ML18018B710

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Forwards Addl Info Re post-accident Sampling Sys,Per SER License Condition 3 Concerning Accuracy,Range & Sensitivity of Radionuclide & Chemical Analysis
ML18018B710
Person / Time
Site: Harris Duke Energy icon.png
Issue date: 07/03/1984
From: Zimmerman S
CAROLINA POWER & LIGHT CO.
To: Harold Denton
Office of Nuclear Reactor Regulation
References
NLS-84-262, NUDOCS 8407110257
Download: ML18018B710 (7)


Text

REGULATOR INFORMATION DISTRIBUTION TEM (RIDS)

ACCESSION NBR: 8407110257 DOC ~ DATE! 84/07/03 NOTARIZED:

NO FAGILs50 400 'Shearon Harr is,Nuclear Power Pl anti Uni t ii 'Car ol ina AUTH,NAME<,,

A/THOR AFFILIATION zIMMERMANEs~ R,

'carolina Power 8 Light co.

'REC IP NAME RECIPIENT APF IL'IATION DENTONEH ~ RE Officet of Nuclear

~ Reactor Regulatloni Directar

SUBJECT:

Forwards addi info re post accident sampling sysiper SER License condition 3 concerning accur acyEr ange 8, sensitivi,ty of radionuclide L chemcial

analysis, DISTRIBUTION CODEI BOOtS COPIES RECEIVED:LTR

. i" ENCL SIZEI TITLE'i Licensing 'Submittal:

PSAR/FSAR Amdts L Related orresponden e

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24 NRR/DHFS/HFEB40 NRR/DHFS/PSRB NRR/DS I'/AEB

'26 NRR/DSI/CPB 10 NRR/DSI/I'CSB 16 NRR/DSI/PSB 19 NRR/DSI/RSB 23 RGN2 EXTERNAL! ACRS 41-DMB/DSS-(AMDTS)

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Carolina Power & Light Company g 1984 SERIAL:

NLS-84-262 Mr. Harold R. Denton, Director Office of Nuclear Reactor Regulation United States Nuclear Regulatory Commission Washington, DC 20555 SHEARON HARRIS NUCLEAR POWER PLANT UNIT NOo 1

DOCKET NO ~ 50 400 POST-ACCIDENT SAMPLING SYSTEM

Dear Mr. Denton:

Carolina Power

& Light Company (CP&L) hereby submits additional information concerning the Shearon Harris Nuclear Power Plant Post-Accident Sampling System.

This information is provided in response to Safety Evaluation Report (SER) License Condition No.

3 from the Chemical Engineering Branch.

This information responds specifically to the part of Subitem (3) concerning

accuracy, range and sensitivity of each radionuclide and chemical analysis.

If you have any questions or require additional information, please feel free to contact me.

Yours very truly, S..

Zitm erman Man er Nuclear censing Section ESS/ccc (240NLU)

CC:

Mr. B. C, Buckley (NRC)

Mr. G. F. Maxwell (NRC-SHNPP)

Mr. James Wing (NRC-CHES)

Mr. J.

P. O'Reilly (NRC-RII)

Mr. Travis Payne (KUDZU)

Mr. Daniel F.

Read (CHANGE/ELP)

Chapel Hill Public Library Wake County Public Library Mr. Wells Eddleman Mr. John D. Runkle Dr. Richard D. Wilson Mr. G. 0. Bright (ASLB)

Dr. J.

H. Carpenter (ASLB)

Mr. J. L. Kelley (ASLB) 8407li0257 840703 PDR ADOCK 05000400 PDR

~

i 411 Fayetteville Street o P. O. Box 1551 o Raleigh. N. C. 27602

Shearon Harris Nuclear Power Plant Safety Evaluation Report License Condition No.

3 Item:

The applicant stated that periodic operational testing of the post-accident sampling system will be performed, but has not indicated the frequency and type of testing and operator training requirements for post-accident sampling.

The Staff has determined that the proposed post-accident sampling system partially meets the acceptance criteria of Item II.B.3 in NUREG-0737.

Before exceeding 5 percent power operation, the applicant shall have installed and have operational the post-accident sampling system.

Before 5 percent power operation, the applicant also shall (1) submit for NRC approval a core damage assessment procedure that incorporates, as a minimum, hydrogen levels, reactor coolant system

pressure, core exit thermocouple temperatures, and containment radiation levels, in addition to radionuclide data; (2) demonstrate applicability of procedures and instrumentation in the post-accident water chemistry and radiation environment, and retraining of operators on semiannual basis; (3) provide the plant procedures for chemical analyses and provide the accuracy,
range, and sensitivity of each of the radionuclide and chemical analyses.

RESPONSE

The Post-Accident Sampling System (PASS) shown on FSAR Figure 9.3.2-1 provides the capability to obtain diluted and undiluted samples of the containment atmosphere and the reactor coolant system and to analyze reactor coolant for dissolved

oxygen, pH, hydrogen, and total gas.

The diluted and undiluted samples will be subjected to laboratory analysis for radionuclides, chlorides, and boron concentration.

The indications from the post-accident control panel and results from laboratory analyses are used in conjunction with the core damage assessment procedure to estimate core damage.

For further system description, see FSAR Section 9.3.2.2.3, Amendment No. 5.

The accuracy,

range, and sensitivity of each radionuclide and chemical analysis is listed below:

I.

Reactor Coolant A.

PASS Online Anal ses 1.

Dissolved Ox en The dissolved oxygen sample measurement is obtained by passing reactor coolant through the dissolved oxygen probe assembly.

The oxygen measurement has an accuracy of

+ 1 percent of signal or + 1 ppb, whichever is greater.

The dissolved oxygen is indicated and recorded continuously in the range of 0-20 ppm.

The sensitivity of the oxygen analyzer is 0.05 percent of full scale.

(240NLU/ccc)

'based strictly on the accuracy of the analysis proceduxes employed in the laboratory.

The accuracy of the volume of sample (10 ml) is not a factor since the laboratory will use a

measured aliquot for each particular analysis.

2.

Diluted Li uid Grab Sam le The diluted liquid sample is obtaine by capturing a

.1 ml sample of reactor coolant in a specially designed valve bore.

The

.1 ml sample is then flushed with 100 ml of dilution water from a syringe into a sample bottle.

This equates to a 100:1 dilution.

The accuracy of the dilution is determined by three factors; the accuracy of the valve bore, the accuracy of the 100 ml syringe, and the accuracy of the laboratory analysis.

The valve bore has an accuracy of better than +

1 percent.

The syringe has an accuracy of +

1 percent.

Coupling these two accuracies gives an overall dilution accuracy of k 2 percent.

Once in the laboratory, the 100.1 ml of sample will be aliquoted as required by the analysis.

The laboratory analysis accuracy will be added to the dilution accuracy for an overall accux'acy range.

3.

Diluted Gas Grab Sam le The diluted gas grab sample is obtained by blending dilution gas with the stripped gas effluent from the phase separator.

The dilution is adjustable from 1:I to 1000:1.

The diluted sample is then captured in a sample cylinder and transferred to the lab for analysis.

The accuracy of the measurements is based on the accuracy of the dilution and the accuracy of the laboratory analysis.

The accuracy of the gas-blending unit is +

1 percent.

For laboratory analysis, the sample will then be aliquoted from the sample cylinder by syringe or other means and analyzed in the laboratory.

II.

Containment Atmos here NUREG-0737 II.B.3 also requires the capability to obtain containment atmosphere samples for determination of the hydrogen levels in containment and quantification of containment atmosphere radionuclides.

The post-accident hydrogen monitoring system is described in FSAR Section 6.2.5.1.3.

The redundant in-line hydrogen analyzer samples containment air and measures the hydrogen concentration with a range of 0-10 percent hydrogen (by volume) and an accuracy of + 2 percent of full scale.

The sensitivity of the containment atmosphere hydrogen analyzer is 0.1 percent hydrogen by volume.

A containment atmosphere sample for quantification of radionuclides is obtained via the hydrogen analyzer cabinet by the remote sample dilution panel as shown on FSAR Figuxe 6.2.5-7 (Amendment 14).

The sample line is heat traced to limit plateout prior to sample collection.

The remote sample dilution panel provides a grab sample of containment atmospheric gases and a diluted or undiluted cooled gas sample for further radiological analysis.

An iodine sample is obtained via a silver zeolite filter cartridge.

The containment atmosphere sample is collected (240NLU/ccc)

~'n a

10 cc or 150 cc grab sample cylinder with dilution as required.

The gas sample is diluted with dilution gas in the 10 cc cylinder with an accuracy of 5 percent.

The 150 cc sample will have a greater accuracy therefore the 10 cc sample accuracy is the limiting value.

The sample panels pressure transducer range is 0-10,000 mm Hg with a reading accuracy of t 1.5 percent.

The dilution accuracy will be verified after the dilution equipment is calibrated and the system functional performance test is completed.

(240NLU/ccc)