ML13289A246

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6.a.ii.20 SQN CY11 Tri Releases
ML13289A246
Person / Time
Site: Sequoyah  Tennessee Valley Authority icon.png
Issue date: 08/24/2012
From:
Tennessee Valley Authority
To:
Office of Nuclear Reactor Regulation
Shared Package
ML13289A109 List: ... further results
References
Download: ML13289A246 (10)


Text

SUMMARY

OF RELEASES Ammonia Hydrazine Lead Naphthalene Zinc Compounds SECTION 3 - ACTIVITIES AND USES TRI Form R Value 3.1a,e l 3.3c 3.3c 3.3c 3.1a,e l 3.3c 3.3c SECTION 4.1 - MAXIMUM ONSITE Threshold Wksht Sum Threshold Wksht Sum Threshold Wksht Sum MAXIMUM AMOUNT ONSITE 0.00 19,866.00 380.10 172.39 46,431.64 TRI Form R Value 01 04 02 02 04 SECTION 5.1 - FUGITIVE AIR FIRING RANGE NA 0.65 0.00 BOILER WATER TREATMENT 0.00 NA NA NA WELDING RODS NA 0.00 0.00 TOTAL 0.00 0.00 0.65 0.00 0.00 Sec. 5.1 A TRI Form R Value 0.00 0.00 0.70 0.00 0.00 Sec. 5.1 B Basis of Estimate O O E1 O O SECTION 5.2 - STACK AIR FUEL NA 0.00 0.00 Sec. 5.2 A TRI Form R Value NA NA 0.00 0.00 0.00 Sec. 5.2 B Basis of Estimate E1 O E1 AIR 0.00 0.00 0.70 0.00 0.00 SECTION 5.3 - WATER RELEASES TENNESSEE RIVER 0.00 0.00 0.00 0.00 Sec. 5.3.1 A TRI Form R Value 0.00 0.00 0.00 NA 0.00 Sec. 5.3.1 B Basis of Estimate C O M2 C Sec. 5.3.1 C  % from Stormwater NA 0.00 0.00 0.00 WATER 0.00 0.00 0.00 NA 0.00 SECTION 5.5.4 - ON-SITE OTHER DISPOSAL FIRING RANGE NA 379.45 32.85 OTHER 0.00 0.00 0.00 Sec. 5.5.4 A TRI Form R Value NA 0.00 380.0 NA 33.00 Sec. 5.5.4 B Basis of Estimate O C O LAND NA 0.00 380.00 NA 33.00 SECTION 6.2 - OFF-SITE DISPOSAL RHEA COUNTY LANDFILL M64 NA NA 0.00 NA NA Sec. 6.2 A TRI Form R Value NA NA 0.00 NA NA Sec. 6.2 B Basis of Estimate O CHEMICAL WASTE MANAGEMENT - EMELLE M65 NA NA 0.90 NA NA Sec. 6.2 A TRI Form R Value NA NA 0.90 NA NA Sec. 6.2 B Basis of Estimate O US TVA MS HAZ WASTE STORAGE FACILITY M94 NA NA 0.04 NA NA Sec. 6.2 A TRI Form R Value NA NA 0.00 NA NA Sec. 6.2 B Basis of Estimate O BUCKNER BARREL SALES CORP. M99 NA NA 0.00 NA NA Sec. 6.2 A TRI Form R Value NA NA 0.00 NA NA Sec. 6.2 B Basis of Estimate O HOLSTON GROUP M99 NA NA 3.73 NA NA Sec. 6.2 A TRI Form R Value NA NA 3.70 NA NA Sec. 6.2 B Basis of Estimate O CLEAN HARBORS ENVIRONMENTAL SERVICES, INC. M99 NA NA 0.00 NA NA Sec. 6.2 A TRI Form R Value NA NA 0.00 NA NA Sec. 6.2 B Basis of Estimate O TCI OF ALABAMA, LLC M99 NA NA 0.08 NA NA Sec. 6.2 A TRI Form R Value NA NA 0.10 NA NA Sec. 6.2 B Basis of Estimate O CLEAN HARBORS DEER PARK M99 NA NA 0.00 NA NA Sec. 6.2 A TRI Form R Value NA NA 0.00 NA NA Sec. 6.2 B Basis of Estimate O OFF-SITE DISPOSAL 0.00 0.00 4.70 0.00 0.00 SECTION 6.2 - OFF-SITE RECYCLING TENNESSEE VALLEY RECYCLING Sec. 6.2 A TRI Form R Value NA NA NA NA NA Sec. 6.2 B Basis of Estimate NA NA NA NA NA SECTION 7 - ON-SITE WASTE TREATMENT METHODS AND EFFICIENCY Sec 7A.1a Waste Stream Code W W W NA W Sec 7A.1b Treatment Method H081 l H129 l NA H081 l H129 l NA H081 l H129 l NA NA H081 l H129 l NA Treatment Efficiency  % 0.00 0.00 0.00 NA 0.00 Sec 7A.1d E6 E6 E6 E6 08/24/2012 SQN CY11 TRI Releases.xlsx Page 1 of 10

SUMMARY

OF RELEASES Ammonia Hydrazine Lead Naphthalene Zinc Compounds SECTION 8 - SOURCE REDUCTION AND RECYCLING ACTIVITIES SECTION 8.1A - TOTAL DISPOSAL TO ON-SITE LANDFILL Column A Prior Year NA NA NA NA NA Current Year NA NA NA NA NA Column B TRI Form R Value NA NA NA NA NA Column C Following Year NA NA NA NA NA Column D 2nd Following Year NA NA NA NA NA SECTION 8.1B - TOTAL OTHER ON-SITE DISPOSAL Column A Prior Year NA NA 440.0 NA 0.00 Current Year 0.00 0.00 380.7 0.00 33.00 Column B TRI Form R Value 0.00 0.00 380.0 0.00 33.00 Column C Following Year 0.00 0.00 380.0 0.00 33.00 Column D 2nd Following Year 0.00 0.00 380.0 0.00 33.00 SECTION 8.1C - TOTAL OFF-SITE DISPOSAL TO LANDFILL Column A Prior Year NA NA 4.90 NA NA Current Year NA NA 0.90 NA NA Column B TRI Form R Value NA NA 0.90 NA NA Column C Following Year NA NA 0.90 NA NA Column D 2nd Following Year NA NA 0.90 NA NA SECTION 8.1D - TOTAL OTHER OFF-SITE DISPOSAL Column A Prior Year NA NA 0.30 NA NA Current Year NA NA 3.80 NA NA Column B TRI Form R Value NA NA 3.80 NA NA Column C Following Year NA NA 3.80 NA NA Column D 2nd Following Year NA NA 3.80 NA NA SECTION 8.5 - TOTAL QUANTITY RECYCLED OFFSITE Column A Prior Year NA NA NA NA NA Current Year NA NA NA NA NA Column B TRI Form R Value NA NA NA NA NA Column C Following Year NA NA NA NA NA Column D 2nd Following Year NA NA NA NA NA SECTION 8.6 - TOTAL QUANTITY TREATED ONSITE Column A Prior Year NA NA NA NA NA Current Year NA NA NA NA NA Column B TRI Form R Value NA NA NA NA NA Column C Following Year NA NA NA NA NA Column D 2nd Following Year NA NA NA NA NA SECTION 8.8 - RELEASES DUE TO ONE-TIME EVENTS Column A Prior Year NA NA NA NA NA Current Year NA NA NA NA NA Column B TRI Form R Value NA NA NA NA NA Column C Following Year NA NA NA NA NA Column D 2nd Following Year NA NA NA NA NA SECTION 8.9 - PRODUCTION RATIO TRI Form R Value 0.00 0.70 0.86 5.13 0.00 TRI Chemical Reportable? Air Water Onsite Disposal Off-Site Disposal Total Ammonia No Antimony Compounds No Arsenic Compounds No Barium Compounds No Benzo(g,h,i)perylene No Chlorine No Cadmium Compounds No Chromium Compounds No Cobalt Compounds No Copper Compounds No Dioxin and Dioxin-like Compounds, grams No Ethylene Glycol No Hydrazine Yes 0.00 0.00 0.00 0.00 0.00 Hydrochloric Acid (aersol) No Hydrogen Flouride No Lead / Lead Compounds Yes 0.70 0.00 380.00 4.70 385.40 Manganese Compounds No Mercury Compounds No Naphthalene No Nickel Compounds No Nitrate Compounds No PACs No Selenium Compounds No Silver Compounds No Sulfuric Acid No Thallium Compounds No Vanadium Compounds No Zinc / Zinc Compounds No 0.00 0.00 0.00 0.00 Totals 0.70 0.00 380.00 4.70 385.40 08/24/2012 SQN CY11 TRI Releases.xlsx Page 2 of 10

AIR EMISSIONS Fugitive Air Emissions From Ammunition Use 1

Ammunition Fired : 1,086.00 lbs Lead Units Air Emission Factor2 0.0006 lbs/lbs Fugitive Air Emissions 0.65 lbs Notes:

1. "Ammunition" worksheet L:\CY 11\Nuclear TRI Files\SQN\Thresholds\SQN CY11 TRI Thresholds.xlsx
2. EPA default emission factor is pounds of pollutant per ton (i.e., 2,000 pounds) of rounds fired. For lead, emission factor is 1.2 pounds of lead per 2,000 pounds of rounds fired [AP-42 Chapter 13.3 Explosives Detonation (2/1980)].

Air Emissions from Point-Source Fuel Combustion Gasoline 1: - gallons No.2 Fuel Oil 1: 32,308.26 gallons 2 3 4 Lead Compounds Naphthalene PACs Units Gasoline Emission Factors -- 5.88E-05 -- lb/lb Diesel Emission Factors 1.25E-06 1.19E-05 1.75E-09 lb/gal Stack Air Emissions 0.04 0.4 0.0001 lbs Notes:

1 "Fuel"

1. "F l" worksheet k h t L \CY 11\Nuclear L:\CY 11\N l TRI Fil \SQN\Th h ld \SQN CY11 TRI Th Files\SQN\Thresholds\SQN h ld l Thresholds.xlsx
2. Fuel oil values are found in Table C-1 of EPAs Emergency Planning and Community Right-to-Know Act - Section 313: Guidance for Reporting Releases and Other Waste Management Quantities of Toxic Chemicals: Lead and Lead Compounds (EPA 260-B-01-027; December 2001).
3. Organics manufactured during gasoline combustion are associated with exhaust and crankcase emissions. These estimates were derived from AP-42, Volume 1, Chapter 3.3 "Gasoline and Diesel Industrial Engines."
4. Fuel oil values are found in Locating & Estimating Air Emissions from Sources of Polycyclic Organic Matter (EPA-454/R-98-014; July 1998).

08/24/2012 SQN CY11 TRI Releases.xlsx Page 3 of 10

LAND DISPOSAL Land Disposal - Firing Range Lead Zinc Units 1,3 Amount Used 380.10 32.85 lbs Air Emissions 0.65 - lbs Land Disposal3 379.45 32.85 lbs Notes:

1. "FireRnge" worksheet L:\CY 11\Nuclear TRI Files\SQN\Thresholds\SQN CY11 TRI Thresholds.xlsx 08/24/2012 SQN CY11 TRI Releases.xlsx Page 4 of 10

WATER RELEASES Flow Releases (mg/L)

Outfall Name Mgd Antimony Arsenic Barium Beryllium Cadmium Chromium Chlorine Cobalt Copper Lead Manganese 101 1,490.73 0.0000 0.00005 0.0120 0.0000 0.0000 0.0000 0.0000 0.0000 0.0002 0.0000 0.7770 110 1,594.50 116 0.060 117 0.014 118 0.000 103 1.197 0.001 0.001 0.000 0.001 0.001 0.00 0.00 0.00 0.00 0.00 0.00 107 0.003 Totals (lb/yr) 0.00 Notes:

1 Flows (long-term average) taken from SQN NPDES permit application, issued 02/02/2011: L:\CY11\Nuclear TRI Files\SQN\SQN permit application 01.27.09.pdf 2 Concentrations taken from SQN NPDES permit application 01/27/09 which required monitoring for all metals; max daily effluent onsite - intake used as there were no long-term aver 3 From the NPDES permit, Outfalls 101, 116-118 discharge to the TN River. Outfall 103 is an internal wastewater outfall which discharges into Outfall 101 so concentrations are not u are stormwater outfalls that do not require monitoring. Outfalls 116-117, 110 are backwash wastewater outfalls that require no monitoring.

4 From NPDES permit application, no monitoring data for outfalls 110, 116-118, and 107.

5 Based on analyses from other plants, process water from the cooling tower / condensers typically do not contain metals. Therefore, all of the metal concentrations lower than detec 6 Covered by the TN Multisector stormwater permit, which requires monitoring for iron only. The site NPDES permit does not require routine monitoring (DMR) for an 7 NPDES P Permit it Application A li ti renewall monitoring it i data d t (the (th composite it metal t l sample) l ) is i used d to t estimate ti t releases l to t the th T 8 Hydrazine is added to the water prior to discharge. The hydrazine reacts in the water to form ammonia. Therefore, no hydrazine is released to the Tennessee River.

9 Zinc discharge calculated by mass balance and not the one-time sample.

ZINC MASS BALANCE Chemical Quantity Percent Zinc Released Name Used (lbs) Zinc TN River (lbs)

MSW-109 0.00 12.5% 0.00 Flogard MS3267 0.00 25.0% 0.00 Source: L:\CY 11\Nuclear TRI Files\SQN\Thresholds\SQN CY11 TRI Thresholds.xlsx - Chemicals Notes:

1 The zinc used in boiler water treatment is assumed to be released to the Tennessee River and the NPDES data is not used.

08/24/2012 SQN CY11 TRI Releases.xlsx Page 5 of 10

AMMONIA RELEASES BOILER WATER TREATMENT TOTAL LBS Ammonia used for boiler water treatment, lb/yr NBWT 0.00 TOTAL AMMONIA RELEASE TOTAL LBS Air releases due to ammonia storage tank leakage, lbs/yr TankLeak 0.00 Sum total of ammonia in the flue gas from NOx reduction and FGC, lb/yr L 0.00 Total stack air ammonia releases, lb/yr NS 0.00 Stack air ammonium bisulfate (ABS) releases, lb/yr - not reportable NS_ABS 0.00 Total fugitive air ammonia releases, lb/yr NF 0.00 Total land ammonia releases, lb/yr - Not reportable NL 0.00 Total water ammonia releases, lb/yr NW 0.00 Total reportable ammonia releases, lb/yr NTR 0.00 TOTAL AMMONIA TREATED ONSITE 0.00 PERCENT TREATED ONSITE 0 Notes:

1. Ammonia was not reportable because less than 100,000 lbs of solution was used.

Threshold is based on total solution amount*0.10 (10 percent).

2. Ammonia treated onsite calculated from "A Method for Estimating Total Ammonia Emissions from Stationary Power Plants," by S.L. Wilson, K.E. Harrison, & L.S. Monroe.

Assumption was made that the fate of ammonia would be the same as it is inn fossil plants.

3. Ammonia used for boiler water treatment obtained from the total ammonium hydroxide amount times the percent contribution times the molecular weight ratio of ammonia to ammonium hydroxide Source: L:\CY 11\Nuclear TRI Files\SQN\Thresholds\SQN CY11 TRI Thresholds.xlsx - Chemicals 08/24/2012 SQN CY11 TRI Releases.xlsx Page 6 of 10

OFF-SITE DISPOSAL DISPOSITION Off Site Disposal-M10 Off-site Disposal-M65 Off-site Disposal-M99 Off Site Disposal-M10 Off-site Disposal- CLEAN HARBORS Clean Harbors Off-site Disposal-CHEMICAL WASTE BUCKNER BARREL SALES TCI OF ALABAMA, RHEA COUNTY Grand Total GENERATOR Data Muscle Shoals HWSF Total M65 Total ENVIRONMENTAL SERVICES, HOLSTON GROUP Deer Park, La M99 Total MANAGEMENT - EMELLE CORP. LLC LANDFILL INC. Porte, TX SQN Sum of AS (lb) 0.04 0.04 0.90 0.90 3.37 0.00 3.37 4.32 Sum of BA (lb) 0.88 0.88 17.33 17.33 66.91 0.00 66.91 85.12 Sum of CD (lb) 0.01 0.01 0.17 0.17 0.67 0.01 0.68 0.86 Sum of CR (lb) 0.06 0.06 0.99 0.99 3.36 0.01 2.45 3.37 6.86 Sum of PB(lb) 0.04 0.04 0.90 0.90 3.73 0.08 0.001 3.80 4.75 Sum of HG (lb) 0.00 0.00 0.03 0.03 0.13 0.00 4.00 0.13 4.17 Sum of SE (lb) 0.01 0.01 0.18 0.18 0.67 0.00 0.67 0.86 Sum of AG (lb) 0.04 0.04 0.91 0.91 3.35 0.00 3.35 4.30

Reference:

L:\CY 11\Waste Data\CY11_HWSF Calculations -C (043012c).xlsx Notes: Additional spill information provided in SQN CY11 TRI Questionnaire.docx 1 Lab pack shipment of potassium dichromate (6 lbs) shipped to Clean Harbors Deer Park, La Porte TX (EPA ID TXD055141378)

K2Cr2O7:

K 39.098 Cr 51.996 O 15.999 ratio Cr/K2Cr2O7 0.408 lbs Cr shipped 2.446 2 Lab pack shipment of waste mercury (4 lbs) shipped to Clean Harbors Deer Park, La Porte TX (EPA ID TXD055141378) 3 Used oil shipments for oil showing above detection limits for lead:

3/15/11 - 550 gallons Used oil - gallons 550 gal Emission factor 1.25E-06 lb/gal lbs lead shipped 6.88E-04 lbs 08/24/2012 SQN CY11 TRI Releases.xlsx Page 7 of 10

WELDING ROD AIR EMISSIONS Total Chromium Colbalt Lead Manganese Nickel Item Description Type Notes Weight (lb) EF lbs EF lbs EF lbs EF lbs EF lbs 1 7018 MR 1/8 E7018 0.060 0.000 0.010 0.000 ND 10.300 0.000 0.020 0.000 2 95/5 Average 1.0000 3.465 0.000 0.012 0.000 0.930 0.000 15.684 0.000 2.720 0.000 3 Aluminim Tig Wire* Average 3.465 0.000 0.012 0.000 0.930 0.000 15.684 0.000 2.720 0.000 4 BAG7 Average 1.9928 3.465 0.000 0.012 0.000 0.930 0.000 15.684 0.000 2.720 0.000 5 BCUP2 Average 3.465 0.000 0.012 0.000 0.930 0.000 15.684 0.000 2.720 0.000 6 BCUP5 Average 0.6237 3.465 0.000 0.012 0.000 0.930 0.000 15.684 0.000 2.720 0.000 7 E30816 E308 5.240 0.000 0.010 0.000 ND 3.460 0.000 1.840 0.000 8 E30916 E70S 0.010 0.000 0.010 0.000 ND 3.180 0.000 0.010 0.000 9 E31616 E70S 0.010 0.000 0.010 0.000 ND 3.180 0.000 0.010 0.000 10 E7018 E7018 274.4720 0.060 0.000 0.010 0.000 ND 10.300 0.028 0.020 0.000 11 E70S3 E70S 0.9855 0.010 0.000 0.010 0.000 ND 3.180 0.000 0.010 0.000 12 E70S6 E70S 0.010 0.000 0.010 0.000 ND 3.180 0.000 0.010 0.000 13 E70S6(SP) E7018 0.060 0.000 0.010 0.000 ND 10.300 0.000 0.020 0.000 14 E9018B3 E9018 2.120 0.000 ND ND 7.830 0.000 0.130 0.000 15 ENICRFE3 Average 3.465 0.000 0.012 0.000 0.930 0.000 15.684 0.000 2.720 0.000 16 ER309 Average 4.6403 3.465 0.000 0.012 0.000 0.930 0.000 15.684 0.001 2.720 0.000 17 ER309L Average 8.5000 3.465 0.000 0.012 0.000 0.930 0.000 15.684 0.001 2.720 0.000 18 ER316/L Average 24.8285 3.465 0.001 0.012 0.000 0.930 0.000 15.684 0.004 2.720 0.001 19 ER320 ENiCrMo 4.200 0.000 ND ND 0.430 0.000 2.470 0.000 20 ER5356 E70S 1.3548 0.010 0.000 0.010 0.000 ND 3.180 0.000 0.010 0.000 21 ER70S6 Average 107.6631 3.465 0.004 0.012 0.000 0.930 0.001 15.684 0.017 2.720 0.003 22 ER70S6(SP) E70S 0.010 0.000 0.010 0.000 ND 3.180 0.000 0.010 0.000 23 ER90SB3 Average 77.2491 3.465 0.003 0.012 0.000 0.930 0.001 15.684 0.012 2.720 0.002 24 ERCUSIA Average 3.465 0.000 0.012 0.000 0.930 0.000 15.684 0.000 2.720 0.000 25 ERNICR3 Average 3.465 0.000 0.012 0.000 0.930 0.000 15.684 0.000 2.720 0.000 26 ERNICRMO3 ENiCrMo 24.4797 4.200 0.001 ND ND 0.430 0.000 2.470 0.001 27 ERNICROMO3 ENiCrMo 4.200 0.000 ND ND 0.430 0.000 2.470 0.000 28 Mig Welding Rod (unspecified) Average 3.465 0.000 0.012 0.000 0.930 0.000 15.684 0.000 2.720 0.000 29 RCOCRA Average 3.465 0.000 0.012 0.000 0.930 0.000 15.684 0.000 2.720 0.000 30 SN96WS Average 3.465 0.000 0.012 0.000 0.930 0.000 15.684 0.000 2.720 0.000

-- Total 527.7895 0.009 0.000 0.002 0.064 0.007 Notes:

1 Pounds of metal emitted per 10,000 pounds of welding rods used 2 The "Average" emission factor is used where there is no emission factor information provided for a particular welding rod.

3 Amounts taken from: L:\CY 11\Nuclear TRI Files\SQN\Thresholds\SQN CY11 TRI Thresholds.xlsx 08/24/2012 SQN CY11 TRI Releases.xlsx Page 8 of 10

WELDING ROD AIR EMISSIONS Welding Emission Factors Column Number 1 2 3 4 5 6 7 8 Type Chromium Colbalt Lead Manganese Nickel PM10 Notes 14Mn-4Cr 1.39E+01 ND ND 2.32E+02 1.71E+01 8.16E+01 E110 2.00E-02 ND ND 2.02E+01 1.12E+00 2.08E+01 E11018 9.69E+00 ND ND 1.38E+01 1.02E+00 5.70E+01 E308 5.24E+00 1.00E-02 ND 3.46E+00 1.84E+00 1.08E+01 1 E310 2.53E+01 ND 2.40E-01 2.20E+01 1.96E+00 1.51E+01 E316 9.70E+00 ND ND 5.90E+00 9.30E-01 1.00E+01 E410 ND ND ND 6.85E+00 1.40E-01 1.32E+01 E6010 3.00E-02 ND ND 9.91E+00 4.00E-02 2.56E+01 E6011 5.00E-02 1.00E-02 ND 9.98E+00 5.00E-02 3.84E+01 E6012 ND ND ND ND ND 8.00E+00 E6013 4.00E-02 1.00E-02 ND 9.45E+00 2.00E-02 1.97E+01 2 E7018 6.00E-02 1.00E-02 ND 1.03E+01 2.00E-02 1.84E+01 2 E7024 1.00E-02 ND ND 6.29E+00 ND 9.20E+00 E7028 1.30E-01 ND 1.62E+00 8.46E+00 ND 1.80E+01 E70S 1.00E-02 1.00E-02 ND 3.18E+00 1.00E-02 5.20E+00 E70T 4.00E-02 ND ND 8.91E+00 5.00E-02 1.51E+01 E71T 2.00E-02 2.00E-02 ND 6.62E+00 4.00E-02 1.22E+01 E8018 1.70E-01 ND ND 3.00E-01 5.10E-01 1.71E+01 E9015 ND ND ND ND ND 1.70E+01 E9018 2.12E+00 ND ND 7.83E+00 1.30E-01 1.69E+01 ECoCr ND ND ND ND ND 2.79E+01 EM12K ND ND ND ND ND 5.00E-02 ENi-Cl ND ND ND 3.90E-01 8.90E+00 1.82E+01 ENiCrMo 4.20E+00 ND ND 4.30E-01 2.47E+00 1.17E+01 ENi-Cu ND ND ND ND ND 1.01E+01 ENi-Cu-2 ND ND ND 2.12E+00 4.23E+00 ND ER1260 4.00E-02 ND ND ND ND 2.05E+01 ER316 5.28E+00 ND ND 2.45E+00 2.26E+00 3.20E+00 ER5154 1.00E-01 ND ND 3.40E-01 ND 2.41E+01 ERNiCrMo 3 53E+00 3.53E+00 ND ND 7 00E-01 7.00E-01 1 25E+01 1.25E+01 3 90E+00 3.90E+00 ERNiCu 1.00E-02 ND ND 2.20E-01 4.51E+00 2.00E+00 2 Average 3.46E+00 1.17E-02 9.30E-01 1.57E+01 2.72E+00 1.84E+01 3 Notes:

A Source: AP-42, 12.19 Electric Arc Welding, 1/95, Table 12.19-1 and 19-2 B For metals: pounds of metal emitted per 10,000 pounds of electrode consumed C For PM10: pounds of PM10 emitted per 1,000 pounds of electrode consumed D "ND" denotes "No Data."

1 AP-42 lists several emission factors for E308. This is due to several different welding processes that exist.

Of the emission factors listed, the maximum emission factor is selected for conservative results.

2 Value listed is <0.01. 0.01 was used since it is the upper bound.

3 Average is used where there is no emission factor information provided for a particular welding rod.

08/24/2012 SQN CY11 TRI Releases.xlsx Page 9 of 10

PRODUCTION RATIOS (What was used compared to last year - OU is best indicator for what was used)

Reportable TRI Otherwise Use CY09 CY10 CY11 CY11/CY10 Ratio Chemical AMMONIA chem usage 0.00 0.00 0.00 0.00 CHLORINE chem usage 0.00 0.00 7,775.67 0.00 HYDRAZINE chem usage 0.00 28,301.11 19,866.00 0.70 firing range 0.00 441.57 380.10 LEAD welding rods 0.00 0.00 0.00 total 0.00 441.57 380.10 0.86 fuel 0.00 0.02 0.00 LEAD COMPOUNDS firing range 0.00 0.28 0.24 total 0.00 0.30 0.24 0.80 PACS fuel 0.00 0.31 3.39 10.94 NAPTHELENE fuel 0.00 172.39 885.08 5.13 ZINC COMPOUNDS chem usage 0.00 0.00 0.00 0.00 chem usage 0 0.00 firing range 0.00 38.04 32.85 ZINC welding rods 0.00 0.47 0.34 total 0.00 38.51 33.19 0.86 Notes:

1 OU values taken from L:\CY 11\Nuclear TRI Files\SQN\ Thresholds\SQN CY11 TRI Thresholds.xlsx 2 Most CY09 values unknown - Form A submittal or totals only from NPG 08/24/2012 SQN CY11 TRI Releases.xlsx Page 10 of 10