonged or repeated contact with skin. Keep container closed. Use only with adequate ventilation. Wash thoroughly after handling. WARNING! Contact with acids, water or ice releases sulfur dioxide gas which may be harmful or deadly if inhaled. Use of this product in confined spaces may cause suffocation leading to death. Do not use in unventilated areas such as in the holds of fishing boats, walk-in coolers or confined spaces. Use only in ventilated areas.

Potential Health Effects: Eyes Exposure to particulates or solution of this product may cause stinging, tearing and redness. Prolonged contact with solutions of this product may cause conjunctivitis, ulceration and corneal abnormalities.

Potential Health Effects: Skin This product can cause irritation of the skin, especially after prolonged exposures. Repeated skin contact may lead to skin sensitization, an allergic reaction and dermatitis (red, cracked skin). Skin contact can cause allergic skin reaction in susceptible individuals, with symptoms including itching, rash and welts.

Potential Health Effects: Ingestion Ingestion of this product can irritate the tissues of the mouth, esophagus, and other tissues of the digestive system. Symptoms of exposure can include central nervous system depression, gastrointestinal and cardiac abnormalities, and violent colic. Sulfite compounds, such as this product, can cause a severe allergic reaction in sensitive individuals and some asthmatics, which can be life-threatening.

Potential Health Effects: Inhalation Breathing dusts or particulates generated by this product can lead to irritation of the nose, throat or respiratory system. Symptoms of such exposure could include coughing and sneezing. This product can cause an asthma-like allergy with symptoms such as shortness of breath, wheezing, coughing, urticaria, angioedema, nasal congestion, nasal polyp swelling and chest tightness. Severe general (anaphylactic) reactions can occur, which can be life-threatening in some cases.

HMIS Ratings: Health Hazard: 2* Fire Hazard: 0 Physical Hazard: I Hazard Scale: 0 = Minimal I = Slight 2 = Moderate 3 = Serious 4 = Severe * = Chronic hazard Issue Date: 09/09/98 09:52:46 CLW Page I of 8 Revision Date: 10/22/07 4:23 PM SEP

Material Safety Data Sheet Material Name: Sodium Metabisulphite or Sodium Metabisulfite ID: C1-143

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Section 4 - First Aid Measures ***

First Aid: Eyes In case of contact with eyes, rinse immediately with plenty of water for at least 20 minutes. Seek immediate medical attention if any adverse effect occurs.

First Aid: Skin Remove all contaminated clothing. For skin contact, wash thoroughly with soap and water for at least 20 minutes. Seek immediate medical attention if irritation develops or persists.

First Aid: Ingestion Have victim rinse mouth thoroughly with water. DO NOT INDUCE VOMITING. Have victim rinse mouth thoroughly with water, if conscious. Contact a physician or poison control center immediately. Never give anything by mouth to a victim who is unconscious or having convulsions.

First Aid: Inhalation Remove source of contamination or move victim to fresh air. Apply artificial respiration if victim is not breathing. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Administer oxygen if breathing is difficult. Get immediate medical attention.

First Aid: Notes to Physician Provide general supportive measures and treat symptomatically.

Section 5 - Fire Fighting Measures ***

Flash Point: Not flammable Method Used: Not applicable Upper Flammable Limit (UEL): Not applicable Lower Flammable Limit (LEL): Not applicable Auto Ignition: Not applicable Flammability Classification: Not applicable Rate of Burning: Not applicable General Fire Hazards When involved in a fire, this material may decompose and produce irritating vapors, acrid smoke and toxic gases (i.e. sulfur oxides and sodium oxides). Contact with acids, water and ice produces sulfur oxide, which presents a fire hazard due to its flammability.

Sodium Metabisulfite is a reducing agent and reacts explosively with oxidizers.

Hazardous Combustion Products Sodium sulfide and sulfur oxides.

Extinguishing Media In case of fire, use water fog, dry chemical, carbon dioxide or regular foam.

Fire Fighting Equipment/Instructions Firefighters should wear full protective clothing including self-contained breathing apparatus. If possible control runoff from fire control or dilution water to prevent environmental contamination.

NFPA Ratings: Health: 2 Fire: 0 Reactivity: I Other:

Hazard Scale: 0 = Minimal I = Slight 2 = Moderate 3 = Serious 4 = Severe

Section 6 - Accidental Release Measures ***

Containment Procedures Stop the flow of material, if this can be done without risk. Contain the discharged material. If sweeping of a contaminated area is necessary use a dust suppressant agent, which does not react with product (see Section 10 for incompatibility information).

Clean-Up Procedures Small releases can be cleaned-up wearing gloves, goggles and suitable body protection. In case of a large spill (in which excessive dusts can be generated), clear the affected area, protect people, and respond with trained personnel. Place all spill residues in an appropriate container and seal. Thoroughly wash the area after a spill or leak clean-up. Prevent spill rinsate from contamination of storm drains, sewers, soil or groundwater.

Evacuation Procedures Evacuate the area promptly and keep upwind of the spilled material. Isolate the spill area to prevent people from entering. In case of large spills, follow all facility emergency response procedures.

Special Procedures Remove soiled clothing and launder before reuse. Avoid all skin contact with the spilled material. Have emergency equipment readily available.

Issue Date: 09/09/98 09:52:46 CLW Page 2 of 8 Revision Date: 10/22/07 4:23 PM SEP

Material Safety Data Sheet Material Name: Sodium Metabisulphite or Sodium Metabisulfite ID: C1-143

Section 7 - Handling and Storage **

Handling Procedures Do not breathe dust. Avoid all contact with skin and eyes. Use this product only with adequate ventilation. Wash thoroughly after handling. Avoid accumulation of dusts of this product. Remove contaminated clothing immediately. Keep in dust-tight containers. Keep away from all heat sources. Individuals responsible for the procurement, use or application of Sodium Metabisulfite must familiarize themselves with the appropriate safety and handling precautions involved. Specifically, for the prevention of Black Spot on shrimp, Sodium Metabisulfite should only be used as a dilute (1.25%) solution and only in well-ventilated area. NEVER USE SODIUM METABISULFITE IN A DRY FORM DIRECTLY ON THE SHRIMP AND NEVER IN A CONFINED SPACE SUCH AS THE HOLD OF A SHRIMP BOAT OR A WALK-IN COOLER. DEADLY SULFUR DIOXIDE GAS CAN BE GENERATED AND ACCUMULATED IN CONFINED SPACES, CREATING AN EXTREMELY HAZARDOUS CONDITION WHICH CAN CAUSE SUFFOCATION LEADING TO DEATH.

Storage Procedures All employees who handle this material should be trained to handle it safely. Open containers slowly on a stable surface. Containers of this product must be properly labeled. Empty containers may contain residual amounts of this product; therefore, empty containers should be handled with care. Keep this product in an airtight container. Store containers in a cool, dry location, away from direct sunlight, sources of intense heat, or where freezing is possible. Store away from incompatible materials (see Section 10, Stability and Reactivity). Keep container tightly closed when not in use. Inspect all incoming containers before storage to ensure containers are properly labeled and not damaged. Do not store this material in open or unlabeled containers. Limit quantity of material stored.

- - Section 8 - Exposure Controls / Personal Protection Exposure Guidelines A: General Product Information Sulfur Dioxide, which is released slowly at ambient temperatures from this material, has established exposure limits as follows:

ACGIH: 5.2 mg/m 3 TWA 13 mg/m 3 STEL OSHA: 13 mg/m3 TWA; 5 mg/m 3( Vacated 1989 PEL) 13 mg/m3 (Vacated 1989 PEL)

NIOSH: 5 mg/mn3 TWA 13 mg/rn3 STEL 100 ppm (IDLH)

DFG MAKs 5.3 mg/in 3 TWA (Inhalable fraction of the aerosol)

I.MAK 15 min., average value, I-hr interval B: Component Exposure Limits The exposure limits given are for Sodium Metabisulfite (7681-57-4).

ACGIH: 5 mg/m3 TWA NIOSH: 5 mg/m 3 TWA Engineering Controls Use mechanical ventilation such as dilution and local exhaust, necessary for use in enclosed or confined spaces due to the slow release of sulfur dioxide. Use a corrosion-resistant ventilation system and exhaust directly to the outside. Treatment of exhaust gases may be required to prevent environmental contamination. Supply ample air replacement.

PERSONAL PROTECTIVE EQUIPMENT The following infomnation on appropriatePersonalProtective Equipment is provided to assist employers in complying with OSHA regulationsfound in 29 CFR Subpart I (beginning at 1910.132). Please reference applicableregulations and standardsfor relevant details.

Personal Protective Equipment: Eyes/Face Wear safety glasses (or goggles). If necessary, refer to U.S. OSHA 29 CFR 1910.133.

Personal Protective Equipment: Skin Wear impervious gloves, boots and coveralls to avoid skin contact. Gloves should be tested to determine their suitability for prolonged contact with this material. If necessary, refer to U.S. OSHA 29 CFR 1910.138.

Date: 09/09/98 09:52:46 Page 3 of 8 Revision Date: 10/22/07 4:23 PM SEP Issue Date: 09/09/98 09:52:46IssueCLW CLW Page 3 of 8 Revision Date: 10/22/07 4:23 PM SEP

Material Safety Data Sheet Material Name: Sodium Metabisulphite or Sodium Metabisulfite ID: C1-143

- - - Section 8 - Exposure Controls / Personal Protection (Continued)***

Personal Protective Equipment: Respiratory If airborne concentration is high, use an appropriate respirator or dust mask. If airborne concentrations are above the applicable exposure limits, use NIOSH-approved respiratory protection. If respiratory protection is needed, use only protection authorized in the U.S. Federal OSHA Standard (29 CFR 1910.134), applicable U.S. State regulations. Oxygen levels below 19.5% are considered IDLH by OSHA. In such atmospheres, use of a full-facepiece pressure/demand SCBA or a full facepiece, supplied air respirator with auxiliary self-contained air supply is required under OSHA's Respiratory Protection Standard (1910.134-1998).

Personal Protective Equipment: General Wash hands thoroughly after handling material. Do not eat, drink or smoke in work areas. Have a safety shower or eyewash fountain available. Use good hygiene practices when handling this material, including changing and laundering work clothes after use. Discard contaminated shoes and leather goods.

Section 9 - Physical & Chemical Properties ***

Physical Properties: Additional Information The data provided in this section are to be used for product safety handling purposes. Please refer to Product Data Sheets, Certificates of Conformity or Certificates of Analysis for chemical and physical data for determinations of quality and for formulation purposes.

Appearance: White to yellowish crystalline powder Odor: Mild odor of rotten eggs (sulfurous)

Physical State: Solid pH: 4.5-5 (10% solution)

Vapor Pressure: Not applicable Vapor Density: Not applicable Boiling Point: Not applicable Freezing/Melting Point: 302 deg F (150 deg C)

Solubility (H20): 40% @ 20 deg C Specific Gravity: 1.4 (H20 = 1)

Softening Point: Decomposes upon heating Particle Size: Not determined Molecular Weight: 190.13 Bulk Density: 1.48 g/cc Chemical Formula: Na2S205

Section 10 - Chemical Stability & Reactivity Information ***

Chemical Stability Product is normally stable. Sodium Metabisulfite is air and moisture sensitive and releases sulfur dioxide slowly at ambient temperatures. Sodium Metabisulfite will decompose on heating to form sodium sulfate.

Chemical Stability: Conditions to Avoid Avoid moisture, high temperatures, exposure to air and incompatible materials.

Incompatibility This material is incompatible with strong oxidizers, sodium nitrite and alkalis. Sodium Metabisulfite may produce sulfur dioxide gas when in contact with acids and/or water and ice. Large-scale addition of solid sodium disulfite to an unstirred and too-concentrated solution of sodium nitrite may cause a vigorous exothermic reaction.

Hazardous Decomposition Products of thermal decomposition include sodium sulfate, sulfur oxides, and sodium oxide. Products of hydrolysis include sodium dioxide.

Hazardous Polymerization Will not occur.

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Section 11 - Toxicological Information Acute and Chronic Toxicity A: General Product Information May cause eye, skin, nose, throat and respiratory tract irritation. May be harmful if swallowed.

Chronic: Long term skin overexposure to this product may lead to dermatitis (red, itchy skin). Prolonged or repeated contact may cause allergic respiratory and skin reactions in sensitive individuals. Respiratory sensitization can be life-threatening in some cases.

B: Component Analysis - LD50/LC50 Sodium Metabisulfite (7681-57-4):

LD 50-lntravenous-rat: 115 mg/kg; LD 50-Parenteral-mouse: 910 mg/kg; LD 50-Oral-mouse: 5989 mg/kg; LDLo-lntravenous-mouse:

1220 mg/kg; LD 50-lntravenous-rabbit: 1220 mg/kg Issue Date: 09/09/98 09:52:46 CLW Page 4 of 8 Revision Date: 10/22/07 4:23 PM SEP

Material Safety Data Sheet Material Name: Sodium Metabisuiphite or Sodium Metabisulfite ID: C1-143 1 * *

Section 11 - Toxicological Information (Continued) **

Acute and Chronic Toxicity (continued):

B: Component Analysis - TDLo/LDLo Sodium Metabisulfite (7681-57-4):

LDLo-lntravenous-rabbit: 192 mg/kg; TDLo-Oral-rat: 75 mg/kg/I5 days-continuous: Kidney, Urethra, Bladder: other changes; Biochemical: Enzyme inhibition, induction, or change in blood or tissue levels: phosphatases, Enzyme inhibition, induction, or change in blood or tissue levels:- dehydrogenases; TDLo - Oral - pig: 562 gm/kg/48 weeks-continuous: Liver: changes in liver weight Kidney, Urethra, Bladder: changes in bladder weight Nutritional and Gross Metabolic - weight loss or decreased weight gain; TDLo-Oral-rat: 20 gin/kg: multigenerations: Reproductive: Effects on Newborn: stillbirth; TDLo-Oral-rat: 40 gm/kg:

multigenerations: Reproductive: Effects on Newborn: weaning or lactation index (e.g., # alive at weaning per # alive at day 4);

Cytogenetic analysis-hamster Ovary: 180 ag/L; Sister chromatid exchange: Rodent-hamster Ovary: 200 jIg/L; TDLo-Subcutaneous-mouse: 806 mg/kg/26 weeks-intermittent: Tumorigenic: equivocal tumorigenic agent by RTECS criteria Skin and Appendages:

tumors; TDLo-Oral-mouse: 14 gm/kg: female 8-12 day(s) after conception: Reproductive: Effects on Newborn: other neonatal measures or effects; TDLo-Parenteral-imouse: 60 mg/kg: female 8 day(s) after conception: Reproductive: Effects on Embryo or Fetus: fetotoxicity (except death, e.g., stunted fetus), Specific Developmental Abnormalities: musculoskeletal system Carcinogenicity A: General Product Information No information available.

B: Component Carcinogenicity Sodium Metabisulfite (7681-57-4)

ACGIH: TLV-A4 - Not classifiable as a Human Carcinogen Sulfur Dioxide (decomposition product)

ACGIH: TLV-A4 - Not classifiable as a Human Carcinogen IARC: Group 3 - Not classifiable as to carcinogenicity in humans.

Epidemiology Sodium metabisulfite has caused severe allergic reactions in asthmatics and sulfite sensitive individuals.

Neurotoxicity Has not been identified.

Mutagenicity Human mutation data are available for Sodium Metabisulfite, these data were obtained during clinical studies on specific human tissues exposed to high doses of this compound.

Teratogenicity Clinical studies on test animals exposed to relatively high doses of Sodium Metabisulfite provided teratogenic data.

Other Toxicological Information No information available.

S*

- Section 12 - Ecological Information ***

Ecotoxicity A: General Product Information This product is expected to be harmful to aquatic life in low concentration.

B: Ecotoxicity No information available.

Environmental Fate Sodium Metabisulfite:

Water Solubility = 470 g/L (20'C).

Chemical Oxygen Demand (COD) 165 mg oxygen/g compound

Section 13 - Disposal Considerations ***

US EPA Waste Number & Descriptions A: General Product Information Sodium Metabisulfite is considered hazardous to the environment in aqueous solutions. EPA waste number for reactivity (D003) may be applicable to wastes of this product.

Issue Date: 09/09/98 09:52:46 CLW Page 5 of 8 Revision Date: 10/22/07 4:23 PM SEP

Material Safety Data Sheet Material Name: Sodium Metabisulphite or Sodium Metabisulfite ID: C1-143 1*** Section 13 - Disposal Considerations (Continued)

US EPA Waste Number & Descriptions (continued):

B: Component Waste Numbers No EPA Waste Numbers are applicable for this product's components.

Disposal Instructions All wastes must be handled in accordance with local, state and federal regulations or with regulations of Canada and its Provinces.

This product, if unaltered by use, may be disposed of by treatment at a permitted facility or as advised by your local hazardous waste regulatory authority.

Section 14 - Transportation Information NOTE: The shipping classification information in this section (Section 14) is meant as a guide to the overall classification of the product. However, transportation classifications may be subject to change with changes in package size. Consult shipper requirements under I.M.O., I.C.A.O. (I.A.T.A.) and 49 CFR to assure regulatory compliance.

US DOT Information Shipping Name: Not Regulated Hazard Class: Not Classified UN/NA #: Not Classified Packing Group: None Required Label(s): None International Air Transport Association (IATA)

For Shipments by Air transport: We classify this product as hazardous (Class 9) when shipped by air because 49 CFR 173.140 (a).

"For the purposes of this subchapter, miscellaneous hazardous material (Class 9) means a material which presents a hazard during transportation, but which does not meet the definition of any other hazard class. This class includes: (a) Any material which has an anesthetic, noxious, or other similar property which could cause extreme annoyance or discomfort to a flight crew member so as to prevent the correct performance of assigned duties."

UN: UN 3077 Proper Shipping Name: Environmentally hazardous substance, solid, n.o.s. (sodium metabisulfite)

Hazard Class: 9 Packing Group: Ill Passenger & Cargo Aircraft Packing Instruction: 911 Passenger & Cargo Aircraft Maximum Net Quantity: 400 kg Limited Quantity Packing Instruction (Passenger & Cargo Aircraft): Y91 l Limited Quantity Maximum Net Quantity (Passenger & Cargo Aircraft): 30 kg Special Provisions: A97 A 149 ERG Code: 9L International Maritime Organization (I.M.O.) Classification Sodium Metabisulfite is not regulated under I.M.O.

S*** Section 15 - Regulatory Information ***

US Federal Regulations A: General Product Information No additional information.

B: Component Analysis This material does not contain any chemicals required to be identified under SARA Section 302 (40 CFR 355 Appendix A),

SARA Section 313 (40 CFR 372.65) and/or CERCLA (40 CFR 302.4).

SARA 302 There are no specific Threshold Planning Quantities for Sodium Metabisulfite. The default Federal MSDS (EHS TPQ) submission and inventory requirement filing threshold of 10,000 lbs (4,540 kg) therefore applies, per 40 CFR 370.20.

C: Sara 311/312 Tier 11 Hazard Ratings:

Component CAS # Fire Reactivity Pressure Immediate Chronic Hazard Hazard Hazard Health Hazard Health Hazard Sodium Metabisulfite 7681-57-4 No Yes No Yes Yes Issue Date: 09/09/98 09:52:46 CLW Page 6 of 8 Revision Date: 10/22/07 4:23 PM SEP

Material Safety Data Sheet Material Name: Sodium Metabisulphite or Sodium Metabisulfite ID: C1-143

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Section 15 - Regulatory Information (Continued) ***

US Federal Regulations (continued)

U.S. State Regulations A: General Product Information California Proposition 65 Sodium Metabisulfite is not on the California Proposition 65 chemical lists.

B: Component Analysis - State The following components appear on one or more of the following state hazardous substance lists:

Component ICAS # CA FL MA IMN INJ PA Sodium Metabisulfite 7681-57-4 Yes Yes Yes Yes Yes No Other Regulations A: General Product Information No other information available.

B: Component Analysis - Inventory Component ICAS # TSCA DSL EINECS ISodium Metabisulfite 17681-57-4 1Yes IYes IYes C: Component Analysis - WHMIS IDL The following components are identified under the Canadian Hazardous Products Act Ingredient Disclosure List:

Com onent CAS # I Minimum Concentration Sodium Metabisulfite 7681-57-4 1 percent ANSI LABELING (Z129.1):

WARNING! MAY BE FATAL IF SWALLOWED. CAUSES SKIN AND EYE IRRITATION. HARMFUL IF INHALED. MAY CAUSE ALLERGIC SKIN AND SEVERE RESPIRATORY REACTION. RESPIRATORY REACTIONS MAY BE LIFE-THREATENING. Keep from contact with clothing. Do not taste or swallow. Do not get on skin or in eyes. Avoid breathing dusts or particulates. Avoid prolonged or repeated contact with skin. Keep container closed. Use only with adequate ventilation. Wash thoroughly after handling. Wear gloves, goggles, faceshields, suitable body protection, and NIOSH/MSHA-approved respiratory protection, as appropriate. FIRST-AID: In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. If inhaled, remove to fresh air. If ingested, do not induce vomiting. Get medical attention. IN CASE OF FIRE: Use water fog, dry chemical, CO 2, or "alcohol" foam. IN CASE OF SPILL: Absorb spill with inert material. Place residue in suitable container. Consult Material Safety Data Sheet for additional information.

Issue Date: 09/09/98 09:52:46 CLW Page 7 of 8 Revision Date: 10/22/07 4:23 PM SEP

Material Safety Data Sheet Material Name: Sodium Metabisulphite or Sodium Metabisulfite ID: C1-143

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Section 16 - Other Information ***

Other Information Chem One Ltd. ("Chem One") shall not be responsible for the use of any information, product, method, or apparatus herein presented ("Information"), and you must make your own determination as to its suitability and completeness for your own use, for the protection of the environment, and for health and safety purposes. You assume the entire risk of relying on this Information.

In no event shall Chem One be responsible for damages of any nature whatsoever resulting from the use of this product or products, or reliance upon this Infonnation. By providing this Information, Chem One neither can nor intends to control the method or manner by which you use, handle, store, or transport Chem One products. If any materials are mentioned that are riot Chem One products, appropriate industrial hygiene and other safety precautions recommended by their manufacturers should be observed. Chem One makes no representations or warranties, either express or implied of merchantability, fitness for a particular purpose or of any other nature regarding this information, and nothing herein waives any of Chem One's conditions of sale. This information could include technical inaccuracies or typographical errors. Chem One may make improvements and/or changes in the product (s) and/or the program (s) described in this information at any time. If you have any questions, please contact us at Tel. 713-896-9966 or E-mail us at Safetvl chemone.com.

Key/Legend EPA = Environmental Protection Agency; TSCA = Toxic Substance Control Act; ACGIH = American Conference of Governmental Industrial Hygienists; IARC = International Agency for Research on Cancer; NIOSH = National Institute for Occupational Safety and Health; NTP = National Toxicology Program; OSHA = Occupational Safety and Health Administration

Contact:

Sue Palmer-Koleman, PhD Contact Phone: (713) 896-9966 Revision Log 08/28/00 4:23 PM SEP Changed company name, Sect I and 16, from Corporation to Ltd.

06/02/01 9:31 AM HDF Checked exposure limits; made changes to Sect 9; overall review, add SARA 311/312 Haz Ratings.

08/20/01 3:20 PM CLJ Add Shipments by Air information to Section 14, Changed contact to Sue, non-800 Chemtrec Num.

02/18/02 11:13 AM HDF Up-date of SARA Hazard Ratings.

11/20/03 11:50 AM HDF General review and up-date of entire MSDS. Up-graded Section 10 Reactivity Information. Up-date of HMIS categories. Up-date of Section 8. Up-date of Section 14.

06/22/05 1:18 pm SEP Updated IATA Section 14 10/22/07 4:23 PM SEP Updated IATA Section 14 This is the end of MSDS # C1-143 Issue Date: 09/09/98 09:52:46 CLW Page 8 of 8 Revision Date: 10/22/07 4:23 PM SEP

MATERIAL SAFETY DATA SHEET P:4fNALCO )04" ALCOPRODUCT Nalco 73551 EMERGENCY TELEPHONE NUMBER(S)

(800) 424-9300 (24 Hours) CHEMTREC

11. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: Nalco 73551 APPLICATION: DEPOSIT PENETRANT COMPANY IDENTIFICATION: Nalco Company 1601 W. Diehl Road Naperville, Illinois 60563-1198 EMERGENCY TELEPHONE NUMBER(S): (800) 424-9300 (24 Hours) CHEMTREC NFPA 704M/HMIS RATING HEALTH: 0/1 FLAMMABILITY: 1/1 INSTABILITY: 0/0 OTHER:

0 = Insignificant 1 = Slight 2 = Moderate 3 = High 4 = Extreme

12. 1COMPOSITION/INFORMATION ON INGREDIENTS Based on our hazard evaluation, none of the substances in this product are hazardous.

13. 1 HAZARDS IDENTIFICATION

- EMERGENCY OVERVIEW**

CAUTION May cause irritation with prolonged contact.

Do not get in eyes, on skin, on clothing. Do not take internally. Wear suitable protective clothing. Keep container tightly closed. Flush affected area with water.

May evolve oxides of carbon (COx) under fire conditions.

PRIMARY ROUTES OF EXPOSURE:

Eye, Skin HUMAN HEALTH HAZARDS - ACUTE:

EYE CONTACT:

May cause irritation with prolonged contact.

SKIN CONTACT:

May cause irritation with prolonged contact.

INGESTION:

Not a likely route of exposure. No adverse effects expected.

INHALATION:

Not a likely route of exposure. No adverse effects expected.

Nalco Company 1601 W. Diehl Road

Naperville, Illinois 60563-1198 - (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 1/9

MATERIAL SAFETY DATA SHEET A NALCO PRODUCT Nalco 73551 EMERGENCY TELEPHONE NUMBER(S)

(800) 424-9300 (24 Hours) CHEMTREC SYMPTOMS OF EXPOSURE:

Acute :

A review of available data does not identify any symptoms from exposure not previously mentioned.

Chronic :

A review of available data does not identify any symptoms from exposure not previously mentioned.

AGGRAVATION OF EXISTING CONDITIONS:

A review of available data does not identify any worsening of existing conditions.

4. FIRST AID MEASURES EYE CONTACT:

Flush affected area with water. If symptoms develop, seek medical advice.

SKIN CONTACT:

Flush affected area with water. If symptoms develop, seek medical advice.

INGESTION:

Do not induce vomiting without medical advice. If conscious, washout mouth and give water to drink. If symptoms develop, seek medical advice.

INHALATION:

Remove to fresh air, treat symptomatically. If symptoms develop, seek medical advice.

NOTE TO PHYSICIAN:

Based on the individual reactions of the patient, the physician's judgement should be used to control symptoms and clinical condition.

15. 1FIRE FIGHTING MEASURES FLASH POINT: > 400 °F / > 200 °C (COC)

EXTINGUISHING MEDIA:

This product would not be expected to burn unless all the water is boiled away. The remaining organics may be ignitable. Use extinguishing media appropriate for surrounding fire.

FIRE AND EXPLOSION HAZARD:

May evolve oxides of carbon (COx) under fire conditions.

SPECIAL PROTECTIVE EQUIPMENT FOR FIRE FIGHTING:

In case of fire, wear a full face positive-pressure self contained breathing apparatus and protective suit.

16. ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS:

Do not touch spilled material. Restrict access to area as appropriate until clean-up operations are complete. Use personal protective equipment recommended in Section 8 (Exposure Controls/Personal Protection). Stop or reduce any leaks if it is safe to do so. Ventilate spill area if possible.

Nalco Company 1601 W. Diehl Road - Naperville, Illinois 60563-1198 - (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 2/9

MATERIAL SAFETY DATA SHEET NALCOAV NALCOPRODUCT .oo Nalco 73551 EMERGENCY TELEPHONE NUMBER(S)

(800) 424-9300 (24 Hours) CHEMTREC METHODS FOR CLEANING UP:

SMALL SPILLS: Soak up spill with absorbent material. Place residues in a suitable, covered, properly labeled container. Wash affected area. LARGE SPILLS: Contain liquid using absorbent material, by digging trenches or by diking. Reclaim into recovery or salvage drums or tank truck for proper disposal. Contact an approved waste hauler for disposal of contaminated recovered material. Dispose of material in compliance with regulations indicated in Section 13 (Disposal Considerations).

ENVIRONMENTAL PRECAUTIONS:

Do not contaminate surface water.

17. 1 HANDLING AND STORAGE HANDLING:

Avoid eye and skin contact. Do not take internally. Ensure all containers are labelled. Keep the containers closed when not in use.

STORAGE CONDITIONS:

Store the containers tightly closed.

18. 1 EXPOSURE CONTROLS/PERSONAL PROTECTION OCCUPATIONAL EXPOSURE LIMITS:

This product does not contain any substance that has an established exposure limit.

ENGINEERING MEASURES:

General ventilation is recommended.

RESPIRATORY PROTECTION:

Respiratory protection is not normally needed.

HAND PROTECTION:

Neoprene gloves, Nitrile gloves, Butyl gloves, PVC gloves SKIN PROTECTION:

Wear standard protective clothing.

EYE PROTECTION:

Wear chemical splash goggles.

HYGIENE RECOMMENDATIONS:

Keep an eye wash fountain available. Keep a safety shower available. If clothing is contaminated, remove clothing and thoroughly wash the affected area. Launder contaminated clothing before reuse.

19. 1 PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL STATE Liquid Nalco Company 1601 W. Diehl Road - Naperville, Illinois 60563-1198 * (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 3/9

MATERIAL SAFETY DATA SHEET AVNALCO EMERGENCY TELEPHONE NUMBER(S)

(800) 424-9300 (24 Hours) CHEMTREC APPEARANCE Clear Colorless ODOR None SPECIFIC GRAVITY 0.99 - 1.03 @ 77 'F / 25 -C SOLUBILITY IN WATER Complete pH (100 %) 6.6- 7.0 Note: These physical properties are typical values for this product and are subject to change.

10. 1STABILITY AND REACTIVITY STABILITY:

Stable under normal conditions.

HAZARDOUS POLYMERIZATION:

Hazardous polymerization will not occur.

CONDITIONS TO AVOID:

Freezing temperatures.

MATERIALS TO AVOID:

None known HAZARDOUS DECOMPOSITION PRODUCTS:

Under fire conditions: Oxides of carbon 111.1 TOXICOLOGICAL INFORMATIONI The following results are for the polymer.

ACUTE ORAL TOXICITY:

Species LD50 Test Descriptor Rat 2,300 - 16,000 mg/kg The following results are for the polymer.

Rating : Non-Hazardous CARCINOGENICITY:

None of the substances in this product are listed as carcinogens by the International Agency for Research on Cancer (IARC), the National Toxicology Program (NTP) or the American Conference of Governmental Industrial Hygienists (ACGIH).

HUMAN HAZARD CHARACTERIZATION:

Based on our hazard characterization, the potential human hazard is: Low 112. 1ECOLOGICAL INFORMATION ECOTOXICOLOGICAL EFFECTS:

Nalco Company 1601 W. Diehl Road

Naperville, Illinois 60563-1198 - (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 4/9

MATERIAL SAFETY DATA SHEET 0 NALCO PRODUCT Nalco 73551 EMERGENCY TELEPHONE NUMBER(S)

(800) 424-9300 (24 Hours) CHEMTREC The following results are for the product.

ACUTE FISH RESULTS:

Species Exposure LC50 Test Descriptor Rainbow Trout 96 hrs > 1,000 mg/I Product Bluegill Sunfish 96 hrs > 1,000 mg/I Product Fathead Minnow 96 hrs 996 mg/I Product d ACUTE INVERTEBRATE RESULTS:

Species Exposure LC50 EC50 Test Descriptor Daphnia magna 48 hrs > 1,000 mg/I Product Ceriodaphnia dubia 48 hrs 1,320 mo/l Product CHRONIC FISH RESULTS:

Species Exposure NOEC / LOEC End Point Test Descriptor Fathead Minnow 7 Days 250 mg/I / 500 mg/I Reproduction Product CHRONIC INVERTEBRATE RESULTS:

Species Test Type NOEC / LOEC End Point Test Descriptor Ceriodaphnia dubia 3 Brood 125 mg/I / 250 mg/I Reproduction Product PERSISTENCY AND DEGRADATION:

Total Organic Carbon (TOC): 85,000 mg/I Chemical Oxygen Demand (COD): 250,000 mg/I Biological Oxygen Demand (BOD):

Incubation Period Value Test Descriptor 5d 4 mg/l Product ENVIRONMENTAL HAZARD AND EXPOSURE CHARACTERIZATION Based on our hazard characterization, the potential environmental hazard is: Low If released into the environment, see CERCLA/SUPERFUND in Section 15.

113. 1 DISPOSAL CONSIDERATIONS If this product becomes a waste, it is not a hazardous waste as defined by the Resource Conservation and Recovery Act (RCRA) 40 CFR 261, since it does not have the characteristics of Subpart C, nor is it listed under Subpart D.

As a non-hazardous waste, it is not subject to federal regulation. Consult state or local regulation for any additional handling, treatment or disposal requirements. For disposal, contact a properly licensed waste treatment, storage, disposal or recycling facility.

Nalco Company 1601 W. Diehl Road

Naperville, Illinois 60563-1198 * (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 5/9

MATERIAL SAFETY DATA SHEET 04NALCO PRODUCT Nalco 73551 EMERGENCY TELEPHONE NUMBER(S)

(800) 424-9300 (24 Hours) CHEMTREC 114. I TRANSPORT INFORMATION I The information in this section is for reference only and should not take the place of a shipping paper (bill of lading) specific to an order. Please note that the proper Shipping Name / Hazard Class may vary by packaging, properties, and mode of transportation. Typical Proper Shipping Names for this product are as follows.

LAND TRANSPORT:

Proper Shipping Name: PRODUCT IS NOT REGULATED DURING TRANSPORTATION AIR TRANSPORT (ICAO/IATA):

Proper Shipping Name: PRODUCT IS NOT REGULATED DURING TRANSPORTATION MARINE TRANSPORT (IMDG/IMO):

Proper Shipping Name : PRODUCT IS NOT REGULATED DURING TRANSPORTATION 115. I REGULATORY INFORMATION I NATIONAL REGULATIONS, USA:

OSHA HAZARD COMMUNICATION RULE, 29 CFR 1910.1200:

Based on our hazard evaluation, none of the substances in this product are hazardous.

CERCLAISUPERFUND, 40 CFR 117, 302:

Notification of spills of this product is not required.

SARA/SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (TITLE Ill) - SECTIONS 302, 311, 312, AND 313:

SECTION 302 - EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355):

This product does not contain substances listed in Appendix A and B as an Extremely Hazardous Substance.

SECTIONS 311 AND 312 - MATERIAL SAFETY DATA SHEET REQUIREMENTS (40 CFR 370):

Our hazard evaluation has found that this product is not hazardous under 29 CFR 1910.1200.

Under SARA 311 and 312, the EPA has established threshold quantities for the reporting of hazardous chemicals.

The current thresholds are: 500 pounds or the threshold planning quantity (TPQ), whichever is lower, for extremely hazardous substances and 10,000 pounds for all other hazardous chemicals.

SECTION 313 - LIST OF TOXIC CHEMICALS (40 CFR 372):

This product does not contain substances on the List of Toxic Chemicals.

Nalco Company 1601 W. Diehl Road

Naperville, Illinois 60563-1198 * (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 6/9

MATERIAL SAFETY DATA SHEET AVNALCO PRODUCT Nalco 73551 EMERGENCY TELEPHONE NUMBER(S)

(800) 424-9300 (24 Hours) CHEMTREC TOXIC SUBSTANCES CONTROL ACT (TSCA):

The substances in this preparation are included on or exempted from the TSCA 8(b) Inventory (40 CFR 710)

FOOD AND DRUG ADMINISTRATION (FDA) Federal Food, Drug and Cosmetic Act:

When use situations necessitate compliance with FDA regulations, this product is acceptable under : 21 CFR 173.340 Defoaming Agents, 21 CFR 175.105 Adhesives, 21 CFR 176.200 Defoaming Agents used in coatings, 21 CFR 176.210 Defoaming agents used in the manufacture of paper and paperboard, 21 CFR 177.1200 Cellophane, 21 CFR 177.1400 Hydroxyethyl cellulose film, water-insoluble, 21 CFR 176.300 Slimicides, 21 CFR 178.3120 -

Animal glue Limitations: no more than required to produce intended technical effect.

NSF NON-FOOD COMPOUNDS REGISTRATION PROGRAM (former USDA List of Proprietary Substances & Non-Food Compounds):

NSF Registration number for this product is : 137540 This product is acceptable for treatment of cooling and retort water (G5) in and around food processing areas.

This product has been certified as KOSHER/PAREVE for year-round use INCLUDING THE PASSOVER SEASON by the CHICAGO RABBINICAL COUNCIL.

FEDERAL WATER POLLUTION CONTROL ACT, CLEAN WATER ACT, 40 CFR 401.15 / formerly Sec. 307,40 CFR 116.4 / formerly Sec. 311 :

None of the substances are specifically listed in the regulation.

CLEAN AIR ACT, Sec. 112 (40 CFR 61, Hazardous Air Pollutants), Sec. 602 (40 CFR 82, Class I and II Ozone Depleting Substances) :

None of the substances are specifically listed in the regulation.

CALIFORNIA PROPOSITION 65:

This product does not contain substances which require warning under California Proposition 65.

MICHIGAN CRITICAL MATERIALS:

None of the substances are specifically listed in the regulation.

STATE RIGHT TO KNOW LAWS:

The following substances are disclosed for compliance with State Right to Know Laws:

Water 7732-18-5 Polyalkylene glycol Proprietary NATIONAL REGULATIONS, CANADA:

WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM (WHMIS):

This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR.

WHMIS CLASSIFICATION:

Not considered a WHMIS controlled product.

Nalco Company 1601 W. Diehl Road

Naperville, Illinois 60563-1198 - (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 7/9

MATERIAL SAFETY DATA SHEET

)4NALCO PRODUCT Nalco 73551 EMERGENCY TELEPHONE NUMBER(S)

(800) 424-9300 (24 Hours) CHEMTREC CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA):

The substances in this preparation are listed on the Domestic Substances List (DSL), are exempt, or have been reported in accordance with the New Substances Notification Regulations.

116. 1 OTHER INFORMATION Due to our commitment to Product Stewardship, we have evaluated the human and environmental hazards and exposures of this product. Based on our recommended use of this product, we have characterized the product's general risk. This information should provide assistance for your own risk management practices. We have evaluated our product's risk as follows:

" The human risk is: Low

The environmental risk is: Low Any use inconsistent with our recommendations may affect the risk characterization. Our sales representative will assist you to determine if your product application is consistent with our recommendations. Together we can implement an appropriate risk management process.

This product material safety data sheet provides health and safety information. The product is to be used in applications consistent with our product literature. Individuals handling this product should be informed of the recommended safety precautions and should have access to this information. For any other uses, exposures should be evaluated so that appropriate handling practices and training programs can be established to insure safe workplace operations. Please consult your local sales representative for any further information.

REFERENCES Threshold Limit Values for Chemical Substances and Physical Agents and Biological Exposure Indices, American Conference of Governmental Industrial Hygienists, OH., (Ariel Insight# CD-ROM Version), Ariel Research Corp.,

Bethesda, MD.

Hazardous Substances Data Bank, National Library of Medicine, Bethesda, Maryland (TOMES CPS# CD-ROM Version), Micromedex, Inc., Englewood, CO.

IARC Monographs on the Evaluation of the Carcinogenic Risk of Chemicals to Man, Geneva: World Health Organization, International Agency for Research on Cancer.

Integrated Risk Information System, U.S. Environmental Protection Agency, Washington, D.C. (TOMES CPS# CD-ROM Version), Micromedex, Inc., Englewood, CO.

Annual Report on Carcinogens, National Toxicology Program, U.S. Department of Health and Human Services, Public Health Service.

Title 29 Code of Federal Regulations, Part 1910, Subpart Z, Toxic and Hazardous Substances, Occupational Safety and Health Administration (OSHA), (Ariel Insight# CD-ROM Version), Ariel Research Corp., Bethesda, MD.

Registry of Toxic Effects of Chemical Substances, National Institute for Occupational Safety and Health, Cincinnati, OH, (TOMES CPS# CD-ROM Version), Micromedex, Inc., Englewood, CO.

Nalco Company 1601 W. Diehl Road - Naperville, Illinois 60563-1198 - (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 8/9

MATERIAL SAFETY DATA SHEET 04NALCO EMERGENCY TELEPHONE NUMBER(S)

(800) 424-9300 (24 Hours) CHEMTREC Ariel Insight# (An integrated guide to industrial chemicals covered under major regulatory and advisory programs),

North American Module, Western European Module, Chemical Inventories Module and the Generics Module (Ariel Insight# CD-ROM Version), Ariel Research Corp., Bethesda, MD.

The Teratogen Information System, University of Washington, Seattle, WA (TOMES CPS# CD-ROM Version),

Micromedex, Inc., Englewood, CO.

Prepared By: Product Safety Department Date issued: 05/08/2006 Version Number: 1.12 Nalco Company 1601 W. Diehl Road

Naperville, Illinois 60563-1198 * (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 9/9

MATERIAL SAFETY DATA SHEET 04NALCO PRODUCT 3D TRASAR 3DT195 EMERGENCY TELEPHONE NUMBER(S)

(800) 424-9300 (24 Hours) CHEMTREC

11. 1 CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: 3D TRASAR 3DT195 COMPANY IDENTIFICATION: Nalco Company 1601 W. Diehl Road Naperville, Illinois 60563-1198 EMERGENCY TELEPHONE NUMBER(S): (800) 424-9300 (24 Hours) CHEMTREC NFPA 704M/HMIS RATING HEALTH: 0/1 FLAMMABILITY: 1/1 INSTABILITY: 0/0 OTHER:

0 = Insignificant 1 = Slight 2 = Moderate 3 = High 4 = Extreme

12. 1 COMPOSITION/INFORMATION ON INGREDIENTS Based on our hazard evaluation, none of the substances in this product are hazardous.

Hazardous Substance(s) CAS NO % (w/w)

13. 1HAZARDS IDENTIFICATION

- EMERGENCY OVERVIEW**

CAUTION May cause irritation with prolonged contact.

Do not get in eyes, on skin, on clothing. Do not take internally. Use with adequate ventilation. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. After contact with skin, wash immediately with plenty of water.

Wear suitable protective clothing.

May evolve oxides of carbon (COx) under fire conditions. May evolve oxides of sulfur (SOx) under fire conditions.

PRIMARY ROUTES OF EXPOSURE:

Eye, Skin HUMAN HEALTH HAZARDS - ACUTE:

EYE CONTACT:

No adverse effects expected.

SKIN CONTACT:

No adverse effects expected.

INGESTION:

Not a likely route of exposure. No adverse effects expected.

Nalco Company 1601 W. Diehl Road

Naperville, Illinois 60563-1198 * (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 1/9

MATERIAL SAFETY DATA SHEET

)4NALCO PRODUCT 3D TRASAR 3DT195 EMERGENCY TELEPHONE NUMBER(S)

(800) 424-9300 (24 Hours) CHEMTREC INHALATION:

Not a likely route of exposure. No adverse effects expected.

SYMPTOMS OF EXPOSURE:

Acute :

A review of available data does not identify any symptoms from exposure not previously mentioned.

Chronic :

A review of available data does not identify any symptoms from exposure not previously mentioned.

14. 1 FIRST AID MEASURES EYE CONTACT:

Flush affected area with water. If symptoms develop, seek medical advice.

SKIN CONTACT:

Flush affected area with water. If symptoms develop, seek medical advice.

INGESTION:

Get medical attention. Do not induce vomiting without medical advice. If conscious, washout mouth and give water to drink.

INHALATION:

Remove to fresh air, treat symptomatically. If symptoms develop, seek medical advice.

NOTE TO PHYSICIAN:

Based on the individual reactions of the patient, the physician's judgement should be used to control symptoms and clinical condition.

15. 1 FIRE FIGHTING MEASURES FLASH POINT: Not applicable EXTINGUISHING MEDIA:

This product would not be expected to burn unless all the water is boiled away. The remaining organics may be ignitable. Use extinguishing media appropriate for surrounding fire.

FIRE AND EXPLOSION HAZARD:

May evolve oxides of carbon (COx) under fire conditions. May evolve oxides of sulfur (SOx) under fire conditions.

SPECIAL PROTECTIVE EQUIPMENT FOR FIRE FIGHTING:

In case of fire, wear a full face positive-pressure self contained breathing apparatus and protective suit.

16. 1 ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS:

Restrict access to area as appropriate until clean-up operations are complete. Use personal protective equipment recommended in Section 8 (Exposure Controls/Personal Protection). Stop or reduce any leaks if it is safe to do so.

Ventilate spill area if possible.

Nalco Company 1601 W. Diehl Road

Naperville, Illinois 60563-1198 * (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 2/9

MATERIAL SAFETY DATA SHEET NALCO AWNALCOPRODUCT .oo 3D TRASAR 3DT195 EMERGENCY TELEPHONE NUMBER(S)

(800) 424-9300 (24 Hours) CHEMTREC METHODS FOR CLEANING UP:

SMALL SPILLS: Soak up spill with absorbent material. Place residues in a suitable, covered, properly labeled container. Wash affected area. LARGE SPILLS: Contain liquid using absorbent material, by digging trenches or by diking. Reclaim into recovery or salvage drums or tank truck for proper disposal. Clean contaminated surfaces with water or aqueous cleaning agents. Contact an approved waste hauler for disposal of contaminated recovered material. Dispose of material in compliance with regulations indicated in Section 13 (Disposal Considerations).

ENVIRONMENTAL PRECAUTIONS:

Do not contaminate surface water.

17. 1 HANDLING AND STORAGE HANDLING:

Do not get in eyes, on skin, on clothing. Do not take internally. Use with adequate ventilation. Do not breathe vapors/gases/dust. Keep the containers closed when not in use. Have emergency equipment (for fires, spills, leaks, etc.) readily available. Ensure all containers are labeled.

STORAGE CONDITIONS:

Store in suitable labeled containers. Store the containers tightly closed.

SUITABLE CONSTRUCTION MATERIAL:

Neoprene, EPDM, Epoxy phenolic resin, Buna-N, Polyurethane, Hypalon, Polyethylene, HDPE (high density polyethylene), Viton, Compatibility with Plastic Materials can vary; we therefore recommend that compatibility is tested prior to use., PVC UNSUITABLE CONSTRUCTION MATERIAL:

Brass, Stainless Steel 304, Stainless Steel 316L, 100% phenolic resin liner

18. 1 EXPOSURE CONTROLS/PERSONAL PROTECTION OCCUPATIONAL EXPOSURE LIMITS:

This product does not contain any substance that has an established exposure limit.

ENGINEERING MEASURES:

General ventilation is recommended.

RESPIRATORY PROTECTION:

Respiratory protection is not normally needed.

HAND PROTECTION:

When handling this product, the use of chemical gloves is recommended., The choice of work glove depends on work conditions and what chemicals are handled, but we have positive experience under light handling conditions using gloves made from, PVC, Gloves should be replaced immediately if signs of degradation are observed.,

Breakthrough time not determined as preparation, consult PPE manufacturers.

SKIN PROTECTION:

Wear standard protective clothing.

Nalco Company 1601 W. Diehl Road

Naperville, Illinois 60563-1198 * (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 3/9

MATERIAL SAFETY DATA SHEET 04NALCO (800) 424-9300 (24 Hours) CHEMTREC EYE PROTECTION:

Wear safety glasses with side-shields.

HYGIENE RECOMMENDATIONS:

Use good work and personal hygiene practices to avoid exposure. Consider the provision in the work area of a safety shower and eyewash. Always wash thoroughly after handling chemicals. When handling this product never eat, drink or smoke.

19. 1PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL STATE Liquid APPEARANCE Clear Orange ODOR Mild SPECIFIC GRAVITY 1.25 @ 60 °F / 15.6 °C DENSITY 10.39 lb/gal SOLUBILITY IN WATER Complete pH (100 %) 4.7 VISCOSITY 84 cps @ 77 'F / 25 'C VAPOR PRESSURE 16 mm Hg @ 100 °F/38 °C Note: These physical properties are typical values for this product and are subject to change.

110. 1STABILITY AND REACTIVITY STABILITY:

Stable under normal conditions.

HAZARDOUS POLYMERIZATION:

Hazardous polymerization will not occur.

CONDITIONS TO AVOID:

Extremes of temperature MATERIALS TO AVOID:

Contact with strong oxidizers (e.g. chlorine, peroxides, chromates, nitric acid, perchlorate, concentrated oxygen, permanganate) may generate heat, fires, explosions and/or toxic vapors.

HAZARDOUS DECOMPOSITION PRODUCTS:

Under fire conditions: Oxides of carbon, Oxides of sulfur

11. 1 TOXICOLOGICAL INFORMATION No toxicity studies have been conducted on this product.

Nalco Company 1601 W. Diehl Road - Naperville, Illinois 60563-1198 * (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 4/9

MATERIAL SAFETY DATA SHEET

)4NALCO PRODUCT 3D TRASAR 3DT195 EMERGENCY TELEPHONE NUMBER(S)

(800) 424-9300 (24 Hours) CHEMTREC SENSITIZATION:

This product is not expected to be a sensitizer.

CARCINOGENICITY:

None of the substances in this product are listed as carcinogens by the International Agency for Research on Cancer (IARC), the National Toxicology Program (NTP) or the American Conference of Governmental Industrial Hygienists (ACGIH).

HUMAN HAZARD CHARACTERIZATION:

Based on our hazard characterization, the potential human hazard is: Low 112. 1 ECOLOGICAL INFORMATION ECOTOXICOLOGICAL EFFECTS:

The following results are for the product.

ACUTE FISH RESULTS:

Species Exposure LC50 Test Descriptor Fathead Minnow 96 hrs 4,000 mg/I Product Rainbow Trout 96 hrs 2,222 mg/I Product ACUTE INVERTEBRATE RESULTS:

Sspecies Exposure LC50 EC50 Test Descriptor Daphnia magna 48 hrs 921 mg/I Product PERSISTENCY AND DEGRADATION:

Total Organic Carbon (TOC): 120,000 mg/I Chemical Oxygen Demand (COD): 310,000 mg/I Biological Oxygen Demand (BOD):

Incubation Period Value Test Descriptor 5d 7,320 m/II Product The organic portion of this preparation is expected to be poorly biodegradable.

MOBILITY:

The environmental fate was estimated using a level III fugacity model embedded in the EPI (estimation program interface) Suite TM , provided by the US EPA. The model assumes a steady state condition between the total input and output. The level III model does not require equilibrium between the defined media. The information provided is intended to give the user a general estimate of the environmental fate of this product under the defined conditions of the models. If released into the environment this material is expected to distribute to the air, water and soil/sediment in the approximate respective percentages; Air Water Soil/Sediment

<5% 10-30% 50-70%

Nalco Company 1601 W. Diehl Road

Naperville, Illinois 60563-1198 * (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 5/9

MATERIAL SAFETY DATA SHEET

)4NALCO EMERGENCY TELEPHONE NUMBER(S)

(800) 424-9300 (24 Hours) CHEMTREC The portion in water is expected to be soluble or dispersible.

BIOACCUMULATION POTENTIAL This preparation or material is not expected to bioaccumulate.

ENVIRONMENTAL HAZARD AND EXPOSURE CHARACTERIZATION Based on our hazard characterization, the potential environmental hazard is: Low If released into the environment, see CERCLA/SUPERFUND in Section 15.

113. I DISPOSAL CONSIDERATIONS I If this product becomes a waste, it is not a hazardous waste as defined by the Resource Conservation and Recovery Act (RCRA) 40 CFR 261, since it does not have the characteristics of Subpart C, nor is it listed under Subpart D.

As a non-hazardous waste, it is not subject to federal regulation. Consult state or local regulation for any additional handling, treatment or disposal requirements. For disposal, contact a properly licensed waste treatment, storage, disposal or recycling facility.

114. I TRANSPORT INFORMATION I The information in this section is for reference only and should not take the place of a shipping paper (bill of lading) specific to an order. Please note that the proper Shipping Name / Hazard Class may vary by packaging, properties, and mode of transportation. Typical Proper Shipping Names for this product are as follows.

LAND TRANSPORT:

Proper Shipping Name : PRODUCT IS NOT REGULATED DURING TRANSPORTATION AIR TRANSPORT (ICAO/IATA):

Proper Shipping Name: PRODUCT IS NOT REGULATED DURING TRANSPORTATION MARINE TRANSPORT (IMDG/IMO):

Proper Shipping Name: PRODUCT IS NOT REGULATED DURING TRANSPORTATION

15. 1REGULATORY INFORMATION NATIONAL REGULATIONS, USA:

OSHA HAZARD COMMUNICATION RULE, 29 CFR 1910.1200:

Based on our hazard evaluation, none of the substances in this product are hazardous.

Nalco Company 1601 W. Diehl Road - Naperville, Illinois 60563-1198 - (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 6/9

MATERIAL SAFETY DATA SHEET

)NALCO PRODUC 3D TRASAR 3DT195 EMERGENCY TELEPHONE NUMBER(S)

(800) 424-9300 (24 Hours) CHEMTREC CERCLA/SUPERFUND, 40 CFR 117,302:

Notification of spills of this product is not required.

SARA/SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (TITLE Ill) - SECTIONS 302, 311, 312, AND 313:

SECTION 302 - EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355):

This product does not contain substances listed in Appendix A and B as an Extremely Hazardous Substance.

SECTIONS 311 AND 312 - MATERIAL SAFETY DATA SHEET REQUIREMENTS (40 CFR 370):

Our hazard evaluation has found that this product is not hazardous under 29 CFR 1910.1200.

Under SARA 311 and 312, the EPA has established threshold quantities for the reporting of hazardous chemicals.

The current thresholds are: 500 pounds or the threshold planning quantity (TPQ), whichever is lower, for extremely hazardous substances and 10,000 pounds for all other hazardous chemicals.

SECTION 313 - LIST OF TOXIC CHEMICALS (40 CFR 372):

This product does not contain substances on the List of Toxic Chemicals.

TOXIC SUBSTANCES CONTROL ACT (TSCA):

The substances in this preparation are included on or exempted from the TSCA 8(b) Inventory (40 CFR 710)

FEDERAL WATER POLLUTION CONTROL ACT, CLEAN WATER ACT, 40 CFR 401.15 / formerly Sec. 307, 40 CFR 116.4 / formerly Sec. 311 :

None of the substances are specifically listed in the regulation.

CLEAN AIR ACT, Sec. 112 (40 CFR 61, Hazardous Air Pollutants), Sec. 602 (40 CFR 82, Class I and II Ozone Depleting Substances) :

This product may contain trace levels (<0.1% for carcinogens, <1% all other substances) of the following substance(s) listed under the regulation:

Substance(s) Citations 0 Methanol Sec. 111, Sec. 112 CALIFORNIA PROPOSITION 65:

This product does not contain substances which require warning under California Proposition 65.

MICHIGAN CRITICAL MATERIALS:

None of the substances are specifically listed in the regulation.

STATE RIGHT TO KNOW LAWS:

None of the substances are specifically listed in the regulation.

NATIONAL REGULATIONS, CANADA:

Nalco Company 1601 W. Diehl Road

Naperville, Illinois 60563-1198 * (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 7/9

MATERIAL SAFETY DATA SHEET 04NALCO PRODUCT 3D TRASAR 3DT195 EMERGENCY TELEPHONE NUMBER(S)

(800) 424-9300 (24 Hours) CHEMTREC WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM (WHMIS):

This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR.

WHMIS CLASSIFICATION:

D2A - Materials Causing Other Toxic Effects - Very Toxic Material CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA):

The substance(s) in this preparation are included in or exempted from the Domestic Substance List (DSL).

INTERNATIONAL CHEMICAL CONTROL LAWS AUSTRALIA All substances in this product comply with the National Industrial Chemicals Notification & Assessment Scheme (NICNAS).

EUROPE The substances in this preparation have been reviewed for compliance with the EINECS or ELINCS inventories.

116. 1OTHER INFORMATION This product material safety data sheet provides health and safety information. The product is to be used in applications consistent with our product literature. Individuals handling this product should be informed of the recommended safety precautions and should have access to this information. For any other uses, exposures should be evaluated so that appropriate handling practices and training programs can be established to insure safe workplace operations. Please consult your local sales representative for any further information.

REFERENCES Threshold Limit Values for Chemical Substances and Physical Agents and Biological Exposure Indices, American Conference of Governmental Industrial Hygienists, OH., (Ariel Insight# CD-ROM Version), Ariel Research Corp.,

Bethesda, MD.

Hazardous Substances Data Bank, National Library of Medicine, Bethesda, Maryland (TOMES CPS# CD-ROM Version), Micromedex, Inc., Englewood, CO.

IARC Monographs on the Evaluation of the Carcinogenic Risk of Chemicals to Man, Geneva: World Health Organization, International Agency for Research on Cancer.

Integrated Risk Information System, U.S. Environmental Protection Agency, Washington, D.C. (TOMES CPS# CD-ROM Version), Micromedex, Inc., Englewood, CO.

Annual Report on Carcinogens, National Toxicology Program, U.S. Department of Health and Human Services, Public Health Service.

Title 29 Code of Federal Regulations, Part 1910, Subpart Z, Toxic and Hazardous Substances, Occupational Safety and Health Administration (OSHA), (Ariel Insight# CD-ROM Version), Ariel Research Corp., Bethesda, MD.

Nalco Company 1601 W. Diehl Road

Naperville, Illinois 60563-1198 * (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 8/9

MATERIAL SAFETY DATA SHEET AVNALCO PRODUCT 3D TRASAR 3DT195 EMERGENCY TELEPHONE NUMBER(S)

(800) 424-9300 (24 Hours) CHEMTREC Registry of Toxic Effects of Chemical Substances, National Institute for Occupational Safety and Health, Cincinnati, OH, (TOMES CPS# CD-ROM Version), Micromedex, Inc., Englewood, CO.

Ariel Insight# (An integrated guide to industrial chemicals covered under major regulatory and advisory programs),

North American Module, Western European Module, Chemical Inventories Module and the Generics Module (Ariel Insight# CD-ROM Version), Ariel Research Corp., Bethesda, MD.

The Teratogen Information System, University of Washington, Seattle, WA (TOMES CPS# CD-ROM Version),

Micromedex, Inc., Englewood, CO.

Prepared By: Product Safety Department Date issued: 03/21/2007 Version Number: 1.4 Nalco Company 1601 W. Diehl Road ° Naperville, Illinois 60563-1198 ° (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 9/9

ODYSSEY MANUFACTURING CO.

MATERIAL SAFETY DATA SHEET REVISED 7/2/00 SECTION 1 CHEMICAL PRODUCT AND COMPANY IDENTIFICATION ODYSSEY MANUFACTURING CO. EMERGENCY RESPONSE NUMBER:

1484 Massaro Boulevard 1-800-ODYSSEY (FLORIDA)

Tampa, Florida 33619 1-813-635-0339 (24 hours2.777778e-4 days 0.00667 hours 3.968254e-5 weeks 9.132e-6 months ) 1-813-635-0339 SUBSTANCE: SODIUM HYPOCHLORITE TRADE NAME: Ultra-CHLOR CHEMICAL NAME/SYNONYMS: Sodium Hypochlorite Solution, Bleach Solution, Bleach Liquor, Hypo-solution, Bleach, and Liquid Bleach.

CAS NUMBER: 7681-52-9 CHEMICAL FAMILY: Alkali FORMULA: NaOCI DOT PROPER SHIPPING NAME: Hypochlorite Solution DOT HAZARD CLASS: 8 (Corrosive) PG III; PG II (For solutions greater than 16% available chlorine)

DOT IDENTIFICATION NO: UN1791 RQ: 100 pounds DOT EMERGENCY GUIDE NO: 154 SECTION II COMPOSITION. INFORMATION ON INGREDIENTS INGREDIENT(S):

Sodium Hypochlorite (NaOCI) 10.0 - 20.0% wt Sodium Hydroxide (NaOH) 0.1 - 0.4% wt Water (H 20) 79.7 - 89.9% wt SECTION I!1 HAZARDS IDENTIFICATION NFPA CLASSIFICATION (SCALE 0-4): Health=2 Fire=0 Reactivity=l EC CLASSIFICATION (ASSIGNED): C (Corrosive)

EMERGENCY OVER VIE W COLOR: Yellow PHYSICAL FORM: Liquid ODOR: Chlorine Odor MAJOR HEALTH HAZARDS: Respiratory Tract Burns, Skin Burns, Mucous Membrane Burns, and Eye Irritation HAZARDOUS MIXTURES WITH OTHER LIQUIDS, SOLIDS, OR GASES: Reacts violently with acids liberating chlorine gas. Also reacts with organic substance. When heated, gives off oxygen that may increase fire hazard.

I

POTENTIAL HEALTH EFFECTS INHALATION:

SHORT TERM EXPOSURE: Irritation to respiratory tract. May have same as effects reported in other routes of exposure, burns, blisters, nausea, difficulty breathing, and lung congestion.

LONG TERM EXPOSURE: Same as effects reported in short term exposure.

SKIN CONTACT:

" SHORT TERM EXPOSURE: Irritant, reddening of the skin. May have burns, blisters, and itching

" LONG TERM EXPOSURE: Same as effects reported in short term exposure.

EYE CONTACT:

SHORT TERM EXPOSURE: Irritation (possibly severe), possible eye damage

" LONG TERM EXPOSURE: Same as effects reported in short term exposure.

INGESTION:

" SHORT TERM EXPOSURE: Burns, vomiting stomach pain, disorientation, bluish skin color, convulsions, coma

LONG TERM EXPOSURE: Same as effects reported in short term exposure.

CARCINOGEN STATUS OSHA: N NTP: N IARC: N SECTION IV FIRST AID MEASURES INHALATION: Remove from exposure and get fresh air. Use a bag valve mask or similar device to perform artificial respiration (rescue breathing) if needed. Keep warm and at rest. Get medical attention immediately if artificial respiration is required.

SKIN CONTACT: Remove contaminated clothing, jewelry, and shoes immediately. Flush affected area with large amounts of water, preferably a safety shower. Use soap or mild detergent and large amounts of water until no evidence of chemical remains (at least 15-20 minutes). For bums, cover affected area securely with sterile, dry, loose fitting dressing. If skin is burned, get medical attention immediately.

EYE CONTACT: Wash eyes immediately with large amounts of water, occasionally lifting upper and lower lids, until no evidence of chemical remains (at least 15 minutes). Continue irrigating with a normal saline solution until ready to transport to physician. Cover with sterile bandages. Get medical attention immediately.

INGESTION: Rinse mouth with water. Drink large quantities of milk (water if no milk is available). Milk of magnesia may be helpful. DO NOT USE ACIDIC ANTIDOTES SUCH AS SODIUM BICARBONATE.

When vomiting occurs, keep head lower than hips to help prevent aspiration. If person is unconscious, do not induce vomiting and turn their head to the side. Never make an unconscious person vomit or drink fluids. Get medical attention.

NOTE TO PHYSICIAN: For inhalation, consider oxygen. For ingestion, avoid gastric lavage, emesis, sodium bicarbonate and acid solutions. Consider the use of antacids.

SECTION V FIRE FIGHTING MEASURES FLASH POINT: Non-flammable FLAMMABLE LIMITS: Non-flammable FIRE AND EXPLOSION HAZARDS: Negligible fire hazard. Oxidizer. This material will react with some metals and cause liberation of oxygen. May ignite or explode on contact with combustible materials. Toxic fumres can be liberated by contact with acid or heat.

EXTINGUISHING MEDIA: Regular dry chemical, carbon dioxide, water, or foam suitable for surrounding fire.

For large fires, use regular foam or flood with fine water spray.

FIRE FIGHTING: Wear self-contained breathing apparatus and full protective clothing. Move container from fire area if it can be done without risk. Cool containers with water spray until well after the fire is out. Stay away from the ends of tanks. Use extinguishing agents appropriate for surrounding fire. Do not get water directly on material. For large fires, flood with fine water spray. Reduce vapors with water spray. Apply water from a protected location or from a safe distance. Avoid body contact or inhalation of material or combustion by-products. Stay upwind and keep out of low areas.

2

SECTION VI ACCIDENTAL RELEASE MEASURES OCCUPATIONAL RELEASE: Do not touch spilled material. Stop leak if possible without personal risk. For small spills, collect spilled material in appropriate container for disposal and consider absorbing with sand or other non-combustible material (e.g., do not use sawdust or other combustible material). Be advised, however, that the use of absorbing material is creating hazardous waste and this absorbing material must now be disposed of properly. Collect spilled material in appropriate container for disposal. For small dry spills, move containers away from spill to a safe area. For large spills, dike for later disposal. If possible, do not allow material to enter sewers, streams, ponds or storm conduits as concentrated solutions will seriously injure aquatic life. Keep unnecessary people away, isolate hazard area and deny entry. Contain in as small an area as possible, such as a holding area for dilution and neutralization. Contain spill in plastic drums when available. Dispose of in accordance with Federal, State, and local regulations. Personnel engaged in cleanup operations must be equipped with NIOSH approved respirator protection, rubber boots, gloves, and clothing to avoid body contact.

Reportable Quantity (RQ): 100 pounds. Notify Local Emergency Planning Committee and State Emergency Response Commission for release greater than or equal to RQ (U.S. SARA Section 304). If release occurs in the U.S. and is reportable under CERCLA Section 103, notify the National Response Center at (800) 424-8802 (USA) or (202) 426-2675 (USA).

ADVANCE PLANNING: Plan in advance for an occupational release and have necessary equipment and neutralization agents on-site. Contact Odyssey Manufacturing for assistance.

SECTION VII HANDLING AND STORAGE Store in vented, closed containers that provide protection from direct sunlight. Keep separated from incompatible substances and do not store near acids, heat, or oxidizable materials or organics. When handling, do not mix with other cleaning agents that may liberate chlorine gas vapors (e.g., acidic agents).

Store and handle in accordance with all current regulations and standards including NFPA 430 Code for the Storage of Liquid and Oxidizing Materials.

SECTION VIII EXPOSURE CONTROLS AND PERSONNEL PROTECTION EXPOSURE LIMITS: 2 mg/m3 AIHA recommended STEL 15 minute(s) for Sodium Hypochlorite VENTILATION: Provide local exhaust ventilation system. Ensure compliance with applicable exposure limits.

EYE PROTECTION: Splash goggles are preferred to a faceshield. Another option is to wear splash resistant safety goggles with a faceshield. Provide an emergency eye wash fountain and quick drench shower in the immediate work area.

CLOTHING: It is recommended to wear appropriate chemical resistant clothing to avoid body contact such as a rubber apron or rain suit. Boots are preferred for footwear.

GLOVES: Wear appropriate chemical resistant gloves.

RESPIRATOR: Under conditions of frequent use or heavy exposure, respiratory protection may be needed.

Respiratory protection is ranked in order from minimum to maximum. Consider warning properties before use.

" Any chemical cartridge respirator with organic vapor cartridge(s).

" Any chemical cartridge respirator with a full facepiece and organic vapor cartridge(s)

" Any air-purifying respirator with a full facepiece and an organic vapor canister

" Any supplied-air respirator with full facepiece and operated in a pressure-demand or other positive-pressure mode in combination with a separate escape supply (Use for Unknown Concentrations or those that may be Immediately Dangerous to Life or Health)

" Any self-contained breathing apparatus with a full facepiece (Use for High Concentrations or those which are immediately Dangerous to Life or Health)

SECTION IX PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL APPEARANCE: Liquid APPEARANCE AND ODOR: Clear - Chlorine odor like household bleach.

COLOR: Greenish -Yellowish cast MOLECULAR WEIGHT: 74.44 MOLECULAR FORMULA: Na-O-CI 3

BOILING POINT: Degrades at 230 Degrees Fahrenheit FREEZING POINT: 7 Degrees Fahrenheit SPECIFIC GRAVITY: 1.15 - 1.17 at 60 Degrees Fahrenheit PH: Approximately I1 - 13 VAPOR PRESSURE (mm HG): Vapor Pressure of water + decomposition product Vapor Pressure VAPOR DENSITY: Not Available SOLUBILITY IN WATER: Complete VOLATILITY: Not Available EVAPORATION RATE: >1 COEFFICIENT OF WATER /OIL DISTRIBUTION: Not Available SECTION X STABILITY AND REACTIVITY REACTIVITY: Stable at normal temperatures and pressure.

CONDITIONS TO AVOID: Avoid heat, flames, sparks and other sources of ignition. Dangerous gases may accumulate in confined spaces. May ignite or explode on contact with combustible materials.

INCOMPATIBLES: Acids, metals, amines, combustible materials, reducing agents. Specific reactions with sodium hypochlorite include the following:

ACIDS: Violent reaction.

ALUMINUM: Corrosive action.

AMINES: Form explosive chloramines.

AMMONIA: Form explosive chloramines.

AMMONIUM SALTS: May form explosive product.

BENZYL CYANIDE (ACIDIFIED): Explosive reaction.

CELLOLOSE: Violent reaction ETHYLENEIMINE: Forms explosive I-chloroethyleneimine.

FORMIC ACID: Explosive mixture.

METHANOL: May form explosive compound.

NITROGEN COMPOUNDS: Forms explosive N-chloro compounds.

ORGANIC AND COMBUSTIBLE MATERIALS: Fire and explosion hazard.

OXALIC ACID: Intense reaction REDUCING AGENTS: Fire and explosion hazard ZINC: Corrosive HAZARDOUS DECOMPOSITION:

Thennal decomposition products - Chlorine and Hydrochloric Acid Vapors Decomposition Products - Hypochlorous Acid Vapors POLYMERIZATION: Will not polymerize.

SECTION XI SODIUM HYPOCHLORITE TOXILOGICAL INFORMATION IRRITATION DATA: 10 mg eyes - rabbit moderate TOXICITY DATA:

Igm/ kg oral-woman; TDLo; 45mg/kg intravenous-man TDLo; 5800 mg/ kg oral-mouse LD50; 140 mg/ kq/9 week(s) continuous oral-rat TDLo CARCINOGEN STATUS: According to the IARC, animal inadequate evidence, human no adequate data, Group 3 (Hypochlorite salts)

LOCAL EFFECTS:

Corrosive: inhalation, skin contact, eye, ingestion hazards ACUTE TOXICITYLEVEL:

Slightly Toxic if ingested MUTAGENIC DATA:

Mutation in micro organisms - Salmonella typhimurium 1mg / plate (-S9); DNA repair - Escherichiacoli 20ug/

disc; DNA damage - Esoherichiacoli 420 umol/L; phage inhibition capacity - Esoherichiacoli 103 ug/ well; micronucleus test - non-mammalian species multiple 200 ppb; cytogenetic analysis - non-mammalian species multiple 120 ug/ L; cytogenetic analysis - human lymphocyte 100 ppm 24hour(s); sister chromatid exchange -

human embryo 149 nig L; cytogenetic analysis - hamster lung 100 mg/ L HEALTH EFFECTS:

INHALATION ACUTE EXPOSURE: May cause severe bronchial irritation, sore throat with possible blistering, coughing, 4

stomatitis, nausea, labored breathing, shortness of breath and pulmonary epedema. 10-20 rag/m3 causes burning of the nose and throat; 40-60 mg/n3 may be fatal. If sufficient amounts are absorbed, may cause effects as detailed in acute ingestion.

CHRONIC EXPOSURE: No data available.

SKIN CONTACT ACUTE EXPOSURE: Extent of damage depends on concentration, pH, volume of solution and duration of contact. May cause redness, pain, blistering, itchy eczema and chemical burns. Sensitization reactions are possible in previously exposed persons.

CHRONIC EXPOSURE: Effects depend on concentration and duration of exposure. Repeated or prolonged contact with corrosive substances may result in dermatitis or effects similar to acute exposure. Allergic dermatitis has also been reported.

EYE CONTACT ACUTE EXPOSURE: May cause redness, pain, and blurred vision. Solutions of 5% splashed in human eyes have caused a burning sensation and later only slight superficial disturbance of the corneal epithelium which cleared completely in the next day or two without special treatment. However, one animal study reports a 5%

solution causing only moderate irritation with clearing within 7 days. A higher concentration of 15% tested on rabbit eyes caused immediate severe pain, hemorrhages, rapid onset of ground-glass appearance of the corneal epithelium, moderate bluish edema of the whole cornea, chemosis and discharge for several days.

Such eyes have sometimes healed in 2-3 weeks with slight or no residual corneal damage but they had neovascularization of the conjunctiva and distortion of the nictitating membrane by scarring.

CHRONIC EXPOSURE: Depending on concentration and duration of exposure, symptoms may be as those of acute exposure.

INGESTION ACUTE EXPOSURE: May cause irritation and erosion of the mucous membranes, vomiting (possibly bloody) and abdominal pain and spasms. A drop in blood pressure, shallow respiration, edema (possibly severe) of pharynx, larynx, and glottis, confusion, convulsions, delirium and coma may occur. Cyanosis and circulatory collapse are possible. Esophageal or gastric perforation and strictures are rare. Death may occur, usually due to complications of severe local injury such as toxemia, shock, perforations, hemorrhage, infection and obstruction. Massive ingestions may produce fatal hyperchloremic metabolic acidosis or aspiration pneumonitis.

CHRONIC EXPOSURE: Sensitization reactions are reported in individuals who are exposed in small amounts through their water supply. High doses have caused sperm abnormality in mice.

SECTION Xll ECOLOGICAL INFORMATION ECOTOXICITY DATA:

FISH TOXICITY: 94.0 ug/L 96h hour(s) LC50 (Mortality) Cutthroat trout (Oncorhynchus clarki)

INVERTEBRATE TOXICITY: 31.6 ug/L 7 hour8.101852e-5 days 0.00194 hours 1.157407e-5 weeks 2.6635e-6 months (s) 1C50 (Species Diversity) Protozoan phylum (Protozoa)

ALGAL TOXICITY: 90 ug/L 96 hour0.00111 days 0.0267 hours 1.587302e-4 weeks 3.6528e-5 months (s) LC50 (Mortality) Algae, phytoplankton, algai mat (Algae)

PHYTOTOXICITY: 230 ug/L 35 hour4.050926e-4 days 0.00972 hours 5.787037e-5 weeks 1.33175e-5 months (s) (Biomass) Curled pondweed (Potamogeton crispus)

OTHER TOXICITY: 2.1 ug/L 28 day(s) (Chlorophyll) Aquatic community (Aquatic community)

ENVIRONMENTAL

SUMMARY

Highly toxic to aquatic life.

SECTION XIII DISPOSAL CONSIDERATIONS Subject to disposal regulations: U.S. EPA 40 CFR 262. Hazardous Waste Number(s): DOO 1. Dispose in accordance with all applicable regulations.

SECTION XIV TRANSPORT INFORMATION U.S. DOT 49 CFR 172.101 SHIPPING NAME-UN NUMBER: Sodium Hypochlorite) - UN 1791 U.S. DOT 49 CER 172.101 HAZARD CLASS OR DIVISION: 8 U.S. DOT 49 CFR 172.101 PACKING GROUP: III (less than 16% available chlorine) / 11(16% or more available chlorine)

U.S. DOT 49 CFR 172.101 AND SUBPART E LABELING REQUIREMENTS: Corrosive U.S. DOT 49 CFR 172.101 PACKAGING AUTHORIZATIONS:

EXCEPTIONS: 49 CFR 173.154 5

NON- BULK PACKAGING: 49 CFR 173.203 (less than 16% available chlorine) / 49 CFR 173.202 (16% or more available chlorine)

BULK PACKAGING: 49 CFR 173.241 (less than 16% available chlorine) /: 49 CFR 173.242 (16% or more available chlorine)

U.S. DOT 49 CFR 172.101 QUANTITY LIMITATIONS:

PASSENGER AIRCRAFT OR RAILCAR: 5 LITERS / (less than 16% available chlorine) / I LITERS (16% or more available chlorine)

CARGO AIRCRAFT ONLY: 60 LITERS / (less than 16% available chlorine) / 30 LITERS (16% or more available chlorine)

SECTION XV REGULATORY INFORMATION U.S. REGULATIONS TSCA INVENTORY STATUS: Y TSCA 12(b) EXPORT NOTIFICATION: Not listed.

CERCLA SECTION 103 (40CFR302.4): Y SODIUM HYPOCHLORITE: 100 LBS RQ SARA SECTION 302 (40CFR355.30) : N SARA SECTION 304 (40CFR355.40) : N SARA SECTION 313 (40CFR372.65): N SARA HAZARD CATEGORIES, SARA SECTIONS 311/312 (40CFR370.21):

ACUTE: Y CHRONIC: N FIRE: N REACTIVE: N SUDDEN RELEASE: N OSHA PROCESS SAFETY (29CFRIS1O.1 19): N STATE REGULATIONS:

California Proposition 65: N EUROPEAN REGULATIONS:

EC NUMBER (BINECS) : 231-668-3 EC RISK AND SAFETY PHRASES:

R 31 Contact with acids liberates toxic gas.

R 34 Causes burns.

S V2 Keep locked-up and out of reach of children.

S 28b After contact with skin, wash immediately with plenty of soap and water.

S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible)

S 50 Do not mix with incompatible materials.

CONCENTRATION LIMITS:

C>10% C R 31-34 5%<=C<=10% Xi R 31-36/38 GERMAN REGULATIONS:

WATER HAZARD CLASS (WGK): 2 (Official German Classification)

SECTION XVI OTHER INFORMATION For additional information, contact our technical service department.

Information contained in this MSDS refers only to the specific material designated and does not relate to any process or use involving other materials. This information is based on data believed to be reliable, and the Product is intended to be used in a manner that is customary and reasonably foreseeable. Since actual use and handling are beyond our control, no warranty, express or implied, is made and no liability is assumed by Odyssey Manufacturing in connection with the use of this information.

6

SAFETY DATA SHEET

)4NALCO PRODUCT ACTI-BROM 1338 EMERGENCY TELEPHONE NUMBER(S)

(800) 424-9300 (24 Hours) CHEMTREC

11. 1 CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: ACTI-BROM 1338 APPLICATION: CHLORINE ENHANCER, BIODISPERSANT COMPANY IDENTIFICATION: Nalco Company 1601 W. Diehl Road Naperville, Illinois 60563-1198 EMERGENCY TELEPHONE NUMBER(S): (800) 424-9300 (24 Hours) CHEMTREC NFPA 704M/HMIS RATING HEALTH: 1/1 FLAMMABILITY: 0/0 INSTABILITY: 0/0 OTHER:

0 = Insignificant 1 = Slight 2 = Moderate 3 = High 4 = Extreme * = Chronic Health Hazard

12. 1COMPOSITION/INFORMATION ON INGREDIENTS Our hazard evaluation has identified the following chemical substance(s) as hazardous. Refer to Section 15 for more information.

Hazardous Substance(s) CAS NO % (w/w)

Sodium Bromide 7647-15-6 30- 60

13. 1 HAZARDS IDENTIFICATION

- EMERGENCY OVERVIEW**

WARNING HARMFUL IF SWALLOWED. HARMFUL IF ABSORBED THROUGH SKIN. CAUSES MODERATE EYE IRRITATION.

Avoid contact with skin, eyes, or clothing. Wash thoroughly with soap and water after handling. Remove contaminated clothing and wash before reuse.

Wear suitable protective clothing, gloves and eye/face protection.

Not flammable or combustible. May evolve hydrogen bromide and bromine under fire conditions.

PRIMARY ROUTES OF EXPOSURE:

Eye, Skin HUMAN HEALTH HAZARDS - ACUTE:

EYE CONTACT:

Can cause mild to moderate irritation.

SKIN CONTACT :

May cause irritation with prolonged contact. Harmful if absorbed through skin.

Nalco Company 1601 W. Diehl Road

Naperville, Illinois 60563-1198 * (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access.

1/11

SAFETY DATA SHEET

)04 NALCO PRODUCT ACTI-BROM 1338 EMERGENCY TELEPHONE NUMBER(S)

(800) 424-9300 (24 Hours) CHEMTREC INGESTION:

Not a likely route of exposure. May be harmful if swallowed.

INHALATION:

Not a likely route of exposure. Repeated or prolonged exposure may irritate the respiratory tract.

AGGRAVATION OF EXISTING CONDITIONS:

A review of available data does not identify any worsening of existing conditions.

HUMAN HEALTH HAZARDS - CHRONIC:

No adverse effects expected other than those mentioned above.

4. FIRST AID MEASURES IF SWALLOWED: Call a poison control center or a doctor immediately for treatment advice. DO NOT INDUCE VOMITING. Do not give anything to drink.

IF IN EYES: Hold eye open and rinse slowly and gently with water for 15-20 minutes. After at least 15 minutes of rinsing or after it is judged that nearly all of the contamination has been removed. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing. Call a poison control center or a doctor immediately for treatment advice.

IF ON SKIN OR CLOTHING: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. Call a poison control center or doctor for treatment advice.

IF INHALED: Move person to fresh air. If person is not breathing, call 911 or ambulance, then give artificial respiration, preferably mouth-to-mouth, if possible. Call a poison control center or doctor for treatment advice.

NOTE TO PHYSICIAN:

Based on the individual reactions of the patient, the physician's judgement should be used to control symptoms and clinical condition.

15. 1 FIRE FIGHTING MEASURES FLASH POINT: None EXTINGUISHING MEDIA:

Use extinguishing media appropriate for surrounding fire.

FIRE AND EXPLOSION HAZARD:

Not flammable or combustible. May evolve hydrogen bromide and bromine under fire conditions.

SPECIAL PROTECTIVE EQUIPMENT FOR FIRE FIGHTING:

In case of fire, wear a full face positive-pressure self contained breathing apparatus and protective suit.

Nalco Company 1601 W. Diehl Road

Naperville, Illinois 60563-1198 * (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access.

2/11

SAFETY DATA SHEET

)4NALCO EMERGENCY TELEPHONE NUMBER(S)

(800) 424-9300 (24 Hours) CHEMTREC

6. ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS:

Restrict access to area as appropriate until clean-up operations are complete. Stop or reduce any leaks if it is safe to do so. Do not touch spilled material. Ventilate spill area if possible. Use personal protective equipment recommended in Section 8 (Exposure Controls/Personal Protection).

METHODS FOR CLEANING UP:

SMALL SPILLS: Soak up spill with absorbent material. Place residues in a suitable, covered, properly labeled container. Wash affected area. LARGE SPILLS: Contain liquid using absorbent material, by digging trenches or by diking. Reclaim into recovery or salvage drums or tank truck for proper disposal. Contact an approved waste hauler for disposal of contaminated recovered material. Dispose of material in compliance with regulations indicated in Section 13 (Disposal Considerations).

ENVIRONMENTAL PRECAUTIONS:

Do not discharge effluent containing this product into lakes, streams, ponds, estuaries, oceans or other waters, unless in accordance with the requirements of a National Pollutant Discharge Elimination System (NPDES) permit and the permitting authority has been notified in writing prior to discharge. Do not discharge effluent containing this product to sewer systems without previously notifying the local sewage treatment plant authority. For guidance contact your State Water Board or Regional Office of the EPA.

7. HANDLING AND STORAGE HANDLING:

Do not get in eyes, on skin, on clothing. Do not take internally. Use with adequate ventilation. Do not breathe vapors/gases/dust. Keep the containers closed when not in use. Have emergency equipment (for fires, spills, leaks, etc.) readily available. Ensure all containers are labeled. Do not mix with acids.

STORAGE CONDITIONS:

Store the containers tightly closed. Store in a cool well ventilated area away from direct sunlight.

UNSUITABLE CONSTRUCTION MATERIAL:

Shipping and long term storage compatibility with construction materials can vary; we therefore recommend that compatibility is tested prior to use.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION OCCUPATIONAL EXPOSURE LIMITS:

This product does not contain any substance that has an established exposure limit.

ENGINEERING MEASURES:

General ventilation is recommended.

RESPIRATORY PROTECTION:

Respiratory protection is not normally needed. Where concentrations in air may exceed the limits given in this section or when significant mists, vapors, aerosols, or dusts are generated, an approved air purifying respirator equipped with Nalco Company 1601 W. Diehl Road

Naperville, Illinois 60563-1198 ° (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access.

3/11

SAFETY DATA SHEET

)4NALCO PRODUCT ACTI-BROM 1338 EMERGENCY TELEPHONE NUMBER(S)

(800) 424-9300 (24 Hours) CHEMTREC suitable filter cartridges is recommended. Consult the respirator / cartridge manufacturer data to verify the suitability of specific devices. In event of emergency or planned entry into unknown concentrations a positive pressure, full-facepiece SCBA should be used. If respiratory protection is required, institute a complete respiratory protection program including selection, fit testing, training, maintenance and inspection.

HAND PROTECTION:

Neoprene gloves Nitrile gloves Butyl gloves PVC gloves SKIN PROTECTION:

Wear chemical resistant apron, chemical splash goggles, impervious gloves and boots.

EYE PROTECTION:

Wear chemical splash goggles.

HYGIENE RECOMMENDATIONS:

Use good work and personal hygiene practices to avoid exposure. Keep an eye wash fountain available. Keep a safety shower available. If clothing is contaminated, remove clothing and thoroughly wash the affected area. Launder contaminated clothing before reuse. Always wash thoroughly after handling chemicals. When handling this product never eat, drink or smoke.

HUMAN EXPOSURE CHARACTERIZATION:

Based on our recommended product application and personal protective equipment, the potential human exposure is:

Moderate

9. PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL STATE Liquid APPEARANCE Colorless ODOR None SPECIFIC GRAVITY 1.43 - 1.49 @ 77 -F / 25 °C DENSITY 12.0 - 12.4 lb/gal SOLUBILITY IN WATER Complete pH (100 %) 4.0 - 9.0 VISCOSITY 5 cps @ 72 °F / 22 °C FREEZING POINT -13 'F / -25 'C BOILING POINT 230 'F / 110 °C VAPOR PRESSURE 7.6 mm Hg @ 68 'F / 20 'C VOC CONTENT 0.00 %

Note: These physical properties are typical values for this product and are subject to change.

10. STABILITY AND REACTIVITY STABILITY:

Stable under normal conditions.

Nalco Company 1601 W. Diehl Road

Naperville, Illinois 60563-1198 * (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access.

4/11

SAFETY DATA SHEET 04NALCO PRODUCT ACTI-BROM 1338 EMERGENCY TELEPHONE NUMBER(S)

(800) 424-9300 (24 Hours) CHEMTREC HAZARDOUS POLYMERIZATION:

Hazardous polymerization will not occur.

CONDITIONS TO AVOID:

Freezing temperatures.

MATERIALS TO AVOID:

Contact with strong acids (e.g. sulfuric, phosphoric, nitric, hydrochloric, chromic, sulfonic) may generate heat, splattering or boiling and toxic vapors. Contact with strong oxidizers (e.g. chlorine, peroxides, chromates, nitric acid, perchlorate, concentrated oxygen, permanganate) may generate heat, fires, explosions and/or toxic vapors. Reducing agents HAZARDOUS DECOMPOSITION PRODUCTS:

Under acidic conditions: Hydrogen bromide 111. ITOXICOLOGICAL INFORMATION I The following results are for a similar product.

ACUTE ORAL TOXICITY :

Species: Rat LD50: > 5,000 mg/kg Test Descriptor: Similar Product ACUTE DERMAL TOXICITY:

Species: Rabbit LD50: > 2,000 mg/kg Test Descriptor: Similar Product PRIMARY SKIN IRRITATION:

Species: Rabbit Draize Score: 0.4/8.0 Test Descriptor: Similar Product Remarks: Not irritating SENSITIZATION :

This product is not expected to be a sensitizer.

CARCINOGENICITY:

None of the substances in this product are listed as carcinogens by the International Agency for Research on Cancer (IARC), the National Toxicology Program (NTP) or the American Conference of Governmental Industrial Hygienists (ACGIH).

Nalco Company 1601 W. Diehl Road

Naperville, Illinois 60563-1198 * (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access.

5/11

SAFETY DATA SHEET 04NALCO (800) 424-9300 (24 Hours) CHEMVTREC HUMAN HAZARD CHARACTERIZATION:

Based on our hazard characterization, the potential human hazard is: Low 112. 1ECOLOGICAL INFORMATION ECOTOXICOLOGICAL EFFECTS:

The following results are for the product.

ACUTE FISH RESULTS:

Species Exposure LC50 Test Descriptor Bluegill Sunfish 96 hrs > 1,000 mg/I Product Rainbow Trout 96 hrs > 1,000 mg/I Product Guppy 96 hrs 538 mg/I Product Fathead Minnow 96 hrs > 1,000 mg/I Product Inland Silverside 96.00 hrs > 5,000.000 mg/I Product ACUTE INVERTEBRATE RESULTS:

Species Exposure LC50 EC50 Test Descriptor Daphnia magna 48 hrs > 1,000 mg/I Product Mysid Shrimp (Mysidopsis 96.00 hrs 1,827.000 Product bahia) mg/I PERSISTENCY AND DEGRADATION:

Total Organic Carbon (TOC): 2,000 mg/I Chemical Oxygen Demand (COD): 53,000 mg/I Biological Oxygen Demand (BOD): This material is an oxidizing biocide and is not expected to persist in the environment.

Greater than 95% of this product consists of inorganic substances for which a biodegradation value is not applicable.

MOBILITY:

The environmental fate was estimated using a level III fugacity model embedded in the EPI (estimation program interface) Suite TM, provided by the US EPA. The model assumes a steady state condition between the total input and output. The level III model does not require equilibrium between the defined media. The information provided is intended to give the user a general estimate of the environmental fate of this product under the defined conditions of the models.

If released into the environment this material is expected to distribute to the air, water and soil/sediment in the approximate respective percentages; Air Water Soil/Sediment

<5% 30-50% 50-70%

The portion in water is expected to be soluble or dispersible.

Nalco Company 1601 W. Diehl Road - Naperville, Illinois 60563-1198 * (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access.

6/11

SAFETY DATA SHEET

)4NALCO (800) 424-9300 (24 Hours) CHEMTREC BIOACCUMULATION POTENTIAL This preparation or material is not expected to bioaccumulate.

ENVIRONMENTAL HAZARD AND EXPOSURE CHARACTERIZATION Based on our hazard characterization, the potential environmental hazard is: High Based on our recommended product application and the product's characteristics, the potential environmental exposure is: Moderate If released into the environment, see CERCLA/SUPERFUND in Section 15.

13. DISPOSAL CONSIDERATIONS If this product becomes a waste, it is not a hazardous waste as defined by the Resource Conservation and Recovery Act (RCRA) 40 CFR 261, since it does not have the characteristics of Subpart C, nor is it listed under Subpart D.

As a non-hazardous waste, it is not subject to federal regulation. Consult state or local regulation for any additional handling, treatment or disposal requirements. For disposal, contact a properly licensed waste treatment, storage, disposal or recycling facility.

14. TRANSPORT INFORMATION The information in this section is for reference only and should not take the place of a shipping paper (bill of lading) specific to an order. Please note that the proper Shipping Name / Hazard Class may vary by packaging, properties, and mode of transportation. Typical Proper Shipping Names for this product are as follows.

LAND TRANSPORT:

Proper Shipping Name: PRODUCT IS NOT REGULATED DURING TRANSPORTATION AIR TRANSPORT (ICAO/IATA):

Proper Shipping Name: PRODUCT IS NOT REGULATED DURING TRANSPORTATION MARINE TRANSPORT (IMDG/IMO):

Proper Shipping Name : PRODUCT IS NOT REGULATED DURING TRANSPORTATION

15. REGULATORY INFORMATION This section contains additional information that may have relevance to regulatory compliance. The information in this section is for reference only. It is not exhaustive, and should not be relied upon to take the place of an individualized compliance or hazard assessment. Nalco accepts no liability for the use of this information.

NATIONAL REGULATIONS, USA:

Nalco Company 1601 W. Diehl Road

Naperville, Illinois 60563-1198 * (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access.

7/11

SAFETY DATA SHEET 04NALCO PRODUCT ACTI-BROM 1338 EMERGENCY TELEPHONE NUMBER(S)

(800) 424-9300 (24 Hours) CHEMTREC OSHA HAZARD COMMUNICATION RULE, 29 CFR 1910.1200:

Based on our hazard evaluation, the following substance(s) in this product is/are hazardous and the reason(s) is/are shown below.

Sodium Bromide: Non-Hazardous CERCLA/SUPERFUND, 40 CFR 302:

Notification of spills of this product is not required.

SARA/SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (TITLE Ill) - SECTIONS 302, 311, 312, AND 313:

SECTION 302 - EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355):

This product does not contain substances listed in Appendix A and B as an Extremely Hazardous Substance.

SECTIONS 311 AND 312 - MATERIAL SAFETY DATA SHEET REQUIREMENTS (40 CFR 370):

Our hazard evaluation has found this product to be hazardous. The product should be reported under the following indicated EPA hazard categories:

X Immediate (Acute) Health Hazard

- Delayed (Chronic) Health Hazard

- Fire Hazard

- Sudden Release of Pressure Hazard

- Reactive Hazard Under SARA 311 and 312, the EPA has established threshold quantities for the reporting of hazardous chemicals.

The current thresholds are: 500 pounds or the threshold planning quantity (TPQ), whichever is lower, for extremely hazardous substances and 10,000 pounds for all other hazardous chemicals.

SECTION 313 - LIST OF TOXIC CHEMICALS (40 CFR 372):

This product does not contain substances on the List of Toxic Chemicals.

TOXIC SUBSTANCES CONTROL ACT (TSCA):

The substances in this preparation are included on or exempted from the TSCA 8(b) Inventory (40 CFR 710)

FOOD AND DRUG ADMINISTRATION (FDA) Federal Food, Drug and Cosmetic Act:

When use situations necessitate compliance with FDA regulations, this product is acceptable under: the following use conditions.

This product may be used to treat pulp and papermill water systems in situations requiring FDA sanction provided the bromide concentration in the water is kept below 22 ppm. The product must be used in conjunction with an oxidant such as bleach or gaseous chlorine. Follow instructions for use in pulp and papermill on the product label.

NSF NON-FOOD COMPOUNDS REGISTRATION PROGRAM (former USDA List of Proprietary Substances &

Non-Food Compounds):

NSF Registration number for this product is : 142570 This product is acceptable for treatment of cooling and retort water (G5) in and around food processing areas. This product is acceptable for treating boilers, steam lines, and/or cooling systems (G7) where neither the treated water nor the steam produced may contact edible products in and around food processing areas.

Nalco Company 1601 W. Diehl Road

Naperville, Illinois 60563-1198 * (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access.

8/11

SAFETY DATA SHEET tdNALCO )AWNALCOPRODUCT .oo ACTI-BROM 1338 EMERGENCY TELEPHONE NUMBER(S)

(800) 424-9300 (24 Hours) CHEMTREC FEDERAL INSECTICIDE, FUNGICIDE AND RODENTICIDE ACT (FIFRA):

EPA Reg. No. 1706-168 In all cases follow instructions on the product label.

This product has been certified as KOSHER/PAREVE for year-round use INCLUDING THE PASSOVER SEASON by the CHICAGO RABBINICAL COUNCIL.

FEDERAL WATER POLLUTION CONTROL ACT, CLEAN WATER ACT, 40 CFR 401.15 / formerly Sec. 307, 40 CFR 116.4 / formerly Sec. 311 :

Substances listed under this regulation are not intentionally added or expected to be present in this product. Listed components may be present at trace levels.

CLEAN AIR ACT, Sec. 112 (Hazardous Air Pollutants, as amended by 40 CFR 63), Sec. 602 (40 CFR 82, Class I and II Ozone Depleting Substances):

Substances listed under this regulation are not intentionally added or expected to be present in this product. Listed components may be present at trace levels.

CALIFORNIA PROPOSITION 65:

Substances listed under California Proposition 65 are not intentionally added or expected to be present in this product.

MICHIGAN CRITICAL MATERIALS:

Substances listed under this regulation are not intentionally added or expected to be present in this product. Listed components may be present at trace levels.

STATE RIGHT TO KNOW LAWS:

This product is a registered biocide and is exempt from State Right to Know Labelling Laws.

INTERNATIONAL CHEMICAL CONTROL LAWS:

CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA):

The substance(s) in this preparation are included in or exempted from the Domestic Substance List (DSL).

AUSTRALIA All substances in this product comply with the National Industrial Chemicals Notification & Assessment Scheme (NICNAS).

CHINA All substances in this product comply with the Provisions on the Environmental Administration of New Chemical Substances and are listed on the Inventory of Existing Chemical Substances China (IECSC).

EUROPE The substance(s) in this preparation are included in or exempted from the EINECS or ELINCS inventories Nalco Company 1601 W. Diehl Road

Naperville, Illinois 60563-1198 * (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access.

9/11

SAFETY DATA SHEET N04NALCO PRODUCT ACTI-BROM 1338 EMERGENCY TELEPHONE NUMBER(S)

(800) 424-9300 (24 Hours) CHEMTREC JAPAN All substances in this product comply with the Law Regulating the Manufacture and Importation Of Chemical Substances and are listed on the Existing and New Chemical Substances list (ENCS).

KOREA All substances in this product comply with the Toxic Chemical Control Law (TCCL) and are listed on the Existing Chemicals List (ECL)

NEW ZEALAND All substances in this product comply with the Hazardous Substances and New Organisms (HSNO) Act 1996,and are listed on or are exempt from the New Zealand Inventory of Chemicals.

PHILIPPINES All substances in this product comply with the Republic Act 6969 (RA 6969) and are listed on the Philippines Inventory of Chemicals & Chemical Substances (PICCS).

16. OTHER INFORMATION Due to our commitment to Product Stewardship, we have evaluated the human and environmental hazards and exposures of this product. Based on our recommended use of this product, we have characterized the product's general risk. This information should provide assistance for your own risk management practices. We have evaluated our product's risk as follows:

The human risk is: Low

The environmental risk is: Moderate Any use inconsistent with our recommendations may affect the risk characterization. Our sales representative will assist you to determine if your product application is consistent with our recommendations. Together we can implement an appropriate risk management process.

This product material safety data sheet provides health and safety information. The product is to be used in applications consistent with our product literature. Individuals handling this product should be informed of the recommended safety precautions and should have access to this information. For any other uses, exposures should be evaluated so that appropriate handling practices and training programs can be established to insure safe workplace operations. Please consult your local sales representative for any further information.

REFERENCES Threshold Limit Values for Chemical Substances and Physical Agents and Biological Exposure Indices, American Conference of Governmental Industrial Hygienists, OH., (Ariel Insight TM CD-ROM Version), Ariel Research Corp.,

Bethesda, MD.

Hazardous Substances Data Bank, National Library of Medicine, Bethesda, Maryland (TOMES CPS TM CD-ROM Version), Micromedex, Inc., Englewood, CO.

IARC Monographs on the Evaluation of the Carcinogenic Risk of Chemicals to Man, Geneva: World Health Organization, International Agency for Research on Cancer.

Nalco Company 1601 W. Diehl Road

Naperville, Illinois 60563-1198 - (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access.

10/11

SAFETY DATA SHEET

~NALCO )041'ALCOPRODUCT ACTI-BROM 1338 EMERGENCY TELEPHONE NUMBER(S)

(800) 424-9300 (24 Hours) CHEMTREC M

T Integrated Risk Information System, U.S. Environmental Protection Agency, Washington, D.C. (TOMES CPS CD-ROM Version),

Micromedex, Inc., Englewood, CO.

Annual Report on Carcinogens, National Toxicology Program, U.S. Department of Health and Human Services, Public Health Service.

Title 29 Code of Federal Regulations, Part 1910, Subpart Z, Toxic and Hazardous Substances, Occupational Safety and Health Administration (OSHA), (Ariel Insight TM CD-ROM Version), Ariel Research Corp., Bethesda, MD.

Registry of Toxic Effects of Chemical Substances, National Institute for Occupational Safety and Health, Cincinnati, OH, (TOMES CPSTM CD-ROM Version), Micromedex, Inc., Englewood, CO.

Ariel InsightTM (An integrated guide to industrial chemicals covered under major regulatory and advisory programs),

North American Module, Western European Module, Chemical Inventories Module and the Generics Module (Ariel Insight TM CD-ROM Version), Ariel Research Corp., Bethesda, MD.

The Teratogen Information System, University of Washington, Seattle, WA (TOMES CPS TM CD-ROM Version),

Micromedex, Inc., Englewood, CO.

Prepared By : Product Safety Department Date issued : 03/14/2011 Version Number: 1.19 Nalco Company 1601 W. Diehl Road

Naperville, Illinois 60563-1198 * (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access.

11 / 11

3F0814-03, Reporting Related to the National Pollutant Discharge Elimination System (NPDES) Permit Id FL0000159-014-IW1S

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3F0814-03, Reporting Related to the National Pollutant Discharge Elimination System (NPDES) Permit Id FL0000159-014-IW1S

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