ML16342D363

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Insp Repts 50-275/96-08 & 50-323/96-08 on 960603-07.No Violations Noted.Major Areas Inspected:Solid Radioactive Waste Mgt,Transportation of Radioactive Matl & Programs for Secondary & Primary Chemistry
ML16342D363
Person / Time
Site: Diablo Canyon  Pacific Gas & Electric icon.png
Issue date: 07/10/1996
From:
NRC OFFICE OF INSPECTION & ENFORCEMENT (IE REGION IV)
To:
Shared Package
ML16342D364 List:
References
50-275-96-08, 50-275-96-8, 50-323-96-08, 50-323-96-8, NUDOCS 9607160164
Download: ML16342D363 (48)


See also: IR 05000275/1996008

Text

ENCLOSURE

U.S.

NUCLEAR REGULATORY COMMISSION

REGION IV

Docket Nos.:

License'os.:

Report No.:

Licensee:

Facility:

Location:

Dates:

Inspectors:

Approved By:

50-275

50-323

DPR-80

DPR-82

50-275/96-08

50-323/96-08

Pacific Gas

and Electric Company

Diablo Canyon Nuclear

Power Plant, Units

1 and

2

7 1/2 miles

NW of Avila Beach

San Luis Obsipo, California

June 3-7,

1996

Larry T. Ricketson,

P.E.,

Senior Radiation Specialist

Plant Support

Branch

J. Blair Nicholas.

Ph.D.. Senior Radiation Specialist

Plant Support Branch

Blaine Murray, Chief, Plant Support

Branch

Division of Reactor Safety

ATTACHMENT:

Partial List of Persons

Contacted

List of Inspection

Procedures

Used

List of Items Opened,

Closed,

and Discussed

List of Acronyms

9607i60164 9607i0

PDR

ADQCK 05000275

8

PDR

1

0

-2-

EXECUTIVE SUMMARY

Diablo Canyon Nuclear

Power Plant,

Units

1 and

2

NRC Inspection Report 50-275/96-08;

50-323/96-08

These routine.

announced

inspections

focused

upon the licensee's

programs for

solid radioactive waste

management

and transportation of radioactive materials

and the programs for secondary

and primary chemistry.

Plant

Su

ort

A good solid radioactive waste

management

program was implemented.

Aggressive

measures

were taken to reduce the generation of radioactive

waste.

Waste

was properly classified

and characterized

for burial.

Improvement

was needed

in how radioactive waste

was stored to prevent

potential

personnel

safety hazards

(Section Rl. 1).

A good radioactive materials

and radioactive waste transportation

rogram was

implemented.

The licensee

was properly implementing the

atest revisions of transportation

regulations

(Section R1.2).

The water chemistry

and radiochemistry

programs

were effectively

implemented.

Target levels, action levels,

and corrective actions for

out-of-specification chemistry conditions were properly established

and

implemented

(Section Rl.3).

The reactor

shutdown chemistry control for Refueling Outage

1R7 was not

successful

in reducing the source term to less than that experienced

in

Refueling Outage

1R6.

The reactor

shutdown chemistry control program

implemented for Refueling Outage

2R7 was successful

in reducing the

source term and radiation exposure to personnel.

The implementation of

the reactor

shutdown chemistry control program to reduce the source term

during refueling outages

improved from Refueling Outage

1R7 to Refueling

Outage

2R7 (Section R1.4).

The analytical

instruments

in the secondary

and primary chemistry

laboratories

and the radiochemistry counting facility were properly

calibrated.

and

a good quality control program was implemented

(Section R2.1).

Solid radioactive waste

management

and radioactive waste/material

transportation

procedures

provided adequate

guidance

(Section R3.1).

Good water chemistry and radiochemistry

programmatic

procedures

were

established

and implemented

(Section R3.2).

Radiation protection foremen,

radwaste

engineers,

and radiation

protection technicians

demonstrated

a good knowledge of radioactive

material

and radioactive waste transportation

requi rements

(Section R4.1).

0

-3-

The analytical

performance quality control program was properly

implemented

(Section R4.2).

Generally,

workers were qualified for the tasks

performed.

Appropriate

training was provided to all individuals taking part in transportation

activities,

except utility workers (laborers).

The training adequately

addressed

the revisions in the transportation

regulations

(Section

R5.1)

.

An excellent continuing training program was implemented for the

chemistry technical staff.

The licensee

maintained

a well trained

and

qualified staff to effectively implement the water chemistry and

radiochemistry

programs.

The training chemistry laboratory was

considered

a strength

(Section R5.2).

The stability of the chemistry section's staffing provided

a high

reliability of chemistry program performance

and was considered

a

strength

(Section

R6. 1).

Oversight of solid waste

management

and transportation activities was

'inimal.

Programmatic oversight of transportation activities was

lacking, but reviews

by quality control personnel

sufficed to ensure

regulatory compliance.

Audits in this area would benefit from auditors

with more specialized

experience

(Section

R7. 1).

An excellent,

comprehensive

audit and excellent

assessments

of the

chemistry/radiochemistry

program were performed

by the quality assurance

organization.

Excellent oversight of the water chemistry

and

radiochemistry

programs

was achieved

(Section R7.2).

4

Re ort Details

Summar

of Plant Status

The plant operated

at full power during the entire inspection period.

There

were ho operational

occurrences

that impacted the two inspections.

IV.

Plant

Su

ort

Rl

Rl.l

Radiological Protection

and Chemistry

(RP8C) Controls

Solid Radioactive

Waste

Mana ement

Pro

ram

Ins ection Sco

e

86750

Waste processing

areas

were toured,

selected

waste classification

and

characterization

documentation

was reviewed,

and cognizant licensee

personnel

were interviewed.

Observations

and Findin s

Through record reviews, the inspector verified that radioactive waste

streams

were sampled

and analyzed

as required.

Analyses to determine

scaling factors for nongamma-emitting

nuclides were performed

by

a

vendor laboratory.

Scaling factors were updated regularly,

incorporating the latest waste stream analysis results.

The inspector

reviewed documentation

for selected

examples of

radioactive waste

packaged for burial

and determined that the waste

was

proper ly classified

and characterized.

The inspector confirmed. through document

reviews

and personnel

interviews, that the licensee

implemented

an aggressive

waste reduction

program.

Since

1992. the licensee

reduced waste generation

approximately

50 percent.

The inspector

toured the radioactive waste processing

and storage

areas.

No problems were identified, except in Vault 26 of the radioactive waste

storage

area.

Barrels of radioactive waste

wer e placed

on wooden

pallets

and stacked three tiers high.

The inspector

noted

one barrel

(96-D-031)

on the top level protruding approximately

30 percent over the

'edge of its pallet.

Licensee

personnel later stated that the barrel

contained

compacted

dry activated waste

and weighed 453 pounds.

The inspector

expressed

a concern that the barrel

posed

a personnel

safety hazard, if it fell because of seismic activity or any other

reason with people in the area.

Licensee representatives

acknowledged

the inspector 's concern

and restacked

the barrel.

Licensee

representatives

stated that barrels

were sometimes

compressed slightly

during the compaction operations.

When this occurred. all barrels

were

-5-

not the

same height; therefore,

the surface.

on which the next layer

of'allets

and barrels

were stacked,

was not level making the configuration

unstable.

To correct this situation,

licensee

representatives

stated

that they would evaluate the use of metal shelving in the barrel

storage

area to provide

a more stable

base

on which to set

loaded barrels.

Conclusions

A good solid radioactive waste

management

program was implemented.

Aggressive

measures

were taken to reduce the generation of waste.

Waste

was properly classified

and characterized

for burial.

Improvement was,

needed in the manner in which some waste

was stored to prevent potential

personnel

safety hazards.

Trans ortation of Radioactive

Waste

and Radioactive Materials

Ins ection Sco

e

86750

TI 2515/133

Documentation for selected

radioactive materials

and radioactive waste

shipments.

certificates of compliance for NRC certified containers,

consignee

radioactive materials

licenses,

and licensee

reference

material

were reviewed.

Observations

and Findin s

A random review by the inspector confi rmed that the licensee

maintained

copies of applicable certificates,

licenses,

and regulations.

Shipping papers for radioactive materials

shipments

contained the

information required

by 49 CFR 172, Subpart

C.

In addition to this

information, radioactive waste shipment documentation

included manifests

that conformed to the requi rements of 10 CFR Part 20, Appendix F and

49 CFR 173.433.

Shipping documents

included radioactive source activity

measurements

recorded in international

system (SI) units

as well as

customary units.

Emergency telephone

numbers

and backup

emergency

contact telephone

numbers

included with the shipping papers

were

current.

Photographs

of radioactive waste shipments

confirmed that shipments

were

properly labeled,

marked.

and placarded,

when applicable.

Radiation

survey records indicated that radiation

and contamination levels of

shipments

were within regulatory limits:

No problems

were identified at the waste burial site, involving the

licensee's

shipments,

during the previous two years.

a

Conclusions

A good radioactive materials

and radioactive waste transportation

program was

implemented.

The licensee

was properly implementing the

latest regulatory revisions.

Li ht Water

Reactor

Chemistr

Control

Ins ection

Sco

e

84750

The water chemistry

and radiochemistry analytical

data were reviewed.

Observations

and Findin s

The inspector

reviewed secondary

water chemistry data

and reactor

coolant chemistry data for 1995 and the first quarter of 1996 to

determine

compliance with Technical Specification requirements.

It was

verified that required water chemistry

and radiochemistry

sampling

and

analyses

were performed in both units.

The review included

an

inspection of secondary

water quality data.

steam generator water

chemistry

and radiochemistry data,

and reactor coolant water chemistry

and radiochemistry

data plotted from the data

recorded in the

computerized

chemistry data

management

system.

The inspector

reviewed

the records of out-of-specification chemical

parameters

and the

licensee's

corrective actions taken when chemistry parameters

did not

meet established

chemistry control limits.

Very few out-of-specification chemistry conditions were noted during

normal plant operation.

Host of the out-of-specification chemistry

conditions resulted during plant evolutions (e.g. reactor

shutdown

or

startup)

and were promptly corrected

and brought to within the

applicable chemistry control limits.

The licensee's

chemistry control limits for secondary

and primary water

systems

were established

according to the Electric Power

Research

Institute (EPRI) guidelines for pressurized

water reactor secondary

and

primary water chemistry.

The licensee

had established

target levels,

action levels,

and corrective actions for out-of-specification chemistry

conditions.

The action levels

and corrective actions to

'ut-of-specification

chemistry conditions were strictly enforced.

The review of the secondary

chemistry data for Units

1 and

2 during the

first quarter of 1996 indicated only minor out-of-specification

conditions involving sulfate in the steam generators,

hydr azine

and iron

in the feedwater,

and dissolved

oxygen in the condensate.

Primary chemistry

and radiochemistry data for Units

1 and

2 for the

period of 1995 through the first quarter of 1996 were reviewed.

The

data indicated that all reactor

coolant system chemistry parameters

required

by Technical Specifications

were maintained within

)I

-7-

specification.

The only non-technical

specification reactor coolant

system chemistry parameter

which was not maintained at all times within

the target operational

concentration limits was the lithium

concentration.

c.

Conclusions

The water chemistry

and radiochemistry

programs

were effectively

implemented.

Target levels'ction levels,

and corrective actions for

out-of-specification chemistry conditions were properly, established

and

implemented.

R1.4

Refuelin

Outa

e Chemistr

Control

a.

Ins ection Sco

e

84750

The chemistry control program during reactor operation

and during

shutdown prior to an outage

was reviewed to determine the effectiveness

in reducing the radiation source term during plant operation

and

especially during plant outages.

b.

Observations

and Findin s

The licensee

implemented

a three step chemistry control program to

reduce the radiation source term during plant operation

and especially

during plant outages.

~

The first step

was to control

and maintain the

pH 'of the reactor

coolant during normal plant operation in a band from 6.9 to'7.6 to

minimize corrosion

formation and buildup in the reactor primary

system.

The second

step

was to establish

an acidic reducing envi ronment in

the reactor coolant system to maintain the corrosion products in a

soluble state

so that they would be removed

by filters and

demineralizers;

and therefore,

minimize crud deposition

and crud

bursts during outage conditions.

Additionally, hydrogen peroxide

was injected into the reactor coolant system to shock the system

from a chemically reducing environment during cool-down to a

chemically oxidizing envi ronment.

This made corrosion

products

soluble so that they would be removed from the reactor coolant

system

by filters and demineralizers.

~

The third step

was to control the reactor coolant system startup

chemistry

and reduce nickel buildup in the reactor primary system.

During the Unit 1 Refueling Outage

1R7 conducted in September

1995, the

licensee initiated the chemistry control program. described

above in an

attempt to reduce the radiation source term.

A total of 3083 curies of

-8-

cobalt-58,

38 curies of cobalt-60,

and 4010 grams of nickel were removed

from the reactor coolant system during the shutdown.

Immediately following the hydrogen peroxide addition, the cobalt-58

activity peaked at 6.79 microcuries

(pCi) per milliliter (ml). and the

cobalt'-60 activity peaked at 6.33E-02 pCi/ml.

One reactor coolant

pump

was run for approximately 3.5 hours5.787037e-5 days <br />0.00139 hours <br />8.267196e-6 weeks <br />1.9025e-6 months <br /> after the hydrogen peroxide

addition.

The cobalt-58 activity was reduced

from 6.79 pCi/ml to

4.57 yCi/ml.

This did not allow for sufficient cleanup of the reactor

coolant system,

and the dose rates

measured

in the steam generator

bowls

and reactor coolant piping were significantly higher than the dose rates

experienced

.during the Unit 1 Refueling Outage

1R6.

The dose rates

had

increased

50 percent in 3 of the steam generator

bowls and

100 percent

in the fourth steam generator

bowl.

Additionally, dose rates throughout

the reactor primary system

as well as

above the flooded reactor

cavity

were approximately

25 to 35 percent greater

than during Refueling Outage

1R6.

The effective average

dose rate for refueling work in containment

increased

to 7.45 milli rems

(mrems) per man-hour during Refueling Outage

1R7 compared to 4.43 mrems/man-hour

during Refueling Outage

1R6.

The

inspector

concluded that the reactor

shutdown chemistry control program

for Refueling Outage

1R7 was not successful

in reducing the source term

and contributed to the higher doses

in the steam generators

and the

reactor primary system than previously experienced

in Refueling Outage

1R6.

The licensee identified the following contributory causes

for the high

dose rates in the steam generators

and the reactor primary system during

Refueling Outage

1R7:

The reactor coolant system

was not sufficiently cleaned

up prior

to the floodup of the reactor cavity.

The demineralizer

used

during the shutdown for the reactor coolant cleanup

exhausted

earlier than expected,

and it took approximately

2 days to get

a

new demineralizer

back in service.

Also, after the reactor cavity

floodup, it took much longer to cleanup the reactor

coolant system

because

of the increased

volume from 100,000 gallons to 400,000

gallons in the reactor coolant system.

During a unit trip approximately

3 weeks prior to the refueling

outage,

crud was'deposited

in the reactor core region.

The end of

operating cycle reactor

coolant

pH (7.5-7.6) facilitated the

transport of the activated corrosion products

from the reactor

core region to the steam generator

bowls.

From the lessons

learned during Refueling Outage

1R7, the licensee

proposed the following corrective

actions to be incorporated into the

Unit 2 Refueling Outage

2R7 schedule to increase

the success

of the

reactor

coolant system cleanup during the reactor

shutdown

and the

reduction of source term and personnel

dose.

J

f

~

Operate at

a lower pH (7.4 versus 7.6) during the end of the

operating cycle to minimize the transport of activated corrosion

products

from the core into the steam generators

prior to

shutdown.

~

Strictly adhere to fPRI recommended activity cleanup limits in the

reactor coolant system prior to floodup of the reactor cavity.

~

Maintain acid reducing conditions in the reactor

coolant system

during cooldown, for a minimum of 24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br /> to ensure

complete

decomposition of the nickel ferrites.

~

Maintain

a spare cation demineralizer

loaded

and available

should

the first shutdown cation demineralizer

exhaust early.

Run the reactor coolant

pumps for a minimum of 24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br /> after the

addition of hydrogen peroxide to the reactor coolant system.

During Refueling Outage

2R7 conducted in April 1996, the licensee

initiated the chemistry control program described

above to reduce the

radiation source term.

A total of 2360 curies of cobalt-58,

19.2 curies

of cobalt-60.

and 4420 grams of nickel were removed from the reactor

coolant system during the shutdown.

Immediately following the hydrogen peroxide additions

the cobalt-58

and

cobalt-60 activities peaked at 3.4 pCi/ml and 1.3E-02 yCi/ml,

respectively.

Two reactor coolant

pumps were run for approximately

27

hours after the hydrogen peroxide addition to facilitate

maximum reactor

coolant system cleanup.

The cobalt-58 activity was reduced

from a

maximum concentration of 3.4 pCi/ml to 7.6E-01 pCi/ml.

The total cumulative outage

exposure through core off 'load was reduced

from 45 man-rems during Refueling Outage

2R6 to 35 man-rems during

Refueling Outage

2R7.

The inspector concluded that these radiation dose

'eductions

were

a direct result of the licensee successfully

implementing the reactor

shutdown chemistry control program.

c.

Conclusions

The reactor

shutdown chemistry control program for Refueling Outage

1R7

was not successful

in reducing the source

term to less than previously

experienced

in Refueling Outage

1R6.

The effective average

dose rate

for refueling work in containment during Refueling Outage'R7

was

reduced

by approximately

40 percent

from that experienced. during

Refueling Outage

2R6 as

a result of the implementation of a more

effective and controlled reactor

shutdown chemistry control program.

The reactor

shutdown chemistry control program implemented for Refueling

Outage

2R7 was successful

in reducing the source term and radiation

exposure to personnel.

The implementation of the reactor

shutdown

-10-

R2

R2.1

chemistry control program to reduce the source term during refueling

outages

improved from Refueling Outage

1R7 to Refueling Outage

2R7.

Status of RP8C Facilities and Equipment

A recent discovery of a licensee operating their facility in a manner

contrary to the Updated Final Safety Analysis Report

(UFSAR) description

highlighted the need for a special

focused

review that compares

plant

practices,

procedures

and/or

parameters

to the

UFSAR descriptions.

While performing the inspections

discussed

in this report. the

inspectors

reviewed the applicable portions of the

UFSAR that related to

the areas

inspected.

The inspectors verified that the

UFSAR wording was

consistent with the observed plant practices,

procedures

and/or

parameters.

Secondar

and Primar

Chemistr

Laboratories

Ins ection Sco

e

84750

The secondary

chemistry laboratories,

secondary

chemistry sample

rooms

and associated

in-line process

instrumentation,

and primary chemistry

laboratory for both units were inspected.

The calibration

and quality

control programs for the analytical

instrumentation in the secondary

and

primary chemistry laboratories

and radiochemistry counting facility were

reviewed.

Observations

and Findin s

The secondary

chemistry laboratories

were equipped with state-of-the-art

analytical instrumentation to perform the required analyses'n

in-line

ion chromatograph

was installed in each of the units for continuous

online analyses

of anions

and cations

and to monitor chemical

parameters

in the secondary

water systems.

State-of-the-art in-line process

instrumentation

was installed in the secondary

chemistry sample

rooms of

both units.

The in-line process

instrumentation

in the sample

rooms of

both units was calibrated,

and

an instrument quality control program was

implemented.

During the inspection, all in-line process

instrumentation

in both secondary

chemistry sample

rooms was operational.

The analytical

instruments

in the secondary

chemistry laboratories

and

primary chemistry laboratory were calibrated,

and

an instrument quality

control program was implemented.

The licensee

was using instrument

quality control charts to trend quality control data.

Th'e inspector

reviewed the quality control data charts for 1996 for selected

analytical

instruments

in the secondary

and primary chemistry

laboratories

and found them satisfactory.

The analytical

instruments

in

the secondary

and primary chemistry laboratories

were properly

calibrated.

and

a good quality control program was implemented.

0

R3

R3. 1

The radiochemistry counting facility instrumentation

and selected

detector calibration and quality control data were inspected.

Sufficient state-of-the-art

analytical

instrumentation

was maintained to

perform the required radiochemistry analytical

measurements.

The

radiochemistry counting facility's instruments

were properly calibrated,

and

a good quality control program was implemented.

Conclusions

The secondary

and primary chemistry laboratories

and radiochemistry

counting facility were equipped with state-of-the-art

analytical

instrumentation to perform the required analyses.

The analytical

instruments

in the secondary

and primary chemistry laboratories

and the

radiochemistry counting facility were properly calibrated,

and

a good

quality control program was implemented.

RP8C Procedures

and Documentation

Radiation Protection

Procedures

Ins ection Sco

e

TI 2515/133

Selected solid radioactive waste

management

and transportation

procedures

were reviewed.

b.

Observations

and Findin s

Procedure

RCP D-631, "Radioactive Materials Shipments,"

Revision

1,

and

Procedure

RCP RW-4. "Solid Radioactive

Waste Shipment," Revision

12,

were reviewed.

Procedure

RCP D-631 addressed

revisions in regulatory

requi rements,

such as,

the division of the low specific activity

category into subcategories

and the introduction of the surface

contaminated

object category.

The procedure also included guidance in

the use of international units on shipping papers.

Procedure

RCP 0-631 was sometimes

cumbersome to use.

This was, in part,

because of the inconsistent

manner in which it implemented regulatory

requirements.

In some cases,

the procedure

restated

requirements,

such

as when instructing the reader

on low specific activity subcategories;

and in other cases, it simply referenced

the regulatory requirements.

In the latter cases.

the reader

had to refer to the specific regulation'.

As

a specific example,

Section 7.2.g. of Procedure

RCP D-,631 instructed

the reader to record the Department of Transportation A-values, but did

not include

a reference to the location of the values.

The reader

had

to review the definition of A-values in Section

3 of the procedure to

find the regulatory reference.

then refer to 49

CFR 173.433

or

49

CFR

173.435 to determine the values.

Aside from this. the procedure

provided adequate

guidance.

R3.2

R4

R4.1

-12-

Procedure

RCP

RW-4 needed

minor editorial revisions.

The procedure

referenced

a subdivided fissile class of materials

and

NRC Region

V (in

reference to filing reports).

Neither reference

was appropriate.

The

procedure

revision reviewed

became effective April 15,

1996.

Conclusions

Procedures

established

to implement the solid radioactive waste

and

transportation

programs

provided adequate

guidance.

Secondar

and Primar

Chemistr

Procedures

Ins ection Sco

e

84750

Selected

water chemistry

and radiochemistry

procedures

were reviewed.

Observations

and Findin s

Chemistry department

admi'nistrative procedures,

chemistry control

procedures,

sampling

and analyses

procedures.

and calibration and

quality control procedures

for in-line process

instrumentation

and

laboratory analytical

instruments

were written and approved.

A review

of selected

procedures

revised since the previous

NRC chemistry

inspection

conducted in July 1994 indicated that the chemistry

and

environmental

operations

department

had revised

and implemented

adequate

procedures

which met the commitments in the

UFSAR and Technical

Specifications for both units.

Conclusion

The licensee

had established

and implemented

good water chemistry

and

radiochemistry

programmatic procedures.

Staff Knowledge and Performance

Radiation Protection Staff

Ins ection Sco

e

TI 2515/133

Radiation protection foremen,

radwaste

engineers.

and radiation

protection technicians

were interviewed with regard regulatory

requirements

for transportation of radioactive waste/materials.

Observations

and Findin s

Radiation protection foremen,

radwaste

engineers,

and radiation

protection technicians

were knowledgeable of regulatory requirements

and

recent regulatory revisions.

Other than

a laundry shipment,

no

radioactive shipments

were conducted the week of the inspection.

-13-

Therefore.

the inspector

was unable to make any observations

of actual

performance of shipping preparations.

Conclusions

Radiation protection

foremen,

radwaste

engineers,

and radiation

protection technicians

were familiar with radioactive material

and

radioactive waste transportation

requirements.

Chemical

and Radiochemical

Anal sis Performance

ualit

Control

Pro

ram

Ins ection Sco

e

84750

The chemistry section's

inter-laboratory chemical analysis

cross

check

program and radiochemical

analysis

intra-company cross

check program

were reviewed to determine the quality of analytical

performance in the

secondary

and primary chemistry laboratories

and radiochemistry counting

facility.

Observations

and Findin s

The licensee participated in a chemical analysis inter-laboratory cross

check program administered

by a contract laboratory

as

a means of

evaluating chemistry/radiation protection technician analytical

performance.

The inspector

reviewed the results of the licensee's

performance

during the period January

1995 through

May 1996 in the

chemical analysis inter -laboratory cross

check program of blind samples

in water- chemistry.

A high percentage

of the licensee's

analytical

results

met the contract laboratory's

acceptance criteria.

The licensee

also participated in a radiochemical

analysis

intra-company

cross

check program administered

by .the licensee's

Technical

and

Ecological Services

laboratory.

The inspector

reviewed the results of

the licensee's

performance

during the period January

1994 through

May 1996 of spiked samples

supplied semiannually to the station's

radiochemistry laboratory

and counting facility.

The licensee's

analytical results of the spiked samples

met the acceptance criteria

established

in the station's

Inter-departmental

Administrative

Procedure

CY1.ID1, "Radiochemical

Intracompany

Cross-Check

Program,"

Revision 2.

Conclusions

A good analytical

performance quality control program was properly

.implemented.

-14-

R5

R5

1

Staff Training and Qualification

Radiation Protection

Personnel

Ins ection Sco

e

TI 2515/133

Training materials,

attendance lists,

and the results of tests

taken by

students

related to training on the changes to the Department of

Transportation

and

NRC transportation

regulations

were reviewed.

Qualifications of quality assurance

personnel

is discussed

in Section

R7.1.

Observations

and Findin s

In-house training on packaging, transferring,

and transporting of

radioactive materials

was typically provided to select

employees

on an

annual

basis.

Individuals involved in transportation activities were

requi red to attend the training at two-year intervals.

However,

because

of the changes

in transportation

regu'lations,

the licensee elected to

have

a vendor present

the most recent training.

The inspector

reviewed the training material

and found it to be

comprehensive

regarding regulatory requirements

and regulatory changes.

The inspector

reviewed attendance lists and determined that radwaste

technicians

and supervisors,

quality control personnel,

and quality

assurance

personnel

attended

the training.

Utilityworkers (laborers) did not attend the training on regulatory

requirements.

However, through interviews with utility workers

and

supervisors,

the inspector determined that utility workers performed

various functions. including loading shipping containers,

sampling

radwaste filters, weighing radioactive materials

packages,

and blocking

and bracing packages

in preparation for shipment.

Subpart

H of 49

CFR requires in 172.702 that hazmat

employees

be trained

in the functions they perform.

The definition of a hazmat

employee

from

49 CFR 171.8 is

a person

who, in the course of employment, directly

affects hazardous

material transportation

safety.

49

CFR 172.704(a)

states that hazmat

employees

shall

be provided with training to provide

familiarity with the requirements

of that subchapter

. and 49

CFR

172.704(b) states that each

hazmat

employee shall

be provided function

specific training.

Information Notice No. 92-72 discussed

employee training requirements.

One of the examples of workers requiring training is that of individuals

who brace

and block packages

in preparation for transportation.

The

inspector identified the failure to provide the type of training

W

-15-

required

by 49

CFR 172.704 to utility workers

who directly affected

hazardous

material transportation

safety

as

a violation of

49 CFR 172.702.

The inspector

determined

through interviews that the licensee

had

experienced

no problems related to the shifting of loads during

radioactive shipments.

'icensee

representatives

stated that utility

workers worked under the supe~vision of radiation protection

technicians.

Radiation protection technicians

were trained in bracing

and blocking of packages

for transport

as part of their accredited

training program.

This failure constitutes

a violation of minor

significance

and is being treated

as

a non-cited violation, consistent

with Section

IY of the

NRC Enforcement Policy (50-275/9608-01;

50-323/9608-01).

Conclusions

Generally,

workers were qualified for the tasks

performed.

Appropriate

training was provided to all individuals taking part in transportation

activities,

except utility workers.

Training provided to workers

adequately

addressed

the revisions in the transportation

regulations.

Chemistr

Trainin

and

uglification

Ins ection Sco

e

84750

Continuing training and qualification programs for the

chemistry/radiation protection technicians

assigned to the chemistry

organization

and the qualifications of selected

chemistry personnel

were

reviewed.

Observations

and Findin s

The inspector

interviewed the chemistry/radiation protection training

team leader

and the two training instructors for the chemistry staff and

determined that no p'ersonnel

had joined the chemistry organization

during the past

4 years.

Training records, qualification cards.

and

ANSI qualification worksheets for selected

members of the chemistry

technical staff were reviewed.

All chemistry/radiation protection

technicians

assigned to the chemistry organization

had completed the

initial training program and met the qualifications specified in

ANSI N3. 1-1978.

The licensee

had developed

a training matrix for

tracking the chemistry task training completed

by each of the

chemistry/radiation protection technicians.

A quality assurance

assessment

of the chemistry

and radiation protection

technician qualification program was performed in April 1996.

The

assessment

suggested

several

enhancements

to the qualification matrix.

-16-

R6

R6.1

The continuing training program for the chemistry/radiation protection

technicians,

as described

in Training Administrative Procedure

TQ2.DC5.

"Chemistry and Radiation Protection Technician Training." Revision 0,

was reviewed.

The chemistry organization's

continuing training

schedules

for 1995 and

1996 were reviewed.

The instructor training program and the experience

and training of'he

two chemistry training instructors

were reviewed.

The chemistry

training instructors were experienced

and well qualified.

The inspector

noted that the two chemistry training instructors.

as part of thei r

instructor continuing training program,

scheduled

8 hours9.259259e-5 days <br />0.00222 hours <br />1.322751e-5 weeks <br />3.044e-6 months <br /> per quarter

working in the plant with the plant chemistry staff to keep current with

plant chemistry activities and instrumentation.

The chemistry training laboratory maintained

by the learning services

department

was toured

and inspected.

The laboratory

was well equipped

and was considered

a strength for developing

new procedures

and

conducting initial training on new laboratory analytical

instrumentation.

Conclusions

An excellent continuing training program was implemented for the

chemistry technical staff.

A well trained

and qualified staff was

maintained to effectively implement the water

chemistry

and

radiochemistry

programs.

The training chemistry laboratory

was

considered

a strength.

RP8C Organization

and Administration

Chemistr

Or anization

and Staffin

Ins ection Sco

e

84750

The organization. staffing.

and assignment of the chemistry program

responsibilities

were reviewed.

Observations

and Findin s

Technical Specification 6.2 identified the licensee's facility

organizations.

The licensee's

organization, staffing,

and lines of

authority,

as they related to the chemistry section within the chemistry

and environmental

operations

department,

which was responsible for the

implementation of the water chemistry

and radiochemistry

programs,

were

reviewed.

There were no major structural

changes to the chemistry

organization since the previous

NRC inspection of the chemistry program

conducted in July 1994.

Also, there were no major

changes

in the

chemi stry program or the way in which the chemistry organization

functioned.

The inspector

concluded that the chemistry

and

-17-

R7

R7.1

environmental

operations

department's

organizational

structure

was in

accordance

with Technical Specifications.

Procedures

were reviewed for the assignment of responsibilities f'r the

management

and implementation of the chemistry program.

The inspector

determined that the duties

and responsibilities of the chemistry

organization

were implemented in an excellent

manner.

The inspector

determined,

through discussions

and observations,

that the chemistry

staff were familiar with the requirements of the water chemistry

and

radiochemistry

programs

and maintained

a high level of performance.

The inspector

reviewed the staffing of the chemistry section.

The

inspector

concluded that the chemistry section's

organization

was very

stable

and adequate to meet shift staffing requirements

and perform the

required duties.

The stability of the chemistry section's

organization

was considered

a strength.

Conclusions

The chemistry

and environmental

operations

department's

organizational

structure

met staffing requirements.

The chemistry section's staffing

was stable

and had experienced

no turnover of personnel.

The stability

of the chemistry section's staffing provided

a high reliability of

chemistry program performance

and was considered

a strength.

Quality Assurance in RPKC Activities

Solid Radioactive

Waste

Mana ement/Trans

ortation of Radioactive

Materials

Ins ection Sco

e

86?50

Quality assurance

personnel

were interviewed.

Quality assurance

audits,

quality assurance

assessments/surveillances,

quality control reviews,

and problem reports

were reviewed.

Observations

and Findin s

Technical Specification 6.5.3.8 j. requires that the process

control

program be audited every 24 months.

The licensee's

response,

dated

December

6,

1979, to

NRC Bulletin 79-19 committed to the auditing of

transportation activities.

The 1994 quality assurance

audit checklist

and results

were reviewed.

The executive

summary included little concerning the assessment

of

transportation activities.

However, the checklist for the audit

demonstrated

that aspects

of the transportation

program were reviewed.

The licensee

responded to the inspector 's request for the

1996 quality

assurance

audit of the solid radioactive waste

and transportation

-18-

activities by informing the inspector that they were conducting,

what

they termed,

a "continuous audit" of the solid radioactive waste

management

and transportation activities.

The draft of the 1996 quality

assurance

audit was reviewed.

The audit focused

on solid radioactive

waste

management

topics.

There was

no assessment

of transportation

activities.

Reviews to be included in the

1996 audit report began in September

1995

and were scheduled to end in July 1996.

Quality assurance

management

committed during the exit meeting to review transportation activities

before the audit period ended.

The inspector determined.

through interviews with quality assurance

personnel,

that few quality assurance

observations/sur vei llances

were

conducted to review either solid radwaste

management

or transportation

activities.

However, quality control personnel

frequently reviewed

transportation

documentation

and package preparation to ensure

compliance with regulatory requirements.

The inspector interviewed the personnel

who performed the 1996 audit and

determined that the individual responsible for conducting the majority

of the audit was

an experienced

auditor with operations

experience.

However, the auditor had little radiation protection experience.

The

other quality assurance

auditor had radiation protection experience

but.

because of other duties.

provided little input to the audit.,

The

quality control specialist

who performed periodic reviews of shipment

preparation

and documentation

had extensive

experience with the

transportation of radioactive materials

and radioactive waste.

Conclusions

Oversight of solid waste

management

and transportation activities was

minimal.

Oversight of transportation activities from a programmatic

perspective

was lacking. but reviews by quality control personnel

helped

to ensure regulatory .compliance.

Audits in this area

could benefit from

auditors with more experience in the area of review.

Chemistr

ualit

Assurance

Pro

ram

Ins ection Sco

e

84750

An audit and two assessments

of the chemistry program were reviewed.

Observations

and Findin s

The quality assurance

audit schedule for 1995-1996 issued

Hay 29,

1996,

was reviewed.

This schedule reflected

a biennial audit schedule for the

chemistry/radiochemistry

program.

The audit schedule

indicated that the

chemistry/radiochemistry

audit was to be performed in November of the

-19-

R8

R8.1

odd numbered years.

The audit schedule

was in compliance with the

Technical Specification audit frequency requirement.

The qualifications of the quality assurance

auditors

who performed the

audit of the chemistry program were reviewed.

The quality assurance

auditors were well qualified and knowledgeable of chemistry program

activities conducted at nuclear

power facilities.

Reports of a quality assurance

audit and two assessments

performed

during 1995 and

1996 of the areas

related to the performance of the

water chemistry

and radiochemistry

programs

were reviewed for scope,

thoroughness

of program evaluation,

and timely followup of identified

deficiencies.

The audit and assessments

were performed in accordance

with quality assurance

procedures

by qualified auditors.

The reviewed

quality assurance

audit and assessments

of the water chemistry and

radiochemistry

programs

were thorough

and of excellent quality.

The

audit and assessments

provided excellent oversight

and evaluation of the

licensee's

performance

in implementing the water chemistry

and

radiochemistry

programs in accordance

with the Units

1 and

2 Technical

Specifications'equirements.

The inspector concluded that the audit's

and assessments'bservations

and findings were insightful and that they provided excellent oversight

of the chemistry program implementation.

Conclusions

An excellent.

comprehensive

audit and excellent

assessments

of the

chemistry/radiochemistry

program were performed

by the quality assurance

organization.

Excellent oversight of the water chemistry

and

radiochemistry

programs

was achieved.

Miscellaneous

RP8C Issues

(92904)

Closed

Ins ection followu

Item 275/9402-01

323/9402-01:

Problem

Investi ation and Documentation

This item involved the lack of followup to the detection of increased

cobalt-58 activity in 6 samples

out of 68 samples of algae analyzed

during 1992.

The detected

concentrations

of cobalt-58 in the

6 samples

were much less than the reporting level.

Subsequent

samples collected

during 1992 and

1993 had either non-detectable

or significantly lower

levels of activity.

The inspector verified that

a change to Procedure

,

WI.A-11, "Review of Radioanalytical

Data." was approved

and issued to

include administrative limits for isotopes of interest (including

cobalt-58) in algae samples,

the requirement to initiate an Action

Request if any administrative limit is exceeded,

and the requi rement to

notify plant personnel

in a timely manner.

The procedure

change also

requi red that

a data

base for trending the environmental

sample analyses

results

be maintained

by Technical

and Ecological Services

personnel.

li

-20-

R8.2

Closed

Violation 275/9402-02

323/9402-02:

Radi pl o ical Environmental

Monitorin

Procedures

This vi'olation involved several

examples of failure to follow

established

procedures

for the implementation of the Radiological

Environmental

Monitoring Program.

The inspector verified that the

corrective actions described

in the licensee's

response letter,

dated

May 2,

1994,

which included specific procedural

changes to identified

procedures,

were implemented.

-21-

V. Hang ement Heetin

s

Xl

Exit Heeting Summary

The inspectors

presented

the results of the two inspections to members

of licensee

management

at the conclusion of the inspections

on June 7,

1996.

The licensee -acknowledged

the findings presented.

The inspectors

asked the licensee

whether

any materials

examined during

the inspections

should

be considered proprietary.

No proprietary

information was identified.

n

Licensee

ATTACHMENT

PARTIAL LIST OF

PERSONS

CONTACTED

D. Brosnan,

Director, Regulatory Services

B. Crockett.

Manager,

Nuclear Quality Services

R. Gagne,'adwaste

Foreman,

Radiation Protection

J.

Gardner,

Senior Engineer,

Chemistry and Environmental

Operations

R. Gray, Director, Radiation Protection

F. Guerra,

General

Foreman,

Chemistry

and Environmental

Operations

C. Harbor.

NRC Interface,

Regulatory Services

J.

Hays, Director, Chemistry and Environmental

Operations

J.

Hinds, Director-Quality Control, Nuclear Quality Services

H. Karner, Acting Director-Quality Assurance,

Nuclear Quality Services

J.

Knemeyer,

Engineer,

Chemistry

and Environmental

Operations

C. Miller, Engineer,

Radiation Protection

H. Paperno,

Quality Assurance

Engineer,

Nuclear Quality Services

R.

Powers.

Manager,

Operations

Services

M. Somervi lie, Senior

Engineer,

Radiation Protection

B. Synder, Training Leader,

Learning Services

D. Taggart

~ Director-Nuclear Safety Engineering Nuclear Quality Services

M. Wang,

Engineer,

Radiation Protection

E. Wessel,

Engineer,

Chemistry

and Environmental

Operations

J.

Young, Director. Nuclear Quality Services

NRC

S. Boynton, Resident

Inspector

M. Tschi ltz, Senior Resident

Inspector

-2-

INSPECTION

PROCEDURES

USED

IP 86750

TI 2515/133

IP 84750

Solid Radioactive

Waste

Management

and Transportation of

Radioactive Materials

Implementation of Revised

49 CFR Parts

100-179

and

10 CFR Part 71

Radioactive

Waste Systems;

Water

Chemi stry; Confirmatory

Measurements

and Radiological

Environmental Monitoring

ITEMS OPENED

CLOSED

AND DISCUSSED

~oened

50-275/9608-01

50-323/9608-01

Closed

50-275/9402-01;

50-323/9402-01

50-275/9402-02:

50-323/9402-02

50-275/96-08-01

50-323/96-08-01

NCV

HAZMAT Training

IFI

Problem Investigation

and Documentation

VIO

Radiological

Environmental Monitoring Program

Procedures

NCV

HAZMAT Training

Discussed

None

-3-

LIST OF ACRONYHS USED

EPRI

UFSAR

1R7

2R7

pCilml

ppb

ppm

Electric Power Research

Institute

Updated Final Safety Analysis Report

Unit 1 Refueling Outage

Number

7

Unit 2 Refueling Outage

Number

7

microcuries

per milliliter

parts per billion

parts per million