ML18199A134
| ML18199A134 | |
| Person / Time | |
|---|---|
| Site: | 07000036 |
| Issue date: | 05/15/2017 |
| From: | Pallagi K Testamerica Labs, Westinghouse |
| To: | Gregory Chapman Division of Decommissioning, Uranium Recovery and Waste Programs |
| G CHAPMAN NMSS DUWP | |
| Shared Package | |
| ML18199A128 | List: |
| References | |
| HEM-17-35 | |
| Download: ML18199A134 (17) | |
Text
ANALYTICAL REPORT TestAmerica Laboratories, Inc.
TestAmerica St. Louis 13715 Rider Trail North Earth City, MO 63045 Tel: (314)298-8566 TestAmerica Job ID: 160-14366-1 Client Project/Site: HDP For:
Perma-Fix Environmental Services Inc.
2800 Solway Road Knoxville, Tennessee 37931 Attn: Brian Miller Authorized for release by:
10/26/2015 1:30:26 PM Rhonda Ridenhower, Manager of Project Management rhonda.ridenhower@testamericainc.com Designee for Ivan Vania, Project Manager II (314)298-8566 ivan.vania@testamericainc.com This report has been electronically signed and authorized by the signatory. Electronic signature is intended to be the legally binding equivalent of a traditionally handwritten signature.
Results relate only to the items tested and the sample(s) as received by the laboratory.
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Table of Contents Client: Perma-Fix Environmental Services Inc.
Project/Site: HDP TestAmerica Job ID: 160-14366-1 Page 2 of 17 TestAmerica St. Louis 10/26/2015 Cover Page..............................................
1 Table of Contents.........................................
2 Case Narrative...........................................
3 Chain of Custody..........................................
5 Receipt Checklists.........................................
6 Definitions/Glossary.......................................
7 Method Summary.........................................
8 Sample Summary.........................................
9 Client Sample Results......................................
10 QC Sample Results........................................
12 QC Association Summary...................................
15 Tracer Carrier Summary....................................
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Case Narrative Client: Perma-Fix Environmental Services Inc.
TestAmerica Job ID: 160-14366-1 Project/Site: HDP Job ID: 160-14366-1 Laboratory: TestAmerica St. Louis Narrative CASE NARRATIVE Client: Perma-Fix Environmental Services Inc.
Project: HDP Report Number: 160-14366-1 With the exceptions noted as flags or footnotes, standard analytical protocols were followed in the analysis of the samples and no problems were encountered or anomalies observed. In addition all laboratory quality control samples were within established control limits, with any exceptions noted below. Each sample was analyzed to achieve the lowest possible reporting limit within the constraints of the method. In some cases, due to interference or analytes present at high concentrations, samples were diluted. For diluted samples, the reporting limits are adjusted relative to the dilution required.
TestAmerica St. Louis attests to the validity of the laboratory data generated by TestAmerica facilities reported herein. All analyses performed by TestAmerica facilities were done using established laboratory SOPs that incorporate QA/QC procedures described in the application methods. TestAmericas operations groups have reviewed the data for compliance with the laboratory QA/QC plan, and data have been found to be compliant with laboratory protocols unless otherwise noted below.
The test results in this report meet all NELAP requirements for parameters for which accreditation is required or available. Any exceptions to NELAP requirements are noted in this report. Pursuant to NELAP, this report may not be reproduced, except in full, without the written approval of the laboratory.
Calculations are performed before rounding to avoid round-off errors in calculated results.
All holding times were met and proper preservation noted for the methods performed on these samples, unless otherwise detailed in the individual sections below.
All solid sample results for Chemistry analyses are reported on an "as received" basis unless otherwise indicated by the presence of a %
solids value in the method header. All soil/sediment sample results for radiochemistry analyses are based upon sample as dried and disaggregated with the exception of tritium, carbon-14, and iodine-129 by gamma spectroscopy unless requested as wet weight by the client.
This laboratory report is confidential and is intended for the sole use of TestAmerica and its client.
RECEIPT The samples were received on 10/20/2015; the samples arrived in good condition, properly preserved. The temperature of the coolers at receipt was 20.3 C.
TECHNETIUM-99 (ICPMS)
Samples L03-02-25-P-S-B-00 (160-14366-1) and L03-02-26-P-S-B-00 (160-14366-2) were analyzed for Technetium-99 (ICPMS) in accordance with EPA SW-846 Method 6020A. The samples were prepared on 10/20/2015 and analyzed on 10/22/2015.
No analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.
PERCENT SOLIDS Samples L03-02-25-P-S-B-00 (160-14366-1) and L03-02-26-P-S-B-00 (160-14366-2) were analyzed for percent solids in accordance with EPA Method 160.3 MOD. The samples were analyzed on 10/21/2015.
No analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.
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Case Narrative Client: Perma-Fix Environmental Services Inc.
TestAmerica Job ID: 160-14366-1 Project/Site: HDP Job ID: 160-14366-1 (Continued)
Laboratory: TestAmerica St. Louis (Continued)
CESIUM-137 & OTHER GAMMA EMITTERS (GS)
Samples L03-02-25-P-S-B-00 (160-14366-1) and L03-02-26-P-S-B-00 (160-14366-2) were analyzed for Cesium-137 & Other Gamma Emitters (GS) in accordance with DOE GA-01-R. The samples were dried on 10/20/2015, prepared on 10/21/2015 and analyzed on 10/22/2015.
The replicate error ratio was outside of the acceptance limits of 1 for protactinium-231. Both the sample and duplicate activity were less than the MDC. The data is reported.L03-02-25-P-S-B-00 (160-14366-1), L03-02-26-P-S-B-00 (160-14366-2), (LCS 160-217683/2-A), (MB 160-217683/1-A), (160-14346-A-1-C) and (160-14346-A-1-D DU)
Radium-226 is reported in these samples at the client's request. Radium-226 is reported from the 609.31 keV line of bismuth-214.
Because the samples have not had a 21-day ingrowth, the activity for radium-226 is an estimated value and may be biased low. This bias is caused by the disruption of secular equilibrium between radium-226 and bismuth-214 by the loss of radon-222 during sample preparation.L03-02-25-P-S-B-00 (160-14366-1), L03-02-26-P-S-B-00 (160-14366-2), (LCS 160-217683/2-A), (MB 160-217683/1-A),
(160-14346-A-1-C) and (160-14346-A-1-D DU)
No additional analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.
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Login Sample Receipt Checklist Client: Perma-Fix Environmental Services Inc.
Job Number: 160-14366-1 Login Number: 14366 Question Answer Comment Creator: Clarke, Jill C List Source: TestAmerica St. Louis List Number: 1 True Radioactivity wasn't checked or is </= background as measured by a survey meter.
True The cooler's custody seal, if present, is intact.
N/A Sample custody seals, if present, are intact.
True The cooler or samples do not appear to have been compromised or tampered with.
N/A Samples were received on ice.
True Cooler Temperature is acceptable.
True Cooler Temperature is recorded.
True COC is present.
True COC is filled out in ink and legible.
True COC is filled out with all pertinent information.
N/A Is the Field Sampler's name present on COC?
True There are no discrepancies between the containers received and the COC.
True Samples are received within Holding Time.
True Sample containers have legible labels.
True Containers are not broken or leaking.
True Sample collection date/times are provided.
True Appropriate sample containers are used.
True Sample bottles are completely filled.
True Sample Preservation Verified.
True There is sufficient vol. for all requested analyses, incl. any requested MS/MSDs N/A Containers requiring zero headspace have no headspace or bubble is
<6mm (1/4").
True Multiphasic samples are not present.
True Samples do not require splitting or compositing.
N/A Residual Chlorine Checked.
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Definitions/Glossary TestAmerica Job ID: 160-14366-1 Client: Perma-Fix Environmental Services Inc.
Project/Site: HDP Qualifiers Rad Qualifier Description U
Result is less than the sample detection limit.
Qualifier F
Duplicate RPD exceeds the control limit Glossary These commonly used abbreviations may or may not be present in this report.
Listed under the "D" column to designate that the result is reported on a dry weight basis Abbreviation
%R Percent Recovery CFL Contains Free Liquid CNF Contains no Free Liquid DER Duplicate error ratio (normalized absolute difference)
Dil Fac Dilution Factor DL, RA, RE, IN Indicates a Dilution, Re-analysis, Re-extraction, or additional Initial metals/anion analysis of the sample DLC Decision level concentration MDA Minimum detectable activity EDL Estimated Detection Limit MDC Minimum detectable concentration MDL Method Detection Limit ML Minimum Level (Dioxin)
NC Not Calculated ND Not detected at the reporting limit (or MDL or EDL if shown)
PQL Practical Quantitation Limit QC Quality Control RER Relative error ratio RL Reporting Limit or Requested Limit (Radiochemistry)
RPD Relative Percent Difference, a measure of the relative difference between two points TEF Toxicity Equivalent Factor (Dioxin)
TEQ Toxicity Equivalent Quotient (Dioxin)
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Method Summary TestAmerica Job ID: 160-14366-1 Client: Perma-Fix Environmental Services Inc.
Project/Site: HDP Method Method Description Laboratory Protocol SW846 6020A Metals (ICP/MS), Tc-99 TAL SL EPA Moisture Percent Moisture TAL SL SW846 6020A Metals (ICP/MS), Tc-99 in Activity TAL SL DOE GA-01-R Cesium-137 & Other Gamma Emitters (GS)
TAL SL Protocol
References:
DOE = U.S. Department of Energy EPA = US Environmental Protection Agency SW846 = "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates.
Laboratory
References:
TAL SL = TestAmerica St. Louis, 13715 Rider Trail North, Earth City, MO 63045, TEL (314)298-8566 TestAmerica St. Louis Page 8 of 17 10/26/2015 1
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Sample Summary TestAmerica Job ID: 160-14366-1 Client: Perma-Fix Environmental Services Inc.
Project/Site: HDP Lab Sample ID Client Sample ID Received Collected Matrix 160-14366-1 L03-02-25-P-S-B-00 Solid 10/19/15 15:45 10/20/15 11:10 160-14366-2 L03-02-26-P-S-B-00 Solid 10/19/15 15:35 10/20/15 11:10 TestAmerica St. Louis Page 9 of 17 10/26/2015 1
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Client Sample Results TestAmerica Job ID: 160-14366-1 Client: Perma-Fix Environmental Services Inc.
Project/Site: HDP Lab Sample ID: 160-14366-1 Client Sample ID: L03-02-25-P-S-B-00 Matrix: Solid Date Collected: 10/19/15 15:45 Date Received: 10/20/15 11:10 Method: GA-01-R - Cesium-137 & Other Gamma Emitters (GS)
Analyte Actinium 228 1.13 (2+/-)
0.161 (2+/-)
1 10/22/15 19:10 10/21/15 13:17 pCi/g 0.116 RL MDC 0.114 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
pCi/g 10/21/15 13:17 10/22/15 19:10 1
0.106 0.101 0.101 U
-0.00257 Americium 241 pCi/g 10/21/15 13:17 10/22/15 19:10 1
0.457 0.559 0.535 1.58 Bismuth 212 pCi/g 10/21/15 13:17 10/22/15 19:10 1
0.0796 0.136 0.107 0.829 Bismuth 214 pCi/g 10/21/15 13:17 10/22/15 19:10 1
0.0794 0.156 0.0871 0.999 Lead 212 pCi/g 10/21/15 13:17 10/22/15 19:10 1
0.0713 0.129 0.0843 0.933 Lead 214 pCi/g 10/21/15 13:17 10/22/15 19:10 1
1.16 2.15 1.24 17.4 Potassium 40 pCi/g 10/21/15 13:17 10/22/15 19:10 1
5.35 2.17 2.16 U
2.74 Protactinium 234m pCi/g 10/21/15 13:17 10/22/15 19:10 1
1.22 0.224 0.219 U
0.422 Protactinium 231 pCi/g 10/21/15 13:17 10/22/15 19:10 1
0.0796 0.136 0.107 0.829 Radium 226 pCi/g 10/21/15 13:17 10/22/15 19:10 1
0.943 0.375 0.358 1.07 Thorium 234 pCi/g 10/21/15 13:17 10/22/15 19:10 1
0.228 0.145 0.144 U
0.0857 Uranium 235 pCi/g 10/21/15 13:17 10/22/15 19:10 1
0.116 0.161 0.114 1.13 Thorium 232 Tl-208 0.362 0.0493 0.0618 0.0369 pCi/g 10/21/15 13:17 10/22/15 19:10 1
(2+/-)
(2+/-)
MDC RL Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Other Detected Radionuclides Uncert.
Uncert.
Lab Sample ID: 160-14366-1 Client Sample ID: L03-02-25-P-S-B-00 Matrix: Solid Date Collected: 10/19/15 15:45 Percent Solids: 91.6 Date Received: 10/20/15 11:10 Method: 6020A - Metals (ICP/MS), Tc-99 RL MDL Technetium 99 ND 0.000065 0.000019 mg/Kg
10/20/15 15:03 10/22/15 11:11 1
Analyte Dil Fac Analyzed Prepared Unit D
Result Qualifier Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Analyte Technetium 99 0.0222 U (2+/-)
0.117 (2+/-)
1 10/22/15 11:11 10/20/15 15:03 pCi/g 0.222 1.30 RL MDC 0.117 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
Re 30 - 110 Carrier 10/20/15 15:03 10/22/15 11:11 1
Dil Fac Analyzed Prepared Qualifier Limits
%Yield 85 Lab Sample ID: 160-14366-2 Client Sample ID: L03-02-26-P-S-B-00 Matrix: Solid Date Collected: 10/19/15 15:35 Date Received: 10/20/15 11:10 Method: GA-01-R - Cesium-137 & Other Gamma Emitters (GS)
Analyte Actinium 228 0.960 (2+/-)
0.138 (2+/-)
1 10/22/15 19:11 10/21/15 13:17 pCi/g 0.0810 RL MDC 0.0967 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
pCi/g 10/21/15 13:17 10/22/15 19:11 1
0.0835 0.0496 0.0496 U
0.00885 Americium 241 pCi/g 10/21/15 13:17 10/22/15 19:11 1
0.275 0.369 0.342 1.32 Bismuth 212 pCi/g 10/21/15 13:17 10/22/15 19:11 1
0.0430 0.0969 0.0704 0.640 Bismuth 214 pCi/g 10/21/15 13:17 10/22/15 19:11 1
0.0538 0.126 0.0657 0.829 Lead 212 TestAmerica St. Louis Page 10 of 17 10/26/2015 1
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Client Sample Results TestAmerica Job ID: 160-14366-1 Client: Perma-Fix Environmental Services Inc.
Project/Site: HDP Lab Sample ID: 160-14366-2 Client Sample ID: L03-02-26-P-S-B-00 Matrix: Solid Date Collected: 10/19/15 15:35 Date Received: 10/20/15 11:10 Method: GA-01-R - Cesium-137 & Other Gamma Emitters (GS) (Continued)
Analyte Lead 214 0.798 (2+/-)
0.107 (2+/-)
1 10/22/15 19:11 10/21/15 13:17 pCi/g 0.0603 RL MDC 0.0683 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
pCi/g 10/21/15 13:17 10/22/15 19:11 1
0.267 1.95 1.00 16.3 Potassium 40 pCi/g 10/21/15 13:17 10/22/15 19:11 1
3.46 1.93 1.93 U
0.747 Protactinium 234m pCi/g 10/21/15 13:17 10/22/15 19:11 1
1.04 0.638 0.635 U
-0.535 Protactinium 231 pCi/g 10/21/15 13:17 10/22/15 19:11 1
0.0430 0.0969 0.0704 0.640 Radium 226 pCi/g 10/21/15 13:17 10/22/15 19:11 1
0.644 0.433 0.415 1.17 Thorium 234 pCi/g 10/21/15 13:17 10/22/15 19:11 1
0.198 0.126 0.125 U
0.106 Uranium 235 pCi/g 10/21/15 13:17 10/22/15 19:11 1
0.0810 0.138 0.0967 0.960 Thorium 232 Tl-208 0.260 0.0395 0.0478 0.0315 pCi/g 10/21/15 13:17 10/22/15 19:11 1
(2+/-)
(2+/-)
MDC RL Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Other Detected Radionuclides Uncert.
Uncert.
Lab Sample ID: 160-14366-2 Client Sample ID: L03-02-26-P-S-B-00 Matrix: Solid Date Collected: 10/19/15 15:35 Percent Solids: 80.7 Date Received: 10/20/15 11:10 Method: 6020A - Metals (ICP/MS), Tc-99 RL MDL Technetium 99 ND 0.000075 0.000023 mg/Kg
10/20/15 15:03 10/22/15 11:15 1
Analyte Dil Fac Analyzed Prepared Unit D
Result Qualifier Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Analyte Technetium 99 0.265 (2+/-)
0.106 (2+/-)
1 10/22/15 11:15 10/20/15 15:03 pCi/g 0.257 1.50 RL MDC 0.103 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
Re 30 - 110 Carrier 10/20/15 15:03 10/22/15 11:15 1
Dil Fac Analyzed Prepared Qualifier Limits
%Yield 83 TestAmerica St. Louis Page 11 of 17 10/26/2015 1
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QC Sample Results TestAmerica Job ID: 160-14366-1 Client: Perma-Fix Environmental Services Inc.
Project/Site: HDP Method: 6020A - Metals (ICP/MS), Tc-99 Client Sample ID: Method Blank Lab Sample ID: MB 160-217468/1-A Matrix: Solid Prep Type: Total/NA Analysis Batch: 217906 Prep Batch: 217468 RL MDL Technetium 99 ND 0.000059 0.000018 mg/Kg 10/20/15 15:03 10/22/15 10:04 1
MB MB Analyte Dil Fac Analyzed Prepared D
Unit Result Qualifier Client Sample ID: Lab Control Sample Lab Sample ID: LCS 160-217468/2-A Matrix: Solid Prep Type: Total/NA Analysis Batch: 217906 Prep Batch: 217468 Technetium 99 0.00123 0.00127 mg/Kg 103 80 - 120 Analyte LCS LCS D
Unit Result Qualifier
%Rec Spike Added
%Rec.
Limits Client Sample ID: Matrix Spike Lab Sample ID: 160-14364-A-14-E MS Matrix: Solid Prep Type: Total/NA Analysis Batch: 217906 Prep Batch: 217468 Technetium 99 0.00019 0.00136 0.00157 mg/Kg 101 75 - 125
Analyte MS MS D
Unit Result Qualifier
%Rec Spike Added Sample Result Sample Qualifier
%Rec.
Limits Client Sample ID: Matrix Spike Duplicate Lab Sample ID: 160-14364-A-14-F MSD Matrix: Solid Prep Type: Total/NA Analysis Batch: 217906 Prep Batch: 217468 Technetium 99 0.00019 0.00136 0.00155 mg/Kg 100 75 - 125 1
30
Analyte MSD MSD D
Unit Result Qualifier
%Rec Spike Added Sample Result Sample Qualifier
%Rec.
Limits Limit RPD RPD Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Client Sample ID: Method Blank Lab Sample ID: MB 160-217468/1-A Matrix: Solid Prep Type: Total/NA Analysis Batch: 217907 Prep Batch: 217468 Technetium 99 Analyte U
1 10/22/15 10:04 10/20/15 15:03 pCi/g 0.203 MDC 1.19 RL 0.0569 0.0569 (2+/-)
(2+/-)
MB
-0.009764 MB Dil Fac Prepared Analyzed Unit Result Qualifier Uncert.
Count Uncert.
Total Carrier Re 30 - 110 10/20/15 15:03 10/22/15 10:04 1
Dil Fac Prepared Analyzed Qualifier Limits
%Yield 84 MB MB Client Sample ID: Lab Control Sample Lab Sample ID: LCS 160-217468/2-A Matrix: Solid Prep Type: Total/NA Analysis Batch: 217907 Prep Batch: 217468 Technetium 99 Analyte 120 80 103 21.68 21.1 9.84 1.16 0.198 RL MDC (2+/-)
LCS LCS pCi/g Unit Result Qual
%Rec Added Spike Limits
%Rec.
Uncert.
Total Re Carrier 30 - 110 LCS Qualifier Limits
%Yield 86 LCS TestAmerica St. Louis Page 12 of 17 10/26/2015 1
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QC Sample Results TestAmerica Job ID: 160-14366-1 Client: Perma-Fix Environmental Services Inc.
Project/Site: HDP Method: 6020A - Metals (ICP/MS), Tc-99 in Activity (Continued)
Client Sample ID: Matrix Spike Lab Sample ID: 160-14364-A-14-E MS Matrix: Solid Prep Type: Total/NA Analysis Batch: 217907 Prep Batch: 217468 Technetium 99 Analyte 125 75 101 26.81 23.3 3.17 12.7 1.30 0.222 RL MDC (2+/-)
MS MS pCi/g Unit Result Qual
%Rec Added Spike Result Sample Sample Qual Limits
%Rec.
Uncert.
Total Re Carrier 30 - 110 MS Qualifier Limits
%Yield 85 MS Client Sample ID: Matrix Spike Duplicate Lab Sample ID: 160-14364-A-14-F MSD Matrix: Solid Prep Type: Total/NA Analysis Batch: 217907 Prep Batch: 217468 Technetium 99 Analyte 1
0.01 125 75 100 26.58 23.3 3.17 11.4 1.32 0.226 RL MDC (2+/-)
MSD MSD pCi/g Unit Result Qual
%Rec Limit Added Spike Result Sample Sample Qual Limits
%Rec.
Uncert.
Total RER RER Re Carrier 30 - 110 MSD Qualifier Limits
%Yield 84 MSD Method: GA-01-R - Cesium-137 & Other Gamma Emitters (GS)
Client Sample ID: Method Blank Lab Sample ID: MB 160-217683/1-A Matrix: Solid Prep Type: Total/NA Analysis Batch: 217956 Prep Batch: 217683 Actinium 228 Analyte U
1 10/22/15 16:29 10/21/15 13:17 pCi/g 0.0547 MDC RL 0.0284 0.0284 (2+/-)
(2+/-)
MB 0.001968 MB Dil Fac Prepared Analyzed Unit Result Qualifier Uncert.
Count Uncert.
Total 1
10/22/15 16:29 10/21/15 13:17 pCi/g 0.0174 0.0109 0.0108 U
0.009685 Americium 241 1
10/22/15 16:29 10/21/15 13:17 pCi/g 0.160 0.0860 0.0860 U
-0.02393 Bismuth 212 1
10/22/15 16:29 10/21/15 13:17 pCi/g 0.0343 0.0157 0.0157 U
0.0008216 Bismuth 214 1
10/22/15 16:29 10/21/15 13:17 pCi/g 0.0215 0.0105 0.0105 U
0.0007914 Lead 212 1
10/22/15 16:29 10/21/15 13:17 pCi/g 0.0348 2.27 2.27 U
-0.01557 Lead 214 1
10/22/15 16:29 10/21/15 13:17 pCi/g 0.229 0.104 0.104 U
0.01271 Potassium 40 1
10/22/15 16:29 10/21/15 13:17 pCi/g 1.88 0.994 0.993 U
0.1981 Protactinium 234m 1
10/22/15 16:29 10/21/15 13:17 pCi/g 0.259 0.145 0.144 U
0.04909 Protactinium 231 1
10/22/15 16:29 10/21/15 13:17 pCi/g 0.0343 0.0157 0.0157 U
0.0008216 Radium 226 1
10/22/15 16:29 10/21/15 13:17 pCi/g 0.239 0.0790 0.0787 U
0.06280 Thorium 234 1
10/22/15 16:29 10/21/15 13:17 pCi/g 0.0603 0.0418 0.0418 U
-0.006812 Uranium 235 1
10/22/15 16:29 10/21/15 13:17 pCi/g 0.0547 0.0284 0.0284 U
0.001968 Thorium 232 Other Detected Radionuclide None MB (2+/-)
(2+/-)
MDC RL pCi/g 10/21/15 13:17 10/22/15 16:29 1
MB Dil Fac Prepared Analyzed Unit Result Qualifier Uncert.
Count Uncert.
Total Radionuclides Other Detected TestAmerica St. Louis Page 13 of 17 10/26/2015 1
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QC Sample Results TestAmerica Job ID: 160-14366-1 Client: Perma-Fix Environmental Services Inc.
Project/Site: HDP Method: GA-01-R - Cesium-137 & Other Gamma Emitters (GS) (Continued)
Client Sample ID: Lab Control Sample Lab Sample ID: LCS 160-217683/2-A Matrix: Solid Prep Type: Total/NA Analysis Batch: 217754 Prep Batch: 217683 Americium 241 Analyte 116 87 105 105.9 101 11.0 0.583 RL MDC (2+/-)
LCS LCS pCi/g Unit Result Qual
%Rec Added Spike Limits
%Rec.
Uncert.
Total Cesium 137 34.4 39.46 4.08 0.200 0.184 pCi/g 115 87 - 120 Cobalt 60 33.6 37.45 3.71 0.129 pCi/g 111 87 - 115 Client Sample ID: Duplicate Lab Sample ID: 160-14346-A-1-D DU Matrix: Solid Prep Type: Total/NA Analysis Batch: 217756 Prep Batch: 217683 Actinium 228 Analyte 1
0.10 0.8889 0.918 0.146 0.106 RL MDC (2+/-)
DU DU pCi/g Unit Result Qual Limit Result Sample Sample Qual Uncert.
Total RER RER Americium 241 0.00816 U 0.01831 U 0.0588 0.0984 pCi/g 0.09 1
Bismuth 212 1.58 1.202 0.459 0.376 pCi/g 0.40 1
Bismuth 214 0.801 0.7522 0.122 0.0660 pCi/g 0.20 1
Lead 212 0.948 0.9832 0.145 0.0499 pCi/g 0.12 1
Lead 214 0.876 0.8272 0.116 0.0567 pCi/g 0.21 1
Potassium 40 16.6 16.72 2.01 0.326 pCi/g 0.04 1
Protactinium 234m 5.54 3.419 U 2.58 4.70 pCi/g 0.38 1
Protactinium 231 0.425 U
-0.5922 U F 0.630 1.03 pCi/g 1.16 1
Radium 226 0.801 0.7522 0.122 0.0660 pCi/g 0.20 1
Thorium 234 1.94 2.244 0.566 0.759 pCi/g 0.26 1
Uranium 235 0.523 0.6231 0.208 0.233 pCi/g 0.27 1
Thorium 232 0.918 0.8889 0.146 0.106 pCi/g 0.10 1
Pb-210 1
0.10 1.507 1.65 0.683 0.804 RL MDC (2+/-)
DU DU pCi/g Unit Result Qual Limit Result Sample Sample Qual Uncert.
RER RER Total Other Detected Radionuclides Tl-208 0.329 0.3187 0.0533 0.0275 pCi/g 0.09 1
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QC Association Summary TestAmerica Job ID: 160-14366-1 Client: Perma-Fix Environmental Services Inc.
Project/Site: HDP Metals Prep Batch: 217468 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Solid None 160-14364-A-14-E MS Matrix Spike Total/NA Solid None 160-14364-A-14-F MSD Matrix Spike Duplicate Total/NA Solid None 160-14366-1 L03-02-25-P-S-B-00 Total/NA Solid None 160-14366-2 L03-02-26-P-S-B-00 Total/NA Solid None LCS 160-217468/2-A Lab Control Sample Total/NA Solid None MB 160-217468/1-A Method Blank Total/NA Analysis Batch: 217906 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Solid 6020A 217468 160-14364-A-14-E MS Matrix Spike Total/NA Solid 6020A 217468 160-14364-A-14-F MSD Matrix Spike Duplicate Total/NA Solid 6020A 217468 160-14366-1 L03-02-25-P-S-B-00 Total/NA Solid 6020A 217468 160-14366-2 L03-02-26-P-S-B-00 Total/NA Solid 6020A 217468 LCS 160-217468/2-A Lab Control Sample Total/NA Solid 6020A 217468 MB 160-217468/1-A Method Blank Total/NA General Chemistry Analysis Batch: 217496 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Solid Moisture 160-14363-A-1 DU Duplicate Total/NA Solid Moisture 160-14366-1 L03-02-25-P-S-B-00 Total/NA Solid Moisture 160-14366-2 L03-02-26-P-S-B-00 Total/NA Rad Leach Batch: 217185 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Solid Dry and Grind 160-14346-A-1-D DU Duplicate Total/NA Leach Batch: 217466 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Solid Dry and Grind 160-14366-1 L03-02-25-P-S-B-00 Total/NA Solid Dry and Grind 160-14366-2 L03-02-26-P-S-B-00 Total/NA Prep Batch: 217468 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Solid None 160-14364-A-14-E MS Matrix Spike Total/NA Solid None 160-14364-A-14-F MSD Matrix Spike Duplicate Total/NA Solid None 160-14366-1 L03-02-25-P-S-B-00 Total/NA Solid None 160-14366-2 L03-02-26-P-S-B-00 Total/NA Solid None LCS 160-217468/2-A Lab Control Sample Total/NA Solid None MB 160-217468/1-A Method Blank Total/NA Prep Batch: 217683 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Solid Fill_Geo-0 217185 160-14346-A-1-D DU Duplicate Total/NA Solid Fill_Geo-0 217466 160-14366-1 L03-02-25-P-S-B-00 Total/NA Solid Fill_Geo-0 217466 160-14366-2 L03-02-26-P-S-B-00 Total/NA Solid Fill_Geo-0 LCS 160-217683/2-A Lab Control Sample Total/NA TestAmerica St. Louis Page 15 of 17 10/26/2015 1
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QC Association Summary TestAmerica Job ID: 160-14366-1 Client: Perma-Fix Environmental Services Inc.
Project/Site: HDP Rad (Continued)
Prep Batch: 217683 (Continued)
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Solid Fill_Geo-0 MB 160-217683/1-A Method Blank Total/NA TestAmerica St. Louis Page 16 of 17 10/26/2015 1
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Tracer/Carrier Summary TestAmerica Job ID: 160-14366-1 Client: Perma-Fix Environmental Services Inc.
Project/Site: HDP Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Prep Type: Total/NA Matrix: Solid Lab Sample ID Client Sample ID (30-110)
Re 85 160-14364-A-14-E MS Percent Yield (Acceptance Limits)
Matrix Spike 84 160-14364-A-14-F MSD Matrix Spike Duplicate 85 160-14366-1 L03-02-25-P-S-B-00 83 160-14366-2 L03-02-26-P-S-B-00 86 LCS 160-217468/2-A Lab Control Sample 84 MB 160-217468/1-A Method Blank Tracer/Carrier Legend Re = Re TestAmerica St. Louis Page 17 of 17 10/26/2015 1
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