Text

Rev 0 to HS-EP-02850, Hazardous Chemical & Oil Spills
	ML20035F207
Person / Time
Site:	Davis Besse
Issue date:	02/15/1993
From:	Asby A; TOLEDO EDISON CO.
To:	;
References
	HS-EP-02850, HS-EP-2850, NUDOCS 9304210029
	Download: ML20035F207 (98)
	v • d • e

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1 CICSPQ MANUAL TABLE OF CONTENTS DATE/ TIME C4/12/93 15:23:33 D8 EMER. PLAN: OFF NORMAL OCCURRENCE PROCEDURES MANUAL:

EPON REVISION:

19 PROCEDURE EFFECT ALTERATION TAS NUMBER REV ST DATE ALTERATIONS EFF DATE TITLE 001 HS-EP-02000 02 CE 03/02/93 MEDICAL EMERGENCIES OLD: AD-1827.02 002 HS-EP-02805 01 CE 04/20/90 DAVIS-BESSE EMERGEFCY TELEPHONE SYSTEM 003 HS-EP-02807 03 CE 07/13/92 HFLIPAD USE 004 HS-EP-02810 01 CE 03/30/90 TORNADO OLD: EP-4100.00 005 HS-EP-02820 02 CE 09/02/88 EARTHOUAME OLD: EP-4200.00 006 HS-EP-02830 01 CE 12/30/92 FLOODING OLD: EP-4300.00 007 HS-EP-02840 01 CE 12/08/92 EMPLOSION OLD: EP-4400.00 008 HS - E P - 02850 00 CE 06/21/91 C 922630 04/12/93 HAZARDOUS CHEMICAL AND OIL SPILLS OL D : a8 1703.14 OLD; EP-4500 009 HS-EP-02861 00 CE 07/03/90 RADIOLOGICAL INCIDENTS DLD: AB-5203.13 OLD: AB-1203.22 OLD: AB-1203.39 010 HS-EP-02864 00 CE 01/03/89 C 901931 05/16/90 CONTAINMENT EVACUATION OLD: AD-1827.13 011 HS-EP-02870 03 CE 04/05/93 STATION ISOLATION OLD: EP-4700.00 012 HS-EP-02880 00 CE 07/26/91 INTERNAL FLOODING I

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SUBJE CT E F F ECTiv E D AT E INfTI ATED BY hk j j D. A. Isley HAZARDOUS CHEMICAL AND OIL SPILLS SUPE RSED ES APPROVED BY (D4wnsion Director)

AB 1203.14 EP-4500 T. J. Myers Complete rewrite of HS-EP-4500 Prepared by:

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/ Fate Procedure Classification:

X Safety Related Quality Related Os Non-Ouality Related

4 Hazardous Chemical and 2

HS-EP-02850 Oil Spills R0 C-1 5 O

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Hazardous Chemical and 4

HS-EP-02850 Oil Spills R0 C-1 TABLE OF CONTENTS Page 1.0 PURPOSE 5

2.0 REFERENCES

5 3.0 DEFINITIONS 7

4.0 RESPONSIBILITIES 9

5.0 INITIATING CONDITIONS 10 6.0 PROCEDURE 12 6.1 Activation of the Hazwoper Response Plan 12 l 0-4 6.2 Shift Supervisor or Designee Actions 12 6.3 Spill Response Actions 15 6.4 Environmental Compliance (EC) Notifications 17 6.5 10 CFR 50.72 Notifications 19 6.6 Cleanup and Recovery Actions 19 6.7 Spill Notification Form Completion 20 6.8 Deactivation 20 en 7.0 FINAL CONDITIONS 20 8.0 RECORDS 20 ATTACHMENT 1.

Incident Command System 21 ATTACHMENT 2.

Spill Prevention Control and Countermeasure (SPCC) Plan 24 l

l ATTACHMENT 3.

Spill Notification Form (ED 7892) 48 ATTACHMENT 4.

Spill Notification Continuation Sheet (ED 7892A) 50 ACHMENT 5.

Locations of Spill Control Equipment 51 l

ATTACHMENT 6.

Site Map of Flapper Gates and Marsh Pumps 52 ATTACHMENT 7.

Decontamination Area Establishment and Methods 53 ATTACHMENT 8.

SARA / CERCLA Hazardous Chemical Locations and Spill Event Guidelines 58 l

ATTACHMENT 9.

Resource Conservation and Recovery Act (RCRA)

Contingency Plan 75

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Hazardous Chemical and 4a HS-EP-02850 Oil Spills RD C-1 #

TABLE OF CONTENTS (Continued)

Page ATTACHKENT 10. Spill and Incidental Release Cleanup Plans Boa COMMITMENTS 81 O

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4 Hazardous Chemical and 5

HS-EP-02850 RO C-1 Oil Spills 0

1.0 PURPOSE 1.1 This procedure identifies and provides the followingt f

1.1.1 Actions to be taken in the event of an oil, mixed waste or non-radiological hazardous chemical spill event (incidents which require Hazwoper response implementation).

1.1.2 Actions to be taken to respond to and cleanup small incidental spills (incidents which do not require Hazwoper C-g response implementation).

1.1.3 Information on the site locations of oil, hazardous and non-hazardous chemical sources.

1.2 This procedure fulfills applicable requirements for the following Plans:

1.2.1 Hazardous Substance Emergency Response Plan and a portion of the written Health and Safety Plan, as required by 29 CFR 1910.120 Hazardous Waste Operations and Emergency Response (HAZWOPER) 1.2.2 Contingency Plan for the Chemical Waste Storage Area and Mixed Vaste Storage Area, as required by 40 CFR 265 Subpart D, Contingency Plan and Emergency Procedure 1.2.3 Spill Prevention Control and Countermeasure (SPCC) Plan, as required by 40 CFR 112, Oil Pollution Prevention a

1.2.4 Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) 1.2.5 Superfund Amendments and Reauthorization Act (SARA) 1.2.6 Contingency Plan as required by OEPA Regulation 3745-52..

Standards for Generators of Hazardous Waste.

g, 1.2.7 NO-HS-00500, Nuclear Emergency Preparedness.

2.0 REFERENCES

2.1 Developmental 2.1.1 Federal Statutes Comprehensive Environmental Response, Compensation, and a.

I Liability Act (CERCLA) of 1980 i

b.

Superfund Amendments and Reauthorization Act (SARA) of 1986 c.

Resource Conservation and Recovery Act (RCRA) of 1976 1

HS-EP-02850 5a Hazardous Chemical and R0 C-1 4 oil Spills v

2.1.2 Code of Federal Regulations a.

29 CFR 1910.120. Hazardous Vaste Operations and Emergency Response b.

40 CFR 112. Oil Pollution Prevention 40 CFR 265 Subpart D. Contingency Plan and Emergency c.

Procedure i

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HS-EP-02850 011 Spills R0 C-1 l

d.

40 CFR 300. National Oil and Hazardous Substances Pollution Conngency Plan t

2.2 Implementation j

2.2.1 Code of Federal Regulations a.

10 CFR 50.72, Immediate Notification Requirements for Operating Nuclear Power Reactors b.

40 CFR 302. Designation. Reportable Quantities and Notification 40 CFR 355. Emergency Planning and Notification c.

2.2.2 Federal and State Codes. Standards, and Permits a.

DBNPS National Pollutant Discharge Elimination System (NPDES) Permit b.

Ohio Administrative Code; Ohio Environmental Protection J

Agency (OEPA) Regulations Chapter 3745-52. Standards d-l for Generators of Hazardous Vaste.

c.

Ohio Administrative Code; OEPA Regulations Chapter 3750-25. Emergency Release Notification.

I 2.2.3 Nuclear Group Procedures a.

NG-IS-00002. General Nuclear Security Requirements b.

NG-PS-00106. Nuclear Records Management c.

NG-HS-00504. Hazardous and Non-hazardous Chemical Vaste Management d.

NG-NL-0808. Regulatory Agency Communications e.

NG-HS-00500. Nuclear Emergency Preparedness

~I f.

NG-NL-00807. Regulatory Reports 2.2.4 Section/ Unit Procedures a.

DB-OP-02533. Control Room Em',rgency Ventilation Load Shedding b.

SP 1106.08 (DE-OP-06230). Steam Generator Secondary Side Fill. Drain and Layup c.

DB-OP-06903. Plant Shutdown and Cooldown d.

HS-EP-01500 Emergency Classification e.

HS-EP-02530. Evacuation f.

HS-EP-02000, Medical Emergencies l

i f

Hazardous Chemical and 6a 115-EP-02850 R0 C-1 Oil Spills h

2.2.5 Other Documents DENPS Integrated On-Call Report a.

b.

DBNPS Controlled Materials Hazard Evaluation Index l

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HS-EP-02850 R0 C-1 Oil Spills c.

DBNPS Emergency Plan d.

DENPS Emergency Plan Telephone Directory e.

Toledo Edison Manual for Cleanup of PCB Fluids. PCB-Contaminated Fluids, and Non-PCB Dielectric Fluids 3.0 DEFINITIONS 3.1 EMERGENCY RESPONSE - A response effort by employees from outside the immediate release area or by other designated responders (i.e. local fire departments) to a spill event which results or is likely to result in an uncontrolled release of a hazardous chemical. Responses

(-j to releases of hazardous chemical where there is no potential safety or health hazard are not considered emergency respor.ses.

l 3.2 ENVIRONMENT - For the purpose of this procedure, means outside of the system (drum, container, tank, pipeline, process vessel, etc.)

intended /designad to contain a hazardous chemical.

3.3 HAZARDOUS CHEMICAL - For the purpose of this procedure, this term includes the following categories of chemical / substance hazard classifications:

3.3.1 Hazardous Substance - Any substance, biological or disease causing agent which may result in adverse effects to the health and safety of employees or their offspring as a b'

result of release to the environment and, as listed in 40 CFR Part 302 and 49 CFR Part 172.

3.3.2 Extremely Hazardous Substance - Any substance that can cause serious or adverse health effects with only a single exposure (listed in Appendices A and B of 40 CFR Part 355).

3.3.3 Hazardous Chemical - Any chemical which is considered to be a physical or health hazard under the OSHA's Hazard Communication Standard (29 CFR 1910.1200).

3.3.4 Hazardous Waste - Any liquid or solid waste as identified by one or more characteristics (corrosivity, ignitability, reactivity, or toxicity) or is on one of the EPA lists of hacardous wastes as referenced in 40 CFR 261 and 49 CFR 171.

3.4 HAZWOPER TRAINED INDIVIDUAL - An individual that is qualified on the use of a self-contained breathing apparatus (SCBA) and has received the required training as defined by OSHA 29 CFR 1910.120 to respond to a spill event.

3.5 INCIDENT COMMAND SYSTEM - Consists of the following organizational f

structure (DBNPS title with OSHA title in parentheses) as defined by OSHA for responding to spills (Attachment 1 Incident Command System, provides additional information):

O 3.5.1 Shif t Supervisor or Designee (Incident Commander)

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3.5.2 Assistant Shift Supervisor or HAZWOPER Trained Shop l

Supervisor (On-Scene Coordinator, also known as " Operations Section Chief *)

3.5.3 On-Call Supervisor - Environmental and Safety and/or Nuclear Industrial Safety and Hygiene (NISH) (Safety Person) 1 I

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HS-EP-02850 i

011 Spills R0 C-1 0

3.5.4 On-Call Public Relations Manager /JPIC Hanager/ Writer (Information Person) l 3.5.5 Security (Liaison Person) 3.5.6 HAZWOPER trained individual most familiar with affected system (Planning Section Person) 3.5.7 On-Call Maintenance Superintendent / Operations Support Center Manager (Logistics Section Person) 3.5.8 Contracts and Budget Manager (Finance Section Person) 3.6 MIXED VASTE - Any waste consisting of both a hazardous waste and radioactive material.

3.7 NAVIGABLE WATERWAYS - Indicates the following:

3.7.1 All navigable water of the United States (U.S.), and adjacent wetlands (for example, the marsh surrounding DBNPS).

3.7.2 Tributaries of navigable waters of the U.S.

(including adjacent wetlands).

3.7.3 All other waters of the U.S. such as intrastate lakes, rivers, streams, and wetlands which may be used for recreational or commercial (including commercial fishing) purposes.

3.8 OIL - Means oil of any kind or in any form, including, but not limited tot petroleum: fuel oils oil refuse: mixture of oil with wastes other than dredgied oil (oils contaminated with PCBs or hazardous chemicals 1,

shall be considered Hazardous Chemicals).

L-I 3.9 OIL BOOM - A floating device which confines oil spilled on the surface of a body of water.

3.10 REPORTABLE QUANTITY (RQ) - When released, the minimum quantity of a j

hazardous substance as identified in 40 CFR Parts 302 and 355 which j

requires emergency notification to a regulatory agency.

3.11 SPILL AREA ZONES / BOUNDARIES - The following zones are established around a spill area to maintain control of the area and personnel safety:

3.11.1 Hot Zone - Consists of the actual spill area.

3.11.2 Varm Zone - Consists of an area surrounding the hot zone at a distance that provides safety from physical contact hazards and/or any airborne chemical contamination, an area for setting up decontamination materials, and entry / exit work space for teams in personal protective equipment. Only the entering / exiting spill response team and decon personnel are permitted in this area.

~

l e

Hazardous Chemical and 9

HS-EP-02850' i

R0 C-1

-l Oil Spills 3.11.3 Cold Zone - Consists of an area outside of the Warm Zone I

that is used by the remaining responding HAZWOPER trained individuals for support activities.

l 3.12 SPILL / INCIDENTAL RELEASE - Small spills or incidental releases of j

chemicals or oils which can be absorbed, neutralized or contained at

[

I the time of release by employees in the immediate release area or by maintenance personnel, which. pose no safety or health hazard (i.e.

g,!

f fire, explosion..or chemical exposure), and, do not require i

notifications of the release. These spills / releases are not

' emergency responses' or ' spill evtnts' and do not require l

implementation of the Hazwoper Response Plan.

i 3.13 SPILL EVENT - Means:

i 3.13.1 A discharge (any spill', leaking, pumping, pouring, emptying, or dumping except any discharges authorized by a Federal or i

State permit) of oil into or upon navigable waters or j

adjoining shorelines in harmful quantities (causes a film or sheen on, or discolora.ica of, water surf ace, or causes a j

sludge or emulsion to be deposited beneath water surface or l

upon adjoining shorelines).

i 3.13.2 A release (spilling, leaking, pumping, pouring, emptying, discharging, injecting, leaching, dumping, or disposing) of l

a hazardous chemical, mixed waste or PCB containing oils i

into the environment.

T-l 3.13.3 A release or discharge of any material of unknown source.

j I

3.14 SPILL KITS - For the purpose of this procedure, these kits are used I

for chemical hazards and are not the same spill kits used for RC i

purposes in the Radialogical Control Area.

f i

3.15 TLV - THRESHOLD LIMIT VALUE - The airborne concentration of a material' to which nearly all workers can be exposed without adverse effects.

3.16 TLV-TWA - THRESHOLD LIMIT VALUE-TIME WEIGHTED' AVERAGE - The allowable O*l time weighted average concentration for a normal 8-hour work day or-40-hour week.

l 4.0 RESPONSIBILITIES i

(

4.1 The Plant Manager shall ensure that.HAZWOPER trained individuals are available to respond to an emergency oil, mixed waste, or hazardous t

chemical spill event.

4.2 The Shift Supervisor or designee shall:

i L

4.2.1 Make required onsite notifications.

4.2.2 Determine if a spill event has occurred and entered into

.Os.

DBNPS Emergency Plan for Hazwoper Response as necessary.

I-1 l

i I

Hazardous Chemical and 9a HS-EP-02850 l

R0 C-1 4 011 Spills O

4.2.3 Dispatch HAZWOFER trained individuals to the spill event site within the Protected Area or the Owner-Controlled Area.

i i

4.3 The On-Call Supervisor - Environmental and Safety shall:

t t

4.3.1 Ensure timely mitigation of spill event.

4.3.2 Make required onsite and offsite notifications.

i l

4.3.3 Provide technical assistance during response and cleanup efforts.

4.3.4 Ensure personnel protective equipment and practices are prescribed during an emergency response.

4.3.5 Ensure monitoring of personnel for hazardous chemical exposure.

O, l

O

e Hazardous Chemical and 10 HS-EP-02850 R0 C-1 Oil Spills 4.3.6 Prepare any required regulatory reports to EPA and/or OSHA.

4.3.7 Ensure that Spill Kits for use with chemical or oil spill events are stocked with emergency response equipment.

4.4 The Manager - Plant Operations (excluding Chemistry) shall provide HAZWOFER trained individuals for responding to spills to perform actions on equipment as required by Operations and this procedure.

4.5 The Superintendent - Chemistry shall provide HAZWOPER trained individuals for responding to spills to perform actions on equipment as required by Chemistry and this procedure and analyze released process fluids, etc. for hazardous chemical levels.

4.6 The Manager - Radiological Protection (RP) shall provide HAZWOPER IC-l trained individuals for responding to spills to provide RC expertise for containment / cleanup in the RP Area to prevent / reduce spread of radioactive contamination.

4.7 The Manager - Plant Maintenance shall:

4.7.1 Provide HAZWOPER trained individuals from Maintenance Services for responding as directed to a spill event within the Protected Area or the Owner-Controlled Area.

4.7.2 Isolate site waterways during a spill event as directed by the Shift Supervisor or designee or On-Scene Coordinator and w

as coordinated by the On-Call Supervisor - Environmental and } c_

Safety.

4.7.3 Provide clean up of spilled material as directed and coordinated by the Shif t Supervisor or on-Call Supervisor -

N1 Environmental and Safety.

4.8 The Manager - Materials Management shall provide HAZWOPER trained individuals for responding as directed to spills in the warehouses and associated yards.

4.9 The Manager - Nuclear Training shall provide adequate training to personnel to meet the requirements of 29 CFR 1910.120.

4.10 All DBNPS personnel shall immediately report oil, mixed waste, or hazardous chemical spill events to the Shift Supervisor.

5.0 INITIATING CONDITIONS This procedure shall be used when one or more of the following occur:

5.1 The Shift Supervisor has determined that entry into this procedure is necessary based on conditions such as in the following steps or after consultation with the On-Call Supervisor - Environmental and Safety.

O

Hazardous Chemical and 10a HS-EP-02850 011 Spills R0 C-1 +

5.2 An Operations alarm procedure has directed personnel to this procedure.

5.3 If a hazardous chemical, oil, and/or mixed waste spill event as described below has occurred at DBNPS, the Shift Supervisor shall initiate the DBNPS Emergency Plan for Hazwoper Response 5.3.1 In the Auxiliary / Turbine Buildings, a hydrazire and/or ammonium hydroxide / morpholine tank (s) or drum of Nalco 1355 Corrosion Inhibitor, Nalco 7330 blocide or Hydrogen Peroxide has leake./ ruptured, 5.3.2 The amount of hydrazine released has exceeded the EPA reportable quantity of one pound, i.e. 23,990 gallons of 5 ppm process fluid, O

t 4

O

i l

(

l Hazardous Chemical and 11 HS-EP-02850 R0 C-1 l

011 Spills 5.3.3 in the Water Treatment Plant. sodium hydroxide, sulfuric acid, and/or sodium hypochlorite tank (s) has f

leaked / ruptured,

)

i 5.3.4 For an oil release, a sufficient volume (i.e. 25 gallons) has leaked and poses the potential for or has reached the Training Center Pond and/or the settling basins.

I I

I-l t

l NOTE 5.3.5 i

l l

The reportable quantity for PCB is 1 pound.

l I

I i

l____________________________f.

5.3.5 Any oil leakage which may have eriginated from equipment with PCB containing oil (i.e., overhead lighting or pump

(

l capacitors),

5.3.6 An event which presents exposure to Asbestos waste or l

Asbestos containing material (i.e., insulations) has occurred.

t 5.3.7 A spill or leak has occurred at any work location, chemical l

storage area, CWSA, or accumulation area which may expose l

personnel to hazardous materials, hazardous waste, or mixed j

waste (this includes miscellaneous laboratory solution, chemical or reagent spills or leaks which may be toxic.

reactive, ignitable or corrosive).

I 5.3.8 Component Cooling Water Leakage',

l 5.3.9 A leak or spill from an unknown source has occurred, t

5.4 If a spill or incidental release has occurred which poses no threat of j

personnel exposure (including airborne exposure) or migration to the environment, and, is not required to be reported to local, state or l

federal agencies, the Hazwoper Response Plan is not required to be j

implemented. Spills considered incidental releases and their recommended responses are outlined in Attachment 10.

l 5.5 Contact the Supervisor - Environmental and Safety for determination of the required response for spills not listed under Step 5.3 or Step 5.4 (Attachment 10).

I

,,,m

b Hazardous Chemical and 12 HS-EP-02850 R0 C-1 Oil Spills 0

6.0 FROCEDURE 6.1 Activation of the Harwoper Response Plan l C-(

6.1.1 This procedure may be activated by one or more of the r

following:

a.

An alarm is activated that gives indication of a possible spill, for example unexpected low level in a hazardous chemical / oil tank and/or high sump alarms in area of tank.

b.

A person has discovered a spill or spill involving a fire and has promptly called the Control Room via Gai-Tronics Line 5 or Extension 7777.

I I

l NOTE 6.2 l

1 l

l Steps 6.2.1 through 6.2.11 (inclusive) can be l

l conducted concurrently.

l l_ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _I 6.2 Shift Supervisor or Designee Actions The Shift Supervisor or designee shall:

6.2.1 Request from the person discovering the spill event at least the following informations s.

Source of material spilled b.

Size / Amount of material c.

Nature / Type of material d.

Location and movement of spill 6.2.2 Clear the spill area of personnel as follows:

a.

Inside the Protected Area, announce over the Gai-Tronics that personnel must leave and stay clear of the spill or fire involving a spill area.

b.

In the Owner-Controlled Area, notify Security te request personnel to leave and stay clear of the pill j

area.

c-1 6.2.3 Ensure the area is posted to avoid personnel exposure.

6.2.4 If the event is a fire involving spilled oil, hazardous themicals, or mixed waste:

O a.

Inside the Protected Area, follow appropriate fire procedures.

1 l

Hazardeus Chemical and 13 HS-EP-02850 RO C-1 Oil Spills i

a b.

In the Owner-Controlled Area, request Security to 5

f contact the appropriate offsite fire department for response to the designated area.

6.2.5 If necessary, have an operator or designated individual do f

one or both of the following actions:

[

t i

a.

Lockout sump pumps in and/or adjacent to the spill area (see Attachment 2, Spill Prevention Control and Countermeasure (SPCC) Plan, for equipment containing oil and specific sumpts) in the area), and/or i

b.

Lockout the settling basin transfer pumps.

l I

l l

NOTE 6.2.6 l

l 1

1 l

Depending on conditions of the spill event certain l

[

i regulatory agencies must be notified of the spill l

l l

l within 30 minutes of discovery.

l l

L _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _I j

6.2.6 Contact the On-Call Supervisor - Environmental and Safety l C-f l

l with spill event conditions (i.e. quantity, substance released, movement of spill etc.) for concurrence and/or determination. that activation of the Harwoper Response Plan l

l is required, and for determination of whether the quantity j

meets the regulatory limits for reporting.

l 6.2.7 Record spill event information on Spill Notification Form j

r (SNF) Attachment 3.

If the Harwoper Response Plan will not l

be implemented and no further action is required, forward

{,y

{

the SNF (for information purposes only) to the on-call I

I Supervisor - Envirunmental and Safety.

I 6.2.8 Evaluate spill event conditions for emergency classification in accordance with HS-EP-01500. Emergency Classification j

I l

I 6.2.9 If the Harwoper Response Plan is initiated, notify the f ollowing:

On-Call Operations Superintendent i

a.

b.

On-Call Maintenance Superintendent g

c.

On-Call Material Manager. if spill is in varahoucas or associated yards.

d.

On-Call Radiological Protection Supervisor, if

e. pill in in RRA.

- " - +

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we+

r=y-

"W gT mc-w r--W' e=Jm' W*uviry

_a+%wp 4.1v

me we'-6=*W*Me FWMfD*f-*

T* - - ' -tr

'e-

Hazardous Chemical and 13a HS-EP-02850 t

j R0 C-1 4r Oil Spills 6.2.10 Check the Control Room for unusual vapors / fumes and if present, manually isolate the Control Room ventilation air supply. If Control Room emergency ventilation system is required to be put in service, follow the actions of DB-OP-02533 Control Room Emergency Ventilation Lead Shedding.

I I

l NOTE 6.2.11 l

1 I

l A minimum of six HAZWOPER trained individuals are l

l needed for responding to and entering a spill event l

l l

area.

l_ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _l 6.2.11 If the RAZWOPER Response Plan is required to be implemented, request HAZWOPER trained individuals report to an area for briefing of spill event.

If mpill is in the Owner-Controlled Area, the HAZWOPER a.

t ained individuals available for responding would be Maintenance Services On-Call Supervisor -

Environmental and Safety, and Materials Management (if i

spill is in warehouses or associated yards). A Maintenance Services Supervisor (s) and additional I

servicemen may be called in for assistance.

6.2.12 Designate a minimum of six RAZWOPER trained individuals to the following incident Command System positions and actions (see Attachment 1 Incident Command System):

a.

One individual as the Dn-Scene Coordinator who may/will also act as the Safety Person b.

For spill event in the Owner-Controlled Area, the On-Scene Coordinator may be delegated to:

On-Call Supervisor - Environmental and Safety, o

Maintenance Services Supervisor (called in), or 8

o on-Call Material Manager, if spill is in i

varehouses or associated yards c.

Two individuals as the Initial Entry Team i

d.

Two individuals as the Backup Entry Team l

e.

One individual as the Decon Team i

l l

l

\\

Ila-a rdous Chemical and 14 HS-EP-02B50 R0 C-1 Oil Spiils i

i I

l NOTE 6.2.13 l

1 l

l A minimum of six !!AZWOPER trained individuals are l

l needed for responding to and entering a spill event j

l l

atea.

l_ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _I 6.2.13 Dispatch HAZWOFER trained individuals to spill area.

6.2.14 Record spill event information and notifications on the Spill Notification Form (SNF) (Attachment 3) and SNF Continuation Sheet (Attachment 4) and forward to the On-Call l

i Supervisor - Environmental and Safety.

I s

]

l

/~

(m l

l

Hazardous Chemical and 15 HS-EP-02850 011 Spills R0 C-1 l

1 l

l NOTE 6.3 l

1 I

l Typical Locations and contents of spill kits can he l

l c-i l

found in Attachment 5. Locations of Spill Control l

l Equipment.

l I_ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _I VARNING 6.3 Personnel responding to a spill shall maintain a buddy

system to ensure rapid assistance in the event of an emergency. A backup team (with an equivalent level of

personal protective equipment [PPE] and self-contained

breathing apparatus [SCBA]. unles s detennined othe rwise ) is requited to be standing by.

For unknown atmospheres / spill event. Level A chemical PPE and SCBA shall be worn initially to conduct-an assessment of the spill area and also during response actions until the On-Call Supervisor - Environmental and Safety determines that a lower level of protection

is acceptable based on conditions.

6.3 Spill Response Actions 6.3.1 The Incident Command System Safety Person or Nuclear Industrial Safety and Hygiene (NISH) shall:

a.

Ensure appropriate PPE is selected and used by responding personnel, b.

Monitor personnel (i.e. SCBA times, physiological conditions such as heat stress. etc.) and maintain chemical exposute records.

6.3.2 The individuals responding to the spill area shall notif y the Shift Supervisor or designee that they are ready to enter the spill area.

6.3.3 The On-Scene Coordinat or and HAZVOPER trained individuals responding to the spill area shall ensure all individuals.

I except the spill response team, are cleared from the spill area.

O l

l l

4 l

Hazardous Chemical and 16 HS-EP-02850 J

4 R0 C-1 1

011 Spills 4 O 6.3.4 The On-Scene Coordinatcr and HAZWOPER trained individuals shall:

a.

At the spill area. establish the boundaries between the hot, warm, and cold zones.

i i

I l

NOTE 6.3.4.b l

1 I

.]

j NISH may be able to assist with identifying spilled l

l material by using monitoring equipment.

l l_ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _I b.

If the spilled material is unknown, attempt to identify it.

c.

Obtain the Material Safety Data Sheet (MSDS) on the spilled material from the DSNPS Controlled Material Hazard Evaluation Index for use by the spill response i

team.

I d.

Obtain weather data from the DBNPS meteorological monitoring system for spill pathway projections, etc.,

if necessary.

[

Evaluate the situation and develop a plan of action e.

which may consist of one or more of the following:

1.

Covering nearby drains.

1.

2.

Locking out pumps / sumps.

3.

Containing spilled material by diking, absorbing, plugging / patching and/or overpacking the container, etc.

4.

Sending a Maintenance Services person out tc-isolate the ponds or marsh by closing flapper gates or turning off/ locking out r.arsh pumps as requested by the Supervisor - Environmental and I f-1 Safety to prevent the spilled material from reaching tle Navarre Marsh, Toussaint River, or Lake Erie (see Attachment 6, Site Map of Flapper Gates and Marsh Pumps).

f.

Drain any fluid from defective equipment.

g.

Neutralize or treat the spilled material to render it less harmful, if applicable.

]

h.

Collect the spilled material using a pump or vacuum. if applicable.

1.

Eyaluate the pir.n of action continuons1y due to changing spill area conditions.

Hazardous Chemical and 17 HS-EP-02850 R0 C-1 Oil Spills j.

Set up a decontamination area, Attachment 7 Decontamination Ares Establishment and Methods, in the warm zone adjacent to the spill area, if applicable.

k.

In the event of an oil spill, Attachment 2. Spill Prevention Control and Countermeasures (SPCC) Plan, provides further actions /information to mitigate the spill.

1.

In the event of a hazardous chemical spill, Attachment 8 SARA / CERCLA Hazardous Chemical Locations and Spill Event Guidelines, provides further actions /information to mitigate the spill.

m.

In those spill events that involve a release of material stored in the Chemical Vaste Storage Area or a release of material stored in a Mixed Waste Storage Area Attachment 9 Resource Conservation and Recovery Act (RCRA) Contingency Plan, shall be used.

l 6.3.5 If the spill is too large for site personnel to mitigate, the On-Call Supervisor - Environmentsl and Safety shall make IC-l arrangements f or an of f site environmental services contractor to respond with assistance.

6.4 Environmental Complianca (EC) Notifications 6.4.1 The On-Call Supervisor - Environmental and Safety shall O

If necessary, request Chemistry personnel to collect a.

and analyze samples from process fluids, settling basins, ponds, or other points as requested.

b.

Complete Part II A of the Spill Notification Form (Attachment 3) upon notification from the Shift Supe rvis or.

c.

Notify the following personnel, at a minimum, and document on Part II B of the Spill Notification Form (Attachment 3):

1.

Manager - Nuclear Licensing 10~i 2.

Director - Technical Services 3.

Public Affairs 4.

Electrical Maintenance Superintendent or Supervisor (only if the spill originated from j

electrical equipment)

]

II-I 6.4.2 If the event is a chemical spill the on-Call Supervisor -

Environme:2tal and Safety sh il h

a.

Determine based on available information if:

l.

j I!^

Hazardous Chemical and 18 HS-EP-02850 R0 C-1 Oil Spills 1

1.

The substance meets or exceeds the Reportable Quantity iRQ) for a CERCLA bazardous substance (40 CFR 302) and has been released from the intended system and has spread into the environment, or 2.

The released substance meets or exceeds the RQ for J

a SARA hazardous or extremely hazardous substance (40 CFR 355) and has spread or has the potential to spread offsite. or 3.

The spill is.an unauthorized discharge as identified in the DBNPS National Pollutant j

Discharge Elimination System (NPDES) Permit.

l l

NOTE 6.4.2.b l

l I

l For the local, state, and federal agencies, the DBNPS l f

l Emergency Plan Telephone Dxtectory contains the l

l respective phone numbers.

}

l-----------------------------

I b.

For a CERCtA spill event, notify.the Ohio Environmental Protecticn Agency (OEPA). the National Response Center.

and the Local Emergency Planning Comnittee (LEPC).

c.

For a SARA spill event, notify the OEPA. Local Emergency Planning Committee (LEPC), and the U.S. Coast 7

Cuard (if the substance has spread into navigable waterways),

l d.

For an NPDES spill event, notify the OEPA.

6.4.3 If the event is an oil spill the On-Call Supervisor -

lc-g Environmental and Safety shall:

a.

Determine based on available information if the released substance has created an oil sheen on navigable waterways.

b.

If an oil spill on navigable waterway's has occurred as determined in 6.4.3.a. notify the U.S. Coast Guarde l

c.

Determine source of oil and verify oil is non PCB.

IC-l 6.4.4 If the release does not meet any of the conditions in 6.4.2-or 6.4.3. the On-Call Safety / Environmental Supervisor should:

Consult with the Manager - Nuclear Lf:ensing, the l 0-8 a.

Lirector - Technical Services and the Plant Manager to determine which, if any, of the agencies listed in Part II C or D of the Spill Notification Form (Attachment.3) are to be notified of the event.

-~

Hazardous Chemical and 19 HS-EP-02850 R0 C-1 Oil Spills b.

Upon recommendation, make the appropriate notifications and document on the form.

6.4.5 The On-Call Supervisor - Environmental and Safety shall document all calls to a regulatory agency and any other appropriate above calls on a Telephone Call Documentation Form (ED 6650).

6.4.6 The emergency notification to the government agencies shall be followed up with a written report as soon as practical within the specified time frame. The report shall be prepared by the On-Call Supervisor - Environmental and Safety and submitted in accordance with NG-NL-0808 and c-i NO-NL-00807.

6.5 10 CFR 50.72 Notifications 6.5.1 If any of the offsite agencies were notified as identified in Steps 6.4.2 and/or 6.4.3, the On-Call Supervisor -

Environmental and Safety shall notify the Shift Supervisor.

l(-l 6.5.2 The Shift Supervisor or designee ensures that the Nuclear Regulatory Commission has been notified as required by 10 CFR 50.72(b), Immediate Notification Requirements for Operating Nuclear Power Reactors, Non-Emergency Events, Four-Hour Reports.

6.6 Cleanup and Recovery Actions 6.6.1 The spilled substance and cleanup materials such as used pads, pillows, booms, clothing, and other equipment shall be recovered and placed in drums or other approved containers as identified by the On-Call Supervisor - Environmental and 1

Safety.

10-1 6.6.2 Label and accumulate / store these containers according to NG-HS-00504 Hazardous and Nonhazardous Chemical Vaste Management.

6.6.3 The On-Call Supervisor - Environmental and Safety shall make arrangements for disposal of collteted waste materials according to the requirements of NG-HS-00504.

6.6.4 The On-Call Supervisor - Environmental and Safety shall ensure that environmental samples are collected and analyzed, if methods are available, to verify the cleanup response is adequate.

O

[

Hazardous Chemical and 20 HS-EP-02850 R0 C-1 011 Spills l

6.7 Spill Notification Form Completion 6.7.1 The On-Call Supervisor - Environnental and Safety shall _

f(-l f

f complete Part II E of the Spill Notification Form when the event is terminated.

6.7.2 If additional actions are taken past completion of the Spill Notification Form, the original package shall be supple-mented with Spill Notification Continuation Sheets I

(Attachment 4) documenting the actions taken.

1 1

6.7.3 The spill Notification Form package shall be submitted to i

Records Management according to NG-PS-00106. Nuclear Records f(-l l

t Management.

6.8 Deactivation 6.8.1 The Shif t Supervisor or designee, in consultation with the On-Call Supervisor - Environmental and Safety, determines that all spilled chemicals or oils have been confined, t

controlled, absorbed, or transported offsite and pose no j

threat to personnel, the plant, the environnent, er to j

navigable waterways.

+

6.8.2 The On-Call Supervisor - Environmental and Safety ensures f(-l that:

i

(

a.

The necessary information required by 29 CFR 1910.120 to prepare the written critique of the response and recovery efforts is compiled.

i i

b.

The Final Status portion of the Spill Notification Form has been completed.

l 7.0 FINAL CONDITIONS l

l The spill has been contained, recycled, or removed from the DBNPS site and poses no threat to the health and safety of personnel, the plant, or the environment.

8.0 RECORDS 8.1 The following quality assurance records are completed by this procedure and shall be listed on the Nuclear Records List, captured, and submitted to Nuclear Records Management in accordance with NG-PS-00106:

8.1.1 Completed Spill Notification Forms and associated documentation 8.2 The following non-quality assurance records are completed by this procedure and may be captured and submitted to Nuclear Records

_ l(-j O

Management, in accordance with NG-PS-00106:

8.2.1 None

om WW WH=

un n incident *

Positions required to be

3. g-Commander filledwith a minimum of six Zg (ShiftSupervisor ilAZWOPEHtrained individuals "n

___or _Designgel _.

when responding

(

regardless of spill size K

WW Aide (g,kee[m/,comrninucajions)__

g a.

NOTE:On-scene Coordinator On-Scene Coordm.ator. (1) may also act as the

-z O

Safety Person o:n a

C1 M

E 4

P 8

s.

x w

c Safety Person * (1)

Initial Entry Team * (2)

Backup Entry Team *(2 DeconTeam* (1) g g

n m

y w

e eMx Planning Section information Liason Logistics Person Person Person Person y>

Om mM o>

7 "O

O M

m tM O

La W O

O e

~

9 Hazardous Chemical and 22 HS-EP-02850 R0 C-1 Oil Spills INCIDENT COMMAND SYSTEM (Continued)

The Incident Command System shall consist of the following organizational structure as defined by OSHA and includes reference to DBNPS plant and emergency plan titles (any number of these positions may be used in a spill response depending on the spill size, etc.):

OSHA Position DBNPS Title Actions / Duties 1.

Incident Shif t Supervisor or o Develops and implements strategic Commander Designee /On-Call decisions.

Emergency Director o Activates the Incident Command System (Hazardous Substance Emergency Plan duties) and HAZWOPER trained individuals.

o Maintains overall control of spill l

event.

2.

On-Scene Assistant Shift 0 Oversees and coordinates. response Coordinator Supervisor or Senior actions at the spill area.

Person, i.e. a o Maintains communications with the I

HAZWOPER Trained Shop Incident Commander.

Controls access of personnel to spill Supervisor. On-Call 8

i Supervisor -

area.

g,l Environmental and l

l Safety or Materials i

l Management Supervisor / Manager (if in Owner-Controlled r

Area) 3.

Safety Initially may be any e Responsible for safe conditions and Person HAZWOPER trained actions such as ensuring barricade individual, who.vould rope is in place and unnecessary turn over actions te personnel are kept out of the spill the On-Call Supervisor area.

I4 Environmental and 0 Monitoring SCBA times for HAZWOPER Safety and/or individuals in spill area.

i i

NISH.

0 Ensure proper PPE is used.

j j

o Monitor HAZWOPER individuals for other l

physiological conditions, i.e. heat.

stress, etc.

4 Information On-Call Public 0 Acts as contact for disseminating Person Relations Manager /

information on spill-event to media JPIC Manager / Writer NOTE 5:

Any governmental agency (i.e. EPA. OSHA. etc ) representative shall be referred to the On-Call Supervisor - Environmental and Safety or g g.g On-Call Licensing Manager.

Acts as_ contact upon arrival at DBNPS 5.

Liaison Security acts as O

Person escort in Protected for offsite groups, i.e. fire depart-g Area ments, emergency medical squad. etc.,

responding to spill event.

ATTACHMENT'1 Page 2 of.3

Hazardous Chemical and 23 HS-EF-02850 011 Spills R0 C-1 O

INCIDENT COMMAND SYSTEM (Continued)

OSHA Position DENPS Title Actions / Duties 6.

Planning A HAZWOPER trained 0 Collects, evaluates, and disseminates Section individual responding information on the spill event, that is most o Understands the current spill event knowledgeable of condition.

system involved in o Continuously predicts probable cause the spill of events during response to spill event.

o Prepares alternative course of actions to assist in maintaining control of spill event.

7.

Logistics On-Call Maintenance o Provides/ stages materials, facilities.

Section Superintendent /

services, etc. to support spill Person Operations Support response actions.

Center Kanager 8.

Finance Contracts and Budget o Responsible for financial and cost Section Manager analysis aspects of spill event.

Person In addition to the above positions, an aide (logkeeper/ communications) to the Incident Commander may be necessary for some spill situations.

I I

l NOTE l

l l

l Minimum response to implement the Harwoper l

l Response is a 6 man team as follows:

l 1

I c.i l

1 On-scene coordinator / safety person l

l 2

Entry persons l

l 2

Backup entry persons l

l 1

Decontamination person l

l l

l_ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _I ll k i

ATTACHMENT 1 Page 3 of 3 i

q b

Hazardous Chemical and 24 HS-EP-02850 RO Oil Spills O

SPILL PREVENTION CONTROL AND COUNTERMEASURE (SPCC) PLAN General Information l

l A.

Name and location of facility:

Name:

Davis-Besse Nuclear Power Station Location: 5501 North S.R. 2, Oak Harbor, Ohio 43449-9760 i

Direction and distance to nearest town (see attached map) -

Oak Harbor (SV - 6.5 miles)

County:

Ottava State:

Ohio l

B.

Name, address, and phone number of owner or operator:

1 Name:

Centerior Energy Corporation County:

Cuyahoga j

Address:

P.O. Box 94661 State:

Ohio l

City:

Cleveland Zip:

44101-4661 i

l Telephone t

Number:

(216) 622-9800 l

C.

Name or title of person in charge of facility:

f Name or title: Plant Manager I

D.

Name of person responsible for oil spill prevention / mitigation at facility:

t sa ;

Name or title: Shift Supervisor l

Certification I hereby certify and attest that I am familiar with the facility and the i

information contained in this plan and that to the best of my knowledge and belief such information is true, complete, and accurate. Purther, this plan has i

been prepared in accordance with good engineering practices.

- l l

l As e. T.

A.--,-

Printed Name of Registered Engineer Signature of Regfstered Engineer I

N\\N bI e h OM 7. %, 19 Cff Registration Number Date r

lO ATTACHMENT 2 Page 1 of 24 h -.-,...

Hazardous Chemical and 25 HS-EP-02850 RO Oil Spills O

SPILL PREVENTION CONTROL AND COUNTERMEASURE (SPCC) PLAN (Cont.)

DBNPS Site Area and Nearest Towns E

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ATTACHMENT 2 Page 2 of 24

4 Hazardous Chemical and 26 HS-EP-02850 R0 Oil Spills SPILL PREVENTION CONTROL AND COUNTERMEASURE (SPCC) PLAN (Cont.)

DBNPS Finished Site Topography E

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ATTACHMENT 2 Page 3 of 24

l I

Hazardous Chemical and 27 HS-EP-02850 R0 Oil Spills 0

SPILL PREVENTION CONTROL AND COUNTERMEASURE (SPCC) PLAN (Cont.)

Oil Locations and Oil Spill Diagnosis and Response Table of Contents Attachment 1.0 Discussion of 011 Spill Containment Page No.

6 1.1 Security Considerations 6

1.2 Personnel Training 1.3 Discussion of 011 Tank Testing 6

7 1.4 Discussion of 011 Interceptors 1.5 Oil Discharge Cleanup - General Actions 8

10 1.6 DBNPS Site Map 2.0 011 Locations and Specific 011 Spill Situations 2.1 Diesel Oil Storage Tank Leak / Rupture 11 2.2 Diesel Fire Pump Day Tank Leak / Rupture 11 2.3 Emergency Diesel Generator (EDG) Day Tanks Leak / Rupture 12

=

2.4 Emergency Diesel Generator (EDG) Fuel Oil Storage Tank Leak / Rupture 12 2.5 Miscellaneous Diesel Generator Day Tank Leak / Rupture 13 2.6 Turbine-Generator (T-G) Lube Oil Storage Tank Leak / Rupture 14 2.7 Lubricating Oil (LO) Storage Room Tank Leak / Rupture 15 2.8 Main Feed Pump Turbine (MFPT) Lubricating Oil (LO) Tanks or MFPT Used LO Tank Leak / Rupture 15 2.9 Main Transformer Leak / Rupture 16 2.10 Auxiliary Transformer Leak / Rupture 16 2.11 Startup Transformer 01 Leak / Rupture 17 2.12 Startup Transformer 02 Leak / Rupture 17 2.13 Bus Tie AC or BD Transformer Leak / Rupture 17 2.14 Electro-Hydraulic Control (EBC) System Leak or Tank Leak / Failure 18 ATTACHMENT 2 Page 4 of 24

a I

i Hazardous Chemical and 28 HS-EP-02850 RO 011 Spills SPILL PREVENTION CONTROL AND COUNTERMEASURE (SPCC) PLAN (Cont.)

l

?

Oil Locations and Oil Spill Diagnosis and Response (Cont.)

' Table of Contents (Cont.)

Attachment

[

2.0 Oil Locations and Specific 011 Spill situations (Cont.)

Page No.

i' 18 j

2.15 Lubricating Oil Drum Storage Room 2.16 PSF 2000-Gallon Vaste 011 Storage Tank Leak / Rupture 19 l

2.17 Lubricating Oil Spill Within the Radiological Controlled l

20-l Area (RCA) r 2.18 DBAB Emergency Diesel Generator (EDG) Day Tank Leak / Rupture 21 l

2.19 DBAB Emergency Diesel Generator (EDG) Fuel Oil Storage 21 f

Tank Leak / Rupture l

2.20 Fuel Tanks Located at Service Building 4 22 l

i 2.21 Vaste Diesel Fuel /0il in Containers at the Chemical Vaste

)

Storage Area and Chemical Vaste Accumulation Areas 22 f

-t O

2.22 Equipment Containing PCB Dielectric Fluid 23 f

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i l

l l

O ATTACHMENT 2 Page 5 of 24

I i

Hazardous Chemical and 29 HS-EP-02850 R0 Oil Spills SPILL PREVENTION CONTROL AND COUNTERMEASURE (SPCC) PLAN (Cont.)

Oil Locations and Oil Spill Diagnosis and Response (Cont.)

I 1.0 Discussion of 011 Spill Containment 1.1 Security Considerations All the oil tanks at the Davis-Besse Nuclear Power Station are located in an area that has a security lighting system and is patrolled 24 i

hours a day by security personnel. Most of the tanks are located behind the inner fence within the Protected Area (see Attachment 2, i

Page 10, DBNPS Site Map). The possibility of vandalism and tampering is minimized through controlled access to the site via the Service Road and by virtue of the plant's distance from the highway.

1.2 Personnel Training Designated personnel responsible for responding to an oil spill are on site or on call continuously. They are trained in:

l 1.2.1 Proper operation and maintenance of equipment.to prevent discharge of oil 1.2.2 The proper procedure to follow in the event of an oil spill situation 1.2.3 Applicable Spill Prevention Control and Countermeasures (SPCC) Pollution Laws, Rules and Re.gulations 1.3 Discussion of 011 Tank Testing 1.3.1 40 CFR 112.7(e)(2) states that certain tanks should be regularly pressure or integrity tested. These tanks include aboveground tanks and the testing techniques that could be used are hydrostatic testing, visual inspection, or non-destructive shell thickness testing. Tank supports and foundations should be included in these inspections. Also, the tank exterior should frequently be observed for signs of deterioration, leaks which might cause a spill, or accumulation of oil in diked areas.

1.3.2 The oil storage tanks at DBNPS are periodically visually inspected by various groups, i.e. Operations or Maintenance Services, dependent on the tanks' locations. As a preventive maintenance activity, several tanks such as the Emergency Diesel Generator Fuel Oil Storage Tanks (40,000 gallon capacity each) are periodically drained and inspected internally.

O!

ATTACHMENT 2 Page 6 of 24

i h

Hazardous Chemical and 30 HS-EP-02850 R0 Oil Spills O

SPILL PREVENTION CONTROL AND COUNTERMEASURE (SPCC) PLAN (Cont.).

Oil Locations and Oil Spill Diagnosis and Response (Cont.)

1.4 Discussion of 011 Interceptors 1.4.1 All drains in the plant, where oil contamination is possible, discharge to the Storm Sever System via a Josam l

Oil Interceptor. There are five (5) oil interceptors strategically located to accommodate the drains in the station which drain to the Training Center Pond. Also, there are two (2) cil interceptors located in the northeast parking lot which drain to the north marsh. The oil l

(

interceptors are located on Attachment 2, Page 10, DBNPS Site Map. The parking lot by the Personnel Processing Facility (PPF) does not have oil interceptors.

t The oil interceptors are located in the following areas:

Oil Interceptor #1:

East of the Turbine Building Reference Drawings:

M-162, C-52 250 Gallon capacity Influent Drain Source: Sump Pump Discharge 011 Interceptor #2:

North of Station Turbine Building Reference Drawings:

M-162, C-51 7

250 Gallon Capacity Influent Drain Source: Sump Pump Discharge 011 Interceptor #3:

Near Station Valve Room No. 2 Reference Drawings: M-165, C-51 100 Gallon Capacity Influent Drain Source: Sump Pump Discharge Oil Interceptor #4:

Near the Diesel Fuel Oil Pump House Reference Dravings:

M-169, C-34 100 Gallon Capacity Influent Drain Source: Sump Pump Discharge, Diesel Oil Pump No. 4, Diesel Oil Storage Tank Oil Interceptor #5:

North of the Auxiliary Building Reference Dravings:

M-172, C-53 250 Gallon Capacity Influent Drain Source: Multiple Floor Drains Oil Interceptor #6A:

Main Parking Lot by Old Guard House Reference Drawings: C-51 100 Gallon Capacity Influent Drain Source: Parking Lot Storm O

Drains ATTACHMENT 2 Page 7 of 24

i Hazardous Chemical and 31 HS-EP-02850 R0 Oil Spills SPILL PREVENTION CONTROL AND COUNTERMEASURE (SPCC) PLAN (Cont.)

Oil Locations and Oil Spill Diagnosis and Response (Cont.)

Oil Interceptor #6B:

Main Parking Lot by Old Guard House Reference Drawings: C-51 100 Gallon Capacity Influent Drain Source: Parking Lot Storm Drains 1

I l

NOTE 1.4.2 l

1 I

]

Preventive Maintenance records are generated by l

l Maintenance Services to document pumping activities.

l l

Such records list, at a minimum, the date, area, and l

l quantity of precipitation pumped from the interceptor l l

storage tanks.

l l_ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _l 1.4.2 Each oil interceptor is equipped with an oil storage tank.

These oil storage tanks collect and contain the oil accumulated from leaks, accidents or ruptures of oil systems, oil tanks and equipment containing oil. Levels in these tanks are periodically checked and pumped out.

1.4.3 If any of the oil interceptor storage tanks are overfilled in the event of oil spill, observe the north marsh or Training Center pond for evidence of oil. Contain the oil

~

by closing flapper gates and/or turning off marsh pumps and using oil booms and absorbent material. Also, oil booms and absorbent material may be used at the spill source to contain and prevent more oil from entering the oil interceptors.

1.5 Oil Discharge Cleanup - General Actions 1.5.1 Symptoms a.

Visible oil slick on surface of floor, ground, or vater.

b.

Leaks from equipment containing oil such as pumps and lubricating 1.nes.

1.5.2 Specific Action For PCB oil spills, refer to the Manual for Cleanup of a.

PCB Fluids, PCB Contaminated Fluids, and Non-PCB Dielectric Fluids.

b.

For oil spills within the RCA, follow ALARA precautions and use appropriate RC procedures in addition to the applicable requirements of this procedure.

ATTACHMENT 2 Page 8 of 24

1 i

Hazardous Chemical and 32 HS-EP-02850 R0 i

Oil Spills SPILL PREVENTION CONTROL AND COUNTERMEASURE (SPCC) PLAN (Cont.)

Oil Locations and 011 Spill Diagnosis and Response (Cont.)

Use any equipment available, such as absorbents, oil c.

booms, and sand bags, to minimize the leak as much as l

possible.

d.

Contact available firms for supplies and equipment to contain, minimize, and clean up the oil spill.

i Commercial firms are listed in the DBNPS Emergency Plan I

Telephone Directory.

1.5.3 Discussion The station is equipped with retention areas and oil l

a.

interceptors to prevent any oil discharges. If an accident causes an oil spill on the roadways and j

parking lot, or the drainage system becomes contaminated with oil, every' effort shall be made te determine the source and curtail any additional i

spillage, b.

Precipitation.will accumulate in the retention areas I

()

and is periodically pumped out by Maintenance Services.

l i

i 1

i i

I i

I O

i ATTACHMENT 2 Page_9 of 24 i

l I

r

Hazardous Chemical and 33 HS-EP-02850 011 Spills RO O

SPILL PREVENTION CONTROL AND COUNTERMEASURE (SPCC) PLAN (Cont.)

011 Locations and Oil Spill Diagnosis and Response (Cont.)

DBNPS Site Map

1. SOMCE SLDG #2

2. 88UCLEAR PROJECT CDtTER

3. EfMCE SLIA 44

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ATTACHMENT 2 Page 10 of 24

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Hazardous Chemical and 34 HS-EP-02850 l

R0 l

i 011 Spills l

SPILL PREVENTION CONTROL AND COUNTERMEASURE (SPCC) PLAN (Cont.)

011 Locations and Oil Spill Diagnosis and Response (Cont.)

2.0 Oil Locations and Specific 011 Spill Situations 1

2.1 Diesel Oil Storage Tank Leak / Rupture l

3 2.1.1 Symptoms Oil accumulation within the Diesel Oil Storage Tank I

retaining structure.

2.1.2 Discussion l

The Diesel Oil Storage Tank is designed so in the event of a i

leak or rupture, the retaining structure around the tank vill contain the entire 100,000 gallon capacity of the tank, l

plus an additional 15,000 gallons of precipitation and fire

+

Periodically, the retaining vall area is checked and vater.

any accumulated precipitation is pumped out using a sub-mersible pump. For the diesel oil storage tank, Computer Alar:n L378 receives data from tank contents level trans-

[

mitter LT 1441 (Foxboro Electronic Transmitter, DP Cell).

LT 1441 is located in the southeast quadrant of the l

retaining moat, about 1.5 feet above the moat floor, near the moat floor access ladder. A local level indicator gauge f

O.

is also located in the southeast quadrant of the moat area, j

about 6 feet above the moat floor under the tank access

[

i catvalk. This level gauge (LIS-1102, Varec Pigure #2500 Series, Model B) is used to determine amount stored and to l

monitor amount in tank during filling operations.

2.2 Diesel Fire Pump Day Tank Leak / Rupture 2.2.1 Symptoms l

l Oil accumulation within the Diesel Day Tank retaining curb.

2.2.2 Specific Action E the Diesel Oil (DO) Transfer Pumps, P8-1 and P8-2, a.

i are transferring oil to the Diesel Fire Pump Day Tank i

b.

THEN stop the DO Transfer Pumps P8-1 and P8-2 1.

P8-1 is povered from MCC E12B (BE 1257), control switch HIS1105.

2.

P8-2 is povered from MCC F12B (BF 1257), control switch HIS1107.

3.

The control svitches may be placed in lockout positions.

ATTACHMENT 2 Page 11 of 24 I

l l

l Hazardous Chemical and 35 HS-EP-02850 l

R0 Oil Spills SPILL PREVENTION CONTROL AND COUNTERMEASURE (SPCC) PLAN (Cont.)

Oil Locations and Oil Spill Diagnosis and Response (Cont.)

2.2.3 Discussion i

The Diesel Fire Pump Day Tank may be filled with the use of l

the Diesel Oil Transfer Pumps P8-1 and P8-2.

The Diesel l

Fire Pump Day Tank (capacity 350 gallons) is designed so in the event of a leak or rupture the retaining curb around the tank vill contain any accumulated oil.

2.3 Emergency Diesel Generator (EDG) Day Tank (s) Leak / Rupture l

2.3.1 Symptoms 011 accumulation within a Diesel Generator Day Tank Area 2.3.2 Specific Action In the event of a rupture in the Day Tank (s) 1-1 or a.

1-2, respectively:

1.

Stop EDG Fuel Oil Storage Tank 1-1 Transfer Pump P195-1 vith local breaker BE1298 (MCC E12F) 2.

Stop EDG Fuel Oil Storage Tank 1-2 Transfer Pump h

P195-2 vith local breaker BP 1230 (MCC F12A) b.

Use portable pumping equipment to pump the fuel oil from Oil Interceptor 85 directly into vaste oil containers / drums.

2.3.3 Discussion Due to special seismic construction in the area where a.

the Diesel Generator Day Tanks are located, a rupture is very unlikely. Any fuel oil accumulated from leaks in the Day Tanks (total capacity 12,000 gallons),

Diesel Generators, or associated piping are removed by the floor drains to the storm sever system via Oil Interceptor $5, which has an oil storage tank capacity of 250 gallons. Refer to Attachment 1, 1.4.3 for further actions in the event the oil interceptor storage tank overfills.

b.

In the event of a rupture, any oil that is pumped to the Transf>rmer Collection Tank can be removed to vaste oil containers / drums.

2.4 Emergency Diesel Generator (EDG) Fuel Oil Storage Tank Leak / Rupture 2.4.1 Symptoms Oil accumulation on the ground in the vicinity of the Emergency Diesel Generator Fuel Oil Storage Tanks.

ATTACHMENT 2 Page 12 of 24

i Ha:ardous Chemical and 36 HS-EP-02850 R0 Oil Spills

-s SPILL PREVENTION CONTROL AND COUNTERMEASURE (SPCC) PLAN (Cont.)

Oil Locations and Oil Spill Diagnosis and Response (Cont.)

2.4.2 Specific Action Utilize all means available to keep oil away from Catch a.

Basin 17 (located just south of the tanks), and Collection Box 32 (located off the Northwest Corner of the tanks).

b.

Observe the pond by the Davis-Besse Training Center for evidence of oil. Contain oil in the pond by closing the flapper gates, using oil booms which are available in the CVSA general spill kit and contacting Environmental Compliance.

c.

Isolate the tank from the system.

\\

2.4.3 Discussion Each tank has a 40,000 gallon capacity. If a rupture or leak occurred below the level of liquid, the fuel oil vould leak into the ground, requiring extensive cleanup. Local level indicators (analog meters) are located adjacent to the filling point for each tank. Input for each indicator is received from a capacitance probe that is located within the

' (-

tank (Indicator LI 4891 receives input from probe in Tank i

T153-1; Indicator LI 4892 receives input from probe in Tank T153-2). The indicator registers from 30,000 gallons (0%)

to 40,000 gallons (100%) on an inverse Icgarithmic scale, vith a high level local alarm light setpoint of 39,850 gallons and a lov level local alarm light setpoint of 38,000 gallons. Periodic monitoring of tank inventories and close

~

monitoring of fuel oil levels during filling procedures should prevent overfills from occurring.

2.5 Miscellaneous Diesel Generator Day Tank Leak / Rupture 2.5.1 Symptoms Oil accumulation within Room #308, Miscellaneous Diesel l

Generator Day Tank Room.

2.5.2 Specific Action Operations is notified that a High/Lov Oil Level Alarm a.

has been received from the Miscellaneous Diesel Day j

Tank.

b.

Verify if there is (or is not) a tank leak / rupture.

IF a tank leak / rupture exists, close Isolation Valve DO c.

(-'

TI2, Miscellaneous Diesel Day Tank Isolation Valve, in the Miscellaneous Diesel Day Tank Room, ATTACHMENT 2 Page 13 of 24 i.

Hazardous Chemical and 37 HS-EP-02850 R0 Oil Spills SPILL PREVENTION CONTROL AND COUNTERMEASURE (SPCC) PLAN (Cont.)

Oil Locations and Oil Spill Diagnosis and Response (Cont.)

d.

THEN stop the Diesel Oil Transfer Pumps, P8-1 and F8-2, if they are running.

1.

F8-1 is povered from MCC E12B (BE 1257), control switch HIS 1105.

2.

PB-2 is povered from MCC F12B (BF 1257), control switch HIS 1107.

3.

The control switches may be placed in lockout positions.

2.5.3 Discussion a.

The Miscellaneous Diesel Day Tank Room is a retaining structure with no floor drains that vill easily contain the contents of the 740-gallon Capacity Tank.

b.

Valve D0 112 is normally closed, and should be opened only when filling the Miscellaneous Diesel Day Tank, Normally the tank is gravity-filled from the Diesel c.

Oil / Diesel Fuel Storage Tank.

2.6 Turbine-Generator (T-G) Lube Oil Storage Tank Leak / Rupture 2.6.1 Symptoms e

Oil accumulation within the T-G Lube Oil Tank Room 2.6.2 Specific Action Stop the Lube Oil Storage Room Sump Pumps 1-1 and 1-2 a.

by deenergizing the breakers at MCC E33B (BE 3366) for Sump Pump 1-1 and F33B (BF 3366) for Sump Pump 1-2.

b.

If a temporary pump is in the sump, ensure the pump is also shut off.

2.6.3 Discussion Any oil accumulation from a leak or rupture in the T-G Lube Oil Tank Room or the Lube Oil Storage Tank Room vill drain into the Lube Oil Storage Tank Room Sump. The sump discharges to the storm sever via Oil Interceptor #1, which has an oil storage tank capacity of 250 gallons. By stopping the Lube Oil Storage Tank Room Sump Pump 1-1 and 1-2 at MCC E33B (BE 3366) for Pump 1-1 and MCC F33B (BF 3366) for Pump 1-2, the accumulated oil vould be contained in the Lube Oil Storage Tank Room, thus preventing any oil from reaching the storm sever system. In the event the oil interceptor storage tank is overfilled, refer to Attachment 2, 1.4.3 for further actions.

ATTACHMENT 2 Page 14 of 24

i o

Hazardous Chemical and 38 HS-EP-02850 R0 Oil Spills SPILL PREVENTION CONTROL AND COUNTERMEASURE (SPCC) PLAN (Cont.)

Oil Locations and Oil Spill Diagnosis and Response (Cont.)

2.7 Lubricating Oil (LO) Storage Room Tank Leak / Rupture 2.7.1 Symptoms Oil accumulation in the LO Storap Tank Room 2.7.2 Specific Action l

Stop the LO Storage Room Sump Pumps 1-1 and 1-2 by a.

deenergizing the breakers at MCC E33B (BE 3366) for i

Sump Pump 1-1 and F33B (BF 3366) for Sump Pump 1-2.

b.

If a temporary pump is in the sump, ensure tha pump is also shut off.

j 2.7.3 Discussion Any oil accumulation from a leak or rupture in the T-G LO Tank Room or the LO Storage Tank Room vill drain into the Lo Storage Tank Room Sump. The sump discharges to the storm sever via Oil Interceptor #1, which has an oil storage tank capacity of 250 gallons. By stopping the Lo Storage Tank i

O' Room Sump Pump 1-1 and 1-2 at MCC E33B (BE 3366) for Pump i

l 1-1 and MCC F33B (BF 3366) for Pump 1-2, the accumulated oil vould be contained in the LO Storage Tank Room, thus preventing any oil from reaching the storm sever system. In

. j the event the oil interceptor storage tank is overfilled,

-l refer to Attachment 2, 1.4.3 for further actions.

]

2.8 Main Feed Pump Turbine (MFPT) Lubricating 011 (LO) Tanks or MFFT Used LO Tank Leak / Rupture 2.8.1 Symptoms I

011 accumulation in MFFT LO Tank pit.

2.8.2 Specific Action a.

Stop Coadenser Pit (vest) Sump Pumps by opening the breakers at MCC E32B (BE 3289) for Sump Pump 1-1A and j

F32B (BF 3289) for Sump Pump 1-1B.

i l-b.

If there is a temporary' sump pump installed in the Vest Condenser Pit used to pump to the East Condenser Pit, ensure the temporary pump is also shut off; it vill-be povered via a lead cord from a nearby 110V receptacle.

2.8.3 Discussion Any oil leaks from the MFPT LO Tanks #1 and/or #2 or a.

Used MFPT LO Tank vill accumulate in the MFFT LO Tank Pit. The Pit has drain plugs in place to prevent oil ATTACHMENT 2 Page 15 of 24 I-

I' s

Hazardous Chemical and 39 HS-EP-02850 R0 Oil Spills SPILL PREVENTION CONTROL AND COUNTERMEASURE (SPCC) PLAN (Cont.)

Oil Locations and Oil Spill Diagnosis and Response (Cont.)

and liquid draining to the West Condenser Pit Sump through the floor drains. The sump level is automati-cally controlled by Sump Pumps 1-1A and 1-1B, which discharge to the storm sever via Oil Interceptot "?.

which has an oil storage tank capacity of 250 gallons.

In the event the oil interceptor storage tank is overfilled, refer to Attachment 2,1.4.3 for further actions.

b.

In the event of a large rupture in the MFPT LO Tanks (1200 gallons each), or the MFPT Used LO Tank (2800 gallons), stopping Condenser Pit (West) Sump Pump 1-1A at MCC E32B (BE 3289) and for Sump Pump 1-1B, MCC F32B (BF 3289) vill cause the following events to occur:

1.

Oil level in the sump vill reach a High level.

2.

High oil level vill start the Condenser Pit Flood Pump 1-1, which discharges to the settling basin.

2.9 Main Transformer Leak / Rupture 2.9.1 Symptoms Oil accumulation within the Main Transformer retaining structure and Transformer Collection Tank.

2.9.2 Discussion In the event of a rupture in the Main Transformer, which contains 24,000 gallons of oil, the retaining structure vill collect the leaking oil and drain into the Transformer Collection Tank, which has a capacity of 54,600 gallons.

This vill prevent oil from reaching any waterway.

Station personnel should notify TE Power Systems for possible reclaiming of oil from the Transformer Collection Tank.

2.10 Auxiliary Transformer Leak / Rupture 2.10.1 Symptoms Oil accumulation within the Auxiliary Transformer retaining structure and Transformer Collection Tank.

till ATTACHMENT 2 Page 16 of 24

J e

Hazardous Chemical and 40 HS-EP-02850 RO Oil Spills V

SPILL PREVENTION CONTROL AND C0UNTERMEASURE (SPCC) PLAN (Cont.)

Oil Locations and Oil Spill Diagnosis and Response (Cont.)

2.10.2 Discussion In the event of a rupture in the Auxiliary Transformer, which contains 4,600 gallons of oil, the retaining structure vill collect the leaking oil and drain into the Transformer Collection Tank, which has a capacity of 54,600 gallons.

This vill prevent oil from reaching any vaterway.

Station personnel should notify TE Power Systems for possible reclaiming of oil from the Transformer Collection Tank.

2.11 Startup Transformer 01 Leak / Rupture 2.11.1 Symptoms Oil accumulation within the 01 Startup Transformer retaining structure and Transformer Collection Tank.

2.11.2 Discussion In the event of a rupture in the 01 Startup Transformer, O.

which contains 4,750 gallons of oil, the retaining structure vill collect the leaking oil and drain into the Transformer Collection Tank, which has a capacity of 54,500 gallons.

This vill prevent oil from reaching any vatervay.

Station personnel should notify TE Power Systems for possible reclaiming of oil from the Transformer Collection Tank.

2.12 Startup Transformer 02 Leak / Rupture 2.12.1 Symptoms Oil accumulation within the 02 Startup Transformer retaining structure.

l 2.12.2 Discussion In the event of a rupture in the 02 Startup Transformer, which contains 4,750 gallons of oil, the retaining structure vill contain the leaking oil, preventing oil from reaching any watervay.

2.13 Bus Tie AC or BD Transformer Leak / Rupture 2.13.1 Symptoms l

011 accumulation within the affected Bus Tie Transformer Retaining Structure and Transformer Collection Tank.

l ATTACHMENT 2 Page 17 of 24

I i

l l

Hazardous Chemical and 41 HS-EP-02850 R0 Oil Spills SPILL PREVENTION CONTROL AND COUNTERMEASURE (SPCC) PLAN (Cont.)

Oil Locations and Oil Spill Diagnosis and Response (Cont.)

2.13.2 Discussion In the event of a rupture in the AC or BD Bus Tie Trans-former, each of which contains 1,926 gallons of oil, the l

retaining structure vill collect the leaking oil and drain into the Transformer Collection Tank, which has a capacity of 34,600 gallons. This vill prevent oil from reaching any waterway. Station personnel should notify TE Power Systems for possible reclaiming of oil from the Transformer Collection Tank.

2.14 Electro-Hydraulic Control (EBC) System Leak or Tank Leak / Failure 2.14.1 Symptoms For a leak, perform a visual inspection.

2.14.2 Specific Actions Operations performs those actions required by alarm a.

procedures.

b.

Identify and cover floor drains in the area of the spill.

Dike and protect grating area near EHC Sump on 585' c.

Level.

d.

Soak up spilled material with clay, savdust, kitty-litter, or fuller's earth, Flush spill area vith detergent and water.

e.

2.14.3 Discussion The EHC system provides hydraulic pressure to operate the turbine valves, turbine stop and control valves, and combined intermediate valves. Because of the high temperature involved, normal hydraulic fluid vould pose a fire hazard. To avoid this, the EHC system utilizes "Fyrquel - EHC" as an operating medium. Fyrquel - EHC has an open cup flash point of 455'F and is a Tri-Aryl Phosphate Ester. The material is not corrosive to glass or metals, but vill soften and deteriorate plastics and elastomers.

The product is not considered a hazardous vaste and is not regulated by the EPA. Vear suitable protective clothing to prevent skin and eye contact.

2.15 Lubricating 011 Drum Storage Room 2.15.1 Symptoms l

Oil accumulation within the Drum Storage Room.

ATTACHMENT 2 Page 18 of 24 l

l-u j

I Hazardous Chemical and 42 HS-EP-02850 R0 l

011 Spills SPILL PREVENTION CONTROL AND COUNTERMEASURE (SPCC) PLAN (Cont.)

t Oil Locations and Oil Spill Diagnosis and Response (Cont.)

2.15.2 Specific Action i

Plug / patch or overpack the leaking container, if possible.

The drain located in the room has been closed permanently, therefore, no actions are required to keep the oil away from the drain.

f 2.15.3 Discussion A maximum of twenty-two (22) 55-gallen drums of oil can be stored on their sides in racks. Site glasses / tubes which can be used to determine drum contact level and an outlet

[

are located at the bung openings. The room has a retaining curb located inside the door to prevent oil from spreading out of the room.

i 2.16 PSF 2000-Gallon vaste Oil Storage Tank Rupture 2.16.1 Symptoms Rapid lowering of tank level as indicated on Petrometer a.

level indicator located on vall inside door 365B.

O l

b.

Gradual lovering of tank level as indicated by inventory control methods.

l 2.16.2 Specific Action a.

Block oil outlet from oil interceptor.

b.

Pump out vaste oil remaining in tank.

c.

Excavate tank to determine condition and remedial i

l action.

1 2.16.3 Discussion Twenty-one floor drains throughout the PSF feed a gravity-fed cast iron oil interceptor located just inside and north of the roll-up door on the east vall of the PSP. Oil c

run-off from this oil interceptor goes to a 2000-gallon vaste oil storage tank located just outside the east vall of l

l the PSF, online with the oil interceptor. The 2000-gallon tank is UL listed,' constructed of Fiberglas, installed l.

below-ground, and carries a 30 year varranty from the date t

of purchase (1987). Total failure is unlikely. See SSOE l

drawings M-1550 and 1551 for SSOE project number 84816.

O ATTACHMENT 2 l

Page 19 of 24

.. ~

'i Hazardous Chemical and 43 HS-EP-02850 R0 Oil Spills O

SPILL PREVENTION CONTROL AND COUNTERMEASURE (SPCC) PLAN (Cont.)

Oil Locations and Oil Spill Diagnosis and Response (Cont.)

l NOTE 2.17 l

1 l

l l

The containment vessel is not accessible during plant l l

l operation, therefore entry for inspection / verification l l

purposes is not possible.

l l

l______________________________I l

2.17 Lubricating 011 Spill Vithin the Radiological Control Area (RCA) f 2.17.1 Symptoms 011 accumulation on floor of containment or other locations within the RCA, such as adjacent to reactor coolant pumps (RCP), oil drums, etc.

l 2.17.2 Specific Actions If abnormal conditions exist for the RCPs, the a.

appropriate abnormal operations procedures shall be initiated.

b.

For other oil leaks / spills within the RCA, contain with absorbent materials or booms.

2.17.3 Discussion Each RCP has a lubricating oil reservoir consisting of a.

two sumps, one upper (capacity 200 gallons) and one lower (capacity 25 gallons). RCP 1-1-1 (P36-1) and 1-1-2 (P36-2) oil drains into RCP Motor Oil Drain Tank 1-1-1 (T-156-1) (capacity 250 gallons). RCP 1-2-1 (P36-3) and 1-2-2 (P36-4) oil drains into RCP Motor Oil Drain Tank 1-1-2 (T-156-2) (capacity 250 gallons).

Both drain tanks are designed to completely contain both RCP oil reservoirs sumps and are equipped with a manual level indicator. The drain tank levels are checked when containment entry is possible.

1 b.

Various pumps and equipment located in the RCA may contain small amounts of lubricating oil. Any of this oil, if spilled, vould accumulate in the area of the equipment or flov to a floor drain which is connected to the Miscellaneous Liquid Radvaste System. ALARA precautions and RC procedures shall be followed in the RCA in addition to other stated cleanup methods of an oil spill.

O ATTACHMENT 2 Page 20 of 24

t l

4 t

4 Hazardous Chemical and 44 HS-EP-02850 R0 j

Oil Spills O

SPILL PREVENTION CONTROL AND COUNTERMEASURE (SPCC) PLAN (Cont.)

f oil Locations and Oil Spill Diagnosis and Response (Cont.)

l 2.18 DBAB Emergency Diesel Generator (EDG) Day Tank Rupture f

2.18.1 Symptoms l

011 accumulation within the Diesel Day Tank room or flow

~

under building door to ground outside.

i ii 2.18.2 Specific Actions i

Pump out the remaining diesel fuel to an appropriate a.

storage container.

b.

Contain the oil usin; booms.or other absorbent material.

2.18.3 Discussion The DBAB EDG Day Tank (capacity 300 gallons) is constructed with an inlet /isolatioa valve (D-01) from the DBAB EDG Fuel 1

~

011 Storage Tank, an 8,000-gallon tank. The tank is equipped with a manual level gauge.

2.19 DBAB Emergency Diesel Generator (EDG) Fuel Oil Storage Tank Rupture j

,- l 2.19.1 Symptoms j

l l

a.

Loss cf diesel fuel oil as indicated by manual tank gauge readings.

i b.

Accumulation of oil on surface of Cooling Tower Pond i

9.

2.19.2 Specific Actions Pump out the remaining diesel fuel to an appropriate a.

storage container.

b.

Contain the oil using booms or other absorbent material.

2.19.2 Discussion The DBAB EDG Fuel Oil Storage Tank (Capacity 8,000 gallons) is an underground storage-tank constructed of fiberglass reinforced plastic vith no internal tank protection and piping.is of bare steel (no cathodic protection).

O

-ATTACHMENT 2 Page 21 of 24

~. _.. _.,, _ _,. _. _. _. ~ _. _. _ _..,. _. _ _.. ~. _. _. _

'l Hazardous Chemical anc 45 HS-EP-02850 R0 Oil Spills SPILL PREVENTION CONTROL AND COUNTERMEASURE (SPCC) PLAN (Cont.)

Oil Locations and Oil Spill Diagnosis and Response (Cont.)

2.20 Fuel Tanks Located At Service Building 4 2.20.1 Symptoms Diesel fuel and/or gasoline accumulation within the concrete dike surrounding the fuel tanks.

2.20.2 Discussion The diesel fuel storage tank (capacity 1,000 gallons) and gasoline storage tank (capacity 2,000 gallons) are contained in a concrete retaining structure. This structure is designed to contain the total volume of both tanks plus an additional 15% capacity for precipitation and fire water.

Periodically, the diked area / structure is checked and any accumulated liquid is removed to the appropriate vaste druni.

l NOTE 2.21 l

1 I

The Chemical Vaste Storage Area (CVSA) is located l l

a.

l outside of the Protected Area northeast of the l

l Switch Yard.

l l

b.

Two of the Chemical Vaste Accumulation Areas l

I (CVAAs) are located at the following areas:

l l

1)

Self-contained storage building adjacent to l l

the north Train Bay Door of the Turbine l

l Building, within the Protected Area l

l 2)

Self-contained storage building adjacent to l l

the paint / sandblast / veld shops (Butler l

l Buildings) l l_ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _I 2.21 Vaste Diesel Fuel /0il in Containers at the Chemical Vaste Storage Area and Chemical Vaste Accumulation Areas 2.21.1 Symptoms Oil accumulating within the curbed, concrete pad, a.

self-contained building, or gcound surface of the CVSA or the CVAAs.

b.

Oil overflowing the curb or containment part of the building and accumulating on the gravel, stone, asphalt, grass, or other ground surfaces surrounding the CVSA or CVAAs.

O ATTACHMENT 2 Page 22 of 24

i J i

l I

Hazardous Chemical and 46 HS-EP-02850 l

RO l

Oil Spills

{

SPILL PREVENTION CONTROL AND COUNTERMEASURE (SPCC) PLAN (Cont.)

Oil Locations and Oil Spill Diagnosis and Response (Cont.)

f 2.21.2 Specific Action Use any equipment available, such as absorbents, oil a.

booms, and sand bags, to minimize the leak and contain j

l the spill.

b.

Contact the EC Supervisor if any leaking or spilled diesel fuel / oil drums are found at the CVSA or CVAAs.

l

-l 2.21.3 Discussion The station is equipped with retention areas and oil a.

interceptors to contain any oil spills. The oil i

interceptors should be utilized in the event of a large oil spill or leak from 55-gallon drums at the CVAAs.

j b.

Any oil leak or spill from 55-gallon drums at the CVSA is contained in the ctrbed concrete pad. Oil should be removed, thus preventing eventual accumulation to a volume that could enter the nearby drainage ditch which O

drains to the Marsh Area.

2.22 Equipment Containing PCB Dielectric Fluid a

2.22.1 The following equipment contains polychlorinated biphenyl (PCB) dielectric fluid:

Equipment No.

Serial No.

Location Transformer 2 Vestinghouse TAV7035-02 Between Service Building 2 & 3 Transformer 8' G 859852A Vest of Radvaste Building and adjacent to east side of small blue shed containing a transformer 1

8These transformers vill be retrofilled in 1991 and 1992.

l

!O

. ATTACHMENT 2 Page 23 of 24 l

~

1 Hazardous Chemical and 47 HS-EP-02850 RO Oil Spills O

SPILL PREVENTION CONTROL AND COUNTERMEASURE (SPCC) PLAN (Cont.)

l Oil Locations and Oil Spill Diagnosis and Response (Cont.)

2.22.2 Many of the larger pumps, i.e. Circulating Vater Pumps and j

Condensate Vater Pumps, have been found to contain PCB capacitors. Currently, it is unknown if the other pumps of this size or larger contain PCB capacitors. Therefcre, it is prudent to assume the capacitors are PCB in a spill situation until determined otherwise. This equipment includes the following Circulating Vater Pumps (CVP) motor capacitors except a.

CVP #3 i

i i

b.

Condensate Pumps motor capacitors except pump 1-1 l

c.

Reactor Coolant Pump motor capacitors l

d.

Service Vater Pump motor capacitors Component Cooling Pump motor capacitors e.

1 l

0 ATTACHMENT 2 Page 24 of 24

l Hazardous Chemical and 48 HS-EP-02850 R0 Oil Spills

)

SPILL NOTIFICATION FORM (ED 7892) u,- -

1

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._- =,

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A SMLL 58FOfMSATON

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STATUS AT TDE OF NOTFICATON TO ENVrOeseteTAL COesPUANCE SC SUPENISOR (SEAfE)

DATE PHONE i

E OseWTEte0Trt Afmes PEMBON CONTACTED DATE Tag psmALS 1 ON-CALL OPERAT90N5 $UPERlWTDOENT 10N-CALL 60ANTEMApG EPEPINTIMDENT

3. on-CALL $Ar8Tr/

EMNAL SWPSBT!some 4 ON-CALL $$IERI AL $MNAQR CONT. SERvtCE RADIOLOGICAL I CONTROLS SUPERYt50R

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C. AS-4EEDED peOTIRCATIOseS 1 CHEAASTRY E Fuf efuMDE

& NUCLEARDOuST984LGAFETY ANDHYGedE eeJCLEAR REGULATORT CosMI5510N

FOR 10 CFR 50.72 (b) 4-tit. RPT.

,m searEmeoaco==wsToemsu Emison l

eCe arE=oon co=uns eAnT e ATTACHMENT 3 Page 1 of 2

h I

Hazardous Chemical and 49 HS-EP-02850 RO Oil Spills O

SPILL NOTIFICATION FORM (ED 7892) (Cont.)

El pk.n esCATION Kmmi Paaraor enn e seu ismmCaTtom w rTo n.

sme.s = am ais e _i A.

Spa.L per_ __ TION 1 As - _ _ :Isosa SnfR Superwtaar) w oF snrf suetavmon acromesa oAu Ano Test Cmmo a====

oarr ne rnar ooCOeco o.Tt Ana w secun ewoe oceAr w m seu.conunev. w BOURCE 4 8eATURE OF SPELL LOCATioM OF Spu esimaano votuus a mTom OF seu

,. met seusogm i

WEANER CON 3 MONS

.ovewwrcrseu reasoaseLO=eneut rr A/oa osm; wannaars mecTso uux,escTro CORFECIWE ACTONS TaEEN-ST ATUE AT YtdE OF ocTFEATON mm CONTACTED DATE 11hf N

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DATE Tem ervants C. CM'PWTE secrTreCATIDss t STATE OF t>c *esssoasWrat suc1cflam asescv mnum verwuATON OF =4 fu.nrs ATION TO artAn ewnasev mospouss -

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2. LpfTED STATES ConsT OumfD 1

L PINAL STATUS OF EVENT Feent ST ATus aaouc neCcuraco Awxm Lost Anover sauso l

Acxrft on c>eoeC HEALD R$f:S RCRA MZAFOous vsASTE CERCLA 80

$AAA - SC cwa CDWTFLAATON S>EETS ATTACMEDT l

DATE l

POftW CDIs'L1'ED BY O vrs O se ATTACHMENT 3 Page 2 of 2 l

l Hazardous Chemical and 50 HS-EP-02850 R0 Oil Spills S?ILL NOTIFICATION CONTINUATION SHEET (ED 7892A)

THE TOLEDO EDtSON COMPANY SPILL NOTIFCATION. CONTINUATION SHEET

$wfET ED 7892A 1 y

DATE OF SPILL IDENTIFY PAftT AND SECTION OF FORM CONTAINED ON THESE &HEETE.

$IGN AND DATE EACH ITEW LISTED ON THE SHEET.

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ATTACHMENT 4 Page 1 of 1

4 l

1 Hazardous Chemical and

$1 HS-EP-02850 Oil Spills R0 C-1 J LOCATIONS OF SPILL CONTROL EOUIPMENT f

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Hazardous Chemical and 53 HS-EP-02850 RO l

l Oil Spills DECONTAMINATION AREA ESTABLISHMENT AND METHODS I

I l

CAUTION 1.0 l

l i

l No eating, drinking or smoking /cheving shall be l

l allowed within the Hot or Varm Zones of the spill l

l l

area.

l l

1.0 Establishment of the Decontamination Area 1.1 Location 1.1.1 The decon area shall be set up at the entry / exit to the Hot Zone but within the Varm Zone. The entry / exit point of the spill area shall be upvind of the spill. The decon area shall be set up on a level surface to prevent any decon j

liquids from spreading outside of the decon area.

i i

l l

1.2 Equipment 1.2.1 The decon area shall consist of visqueene, decon pool (s),

step off pad (s), and drum (s) for contaminated personal protective equipment (PPE).

1.2.2 Decon equipment that shall be available for use include the decon solution (see 1.2.3), hand sprayer (s) for decon solution, brushes, sponges, rags, clean PPE, and plastic bags for temporarily holding contaminated equipment prior to deconning.

1.2.3 Decon solutions should react mildly to neutralize the contaminants from the spill. If the spilled material is unknown a general decon solution may be used. Hovever, this should be tested on a small area to ensure that a worse condition is not created. Listed belov are spilled materials with the suggested decon solution. Following this list is the actual content of each decon situation.

Decon Solution Spilled Material (See Table Below)

A Inorganic acids Heavy metals (i.e. mercury, lead, cadmuim, etc.)

l Pesticides, fungicides, herbicides B

Chlorinated phenols, dioxins, PCBs, Cyanides Ammonia and other nonacidic inorganic wastes O.

ATTACHMETE 7 Page 1 of 5 l

i

I

.)

Hazardous Chemical and 54 HS-EP-02850 i

RO O

1 011 Spills DECONTAMINATION AREA ESTABLISHMENT AND METHODS (Continued)

Decon Spilled Material Solution l

(See Table Below)

Solvents and organic compounds (i.e.

C

~

trichloroethylene, chloroform, toluene, PBBS, (or A) l t

and PCBs Oily, greasy unspecified vastes C

l D

l Inorganic bases l

Alkali and pH basic waste General cleaning, removal of previous hazardous E

decon solution (this method is preferred by EPA and should suffice in most cases) i Decon Solution Content f

A Solution contains 5% sodium carbonate (Na CO ) and 5% trisodium phosphate (Na

).

I To i gkilons water, add one pound of Na'

[

l (soda line) and 1 lb. Na,PO,. Stirunti I

evenly mixed.

B Solution contains 10% calcium hypochlorite (Ca(Clo) ).

To 2 gallons water, add 2 lbs.

Ca(Clo),,. Stir with wooden or plastic stirrer until evenly mixed.

i C

Solution contains 5%. trisodium phosphate (Na PO To 2 gallons water, add 1 lb. of Na,k'.). Stir until evenly mixed.

I I

i l

CAUTION SOLUTION D l

l l

I

]

Concentrated hcl is very corrosive.

l I

I D

Dilute solution of hydrochloric acid (hcl).

To 2 gallons water, slowly add one-third (1/3) cup concentrated hcl. Stir with wood or plastic stirrer.

E Solution contains dishwashing liquid or other O

household detergent such as Tide.

ATIACHMENT 7 Page 2 of 5 i'

1 Hazardous Chemical and 55 HS-EP-02850 RO Oil Spills O,

DECONTAMINATION AREA ESTABLISHMENT AND METHODS (Continued) 1.3 Decon Area Activation The Decon Area shall be activated upon determination that the spilled materials warrant use of decon solutions. The Decon Area shall be initially activated prior to entry of the first team and equipment into the Hot Zone of the spill area. The individual (s) working in the decon area must be HAZWOPER trained and as few as one person can make up the decon team.

l CA1TfION 2.0 l

l l

l Prioritize contaminated personnel as follows:

l l

1.

Damaged suits /PPE, internal contamination of l

l person, injured personnel, or person with low air l l

l SCBA.

l 2.

Person with least contaminated exterior surface l

l of suit /PPE.

l l

3.

Person with most contaminated exterior surface l

l of suit /PPE.

l l_ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _l 2.0 Hazardous Substances Decontamination Methods 2.1 Emergency Decontamination 2.1.1 Emergency decon consists of the immediate removal of contamination from personnel without using : formal decon methods.

2.1.2 The primary concerns for emergency decon are:

Preventing nore severe injuries a.

b.

Preventing loss of life Preventing heat stress which could lead to more severe c.

heat-related conditions or injuries 2.1.3 For person with life-threatening condition, medically treat first until stabilized then decontaminate.

2.1.4 For high contaminant exposure / injury risk to person, decontaminate first then medically treat.

2.1.5 For slightly injured person and if the victim can wait a short time, decontaminate first then treat.

2.2 Primary Decontamination 2.2.1 Primary decontamination is the initial decon of personnel on the scene as they are exiting the Hot Zone of the spill area.

ATTACHMENT 7 Page 3 of 5

Ha::ardous Chemical and 56 HS-EP-02B50 C-)

DECOtEAMItaTICN AREA ESTABLISHME2Tr AND METHODS (Continued) 2.2.2 HAZWOPER trained personnel acting as the decon team shall use the same level of PPE as the personnel within the Hot Zone unless determined that a lower level of PPE is acceptable.

2.2.3 Personnel exiting the Hot Zone shall:

Place any contaminated equipment in a plastic bag for a.

cleaning after decon of person.

b.

Step into first decon pool.

2.2.4

'Ihe decon team shall:

Use decon solution and rub on suit from head to toe a.

with sponge or cloth; use brush on boots only, rinse from head to toe with decon solution in hand sprayer.

b.

Have person being deconned lift one boot, rinse, and have person step into decon pool #2. Repeat with second foot.

In decon pool #2, use a soap solution to remove the c.

decon solution; follow same procedure as in 2.2.4.a above; rinse each boot last as person steps from pool onto clean visqueene.

2.2.5 Person exiting the decon pools shall remove PPE in following order and place in designated containers:

a.

Outer boots b.

Outer gloves c.

Tape d.

Suit with attached boot, roll inside towards outside Remove boot or suit with attached boot and place foot e.

on clean step-off pad f.

Repeat with other foot Remove inner gloves, if separate from suit g.

1 i

\\

ATTACHME!Tr 7 f

Page 4 of 5 I

Hazardous Chemical and 57 HS-EP-02850 RO Oil spills O

DECCtCAMINATION AREA ESTABLISHMENT AND METHODS (Continued) 2.3 Secondary Decontamination 2.3.1 secondary decon will consist of cleaning /deconning contaminated equipment, monitoring and inspecting PPE after primary decon to ensure it is free of contamination (except for disposable PPE).

2.3.2 If equipment /PPE is still contaminated, wash with the decon solution followed by the soap solution thoroughly rinse, and monitor / inspect for contamination.

2.4 Decontamination of Decon Personnel 2.4.1 Upon completion of decon of personnel exiting the Hot Zone, the decon personnel shall decon as follows:

Use decon pool with least level of contamination or use a.

new pool.

b.

Follow steps as outlined in 2.2.3 through 2.2.5.

O l

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O ATTACHMon 7 f

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Hazardous Chemical and 58 HS-EP-02850 R0 Oil Spills O

i SARA / CERCLA HAZARDOUS CHEMICAL LOCATIONS AND SPILL EVENT GUIDELINES

, Table of Contents i

Attachment 1.0 Hazardous Chemical Locations Page No.

l i

2 1.1 Inside Protected Area 3

1.2 Ovner-Controlled Area 2.0 Hazardous Chemical Spill Event Guidelines 5

l Ammonium Hydroxide (NH,OH)/ Morpholine / Amine Compounds 2.1 6-l 2.2 Chill Water (i.e. Nalco Sure-Cool 1355) 7 2.3 Circulating Water Conditioner (i.e. Nalco Sure-Cool) 7 2.4 Component Cooling Water (CCW) 8 i

2.5 Hazardous Waste - Solvents 9

l

+

2.6 Hydrazine (N,H,)

11 2.7 Hydrogen Peroxide (H,0,)

11 2.8 Lithium Hydroxide (LiOH H,0) 2.9 Sodium Bisulfite, NaHSO, (i.e. Nalco 7408) 12 j

12 2.10 Sodium Hydroxide (NaOH) 14 l

2.11 Sodium Hypochlorite (NaOCL)

I 15 2.12 Sulfuric Acid (H,SO,)

2.13 Turbine Plant Cooling Water (TPCW) (i.e. Nalco Sure-Cool 1355 and biocide, i.e. Nalco 7330) 16 j

I 2.14 Offsite Release 'Ihat Results in Hazard to Station Operations 16 O

ATIACHMENT 8 i

I Page 1 of 17 l

Hazardous Chemical and 59 HS-EP-02850 R0 C-1 011 Spills O

[ start]

SARA / CERCLA RAZARDOUS CHEMICAL LOCATIONS AND SPILL EVENT GUIDELINES (Cont.)

1.0 Hazardous Chemical Locations 1.1 Inside Protected Area:

1.1.1 Approved (permanent or temporary) Chemical Waste Accumulation Areas 1.1.2 Chemistry Laboratories a.

603', southeast quadrant of Auxiliary Building, directly outside personnel hatch into containment structure and east of spent fuel pool b.

585', southwest quadrant of Turbine Building, Chemistry secondary plant processes sampling panel 1.1.3 Water Treatment Plant a.

Sodium Hydroxide (maximum: 16,000-gallon tank) 585',

located outside and directly north of Water Treatment Plant, inside containment pad b.

Sulfuric Acid (maximum: 20,000-gallon tank) 585',

located outside and directly north of Water Treatment i

Plant, inside containment pad c.

Sodium Hypochlorite (maximum: 7,500-gallon tank) 585':

IC-1 o Outside the northwest corner of Vater Treatment Plant, inside secondary containment dike f-l o Inside Water Treatment Plant, centrally located, at splitter box 0

Inside Water Treatment Plant, 603', on mezzanine between the chlorine detention tanks d.

Chemical Storage Room 585', on west side of Water Treatment Plant, ground level, between transformer room and chlorine feed room e.

Chemical Laboratory 565', in west side of Water Treatment Plant, bottom level, between freestanding domestic water pumps and demineralized water pumps 1.1.4 Turbine Building I

I a.

On east side of Train Bay 585*, west of recirculating water pumps Nalco Circulating Water Conditioner -

4,000-gallon (maximum) tank l

ATTACHMENT B Page 2 of 17 i

j 1

i HS-EP-02850 j

Hazardous Chemical and 60 R0 C-1

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SARA / CERCLA HAZARDOUS CHEMICAL LOCATIONS AND SPILL EVENT GUIDELINES (Cont.)

f b.

Chemical Feedwater Addition Area 585', west side of l

stator coolers and south side.of auxiliary boilers l

t Ammonium Hydroxide / Morpholine / Amine Compounds -

o 500-gallon (maximum) elevated tank..about 10 1-liter bottles for NH 0H, and 1 to 2 55-gallon l

t drums morpholine or selected amine compound l C -t j

Hydrazine - 500-gallon (maximum) elevated tank.

~

0 l

and about 2 30-gallon and/or 55-gallon drums Nalco corrosion inhibitor - 1 to 2 55-gallon drums O

Nalco algaecide - 1 to 2 55-gallon drums I

o

((-t j

Auxiliary Boiler Chemical Addition Package 1-1 606*,

c.

l upper part of Auxiliary Steam Boiler Room (through Door

}

l 439):

{

f Hydrazine gallon (maximum) elevated tank,

{.

8 t

western-most tank l

Ammonia gallon (maximum) elevated tank, l

o eastern tank Vest Condenser Pit Sump Area 567*

)

d.

West Condenser Pit Sump Area 567' (behind Door 201E) l U -I

\\

l 1 to 3 55 gallon drums of Hydrogen Peroxide

)

l 1.1.5 Service Building 6 - Painting Area i

1.1.6 Mixed Waste Storage Area, 585', outside and west of 1

i Auxiliary Building, east of Borsted Vater Storage Tank -

waste stored in 55-gallon drums inside yellow Lowest Specific Activity (LSA) boxes; area is roped and tagged RRA.

1.1.7 Auxiliary Building 585'. Anti-contamination clothing laundry unit in southwest quadrant of Train Bay - 1 to 3 l

30-gallon drums of halogenated solvent-1.2 Owner-Controlled Area:

1.2.1 Approved (permanent or temporary) Chemical Vaste I

Accumulation Areas 1.2.2 Warehouse a.

Z Building (all hazardous materials except battery acids) b.

Shed 2 Warehouse (all batteries: all battery acids) l l

ATTACHMENT 8 I

Page 3 of 17 l

l

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Hazardous Chemical and 61 HS-EP-02850 R0 C-1 Oil Spills O

SARA / CERCLA HAZARDOUS CHEMICAL LOCATIONS AND SPILL EVENT GUIDELINES (Cont.)

1.2.3 Training Center Labs - first floor. Training Center a.

Chemistry Lab - various chemical storage areas b.

Mechanical Lab - flammable cabinet c.

Metrology Lab - flammable cabinet (small) 1.2.4 Chemical Waste Storage Area 1.2.5 Wastewater Treatment Plant a.

Sodium Hypochlorite (maximum: 250 gallons) 5-gallon I C~ l carboys located approximately 15' outside the entrance to Wastewater Treatment Plant 1.2.6 DBAB and Annex Records Management Darkroom, first floor. DBAB, a.

southwest corner: Kodak film developing and cleaning chemical solutions b.

EC Onsite lab - DBAB Annex Room 162; flammable cabinet c.

NISH lab - DBAB Annex, Room 160; flammable cabinet j

i i

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ATTACHHENT B i

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Hazardous Chemical and 62 HS-EP-02850 011 Spills R0 C-1 l

SARA / CERCLA HAZARDOUS CHEMICAL LOCATIONS AND SPILL EVENT GUIDELINES (Cont.)

2.0 Hazardous Chemical Spill Event Guidelines 1

I l

NOTE 2.1 l

I I

l Selected amine compounds will be the chemicals l

l C-t l

routinely used; ammonium hydroxide will be used only l

l during system wet layups or at the discretion of l

l Chemistry.

l l_ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _I I

2.1 Ammonium Hydroxide (NH 0H)/ Morpholine / Amine Compounds 4

2.1.1 Symptoms a.

Chemical accumulation in the dike under Feed Water Chemical Addition Tanks T-49 (pH control tank 1-1) and T-50 (pH and/or dissolved oxygen control tank 1-2) containing the 500-gallon solution of ammonium hydroxide, morpholine, or amine compounds.

l b.

Chemical accumulation under/near Steam Generator 1-1 and 1-2 Wet Layup Chemical Addition Tanks 1-1 and 1-2, T139-1 and T139-2.

2.1.2 Specific Action a.

Isolate the West Condenser Sump by locking out pumps s

P-33A and P-33B, and lock out Ammonia feed pump P-34 g 'I (check spare pump P163 if in use).

b.

If tank T-49 is overflowing:

1.

Isolate CD-212 (condensate water inlet to tank) 2.

Close SC-30 SC-38, SC-105 (NH 0H and hydrazine 4

tanks cross tie) 3.

Verify that SC-28 and SC-34 are closed 4.

Lock out Flood Pump P174-1 i

c.

If the tank T-50 is overflowing:

1.

Isolate CD-211 (condensate water inlet to tank) 2.

Close SC-31, SC-37, SC-105 (tanks T-49 and T-50 cross tie) 3.

Verify that SC-29 and SC-35 are close 4.

Lock out Flood Pump P174-1.

d.

If chemical is leaking from either anti-siphon valve

(%

associated with each Steam Generator Wet Lay-up Chemical Addition Tanks 1-1 and 1-2:

ATTACHMENT 8 Page 5 of 17 i

1 Hazardous Chemical and 63 HS-EP-02850 R0 Oil Spills SAFA/CERCIA HAZAFIW3S CHEMICAL LOCATICNS AND SPILL EVDC GUIDELINES (Cont.)

1.

Check the valve lineups downstream of the tanks and ensure in correct position according to status of the plant, i.e. DB-OP-06903, Plant Shutdown and 1

Cooldown and/or DB-OP-06230, Steam Generator Secondary Side Fill, Drain and Layup.

2.

Dike around or cover floow drains in or adjacent to the spill area.

2.1.3 Discussion W e Morpholine /tEl OH/ Amine chemicals are used as pH a.

control of the fe b ter system. We 151 OH/ Morpholine /

Amine tank T-49 is located in the same dike structure as the Hydrazine/ Morpholine / Amine tank T-50.

We dike will contain about 5% of the total volume of both tanks. The tanks and dike are located on 585' level, Turbine Building, south of the Auxiliary Boiler Room, over grating. We level below, west condenser pit, 565' level, contains pumps where this material would accumulate. We material would be neutralized in the sumE. before releasing to the ponds / settling basins.

b.

W e Steam Generator 1-1 and 1-2 Wet Layup Chemical Addition Tanks (T139-1 and T139-2) are located in Mechanical Penetration Rooms 1 and 2 (Room #208 and 236), Level 565', respectively. m e tanks are designed to receive chemicals by a direct pour or by a semi-closed system, tygon tubing and hand pump. We chemicals used are annonium hydroxide, hydrazine, morpholone, or other amine compounds. he chemical level is made up to a maximum of 100 ppm. If a spill occurs the following rooms could also be affected with chemical vapors, Mechanical Penetration Rooms 3 and 4, Make-up Pump Room, the two Emergency Core Cooling System Pump Rooms, and the Decay Heat Exchanger Room.

W ese rooms all share a connon air supply and are all interconnected by the annulus and/or pipe chases.

Wese rooms can be purged of air contaminants by switching the Containment Purge Ventilation System over to the Mechanical Penetration Rooms.

2.2 Chill Water (i.e. Nalco Sure-Cool 1355) 2.2.1 Symptoms Leaks from Chill Water pipes or lifted relief valves a.

(PSV-5194, PSV-5196, PSV-5198).

b.

Unusually high demineralized water makeup.

G:

i ATIACHMDC 8 Page 6 of 17

Hazardous Chemical and 64 HS-EP-02850 R0 Oil Spills SARA /CERCIA HAZARDOUS CHEMICAL LOCATIONS AND SPIII EVDfr GUIDELINES (Cont.)

6 2.2.2 Specific Action l

a.

Collect leaking liquid directly into container which can then be emptied into Turbine Plant Cooling Water Low Level Tank (T-39).

b.

Check to determine if relief valves have been lifted.

Contact Chemistry to determine chemical content of c.

Chill Water System.

2.2.3 Discussion l

Chill water contains a Nalco corrosion inhibitor which is a personnel health hazard and also should not be released to floor drains. If the relief valves are lifted, leaking material that is not collected would flow to floor drains.

2.3 Circulating Water Conditioner (i.e. Nalco Sure-Cool) 2.3.1 Symptoms Chemical accumulation on floor in area of tank.

2.3.2 Specific Action a.

Cover the floor drains with sewer stoppers located in the Main Spill Kit.

b.

Contain the material with absorbent. Clean up and place in appropriate drunVcontainer.

Place completed label on containers describing, at a c.

minimum, contents, date of cleanup, department, and contact person.

2.3.3 Discussion l

he Nalco Circulating Water Conditioner material is contained in a 3985 gallon fiberglass upright tank sitting on a 4" concrete platforin. We tank is located on the east side of the Train Bay 585', Turbine Building. The tank is i

l located in close vicinity to floor drains.

I 2.4 Component Cooling Water (CCW) l 2.4.1 Symptoms Chemical accumulation in area of Chemical Pot Feeder 1-1 (T13) and/or Component Cooling (CC) Surge Tank (T12).

C)i Q

ATTACHMDC 8 Page 7 of 17

Hazardous Chemical and 65 HS-EP-02850 R0 Oil Spills SARA /CERCIA HAZARDOUS CHDiICAL IOCATIONS AND SPILL EVDC GUIDELINES (Cont.)

2.4.2 Specific Action a.

Check to determine if valves CCll4 and CCll5 are open when adding 35% N,H, to the Chemical Pot Feeder 1-1.

b.

Check to determine if any valves, including pressure relief valve CC 3602, are not in correct position during chemical addition to the CC Surge Tank.

2.4.3 Discussion One to two liters of 35% hydrazine (N,H ) solution are added to the Chemical Pot Feeder 1-1.

Demihefalizedwatercanbe added at this point to dilute the N H. From the Feeder the NH solution enters the CC Surge T$nk (tank capacity - 1800 gklion). WeNH solution ranges from 5-15 ppm. The Feeder and Surgh tank are Icecated in fan alley, level 623'.

Floor drains near the tank drain to the Miscellaneous Waste Drain Tank.

2.5 Hazardous Waste - Solvents 2.5.1 Symptoms Hazardous waste liquids accumulating around the base of the container / drum at a Chemical Waste Accumulation Area or the Chemical Waste Storage Area.

r 2.5.2 Specific Action Contain the material with absorbent and place leaking container in an overpack drum. Cleanup spilled material and place in container. Place label on appropriate containers as to contents, date of cleanup, department, and contact person.

2.5.3 Discussion a.

W e storage buildings for two of the CKAAs are self-contained units designed to hold approximately 350 gallons of leaking material in the spill pan. These buildings are located by the north train bay door, Turbine Building, and the sandblast / paint / weld shop butler buildings.

b.

In the Records Management Darkroom a spill kit is set up with a sewer stopper to cover the floor drain and absorbent material. We waste is contained in 30 gal.

plastic drums on rollers / wheels thus allowing visual inspection under the drums for accumulation of liquid.

l c.

We CWSA is a curbed concrete pad with a hazardous I

waste section separated by a curb from the unknown and l

nonhazardous waste sections. We curb is designed to ATIACHMDC 8 Page 8 of 17

Hazardous Chemical and 66 HS-EP-02850 l

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SARA / CERCLA RAZARDOUS CHEMICAL LOCATIONS AND SPILL EVENT GUIDELINES (Cont.)

contain 25% of spilled material when section is at storage capacity. The CVSA has a roof and sides therefore precipitation accumulation is minimal.

The CWSA is inspected weekly to ensure drum integrity and compatible wastes are in the correct sections. A drainage ditch is located east of the CWSA and has flapper gates which could be used in the case of a large spill.

WARNING 2.6 Hydrazine is considered to be a carcinogen, therefore exercise caution with this chemical.

2.6 Hydrazine (N H )

24 2.6.1 Symptoms a.

Chemical accumulation in the dike under the Feedwater Chemical Addition Tank (Feedtank T-50) containing the 500 gallon solution of hydrazine/ morpholine / amine compounds.

1 b.

Chemical accumulation at base of 30-gallon drums i

x containing 30Z hydrazine.

c.

Chemical accumulation at the base of the Steam Generator 1-1 or 1-2 Vet Layup Chemical Addition Tanks in Mechanical Penetration Rooms 1 and 2. respectively.

t WARNING 2.6.2 The hydrazine tank and drums are located on the floor

directly above the sump. Therefore, assess the area prior to entering to determine if PPE is necessary for personal safety.

l

\\

2.6.2 Specific Action a.

Isolate the West Condenser Sump by opening the breakers at MCC E32B (BE 3289) for Sump Pump 1-1A and F32B (BF 3289) for sump pump 1-1B).

And lockout hydrazine feed S'I pump P-35.

Check spare pump P163 if in use.

b.

If tank T-49 is overflowing:

1.

Isolate CD-212 (condensate water inlet to tank) g-'

(_/

i 2.

Close SC-30, SC-38 SC-105 (tanks T 49 and T-50 cross tie)

ATTACHMENT 8 Page 9 of 17 l

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Hazardous Chemical and 67 HS-EP-02850 R0 Oil Spills SARA / CERCLA HAZARDOUS CHEMICAL LOCATIONS AND SPILL EVENT GUIDELINES (Cont.)

3.

Verify that SC-28 and SC-34 are closed 4.

Lock out Flood Pump Pl74-1.

c.

If tank T-50 is overflowing:

1.

Isolate CD 211 (condensate water inlet to tank) 2.

Close SC-31, SC-37, SC-105 (tanks T-49 and T-50 cross tie) 3.

Verify that SC-29 and SC-35 are closed 4.

Lock out Flood Pump P 174-1.

d.

If chemical is leaking from either anit-siphon valve associated with each Steam Generator Vet Lay-up Chemical Addition Tanks 1-1 and 1-2:

1.

Check the valve line ups down stream of the tanks and ensure in correct position according to status of the plant, i.e. DB-OP-06903, Plant Shutdown and Cooldown and/or DB-OP-06230, Steam Generator Secondary Side Fill, Drain and Layup.

2.

Dike around or cover floor drains in or adjacent to the spill area.

e 2.6.3 Discussion a.

The N H tank is located in the same dike structure as the almbnium hydroxide / morpholine tank. The dike will contain about 5% of the total volume of both tanks.

W e tanks and dike are located on 585' level, Turbine Building, south of the auxiliary boiler room, over grating. We level below, west condenser pit, 565' level, contains a sump where this material would accumulate. W e material would be neutralized in the sump before releasing to the ponds / settling basins.

Caution must be exercised with this chemical in a spill area - it is considered a carcinogen.

b.

W e Steam Generator 1-1 and 1-2 Wet Layup Chemical Addition Tanks (T139-1 and T-139-2) are located in l

Mechanical Penetration Rooms 1 and 2 (Room 208 and 236), level 565', respectively. We tanks are designed to receive chemicals by a direct pour or by a semi-closed system, tygon tubing and hand pump. The i

chemicals used are amonium hydroxide, hydrazine, norpholine, or other amine compounds. We chemical level is made up to a maximum of 100 p;xn. Ir a spill occurs the following rooms could also be affected with chemical vapors, Mechanical Penetration Rooms 3 and 4, ATIACHMEtTI B Page 10 of 17 l

i 68 HS-EP-02850 Hazardous Chemical and RO C-1 011 Spills SARA / CERCLA HAZARDOUS CHEMICAL LOCATIONS AND SPILL EVENT GUIDELINES (Cont.)

Makeup Pump Room, the two Emergency Core Cooling System Pump Rooms, and the Decay Heat Exchanger Room. These rooms all share a common air supply and are all interconnected by the annulus and/or pipe chases.

These rooms can be purged of air contaminants by switching the Containment Purge Ventilation System over to the Mechanical Penetration Rooms.

2.7 Hydrogen Peroxide (H 0 )

22 l

I l

NOTE 2.7.1 l

~I l

HO is a potential fire combustible hazard if j

l conkaminatedwithforeignmaterial.

l 2

l_ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _l i

2.7.1 Symptoms Chemical accumulation on floor around the base of the containers / carboys.

i 2.7.2 Specific Action

?

(s_-

a.

Cover the floor drains with sewer stoppers stored in the spill kit near the 7.500-gallon sodium hypochlorite K-j tank adjacent to the WTP.

b.

Contain the material with absorbent and/or an overpack drum.

i c.

Clean up spilled material and place in appropriate container.

d.

Place completed labeln on containers describing, at a l

minimum, contents, date of cleanup, department, and

~

contact person.

2.7.3 Discussion l

One to three SS-gallon drums of hydrogen peroxide are stored in the Water Treatment Plant Chemical Storage Room or behind Ed i

Door No. 201E in the West Condenser Pit Sump Area 567'.

The chemical is used to neutralize hydrazine in the West Condenser Pit Sump.

2.8 Lithium Hydroxide (LiOH H O) l 2

2.B.1 Symptoms Leaking out of mix tank (T-8) on 585' level near spent fuel

(/j pool filter room.

l ATTACHMENT 8 Page 11 of 17 I

Hazardous Chemical and 68a HS-EP-02850 011 Spills R0 C-1 E 2.6.2 Specific Action Isolate MU-300 and MU-301 valves and lockout Lithium Hydroxide Chemical Addition Pump P-39.

2.8.3 Discussion Lithium hydroxide is used in the Reactor Coolant System (RCS) for pH control. The mixing tank (T-8) will contain 50 gallons of LICH H O solution. Any leaking material could 2

i ee l

i l

i h

l 1

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Hazardous Chemical and 69 HS-EP-02850 RO Oil Spills t

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SARA /CERCIA HAZARDOUS NDiICAL IDCATIONS AND SPILL EVDC GUIDELINES (Cont. )

go to the floor drains located in this area which are l

connected to the liquid radwaste processing system. Lithium hydroxide solution is also used to saturate the purification demineralizers.

l l

[

l CAUTION 2.9 l

I I

l Sodium bisulfite can liberate sulfur dioxide (SO ) gas l l

when in contact with strong acids. Both NaHSO lind l

l l

l SO, are irritants.

l l

l 2.9 Sodium Bisulfite, NaHSO, (i.e. Nalco 7408) 2.9.1 Symptoms Liquid accumulation at base or beneath chemical a.

porta-feed container.

b.

Residue or liquid accumulation at hose connections to porta-feed container or pump.

2.9.2 Specific Action a.

Isolate the pump and discharge line.

b.

Isolate the porta-feed container, Contain the spilled substance with absorbent material.

c.

Cleanup and place in appropriate drum / container.

2.9.3 Discussion The Nalco 7408 product is contained in a 400 gallon porta-feed unit which is set up on a skid at the base of the hill west of the welding training building. Nalco 7408 (contains about 40% sodium bisulfite) is used to eliminate free available chlorine from the station discharge. A feed line connected to the porta-feed unit is placed up the hill to the station collection box where Nalco 7408 is fed directly to the discharge via manual skid operation. This product was originally procured and placed at this location for chlorine discharge control for Zebra mussel mitigation. The Nalco 7408 dechlorination system can also be used during chlorination system transients or equipment failure.

2.10 Sodium Hydroxide (NaOH) 2.10.1 Symptoms Sodium hydroxide, 20% solution, accumulating in the following areas:

v ATIACIDE2C 8 Page 12 of 17

Hazardous Chemical and 70 HS-EP-02850 R0 Oil Spills SARA / CERCLA HAZARDOUS CHEMICAL LOCATIONS'AND SPILL EVENT GUIDELINES (Cont.)

i If acid and caustic storage tank pit outlet ball valve a.

VT-239 is open, accumulation vill occur in the small sump, 365' level, northwest corner of the Water Treatment Plant (VTP). The sump is pumped out by manually operating a temporary pump.

b.

If valve VT-239 is closed, accumulation vill occur in the dike containment surrounding the tanks.

VTP (large) Sump 1-1 high level alarm LAH-L898 in c.

Control Room (alarm on computer point L-898).

d.

Surrounding roadways / parking areas if tank puncture or rupture is high and liquid leaks past the containment structure.

2.10.2 Specific Action a.

If valve VT-239 is closed:

1.

Ensure the small sump has sump pumps turned on.

The sump has a manually operated temporary pump.

2.

Open ball valve VT-239 using the control lever to release a constant flow of liquid.

l 3.

Ensure flow is slow enough that the sump pumps can remove the Ifquid to the large sump before the small sump overflows.

4.

Liquid vill be pumped from small sump to large sump and neutralized before discharge to settling basins. Discharge from the settling basins is through the collection box.

VARNING 2.10.3 If NaOH and H SO are both released from their respectivestbrahetanks,thetwochemicalswill react violently, releasing large amounts of heat, energy, and toxic fumes.

2.10.3 Discussion Up to 16,000 gallons of NaOH (also known as caustic soda) at 20% concentration are stored in the tank (T-58) (capacity =

16,000 gallons) north of the Water Treatment Plant and adjacent to the sulfuric acid tank.

ATIACHME!fr 8 Page 13 of 17

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Hazardous Cheulcal and 71 HS-EF-02850 i

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l

)

The sulfuric acid tank is in the same dike containment as t

the liaCH tank.

NaOH solution is used in the water treatment f

l

)

process.

l 4

I 2.11 Sodium Hypochlorite (Na0Cl) i 2.11.1 Symptoms 4

Liquid accumulating in the secondary / containment tank a.

surrounding the NaOCl tank.

l b.

Liquid accumulating on the ground outside the i

secondary / containment tank.

Liquid accumulating et base of Na0Cl carboys in WTP c.

7 chemical storage room or at the WTP splitter box.

d.

Accumulation of chlorine vapors in WTP.

l 4

2.11.2 Specific Action For liquid accumulating in secondary / containment tank, s.

if possible, locate and stop the leak.

f b.

For liquid accumulating outside the secondary /

i containment tank, locate and stop the leak.

For liquid accumulating outside the carboys, locate and c.

stop the leak and/or over pack the carboy in a 55 gal.

j drum.

j 2.11.3 Discussion l

Up to 250 gallons (5-gallon carboys) of NaOCl are stored in if-t i

the WTP chemical. storage room. 585' level. These carboys are typically used at the WTP splitter box, 585* 1evel.

-l 1

The Na0C1 tank is designed with a secondary / containment tank I

which will contain 110% of the Na0Cl tank volume (1001 =

7,500 gallons). The Na0Cl is a 152 solution. This tank

.l supplies the station chlorination systems. An alarm for.

l high or low tank level LAHL 6380, alarms at the WTP annunciator alarm panel'115-2-G HYPOCHLORITE STORAGE TK LVL f.[

HIGH-LOW and also in the Control Room annunciator

^

alarm 9-3-B STA WTR PRE-TREATMENT SYS TRBL. The'Na0C1 tank feeds solution via a l' CPVC line to the suction header for the permanent chlorination' pumps located-in the WTP chlorination equipment room. All chlorine solution lines, except the feedline from the Na0Cl tank to the feed pumps, that must be run exterior to buildings are placed in a concrete trench to mitigate the possibility of rupture due-to physical contact and to facilitate isolation and repair of chlorine system piping. The concrete trench runs between j

the WTP, circulating water canal, and the station.

ATTACHMENT 8 l(-l Page~14 of 17

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Hazardous Chemical and 72 HS-EP-02850 R0 Oil Spills SAFA/ CERCLA HAZAFIn3S CHEMICAL IDCATIONS AND SPILL EVE 2fr GJIDELIhT:S 4,,

, t.)

'Ihe Water Treatment Chlorination System is enc 3cM it '.he Water Treatment Building. Due to its location, moct Jeaks in this system can be classified as local.

2.12 Sulfuric Acid (H,SO,)

2.12.1 Symptomt.

Sulfuric acid, 931, concentration, accumulating in the following areas:

If dike containment valve Wr-239 is open, accumulation a.

will occur in the small sump, 565' level, northwest corner of the kTP.

b.

If valve Wr-239 is closed, accumulation will occur in the dike containment surrounding the H,SO, and NaOH tanks.

hTP (large) Sump 1-1 high level alarm IAH-LB98 in c.

Control Rcom (alarm on computer point L-898).

d.

Surrounding roadways / parking areas if tank puncture or rupture is high and liquid leaks past the containment structure.

2.12.2 Specific Action e

KARNItr,2.12.2.a Large quantities of sulfuric acid admitted to sumps will cause a chemical reaction involving high tempera

tures and a resultant generation of toxic fumes, which

could be a personnel safety hazard. Also, do ICI add water to concentrated H SO due to resulting in a violent reaction, releabe bf heat and energy.

a.

If acid and caustic storage tank pit outlet ball valve Wr-239 is closed:

1.

Ensure the small sump has sump pumps turned on.

f 2.

Open ball valve Wr-239 using the control lever to release a constant flow of liquid.

f l

3.

Ensure flow is slow enough that the sump pumps can remove the liquid to the large sump before the small sump overflows.

ATTACHME2TT 8 Page 15 of 17 l

Hazardous Chemical and 73 HS-EP-02850 R0 Oil Spills SARA / CERCLA HAZAFnrUS CHDi1 CAL LOCATIONS AND SPILL EVE 2C GUIDELINES (Cont. )

4.

Liquid will be pumped from small sump to large sump and neutralized before discharge to settling basins. Discharge from the settling basins is through the collection box.

WARNING 2.12.3 If H SO and NaOH are both released from their respective storage tanks, the ;wo chemicals will react

violently, releasing large arounts of heat, energy, and toxic fumes.

2.12.3 Discussion Up to 20,000 gallons of concentrated sulfuric acid are stored in the tank (T-59) north of the WIP and adjacent to the sodium hydroxide (NaOH) tank.

The sulfuric acid tank is in the same dike containment as the NaOH tank.

H,SO, is used in the water treatment process.

O V

2.13 Turbine Plant Cooling Water (TPCW) (i.e. Nalco Sure-cool 1355 and biocide, i.e. Nalco 7330) 2.13.1 Symptoms Decrease in level of the high level coolant water (CW) tank (T-38).

2.13.2 Specific Action j

Contact Chemistry to determine chemical content of TPCW system.

2.13.3 Discussion l

TPCW is used to cocl many pieces of equipment such as generator hydrogen cooler, Electro-Hydraulic Control (EHC) fluid coolers, and main feed pump lube oil coolers. TPCW l

contains a low concentration of Ndlco Sure-Cool 1355 and a biocide, Nalco 7330.

2.14 Offsite Release 'Ihat Results in Hazard to Station Operations 2.14.1 Synptoms Unusual odor or smell of gases in the Control Room or plant structures that is traced to an offsite source.

ATIACHMDC 8 l

Page 16 of 17

Hazardous Chemical and 74 HS-EP-02850 R0 Oil Spills SARA /CERCIA HAZAFDrUS CHEMICAL IDCATIONS AND SPILL EVDC GLTIDELINES (Cont.)

2.14.2 Specific Actions Persons detecting the leak or unusual odor inform the a.

Control Room of the severity, nature, and location of the leak or odor, b.

Shift Supervisor (an Assistant Shift Supervisor will act in the absence of the Shift Supervisor).

1.

Upon detection of unusual or noxious vapors or fumes in the Control Room, manually isolate the Control Room ventilation fresh air supply. If Control Room EVS is put in service, follow the actions of AB 1203.42 (DB-OP-02533).

2.

Evaluate the situat_.on in accordance with HS-EP-01500, Emergency Classification, and take appropriate actions.

3.

Should a transportation accident occur on State Route 2 near the plant, releasing toxic gas which may affect plant personnel, notify the Ottawa County Sheriff so that appropriate County and State response agencies are contacted.

'Ihe purpose of this section of the procedure is to a.

ensure a transportation accident near the site does not affect control room habitability.

b.

Based on an evaluation of the types of toxic chemicals that are transported past the Davis-Besse Station on State Route 2, formaldehyde was determined to be the only one that may be of consequence to the Station.

If the wind is from a direction that is or has the potential to cause the formaldehyde vapors to pass over DBNPS, the Control Room Operators shall manually close the Control Room Air Intake Isolation Dampers. If Control Room EVS is put in service, follow the actions of AB 1203.42 (DB-OP-02553).

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l ATIACHMDR 8 l

Page 17 of 17 i

I Hazardous Chemical and 75 HS-EP-02850 R0 l

Oil Spills RESOURCE CONSERVATICN AND RECOVERY ACT (RCPA) COtfrINGENCY PLAN 1.0. Continoency Plan 1.1 Any initiating event (fire, explosion, spill, etc.) involving a l

chemical waste or mixed waste shall immediately be reported to the Control Room. A description and locations of the Chemical Waste Accumulation Areas (CWAAs) and Chemical Waste Storage Area (CRSA) can be found in NG-HS-00504.

1.1.1 he Shift Supervisor shall be notified and may mobilize a designee to directly manage the situation.

he Shift Supervisor shall note details pertaining to time, 1.1.2 l

date, and events in the Unit Log for any incident that i

involves implementing this Contingency Plan.

l 1.1.3 If the Shift Supervisor determines that evacuation is necessary, the Shift Supervisor shall initiate Emergency Plan Implementing Procedure HS-EP-02530, Evacuation, and shall determine the extent of the area that needs to be evacuated.

l 1.1.4 contingency Plan administration shall be directed and l

m supervised by the On-Call Safety / Environmental Supervisor l

[ primary RCFA Contingency Plan Emergency Coordinator (CPEC)).

1.1.5 he name, address, and office and home telephone numbers of each qualified CPEC shall be listed in the Emergency Plan Telephone Directory.

We directory shall be updated as new personnel are

-a.

qualified or are removed from the position.

b.

At least one CPEC shall be either onsite or oncall at all times.

c.

CPECs shall be thoroughly familiar with:

I 1.

All aspects of the Contingency Plan i

2.

Operations and activities at the facility 3.

Location and characteristics of wastes handled 4.

Locations of records within the facility i

5.

Facility layout d.

The CPEC shall have the authority to commit resources needed to implement the Contingency Plan.

ATIACHFmT 9 Page 1 of 6 l

o Hazardous Chemical and 76 HS-EP-02850 RO Oil Spills O

RESOURCE CONSERVATION AND RECOERY ACT (RCRA) CONTI?GENCY PLAN (Cont.)

Upon being alerted to a fire, explosion, or any unplanned release of 1.2 chemical or mixed waste, the following actions shall be implemented under the direction of the Shift Supervisor.

1.2.1 Refer to Emergency Plan Offnormal Procedure HS-EP-02850, Hazardous Chemical and Oil Spills. Perform initial actions and notifications as applicable for the situation.

1.2.2 If the event does not meet the criteria of HS-EP-02850, the On-Call Safety / Environmental Supervisor (Contingency Plan Administrator) should be contacted for instructions.

1.2.3 The following organizations or agencies may be mobilized to provide support in response activities:

a.

Fire Fighting 1.

Inside the Protected Area - the DBNPS Fire Brigade Captain shall direct the response of the Fire Brigade, as requested by the Shift Supervisor.

2.

In the Owner-Controlled Area - a local offsite fire department will respond, as requested by the Shift Supervisor /SAS Operator.

b.

Medical Treatment - We First Aid Team Leader shall direct the response of the First Aid Team, as requested by the Shift Supervisor.

c.

Chemical Waste Control and/or Recovery - h e On-Scene Coordinator shall direct activities according to HS-EP-02850, as requested by the Shift Supervisor with appropriate support and guidance by the On-Call Safety /

Environmental Supervisor, d.

Outside Assistance - Local support for fire and first aid assistance may be obtained by contacting the SAS operator at extension 7777 and requesting outside assistance.

i

!CrE:

Telephone numbers for support groups are located in the DBNPS Emergency Plan Telephone Directory.

e.

Internal Assistance 1.

Centerior Environmental Activities for technical support.

2.

If outside assistance is required for emergency equipment or medical treatment, see HS-EP-02850 for actions.

ATIACHME2rr 9 Page 2 of 6 j

i 1

Hazardous Chemical and 77 HS-EP-02850 RO j

p Oil Spills

(

RESOURCE CONSERVATICN AND RECOVERY ACT (RCFA) CCtCIIGDJCY PIR4 (Cont. )

f.

If a chemical waste release has occurred which could threaten human health or the environment outside this j

facility, perform notification activities as prescribed by HS-EP-02850.

g.

W e following information as prescribed by HS-EP-02850 shall be available for reports to offsite regulatory agencies:

j 1.

Name and telephone number of facility's reporter 2.

Name and address of facility 3.

Time and type of incident 4.

Name and quantity of materials involved, to the extent known 5.

Extent of injuries, if any 6.

Possible hazard to human health, or to the environment outside the facility 1.2.4 Overall access to the DBNPS site shall be controlled by Nuclear Security as prescribed by !G-IS-00002, General Nuclear Security Requirements.

1.3 Emergency response equipment and supplies at Davis-Besse should be utilized under the direction of the CPEC.

i

~

1.4 If a chemical waste spill event should occur, consult Section III of this Contingency Plan for instructions required for follow-up iters (for example, written reports).

J 1.5 This Contingency Plan shall be maintained as follows:

1 1.5.1 he Contingency Plan shall be incorporated as a part of Emergency Plan Offnormal Procedure HS-EP-02850, Hazardous Chemical and Oil Spills.

1.5.2 HS-EP-02850 is located in the Emergency Plan Offnormal Procedures Volume. As such, controlled copies of HS-EP-02850 shall be maintained at the following facilities:

a.

All DBNPS emergency facilities b.

Local (offsite) emergency response organizations l

c.

State emergency response organizations 1.5.3 Copies of HS-EP-02850 and all revisions to HS-EP-02850 shall be maintained by Records Management as prescribed by IG-IM-00106, Nuclear Records Management.

OV ATTACHME!n 9 Page 3 of 6 i

I t

=

Hazardous Chemical and 78 HS-EP-02850 R0 Oil Spills RESOURCE CCNSERVATICN AND PM'ERY ACT (RCRA) CCIEINGD4CY PLAN (Cont.)

j DBNPS 1.6 This Contingency Plan and associated support documents (e.g.:

Emergency Plan Telephone Directory) should be amended, if necessary, whenever:

1.6.1 Applicable regulations are revised.

1.6.2 h e Contingency Plan fails to be effective in an emergency.

1.6.3 The facility changes design, construction, operation, main-tenance, or other circumstances in such a way to increase the potential for fire, explosions, or releases of hazardous materials or hazardous waste ( W) or HW constituents to the environment, or changes the response necessary in an emergency.

1.6.4 The list of CPECs changes.

1.6.5 ne list of emergency equipnent changes.

1.7 Letters of Agreement between Toledo Edison and offsite agencies who may be called upon to render assistance in the event of an emergency shall be maintained in Appendix C of the DBNPS Emergency Plan.

2.0 Checklist of Emergency Equipment Full details of descriptions and locations are available in the Davis-Besse Emergency Plan, and fire suppression particulars (in complete detail), in the Fire Hazard Analysis Report. All equipment listed is available for use in an emergency / spill event situation.

EMERGDiCY D7JIPMENT LOCATICNS/ AVAILABILITY Tire Extinguishers Located throughout DBNPS site -

posted / signed areas Eye Wash Stations /

Inside Paint Shop (for shop and CNSA Portable Showers use)

Inside North Train Bay, Turbine Building, 585' level (for Turbine Building and CHAA use)

First Aid Kits Located throughout plant (perireters of turbine building)

Alarm and Communication Gai-tronics - located throughout entire DBNPS site. In addition, personnel can i

System use hand-held radios which can be

~

monitored by the Control Room base radio Fire Hydrant Located between various buildings throughout DBNPS site l

I ATTACHMDC 9 I

Page 4 of 6

I f

Hazardous Chemical and 79 HS-EP-02850 R0 Oil spills FfmURCE CCNSERVATION AND RECOVERY ACT (RCPA) 'C0tEINGDCI PIAN (Cont.)

EMERGENCY ITUIPMENT IDCATIONS/AVAIIABILITY rire' Alarm Station Alarm through Gai-tronics rire Blankets Inside North Train Bay Stretcher Inside North Train Bay Breathing Air Mine Safety Appliance (MSA) SCBAs, 30 i

and 60 minutes (only NISH has 30 minute j

bottles) and spare bottles.

j O Supply Kit for O Supply Kit will be available for Mbdical Dnergency Hkalth Center nurses use only.

Oil Absorbent Available through Maintenance Services l

Cleaning Cloths Available through Maintenance Services Disposal Drums Provided and controlled by existing fire plan through Maintenance Services Containment / Barrier Available through Maintenance Services Equipment and Supplies 3.0 follow-Up Operations and Reporting i

( We following requirements originate from 3ection 264.56 of the May 19, 1980 Federal Register.)

i l

3.1 Innediately after an event, the On-Call Safety / Environmental Supervisor shall provide for treatment, storage, or disposal of recovered waste, contaminated soil or surface water, or any other material that results from a release, fire, or explosion at the.

j facility, unless it can be demonstrated that the recovered material is i

not a hazardous waste.

3.2 he On-Call Safety / Environmental Supervisor shall ensure compliance with the following in the affected area of the facility:

3.2.1 Only waste that is compatible with the released material is treated, stored, or disposed of until cleanup procedures are-completed.

3.2.2 All emergency equipment used to respond to the event has been cleaned, and is fit for its intended use before normal operations are resumed.

ATIACHMDR 9 Page 5 of 6 i

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Hazardous Chemical and 80 HS-EP-02850 R0 Oil Opills RESOURCE CCNSERVATION A!D RECOVERY ACT (RCRA) CONTINGENCY PIAN (Cont.)

3.3 Toledo Edison shall notify the US EPA Regional Administrator and appropriate State and local authorities that the facility is in com-pliance with Section III.B of this Contingency Plan before resuming normal operations in the affected area of the facility.

3.3.1 within 15 days after the incident, a written report on the incident must be submitted to the US EPA Regional Administrator.

l 3.3.2 he written report shall include:

Company name, address, and telephone number a.

l b.

Facility name, address, and telephone number l

c.

Date, time, and type of incident (fire; explosion; i

spill; etc.)

I d.

Name and quantity of materials involved e.

W e extent of injuries, if any f.

Where applicable, an assessment of actual or potential hazards to human health or the environment g.

Estimate of quantity and the disposition of recoveied material that resulted from the incident O

r O

ATIACHMENT 9 Page 6 of 6

Hazardous Chemical and 80a HS-EP-02850 Oil Spills RD C-1 4' O

ATTACHMENT 10:

SPILL OR INCIDENTAL RELEASE CLEANUP PLAN 1.0 This plan shall only be used if the spill or incidental release:

1.1 Does not involve oil, chemicals, mixed waste, or hazardous vaste of reportable quantities as determined by the Supervisor -

Environmental and Safety, 1.2 Does not pose a threat of personnel exposure, and 1.3 Does not pose a threat of migration to the environment.

2.0 Use of appropriate PPE to prevent skin and eye contact shall be employed.

3.0 Initial response shall be to contain or minimize the spill. This may include:

3.1 Use of dikes, booms, absorbents or overpacks 3.2 Covering nearby or other affected drains 3.3 Posting the area to prevent spreading of the spill by personnel.

4.0 Ensure all containerized materials are labeled as follows:

4.1 Non-Hazardous Materials:

a.

Date ml I

b.

Contents c.

Source d.

Contact person e.

Indicate 'non-hazardous' i

4.2 Small amounts of hazardous materials:

l a.

Date b.

Contents l

l c.

Source l

d.

Contact person j

e.

Indicate

hazardous vaste" and consult NG-HS-00504 and ISG-26 for appropriate caution labels 5.0 Ensure hazardous vaste materials are handled per NG-HS-00504 and (V) cleanup personnel for hazardous materials have received RCRA training per NG-HS-00504.

l ATTACHMENT 10 Page 1 of 5 l

l

t I

Hazardous Chemical and 80b HS-EP-02850 R0 C-1 4 l

Oil Spills ATTACHMENT 10: SPILL OR INCIDENTAL RELEASE CLEANUP PLAN (Continued) 6.0 Cleanup and Recovery Response Matrix WARNING 6.1 Adequate ventilation and skin / eye protection should be used, the TLV is 50 ppm.

Description Spill Limit

Response

6.1 Ethyliene Glycol

<25 gallons Containerize, label as non-hazardous waste and remove to the CWSA or CWAA as appropriate.

6.2 Non PCB Oils

<25 gallons Containerize, label as non-hazardous vaste and remove to the CWSA or CWAA as appropriate.

6.3 Gasoline or

<25 gallons Containerize, label as non-Diesel Fuel hazardous vaste and remove to the CWSA or CWAA as appropriate.

s i

I l

NOTE 6.4 l

l l

l Many hydraulic fluids are chlorinated. The MSDS l

l should be consulted to ensure non-halogen status.

l l

l l_ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _l 6.4 Non-Haloginated

<25 gallons Containerize, label as non-Hydraulic Fluid hazardous waste and remove to the CWSA or CWAA as appropriate.

6.5 Nalco 1332 N/A Containerize if large amounts Water Conditioner are spilled or tank is ruptured.

Label as non-hazardous waste.

Flush residual spill amounts of water to drain.

I l

i ATTACHMENT 10 Page 2 of 5 i

i E

- a Hazardous Chemical and 80c HS-EP-02850 l

R0 C-1 4

l Oil Spills l

ATTACHMENT 10: SPILL OR INCIDENTAL RELEASE CLEANUP PLAN (Continued) i VARNING 6.6 j

e Ensure material does-not come in contact with peroxide.

f 1002 morpholine is hazardous (TWA 20 ppm) and-requires Hazwoper response implementation.

l l

I Description Spill Limit

Response

i 6.6 Nalco 352

<55 gallons Containerize residual, and Nalco 88UM041 label as non-hazardous waste.

l (20-402 morpholine) remove to CWSA or CWAA as j

appropriate.

i l

NOTE 6.7 l.

j i

I l

If material is mixed with water.. the-solution l

l is extremely caustic, a hazardous waste, and l

j may require Hazwoper response.

l l

1 l_ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _l l

WARNING 6.7 Respiratory protection for dust generation should l

be used and contact with water should be avoided.

j j

i 6.7 Non-radiological

<100 pounds Containerize. label as non-Lithium Hydroxide hazardous waste and remove to the (caustic powders)

CWSA or CWAA as. appropriate.

ATTACHMENT 10 Page 3 of 5

. _., _.. ~. _,. _.,.

_. ~., -, -..,,.. _

L 4

e e

Hazardous Chemical and 80d HS-EP-02850 R0 C-1 4 Oil Spills ATTACHMENT lor SPILL OR INCIDENTAL RELEASE CLEANUP PLAN (Continued)

(

WARNING 6.8 Respiratory protection for dust generation should be used. The TLV is 5 ppm, and can liberate 50, l

when in contact with acids.

l I

Description Spill Limit

Response

l 6.8 Non-radiological

<100 pounds Containerize, label as non-Sodium Bisulfite-hazardous waste and remove to the Anhydrous CWSA of CWAA as appropriate.

l 6.9 TPCW N/A Containerize, label as non-hazardous waste and remove to the CWSA or CWAA as appropriate.

6.10 Fyrquel EHC Fluid

<55 gallons Reclaim if possible.

Containerize waste and label as "non-hazardous

waste. Remove t CVSA or CWAA as appropriate.

WARNING 6.11 Ensure material will not come in contact with other chemicals; especially acids which could react to cause liberation of lethal chlorine gas.

6.11 Sodium

<5 gallons Containerize, label as Hypochlorite hazardous waste and remove to the CWSA or CWAA as appropriate.

WARNING 6.12 Avoid contact with combustible materials. Use adequate ventilation: TLV is 2 ppm.

6.12 Lattery Acid /

<5 gallons Containerize, label as Electrolyte hazardous waste, and remove f

Solutions to the CWSA or CWAA as appropriate.

ATTACHMENT 10 Page 4 of 5

A

- +.

a Hazardous Chemical and 80e HS-EP-02850 Oil Spills R0 C-1 4 ATTACHMENT los SPILL OR INCIDENTAL RELEASE CLEANUP PLAN (Continued)

Description Spill Limit

Response

6.13 Records

<1 pint Management /

Photographic Materials l

l 6.13.1 Non-Hazardous Waste o

Kodak Prostor Plus Containerize, label as o

Kodak Prostor Plus Developer non-hazardous waste, and o

Kodak Fixer Wash System Cleaner remove to the CVSA or CWAA as o

3M Type 028 Fix (used)*

appropriate.

o Diazorb Crystals (used)*

o 3M Ammonia Absorber Pak (used)*

o 3M (D-5 Developer (used))*

o Aqua Ammonia Solution 1 (used)*

(

o Aqua Ammonia Solution 2 (used)*

l 6.13.2 Hazardous Waste o

Kodak Developer Containerize, label as l

)

System Cleaner hazardous vaste and s

o Kodak Liquid Developer remove to the CVSA.

l Systems Cleaner I

o Fedron ml o

3M Ammonia Absorber Pak (virgin / unused) o 3M CD-5 Developer (virgin / unused)

I o

3M Type 028 Fix (virgin / unused) o Aqua Ammonia Solution 1 (virgin / unused) o Aqua Ammonia Solution 2 (virgin / unused) o Diazorb Crystals (virgin / unused) 6.14 Paints and

<5 gallons Containerize, label as Solvents hazardous waste and remove to the CWAA or CWSA as j

l l

appropriate.

Small quantities of spent material used in the Photographic Equipment may be flushed j

with a large volume of water.

ATTACHMENT 10 Page 5 of 5

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t Hazardous Chemical and 81 HS-EP-02850 R0 C-1 Oil Spills O

COtt4ITMENTS Section Reference Comments 6.2.10 and TERMS O 09590 Operators (Shift Supervisor or,

Assistant Shift Supe rvis or) shall secure / isolate Control Room Section 2.14 Ventilation System and start the Control Room Emergency Ventilation System (with fresh air damper closed) in the event of a toxic gas release. If fumes from a toxic liquid release are detected in the Control Room atmosphere, the Shift Supervisor shall secure the fresh air damper to the Control Room ventilation system.

Entire Procedure TERMS Q 00064 NUREG 1.33, Appendix A. F.18 states that typical safety-related activities i.e. expected transients, should be covered by procedures. Specifically, these procedures are for combating emergencies and other significant events.

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ML20035F207

Text

2.0 REFERENCES

2.0 REFERENCES

-

Response

Response

Response

Response

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