Text

Union Electric Co Callaway Power Plant NPDES Permit Reapplication Feb 1985
	ML20107C933
Person / Time
Site:	Callaway
Issue date:	02/04/1985
From:	; UNION ELECTRIC CO.
To:	;
Shared Package
ML20107C928	List: ML20107C933;
References
	NUDOCS 8502220148
	Download: ML20107C933 (115)
	v • d • e

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g Union Electric Company Callaway Power Plant I NPDES PERMIT RE-APPLICATION February, 1985 I

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FOR AGENCY USE ONLY APPLICATION NWfBER

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, n c iggg7 FORM A - APPLICATION FOR DISMAMM PERMIT - ALL APPLICANTS I

DO NOT ATTEMPT TO COMPLETE THIS FORM BEFORE READING THE ACCOMPANYING INSTRUCTIONS MISSOURI DEPARTMENT OF NATURAL RESOURCES - DIVISION OF ENVIRONMENTAL QUALITY I P. O. Box 1368 5 Jefferson City, Missouri 65102 1.10 construction permit application . A $25.00 filing fee moist accompany each application for a construction permit.

1.20 Operating permit application I . A $75.00 filing fee must accompany each application for an operating permit.

Filing fees must be in the form of check, bank draft, or money order, payable to the State of Missouri. Cash will not be accepted.

1 2.10 Name of Facility Callaway Plant 2.20 Facility Address P.O. Box 620, Fulton Mo. 65251 Street City State Zip Code j 2.30 This facility is now in operation under Missouri operating Permit NumberMO-0098001 2.40 This is a new facility and was constructed under Missouri Construction Permit Number

. (Complete only if this facility does not have an operating permit.)

2.50 Owner Name Union Electric Company Phone (314) 554-2106

! Address 1901 Gratice St.- St. Louis, Mo. 63103 Street City State Zip Code 2.60 Operating Authority Name Same

Address Street City State Zip Code I

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2.70 Facility Contact Name Steven E. Miltenberger Phone (314) 676-8000 Title Plant Manager 2.80 Additional forms necessary to complete this applications

a. Does your facility receive and treat basically domestic waste:

yes (complete form B) no

See Outfall 007 3 b. Is your facility a manufac turing, commercial, mining or silviculture waste g treatment facility: I yes (complete form C and answer e of this subpart)

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no I c. Is your facility considered a " primary industry" under EPA guidelines:

I yes (complete forms C & D) no I certify that I am familiar with the information contained in the application, that I2.90 to the best of my knowledge and belief such information is true, complete and accurate, and if granted this permit, I agree to abide by the Missouri Clean Water Law and all rules, regulations, orders and decisions, subject to any legitimate

.I appeal available to applicant under the Missouri Clean Water Law, of the Missouri Clean Water Commission.

i Dates cP / '

b Applicant's Sigtiature (see instructions)

D. F. Schnell, Vice President Nuclear I

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CWC 105A ,

Page 2 ERv.12/80

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FOR AGENCY USE ONLY APPLICATION NUMBER MO -

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i L DATE RECEIVED FORM C - APPLICATION FOR DISCHARGE PERMIT MANUFACTURING, COD 9fERCIAL, MINING AND SILVICULTUh OPERATIONS I DO NOT ATTEMPT TO COMPLETE THIS FORM BEFORE READIPG THE ACCOMPANYING INSTRUCTIONS MISSOURI DEPARTMENT OF NATURAL RESOURCES - DIVISION OF ENVIRONMENTAL QUALITY P. O. Box 1368 Jefferson City, Missouri 65102 1.00 NAME OF FACILITY Callaway Power Plant 1.10 This facility is now in operation under Missouri Operating Permit Number MO-0098001 1.20 This is a new facility and was constructea under Missouri Construction Permit Number 0 permit.)

. (Complete only if this facility does not have an operating I 2.00 List the Standard Industrial Classification (SIC) codes applicable to your facility (4 digit code).

a. first 4911 Electric Services b. second 4949 Water Supply l c. third d. fourth 2.10 For each outfall give the legal description

! Outfall Number (list) % k Sec T R County See Attachment A '

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lt 2.20 For each outfall list the name of the receiving water Outfall number (list) Receiving water All designated outfalls discharge to the Missouri River.

I 2.30 Briefly describe the nature of your business: Steam Electric Power Plant (Nuclear)

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,E CWC 105C g

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I ALL FLOWS IN GPD 2.40 A. Attach a line drawing showing the water flow through the facility. Indicate sources of I intake water, operations contributing wastewater to the effluent, and treatment units labeled to correspond to the more detailed descriptions in Item B. Construct a water balance on the line drawing by showing average flows between intakes, operations, treat-ment units, public sewers and outfalls. If a water balance cannot be determined (e.g.,

I for certain mining activities), provide a pictorial description of the nature and amount of any sources of water and any collection or treatment measures.

I B. For each outfall, provide a description of: (1) All operations contributing wastewater to the effluent, including process wastewater, sanitary wastewater, cooling water, and storm water runoff; (2) The average flow contributed by each operation; and (3) The treatment received by the wastewater. Continue,on additional sheets if necessary.

1. Out- 2. Operation (s) contributing flow 3. Treatment fall No. a. Operation (list) b. Average flow a. Description b. List codes from (include units)

I (list) 001 - Radwaste Treatment System (maximum flow) 113500(258,000)

Table A Treatment - Discharge. Other wastewater treatment systems are used as required to treat this wastestream for recycle or discharge in compliance with h1C requirements and are also available as auxiliary or backup treatment systems to treat this discharge for compliance with NPDES permit limitations. (See Attachment A)

Codes - 4-A I Subsystems -

Boron Recycle 2500 Liquid Radwaste 7500 Train A 1500 Train B 6000 Laundry / Hot Shower 500 -

Secondary Liquid Waste 103,000 Condensate Regen 88,000 Floor Drains 15,000 Steam Generator Blowdown 0 CWC 105C Page 2 A L

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ALL FLOWS IN GPD

'2.40 A. Attach a line drawing showing the water flow through the facility. Indicate sources of intake 4 ter, operations contributing wastewater to the ef fluent, and treatment units labeled to correspond to the more detailed descriptions in It'm e B. Construct a water balance on the line drawing by showing average flows between intakes, operations, treat-ment units, public sewers and outfalls. If a water balance cannot be determined (e.g.,

for certain mining activities), provide a pictorial description of the nature and amount of any sources of water and any collection or treatment measures.

B. For each outfall, provide a description of: (1) All operations contributing wastewater to the effluent, ihcluding process wastewater, sanitary wastewater, cooling water, and I storm water runoff; (2) The average flow contributed by each operation; and (3) The treatment received by the wastewater. Continue on additional sheets if necessary.

1. Out- 2. Operation (s) contributing flow 3. Treatment fall No. a. Operation (list) b. Average flow a. Description b. List codes from (list) (include units) Table A (maximum flow)

I NOTE: Solid waste from the radwaste trectment system is disposed of in accordance with Nuclect Regulatory Commission (NRC) regulations.

l 002) Cooling Tower Blowdown 5,960,000 (14,400,000)

Treatment - Discharge 4A 1.

l 003) Water Treatment Plant Blowdown 332000 (1,305,000)

NOTE: The above flows represent the system wastewater effluent. Actual discharge may vary from zero, with total recycle, to the maximum above, with direct discharge.

Treatment - ranges from Sedimentation to Discharge (direct) to Reuse / Recycle Codes 1-U and/or 4-A and/or 4-C Subsystems - Clarifier blowdown 330,000 -

, Carbon Filter backwash 1700 l

CWC 105C Page 2B

i ALL FLOWS IN GFD 2.40 1A.,Attachalinedrawingshowingthewaterflowthroughthefacility. Indicate sources of intake water, operations contributing wastewater to the effluent, and treatment units labeled to correspond to the more detailed descriptions in Item B. Construct a water I balance on the line drawing by showing average flows between intakes, operations, treat-ment units, public sewers and outfalls. If a water balance cannot be determined (e.g.,

for certain mining activities), provide a pictorial description of the nature and amount of any sources of water and any collection or treatment measures.

B. For each outfall, provide a description of: (1) All operations contributing wastewater to the effluent, including process wastewater, sanitary wastewater, cooling water, and I storm water runoff; (2) The average flow contributed by each operation; and (3) The treatment received by the wastewater. Continue on additional sheets if necessary.

1. Out- 2. Operation (s) contributing flow 3. Treatment IfallNo.(list)

a. Operation (list) b. Average flov (include units)

a. Description b. List codes from Table A (maximum flow) 004 - Demineralizer Systems Wastes 70300(187000)

Treatment - Neutralization, Sedimentation and Discharge.

Codes; 2-K, 1-U, 4-A I Subsystems - Cation Regneration 21300 Anion Regen. 38700 4

Mixed Bed Regen. 3300 Building Sumps. 7000 I

005 - Oily Wastewater Separator 33000(144000)

Treatment - Gravity / Coalescer, Filtration, Discharge Codes; undefined, 4-A NOTE: Removed oil is accumulated on site, and disposed of in accordance I with applicable regulations.

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r ALL FLOWS IN GPD I2.40 ,

A. Attach a line drawing showing the water flow through the facility. Indicate sources of intake water, operations contributing wastewater to the ef fluent, and treatment units 1 labeled to correspond to the more detailed descriptions in Item B. Construct a water balance on the line drawing by showing average flows between intakes, operations, treat-ment units, public sewers and outfalls. If a water balance cannot be determined (a.g.,

I for certain mining activities), provide a pictorial description of the nature and amount of any sources of water and any collection or treatment measures.

I B. For each outfall, provide a description of: (1) All operations contributing wastewater to the effluent, including process wastewater, sanitary wastewater, cooling water, and storm water runoff; (2) The average flow contributed by each operation; and (3) The treatment received by the wastewater. Continue en additional sheets if necessary.

1. Out- 2. Operation (s) contributing flow 3. Treatment fall No. a. Operation (list) b. Average flow a. Description b. List codes from (include units)

I (list) Table A (maximum flow) 007 - Sanitary Wastewater Treatment Plant 24000 (40000)

Treatment - Activated Sludge, Sedimentation, Discharge to Surface Water Codes; 3-A, 1-U, 4-A NOTE: Sanitary waste treatment sludge is accumulated on site in an aerated sludge holding basin, then transferred for disposal to a publicly owned treatment works. At the present time, the city of Columbia, MO., receives our sludge for treatment and. disposal.

008 - Cooling Water Chemical Control System 1000 (4000)

Treatment - Discharge. Code 4-A Subsystems - Water Softener Regen 500 Maintenance Washes 500 009 - Intake Electric Heaters 0 (1000)

Treatment - Neutralization, Discharge Codes; 2-K, 4-A B

CWC 105C Page 2D L .

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2.40 ccatinued _

C Except for storm runote. :eaks. or spills. are any of the cisenarges cescribed in items A or B intermit: cot or seasenas K TES tcomplete the tcIlowing tabler D NO .go to Section 2 S01 ,

i 3. FREQUENCY 4. FLOW {

I l.DUTFALL 2. OPER ATION Is) 8. FLOW RATE ,In m@ L TOTAL VOLUME [5Ein CONTRIBUTING FLOW a OAYS 0 MCNTHs c. cur. ?

g7 gg;4 HUMBER I

PER WEEit PER ?! AR lQ,';, ll'll, ' f,Q* I ?ly"

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I 2.50 MAXIMUM PRODUCTION J ' ~1.l7 h l ' D f',n ,- - . J. - . .

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& TES (complete B) O NO (go to Section 2 60s I 8. Are the limitations in the applicable effluent guideline expressed in terms of production for att.er measure at operatic <t>?

O TES (complete C) m no(go to Section 2 60)

C. If you answered "Yes" to 8.1151 the quantity which represents an actual measurement of your maximurn level of production, expressed in the terms and units used in the applicable effluent guideline. and indicate the affected outfalls.

I a QUANTITY PER DAY h. UNITS OF MEASURE

l. M AXIMUM QUANTITY

c. OPER ATlON. PROCUCT M ATERIAL ITC.

ispecitys 2.AFFECTED DUTFALLS thst outtait numoerst I

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A. Are you now required by any Federal. State or local authority to meet any implementation schecute for the construction. uporad:nq or operation of I waste-water treatment equipment or practices or any other environmental programs which may affect the discharges described in this application?

This includes, but is not limited to, permit conditions. administrative or enforcement orders, enforcement compliance schedule letters, stipulations, court orders, and grant or loan conditions. O TES (complete the following table) B NO (to go 3 00) 1.10ENTIFICAT10N OF CON 0lTION, 2.AFFECTE0 OUTFALLS

3. BRIEF OESCRIPTION OF PROJECT a etcwsra e noncm AGREEMENT, ETC. a no a souct es oiscnust I

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B. OPil0NAL: You may attach additional sheets describing any additional water pollution controf programs ( or other environmentalprojects which may ettect your discharges) ycu now have underway or which you plan. Indicate whether each prograrn is now underway or planned. and and;cate your I

P1 ARK 'X'IF OES::!!!PT10N OF f.DDITIONAL C0HTF.0L Pr.0GttAMS IS ATTACHED. f I * actual or planned schedules for construction

See Attachment B PAGE 3

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I 3.00 INTAKE AND EFFLUENT CHARACTERISTICS A&B. See instructions before proceeding - Complete one table for each outf all - Annotate the outfall number in the space provided.

NOTE: Table 1 is included on separate sheets numbered 6 through 7.

C. Use the space below to list any of the pollutants listed in Table B of the instruc-tions, which you know or have reason to believe is discharged or may be discharged I from any outfall. For every pollutant you list, briefly describe the reasons you believe it to be present and report any anatytical data in your possession.

I 1. Pollutant Asbestos

2. Source Asbestos Cement Board is used in the Cooling Tower Fill.

The cooling Tower Basin Chemistry is controlled I to minimize tower fill deterioration.

I Strontium, Several isotopes of Strontium and Zirconium are produced Zirconium within the reactor by fission and activation processes.

Calculations show that a very small amount of these (approximately 10E-6 mg/1) may be released I isotopes from Outfall 001.

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3.10 SIOLOGICAL T0XICITY TESTING DATA Do you have any knowledge or reason to believe that any biological test for acute or chronic toxicity has been made on any of your discharges or on a receiving water in relation to your di scharge within the last 3 years?

I Yes (identify the test (s) and describe their purposes below) X No (go to 3.20)

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3.20 CONTRACT ANALYSIS INFORMATION W ne any of the analyses reported performed by a contract laboratory or consulting firm?

Yes (list the name, address, and telephone number of, and No (go to 3.30)

I1 pollutants analyzed, by each such laboratory or firm below)

C. Telephone D. Pollutants Analyzed

I A. Name B. Address (area code & No.) (list)

Controls for Environmental Pollution, Inc.

P. O. Box 5351 Santa Fe, New Mexico 87502 800-545-2188

See Attachment F I 3 .30 CERTIFICATION that I have personally examined and am familiar with the I I certify under information penaltyinofthis submitted lawapplication and all attachments and that, based on my inquiry of those individuals immediately responsible for obtaining the information, I believe that th2 information is true, accurate and complete. I am aware that there are significant I penalties for submitting false information, including the possibility of fine and imprison-ment.

D. F. Schnell, Vice President - Nuclear (314) 554-2650 A. Nane & Official Title (type or print) B. Phone No. (area code & No.)

S all C. Signature (see iristructions)'

aNac D. Date Signed CWC 105C Page 5 I

M. W W W W W W M M M W W M M M M M M M Form C

' 'PLEASE PNINT OR TYPE. You may report some er all el this leierMaHen en separate shesis TABLE I fcr 3.00 Item A Ai B tuse the same formats lastead el complehog these pages.

SEE INSTRUCTIONS. .. - ,,

-,- -x q, y ,4. Guir ALL NO.

INTAKE AND EFFLUENT CH ARACTERISTICS (continued from page 3 of form 2 CJ ,.g ,

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PART A -- Yoiiim}t provide the sesults of at least one analysis for every pollutant m this table Complete one table for each outtall. See instructions for additional details.

4. INTAKE toptionals

2. EFFLUENT 3. UNITS Ispecs/y #1blanA)

ION U I hNOOF

1. POLLUTANT 4 M AllMUM OARY VALUE E MAIBMUM 30 SAY VALUE ednm. c. LONC TERM AVAG. VRUE e # ****' e NG OF s Couctu

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UII,IE 53 35 1 mg/l Ibs/d e su sn,.a..

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" ' " " """ """" """ STANDARD UNITS

.su 9 0 PART B - Mark "X" in column 2-a for each pollutant you know or have reason to believe is present. Mark "X" in column 2-b f or each pollutant you believe to be absent. Il you 2-a for any po!!utant. you must provide the results of at least one analysis for that pollutant. Complete one table for each outfall.See the instructions for additional details and requirements.

4. UNITS 5. INTAKE f optionats

3. EFFLUENT f.P0tEUT. 2. MAas T & We OF a LONG TI AM AVERAr.L V ALUE h NO Of ANT AN t. MAIIMUM 30 OAV VALUE ,,a ns nm, c. LONG TE AM AVRC. VALUE #4 ma ame, & CONCIN.

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Flow shown is for day of sampling; See attachment F I

M M M M M M M M M M M M S U O U r i CONTINUES FROM FRONT

1. POLLI,T- 2. MARK X*

3. EFFLUENT 4. UNITS 5. C~ TAK E (optional) *'

SN s'wUs t"uEs & MAllNUM SARY VR UE t. NAXINUN 30 OAY V Atut e t mumme & LONG TIRN AVS$. VALUE ..t mume. G. N6. Of *

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d' X 1.04E-7 31.2 (Not cali:ulated; see radiological record) 1 uC/mi uC/d aisca X 1.78E-7 53.4 (Not cal <:ulated; see radiological record) 1 uC/mi uC/d 136 Amhum tas y lNA X n :.u.se.

NIEros. X 2649 1752 1 mg/l lbs/d i suei e.

X 0.06 0.04 1 mg/l lbs/d a Sult te NIE4s si X e2 41 1 mg/l Ibs/d a 5 rixtants

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gew es

X 4 0.01 4 0.007 1 mg/l lbs/d i no. ram X 3.10 2.05 1 mg/l lbs/d I tagne$eum. .

IiI$es a X 1.84 1.22 1 mg/l 1bs/d a ustybdenum i7E 9e n X 4 0.01 4 0.007 1 mg/l lbs/d y e no.am

$$

se X 0.36 0.24 1 mg/l lbs/d

. im re, X 4 0.1 4 0.07 1 mg/l 1bs/d i.

a 'i'u~"e" x

cwe ease *Less than one liter of a surfactant product PAGE 7 ** Estimated maximum boron concentration is 10 mg/l

am one will be present in 88000 gal of condensate regenerati on waste.

M M M M M M M M M M W W M M M M M M M Form C

'PLEASE PAINT OR TTPE. Teu may report some er all el this internation en separate sheets TABLE I for 3 00 Item A & B 1 t

tust the same format) instead et completing these pa0es.

SEE INSTRUCTIONS. cre "q.* 34T i

~-

n p- , y ,c s .f.-.

. g ' $ g .gb ; , 9 d Ou rAtt me.

CTAKE AND Ef f tUENT CH ARACTElllSTICS icontenced trom page 3 of form 2-C) g

..g.g. M Q.,, .9 { Ql. e 002 PART A -- You must provide the results of at least one analysis for every pollutant en this table Complete one table for each outfall See mstructions for additional details.

4. INTAKE foptionals

2. EFFLUENT 3. UNITS fspecify sf blankJ

.LO it VI E VALUE b uo 0F I. POLLUTANT a MAllMUM OAltV VALUE b MAIIMUM 30 0AY VALUE #4=.m e t0NG if 8M AVAG. VALUE s.r= un"' d h0 0F a cDNcf M- ANALY1f8 "I

pesct$bres 421 mass ANALTsES 18Ar0h k MAIS gj(,, m uass react Naates cascadhates a s.acanecd 8,g" 8' 12 720 1 mg/1 , Ibs/d ,

. cn cs mg/l Ibs/d "Arra h"'ad 47.2 2830 1 5

c i.ss.re

.o... c 58 3500 1 mg/l 1bs/d d roid sust.naed 5*** 8'35' 144 8640 47.4 2510 35.8 1/h/13 mg/l Iba/d e Am.on.a ..i es 1 mg/l Ibs/d 0.1 6 VALUE VALUE VRUE '

, geo, VALUE 7,200,000 6.360,000 4.550.000 1/31/92 NA gal /d VRUE VRUE VRUE

,r,,,,,,,,, vA101 ,C

""" 15.6 66 66 1/3_1.f_92 VALUE VAtut VRUE n i..,,, a,,, Vuut C

""**'" N.A. '

utusmum maximuss mimesses maXle8vm 8.50 8.59 7.6 8.95 8/92 PART B - Mark"X"in column 2-a for each pollutant you know or have reason to believeis present. Mark "X" in column 2-b for each p 2-a for any pollutant you must provide the results of at least one analysis for that pollutant. Complete one table for each outf all.See the instruction and requirements. 5. INT AKE (optional)

3. EFFLUENT

4. UNITS I.P0LLUT- 2. ht Ann T & LONE TERM AVERAct VAtui k NO OF ANT A" k MAXIMUM 30 BAT VALUE e,# meem , c. LONG T[sM AVRG. VALUE #,t =m 6. NO. OF a c0NcrN. A a [Sa a. MAIIMuM OAILY VALUE mus A,jfg* TaAma kN ,,,c,p,,,,, m enu v AS NO A " m uass g,,c, jg,,,,

(,t avalable) Er s!*e conce$ hares casca$1 ares Gam'a x

. cnw X 0.0 4 mg/l lbs/d <

c Cole,

_u X

d Focal c**= X

. ri

.d.

X 1.3 78 1 mg/l Ibs/d i 01','E=, X

\

PAGE 8 cee ime

5 M M M M M M M M O O O M U S M M M O,

s CONTINUED FROM FRONT .

1. POLLUT- 2. EARK T 3. EFFLUENT 4. UNITS 5. INTAKE Ioptiona/J !'

$TAg },, h, & MAIWUN BAILY VALUE t. M AIIMUM 30 BAY VAtut w asm, c.LONG TE AM AVOS. VALUE w num, 4 NO. Of a LONG IIRM AVFRACf VALUE k WO Of **

,,, d ~.,.o ,, en, a, _, a ,,, - _, a., - _,a. , a- i;ti- a1C.ONCl.u.

m0

aa$s

_, as ,,, ... i;ti-1ll4',',e -

,,s = X n o,e a,.d 1/4/

X 3.3 200 1.5 80 1.4 53 13 mg/l lbs/d

. e weio. s EEiN# X 1.8 110 1 mg/l lbs/d g Rad.oactevitt til Alpha umm X

.218 eta iotJ

.m nad e va' .

X is: nao.om a ice X

= sone.

Za!!'am X 930 55800 1 mg/l lbs/d i Sutt.

eas s, de X

m Suiteit tas 501 nas 45 3i X z2 e100 1 mg/l lbs/d a Sweactants X

e num.w.,

suo um S S - X 0.8 50 1 mg/l lbs/d 9s,w.

E$nh X 0.3 20 1 mg/l lbs/d 1S?*"

u.2. ., X lof.f'"

v a , X s i,0. ims X 3.99 240 1 mg/l lbs/d Idj"*' '

u*n 95 48 X 93.2 5710 1 mg/l lbs/d

. ea nav aw.

sois g4n ss 7 X g tanganese n'$ m s, X 0.26 16 1 mg/l lbs/d

. v voia

"** 2' 5' X e 0.1 46 1 mg/l lbs/d e id ,wum iid 27e X w c inst

a. PAGE 7 an. oss

M M M M M M M M M M W m M M M m e em Form C ** clarifier Blowdown Supernatent

~ some er all el this internation en separate sheels PLEASE PRINT OR TYPL You maV TABLE I for.3.00 item A & 8 tuse the same format) instead el ca eting these pages.

SEE INSTRUCil0NS. -y m wm. . m, v l e gg . m. n . o,- c v lNT AKE AND Ef FLUENT CN ARACTERISTICS (continued from page J of form 2-CJ gg,,, a ;.g ..jg. g*,.,{ g,.j.g*n Mv] ouTF003* ALL*mo. ,

PART A - You must provide the results of at least one analysis for every pollutant m this table Complete one table for each4.outtall lN1AKESee instructions for addition toptionato 2.Ef FLUENT 3.Unl15 Ispecsfy siblank) 1888 8" IIII II

6 No of

t. MAllMUM 30 DAY VALUE edans m t LONG TERM AVRG. VALUE #dmem 1 RO Of a c0Ncgg.

1. POLLUT ANT a MAllMUM OAILY VALUE

"'** ""' muass ANALYS($ 194I10s L MASI yQ m aass ANALV358 cosciNnates taat Naarne

_ Jdates og[.Yfd 13 36 1 ing/l 1bs/d 6 1 b chemual ogga 0'ad 67.6 186 1 mg/l lbs/d 16 1 clUeIo'c7' 96 264 1 ma/1 lbsid 46 1 Iddris?'" 8 20 2 mg/l 1bs/d 53 1 5.8 1 mg/l 1bs/d 0.1 1 2.1 VALUE VALUE VALUE

,,% VALUE 330,000* ** 1 NA gal /d i vuUE vAtut VALUE vaut ,C

,i,,,,.

'*** 11.4 VALU(

VRUE

.,,,,,,,w, v4LUE VALUt ,C NA NA N.A.

minMeum manseque mMMasses maximum PAfiT B - Mar k ~X"in column 2-a for each pollutant you know or have reason to believe is present. Mark "X" in column 2-b for each pollutant you bel 2-a for any pollutant. you must provide the results of at least one analysis for that pollutant. Complete one table for each outf all.See the instructio and requirements. 5. INTAKE (opfsonall

3. EFFLUENT

4. UNITS

1. PottuT- 2. MARE'r & NO. Of a 104C IERM AVERAGE VALUE

6 NO Of k IIAllMUM 30 SAY VALUE #dsvs.ranse, t LONS TERM AVAG. VALUE vos..#aw s.c0Nttu.

ANT AND g,ej, g, s. MAllMUM OAILY V ALUE A "'*8 E "'** Y $ MANN IN CDectNestes O ""I V I

coatibfes centshasten te av si bth) $ g!$1 coscihnates a!#".f X f.'fll% x c color X

a ana:

c*""" X "gji 1

0.44 1

' i rIs'#'A X EI.T=, X mg/1 0.9 i C"8 ' *** See Attachment F

! *This data represents a single days' analysis; See Attachment F.

M M MIM M M M M & M M M O O O O M S o 5

CONTINUED FROM FRONT _' -

1. POLLUT- 2.El.ast T 3. EFFLUENT 4. UNITS 5. C~TAKE (optionif)

ATA Kl,", a MAI: MUM GAU VALUE 4 98AXIMUM 30 BAV VAttlE ntnadan=> t t0NG TERM AVAG. VAtut or a.a.same d. NO. 0F a CONCEN-a W W AM VM kWH **

N k "gg

- ,,,,, jg,,,, maan ,,,c,jh,,,,, m uass A/3jg-gg,gj %g., A " ass c,,,c, jg,,,, m uass A/3j3- TaAlsoN tir avadablef g ,,

Netsegen fote ei n,orgaswc X b 01 and -.w n e

. c e:

X 86

240 1 mg/l 4.7 g

.'57,I747' om i4 c X I mg/l 40.1 1 g Radioattsvity 111 Alplia umm X

eh 8 eta 19144 X

.31 Radeum.

Iotal 148 Radeum 7/6 10181 X

k Sulfate

'fils),si y 1 mg/l 177 1 s Suttiae las $)

m Sulhte IflE'es 3> X 1 28/F 42 1 a Sustar.tants X

. aium.num.

iil$ 90 si X 0.2 0.6 1 mg/l lbs/d 0.4 1 Barium.

al$ n s, X 2.3 6.3 1 mg/l lbs/d 0.1 1 Boron iS5 42 s> X ma/1 0.5 1 e tobais voim v444 e X mg/l 4 0.01 1 s iron v.is

"*""* mg/l X 29.0 79.8 1 lbs/d 0.83 1 GLagnessum. e

' mg/l is$,s 4. X 115 316 1 lbs/d 27.5 1

. umybdenum iY4S 9s n y 4 0.01 1 MJnganese

<$$

58 X 53.9 148 1 mg/l lbs/d 0.13 1

. v.n voim

'd* 2' 5' mg/l X 4 0.1 40.3 1 lbs/d 4 0.1 1 Im'$'"'""

use 32 s' X E8'i y

Result suspect, additional analysis will be performgdgE 7

W W W W W W W M M M M M M M M M M M M i Form C PLEASE PRINT OR TYPE. Yee maV report some er all el this tolermation en separate sheets TABLE I for 3.00 Item A & 8

Clarifier Blowdown !

I tuse itse same format) lastead el completing these pages.

SEE INSTRUCTIONS. , .

- -.-- .g 77-OUlr ALL NO.

INTAKE AND EFFLUENT CH ARACTERISTICS (contmued from page 3 cf fortn 2-C) 1.g- . g r ej,. g g g. _ , jh .J .- -r ..] 003*

PART A - You must provide the sesults of at least one analysts for every pollutant in this table. Complete one table for each outf all See Instructions for additional delads.

3.plTS Ispecsty sf blanA) 4. INTAKE foptionah

2. EFFLUENT j E 8 II b N0 0F a MAliMUM 0AILV V ALUE E MAllMUM 30 0AV VALUE #.t um s. LONG TERM AVAG. V ALUE s.s maa '" ( N0 0F s.c0NcfN.

j l. POLLUT ANT IRAilog bM C,,t, gy,,,,, A mass mWM

' jesceNaaTem Jact$bTee coett$faafee I a euxhemcal f,fR" *'*'"' 1 mg/l lbs/d 6 1 12 33 b Chem tai

iJga o'**ad 64.4 177 1 mg/l ibs/d 16 1 c,Te.la.1,01am6 c 1 55 150 1 mg/l lbs/d 46 1 e r is s si,ea a soledn f r$$# 60400 166,000 2 ma/1 lbs/d 53 i e a me a .c =,

1.4 3.9 1 mg/l lbs/d 0.1 1 VALUE VALUE VALUE

,,,,, VALUE 330,000** NA NA gal /d 1 VALUE VALUE VALUE

,y,.,,,,,, VALUE ,C 3

,.*'e" 11.4 1 VALUE VALUE VALUE Q Tempe,alwe hALUE NA

""***'8 N.A.

Misiii4UM MAIIMUE4 MtMIMURI MAIIMUM

,g 7.75 7.97 _

PART B - Mark"X"in column 2-alor each pollutant you know or have reason to believeis present. Mark "X"in column 2-b for each pollutant you believe to be absent. If you 2-a for any pollutant, you must provide the results of at least one analysis for that pollutant. Complete one table for each outfall.See the instructions for addi and requirements. 5. INTAKE toptionalJ

3. EFFLUENT 4. UNITS

1. rottuT- 2.Mann r s LONG IIRM AVERACI VALUE 6 NO 0F d NO Of 1 A" ' a MAllMUM OA!LV VALUE k MA11 MUM 30 DAV VALUE wem c. LONG TERM AVAG VALUE e.t,m a CONcfN.

I' 8E A A"a c NO e imEs m enu ,,,c, jy,,,,, mean m ean 8,jj( TaATWN g,,g, jg,,,, m uass vs v,t .otes Eli s'It c ce4% ree cotalYanies

$$O's. X E.?Ne*.*a.>a y c csa Y

e rms Col.leem y

. ri .a.

*** a n' mn/1 (L AA 1 X

e m.m n.m.i'"*'i.- X mg/l 0.9 1 PAGE6 cwe ac ** See Attachment F I

M M M M M M M M O O O O M M ,

j CONTINUED FROM FRONT -

1. POLLUT- 2. Cant *X* 3. EFFLUENT 4. UNITS 5. INTAKE foptional) **

$TA gg ,

, gj, b

E MAXIMUM OAILY VALUE t RIAIIMUM 30 0AV VAluf ed avadan=> c. LONG TIRM AWAG. VALUE 4d a.adanar, d. NO. 0F g gggggg. a. tDNG TERM AVERAGI VALUE t.20 0F **

Id avadao/c) l,'!, si',, cancij% rie, m eus ,,,,, jgy,, m eus ,,,,, j g,,,, maan yglg' TRAIEN ,,,,, jh,,,, m aus A{gfg-9

.Iolal as n, Organec X b Od and X 29* 80 1 mg/l lbs/d 4.7 1 e Phosphosus l9$d*o'.# X mg/l 0.1 1 g Rad.extsvety 411 Alpha ime X

1218 eta ime X

sk Rsdeum X

141 RadoufR m ime X

s sanae IIInfUss. X 1 mg/1 lbs/d 177 1 8 Sulfide oss so y

a Sufiste EOsm X 1 mg/l lbs/d 42 1 n Suttattants

~ {Asum.num ir*2S 5 5' X 15.2 41.8 1 mg/l 1bs/d 0.4 1

$p e iu .$nt X 1.5 4.1 1 mg/l 1bs/d 0.1 1 Boron

$$c ei X 1 mg/l Ibs/d 0.5 1 i loi7'"

l tise 4 45 x 1 mst/1 lbs/d 40.01 1 s toa ims X 23.2 63.8 1 mg/l lbs/d 0.83 1 i

i cans <

s'/$ ss 4. x 123 338 1 mg/l ibs/d 27.5 1 m u.ivoma.m.

47$ss ri X 1 mg/1 lbs/d 40.01 1 gaaganes.

<ios a si X 52.8 145 1 mg/l lbs/d 0.13 1 e Tin Total i'** 3' 5' l X 40.1 40.3 1 mg/l lbs/d 40.1 1 l J ,'j'a'"'"

l ir4e r e X

=

cwc insc

Result suspect, additional analysis will PAGE7 3 "a '8/" be performed.

M M M M M M M M M M M M M M M M M. M' Form C

' 'PLEASE PRINT OR TYPE.Teu may r t some er all el this laternation se separate sheets TABLE I for 3.00 item A & B -

ruse the same toiman instead el comp eting these pages. i SEE INSTRUCil0NS. --

- ,, . , g.3 gu,,,,g ,,_ l

. ,,_.7

,. mE, .h

~,TAKE AND ElFLUENT CH ARACTERISTICS (continued kom page 3 of form 7c) l y,g. ggl ,

. y; , j ff,ih 004 I 9

PART A - You must provide the results of at least one analysis for every pollutant in this table Complete one table for each outtall, See mstructions for additional details.

2. Ef FLUENT 3. UNITS tspectly siblank) A INIAKE LOP!'OR'li k MAIIMUM 30 OAV VALUE #dm s Wr, c, LONG TE AM AVRG. VALUE id *** a LONG TERM AVISAGf VRW t NO 0F *

1. POLLUTANT a MAXIMUM OAILY VALui t h6 Of a C0hcf N.

" *"'" cualkree m =au AnRrsts taArma 0. NASS c,,r, j(,, m aass AMRVS18

_ _rmdkras casalkres

. s.n.m.ca mg/l aga ****"' 7 4 1 1bs/d

. ca =a fga ****** 14 8.9 1 mg/l Ibs/d E.'s",IJc'," 47 30 1 mg/l lbs/d

, i a s.-e.

5** ' " S' 1 mg/1 lbs /d 17 11

.Ammaa .u=,

20.1 4 0.06 1 mg/l lbs/d VALUE VAtut VRUE VRUE a gw NA gal /d 76000 1 VALUE VALUE VALUE

, g,.,,, m, vuuE ,C

,. arm 20.2 1 VRUg VALUE VALUE VALUE a T.meerme ssammen NA >

MINtaIUM MAXIMURI MMIIMUM MAIN 00M

,g STANDARD UNITS 8.15 1 -

same -

PART B - Mark"X" in column 2-aIor each pollutant you know or have reasonto believeis present. Mark "X" in column 2-b for each pollutant you believe to be absent. If you m 2-a for any pollutant. you must provide the results of at least one analysis for that pollutant. Complete one table for each outfall.See the instructions for ad and requirements. 5. INTAKE (optsonal)

3. EFFLUENT 4. UNITS

3. POLLUT- 2. M4na T a. LONGI!RM AVERACE VRUE t N0 of ANTAN0 t. MAIIMUM 30 SAT VALUE ,emaws, c. LONG TtBM AVRC. VALUE #d wa asas, 4 NO Of a c0Nctu.

,Q , ,Q, s. MAllMUM OAILY VALUE kM """

CAS N0 """" "" m aass Ajlg*

y TaAHoN cascadbine I S (er avantabds $ s$v casalbrus cancilbree cancelbres 0?lEE'M X tef 13.a ,

c c.=

X

. Facal c"** X N N' 1.0 1 mg/l lbs/d I X 1.6 n,

n.N.u m..e- X 1.0 0.63 1 mg/1 lbs/d PAGE S m ia>c

M M M M M M M M M M M M M M M M,

'i CONTINUED FROM FRONT ,-

5. C.T AK E (optional) **

1 1. POLLUT- 2.CAnn r 3. EFFLUCT 4. UNITS

t. M AllMUM 30 BAT VALUE t.t avueur. t LONG TERM AVAG. VALUE e.t4.uam, d. NO. OF * # W ON N IUU

$TAN sus teNa a MAllMUM BAILY VALUE

& CONCIN- ggg fa celabic) si r sI!ir esecr$bres cascalbres cancelYaates V$fS' I8AI88 cancilbres m uass A,jjg' fffoTao.c en e, X b OJ and

. c<m X 6.0 3.8 1 mg/l lbs/d

. ev.os.+o..s

Js Ps folat urni4 o. X s Rad oJClevtly its Alpha 68 X in eeta

'" X a, edo m .

io

x tai Ada m a isa ,

. s .,.

'OS). . X 1790 1134 1 mg/l Ibs/d i ss d.

en si m $.altit.

'OE's4 3i y 42 41 1 mg/1 lbs/d a sustattasis X

e Alum num A li45 90 se - X 0.2 0.1 1 mg/l lbs/d fl '"'

g.o as 3, X 4 0.1 4 0.06 1 mg/l lbs/d 10 **

g. . 1 e tocan loss v44o de 46 y 5 kon Total X 1.06 0.672 1 mg/l lbs/d i u, s .

I"#.e ss ai X 104 65.9 1 mg/l lbs/d

. us, m imm aase n X Io"m"'""'

083S 5 5' X 0.02 0.01 1 mg/l lbs/d

. T.a TWA

"'*" mg/l X z 0.1 e 0.06 1 lbs/d Ia'A**

a.e u e 1 cwc insc PAGE 7 q na s>m

W W W W W W M M M M M M Form C

' hEASE PRINT OR TYPE. You may report some er all el this interestion en separate sheets TABLE I for 3.N ItOE A & B fuse the $3tne format) instead el completing these pages.

SEE INSTRUCTIONS. ' I INTAKE AND EFFLUENT CN ARACTERISTICS (continued from page 3 of form 74 J ',p yvj,4 ["fh1;

.s w<,

{p ./j.7

?

gg pwm,.,y

,3 .,f ,Q.gey-Te$

O~

7,,g:,UTF ALL IIG. ~

8 PART A - You must provide the results of at least one analysis for every pollutant in this table Complete one table for each outf all See instructions for additional details.

4 lNTAKE toptionato

2. EFELUENT 3. UNITS ispecsty #I blank)

t. MAIIMUM 30 BAT VRUE #damo.w. t LONG TERM AVAG VALUE e.s**'*"' s he OF 8 8 U I t NO OF .

1.POLLUTANf a MAIiMUM BAILY VRUE a couctu.

"" c ctl Lie. iri mass ANALYSES 3RAll0g t MASS gg,, pimass ANALY$[$

, Lo.jcare. c ciEYeave.

.s e a

",Jr* **""' 10 3.8 1 ma/1 lbs/d a c.em4W 60.7 23.3 i mg/l lbs/d

."/JI' "'""* ,,,_

c '."."I8c", 41 .16 1 mg/1 lbs/d

. i s -.

lbs/d 5** 55' 21 8.1 11.3 2.54 8.5 2.3 1.1.3 ma/1

. a. ,n n, mg/l lbs/d 0.2 0.08 T VALUE VALUE VALUE VALUE

,y%

46000* 45000 33000 1,5,13 NA gal /d

~

VALUE VALUE VALUE

,i,.,,,a,,, vALUE ,C

'*"** 20.2 T VALUE VALUE

' WALUE VALUE n 3,.,,,,,, ,C 85 - 8 N.A.

usMamuss manimoes meseMesses manMeuaE

,,,, STANDARD UNITS 8.15 same 8.05 8.68 PART B - Mark"X"in column 2-a for each pollutantyou know or have reasonto believeis present. Mark "X"in column 2-b for each pollutant you believe to be absent. If you mark column 2-a for any pollutant, you must provide the results of at least one analysis for that pollutant. Complete one table for each outfall.See the instructions for additional details and re3uirements. 4. UNITS 5. lNTAKE foprsonaff

2. Mann T 3. EFFLUENT l.POLLUT- 8 NO. OF a.LONG TERM AVERACE VALUE ILNO 0F

b. MAIIMUM 30 BAV VALUE #d msmee, c. LONG TE94 AVAG. VALUE se mesamr ANT AND *

,J, 45, 3. MAllMUM BAILV VALUE s.c0NcfN. " "'88 *" EIE

"'" ""'" c alkie. *"'" '"sII I" A T S" a.alkie.

E."2.,"Si a s". . c n4L, c nlLt SAT *J'M x

f. Cat.~~a x e cas.

X

. reem ca'** X i

. rw.

""'**** I 0.64 0.25 1 mg/l lbs/d i .

en -

aa'a' das *< X 1.63 2.66 1 mg/l Ibs/d 8'C '*C

Daily average flow during week of sampling.

e C

m W W W M M M M M M M M M CONTINUED FROM FRONT I. POLluT- 2. RIARK T 3. EFFLUENT 4. UNITS 5. INTAKE (optional) -

$TAu M, & MAllNUM OAltf VALUE t.NAIIMUM 30 0AY VAtut ed e mise, c LONG TERM AVOS. WALUE e.sava.sm & No. OF E CONCEN- a touG TERM AVERACE VALUE t.NO 0F **

l 8'Jdd81'8 " " " """" gIII

, liY n'* r ewrlhes concilkres " " "

cancilhee Th IRAll0N g,,,c,j h , m eus A,jAs -

, .ge.

.I.,o ts Organec X a OJ and ca= X 1.2 7.2 1.6 ~

3.0 5.1 1.4 1,1,3 mg/l lbs/d'

',NME ans i4 ei X 0.4 0.2 1 mg/l 1bs/d l Maeomtevdy a ti K.ipha Ie449 aisaa ime g

43 Ra@um I.td 14a Radwm 726 total X

m s.ase

'Uff,si X 360 138 1 mg/l lbs/d i somd.

fJS Ss a Suit.re

'I$s-si X z2 40.8 1 mg/l lbs/d n Suetutanis X

IetM ove 90 9 X 15.2 5.38 1 mg/l lbs/d

$g e iom$ 4s X s, 0.2 0.08 1 mg/l lbs/d e so, II"Isc ai X 0.2 0.08 1 mg/l lbs/d ci m.'.a*'" .i X

s. reu

" 5.60 X 2.15 1 mg/1' lbs/d g,e,jeaesa .

ass es 4 X 47.4 18.2 1 mst/1 lbs/d

. u,w e EEss n X e0.01 e 0.004 1 mg/l lbs/d y e.. es.

u""s 96 si X 0.16 0.061 1 mg/1 lbs/d

. im som

"'*3'"

X z 0.1 40.04 1 mg/1 lbs/d i.' n g.i.i~~ X cwe oc PAGE 7 se iseso t

M M M M M M M ql Form C . ,

i

'rLEAsl ra NT on TTPE. Tom may report some er all ei this Internation se separate sheets TABLE I for 3.00 iteIR A & B ,

tuse itse same format) instead el completing Ibest pages. t SEE INSTRUCil0NS. "' ws ; . s.

, gy; un 7m.3 ' .E ..

,l' Ng f.fr7<0-4.#dg OUTFRL No. f INTAKE AND EliLUENT CH ARACTERISTICS (continued from page 3 of Form 2-C) ,,.,;,.. , j {'% g ',, . . ,' Et4Ms9.m ,007. ,

PART A - You must provide the results of at least one analysis for every pollutant in this table. Complete one table for each outf all See instructions for additional details.

3.UntTS Ispecofyilblank) 4.l8tfAKE toptionalf

2. EFELUENT

t. MAIMUM 30 0AT V Alut ve nmems. LONG i[AM AvK VALUE s.snmua* ( 110 0f a teNCEg.

"" ' U b N0 0F

1. POLLUTANT a MAIMUM BAILY VRUE ANAlviES Aeutsts b. MA38 m uass

""'" ""'" coscrdkres mean TaAlloN m jk ,,,

. p.cidssi e. concvUnares a e.athem.sd 1 mg/l lbs/d f X ""* _

8 2 a chantal 1 mg/l lbs/d fg **** 33.4 9.62 c im.a.

a

,rtor 8c,nc 1 mg/l 1bs/d ca,t 19 5.5 e feassesse.ees 58 a arss' 27.6 4.37 11.5 2.2 1,1,3 mg/l 1bs/d 24 6.9

,n e,

.a e 0.1 e 0.03 1 mg/1 lbs/d VALUE VALUE VRUE

,g% vAtuE 34560 35000 23000 1.4.13 NA Ral/d vuut vaut

,,,,,,,,,,, vAtui vaut ,C

=> 13.6-16.5 7 vaut vitut vuut vauf ,C n aarn N.A.

minimens maniasses usNemune manMews STANDARD UNITS

X" in column 2-b for each pollutant you believe to be absent. If you mark column PART B - Mark ~X" in column 2-a for each pollutant you know cr have reason to believeis present. Mark 2-a for any pollutant. you must provide the results of at least one analysis for that pollutant. Complete one table for each outf all.See the instructions for add and requirements. 5. INTAK E (optional)

3. EFFLUENT

4. UNITS 1.POLLUT- 2. mann T bN OF t No ef a LONC TEAM AVERACE VALUE Ai8T AND p,4, ,e ,ej, a MAImum SAILT VALUE b. MAImUM 30 SAT VEUE namuam c. LONS TillM AVK VALUE es .s.am a CONCEg, IIAI88 ' *"'" YSE S' CASNO "" """' cascalbies TSES' cascalhtes let avastabd# $ sst caecidbres concedMies d

88m x

. cm '

sma an.e.s g c ca.

X e

c.F. "==cal X 150 N.A. 4 co1/mi NA i

. rio.

s'm as si X 0.80 0.23 1 mg/l lbs/d ,

en -

a*a '** ** X 40 12 1 mg/l 1bs/d PAGEE twciac s

E E E E E E E

} CONTINUEJ FROM FRONT -

1. POLLUT- 2. 84 ARE *E* 3. EFFLUENT **

A 4. UNITS 5. ETAKE (optional)

C SN 'sYa i Ms & MAX 4 MUM OARY VR UE e MAllMUM 30 0AY VRUE e,# avsme, c. LONG il AM AVAS. VRUE w 4.a.ame. d. 0 Of a LONG MM AMAGE VRUE **

f.t awt soies [", **

esisesAktise

""'" mlhies ""'** ""'**

a CONCEN-taAISN gtpggg k h,0nM

.r cancilkvise Yst s' gg,,gg j(y, m uass A,s( g-9n.

.fA X 0.7 0.2 1 mg/l 1bs/d 6 04 ana

'" 1.4 mg/l

. en.spaa,.s X 5.0 1 Ibs/d an h f asal dia 14 0 3 Radseat.wsty X 5,8 1.7 1 mg[1 lbs[d iII Alpfla ima y

(?s Beta Ion.:s X

oe cas Tots tel Radas.

726 10tal li $*8 tate lfNS're s. X- 130_* 37.1 1 mst/1 lbs/d i s ina.

oss s,

. Suffalt dasSO4 e14,15 45 3>

I a swiniants X e 0.1 4 0.03 1 mg/l lbs/d

. a= .

I.64l a4. > so w I 0.2 0.06 1 mg/l lbs/d g e,io.

45$ n 3, mg/l X 40.1 4 0.03 1 lbs/d y e aa is$ o s. X 0.5 0.1 1 mg/l lbs/d Ya"***

va a *> X i we. rois X 0.10 0.03 1 mg/l lbs/d i e.a9nes .

I5 fess. X 41.6 12.0 1 mg/l lbs/d

. us,no iU$se ri X f 's"*"~

a4* 96 9 I e 0.01 4 0.003 1 mg/1 lbs/d e T. Totd X 4 0.1 e.0.03 1 mst/1 lbs/d UA'*""

v= 2e 58 X twc inse PAGE 7 g '" 'sa *Not anilyzed by C.E.P. (See Attachment F), Grab sample taken 9/20/84.

iM .

M M M M M M 1

i .

I Form C s some er all allins intermatise en separate sheets TABLE I for,3.00 item A & B

' 'PLEASE fuse the same PRINT form.4f)on TYPE.Yee instead el camp may rytimg these pages.

SEE INSTRUCTIONS.

., mgr

' ' - rc 5 - ., i +: Culf ALL N0.

. ittg'.p .' ':e

. . 008 INTAKE Afl0 EFFLUENT CH ARACTERISTICS (continued from page 3 of form 2 C) a .. i -w M a 1.~.n _ ,_ _

__PART A - You must provide the results of at least one analysis for every pollutant in this table Complete one table for each outf all See instructions for additional details.

4. INTAKE (optionah

2. EFFLUENT 3. UNITS (specsty si blank)

II I t NO 0F

u AllMUM OAILV VALUE t. MAIIMUM 30 OAV VALUE edmu aw, c. LONG TERM AVRC. VALUE ed maan"' d to 0F a c0NCEg. AmAtms I. POLLUTANT &#ums a Mass canaki., m ean canJLim

- cascakr, m =*u imen

~

ca.raki

.n - a 1 mg/l 1bs/d "qj *** 6 0.025 s cims 84 ga * *' 17.8 0.0742 1 mg/l lbs/d OUId7 38 0.16 1 mg/l 1bs/d

. reesos 5*'u'u' 43 0.18 1.7 0.0071 1.3 0.0054 1.2.3 mm/1 lbs/d

.a..=, 1 mg/l ibs/d 0.2 0.0008 VALUE VALUE VALUE a pg VALUt 500* 500* 500* *

'"UI M 'I MM WN e 1**0*'Su'* *C 1

'**" 18.2 VALUE VALUE NLUE VALUE ,C

,a""*'

fe.permwe NA 8.17 same 7. 6 03 1.3 PART B - Mark ' X"in column 2-aIor each pollutant you know or have reason to believeis present. Mark "X"in column 2-b for each pollutant you believe to be a 2-a foi any pollutant, you must provide the results of at least one analysis for that pollutant. Complete one table for each outf all.See the instructions for ad and Iequirements. 5. INT AKE toptional)

4. UNITS 2T ann r 3. EFFLUENT 1.PottUT. b MAXIMUM 30 SAv VAluf ,tnu =, t LONG TERM AVRG. VALUE senum i NO Of

LotG TERM AVERAGE VALUE D N0 of ANTAN0 3, /,y, a M ArtualM OA:LV VALUE at r=onefN.

== '""* _as. - un 0

,,, .. s, =, a, C

_as. a- _at. == _at. ui

. s.

(24%9 67 h y Im'IE.**m.m X l s can.e X

e rum Coh,or.

. r.n o6 " X 0.44 0.0018 1 mg/l Ibs/d' e

n.

u.ame

. s a, I FAGE S c.c ia,c I

Estimated Average Flow

m M M M % ,,

- CONTINUED FROM FRONT -

1. PDLLUT- 2. 50 ARK T 3. EFFLUENT 4. UNITS 5. CTAKE foptiorian '

A C SN 'abMe **

a MAIlmum sAILY VAtut e NAIIMUM 38 BAY VALUE waame, c. LONG IERM AVRG. VALUE wa.umes d. No. Of a CONefg. a LONG TERM AVERACE VALUE b h4 Of

Pf d'3d*8 $i s er esectlYeanes caecil% ares camerl% arms A "'**

Y$fs' inAll0E castilYastics N "'**

1 S' fff.*L

.n e, X n Od and

- X 3.6 0.015 1.2 0.0050 0.85 0.0035 1/ 2/3 ""

en

=/1 lbs/d

,.,4 ,o,s,1. ,. .

sim is o, X

,cu . ,

sie Alpna X

m s.ia Este es, na.w.

X een R.d.u.

I k SulIJf.

l"llis si X_ 180 0.751 1 mg/l lbs/d is

- s.

.s.,,,,.

If$hm X 42 4 0.008 1 mg/l lbs/d .

A sesfMfJets X

.o.

i$$

9 I 0.6 0.003 1 mg/l lbs/d qe iSU nm I e 0.1 4 0.0004 1 mg/1 lbs/d Iau'I'*

,u. . ., I ISa***

ase 4:

X S lies Iotal X 4.22 0.0176 1 mg/l 1bs/d ie s IS$** I 19.7 0.0821 1 mg/l lbs/d

. u. ion .

<N"n c n X y,rp.a.s.

annus X 0.11 0.00046 1 mg/l lbs/d

., v ram

X a 0.1 e0.0004 1 mg/l lbs/d l . s aan .

IesA

440 3? 6e y i cwe sost PAGE 7 a it so l

l >

M M M M M M M M M W W M M M M M

{i Form C PLEASE PRINT OR TYPE. Teu may report some er all el this laternallen se separate sheets TABLE I for 3.00 Item A & B

<ase tric same tormarnestead et completing thne pages.

SIE INSTRUCTIONS. ' ~

T' ~* ; M'77 OUTFALL NO

' ft;'~

. . .T I' ' ' ' C "'

_'"P..- 009

-e 'A' n* k.

INTAKE AND EFFLUENT CNARACTERISTICS (continued trom page 3 ciform 2 C) ;

. x

. . _. c. : . a . a - ~

WRI A - You must provide the results of at least one analysis for every pollutant m this table. Complete one table for each outfall Set mstructions for additional details.

3. UNITS fspecify sIblank) 4. INTAKE (optionals

2. EFFLUENT

I "O HE II I UI t NO Of

1. POLLUTANT a MAI! MUM OAILY Vuut k NAIIMUM 30 SAf VALUE wmmuam t LONG TERN AVRG. VALUE wmetam d NO OF a. c0p [u.

""'" m "*" Akursts t mass e,a gh,, m ean ANuvsts coalba ""'" cansk coalk tan. ion

.e -,

8,ga D'*"'a 10 0.08 1 rra/1 lbs/d s cu~s "J8f" *" 59 0.49 1 mg/1 lbs/d

,c,r , o.s.,

. roc

.c 30 0.25 1 mg/l Ibs/d e i u se 5d'*"'55> 12 0.10 1 mg/1 lbs/d

'"*""* mg/l lbs/d 18 0.15 1 VALUg VALUE VALUE

, g% VALUE 6000* NA NA gal /d VALUg VALUE VALUt VALUE

. e 18*ervahme

'"**" No Data Vuut VAtut

.,,,.,,,, vuut VAtut

,C a-aans NA numinum maxim measmuss manusum

,,,, STANDARD UNITS PART B - Mark ~X'in column 2-a for each pollutant you'know or have reason to believeis present. Mark X" in column 2-b for.each pollutant you believe1o be absent. If you mark column 2-a for any pollutant, you must provide the results of at least one analysis for that pollutant. Complete one table for each outfall.See the instructions for additional details and requirements.

4. UNITS 5. INTAKE (optionals TPOLLUT- 2. mass T 3. EFFLUENT t No 0F ANfA 0 *

,., g , ,, g, e. maximum SAiLV VALUE t. MAllMUN 30 SAY VALUE s.tma.uam c. LONG TERM AVAG. VALUE wm,uwe, d. NO. Of a CONCIN.

L Mass 6 LONG TERM AVERACl VALUE Cg N0 ""'" cualk. *"'" c alk. *"'" 'vjji in a g c,,n j ,, m man A,{fy r., a.a. ras 0 J'. c alk.

$IEUIm x n cm.

'd# 8""d '

,X 0.0 1 mg/1 lbs/d c Caine X

e c.sw..== g

. ei g

*""** I 0.13 0.0011 1 mg/l 1bs/d L"1." 7 I cwc iac PAGES

Maximina Estimated Flow - See Attachment F ** Before Neutralization I

M M 1 CONTINUES FROM FRONT W @W 'M M M MM W W WM M M M 'M 4,

1. POLL T- 2. M Amt T 3. EFFLUENT 5. ETAKE fophotrac

4. UNITS

$Iay 3n

<d a *wes K 3, a mammun satt vuut a mannum se ear vaut ,.um e tencitam aves. watut ,.

"""' ""'" tge of m ,. , e tonc iEam avtuct vatus of .'*

s%, s'ir cualkr co.albe ca.cilba vsti l'AIS' cueilb """' n.,m,o,i vst I,Yo*YIa.c

.4, 2 I

. ca 6"* 0.15 I 2.9 1 mg/l lbs/d

. en.s l9Ei I." X e,6 Alpna I.83 g oise, Ieta

.2 ca sas *

. ca 226 I.lM X

a swim.

IIIa!$hs. I 1590 79.6 1 mg/l lbs/d i sne X 4.7 0.23 1 mg/l lbs/d G Switate

!i1Ehm X 54.5 2.72 _

1 mg/l lbs/d

. $entMthats X

ila * "

8NS $ 5' X 0.3 0.018 1 mg/l Ibs/d fS u..I'" nm I fll~

use e a X IEa*

u= 4: 4.

I s a m imm I 0.11 0.00092 1 mg/1 lbs/d i caean ,

f.ta ac ss. x 0.2 0.002 1 me/1 lb s /d

. us,no.a EEs n X yyaaese uom se X 0.02 0.0002 1 mg/l Ibs/d

. v rue

"**3

I .e 0.1 40.0008 1 mg/l lbs/d i ' '"~~

v~ n X twc inst PAGE 7 j

s ca t

9

i 1

+ v

) FOR ACENCY USE ONLY APPLICATION NUMBER '

)

I E _

MO -

DATE RECEIVED i

i l

FORM D - APPLICATION FOR DISCHARCE PERMIT - PRIMARY INDUSTRIES DO NOT ATTEMPT TO COMPLETE THIS FORM BEFORE READING THE ACCOMPANYING INSTRUCTIONS MISSOURI DEPARTMENT OF NATURAL RESOURCES - DIVISION OF ENVIRONMENTAL QUALITY P. O. Box 1368 Jefferson City, Missouri 65102 1.00 NAME OF FACILITY Callaway Power Plant 1.10 This facility is now in operation under Missouri Operating Permit NumberMO-0098001 1 20 This is a new facility and was constructed under Missouri Construction Permit Number (Complete only if this facility does not have an operating 1

permit).

This form is to be filled out in addition to forms A & C " Application for Discharge Permit" for I the Primary Industries listed below -

INDUSTRY CATECORY I6 Adhesives and sealants Ore mining Aluminum forming Organic chemicals manufacturing Auto and other laundries Paint and ink formulation l

i I B2ttery manufacturing C:a1 mining C211 coating Pesticides Petroleum refining Pharmaceutical preparations I Capper forming Electric and electronic compounds Electoplating Photographic equipment and supplies Plastic & synthetic materials manufacturing Plastic, processing i Explosives manufacturing ,

Porcelain enameling Foundries Print *in*g and publishing

. Cum and wood chemicals Pulp and paperboard allis Inorganic chemicals manufacturing Rubber processing i

Iron and steel manufacturing Soap and detergent manufacturing Leather tanning and finishing Steam electric power plants Mechanical products manufacturing Textile allis Nonferrous metals manufacturing Timber products processing l

lI

! Page 1

I - .- . _.

M,h M MM M M M MM W M MM MM M' W M,

~

APPLICATION FDR DISCHARGE PERMIT Form D - Primary Industries H

NPDES # (11 Assigned) ouiratt auMsER MO-0098001 001 1.30 if you are a primary industry and this outfall contains process wastewater, refer to Table A in the instructions to detern;ne which of the GC/MS fractions you must tes column 2-a for all such GC/MS fractions that apply to your industry and for ALL toxic metals, cyanides, and totalpheno s. Mark "X"in column 2-b for each pollutant you know or have reason to believe is present. Mark *X"in column 2-c for each pollutant you believe to be absent. lf you mark either olumns 2 a or 2-b for any pollutant. you must provide the re suits of at least one analysis for that pollutant. Note that there are sey.:n pages to this part;please review each carefully. Complete one table (aft seven pages) for each outfa!!. Se instructions for additional details and reouisements. 5.lHTAKE (optional)

3. EFFLUENT 4. UNITS

l. POLLUTANT 2. M ARE T k MAllMUM 30 CAT VAtuf pr ute c.10NC TERM AVRG. VAtut v,r .a am t N0 Of a c0NCfs. tLONG TEAM AVERACE VALUE 4,N,0,. OF h,

E' SNs OEs a MAIIMUM BARY VALUE 8" aw coerMaree aus Af3-y mm LMU q,gy, ,s am y3g 3'

_ .4avadas/el See Es si.'s ceci&rion conceMarm 4

METALS CYAMIGE. AND TOTAL PHENSLS X .05 .03 1 mg/l lbs/d Fu Arsenic.Tets 8' " 3' "

X 4.01 4.007 1 mg/l' lbs/d w s.,s lbs/d

'"d"***'

X 4.001 4.0007 1 mg/1 4u c.c

'''''' X .009 .006 1 mg/l Iba/a 5

w cm.. m I 4.01 4.007 i i g/i Ibs/d su cap,. Tem

'me w a X .80 .53 1 ma/1 lbs/d ru tea. ran

*3S S'* I .01 .007 1 mg/l 1bs/d aM Mertwy, TetW X e.0004 4.0003 1 mg/1 lbs/d 9u leirket veld

' ' * * * "- X .4 .3 1 mg/l lbs/d iou se.ea

'ad in 2-e n X .02 .01 1 mg/l lbs/d I

ItM sdwer.iets v4en

X .06 .04 1 1 mg/l 1bs/d izu ina ina u+*:s e x .03 .02 1 mg/l lbs/d iY"*#Ee**# X z.1 4.07 1 mg/l lbs/d X 4.1 4.07 1 mg/l lbs/d Ya X 4.001 4.0007 1 mg/l lbs/d DIOXIN .

OEscalSE RE5utit ge iew n o .oisasie X CONTINUE CN REVERSE g.c in PAGE 2

M N M M Y M Y M Y M & M Y' . O Y /S & O Y CONTINUED FR0RI THE FRONT

3. EFFLUENT 4. UNITS 5. INTAKE (opteona/J 1.POLLUT ANT 2.staaK T k 6 Of hh ta awwes

EE'

,A. Er

/ Es &Ee sMr a MAIIMUM OA1Y VALUf c cdkre. S "*"

k M AXIMUM 30 DAY VALUE as m c t04GTERM AVRC VALUE g m cac# ne. ""'" ca.cilkre.

tg,g riti 8F a CONCrg.

nArea a mass a LONGTERM AVERAGE VALUE eigggg. m .au Vui GC/MS FRACTION - VOLATILE COMPOUNDS tv urem.

X 47.5 4.0050 1 ug/l 1bs/d 2v u,,

'*"3" X 45.2 4.0034 1 ug/l lbs/d av om.=

" 2 44.4 4.0029 1 ug/l lbs/d

,0fii.e.

se as u X 45.8 4 .0038 1 un/1 lbs/d sv s, .

X 44.7 4.0031 'l ug/l lbs/d sv c,no.

$5"w** X 42.8 4.0019 1 ug/l lbs/d 2V Chloectpeareae I 46.0 4.0040 1 ug/l Ibs/d a c==.*

E2?.*ii X e 3.1 4. 0021 1 un[1 lbs/d 9v Caseroethans

" 2' X 48.2 4.0054 1 ug/1 lbs/d lov 2 CPt.re E"ilIN "" X 42.6 4.0017 1 ug/l lbs/d uv ca.. .

I e 1.6 4.0011 1 ua/1 lbs/d L*OL irs 2r+ x e 2.2 4.0015 1 un/1 lbs/d ersY X e. 5.0 e. 0033 1 ug/l 1bs/d in i s oo .

- - "i"3' x 44.7 4.0031 1 ug/l Ibs/d isv 5 2 no .

""*""" X 4 2.8 L.0019 1 un/1 lbs/d 16v 110@l.t&

"'"' X e- 2.8 e .0019 1 un/1 lbs/d 1N 12 Datwese

",a"*u" oo'x 's.'.".- 46.0 e. 0040 1 un/1 lbs/d E6I X e.4.0 e .0026 1 ua/1 lbs/d 19v Em,ii=nieae I e. 7.2 e. 00_48 1 ua/1 lbs/d

""',i xv uem '

'*"" 1 ug/l Ibs/d X 41.2 A.00079 2iv

' ' " wemp3' y e. 1, o e .00066 1 ug/l Ibs/d PAGE 3 CONTINUE ON PAGE 4 cucrea

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These valu-a cr2 fcr the diccsived 4 form cf tha metal co rcgulcted 12 APPLICATION F3R DISCHARGE PERMIT our current permit.

Forst D - Primary Industries TABLE H ,,,,,t,,,,,,

NPDES s (11 Assigned)

MO-0098001 002 1.30 !! you are a primary industry and this outfall contains process wastewater, refer to Table A in the instructions to determine which of the GC/MS fractio column 2-a for all such GC/MS fractions that apply to your industry and for ALL toxic metals. cyanides, and totalphenots. Mark "X" in column 2-b for each pollutarit reason to believe is present Mark"X"in column 2 c for each po!!utant you believe to be absent. lf you mark either columns 2-a or 2-b for any po!!utant, you must pr suits of at least one analysis for that pollutant. Note that there are seven pages to this part;please review each carefu!!y. Complete one table (allseven pages) for eac ,

instructions for additional details and recuirements. 5. INTAKE (optionar)

3. Ef f LUENT 4. UN115 l.PetLUTANT 2. BIAeK T atoms riam avtaact vnut a no or i a manmum ao sav vaut r ue. c temsitam avas vuut w a a no or a cancts.

$$ ah AL a manmum naar vuut

" ** "" 9.ir? ** #N

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_ y =' acte *b""A . f v_ c cib ,

teETALS, CYAmioE. AND TOTAL PNENGLS

" ""5 ca.alkrra. ca.cilkvic.

~ 0$?? Ele I

".f'7 '"" x OmT.Me in x 0$lsNu 1 j"j%"IIs x 4.01 A .6 1 mg/l 1bs/d

.= c . v.m maa I .41 25 0.41* 20

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l/1/3 ag/l Ibs/d m n a su ,

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-212s- etscast afscLis

-- o .. . I CONTINUE ON REVERSE PAGE 2 cac sea

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S O & S S S S S S S S S S S S & &=O CONTINUED FROM THE FRONT 2.asARN T 3. EFFL UEllT 4. UNITS 5. INTAKE toptiona/J I. POLLUTANT AI

g,5, 45, k N AllMUM 30 DAY VALUE S me,taam c.LONG TERM AVRG.VALUE #dwmess, d.h6 0F k.MA$$ aLONG TiltM Ar[AACE WAtut k OF gg

188 a MAI! MUM OAILY VALUE gtCEN-MN m us ,,,cdy,,,,, mms aggaga sra ms y3gh' (J avadaale) "5' Est air cancd7unse l 88 " 8 cseciUnanos A,jjg-GC/MS FRACTION - BASE /NEUskAL COMPOUNDS (contmuedJ 4:s u m.we Tnt'~ X 4as Phenannwone 145 01 8) g Sb"' r a68 8 2 4 - Ire-ctWarebensene 1120 62-1) X GC/MS FRACTION - PESTICIDES IP Alee 462 g 2P enc OnMW g

3P 3 8nC 43t985 4 g 4P T BHC (2 89 9p X

SP Sanc (319 # #

y GP CNordane (SN49 FP 4 t@Di saa X aP 4 s 00E 472 55 96 y

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,'Eif. X seP nessacmar so44 si g

esc as CONTINUE ON PAGE 8 PAGE 7

1 I

s.

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I .

E E E E E W M M M M M g g g APPLICATION FOR DISCHARGE PERMIT Forni 0 - Primary ladustries

Clarifier Blowdown Supernatent-TABLE N llPDES # (I/ Assigne1) outrALLaumets

See Attachment F HO-0098001 003 1.30 if you are a primary industry and this outf all contains process wastew ater. refer to Table A in the instructions t coiunm?-a for all such GC/MS fractions that apply to your industry and for ALL toxic metals. cyanides, and total phenols reason to believe s present. Mark X"in column 2-c for each po!!utant you believe C to lt be absent. if you mark rater columns 2

. suits of at least one analysis for that pollutant. Note that there areseven pages to this part;please review each carefully. omp e e one a instructions for adstional details and requirements. 4. UNITS 5 INTAKE (ogtsona4

3. EFFLUENT b NO Of

l. POLLUTANT a. Mane T a 54 0F alonC TERM AVIRAct vatU(

s cShers. " 'rn AND CAS

<UO'E .di e e

gwg.

3, e

g,$g if*., c a 5U1505 84E7 VRUE

,L. 'a =

& MAIt#UM 33 5AY VEM we ma= t 1958 ftBN Avat VEUE w mmee c aN., ** ca& ~ 'n '"'*" "la'?P*

a "5 ISETALS.CTANISE. AND TOTAL PNEIBOLS w.----. 1 mg/l lbs/d 4 .01 1

*d**** X A .01 4 .03 m an= tem 1 mg/l lbs/d 4. 01 1

"** m a X 4 .01 .* . 03 lbs/d 4.001

~

m e , man. 1 mg/l 1

'dd i'** "D x .'.001 4 .003

.= ca . 1 mg/l lbs/d 4.001 i

- d**** X .009 .02 su ca.. 1 mg/l Ibs/d 4 .01 1

'*d"***'* X 4.01 4 .03

- us c.,,.. tes 1 mg/l lbs/d 4.01 1 5" S e X .01 .03 M toad. Total 4 .03 1 mg/l lbs/d 4 .01 1 l'* *' m X 4.01 w unc.,.ims 1 mg/l lbs/d L .0004 1

"* X 4.0004 4.001 m h.am.ses 1 mg/l Ibs/d L.1 i

' " ' * * *- X .1 .3 wu se 4 .03 1 ns/1 lbs/d 4.01 1

'*d in'2*3 X 4.01 11u sdver. vote 1 mg/l lbs/d 4.01 1

- - u

X -'.01 4 .03 4 .03 1 mg/l lbs/d 4 .01 1

<me'E*%* x L,gt 1 mg/l Ibs/d Z.1 1 0"e'eE*'*# X C.1 4.3 l ems"I/s*

1 mg/l lbs/d 4.1 1 X .1 .3 isu en 1 mg/l lbs/d 4.001 1

'*d X -C.001 4 .003 880EIN N5cm0E Mt 1Ts

2gg;,,

0... nmeei e X CONTINUE ON REVERSE PAGE 2

CWC 158

E E E E E E E E E E E E E E E E O E, E O

CONTINUED FROM TNE FRONT

4. UNIT 5 5.181TAKE fophorta0

l. POLLUTANT 2. as ANK T 3. Eff LUENT a NO. Of tLONGTERM AWIRAf,E Vault k Of

& WAllMUM OAfLT VALUE k ld AIlMUM 30 SAY V ALUE ed ===am eLONS TERM AVAt VALUf tarwa.una a CONCEO.

h0M

E$' OE8 AE8 ItA N kNW sig,g a mass ,gg g' a mass ,,,,, gy,,,,, m mass ,,,,, jy,,,, m mass 8,73-fsi antat>!rs pita $"l: s$r cancilhares sc/Ms rRacn0N - VOLATILE COMPQUNOS IV Atrolem I X 47.5 4.021 1 ug/l lbs/d 4 7.5 1 2V Aceytonetssie imi n " X 45.2 4 .014 1 ua/1 lbs/d 4 5.2 1 av seir=

d ' "

X 44.4 4 .012 1 ug/l lbs/d 44.4 1 av e.ucm,

@"Ciy"" X 45.8 4 .016 1 ug/l lbs/d 4 5.8 1 SW 9,onicism vsrsa X 44.7 4 .013 'l ug/l lbs/d L 4.7 1 w c.t iE'r*27* X 42.8 4 .0077 1 un/1 lbs/d 42.8 ~1

(

IV ChieteDentreeg "oa m is X 46.0 4.017 ,

I un/1 lbs/d 46.0 i a cuven,-

,70U,*" X 43.1 4 .0085 1 ug/l lbs/d c 3.1 1 w cuo..ch-us asi X A8.2 A .023 1 ug/l lbs/d 48.2 1 inv r ca .-

U"J'Ifl,"** X 42.6 4 .0072 1 ug/l Ibs/d 42.6 1 11V chlorokpaie

'5' 6a s' X cl.6 4 .0044 1 'ug/l lbs/d 41.6 1 12v 04me- ~

NET"'" X 42.2 4 .0061 1 ug/l Ibs/d 42.2 1 UV 0 riore

'RE T,'*'"" X 45.0 L.014 1 ua/1 lbs/d 45.0 1 uv n o.wo..

maa v$ n X 44.7 c.013 1 ug/l lbs/d A 4.7 1 E4E#EoYEE i X 42.8 A.0077 1 ug/l lbs/d 42.8 1 SW I t D.<h

"v'a vm X 42.8 4.0077 1 ug/l lbs/d 42.8 1 ITV 12 0<hlou r*= vw s' X 46.0 4.017 1 ug/l lbs/d c 6.0 1 isv i r o.~o-fs'!!'IJ X 44.0 L.011 1 ug/l Ibs/d A4.0 1 m Em,io,*~

iia si e X A7.2 L.020 1 ug/l lbs/d 47.2 1 2av une...

X L1.2 A .0033 1 ug/l Ibs/d 41.2 1

?IV Meshyl

v * X 41.0 4 .0028 1 ug/l lbs/d 41.0 1 PAGE 3 CONTINUE ON PAGE 4 cuc$ ass

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APPLICATION FOR DISCHARGE PERMIT Form D - Primary Industries

'I cutFALLsomets

Clarifier Blowdown llPDES # (11 Assigned) ,

See Attachment F MO-0098001 003 1.30 If you are a primary industry and this outfall contains process wastewater. refer totable A in the instructions to determi column 2-a for all such GC/MS fractions that apply to your industry and for ALL toxic metals. cyanides, and totalphenols. Mark "X reason to believe is present. Mark *X"in column 2-c for each pollutant you believe to be absent.lf you mark either columns 2-a or 2-b

sults of at least one analysis for that pollutant. Note that there are seven pages to this part;please review each carefully. Complete instructions for additional details and requirements. 4. UNITS 5. INTAKE (ognat) 2.neans R* 3. EfflufNT h NO 0F I. POLLUTANT i NO. OF aCONCIN.

tLONG !!RM AVERAGE VALU(

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la mass ,,,,, jg,,,, A,jpg-33 """

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E E E E E E E E E g g g g CONTINUED FROM THE FRONT 5. lNTAKE (optional)

3. Eff LUENT 4. UNITS

3. POLLUT ANY 2. MARK T Of I

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GC/MS FRACTION - VOLATILE COMPOUNDS 2.-

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. nr . Towa. SE8CMOE NTS

'Na$i o 48 CONTINUE ON REVERSE PAGE 2

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M M M M M M ,M CONTINUED FROM THE FRONT

4. UNITS 5. HIT AKE (optional)

1. POLLUTANT 2. MARK T 3. Ef f tUEi1T a.L0gGifRM AVEGAGE VALUE k BG. 8F k M AIIMUM 30 BAT VALUE e.t mamm, cLONGTERM AVAB VALUE farmsawes & NO. Of hf$

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2. ManK T 3. EFFLUENT 4. UNITS 5. INTAKE toptiona0

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g..q~y.-q m g-g g y g~ ~g g g g y y q q APPLICATION FOR DISCH ARGE PERMIT Form D - Primary industries ouirAtt uUmsEs IIPDES f (II Assigned)

Mo-0098001 005 1.30 if you are a primary industry and this out!all contains process wastewater, refer to Table A inh the instru column 2-a for all such GC/MS fractions that apply to your industry and for ALL toxic metals. cyanides,and id the tetotalphen reason to believe is present Mark 'X'in column 2-c for each pollutant you believe to instructions for additional details and requirements. 4. UNITS 5.lNTAKE (optional)

3. EFFLUENT a10NS TIRM AVfRAcf VALU[

t NO Of 1.P0tlUTANT 2.asanat T t 50. OF & c0NC(q.

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'oD5isdiI I CONTINUE ON REVERSE

CONTINUES FROM TME FRONT

4. UNITS 5. HIT AR E (optional)

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APPLICATION FOR DISCHARGE PERMIT Form D - Primary Industries OttTFKL EUn8th NPDES E (11 Assigned)

MO-0098001 008 1.30 11 you are a primary industry and this out!all contains process wastewater refer tot able A in the instructions to deter entumn2-alor all such GC/MS fractions that apply to your industry and for ALL toxic metals. cyanides.and totalphenols. Mark "X reason to believe is present. Mark"X"in column 2-c for each pollutant you believe to be absent. lf you mark either columns 2-a o suits of at least one analysis for that pollutant. Note that there are seven pages to this part.please review each carefully. Comple instructions for additional details and requirements. 4. UNITS 5. INTAKE (oprianal)

3. EFFLUENT b NO 0F

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g a is aev ool'eiami issied m item i 30 a sebstaece or a comaomeet of a subsiaece aica vou do or aeci taat vee iii ove, iae ee i s vears ese or manufacture as an intermedia!e or final product or byproduct?

,K 1ES II:st all such po!!utants belowl l I NG tra la Bt The following substances are used in our chemical laboratories and might be present in I trace quantities in our discharges (see attachment E); Antimony, Chromium, Copper, Lead, Mercury, Nickel, Phenols and Silver.

l l

I The following solvents are used on the plant site but are not believed present in our discharges; Trichloroethane, Trichloroethene, Tetrachloroethene, Toluemt, and Methylene Chloride.

I B Are your operations such that your raw matetials. processes or products can reasonably be enpected lo vary so tSat your discharges ol pollutants may during the next 5 years exceed two times the manimum values reported m item 1301 51ES tcomplete C belowl a NO Igo to Section 3001 C If you anseered "Yes" to item B explain below and describe in detail the sources ar'd expected levels of such po'lutants which you anticipate w ll be dis-charged from each outfall over the next $ years. to the best of your ability at this time Continue on additional sheets if you need more space Waste streams can be expected to exhibit variability as the result of varying i

g influent water quality. Variability in intake water quality due to the effects of g rainfall, runoff and upstream pollutant discharges might cause the discharge value on a gross basis to exceed two times the maximum values reported in Item 1.30.

I I

I Were any of the analyses reported in 130 performed by a contract laboratory or consulting firm?

x its tirst the name. address. and telephone number of and a N0 Igo to 4 00) analyled by each $Uch laboratory of him below) i Controls For A matet P.O. Box 5351 S.A00RISS Santa Fe, N.M. 87502 C. itLIPuent wee r-v a ae .

800-545-2188 O Pettut4Nr8 ANattit0 'm See Environmental' Pollution Attachment F I

I I

I I -

I certoly under penalty of law that I have personally examined and am famshar with the Informahon submittedin this apphcation and all attachments and that bas ed on my onquity ol those lndividuals immediately tesponsoble for obtaining the informa tion Ibeheve lhat the rn.

I formation as true. accurate and complete I am aware that there are signohtant penallres for submitting false onformat10n encluding the

> possabahty of hne and Imprisonment B. PHONE NO. om <mre 4 em e A. NAME & OHICIAL TITLE stwr sie inners

! D. F. Schnell, Vice President-Nuclear (314) 554-2650

0. DATE SIGNED

, C. SIGNATURE (L/M / &Nw g,'$ PAGE 9

NPDES Parmit #MO-0098001 I I Attachment A I Description of Outfalls dO1) Radwaste Treatment System.

This system serves to collect, process, store, recycle and dispose I of liquid radioactive waste generated at Callaway. Five general sub-systems can be defined as described below.

The Baron Recycle System receives reactor coolant for the purpose I of recovering the boric acid for reuse in the plant. Boric acid is used as a neutroa absorber / moderator in the primary loop.

I The Liquid Radwaste System collects and processes floor and equip-ment drains from the containment, auxiliary building, fuel build-ing and radwaste buildings.

The Laundry and Hot Shower system treats waste generated f rom washing radioactively contaminated protective gear and clothing and personnel decontamination shower wastewater.

The Secondary Liquid k'aste system is used to process condensate demineralizer regeneration wastes and potentially radioactive I liquid waste collected from the turbine building. The condensate demineralizer regeneration waste is divided into two wastestreams; High TDS waste from the acid and caustic rinses used when chemi-cally regenerating spent resin, and low TDS waste which results I

from the initial backflushing of unregenerated resin and the final rinsing of the regenerated resin to remove acid and caustic.

I Steam Generator Blowdown is normally demineralized and recycled to the main condenser for reuse in the secondary cycle. Provisions also exist to discharge the treated blowdown via 001.

It should be noted that the radwaste treatment system is specifi-cally designed for flexibility to achieve Nuclear Regulatory Com-mission (NRC) limitations. Actual treatment for any given batch of wastewater is dictated by the following criteria.

1) The level of radiological contamination and the corresponding NRC mandated discharge criteria.

2) The NPDES permit discharge limitations.

I 3) The most offective waste treatment scheme that will give the smallest volume of solid radwaste.

I ENVattachA 02/04/85 - dls 5

I .

N

I' I

! 4) Overall wastestream management--processing and holdup rates, volumes of other wastestreams requiring treatment or storage, I etc.

5) The need, feasibility and economics of the recycle versus dis-I charge options.

The following wastewater treatment systems are used as required to treat this wastestream for recycle or discharge in compliance with I NRC requirements and are also available as auxiliary or backup treatment systems to treat this discharge for compliance with NPDES permit limitations: Evaporation and/or Mixing and/or Fil-I tration and/or Carbon Adsorption and/or Ion Exchange and/or Neu-tralization and/or Reuse / Recycle of Treated Effluent.

002) Cooling Tower Blowdown A cooling tower is utilized to dissipate excess heat to the at-mosphere from the Circulating and Service Water Systems. Outfall I 002 is designated as the cooling tower blowdown discharge. Blew-down from the cooling tower is necessary to maintain dissolved solids concentration in the recirculating water within acceptable operating limits.

003) Water Treatment Plant Blowdown The water treatment plant supplies clarified river water for cool-ing tower makeup and various other plant water systems. The suspended material which is removed from the river vater is with-I drawn from the bottom of the clarifiers as sludge. This wastestream, the water treatment plant blowdown, is designated as Outfall 003. The existing permit limitations are restrictive to I the extent that direct discharge is not possible. Current prac-tice at the plant is to route clarifier sludge to a sedimentation lagoon with the supernatent recycled to the head of the water treatment plant. Filter backwash from the sand and carbon filters I in the plants domineralized water system is also a component of this outfall. Refer to attachment B for details concerning other potential discharge mechanisms.

004) Demineralizer System Wastes The demineralized water system (DWS) is used to produce the high I quality makeup water required by some plant processes. A well on the plant site is used as the water source for the DWS, Outfall 004 consists of wamtes generated frem resin regeneration and miscellaneous wastes from floor drainage and wet well overflows.

These waste streams will be routed to a sedimentation pond prior to discharge.

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I I 005) Oil Separator Discharge The discharge from Outfall 005 emanates from the Oily Wastewater Separator System (OWSS), which receives, treats and discharges nonradioactive, potentially oily wastewater from nonradioactive I areas of the power block and fire pumphouse. The wastewater will consist of monitoring effluent, washdowns, equipment leakage and maintenance drainage. In the event of a fire in the power block, I firefighting runoff will be discharged to the OWSS.

006) Circulating and Service Water Pumphouse Oil Separator and Neu-tralization Semp Outfall 006 has been eliminated and deleted from the permit by a modification dated June 23, 1981.

I 007) Sanitary Treatment Plant Outfall #007 is defined as the sanitary wastewater treatment sys-I tem discharge. The existing system consists of two 25,000 gallon aerated surge tanks, two 20,000 gallon per day extended aeration treatment units and a 7,500 gallon sludge holding tank. The STP I sludge is currently trucked to the city of Columbia treatment plant for further treatment, and disposal.

008) Chemical Water Treatment Unit Wastewater in Outfall 008 originates in the Cooling Water Chemical Control System (CWCCS) building, and results from water softener I operation for support of sodium hypochlorite generation. Sodium hypochlorite is used as a biocide in the Circulating and Service Water Systems.

009) Intake Heater Blowdown g Outfall 009 was redefined by permit modification dated g December 13, 1983. The river intake structure contains two recir-culating electric heaters which are used to prevent ice formation on the intake bar screens during the winter months. Discharges I occur during the infrequent blowdown or annual / biannual drainage of these boilers.

lI Note that outfalls 001 through 008 all discharge into a combined dis-I charge pipeline which terminates at the Missouri River adjacent to the I ENVattachA 01/31/85 - mha I

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' t plant intake structure. The attached table lists the legal description of each outfall location.

1 Legal Description - Outfalls Outfall 1/4 1/4 Sec T R 001 NE NE 14 46N 8W jlW 002 hV hV 13 46N 8W

003 SW NW 13 46N 8W 004 SE SW 13 46N 8W 4

3 46N

g 005 SW hV 13 8W 007 NE SE 14 46N 8W 008 NE NE 14 46N 8W 009 hV hv 5 45N 7W I

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NPDES Parnit #MO-0098001 I Attachment B Clarifier Blowdown Discharge Options I (Outfall 003)

I As the DNR is aware, in May of 1980, Union Electric Company (UE) requested a " fundamentally different factors" (FDF) variance to allow it to return clarifier blowdown and filter backwash discharges from the water treatment plant directly to the Missouri River through the com-I bined discharge line. Because of some initial confusion at the U.S. En-vironmental Protection Agency (EPA) Region VII, no decision was reached prior to issuance of the present NPDES permit on August 8, 1980. Ac-cordingly, the present permit imposes limitations on TSS that preclude I return of clarifier blowdown to the river. It was contemplated at that time, however, that the permit would be modified to incorporate the FDF variance, when granted.

Throughout extended consideration of the FDF variance by EPA, both the Missouri DNR and EPA Region VII have recommended approval of the I variance. In a February 9, 1983 letter to Dr. Allan S. Abramson, EPA Region VII, Mr. Hentges transmitted the NPDES permit conditions that DNR would implement for Outfall 003 when the variance is finally granted.

EPA Headquarters personnel have raised qt.estions about the " existing I source" status of the Callaway Plant that requires EPA access to equip-ment vendor contracts claimed by the vendors as confidential and pro-prietary information. Due to the long delays in securing vendor ap-proval for release of the contract provisions to EPA, which was only I recently granted, there is still no final approval of the FDF variance.

UE is hopeful, however, of obtaining approval of the FDF variance prior to issuance of the renewal NPDES permit. UE therefore requests incor-I poration into the renewal NPDES permit of the Outfall 003 conditions stated in Mr. Hentges' February 9, 1983 letter.

In the absence of an FDF variance or other relief, UE is presently rou-ting clarifier blowdown to a settling pond for removal of TSS. Superna-tent from the pond is drawn off under normal operations and recycled to I the head of the water treatment plant. The removed TSS is retained in the settling pond. However, it may not always be possible to recycle some or all of the supernatent from the settling ponds. For this reason, UE requests retention of the designation for Outfall 003 in the I present permit and authorization to discharge supernatent including clarifier blowdown and filter backwash water, from the settlinE Ponds.

I In the event that no FDF variance is granted prior to reissuance of the NPDES permit, UE further requests that limitations for Outfall 003 be established on the basis of best engineering judgment (BEJ). Currently applicable federal EPA regulations at 40 C.F.R. Part 423 (1983) specify I "best available technology" (BAT) for designated priority pollutants and non-conventional pollutants, but set no effluent limitations for conventional pollutants for renewal permits issued under BAT rules. In-ENVattachB f

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I stead, 40 C.F.R. & 423.14 (1983) reserves the "best conventional technology" (BCT) effluent limitations for later adoption and implementation. Since TSS and oil and grease (0&G), are bot.. conven-I tional pollutants, 40 C.F.R. & 401.16 (1983), the DNR has discretion to set BEJ limits for these pollutants in the reissued NPDES permit. In light of the fact that all regulatory authorities involved in the FDF variance proceedings have agreed that the most desirable and feasible I treatment of Outfall 003 discharges at Callaway Plant is return of the suspended solids to the river, UE requests BEJ limits equivalent to those stated in Mr. Hentges' February 9, 1983 letter. Such limits would also be consistent with the Dht's practice for other water treatment I plants throughout the state.

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NPDES Parnit IMO-0098001 I Attachment C Description of Intermittent Flows Six of the eight outfalls defined in this application can be con-sidered to include intermittent discharges since they process and/or release wastewater in discrete batches. Each is described below.

001 - Radwaste Treatment - All of the subsystems described in Attachment A, except steam generator blowdown, process or release discrete batches of wastewater. The frequency and magnitude of each is F(ghly variable.

I However, discharge flow rates are relatively constant. Existing equip-ment produces discharge flows of approximately 100 gpm. New tanks cur-rently under construction will be capable of discharging at approxi-mately 200 gpm.

During recovery from major plant outages and other unusual transient conditions, it may be necessary to discharge steam generator blowdown.

The discharge flow rate varies up to 360 gpm, resulting in a maximum I daily discharge flow of up to 518,400 gallons. As this discharge is an-ticipated very infrequently, the steam generator blowdown flow was not included in the maximum flows shown in Form C, Item 2.40. Steam genera-I tor blowdown is typically treated by demineralization. Test data from a semple taken in December, 1984 (during recycle) represents the typical blowdown water quality:

- Form C Table A Parmaters -

I BOD COD 9 ag/l 10.7 mg/l I TOC Ammonia 13 mg/l

<0.1 mg/l

- Form C Table B Parameters (measurable)

I Oil and Grease Sulfate 0.25 mg/l 2 mg/l Iron 0.03 mg/l All other parameters tested (the same as those identified for outfall 001) were below the method limit of detection.

I This includes all 13 toxic metals, cyanide, phenol, and the GC/MS volatiles and Acid Extractable fractions.

I 003 - Clarifier Blowdown - The clarifier blowdown effluent flume is con-tinuously flushed (approx 200 gpm) with raw river water to prevent solids blockage. Powever actual clarifier blowdown is intermittent.

Blowdown rate is relatively constant, but duration and frequency can vary depending on river suspended solids concentration and plant water I demands. The DWS sand and carbon filter backwashes are also intermit-tent based on the variation in treated water demands. Currently the sand filters are not in use, because well water is being used as the rav ENVattachC 01/31/85 - sha I

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I water source. The carbon filters are currently backflushed once per week, generating 6,000 gallons from each of two filter beds.

004 - Demineralized Water System - Effluent from this process is col-lected in a neutralization tank for pH adjustment, before being batch I released to a lagoon for further sedimentation treatment. An existing clarifier sludge pond has recently been modified for this purpose. Use of the lagoon vill moderate the discharge of tiiese batch releases.

005 - Oily Waste Separator System - This treatment unit operates in a intermittent mode, at a fixed rate of 100 gpm. The frequency of opera-tion is highly variable based on influent flows from many diverse I locations.

008 - Circulating Water Chemical Control System - The only routine dis-8 charge from this system is from the regeneration of a water softener.

It is an intermittent release with a total volume of approximately 500 gallons.

009 - Intake Heater Blowdown - Discharges from this outfall are seasonal and intemittent. During winter operational periods, it is estimated I that blowdown will occur approximately once per week (less than 100 gallons). Anticipated annual drainage is approximately 6,000 gallons.

The flow values shown in Form C, Items 2.40 A and B reflect our I current estimates of the normal, routine discharge frequency and volumes for these outfalls.

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W NPDES Parmit #M0-0098001 I Attachment D Other Discharges I. Separately Regulated Discharges Storm water runoff (SWR) discharges from the Callaway Plant I site are currently authorized under a separate permit. NPDES Per-mit #MO-0091537 defines seven outfalls which correspond to individual settling ponds built to control runoff from the con-struction site. This permit expires January 15, 1986.

Recently, federal regulations substantially altered the clas-sification and permit requirements applicable to SWR discharges (see the Federal Register of September 26, 1984, revisions to 40 8 CFR Part 122).

As a result of these new regulations we intend to update and resolve the issue of stormwater runoff from Callaway Plant in I separate correspondence with the Department of Natural Resources (DNR).

II. Other Discharges I A. Intake Structure Stilling Basin.- In a modification of this permit, dated December 13, 1983, the DNR redesignated Outfall 009, to apply to the intake structure electric heaters only.

The basis of the change was the acknowledgment that the other I discharges from the intake were not contaminated with process materials or wastes. We believe that this evaluation is still appropriate and request no change concerning the intake.

B. Cooling Tower Bypass - As previously identified, there is a bypass valve between the cooling tower clarified water makeup line and the cooling tower blowdown line. This bypass supplies i

I treated water to meet NRC dilution requirements for discharges from the radwaste treatment system when cooling tower blowdown by itself is insufficient to meet the dilution requirements.

I Dilution flow through the Bypass may vary from 0-10,000 gpm based on cooling tower blowdown flow and NRC limits.

i g As this discharge is the return of (clarified) river water back to river, it 18 our opinion that it does not meet the criteria 5 necessary for permitting as an NPDES outfall.

I Note that the startup and maintenance of our three clarifiers sometimes requires that we discharge treated or partially treated water. The Cooling Tower Bypass valve, or other perma-nent or temporary drainage connections may be used intermittan-I tly to release this off-specification (greater than 15 mg/l total suspended solids) river water. Since the quality of this water will be equivalent to our better than river water, we view such releases to be equivalent to those above.

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Fire Protection Drain Test Connections - In accordance with the I C.

National Fire Protection Association's (NFPA) Standard, fire protection drain connections are tested on a quarterly basis.

The test consists of opening valves and monitoring the water I delivery rates. Approximately 40 such connections are located throughout the plant. A number of these cannot be discharged into the areas in which they are loacted as it would create a nuisance or hazard to the local equipment or personnel. There-I fore, temporary or permanent pipes or hoses are used to divert this water outside various buildings into adjacent grounds.

The water source is two fire protection tanks containing only filtered groundwater from the demineralized water system. In addition, maintenance requirements for these tanks require draining and refilling approximately once every five years.

Each of these tanks has a capacity of 300,000 gallons.

D. Demineralized Water Storage Tank - On infrequent occasions, these tanks may become contaminated with low levels of silica from the makeup demineralizers. If this occurs, this water I cannot be used as makeup to the plant and, therefore, must be directed to waste. The tank is drained to the stormwater I runoff system at a rate of approximately 50-100 gpm. The total volume is 50,000 gallons per tank (two 1.otal). Overall water quality is high, with typical TSS of < 1 mg/l and pH in the range of 6 to 8.

E. Ultimate Heat Sink (UHS) Pond - Callaway Plant has a single water retention pond which serves as the ultimate heat sink I (UHS) for the Essential Service Water System (ESWS). The ESWS provides water for cooling of safety related equipment and is utilized in the event the Service Water System becomes inoperable. When the ESWS is operating, water is pumped from I the UHS pond through power block equipment, a mechanical draft cooling tower, and back to the pond. The UHS pond has a spill-way which is connected to the plant stormwater runoff system.

I Hakeup water for the UHS pond is supplied by the treated water plant and is added when the pond level drops below a 2 foot freeboard as measured from the UBS spillway. Makeup water to I the pond ceases once an 18 inch freeboard level is reached.

There is a high water level alarm on the pond which is set at a 12 inch freeboard. In the event water levels were to increase in the pond, levels would be reduced by pumping water frcm the I pond to the cooling tower basin through the ESWS. We do not anticipate any releases from the UHS pond.

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NPDES Parmit #M0-0098001 I Attachment E Chemical Usage The various chemical compounds that may occur in the discharges from Callaway Plant during normal operation fall into three usage categories.

Bulk Usage This group of compounds describes chemicals which are added I directly to specific water systems for tresttment at some regular rate or interval. Table 1 lists these chemicals along with their predominant function and potential discharge points.

8 Laboratory Reagents This category consists of a group of compounds stored and used in I the plants four on site laboratories. The predominant characte-ristic of this group is the relatively low usage which would result in negligable levels in the effluent. Laboratory reagents may be I discharged through the radwaste treatment Outfall 001, and sanitary wastewater Outfall 007. At the request of the Department, Union Electric will provide an inventory of these chemical compounds.

I Other Chemical Compounds This grouping includes other chemical compounds which may be dis-I charged and are not included in the previous lists. An example of a compound in this group is hydrochloric acid, which is used to clean the hypochlorite generation cells periodically. This should I result in less than 1,000 gallons / year. General housekeeping and maintenance chemicals, and erosion / corrosion products or byproducts from the PlantsHowever,theFormCandDanalytIc$[enotidi1hdu-infrastructure or fuel materials datasEou I ally assessed. ,

reflect contributions from these sources.

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I Table 1 Bulk Chemical Usage - Callaway

1) Ammonium hydroxide - used for pH control in recirculating water I 2) systems; Outfalls 001, 005 and 009 Aquazine - an algae control chemical used seasonally in the clari-fier blowdown and demineralized water system treatment lagoons.

3) Boric acid - used as a neutron moderator to provide reactivity con-trol Outfall 001.

4) Dispersants - (organic polymers principally phosphate based) used to reduce solids deposition in the circulating and service (cooling tower) water systems; Outfall 002.

5) Hydrazine - used for dissolved oxygen control in recirculating water systems; Outfalls 001, 005 and 009.

6) Lithium hydroxide - used for pH control in the primary loop; Out-fall 001.

7) Nitrite / borate products (solutions) - used as corrosion inhibitors in recirculating water systems; Outfall 005.

8) Polyelectrolytes - used as a coagulant in the water treatment plant; Outfall 003.

9) Sodium chloride (rock salt) - used to produce sodium hypochlorite I on site; Outfall 008.

10) Sodium hydroxide - used for regenerating demineralizer resins and I for pH control in various wastewater systems; Outfalls 001, 002, 004 and 009.

I 11) Sodium hypochlorite - used as a biocide in the circulating, service and potable water systems; Outfall 002.

12) Sodium molybdate - used as a corrosion inhibitor in recirculating I water systems; Outfall 001 and 005.

13) Sodium sulfite - used as an oxygen scavenger and for conductivity control in the intake structure heaters; Outfall 009.

14) Sodium tolytriazole - used as a copper corrosion inhibitor; Out-falls 001, 002 and 005.

15) Sulfuric acid - used for regenerating demineralizer resins and for pH control in varioas water and wastewater systems; Outfalls 001, I 002, 004 and 009.

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I NPDES Permit #M0-0098001 I Attachment F NPDES Sampling and Analysis The chemical analysis of the various vastestreams reported in this application came from two principal sources; 1) discharge monitoring data as required by our existing NPDES permit and 2) a special sampling and analytical project conducted in early December, 1984.

Historical data from previous DMR's is of limited use since only the most recent months are likely to be representative of normal I operation.

The reapplication sampling effort was conducted by plant personnel during December 4 through 6, 1984. Power generation at the plant I averaged in excess of 90% of capacity during this period.

Because of the unresolved status of some outfalls (see discussion I of outfall 003 and 004), and power ascention testing and reapplication time constraints, some special sampling and analysis techniques were utilized. Further, as a result of the intermittent or batch discharge I nature of many outfalls it became necessary to deviate from the reappli-cation sampling instructions. Each sample location is discussed separately below to clarify these details and to allow the data to be interpreted correctly.

For the sampling project, plant personnel performed analysis for those parameters requiring on site or radiological analysis. Other analysis was performed by Controls for Environmental Pollution.

Outfall 001 As previously defined, routine discharges from this outfall are from one of five sources - the Boron Recycle System, the Liquid Radwaste System, Laundry and Hot Shower system, Secondary Liquid Waste system, I and (less frequently) Steam Generator Blowdown. While processed separately, these vastestreams are normally comingled and retained in various tanks prior to discharge. Thus, discrete samples of each sub-I system could not be obtained. Further, Steam Generator Blowdown was re-cycled without discharge during our sampling project schedule. (See Attachment C, concerning blowdown analysis).

In view of the above conditions and the necessity that plant opera-tions not be constrained by the testing program, the following approach was utilized. Within a single 24 hour2.777778e-4 days 0.00667 hours 3.968254e-5 weeks 9.132e-6 months period, December 5 & 6, 1984,

.l samples were taken of each of a total of three batch releases made. All W samples were grabs taken from well mixed tanks (under recirculating con-ditions) prior to release. Each sample was analyzed independently. The values shown in the following Maximum Daily Value columns reflect the I corresponding flow weighted averages and total masses calculated from this data.

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1) Form C, Table I, Item 3.00 a) A, Heading 2a and b) B, Heading 3a and

2) Form D, Item 1.30, Heading 3a, One further exception is noted. After these samples were taken, plant personnel performed TSS analysis to verify compliance before authorizing the release from these tanks. The TSS levels were not ac-I ceptable so the tanks were recirculated through additional filters prior to release. The TSS values shown represent conditions just prior to discharge. The remaining data is therefore conservative in some respects as the polishing filtration would remove some portion of any I parameters having suspended fractions, principally total metals.

Also note that Oil and Crease analysis is calculated from averages I of four grab samples from each tank.

The maximum thirty day and long term average values shown in both I forms represent data compiled from the DMR's from October, November, and December, 1984. Previous months' data are not considered to be repre-sentative of normal plant operation.

Outfall 002 Cooling tower blowdown was sampled over a 24 hour2.777778e-4 days 0.00667 hours 3.968254e-5 weeks 9.132e-6 months period on I December 4 and 5. The discharge was maintained at a constant flow rate of 5000 gpm. Flow proportional composite and multiple grab samples were taken as appropriate.

Data under " Maximum Daily Value" headings reflect the above samples. " Maximum 30 Day" and "Long Term Average" values are based on routine DMR's for October thru December, 1984. As previously discussed, this period best represents operating conditions.

Outfall 003 Clarifier blowdown is primarily dependent on plant water use and river suspended solids concentration. Thus, rather than attempt a 24 hour2.777778e-4 days 0.00667 hours 3.968254e-5 weeks 9.132e-6 months flow proportional composite of this outfall, which would only be representative of current winter, low flow-low river TSS conditions and unduly biased by the continuous blowdown line flushing, we sampled only during the actual blowdown operation of each clarifier. On the sampling date, December 5, each of the three clarifiers was only blown down once I for approximately 10 minutes. Two separate sets of grab samples were taken from each clarifier. These grab samples were then combined (when appropriate) into two separate composite samples, representing the com-I bined discharge from all three clarifiers.

This outfall has the potential for direct discharge (pending FDF I approval or appropriate BEJ limits) or the discharge of supernatent fol-lowing sedimentation of solids. Therefore, the analysis of the two com-ENVattachF 01/31/85 - mha I

I posite samples were treated differently to reflect these two discharge options.

Instructions were given to the contract lab to analyze one sample I as received to reflect the direct discharge alternative. The second, duplicate, sample was allowed to settle for approximately 24 hours2.777778e-4 days 0.00667 hours 3.968254e-5 weeks 9.132e-6 months , and the supernatent analyzed to approximate the quality of a discharge from the lagoon.

These values are shown on two separate data tables under the

" Maximum Daily Value" headings, one is labeled Clarifier Blowdown; the other, Clarifier Blowdown Supernatent. The mass values shown were cal-culated using our estimated average flow rate per Form C Item 2.40 A and It should also be noted that demineralizer regeneration vaste is currently combined with clarifier blowdown in a single lagoon, with supernatent recycled to the water treatment plant stilling basin. Con-I sequently no additional data is available for the individual discharge from Outfall 003 (and 004).

Outfall 004 As described in Attachment C wastewater discharges from the Demin-eral bed Water System occur as batch releases. Under current operations I a. entire day's discharge can be retained in the neutralization basin for pH adjustment before discharging to a sedimentation pond. As this is a recirculating, mechanically mixed tank, a single grab sample was I taken on December 5. Multiple samples were taken for oil and grease.

As the dedicated lagoon is not yet operational, special handling I was required to approximate sampling of supernatent only. The labora-tory was instructed to allow this sample to settle for approximately 24 hours2.777778e-4 days 0.00667 hours 3.968254e-5 weeks 9.132e-6 months and then analyze the supernatent only. As the lagoon is quite large in comparison to this flow, this data should be quite ccuservative I with respect to the suspended fraction of any parameter.

As with Outfall 003 these values and the estimated average flows I are used to calculate mass values. Both are listed under the Maximun Daily Value column.

Outfall 005 The Oily Waste Separator System batch processes wastewater based on level actuators on an influent wastewater storage tank. The system nor-mally operates in an automatic mode rendering sampling difficult. Fre-quency of operation is quite unpredictable and dependent on many inde-pendent influent sources.

On December 5, the system was operated manually to obtain samples for analysis. Two processing / discharge events were initiated. Grab samples from each were taken and composited as appropriate.

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l These data are shown under both forms in the " Maximum Daily Value" I heading. " Thirty Day Maximum" and "Long Term Average" values are calcu-lated from DMR data from October through December, 1984.

Outfall 007 The Sanitary Treatment Plant was operated at a constant rate of ap-I proximately 24 gpm during the sampling period. Twenty four hour flow proportional and grab samples were taken on December 4 and 5.

Data obtained on these dates are reported under the " Maximum Daily I Value" heading. Other reported ialues are calculated for DMR's from the period October through December, 1984.

gitfall 008 The only process wastewater generated by the Circulating and Ser-vice Water System results from the regeneration'of the system water I softener. Only a single regeneration event occurred during the sample period, on December 5. A continuous composite sample was collected dur-ing the 1-1 1/2 hour discharge event. This procedure is also used to obtain a representative sample of the discharge for the routine DMR's.

These data ar'e shown under the " Maximum Daily Value" heading. Ad-ditional values are calculated from DMR's for November and December, 1984, as other data are both quite limited and nonrepresentative of

" normal" conditions.

Outfall 009 The intake heaters were not in use at the time of sampling; in fact, there have been no discharges to date. However, the system chem-I istry is in a wet lay up condition, which would represent a conservative or worst case condition.

I A single grab sample was taken on December 4 and adjusted with both acid and base to meet discharge criteria (both were used as it was overtreated). The sample was then subdivided for analysis.

This sample is representative of a " worst" case release and is shown under the Maximum Daily Value heading. No other data is Missouri River Flow proportional composite and individual grab samples, were ob-I tained over a 24 hour2.777778e-4 days 0.00667 hours 3.968254e-5 weeks 9.132e-6 months period on December 4 and 5, from the head of the water treatment plant. These samples were taken without recycle from the clarifier blowdown lagoon. These data are shown under the intake ,

heading on both Forms C and D for Outfall 003 under the following sections:

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1. Form C, Table I, Item 3.00 a) A, Heading 4a b) B, Heading Sa

2. Form D, Item 1.3, Heading Sa All analyses were conducted in accordance with Standard Method and/or EPA methodology. Specific test methods or additional detail on other aspects of the sampling or analysis program is available at your I request.

Important notes on mass discharge calculations:

Where calculated, mass discharges under the Maximum Daily Value He'ading, represent values calculated from the analytical data and the measured flows during the sampling event. Consequently the values shown I do not necessarily represent an actual maximum mass discharge value.

The same is true for Outfalls 003 and 004 for which mass values I were calculated based on estimated average flow. For Outfal1 009, the estimated maximum flow was used to calculate mass values. Mass dis-charges for Thirty Day Maximum and Long Term Average headings are based on their associated flows, per the DMR.

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NPDES Parmit #M0-0098001 I

Attachment C Section 311 and Superfund Exemptions The chemicals listed below are used in water treatment processes in amounts exceeding their " reportable quantities" under 40CFR 117 (1980).

Reportable Quantity Chemical Usage (1bs/ day) (lbs/ day) Outfalls Sodium hydroxide 1160 1,000 001,002,004,009 I Sodium hypochlorite Sulfuric acid 467 20300 100 1,000 002,007 001,002,004,009 I Union Electric requests exclusion under the NPDES exemptions from Section 311 and Superfund reporting for these three compounds and all others that are, as reported in this application, present in continuous or anticipated intermittent discharges. Appropriate monitoring will be I performed. These and other discharges for which exclusion are requested are exempt from section 311 liability by 40 CFR 117.12(a)(1) if they are in compliance with the permit and by 117.12(a)(2) or (3) if they are not. Discharges that are excluded from 311 are also excluded from Superfund. Any discharges other than those resulting from on-site spills would either result from circumstances identified in this appli-cation and be subject to neutralization treatment (See 177.12(c)) or would be a continuous or anticipated intermittent discharge originating within the operating or treatment systems at the plant (see 117.12 (d)).

These discharges are therefore excluded from Section 311 and Superfund reporting liability.

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eq NPDES Parnit #MO-0098001 I Attachment H General Comments on Standards Setting In anticipation of conditions which may be set in this permit rene-wal, Union Electric requests the consideration of the following comments.

1) Mass Limits On November 19, 1982, EPA published new regulation for 4Q CFR Part 423, " Steam Electric Pouer Generating Point Source Category" (47 FR 52290). Section 423.13(g) specifically allows the permitting authority I .

to express the quantity of pollutants allowed to be discharged as a concentratierr limitation instead of a mass-based limitation. Fixed num-erical mass discharge limitations necessarily impose implicit flow res-trictions at the allowable concentration levels. These flow restrie-I tions are too inflexible to cope with the flow variability conditions and the electrical reliability imperatives placed on steam electric power plants. Unlike some industries in wliich wastestream flow varia-bility is the result of a single factor, like productica, Callaway Plant I has no such single parameter indicative of flow. Further as a utility whose production is dictated by public consumption the plant must be capable of attaining and maintaining full power production for as long as necessary.

Since we feel that the concentration based limits are sufficient and more appropriate for regulation of power plant discharges, we I request that you delete the exiting mass limitations when reissuing this permit. Note that you exercised this option when re-issuing our Meramec and Ashley Plant permits in May of 1983.

2) Net Credits In a situation whereby a limitation might be set on the discharge of a priority pollutant, Union Electric feels it should reflect an ad-justment credit for pollutants in the intake water, the Missouri River.

As complete removal of compounds in this category would not be achieved I by the water treatment systems at the Callaway Power Plant, we hereby request an appropriate n_g limitation be applied as necessary.

3) Continuous pH Monitoring In 1982, the Environmental Protection Agency modified its effluent limitation guidelines for pH for all industrial discharges (47 F.R.

24534. June 4, 1984). The modified pH guidelines require (1) compliance

( with pH limitations 99% of the time, measured on a monthly basis for in-dustrial dischargers who, pursuant to their NPDES permits, continuously monitor the pH of effluent discharge wastewaters; and (2) limit, for such discharges the duration of individual excusions from the required pH range to 60 minutes.

We submitted a request to ta5te advantage of this pH rule relaxation I on August 26,.1982, within the federally allotted period. We, there-fore, request that the above change be incorporated into the continuous monitoring requirement on outfall 002, cooling tower blowdown.

ENVattachH 01/24/85 - mha

6 NPDES Parmit #MO-0098001 I Attachment I Section 316(b) Demonstration Status The Callaway 316(b) demonstration consists of two parts, an en-trainment study and impingement study. Part one, the entrainment study I was started during the spring of 1984'and was successfully completed fall of 1984. Part two, the impingement study is scheduled to start within 90 days of commercial operation of the plant. Conditions permit-ting, the impingement study will begin on schedule and will be conducted I weekly for one year. Within 18 months from the start of the impingement program a final intake assessment report will be submitted to the department.

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ML20107C933

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