ML11214A190

Laboratory Testing of Zeolitic Materials Submitted by Department of Civil, Structural and Environmental Engineering of the University of Buffalo

ML11214A190
Person / Time
Site:	West Valley Demonstration Project, P00M-032
Issue date:	12/14/2009
From:	Rabideau A, Ross E, Seneca S, Bronner C University of Buffalo
To:	NRC/FSME, West Valley Environmental Services
References
WVDP-506, Rev. 0
Download: ML11214A190 (562)

Text

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Appendix:ZeoliteCharacterizationprocedure,June12009Scope:Thistestwillbeusedtocharacterizethedistributionofsorbedcationsonthezeolitematerialscollectedfromtheinstalledpermeabletreatmentwall(PTW).Process:CationswillbeflushedfromthezeolitematerialusingamodifiedversionofthestandardbatchexchangemethoddescribedbyCerrietal.intheirjournalarticleinClayandClayMineralsVol.50No.1,127 135,2002.Generalprocessstepsareasfollows:1.Forsamplesofdryunprocessedmaterial,aprewashingstepisrecommendedtoremovefineparticlesthatwouldbelostduringsubsequenthandling(thisstepisomittedforsamplesfromthefieldorcomple te dcolumntests).Regardlessofpreliminaryprocessing,drythezeolite(e.g.,overnightat103degreesCelsius).2.Weighoutaspecifiedmassofdriedzeolite(m z).Recommended:9grams;3.Preparea1MNH 4+solutionusingNH 4 Cl;4.Combinespecifiedamountofzeoliteandsolutionintesttube.Recommended:1:10solid liquidratio=9gramsofzeoliteand90gramsofNH 4 Clsolution;5.Placecapontesttubeandtapetoseal;6.Placetesttube(s)onrotatortoslowlymixoveraspecifiedperiodoftime.Recommended=4days;7.Separaterinsatebyvacuumfiltrationfollowedbysyringefiltrationusinga0.45µmfilter;8.Collectrinsateinabeak er;9.Carefullyremoveallsolidmaterial(fro mfilterandglassware)andreplaceintesttube.10.Repeatsteps4through6twice(i.e.,threeseparaterinseswith90gofsolution,eachwith4daysofmixing).Allrinsate(foreachzeolitesample)iscombinedinasinglebeaker.Carefullymeasureandrecordtotalvolumeofcollectedrinsate(V T);11.Storerinsateinprepreservedlabeledsamplecontainersuntildeliveredtolaboratoryforcationanalysis.

Thesestepswillbefollowedbyanalysisoftherinsateforthefollowingcations:Ca 2+,Mg 2+,Na+,K+andSr 2+.Theconcentrationofeachsorbedcationiscomputedasfollows; whereq iisthesorbedconcentrationofcationi(mg/kg),C iistheconcentrationofcationiintherinsate(mg/L),V Tisthetotalvolumeofrinsate(mL,typically270mL),andm zisthemassofzeolite(g,typically9g).

MOUSER Version 2 Overview of key features

COLUMBIA ANALYTICAL SERVICES, INC.

Water Sample Matrix:

Project: Jarvis Hall

University of Buffalo Client: Analytical Report R0904198 7/15/09 - 7/16/09

7/29/09 Date Received:

Date Collected:

Service Request:

Basis: Analysis Method:

Units: NAµg/L 200.7 Calcium, Total Prep Method:

EPA 3010AResultQMRLMDL Dilution Factor Date Analyzed Lab Code Date Extracted Sample Name 58200010000200010 8/4/09 13:07 7/30/09 R0904198-001 405 57700010000200010 8/4/09 13:36 7/30/09 R0904198-002 406 55500010000200010 8/4/09 13:41 7/30/09 R0904198-003 407 46700010000200010 8/4/09 13:45 7/30/09 R0904198-004 408 52200010000200010 8/4/09 13:49 7/30/09 R0904198-005 409 46700010002001 8/4/09 16:21 7/30/09 R0904198-006 410 46300010002001 8/4/09 16:26 7/30/09 R0904198-007 411 45400010002001 8/4/09 16:30 7/30/09 R0904198-008 412 68200010000200010 8/4/09 14:14 7/30/09 R0904198-009 413 66800010000200010 8/4/09 14:18 7/30/09 R0904198-010 414 69000010000200010 8/4/09 14:23 7/30/09 R0904198-011 415 64000010000200010 8/4/09 14:27 7/30/09 R0904198-012 416 61800010000200010 8/4/09 14:31 7/30/09 R0904198-013 417 58600010000200010 8/4/09 14:35 7/30/09 R0904198-014 418 59100010000200010 8/4/09 14:40 7/30/09 R0904198-015 419 54900010000200010 8/4/09 14:44 7/30/09 R0904198-016 420 100010002001 8/4/09 12:29 7/30/09 R0904198-MB U Method Blank COLUMBIA ANALYTICAL SERVICES, INC.

Water Sample Matrix:

Project: Jarvis Hall

University of Buffalo Client: Analytical Report R0904198 7/15/09 - 7/16/09

7/29/09 Date Received:

Date Collected:

Service Request:

Basis: Analysis Method:

Units: NAµg/L 200.7 Magnesium, Total Prep Method:

EPA 3010AResultQMRLMDL Dilution Factor Date Analyzed Lab Code Date Extracted Sample Name 2930010001001 8/4/09 15:34 7/30/09 R0904198-001 405 2870010001001 8/4/09 15:55 7/30/09 R0904198-002 406 2630010001001 8/4/09 16:00 7/30/09 R0904198-003 407 2620010001001 8/4/09 16:04 7/30/09 R0904198-004 408 2470010001001 8/4/09 16:17 7/30/09 R0904198-005 409 2370010001001 8/4/09 16:21 7/30/09 R0904198-006 410 2310010001001 8/4/09 16:26 7/30/09 R0904198-007 411 2390010001001 8/4/09 16:30 7/30/09 R0904198-008 412 5630010001001 8/4/09 16:35 7/30/09 R0904198-009 413 5420010001001 8/4/09 16:39 7/30/09 R0904198-010 414 5940010001001 8/4/09 16:44 7/30/09 R0904198-011 415 5150010001001 8/4/09 16:48 7/30/09 R0904198-012 416 5280010001001 8/4/09 16:53 7/30/09 R0904198-013 417 5000010001001 8/4/09 16:57 7/30/09 R0904198-014 418 4800010001001 8/4/09 17:21 7/30/09 R0904198-015 419 4580010001001 8/4/09 17:25 7/30/09 R0904198-016 420 100010001001 8/4/09 12:29 7/30/09 R0904198-MB U Method Blank COLUMBIA ANALYTICAL SERVICES, INC.

Water Sample Matrix:

Project: Jarvis Hall

University of Buffalo Client: Analytical Report R0904198 7/15/09 - 7/16/09

7/29/09 Date Received:

Date Collected:

Service Request:

Basis: Analysis Method:

Units: NAµg/L 200.7 Potassium, Total Prep Method:

EPA 3010AResultQMRLMDL Dilution Factor Date Analyzed Lab Code Date Extracted Sample Name 26300020000100010 8/4/09 13:07 7/30/09 R0904198-001 405 30200020000100010 8/4/09 13:36 7/30/09 R0904198-002 406 33400020000100010 8/4/09 13:41 7/30/09 R0904198-003 407 35700020000100010 8/4/09 13:45 7/30/09 R0904198-004 408 45900020000100010 8/4/09 13:49 7/30/09 R0904198-005 409 49400020000100010 8/4/09 13:53 7/30/09 R0904198-006 410 54400020000100010 8/4/09 13:57 7/30/09 R0904198-007 411 56100020000100010 8/4/09 14:10 7/30/09 R0904198-008 412 26500020000100010 8/4/09 14:14 7/30/09 R0904198-009 413 29400020000100010 8/4/09 14:18 7/30/09 R0904198-010 414 34600020000100010 8/4/09 14:23 7/30/09 R0904198-011 415 41900020000100010 8/4/09 14:27 7/30/09 R0904198-012 416 51100020000100010 8/4/09 14:31 7/30/09 R0904198-013 417 56900020000100010 8/4/09 14:35 7/30/09 R0904198-014 418 64900020000100010 8/4/09 14:40 7/30/09 R0904198-015 419 68100020000100010 8/4/09 14:44 7/30/09 R0904198-016 420 200020001001 8/4/09 12:29 7/30/09 R0904198-MB U Method Blank COLUMBIA ANALYTICAL SERVICES, INC.

Water Sample Matrix:

Project: Jarvis Hall

University of Buffalo Client: Analytical Report R0904198 7/15/09 - 7/16/09

7/29/09 Date Received:

Date Collected:

Service Request:

Basis: Analysis Method:

Units: NAµg/L 200.7 Sodium, Total Prep Method:

EPA 3010AResultQMRLMDL Dilution Factor Date Analyzed Lab Code Date Extracted Sample Name 22700010000100010 8/4/09 13:07 7/30/09 R0904198-001 405 22200010000100010 8/4/09 13:36 7/30/09 R0904198-002 406 21200010000100010 8/4/09 13:41 7/30/09 R0904198-003 407 18200010001001 8/4/09 16:04 7/30/09 R0904198-004 408 20200010000100010 8/4/09 13:49 7/30/09 R0904198-005 409 18200010001001 8/4/09 16:21 7/30/09 R0904198-006 410 18100010001001 8/4/09 16:26 7/30/09 R0904198-007 411 18400010001001 8/4/09 16:30 7/30/09 R0904198-008 412 24800010000100010 8/4/09 14:14 7/30/09 R0904198-009 413 24900010000100010 8/4/09 14:18 7/30/09 R0904198-010 414 25100010000100010 8/4/09 14:23 7/30/09 R0904198-011 415 23800010000100010 8/4/09 14:27 7/30/09 R0904198-012 416 23200010000100010 8/4/09 14:31 7/30/09 R0904198-013 417 22000010000100010 8/4/09 14:35 7/30/09 R0904198-014 418 23300010000100010 8/4/09 14:40 7/30/09 R0904198-015 419 21500010000100010 8/4/09 14:44 7/30/09 R0904198-016 420 100010001001 8/4/09 12:29 7/30/09 R0904198-MB U Method Blank COLUMBIA ANALYTICAL SERVICES, INC.

Water Sample Matrix:

Project: Jarvis Hall

University of Buffalo Client: Analytical Report R0904198 7/15/09 - 7/16/09

7/29/09 Date Received:

Date Collected:

Service Request:

Basis: Analysis Method:

Units: NAµg/L 200.7 Strontium, Total Prep Method:

EPA 3010AResultQMRLMDL Dilution Factor Date Analyzed Lab Code Date Extracted Sample Name 43200100010010 8/4/09 13:07 7/30/09 R0904198-001 405 32600100010010 8/4/09 13:36 7/30/09 R0904198-002 406 21000100010010 8/4/09 13:41 7/30/09 R0904198-003 407 10900100010010 8/4/09 13:45 7/30/09 R0904198-004 408 7500100010010 8/4/09 13:49 7/30/09 R0904198-005 409 5600100010010 8/4/09 13:53 7/30/09 R0904198-006 410 5100100010010 8/4/09 13:57 7/30/09 R0904198-007 411 4260100101 8/4/09 16:30 7/30/09 R0904198-008 412 43600100010010 8/4/09 14:14 7/30/09 R0904198-009 413 33000100010010 8/4/09 14:18 7/30/09 R0904198-010 414 20200100010010 8/4/09 14:23 7/30/09 R0904198-011 415 9400100010010 8/4/09 14:27 7/30/09 R0904198-012 416 5300100010010 8/4/09 14:31 7/30/09 R0904198-013 417 3800100101 8/4/09 16:57 7/30/09 R0904198-014 418 3330100101 8/4/09 17:21 7/30/09 R0904198-015 419 2890100101 8/4/09 17:25 7/30/09 R0904198-016 420 100100101 8/4/09 12:29 7/30/09 R0904198-MB U Method Blank Comments: Form 1A SuperSet

Reference:

\\Inflow2\Starlims\LimsReps\AnalyticalReport.rpt 09-0000114388 rev 00 Printed 8/5/09 16:44

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