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{{#Wiki_filter:S58 090813 800- NPDES CORRESPONDENCE Tennessee Valley Authority Post Office Box 2000 Soddy Daisy, Tennessee 37384-2000 Timothy P. Cleary Site Vice President Sequoyah Nuclear Plant August13,2009 Mr. Patrick Cromer State ofT ennessee Department of Environment and Conservation Division of Water Pollution Control Enforcement & Compliance Section 6th Floor, L & C Annex 401 Church Street Nashville, Tennessee 37243-1534
Dear Mr. Cromer:
SEQUOYAH NUCLEAR PLANT- DISCHARGE MONITORING REPORT FOR JULY 2009 Enclosed is the July, 2009 Discharge Monitoring Report for Sequoyah Nuclear Plant certified by the duly authorized representative. On 7/8/09 the pH on Outfall 103 exceeded the limit due to a suspected algae bloom. Sulfuric acid was added to the pond and on 7/9/09 the pH was within limits. This excess is being addressed through Sequoyah's corrective action program in order to reduce, eliminate, and prevent recurrence. If you have any questions or need additional information, please contact Ann Hurt at (423) 843-6714 or Stephanie Howard at (423) 843-6700 of Sequoyah's Environmental staff. S.ince~el, -c=~ .. (--t'l~I Timothy P. Cleary Y Site Vice President Sequoyah Nuclear Plant AH Enclosure cc (Enclosure): Chattanooga Environmental Field Office Division of Water Pollution Control State Office Building, Suite 550 540 McCallie Avenue Chattanooga, Tennessee 37402-2013 U.S. Nuclear Regulatory Commission ATTN: Document Control Desk Washington, D.C. 20555 cc: D. J. Bodine, POB 2A-SQN A. A. Ray, WT 7C-K C. R. Church, POB 2B-SQN G. R. Signer, WT 6A-K T. P. Cleary, OPS 4A-SQN B. A. Wetzel, OPS 4A-SQN S. S. Koss, LP 4B-C EDMS, WT CA-K (Enclosure) D. E. Pittman, LP 5E-C DMR0907.doc p:n1ted on recycled paper
REVIEW /CONCURRENCE SHEET DOCUMENT NAME: SEQUOYAH NUCLEAR PLANT- DISCHARGE MONITORING REPORT FOR JULY 2009 ORGANIZATION: Chemistry and Environmental DOCUMENTPREPAREDBY: AnnHurt DATE: 08/06/2009 CATEGORY: NPDES Correspondence CONCURRENCES Name R C Signature - Comment Date V N Ann Hurt X Stephanie A Howard X Alan K Barringer X Debra J Bodine X Beth A. Wetzel X Chris R Church X Timothy P Cleary X (for signature) INSTRUCTIONS: Originator will determine the review/concurrence assignment. REVIEW: Examine technical content and commitments made. A review (RV) should confirm the truth and accuracy of factual statements and indicate agreement with commitments made which are applicable to the reviewer's organization. CONCURRENCE: Indication of agreement with the document as a whole. Concurrence (CN) signifies that the document is responsive to the intended purpose, logical in construction, and clear in meaning in the eyes of the recipient. A concurrence signature indicates that the individual would be willing to sign the document for the agency.
Tennessee Valley Authority Post Office Box 2000 Soddy Daisy, Tennessee 37384-2000 Timothy P. Cleary Site Vice President Sequoyah Nuclear Plant August13, 2009 Mr. Patrick Cromer State of Tennessee Department of Environment and Conservation Division of Water Pollution Control Enforcement & Compliance Section 1 6 h Floor, L & C Annex 401 Church Street Nashville, Tennessee 37243-1534
Dear Mr. Cromer:
SEQUOYAH NUCLEAR PLANT- DISCHARGE MONITORING REPORT FOR JULY 2009 Enclosed is the July, 2009 Discharge Monitoring Report for Sequoyah Nuclear Plant certified by the duly authorized representative. On 7/8/09, the pH on Outfall 103 exceeded the limit due to a suspected algae bloom. Sulfuric acid was added to the pond and on 7/9/09 the pH was within limits. This excess is being addressed through Sequoyah's corrective action program in order to reduce, eliminate, and prevent recurrence. If you have any questions or need additional information, please contact Ann Hurt at (423) 843-6714 or Stephanie Howard at (423) 843-6700 of Sequoyah's Environmental staff. Sincerely, rZJ1J
- mothj;:y Site Vice President Sequoyah Nuclear Plant 1'
Enclosure cc (Enclosure): Chattanooga Environmental Field Office Division of Water Pollution Control State Office Building, Suite 550 540 McCallie Avenue Chattanooga, Tennessee 37402-2013 U.S. Nuclear Regulatory Commission ATTN: Document Control Desk Washington, D.C. 20555 p~1nted on recycled paper
PERMITTEE NAME/ADDRESS (Include Facility Name/Location if Different) NATIONAL POLLUTANT OISCHARGE ELIMINATION SYSTEM (NPOES) MAJOR Form Approved. Name_~A-SEQUOYA~UCLEA~LANT _ _ _ _ DISCHARGE MONITORING REPORT (OMR) OMB No. 2040-0004 (SUBR 01) AddresL _..!: ~BOX_1900 _ _ _ _ _ _ _ _ _ _ _ _ ---~TEROFFICESB-2A-SQ~-------- TN0026450 101 G F- FINAL - _ _ __§_ODD.Y...- DAISY_ _.It:!_]738L _ _ _ _ _ _ _ DIFFUSER DISCHARGE Facility_ ...I:JA- SEQUOYAH NUCLEAR PLANT_ _ _ _ _ _ Locatio.!!_ J::!AMIL TOH_COUNTY __________ _ EFFLUENT YEAR DAY NO DISCHARGE [J *** ATTN: Stephanie A. Howard From I 09 I -- I -- I 31 NOTE: Read instructions before completinq this form. PARAMETER QUANTITY OR LOADING QUALITY OR CONCENTRATION I NO. [FREQUENCY SAMPLE EX OF TYPE ANALYSIS AVERAGE MAXIMUM UNITS. MINIMUM AVERAGE MAXIMUM UNITS
******** ******** ******** ******** 29.3 0 31 /31 I MODELD 04 . BETWEEN SAMP. &
DEG.C s 0 0 0 530 1 0 0 EFFLUENT GROSS VALUE OIL AND GREASE 00556 0 0 EFFLUENT GROSS VALUE NDUIT OR THRU T PLANT 0 0 NAME/TITLE PRINCIPAL EXECUTIVE OFFICER I Certify under penally of law thai this document and all attachments were prepared under my Timothy P. Cleary direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or
/Jtl.pt j_QJL c~ c~ .ctlc~'-.)(l. ~~ TELEPHONE DATE persons who manage the system, or those persons directly responsible for gathering the Principal Environmental Engineer information, the information submitted is . to the best of my knowledge and belief. true. 423 843-6700 09 08 07 Sequoyah Site Vice President accurate, and complete. I am aware that there are significant penalties for submitting false SIGNATURE OF PRINCIPAL EXECUTIVE I TYPED OR PRINTED information, including the possibility of fine and imprisonment for know1ng violations OFFICER OR AUTHORIZED AGENT AREA ~ODE l NUMBER YEAR MO DAY COMMENTS AND EXPLANATION OF ANY VIOLATIONS (Reference all attachments here)
No closed mode operation. The following information is included in an attachment: CCW data EPA Form 3320-1 (REV 3/99) Previous editions may be used Page 1 of 2
DMR Attachment CCW Data CCWTRENCH Extractable Petroleum Date/Time Collected Hydrocarbons Analysis Date/Time Analyst Method 07/15/2009 @ 1022 0.52 mg/1 07/16/2009@ 2355 JAB EPH CCWCHANNEL Extractable Petroleum Date/Time Collected Hydrocarbons Analysis Date/Time Analyst Method 07/15/2009 @ 1023 <0.10 mg/1 07/17/2009@ 0005 JAB EPH
PERMITIEE NAME/ADDRESS (Include Facility Name/Location if Different) NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPOES) MAJOR Form Approved. Name_~A-SEQUOYA~UCLEARPLANT _ _ _ _ DISCHARGE MONITORING REPORT (OMR) OMB No. 2040-0004 (SUBR 01) Add res§_ ___!:..~BOX_gQOO _ _ _ _ _ _ _ _ _ _ _ _ TN0026450 101 G F- FINAL ---~TEROFFICESB-2A-SQ~-------- - _ _ __§_ODDY- DAISY_ _1!::!.]738!_ _ _ _ _ _ _ _ PERMIT NUMBER DISCHARGE NUMBER DIFFUSER DISCHARGE Facilitv_ _IVA-_§!:QUOYAH NUCLEAR PLANT_ _ _ _ _ _ Locatio.!l._ _!:!AMIL TO.!::!....COUNTY __________ _ MONITORING PERIOD EFFLUENT From YEAR DAY NO DISCHARGE D ... ATIN: Stephanie A. Howard 09 To 31 NOTE: Read instructions before completinq this form. PARAMETER QUANTITY OR LOADING QUALITY OR CONCENTRATION I NO. IFREQUENCY I SAMPLE OF TYPE ANALYSIS AVERAGE MAXIMUM UNITS MINIMUM UNITS ll.,nLVr\INt:. TOTAL RESIDUAL ******** ******** ******** 0.017 0.031 GRAB 19 0 0 RE- C, RATE OF 0 0 EFFLUENT GROSS VALUE
-~~lCLtL~ OtlL'V-lO-*Ld NAME/TITLE PRINCIPAL EXECUTIVE OFFICER I Certify under penalty of law that this document and all attachments were prepared under my TELEPHONE DATE direction or supervision in accordance wilh a system designed to assure that qualified personnel Timothy P. Cleary properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the Principal Environmental Engineer information, the information submitted is , to the best of my knowledge and belief, true, 423 I 843-6700 09 08 07 Sequoyah Site Vice President accurate, and complete. I am aware that there are significant penalties for submitting false SIGNATURE OF PRINCIPAL EXECUTIVE information, including the poss1b11ity of fine and imprisonment for knowing violations.
TYPED OR PRINTED OFFICER OR AUTHORIZED AGENT AREA~MBER YEAR MO DAY CODE COMMENTS AND EXPLANATION OF ANY VIOLATIONS (Reference all attachments here) The following injections occured: 1. MSW-101 (max calc. cone. was 0.076mg/L--Iimit 0.2mg/L) 2. Biodetergent 73551 (max. calc. cone. was 0.017mg/L--Iimit 2.0mg/L) 3. H-150M (max. calc. cone. was 0.040mg/L--Iimit 0.050mg/L) 4. H-150M (low detection level analytical method was <0.050mg/L--Iimit 0.050mg/L) EPA Form 3320-1 (REV 3/99) Previous editions may be used Page 2 of 2
PERMITTEE NAME/ADDRESS (Include Facility Name/Location if Different) NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPOES) MAJOR Form Approved. Name_~A-SEQUOYA~UCLEA~LANT _ _ _ _ DISCHARGE MONITORING REPORT (OMRJ OMB No. 2040-0004 (SUBR 01) Addres_L J:.~BOX 2000 _ _ _ _ _ _ _ _ _ _ _ _ ---~TEROFFICESB-2A-SQ~-------- TN0026450 101 T F-FINAL - _ _ _§ODDY- DAISY_ _IN 37381.__ _ _ _ _ _ _ _ PERMIT NUMBER DISCHARGE NUMBER I BIOMONITORING FOR OUTFALL 101 Facility_ ~A- SEQUOYAH NUCLEAR PLANT_ _ _ _ _ _ LocatioD._ J:::!AMILTOli_COUNTY__________ _ MONITORING PERIOD EFFLUENT YEAR DAY NO DISCHARGE [ ] *** ATTN: Stephanie A. Howard From 09 To 31 NOTE: Read instructions before completinQ this form. PARAMETER QUALITY OR CONCENTRATION I NO. !FREQUENCY SAMPLE EX OF TYPE ANALYSIS UNITS MINIMUM AVERAGE MAXIMUM UNITS CHR ******** ******** i3 NAME/TITLE PRINCIPAL EXECUTIVE OFFICER I Certify under penalty of law that this document and all attachments were prepared under my Timothy P. Cleary direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or
.,Jti,oti0.1GZL Q,\ -dlVLA-iCu_J TELEPHONE DATE persons who manage the system, or those persons directly responsible for gathering the Principal Environmental Engineer 07 information, the information submitted is , to the best of my knowledge and belief, true, 423 843-6700 09 08 Sequoyah Site Vice President accurate, and complete. I am aware that there are significant penalties for submitting false Information, including the possibility of fine and Imprisonment for knowing violations.
SIGNATURE OF PRINCIPAL EXECUTIVE I OFFICER OR AUTHORIZED AGENT AREAl NUMBER YEAR MO DAY TYPED OR PRINTED CODE COMMENTS AND EXPLANATION OF ANY VIOLATIONS (Reference all attachments here) Toxicity was not sampled in July 2009. EPA Form 3320-1 (REV 3/99) Previous editions may be used Page 1 of 1
PERMITTEE NAME/ADDRESS (Include Facilitv Name/Location if Different) NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPOES) MAJOR Form Approved. Na~-~A-SEQUOYA~UCLEARPLANT _ _ _ _ DISCHARGE MONITORING REPORT (OMRi OMB No. 2040-0004 (SUBR 01) Add res.§_ _f.~BOX_2900 _ _ _ _ _ _ _ _ _ _ _ _ ---~TEROFFICESB-2A-SQ~-------- TN0026450 ~~~-1:..:0;,.;.1~Y~~ F- FINAL - _ _ _§_ODD..Y.: DAISY_ _IN 37381._ _ _ _ _ _ _ _ PERMIT NUMBER DISCHARGE NUMBER ANNUAL MONITORING (PCBS) Facility_ JYA- SEQUOYAH NUCLEAR PLANT_ _ _ _ _ _ Locatio.!l_ _!:jAMIL TO.!:!..COUNTY __________ _ MONlTOEING__P_EHlQD EFFLUENT YEAR DAY NO DISCHARGE [ ] *** ATTN: Stephanie A. Howard From 08 To 31 NOTE: Read instructions before completinq this form. PARAMETER QUALITY OR CONCENTRATION I NO. [FREQUENCY[ SAMPLE EX OF TYPE ANALYSIS MAXIM UNITS MINIMUM AVERAGE MAXIMUM UNITS POLYCHLORINATED BIPHENYLS ******** ******** ******** <0.0 0 1 /365 GRAB 19 0 0 ENT GROSS VALUE
.J ~4Jhwtk~ u\.fuit-00-~d NAME/TITLE PRINCIPAL EXECUTIVE OFFICER I Certify under penalty of law that this document and all attachments were prepared under my TELEPHONE DATE direction or supervision in accordance with a system designed to assure that qualified personnel Timothy P. Cleary properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the Principal Environmental Engineer information, the information submitted is , to the best of my knowledge and belief, true, 423 843-6700 09 08 07 Sequoyah Site Vice President accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fine and imprisonment for knowing violations SIGNATURE OF PRINCIPAL EXECUTIVE I TYPED OR PRINTED OFFICER OR AUTHORIZED AGENT AREA I NUMBER YEAR MO DAY CODE COMMENTS AND EXPLANATION OF ANY VIOLATIONS (Reference all attachments here)
PCBs were sampled on 7/1/09@ 1101. EPA Form 3320-1 (REV 3/99) Previous editions may be used Page 1 of 1
PERMITTEE NAME/ADDRESS (Include Facility Name/Location if Different) NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPDES) MAJOR Form Approved. Na~-~A-SEQUO~~UCLEA~LANT _ _ _ _ DISCHARGE MONITORING REPORT (OMR! OMB No. 2040-0004 (SUBR 01) Add res§_ _E.~BOX..£9QQ_ _ _ _ _ _ _ _ _ _ _ _ _ TN0026450 103 G F- FINAL ---~TEROFFICESB-2A-SQ~-------- - _ _ _20DD.Y_- DAISY_ _IN 37381_ _ _ _ _ _ _ _ PERMIT NUMBER DISCHARGE NUMBER LOW VOL WASTE TREATMENT POND Facility_ _IVA -_§E.QUOYAH NUCLEAR PLANT_ _ _ _ _ _ Locatio.!!_ _!jAMIL TOJ:LCOUNTL _ _ _ _ _ _ _ _ _ _ MONITORING PERIOD EFFLUENT YEAR : t];R I MO I DAY *** NO DISCHARGE D ... ATTN: Stephanie A. Howard From 09 To 09 07 31 NOTE: Read instructions before completinQ this form. PARAMETER QUANTITY OR LOADING QUALITY OR CONCENTRATION I NO. !FREQUENCY! SAMPLE EX OF TYPE ANALYSIS AVERAGE MAXIMUM UNITS MINIMUM AVERAGE
******** ******** 6.9 ******** 9.3 1 17 I 31 12 0 0 , IN CONDUIT OR THRU ENT PLANT I NAMEITITLE PRINCIPAL EXECUTIVE OFFICER Timothy P. Cleary I Cerflfy under penalty of law that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or I' I ,.JJ4 .* **., J v4:[.'f.,T1CLf L.C * . l"-..; OA.c TELEPHONE DATE persons who manage the system, or those persons directly responsible for gathering the I mformation, the informatJon submitted 1s , to the best of my knowledge and belief, true, Principal Environmental Engineer 423 843-6700 09 08 07 Sequoyah Site Vice President I accurate, and complete. I am aware that there are sigmficant penalties for submitting false information, including the possibility of fine and Imprisonment for knowing violations.
SIGNATURE OF PRINCIPAL EXECUTIVE I OFFICER OR AUTHORIZED AGENT AREA I NUMBER YEAR MO DAY I TYPED OR PRINTED
- - - - ---- ---~-
CODE COMMENTS AND EXPLANATION OF ANY VIOLATIONS (Reference all attachments here) On 7/8/09 the pH limit was exceeded due to a suspected algae bloom. Sulfuric acid was added to the pond and on 7/9/09 the pH was within limits. This exceedance is being addressed through Sequoyah's corrective action program in order to reduce, eliminate, and prevent recurrence. EPA Form 3320-1 (REV 3199) Previous editions may be used Page 1 of 1
PERMITTEE NAME/ADDRESS (Include Facilitv Name/Location if Different) NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPOES) MAJOR Form Approved. Name_~A-SEQUOYA~UCLEA~LANT _ _ _ _ DISCHARGE MONITORING REPORT (DMRJ OMB No. 2040-0004 (SUBR 01) Addres_L .£. ~BOX_19QQ.. _ _ _ _ _ _ _ _ _ _ _ _ ---~TEROFFICESB-2A-SQ~-------- TN0026450 107 G F- FINAL - _ _ __§ODD.r._- DAISY_ _.IN 37381._ _ _ _ _ _ _ _ PERMIT NUMBER METAL CLEANING WASTE POND Facility_ ~A -..§EOUOYAH NUCLEAR PLANT_ _ _ _ _ _ Locatio!)_ .J::!AMILTO.!::!_COUNTY_ _ _ _ _ _ _ _ _ _ _ EFFLUENT YEAR NO DISCHARGE I XX I *** ATTN: Stephanie A. Howard From 1 09 I _ I - - I NOTE: Read instructions before completinq this form. PARAMETER QUANTITY OR LOADING QUALITY OR CONCENTRATION I NO. EX IFREQUENCY OF I SAMPLE TYPE AVERAGE MAXIMUM UNITS MINIMUM RAGE PH ******** ******** ******** 00400 0 0 EFFLUENT GROSS VALUE SOLIDS, TOTAL SUSPENDED 00530 0 0 EFFLUENT GROSS VALUE LAND GREASE 0 0 EFFLUENT GROSS VALUE OSPHORUS, TOTAL (AS P) 1 0 0 FFLUENT GROSS VALUE (AS CU) 0 0 EFFLUENT GROSS VALUE IRON, TOTAL (AS FE) 01045 0 0 EFFLUENT GROSS VALUE FLOW, IN CONDUIT OR THRU TREATMENT PLANT 0 0 NAME/TITLE PRINCIPAL EXECUTIVE OFFICER I Certify under penalty of law that this document and all attachments were prepared under my TELEPHONE DATE Timothy P. Cleary direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inqwry of the person or Jtf-41t., (OJLL(:_Q<\ .Q1!A_) OA.d
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persons who manage the system, or those persons directly responsible for gathenng the Principal Environmental Engineer information, the information submitted is , to the best of my knowledge and belief, true, 423 843-6700 09 08 07 Sequoyah Site Vice President accurate, and complete. I am aware that there are significant penalties for submitting false Information, including the possibility of fine and imprisonment for know1ng violations. SIGNATURE OF PRINCIPAL EXECUTIVE I OFFICER OR AUTHORIZED AGENT AREAl NUMBER YEAR MO DAY I TYPED OR PRINTED CODE COMMENTS AND EXPLANATION OF ANY VIOLATIONS (Reference all attachments here) No Discharge this Period EPA Form 3320-1 (REV 3/99) Previous editions may be used Page 1 of 1
PERMITIEE NAME/ADDRESS (Include Facility Name/Location if Different) NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPOES) MAJOR Form Approved. Name_~A-SEQUOYA~UCLEA~LANT _ _ _ _ DISCHARGE MONITORING REPORT (DMR) (SUBR 01) OMB No. 2040-0004 Addres.L _.!: Q,_BOX2QOO _ _ _ _ _ _ _ _ _ _ _ _
---~TEROFFICESB-2A-SQ~-------- TN0026450 110 G F- FINAL - _ _ _§.ODD.Y_- DAISY_ _I~7381_ _ _ _ _ _ _ _
RECYCLED COOLING WATER Facility_ JYA -..§.FQUOYAH NUCLEAR PLANT_ _ _ _ _ _ Locatio..!l._ _l::!AMIL TOJ::!...COUNTY.._ _ _ _ _ _ _ _ _ _ _ EFFLUENT YEAR NO DISCHARGE I XX I *** ATTN: Stephanie A Howard From I 09 I I NOTE: Read instructions before completinQ this form. PARAMETER QUANTITY OR LOADING QUALITY OR CONCENTRATION I NO. IFREQ EX OF AVERAGE MUM UNITS MINIMUM ANALYSIS AVERAGE MAXIMUM UNITS
, WATER DEG. ******** ********
04 ******** ******** 04 0 0 0 0 DUITORTHRU T PLANT 0 0 RINE, TOTAL RESIDUAL 0 0 NAME/TITLE PRINCIPAL EXECUTIVE OFFICER I Certify under penally of law that th1s document and all attachments were prepared under my , , I . Timothy P. Cleary direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the informat1on submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the _,Jt:;¥hc.:.J (..<._.(__ uz .<LLvL.__)(,~Ac TELEPHONE I DATE information, the information submitted is , to the best of my knowledge and belief, true, Principal Environmental Engineer Sequoyah Site Vice President accurate, and complete. I am aware that there are significant penalties for submitting false 423 843-6700 09 1 08 07 information, including the possibility of fine and imprisonment for knowing violations. SIGNATURE OF PRINCIPAL EXECUTIVE I TYPED OR PRINTED OFFICER OR AUTHORIZED AGENT AREA I NUMBER MO DAY YEAR/ CODE COMMENTS AND EXPLANATION OF ANY VIOLATIONS (Reference all attachments here) No Discharge this Period EPA Form 3320-1 (REV 3199) Previous editions may be used Page 1 of 1
PERMITIEE NAME/ADDRESS (Include Facility Name/Location if Different) NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPOES) MAJOR Form Approved. Name_~A~EQUOYA~UCLEARPLANT _ _ _ _ DISCHARGE MONITORING REPORT (OMRJ OMB No. 2040-0004 (SUBR 01) Add res§_ _E. ~BOX.1.QQ.Q_ _ _ _ _ _ _ _ _ _ _ _ _ ---~TEROFFICESB-2A-SQ~-------- TN0026450 110 T F- FINAL - _ _ _§_ODD..1_- DAISY_ _IN 3738L _ _ _ _ _ _ _ RECYCLED COOLING WATER Facility_ _s:./A- SEQUOYAH NUCLEAR PLANT_ _ _ _ _ _ Locatio..!J._ _!:!AMIL TOJi..COUNTY __________ _ EFFLUENT YEAR DAY NO DISCHARGE I XX I *** ATTN: Stephanie A. Howard From I 09 I -. I -
- I 31 NOTE: Read instructions before completinq this form.
PARAMETER 0 0 EFFLUENT GROSS VALUE
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NAMEfTITLE PRINCIPAL EXECUTIVE OFFICER I Certify under penally of law that this document and all attachments were prepared under my TELEPHONE DATE direction or supervision in accordance with a system designed to assure that qualified personnel Timothy P. Cleary properly gather and evaluate the information submitted. Based on my tnquiry of the person or persons who manage the system, or those persons directly responsible for gathering the Principal Environmental Engineer Sequoyah Site Vice President information, the information submitted is , to the best of my knowledge and belief, true, 423 843-6700 09 08 07 accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fine and imprisonment for knowing violations SIGNATURE OF PRINCIPAL EXECUTIVE l OFFICER OR AUTHORIZED AGENT AREAl NUMBER YEAR MO DAY TYPED OR PRINTED CODE
--- -~-
COMMENTS AND EXPLANATION O,F ANY VIOLATIONS (Reference all attachments here) No Discharge this Period EPA Form 3320-1 (REV 3/99) Previous editions may be used Page 1 of 1
PERMITTEE NAME/ADDRESS (Include Facility Name/Location if Different) NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPOES) MAJOR Form Approved. Na~_~A-SEQUOYA~UCLEA~LANT _ _ _ _ DISCHARGE MONITORING REPORT (OMRJ OMB No. 2040-0004 (SUBR 01) Addres_L _f_.~BOX.1.QQQ_ _ _ _ _ _ _ _ _ _ _ _ _ ---~TEROFFICESB-2A-SQ~-------- TN0026450 116 G F- FINAL - _ _ ~ODDY- DA!.§.Y_ ___IN 37381_ _ _ _ _ _ _ _ BACKWASH Factlitv_ JYA- SEQUOYAH NUCLEAR PLANT_ _ _ _ _ _ Locatio.!}_ _!::!AMILTO.!:!_COUNTY_ _ _ _ _ _ _ _ _ _ _ EFFLUENT ATIN: Stephanie A Howard YEAR From I 09 I -- I -- I DAY 31 NO DISCHARGE D *** NOTE: Read instructions before completinQ this form. PARAMETER NO. !FREQUENCY! SAMPLE EX OF TYPE ANALYSIS MAXIMUM UNITS RIS, FLOATING (SEVERITY) 0 0 1 I 31 VISUAL 9A 0 IL AND GREASE VISUAL 0 0
.J tL:ptlO..iL-~tDz ,<f..bit.") 0:-'-- cJ NAME/TITLE PRINCIPAL EXECUTIVE OFFICER I Certify under penalty of law that this document and all attachments were prepared under my TELEPHONE DATE direction or supervision in accordance with a system designed to assure that qualified personnel Timothy P. Cleary properly gather and evaluate the information submitted. Based on my inqwy of the person or persons who manage the system, or those persons dtrectly responsible for gathering the Principal Environmental Engineer . . . informat1on, the information submitted is , to the best of my knowledge and belief, true, 423 I 843-6700 09 08 07 Sequoyah S1te VICe PreSident accurate, and complete. I am aware that there are signif1cant penalties for submitting false SIGNATURE OF PRINCIPAL EXECUTIVE information, indudmg the poss1bility of fine and imprisonment for know1ng violations. OFFICER OR AUTHORIZED AGENT AREAl NUMBER YEAR MO DAY TYPED OR PRINTED CODE COMMENTS AND EXPLANATION OF ANY VIOLATIONS (Reference all attachments here)
Operations performs visual inspections for floating debris and oil and grease during all backwashes. EPA Form 3320-1 (REV 3/99) Previous editions may be used Page 1 of 1
PERMITTEE NAME/ADDRESS (Include Facility Name/Location if Different) NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPOES) Form Approved. MAJOR Name_~A-SEQUOYA~UCLEA~LANT _ _ _ _ DISCHARGE MONITORING REPORT (DMR) (SUBR 01) OMB No. 2040-0004 Addres,L _E ~BOX_1900 _ _ _ _ _ _ _ _ _ _ _ _ ---~TEROFFICESB-2A-SQ~-------- TN0026450 117 G F- FINAL - _ _ _§.ODDl- DAISY_ _IN 3738L _ _ _ _ _ _ _ BACKWASH Facility_ _IVA -_g':QUOYAH NUCLEAR PLANT_ _ _ _ _ _ Locatio.!}_ .J::!AMILTO..!i._COUNTl:_ _ _ _ _ _ _ _ _ _ _ EFFLUENT ATTN: Stephanie A Howard YEAR From I 09 I -- I -- I NO DISCHARGE C *** NOTE: Read instructions before completinq this form. PARAMETER QUANTITY OR LOADING QUALITY OR CONCENTRATION I NO. [FREQUENCY[ SAMPLE EX OF TYPE AVERAGE MAXIMUM UNITS MINIMUM AVERAGE MAXIMUM UNITS BRIS, FLOATING (SEVERITY) ******** ******** ******** ******** 0 0 9A 0 OIL AND GREASE VISUAL 84066 1 0 0 EFFLUENT GROSS VALUE NAME/TITLE PRINCIPAL EXECUTIVE OFFICER I Certify under penalty of law that th1s document and all attachments were prepared under my Timothy P. Cleary direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inqwry of the person or
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I) TELEPHONE DATE persons who manage the system, or those persons directly responsible for gathering the Principal Environmental Engineer information, the information submitted is , to the best of my knowledge and belief. true, 423 843-6700 09 08 07 Sequoyah Site Vice President accurate, and complete. I am aware that there are significant penalties for submitting false SIGNATURE OF PRINCIPAL EXECUTIVE I TYPED OR PRINTED information, including the possibility of fine and imprisonment for knowing violations. OFFICER OR AUTHORIZED AGENT AREA CODE l NUMBER YEAR MO DAY COMMENTS AND EXPLANATION OF ANY VIOLATIONS (Reference all attachments here) Operations performs visual inspections for floating debris and oil and grease during all backwashes. EPA Form 3320-1 (REV 3/99) Previous editions may be used Page 1 of 1
PERMITIEE NAME/ADDRESS (Include Facility Name/Location if Different) NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPOES) Form Approved. MAJOR Na~-~~*SEQUOYA~UCLEA~LANT _ _ _ _ DISCHARGE MONITORING REPORT (OMR) OMB No. 2040-0004 (SUBR 01) Addres_L _f ~BOX.1QQQ_ ___________ _ ---~TEROFFICESB-2A-SQ~-------- TN0026450 118 G F- FINAL - _ _ _§_ODD_.l:_- DAISY_ _IN 37381._ _ _ _ _ _ _ _ PERMIT NUMBER DISCHARGE NUMBER I WASTEWATER & STORM WATER Facility_ JYA- SEQUOYAH NUCLEAR PLANT_ _ _ _ _ _ Locatio..!l_ _!:!AMIL TO.!::!_COUNTY._ _ _ _ _ _ _ _ _ _ _ MONITORING PERIUU EFFLUENT YEAR I MO I DAY I DAY NO DISCHARGE I XX I *** ATTN: Stephanie A. Howard From 09 07 01 To 31 NOTE: Read instructions before completinQ this form. PARAMETER QUALITY OR CONCENTRATION I NO. IFREQUENCY I SAMPLE TYPE MINIMUM AVERAGE MAXIMUM UNITS (DO) ******** ******** 19 DUIT ORTHRU T PLANT 0 0 NAME/TITLE PRINCIPAL EXECUTIVE OFFICER I Certify under penalty of law that th1s document and all attachments were prepared under my _,.:jte_p)[cuU£Ct<tku_uz d TELEPHONE DATE direction or supervision m accordance with a system designed to assure that qualif1ed personnel Timothy P. Cleary properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the Principal Environmental Engineer Sequoyah Site Vice President information, the information submitted IS , to the best of my knowledge and belief, true, 423 843-6700 09 08 07 accurate, and complete. I am aware that there are significant penalties for submitting false information, 1ncluding the possibility of fine and imprisonment for knowing violations SIGNATURE OF PRINCIPAL EXECUTIVE l OFFICER OR AUTHORIZED AGENT AREAl NUMBER YEAR MO DAY TYPED OR PRINTED CODE COMMENTS AND EXPLANATION OF ANY VIOLATIONS (Reference all attachments here) During this reporting period, there has been no flow from the Dredge Pond other than that resulting from rainfall. EPA Form 3320-1 (REV 3/99) Previous editions may be used Page 1 of 1
S58 090911 800 - NPDES CORRESPONDENCE September 11 , 2009 State of Tennessee Department of Environment and Conservation Division of Water Pollution Control Enforcement & Compliance Section 61h Floor, L & C Annex 401 Church Street Nashville, Tennessee 37243-1534
Dear Mr. Patrick Cromer:
SEQUOYAH NUCLEAR PLANT- DISCHARGE MONITORING REPORT FOR AUGUST 2009 Enclosed is the August 2009 Discharge Monitoring Report for Sequoyah Nuclear Plant. If you have any questions or need additional information, please contact Ann Hurt at (423) 843-6714 or Stephanie Howard at (423) 843-6700 of Sequoyah's Environmental staff. Sincerely, ~:~~ Site Vice President Sequoyah Nuclear Plant AH Enclosure cc (Enclosure): Chattanooga Environmental Field Office Division of Water Pollution Control State Office Building, Suite 550 540 McCallie Avenue Chattanooga, Tennessee 37402-2013 U.S. Nuclear Regulatory Commission ATTN: Document Control Desk Washington, D.C. 20555 cc: D. J. Bodine, POB 2A-SQN A. A. Ray, WT 11A-K C. R. Church, POB 2B-SQN G. R. Signer, WT 6A-K T. P. Cleary, OPS 4A-SQN B. A. Wetzel, OPS 4A-SQN D. E. Pittman, LP SE-C EDMS, WT CA-K (Enclosure) DMR0908.doc
REVIEW /CONCURRENCE SHEET DOCUMENT NAME: SEQUOYAH NUCLEAR PLANT- DISCHARGE MONITORING REPORT FOR AUGUST 2009 ORGANIZATION: Environmental DOCUMENT PREPARED BY: Ann Hurt DATE: 09/08/09 CATEGORY: NPDES Correspondence CONCURRENCES Name R c Signature - Comment Date v N Ann Hurt X Stephanie A Howard X Debra J Bodine X Beth A. Wetzel X Chris R Church X Timothy P Cleary X (for signature) I\~E?r'C'l INSTRUCTIONS: Originator will determine the review/concurrence assignment. REVIEW: Examine technical content and commitments made. A review (RV) should confirm the truth and accuracy of factual statements and indicate agreement with commitments made which are applicable to the reviewer's organization. CONCURRENCE: Indication of agreement with the document as a whole. Concurrence (CN) signifies that the document is responsive to the intended purpose, logical in construction, and clear in meaning in the eyes of the recipient. A concurrence signature indicates that the individual would be willing to sign the document for the agency.
Tennessee Valley Authority Post Office Box 2000 Soddy Daisy, Tennessee 37384-2000 Timothy P. Cleary Site Vice President Sequoyah Nuclear Plant September 11, 2009 State of Tennessee Department of Environment and Conservation Division of Water Pollution Control Enforcement & Compliance Section 6th Floor, L & C Annex 401 Church Street Nashville, Tennessee 37243-1534
Dear Mr. Patrick Cromer:
SEQUOYAH NUCLEAR PLANT- DISCHARGE MONITORING REPORT FOR AUGUST 2009 Enclosed is the August 2009 Discharge Monitoring Report for Sequoyah Nuclear Plant. If you have any questions or need additional information, please contact Ann Hurt at (423) 843-6714 or Stephanie Howard at (423) 843-6700 of Sequoyah's Environmental staff. Sincerely, 4~ Timothy P. Cleary Site Vice President Sequoyah Nuclear Plant Enclosure cc (Enclosure): Chattanooga Environmental Field Office Division of Water Pollution Control State Office Building, Suite 550 540 McCallie Avenue Chattanooga, Tennessee 37402-2013 U.S. Nuclear Regulatory Commission ATTN: Document Control Desk Washington, D.C. 20555 p~inted on recycled paper
PERMITIEE NAME/ADDRESS (Include Faci/itv Name/Location if Different) NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPDE;S) Form Approved. MAJOR Na~-~A-SEQUOYA~UCLEARPLANT _ _ _ _ DISCHARGE MONITORING REPORT (DMR) OMB No 2040-0004 (SUBR 01) Add res§_ _E.~BOX 20QQ.. _ _ _ _ _ _ _ _ _ _ _ _
---~TEROFFICESB-2A-SQ~-------- TN0026450 F- FINAL ---~ODDY-DAIS~~738L _______ _ DIFFUSER DISCHARGE Facility_ ..JYA -..§E:QUOYAH NUCLEAR PLANT_ _ _ _ _ _
Locatio.!}_ .J::!AMILTOJ:i.COUNTY __________ _ EFFLUENT From
*** NO DISCHARGE D ...
ATTN: Stephanie A. Howard 1 __ I -- 1 -
- 1 NOTE: Read instructions before completing this form.
PARAMETER NO. 'FREQUENCY' SAMPLE EX OF TYPE ANALYSIS AVERAGE UNITS WATERDEG. ******** 04 0 31 I 31 I MODELD 0 RE, WATER DEG. RADE 1 0 0 P. DIFF. BETWEEN SAMP. & UPSTRM DEG.C s 0 0 0 0 0 EFFLUENT GROSS VALUE
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NAME/TITLE PRINCIPAL EXECUTIVE OFFICER 1Certify under penalty of law that this document and all attachments were prepared under my TELEPHONE DATE r-~-- f--* direction or supervision in accordance with a system des1gned to assure that qualified personnel Timothy P. Cleary properly gather and evaluate the information submitted Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the Sequoyah ite Vice P sident information. the information submitted is , to the best of my knowledge and belief, true, -*- 423 843-7001 09 09 08 Sequoyah Site Vice President accurate, and complete. I am aware that there are significant penalties for submitting false SIGNATURE OF PRINCIPAL EXECUTIVE I TYPED OR PRINTED information, including the possibility of fine and imprisonment for knowing violations. OFFICER OR AUTHORIZED AGENT AREA CODE I NUMBER YEAR M~~~ DAY COMMENTS AND EXPLANATION OF ANY VIOLATIONS (Reference all attachments here) No closed mode operation. The following information is included in an attachment: CCW data. Measured values for thermal compliance and Diffuser flow used for 8/29 thru 8/31 (rather than computed values) because thermal compliance model was out of service due to failure of instrumentation for Diffuser flow. EPA Form 3320-1 (REV 3/99) Previous editions may be used Page 1 of 2
DMR Attachment CCW Data CCWTRENCH Extractable Petroleum Dateffime Collected Hydrocarbons Analysis Dateffime Analyst Method No water would come out of the pump. No sample could be obtained. CCWCHANNEL Extractable Petroleum Dateffime Collected Hydrocarbons Analysis Dateffime Analyst Method 08/11/2009@ 1025 <0.10 mg/1 08/14/2009 @ 0956 JOB EPH
PERMITTEE NAME/ADDRESS (Include Facility Name/Location ifDifferentJ NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPDESJ MAJOR Form Approved. Name_~A-SEQUOYA~UCLEARP~NT _ _ _ _ DISCHARGE MONITORING REPORT (OMRJ OMB No. 2040-0004 (SUBR 01) Addres§_.J:-~BOX..lflOO - - - - - - - - - - - -
---~TEROFFICESB-2A-SQ~-------- TN0026450 101 G F- FINAL ---~DDY-DAISY~~738L _ _ _ _ _ _ _ _
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NOTE: Read instructions before completinQ this form. PARAMETER QUANTITY OR LOADING Q-UALITY OR CONCENTRATION I NO. IFREQUENCY I SAMPLE EX OF TYPE ANALYSIS AVERAGE MAXIMUM UNITS MINIMUM AVERAGE MAXIMUM UNITS CHLORINE, TOTAL RESIDUAL ******** ******** ******** 0.021 0.034 22/31 GRAB
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~-----:rEi.~EPHONE ---- - ~9~ f .Pf.u~l NAME/TITLE PRINCIPAL EXECUTIVE OFFICER 1Certify under penalty of law that this document and all attachments were prepared under my DATE t--~---- direction or supervision in accordance with a system designed to assure that qualified personnel Timothy P. Cleary properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the s:quoyah -!ite Vice Presirent information, the information submitted is , to the best of my knowledge and belief, true, 423 843-7001 09 09 08 Sequoyah Site Vice President accurate, and complete. t am aware that there are significant penalties for submitting false SIGNATURE OF PRINCIPAL EXECUTIVE I TYPED OR PRINTED information. including the possibility of fine and imprisonment tor knowing violations. OFFICER OR AUTHORIZED AGENT AREA CODE I NUMBER YEAR MO DAY COMMENTS AND EXPLANATION OF ANY VIOLATIONS (Reference all attachments here)
The following injections occured: 1. Biodetergent 73551 (max. calc. cone. was 0.017mg/L-Iimit 2.0mg/L) 2. MSW-101 (max. calc. cone. was 0.061mg/L--Iimit 0.2mg/L) 3. H-150M (max. calc. cone. was 0.04mg/L--Iimit 0.050mg/L) 4. H-150M (low detection level analytical method) results have not been received yet. EPA Form 3320-1 (REV 3/99) Previous editions may oe usea Page 2 of 2
PERMITIEE NAME/ADDRESS (Include Facility Name/Location if Different! NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPDES) Form Approved. MAJOR Na~-~A-SEQUOYA~UCLEARP~~---- DISCHARGE MONITORING REPORT (DMR! (SUBR 01) OMS No. 2040-0004 Addres,L __e.Q._Iill,_X 2000 _ _ _ _ _ _ _ _ _ _ _ _
---~T~FFigSB-2A-SQ~-------- TN0026450 F- FINAL - _ _ _§QQ.DY- DAISY._I_N._]7381_ _ _ _ _ _ _ _ _ _ BIOMONITORING FOR OUTFALL 101 Facilitv_ JYA- SEQUOYAH NUCLEAR PLA.JiT_ _ _ _ _ _
LocatiOJL .J:!AMILTO!!._COUNTY __________ _ EFFLUENT ATTN: Stephanie A. Howard From LQ9 YEAR
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1 NOTE: Read instructions before completing this form. PARAMETER QUANTITY OR LOADING QUALITY OR CONCENTRATION ltiiC>.IFREOU_E_N_C_Y,--S_A_M_P_L_E.--, I EX I ANALYSISOF TYPE AVERAGE MAXIMUM UNITS MINIMUM AVERAGE MAXIMUM UNITS IC25 STATRE 7DAY CHR ******** ******** ** ******** ******** 23 CERIODAPHNIA TRP3B 1 0 0 EFFLUENT GROSS VALUE
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j NAME/TITLE PRINCIPAL EXECUTIVE OFFICER 1Certify under penalty of law that this document and all attachments were prepared under my ~A TELEPHONE __ DATE__ Timothy P. Cleary direction or supervision in accordance with a system designed to assure that qualified personnel property gather and evaluate the information submitted. Based on my inquiry of the person or T .>>.. f~ c-------** persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is , to the best of my knowledge and belief, true, Sequoyah s1e Vice Preside~ 423 843-7001 09 09 08 ! Sequoyah Site Vice President accurate, and complete. I am aware that there are significant penalties for submitting false SIGNATURE OF PRINCIPAL EXECUTIVE I TYPED OR PRINTED information. including the possibility of fine and imprisonment for knowing violations. OFFICER OR AUTHORIZED AGENT AREA CODE I NUMBER YEAR MO DAY I COMMENTS AND EXPLANATION OF ANY VIOLATIONS (Reference all attachments here) Toxicity was not sampled in August 2009. EPA Form 3320-1 (REV 3199) Previous editions may be used Page 1 of 1
PERMITTEE NAME/ADDRESS (Include Facility Name/Location if Different) NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPDES) Form Approved. MAJOR Na~-~A-SEQUOYA~UCLEA~LANT _ _ _ _ DISCHARGE MONITORING REPORT (DMRI (SUBR 01) OMB No. 2040-0004 Add res§_ .J:.Q.._BOX 20QQ_ _ _ _ _ _ _ _ _ _ _ _ _
---~TEROFFICESB-2A-SQ~-------- TN0026450 103 G F- FINAL - _ _ _§QQ.DY
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Locatio.!l_ .J::!AMILTOJi.COUNTY._ _ _ _ _ _ _ _ _ _ _ EFFLUENT YEAR ATTN: Stephanie A. Howard From 09
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r- PARAMETER QUANTITY OR LOADING NOTE: Read instructions before completinQ this form. QUALITY oR coNCENTRATION 1 NO. IFREQUEt*i"cvr SAMPL-e-* EX OF TYPE i AVERAGE MAXIMUM UNITS MINIMUM AVERAGE MAXIMUM UNITS ANALYSIS PH ******** ******** 6.7 ******** 7.4 0 13 /31 GRAB
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***;*;;{p~~MtT:... i:o' ,, RE~UIIi~EMt:tfJ;:l, ~,;," ,:, '_y\:~,;;0!/" ~;.!:Jw'"t NAME/TITLE PRINCIPAL EXECUTIVE OFFICER 1Ce1iify under penalty of law that this document and all attachments were prepared under my TELEPHONE DATE direction or supervision in accordance with a system designed to assure that qualified personnel Timothy P. Cleary properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is . to the best of my knowledge and belief. true, 423 843-7001 09 09 08 Sequoyah Site Vice President accurate, and complete. I am aware that there are significant penalties for submitting false SIGNATURE OF PRINCIPAL EXECUTIVE I TYPED OR PRINTED information, including the possibility of fine and imprisonment for knowing violations. OFFICER OR AUTHORIZED AGENT AREA CODE I NUMBER YEAR MO-- DAY COMMENTS AND EXPLANATION OF ANY VIOLATIONS (Reference all attachments here)
EPA Form 3320-1 (REV 3/99) Previous editions may be used Page 1 of 1
PERMITIEE NAME/ADDRESS (Include Facility Name/Location if Different) NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPDES) Form Approved. MAJOR Na~-~A-SEQUOYA~UCLEARPLANT _ _ _ _ DISCHARGE MONITORING REPORT (OMRI OMB No. 2040-0004 (SUBR 01) Add res§_ _E.Q..BOX.1QOO _ _ _ _ _ _ _ -
- _ _ _ _
---~TEROFFICESB-2A-SQ~-------- TN0026450 107 G F- FINAL - _ _ _§.ODD_Y..- DAISYJ.N_j73BL _ _ _ _ _ _ _ _ METAL CLEANING WASTE POND Facility_ ..JYA- SEQUOY~NUCLEAR PLANT_ _ _ _ _ _
Locatio.!!_ _j:JAMIL TOli.COUNTL _ _ _ _ _ _ _ _ _ _ _ EFFLUENT YEAR DAY
*** NO DISCHARGE I XX I ***
ATTN: Stephanie A. Howard From 09 31 NOTE: Read instructions before completinQ this form. PARAMETER QUANTITY OR LOADING QUALITY OR CONCENTRATION I NO. EX IFREQUENCY OF SAMPLE TYPE ANALYSIS AVERAGE MAXIMUM UNITS MINIMUM AVERAGE MAXIMUM UNITS PH ******** ******** ******** 12 00400 1 0 0 EFFLUENT GROSS VALUE SOLIDS, TOTAL SUSPENDED 00530 0 0 EFFLUENT GROSS VALUE OIL AND GREASE 19 00556 1 0 0 .;)~;;*~.;tl~'.f':::;~~; *~ MG/L EFFLUENT GROSS VALUE : *DAILY:; MXi PHOSPHORUS, TOTAL (AS P) 19
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00665 0 0 MG/L EFFLUENT GROSS VALUE .* J. DAIL.YMX* COPPER, TOTAL (AS CU) 01042 1 0 0 EFFLUENT GROSS VALUE IRON, TOTAL (AS FE) 01045 0 0 EFFLUENT GROSS VALUE FLOW, IN CONDUIT OR THRU TREATMENT PLANT 50050 1 0 0 EFFLUENT GROSS VALUE T*~f~ NAME/TITLE PRINCIPAL EXECUTIVE I Certify under penalty of law that this document and all attachments were prepared under my TELEPHONE DATE
~~--- ----~-- . OFFICER direction or supervision in accordance with a system designed to assure that qualified personnel **-*-----r----*-
Timothy P. Cleary properly gather and evaluate the information submitted. Based on my inquiry of the person or I persons who manage the system, or those persons directly responsible for gathering the Sequoyahb;te Vice Pr ident information, the information submitted is , to the best of my knowledge and belief, true, 423 843-7001 09 09 08 Sequoyah Site Vice President accurate, and complete. I am aware that there are significant penalties for submitting false SIGNATURE OF PRINCIPAL EXECUTIVE I TYPED OR PRINTED information, including the poss.ibility of fine and imprisonment for knowing violations. OFFICER OR AUTHORIZED AGENT AREA CODE I NUMBER YEAR MO DAY COMMENTS AND EXPLANATION OF ANY VIOLATIONS (Reference all attachments here) No Discharge this Period EPA Form 3320-1 (REV 3/99) Previous editions may be used Page 1 of 1
PERMITTEE NAME/ADDRESS (Include Facility Name/Location if Different) NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPDES) Form Approved. MAJOR Na~-2~-SEQUOYA~UCLEARP~~---- DISCHARGE MONITORING REPORT (DMRI (SUBR 01) OMB No. 2040-0004 Addres.L ...f..~BOX2QQQ. ___________ _
---~TEROFFICESB-2A-SQ~-------- TN0026450 110 G F- FINAL
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*** NO DISCHARGE [0 ***
NOTE: Read instructions before completin~ this form.
~-- PARAMETER QUANTITY OR LOADING QUALITY OR CONCENTRATION I NO. IFREQUENCY ISAMPLE' EX OF TYPE ANALYSIS AVERAGE MAXIMUM UNITS MINIMUM AVERAGE MAXIMUM UNITS ~ERATURE,WATER DEG. ******** ******** 04 ******** ******** 04 lcE.NTIGRADE I
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NAME/TITLE PRINCIPAL EXECUTIVE OFFICER I Certify under penalty of law that thrs document and all attachments were prepared under my TELEPHONE DATE direction or supervision rn accordance with a system designed to assure that qualified personnel Timothy P. Cleary properly gather and evaluate the information submitted. Based on my inqurry of the person or persons who manage the system, or those persons directly responsible for gathering the Sequoya Site Vice P sident information, the information submitted is , to the best of my knowledge and belief, true, 423 843-7001 09 09 08 Sequoyah Site Vice President accurate, and complete. I am aware that there are significant penalties for submitting false SIGNATURE OF PRINCIPAL EXECUTIVE I information, includrng the possibility of fine and imprisonment for knowing violations. *Ma- DAY OFFICER OR AUTHORIZED AGENT AREA I TYPED OR PRINTED COMMENTS AND EXPLANATION OF ANY VIOLATIONS (Reference all attachments here) CODE I NUMBER YEAR No Discharge this Period EPA Form 3320-1 (REV 3/99) Previous editions may be used Page 1 of 1
PERMITIEE NAME/ADDRESS (Include Facility Name/Location if Different) NATIONAL POLLUTANT OISCHARGE ELIMINATION SYSTEM (NPDES) MAJOR Form Approved. Na~-~A-SEQUOYA~UCLEARPLANT ___ _ DISCHARGE MONITORING REPORT (DMR) OMB No. 2040-0004 (SUBR 01) Addres,L _E.Q,_BOX 2000 _ _ _ _ _ _ _ _ _ _ _ _ TN0026450 110 T F- FINAL ---~TEROFFICESB-~SQ~-------- - _ _ _§ODDY- DAISYJN_]7361._ _ _ _ _ _ _ _ _ _ RECYCLED COOLING WATER Facilitv_ ..JYA- SEQUOYAH NUCLEAR PLANT_ _ _ _ _ _ Locatio.!!_ _!:!AMILTOJ:i_COUNTY__________ _ EFFLUENT YEAR
*** NO DISCHARGE [EKj ***
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- NOTE: Read instructions before completing this form.
PARAMETER QUANTITY OR LOADING QUALITY OR CONCENTRATION I NO. IFREQUENCY I SAMPLE EX OF TYPE ANALYSIS AVERAGE MAXIMUM UNITS MINIMUM AVERAGE MAXIMUM UNITS IC25 STATRE 7DAY CHR ******** ******** ** ******** ******** CERIODAPHNIA
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NAME/TITLE PRINCIPAL EXECUTIVE OFFICER I Certify under penalty of law that this document and all attachments were prepared under my TELEPHONE DATE direction or supervision in accordance with a system designed to assure that qualified personnel
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No Discharge this Period EPA Form 3320-1 (REV 3/99) Previous editions may be used Page 1 of 1
PERMITTEE NAME/ADDRESS (Include Facility Name/Location if Different) NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPDES) Form Approved. MAJOR Name_~A-SEQUOYA~UCLEARP~NT _ _ _ _ DISCHARGE MONITORING REPORT (DMRJ (SUBR 01) OMB No. 2040-0004 Addres.L _E.~BOX 2000 _ _ _ _ _ _ _ _ _ _ _ _ ---~TEROFFICESB-2A-SQ~-------- TN0026450 116 G F- FINAL - _ _ _§_ODDY- DAISY...IN~7381._ _ _ _ _ _ _ _ _ _ BACKWASH Facilitv_ JYA -..§EQUOYAH NUCLEAR PLANT_ _ _ _ _ _ Locatio.!L .J:!.AMILTOl:LCOUNTL _ _ _ _ _ _ _ _ _ _ _ EFFLUENT YEAR DAY
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ATTN: Stephanie A. Howard From! 09 -- -- 31 NOTE: Read instructions before completinQ this form. _ _ ___.., PARAMETER QUANTITY OR LOADING QUALITY OR CONCENTRATION I NO~lFREQUENCYT. y SAMPLE EX OF . I. TYPE AVERAGE MAXIMUM UNITS MINIMUM AVERAGE MAXIMUM UNITS DEBRIS, FLOATING (SEVERITY) SAMPLE MEASUREMENT
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NAMErrJTLE PRINCIPAL EXECUTIVE OFFICER I Certify under penalty of law that this document and all attachments were prepared under my TELEPHONE DATE direction or supervision in accordance with a system designed to assure that qualified personnel Timothy P. Cleary properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the Site Vice Prfsident information, the information submitted is . to the best of my knowledge and belief, true, 423 843-7001 09 09 08 Sequoyah Site Vice President accurate, and complete. 1am aware that there are significant penalties for submitting false SIGNATURE OF PRINCIPAL EXECUTIVE I TYPED OR PRINTED information. including the possibility of fine and imprisonment for knowing violations. OFFICER OR AUTHORIZED AGENT AREA CODE I NUMBER YEAR MO DAY I -* COMMENTS AND EXPLANATION OF ANY VIOLATIONS {Reference all attachments here) Operations performs visual inspections for floating debris and oil and grease during all backwashes.
--*----*-*--------*~---~--------
EPA Form 3320-1 (REV 3/99) Previous editions may be used Page 1 of 1
PERMITTEE NAME/ADDRESS (Include Facility Name/Location if Different) NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPDES) Form Approved. MAJOR Na~-~A-SEQUO~~UCLEARPLANT _ _ _ _ DISCHARGE MONITORING REPORT (DMRJ OMB No. 2040-0004 (SUBR 01) Addres,L _E.~BOX 2000 _ _ _ _ _ _ _ _ _ _ _ _ ---~~ROFFICESB-2A-SQ~-------- TN0026450 117 G F- FINAL
- _ _ _§ODQY.: DAISY...I.N..J738i_ _ _ _ _ _ _ _ _ BACKWASH Facility_ ..JYA -_lli:QUOYAH NUCLEAR PLANT_ _ _ _ _ _
Locatio.!l._ ..J:!AMIL TOl:LCOUNTL_ _ _ _ _ _ _ _ _ _ _ EFFLUENT YEAR
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ATIN: Stephanie A. Howard From I 09 I -- 1 -
- 1 NOTE: Read instructions before completinQ this form.
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-~--Q-U_A_L_ITY_O_R_C_O_N_C_E_N_TR_A_T_IO_N SAMPLI PARAMETER QUANTITY OR LOADING EX I OF TYPE AVERAGE MAXIMUM UNITS MINIMUM AVERAGE MAXIMUM I UNITS I I ANALYSIS DEBRIS, FLOATING (SEVERITY) ******** ******** .. ******** ******** 0 9A 1 I 31 VISUAL ..1 01345 EFFLUENT GROSS VALUE 0 0
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~~ME!TITLE PRINCIPAL EXECUTIVE OFFICER I Certify under penalty of law that this document and all attachments were prepared under my TELEPHONE I DATE direction or supervision in accordance with a system designed to assure that qualified personnel I Timothy P. Cleary properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is , to the best of my knowledge and belief, true, 843-7001 I 09 09 08 I .. Sequoyah Site Vice President accurate, and complete. I am aware that there are significant penalties for submitting false t TYPED OR PRINTED information, including the possibility of fine and imprisonment for knowing violations. COMMENTS AND EXPLANATION OF ANY VIOLATIONS (Reference all attachments here) WL NUMBER IYEAR I MO I DAY Operations performs visual inspections for floating debris and oil and grease during all backwashes. EPA Form 3320-1 (REV 3/99) Previous editions may be used Page 1 of 1
PERMIITEE NAME/ADDRESS (Include Facility Name/Location if Different) NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPDES) MAJOR Form Approved.
~~-~A-SEQUOYA~UCLEA~LANT _ _ _ _ DISCHARGE MONITORING REPORT (DMRJ OMB No. 2040-0004 (SUBR 01)
Add res.§_ .J:.Q._BOX 2000 _ _ _ _ _ _ _ _ _ _ _ _ _
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ATTN: Stephanie A. Howard From l.Q!!_ 1 -- 1 -. 1 NOTE: Read instructions before completin{:l this form. PARAMETER QUANTITY OR LOADING _ _ _Q_U_A_L-ITY_O_R_C_O_N-.,C_E_N_T-RA_T_I_ON I I NO. FREQUENCYTSAM-PLE I EX OF TYPE ANALYSIS AVERAGE MAXIMUM UNITS MINIMUM AVERAGE MAXIMUM UNITS OXYGEN, DISSOLVED (DO) ******** ******** ******** ******** 19 00300 0 0 <' .: PERMIT .
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EFFLUENT GROSS VALUE * * * . MO'*AVG": cr-..~.~ NAMEiTITLE PRINCIPAL EXECUTIVE OFFICER 1Certify under penalty of law that this document and all attachments were preparad under my TELEPHONE DATE direction or supervision in accordance with a system designed to assure that qualified personnel
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f-- Sequoy~J Site Vice resident Timothy P. Cleary properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is , to the best of my knowledge and belief, true, 423 843-7001 09 Sequoyah Site Vice President accurate, and complete. I am aware that there are significant penalties for submitting false SIGNATURE OF PRINCIPAL EXECUTIVE I information, including the possibility of fine and imprisonment for knowing violations. OFFICER OR AUTHORIZED AGENT AREA I NUMBER YEAR f--- TYPED OR PRINTED CODE COMMENTS AND EXPLANATION OF ANY VIOLATIONS (Reference all attachments here) During this reporting period, there has been no flow from the Dredge Pond other than that resulting from rainfall. EPA Form 3320-1 (REV 3/99) Previous editions may be used Page 1 of 1
S58 091013 800- NPDES CORRESPONDENCE October 13, 2009 State of Tennessee Department of Environment and Conservation Division of Water Pollution Control Enforcement & Compliance Section 61h Floor, L & C Annex 401 Church Street Nashville, Tennessee 37243-1534
Dear Mr. Patrick Cromer:
SEQUOYAHNUCLEAR PLANT- DISCHARGE MONITORING REPORT FOR SEPTEMBER 2009 Enclosed is the September 2009 Discharge Monitoring Report for Sequoyah Nuclear Plant. If you have any questions or need additional information, please contact Ann Hurt at (423) 843-6714 or Stephanie Howard at (423) 843-6700 of Sequoyah's Environmental staff. S~er~. ly 1. c~vr~P~ Timothy P.* Cleary ' ) Site Vice President Sequoyah Nuclear Plant - AH Enclosure cc (Enclosure): Chattanooga Environmental Field Office Division of Water Pollution Control State Office Building, Suite 550 540 McCallie Avenue Chattanooga, Tennessee 37402-2013 U.S. Nuclear Regulatory Commission ATTN: Document Control Desk Washington, D.C. 20555 cc: C. R. Church, POB 28-SQN A. A Ray, WT 11A-K T. P. Cleary, OPS 4A-SQN G. R. Signer, WT 6A-K W. A Nurnberger Ill, POB 2A-SQN B. A Wetzel, OPS 4A-SQN D. E. Pittman, LP 5E-C EDMS, WT CA-K DMR0909.doc
REVIEW/CONCURRENCE SHEET DOCUMENT NAME: SEQUOYAH NUCLEAR PLANT - DISCHARGE MONITORING REPORT FOR SEPTEMBER 2009 ORGANIZATION: Environmental DOCUMENT PREPARED BY: Ann Hurt DATE: 10/07/2009 CATEGORY: NPDES Correspondence CONCURRENCES Name R c Signature - Comment Date v N Ann Hurt X Stephanie A Howard X W. A. Nurnberger X Beth A. Wetzel X Chris R Church X (~ 6c Timothy P Cleary X (for signature) ~- i!.oclo'i' INSTRUCTIONS: Originator will determine the review/concurrence assignment. REVIEW: Examine technical content and commitments made. A review (RV) should confirm the truth and accuracy of factual statements and indicate agreement with commitments made which are applicable to the reviewer's organization. C.ONCURRENCE: Indication of agreement with the document as a whole. Concurrence (CN) signifies that the document is responsive to the intended purpose, logical in construction, and clear in meaning in the eyes of the recipient. A concurrence signature indicates that the individual would be willing to sign the document for the agency.
Tennessee Valley Authority Post Office Box 2000 Soddy Daisy, Tennessee 37384-2000 Timothy P. Cleary Site Vice President Sequoyah Nuclear Plant October 13, 2009 State of Tennessee Department of Environment and Conservation Division of Water Pollution Control Enforcement & Compliance Section 61h Floor, L & C Annex 401 Church Street Nashville, Tennessee 37243-1534
Dear Mr. Patrick Cromer:
SEQUOYAH NUCLEAR PLANT- DISCHARGE MONITORING REPORT FOR SEPTEMBER 2009 Enclosed is the September 2009 Discharge Monitoring Report for Sequoyah Nuclear Plant. If you have any questions or need additional information, please contact Ann Hurt at (423) 843-6714 or Stephanie Howard at (423) 843-6700 of Sequoyah's Environmental staff. Sincer:; . ~J,f--f~ Timothy P. Cleary. Site Vice President V Sequoyah Nuclear Plant Enclosure cc (Enclosure): Chattanooga Environmental Field Office Division of Water Pollution Control State Office Building, Suite 550 540 McCallie Avenue Chattanooga, Tennessee 37402-2013 U.S. Nuclear Regulator)i Commission ATTN: Document Control Desk Washington, D.C. 20555 p~inted on recycled paper
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. . . 11nformat1on, the 1nformat1on subm1tted 1s, to the best of my knowledge and belief, true, ----------~- __ --------------i 423 8 43 -7 001 ! 07 "-----L---------t...- *-------~--- ! 09 , 1 1
- . . .S. equoy_ ah S_ l_te V1ce P_ resident ;accurate, and complete 1am aware that there are sigmficant penaltiesfor subm1tt1ng false SIGNATURE OF PRINCIPAL EXECUTIVE _j i _____ ... _ * * - - - -~..----- ---------------i'nformat1on, including the possibility of fme and Imprisonment for know1ng VIolations OFFICER OR AUTHORIZED AGENT 1 AREA ! NUMBER YEART MO ! DAY ,
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COMMENTS AND EXPLANATION OF ANY VIOLATIONS (Reference all attachments here) No closed mode operation.* The following information is included in an attachment: CCW data EPA Form 3320-1 (REV 3/99) Previous editions may be used Page 1 of 2
DMR Attachment CCW Data CCWTRENCH Extractable Petroleum Date/Time Collected Hydrocarbons Analysis Date/Time Analyst Method No water would come out of the pump. No sam()le could be obtained. CCWCHANNEL Extractable Petroleum Date/Time Collected Hydrocarbons Analysis Date/Time Analyst Method 09/08/09 @ 1305 <0.10 mg/1 09/11/09@ 0014 CLS EPH
PERMITIEE NAME/ADDRESS (Include Facility Name/Location if Different) NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPOES) MAJOR Form Approved. Name Address PO BOX2000
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' Timothy P. Cleary Iproperly gather and evaluate the information subm1tted. Based op my 1nqwry of the person or i : 1 , I !persons who manage the system. or those persons d;rectly responsible for gathenng the : Sequoya Site VIce esident i I I1 1 . . . ilnformation,thelnforma!lonsubmlttedls,tothebestofmyknowledgeandbeltef,true. i------ _________ - - - - - - - <1 423 843-7001 ! 09 , 10 07 r,'____________________________
1 Sequoyah S1te V1ce President 'accurate. and complete 1am aware that there are s1gntftcant penalties for submtttlng false ' SIGNATURE OF PRINCIPAL EXECUTIVE I i ] ! ;1 i __J,ntormatton, 'nclud1ng the poss1btilty of ftne and tmpnsonment for knowtng vtolat1ons i OFFICER OR AUTHORIZED AGENT ~-AREAT-NiJMs_E_R_lYEA-RT MO --T'DAY1 ___ ---~~~D _PRINT~--_OR _ __ -~- __ __ ___ ______ _ ______ ____ __ __ ____ __ __________ ... .L --------*--*~----------- ____________ ~()QE__i ___________ L __ ___j_ ____ l____ j COMMENTS AND EXPLANATION OF ANY VIOLATIONS (Reference all attachments here) The following injections occured: 1. MSW 101 (max calc. cone_ was 0.033mg/L--Iimit 0.2mg/L) 2. Floguard MS6236 (max. calc. cone. was 0.034mg/L--Iimit 0.2mg/L) 3. H-150M (max. calc. cone. was 0.04mg/L--Iimit 0.050mg/L) 4. H-150M (low detection level analytical method was <0.050mg/L--Iimit 0.050mg/L) EPA Form 3320-1 (REV 3/99) Previous editions may be used Page 2 of 2
PERMIITEE NAME/ADDRESS (Include Facility Name/Location if Different) NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPOESJ MAJOR Form Approved. Name_~VA-SEQUOYA~UCLEARPLANT _ _ _ _ DISCHARGE MONITORING REPORT (DMRJ Addres_L ..£'..~BOX..1.QOO ___________ _ (SUBR 01) OMB No. 2040-0004
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f..'I NAME/TITLE PRINCIPAL 1 EXECUTIVE OFFICER *~. I Certrfy under pe. ~arty of. law that.this document and all attachments. w_ere prep. ared. under my
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COMMENTS AND EXPLANATION OF ANY VIOLATIONS (Reference all attachments here) Boron was sampled on July 1, 2009. EPA Form 3320-1 (REV 3/99) Previous editions may be used Page 1 of 1
PERMITTEE NAME/ADDRESS (Include Facility Name/Location if Different) NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPDES) MAJOR Form Approved Na~-~A-SEQUOYA~UCLEARPLANT _ _ _ _ DISCHARGE MONITORING REPORT !DMR! OMB No. 2040-0004 (SUBR 01) Addres_L _E.Q,_BOX.£900 _ _ _ _ _ _ _ _ _ _ _ _
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EPA Form 3320-1 (REV 3/99) Previous editions may be used Page 1 of 1
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PERMITTEE NAME/ADDRESS (Include FacilitY Name/Location if Different) NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPOES) Form Approved. MAJOR Na~-~A-SEQUOYA~UCLEARPLANT _ _ _ _ DISCHARGE MONITORING REPORT (OMRJ OMB No. 2040-0004 (SUBR 01) Add res.§_ _E.~BOX 2000 _ _ _ _ _ _ _ _ _ _ _ _ ~--~TEROFFICESB-2A-SQ~-------- TN0026450 ! 110 T . F- FINAL _ _ _ 20DDY-DAISY~~738L _ _ _ _ _ _ _ _ _F>_~R~li_flll,JMB~FL_ __ ~J§_G_8f>.fi"(3~~Nu]I@*~~J RECYCLED COOLING WATER Facility_ JYA- SEQUOYAH NUCLEAR PLANT_ _ _ _ _ _ G~AiJ--~~~~i~~RlNG_f{~f;TT~~i2 EFFLUENT Locati~~MILTO~OUN~----------
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PERMITIEE NAME/ADDRESS (Include Facility Name/Location It Different) NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPOES) MAJOR Form Approved Name_~A-SEQUOYA~UCLEARPLANT _ _ _ _ DISCHARGE MONITORING REPORT (OMR) AddresL _E.~BOX.1.QOO _ _ _ _ _ _ _ _ _ _ _ _ (SUBR 01) OMB No. 2040-0004
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PERMITIEE NAME/ADDRESS (Include Faciiltv Name/Location if Different) NATt~)NAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPOES) MAJOR Form Approved. Na~-~A-SEQUOYA~UCLEA~LANT _ _ _ _ DISCHARGE MONITORING REPORT (DMR) Addres_L __f.~BOX_1900 _ _ _ _ _ _ _ _ _ _ _ _ (SUBR 01) OMB No. 2040-0004
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PERMITIEE NAME/ADDRESS (Include Facility Name/Location if Different) NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPOES) MAJOR Form Approved. Na~_~A-SEQUO~~UCLEARPLANT _ _ _ _ DISCHARGE MONITORING REPORT (OMRJ (SUBR 01) OMB No. 2040-0004 Addres.§_....!: ~BOX 2000 _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ .J!NTEROFFICE SB-2A-SQfil_ _ _ ' - _ _ _ _ _ TN0026450 1 F- FINAL o.,--*-=-===~-"'="-"'"*"-"o*-=~""-- .-o..=---oo-=-.**==- ~==--.. L_---=------,_.,-,.,.~--*===~=="'-"-*~-- ~---="~-- =;j _ _ _ 20DDY-DAISY~~738L _ _ _ _ _ _ ~~ *
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8 S58{)91'119 800- NPDES CORRESPONDENCE November 9, 2009 State of Tennessee Department of Environment and Conservation Division of Water Pollution Control Enforcement & Compliance Section 61h Floor, L & C Annex 401 Church Street Nashville, Tennessee 37243-1534
Dear Mr. Patrick Cromer:
SEQUOYAH NUCLEAR PLANT- DISCHARGE MONITORING REPORT FOR OCTOBER 2009 Enclosed is the October 2009 Discharge Monitoring Report for Sequoyah Nuclear Plant. If you have any questions or need additional information, please contact Ann Hurt at (423) 843-6714 or Stephanie Howard at (423) 843-6700 of Sequoyah's Environmental staff. Sincerely, "~f~ Timothy P~]leary Site Vice President Sequoyah Nuclear Plant AH Enclosure cc (Enclosure): Chattanooga Environmental Field Office Division of Water Pollution Control State Office Building, Suite 550 540 McCallie Avenue Chattanooga, Tennessee 37402-2013 U.S. Nuclear Regulatory Commission ATTN: Document Control Desk Washington, D.C. 20555 cc: C. R. Church, POB 2B-SQN D. E. Pittman, LP 5E-C T. P. Cleary, OPS 4A-SQN A. A. Ray, WT 11 A-K S. A. Howard, SB 2A-SQN G. R. Signer, WT 6A-K P. R. Lapointe, WT 11 B-K B. A. Wetzel, OPS 4A-SQN W. A. Nurnberger Ill, POB 2A-SQN EDMS, WT CA-K DMR0910.doc
REVIEW/CONCURRENCE SHEET DOCUMENT NAME: SEQUOYAH NUCLEAR PLANT- DMR OCTOBER 2009 ORGANIZATION: Environmental DOCUMENT PREPARED BY: Ann Hurt DATE: 11/06/2009 CONCURRENCES Name R c Signature - Comment Date v N Ann Hurt X Stephanie A Howard X W. A. Nurnberger X Beth A. Wetzel X Chris R Church X INSTRUCTIONS: Originator will determine the review/concurrence assignment. REVIEW: Examine technical content and commitments made. A review (RV) should confirm the truth and accuracy of factual statements and indicate agreement with commitments made which are applicable to the reviewer's organization. CONCURRENCE: Indication of agreement with the document as a whole. Concurrence (CN) signifies that the document is responsive to the intended purpose, logical in construction, and clear in meaning in the eyes of the recipient. A concurrence signature indicates that the individual would be willing to sign the document for the agency.
Tennessee Valley Authority Post Office Box 2000 Soddy Daisy, Tennessee 37384-2000 Timothy P. Cleary Site Vice President Sequoyah Nuclear Plant November 9, 2009 State of Tennessee Department of Environment and Conservation Division of Water Pollution Control Enforcement & Compliance Section 61h Floor, L & C Annex 401 Church Street Nashville, Tennessee 37243-1534
Dear Mr. Patrick Cromer:
SEQUOYAH NUCLEAR PLANT- DISCHARGE MONITORING REPORT FOR OCTOBER 2009 Enclosed is the October 2009 Discharge Monitoring Report for Sequoyah Nuclear Plant. If you have any questions or need additional information, please contact Ann Hurt at (423) 843-6714 or Stephanie Howard at (423) 843-6700 of Sequoyah's Environmental staff. Sincerely,
- "j:!v Site Vice President Sequoyah Nuclear Plant Enclosure cc (Enclosure):
Chattanooga Environmental Field Office Division of Water Pollution Control State Office Building, Suite 550 540 McCallie Avenue Chattanooga, Tennessee 37402-2013 U.S. Nuclear Regulatory Commission ATTN: Document Control Desk Washington, D.C. 20555 printed on recycled paper
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I Cert1fy under penalty of law that.this docu. ment an.d all attachments were p. repared under my
*---*- ----------- 'd1rect!on or supervtston tn accordance w1th a system destgned to assure that qualtfted personnel ,i....h .~ . .~
o*~~ .Cl].U-~ j/_ "' J TELEPHONE DATE Timothy P. Cleary properly gather and evaluate the 1nformat1on submitted. Based on my mqu~ry of the person or i *\)w persons who manage the system,or those persons d~rectly responsible for gathenng the Environmental Manager SQN & WBN Information, the 1nformat1on subm1tted is, to the best of my knowledge and bel1ef, true, ______ ___ -----------** 423 843-7001 09 11 12 Sequoyah Site Vice President accurate, and complete. I am aware that there are signtficant penalttes for submitting false
.* 1nformat1on, 1ncluding the possibility of fine and 1mpnsonment for knowing violations.
TYPED OR PRINTED COMMENTS AND EXPLANATION OF ANY VIOLATIONS (Reference all attachments here) No closed mode operation. The following information is included in an attachment: CCW data EPA Form 3320-1 (REV 3/99) Previous editions may be used Page 1 of 2
DMR Attachment CCW Data CCWTRENCH Extractable Petroleum Date/Time Collected Hydrocarbons Analysis Date/Time Analyst Method No water would come out of the pump. No sample could be obtained. CCWCHANNEL Extractable Petroleum Date/Time Collected Hydrocarbons Analysis Date/Time Analyst Method 10/14/2009@ 1051 <0.10 mg/1 10/16/2009 @ 1130 JOB EPH
NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPDES) Form Approved PERMITTEE NAME/ADDRESS (Include Facility Name/Location if Different) MAJOR Name_~A-SEQUOYA~UCLEA~LANT _ _ _ _ DISCHARGE MONITORING REPORT (OMR) OMB No. 2040-0004 (SUBR 01) Addres_L _E ~BOX_1900 _ _ _ _ _ _ _ _ _ _ _ _ TN0026450 101 G F- FINAL ---~TEROFFICESB-2A-SQ~-------- ---~ODDY-DAISYJ~738L _______ _ J'E:BMJT Nl)MBER _ DISCH,A.RG_E_ NUI\nBE:R _ DIFFUSER DISCHARGE Facility_ _2_VA- SEQUOYAH NUCLEAR PLANT_ _ _ _ _ _ Locatio.Q__ J::!AMIL TOJi.COUNTL _ _ _ _ _ _ _ _ _ _ MQNIJORING. P.FRIQD . EFFLUENT __YEAR ...* 1\AO_. Dfi_Y__ J YEAR M9 __.Q~Y
*** NO DISCHARGE ATTN: Stephanie A. Howard From 09 10 01 To 09 10 31 NOTE: Read instructions before completinq this form.
PARAMETER QUANTITY OR LOADING QUALITY OR CONCENTRATION ------- - . - NO. FREQUENCY SAMPLE EX OF TYPE AVERAGE MAXIMUM UNITS MINIMUM AVERAGE MAXIMUM UNITS ANALYSIS CHLORINE, TOTAL RESIDUAL ******** ******** ******** 0.016 0 25/31 GRAB
-~
50060 ******** MG/L
---**-'--** ---*--*-..**-* 111'1V ,., 11'""' 11-" 1 IWI'""' *- --*--*~---.-!?~_xs 0 ******** ********
0 31 I 31 CALCTD 62 82234 0 0 PERMIT 2 DEG REQUIREMENT C/HR EFFLUENT GROSS VALUE _DAU..Y.MX NAME/TITLE PRINCIPAL EXECUTIVE OFFICER *I Certify under penalty of law that thiS document and all attachments were p. repared under my
- drrectron or supervisron rn accordance wrth a system designed to assure that qualrfred personnel J~
1.Q.....p~ J I 0n' ~tzX.L...-t d.- TELEPHONE DATE Timothy P. Cleary properly gather and evaluate the 1nformat1on submitted. Based on my 1nqU1ry of the person or ,*
- persons who manage the system,or those persons directly responsible for gathering the Environmental Manager SQN & WBN rnformatron, the rnformatron submrtted 1s , to the best of my knowledge and bel1ef, true, ---. --- ------- - --**
423 843-7001 09 11 12 Sequoyah Site Vice President ,accurate, and complete. 1 am aware that there are sign1f1cant penalt1es for subm1tting false SIGNATURE OF PRINCIPAL EXECUTIVE _*Information, including the possJbiiJty of fine and '1mpnsonment for knowmg v1olat1ons OFFICER OR AUTHORIZED AGENT AREA NUMBER -ivEAR .. Mo DAY r TYPED OR PRINTED CODE COMMENTS AND EXPLANATION OF ANY VIOLATIONS (Referen~~-;,/ ~ttachments he~e) The following injections occured: 1. MSW 101 (max. calc. cone. was 0.038mg/L--Iimit 0.2mg/L) 2. Floguard MS6236 (max. calc. cone. was 0.038mg/L--Iimit 0.2mg/L) 3. Spectrus CT1300 (max. calc. cone. was 0.047mg/L--Iimit 0.050mg/L) 4. Spectrus CT1300 (low detection level analytical method was <0.050mg/L--Iimit 0.050mg/L) EPA Form 3320-1 (REV 3/99) Previous editions may be used Page 2 of 2
PERMITIEE NAME/ADDRESS (Include Facility Name/Location if Different) NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPDES) Form Approved. MAJOR Na~-~A-SEQUOYA~UCLEA~LANT _ _ _ _ DISCHARGE MONITORING REPORT (DMR) OMB No. 2040-0004 (SUBR 01) Addres.2.._ __E.~BOX..1.QOO _ _ _ _ _ _ _ _ _ _ _ _
---~TEROFFICESB-2A-SQ~-------- F- FINAL ---~ODDY-DAISY~~738L _ _ _ _ _ _ _ _
f>E:RMITNL)_r\}IElER DJSQ_I:Jt.RG_E_NUivlBER _ BIOMONITORING FOR OUTFALL 101 Facility_ _])/A- SEQUOYAH NUCLEAR PLANT_ _ _ _ _ _ Locatio..!l.._ _jjAMIL TOJi.COUNT::(_ _ _ _ _ _ _ _ _ _ _ EFFLUENT lv1Qf':JJIQBING E'I:1~10IL... ~~~-~~-~~-- -
'!'EAFL.MO____ Di\Y '_x~_B _l'y'1Q~"--PAY_
NO DISCHARGE ATTN: Stephanie A Howard From 09 10 01 To 09 10 31 NOTE Read instructions before completinq this form PARAMETER QUANTITY OR LOADING QUALITY OR CONCENTRATION NO. . FREQUENCY SAMPLE EX OF TYPE ANALYSIS UNITS IC25 STATRE 7DAY CHR ******** ******** ** Monitoring ******** SAMPLE ******** 23 CERIODAPHNIA MEASUREMENT Not Re uired . c -----------**-- ------ --*- ------** ----- ------- .. ________g________,___ ------- _____________ , _____ ---- .- ------ - --- --- - --- --- .------------------------.
- TRP38 1 0 0 PERMIT . . ******** **** **45.2 ' . ******** . ******** PERCENT . I SEE f COMPOS:
EFFLUENT GROSS VALUE R_E~~~~~~~-- MINIMUM _j~~~~I__i___ IC25 STATRE 7DAY CHR sAMPLE ******** ******** ** Monitoring ******** ******** 23 PIMEPHALES MEASUREMENT Not Re uired j TRP6C 1 0 0
,,-----~-~--- ---**----*- -T ------;~**-**** --~-- ---- ....9..,.. -- ------r-------------------- --~- -- . i,. . ---------- --fi COMPOS 45.2* - if ******** ******** PERCENT SEE EFFLUENT GROSS VALUE . MIMINUM--~1-- ' _ __ ____ ___ __i_f"E_I3_r.Jl_l"[j _
I---------------- i
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REQUIREMENT I SAMPLE MEASUREMENT
---------~- =~--~I---- ---- ~-F,ER_MIT_ -~----t-_~-------------------- - - -:_* -:-----
1 REQUtREfv1ENT ____ j-1~-------- *-*** ."_-_____ *' 1
. SAMPLE ' MEASUREMENT ~----; PEHMlr---*--r*--c--- --_ -_--.--r ---- -------
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_-_-! . -. ___ -----_*-.r*.
- - - -__._-- ------------~---"i ------------~-L~~Qu~~~Nrj_~~-----~ -~--- -* l__ _
NAME/TITLE PRINCIPAL EXECUTIVE OFFICER I Cert1fy under penalty of law that this docu. ment and all attachments were prepared under my dtrectton or SUperVISIOn in accordance with a syste~ destgned to assure that qua!tfted personnel :
')twtru'. 'l)....Q_ , ~ . . 0\ 4.f{..{) d J\. - C~ --~**----
TELEPHONE
-**-*-* -~*---
DATE Timothy P. Cleary properly gather and evaluate the mformat1on submitted. Based on my 1nqU1ry of the person or persons who manage the system, or those persons dlfectly responsible for gathenng the Environmental Manager SQN & WBN
. . . tnformatton, the Information submttted ts , to the best of my knowledge and belief, true, 423 843-7001 09 11 12 Sequoyah Site V1ce President accurate, and complete. 1am aware that there are s1gnif1cant penalties for submitting false SIGNATURE OF PRINCIPAL EXECUTIVE Information, including the possib1i1ty of fine and impnsonment for know1ng violations. OFFICER OR AUTHORIZED AGENT AREA r~
TYPED OR PRINTED NUMBER YEAR. MO DAY CODE COMMENTS AND EXPLANATION OF ANY VIOLATIONS (Reference all attachments here) Toxicity was not sampled in October 2009. EPA Form 3320-1 (REV 3/99) Previous editions may be used Page 1 of
PERMITTEE NAME/ADDRESS (Include Facilitv Name/Location if Different) NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPOES) Form Approved. MAJOR Na~-~A-SEQUOYA~UCLEA~LANT _ _ _ _ DISCHARGE MONITORING REPORT (OMR) OMB No. 2040-0004 (SUBR 01) Addres_L ...J:.~BOX_1900 ___________ _ TN0026450 103 G F- FINAL ---~TEROFFICESB-~-SQ~-------- _ _ _ 20DDY-DAISY2~738L _ _ _ _ _ _ _ _ ~E_13MII t-,JUME3ER LOW VOL. WASTE TREATMENT POND Facility_ ~A ._gQUOYAH NUCLEAR PLANT_ _ _ _ _ _ Locatio!]_ _!jAMIL TOl:!._COUNTY._ _ _ _ _ _ _ _ _ _ _ MONITQRINGPEBlQO EFFLUENT
~
YE;t\13. MO DAY c "YEAB .MQ.~**- QAY_ *** NO DISCHARGE ATTN Stephanie A Howard From 09 10 01 To 09 10 31 NOTE: Read instructions before completinq this form PARAMETER QUANTITY OR LOADING QUALITY OR CONCENTRATION NO. FREQUENCY SAMPLE EX OF TYPE
-~-
ANALYSIS MAXIMUM UNITS
*--~~l PH ******** ******** 6.8 ******** 7.6 GRAB 12 00400 0 0 ******** ~-~-------- **.;*****- ** _.* s.o*_----~ ~ ********
- 9.o su MINIMUM MAXIMUM SOUDS,TOTALSUSPENDED SAMPLE -t 73 86 26 ******** 8 9 0 4 I 31 GRAB MEASUREMENT 19 00530 0 0 1250 LBS/DY r - *;;;;;;.-:,;.;* 100 MG/L EFFLUENT GROSS VALUE
~-*--- -----------
OAIJ,Y NIX . _l O.t\1!,Y MX _ OIL AND GREASE SAMPLE <54 <59 ******** <6 <6
, MEASUREMENT 26 19 -~-~-~~~~~]~~;~~~~~~] ~~~~/DY 00556 1 0 0 15 20 MG/L EFFLUENT GROSS VALUE ----*" ~.:. MP AY~L~ -~~All.Y MX__ , **-
FLOW, IN CONDUIT OR THRU SAMPLE 1.015 1.343 ******** ******** ******** TOTALZ
- MEASUREMENT 03 TREATMENT PLANT
-~~t~~~~=~~.-.~ ~~~::~-~ d:!t$~~ _l___M_G_D~_[____~~~-~--L-~----'--~-----__;_-
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[NAME/TITLE PRINCIPAL EXECUTIVE OFFICER 1 1 Certify under penalty of law that th1s document and all attachments were prepared under my TELEPHONE DATE
---- - -*- * * ---- - --- -------'direction or superv1s1on 1n accordance w1th a system des1gned to assure that qual1f1ed personnel Timothy P. Cleary _properly gather and evaluate the mformation submitted Based on my 1nquiry of the person or persons who manage the system, or those persons d1rectly respons1ble for gathenng the Environmental ManagerSQN & WBN 11 12 ,informat1on, the Information submitted is , to the best of my knowledge and belief, true, --- "--
423 843-7001 09 Sequoyah Site Vice President accurate, and complete I am aware that there are significant penalt1es for subm1tting false SIGNATURE OF PRINCIPAL EXECUTIVE
.Information. including the possib1hty of fine and 1mpnsonment for know1ng violations. OFFICER OR AUTHORIZED AGENT AREA NUMBER ,-YEAR MO DAY
- i. T~PED_ OR -PRINTED _____ _ CODE COMMENTS AND EXPLANATION OF ANY VIOLATIONS (Reference all attachments here)
EPA Form 3320-1 (REV 3199) Previous editions may be used Page 1 of
PERMITIEE NAME/ADDRESS (Include Facility Name/Location if Different) NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPOES) MAJOR Form Approved. Na~_~A-SEQUOYA~UCLEA~LANT _ _ _ _ DISCHARGE MONITORING REPORT (OMR) (SUBR 01) OMB No. 2040-0004 Addres_L __I'?. ~B0><.1.QOO _ _ _ _ _ _ _ _ _ _ _ _ TN0026450 F- FINAL ---~TEROFFICESB-2A-SQ~-------- - .*--- -=* ~-~~~ *-~ . --
---~ODDY-DAISY~~738L _ _ _ _ _ _ _ _ . _l'_EBM_IT_f\ll)M§_E:_R_ i_[)lSC::H6R_GE:_ f\IUfliiB_E_B METAL CLEANING WASTE POND Facility_ JYA -..§!:QUOYAH NUCLEAR PLANT_ _ _ _ _ _
LocatiO..!}_ .J:!AMILTOJ:LCOUNTY._ _ _ _ _ _ _ _ _ _ _ .MON_LmRING f'E:_RI_OD EFFLUENT
.'I'EAJ3__ . f'..'lO ~QA'( _ '(E;AR __ MQ. [)~L.
NO DISCHARGE XX ATIN: Stephanie A. Howard From 09 10 01 To 09 10 31 NOTE Read instructions before completinq this form PARAMETER QUALITY OR CONCENTRATION NO . . FREQUENCY SAMPLE EX OF TYPE ANALYSIS AVERAGE UNITS PH SAMPLE ******** ******** MEASUREMENT 12 00400 1 EFFLUENT GROSS VALUE 0 0
--~~-~J~~~~0~:-~#mm _ ]_ _ ";;****** -~
MAXIMUM 9.0 su GRAB SOUDS,TOTALSUSPENDED SAMPLE ******** ******** ******** ******** 19 MEASUREMENT 00530 0 0 PERMIT 1 REQUIREM~NT MG/L -oATl..v--TcoMPos' EFFLUENT GROSS VALUE OIL AND GREASE SAMPLE I MEASUREMENT 19 00556 0 0 15 MG/l EFFLUENT GROSS VALUE ___________[;)AibXJtlt.>t _ ,___ _ 'F>i=tospj:.loR:Lis~rorAL (AS P) 19 00665 1 0 0 ******** ******** 1.0 MG/L DAILY i COMPOS .EFFLUENT GROSS VALUE DAILYMX : -
-'.----~~----------~ ---- '
I 01042 1 0 0 --------~-..~ PERMIT* t"* *.*"_~_- ___..-.c-_ _-_---.-_-~
******** __-- _------_---_r. ******** i ******** 1.0 REQUIREMENT : * ***. . * * *...
'EFFLUENT GROSS VALUE :.. ,,*. ___ ! DAILY MX 'IRON, TOTAL (AS FE) SAMPLE ******** ******** ******** 19
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MEASUREMENT 1
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- 01045 1 0 0 ----****;-;;;*~--"---;~~~~~~-~--~:__ -l-oA'it:v~-:cor.iF>os1 EFFLUENT GROSS VALUE
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J *.. FLOW, IN CONDUIT OR THRU SAMPLE ******** ******** ******** TREATMENT PLANT : MEASUREMENT 03
*~-r ot..li:v-rcAt:c:r-o *
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__ _c_J_ __________ ,__: [ NAME/TITLE PRINCIPAL EXECUTIVE OFFICER i.l Certify under penalty of law that.this document and all attachment;;ere prepared under my
- ---- **- ~ - ~- --*-- --------- ----- ------------ ** * -~---- * ----*- dtrectton or superv1ston tn accordance wtth a system destgned to assure that qual1f1ed personnel A ;. l J-r; (\~t..l'Ltt)._..Q_
Q /{ TELEPHONE j Timothy P. Cleary ,properly gather and evaluate the tnformation submttted. Based on my tnquiry of the person or * \.X.>fJ' '
* *persons who manage the system.or those persons dtrectly responstble for gathenng the
- Environmental Manager SON & WBN
. . . ;tnformation, the tnformatton submttted ts, to the best of my knowledge and belief. true, _______________ ... *--** ____ _ ____ _ 423 843-7001 09 11 12 i Sequoyah S1te V1ce President *accurate. and complete. 1am aware that there are stgnificant penalties for submttting false
_________________ jmformat1on, tncludtng th: possibiltty of fine and imprisonment for knowing violattons. AREA NUMBER 1 YEAR - MO DAY 1 TYPED OR PRINTED ' CODE . COMMENTS AND EXPLANATION OF ANY VIOLATIONS (Reference all attachments here) No Discharge this Period EPA Form 3320-1 (REV 3/99) Previous editions may be used Page 1 of
PERMITIEE NAME/ADDRESS (Include Facility Name/Location if Different) NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPOES) MAJOR Form Approved. Name_~A-SEQUOYA~UCLEA~LANT _ _ _ _ DISCHARGE MONITORING REPORT (OMRJ OMB No 2040-0004 (SUBR 01) Addres_L .£ ~BOX_1900 ___________ _ ---~TEROFFICESB-2A-SQ~-------- TN0026450 11 0 G F - FINAL ---~OD~DAISY~~73BL _______ _ PERMIT NUMBER DI~C::_HARGE_I'J_UMBER RECYCLED COOLING WATER Facility_ _s:.JA- SEQUOYAH NUCLEAR PLANT_ _ _ _ _ _ LocatiO.!l._ __!:jAMIL TO.!i_COUNT:L_ _ _ _ _ _ _ _ _ _ _ . MONITORING. PERJQQ EFFLUENT _ YEA13 MQ DAY __YEAR MO_: _.DAY
. XX ATTN: Stephanie A. Howard From 09 10 01 To- OS - 10 J1 NO DISCHARGE NOTE. Read instructions before completinq this form.
PARAMETER QUANTITY OR LOADING QUALITY OR CONCENTRATION NO. FREQUENCY SAMPLE EX OF TYPE ANALYSIS : MAXIMUM UNITS MINIMUM AVERAGE MAXIMUM UNITS TEMPERATURE, WATER DEG. CENTIGRADE
******** ~~ ******** ******** 04 00010 z INSTREAM MONITORING 0 0 - --- ~~~~~~~~~~-T~-: - *~****** 1- ******** DEG c I ******** - -; -~*****;; --~-DA~~y3MX DAILY GRAB"4 - __ j PH SAMPLE ******** ******** ********
MEASUREMENT 12 00400 0 0 ******** 6.0 ******** 9.0 su I EFFLUENT GROSS VALUE
--~- . --~* - I .. MJNIMUIVI I\/IAXIMI.J!\11 SOLIDS, TOTAL SUSPENDED ******** ******** 19 - ----.,-~----- .. ~ ---~ -- *---------------~- .1 00530 1 0 0 30 MG/L DAILY -,-COMPOS EFFLUENT GROSS VALUE DAILY MX OIL AND GREASE ******** ******** ********
19 00556 1 EFFLUENT GROSS VALUE 0 0 PERMIT REQUIREMENT
********** [-- ******** *'!'&****** ******** 15 DAILY MX
'FLOW, IN CONDUIT OR THRU SAMPLE ******** ******** ******** MEASUREMENT ; 03 TREATMENT PLANT 50050 1 0 0 ~-o.AII..Y~; CALCTD REPORT* EFFLUENT GROSS VALUE MOAVG i . i
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CHLORINE, TOTAL RESIDUAL SAMPLE ******** ******** ******** MEASUREMENT 19
---------------~--+-*--*--**--*-----_*****--~----*_**-_-****' .. -** -----~-
50060 1 0 0 PERMIT ' ******** * ******** ******** MG/L -*: WEEKLv[-GR.As-4 REQUIREMENT i EFFLUENT GROSS VALUE
.- -- --"-L.___. - - -
SAMPLE MEASUREMENT
- ~wULOdtuud NAME/TITLE PRINCIPAL EXECUTIVE OFFICER *I Certify under penalty of law that th1s document and all attachments were prepared under my TELEPHONE DATE
---~direction or superv1s1on in accordance w1th a system designed to assure that qualified personnel Timothy P. Cleary properly gather and evaluate the Information subm1tted Based on my 1nqUify of the person or persons who manage the system, or those persons directly responsible for gathering the Environmental Manager SQN & WBN . . . 1nformat1on, the information submitted 1s . to the best of my knowledge and belief. true, --- --- ----------- --- -
423 843-7001 09 11 12 Sequoyah S1te Vice Prestdent accurate, and complete I am aware that there are s>gnlficant penalties for subm1tt1ng false SIGNATURE OF PRINCIPAL EXECUTIVE 1nformat1on including the poss1biiJty of fine and 1mpnsonment for know1ng VIolations OFFICER OR AUTHORIZED AGENT AREA NUMBER . TYEAR MO DAY TYPED OR PRINTED CODE COMMENTS AND EXPLANATION OF ANY VIOLATIONS (Reference all attachments here) No Discharge this Period EPA Form 3320-1 (REV 3/99) Previous editions may be used Page 1 of 1
PERMITIEE NAME/ADDRESS (Include Facility Name/Location if Different) NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPOES) MAJOR Form Approved. Na~-~A-SEQUOYA~UCLEA~LANT _ _ _ _ DISCHARGE MONITORING REPORT !DMR) OMB No. 2040-0004 (SUBR 01) Addres.§_ ___£: ~BOX_1900 _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ ffiTEROFFICESB-2A-SQ~-------- TN0026450 110 T F- FINAL ---~OD~DAISY~~738L _______ _ RECYCLED COOLING WATER _ J='£8MIJNLJI\/1~_E_FL . QL!?G_HARQI::_i'J.!JM~ER Facility_ ...J.YA- SEQUOYAH NUCLEAR PLANT_ _ _ _ _ _ Locatio..Q_ JjAMIL TOl::!._COUNTY __________ _ EFFLUENT NO DISCHARGE -xx' ATTN: Stephanie A. Howard From NOTE Read instructions before completinq this form. PARAMETER QUALITY OR CONCENTRATION -------- NO. 'i=REQUENCYT SAMPLE OF , TYPE ANALYSIS MAXIMUM AVERAGE IC25 STATRE 7DAY CHR ******** ******** CERIODAPHNIA ~~~~§N~ (3~~~~~VA_L_U~-------~-~~~~~~~~~~~~~--- ******** --r ;;;;;-*-;;-----~ **** -- --- -***;;;;*;----- PERCENT ---~~ A~~~~~TCOMPOS IC25 ST ATRE 7DAY CHR SAMPLE ******** ****www.,.. PIMEPHALES MEASUREMENT 23 TRP6C 0 EFFLUENT GROSS VALUE 0 SAMPLE r ******** l MEASUREMENT
,-**--*-*-----~-. --*-*--*~-:--- --~ -- --~-- - - --------------------*-***----1 PERMIT 1 .i I REQUIREMENT ! !
__________L_c; _______ -'-~------L-- ________ ------------'-----L-- sAMPLE MEASUREMENT 1
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SAMPLE MEAS~R~~EN~~----- _ ---- _ ____: _ PERMIT i . . . -* REQUIREMENT : 1 c_-- PE-RMil'-----;*------ -------:-1*--- ---------------*-------- *1 i REQUIREMENT i . . i
---~--- __ .:.,;___ ~,~ _L_ __ ________ I 'I Cert1fy under penalty of law that this document and all attachments were prepared under my TELEPHONE DATE Timothy P. Cleary -*_,direction or supervision in accordance with a system designed to assure that qualified personnel *properly gather and evaluate the information submitted. Based on my mquiry of the person or ipersons who manage the system, or those persons directly responsible for gathering the ~trtO~
Environmental Manager SON & WBN 09 11 Sequoyah Site Vice President Information, the information submitted is, to the best of my knowledge and bel1ef, true, *--- ------- - --- - - --- -------- -- ---------- 12
!accurate. and complete I am aware that there are significant penalt1es for submitting false SIGNATURE OF PRINCIPAL EXECUTIVE 1- *Information including the possibility of fine and 1mpnsonment for knowing violations OFFICER OR AUTHORIZED AGENT NuMsE_R __ 1vE'.A.R-- rvio DAY TYPED OR PRINTED ~- --- - --- . "*-*- --- ---
COMMENTS AND EXPLANATION OF ANY VIOLATIONS (Reference all attachments here) No Discharge this Period EPA Form 3320-1 (REV 3/99) Previous editions may be used Page 1 of 1
PERMITIEE NAME/ADDRESS (Include Facility Name/Location if Different) NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPDES) Form Approved. MAJOR Na~_~A-SEQUOYA~UCLEA~LANT _ _ _ _ DISCHARGE MONITORING REPORT (DMRJ OMB No. 2040-0004 (SUBR 01) Addres_L .£ ~BOX...£900 _ _ _ _ _ _ _ _ _ _ _ _ TN0026450 116 G F- FINAL ---~TEROFFICESB-2A-SQ~-------- _ _ _ 20DDY-DAISY~~73BL _ _ _ _ _ _ _ _ _.PI::RMITJ-Il)M_B_E 8 BACKWASH llCilitv_ ...JYA -..§!:QUOYAH NUCLEAR PLANT_ _ _ _ _ _ Locatio..!l.._ _!:!AMIL TOJi.COUNTY __________ _ MOI'jU9RJNG_ PE;RI()Q EFFLUENT
. 'r'EAR , MO. . _DAY: j!':Af~. _. _ MO 0./'IY NO DISCHARGE ATIN: Stephanie A. Howard From o9 10 01 To* 09 10 31 NOTE Read instructions before comoletino this form PARAMETER QUANTITY OR LOADING QUALITY OR CONCENTRATION NO. FREQUENCY SAMPLE EX OF . TYPE ANALYSIS AVERAGE DEBRIS, FLOATING (SEVERITY) SAMPLE -******** ******** ******** 1 I 31 VISUAL MEASUREMENT 0 9A 0
____;_*~_~_-*_*_*_*_-_--_-_-jL--~*_*_*_*_*_*_*_*__L__**_*_*-~--**_*_*_*_*_*_*_~-~-**_*_*_*_*_**__~~ftn~R~()=-E~~~~l ~~~~:f 01345 0 0 EFFLUENT GROSS VALUE
---*-~*-------~- -*----- -----
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PERMIT -"-- ' REQUIREMENT PERMiT --------*** --******--*--*-***-******--, REQUIREMENT SAMPLE MEASUREMENT ~AMEITIT~E_PR_I~CIPAL EXECUTIVE OFFICER
-~~o~~td I Certrfy under penalty of law that this document and all attachments were prepared under my TELEPHONE DATE --- --- --- *--- * -------- -:dtrectton or supervtston tn accordance wtth a system destgned to assure that qual1f1ed personnel Timothy P. Cleary 'properly gather and evaluate the rnformation submitted. Based on my rnquiry of the person or
- persons who manage the system, or those persons directly responsible for gathenng the Environmental Manager SQN & WBN rnformatron, the information submitted is , to the best of my knowledge and belief. true. ---- --- 423 843-7001 09 11 12 Sequoyah Site Vice President 'accurate, and complete. I am aware that there are signtf1cant penalties for submitt1ng false SIGNATURE OF PRINCIPAL EXECUTIVE r* -*"-*--
r* TYPED OR PRINTED _:information. includrng the possrbrlity of fine and imprisonment for knowrng violations OFFICER OR AUTHORIZED AGENT AREA CODE NUMBER YEAR* MO DAY COMMENTS AND EXPLANATION OF ANY VIOLATIONS (Reference all attachments here) Operations performs visual inspections for floating debris and oil and grease during all backwashes. EPA Form 3320-1 (REV 3/99) Previous editions may be used Page 1 of 1
PERMITTEE NAME/ADDRESS (Include Facilitv Name/Location if Different) NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPOES) Form Approved. MAJOR Na~-~A-SEQUOYA~UCLEA~LANT _ _ _ _ DISCHARGE MONITORING REPORT (OMR) OMB No. 2040-0004 (SUBR 01) Addres_L___!:~BOX_1900 - - - - - - - - - - - - ---~TEROFFICESB-2A-SQ~-------- - - ----~ ------- 117 G --~-- F- FINAL _ _ _ 20DDY-DAISY~~738L _ _ _ _ _ _ _ _ PERMIT NUMBER
-------------- ----------- ----- -- _I:)L§C:tt_ARQ_~ f'JU_flllBE:R_ BACKWASH Facility_ ~A- SEQUOYAH NUCLEAR PLANT_ _ _ _ _ _
LocatiO..!]_ .J:!AMILTO..!i_COUNTY __________ _ fi!IONITQRING PE;RIQQ- . EFFLUENT Xi;AR .MO [)A~Y _
- YE;AR MO.
ATTN: Stephanie A. Howard From 09 10 01 To - -()g -:~()- - NO DISCHARGE NOTE: Read instructions before completinq this form. PARAMETER QUANTITY OR LOADING QUALITY OR CONCENTRATION NO. FREQUENCY SAMPLE EX OF TYPE ANALYSIS AVERAGE MAXIMUM UNITS DEBRIS, FLOATING (SEVERITY) ******** ******** 0 0 1 I 31 VISUAL 9A 01345 0 0 P~RMIT .... ****-***-- -_--------------,--
******** -- ---~---
REQUIREMENT EFFLUENT GROSS VALUE OIL AND GREASE VISUAL SAMPLE ******** 0 ******** MEASUREMENT 94
-------* _______________...._ _ .. --- ----------- ------1 84066 1 0 0 REPORT i EFFLUENT GROSS VALUE MOOIQIAL_j_
SAMPLE
- MEASUREMENT
- ---~~---- --;:-~-J*-~---.,-*-*---*--*7****-****-*-*--;*-***T****-**------~--
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[ NAME/TITLE PRINCIPAL EXECUTIVE OFFICER *I Cert1fy under penalty of law that this document and all attachments were prepared under my TELEPHONE DATE
* ------ ----~- *-**** ~d1rect1on or superviSIOn tn accordance w1th a system des1gned to assure that qualified personnel Timothy P. Cleary :properly gather and evaluate the Information submitted Based on my inqu:ry of the person or persons who manage the system. or those persons d:rectly responsible for gathering the Environmental Manager SQN & WBN
- Information, the Information submitted is, to the best of my knowledge and belief, true, --*-- -- .. --- -- -* 423 843-7001 09 11 12 Sequoyah Site Vice President accurate, and complete. I am aware that there are s1gn1ficant pena!t1es for submitting false
----- ---~
SIGNATURE OF PRINCIPAL EXECUTIVE
*information, including the possibility of fine and 1mprt"sonment for know1ng violations 1 OFFICER OR AUTHORIZED AGENT ; AREA NUMBER YEARl MO DAY I -- __TYPED §~_~_RINTED CODE COMMENTS AND EXPLANATION OF ANY VIOLATIONS (Reference all attachments here)
Operations performs visual inspections for floating debris and oil and grease during all backwashes. EPA Form 3320-1 (REV 3/99) Previous editions may be used Page 1 of
PERMITTEE NAME/ADDRESS (Include Facilitv Name/Location if Different) NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPOES) MAJOR Form Approved. Name_~A-SEQUOYA~UCLEA~LANT _ _ _ _ DISCHARGE MONITORING REPORT (OMRJ (SUBR 01) OMB No. 2040-0004 Addre~~~Bo~oo _ _ _ _ _ _ _ _ _ _ _ _ ___ ffiTEROFFICESB-2A-SQ~-------- TN0026450 _o-~------- -- -~---
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- __ _20DDY- DAISY,__I.N_2738!__ _ _ _ _ _ _ _ _ & STORM WATER PERMIT _NUME3!=R QI~C::I:lt.R<3~_Nl)I\IIBE:K WASTEWATER Facility_ _IYA- SEQUOYAH NUCLEAR PLANT_ _ _ _ _ _
Locatio.!}_ _jjAMIL TO_tl_COUNTL _ _ _ _ _ _ _ _ _ _ M~QN!!ORJNG. P_ERJQD EFFLUENT YEAR~ ~MQ~-~-_DAY. :YEAR MO DAY To ~o9 ,_1o~* 31. NO DISCHARGE XX ATTN Stephanie A. Howard From 09
- 10 01 NOTE: Read instructions before completino this form PARAMETER QUANTITY OR LOADING QUALITY OR CONCENTRATION NO. -FREQUENCYc SAMPLE EX OF TYPE ANALYSIS AVERAGE MAXIMUM UNITS MINIMUM AVERAGE MAXIMUM UNITS
.OXYGEN, DISSOLVED (DO) SAMPLE ******** ******** ******** ******** MEASUREMENT 00300 1 0 0 PFRMIT
******** ******** 2.0 ******** ********
EFFLUENT GROSS VALUE DAILY MN SOLIDS, TOTAL SUSPENDED SAMPLE ******** ******** 19 00530 1 0 0 I* -- -- - ~ 100 MG/L EFFLUENT GROSS VALUE DAILY MX
-- -*---. ---- -* ~---~-~-~~
SOLIDS, SETTLEABLE SAMPLE ******** ********
' MEASUREMENT 25 00545 1 0 0 MLIL ...... I ONCETTGRAB EFFLUENT GROSS VALUE i
__ L__:MONTH i FLOW, IN CONDUIT OR THRU SAMPLE ******** ******** TREATMENT PLANT MEASUREMENT
~---
.50050 1 0 0 PERMIT REPORT **~***** ******** i ONCE/ ESTIMA
~ REQUIREMENT i EFFLUENT GROSS VALUE MOAVG BATCH PERMIT REQUIREMENT SAMPLE MEASUREMENT PERMIT~-: --------_*]--.--- ----------~
REQUIREMENT
***-*------ --.. - .. --- 1 SAMPLE MEASUREMENT PERMIT REQUIREMENT ~JtwhaJuL QcJbl0Cucl NAME/TITLE PRINCIPAL EXECUTIVE OFFICER :1 Certify under penalty of law that th1s document and all attachments were prepared under my TELEPHONE DATE --*direction or supervision 1n accordance wtth a system designed to assure that qualtfied personnel Timothy P. Cleary ;properly gather and evaluate the mformation submitted Based on my 1nquiry of the person or persons who manage the system, or those persons dtrectly responsible for gathering the Environmental Manager SQN & WBN S . . . ,information, lhe information submitted 1s, to the best of my knowledge and belief. true, -~- -- - 423 843-7001 09 11 12 equoyah S1te Vice PreSident *accurate, and complete 1am aware that there are s1gnificant penalties for submitting false SIGNATURE OF PRINCIPAL EXECUTIVE I ........ "information, Including the possibility of f1ne and 1mpnsonment for knowing violations OFFICER OR AUTHORIZED AGENT AREA TYPED OR PRINTED NUMBER YEAR MO DAY .. -- -- CODE COMMENTS AND EXPLANATION OF ANY VIOLATIONS (Reference all attachments here)
During this reporting period, there has been no flow from the Dredge Pond other than that resulting from rainfall. EPA Form 3320-1 (REV 3/99) Previous editions may be used Page 1 of 1
Page 2 of2 Address Information Ship to: Ship from: Mr. Patrick Cromer Ruth Ann Hurt TDEC- Div. ofWater TVA Pollution 6th Floor, L & C Annex SEQUOYAH NUCLEAR PLANT 401 Church Street Nashville, TN SODDY DAISY, TN 372431534 37379 us us 4238436700 4238436714 Shipping Information Tracking number: 793012384700 Ship date: 11112/2009 Estimated shipping charges: 4.52 Package Information Service type: Priority Overnight Package type: FedEx Envelope Number of packages: 1 Total weight: 1LBS Declared value: O.OOUSD Special Services: Pickup/Drop-off: Use an already scheduled pickup at my location Billing Information Bill transportation to: Sender Your reference: P.O. no.: Invoice no.: Department no.: Thank you for shipping online with Fedex ShipManager at fedex.com. Please Note Fed Ex wtll not be responsible for any clatm in excess of $100 per package, whether the result of loss, damage, delay, non-delivery, mtsdelivery, or misinformatton, unless you declare a htgher value, pay an addttional charge, document your actual loss and file a ttmely clatm. Ltmttattons found in the current Fed Ex Servtce Gutde apply. Your right to recover from Fed Ex for any loss, tncluding tntnnsic value of the package, loss of sales, income interest, profit, attorney's fees, costs, and other forms of damage whether direct, mcidental, consequential, or spetcal is limtted to the greater of $100 or the authonzed declared value. Recovery cannot exceed actual documented loss. Maximum for 1tems of extraordtnary value .ts $500, e g., Jewelry, prec1ous metals, negotiable mstruments and other t1ems ltsed in our Service GUide Written clatms must be ftled within strrct ttme ltmtts; Consult the applicable Fed Ex Serv1ce Gu1de for deta1ls The esttmated shipptng charge may be dtfferent than the actual charges for your shtpment Otfferences may occur based on actual wetght, dimensions, and other factors Consult the applicable F edt:::x Servtce Gutde or the Fed Ex Rate Sheets for details on how shtpping charges are calculated https ://www. fedex.cornl shi pping/html/en/PrintiF ram e. html 11112/2009
Page 2 of2 Receipt Address Information Ship to: Ship from: Mr. Mike Kelley Ruth Ann Hurt Chattanooga EAC - Div. of TV A Water State Office Building, Suite SEQUOYAH NUCLEAR 550 PLANT 540 McCallie Avenue Chattanooga, TN SODDY DAISY, TN 374022013 37379 us us 423-843-6700 4238436714 Shipping Information Tracking number: 793012387813 Ship date: 11/12/2009 Estimated shipping charges: 4.52 Package Information Service type: Priority Overnight Package type: FedEx Envelope Number of packages: 1 Total weight: 1LBS Declared value: O.OOUSD Special Services: Pickup/Drop-off: Use an already scheduled pickup at my location Billing Information Bill transportation to: Sender Your reference: P.O. no.: Invoice no.: Department no.: Thank you for shipping online with Fedex ShipManager at fedex.com. Please Note Fed Ex w1ll not be responsible for any claim 1n excess of $100 per package, whether the result of loss, damage, delay, non-delivery, misdelivery, or misinformation, unless you declare a higher value. pay an additional charge, document your actual loss and f1le a timely cla1m Limitations found m the current Fed Ex Service Guide apply. Your nght to recover from Fed Ex for any loss, 1ncluding 1ntnns1c value of the package, loss of sales, mcome Interest, profit, attorney's fees, costs, and other forms of damage whether direct, 1nC1dental, consequential, or speical IS lim1ted to the greater of $100 or the authorized declared value Recovery cannot exceed actual documented loss Maximum for items of extraordrnary value is $500, e g , jewelry. prectous metals, negotiable rnstruments and other items !I sed in our Service Guide Wntten claims must be filed within stnct time lrmits; Consult the applrcable FedEx Service Guide for detarls The estimated shipping charge may be drfferent than the actual charges for your shrpment Differences may occur based on actual weight, d1mensions, and other factors. Consult the applicable .E.5t(1Ex Serv_L(,._:_~_iliUQ~ or the FedEx Rate Sheets for detailS on how shipping charges are calculated https ://www. fedex. corn!shi pping/html/en/PrintiF rame .html 11/12/2009
Page 2 of2 Address Information Ship to: Ship from: To whom it may concern: Ruth Ann Hurt Nuclear Regulatory TVA Commission ATTN: Document Control SEQUOY AH NUCLEAR Desk PLANT Washington, DC SODDY DAISY, TN 20555 37379 us us 423-843-6700 4238436714 Shipping Information Tracking number: 798132826204 Ship date: 11112/2009 Estimated shipping charges: 4.52 Package Information Service type: Priority Overnight Package type: FedEx Envelope Number of packages: 1 Total weight: 1LBS Declared value: O.OOUSD Special Services: Pickup/Drop-off: Use an already scheduled pickup at my location Billing Information Bill transportation to: Sender
*Your reference:
P.O. no.: Invoice no.: Department no.: Thank you for shipping online with Fedex ShipManager at fedex.com. Please Note Fed Ex will not be responsible for any claim 1n excess of $100 per package, whether the result of loss, damage, delay, non-delivery, misdelivery, or misinformation, unless you declare a h1gher value, pay an additional charge, document your actual loss and file a timely claim. Limitations found in the current FedEx Service Guide apply. Your right to recover from FedEx for any loss, including Intrinsic value of the package, Joss of sales, income 1nterest, profit, attorney's fees, costs, and other forms of damage whether dtrect, incidental, consequential, or speical1s limited to the greater of $100 or the authorized declared value Recovery cannot exceed actual documented loss Maximum for ttems of extraordinary value is $500, e g , jewelry, precious metals, negot1able mstruments and other 1tems lised 1n our Servtce Gurde Written claims must be ftled within strict time ltmtts; Consult the applicable F edEx Serv1ce Gutde for detatls The esttmated shtpptng charge may be dtfferent than the actual charges for your shipment Differences may occur based on actual wetght, dimensions, and other factors Consult the applicable .[?dEx SeJ.Yl£§.J?..!J!Q!l or the FedEx Rate Sheets for detatls on how shtpptng charges are calculated https ://www. fedex.com/ shi pping/html/en/PrintiF rame.html 11/12/2009
S58 091214 800- NPDES CORRESPONDENCE December 14, 2009 State of Tennessee Department of Environment and Conservation Division of Water Pollution Control Enforcement & Compliance Section 6111 Floor, L & C Annex 401 Church Street Nashville, Tennessee 37243-1534
Dear Mr. Patrick Cromer:
SEQUOYAH NUCLEAR PLANT - DISCHARGE MONITORING REPORT FOR NOVEMBER 2009 Enclosed is the November 2009 Discharge Monitoring Report for Sequoyah Nuclear Plant If you have any questions or need additional information, please contact Ann Hurt at (423) 843-6714 or Stephanie Howard at (423) 843-6700 of Sequoyah's Environmental staff. Sincerely,
~- ... ./)-? ~ ~ -/{ ~:u_ ~-~ //
Christopher R. Church Site Vice President Sequoyah Nuclear Plant AH Enclosure cc (Enclosure): Chattanooga Environmental Field Office Division of Water Pollution Control State Office Building, Suite 550 540 McCallie Avenue Chattanooga, Tennessee 37402-2013 U.S. Nuclear Regulatory Commission ATTN: Document Control Desk Washington, D.C. 20555 cc: C. R. Church, OPS 4A-8QN D. E. Pittman, LP SE-C S. A. Howard, SB 2A-8QN A. A. Ray, WT 11A-K K. Langdon, POB 2B-8QN G. R. Signer, WT 6A-K P. R. Lapointe, WT 11 B-K B. A. Wetzel, OPS 4A-8QN W. A. Nurnberger Ill, POB 2A-8QN Kimberly Hodges (EDMS), LP 2V-C OMR0911.doc
REVIEW/CONCURRENCE SHEET DOCUMENT NAME: SEQUOYAH NUCLEAR PLANT- NOVEMBER DMR 2009 ORGANIZATION: Environmental DOCUMENT PREPARED BY: Ann Hurt DATE: 12/08/2009 CONCURRENCES Name R c Signature - Comment Date v N R.A.M.Hurt X S. A Howard X W. A. Nurnberger X B. A. Wetzel X K. Langdon X C. R. Church INSTRUCTIONS: Originator will determine the review/concurrence assignment. REVIEW: Examine technical content and commitments made. A review (RV) should confirm the truth and accuracy of factual statements and indicate agreement with commitments made which are applicable to the reviewer's organization. CONCURRENCE: Indication of agreement with the document as a whole. Concurrence (CN) signifies that the document is responsive to the intended purpose, logical in construction, and clear in meaning in the eyes of the recipient. A concurrence signature indicates that the individual would be willing to sign the document for the agency.
Tennessee Valley Authority, Post Office Box 2000, Soddy Daisy, Tennessee 37384*2000 December 14,2009 State of Tennessee Department of Environment and Conservation Division of Water Pollution Control Enforcement & Compliance Section 6th Floor, L & C Annex 401 Church Street Nashville, Tennessee 37243*1534
Dear Mr. Patrick Cromer:
SEQUOYAH NUCLEAR PLANT* DISCHARGE MONITORING REPORT FOR NOVEMBER 2009 Enclosed is the November 2009 Discharge Monitoring Report for Sequoyah Nuclear Plant. If you have any questions or need additional information, please contact Ann Hurt at (423) 843-6714 or Stephanie Howard at (423) 843-6700 of Sequoyah's Environmental staff. Sincerely, ~?ei~u~ Site Vice President Sequoyah Nuclear Plant Enclosure cc (Enclosure): Chattanooga Environmental Field Office Division of Water Pollution Control State Office Building, Suite 550 540 McCallie Avenue Chattanooga, Tennessee 37402-2013 U.S. Nuclear Regulatory Commission ATIN: Document Control Desk Washington, D.C. 20555
PERMITTEE NAME/ADDRESS (Include Facility Name/Location if Different} NATIONAL POLLUTANT DISCHAHGE ELIMINATION SYSTEM (NPDE$) MAJOR Form Approved.
. DISCHARGE MONITORING REPORT (DMRJ
~~--N~SEOUOU~UCL~RP~~-- (SUBR 01) OMB No. 2040*0004 MmmJ...Q.JI.OX 2000_----------- P~R~~~~~~~R II DISCHARG: ~~M;ER I ---~~ROFFICESB*~-S~L _ _ _ _ _ _ _ F *FINAL _ _ _ JODD~~~~.m~~------- DIFFUSER DISCHARGE ~~~-~~~~~HNUC~RP~N~--- h~R I ~~ n~;r~: r~:1 ~ I~: I EFFLUENT ~~~~~~~~---------- ATTN: Stephanie A. Howard From *** NO DISCHARGE D *** NOTE: Read instructions before comoletinQ this form. X PARAMETER OUANT1TY OR LOADINCi OUALITY OR CONCENTRAnON NO. FREQUENCY SAMPLE
~----------~----------~------~----------~------------~----------~----~
AVERAGE MINIMUM AVERACE MAXIMUM UNITS EX OF ANALYSIS TYPE TEMPERATURE, WATER DEG. SAMPLE ******** ******** ******** 17.3 04 0 30 I 30 MODELD CENTIGRADE MEASUREMENT 00010 z 0 0 ~PERMIT REQUIREMENT. i '
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REQUIREMENT
............ ******** RePORT DEG.C. .. SEE *CKREQ EFFLUENT GROSS VALUE DAILY.MX .: PERMIT TEMP. DIFF. BETWEEN SAMP. & SAMPLE ******** ******** 0.7 0 30/30 CALCTO MEASUREMENT 04 UPSTRM DEG.C 00016 1 vv 0 EFFLUENT GROSS VALUE PERMIT REQUIREMENT ' *. -~ * .... ~~* ******** . ** < *~5.0 DEG.C. . ';CONTtN uous C~CTO DAILYMX PH SAMPLE ******** 7.6 ******** 8.0 0 6/30 GRAB MEASUREMENT 12 00400 1 0 0 PERMIT ******** '6.0 9.0 su WEEKLY GRAB REQUIREMENT EFFLUENT GROSS VALUE MINIMUM MAXIMUM SOLIDS, TOTAL SUSPENDED SAMPLE ******** ******** 9 9 0 1 I 30 GRAB MEASUREMENT 19 00530 1 0 0 PERMIT ~***** ******** *30 100 MG/l MONTHLY GRAB REQUIREMENT EFFLUENT GROSS VALUE . :MOAVO' DAILYMX OIL AND GREASE SAMPLE ******** ******** <5 <5 0 1130 GRAB 19 00556 1 0 0 MEASUREMENT PERMIT ........... .......... .:. :us* * *;: ... . 20 . . MG/L ~ON~LY GRAB*
EFFLUENT GROSS VALUE REQUIREMENT
.Mo:Avo. : **DAILY:Mx :*
FLOW, IN CONDUIT OR THRU SAMPLE ******** ******** ******** ******** 0 30/30 RCORDR MEASUREMENT ** TREATMENT PLANT 50050 1 0 0 EFFLUENT GROSS VALUE PERMIT REQUIREMENT
******'** ******** . *.' ******** - .CONTIN* RCORDR uous NAME/TITLE PRINCIPAL EXECUTIVE OFFICER 1Certify under penalty of law that this document and all attachments were prepared under my TELEPHONE DATE direction or supervision in accordance with a system designed to assure that qualified personnel Christopher R. Church properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information. the information submitted is
- to the best of my knowledge and belief. true, 423 843*7001 09* 12 08 Sequoyah Site Vice President accurate, and complete. I am aware that there are significant penalties for submitting false SIGNATURE OF PRINCIPAL EXECUTIVE 1 - - - - - - - - - - - - - - - - - t i n f o r m a t i o n , including the possibility of fine and imprisonment for knowing violations.
OFFICER OR AUTHORIZED ACENT NUMBER YEAR MO DAY TYPED OR PRINTED COMMENTS AND EXP~NATION OF ANY VIO~TIONS fReference all attachments het No closed mode operation. The following infonnation is included in an attachment: 1. CCVV data 2. veliger monitoring data EPA Form 3320*1 (REV 3199) Previous editions may be used Page 1 of 2
DMR Attachment CCW Data CCWTRENCH Extractable Petroleum Date/Time Collected Hydrocarbons Analysis Date/Time Analy_st Method No water would come out of the pump. No sample could be obtained. CCWCHANNEL Extractable Petroleum Date/Time Collected Hydrocarbons Analysis Date/Time Analyst Method 11/11/2009@ 1110 <0.10 mg/1 11/13/2009 _@_ 1006 KMF EPH
Mean# of NOTES:% Mean# of Water Water SUB Sample Date %Settlers Sample Date Asiatic LOCATION Gravid Asiatic COLLECTED BY ZM/m3 Temp. ("C) Temp. ("C) LOCATION Clams/m3 Clam 11/03/2009 133 0 16 11/03/2009 76 16 In plant RCW CMW 11/10/2009 417 6.1 16 11/10/2009 25 16 In plant RCW CMW 11/17/2009 269 0 16 11/17/2009 0 16 In plant RCW CMW 11/24/2009 36 50 15 11/24/2009 18 15 In plant RCW CMW 12/01/2009 32 0 13.5 12/01/2009 0 13.5 In plant RCW WE
PERMITrEE NAME/ADDRESS (Include Facility NameA..ocation if Different) NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPDESJ MAJOR Form Approved. Name TVA* SEOUOVAH NUCLEAR PLANT DISCHARGE MONITORING REPORT (DMR) OMB No. 2040-0004 A(Jdress P.O.BOX2000 =========== ---~INTEROFFICUB*2A*SQ~------- _ _ _ JODDY~AISY.m~~------- (SUBR 01) Faciii~_NA~EQUO~HNUCLEARP~N~--- ~~0-~MI~~OUN~---------- EFFLUENT QAY
... NO DISCHARGE D ...
ATIN: stephanie A. Howard 30 NOTE: Read instructions before completinQ this form. PARAMETER QUANTITY OR LOADING OUALITY OR CONCENTRAnON NO. FREQUENCY SAMPLE EX OF TYPE AVERAGE MAXIMUM UNITS MINIMUM AVERAGE MAXIMUM UNITS ANALYSIS CHLORINE, TOTAL RESIDUAL ******** ******** ******** 0.024 0.056 0 41 I 30 GRAB
** 19 50060 0 0 PERMIT:;.. ~~- :* * * ~~UiREM.ENT*-*:~ : .:.-.~ ~~*~* ~* **=
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- C, RATE OF ******** 0 ******** 0 30/30 CALCTD 62 CHANGE 82234 1 0 0 2 DEG ******** ******* CONTIN CALCTD EFFLUENT GROSS VALUE DAILYMX
- C/HR uous SAMPLE MEASUREMENT SAMPLE MEASUREMENT
~;;~
NAMEniTLE PRINCIPAL EXECUTIVE OFFICER I Certify under penally of law that this document and all attachments were prepared under my TELEPHONE DATE direction or supervision in accordance with a system designed to assure that qualified personnel Christopher R. Church properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the infonnation, the information submitted is , to the best of my knowledge and belief, true, Sequoyah Site Vice President 423 843-7001 09 12 08 Sequoyah Site Vice President accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fine and imprisonment for knowing violations. SIGNATURE OF PRINCIPAL EXECUTIVE J TYPED OR PRINTED OFFICER OR AUTHORIZED AGENT
~~~~I NUMBER YEAR MO DAY COMMENTS AND EXP~NATION OF ANY VIOLATIONS fReference all attachments he!
EPA Form 3320-1 (REV 3/99) Previous editions may be used Page 2 of 2
PERMITTEE NAME/ADDRESS (Include Facility Name/Location if Different) NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPDES) MAJOR Form Approved. DISCHARGE MONITORING REPORT ~~--~~seouon~ucLEMP~~--- (DMR) (SUBR 01) OMS No. 2040*0004 &rm:~ _P.O.J!OX 2000_ _ _ _ _ _ _ _ _ _ _ _ ---~~ROFFICESB*~*SQ~------ F- FINAL _ _ _ JODDY~~~~.m37~-------- BIOMONITORING FOR OUTFALL 101 F~~-~~~~~HN~LEARP~N~--- ~~~AMI~NCOU~---------- EFFLUENT AlTN: stephanie A. Howard
-* NO DISCHARGE D ***
NOTE* Read instructions before comoletino this form X PARAMETER OUANm'Y OR LOADING QUALITY OR CONCENTRATION NO. FREQUENCY SAMPLE
~----------~-----------p------~----------~------------~----------~----~
AVERAGE MAXIMUM UNITS MINIMUM AVERAGE MAXIMUM UNITS EX OF ANALYSIS TYPE IC25 STATRE 7DAV CHR SAMPLE ******** ******** >100.0 ******** 1 I 180 COMPOS MEASUREMENT ** 23 0 CERIODAPHNIA TRP3B 1 0 EFFLUENT GROSS VALUE 0 ... *.:;~P~r .. :**... :***. R£au*~E,..eNT .* *
-=**....** .- **** .* ..::~t~**:~*~;:,'*.:.:p, ; ;* ......~*** .* .* . **:* ........ .*** *.*:*.* PERCENT 1./ ** '.' t :**see*:>* C0fv1f.'P~
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23 0 1 I 180 COMPOS PIMEPHALES MEASUREMENT TRP6C 1 0 0 PERMIT ******** ******** 45~2' ******** ******** PERCENT SEE COMPOS REQUIR~MENT EFFLUENT GROSS VALUE MIMINUM PERMIT SAMPLE MEASUREMENT PERMIT REQUIREMENT I. SAMPLE MEASUREMENT
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~!~nt NAME/TITLE PRINCIPAL EXECUTIVE OFFICER I Certify under penalty of law that this document and all attachments were prepared under my TELEPHONE DATE direction or supervision in accordance with a system designed to assure that qualified personnel Christopher R. Church properly gather and evaluate the infonnation submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is , to the best of my knowledge and belief, true. 423 843-7001 09 12 08 Sequoyah Site Vice President accurate, and complete. I am aware that there are significant penalties for submitting false infonnation, including the possibility of fine and imprisonment fOI' knowing violations.
SIGNATURE OF PRINCIPAL EXECUTIVE I 1YPED OR PRINTED OFFICER OR AUTHORIZED AGENT
~~;~I NUMBER YEAR MO DAY COMMENTS AND EXPLANATION OF ANY VIOLATIONS /Reference all attachments he!
Toxicity was sampled 11/15/2009- 11120/2009. Report will be submitted with the December 2009 DMR. EPA Form 3320-1 (REV 3199) Previous editions may be used Page 1 of 1
PERMITTEE NAME/ADDRESS (Include Facility Name/Location if Different} NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPDES) Form Approved. MAJOR
===========
Name TVA* SEOUOYAH NUCLEAR PLANT DISCHARGE MONITORING REPORT (DMRJ OMB No. 2040-0004 (SUBR 01) P.O.BOX~ l---p-~-~-~r-0~-~-~_;,5s..;;.~-R--III DISCHARC:~~M~ER I ~~~~.WASTE TREATMENT POND Address
<INTEROFFICE SB*2A*SQN)
SOD~*DAISY.m37~-====
F~~-NA~EQ~~HN~LEARP~N~--- ~~~~AMI~NCOUN~---------- ATTN: stephanie A. Howard I YEAR MO t:qRJNG p=i MD QAY 30 EFFLUENT
*** NO DISCHARGE D ...
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w-~~ NAMEflmE PRINCIPAL EXECUTIVE OFFICER I Certify under penalty of law that this document and all attachments were prepared under my TELEPHONE DATE direction or supervision in accordance with a system designed to assure that qualified personnel Christopher R. Church property gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system. or those persons directly responsible for gathering the infonnation. the infonnation submitted is . to the best of my knowledge and belief, true, Site Vice rest ent 423 843-7001 09 12 08 Sequoyah Site Vice President accurate. and complete. I am aware that there are significant penalties for submitting false I SIGNATURE OF PRINCIPAL EXECUTIVE infonnation, including the possibility of fine and imprisonment for knowing violations.
~~~~I OFFICER OR AUTHORIZED ACENT NUMBER YEAR MO DAY ~PED OR PRINTED COMMENTS AND EXPLANATION OF ANY VIOLATIONS (Reference all attachments her The Turbine Building Sump (TBS) was discharged directly to the Yard Pond (YP) on 11/02/09@ 0147- 11/06/09@ 1516 and on 11/13/09@ 1135- 11/16/09@ 1317.
EPA Form 3320-1 (REV 3199) Previous editions may be used Page 1 of 1
PERMITTEE NAME/ADDRESS (Include Facility Name/Location if Different} NATIONAL POLLUTANT DISCHARr,E ELIMINATION SYSTEM (NPDES} MAJOR Form Approved. DISCHARGE MONITORING REPORT (DMRJ Na~--N~SEOUOY~~UCLEMP~~--- (SUBR 01) OMB No. 2040-0004 Address_P.O..J.OX 2000_ _ _ _ _ _ _ _ _ _ _ _ ---~~ER~FICESB-~*SQ~------ _ _ _ JODDY~AI~TN37~------- Fa~-~~EO~HNUCLEARP~N~---- ~~o~A~ro~~Nn _________ _ EFFLUENT PA'f *** NO DISCHARGE IXX I *** ATTN: stephanie A. Howard 30 NOTE; Read instructions before completinQ this form PH 00400 1 PARAMETER 0 0
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NAME/TITLE PRINCIPAL EXECUTIVE OFFICER I Certify under penalty of law that this document and all attachments were prepared under my TELEPHONE DATE direction or supervision in accordance with a system designed to assure that qualified personnel Christopher R. Church properly gather and evaluate the information submitted Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information. the information submitted is
- to the best of my knowledge and belief, true, 423 843-7001 09 12 08 Sequoyah Site Vice President accurate. and complete. I am aware that there are significant penalties for submitting false information. including the possibility of fine and imprisonment for knowing violations.
SIGNATURE OF PRINCIPAL EXECUTIVE J TYPED OR PRINTED OFFICER OR AUTHORIZED AGENT
~~~~I NUMBER YEAR MO DAY COMMENTS AND EXPLANATION OF ANY VIOLATIONS (Reference all attachments het No Discharge this Period EPA Form 3320-1 (REV 3199) Previous editions may be used Page 1 of 1
PERMITTEE NAME/ADDRESS (Include Facility Name/Location If Different} NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPDIESJ Form Approved. MAJOR Nam~-N~SEOUOY~~UCLEARP~~--- DISCHARGE MONITORING REPORT fDMRJ OMB No. 2040-0004 (SUBR 01) Address _P.O.JtOX 2000_ _ _ _ _ _ _ _ _ _ _ _ ---~INTEROFFICESB*2A*SQ~------- F- FINAL _ _ _ JODDY~AISY.TN~3BL _ _ _ _ _ _ _ RECYCLED COOLING WATER Faciii~-~~EQU~A~~~~~N~---- ~c~o~~~~~Nn _________ _ EFFLUENT
*** NO DISCHARGE IXX I ***
ATTN: stephanie A. Howard NOTE: Read instructions before completinQ this form. X PARAMETER OUANnTY OR LOADING QUALITY OR CONCENTRAnON NO. FREQUENCY SAMPLE EX OF TYPE AVERAGE MAXIMUM UNITS MINIMUM AVERAGE MAXIMUM UNITS ANALYSIS TEMPERATURE, WATER DEG. CENTIGRADE SAMPLE MEASUREMENT 04 *-***** *-***** 04 00010 z 0 0 . PERMIT REQtJ.UWM:NT
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****'**** ******** ..... . **s.o *. **'*'***** 9.0 su WEEKLY GRAB EFFLUENT GROSS VALUE MINIMUM MAXIMUM SOUDS, TOTAL SUSPENDED SAMPLE MEASUREMENT ******** ******** ... ******** ******** 19 00530 1 0 0 EFFLUENT GROSS VALUE PERMfT REQUIREMENT DAILYMX 30 MG/l DAILY COMPOS OIL AND GREASE SAMPLE MEASUREMENT ******** ******** .. ******** ******** 19 00556 1 0 0 PERMIT *****'**** ******** ..... ******** ***'***** 15 MG/L DAILY GRAB REQUIREMENT EFFLUENT GROSS VALUE DAILYMX FLOW, IN CONDUIT OR THRU TREATMENT PLANT SAMPLE MEASUREMENT 03 50050 1 0 0 EFFLUENT GROSS VALUE PERMIT REQUIREMENT REPORT
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REQlJIRIEJ.1ENi NAME/TITLE PRINCIPAL EXECUTIVE OFFICER I Certify under penalty of law that this doaJmenl and all attachments wero prepared under my
~~!~
TELEPHONE DATE direction or supervision in accordance with a system designed to assure that qualified personnel Christopher R. Church property gather and evaluate the information submitted. Based on my inquiry of the pen10n or persons who manage the system. or those persons direelly responsible for gathering the infonnation, the information submitted is . to the best of my knowledge and belief, true, 423 843-7001 09 12 08 Sequoyah Site Vice President accurate, and complete. I am aware that there are significant penalties for submitting false infonnation, including the possibility of fine and imprisonment for knowing violations SIGNATURE OF PRINCIPAL EXECUTIVE J TYPED OR PRINTED OFFICER OR AUTHORIZED AGENT
~~:_1 NUMBER YEAR MO DAY COMMENTS AND EXPLANAnON OF ANY VIOLATIONS (Reference all attachments het No Discharge this Period EPA Form 3320-1 (REV 3/99) Previous editions may be used Page 1 of 1
PERMITTEE NAME/ADDRESS (Include Facility Name/Location if Different) NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPDESJ Form Approved. MAJOR NamL_N~SEOUO~~UCLEMP~~--- DISCHARGE MONITORING REPORT (DMRJ OMB No. 2040-0004 (SUBR 01) Address_P.O.Jl.OX 2000_ _ _ _ _ _ _ _ _ _ _ _ p~~~~~~~~R II DISCHARG: ~BJ:l ---~IN~OFFICESB*2A*S~L------ F -FINAL _ _ _ JODDY~~ISY.m~~------- RECYCLED COOLING WATER Fa~~-~~~~~~~~R~~--- EFFLUENT ~~~-~~~~---------- ATTN: Stephanie A. Howard From 1 YEAR I t~rNGP~t 09 11 MD 01 I To 09 11 MO I 30 QAY 1 -* NO DISCHARGE IXX I ... NOTE: Read instructions before completinQ this form X PARAMETER QUANTITY OR LOADING QUALITY OR CONCENTRAnON NO. FREQUENCY SAMPLE EX OF TYPE I---==-AVE_RA_G-=E=-"""'~"'--M-AX.,_IM-U-M-....,.-U-N-ITS--1--M-IN-IM_U_M _ __,pooo------..------.,..---~ UNITS ANALYSIS AVERAGE MAXIMUM IC25 STATRE 7DAY CHR SAMPLE ******** ******** ******** ******** 23 MEASUREMENT CERIODAPHNIA TRP38 1 0 0 . P£RMrr REQU~
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~.:-7(,?4 NAME/TITLE PRINCIPAL EXECUTIVE OFFICER I Certify under penalty of law that this document and all attachments were prepared under my TELEPHONE DATE direction or supervision in accordance with a system designed to assure that qualified personnel Christopher R. Church properly gather and evaluate the information submitted. Based on my inquity of the person or persons who manage the system, or those persons directly responsible for gathering the information. the information submitted is , to the best of my knowledge and belief, true, Sequoyah Site Vice President 423 843-7001 09 12 08 Sequoyah Site Vice President accurate, and complete. I am aware that there are significant penalties for submitting false I SIGNATURE OF PRINCIPAL EXECUTIVE information. including the possibility of fine and imprisonment for knowing violations.
TYPED OR PRINTED OFFICER OR AUTHORIZED AGENT
~~~~I NUMBER YEAR MO DAY COMMENTS AND EXPLANATION OF ANY VIOLATIONS tReference all attachments he!
No Discharge this Period EPA Form 3320*1 (REV 3199) Previous editions may be used Page 1 of 1
PERMITTEE NAME/ADDRESS (Include Facility Name/Location if Different) NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPDES) Form Approved. MAJOR DISCHARGE MONITORING REPORT (DMRJ Na~--N~SEOU~AA~~LEARP~~--- (SUBR 01) OMB No. 2040-0004 A.ddress_y.O..!_OX 2000_ _ _ _ _ _ _ _ _ _ _ _ p~~~~~~!~~R II DISCHARC~ ~~M~ER I ---~I~ROFFICESB-~*SQ~------ F- FINAL _ _ _ JOD~~AI~m3~------- BACKWASH FOC~_NA~EQ~YAHNUC~ARP~N~---- I I -=- EFFLUENT ~~0-~~ro~N~---------- YEAR MO t~T!NG Ip~t :::v 1111011 I DA'f I -* NO DISCHARGE D ... ATTN: Stephanie A. Howard From 09. 11 01 TO 09 30 NOTE: Read instructions before completinQ this form PARAMETER QUANTITY OR LOADING OUAUTY OR CONCENTRAnON NO. FREQUENCY SAMPLE EX OF TYPE AVERAGE MAXIMUM UNITS MINIMUM AVERACiE MAXIMUM UNITS ANALYSIS DEBRIS, FLOATING (SEVERITY) SAMPLE MEASUREMENT **-**** ********
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NAMEnJTLE PRINCIPAL EXECUTIVE OFFICER 1Certify under penally of law that this document and all attachments ware prepared under my TELEPHONE DATE direction or supervision in accordance with a system designed to assure that qualified personnel Christopher R. Church properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those p81Sons directly responsible for gathering the
-~ ,
information, the information submitted is , to the best of my knowledge and belief, true. Sequoyah Site Vice Pres1dent 423 843-7001 09 12 08 Sequoyah Site Vice President accurate, and complete. I am aware that there are significant penalties for submitting false I SIGNATURE OF PRINCIPAL EXECUTIVE infonnation, including the possibility of fine and imprisonment for knowing violations. TYPED OR PRINTED OFFICER OR AUTHORIZED AGENT
~~~~I NUMBER YEAR MO DAY COMMENTS AND EXPLANATION OF ANY VIOLATIONS (Reference all attachments he!
Operations performs visual inspedions for floating debris and oil and grease during all backwashes. EPA Form 3320-1 (REV 3/99) Previous editions may be used Page 1 of 1
PERMITTEE NAME/ADDRESS (Include Facility Name/Location if Different) NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPDESJ Form Approved. MAJOR J:!ame__TVA.:_ SEOUOYAH~UCLEAR PLAN!__* __ DISCHARGE MONITORING REPORT (DMRJ OMB No. 2040*0004 (SUBR 01) Address _P.O.JtOX ~- _ _ _ _ _ _ _ _ _ _ _ ---~INTER~FICESB*~*SO~------ F- FINAL _ _ _ JODDY~AI~.m3~~-------- BACKWASH S~~-~~~@~HN~LEARP~NC _ _ _ _ ~~0-~~~~0UN~---------- EFFLUENT ATTN: stephanie A. Howard QAY 30
*** NO DISCHARGE D ...
NOTE: Read instructions before comoletin!l this form. X PARAMETER QUANTITY OR LOADING QUALITY OR CONCENTRAnON NO. FREQUENCY SAMPLE EX OF TYPE r--A-v"""e"""RA_G_E...,_-..,~-----'"I"""---1------.,...-A-V-E-R-A-G-E--r---M-AX-IM_U_M _ __,_U~N...,IT~S~ ANALYSIS DEBRIS, FLOATING (SEVERITY) ~PLE MEASUREMENT
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NAME/TinE PRINCIPAL EXECUTIVE OFFICER I Certify under penalty of law that this document and all attachments were prepared under my TELEPHONE DATE direction or supervision in accordance with a system designed to assure that qualified personnel Christopher R. Church property gather and evaluate the infonnation submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the infonnation submitted is . to the best of my knowledge and belief, true, Sequoyah Site Vice President 423 843-7001 09 12 08 Sequoyah Site Vice President accurate, and complete. I am aware that there are significant penalties for submitting false SIGNATURE OF PRINCIPAL EXECUTIVE 1 - - - - - - - - - - - - - - - - ! i n f o r m a l i o n . including the possibility of fine and imprisonment for knowing violations.
~PED OR PRINTED OFFICER OR AUTHORIZED ACE NT NUMBER YEAR MO DAY COMMENTS AND EXP~NATION OF ANY VIO~TIONS (Reference all attachments 11e1 Operations performs visual inspections for floating debris and oil and grease during all backwashes.
EPA Form 3320-1 (REV 3199) Previous editions may be used Page 1 of 1
PERMITTEE NAME/ADDRESS (Include Facility Name/Location if Different} NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPDESJ MAJOR Form Approved.
===========
Name TVA- SEOUOYAH NUCLEAR PLANT DISCHARGE MONITORING REPORT (DMRJ (SUBR01) OMB No. 2040-0004 l---p-:-R~-~;...;~-~-~-!5.; . 0e;;..eR-~II DISCHARG:~~M~ER I ~~~ATER&STORMWATER Address P.O.BOX2000 ---~IN~ROFFICUB*~-S~L------- _ _ _ J~OY~~ISY.TN37~-------- Fa~~-~~EQU~A~UCLE~P~ID_ _ _ _ _ LOCM~-~MJLro~OUN~---------- EFFLUENT ATTN: Stephanie A. Howard DAY 30
*** NO DISCHARGE IXX I ...
NOTE: Read instructions before completinQ this form. PARAMETER QUANTITY OR LOADING QUALITY OR CONCENTRATION NO. FREQUENCY SAMPLE EX OF TYPE
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MEASUREMENT 03 TREATMENT PLANT 50050 1 0 0 PERMIT REPORT. REPORT MGD ******** . ******** ****"*"* ONCE/ ESTIMA REQUIREMENT EFFLUENT GROSS VALUE . MOAVQ DAILYMX *. BATCH SAMPLE MEASUREMENT PERMIT
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NAMEITmE PRINCIPAL EXECUTIVE OFFICER I Certify under penalty of law that this document and all attachments were prepared under my TELEPHONE DATE directitln or supervision in acconfance with a system designed to assure that qualified personnel Christopher R. Church property gather and evaluate the infonnation submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is , to the best of my knowledge and belief, true, 423 843-7001 09 12 08 Sequoyah Site Vice President accurate, and complete. 1am aware thai there are significant penalties for submilting false SIGNATURE OF PRINCIPAL EXECUTIVE 1---------------------------iinfonnation, including the possibility of fine and imprisonment for knowing violations. OFFICER OR AUTHORIZED AGENT NUMBER YEAR MO DAY TYPED OR PRINTED COMMENTS AND EXP~NATION OF ANY VIO~TIONS fReference all attachments he/ During this reporting period, there has been no flow from the Dredge Pond other than that resulting from rainfall. EPA Form 3320-1 (REV 3/99) Previous editions may be used Page 1 of 1
S58 091013 801 - NPDES CORRESPONDENCE October 13, 2009 State of Tennessee Department of Environment and Conservation Division of Water Pollution Control Enforcement & Compliance Section 61h Floor, L & C Annex 401 Church Street Nashville, Tennessee 37243-1534
Dear Mr. Patrick Cromer:
SEQUOYAH NUCLEAR PLANT- CORRECTION TO DISCHARGE MONITORING REPORT FOR AUGUST 2009 Enclosed is the August 2009 corrected Discharge Monitoring Report for Sequoyah Nuclear Plant. During a review of the raw water chemical treatment program it was noted that Sequoyah began using Floguard MS6236 on 8/21/2009. This updated information has been included in the comments section on discharge number 101 G page 2 of 2. Also, the H-150M information was updated to include the low level detection method results in the comments section on discharge number 101 G page 2 of 2. If you have any questions or need additional information, please contact Ann Hurt at (423) 843-6714 or Stephanie H.oward at (423) 843-6700 of Sequoyah's Environmental staff. Sincerely,
*1
~:Lr::r Ti:~~y ;{Cleary Site Vice President Sequoyah Nuclear Plant AH Enclosure cc (Enclosure): Chattanooga Environmental Field Office Division of Water Pollution Control State Office Building, Suite 550 540 McCallie Avenue Chattanooga, Tennessee 37402-2013 U.S. Nuclear Regulatory Commission ATTN: Document Control Desk Washington, D.C. 20555 cc: C. R. Church, POB 2B-SQN A. A. Ray, WT 11A-K T. P: Cleary, OPS 4A-SQN G. R. Signer, WT 6A-K W. A. Nurnberger Ill, POB 2A-SQN B. A. Wetzel, OPS 4A-SQN D. E. Pittman, LP SE-C EDMS, WT CA-K DMR0908correction.doc
'\
REVIEW/CONCURRENCE SHEET DOCUMENT NAME: SEQUOYAH NUCLEAR PLANT- CORRECTED DISCHARGE MONITORING REPORT FOR AUGUST 2009 ORGANIZATION: Environmental DOCUMENT PREPARED BY: Ann Hurt DATE: 10/07/2009 CATEGORY: NPDES Correspondence CONCURRENCES Name R c Signature - Comment Date v N Ann Hurt X Stephanie A Howard X d W. A Nurnberger X Beth A Wetzel X Chris R Church X Timothy P Cleary X ~ t':Soc~ (for signature) INSTRUCTIONS: Originator will determine the review/concurrence assignment. REVIEW: Examine technical content and commitments made. A review (RV) should confirm the truth and accuracy of factual statements and indicate agreement with commitments made which are applicable to the reviewer's organization. CONCURRENCE: Indication of agreement with the document as a whole. Concurrence (CN) signifies that the document is responsive to the intended purpose, logical in construction, and clear in meaning in the eyes of the recipient. A concurrence signature indicates that the individual would be willing to sign the document for the agency.
Tennessee Valley Authority Post Office Box 2000 Soddy Daisy, Tennessee 37384-2000 Timothy P. Cleary Site Vice President Sequoyah Nuclear Plant October13, 2009 State of Tennessee Department of Environment and Conservation Division of Water Pollution Control Enforcement & Compliance Section 6th Floor, L & C Annex 401 Church Street Nashville, Tennessee 37243-1534
Dear Mr. Patrick Cromer:
SEQUOYAH NUCLEAR PLANT- CORRECTION TO DISCHARGE MONITORING REPORT FOR AUGUST 200~ Enclosed is the August 2009 corrected Discharge Monitoring Report for Sequoyah Nuclear Plant. During a review of the raw water chemical treatment program it was noted thatSequoyah began using Floguard MS6236 on 8/21/2009. This updated information has been included in the comments section on discharge number 101 G page 2 of 2. Also, the H-150M information was updated to include the low level detection method results in the comments section on discharge number 101 G page 2 of 2. If you have any questions or need additional information, please . contact Ann Hurt at (423) 843-6714 or Stephanie Howard at (423) 843-6700 of Sequoyah's Environmental staff. Enclosure cc (Enclosure): Chattanooga Environmental Field Office Division of Water Pollution Control State Office Building, Suite 550 540 McCallie Avenue Chattanooga, Tennessee 37402-2013 U.S. Nuclear Regulatory Commission ATTN: Document Control Desk Washington, D.C. 20555
- p~inted on recycled paper
PERMITIEE NAME/ADDRESS (Include Facility Name/Location if Different) NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPOES) MAJOR Form Approved. Na~_~A-SEQUOYA~UCLEARPLANT _ _ _ _ DISCHARGE MONITORING REPORT (OMRJ OMB No. 2040-0004 Addres_L _E.~BOX 2000 _ _ _ _ _ _ _ _ _ _ _ _ (SUBR 01)
---~TE@FFICESB-~-SQ~-------- TN0026450 101 G F- FINAL
_ _ _ 20DDY-DAISYJ~738L _ _ _ _ _ _ _ _ -*=-~~"=-~-o~=**-'-"'"=-~ Facility_ .:JYA- SEQUOYAH NUCLEAR PLANT_ _ _ _ _ _ F'E::RMIT J',l_l!M!3_ER ~Ql§g_ljA_J3._Q_[;_ NU_rvl_f:3f.:B_ DIFFUSER DISCHARGE
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I NAME/TITLE PRINCIPAL EXECUTIVE OFFICER i I Cert1fy under penalty of law that th1s document and all attachments were prepared under my i , TELEPHONE DATE !----~---------------~-~~--ld!rectlon or supervision in accordanc~ w1th a system designed to ~ssure that qualified personnel '------~---**------~------ - -,---~,--*-------' 1
- Timothy P. Cleary jproperly gather and evaluate the information submitted. Based on my Inquiry of the person or 1persons who manage the system, or those persons directly responsible for gathenng the
* *
- IInformation, the information submitted is, to the best of my knowledge and belief, true, 843-7001 ! 09 I 10 07 :
Sequoyah S1te V1ce President 'accurate, and complete. 1am aware that there are significant penalties for submitting false
~------**~---* .. _____ . ___________________ _Jinformatton, including the possibiltty of fine and impnsonment for know1ng violations TYPED OR PRINTED i --*--------~--- -**- ------ --*-* ---~-- *------- _______________ l__ ____ -*-**~-~--'-------- ------ ----------*----~------ *----~--
COMMENTS AND EXPLANATION OF ANY VIOLATIONS (Reference all attachments here) The following injections occured: 1. Biodetergent 73551 (max. calc. cone. was 0.017mg/L--Iimit 2.0mg/L) 2. MSW-1 01 (max. calc. cone. was 0.061 mg/L--Iimit 0.2mg/L) 2. Floguard MS6236 (max. calc. cone. was 0.031mg/L--Iimit 0.2mg/L) 3. H-150M (max. calc. cone. was 0.04mg/L--Iimit 0.050mg/L) 4. H-150M (low detection level analytical method was <0.050mg/L--Iimit 0.050mg/L). EPA Form----**-------3320-1 (REV 3/99) *-- -----*-----------*-------~ --*-**** -***-*---- Previous editions may be used Page 2 of 2
.J S58 100111 800- NPDES CORRESPONDENCE January 11, 2010 State of Tennessee Department of Environment and Conservation Division of Water Pollution Control Enforcement & Compliance Section 6th Floor, L & C Annex 401 Church Street Nashville, Tennessee 37243-1534
Dear Mr. Patrick Cromer:
SEQUOYAH NUCLEAR PLANT- DISCHARGE MONITORING REPORT FOR DECEMBER 2009 Enclosed is the December 2009 Discharge Monitoring Report for Sequoyah Nuclear Plant. If you have any questions or need additional information, please contact Ann Hurt at (423) 843-6714 or Stephanie Howard at (423) 843-6700 of Sequoyah's Environmental staff. Sincerely,
~Jr,4i Christopher R. Church Site Vice President Sequoyah Nuclear Plant AH Enclosure cc (Enclosure):
Chattanooga Environmental Field Office Division of Water Pollution Control State Office Building, Suite 550 540 McCallie Avenue Chattanooga, Tennessee 37402-2013 U.S. Nuclear Regulatory Commission ATTN: Document Control Desk Washington, D.C. 20555 cc: C. R. Church, OPS 4A-SQN D. E. Pittman, LP SE-C S. A. Howard, SB 2A-SQN A. A. Ray, WT 11A-K K. Langdon, POB 28-SQN G. R. Signer, WT 6A-K P. R. Lapointe, WT 11 B-K B. A. Wetzel, OPS 4A-SQN D. B. Nida, LP SU-C Kimberly Hodges {EDMS), LP 2V-C W. A. Nurnberger Ill, POB 2A-SQN DMR0912.doc
REVIEW/CONCURRENCE SHEET DOCUMENT NAME: SEQUOYAH NUCLEAR PLANT- December DMR ORGANIZATION: Environmental DOCUMENT PREPARED BY: Ann Hurt DATE: 1/7/10 CONCURRENCES Name R C Signature - Comment Date V N R.A.M.Hurt X S. A Howard X W. A. Nurnberger B. A. Wetzel K. Langdon C. R. Church INSTRUCTIONS: Originator will determine the review/concurrence assignment. REVIEW: Examine technical content and commitments made. A review (RV) should confirm the truth and accuracy of factual statements and indicate agreement with commitments made which are applicable to the reviewer's organization. CONCURRENCE: Indication of agreement with the document as a whole. Concurrence (CN) signifies that the document is responsive to the intended purpose, logical in construction, and clear in meaning in the eyes of the recipient. A concurrence signature indicates that the individual would be willing to sign the document for the agency.
Tennessee Valley Authority, Post OH1ce Box 2000, Soddy Oa1sy, Tennessee 37384-.2000 January 11, 2010 State of Tennessee Department of Environment and Conservation Division of Water Pollution Control Enforcement & Compliance Section 61h Floor. L & C Annex 401 Church Street Nashville, Tennessee 37243-1534
Dear Mr. Patrick Cromer:
SEQUOYAH NUCLEAR PLANT- DISCHARGE MONITORING REPORT FOR DECEMBER 2009 Enclosed is the December 2009 Discharge Monitoring Report for Sequoyah Nuclear Plant. If you have any questions or need additional information. please contact Ann Hurt at (423) 843-6714 or Stephanie Howard at (423) 843-6700 of Sequoyah's Environmental staff. Sincerely,
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Christopher R. Church Site Vice President Seguoyah Nuclear Plant Enclosure cc (Enclosure): Chattanooga Environmental Field Office Division of Water Pollution Control State Office Building, Suite 550 540 McCallie Avenue Chattanooga, Tennessee 37402-2013 U.S. Nuclear Regulatory Commission ATTN: Document Control Desk Washington. D.C. 20555
PERMITIEE NAME/ADDRESS (Include Facti/tv Name!Locatton tf Otfferent) NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPDESJ MAJOR Form Approved Name TVA* SEOUOYAH NUCLEAR PLANT DISCHARGE MONITORING REPORT (OMRJ OMB No 2040-0004 &i~e~=P:Q.~oiWo= =========== UNTEROFFICE SB-2A-SQNl ---soo~~~~m~~4------- 5 r-[--P-;_RN_Mo-~~-~-~-!-e-~-R---~II Q!scHARG; (SUBR 01)
~~M~ER I :,;'~;~R o1scHARGE
~~~=~~~@~~~~~~ID===== EFFLUENT ~~~-~~m~~---~------ QAY NO DISCHARGE D ... ATTN: Stephanie A. Howard 31 NOTE: Read 1nstruct1ons before comoletlnQ th1s form. I X PARAMETER QUANTITY OR LOADING QUALITY OR CONCENTRATION NO. FREQUENCY SAMPLE EX OF TYPE ANAlYSIS TEMPERATURE, WATER DEG. SAMPLE MEASUREMENT AVERAGE MAXIMUM UNITS MINIMUM AVERAGE MAXIMUM 13.9 UNITS 04 0 31 I 31 I MODELD CENTIGRADE 00010 z 0 0 PERMIT REQUIREMENT
'******** ****'**** .... *****'*** ******** 30.5 DEG.C . SEE CKREQ INSTREAM MONITORING TEMPERATURE, WATER DEG.
CENTIGRADE SAMPLE MEASUREMENT DAILY MX 28.2 I 04 0 PERMIT 31 I 31 !RCORDR 00010 1 0 0 PERMIT REQUIREMENT
******** ******** .... *****'*** ******** REPORT DEG.C. SEE CKREQ EFFLUENT GROSS VALUE TEMP. DIFF. BETWEEN SAMP. & SAMPLE MEASUREMENT DAILYMX 2.9 04 0 1 PERMIT 31 I 31 CALCTD lI UPSTRM DEG.C 00016 1 w 0 PERMIT REQUIREMENT *"****"** :***"**** .... ******** ******** 5.0 DEG.C. CONTIN CALCTD I
EFFLUENT GROSS VALUE PH SAMPLE MEASUREMENT
........ ******'** .. 7.5 ********
DAILY MX 7.8 12 0 uous 5 I 31 GRAB 00400 1 0 0 PERMIT REQUIREMENT
"******* ******** .... 6.0 ******** 9.0 su WEEKLY GRAB EFFLUENT GROSS VALUE .MINIMUM MAXIMUM SOLIDS, TOTAL SUSPENDED SAMPLE ******** ******** ******** 5 5 0 1 I 31 GRAB MEASUREMENT ** 19 00530 1 0 0 PERMIT REQUIREMENT ******** ******** .... ******** 30 100 MG/l MONTHLY GRAB EFFLUENT GROSS VALUE MOAVG DAILYMX OIL AND GREASE SAMPLE ******** ******** .. ******** <5 <5 19 0 1 I 31 GRAB 00556 1 0 EFFLUENT GROSS VALUE 0
MEASUREMENT PERMIT. REQUIREMENT 15 20 MG/l MONTHLY I GRAB MOAVG DAILY MX FLOW, IN CONDUIT OR THRU TREATMENT PLANT SAMPLE MEASUREMENT
******** 1599 03 ******** ******** ******** .. 0 31 I 31 RCORDR 50050 1 0 0 PERMIT ******** REPORT* MGD ***'***** ******** ******** .... CONTIN RCORDR REQUIREMENT EFFLUENT GROSS VALUE DAILYMX uous i ~1C1J~-O ~G.-\ c.{
NAME/TITLE PRINCIPAL EXECUTIVE OFFICER I Cert1fy under penally of law that th1s document and all anachments were prepared under my TELEPHONE DATE d~recllon or superv.s1on in accordance w1th a system des1gned to assure that quahfled personnel Christopher R. Church properly gather and evaluate the anformahon subm11ted Based on my 1nqu1ry of the person Of persons who manage the system. or those persons d1reclly responsible for gathering the Environmental Manager SON & WBN 1niormahon. the 1nforma11on subm11ted IS
- to the best of my knowledge and belief. true. 423 843-7001 10 01 07 Sequoyah Site Vice President accurate. and complete I am aware thai there are significant penalt1es for submitting false SIGNATURE OF PRINCIPAL EXECUTIVE I TYPED OR PRINTED 1n1ormal1on. Including the possibility of f1ne and 1mpr.soomen1 for knowmg v1olatoons OFFICER OR AUTHORIZED AGENT AREA
.CODE I NUMBER YEAR MO DAY COMMENTS AND EXPLANATION OF ANY VIOLATIONS (Reference all attachments het No closed mode operation. The following information is included in an attachment: 1. CCW Data 2. Veliger Monitoring Data EPA Form 3320-1 (REV 3199) Prevtous editions may be used Page 1 of 2
DMR Attachment CCW Data CCWTRENCH Extractable Petroleum Date/Time Collected Hydrocarbons Analysis Date/Time Analyst Method No water would come out of the pump. No sample could be obtained. CCWCHANNEL Extractable Petroleum Date/Time Collected Hydrocarbons Analysis Date/Time Analyst Method 12/09/2009 @ 10 10 <0.10 mg/1 12/11/2009@ 0425 KMF EPH
Mean# of NOTES:% Mean# of Water Water SUB Sample Date %Settlers Sample Date Asiatic LOCATION Gravid Asiatic COLLECTED BY ZM/m3 Temp. ("C) Temp. ("C) LOCATION Clams/m3 Clam 11/03/2009 133 0 16 11/03/2009 76 16 In plant RCW CMW 11/10/2009 417 6.1 16 11/10/2009 25 16 In plant RCW CMW 11/17/2009 269 0 16 11/17/2009 0 16 In plant RCW CMW 11/24/2009 36 50 15 11/24/2009 18 15 In plant RCW CMW 12/01/2009 32 0 13.5 12/01/2009 0 13.5 In plant RCW WE 12/08/2009 38 0 11 12/08/2009 0 11 In plant RCW CMW
PERMITIEE NAME/ADDRESS (Include Facliltv Name/Location 1f 01fferent} NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPOESJ Form Approved MAJOR DISCHARGE MONITORING REPORT
===========
Name TVA- SEOUOYAH NUCLEAR PLANT (OMR) (SUBR 01) OMS No 2040-0004 M1g{e~-P::Q.:ioi~
---~~~~~u~~~L ______ _
F- FINAL
---~ID~~~rn>>~~------- DIFFUSER DISCHARGE a~~-~~~~~~~~~ro ____ _ EFFLUENT ~~~-~~N~~----------
ATTN: Stephanie A. Howard NO DISCHARGE . D ... NOTE* Read anstruclions before comoletma th1s form X PARAMETER QUANTITY OR LOADING QUALITY OR CONCENTRATION NO.* FREQUENCY SAMPLE EX OF TYPE AVERAGE UNITS ANALYSIS MAXIMUM UNITS MINIMUM AVERAGE MAXIMUM CHLORINE, TOTAL RESIDUAL SAMPLE MEASUREMENT
******** ******** .. ******** 0.015 0.025 19 0 12 I 31 GRAB 50060 1 0 0 PERMIT REQUIREMENT ******** ******** ..... ******** 0.10 0.10 MG/l WEEK- CALCTD EFFLUENT GROSS VALUE MOAVG INST MAX DAYS TEMPERATURE- C, RATE OF ICHANGE SAMPLE MEASUREMENT ******** 0 62 ******** ******** .. 0 I
31 I 31 CALCTD 82234 1 0 0 PERMIT *I ******** 2 DEG ******** ******** ******* .... CONTIN CALC TO REQUIREMENT !EFFLUENT GROSS VALUE DAILY MX C/HR uous SAMPLE I MEASUREMENT I I I PERMIT REQUIREMENT
~
SAMPLE MEASUREMENT I PERMIT REQUIREMENT SAMPLE MEASUREMENT PERMIT ' REQUIREMENT SAMPLE MEASUREMENT I PERMIT REQUIREMENT
--1 SAMPLE MEASUREMENT Ii PERMIT REQUIREMENT ~w~G ~c1~ d NAME/TITLE PRINCIPAL EXECUTIVE OFFICER I Cert1fy under penally of law thai th1s document and all attachments were prepared under my TELEPHONE DATE d1rect1on or superv1s1on 1n accordance w*lh a system designed to assure that quahf1ed personnel Christopher R. Church properly gather and evaluate the information subm11ted Based on my mqwy of the person or persons who manage lhe system. or lhose persons directly responsible for gathenng the Environmental Manager SQN & WBN mformalion. the mformalion subm1tted 1s . to the best of my knowledge and belief. true. 423 843-7001 10 01 07 Sequayah Site Vice President accurate. and complete I am aware that there are Slgn1f1can1 penallies for submztllng false tnformalion. oncludzng the possobzltty of fone and ompflsonment for knowing vzolahons SIGNATURE OF PRINCIPAL EXECUTIVE I J ~~~I OFFICER OR AUTHORIZED AGENT NUMBER YEAR MO DAY TYPED OR PRINTED COMMENTS AND EXPLANATION OF ANY VIOLATIONS tReference all attachments he!
EPA Form 3320-1 (REV 3/99) Previous ed1t1ons may be used Page 2 of 2
PERMITTEE NAME/ADDRESS (Include Fac111tv Name/Location 1f Different) NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPDESJ MAJOR Form Approved DISCHARGE MONITORING REPORT (DMRJ
===========
Name TVA- SEOUOYAH NUCLEAR PLANT (SUBR 01) OMB No 2040-0004 ~~e~ -P:Q.~oj)~=
!INTEROFFICE SB*2A*SONI F- FINAL
SODID=~~W~~~====
~~~-~~~~~~~~~~ID ____ _ PERMIT DIFFUSER DISCHARGE .bQ~tiQ_ ~118.MJJ,TQ.N~QY~- _ _ _ _ _ _ *_ _ _ EFFLUENT
*** NO DISCHARGE D ...
ATIN: Stephanie A. Howard NOTE: Read 1nstruct1ons before comoletlnQ th1s form. C>< PARAMETER QUANTITY OR LOADINCi QUALITY OR CONCENTRATION NO. FREQUENCY SAMPLE EX OF TYPE AVERAGE MAXIMUM UNITS MINIMUM AVERAGE MAXIMUM UNITS ANALYSIS BORON, TOTAL SAMPLE MEASUREMENT
******** ******** .. <0.20 19 0 1 I 92 01022 1 0 0 .*PERMIT REQUIREMENT ******** '******** .... *******' REPORT ******* MG/L QTRLY GRAB EFFLUENT GROSS VALUE SAMPLE MEASUREMENT I
PERMIT REQUIREMENT SAMPLE MEASUREMENT I PERMIT ! REQUIREMENT SAMPLE MEASUREMENT PERMIT REQUIREMENT SAMPLE MEASUREMENT PERMJT REQUIREMENT SAMPLE MEASUREMENT PERMIT '
- REQUIREMENT SAMPLE i I MEASUREMENT I PERMIT REQUIREMENT I*
NAME/TITLE PRINCIPAL EXECUTIVE OFFICER I Cert1fy under penalty of law lhallh1s documenl and all anachments were prepared under my ltctVL,Ll GKLh'(AJ(C*\ d TELEPHONE DATE d1rec11on or supervis1on 10 accordance w1th a syslem des1gned to assure lhat Quahf1ed personnel I Christopher R. Church properly gather and evaluate lhe mformahon subm11ted Based on my inqUify of lhe person or persons who manage the system. or those persons d~rectly responstble for gatherrng the Environmental Manager SON & WBN
.nformahon. the informahon subm1t1ed 1S. to lhe besl of my knowledge and bel*ef. lrue. 423 843-7001 10 01 07 Sequoyah Site Vice President accurate. and complete I am aware that lhere are Slgntftcant penalties for submtttmg false SIGNATURE OF PRINCIPAL EXECUTIVE I TYPED OR PRINTED mformalton. tncludsng the posstbshty of fsne and tmpnsonment for knowtng v*olahons OFFICER OR AUTHORIZED ACiENT AREA rnm:
I NUMBER YEAR MO DAY COMMENTS AND EXPLANATION OF ANY VIOLATIONS fReference all attachments he! Boron was sampled on 10/07/2009@ 1237. EPA Form 3320*1 (REV 3/99) Prewous edittons may be used Page 1 of 1
PERMITTEE NAME/ADDRESS (Include Fac111tv Name!Locat1on 1f 01fferentJ NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPOESJ MAJOR Form Approved Name TVA- SEOUOYAH NUCLEAR PLANT DISCHARGE MONITORING REPORT (DMRJ OMB No 2040-0004 &t~e~ -P::Q.iox~ =========== UNTEROFFJCE SB-2A-SQNI 4 50
~-p-~-~-~...;.~-~..;..~-M....e-ER---lll DISCHARG:~~M:ER I (SUBR 01)
F- FINAL
~ID~~~rn2~~====
~~~-~~~~~~~~~ID ____ _ BIOMONITORING FOR OUTFALL 101 I YEAR MP p:,RING "if~~t MO EFFLUENT ~~~-~~m~~~---------- QAY 31
... NO DISCHARGE D ...
ATTN: Stephanie A. Howard NOTE* Read instructions before com oleMa th1s form X PARAMETER QUANTITY OR LOADING QUALITY OR CONCENTRATION NO. FREQUENCY SAMPLE EX OF TYPE AVERAGE MAXIMUM UNITS MINIMUM AVERAGE MAXIMUM UNITS ANALYSIS IC25 STATRE 7DAY CHR SAMPLE MEASUREMENT
******** ******** .. Monitoring ******** ********
23 CERIODAPHNIA TRP3B 1 0 0 PERMIT REQUIREMENT
******** ******** .... Not Required 45~2 ******** ***'***** PERCENT SEE COMPOS EFFLUENT GROSS VALUE MINIMUM* PERMIT IC25 STATRE 7DAY CHR PIMEPHALES SAMPLE MEASUREMENT ******** ******** .. Monitoring ******** ********
23 II TRP6C 1 0 0 PERMIT REQUIREMENT
******** ******** .... Not Required 45~2 ****'**** *******'* PERCENT SEE COMPOS EFFLUENT GROSS VALUE MIMINUM PERMIT SAMPLE i I MEASUREMENT PERMJT REQUIREMENT SAMPLE MEASUREMENT PERMIT ****
REQUIREMENT SAMPLE I MEASUREMENT PERMIT* REQUIREMENT SAMPLE MEASUREMENT PERMIT . REQUIREMENT ~ SAMPLE MEASUREMENT PERMIT REQUiREMENT
~OJW:_ (j r&'WOA d NAME/TITLE PRINCIPAL EXECUTIVE OFFICER I Certify under penalty of law thatth1s document and all attachments were prepared under my TELEPHONE DATE d1rec11on or supervision 1n accordance w1th a system des1gned to assure that quahf1ed personnel Christopher R Church properly gather and evaluate the mformahon submztted Based on my tnqutry or the person or persons who manage the system. or those persons dzrectly responstble for gathenng the Environmental Manager SON & WBN 423 843-7001 10 01 07 tn1ormahon. the tnformahon submstted 1s . to the best of my knowledge and behef. true.
Sequoyah Site Vice President accurate, and complete I am aware lhat there are stgntftcant penalhes for submztltng false tn1ormallon. mcludzng the posstblhty or f1ne and impnsonment for know1ng v1olahons SIGNATURE OF PRINCIPAL EXECUTIVE I
~~~~ I MO OFFICER OR AUTHORIZED AGENT NUMBER YEAR DAY TYPED OR PRINTED COMMENTS AND EXPLANATION OF ANY VIOLATIONS tReference all attachments hel Toxicity was not sampled in December 2009. Report from November 2009 toxicity sampling is attached.
EPA Form 3320-1 (REV 3199) Prev1ous editions may be used
- Page 1 of 1
December 10,2009 Ruth Ann Hurt, SB 2A-SQN SEQUOY AH NUCLEAR PLANT (SQN) TOXICITY BIOMONITORING, NPDES PERMIT NO. TN002~450, COMPLIANCE TOXICITY TESTS, NOVEMBER, 2009 Per your request, I am only submitting an electronic copy of the subject report. The report provides results of compliance testing using fathead minnows and daphnids. Outfall I 0 I, samples collected November I5-20, showed no toxic effects to fathead minnows or daphnids. The resulting IC 25 values for both species were > I 00 percent. Exposure of fathead minnows and daphnids to intake samples resulted in no significant differences from controls during this study period. Fathead minnows were also exposed to UV treated Outfall I 0 I and intake samples since fish pathogens present in intake water have been the suspected cause of interference (anomalous dose response and high variability among replicates) in previous toxicity testing at Sequoyah. Call me at (256) 386-2755 if you have any questions or cotnments following your review of the report. Cynthia L. Russell Biologist Environmental Engineering Services- West CEB 3A-M Attachment cc (Attachment): Sherrard, R. M., PSC I X-C Files, OE&R, CEB IB-M SQN November 2009M
TENNESSEE VALLEY AUTHORITY TOXICITY TEST REPORT INTRODUCTION I EXECUTIVE
SUMMARY
Report Date: December 10. 2009 I. Facility I Discharger: Sequoyah Nuclear Plant I TV A
- 2. County I State: Hamilton I Tennessee
- 3. NPDES Permit #: TN0026450
- 4. Type of Facility: Nuclear-Fueled Electric Generating Plant
- 5. Design Flow (MGD): I .579
- 6. Receiving Stream: Tennessee River (TRM 483.6)
- 7. 1Q10: 3.49I
- 8. Outfall Tested: 101
- 9. Dates Sampled: November 15-20. 2009
- 10. Average Flow on Days Sampled (MGD): 870. 873. 1761 I1. Pertinent Site Conditi.ons: Production I operation data will be provided upon request.
- 12. Test Dates: November I7 -24. 2009
- 13. Test Type: Short-term Chronic Definitive I4. Test Species: Fathead Minnows (Pimepholes promelos)
Daphnids (Ceriodophnio dubio) I5. Concentrations*Tested (%): Outfall 101: 11.3. 22.6. 45.2. 72.6. 100 Intake: 100.0 Pimepho/es promelos: UV treated OutfalllOl: Il.3. 22.6. 45.2. 72.6. 100 UV treated Intake: 100.0 I6. Permit Limit Endpoint (%): Outfall I 01: ICzs =45.2%
- 17. Test Results: Outfall 101: Pimepholespromelos: ICzs > 100%
Ceriodophnio dubio: IC2s > 100% UV treated Outfall101: Pimepholes prome/os: IC£5 > 100% Page 1 of 102
- 18. Facility
Contact:
Ann Hurt Phone #: (423) 843-6714
- 19. Consulting I Testing Lab: Environmental Testing Solutions. Inc.
- 20. Lab
Contact:
Jim Sumner Phone #: (828) 350-9364
- 21. TV A
Contact:
Cynthia L. Russell Phone#: (256) 386-2755
- 22. Notes: Outfall 101 samples collected November 15 - 20, 2009.. showed no toxic effects to fathead minnows or daphnids. The resulting IC 25 values, for both species, were > 100 percent. Exposure of minnows and daphnids to intake samples resulted in no significant difference from the controls during this study period.
Fathead minnows were also exposed to UV treated Outfall 101 and intake samples since fish pathogens present in intake water have been the suspected cause of interference (anomalous dose response and high variability among replicates) in previous toxicity testing at Sequoyah. Page 2 ofl02
METHODS
SUMMARY
Samples: I. Sampling Point: Outfall 101. Intake
- 2. Sample Type: Composite
- 3. Sample Information:
Date Date Date (MM-DD-YY) (MM-00-YY) Arrival Initial (MM-DD-YY) Sample Time (ET) Time (ET) Temp ..t TRC* Time (ET) ID Collected Received (oC) (mg/L) Last Used By 11-15-09 0944 to 11-1 7-09 1500 101 11-17-09 1315 0.6, 0.7 <0.10 11-16-09 0844 11-18-09 1413 11-15-09 1014 to 11-17-09 1500 Intake 11-17-09 1315 1.1 <0.10 11-16-09 0914 11-18-09 1413 11-17-09 0745 to 11-19-09 1400 101 11-18-09 1505 1.3. 1.4 <0.10 11-18-09 0645 11-20-09 1411 11-1 7-09 0805 to 11-19-09 1400 Intake 11-18-09 1505 0.7 <0.10 11-18-09 0705 11-20-09 1411 11-20-09 1405 11-19-09 0735 to 101 11-20-09 1440 0.8, 0.9 <0.10 11-21-09 14 18 11-20-09 0635 11-22-09 1410 11-20-09 1405 11-19-09 0756 to Intake
- 11-20-09 1440 1.0 <0.10 11-21-09 1418 11-2.0-09 0656 11-22-09 1410
*TRC = Total Residual Chlorine 1
Samples were collected in two 2.5 gallon cubitainers. Temperature was measured in each cubitainer upon arrival. .4. Sample Manipulation: Samples from Outfall 101 and intake were warmed to test temperature (25.0 + 1.0°C) in a warm water bath. Aliquots of Outfall 101 and Intake samples were UV -treated through a 40-watt Smart UV Sterilizer (manufactured by Emperor Aquatics. Inc.) for 2 minutes. Page 3 of 102
Pimephales promelas Ceriodaphnia dubia Test Organisms:
- 1. Source: Aquatox. Inc. In-house Cultures
- 2. Age: 22.50-22.73 hours old <24-hours old Test Method Summary:
- 1. Test Conditions: Static. Renewal Static. Renewal
- 2. Test Duration: Until at least 60% of control females have 3 broods
- 3. Control I Dilution Water: Moderately Hard Synthetic Moderately Hard Synthetic
- 4. Number of Replicates: 1
- 5. Organisms per Replicate: lQ 1
- 6. Test Initiation: (Date/Time)
OutfalllOl 11-17-09 1444 ET I1-1 7-09 1500 ET UV Treated Outfall 101 11-1 7-09 14 30 ET
- 7. Test Termination: (Date/Time)
Outfall 101 11-24-09.1346 ET 1I-24-09 1402 ET UV Treated Outfall 101 11-24-09 1331 ET
- 8. Test Temperature: Outfall I 0 I: Mean= 24.8°C Mean = 24.9°C (24 .5 - 25.3°C} (24.6 - 25.3°C}
Test Temperature: UV-Treated Outfall 10 I: Mean= 24.9~C (24.5 - 25.3°C)
- 9. Physical I Chemical Measurements: Alkalinity. hardness. total residual chlorine. and conductivity were measured at the laboratory in each 100% sample. Daily temperatures were measured in one replicate for each test concentration. Pre- and post-exposure test solutions were analyzed daily for pH and dissolved oxygen.
- 10. Statistics: Statistics were performed according to methods prescribed by EPA using ToxCalc version 5.0 statistical software (Tidepool Scientific Software. McKinneyville. CA}.
Page4 ofl02
TOXICITY TEST RESULTS (see Appendix C for Bench Sheets)
- 1. Results of a Pimephales promelas Chronic! 7-day Toxicity Test.
(Genus species) (Type I Duration) Conducted November 17 - 24. 2009 using effluent from Outfall 101. Test Percent Surviving Solutions (lime interval used -days) (% Effluent) 1 2 3 4 5 6 7 Control 100 100 100 100 100 100 100 11.3% 100 100 100 100 100 100 100 22.6% 100 100 100 100 100 100 100 45.2% 100 100 100 98 98 98 98 72.6% 100 100 100 100 100 100 100 100.0% 100 100 100 100 100 100 100 Intake 100 100 100 98 90 88 88 Mean Dry Weight (mg) Test Solutions (replicate number) (% Effluent) 1 2 3 4 Mean Control 0.830 0.817 0.842 0.797 0.822 11.3% 0.857 0.820 0.819 0.839 0.834 22.6% . 0.849 0.792 0.794 0.884 0.830 45.2% 0.782 0.832 0.849 0.772 0.809 72.6% 0.806 0.758 0.770 0.781 0.779 100.0% 0.852 0.792 0.697 0.716 0.764 Intake 0.397 0.778 0.801 0.889 0.716 ICzs Value: > 100% Calculated TU Estimates: < 1.0 TUc* Permit Limit: 45.2% Permit Limit: 2.2 TUc 95% Confidence Limits: Upper Limit: NA Lower Limit: NA
*TUa = 100/LCso: TUc = 100/ ICzs Page 5 of 102
TOXICITY TEST RESULTS (see Appendix C for Bench Sheets)
- 2. Results of a Ceriodaphnia dubio Chronic/ 7-day Toxicity Test.
(Genus species) (Type I Duration) Conducted November 17 - 24. 2009 using effluent from Outfall 101. Percent Surviving Test (time interval used- days) Solutions 1 2 3 4 5 6 7 (% Effluent) Control 100 100 100 100 100 100 100 11.3% 100 100 100 100 100 100 100 22.6% 100 100 100 100 100 100 100 45.2% 100 100 100 100 100 100 100 72.6% 100 100 100 100 100 100 100 100.0% 100 100 100 100 100 100 100 Reproduction (#young/female/6 days) Test Solutions Data (replicate number) (% Effluent) 1 2 3 4 5 6 7 8 9 10 Mean Control 32 29 26 30 27 30 28 29 31 33 29.5 11.3% 32 31 28 31 30 30 30 28 29 33 30.2 22.6% 32 32 29 32 32 32 32 32 32 34 31.9 45.2% 33 34 33 31 32 36 30 34 33 32 32.8 7~.6% 33 34 34 32 37 33 38 34 30 32 .33.7 100.0% 35 36 32 36 34 36 38 36 38 38 35.9 ICzs Value: > 100% Calculated TU Estimates: < 1.0 TUc* Permit Limit: 45.2% Permit Limit: 2.2*TUc 95% Confidence Limits: Upper Limit: NA Lower Limit: NA
*TUa = 100/LCso: TUc = 100/ ICzs Page 6 of 102
TOXICITY TEST RESULTS (see Appendix C for Bench Sheets)
- 2. Results of a Ceriodaphnia dubia Chronic/ 7-day Toxicity Test.
(Genus species) (Type I Duration) Conducted November 17 - 24, 2009 using water from Intake Percent Surviving Test (time interval used - days) Solutions (% Effluent) 1 2 3 4 5 6 7 Control 100 100 100 100 100 100 100 Intake 100 100 100 100 100 100 100 Reproduction (#young/female/6 days) Test Solutions Data (re_Q_licate number) (%Effluent) 1 2 3 4 5 6 7 8 9 10 Mean Control 31* 27 30 32 28 30 31 30 31 28 29.8 Intake 38 35 33 30 29 . 33 32 31 31 33 32.5 ICzs Value: > 100% Calculated TU Estimates: < 1.0 TUc* Permit Limit: N/A Permit Limit: N/A 95% Confidence Limits: Upper Limit: NA Lower Limit: NA
*TUa = I 00/LCso: TUc = 100/ ICzs Page 7 of 102
TOXICITY TEST RESUL TSI UV-TREATED (see Appendix C for Bench Sheets)
- 3. Results of a Pimephales promelas Chronic/ 7-day Toxicity Test.
(Genus species) (Type I Duration) Conducted November 17 - 24 I 2009 using effluent from UV Treated Outfall 101. Test Percent Surviving Solutions (time interval used - day_s) (%Effluent) 1 2 3 4 5 6 7 Control 100 100 100 100 100 100 100 11.3% 100 100 100 100 100 98 98 22.6% 100 100 100 100 100 100 100 45.2% 100 100 100 100 100 100 100 72.6% 100 100 100 100 100 100 100 100.0% 100 100 100 100 100 100 100 Intake 100 100 100 100 100 100 100 Mean Dry Weight (mg) Test Solutions (replicate number) (%Effluent) 1 2 3 4 Mean Control 0.848 0.718 0.772 0.870 0.802 11.3% 0.876 0.857 0.764 0.755 . 0.813 22.6% 0.749 0.796 0.854 0.806 0.801 45.2% .0.724 0.816 0.825 0.865 0.808 72.6% 0.890 0.775 0.856 0.814 0.834 100.0% 0.775 0.757 0.939 0.867 0.835 Intake 0.813 0.726 0.780 0.770 0.772 IC2s Value: > 100% Calculated TU Estimates: < 1.0 TUc* 95% Confidence Limits: Upper Limit: NA Lower Limit: NA
*TUa = 100/LCso: TUc = 100/ IC2s REFERENCE TOXICANT TEST RESULTS (see Appendix A and D)
SQ_ecies Date Time Duration Toxicant Results (I C2sJ Pimephales promelas November 17-24, 2009 1220 7-days KCI 0.79 g/L Ceriodaphnia dubia November 10-17 I 2009 1115 6-days NaCl 1.07 giL Page 8 of 102
PHYSICAUCHEMICAL
SUMMARY
Water CliemistryMean Values and Ranges for Pimephales prome/as and Ceriodaph~ia dubia Tests. Non-treated Sequoyah Nuck!ar Plant {SQN) OutfaU 101 perfonred Noveni>er 17-24.2009. Test Sample ID Temperature tc> Dissolved Ox_yg_en (mg/L) pH (S.U.) Conductance Alkalinity Hardness Total Residual Initial Final Initial Final Initial Final {J.lmhos/cm) (mg/L CaC03 ) (mg/L CaCOJ) Chlorine (mg/L) 24.8 24.7 7.8 7.4 7.58 7.37 332 62 90 Control 24.7 - 24.8 24.6 - 24.8 7.6 8.0 6.9 7.7 7.42 . 7.79 7.20 -. 7.56 325 336 61 62 88 90 24.8 24.7 7.9 7.3 7.66 7.32 308 11.3% II: 24.7 - 25.0 24.5 - 24.9 7.7 8.2 6.9 7.6 7.57 7.79 7.15 - 7.50 297 317
.$! 24.9 24.8 8.0 7.1 7.63 7.29 291 ~
E 22.6% 24.7 - 25.0 24.6 - 25.0 7.8 8.2 6.3 - 7.6 7.53 - 7.74 7.11 - 7.50 280 *- 299 e
~ 24.9 24.8 8.0 7.1 7.61 7.29 256 II: 45.2% ~ 24 7 - 25.1 24.6 - 25.0 7.7 8.2 6.4 - . 7.7 7.47 - 7.73 7.14 - 7.51 249 266 ~ ..:::: 24.9 24.7 8.1 7.2 7.57 7.28 218 ~ 72.6% .§ 24.7 - 25.1 24.5 . 24.9 7.7 8.3 6.6 7.8 7.41 7.70 7.04 - 7.51 211 - 225 ~ 7.2 7.52 25.0 24.7 8.1 7.25 172 75 87 < 0.10 100.0%
24.7 . 25.3 24.5 - 25.1 7.7 8.3 6.5 1.7 7.32 . 7.67 7.01 7.46 166 181 62 96 69 110 < 0.10 . < 0 10 24.9 24.7 8.2 7.2 7.49 7.24 170 63 75 < 0.10 Intake 24.8 - 25.0 24.6 - 25.1 7.8 8.4 6.5 7.9 7.26 - 7.64 7.01 7.49 163 179 58 66 69 82 < 0.10 - < 0.10 24.8 25.0 7.8 7.9 7.58 7.59 332 62 90 Control 24.6 - 24.9 24.9 . 253 7.6 8.0 7.7 8.1 7.42 - 7.79 7.51 7.71 325 336 61 62 88 90 24.8 25.0 7.9 7.9 7.66 7.59 309 11.3% 24.7 - 24.9 24.9 . 25.2 7.7 8.2 7.6 8.1 7.57 - 7.79 7.52 - 7.71 297 317 -
.$! 25.0 7.9 7.63 7.59 291 oC'.l 24.9 8.0 .; 22.6%
24.7 - 25.0 25.0 - 25.1 7.8 8.2 7.5 8.1 7.53 - 7.74 7.52 - 7.71 .280 *- 299
-5! 24.9 25.0 8.0 7.9 7.61 7.58 256 r:: 45.2% .a:: 24.7 - 25.0 24.9 . 25.2 7.7 8.2 7.6 8.2 7.47 . 7.73 7.51 7.71 249 266 ~ "'::i 24.9 24.9 8.1 7.9 7.57 7.57 218 -~ 72.6%
24.8 - 25.0 24.8 - 25.1 7.7 8.3 7.6 8.2 7.41 7.70 7.48 . 7.69 211 -. 225 t:> 7.9 7.52 7.55 172 25.0 25.0 8.1 75 87 < 0.10 100.0% 24.8 : 25.2 24.8 - 25.2 7.7 8.3 7.6 8.2 7.32 - 7.67 7.46 - 7.66 166 181 62 96 69 110 < 0.10 - < 0.10 25.0 25.0 8.2 7.9 7.49 7.56 170 63 75 < 0.10 Intake 24.9 - 25.0 24.8 - 25.2 7.8 8.4 7.6 8.1 7.26 - 7.64 7.46 - 7.66 163 179 58 66 69 82 < 0.10 . < 0.10 OveraU temperature \C) Average Minimum Maximum Pimephales promelas 24.8 24.5 25.3 Ceriodaphnia dubia 24.9 24.6 25.3 Page 9 of102
PHYSICAUCHEMICAL
SUMMARY
Water Chemistry Mean Values and Ranges for Pimephales promelas Tests. UV-treated Sequoyah Nuclear Plant (SQN) OutfalllOI performed November 17-24. 2009. Test Sample ID Temperature ('C) Dissolved Oxygen (mg!L) pH (S.U.) Conductance Alkalinity Hardness Initial Final Initial Final Initial Final (f.lmhos/cm) (mg/L CaC03) (mg/L CaC03 ) 24.8 24.8 8.0 7.3 7.61 7.35 321 61 89 Control 24.7 - 25.0 24.7 - 24.9 7.9 - 8.2 6.4 - 8.1 7.53 - 7.68 7.19 - 7.53 312 - 332 61 62 86 90 24.9 24.8 7.9 7.3 7.62 7.33 308 11.3°/o 24.8 - 25.1 24.6 - 25.0 7.7 - 8.0 6.9 7.6 7.54 - 7.68 7.16 - 7.51 301 312
.s:"' ~
24.9 24.7 7.9 7.3 7.61 7.33 293 i: 22.6°/o
~
24.8 - 25.1 24.6 - 24.9. 7.8 - 8.1 7.1 - 7.7 7.53 - 7.69 7.16 - 7.52 290 - 299
~ 25.0 24.8 8.0 7.3 7.59 7.31 265 ~c:s 45.2°/o 24.8 - 25.2 24.7 - 24.8 7.9 - 8.1 7.0 - 7.7 7.49 - 7.68 7.15 - 7.49 259 - 273 -=: 25.0 24.8 8.0 7.2 7.55 7.30 218 .s~ ~
72.6°/o 24.8 - 25.2 24.6 - 25.0 7.8 - 8.1 6.8 7.7 7.43 - 7.65 7.11 7.48 214 - 223 25.1 24.8 8.0 7.3 7.51 7.28 173 63 74 100.0°/o 24.9 - 25.3 24.7 - 24.9 8.0 - 8.2 6.9 7.8 7.37 - 7.62 7.09 - 7.47 169 - 181 58 68 65 - 78 25.0 24.7 8.1 7.3 7.51 7.26 171 63 72 Intake 24.9 - 25.2 24.5 - 24.8 8.0 8.3 6.9 - 7.8 7.37 - 7.61 7.07 - 7.47 160 - 189 60 - 66 69 78 Overall temperature (C) Average Minimum Maximum Pimephales promelas 24.9 24.5 25.3 Page 10 of 102
SUMMARY
I CONCLUSIONS Outfall lOt samples collected November 15-20. 2009, showed no toxic effects to fathead minnows or daphnids. The resulting ICz 5 values. for both species. were
> 100 percent. Exposure of minnows and daphnids to intake samples resulted in no significant difference from the controls during this study period.
Fathead minnows were also exposed to UV treated Outfall 101 and intake samples since fish pathogens present in intake water have been the suspected cause of interference (anomalous dose response and high variability among replicates) in previous toxicity testing at . Sequoyah. At the time this study was conducted, insignificant mortality occurred in minnows exposed to non-treated and UV treated samples. Page 11 of 102
Appendix A ADDITIONAL TOXICITY TEST INFORMATION
SUMMARY
OF METHODS
- 1. Pimephales promelas Tests were conducted according to EPA~821-R-02-013 (October 2002) using four replicates, each containing ten test organisms, per treatment. Test vessels consisted of 500-mL plastic disposable cups, each containing 250-mL of test solution.
- 2. Ceriodaphnia dubia Tests were conducted according to EPA-821-R-02-013 (October 2002) using ten replicates, each containing one test organism, per treatment. Test vessels consisted of 30-mL polypropylene cups, each containing 15-mL of test solution.
DEVIATIONS I MODIFICATIONS TO TEST PROTOCOL
- 1. Pimephales promelas None
- 2. Ceriodaphnia dubia None DEVIATIONS I MODIFICATIONS TO PRETEST CULTURE OR HOLDING OF TEST ORGANISMS
- 1. Pimephales promelas None
- 2. Ceriodaphnia dubia None Page 12 of 102
PHYSICAL AND CHEMICAL METHODS
- 1. Reagents, Titrants, Buffers. etc.: All chemicals were certified products used before expiration dates (where applicable).
- 2. Instruments: All identification. service, and caiibration information pertaining to laboratory instruments is recorded in calibration and maintenance logbooks.
- 3. Temperature was measured by SM 2550 B.
- 4. Dissolved oxygen was measured by SM 4500 0 G.
- 5. The pH was measured by SM 4500 H+ B.
- 6. Conductance was measured by SM 2510 B.
- 7. Alkalinity was measured by SM 2320 B.
- 8. Total hardness was measured by SM 2340 C.
- 9. Total residual chlorine was measured by ORION Electrode Method 97-70.
QUALITY ASSURANCE Toxicity Test Methods: All phases of the study including. but not limited to, sample collection. handling and storage. glassware preparation. test organism culturing/acquisition and acclimation. test organism handling during test. and maintaining appropriate test conditions were conducted according to the protocol as described in this report and EPA-821-R-02-013. Any known deviations were noted during the study and are reported herein. REFERENCE TOXICANT TESTS (See Appendix D for control chart information)
- 1. Test Type: 7-day chronic tests with results expressed as IC 2s values in g/L KCl or NaCI.
- 2. Standard Toxicant: Potassium Chloride (KCl crystalline) for Pimephales promelas.
Sodium Chloride (NaCl crystalline) for Ceriodaphnia dubia.
- 3. Dilution Water Used: Moderately hard synthetic water.
- 4. Statistics: ToxCalc software Version 5.0 was used for statistical analyses.
Page 13 of 102
REFERENCES
- 1. NPDES Permit No. TN0026450.
- 2. USEPA. Short-Term Methods for Estimating the Chronic Toxicity of Effluents and Receiving Watersto Freshwater Organisms. EPA-821-R-02-013 (October 2002).
- 3. Standard Methods for the Examination of Water and Wastewater. 21st Edition, 2005.
- 4. Quality Assurance Program: Standard Operating Procedures. Environmental Testing Solutions, Inc (most current version).
Page 14 of 102
Sequoyah Nuclear Plant Biomonitoring November 17 - 24. 2009 Appendix B Diffuser Discharge Concentrations of Total Residual Chlorine, Diffuser Discharge Concentrations of Chemicals Used to Control Microbiologically Induced Corrosion and Mollusks
.During Toxicity Test Sampling
~age 15 oj'l02
Table B-1. Sequoyah Nuclear Plant Diffuser (Outfall 10 1) Discharge Concentrations of Chemicals Used to Control Microbiologically Induced Corrosion Mollusks, During Toxicity Test Sampling, March 12, 1998 - November 20, 2009 Date PCL-401 mg/L Copolymer 03/12/1998 03/13/1998 03/14/1998 03/15/1998 03/16/1998 03/17/1998 03/18/1998 09/08/1998 0.005 09/09/1998 0.011 09/10/1998 0.021 09/11/1998 0.019 09/12/1998 0.015 09/13/1998 0.015 09/14/1998 0.015 02/22/1999 02/23/1999 02/24/1999 02/25/1999 : 02/26/1999 02/27/1999 02/28/1999 08/18/1999 0.024 08/19/1999 0.024 08/20/1999 0.024 08/21/1999 0:024 08/22/1999 0.024 08/23/1999 0.024 08/24/1999 0.023 Page 16 of 102
Table B-1. Sequoyah Nuclear Plant Diffuser (Outfall 10 1) Discharge Concentrations of Chemicals Used to Control Microbiologically Induced Corrosion Mollusks. During Toxicity Test Sampling, March 12. 1998 - November 20, 2009 Date *. Sodium.' ~~*** Hypochlorite... Towerbrom ****PCL;.222.** mg/L rrtg/L.
- PCL-401 mg/L CL0::363:,
*.itlgtL'* Ii~WL~~
mg/L TRC . Phosph;ate Copolymer DMAD Q~~t
*....TRC 01/31/2000 < 0.002 0.026' 0.009 02/01/2000 0.011 0.026 0.028 02/02/2000 0.028 0.026 0.009 02/03/2000 0.008 0.621 *. 0.009 02/04/2000 0.006 *o.oi1
- 0.009 02/05/2000 < 0.002 O.Q27 0.009 02/06/2000 < 0.002 0~027**. 0.009 07/26/2000 *0;0~5,.::,_ 0.019 07/27/2000 o.Q~s:*. 0.019 07/28/2000 .* 0.053 ': 0.018 07/29/2000 *o~9"s$.:;~ ~* 0.019
****Q~~IF.;:.
07/30/2000 0.019 07/31/2000 0.019 08/0112000
- OiOS5*.*> . 0.019 12/1112000 <tQa5g<*** 0.020 12/12/2000 cLo25.*::*.* 0.020' 12/13/2000 ojo2s-***. 0.020 *~'~:~*-; ~-
12/14/2000 Oi6i5:**~*** 0.020 12/15/2000 o~ozs>~., '* 0.020 12/16/2000 : 6.625 *~** .. 0.020 12/17/2000 o.ozs:*.:* 0.020
- ~,~1}
(t06\:-:** 08/26/2001 08/27/2001 o. o§.*~*;* 0.021 0.021 .~ g:&g~:::* 0.06**.**: .. .;..:..:
]i~~;,
- .. ~~
08/28/2001 0.021 08/29/2001 o:osg: ... 0.020 *o.oo5. 08/30/2001 ~ow~*:_:.*:* 0.021 .O;Dp~~;;!.
- 08/31/2001 0.020 11/25/2001 <0.0044 -
11126/2001 <0.0119 0.02 11/27/2001 0.0137 0.019 11128/2001 <0.0089 0.019 11/29/2001 0.0132 0.02 11/30/2001 < 0.0043 0.02 12/09/2001 <0.0042 12/10/2001 <0.0042 -. 12/11/2001 <0.0104 - 12/12/2001 0.0128 0~024. 0.02 12/13/2001 <0.0088 . 0.024 0.02 ~. 12/14/2001 0.0134 0.024 0.02 0.007. Page 17 of 102
Table B-1. Sequoyah Nuclear Plant Diffuser (Outfall 101) Discharge Concentrations of Chemicals Used to Control Microbiologically Induced Corrosion Mollusks, During Toxicity Test Sampling. March 12, 1998- November 20, 2009 Date *Sodium* Towerbrom *PCV*222(:i'. PCL-401 . CL..363~ Cuprostat- H~l~30M Hypochlorite mg/L , *'* .mg!L (~: . mg/L frig/t .. PF '*fi)gik mg/L* TRC Phosphate:-:_ Copolymer ,DMAD mg/L Qua(
.TRC Azole 01102/2002 < 0.0079 0.02 01/03/2002 < 0.0042 0.014 -:.~,:*.
01/04/2002 - 0.0124 0.014 0.009~ 01/05/2002 < 0.0042 - 01/06/2002 < 0.0042 01/07/2002 < 0.0089 0.014 *:o]oos 02/24/2002 < 0.004
' '~
02/25/2002 < 0.004 0.023 '. 02/26/2002 0.0143 0.023 O~QQf
- .:;:.~~;).-
02/27/2002 < 0.0041 0.023 02/28/2002 < 0.0041 0.008 .;.: .....
' ":.:')<
03/01/2002 < 0.0041 0.008 * ~ -1. *.~* ;_ . , . , ... : __: '
.... **~.: :~.--~*.'::}-.~~.:::/;~~:~*;:*
- ~m~
05/05/2002 05/06/2002 0.02 05/07/2002 0.02 05/08/2002 0.019 ::":::/ 05/09/2002 0.02 05/10/2002 0.019 08/04/2002 <0.0058 08/05/2002 <0.0058 0.018 08/06/2002 0.0092 0.018 08/07/2002 <0.0107 0.019
'=~}; .**.
08/08/2002 <0.0061 0.019 . , ;7 -~* -. 08/09/2002 0.0152 0.018 10/06/2002 <0.00497 10/07/2002 10/08/2002 0.0153
<0.0092 0.018 0.018 **-d~db9:
o~9ot: :~ 10/09/2002 0.0124 0.018 0~009. 10/10/2002 0.0134 0.018 ' 0~009*.,'
- '\,-*t~t*:~*~:-,:>
10/11/2002 <0.0042 0.018 01/12/2003 <0.0035 01/13/2003 <0.006 0.019 01/14/2003 <0.0118 0.020 01/15/2003 <0.0063 0.020 01/16/2003 <0.0034 0.020 01/17/2003 <0.0034 0.009 04/06/2003 - ' <0.0073 04/07/2003 -. <0.0189 0.021 04/08/2003 <0.0117 0.021 04/09/2003 <0.0139 0.021 04/10/2003 <0.0113 0.021 04/11/2003 <0.0073 0.022 Page 18 of 102
Table B-1 (continued). Sequoyah Nuclear Plant Diffuser (Outfall 10 I) Discharge Concentrations of Chemicals Used to Control Growth of Microbiologically Induced Bacteria and Mollusks, During Toxicity Test Sampling, March 12, 1998 - November 20, 2009 Date **.*.*Sodium**. <:,; Towerbrom . PCLi222'* . . PCL-40 1 LCb*363: Cuprostat- f{:.t30.M Hypochlortt~
- mg/L *. mgli..: mg/L . IllWE :\ pF 'rtig/L...
.*. mg!L TRC Phosphat~* Copolymer DM~ mg/L _qu~~
TRC ,** . . . Azole
~~-~ ').;-*_~:-:) ~.
06/15/2003 06/16/2003 0.020 *.: o:o22 i:. 06/17/2003 0.014 *.o:o24-06/18/2003 0.014 .:d~QZ-4: 06/19/2003 06/20/2003 0.020 0.020
*g:g~~,*
08/03/2003 08/04/2003 *. 0;058 ,, . 0.020 08/05/2003 ; ().657 .*: 0.020 08/06/2003 . 0.057 0.020 08/07/2003 o.o.si.,* 0.020 08/08/2003 .~ ....Q~P"~~:::.* 0.020 10/05/2003 . ' 0.020 10/06/2003 0.020 10/07/2003 0.020 10/08/2003 0.020 10/09/2003 0.022 10/10/2003 0.024 02/01/2004 0.0093 : 0~027 0.009 02/02/2004 <0.0034 0.026 . 0.009 02/03/2004 - . <0.0034 0.02.9 .. 0.009 02/04/2004 0.0124 o:{)26 0.009 02/05/2004 <0.0034 . o:o2.s. 0.009 02/06/2004 0.0105 0.026. 0.009 05/04/2004 ...* . OX)26**. 0.019 05/05/2004 ... o.o26*.' 0.014 *:moo9.* 05/06/2004 * *oj)37*
- 0.013 05/07/2004 . 0.05,8. 0.020 o.oog:.
05/08/2004 o;oao:,
- 0.021
. . *>t::*...- .
05/09/2004 o:gs8
- 0.020 0.0217 0.05T 0.019 . **'---**
07/04/2004 07/05/2004 <0.0085 o*.Q&T . 0.020 07/06/2004 <0.0077 0.058' 0.020 o.Jsl-- 07/07/2004 0.0252 0.056 0.019 oJ)31 07/08/2004 0.0223 0~05l. 0.019 07/09/2004 0.0182 . ': 0~057 *: 0.020 Page 19 of 102
Table B-1. Sequoyah Nuclear Plant Diffuser (Outfall 10 1) Discharge Concentrations of Chemicals Used to Control Microbiologically Induced Corrosion Mollusks, During Toxicity Test Sampling, March 12, 1998 - November 20, 2009 Date Sodium ,;
- Towerbrom *PCV-222 *. PCL-40 1 HypocNorit mg/L , . mg!L. . mg/L e;,-.,.*_ . TRC Phosph~te. Copolymer mgll..,.
,,._ -~.**'tl(c~**~,
11107/2004 <0.0187 . 11/08/2004 <0.0192 11/09/2004 <0.0233 11/10/2004 <0.0149 11/1112004 <0.0149 11112/2004 <0.0253 02/06/2005 0210712005 02/08/2005 .* 02/09/2005 02/10/2005 02/11/2005 06/05/2005 06/06/2005 . 06/07/2005 06/08/2005 06/09/2005 06/10/2005 07/17/2005 07/18/2005 07/19/2005 07/20/2005 07/21/2005 07/22/2005 10/30/2005 10/31/2005 11101/2005 11102/2005 11/03/2005 11/04/2005 11/14/2005 11115/2005 11116/2005 11/17/2005 11/18/2005 11/19/2005 Page 20 of 102
Table B-1 (continued). Sequoyah Nuclear Plant Diffuser (Outfall 10 1) *Discharge Concentrations of Chemicals Used to Control Growth of Microbiologically Induced Bacteria and Mollusks, During Toxicity Test Sampling, March 12, 1998 - November 20, 2009 Date .* *;~1Sodiutn :' Towerbro * :PCL-222 :* PCL-401 ~:CCI>363*:. Cuprostat-PF H~l30M .H.if50Nt Hypochlorite mg/L mg!L mg/L .(*.: ingtL , mg/L t*;mR4.- ~-.. mg/L TRC . Phosphate Copolymer ::nMAD . Azole Qqah: *Qua~;:*
.'-.TRC 11/12/2006 11/13/2006 11/14/2006 11/15/2006 11/16/2006 11/17/2006 11/26/2006 11/27/2006 11/28/2006 11/29/2006 11/30/2006 12/01/2006 05/28/07 0.015 05/29/07 0.015 05/30/07 0.015 05/31/07 0.015 06/01/07 0.015 06/02/07 0.015 12/02/07 12/03/07 12/04/07 12/05/07 12/06/07 12/07/07 04/13/08 04/14/08 04/15/08 04/16/08 04/17/08 04/18/08 10/26/08 10/27/08 10/28/08 10/29/08 0.030 10/30/08 0.030 I 0/31/08 0.030 Page 21 of 102
Table B-1. Sequoyah Nuclear Plant Diffuser (Outfall 10 1) Discharge Concentrations of Chemicals Used to Control Microbiologically Induced Corrosion Mollusks, During Toxicity Test Sampling. March 12, 1998 -November 20, 2009 Sl,~ Date
~~~<*~.~ ~~: ;.:*
02/08/09 02/09/09 02/10/09 02/11/09 02/12/09 02/13/09 05/10/09 05/11/09 05/12/09 05/13/09 05/14/09 05/15/09 11115/09 11/16/09 .11/17/09 11/18/09 11119/09 11120/09 Page 22 of 102
Sequoyah Nuclear Plant Biomonitoring November 17 - 24, 2009 Appendix C Chain of Custody Records and Toxicity Test Bench Sheets Page 23 of 102
BIOMONITORING CHAIN OF CUSTODY RECORD Page __ J__ of __ l __ C?ilent: TV A Environmental Testing Solution, Inc. Delivered By (Circle One): ~ect Name: Sequoyah NP Toxicity 3 5 1 Depot Street. FedEx UPS Bus Client P~. Number: N/A Asheville, NC Other (specify): Express Courier Facility Sampled: Sequoyah NP 28801 General ~om.m ents: ~ - ~ Adam Detm lmg : -~ - -~ NPDES Number: TN 0026450 Phone: 828-350-9364 Stephen W iII iam s :-:;;
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Fax: 828-350-9368 Samples rem ained on ice thr o u&hout sampl ing and transpon to Collected By: Adam Deimling & Stephen Williams lab. Dissolved Meta ls sample fi ltered and place on ice. Field Identification I Grab/Comp Collection Datcf rimc Contai ner Flow PM.l se12 Sample Description Number& (MGD) Rain Event? f:l~ \ ~ Laboratory Use Volume (Mark as Appropriate) Coll ected c.; :.Otllll~.oV . \-\~(. .. .. \ . Date Time Yes lfYcs, Trace Time- ** .:'Appear* (mm/dd/yy) (Esn Inches ~ ance SQN-101-TOX A Comp 11 / 15/09 - 0944- I (2 .5gal) 11 / 16/09 0844 SQN- 101-TOX B Comp 11 / 15/09- 0944- I (2.5gal) 11 /16/09 0844 SQN-INT-TOX Comp 11 /1 5/09 10 14 . I (2.5 gal) NA 11116/09 09 14 Samp le Custody - Fill In From T op Down Relinquished By (S ignature): Date/Time Received By (Signature): Date/T im e
*.Jo e-r Express Courier ETS 131> "' 11-11-0 Instructions: Clients should fill in al l areas except those in the Laboratory Use" block. Biomonitoring samples are preserved by storing them at 6°C and shipping them in ice. The hold time for each sample is 36 hours from the time of collection. Therefore, please coll ect and ship in such a way that the laboratory will receive the samples with ample time to init iate testing within that time frame. Samples shipped overnight on Friday via FedEx or UPS must be marked for Saturday deli very or they wi ll not arri ve unti l the followi ng Monday.
BIOMONITORING CHAIN OF CUSTODY RECORD Page_J_ of_l_
- TVA Environmental Testing Solution, Inc. Deli vered By (C ircle One):
N P~ect Name: Sequoyah NP Toxicity 3 51 Depot Street. Fed Ex UPS Bus Client P ~* Number: N/ A Asheville, NC Other (specify): Express Courier 28801 GeneraiComments: ~~ Facility Sampled: Sequoyah NP Adam Deimling :
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NPDES Number: TN0026450 Phone: 828-350-9364 Jonathan Walker : 7 Fax: 828-350-9368 Samples remained on ice throughout sampling and transport to Collected By: Adam Deimling & Stephen Williams lab. Dissolved Metals sample filtered and place on ice. Field Identification I Grab/Comp Flow Collection Date!Timc Container Rain Event? Pf\0' ~*s6t2. Sample Description Number & (MGD) ~ Laboratory Use (Mark as Appropriate) If Yes, No Trace ETS Log Time * . Appear-Inches Number ~ ance SQN-101-TOX A Comp I I ll 7/09 - 0745 - I (2.5gal) I II 18/09 0645 812.78 O,i8 0';\1\0 .03 \% SQN-101-TOX B Comp 11117/09 - 0745- I (2.5gal) 11/18/09 0645 872.78 0.18 O"f\H 6-0.3 SQN-INT-TOX Comp 11 / 17/09 - 0805 - I (2.5 gal) NA (),18 O"J\\\B.o4 I Ill 8/09 0705 Relinquished By (Signature): Date/Time
~OY Express Courier Express Courier /3 l\ -tl-<ft ISOS L\- ~-M tSoS E\
Instructions: Clients should fill in all areas except those in the "Laboratory Use" block. Biomonitoring samples arc preserved by storing them at 6°C and shipping them in ice. The hold time fo r each sample is 36 hours from the time of collection. Therefore, please collect and ship in such a way that the laboratory will receive the samples with ample time to initiate testing within that time frame. Samples shipped overnight on Friday via Fed Ex or UPS must be marked for Saturday delivery or they will not ~ive until the following Monday.
BIOMONITORING CHAIN OF CUSTODY RECORD Page of CJ!fnt: TVA Environmental Testing Solution, Inc. Delivered By (Circle One): ~ect Name: Sequoyah NP Toxicity 351 Depot Street. Fed Ex UPS Bus Client P.~ Number: N/A Asheville, NC Other {specify): Express Courier 28801 General Comments: ~~ ........-,..._. Facility Sampled: Sequoyah NP NPDES Number: TN0026450 Phone: Fax: 828-350-9364 828-350-9368 Adrun De;mHng Stephen Willi~ms : < o ~~ Samples remamed on 1ce throughout sampling and transport to Collected By: Adam Deimling & Stephen Williams lab. Dissolved Metals sample filtered and place on ice. Field Identi fication I Gr'ab/Comp Collection Date/Time Container Flow Rain Event? PNU te:t4,: s~ tz.. Sample Description Number& (MGD) Volume Labomtory "qse (Mark as Appropriate) Collected Date Time Yes If Y~-s. Trace ETS Log By . Time Appear-(mm/ddlyy) (ESD Inches Number ET' ance SQN-101-TOX A Comp 11 /19/09 - 0735- 1 (2.5gal) I 1/20/09. 0635
/T6a i6 SQN-101-TOX B Comp 11119/09 - 0735- I (2.5gal) 11 /20/09 0635 1160.'16 SQN-rNT-TOX Comp 11119/09 - 0756- I (2.5 gal) NA 11/20/09 0656 Sample Custody - Fi ll ln From Top Down Relinquished By (Signature): Datenime Received By (Signature):
AdamDeirnling ~0 z:r- r I( a (J(5'-oc: Express Courier /] R UA / 1-Jo-o 7 E..T Express Courier tJIf!.~ tl-lD-o'\ fLJt-{0 E.\ Instructions: Clients should fill in all areas except those in the "Laboratory Usc" block. Biomonitoring samples arc preserved by storing them at 6°C and shipping them in icc. *n1c hold time for each sample is 36 hours from the time of collection. Therefore, please collect and ship in such a way that the laboratory wi ll receive the samples with ample time to initiate testing within that time frame. Samples shipped ovemight on Friday via FedEx or UPS must be marked for Saturday delivery or they will not arrive until the following Monday.
~ =ers i) .,, .. - . ,----..-
Envhonm1nU I T*nl no So luUon s. Inc. Page I of 6 Chronic Whole Effluent Toxicity Test (EPA-82 1-R-02-013 Method 1000.0) Species: Pimephales promelas Client: Tennessee Valley A uthority County: RfrJ .-\A~TON Facility: Seguoyab Nuclea r Plant O utfall: 101 NPDES #: =FN99~9le8 tl nJ OO'Zta'-l SO Project #: __ S..,§."-'\'-1-=------- Dilution preparation information: Comments: Dilution prep (%) II.J 22.6 45.2 72.6 100 Effluent volume (mL) 282.5 565 IIJO 1815 2500 Diluent volume (mL) 2217 5 1935 1370 685 0 Total volume (mL) 2500 2500 2500 2500 2500 Test Orf!anism information: Test information: Organism age: 1.1. ,,~ ~v'l!:. 0\..b Randomizing template: '(eu.o~ Date and times organisms \H\o*Cf\ \\cOO lncubator number and were born between: shelf location: 3(. Organ ism source: A\t:J1-. >A\'(\\ If \\-1\o*O'\ Artemia CHM number: ~'"'~'\'-\ Drying information for weight determination: Transfer bowl information: pH = '1.!:.0 S.U. Date I Time in oven: ill* 1.~*0'\ Temperature =~.1 °C lnitial oven temperature: L.~ *c.. Average transfer volume: Date I Time out of oven: i\*1.~04\ 1~0 o.1.~os~ Final oven tem_l)_erature: 1.,.0 *c. Total c!!Ying time: '"\-~ov.t; Daily feeding and renewal information: Day Date Morning feeding Afternoon feeding Test initiation, Sample numbers used MHSW batch I I I I i Page 27 of 102 SOP AT20- Exhibit AT20.3, revision 04-01-09
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*Ers ~ ~-: .:J EnvllonmenuiTutfnq Solutlont.lnc.
Page 2 of6 Species: Pimepha/es promelas U.. li*c:A I Client: TVA I Seguoyah Nuclear Plant. OutfalllOl. N~n-treated Survival and Growth Data Date: Day CONTROL Jl.J 0/o 22.6°/o I A Non-treated B c D E F G H I J K L 0 10 10 /Q 10 10 /0 /() 10 10 10 10 I 1 10 10 IQ 10 /Q 10 10 10 JO 10 10 /Q 10 2 I 3 10 liJ 10 JD 10 IQ 10 IO lO 10 10 10 JQ lO 10 ID "10
/0 /Q 10 /0 10 10 /T;j I 4 ~~ IC IC ID /0 10 10 10 10 10 10 tO s
10 10 to 10 10**
*~
LO /0 IQ /() IQ I{) II 6
)~ ~~ I() 10 IC /Q IQ /C IQ 10 10 IQ 7
I! A =Pan weight (mg) JO IC /0 IC 10 ID IO /D 10 /Q IO 10 Tray color code::~ 11lDO I~* "1 S" IJ. I ll Analyst: t) C, Date: 10 *.l~ *O-=t B = Pan + Larvae weight (mg) .,.. I Jf.)S' J)./& <+.&.~ 7 1'1.1-;). JJ.t...o floc, l'f.,3 1*1. C/;;z /4, b~ Analyst: :{b~ *z.\.'10 1.'2..4t. ti.S} lttS"Z. '2\.1.5 Z.l."' tZ.'ll t.tt\DJ '2tSS LZ.85 ZZ*~ t)"t Date: )2 *"'~' .vtt C = Larvae w_eigbt (mg)
=8-A ,,'\'4 t.&"\
cs.~o f.\1 t.'(l. 1.'\1 &'.~1 t.to &'. \'\ a.~C\ 8,'{~ 1.'\1. Weigbt per Initial number of larvae (mg)
~ fA~ ~~ "" C /lnilial number of ~~ ~ " < ~ ~ ~ ~ *~ ~ <&;~ ~ ~ ~
q:; larvae o* ()" o* tJ" o* o* a* 0' f;J "" o* ()* t>' Average Percent weight per reduction initial from o.&z."L o. i !>>'-) -\. "i '* o. ~!a() -\.0 1. number of control (-Jo) larvae (mg) I Comment codes: c = clear, d = dead, fg = fungus, k = killed, m = missing, sk = sick, sm = unusually small, lg = unusually large, d&r = decanted and returned, w == wounded. J1_ I I Calculations and data reviewed: Comments: I '~ SOP AT20- Exhibit AT20.3, revision 04-01..09 Page 28 of 102
I iETS Page 3 of6 I _) Envh'Cinm&ntll Tutlng Salualon-. Inc. I Species: Pimeohales promelas Client: TVA I Sequoyab Nuclear Plant, Outfall lOt, Non-treated Date: __1.._\*.......~\....,.1~-.*.;:;d\...=..-_ I Day 45.2% Survival and Growth Data 72.6°/o 100°/o M N 0 p Q R s T u v w X I 0 IQ If:) (CJ to 10 I~ /C 10 10 10 10 /0 1 10 10 ID /0 10 10 10 I 2 IQ ID J() 10 10 /D 10 IO 10
/Q IQ 10 I{J IC 'C 10 10 I 3 4 /b /0 10 LO 10 10 IQ /Q to /0 10 /0 1\) '1'~ 10 IO 10 tO ID 10 I() IQ 10 10 I 5 ID 'i IC 10 1\) 10 10 10 10 10 10 10 6
10 II 7 l{) LO " ~Ur ID 10 /0 10 ID IO IQ 10 tO 10
/Q 10 /0 /Q 10 10 IO 10 \~tl\.
ID
*~n II A= Pan weigbt (mg)
Tray color code:: f""t(24 Analyst: ~ 1S
*'~ ltj,,~ 13,"'f"'\ ,,,q, ICf.o~ N.OI 15'. 71 ,~, IJ.t,.,r "'* 35 1>.83 lf'.:l~
Date: 10
- cJ.q-oD)
B "" Pan + Larvae weight l (mg) Analyst: fu0 Date: \1*0\-1,)"\ cN.~s 'Z z.. "\Y lv-lS l'l.lo3 l.~l\ 2.\.<;~ t.l41 ~'Z.1t 'l.l,,l} z.z.JO zu.oW L1.t*4'l C = Larvae weight (mg) ~ ""8-A 1.tl. t.?Jl c."l'\ 1.1t. i~c'D ,.st '"\.10 ,.t\ a.s1. 1.'\ 2. t..Cl, 1-* fo l Weight per initial number of larvae (mg)
= C /Initial number of larvae ~
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()' ()' o* b' ~* Average Percent IJ weight per initial
- reduction from control o.&ol\ \ .(Q; . o.,,oa s. "Z. .,_ o. 1\o'-\ ,.()7.
number or (%) [ larvae (mR) Comment codes: c = clear, d = dead, fg = fungus, k = killed, m == missing, sk :: sick, sm = unusually small, lg = unusually large, d&r = decanted and returned, w = wounded. [: Calculations and data reviewed: ~ Comments: SOP AT20 - Exhibit AT20.3, revision 04-01-09 Page 29 of 102
II I I' i Page4of6 i II -~ ( I II Species: Pimephales pronrelas Client: TVA I Seguoyab Nuclear Plant, Outfall 101, Non-treated Date: _..ull._-.. 11_,_'_,d1~-
!I Day 0
I /D ID 10 IO I 2 3 tO 10 ID ID /D /0 I 4 ID 10 iI 5 ID ID 6
/0 /{j 10 7
s 10 /D A"' Pan wtight (mg) Tray color codt:: f"'r~, Analyst: I; l <, IY.87 (J.y, II Datt: B = Pan + Larvat weight (mg) 19.10'1 1.\. \Ci I Aoalyst: C a Larvae weight (mg)
~ B- A ,?,,'\1 ,,,i 8.0\
Weight per initial number of larvae (mg)
"'C I Initial number of larvat Averagt Pcrctnt weight per reduction Initial from control o.111o number of (%)
larvae Comment codes: c = clear, d = dead, fg = fungus, k = killed, m = missing, sk = sick, sm = unusually small, lg = Wlusually large, d&r = decanted and returned, w = wounded. I Calculations and data reviewed: Comments' Page 30 of I 02 SOP AT20- Exhibit A T20.3, revision 04-01 -09
~-
TVA I Sequoyah Nuclear Plant, Outfall 101 Non-treated November 17-24, 2009 Pimepllales promelils Chronic Whole Effluent Toxicity Test EPA-821-R-02-013, Method 1000.0 Quality Control Verifacation of Data Entry, Calculation~ and Statistical Analyses Environmental Testing Solutions, Inc. Project DIUIIber: 5812 Re.tiwcd bJ: ~.~.J .~...._ * ... ~ c--.~~oe(%) lieplbll ~a~~~~~ ..... .,
........ Flulaa..t.~ clluY* A
- Pu *li&lal (Ill) ....... .....,.. l.uYuwaps(q)
Not for COillJ)lillncc Assessment. In~emal Laboratory QC Wda**ts....~w~aa Moaa..._.,l Cod!!cllaa cl w..tlllaa We~PtllaliW .. _..r ............... ....,..,.,..,... .. _........... Moe ...tptllaldol ( Jl CClaBL'IIIIItcl ,._,, ..SIIdbl ,,_
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Suwlwtqa-'ucl (Mea . . . . . . - _.,_aot(%) clluYM(q) (%)
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A 10 10 13.60 2190 830 0.830 0830 B 10 10 14 2S 22.42 817 0817 0817 CoD&rol 0822 23 o.au c 10 10 13.11 21 S3 8.42 0.842 0842 100.0 1.3 Not applicable D 10 10 IS SS 23 52 797 0 797 0191 E 10 10 1318 2175 8 S7 0 8S7 0 857 F 10 10 1447 2267 820 0820 0.820 1t.J*n 0834 22 100.0 u c 10 10 14 12 22 31 8.19 0.819 0819 0.134 *1.5 H 10 10 1360 2199 8 39 0 839 0.839 I 10 10 1309 21 sa 849 0.849 0849 J 10 10 1493 2285 7.92 0792 0792 ll.6~. 0830 ~4 100.0 o.uo 5.4 -1.0 K 10 10 1442 22.36 7.94 0794 0.79-4 L 10 10 14.65 2349 884 0.884 0884 M 10 10 13 ll 2095 782 0782 0.782 N 10 9 14 12 2244 832 0924 0832 45.1% 0 832 BS 97.5 0.109 4.6 1.6 0 10 10 13.99 22.48 8 49 0 849 0849 p 10 10 1191 1963 772 0.772 0772 Q 10 10 140S 22.11 806 0806 0806 R 10 10 14.01 21.59 1 sa 0 7S8 0758 71.6*1. 0 779 26 100.0 s 10 10 IS 77 23.47 7.70 0 770 0 770 0.779 1.6 5.1 T 10 10 1491 22.72 781 0 781 0 781 U* 10 10 1361 22 I) 8 S2 0852 0 852 tocw. v 10 10 14 )8 22.)0 7 92 0.792 0 764 9.4 0792 w 10 10 1)8) 20.80 697 0.697 100.0 0.764 9.4 7.0 0697 X 10 10 1526 22 42 7.16 0 716 0716 y 10 s 1487 18 84 397 0794 0 397
- 7. 10 10 13 41 2119 7.78 0718 0 778 100% hluke 0816 61 17.5 0.716 AA 10 10 14 49 22 .so 801 0 801 0801 30.5 l:Z.I 88 10 10 1440 2329 8 89 0 889 0889
~ MSO* M1nimum S1gntficant OUI'erencc:
D*DDeU'I MSD value: 0.0613 PMSD* Percent Mtntmum S1gn1ficant Difference PMSD: 1.3 PMSO IS 11 measure ortc:st prca11on The PMSD 1s the mm1mum perccn1 d,ffcn:ncc becwecn the conuol end trcll%mcnt that can be der:l~ SIIIUstu:AIIy SIBJUficant 1n 11 whole efllucnt tOKICtty test 1aSI!!!& D*DDen'a MSD value: 0.1577 Lower PMSD bound detamincd by USEPA (lOth perccnble) = 12% PMSD: 31.4 Upper PMSD bowld dctcmuncd by USEPA (90th percenule)
- 3D-/o lower 1111d upper PMSO boucds were dcsmnmcd from the lOth 1111d 90th pcrccnulc, rapcctivcly, of PMSD dasa &om EPA's WET ln1erlllbor1110ry Variability Study (USEPA. 200111, USEPA. 2001 b)
USEPA 200Ja. 2001b Fu\&1 Report lnt£rlaboral0f}' Vanabihty Study of EPA Shon-tcnn Chronu; 1111d Awte Whole Effiuent Toltlcaty Test Mdhods. Volumes I and 2*Appcndix EPA-821-8-01-004 and EPA-121-8-0I..OOS US Environmental Protcc:tJon Agenq, Cmc*nnatJ. OH
TVA I Sequoyah Nuclear Plant, OutfalllOl .*Ers
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EnVIronmental Testing Solutions, Inc. Non-treated November 17-24,2009 Statistical Analyses Larval Fisb Growth and Survival Test-7 Day Growth Stan Date: 11/17/2009 Test ID: PpFRCR Sample ID: TV A I Sequoyah Nuclear Plant, Outfall 101 End Date: 11/24/2009 Lab ID: ETS-Envir. Testing Sol. Sample Type: DMR-Discharge Monitoring Report Sample Date: Protocol: FWCHR-EPA-821-R-02-013 Test Species: PP-Pimephales promelas Comments: Non-treated Cone-% 1 2 3 4 0-Control 0.8300 0.8170 0.8420 0.7970 11.3 0.8570 0.8200 0.8190 0.8390 22.6 0.8490 0.7920 0.7940 0.8840 45.2 0.7820 0.8320 0.8490 0.7?20 72.6 0.8060 0.7580 0.7700 0.7810 100 0.8520 0.7920 0.6970 0.7160 Intake 0.3970 0.7780 0.8010 0.8890 Transform: Untraosformed 1-Tailed Isotonic Cone-% Mean N-Meao Mean Min Max CV% N t-Stat Critical MSD Mean N-Mean D-Contto1 0.8215 1.0000 0.8215 0.7970 0.8420 2.345 4 0.8283 1.0000 11.3 0.8338 1.0149 0.8338 0.8190 0.8570 2.162 4 -0.432 2.410 0.0683 0.8283 1.0000 22.6 0.8298 1.0100 0.8298 0.7920 0.8840 5.397 4 -0.291 2.410 0.0683 0.8283 1.0000 45.2 0.8088 0.9845 0.8088 0.7720 0.8490 4.641 4 0.450 2.410 0.0683 0.8088 0.9764 72.6 0.7188 0.9480 0.7188 0.7580 0.8060 2.626 4 1.509 2.410 0.0683 0.7788 0.9401 100 0.7643 0.9303 0.7643 0.6970 0.8520 9.351 4 2.020 2.410 0.0683 0.7643 0.9226 Intake 0.7163 0.8719 0.7163 0.3970 0.8890 30.456 4 Auxiliary Tests Statistic Critical Skew Kun Sbapiro-Wilk's Test indicates normal distribution (p > 0.01) 0.98188138 0.884 0.392664346 0.32317638 Bartlett's Test indicates equal variances (p =0.14) 8.39288521 15.0862722 Hypothesis Test (1-tail, 0.05) NOEC LOEC CbV ru MSDu MSDp MSB MSE F-Prob df Dunnett's Test I 00 > 100 0.06829131 0.08313002 0.00325397 0.00160593 0.123331696 5, 18 Treatments vs 0-Control Linear Interpolation (200 Resamples) Point % so 95% CL(Exp) Skew lC05 65.141 IClO >100 JCI5 >100 IC20 >100 IC25 >100 IC40 >100 IC50 >100 sqn/01 _1 1-J 7-09data
TVA I Sequoyah Nuclear Plant, OutfaU 101- Intake Non-treated November 17-24,2009 ~ETS
- ~ Environmental TesUng Solutions, Inc.
Statistical Analyses Larval Fish Growth and Survival Test-7 Day Growth Start Date: 11117/2009 Test 10: PpFRCR Sample ID: TV A I Sequoyah Nuclear Plant, Outfall I0 I - Intake End Date: 11124/2009 LablD: ETS-Envir. Testing Sol. Sample Type: DMR-Discharge Monitoring Report Sample Date: Protocol: FWCHR-EPA-821-R-02-0 13 Test Species: PP-Pimephales promelas Comments: Non-treated Cone-% 1 2 3 4 D-Control 0.8300 0.8170 0.8420 0.7970 11.3 0.8570 0.8200 0.8190 0.8390 22.6 0.8490 0.7920 0.7940 0.8840 45.2 0.7820 0.8320 0.8490 0.7720 72.6 0.8060 0.7580 0.7700 0.7810 100 0.8520 0.7920 0.6970 0.7160 Intake 0.3970 0.7780 0.8010 0.8890 Transform: Untransformed 1-Tailed Cone-% Mean N-Mean Mean Min Max CV% N t-Stat Critical MSD D-Control 0.8215 1.0000 0.8215 0.7970 0.8420 2.345 4 11.3 0.8338 1.0149 0.8338 0.8190 0.8570 2.162 4 22.6 0.8298 1.0100 0.8298 0.7920 0.8840 5.397 4 45.2 0.8088 0.9845 0.8088 0.7720 0.8490 4.641 4 72.6 0.7788 0.9480 0.7788 0.7580 0.8060 2.626 4 100 0.7643 0.9303 0.7643 0.6970 0.8520 9.351 4 Intake 0.7163 0.8719 0.7163 0.3970 0.8890 30.456 4 0.961 2.353 0.2577 Auxili~ Tests Statistic Critical Skew Kun Shapiro-Wilk's Test indicates nonnal distribution {p > 0.01) 0.82512182 0.749 -1.7159101 4.30798649 F-Test'indicates unegual variances~~= 2.30E-03~ 128.264832 47.4672279 H~e2thesis Test (1-tail, 0.05) MSDu MSDe MSB MSE F-Prob
- df Heteroscedastic t Test indicates no significant differences 0.25768323 0.31367405 0.02215513 0.02397863 0.37355912 1,6 Treatments vs D-Control sqn/01_1 l-17-09data
----------------~--- ---
TVA I Sequoyah Nuclear Plant, OutfalllOl- Non-treated November 17-24, 2009 Pimepha/es promelas Chronic Whole Effiueot Toxicity Test ETS Environmental Testing Solutions, Inc. EPA-821-R-02-013, Method 1000.0 Daily Chemical Analyses Cooceorrarioo Parameter Coorrol 11.3% 22.6% 45.2% 72.6% 100"/o 100% lotakc
I* Page 5 of6 I Species: Pimepltales promela.~ Date: _...&..ILI-...!..11-L-d\~~-- Client: TVA I Seguoyah Nuclear Pla nt, OutfalllOI, Non-treated I I I CONTROL No n-treated I I 11.3% I 22.6% I I 45.2 % I 72.6% I 100% 100% Intake SOP AT20 - Exh ibit A T20.3, revision 04-0 1-09 Page 35 of 102
I Page 6 of 6
~ETS
'~
. ) En-witonment 1l TutJng So'ullons..lnc.
n- n-d\ I Concen-tration I I I I 11.3% I 22.6% I r 45.2% I 72.6% I I 100% I I I 100% Intake I I Page 36 of/02 SOP AT20 - Exhibit AT20.3, revision 04-01-09
Page I of7 Chronic Whole Effluent Toxicity Test (EPA-821-R-02-013 Method 1002.0) Species: Ceriodaohnia dubia Client: Tennessee Valley Authority
- N
_Facility: Seguoyah uclear.:PJant NPDES #: TN0026450 Project #: ........'5&-.'-'-~----- County: Hamilton
* * .;ou:tfall: .ill * ~ ;~, i .*.
I Dilution pre.J!...aration Dilution prep (%) Effluent volume (mL) inf~rmatlon: 11.3 282.5 22.6 565 45.2 1130 72.6 1815 LOO 2500 Comments: I Diluent volume (mL) 2217.5 1935 1370 685 0 Total volume (mL) 2500 2500 2500 2500 2500 I I Test organism source information: Test information: Orslanism ag_e: < 24-hours old Randomizing template color: A.AA.'IL.ft Date and times organisms were born \\*\~*tl\ Q"\CO "'t'O \"U)() between: Incubator number and shelf Culture board: J,\* \ Q-c:A A location: 1.& Replicate number: I . I_ 2 l ) L 4 I s I 6 I 7 I B I 9 I 10 YWTbatch: \\-~(1\ Culture board cup number: '- I , I I' I "\ I
- o I ' \ l"L"tl1~l1.'- _I '2:'\
Transfer vessel information: I pH=.,.~"' S.U. Temperature= ).S,Q OC Selenastrum batch: Average transfer volume (mL): I o*. O!a"\~~ \\*0\*d\ Daily renewal information: Day Date Test initiation and feeding, MHSW Sample n Analyst renewal and feeding, or batch used OutfalllOI termination time 0 2 3 4 5 6 7 Control information: Summary of test endpoints: Control-I Control-2 A~ceptaace criteria
% of Male Adults: {')fu 074 s 200/o 7-day LC~ ) 100 7. %Adults havin_g_ 3m Broods: 1007 .. 1001 :i!80% NOEC toot~ % Mortality: Q1, Q1. S20% LOEC '>1007 ..
Mean Offspring/Female: "2..~.5 "'2.'\ .& :2: 1S.O offspring/female CbV ),11}07.
%CV: ,.'-\ 7. s.'-17. <40.0% ICl! ., 1007~
I I Page 37 of 102 SOP ATil- Exhibit ATI1.2, revision 04-0l-09
Page 2 of7 Species: Cerlodaphn/a dubia Client: TVA I Sequoyab Nuclear Plant. OutfaiiiOI Date: \\ * \1
- oO..
CONTROL~l Survival and Reproduction Data Replicate number Day 1 2 3 4 5 6 7 8 9 10 1 \'~ung produ~ed . (') .0 0*" D D 0 c .0 0 0 Adult mortality
'-- '- '- \.... '--- '- '- '- \,.....
l Young produced c c 0 c 0 {) 0 0 0 0 Adult mortality
'- L- L '-- \.._. '--- L. L.... L.... '--
3 Young produced 0 0 0 a D 0 c 0 0 c Adult mortality
'-- '-- \.._ \__. '--- '-- L- '-- '-- '-
4 Young produced \.\_ l.\ '-t s s "'\ ~ ~ \o Adult mortality L '-- '"'
\._.. \...... '-- '-- \..- '- \.._
5 Young produced \b \0 \.0 \'-. \0 \'1.. \'\._ \.1.. \~ \ \ Adult mortality L. L '-- \......... \.._
'-- '-- '-- L '--
6 Young produced 0 0 0 a c 0 0 C) 0 0 Adult mortality L... '- '- \._. '-- \._ '-- '- L \......... 7 l"\ \ "L ~~
*~
Young produced
'S \S \"1... 1"2... 1"1. 1\o Total young produced ~'2.. 'Z.~ -z..\o 'ltb 'Z., 3() 't..fl "1.'\ !,\ ~~
Final Adult Mortality _L \..._
'- \_ \........_ '-- L '-- \.....
X for 3ns Broods Y-- )(.. "">"- -..,<:.. ~ ~ ~- ">'- ><- Hoff: Aclult monalily (L "'live. D
- dead), SB
- sp5t brood (11ngle brood split bctwcalcwo clays). CO
- cany over (otl'spring carried over wllb &dull dunng trulllCr).
"')C.
CONC: 11.3°/o Survival and Reproduction Data Replicate number Day 1 2 3 4 s 6 7 8 9 10 1 . Young produced 0 0 0 0 0 0 0 () 0 0 Adult mortality L L- L. L L L L L. L_ L... l Young produced 0 0 0 0 0 Q 0 0 () 0 Adult mortality L \..._ L L- \_ L. '-- L. \.... \._ 3 Young produced 0 D 0 c 0 0 a 0 0 0 Adult mortality L L \_. L \..._ \..._ \._
'- L.. '-
4 Young produced ~ '-\ "'\ '-\. s s "-l ~ s Adult mortality L
\\ \~
L. L.. "' L l_ \,_
,,_L L- " \.._ *~'-- '-
Young produced l'L. \~ '1. 10 11. IJ... Adult mortality L.. L. L '- \......
'- \... '-
6 Young produced c D 0 0 c Q_ c _() a 0 7 Adult mortality Young produced L \...... \... l2.. '"-' L
\.~
L
\~
L
\~
L \.._
\'-l \~ \_. ,,L Total youag produced ~2 '3\ ""' 2& 3\ ac .30 ..3() u 2.'i ~~
Final Adult Mortality L \._ '- \.... '- \....._ '-- '- \..... Not~: Adult monality (L *livo, D
- clead), SB
- split brood (single brood split bciWecncwo days), CO
- c:an over (ofrsprina carried over witb aclult dwlll!t cnnsfer).
Concentration:
% Mortality: Ol, Mean Offspring/Female: _30.2 % Reduction from Control-1: .. -z. ""'*
Page 38 of 102 SOP ATtl- Exhibit AT11.2, revision 04-01-09
Page 3 of7 Species: Ceriodaohnla dub/a Client: TVA/ Seguoyab Nuclear Plant. Outfall lOt Date: \\- l1 . o'\
.* coNe: 22.6% Survival and Reproduction Data
-I Replicate number Day 1 2 J 4 5 6 7 8 9 10 I You11g produced 0 D 0 a 0 0 0 0 D 0
. ~du1t mo~lity . '-- \..- L .\.-. .:L. L *.L. L_. \.._. L._
2 Young produced l} D D c D 0 _D c 0 0 3 Adult mortality Young produced
\...
a () L \... 0 l_ b
\. -f) '-
0 L.. D L D D
\._
a
~
I 4 Adult mortality Young produced
\._.
Y.
'5 L.. '4. '-i \.._ \Q \.._. "-\ '-\ '-\ '-- \_.....
s Adult mortality
'-- L \..... \........ L L \.._. L ""
L l.._ I s Young produced Adult mortality
\~ \\ \.._ \""l. \.._ \l.. \....... \1..
L......
\\ '- *~ \....... '~-
1_\ 6 Young produced () 0 ~ a 0 D _0 0 0 D I 7 Adult mortality Young produced
\.._. -\ '~ \.._ '-
l.,2)
\~ '~ \....... \.._.. \'-.
L
\, L \S L '~
lR I Total young produced
~"2.. ~"2- ~ 31. .!.2 ~2.. ~2. 31. 32- ~'"\
Final Adult Mortality l- \..... '-- L- ~ '-- '-- '- '-- L Note: Adult mondity (L
- live. D
- dead), SB
- split brood (sillglc brood split between two days), CO
- e&n over (oftiorinR c;urio:l over with adult cfvrina transfer).
I Concentration:
% Mortality: 07.
Mean Offspring/Female: 3\.'\
% Reduction from Control-1:
I Survival and Reproduction Data Replicate number
-8 *' '*
Day 1 2 3 4 5 6 7 8 9 10 i 1 Young produced Adult mortality 0 L a
\..
(\ L 0 L 0 L 0 L.. 0 L-(j 0 L-10 L 2 Young produced 0 D 0 C) C) 0 0 0 0 o* I 3 Adult mortality Young produced a L \._ a
\......_
() L _Q_
\.
0 L 0 L () L a L (J D Adult mortality \_ L '- L L '- L L '- \.._ I 4 Young produced Adult mortality s L
~
l.
~ s \... \......
s S'
'-\. ~\ \...
s Young produced &0 ID l1. \t.. \'L ll.. \1... l3 I 6 Adult mortality Young produced L 0
'"0" L- L a Q L '-
_Q L 0 L 0 l_ 0 L. 0 L D I 7 Adult mortality Young produced Total youog produced
\S L \S \... '- \S ,, \.._. '-- \-5 \& \¢ \-
L- '-- 15
\.. ~~ 3'-\ ~ 3\ 3'2. 3\:. .3b 0~ .3~ 3'2..
L. '- '- L.. L- L- \..._ L I Final Adult Mortality '- L.. Notl: Adult mon&lity (L
- live, 0
- dead), SB
- split brood (sinsJc brood split between two days), CO
- em over (olfsDrinl( c&rrio:l ovc:r with adult durinR ti'&IU(er).
Concentration:
% Mortality: 07.
I Mean Offspring!Female:
%Reduction from Control*!:
- 31. .. a
- \\. 1. '*
I Page 39 of 102 SOP ATil -Exhibit AT11.2, revision 04-01-09
Page 4 of 7 Species: Ceriodaphnia dubia Client: TVA/SeguoyahNuclcarPiant,OutfalllOl Date: i\-11-0t\ CONC: 72.6% Survival and Reproduction Data R~pllcatt nu mbu Day 1 2 J 4 s 6 7 8 9 10 I Young produc~d L 0 D 0 0 a 0 0 a 0 0 Adult mortality
'- L \.._. L '-- '-- \.._ '-- '--
2 Young produc~d Adult mortality 0
\._
0 0 0 0 a\_ () D 0 0
'- '-- '- '--- \.,__ L L L J Young produc~d ~ 0 0 0 0 0 0 0 0 0 Adult mortality \.._ '-- \.._ '--- '-- \.._ '---- \_ \...__
4 Young produc~d $ s '-\ ~ !,.. y ~ s s '--\ Adult mortality L- \.,__ \_ \..._
'- '- L \..._
s Young produc~d \1_ \1._ ~~ IL.. \~ I!> \~ 1'4 \l 1\ Adult mortality L '- '--- \_
'-- \......- \...._ '- ' - \..._
6 Young produced 0 0 0 0 0 _Q_ D i::l _Q_ a Adult mortality L '-- \....... \....... '- '-- '-- '- \.._ \...._ 7 Young produc~d v., 11 llo 1'-\ \~ 1\o 1_5_ IS l__c-1 1\ Total young produced
~ 3'-\ 2>'-\ 32 -31 3~ .3k ~y 3(.) .3L Final Adult Mortality I._ '- '- ~ '-- '-- '-- -"--- '-- \...._ /{oft: Adult monalny (L
- live, 0
- de:td), SB
- splil brood ("ngle brood splil belwceo 1wo d a)*l. CO
- e& o vc:t of!\prin~ camed over Uo111h adult dunng transfe-r Concentration:
% Mortality: nr.
Mean Offspring/Female: -Y.> .1
% Reduction fro m Control-!: *t"! .1..,.
CONC* 100% Survival and Reproduction Data R~pli cate numb~r Day I 2 J 4 5 6 7 8 9 10 1 Young produced (') a () 0 0 0 _Q Q _0 n Adult mortality L \._.. L L. L L L '-- L '--.: 2 Young produced 0 _Q_ _()_ 0 0 0 0 0 0 () Adult mortality L '- L L L L L- L L \...._ J Young produced 0 0 D 0 0 _C) _0_ 0 0 b Adult mortality
'-- '-- \..__ L L \.._ L L \...._
I 4 5 Young produced Adult mortality Young produced s L L"\ \"L la 10 L s L
\~
4. I~ s s L 11..... l IS s
\...-
I \ L
~
II..\ I.e.
\"{
i Adult mortality \._ L L L \__
'- L L l.._
6 Young produced 0 0 0 0 D 0 0 0 _a_ C5 Adult mortality '-- \_
'- L '- '- L L '- '--
i 7 Young produced Total young produced Final Adult Mortality H. 3S
\_
l8
~b n
3L L 11
~Ia 1<&.
3\.l
\,_
lq 3\o
'-- ~
Jlo ae "2.0 31., 38 l~
)~ .3r:f \.,__
I Nott ' Adult mon.&lity (l
- live, 0- dead). SB
- Jplit b1ood (single brood split betWeen rwo days). CO- t&ll over offspri ng unicd ovCT with a.duh Concentration:
%Monality:
dun~.!_tnnsfer Q7. 3S .'\ I Mean Offspring/Female:
%Reduction from Control- \ : - "2.\ .1?.
I Page 40 of 102 SOP AT l l - Exhib it AT 1 1.2, revision 04-01-09
Page 5 of7 Species: Cerlodaphnia dub/a Client: TVA/ Sequoyah Nuclear Plant. OutfalllOI Date: 1\* \1~0~ CONTROL-2 Survival and Reproduction Data Replicate number Day 1 2 3 4 s 6 7 8 9 10 I .. Young produced 0 0* D D 0 D a 0 0 0 Adult mortality \....... L.. '- \.._* L- '- L L- '-- ~ l Young produced
- D 0 D_ 0 0 D 0 () 0 D Adult mortality L L - L '- '--
I '- '-- \. l- L. 3 Young produced D D D D (J c 0 D 0 a Adult mortality \....- \._. \.._ '- \.._ L. '-- L.... "- 4 Young produced (., '-l ~ s '-\ '-\ '-\ ~l i 5 Adult mortality Young produced
'~ 'i \....
rz.. L-11-
'-- L '~ - '~ \.._ '--
IL.,. tD Adult mortality L '- \....... \.._ 6 a Q _Q_ 0 0 a Young produced ~ D D C) Adult mortality L '- L '-- \_ L '- \.._ 7 Young produced \'-\ \'2. \l. \~ \"2. \'5 \,?;) \S \~ Total young produced
'""' ~() 3t>> ~\ ~\ "1.&
Final Adult Mortality X for 3rcs Broods
~\ 'i- 'Z.""\ ~
L.
)(, ~
3"2..
~ -y. ~ ~ ~ ~ ~ ~ '1'-
Not*. Adult monllity (L
- live, D
- doad), SB
- split brood (sinslc brood splu between nw days), CO .. cany over (olfspnns earned over With adult dunng transfer).
coNe: 100% Intake Survival and Reproduction Data Replicate aumber Day 1 2 3 4 5 6 7 8 9 10 1 Young produced. C) 0 0 0 0 0 0 0 0 0 Adult mortality L '-- L L L L L L- L L 2 Young produced /") a D 0 0 0 0 {) () () Adult mortality ~ '-- L- \...__ L- L. L- L L \...- 3 Young produced (j 0 0 a 0 0 a () Q 0 Adult mortality \.._ L L s'- L '- L L. \._ L. 4 Young produced s \o s "-\ ~ "l 5 \.( 'i Adult mortality L- L L L s Young produced ,,_ L l\ L
&l.
L l'l.. I~ L L
\l... \1. \1.. 11-Adult mortality L L. L._ L L L '- L L '-
6 Young produced D 0 c CJ 0 a 0 0 c 0 7 Adult mortality Youag produced Total youag produced
\'\
l
,, L a1 L '-
I '"'I
\..._
13> L.. alo tS lS L,.. '- lS l. ICc 31 ~5 ~~ ~(;) 2.'\ ~~ ~L. ~\ ~\ 0~ Final Adult Mortality L \. \._ ~- \._ '- ~ '- '-- Not*.* Adult mortality (L
- Gve, D
- dead), SB
- split brood (single brood split between IWo days), CO
- can over (offiprinJt carried over with aduh during transfi:r).
ConcenJratlon:
% Mortality: 07..
Mean Offspring/Female: ~-z.S
% Reduction from Control-2: -"*l7o Page 41 of 102 SOP ATil- Exhibit ATII.2, revision 04-01-09
TVA I Sequoyah Nuclear Plant, OutfalllOl- Non-treated ~ETS November 17-24,2009 Verification of Ceriodaphnia Reproduction Totals . ) Envtronment.-1 Tesdng Solutions. Inc. Coo trol-l 72.6% Replicate number Replicate number Day Total Day Total I 2 3 4 s 6 7 8 9 10 I 2 3 4 s 6 7 8 9 10 1 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 2 0 0 0 0 0 0 0 0 0 0 0 2 0 0 0 0 0 0 0 .0 0 0 0 3 0 0 0 0 0 0 0 0 0 0 0 3 0 0 0 0 0 0 0 0 0 0 0 4 4 4 4 4 5 s 4 4 6 6 46 4 5 s 4 6 6 4 6 5 s 4 50 s 13 10 10 12 10 12 12 12 13 11 115 5 12 12 14 12 13 13 13 14 11 II 125 6 0 0 0 0 0 0 0 0 0 0 0 . 6 0 0 0 0 0 0 0 0 0 0 0 7 15 15 12 14 12 13 12 13 12 16 134 7 16 17 16 14 18 16 19 IS 14 17 162 Total 32 29 26 JO 27 30 28 29 31 33 295 Total 33 34 34 32 37 33 38 34 JO 32 337 Replicate number Replicate number Day Total Day Total I l 3 4 5 6 7 8 9 10 1 2 3 4 5 6 7 8 9 10 I 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 2 0 0 0 0 0 0 0 0 0 0 0 l 0 0 0 0 0 0 0 0 0 0 0 3 0 0 0 0 0 0 0 0 0 0 0 3 0 0 0 0 0 0 0 0 0 0 0 4 s 4 4 4 4 5 5 4 4 4 43 4 s 6 s 6 5 5 7 5 6 6 56 s 11 13 12 13 13 12 12 10 12 12 120 s 14 12 10 13 13 12 15 11 14 14 128 6 0 0 0 0 0 0 0 0 0 0 0 6 0 0 0 0 0 0 0 0 0 0 0 7 16 14 12 14 13 13 13 14 13 17 139 7 16 18 17 17 16 19 16 20 18 18 175 Total 32 31 28 31 30 30 30 28 29 33 302 Total 35 36 32 36 34 36 38 36 38 38 359 22'.6°/o Control-2 Replicate number Replicate number Day Toa.l Day Total I 2 3 4 5 6 7 8 9 10 1 2 3 4 5 6 7 8 9 10 I 0 0 0 0 0 0 0 0 0 0 0 I 0 0 0 0 0 0 0 0 0 0 0 2 0 0 0 0 0 0 0 0 0 0 0 2 0 0 0 0 0 0 0 0 0 0 0 3 0 0 0 0 0 0 0 0 0 0 0 3 0 0 0 0 0 0 0 0 0 0 0 4 4 s 4 4 6 4 4 4 6 5 46 4 4 4 6 4 4 5 4 4 4 4 43 5 14 II 12 12 12 12 11 13 13 II 121 5 13 9 12 12 11 13 12 13 12 10 117 6 0 0 0 0 0 0 0 0 0 0 0 6 0 0 0 0 0 0 0 0 0 0 0 7 14 16 13 16 14 16 17 IS 13 18 152 7 14 14 12 16 13 12 IS 13 15 14 138 Total 32 32 29 32 32 32 32 32 32 34 319 Total 31 27 JO 32 28 JO 31 JO 31 28 298 100°/o Intake Replicate number Replicate number Day Total Day Total I 2 3 4 5 6 7 8 9 10 1 2 3 4 s 6 7 8 9 10 1 0 0 0 0 0 0 0 0 0 0 0 I 0 0 0 0 0 0 0 0 0 0 0 2 0 0 0 0 0 0 0 0 0 0 0 2 0 0 0 0 0 0 0 0 0 0 0 3 0 0 0 0 0 0 0 0 0 0 0 3 0 0 0 0 0 0 0 0 0 0 0 4 s s 6 4 5 6 5 5 4 4 49 4 s 6 5 4 4 4 s 4 4 s 46 s 13 14 12 10 12 12 12 12 12 13 122 s 14 12 11 12 12 13 12 12 12 12 122 6 0 0 *o 0 0 0 0 0 0 0 0 6 0 0 0 0 0 0 0 0 0 0 0 7 IS IS IS 17 1S 18 13 17 17 15 157 7 19 17 17 14 13 16 IS IS IS 16 157 Total 33 34 33 31 32 36 30 34 33 32 328 Total 38 35 33 30 29 33 32 31 31 33 325
T VA I Sequoyah Nuclear Plant, Outfall lOt Non-treated November 17-24, 2009 Ceriodap hnia dubia Chronic Whole Effluent Toxicity Test EPA-821-R-02-013, Method 1002.0 Q uality Control Verification of Data Entry, Calculations, and Statistical Analyses Environmental Testi ng Solutions, Inc. P roject number : 5812 Rcvciwed by: ;"')/ ~
/
C oncent rlltion R eplicate numbe r S urvival A vuage r eproduction *Coeffic.ieot of Pcrcc.nt reduction from vari..uioa (Y*) pc')Okd controls (Y*) (%) (%) (offspr ing/female) I 2 3 4 5 6 7 8 9 10 Control - I 32 29 26 30 27 30 28 29 31 33 100 29.5 7.4 Not a p plicable IIJ % 32 3I 28 31 30 30 30 28 29 33 100 30.2 5.4 -2.4 22.6% 32 32 29 32 32 32 32 32 32 34 100 31.9 3.8 -8.1 45.2% 33 34 33 31 32 36 30 34 33 32 100 32.8 5.1 - 11.2 72.6% 33 34 34 32 37 33 38 34 30 32 100 33.7 7.0 -14.2 100% 35 36 32 36 34 36 38 36 38 38 100 35.9 5J -21.7 Control - 2 31 27 30 32 28 30 31 30 31 28 100 29.8 5.4 Not appl icable 100% Intake 38 35 33 30 29 33 J2 31 31 33 100 32.5 8.0 -9. 1 O utfaii !OI: MSD = Minimum Significant Difference Du nnett's MS D va lue: 1.906 PMSD= Percent Minimum S ignificant Difference PMSD: 6.5 PMSD is a measure of test precision The PMSD is tlte minimum percent di fference between the control and treatment that can be declared statistically significant in a whole effiuent toxiciry test. Intake: Dunnett's MSD value: 1.676 Lower PMSD bound determined by US EPA ( 10"' percentile) = 13%. PMSD: 5.6 Upper PMSD bound determined by US EPA (90lh percentile)= 47%. Lower and upper PMSD bounds were determined l'rom the lOth and 90th percentile, respectively, of PMSD data from EPA's WET Jntcrlabordtory Variability Study (USEPA, 200 1a; USEPA, 200 l b). USEPA. 2000. Understanding and Accounting for Method Variability in Whole Effluent Toxicity Applicattons Under tlte National Pollutant Discharge Elimination Program. EPA-833-R-00-003. US Environmental Protection Agency, Cincinnati , OH. US EPA. 200la, 2001 b. Final Repon : Interlaboratory Variability Study of EPA Shon-term Chronic and Acute Whole Effluent Toxicity Test Methods, Volumes I and 2-Appendix. EPA-821 -B*O 1-004 and EPA-82 1*8-0 1-005. US Environmental Protection Agency, Cincinnati, O H.
TVA I Sequoyah Nuclear Plant, Outfall lOt Non-treated ~ETS November 17-24, 2009 Statistical Analyses . ) Environmental Testing SoCutlons, Inc. Ceriodaphnia Survival and Reproduction Test-Reproduction SwtDate: 11/1712009 Test ID: CdFRCR Sample ID: TVA I Sequoyah Nuclear Plant, OutfaU 101 End Date: 1112412009 Lab ID: ETS-Envir. Testing Sol. Sample Type: DMR-Discharge Monitoring Report Sample Date: Protocol: FWCHR-EPA-821-R-02-013 Test Species: CD-Ceriodaphnia dubia Comments: Non-treated Cone-% I 2 3 4 5 6 7 8 9 10 Control- I 32.000 29.000 26.000 30.000 27.000 30.000 28.000 29.000 31.000 33.000 Cootrol-2 31.000 27.000 30.000 32.000 28.000 30.000 31.000 30.000 31.000 28.000 11.3 32.000 31.000 28.000 31.000 30.000 30.000 30.000 28.000 29.000 33.000 22.6 32.000 32.000 29.000 32.000 32.000 32.000 32.000 32.000 32.000 34.000 45.2 33.000 34.000 33.000 31.000 32.000 36.000 30.000 34.000 33.000 32.000 72.6 33.000 34.000 34.000 32.000 37.000 33.000 38.000 34.000 30.000 32.000 100 35.000 36.000 32.000 36.000 34.000 36.000 38.000 36.000 38.000 38.000 lntake 38.000 35.000 33.000 30.000 29.000 33.000 32.000 31.000 31.000 33.000 Transform: Untransformcd Rank 1-Tailed Isotonic Cone-% Meau N-Mean Mean Min Max CV% N Sum Critical Mean N-Mean Control- I 29.500 0.9899 29.500 26.000 33.000 7.366 10 32.333 1.0000 Control-2 29.800 1.0000 29.800 27.000 32.000 5.434 10 11.3 30.200 1.0134 30.200 28.000 33.000 5.362 10 115.00 75.00 32.333 1.0000 22.6 31.900 1.0705 31.900 29.000 34.000 3.753 10 137.00 75.00 32.333 1.0000 45.2 32.800 1.1007 32.800 30.000 36.000 5.142 10 144.00 75.00 32.333 1.0000 72.6 33.700 1.1309 33.700 30.000 38.000 7.001 10 147.00 75.00 32.333 1.0000 100 35.900 1.2047 35.900 32.000 38.000 5.326 10 153.50 75.00 32.333 1.0000 Intake 32.500 1.0906 32.500 29.000 38.000 7.978 10 Auxiliary Tests Statistic Critical Skew Kurt Kolmogorov D Test indicates non-normal distribution (p <= 0.01) 1.045023799 1.035 0.04119118 0.090545302 Bartlett's Test indicates equBl variances (p = 0.46) 4.634984493 15.08627224 The control means are not signiftcant1y different (p:::;: 0.73) 0.350059429 2. 100922029 Hrpothesis Test (1-tail, 0.05) NOEC LOEC ChV TU Steel's Many-One Rank Test I 00 > 100 Treatments vs Control- I Linear Interpolation (200 Resamples) Point % SD 95o/oCL Skew ICOS >100 ICIO >100 1C15 >100 IC20 >100 IC25 >100 1C40 >100 ICSO >100 sqn/01 _I 1-1 7-09data
TVA I Sequoyah Nuclear Plant, Outfall 101 Non-treated November 17-24,2009 ,;~rs ..) Environmental Testing Solutions, Inc. Statistical Analyses Used for PMSD calculation only. Ceriodaphnia Survival and Reproduction Test-Reproduction Stan Date: 11117/2009 Test ID: CdFRCR Sample ID: TVA I Sequoyah Nuclear Plant, Outfall101 End Date: 11/24/2009 Lab ID: ETS-Envir. Testing Sol. Sample Type: DMR-Discharge Monitoring Repon Sample Date: Protocol: FWCHR-EPA-821-R-02-0 13 Test Species: CD-Ceriodaphnia dubia Comments: Non-treated Cone-% I 2 3 4 5 6 7 8 9 10 Control- I 32.000 29.000 26.000 30.000 27.000 30.000 28.000 29.000 31.000 33.000 Control-2 31.000 27.000 30.000 32.000 28.000 30.000 31.000 30.000 31.000 28.000 11.3 32.000 31.000 28.000 31.000 30.000 30.000 30.000 28.000 29.000 33.000 22.6 32.000 32.000 29.000 32.000 32.000 32.000 32.000 32.000 32.000 34.000 45.2 33.000 34.000 33.000 3i.ooo 32.000 36.000 30.000 34.000 33.000 32.000 72.6 33.000 34.000 34.000 32.000 37.000 33.000 38.000 34.000 30.000 32.000 100 35.000 36.000 32.000 36.000 34.000 36.000 38.000 36.000 38.000 38.000 Intake 38.000 35.000 33.000 30.000 29.000 33.000 32.000 31.000 31.000 33.000 Transform: Uolransformed 1-Tailed Cone-% Mean N-Mean Mean Min Max CV% N t-Stat Critical MSD Control-1 29.500 0.9899 29.500 26.000 33.000 7.366 10 Conlro1-2 29.800 1.0000 29.800 27.000 32.000 5.434 10 11.3 30.200 1.0134 30.200 28.000 33.000 5.362 10 ..0.840 2.287 1.906 22.6 31.900 1.0705 31.900 29.000 34.000 3.753 10 -2.879 2.287 1.906 45.2 32.800 1.1007 32.800 30.000 36.000 5.142 10 *3.959 2.287 1.906 72.6 33.700 1.1309 33.700 30.000 38.000 7.001 10 -5.039 2.287 1.906 100 35.900 1.2047 35.900 32.000 38.000 5.326 10 -7.678 2.287 1.906 Intake 32.500 1.0906 32.500 29.000 38.000 7.978 10 Auxi1i!!l: Tests Statistic Critical Skew Kun Kolmogorov D Test indicates non-normal distribution (p <= 0.01) 1.045023799 1.035 0.04119118 0.090545302 Banlen's Test indicates equal variances (p = 0.46) 4.634984493 I 5.08627224 The control means are not siS!!!ficantll: different~"" 0. 73~ 0.350059429 2.100922029 Hypothesis Test ( 1-tail, 0.05) NOEC LOEC ChV TU MSDu MSDp MSB MSE F-Prob df Dunnett's Test 100 >100 1 1. 906063607 0.064612326 55.14666667 3.474074074 1.3E-09 5,54 Treabnents vs Control~ I sqn/01 _1 1-1 7-09data
TVA I Sequoyah Nuclear Plant, Outfall 101 -Intake Non-treated
~
()Q November 17-24,2009
~ ~ ~ETS Q\
~
~ Statistical Analyses ~ Environmental TesUng Solutions. Inc.
Ceriodaphnia Survival and R5!roduction Test-Reeroduction Start Date: 11/17/2009 Test 10: CdFRCR Sample ID: TVA I Sequoyah Nuclear Plant, Outfall 10 I - lntake End Date: 11/24/2009 Lab ID: ETS-Envir. Testing Sol. Sample Type: DMR-Discharge Monitoring Report Sample Date: Protocol: FWCHR-EPA-821-R-02-0 13 Test Species: CD-Ceriodaphnia dubia Comments: Non-treated Cone-% I 2 3 4 5 6 7 8 9 10 Control- I 32.000 29.000 26.000 30.000 27.000 30.000 28.000 29.000 31.000 33.000 Control-2 31.000 27.000 30.000 32.000 28.000 30.000 31.000 30.000 31.000 28.000 11.3 32.000 31.000 28.000 31.000 30.000 30.000 30.000 28.000 29.000 33.000 22.6 32.000 32.000 29.000 32.000 32.000 32.000 32.000 32.000 32.000 34.000 45.2 33.000 34.000 33.000 31.000 32.000 36.000 30.000 34.000 33.000 32.000 72.6 33.000 34.000 34.000 32.000 . 37.000 33.000 38.000 34.000 30.000 32.000 100 35.000 36.000 32.000 36.000 34.000 36.000 38.000 36.000 38.000 38.000 lntake 38.000 35.000 33.000 30.000 29.000 33.000 32.000 31.000 31.000 33.000 Transform: Untransformed )-Tailed Cone-% Mean N-Mean Mean Min Max CV% N t-Stat Critical MSD Control-1 29.500 0.9899 29.500 26.000 33.000 7.366 10 Control-2 29.800 1.0000 29.800 27.000 32.000 5.434 10 11.3 30.200 1.0134 30.200 28.000 33.000 5.362 10 22.6 31.900 1.0705 31.900 29.000 34.000 3.753 10 45.2 32.800 1.1007 32.800 30.000 36.000 5.142 10 72.6 33.700 1.1309 33.700 30.000 38.000 7.001 10 100 35.900 1.2047 35.900 32.000 38.000 5.326 10 Intake 32.500 1.0906 32.500 29.000 38.000 7.978 10 -2.793 1.734 1.676 Auxili~ Tests Statistic Critical Skew Kurt Shapiro-Wilk's Test indicates normal distribution (p > 0.01) 0.951517842 0.868 0.62319944 1.12773217 F-Test indicates equal variances (p = 0.18) 2.563559294 6.541089535 The control means are not si~ificanuy different(~= 0.73) 0.350059429 2.1 009220i9 Hll!othesis Test (1-tail, 0.05~ MSDu MSDe MSB MSE F-Prob df Homoscedastic t Test indicates no significant differences 1.676261504 0.056250386 36.45 4.672222222 0.0120129 I, 18 Treatments vs Control-2 sqn/01 _I 1-1 7-09dala
TV A I Sequoyah Nuclear Plant, OutfalllOl -Non-treated November 17-27,2009 Ceriodaphnia dubia Chronic Whole Effluent Toxicity Test EPA-821-R-02-013, Method 1002.0 Daily Chemical Analyses Environmental Testing Solutions, Inc. cotratioo Parameter Control 11.3% 22.6% 45.2% 72.6% 100% 100% lotakc
Pagc 6of7 Species: Cerfodaphnia dub/a Date : _...:.1..1..\*_._11
-L-~o~'\c..____ _
- 4 Client: TV A I Seg uovah N.uclear Plant, Outfall I 0 I ChP~ni*tlru*
CONTROL 11.3% 22.6% 45.2% 72.6% 100% 100% I Intake I J Page 48 of 102 SOP AT II - Exhibit AT I 1.2, rev ision 04-01-09
Page 7 o f 7 Species: Cerlodaphnia dubia Client: TVA I Seguoyah Nuclear Plant, Outfa lllOI Date: 1\-\1*0<\ Concen- Parameter
!ration CONTROL 11.3%
22.6% 45.2% I I *.72.6% 100% 100% Intake Page 49 of I 02 SOP AT II -Exhibit A Tll.2, revis ion 04-01 -09
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Species: Pimephales promelas
,~
1' Client: Tennessee Valley Authority County : R.beal AAMIU"ON Facility: Seguoyab Nuclear Plant Outfall: 101 NPDES #: 't'N99l0l(t~ '"'\"W 00~~"50 t~. Project #: _ _,'5&~\:.,!'L::....__ _ _ __ Dilution preparation information: Comments: Di lution prep(%) 11.3 22.6 45.2 72.6 100 Each concentration was UV -treated Effluent volume (mL) 282.5 565 1130 1815 2500 for 2 minutes to remove pathogenic Diluent volume (mL) 2217.5 193 5 1370 685 0 Interferences. Total volume (mL) 2500 2500 2500 2500 2500 Test Orf!anism information: Test information: Organism age: 1."Z..So 't\~:~v1t~ O'-b Randomizing template: !Ill\ ue.. I Date and times organ isms were born between:
\\-1 \,-()Cot \'cOO Incubator number and shelf location:
3& Organism source: A.-roi-- &P\\l\'\ Pp \\-'1\..-t:A. Ar,temia CHI'vl number: lrJ!H.**N~ I Drying information for weight determination: I~ Transfer bowl information: pH= -v~o S.U. Date I T ime in oven: ! 1\*'l.'t- ()'\ Temperature =~.1°C Initial oven temperature: !Qt~*C... Average transfer volume: Date I Time out of oven: )\. '15-0 '\ 0."'2.'!-t.s.- Final oven temperature : Total drying time:
"c *c... ~*1-\ov~
Daily feeding and renewal information: Day Date Morning feeding Afternoo n fe eding Test initiation, Sample numbers used MHSW batch i 0 2 I 3 4 t-7 6 -+~~~~~~~~+-~--+-~~~~~-+~~~~*---~~~~L--+~~~~--~~~~
' 5 I 7 I 'I Page 50 of 102 SOP A T20 - Exhibit A T20.3, revision 04-0 1-09
~ETS Page 2 of6 . ) Envlronm.ntal TcJtlng So lullo ns.lnc.
Species: Pimepha/es prome/as Client: T VA I Sequoyab Nuclear Plan t, Outfall 101, UV-treated Date : _l'-'-\*_1_'1'--*-0 '\..;......__ _ Survival and Growth Data Day CONTROL 11.3% 22.6% UV-t reated A 8 c 0 E F G H I J K L 0 10 /0 IO 10 IO 10 10 /0 to I() 10 IQ I
/0 / () ID /0 / '\) 10 10 10 ID 10 /() 10 2
JO ID /0 ID ID /0 10 10 10 /0 IQ 10 3 ID ID Jo IO IO /Q IO ID ID /0 to to 4 l (j 10 10 /0 ID 10 10 10 10 10 J (J tO 5
/t) ID tD 10 J C) tD 10 /f;J /() /0 ID 1\.)
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T r ay color code :: ~ Ana lys t : ~~~ 1'+.3.). ,.,."\, h .... 1'f N .JJ ~. ~ ~ ~-OS"
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_D_a_tc: 10 * ).. "\" ~o --'1 B ~ Pan + La rva e we ig ht (mg ) . Analyst : ihw 22..'CO 'lt .I S 'l.C. '-10 22.\', \ z.z.-a 'l. I.Z. ~z. l ~. 3'-\ 2 \-'!~ !'Z. I.I'"Z.. t Z.. I i 2\.00 1-zl.'Of? Date ll -01 *0'1 C ~ Larvae weig ht (mg_)
= B- A
- g. ~ l , . ~s 1 -~~ 1 .ll lo 8-SY cf.Ob g . ~& 1.1& j .11 i .10 t .11o 1."-'-1 Weight per initial num ber
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I ~ ~ETS Page 3 of6
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Species: Pimeohales promelas Client: TVA I Seguoyah Nuclear Plant, Outfall lOt. UV-treated Date: 1\- \1*01 Survival and Growth Data Day 45.2°/o 72.6o/o 100°/o
- M N 0 p Q R s T u v w X 0 /0 10 10 10 10 /D /Q 10 /0 10 /0 10 1
ID 10 10 /Q /() /D 10 I~ IO ID /Q 10 2 10 /0 10 /Q IC /(J 10 /Q IO 10 10 /Q 3
/0 10 10 10 ID /Q /Q /() /Q /Q 10 10 4
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/tl /0 IC> 10 /(} IC /D 10 10 /0 10 to A ::z Pan weight (mg)
Tray color code:: AJ4"j Analyst: 2:1 > ll-8~ 1'3 ..;1. 7 l"i.Cf;J 113(Jl 1~.)5" 15.47 J~.e; 1~.0'7 \~1'0 'i* <.,, I'I.C..<c>> IS: 3"'t Date: to- ::l'"i.~o~ B "'" Pan + Larvae weight (mg) .~ :z_\.~'3 z.o.cr3 z.z.te 2 4. ()) 'l"*OI.p Analyst: fu 2\.v~ "t"J,n l2.ol 2.Z.Z.S }..\ .-z..'Z- Z.3.4.(J "'1.\. 'l \ Date: , ,. .0\
- OO\
C :::o Larvae weight (mg)
=8-A 1.1.4 B**'-' &.'l.S a.~.as i. 0,() 1.1S l.SCa ,.*Y 1.1S 1.S1 '\.~"a 8.f-1 Welgbt per initial number oflarvae (mg) ~ q,~ , "t., q; '0,_, ~ ,..."e-, ~ ~\p fb~ h ~" 0\~ Cb'~~"
- a C /Initial number of larvae Average
~*
o* t)" ~* ~ o* t). ()" 1\ (). ~*"' o* ~* Percent weight per reduction initial from control o.sc& , o.1 '1. 0* a:~ -'(.()7. Q.i!>>S - ~ .l "lo number of (%) larvae (m2) Comment codes: c = clear, d = dead, fg = fungus, k = killed, m = missing, sk = sick, sm = unusually small, lg = unusually large, d&r = decanted and returned, w = wounded.
- Calculations and data reviewed: ..Jt_
Comments: Page 52 of 102 SOP AT20 - Exhibit AT20.3, revision 04*0 1*09
TVA I Sequoyah Nuclear Plant, OutfalllOl UV-treated November 17-24, 2009 Pimephales promelas C hro nic Whole E ffluent Toxicity Test EP A-821*R~2~13 , Method 1000.0 Quali1y Control Verification of Data E nt ry, C alculations, and Statistical Analyses Environmental Testing Solutions, Inc. Projrct **uubu: _ _ _ _ _ _ _ __ _ _ _S8_ 11 Rcniwcd b)" No< for Compluoncc A>seument. lnwnal Lobomory QC CC*:u1radoe (%) R.r:prlir a k: l &iaa. -o~~cr al Fi...t *-bc.r rA larue A
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_!'hl r.-rcr.t n.Jactio. fro. co*trU (%) A 10 10 14 J2 2280 8 48 0 848 0848 8 10 10 14.97 22 15 7 18 0 718 0 718 Coe lrol 0 802 87 100.0 0.1102 8.7 Not applitable c 10 10 12 74 2046 772 0 772 0 772 0 10 10 14.11 22 81 8.70 0 870 0 870 E 10 10 1406 22 82 8 76 0 876 0876 F 10 10 1405 22 62 857 0 857 0 857 IJ .J*;. 0 834 65 91.5 OJIIJ 7.7
- 1.4 c 10 9 15 70 23 )4 76-1 08 49 0 764 u 10 10 14 43 2 1 911 7H 0 755 0 755 I 10 10 1363 21 12 7 49 0 749 0 749 J 10 10 14 15 22 II 796 0796 0 796 22 .6*1. 0801 54 100.0 0.&01 5.4 0.1 K 10 10 1246 2100 854 0854 0 854 L 10 10 13.82 21 88 806 0806 0 806 M 10 10 13 84 21 08 7 24 0 724 0 724 N 10 10 13.27 21 4) 8 16 0 816 0 816 4S.l % 0 808 74 100.0 0.&08 7.4 .(1,7 0 10 10 1492 23 17 8 25 0 825 0 825 p 10 10 13 36 2201 8 65 0 865 0 865 10 10 13 )5 22 25 890 0890 0 890 R 10 10 1147 2 1 22 775 0 775 0 775 -4.0 7 2.6*..<. 0 834 60 100.0 0.83-4 6.0 s 10 10 14 87 2J 43 8 56 0856 0 856 T 10 10 I J 07 21 21 g 14 0 814 0 814 u 10 10 I ) 18 2093 775 0 71S 0 775 I OOY, v 10 10 14 61 22 18 7 57 0 757 0835 10 I 01 51 100.0 0.835 10.1 -4.1 w 10 10 14 66 24 05 9 39 0 939 0939 X 10 10 1539 24 06 8 67 0 867 0 867 y 10 10 1540 23 53 8 IJ 0 813 0813
- l. 10 10 IJ 16 20 42 7 26 0 726 0 772 46 0726 100.0 o.m 4.6 J.7 100"/. l~U.ake AA 10 10 15 73 23S3 7 80 0 780 0 780 DB 10 10 12 86 20 56 7 70 0 170 0 770 Ootfall lOb MSO* Mu11mum S oJllllfieam Ooffctenc.c Dwnrn' a MSD valur.: 0.1075 PMS D ~ Pacent Mumnum Stgmfic.a.nt DUfcrenu PMSD: 13.4 PMSD IS a measure oftesl prectston The PMSO u the mmamum pcrunl duTcrencc bcr"WCCn the control and treatment that can be decl.1ttd nattsttc.aHy stgn*flc.ant 111 a INholc cffiucnt toxtcHy lest l!!.!.!!I.i Du.n * <<1't 1\150 v*lu.:: 0.076 4 lower PMSO bound dctcnmncd by I.JSEPA ( lOth pcrt<nllle)
- 12%
PMSD: 9.5 Upper PMSO bound dttennmed by US EPA (90th pcrcenule)
- JO'/o lower and upper PMSO bounds were dctenmned from the lOth and 90th percenlllc, rcspccuvely. of PMSO dau from EPA's WET lnt< rlobontory Vanabrhty Study (US EPA. 2001a. USEPA.
200 1b) US EPA 2001&. 2001 b FU\31 Repon lnter labor:uory Van*bolny Study of EPA Shan-term Chronrt and Atut< Whole Effluent To.,euy TcSI Methods. Volumes I and 2*AppcndJx EPA-821*8-01*004 and EPA*821-8-01*005 US Envll<><unc:null'r o<et< ron Asency. CtnciiUlOI~ 0 11
TVA I Sequoyah Nuclear Plant, Outfall 101 UV-treated
~ETS November 17-24,2009 Statistical Analyses
.. ) Environmental Testing Solutions, Inc. Larval Fish Growth and Survival Test-7 Day Growth Stan Date: 11/17/2009 Test 10: PpFRCR SampleiD: TVA I Sequoyah Nuclear Plant. Outfall101 End Date: 11/24/2009 LablD: ETS-Envir. Testing Sol. Sample Type: DMR-Discharge Monitoring Rcpon Sample Date: Protocol: FWCHR-EPA-821-R-02-013 Test Species: PP-Pimephales promelas Comments: UV-treated Cone-% I 2 3 4 D-Control 0.8480 0.7180 0.7720 0.8700 11.3 0.8760 0.8570 0.7640 0.7550 22.6 0.7490 0.7960 0.8540 0.8060 45.2 0.7240 0.8160 0.8250 0.8650 72.6 0.8900 0.7750 0.8560 0.8140 100 0.7750 0.7570 0.9390 0.8670 Intake 0.8130 0.7260 0.7800 *0.7700 Transform: Untransfonned 1-Tailed Isotonic Cone-% Mean N-Mean Mean Min Max CV% N t-siat Critical MSD Mean N-Mean D-Contro1 0.8020 1.0000 0.8020 0.7180 0.8700 8.727 4 0.8153 1.0000 11.3 0.8130 1.0137 0.8130 0.7550 0.8?60 7.672 4 -0.247 2.410 0.1075 0.8153 1.0000 22.6 0.8013 0.9991 0.8013 0.7490 0.8540 5.374 4 0.017 2.410 0.1075 0.8153 1.0000 45.2 0.8075 1.0069 0.8075 0.7240 0.8650 7.381 4 -0.123 2.410 0.1075 0.8153 1.0000 72.6 0.8338 1.03%. 0.8338 0.7750 0.8900 5.997 4 -0.712 2.410 0.1075 0.8153 1.0000 100 0.8345 1.0405 0.8345 0.7570 0.9390 10.150 4 -0.729 2.410 0.1075 0.8153 1.0000 Intake 0.7723 09629 0.7723 0.7260 0.8130 4648 4 Auxiliary Tests Statistic Critical Skew Kwt Shapiro-Wilk's Test indicates normal distribution (p > 0.01) 0.939999402 0.884 -0.02446093 -1.22636643 Banlett's Test indicates equal variances (p = 0.91) 1.50255847 15.08627224 Hypothesis Test (1-tai~ 0.05) NOEC LOEC ChV TU MSDu MSDp MSB MSE F-Prob df Dunnett's Test 100 >100 0.107485809 0.134022205 0.000919567 0.003978306 0.943894863 5, 18 Treatments vs D-Control Linear Interpolation (200 Resamples) Point % so 95%CL(Exp) Skew IC05 >100 ICIO >100 IC15 >100 IC20 >100 IC25 >100 IC40 >100 ICSO >100 sqn/01 _I J-J7-09data-uv
TVA I Sequoyah Nuclear Plant, OutfalllOl -Intake UV-treated November 17-24, 2009 ~ETS -~ Environmental Testing Solutions, Inc. Statistical Analyses Larval Fish Growth and Survival Test-7 Day Growth Start Date: 11/1712009 Test ID: PpFRCR Sample 10: TV A I Sequoyah Nuclear Plant, Outfall 101 - Intake End Date: 11124/2009 Lab ID: ETS-Envir. Testing Sol. Sample Type: DMR-Discharge Monitoring Report Sample Date: Protocol: FWCHR-EPA-821-R-02-013 Test Species: PP-Pimephales promelas Comments: UV-tteated Cone-% 1 2 3 4 D-Control 0.8480 0.7180 0.7720 0.8700 11.3 0.8760 0.8570 0.7640 0.7550 22.6 0.7490 0.7960 0.8540 0.8060 45.2 0.7240 0.8160 0.8250 0.8650 72.6 0.8900 0.7750 0.8560 . 0.8140 100 0.7750 0.7570 0.9390 0.8670 Intake 0.8130 0.7260 0.7800 0.7700 Transform: Untransfonned J-Tailed Cone-% Mean N-Mean Mean Min Max CV% N t-Stat Critical MSD D-Control 0.8020 1.0000 0.8020 0.7180 0.8700 8.727 4 11.3 0.8130 1.0137 0.8130 0.7550 0.8760 7.672 4 22.6 0.8013 0.9991 0.8013 0.7490 0.8540 5.374 4 45.2 0.8075 1.0069 0.8075 0.7240 0.8650 7.381 4 72.6 0.8338 1.0396 0.8338 0.7750 0.8900 5.997 4 100 0.8345 1.0405 0.8345 0.7570 0.9390 10.150 4 Intake 0.7723 0.9629 0.7723 0.7260 0.8130 4.648 4 0.756 1.943 0.0764 Auxili!!!l Tests Statistic Critical Skew Kurt Shapiro-Wilk's Test indicates nonnal distribution (p > 0.01) 0.96844363 0.749 *0.33306569 -0.81375687 F-Test indicates !:9Ual variances (f2 = 0.30l 3.80257463 47.46722794 H~e2thesis Test (l*tail. 0.05) MSDu MSD£ MSB MSE F-Prob df Homoscedastic t Test indicates no significant differences 0.07642232 0.09528968 0.001770125 0.003093458 0.478019476 1.6 Treatments vs D-Control sqn/01_1 J-17-09dala-uv
TVA I Sequoyah Nuclear Plant, OutfalllOl- UV-treated November 17-24, 2009 Pimephales promelas Chronic Whole Effluent Toxicity Test EPA-821-R-02-013, Method 1000.0 Daily Chemical Analyses Environmental Testing Solutions, Inc. 5812 Cooceotn~tioo Control 11.3% 22.6%
-15.2%
72.6% 100% 100% lolllkr
~EJS Page 5 of 6 ~ Envtronmonl al f*JIInq Solutions, Inc.
Species: Pimephales prome/as Date: 1\ ell Client: TVA I Seguoyah Nuclear P lant, Outfall 101, UV-treated -I CONTROL UV-treated I I I 11.3% I 22.6% I 45.2% I I 72.6% I I 100% I I I 100% Intake I SOP AT20 - Exh ibit AT20.3, revision 04-0 1-09 Page 58 of 102 i*
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Page 6 of6 Concen-trat ion
~I CONTROL
- I 11.3%
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Page Y..3 I Page _ L of _1__ I
~ ~~TS Envtronmentii Tesrlng Solut1o n1:, lnc.
I Total Residual Chlorine (Orion Electrode Method, Orion 97-70) Matrix: Water, RL = 0. 10 mg!L I Analyst I 1=-ti
~0 Meter: Accumet Model AR25 pHIIon Meter I
lodi~e reagent: i:Nrl..3'5] Date analyzed 09 Actd reagent: t?-3'53 I I L aboratory controI stand ard: I Refere nce sta ndard number True value (TV) (mg/1. ) Measured value (MV) (mg/ L)
% RS = MV I TV x I 00 (acceptable range = 90 to t 10% ) 'l:NSSu"1? 0.50 0 * ~11 C\4.2'/
I Sample characteri stics I I I I Lo.oo*nl
£..0.00'-{03 I o.o1.~o LO.OOILAY I 0.001.00 LO .OOIS'2.
I I Nore: All sam ples were analyzed in excess of La boratof'J'_ controI stan d ard : Reference standard True va lue (T V) Measu red value (MV) =
% RS MV I T V x 100 )
I ~'SS~1? number (mg!L) 0.50 (mg!L) 0 . 1.\11 " (acceptable r ange= 90 to 110% ) _9S .LI*J. 11---f:~~--:-----i I Reviewed by Date reviewed Ifl1* O'\ I Page 60 of I 02 SOP C8 - Exhibit C8. 1, rev is ion 09*0 1-09
Page 45 I
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I Total Residual Chlorine (Orion Electrode Method, Orion 97-70) I Analyst I LFI(? Matrix: Water, RL = 0.10 mg/L Meter: Accumet Model AR25 pH/Ion Meter Iodide reagent: ll:.NI2 3S1 Date analyzed
- ll-l'\- 09 Acid reagent: _"J:NIZ.o'=a3 I Calibration:
I Laboi-atory control standard: 'I Reference standard number True value (TV) (mg!L) Measured value (MV) (mg/L)
% RS= MV /TV x 100 (acceprable range"" 90 to 110%) ~SS\1),"?1 0.50 Q.StO IOl..Q"/.
I Sample characteristics I I Sample ID Sample characteristics I I I L0*DOS?i3 LO*OO"'\0 I I I Note: All samples were analyzed in excess or EPA recommended holding time ( 1S minutes) unless otherwise noted. L aboratory controI stan ar, : Reference standard True value (TV) Measured value (MV) % RS= MV /TV x 100 I '+/-N~S\.D1? number (mg/L) 0.50 (mg/L) O-C:,02 (acceprable raage = 90 to 110%) IM.Ll-J. Reviewed by r-...,1'\'*""'~~-w---t I Date reviewed ~.._ ___.i;&.l:'*.._/4.;.*..;:0tf;..a..._ _, I Page 61 of 102 SOP C8 - Exhibit C8.1, revision 09-0 l-09
Page Y 7 I Page _ I_ of _j__ II -~TS
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Total Residual Chlorine {Orion Electrode Method, Orion 97-70) Matrix: Water, RL = 0. 10 mg/L
!I I LA0 Meter: Accumet Model AR25 pH/Ion Meter ~~-r-1::::.. ...~=.::.;'1...!-.----i I Analyst Iodide reagent: ~=~~~~-:1.:\-o::fj===~ Ac id reagent: 'I)\j~ 1 I Date analyzed L:~~~~--~
I L aboratory contraI stan d ard : I Reference stand a rd number True value (TV) (rng/L )
~easured va lue (~
(mg/L)
% RS = MV I TV x 100 (acceptable range = 90 to 110%)
- tN~S\a13 0.50 (').C:/X) \00.0/*
I Sample characteristics I I I I t..D.0008~1 L- o .OOOY"'S I o.oD213 o.ooeQ,B I t-0 .00408 t- D .0() '2.5\ I I Note: All samples were analyzed in excess of EPA recommended holding time ( 15 minutes) unless otherwise noted. Laborato control standard: Reference standa rd True value (TV) ~eus u re d value (MV) % RS = MV I TV x 100 I ( mg/ L) 0.50 o. (mg/L) (acceptable r ange= 90 to 110%)
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Reviewed by 11--..(,::b::J-1-:--..,..---i Date reviewed ..____al....t:]~-..::1.:...:1~*-=0~'\~~ Page 62 of 102 SOP C8 - Exhibit C8 .1, revision 09-01-09
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I Alkalinity (SM 2320 B)
= 1.0 mg CaC03/L Analyst I \~~
Matrix: Water, RL Time initiated I OOSl.!>
- ==\~\.\:s:.:,:)j===~ :o:9:tt:l:.=======
I Date analyzed Titrate samples to pH= 4.50 S.U. Time completed L. Titrant nonnal/ty and multiplier determination: I pH of Deionized water Titrant reference Normality check standard Begin ml End ml Total ml Normality (N) of H 1SOc
=(5 ml Nalcol K 0.05)/E =0.15/E pH Factor or Multiplier* =(N x 50000)1100 ml sample =NxSOO =4.5S.U. number number (f:) (acceptable range~ 0.0180- 0.0220)
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a'LQ ll..O D.Ow6 ~oA Lab~~~~1D lJ
.. ~
cofilio)'~ tan aiil: I Reference standard number True value (TV) (mg CaCOJIL) Sample volume (ml) Begin ml End ml Total ml Multiplier Alkalinity (MV) (mgCaCOVL)
% RS =MV I TV x 100 (acceptable range =90 to 110%) \NS&~~ 100 100 a,. -s '0*~ ~ OA.o*t.
I 12.() q.~ Sample Alkalinity %RPD= I Sample number Sample ID volume Total Multiplier s ( mg CaC()y'L) ((S - D) /((S+D)/21} 1 100 (acceptable range=- ::t: 10%) ll.1"2..o11+ rn>>s ~w ,q Lol I ~ Duplicate (B)
.{
D lol ~ Matrix spike recovery: I Reference standard number Spike value (SV) (m2 CaCOJIL)
. Sample volume (ml)
Begin ml End Total Multiplier Spike alkalinity (A) (mg CaCO,!L) ml ml
\NSS T-~4 !e.z.
I ~ IOU A~.'t 108 \0~ 110 Sample alkalinity (B) Measured spike value (MV) % R=MV /SV X 100 I (mg CaCO.YL) lQl MV.::A-B (mR CaCOJIL)
"\C!
(acceptable range
=75 to 115%)
qe.u 1~
- I Sample measurements:
Sample number Sample ID Sample volume (ml) Begin ml End ml Total ml Multiolier Alkalinity lm2 CaCO.v'L) lf\H*~ H7-0 \£)) t.o.o LoA* I t\*\l-tn8 h*\4-09 -.J 13e.2
~"*
o.o 5.0 -o.e 2.. ld2. (00
\1.0 'f.-o9 5:LH SuJ H.3~.i ~8D 10.3 II()
I f'i\U.J S ~ ~nn,..,. 'v
..t s.e ~-e ~0 ~~
Cl~ lll"l..* a!~ ~C,~ ..,j q.3 q_s o.z. 2.1 I oq H l\*Of OC\ U I 0 .0"1:...
~- p"Jbt ~<d \
60 tOO q..; 2o.n \O.S
~YO ?.~.1- /),.,.
(2) 22.0
~8 z I~IA.9- ifAS'.3 01-~ A1-I 0'1\k"Z..O"'"L o'\ 'U'*t. o'-1 '
J --3 J I N:)~ ae.2. ~.0 ' ~1' Reviewed by: I 1\* 'S*O~ I Page 63 of 102 Date reviewed: SOP C6 - Exhibit C6.1, revision 06-29-09
l\ifl3b4.i.t t wz;.H
- I Page (t Page 2, of I ) Environmental Testing Solutions, Inc.
I Alkalinity (SM 2320 B) Analyst I l6t..v Matrix: Water, RL = 1.0 mg CaC0 31L Time initiated I '>.._ J--.....;:a....c::::::e~---1 I Date analyzed 1\ _1'5' .Q, Titrate samples to pH:: 4.50 S.U . Time completed
' ~ and multiplier determination:
I pH of Deionized water Titrant reference Norm~ check standard Begin ~nu ml ml
-~
ml
. ~5)/E Normality (N) of H1so.
E pH Factor or Multiplier
= (Nx 50000)/100 ml sample =Nx 500 =4.5 s.u. number number ([) (acceptable range ::: O.v auv ~1 I --~
Laboratory controI stantJar,d: I Reference standard number True value (TV) (mg CaCOVL) Sample volume (ml) Begin ml End ml Total ml Multiplier Alkalinity (MV) (mgCaCOVL)
% RS::: MV /TV (acceptable range =-90 to 110%)
X 100 I NSS1'-eM q.s- IO*~ ~9 q~.D'I. I 100 100 ~e.z. 31.-::J. Sample Alkalinity %RPD = I Sample number Sample ID volume Begin End Total Multiplier (mg CaCOYL) ((S- D) /((S+D)Il)} x 100 (acceptable range"": 10%) I I Begin End Total Multiplier Spike alkalinity (A) (mgCaCOYL) ml ml ml I .":f-Sample alkalinity (B) Measured spike value (MV) % R =MV I SV x tOO I (mg CaCO)I'L)
\lO MV=A-B (mR CaCO)I'L)
(acceptable range
""75 to 125%)
loo.u*t. 6D samp1l e measurements: I Sample number Sample lD Sample volume (ml) Begin ml End ml Total ml Multiplier Alkalinity (mg CaC()JIL)
"PJ( .dq.. l().) 10.~ 14 I b.U.tiV'\
R>l KJ{i'Jt/1 6~ Bn Cl:~ Cl.3 q,e l.?J o.c5 ~.2.. tct.tJ lDR,*~,, &.C!ct.,. lo.o \\*'0 t.~ 11-I ~l\l~iVVt 6~ Lt..tttt ~ iVill 5hn a\ ll~ l2.y
\2.'"" o.e 9.3 l3PI I*S l<t>
I 'loll~
~\0 V>'5et \JwtN -f"t.
lo~ 6"~ 15.~
\~(.p l.':}-
20
*e "2-1 ,loiose~ L(.Z...
I \ llil5e3 T3
'N ...
1":1-v
\6-Z \8~
(q.(l o.c..\ 1.4 ,c; I (\- lS* C'i I Page 64 of 102 Reviewed by: Date reviewed: SOP C6 -'Exhibit C6.l, revision 06-29-09
I Page _1B___ I )
~~T£Envlronm~~ntal Testl119 Solullons, Inc.
Page 2 of.......;.3~_ I Alkalinity (SM 2320 B) Analyst I J}ji;)A... Matrix: Water, RL = 1.0 mg CaC0 3/L Time initiated I "=..... Time completed 1-___;::......~c::-----1 I Date analyzed II* ~~ .Q4 Titrate samples to pH= 4.50 S.U. Titrant normality and multioller determination: I ...U ... I' D;ionized water Titrant reference Normality standard R .. nin End
-;r- hnt-- -m.L_ .._ Total Normality (N) of H1S04 =(5 ml Na1C03x 0.05)/E ==0.25/E pH Factor or Multiplier ** . =(N x 50000)/100 ml sample =Nx 500 =4.SS.U. number number lEl (ac .... n2e- 0.0180- 0.0220)
I Laboratory control standard:
~ ----- J-I Reference standard number True value (TV)
(mg CaCOJIL) Sample volume (ml) Begin ml End ml Total ml Multiplier Alkalinity (MV) (mg CaC()JIL)
% RS=MV/TVxiOO (acceptable raage =90 to 110%)
I tNSS 7?>'-( 100 100
~-t.P ~2 q~~ lo.~ 00 l{)J.(J/.
Alkalinity 0
/oRPD==
I Sample number SampleiD Multiplier (mg CaCOy'L) {(S- D) /((S+D)Ill} X 100 (acceptable range :2: 10%) 5a..U SuJ
- Mlf!,trix sp1ike recovery:
Duplicate (B) I Rererem:c: number
... .... lii: .. a, ..
(SV) (me CaCO.JL) value Sample volume (ml)
- *o*
ml li"nd ml Total ml Multiplier Spike alkalinity (A) (mgCaCOYL)
-r I \N~1~f 60 }l)) \QaY Sample alkalinity (B) Measured spike value (MV) % R = MV I SV x 100 I (mg CaCOJIL) MV=A-B (me: CaCOJI'L)
(acceptabl~ range
= 75 to 125%)
tA-o I amp4 e measurements: Sample number Sample ID Sample volume Cml) Begin ml End ml Total ml Multiplier Alkalinity. (mg CaCOJIL)
~ tg(Dca6'"/ ~:5 \Jv.hn 6fl.q 1Jfl to.c..~
I ~v~e~ j{p ~
*lOO J ~~*~ ~.'1 at8 (OJ 4.3 ~0 !1iUCM. ll 1-lf J\f u..Uo l a.s 3t.e, J'-J.f,t, ~.e 'N) .2.D I oDa II 10*0 I J
I 3 z_ J
\ a&tep o-l..~
31S .z_q I J lzO (20 tAll' 7_ .0 l c.to.\f i*tA I I ;z
~
Jh ~ J ---- h\* lS* o\ I Page 65 of I 02 Reviewed by: Date reviewed: SOP C6 - Exhibit C6.1, revision 06-29-09
r** ~ElS
' . ) .............,.,..., ..,,_IM.
Page _ _ _of ~ Page _2_1_ I ~. Analyst I 6sL Alkalinity (SM 2320 B) Matrix: Water, RL = 1.0 mg CaCOj/L Time initiated lj.....:..:lD:...5"-llo"'-----~ Date analyzed 1l* ).d. . O'j Titrate samples to Time completed '-..;.1~)..:.q:..:z:::;.__ _ _..J I' pH= 4.50 S.U. T/Jrant normality and multiplier determination: pH of Normality Normality (N) of H~so. pH Factor or Multiplier.* Deionized Titrant check Begin End Total = (5 ml Na 2C03 1 0.05)/E = (N x 50000)/100 ml sample water reference standard ml ml ml = 0.25/E s:rNx 500
= 4.5 S. U. number number (E) (acceptable range"" 0.0180 -'0.0220)
I &\ 1L. Q..orrec.-t\~t) ~ D .c -) o - o. I \ L aboratofll control standard: *' - IYl ll.<o IO.i I Reference standard number True value (TV) (mg CaCO.v'L) Sample volume (ml) Begin ml End ml Total ml Multiplier Alkalinity (MV) (mg CaC()y'L)
%RS=MV/TVxiOO (acceptable range .. 90 to 110%)
100 100 C\~ 'l) .1- 'ou.0 £o
'ov I ll.'t> Jt.":l Alkalinity %RPD=
I s Multiplier
\0.1 s
(mgCaCoyL) (.p~ {(S - D) /((S+D)/21} 1 100 (acceptable range= :t: 10%) I .M atra. sp~ike recovery:
\\:>.'1 D \c,2-I Reference standard number Spike vaJue (SV)
Sample volume Begin End 1-mL. Total Multiplier Spike alkalinity (A) (mg CaCO.v'L)
- I"l--SS 13Lf (m~tCaCOYL) 5o (ml) 100 ml
~1-.5 0~*21, ~ ~ .. mJ-:.... ~ _, ,~,-:} 12.0 r.r:
Sample alkalinity (B) Measured spike value (MV)" % R = MV I SV x 100 li (mg CaCOJIL) l_q~ MV=A-B (mRCaCoYL) 5'0 (acceptable range
""75 to 115%) \ \ \2°Lo sa_mpjl e measurements:
I Sample number Samole ID Sample volume {ml) Begin ml End ml Total ml Multiplier Alkalinity (mg CaCOJIL)
'\. "21*0~ m H~ t-~.,u ~.0 5_.1- lc.1- '-o\
I \\ .. *t1-o'\ S~vJ
\00 ~~.;
M.D 47.2 3.2 .:3'+
\l J1...0'i rrnt*~ '-'..a 0.0 5.~ 5.'0 to2.
I J).. -1.-0'1 U-r".l .. cJ~
~ a...k:.l 6LA.J ...Jc: .\) \7- ...u.J U) .9..1 "*f IQ.~ -" .l ):"\t6.
i'O.'l.
~lq':} ,,0 I U*l"'*O~
ll* Z.I*O 'i oj ..-I-
\9.~ ~"'!> *~ ~sq 3:t.~
q_\o
\0.4-lee "0
O,lll~.~ -rJA PAI=aH 5:v (;1.) 110 ~ ,01-I O"\ ll .OS J I 2. 50 4
.~q ~ .r.w.;
HL+.~
~-~ s.z. J -~ hu: Jll Reviewed by: Date reviewed: I \\* U *Ol\
Page 66 of 102 L*'* SOP C6 - Exhibit C6.l, revision 06-29-09
r-- I
~ETS .) Envlron""'"l T*uln; Solullon*. Inc.
Page sX Page of2 016 (/) Alkalinity (SM 2320 B) Analyst Date analyzed I Marrix: Water, RL = 1.0 mg CaCO/ L Time initiated Time completed Il=......_,_-=:::::::::4fJ=---.,-----IJJ I ttrant normality and multiplier determination: Tit rate samples to pH= 4.50 S.U.
"'ptr-L I Deionized water Titrant reference Normality check standard ~~6'"
ml
~
ml Jntal ml Normality (N) of H 2S04 (5 ml Na 2C03 1 O.OS)fE 11/! tT:' pH Factor or Multiplier
- (N x 50000)/ 100 ml sample Nx 500 4.5 s.u. number number (E) (acceptable range 0.0180 - O.O..:..:u1 l.t.
I L aboratory control standard: Reference sta ndard I number True va lue (TV) (mg CaCO.YL) Sample volume (ml) Begin ml End ml Total ml Multiplier A lkalinity (M V) (mg CaCO.YL)
% RS = MV I TV x I 00 (acceptable range = 90 to 110%)
- r't-..)'5.5 -:t~4 100 100 'D .D (\ .'S g::; ) 0 .1- lOo \ C>CPlo I
Alkalinity % RPD= I End T otal Mu ltiplier s (mg CaCO.YL) ((S- D) / ((S+D)I 21J (acceptable range=+/- tO%) X 100 D I Matrix spike recovery: I Reference standard number Spike value (SV) (mg CaC O.YL ) Sample volume (ml) Begin ml End ml Total ml Multiplier Spike alkalinity (A) (mg Ca CO.YL)
- IN SS 1- 2, Y. ~~~0 '5D lv-+) ~-+ .';_, 'i.B ("l.) I C.l- 2.J0 I sa*mple alkalinity (B) Measured spike value (M V) % R = M V I SV 1 100 (mg CaCO.YL) MV=A-B (accepta ble range I ll O
( me CaC OYL l l ou
= 75 to 125%) \OOU(_,u samp,e measurements:
I Samo le number Sample lD Sa mple volume (ml) Begin ml End ml Total ml Multiplier Alkalinity (m!! CaCO.YLl 0'\ II I 1... 01.- 11fA - PAP l'IOI in t- I 50 ~'-l-3 ~GB. 5.l; t-i) \ \) .1- 120 I o'\ \\1 2
- 0\. I 1-J I ~Ci.<l ~5. 16 5 ."' 1 J
l ~o : 11(p 0~1\'2..0 . 0{ J .3 .lfi-B i-1-1 .~ 5.5 12.o ""1\B I /")~ '\\k'. 0., 1VA PflFflOZ IW 6U '1-l ~ l-t?.2 ,:;~ C#'l 130 -:.. \1.1J1 t')~ \\ \&. 0 8 I !JP,;,- o.o 5.3 5 .3 \I 0 ~ H? I o\l\ \~ . 6'\ ItA 5.3 11 .0 '5.1 l ~o ~l~2 I D"'\ \l\k. I 0 J ftBArt .., II 0 llD Cj 59 130 ::tw opt\ \11 .05 flfA- <bJJ ~o 1 ' 5D >v.q ~ 1.4 '-+-~ l1-) G)tp I d'l \\ ~~. 63 J 2 ./ .:?J,'-t J+.) 3..1 J *--- ulP Reviewed by: Date reviewed: I \,. 1.1.- o'\ I Page 67 of 102 SOP C6 - Exhibit C6. l , revision 06-29-09
d.. ~
~ET£ Page Page 3 of ..&--'- {; ) Envt ronmfnUI T11tln~ SolutiOf'lt. Inc.
Alkalinity (SM 2320 B) Matrix: Water, RL = 1.0 mg CaCO/ L Analyst lPG< ~/<y\N Time initiated ~...::""-===-..----1 Date analyzed 11 .00 . 0 Titrate samples to Time completed -- L--------' pH = 4.50 S.U. S":' pH ot Deionized water
"'4.5S.U.
ttrant normaI ity an d mu IttpJ Ti tr a n t refere nce numbe r l l/er determination:
._!'lorm a li ty CliecTr-s ta nda rd number D.
ml in End ml T ota l (E) Norma lity (N) of H 1S0 4
= (5 ml Na 1C03 x 0.05)/E 0.25/E (acceptable range- v . n " ' '" '
pH Factor or M ultipl ier
= (N x 50000)/ 100 ml sa mple - Nx 500 I L aboratory contra standard: -r-Reference stll ndard T rue va lue Sa mple Alka linity (MV) % RS = MV /TV x 100 I n umber (T V)
(mg CaCOVL) volu me (ml) Beg in ml End ml Total ml M ult iplier (mg CaCOVLJ (acceptable range
=90 to 11 0%)
- f"-JSS 1; <-\ 100 100 d "-tS ~ :v q_( lo .+ 10'2.. 102...-&i.-o I A lka linity % RPD =
((S
- 0 ) / ((S+ 0 )/21} x 100 I
End Total M u ltiplier (mg CaCOVL) (acceptable r ange - :1: 10%) I Matrt.x spt'ke recovery: I Referen ce standar d number Spike va lu e (SV) (rng CaCOYLI Sa mple volu me (m l) Begin ml End ml Total ml Mu lt iplier Spike a lkalinity (A) (mg CaCOy'L)
- I:'NSS l-3, !.\- IOD ~ 31-./ LJt./.1 '}. 1.0 ll) \0 .=1- lvo I Sa mple alkalinity (B) Meas ured sp ike va lu e (MV) % R = MV I SV x 100-(mgCaCOVL) MV=A- B (acceptable r a nge I ~2.
(mg CaCQVL) Cf8
= 7510 125%)
ct {3-0 't. Samp*e I measurements: I Sam ple nu m ber Samp le ID Sample volume (m l) Beg in ml E nd ml Tota l ml M ultiplie r Alkalin ity (me CaCOYL) o~ 11n . ole I IA -.5&JJ J n+ I 60 ',() .3./ 3.1 tz) l 0 .-:t {N I o" l\1~ . o'i o'\ '\ "Z.C ._os J 1 '].. 3 3.1 {,~J C... J 13.11 3 .0 a.? 56 14cf e.6 I ol\ 1\
~\\\~ . (.)~ \1
- a'S l vA.sGNIO\IN 1 I z ll .D IZ~ O t"'.Cl 3.2
- l .")
~9 &Z.
a'1 II'Z.O . cl--j J 3 N.~ 11- ~ -;,:r- ./{8 I Ol111l,,(J (.., JJAc.S~ Jntw 1 ('},-:;. z..o,8 3. I lJu O'illiX
- OY I 2 I.w.J. -e &l.3. ~ ~.g ~0 o"\ 111..0* oS J 3 ~3.ep O..v.I..P 3.0 c.....e-- v..f Reviewed by:
(J\ Date reviewed : I 1\*11- o'\ li Page 68 of 102 SOP C6 - Exhibit C6 . ! , revision 06-29-09
Page ~4 i.-=J
)~ .~ ~ Page .Y. of B: l{J ) Envl,onn-..nt*l Tf'ftfno Sohlllon~o Inc.
Alka linity (SM 2320 B) Analyst l Matrix: Water, RL = 1.0 mg CaCO;/L Time initiated I Date analyzed T itrate samples to pH= 4.50 S.U. Time completed :=.==~=:==
. . . =====:
Titrant normality and multiplier determination: pH of Norma li ty Nor mali ty (N) of H 2SO* pH Factor or M ultiplier
..Q.
- T itrant check Begin End Total == (5 ml Na 2 C03 x 0.05)/E = (N x 50000)/ 100 ml sample water
-4.5 s.u.
reference numbe r n um ber ml
-- ml ml r:J<\ = 0.25/E (acceptable range 0.0180 . 0.0220) = Nx 500 Lab oratory controI standard:
Reference standard Alkalinity (MY) % RS = MV I TV x 100 I T rue value Sample number (TV) volume Begin End Total Multiplier (mg CaCOYL) (acceptable range (mg CaCOYLl (ml) ml ml ml
- 90 to 110%)
100 T't--ISS '1-34 100 ~~ -~ l~*2.. CJ.U? 10.'1 /IJ3 tOj. o 'I-I A lkalinity %RPD = I End Total Multiplier s (mg CaCOYl) {(S
- D) /{(S+D)I21J x 100 (acceptable range= :1: 10%)
I D atru: sp,ike recovery: I Reference standard number Spike value (SV) (mg CaCOVLl Sample volume (m l) Begin ml End ml Total ml Multiplier Spike alkalinity (A) (mg Ca COYL) 3'NbS 4-~+ ~DO a-r 31t.5' ~L(I 6.1 '~a :+ ~~n I Sample a lkalinity (B) Measu r ed spike valu e (MV) % R=MV / SVxl00 (mg CaCO,!L) MV=A - B (acceptable range I 13 ( mg CaCOYll
- ?o?
=75 to 125%) }03.5 1.
Samp_.I e measurements: I Sample n umber Sample ID Sample volume (ml) Begin ml End ml Tota l ml Mu ltip lier Alkalinity (mgCaCOYLl o<1 1\ \'\ , <J"L- bvJO.inVI 2. OlS" '--11.~ ~2.0 o.~ l~) \0 .'1- I f-I n"' 1\ 21 .o \ J 3 ~ LJz.o l/'2,3 6.3 J 13 0~ L\ \1. 01- I;J,J mmcJtn I loa ':}, t-4 1 0.~ u-s I o'\ \\\£1. c~ ,"' 2 \ /3:') t'fl:(; "'*'
- 6. 0 bl./
0'\ \\ "2..\.C'L.. ~ 3 ~ / (3.$ ~32 t.i.t* 0[) 1111 o\ +o f>l.encJ l ~?) 2. '15.~ ~ l ~ LilJ I o~ 16~ \l t'i. ol.. -ro I
'1-50 I I ~.::;.(0 ~P>.o ~.4 Ll-)
I b'l 0~ 11 2 1 .0 \ ~0 t. J 3 ~ p'{e .o W?.e 1*9 J 3e I Ll-11 lot'.iWl Jou .3o.o 31.P> t.e - lq
' Reviewed by: ~I Date reviewed: I I\ *tt-0'\
I Page 69 of 102 SOP C6 - Exhibit C6. t, revision 06-29-09
TS Page :2 Page - of
~-"5'---
J? U' Alkalinity (SM 2320 B) Matrix: Water, RL = I .0 mg CaC0 3/L Analyst I~ 1~ Time initiated I'-. . . . Time completed f-_.;:==--""'~=----r.-----i Date analyzed 1\ *d.J. *O Titrate samples to I Titrant nv ......." ,h/"l'"r determination: pH= 4.50 S.U. pH of Norma lity --=--~OJ Normality (N) ofH 1S04 pH Factor or Multiplier I Deionized water Titrant reference check standard Begin ml End ml Total ml =O*.l!lt ~ X 0.05)/E
~ = (N x 50000)/ 100 ml sample = N x 500 = 4.5 s.u. number number (El (acceptable range= 0.0180- 0.0220) r-------_ ~
tl I L ab oratory contra stan dard: Reference standard True value Samp le Alkalinity (MV) % RS = MV I TV x 100 I number (TV) (mgCaCOfl_) volume (ml) Begin ml End ml Tota l ml Multiplier (mgCaCOfl_) (acceptable range
= 90*to 110%)
100 100 loo 101.),0'/.
- r.~ss1-34 31-8 41.1 'L3 \0.1 I
I.e Alkalinity % RPD= {(S- D) / ((S+D)/21} x 100 I Sa mple End Multiplier (mg CaCOfl_) number (acceptable raoge 2
- 1: 10%)
10.1 s D I M.atrLX spt'k e recovery: I Reference stand ard Spike value Samp le Spike a lka linity (A) L numbe r (SV) volume lkgin End Tot a l M ultiplier (mg CaCOfl_) r (mgCaCOfl.l (ml) ml ml ml JNSS134- ~ /OJ 31-~ 3~l. ~-0 \O.t 1-3 I Sa mple a lkalin ity (B) Meas ured spike va lue (MV) % R = MV tsv*x too (mg CaCO,!L) MV=A-B (acceptable range
=75to 125%)
I 20 (mg CaCOJIL)
'63 IO<J.o *t, samp1e measurements:
I Sa mple numbe r Sample ID Sa mple volume (m l) Begin ml End ml Total ml M ultiplier Alkalinity (mgCaCOfl_) 5t.UC(n, K.1 IJU) I \oo 3B,z. l~lJ o.9 10 .- t- q_~ I -1 Bl ~ Ki~Vt StufUT"
- 2. l J
3'1.1 '(o.o OP,
~o .fl '-40.5 0.5" I
j_ q-"
"1.'-1 I
I ~
..- -- ~ ~ ~
I - ----_.... Reviewed by : Date reviewed: I 1\*ll*O~ I Page 70 of 102 SOP C6 - Exhibit C6 .1, revision 06-29-09
2lp
~ET£ Page Page lo of - (o -- ) Envfronmenu l Tullng Solutlonl, lnc.
Alkalinity (SM 2320 B) Matrix: Water, RL = 1.0 mg CaCO/ L Analyst ~ Time initiated I \: Date analyzed =c;1;:oc, Titrate samples to Time completed t----'::......:q::::-------; pH= 4.50 S.U. Titrant *w ,.,.Jity and m.oltipller determination: pH,~ Normality Normality (N) of H 2S04 pH Factor or Multiplier I
~
Deion check Begin End Total = (5 ml Na 2C03 x 0.05)/E = (N x 50000)/ 100 ml sample water e standard ml ml ml = 0.25/E = N x 500
= 4.5 s.u. Jei number (E) (acctplablt r3ngt = 0.0180
- 0.0220)
I Laborato.y control standard:
~ ~ = ~~
Reference sta ndard True value Alka linity (MV) % RS MV I TV x I 00 I number (TV) (mgCaCOVLl (ml) Begin
"'- ml End ml Total ml Multiplier (mg CaCOVLJ (acceptablt range
- w 90 to 110%)
100 100 I n,.,,,;,.,.,, sample " ' .:.
~
Sa mple
"' Alkalinity % RPD= ~
((S . D) / I(S+D)/21} I Sample Sample ID vo lume Begin End Multiplier (mg CaCOVL l X 100
~
number (ml) ml ml s
~ ~
Dupl icate (B) D I Matrix spike recovery; I Reference standard numbe r Spike value (SV) (mg CaCOVLl Sample volume (m l) Begin ml End ml Tota l ml
""' ~
Multiplier Spike alkalinity (A) (mg CaCOVLl I Sample a lkalinity (B) (mg CaCOVLJ Measured spike va lue (MV) MV = A-B
% (acct R = MV /~~~
I (mg CaCOVLl = 75 to 125% ) sampje measurements: I Sample number Sample ID Samp le volume (ml) Begin ml E nd ml Total ml Multiplier Alka linity (mg CaCOVLl 1\-n.- ol\ A rn H~ uu I ltD '-\().5 l.\~*2 6~ 10.7 lol I \\-\"2..-c.f\ & 2. ~l.lP ~"./-~ S. t3 i.tJZ 1\- ,,_o'\ 3 a::t.~ £ .1 5 .1 w y. I
' {Q I t \-I'\* 0~ 33.1 36-6 5.1-- ' ~
I I 1--' --- L.---- - lbt y---- Re viewed by: Date reviewed: I \\* 1.1..-01 I Page 71 of l02 SOP C6- Exhibit C6.1, revision 06-29-09
~ETS Page ll Page _ _.:._ \ of :J ) EnvtrontTMnUI Tutino S~uhonJ, It\C.
Total Hardness (SM 2340 C) RL = 1.0 mg CaCO,/L Analyst t _,_J)_t;_;v._ _ _ --4 Time in itiated ~~ o~CJ~W::..:::.___~ Date analyzed . __ 1! *IS -LT) __:..__..:___ _..J Time completed L..--=0....::6~L-i...:....:.. 6:......__ _....~ Titrant normality and multiplier determination: Titrant Normality check Begin End Total Norma lity (N) of EDTA pH Factor or M ultiplier reference standard ml = 0.2/E ml ml = (N x 50000)1 50 ml sample number number (El (acccplablc range= 0.0 180
- 0.0220) = Nx 1000 IJJ ~:?Z.. I.N 55 U).::ll.p o.o IO .o I<) . c.) 0 *020 :Z0-0 L aboratory contra I standard:
Reference standard True va lue Sa mple Hardness (MV) % RS = MV I TV x 100 number (TV) vo lume Begin End To ta l Multiplier (mg CaCO,IL) (accep18 ble range (mg CaCO,IL) (ml) ml ml ml = 90 IO 110%) I ).J"S !:.]D 2.- 40 50 \O .o lZ,o 1, 0 .to.O '-\ 0 ~oo .o*t . Sa mple Hardness "I. RPD = Sample Begin End Total Multiplier (mg CaCO,IL) {(S- D) /f(S+0 )12f) x 100 number ml ml ml 11-11-* 0c,A .~ L.{ .~ :zo-o s .1 ~ -.l '-\.5' ~ ii atrLX spt e recovery: Refe r ence sta ndard Spike value Sa mple ~p ik e hardness (A) I numbe r
\rJ~~ToZ...
(SV) (mg CaCO,IL) 41.) volu me (ml) 60 Begin ml f tq*~ End ml
~ IQ.S' Total ml M ultiplier '2D*O 130 (mg CaCO,IL)
I Sa mple h ard ness (B) (mg CaCO,IL) Z?>o Measured spike valu e (MV) MV = A-B
% R =MY I sv X 100 (acccpra blc r ange (me CaCO,IL)
- 7S lo 12S%)
C!O '-\0 100*0*/_ sample measurements: Sample vo lume Begin E nd Tota l Ha rdness Sa m ple number Sample ID !mil ml ml ml M ultiplier (me CaCO,ILJ Blank TV=ND (should be = 0 mg CaCOJIL) 6D Q,() l) rO o.u z.o. o rvP I \1* \l. 0~ 11 . I 1-\ . 0"1 6 (Y1 Hs J Hv:> ~3.0 tA~-~
~~.5 .3:2,n I-{.}:' ~-S CfO 0() ' (IJ t~ t..f1Y PPJ 0'2.0 ~4 Ljq qe I tnaJ ShaJ....L (T\0.1 s h.c.u).. '3lP.0 4/.£1 '5-0 100 o~J\ 17. .<:6 c,y-Jec.., 4\ Yl 4Z.Z.. 0*3 14 .0 I o~ \\ \t.o~ ~e.m- p,l~ In oo .3A 3.~ IC5) 3=\0 Cl~ l\ ICl . <rz_ ~oc-J I 'CD 391 '1-.0 3.1 lpZ.
I 0'\\ \ \ "L O"'L-
~'i I \1 ~ . 0 '-(
I J 3 2 J I '1-P 0-~ 9 ._3 1.1 q~ 1-1.0 ' z~ 32-Pti!!f!- r;Y..? rJjil~gtrant is used, sample must be diluted. Reviewed by: L---..t;;:&,.+..l'--- -....1 I \\- 'S -09 I Date rev1ewed SOP C7 - Exhibit C7 . I, revision 06-29-09
Page 1(3 i-=J
)!; -.- ;;) ~ Page - -of -].- - , ) £nvfn>>nment*f Tnrif\9 So'uHonL Inc.
Total Hardness (SM 2340 C) Analyst I 16Lv RL = 1.0 mg CaCO/ L Time initiated I . . . . . .____ Date analyzed ~===l\~*=1s::.(J:t)===~ Time completed 1--___;~-'""'Jo:r---~ pH Factor or Multiplier reference = (N x 50000)/ 50 ml sa mple number number = N X 1000 Laborato control standard: Reference standard True va lue Hardness (MV) % RS=MV / TVx 100 number (fV) End Total Multiplier (mg CaC03/L) (accrptable range (mg CaCOYlJ = 90toll0%) 1oo.o l Hard ness % RPD = Sample Begin End Total Multiplier (mg CaCOYl) {(S- D) /{(S+D)/21} x 100 n umber ml ml ml s 1'2.0 lZ.S 0 .'5 20.0 lO
.j D l2.lJ 13.0 o.s aD Spike ha rdness (A)
Begin End Total Multiplier (mg CaCOYl) ml ml ml l2S r5o 1.:;; 10.0 Sample hardness {B) Measured spike value (MV) %R = MV I SV x 100 (mg CaCOYl) MV=A-B (acceptable ra nge (mgCaCOYl) =75 to 125%) 10 40 10o,o*r. sa~n_E . e measurements: Sample volume Begin End Total Hardness Sample number Sample ID (ml) ml ml ml M u ltiolier (mg CaCOYl) TV *u Blank IL (should be = 0 mg CaCOVL) 6,0 '20.0 1e 6~1111 Thr,aCi 10\ ~.LR* ~v. 'P.Jt .Jq_. 6D 15~ 6~
\ ~.2-O.c, f)_?, ft,.o lat~ ~ Jff\ "0~ .&t. Ill. "2 ,q,() OB l'-t1 11'>\U ,' Ju s~ l':i.O 16 - ~ 1.3 Z<..p l..tili1.0 Rl ~ t.-1 s n]\..rr1 . 183 A.'-I I. I ' 2-Z --=::::: -~
P/ite:lfJ> {}f'Vr:tJPtrant is used, sample must be di luted. Revtewed by: Date revtewed I \\*\~-0~ SOP C7- Exhibit C7. 1, revision 06-29-09
Page lq lETS Page
- - -of 4- . ~ Envtrol\m~t~l r, 1tJng Solution I. Inc Total Hardness (SM 2340 C)
Analyst I Bs Date analyzed !--'1""'1.::. L
*&?--.-o 5--~
RL = 1.0 mg CaC0 3/L Time initiated 11--'D::;.._C\.;. .1:...2"-----l Time completed L.._l;_u_-4--=5::......_ _--J Titrant norma Iii)! and multiplier determination: Titrant Normality check Begi n End Total Normality (N) of EDTA pH Factor or Multiplier reference standard ml ml ml = 0.2/E = (N x 50000)/ SO ml sample number number {E) (acccplable range= 0.0180 - 0.0220) =Nx 1000 O.C20'+
.:r ~e. -33::2. J:'tv'S.'S LP5 ~ o.s )0 .3 Ot .1:0 ~l:'sl. e .2:el tre.:..... O?D .~
L aboratory contra stand ard : Reference standard True value Sa mple Hardness (MV) % RS= MV / TV x 100 number (TV) volume Begi n End Total Mu ltipl ier (mg CaCOVLl {acceplable range (mg CaCOVL) (ml) ml ml ml =90 10 liO%)
):'rJSS t-o2- 40 50 to.:, \~.:;>... I.G\ ~O .Y ;3q ~q'J.s*1.
Hardness %RPD = ~. Multiplier (mg CaCO.YL) {(S - 0 ) / [{S+0)/21} x I 00 I J_ s D I atrtx spt'k e recovery: Reference sta ndard Spike va lue Sa mple Spike hardness (A) I number r tvSs -=to1-(SV) (mg CaCOVLl Jf o vol ume 50 (m l) Begin ml
\~ . '5 End ml ..<3 {) (Q,S Total ml Multipl ier c;Rb .Y.
{mg CaCOVL) 13 0 I Sample hardn ess (B) (mg CaCOVL) Measured spike value (MV) MV=A-B
% R = MV I SV x 100 (acceplablc raoge (mg CaCOJIL) ~ 75 IO 125%)
I Samp,I e measuremeflts: (\() J{o IDoSlv Sample volume Begin End Total Hardness I Sample number TV =ND Blank Sample ID So {ml) ml
~3 .o ;?3.v ml D.D ml Multiplier Ol\) .'4
{me CaC03/L} tJO (should be = 0 mg CaCOJIL) I I\ *ZJ.Lf\
~ 1- l~-o'}
JQHS HvO ssco
~..) .0 ~1. 1 <>7-=t.l I~ .:A 41 ~.\
84 _:+3 ltw I 11*11 -0"' 1\
- n.~ o4\ 1\
mHs
/)'} rt s uu I otl.l.
33 .v 33.\P
- 316 .0
>-+ .lf 4 .4-C\0 9o \ \-\"1.-0C.. b 2- 3\3 .0 Jf;;l.:S 4.2., 'B<c I 1\-n -c'\ 3 ;f,;l,-1 <+0.1- Y-2-l-_ 90 ~(p \\- \~
- 0~ tf _.J_..
00 '-+-.:2. 4~ I ~\\\1...()\ 0'\\\\&- 05
---rv J.. - PltF 001 l 2 I 10 j
4 .1}..
\o.q
[ () ,q n .~
\p .'1- \t .'+ IJ
(~) _I-- lQ'60 ,.Lf6.3 l£50 ::- U1'5.3 I II- zz <Ji I Pti~ f1¢ 'Oftlj(j J!lrant is used. sample mus1 be diluted .
- Reviewed by: I~ Da te reviewed SOP C7 - Exhibit C7 .I, revision 06-29-09
Page _2;:_o_ _ Page eX of ----'- 4-_ _ Total Hardness (SM 2340 C) RL = 1.0 mg CaCO;IL I Time initiated '>..,. Time completed t-___;;:::......~=--- --1 Total Norma lity (N) o f EDTA pH Factor or Multiplier reference =0.2/E =(N x 50000)/ 50 ml sample number number E (acccp a - 0.0220) =N X 1000 I Laboratory conI roI s I andard: Reference sta ndard True value Sam ple Hardness (MV) % RS = MY I T V x I 00 number (TV) vo lume Begin End Total Multip lier (mg CaC<>JIL) (accrptablc range I Tt-JSS -:ro2 (mg CaCO.YL) 40 (ml) 50 ml n .~ ml
\Ct~
ml d .I o{ll ~ ~ m90 tO 110%)
~ I(.)':} PS/
I En d Total M ultiplier Hardness (mg CaCO.YL)
% RPD=
((S- OJ /[(S+D)nl) x 100 I u atrt:c. spt'ke recovery: Reference stan dard Spike va lu e Sample S pike hardness (A) number (SV) volum e Begin End Total Mu ltiplie r (mg CaCO.YL) (mg CaCOJIL) (ml) ml ml ml T N'SS 1-o '2- ;{oo 10 ~ .3'-\lo 16.S (5) ..\u~ '31-o I
*2.Lt. )
Sa mple ha rdness (B)-..- Measured spike va lue (MY) %R = MY I SV x I 00 (mg CaCO.YL) MV=A- B (accrptablc range ( me CaCO.YL) = 75 to 125%) I samp e measurements:
~ (.p~pv cQ )\) los"lo Sample vo lume Begin End Total Hardness I Sa mple num ber TV~
Blank Sample ID . (ml) ml ml ml M ultiplier (mg CaCO.YL)
'J/ l OC.. I \ llo * ~ -z._ IJA 1/tr:: tx) 1 in+- I 25 -#.'-" l.-39, .1 3S n1 ~114 ).i.J-.o : IY3 0"' \\ \&' .0'- I 2 I :1£. l 4-II.J> .:S .~ i 140 :: I~?>
o4\ 1\ "lD . ol J .3 j .lfi.\D 3 .4- l 1..;.o ::: '~"' 45.0 o'\t \\ g.n IJ Affip rurt.. IW 10 b .O I al.:l. Ol::l I~ ~~0 --~9.~ o'1 '\ \~ . Cl ~ A-Piht 'tS ~.';)_ to .\ ~~ ().') I LPO 15C, ? I D~ \\,g-. 0 ~ A11 10
--p lc .l '6.~
cc..o I.C\ lo\
~))
I q Q -2 I leO-:: 15'5 I'H ll~H\~ . 10 1 RA.rrt fl. 'f) ~9, l N'\ 1111- oS o'\ 111&-- o~ I-1JA 5G.JJ J It'\ I 2-I '1~ J II .~
)3 .0 13.?, \'5 .1- .;;).v ~ n)
J .-!---"
'32.
11 0 I PIPJ!elfJSt ?Jf 1fni2ant is used. sample must be diluted . Reviewed by: L---~~-=:.:.._----1 Date rev tewed I j{. 27-09 SOP C7 - Exhibit C7 . I, revision 06-29-09
Page _2._1_ iE**r~
!>i ... ) *: ~
EnvirOIIJMIIUITet11"9 Sollltionl, Inc. Page 3 of_4.;......__ Total Hardness (SM 2340 C)
= 1.0 mg CaC03/L Analyst Sst.. I Date analyzed ~,::;..;,.-:t,-;;-.o-c-,_ ___,
RL Time initiated I'::::-.. Time completed ,__~.....<:::::::J;~--r---t Tltram ** v. nnd multiplier determination: Titrant
.u.
Normality check Begm E.IIU
~. .. Normality (N) of EDTA pH Factor or Multiplier reference standard ml ml ml -u. - (N x 50000)/50 ml sample number number (E) (acceptable range"" 0.0180
- 0.0110)- - - - - - _'9/IY X I 000 I L aboratory controI standar,d:
Reference standard True value Sample Hardness (MV) % RS= MV /TV x 100 I number J:'f'SS -=Jo2.. (TV) (mg CaCO:YL) 40 volume (mil 50 Begin ml
\5.1-End ml r+.S L<o Total ml Multiplier ~0.~
(mgCaCOVL)
~3£}
(acceptable range
= 90 to ll0°.4) ~C\a.s'l.
I Hardness %RPD= {(S. D) /[(S+D)Il)) 100 End Total Multiplier (mg CaCOYI.) I I I M.aaix sp1.ke recove ry: Reference standard Spike value Sample Spike hardness (A) I number (SV) (me CaCO,tL) volume (ml) Begin ml End ml Total ml Multiplier (mgCaCO,tL)
~~7o2. £>o ~s- Ol~ *1- I~H-.~ 3.\p tl) ~~~ l50 ** Sample hardness (B)
(mg CaCOJil,) Measured spike value (MV) MV=A-8 (m2 CaCO]I'L)
% R = MV I SV x 100 (acceptable range ... 75 to 115%)
I s~*ampJl e measurements: LoS ~5 ~ IOtD.!l*}. I Sample number TV~ BJank Sample ID Sample volume (ml) Begin ml End ml Total ml Multiplier Hardness (me CaC<h/L) (should be =0 mg CaC03/L) I o~ O~l\ n ,,. o<<o 1VA .Sa.J In r
\t.()'-t I J 'Z-a5 \
J'-+.3
.;llo ..;
l~to.; I til)l.. o
~.o L1-ltl o?~.4 J. <(,2 toC1 l 3 ~ J I O~l\1.0.05 04\ '\l1.65 'f{4 ~IOIUU I ~5 Ol'"b-_0_ I~G.'O J~ 3t.1- \.l?
Lq B)
-:J3 leo I. OCt l\\&. 0~
u ea ' \""t.o *o'-1 .J I 3 z
~
31.+- 33.(/) 3-3. \Q
.3';.2 \A l.'-c 1 J ']~
vs O&s\ll1*0'- 1ffA 6&1'1 Jn-t W I tA5 .2,5.'2,.. 6+-1 L~ Ji\, "1~
- I ~qu \h .. o~
o'\ 111..o. oS -~ I 3 z
~
l :3?.1
~co.ro 3~.'0 ~.'3 1.1-_ \.1- I' -
loq loll I PligB: flfi>~I6Jtrant is used, sample must be diluted. Reviewed by: \llC\(
~-.......:...--=----'
Date reviewed [ l\. "Q b Pa SOP C7 - Exhibit C7 .l, revision 06-29-09
Page =~= .:t~- Page 4 of _Lf_,___
) Environ men~~~ Tt , tino Solullons. lnc .
Total Hardness (SM 2340 C) Analyst Date analyzed I fl.£, 11_ ~~. 09 RL = 1.0 mg CaC0 3/L Time initiated Time completed I: . . ., t----""""""..~=--.-:----i Total Normality (N) of EDT A pH Factor or M ultiplier reference standa rd ml ml ml = (N x 50000)/50 ml sample num be r nu mber Nx 1000 Laborato control standard: Reference sta ndar d T rue value Ha rdness (MY) % RS = MV I TV x 100 number (TV) End Total Mult iplier (mg CaCOl!L) (acceptable range (mg CaCOy'L) ml ml ~90 to 110%)
~.3 1.'3 o?o.'-i 31-Ha rdness % RPD =
Samp le Tota l Multipl ier (mg CaCO.YL) {(S- D) /[(S+D)/2[} I 100 num ber s 4-3 Refe rence sta nd ard Spike va lue Sample Spike hardness (A) num ber (SV) vo lum e Begin End Tota l Multi plier (mg CaCO.YLJ . (m CaCOl/L) ml) ml ml ml J:N'S<; 1-o 2.- --to 1+3.Cl t.H.I 3 .l. 0 .~ lo'S Sa mple hardn ess (B) Measured spike va lue (MV) % R = MV I SV x 100 (mg CaCO.YL) MV=A-B *(accfptable range (mg CaCOl!L) =75 to 125%) SampjI e measurements: 31 3~ BSClo I Sa mple volume Begin End Total Har dness Sa mple number Sample ID (ml) ml ml ml Mu lt iplier (mg CaCO.YLJ TV >..rr"> 0 <=" A lank ..,.lA. I (should be
- U mg LaLU 1/ L)
- I u. Jt/.1 KJ'!JV)
SwCJn(J, ((, /1/l t3J}L K.i J.h ~ t.n' 2.- I z 60 ID.O II. *-c,
\2Ci l3.c, 1I.'6 ll q 139
- 15. 1 1.1(,
- 1. 1
\. 0 \ .~
do.J
~,J ~0 c2+
3"7-I ~ ~
~
I _,::; ~
--=::::
I I Pif)felf1j ~ 1!(J1ant is used, sample must be diluted. Reviewed by: Date reviewed 11. ~ ~ {)Cl SOP C7 - Exhibit C7 . !, revision 06-29-09
. *.~::.: .. *,:>!ki.:::.*:t~*":**.:*'l.:~:..;~,:*i:';,~* -;'~::.~: "* .. ! .* Sequoyah Nuclear Plant Biomonitoring November 17 - 24, 2009 Appendix D Reference Toxicant Test and Control.Chart Page 78 of 102
** Pimephales promelas
- 2) Chronic Reference Toxicant Control Chart Organism Source: Aquatox, Inc.
*~ Environmental Testing Solutions, Inc.
USEPA Control Limits(+/- 2 Standard Deviations) 1.0 0.8 0.6 0.4 1.2
-~
1.0
.USEPA** Warning* and Control Limits* (7 5~h and 90th. Percentile *C Vs)* * *** ~ 0.8 ~ *I)
N u
~
0.6
~ = "'0 I
0.4 l' 1.2 Laboratory Warning and Control Limits (lOth and 25th Percentile CVs) 1.0 0~8 0.6 0.4 Test date 7-day IC15 = 25% inhibition concentration. An estimation of the concentration of potassium chloride that would cause a 25% reduction in Pimephales growth for the test population. - - . Central Tendency (mean IC 25 ) _ .. _ .. . :. Warning Limits (mean IC 25 +/- SA.to or SA_75 ) C'Jt! ~bjmits (mean IC 25 +/- SA_25 , SA. 90 , or 2 Standard Deviations)
lETS ~ Envloonmontal Testing Solutions, Inc. Pimephales promelas Chronic Reference Toxicant Control Chart State ud USEPA ubonatory Laboratory USEPA USEPA Tcstaumber Test date 7-day IC25 CT s Cootrol Limits sA. .. WaroiDg Limits S,us Cootrol Limits s..._75 Waf'DiA& Limits S.ue Cootrol Limits cv (giL KC1) (giL KC1) CT-lS CT+lS CT -Sue CT+SA.II cr- s"-25 CT+ S"-:15 cr-s....'JS CT+SA.7S CT-S.uo CT+Suo 02-25-09 0.76 02-27-09 0.72 0.74 0.03 0.68 0.80 0.09 0.65 0.83 0.15 0.58 0.89 0.28 0.46 1.02 0.33 041 I 07 0.04 03-03-09 0.75 0.74 0.02 0.70 0.79 0.09 0.65 0.83 0.16 0.59 0.90 0.28 0.46 1.02 0.33 0.41 1.08 0.03 4 03-10-09 0.79 0.15 0.03 0.69 0.81 009 0.66 0.85 0.16 0.60 0.91 0.29 0.47 1.04 0.34 0.41 1.09 004 s 03-10-09 0.71 0.76 0.03 0.70 0.81 0.09 0.67 0.85 016 060 0.92 029 0.47 I.OS 0.34 0 42 1.10 004 6 04-14-09 0.70 0.75 0.03 0.68 0.82 0.09 0.66 0.84 0.16 0 59 0.91 0.28 0.46 1.03 034 0 41 109 005 7 04-21-09 0.80 0.76 0.04 0.68 0.83 0.09 0.66 0.85 0.16 0.60 0.91 0.29 0.47 1.04 0.34 0.42 1.10 0 OS 8 05-05-09 0.69 0.75 0.04 0.67 0.83 0.09 066 084 0.16 0.59 0.90 0.28 0.46 1.03 0.34 0.41 1.08 005 9 05-12-09 0.75 0.75 0.04 0.67 0.82 0.09 0.66 0.84 0.16 0.59 0.90 028 0.46 1.03 0.34 0.41 1.08 005 10 06-09-09 0.76 0.75 0.04 0.68 0.82 0.09 0.66 0.84 0.16 0 59 0.91 0.28 0.46 1.03 0.34 0.41 109 0.05 II 06-18-09 0.78 0.75 0.04 0.68 0.82 0.09 0.66 0.84 0.16 0 59 0.91 0.29 047 1.04 0.34 0.41 1.09 0.05 12 07-07-09 0.72 0.75 004 0.68 0.82 0.09 0.66 0.84 0.16 0.59 0.91 0.28 0.46 1.03 0.34 0.41 I 08 005 13 08-04-09 0.78 0.75 0.04 0.68 0.82 0.09 0.66 0.84 0.16 0.59 0.91 0.29 0.47 1.04 0.34 0.41 1.09 0.05 14 08-11-09 0.81 0.75 0.04 0.68 0.83 0.09 0.66 0.85 0.16 0.60 0.91 0.29 0.47 1.04 0.34 0.42 1.09 oos IS 09-15-09 0.72 0.75 0.04 0.68 0.83 0.09 0.66 0.84 0.16 0.59 0.91 0.29 0.47 1.04 0.34 0.41 1.09 0.05 16 10-06-09 0.78 0 75 0.04 0.68 0.83 0.09 0.66 0.84 0.16 0.60 0.91 0.29 0.47 1.04 0.34 0.41 1.09 0.05 17 10*14-09 0.71 0.76 0.04 0.68 0.83 0.09 0.66 0.85 0.16 0.60 0.91 0.29 0.47 1.04 0 34 0 42 1.10 0 OS 18 10-28-09 0.73 0 75 0.03 0.68 0.82 0.09 0.66 0.84 0.16 060 0.91 0.29 0.47 1.04 0.34 0.41 1.09 005 19 11-03-09 0.67 0.75 0.04 067 0.83 0.09 066 0.84 0.16 0.59 0.91 0.28 0.46 1.03 034 0.41 1.09 005 20 11-17-09 0.79 0.75 0.04 0.67 0.83 0.09 0.66 0.84 0.16 0.59 0.91 0.29 0.47 1.04 0.34 0.41 109 005 Nute: 7-d ICzs .. 7-day 25% inhjbition conccntnltlon. An estimation of the concenuation of powsiwn chlonde that would cause a 25% reduction in Pimepba)es gJOwtb for the tesl population. CT =Central teodcncy (mean IC, 5). S = Standard deviation of1he IC1s values. Laboratory Coatrolaad Waroi.ag Limits Laboratory control and wanllJig limits were established using the s18ndard deviation of the l~s values corresponding to the lOth and 25th percentile CVs. These ranges are more stringent than the control and warning limns recommended by USEPA for the test method and endpoint. 5 4 *10 = Standard deviation corresponding to the 10111 percentile CV (SA 10"" 0.12) 111 S"-:15
- Standard deviation corrcspooding to 1hc 2S pcn:c:ntilc CV. (SA zs
- 0.21)
USEPA Coatrolaad Waralq Umits SA-75
- Standard deviarioo corresponding to tbc 7S111 pcrceoti.le CV. ( s.._,
- 0.38)
S.ue .. Standard deviation corresponding to the 9rJl' pc:rccnriJe CV (S.._ 90 .. 0.45) CV = Cocflicicnt of variation of the I~, va!ucs. USEPA 2000 Uodentmdmg llld A.ecoucllll& for Mctbocl Vlriabdity in Whole Effiucnl ToJUCity Appliccons UDder dle Nalianal Pollutw Dasdwgc EhmiDallan Pn1sJam EPA*Bll*R-00-003 US Enwonmental Proteebcxl Aaca:y. ClllCIIIII&U. OH.
&lOxll-17-09
. . ..T~
Precision of Endpoint Measurements S }
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Enviro nme ntal Testing Solutions, Inc. Pimephales promelas Chronic Reference Toxicant Data Control Contr ol Mea n Test n umber TeJt d a te Su rviva l Growth CT cv CT MSD PMSD CT for Control Growth for Control (%) (mg!larvac) (%} (%) for PMSD (%) (mgllarvac} Gro"1h CV (%} I 02-25-09 100 0.659 8.2 0.07 11.1 2 02-27-09 100 0.578 0.6 18 6.8 7.5 0.08 13.1 12. 1 3 03-03-09 100 0.664 0.634 8. 1 7.7 0.08 12.3 12.2 4 03- 10-09 100 0.66 1 0.640 6.8 7.5 0.09 12.9 12.4 5 03-10-09 100 0.696 0.652 8.8 7.7 0.09 12.6 12.4 6 04-14-09 100 0.671 0.655 10.3 8.2 0.08 11.4 12.3 7 04-21 -09 100 0.642 0.653 8.3 8.2 0.07 11.2 12.1 8 05-05-09 100 0.805 0.672 7.9 8.2 O.Q7 8.4 11.6 9 05 -1 2-09 100 0.717 0.677 7.0 8.0 0.06 8.9 11.3 10 06-09-09 100 0.703 0.679 2.5 7.5 0.08 10.7 11.3 II 06-18-09 100 0.790 0.689 6.7 7.4 0.09 11.7 11.3 12 07-07-09 100 0.763 0.696 5.7 7.3 0.11 14.2 11.5 13 08-04-09 100 0.692 0.695 6.2 7.2 O.Q7 10.7 11.5 14 08-11-09 100 0.583 0.687 8.0 7.2 . 0.05 9.3 11.3 15 09-15-09 100 0.723 0.690 9.6 7.4 0.08 10.4 11.3 16 10-06-09 100 0.894 0.702 12.9 7.7 0.12 13 .2 11.4 17 I 0- 14-09 97.5 0.758 0.706 7.6 7.7 0.14 18.3 11.8 18 I 0-28-09 100 0.855 0.7 14 6.5 7.7 0.10 12.0 11. 8 19 11-03-09 100 0.757 0.716 7. 1 7.6 O.Q7 8.8 11.6 20 11-17-09 97.5 0.825 0.722 8.3 7.7 0.10 11.8 11.7 Note: CV = Coefficient of variation for conuol growth. Lower CV bound determined by US EPA (IO"' percentile) = 3.5%. Upper CV bound determ ined by US EPA (90"' percentile) = 20% MSD = Minimum Significant Difference PMSD = Percent Minimum Significant Diffe rence PMSD is a measure of test precision. The PMSD is the minimum percent difference between the control and treatment that can be declared statistically significant in a whole effluent toxicity test. Lower PMSD bound determined by USEPA (10"' percentile) = 12%. Upper PMSD bound determined by USEPA (90111 percentile}= 30%. CT s Central Tendancy (mean Control Growth, CV, or PMSD) USEPA. 2000. Understanding and Accounting for Method Variability in Whole Effluent Toxicity Applications Under the Notional Pollutant Discharge Elimination Program. EPA-833-R-00-003 . US Environmental Protection Agency, Cincinnati, OH. US EPA. 200 Ia. 200 I b. Final Repon: Interlaboratory Variability Study of EPA Shon-tcrm Chronic and Acute Whole Effluent Toxicity Test Methods, Volumes I and 2 Appendix. EPA-821-B-0 1-004 and EPA-821 -B-0 1-005. US Environmental Protection Agency. Cincinnati. 01 1. Organisms obtamedfrom Aquatox. Inc. atox l l- 17-09 Page 8 1 of 102
*** Pimephales promelas ~
J Chronic Reference Toxicant Control Chart Precision of Endpoint Measurements
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- p0P:ftt!t1JylitJimits (mean Control Growth, CV, or PMSD +/- 2 Standard Deviations)
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..J En\"'tonfMfltal Testing SolutionS. Inc. Potassium Chloride Chronic Reference Toxicant Test (EPA-821-R-02-013 Method 1000.0) Species: Pimephales promelas PpKCICR Test Number: ~ Dilution preparation information: Comments: KCI Stock INSS number: 1~1'-\l..- Stock preparation: 50 g KCVL: Dissolve 50 g KCI in 1-L Milli-Q water Dilution prep (mg!L) 450 600 750 900 1050 Stcjck volume (mL) 9 12 15 18 21 Diluent volume (mLf 991 988 985 982 979 Total volume (mL) 1000 1000 1000 1000 1000 Test organism information: Test information: Organism age: l.O*~~ ~wa.s. 0\...b Randomizing template: PoJ~PL-L Date and times organisms \\ -\ 1..-c:f\ \I. OD Incubator number and were born between: shelf location:
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Organism source: f\"TC'J.. &~\t..~ pf 1\--1~-o' Artemia CHM number: 0~ t'\ '"""l y Drying information for weight determination: Transfer vessel pH = S.U. Temperature = oc Date I Time in oven: I \.1:-\- M \ \'-{ D information: ~ .'-\\o 1.~.~ Initial oven temperature: ~-c Average transfer vo lume: Date I Time out of oven: n-1.5-d\ llYO o.~o~ Final oven temperature: r....o*c. Total drying time: 1..'-l* t-\t:~u.1S Daily f eeding and renewal information: Day D ate Morning feedin g Afternoo n feedin g MHSW batch used 0 2 3 4 5 6 7 Page 83 of I 02 SOP AT2 I - Exhibit AT21 . 1, revision 04-0 1-09
~ET£ Page 2 of 5 ..) EtNtronm.nt*ITtUincJ S~ullonL Inc.
I J Species: Pimephales promelas PpKCICR Test Nwnber: I 't~ Survival and Growth Data Day Control 450 m~ KCVL 600 m' K<::VI.. A B c D E F G H I J K L 0
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Page 3 ofS I .I Species: Pimephales promelas PpKCICR Test Number: 1~3 I Survival and Growth Data Day 750 ma: KCI/L 900 mfi KCIIL 1050 m r KCIIL M N 0 p Q R s T v v w X 0 10 ID 10 10 10 /Q 10 10 IC 10 10 10 1 (C) '\'o\ fO ,'" 5 t4 r.,~tA ,~ &.\ c.A
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Pimep!Jal es promelas C hronic Reference Tmdcant Test EPA-821 -R-{)2-0 13, Method 1000.0 Q uality Control Verificat ion of Data Entry, Calcula tions, a nd Statistical Analyses T est . ..,b<r: ---------'""=K.:.:OC:.:.::.:.:R~*~*.:.:'J:. Environmental Testing Solutions, Inc. Tat dates.: . Novembu 17*24 2009 R.. eiwod by: r\J ( A Ca.u* tndol (CQ&Il. 1((1) Rcp&.aiC' t..ld.a.l ..mbr:rol Lana< nuJ ..mbcraf lana< A
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£ 10 9 1499 2202 7 OJ 0 781 0 703 F 10 10 I 3 74 2 1 )) 7 59 0 759 0 7~9 450 0 803 52 97.5 0 .7&3 8.4 5. 1 G 10 10 12 .68 21 22 8 54 0 854 0 854 II 10 10 I 2 51 2067 816 0816 0816 I 10 9 14 II 21 90 7 79 0 865 0779 J 10 10 14 50 22 98 8 48 0848 0 84 8 600 0 826 91 95.0 0.7&3 7.0 5.1 K 10 10 1406 212 1 7 15 0 7 15 0 715 L 10 9 14 ) 4 22 23 7 89 0877 0 789 M 10 8 1348 2032 68 4 0 855 0 6S4 N 10 7 14 64 209~ 6 31 0901 0631 750 0899 46 77.5 <1.698 15.9 15.)
0 10 9 13 S4 22 4) 8 59 0954 0 859 p 10 7 14 21 20 40 619 0 8S4 06 19 10 4 1479 19 12 4 33 I 083 0 43) R 10 5 I 5 29 19 54 4 25 0 850 0 425 900 0 892 14 4 42.5 0.)78 15.7 S4.l s 10 4 I 3 62 16 82 ) 20 0 800 0320 T 10 4 1431 17 65 3 )4 0 835 0 ))4 u 10 2 15 18 16 73 I 55 0 775 o 1~5 v 10 I 15 72 16 90 I 18 I ISO 0894 218 0 118 1050 17.5 0.149 IS.O 8 1.9 w 10 2 14 42 1595 I 53 0 765 0 15) X 10 2 14 73 1644 I 71 0 8H 0 171 DuaDeu *s MSO vahu:: 0.0915 MSD
- Muumum Scgntfica.nt Oc.ffcrcncc PMSD: 11.3 PMSD
- PerCC1U Mmunum Scgntflcant Dcffcrcncc PMSD is a measure of test pn:c,saon 1bc PMSD the manamum percent dtffercnce between the contro l and tru.tmenl that un be dccla.red statuucally stg.ru(lcnnt lll a whole cffiuau toXICi ty lese Lower PMSD bound determmed by US EPA (IOtl1 pertenule)
- 12%
Upper PMSD bound dclermmod by USEPA (90th petc<nule)
- 30%
Lower and uppc PMSD bounds wac dctenrunod fJom tl1c lOth and 90th pcn;cnule, rcspccuvcly, ofPMSD dala from EPA"s WET lntttlabor.uory Vanabduy Study (USEPA. ZOO Ia. USEPA, ZOO I b) US EPA 2001a. 2001b fmal Repon lnlctlaboruory Vanab1hty Soudy or EPA Shono(cnn Chron1c and Atule Whole Effiucnl ToXJclty TcSI Methods. Volumes I and 2*Append1Jl EPA*821*8-0I-004 and EPA*821-B*01.005 US EnvuoruncnJal Pro<ccuoo Agency. CIIICmnau. OH
~ETS ~ EnVIronment.~ TnUng Sclluttons, InC.
Statistical Analyses Larval Fish Growtb aDd Survival Test-7 Day SurviVBI Stwt Date: 1111712009 Test ID: PpKCICR SamplciD: REF-Ref Toxicant End Date: 1112412009 Lab ID: ETS.Envir. Testing Sol. Sample Type: KCL-Potassium chloride Sample Date: Protocol: FWCHR*EPA-821-R-02-013 Test Species: PP*Pimepbalcs promelas Comments: Cooc-mgll. 1 2 3 4 D-Coouol 1.0000 1.0000 1.0000 0.9000 450 0.9000 1.0000 1.0000 1.0000 600 0.9000 1.0000 1.0000 0.9000 750 0.8000 0.7000 09000 07000 900 0.4000 0.5000 04000 0.4000 1050 0.2000 0.1000 0.2000 0.2000 Transform Arcsin ~uare Rool 1-Tailcd Nmnber Total Conc-m15!!:: Mcao N-McaD Mean Min Max CV% N 1-Stat Critical MSD Rcse Number' D-Conuol 0.9750 1.0000 13713 1.2490 1.4120 5.942 4 I 40 450 0.9750 1.0000 1.3713 1.2490 1.4120 5.942 4 0.000 2.410 0.1471 1 40 600 0.9500 0.9744 1.3305 1.2490 1.4120 7.072 4 0.668 2.410 0.1471 2 40
*1s0 0.7750 0.7949 1.0846 0.9912 1.2490 11.294 4 4.696 2.410 01471 9 40 *90() 0.4250 0.4359 0.7099 0.6847 o:1s54 7.091 4 10.836 2.410 0.1471 23 40 *toso 0.1150 0.1195 0.4282 0.3218 0.4636 16.570 4 15.451 2.410 0.1471 33 40 Anxi)iary Tests Statistic Critical Skew Kun Sbapiro-Wilk's Tes1 indicateS oonual distriburioo (p > 0.01) 0.91163939 0.884 -0.1184496 -0.6290117 Bartlca's Test indicates !9ual variances ~e .. 0.82) 2.20082235 15.0862722 H~esis TCSI ~1-rail. 0.05) NOEC LOEC CbV TIJ MSDu MSQE MSB MSE F-Prob df Dunnett's Test 600 150 670.820393 0.07612662 0.07923945 0.63093674 0.00745088 7.3E-12 5,18 Trcannents vs D-Cootrol Maxunilm Likelihood-Probit Parameter Value SE 95°/e Fiducial Limits Conrrol Chi-~ Critical P-value Mu Sigma Iter Slope I 1.90075 2.02798845 7.9258926 15.8756075 0.025 0.02529665 7.81472778 1 2 94271355 0.08402832 3 Intercept -30.020498 5.96965262 -41.721018 -18.319979 TSCR 0.02489373 0.0167698 -0 0079751 0.05776254 Point Pro bits ms!!:: 95% Fiducial Limits EC01 2.674 558.771764 439.30398 632.540335 ECOS 3.355 637.528005 533.944092 700.273975 EC10 3.718 683.954056 591.864566 740.053467 EC15 3.964 717.172783 633.972402 768.743169 EC20 4.158 744.720889 669.099597 792.886858 EC25 4.326 769.196521 700.275338 814.793373 EC40 4.747 834.497847 781392728 877.222284 ECSO 5.000 876.422566 829.69787 922.532758 EC60 5.2S3 920.453569 875.571987 976.186221 EC15 5.674 998.595923 946.148753 1085.24501 EC80 5.842 1031.4153 973.075482 1134.89329 EC85 6.036 1071.03413 1004.29166 1196.99431 EC90 6.282 1123.05276 1043.78666 1281.46378 EC95 6.645 1204.83569 1103.60002 1419.80285 EC99 7.326 1374.65171 1222.28693 1724.95223 Organums obtained from Aquatox, Inc. atoxll-17-09
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Environmental Testing Solutions, Inc. Statistical Analyses Larva] Fish Growth and Surviva1 Test-7 Day Growth Stan Date: 11/1712009 Test ID: PpKCICR Sample ID: REF-Ref Toxicant" End Date: 1112412009 Lab ID: ETS-Envir. Testing Sol. Sample Type: KCL-Potassium chloride Sample Date: Protocol: FWCHR-EPA-821-R-02-0 13 Test Species: PP-PimephaJes promelas Comments: Conc-mg/L 1 2 3 4 D-Control 0.9070 0.8050 0.8430 0.7440 450 0.7030 0.7590 0.8540 0.8160 600 0.7790 0.8480 0.7150 0.7890 750 0.6840 0.6310 0.8590 0.6190 900 0.4330 0.4250 0.3200 0.3340 1050 0.1550 0.1180 0.1530 0.1710 Transfonn: Untransformed 1-Tailed Isotonic Conc-mg/L Mean N-Mean Mean Min Max CV% N t-Stat Critical MSD Mean N-Mean 0-Control 0.8248 1.0000 0.8248 0.7440 0.9070 8.285 4 0.8248 1.0000 450 0.7830 0.9494 0.7830 0.703Q 0.8540 8.441 4 0.933 2.180 0.0975 0.7830 0.9494 600 0.7828 0.9491 0.7828 0.7150 0.8480 6.959 4 0.939 2.180 0.0975 0.7828 0.9491 750 0.6983 0.8466 0.6983 0.6190 0.8590 15.872 4 0.6983 0.8466 900 0.3780 0.4583 0.3780 0.3200 0.4330 15.676 4 0.3780 0.4583 1050 0.1493 0.1810 0.1493 0.1180 0.1710 14.966 4 0.1493 0.1810 Auxiliary Tests Statistic Critical Skew Kun Shapiro-Wilk's Test indicates normal distribution (p > 0.01) 0.93505901 0.805 -0.079593823 -1.15766298 Bartlerrs Test indicates equal variances (p = 0. 93) 0.14925823 9.2103405 Hypothesis Test (1-lail, 0.05) NOEC LOEC ChV TU MSDu MSOp MSB MSE F-Prob df Dunnett's Test 600 >600 0.09751355 0.11823407 0.002338083 0.00400172 0.57733494 2,9 Treatments vs 0-Control Linear Interpolation (200 Resamples) Point mgiL so 95%CL(Exp) Skew ICOS* 444.48 171.45 43.33 936.54 -0.1280 IC10 671.85 93.51 216.91 825.11 -1.2941 IC15 745.05 48.64 537.03 808.42 -0.9607 IC20 768.01 29.70 646.35 819.59 -1.0239 IC25 787.32 20.62 712.96 835.30 -0.5410 IC40 845.27 13.72 797.28 882.88 -0.0132 lCSO 883.90 13.24 846.50 930.45 0.3616
- indicates IC estimate less than the lowest concentration Organisms obtainedfrom Aquatox, Inc. atox 11-1 7-09
Page 4 of 5 Species: Pimepha/es promelas PpKCICR Test Number: 1'\.3 CONTROL 600 mg KCUL 750 mg KCUL 900 mg KCUL STOCK Page 89 of 102
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-I Species: Pimephales promelas PpKCICR Test Number: ~ t f CONTROL I li 750 mg KCVL 1050 mg KCVL SOP AT21 -Exh ibit AT21. 1, revision 04-01 -09 Page 90 of I 02
*** Ceriodaphnia dubia Chronic Reference Toxicant Control Chart J -~ Environmental Testing Solutions. Inc.
1.14 USEPA Control Limits(+/- 2 Standard Deviations) 1.12 .. 1.10 1.08 1.06 1.04 ****** ******** ... ********************* **************************************************** 1.02 2.5
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I' 1.4 Laboratory Warning and Control Limits (1oth and 25th Percentile CVs) 1.3 1.2 1.1 l.O -**- *-**- -**- *-**--*- *-**--*- *- -**-**- --**-**- *-**- *-**-** 0.9 ****************************************************************************************** Test date
- 7-day IC 25 = 25% inhibition concentration. An estimation of the concentration of sodium chloride that would cause a 25% reduction in Ceriodaphnia reproduction for the test population.
- - . Central Tendency (mean IC 25 ) -**-**- Warning Limits (mean IC 25 +/- SA 10 or SA. 75 )
- pa ~<<W~ j,p.its (mean IC25 +/- sA.25' sA.90' or 2 Standard Deviations)
r .I Ceriodaphnia dubia Chronic Reference Toxicant Control Chart Envlronmontallilstlng Solutions, Inc. State and USEPA Laboratory Laboratory USEPA USEPA Tat number Test date 7-day ICzs CT s Control Limits SA.tt Warning Umits SA.ZS Control Limits S"-,5 Warning Umits Control Limits cv (f/1. NaCI) (f/1. NaCI) CT-2S CT+2S CT
- Suo CT + SA. 1o CT
- SA.zs CT + SA.ZS CT
- S""'s CT + S"-'5 CT
- Sue CT + S.uo I 11-04..08 1.07 2 11-04-08 1.10 1.08 0.02 1.05 1.12 0.09 1.00 1.17 0.18 0.90 1.27 0.49 0.60 1.57 0.67 0.41 1.75 002 3 12-02-08 1.06 1.08 002 1.04 1.11 0.09 0.99 1.16 0.18 0.89 1.26 0.48 0.59 1.56 067 0.41 1.74 0.02 4 01-06..()9 1.05 1.07 0.02 1.03 1.11 0.09 0.98 1.16 0.18 0.89 1.25 0.48 0.59 1.55 066 0.41 I 73 0.02 5 02-03..()9 I.OS 1.07 0.02 103 1.10 0.09 0.98 1.15 018 0.88 1.25 0.48 0.59 1.55 0.66 0.41 173 0.02 6 02-24-09 1.07 1.07 0.02 I 03 1.10 0.09 0.98 1.15 0.18 0.89 1.25 0.48 0.59 l.SS 0.66 0.41 I 73 0.02 7 03-10-09 1.07 1.07 0.02 1.04 1.10 0.09 0.98 1.15 0.18 0.89 1.25 0.48 0.59 1.55 0.66 041 1.73 0.01 8 04-14-09 1.09 1.07 002 104 110 0.09 0.98 1.16 0.18 0.89 1.25 0.48 0.59 1.55 0.66 0.41 1.73 0.02 9 05-05-09 I 07 1.07 0.02 1.04 1.10 0.09 0.98 1.16 018 0.89 1.25 0.48 0.59 l.SS 0.66 0.41 1.73 0.01 10 05-05-09 1.08 1.07 0.02 1.04 1.10 0.09 0.99 1.16 0.18 0.89 125 0.48 0.59 1.55 0.66 041 1.73 0.01 11 06..()9..()9 1.07 1.07 0.01 1.04 1.10 0.09 0.99 1.16 0.18 0.89 1.25 0.48 0.59 I.SS 0.66 0.41 1.74 0.01 12 06-09-09 1.07 1.07 0.01 1.04 1.10 0.09 0.99 1.16 0.18 0.89 1.25 048 0.59 1.55 0.66 041 1.74 0.01 13 06-18-09 1.06 1.07 0.01 1.04 l.IO 0.09 0.98 1.16 0.18 0.89 1.25 0.48 0.59 l.SS 0.66 041 1.73 0.01 14 07-07-09 106 1.07 001 1.04 1.10 0.09 0.98 1.16 0.18 0.89 1.25 0.48 0.59 l.SS 0.66 0.41 1.73 0.01 IS 08-04-09 1.07 1.07 0.01 1.05 1.09 0.09 0.98 1.16 0.18 0.89 1.25 0.48 0.59 I 55 0.66 0.41 1.73 0.01 16 08-04-09 1.09 1.07 0.01 I. OS 1.10 0.09 0.99 1.16 0.18 089 1.25 048 0.59 1.55 0.66 0.41 1.74 0.01 17 09:15-09 I OS 1.07 0.01 1.04 1.10 0.09 098 1.16 0.18 0.89 1.25 048 0.59 1.55 0.66 0.41 1.73 0.01 18 10-06-09 1.08 1.07 0.01 104 1.10 0.09 0.99 1.16 0.18 0.89 1.25 048 0.59 1.55 0.66 0.41 1.73 0.01 19 10-14-09 1.07 ).01 0.01 1.05 1.10 0.09 0.99 1.16 0.18 0.89 1.25 0.48 0.59 1.55 0.66 0.41 1.73 0.01 20 11-10-09 1.07 1.07 0.01 1.05 1.10 o09 0.99 1.16 0.18 0.89 1.25 0.48 0.59 1.55 0.66 0.41 1.74 001 Note: 7-d IC>> ~ 7-day 25% inhibition concentration. An estimation ofthe concentration of sodium chloride that would cause a 25% reduction in Cer1odaphn1a reproduction for the test population.
CT .. Central tendency (mean IC2S>* S
- Standard deviation of the lc;s values.
Laboratory Control and Warning Umits Laboratory control and warning limits wcte established using the standard deviation of the l~s values corresponding to the lOth and 25th percenule CVs. These ranges are mon:: stringent than the control and warning limits recommended by USEPA for the test method and endpoint. S._ 10 "' Standard deviation corresponding to the I cf' percentile CV. (S,.. 10 -= 0.08) S.us""' Standard deviaJion corresponding to the 2~ percentile CV. (S,.. u = 0 17) USEPA Controlaod Warning Umits SA.1s "' Standard deviation corresponding to the 75111 percentile CV. (S,.. 15 .. 0.45) Sue
- Standard deviaJion corresponding to the 9rf' percentile CV. (S,.. so .. 0.62)
CV =Coefficient of variation of the lc;s values. USEPA 2000. Understanding and Accounting for Method Variability in Whole Effluent Toxicity Applications Under the National Pollutanl Discharge Elimination Program. EPA-833-R-00.003. US Enviroomen\81 Protection Agency, Cincinnati, OH
** Precision of Endpoint Measurements
- J Ceriodaphnia dubia Chronic Reference Toxicant Data
~ Environmental Testing Solutions, Inc.
Tes t Control Control Mean numbe r Test date Survival Reproduction CT cv CT MSD PMSD CT for Control Mean fo r Control (%) (offspring/female) Reproduction (%) Reproduction (%) for PMSD (%) (offsp ring/female) cv (%) I 11-04-08 100 32.3 5.1 2.2 6.8 2 11-04-08 100 31.5 31.9 6.2 5.6 2.4 7.7 7.2 3 12-02-08 100 31.5 31.8 4.6 5.3 2.5 8.0 7.5 4 01-06-09 100 33.2 32.1 4.0 4.9 2.0 6.1 7.1 5 02-03-09 100 31.4 32.0 6.6 5.3 1.9 6.0 6.9 6 02-24-09 100 32.2 32.0 6.0 5.4 1.8 5.7 6.7 7 03-10-09 100 31.9 32.0 5.8 5.5 2.6 8.2 6.9 8 04-1 4-09 100 33.9 32.2 6.7 5.6 2.0 5.8 6.8 9 05-05-09 100 33.6 32.4 4.3 5.5 2.3 6.8 6.8 10 05-05-09 100 34.6 32.6 7.7 5.7 2.2 6.5 6.8 II 06-09-09 100 31.3 32.5 6.4 5.8 2.1 6.7 6.7 12 06-09-09 100 31.1 32.4 9.4 6. 1 2.6 8.3 6.9 13 06-18-09 100 32.3 32.4 7.3 6.2 1.9 5.8 Q.8 14 07-07-09 100 29.9 32.2 3.3 6. 0 2. 2 7.2 6.8 15 08-04-09 100 30.4 32.1 4.7 5.9 2.2 7.3 6.9 16 08-04-09 100 32.0 32.1 5.1 5.8 2.2 6.9 6.9 17 09-15-09 100 31.6 32.0 5.4 5.8 2.2 7.0 6.9 18 I0-06-09 100 31.4 32.0 4.3 5.7 2.4 7.6 6.9 19 I 0-14-09 100 33.3 32.1 3.5 5.6 2.6 7.7 7.0 20 I l- l 0-09 100 34.0 32.2 6.2 5.6 2.6 7.7 7.0 Note: CV = Coefficient of variation for control reproduction. Lower CV bound determined hy USEPA ( 10'" percentile) = 8.9%. Upper CY bound determ ined by USEPA (90th percentile) = 42% MSD = Minimum Significant Di fference PMSD = Percent Minimwn Significant Difference PMSD is a measure of test precision. The PMSD is the minimum percent difference between the control and treatment that can be declared statistically significant in a whole effluent toxicity test. Lower PMSD bound determi ned by USEPA ( lOth percenti le) = 13%. Upper PMSD bound determined by USEPA (90'11 percentile) = 47%. CT = Central Tcndancy (Mean Control Reproduction, CV, or PMSD) USEPA. 2000. Understanding and Accounting for Method Variability in Whole Effiuent Toxicity Applications Under the National Pollutant Discharge Elimination Program. EPA-833-R-00-003. US Environmental Protection Agency, Cinci nnati, OH. USEPA. 2001 a, 200 I b. Final Report: Interlaboratory Variability Study of EPA Short-term Chronic and Acute Whole Effluent Toxicity Test Methods, Volumes I and 2-Appendix. EPA-821-B-01 -004 and EPA-82 1-B-01-005. US En vironmental Protection Agency, Cincinnati, OH. l /- 10-09 Page 93 of 102
iET _ _ _ l Environmental Testing Solutions, Inc. Ceriodaphnia dubia Chronic Reference Toxicant Control Chart Precision of Endpoint Measurements
.s....=..-.. ~
35 u-
-c = a~ 30 ..... ****************************************************** ***************************** ~.!
a~ 25
~ *! -~E 20 ~ = =.._,~ 15 u
Minimum Acceptance Criteria(> 15.0 offspring per surviving female)
~ ~ .i = 40 = = ...u North Carolina Acceptance Limit(< 40.0%) *- = *~ 1c.. 30 ~
Kentucky Acceptance Limit (< 30.0%)
>~ ... 0 20 = .!:o= *c~
e u.. to
~
u=cS USEPA Upper PMSD Bound (90th percentile< 47.0%) 40 30 20 10 0 ~-L--~~~--~~--~~--~-L~~~~--~_.--L-~--~~~~
... tv\), \\.Jr \v~ ,,\), ~j), fo~ ~,\)q \,.,\\ ,v~ ,,..!~ \),. . o.j)q \)j)q"". ,,,q,,,\}J_,j)q,,,\}J_,.,,q Bj)q\)b'"' ,q "j)q'"' .. nj)q,,, ~ ,~~ \! ~~ ..A.. ~~\ ~ ~j)q o.j)q r,j)q -"'j)q ,.j)q 'j)q ,,,, ~ ..\ \')IJ"' \\)..\! \v~
Test date
- Control Reproduction, Coefficient of Variation (CV), or Percent Minimum Significant Difference
* (PMSD) PMSD is the minimwn significant difference between the control and treatment that can be declared statistically significant.
- -
- Central Tendency (mean Control Reproduction, CV, or PMSD)
- pa_fe-~Jt)pits (mean Control Reproduction, CV, or PMSD +/- 2 Standard Deviations)
Page I of6 Sodium Chloride Chronic Reference Toxicant Test (EPA-821-R-02-013 Method 1002.0) Species: Ceriodaphnia dubia CdNaCJCR #: I 00 Dilution preparation information: Comments: NaCI Stock !NSS number: IN~~ ,v\ Stock preparation: 100 g NaCVl: DISsolve 50 g NaCI 1n 500 mL M1lli-Q water. Dilution p rep (mg/L) 600 800 1000 1200 1400 Stock volume (mL) 9 12 IS 18 21 Diluent volume (mL) 1491 1488 1485 1482 1479 Total volume (mL) 1500 1500 1500 1500 1500 Test orxanism source information: Test information: Org_anism_age: < 24-hours old Randomizing template color: hO ~ Date and times organisms were born 1\-\C> *o'\ Olo1.0 "'t1) 1\\0 Incubator number and shelf between: location: 2.-f> 2-Culture board: Replicate number:
\\-~ *0 I 2 " l~i 4I S I 6 1 7 1 ' 1 9 1 10 YWrbntch:
111-o1.. ~ Culture board cup_ number: 1 &- I'\ I 1\J ~ 110 J'l!. J~J ,_, J1.~ Transfer vessel information: pH "' 1.1"'\ S.U. Temperature "' 1.~..§ oc Selenasrrum batch: Average transfer volume (mL): o. 0~,.,~ ti*OI
- ot\
Daily renewal information: Day Date Test initiation and feeding, MHSW An.alyst renewal a nd feeding, or batch used termination time 0 I\ 2 3 4 5 6 7 Control information: Acceptance criteria Summary of test endpoints:
%of Male Adults: ()1. ~20% 7-day LC50 ") 1'4DtJ %Adults having Jnl Broods: 1Cc1. <: 80% NOEC ~en % Mortality: 07. S 20% LOEC 1000 Mean Offspring/Female: 3'-t.O ;:: 15.0 offspring/female CbV &~'-\. '-l %CV: l.-. l7J < 40.0 % ICa I C>12..1o Page 95 of 102 SOP AT 14 - Exhibit AT 14. I, revision 04-0 1-09
Page 2 of 6 Species: Ceriodaphnia dubia CdNaCICR # : t00 CONTROL Survival and Reproduction Data Replicate number Day 1 2 3 4 5 6 7 8 9 10 I Youo~o: p roduced D 0 D 0 a 0 a 0 0 a Adult mortality \....... \.__ \.....- '-- '-- L.. \..._ L- ~ 2 Young produced 0 D 0 () 0 0 D () 0 C) Adult mortality L L L \...._ \...._ '--- L \.._. L '- 3 Yo ung produced D 0 D D .a 0 L_ a a 0 a Adult morta lity
'-- '- \._ '- '-- '-- L..... '-- "--
4 Young produced 5 ~ 'S y s s s ~ ~ l..\
\..._
Adult mortality
'-- \..._ \.-- '---- L.. \,_ L \.._ \,_
5 Young produced \~ \D l"!> ~4 11... \1... \~ \1. I~ \"L.. Adult mortality L \..... L_ \....... '- \......... '- '- '- '--- 6 Young p r od uced 0 0 Q a 0 0 0 0 o* () 7 Adult mortality Young produced Total young produced
\.._
I Ita L
\~ '- L \$ \.'\ \I ,.., \......... L IL\._
L 1\o \S
\...
01.. 3\ 3'- 3~ 3\o 34 ~:s 31. 3'- .3\ Final Adult Mortality '-- '-- '-- '- '-- \..__ \..__ X for 3'" Broods -y._ "'I-- '1- )(_ )C-. Y- ~ ~ "">"- )<. No1e: Adult mortality (L = lrvc, D = dead), SB =splat brood (smgle brood splat between two days). CO= carry over (offsp n ng carried over with adult during transfer). Concentration:
% Mortality: I 07.
Mean Offspring/Female: I ~'1.0 600 m~ Na Cl/L S urvzva
. I an dR epro ductwn D ata Replicate number Day I 2 J 4 5 6 7 8 9 10 I Young produced C) 0 0 D a 0 (') 0 0 0 Adult mortality \_ '--- L.. L L L L L L \...._
2 Young produced () C:J a (') 6 (") a () 0 a Adult mortality
\.. 1 \._ L \,__ L L L L '-
3 Young produced 0 0 0 0 a 0 0 0 0 0 Adult mortal! ty \...- \,_ L.. L L '- '-- '- L- '---- 4 Young produced
~ (... s 5 s s "-\ 5 s s Adult mortality '- '-- '-- '- '-- \._ '-- L \.._. \... \~ \~ I~ \~ *~
5 Young produced \1.. 1'-\ I\ \'l l'l... Adult mortality \.._. \....... L L L L \.._ L.... L '- 6 Young produced 0 0 0 0 0 0 0 0 G 0 Adult mortality L.. \....... L L \. L L \ \. L 7 Young produced l:i 1'\. II. ~l \""\ \( \g 1"-\ n *~ Total young produced
'03 ~.I 3~ 3$ 3'- 3~ 3S 3t 3S .30 Final Adult Mortality L L \._ \..._ L L \.... L '-- L.._
Nole: Adult mortahty (L = hve, D - dead), SB- spht brood (smgle brood splat between two days). CO = carry over (offspnng carried over with adult during trans fer) . Concentration:
% Mortality: 07.
Mean Offspring/Female: ~- 0
% Reduction from ConlTol: o7..
Page 96 of I 02 SOP AT 14 - Exhibit AT 14. 1, revision 04-0 l-09
Page 3 of6 Species: Ceriodaplmia dubia CdNaCICR #: 100 800 mg Na C IlL S urvival and Reproduction Data Replicate number Day 1 2 3 4 s 6 7 8 9 10 I Young producrd Adult mortllllty L D ~ 0 D () a 0 0 0 0
\.._ \.._ '-- '-- \...._ \...._ L- \,._. \.._
2 Young produced 0 _(')_ () 0 D 6 0 D 0 0 Adult mortlllity .... \...._ \...._ \_ \.._ \.._ \..___, L I.. l 3 Young produced D 0 0 0 0 _Q 0 0 0 0 Adult morta lity '-- \._ \_
'-- '-- '-- \...__ '-- L- '--
4 Young produced ~ s "-\ 'S' s s s s. $ s Adult mortality '-- L L '- L '-- L \.._ L.- L 5 Young produced \"l.. I~ \C.. \~ \"L Adult mortality
\~
L- L 10
- \...... \1.. \ 1,_
L '-- '-- 6 Young produced 0 0 a D () () c 0 0 0 Adult mortality L '- L '-- L.. L L '- L 'L_ 7 Young produced l'-\ I~ \'-\ Total young produced V"'\
~ \\ ~'4 ~~ \l ~~..
1\. 31\ N
.3\ 33 \t ~s 3\ a\
Final Adult Mortality \. '- \_ \...... '-- '-- L '-- '- '-- Note: Adult monahty (L = hve, D = dead), SB = spht brood (smgle brood spht between two days), CO = carry over (offspnng carried over with adult during transfer ). Concentration:
% Mortality: 07.
Mean Offspring/Female: ~~.()
% Reduction from Control: '2. .'\ '1.
1000 mg NCVL a S urvzva. I andR eprod uct wn ' Data Replicate number Day I 2 3 4 s 6 7 8 9 . 10 1 Young produced ~ a
.\.._
0 D_
\..__
() 0 (')
\.._..
0 L. ()
\.__
0 Adult mortality l.__.. \.._.. L L \...._ 2 Young produced 0 0 D () 0 0 D 0 0 0 Adult mortality \...... L \._
'-- L. '- \...._ L- '- '--
3 Young produced 0 0 0 D 0 0 0 nL 0 a Adult mortality L L \...._
'- L.. L '-- L. L-4 Young produced 4 c; 'i ~ 4 s ~ ~ 1..\ "{
Adult morta lity \.._. L.. \_
'-- L.. \....._ L L \._.... \.
I() II '\ 11_ 11.. 10 10 13
*~
5 Young produced I\ Adult mortality L L l- L L \..... L
\.... I.... '-
6 Young produced 0 0 0 u 0 a n 0 0 (J Adult morta lity L L L L L L L. L.. L- k
*1 I~ l"\ ll{ I~ *~
7 Young produced 1'5 1\. \S I] Total young produced
-z'\ ~3 ~tl 1..'\ ~0 .3) 3\ c..tt L.i 0~
Final Adult Mort1lity \........ L L.. L .l- L_ L L. \.....__
\. -
Note: Adult monahty (1..- hvc, D = dead). SB - spht brood (s10glc brood spht between two days), CO - carry over (offspnng - carried over with adult during transfer). Concentration:
% Mortality: D7.
Mean Offspring/Female: 3o.~
% Reduction from Control: /1). "'i 4 Page 9 7 of 102 SOP AT 14 - Exhibit AT 14. I, revision 04-0 1-09
Page 4 of 6 Species: Ceriodaphnia duhia C d NaCIC R # : {()0 1200 mg Na CI/L Survival and Reproduction Data Replicate number Da_y I 2 3 4 5 6 7 8 9 10 I Youog productd 0 0 0 0 (") 0 0 (") 0 0 Adult mortality
'- '-- "- \._ '- L. \.._ L-- '- """---
2 Young productd 0 D 0 tJ a (") ('.. 0 0 a Adult mortality L- L.. L L "- '- \. \. '- \._. J Young productd 0 () 0 0 0 0 0 0 0 0 Adult mortality L.. '-- L. '- L- \..__
'-- '-- L.. '--
4 Young productd ~ '4 :!> s s ~ ~ ~ '-\ '-\ 5 Adult mortality Young productd q L '-- s s L 0 & IQ D L..
'\
L-
., ~ ~
Adult mortality
\ '-- '-- '-- L- '-- L L. '- '--
6 Young productd (i D CJ s 0 0 0 () 0 {) Adult mortality \.. '- \._. \....._ L \....... '-- \._.... '--- "-- 7 Young productd cS s. '\ a 1 1 ICl <<4 C\ ~ Total young produced
"'2.0 ~~ II 10 "1.0 'ZO \~ \""\ 1..0 \~
Final Adult Mortality L.. "-- '-- '-- '-- L '- '-- L- \.._ Note: Adult mortality (L "' live, D = dead), SB =split brood (smg le brood spilt between tw o da ys}, CO= carry over (offspnng c arried over with adult during trans fer). Concentration:
% Mortality: 01.
Mean Offspring/Female: \\.. '1
% Reduction from Control: So.~~-
1400 m~ Na CI/L S urvzva
. I andR eproduct'10n D at a Replicate number Day 1 2 J 4 s 6 7 8 9 10 I Young produced () 0 6 0 () (', (') (') 0 0 Adult mortality L \.._ L.. L L L L.. L \.._ L 2 Young productd () 0 l) 0 0 D () 0 0 0 Adult mortality L L.. L. L \._ L L \.._
J Young produced 0 0 0 0 0 0 0 (j 0 0 Adult mortality
*'-- L \.._ L L L.. L I. L- l..-
4 Young produced D "'1... '-\. \ 0 0 c Y. '-\ "\ Adult mortality \....... '- \._ \.._ \.._ '-- '- L_ 5 Young produced L 0 0 \ 3 5 -3 a 0 0 Adult mortality L.. \.-- '- L L L L '- L.. L 6 Young produced () 0 (:) 0 0 0 0 1 '2. 0 L L. Adult mortality l s Li-s L L
.., L L n
L- I....- 7 Young produced Total young produced
'\ .., '\
0 1.. ., 1..\ 1 r"L 10 0
'5 '- ,£ Final Adult Mortality L '-- '-- '- \._ L \..._ \.__ \..._ '---
Note: Adult mo rtality (L = hve. D = dead). SB = spht brood (smgle brood spht between two days), CO- carry over (offspn ng carried over with adult during transfer). Concentration:
% Mortality: 07.
Mean OffSQ_rin_g/Female: 1.'1
%Reduction from Control: ,~,, & '1.
I Page 98 of 102 SOP AT 14 - Exhibit AT 14. 1, revision 04-0 1-09
ETS Ceriodaphnia dubia Chronic Reference Toxicant Test EPA-821-R-02-013, Method 1002.0 Environmental Testing Solutions, Inc. Quality Control Verification of Data Entry, Calculations, and Statistical Analyses Test oumber: CdNaCICR ##100 Re::~::;: =====d==:*;~:~~~v;em;;be;r;l~0-~1=7=,2=009== Coactotratioo Replicate oumber Survival Averagereproducnoo Coeff'lcieat of' Percaat redgctiota f'rom {mg/LNaCl) (%) (offspriDglfemale) urbtioa (%) matr.,. (%) I 2 3 4 s 6 7 8 9 10 Coot.rol 36 31 36 33 36 34 35 32 36 31 100 34.0 6.2 Not applicable 600 33 38 33 35 36 33 35 32 35 30 100 34.0 6.6 0.0 800 34 34 34 36 31 31 33 35 31 31 100 33.0 5.7 2.9 1000 29 33 30 29 30 31 31 29 28 34 100 30.4 6.2 10.6 1200 20 14 17 10 20 20 13 17 20 18 100 16.9 20.8 SO.J 1400 9 7 9 2 7 12 10 5 6 12 100 7.9 39.8 76.8 Duooett's MSD value: 2.604 MSD== Minimum Significant Difference PMSD: 7.7 PMSD= Percent Minimum Significant Difference PMSD is a me~urc of test precision. The PMSD is the minimum percent difference between the control and treaunent that can be declared statistically significant in a whole effluent toxicity test. Lower PMSD bound detennined by USEPA (lOili percentile) = l3%. Upper PMSD bound determined by USEPA (9fP percentile):;; 47%. Lower and upper PMSD bounds were determined from the lOth and 90th percentile, respectively, ofPMSD data from EPA's WET Interlaboratory Variability Study (USEPA. 2001a; USEPA. 200lb). US EPA. 200 I a, 2001 b. Final Repon: lnterlaboratof)' Variability Study of EPA Shon-term Chronic and Acute Whole Effluent Toxicity Test Methods, Volumes I and 2-Appendix. EPA-821-B-0 1-004 and EPA-821-B-0 1-005. US Environmental Protection Agency, Cincinnati, OH.
-* -'---~------*-*- * - * * - ... ,1_ **
~ETS ~ Envtronmental Testing Solutions, Inc. Statistical Analyses Ceriodaphnia Survival and Reproduction Test-Reproduction Stan Date: 1J!I0/2009 Test ID: Cd.NaCICR SampleiD: REF-RefToxicant End Date: 11117/2009 Lab ID: ETS-Envir. Testing Sol. Sample Type: NACL-Sodium chloride Sample DaJe: Protocol: FWCHR-EPA-821-R-02-013 Test Species: CD-Ceriodaphnia dubia Comments: Conc-mg/L I 2 3 4 5 6 7 8 9 10 D-Control 36.000 31.000 36.000 33.000 36.000 34.000 35.000 32.000 36.000 31.000 600 33.000 38.000 33.000 35.000 36.000 33.000 35.000 32.000 35.000 30.000 800 34.000 3~.000 34.000 36.000 31.000 31.000 33.000 35.000 31.000 31.000 1000 29.000 33.000 30.000 29.000 30.000 31.000 31.000 29.000 28.000 34.000 1200 20.000 14.000 17.000 10.000 20.000 20.000 13.000 17.000 20.000 18.000 1400 9.000 7.000 9.000 2.000 7.000 12.000 10.000 5.000 6.000 12.000 Transform: Untransformed 1-Tailed Isotonic Cone-mS:{!: Mean N-Mean Mean Min Max CV% N t-Sw Critical MSD Mean N-Mean D-Control 34.000 1.0000 34.000 31.000 36.000 6.201 10 34.000 1.0000 600 34.000 1.0000 34.000 30.000 38.000 6.649 10 0.000 2.287 2.604 34.000 1.0000 800 33.000 0.9706 33.000 31.000 36.000 5.714 10 0.878 2.287 2.604 33.000 0.9706
*sooo 30.400 0.8941 30.400 28.000 34.000 6.241 10 3.161 2.287 2.604 30.400 o:8941 *1200 16.900 0.4971 16.900 10.000 20.000 20.771 10 15.015 2.287 2.604 16.900 0.4971 *1400 7.900 0.2324 7.900 2.000 12.000 39.783 10 22.917 2.287 2.604 7.900 0.2324 Auxili~ Tests StaJistic Critical Skew Kun Kolmogorov D Test indicales norma) distribution (p > 0.01) 0.85725808 1.035 -0.4383847 0.05843284 Bartlett's Test indicates eguaJ variances ~ = 0.27} 6.40927744 15.0862722 Hypothesis Test ( 1-tail, 0.05l *NOEC LOEC ChV TU MSDu MSQE MSB MSE F-Prob df Dunnett's Test 800 1000 894.427191 2.60422823 0.07659495 1213.54667 6.48518519 8.2E-33 5, 54 Treatments vs D-Control Linear Interpolation (200 Resamples)
Point mg!L so 95%CL Skew ICOS 853.846154 68.891583 658.291667 950.259615 -0.9158 ICIO 984.615385 37.1605902 889.984375 1018.01841 -0.4734 IC15 1022.22222 10.1708642 1001.41628 1040.13001 0.1120 IC20 1047.40741 9.4426387 1027.71794 1065.06914 0.2104 IC25 1072.59259 ..-(}.34744229 1054.19332 1087.34371 0.2270 IC40 1148.14815 11.8528783 1126.04654 1168.22075 0.4312 ICSO 1198.51852 16.0574224 1169.42431 1229.62477 0.4948 11-10-09
Page 5 of 6 Species: Ceriodaphnia dubia CdNaCICR # : I oD CONTROL 600 mg NaCIIL 800 mg NaCIIL STOCK Page 101 of 102 SOP ATI4 - Exhibit ATI4. 1, revision 04-0 1-09
Page 6 of 6 Species: Ceriodaphnia dubia C dNaCICR #: ( 00 CONTROL 600 mg NaCI!L 800 mg NaCI/L Page 102 of 102 SOP AT 14- Exhibit AT 14.1 , revis ion 04-0 1-09
PERMITTEE NAME/ADDRESS NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPOE$) (Include Fac1/lty Name/Location 1f Different) MAJOR Form Approved DISCHARGE MONITORING REPORT (OMRJ m~--~~SEOU~~~~~~P~~--- (SUBR 01) OMB No 2040*0004 .ru:tru:e~ _P_,_Q._B_OX 2.Q90_ _ _ _ _ _ _ _ - - __ CINTEROFFICE SB*2A*SQN) ===sov~M~rn~3~======== l---p-;_RN_M-~~-~-~-!-5-e~-R----111 PISCHARG: ~~M~ER I ~~~~~~ WASTE TREATMENT POND ~~~-~~~~VA~~~~~ID--~-- EFFLUENT ~~~-~~T~~~-----~---- QAY 31
*** NO DISCHARGE D ...
ATIN: stephanie A. Howard NOTE: Read instructions before comoletlnQ th1s form X PARAMETER QUANTITY OR LOADING QUALITY OR CONCENTRATION NO. FREQUENCY SAMPLE EX OF TYPE ANALYSIS PH SAMPLE MEASUREMENT A.VERAGE MAXIMUM UNITS MINIMUM 7.2 ........ AVERAGE MAXIMUM 8.2 UNITS 12 0 13 I 31 GRAB 00400 1 0 0 PERM1T ***<Ht*** ******** .. . &~o***_. *. ******** ' su EFFLUENT GRQSS VALUE REQUIREMENT SAMPlE MINIMUM 9.0 MAXIMUM " THREE/ WEEK GRAB SOLIDS, TOTAL SUSPENDED MEASUREMENT 56 81 26 6 8 19 0 5 I 31 GRAB 00530 1 0 0 PERMIT 380 1250 LBS/DY **<Ht**** 30 100 MG/L WEEKLY GRAB REQUIREMENT EFFLUENT GROSS VALUE /, MOAVO DAILY MX MOAVG DAILYMX OIL AND GREASE SAMPLE <56 <60 26
******** <6 <6 19 0 5 I 31 GRAB MEASUREMENT 00556 1 0 0 PERMIT . 190 250 LBS/DY ******** 15 20 .-.** MG/l WEEKLY GRAB EFFLUENT GROSS VALUE FLOW, IN CONDUIT OR THRU
- ,REQUJ~E~I:trr SAMPLE MEASUREMENT
,MOAVO 1.196 DAILYMX .**
1.446 03 MOAVG DAILY MX*-"
*'******* .. 0 31 I 31 TOTALZ TREATMENT PLANT 50050 1 0 0 PERM!T REPORT REPORT MGD ......... ******** <Ht****** ** SEE TOTALZ EFFLUENT GROSS VALUE . REQUIREMENT *lito Avo* DAILYMX .'* PERMIT SAMPLE MEASUREMENT I
PERMIT ' REQUIREMENT SAMPLE MEASUREMENT PERMtT. REOliiREMENT SAMPLE MEASUREMENT
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PERMlT. " REQUIREMENT "
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NAME/TinE PRINCIPAL EXECUTIVE OFFICER 1Certafy under penalty of law thatthas document and all attachments were prepared under my TELEPHONE DATE darectaon or superviSIOn an accordance wath a system desagned to assure that quahfaed personnel Christopher R. Church properly gather and evaluate the anformataon submitted Based on my anquary of the person or persons who manage the system, or those persons d1rectly responsable for gathering the Environmental Manager SON & WBN anformation. the information submitted is. to the best of my knowledge and behef. true. 423 843-7001 10 01 07 Sequoyah Site Vice ~resident accurate. and complete I am aware that there are signifacant penallaes for submiltang false tnformalion. ancluding the possabthty of fane and amprasonment for knowang vaolahons SIGNATURE OF PRINCIPAL EXECUTIVE I TYPED OR PRINTED OFFICER OR AUTHORIZED AGENT
~~~~I NUMBER YEAR MO DAV COMMENTS AND EXPLANATION OF ANV VIOLATIONS fReference all attachments her EPA Form 3320-1 (REV 3199) Prev1ous edit1ons may be used Page 1 of 1
PERMITTEE NAME/ADDRESS (Include Factlttv Name/LocatiOn tf Dtfferent} NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPDESJ MAJOR Form Approved Name TVA* SEOUOYAH NUCLEAR PLANT DISCHARGE MONITORING REPORT (DMR} OMB No. 2040-0004 ~gress -P::Q.AOX2~ =========== (SUBR 01)
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a~~-~~EO~~~~~~~ID ____ _ 1---P-:-:-Mo-~~-~-~-!-5e-~-R-~\\ PISCHARc: ~~M~ER \ ~~~:_A~LEANING wAste PoNo ~~~0~~~~~~---------- em~~ E:~L~::,SCHARGE D ... ATIN: stephanie A. Howard I YEAR From: 09 :1 12 MP Ir'5WZYR!NG 01 ] TOr 09 ] Mil 12 Ill>>: 31 NOTE: Read instructions before completina this form PARAMETER X QUANTITY OR LOADING QUALITY OR CONCENTRATION NO. FREQUENCY SAMPLE EX OF TYPE AVERAGE MAXIMUM UNITS MINIMUM AVERAGE MAXIMUM UNITS ANALYSIS PH SAMPLE MEASUREMENT
******** ******** .. 8.0 ******** 8.7 12 0 7 I 31 GRAB 00400 1 0 0 PERMIT- ******** ******** .... ..* 60 ******** 9.0_ . su DAILY GRAB . REQUIREMENT: **:MtNIMOM ... :* . '~
EFFLUENT GROSS VALUE MAXIMUM SOLIDS, TOTAL SUSPENDED SAMPLE ******** ********
******** 2 0 7 I 31 COMPOS MEASUREMENT 19 00530 1 0 0 PERMIT REQUIREMENT *****~** ******** .... *****'*** ****'**** 30 MG/l DAILY COMPOS EFFLUENT GROSS VALUE DAILY MX-OIL AND GREASE . SAMPLE MEASUREMENT ******** ******** .. --~- ******** ******** <6 19 0 7 I 31 GRAB 00556 1 0 0 PERMIT REQUIREMENT ******** ******** .... .******** . ******** 15 MG/l DAILY GRAB EFFLUENT GROSS VALUE DAILYMX PHOSPHORUS, TOTAL (AS P) SAMPLE MEASUREMENT 19 00665 1 0 0 Pl;_RMtT. *. ******** ******** **** ******** .. * ****'**** 1.0 MG/l DAILY . COMPOS I****.
REQJjiREMENT EFFLUENT GROSS VALUE DAILYMX COPPER, TOTAL (AS CU) SAMPLE ******** ********
******** ******** 0.023 0 7 I 31 COMPOS MEASUREMENT 19 01042 1 0 0 PERMIT' ********** ******** **** ******** ******** 1.0 MG/L DAlLY COMPOS REQUIREMENT EFFLUENT GROSS VALUE DAILYMX*
IRON, TOTAL (AS FE) SAMPLE ******** ******** ******** ******** 0.14 0 7 I 31 COMPOS
** 19 MEASUREMENT 01045 1 0 0 PERMIT REQUIREMENT ******** 1.0 MG/l DAILY COMPOS EFFLUENT GROSS VALUE DAILYMX FLOW, IN CONDUIT OR THRU TREATMENT PLANT SAMPLE MEASUREMENT 0.021 0.034 03 ******** ******** ******** .. 0 7 I 31 CALCTD 50050 1 0 0 . PERMIT ." .;. ~~~,~ftT*. ,~EP9RJ" MGD ,._ ******** .... DAIL'f CALCTD REQ~IR~MEN'r_; : *.
EFFLUENT GROSS VALUE MO'AVO *I* DAILY.*MX
~~\.~u-Osllw~cL{d NAME/TITLE PRINCIPAl EXECUTIVE OFFICER I Certify under penally of law that thiS document and all attachments were prepared under my TELEPHONE DATE d1rection or supervision in accordance with a system designed to assure that qualified personnel Christopher R. Church properly gather and evaluate the mformahon subm1tted Based on my mqu1ry of the person or persons who manage \tie system. or those persons d1rectly respons1ble for galhenng the Environmental Manager SON & WBN.
tnformallon. the mformat1on subm11ted IS . to the best of my knowledge and behef. true. 423 843-7001 10 01 07 Sequayah Site Vice President accurate, and complete I am aware that there are Significant penalt1es for subm1tt1ng false SIGNATURE OF PRINCIPAL EXECUTIVE I TYPED OR PRINTED 1nformat1on. 1ncludmg the poss1b1hty of fme and 1mpnsonment for knowing v1olahons OFFICER OR AUTHORIZED AGENT AREA l"OOI: I NUMBER YEAR MO DAY COMMENTS AND EXPLANATION OF ANY VIOLATIONS fReference all attachments he! The Metal Ponds (0utfall107) were discharged directly to the LVWTP (0utfall103) an 12/3/09, 12/8/09, 12/10/09, 12/15/09, 12/16/09, 12/17/09. and 12/22/09. No phosphorous bearing cleaning solutions were used. EPA Form 3320-1 (REV 3/99) Previous editions may be used Page 1 of 1
PERMITTEE NAME/ADDRESS (Include Factlity Name/Location NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPOESJ if DtfferentJ MAJOR Form Approved Name TVA- SEOUOYAH NUCLEAR PLANT DISCHARGE MONITORING REPORT (OMRJ OMB No. 2040*0004 01) idgre:i$J.o.aoxw =========== CINTEROFFICE SB*2A*SON> ---soD~~~~m~~4------- (SUBR F- FINAL RECYCLED COOLING WATER ~~~=NA-w@~~~~~~m===== ~~~~AMIU~~OUN~---------- EFFLUENT NO DISCHARGE IXX I ... ATTN: stephanie A. Howard NOTE Read instructions before comoletrnQ thiS form X PARAMETER QUANTITY OR LOADING QUALITY OR CONCENTRATION NO. FREQUENCY SAMPLE EX OF TYPE AVERAGE MAXIMUM UNITS MINIMUM AVERAGE MAXIMUM UNITS ANALYSIS TEMPERATURE, WATER DEG. SAMPLE ******** ******** ******** ******** MEASUREMENT 04 04 CENTIGRADE 00010 z 0 0 . PERMJT .* RE091.REMENT
"******* .......... DEGC ~******* .......... '38.3 DEGC DAILY GRAB-4 INSTREAM MONITORING DAILY MX
- PH SAMPLE MEASUREMENT 12 00400 1 0 0 PERMIT REQUIREMENT
.......... ****'~~~*** **** 6.0 *' . *:*'*"**** 9.0 I
su WEEKLY GRAB EFFLUENT GROSS VALUE '. MINIMUM MAXIMUM SOLIDS, TOTAL SUSPENDED SAMPLE MEASUREMENT 19 00530 1 0 0 *PERMIT REQUIREMENT.
******** .......... .... . ******** ********. 30 MG/L DAILY COMPOS EFFLUENT GROSS VALUE DAILY MX OIL AND GREASE SAMPLE ******** ******** ******** ********
MEASUREMENT ** 19 00556 1 0 0 PERMIT REQUiREMENT 15 MG/L DAJLY GRAB EFFLUENT GROSS VALUE ; *. DAILYMX FLOW, IN CONDUIT OR THRU SAMPLE ******** ******** ******** MEASUREMENT 03 ** TREATMENT PLANT 50050 1 0 0 EFFLUENT GROSS VALUE PERMIT REQUIREMENT* REPORT MO. AVO REPO~T DAiLYMX MGD ******** ******** ******** - OAJLY CALCTO CHLORINE, TOTAL RESIDUAL SAMPLE MEASUREMENT 19 50060 1 0 0 PERMIT REQUIREMENT
. ****~,"** . "'******* .... .. ********' ******** 0.10 MG/L WEEKLY GRAB-4 EFFLUENT GROSS VALUE . ' . '
DAILYMX SAMPLE MEASUREMENT PERMIT .... REQUIR,~M~NT I*** A~\LLA.ii-0.~~ NAME/TITLE PRINCIPAL EXECUTIVE OFFICER I Certify under penally of law that th1s document and all attachments were prepared under my TELEPHONE DATE d1rect1on or supervision an accordance with a system des1gned to assure that qualified personnel Christopher R Church properly gather and evaluate the informat1on subm1t1ed Based on my tnqutry of the person or persons who manage the system. or those persons d1rectly respons1ble for gathermg the Environmental Manager SON & WBN tnformahon. the anformallon subm11ted is. to the best of my knowledge and belief. true. 423 843-7001 10 01 07 Sequoyah Site Vice President accurate. and complete I am aware that there are s*gn1ftcant penalties for subm111ang false Information, 1nclud1ng the poss1b1hty of fane and 1mpnsonment for know1ng v1ola110ns SIGNATURE OF PRINCIPAL EXECUTIVE L TYPED OR PRINTED OFFICER OR AUTHORIZED AGENT
~~~I NUMBER YEAR MO DAY COMMENTS AND EXPLANATION OF ANY VIOLATIONS (Reference all atuchments he!
No Discharge this Period EPA Form 3320-1 (REV 3199) Previous editions may be used Page 1 of 1
PERMITIEE NAME/ADDRESS (Include Fact/tty Name/Locatton tf Otfferent) NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPDES) MAJOR Form Approved
= == ===
Name TVA* SEOUOYAH NUCLEAR PLANT DISCHARGE MONITORING REPORT (DMRJ (SUBR 01) OMB No 2040-0004 MJ~e~ -PJi.JtOX~== == = UNTEROF~E S~&_S.Q..NL _ _ _ _ _ _ _ F *FINAL =-= = =S.QP.QY _:_PAlSY. TN 2]~4- ______ _ RECYCLED COOLING WATER ~~~-NA~~~~~~~P~W ____ _ EFFLUENT ~~~-~MIUO~~~----------
*** NO DISCHARGE IXX I ...
ATTN: Stephanie A. Howard NOTE* Read Instructions before comoletina this form X PARAMETER QUANTITY OR LOADING QUALITY OR CONCENTRATION NO. FREQUENCY SAMPLE EX OF TYPE AVERAGE MAXIMUM UNITS MINIMUM AVERAGE MAXIMUM UNITS ANALYSIS IC25 STATRE 7DAY CHR SAMPLE MEASUREMENT 23 CERIODAPHNIA I 1 PERMIT. , ******** 45~2 ******** ****llr*** PERCENT COMPOS
**~***** SEMI TRP3B 0 0 '
REQUIREMENT; :. EFFLUENT GROSS VALUE MiNIIUlUM ANNUAL IC25 STATRE 7DAY CHR SAMPLE ******** ******** ******** ******** MEASUREMENT 23 PIMEPHALES TRP6C 1 0 0 PERMIT REQUIREMENT
***:A-**** ******** .... I ' 45.2: ******** ******** PERCENT SEMI COMPOS EFFLUENT GROSS VALUE .. MINIMUM *.* ANNUAL SAMPLE MEASUREMENT I PERMIT REQUIREMENT SAMPLE MEASUREMENT PERMIT RE.9UIR~MENT . * ..
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~~041-~Ad NAMEntTLE PRINCIPAL EXECUTIVE OFFICER I Cer1tfy under penally of law that lhts document and all artachments were prepared under my TELEPHONE DATE dtreclion or supervtston tn accordance w1th a system destgned to assure that qualified personnel Christopher R. Church properly gather and evaluate Ihe tnlormalion submtlted. Based on my" mqutry ollhe person or persons who manage the system. or those p~rsons dtrectly responstble for gathertng !he Environmental Manager SON & WBN mformatton. the informahon submitted tS . to the best of my knowledge and belief. true. 423 843-7001 10 01 07 Sequoyah Site Vice President accurate. and complete I am aware lhallhere are stgntftcanl penalhes for submtthng false tnformallon. tncluding the posstbthly of ftne and impnsonmenl for knowtng vtolaltons SIGNATURE OF PRINCIPAL EXECUTIVE I lYPED OR PRINTED OFFICER OR AUTHORIZED AGENT AREA CODE I NUMBER YEAR MO DAY COMMENTS AND EXPLANATION OF ANY VIOLATIONS fReference all attachments het No Discharge this Period EPA Form 3320*1 (REV 3/99) Previous editions may be used Page 1 of 1
PERMITTEE NAME/ADDRESS (Include Facility Name/Location if Different) NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPOE$) MAJOR Form Approved Name TVA* SEOUOYAH NUCLEAR PLANT DISCHARGE MONITORING REPORT (OMRJ (SUBR 01) OMB No 2040-0004 &tale~ !INTEROFFICE =========== PJi.ee>XiOO~SB*2A*SONl f-----e-;-:-Mo-,~-~-~-!--a~-R-..........jll mscHARc~ ~~M~ER I 5 F- FINAL
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D~~-~~~~~~~~~~ID ____ _ BACKWASH Mil r:yryRING p=~ MJl From Ix~~R I 12 I 01 ] TO [ 09 ] 12 EFFLUENT ~~~-~~TONCN~--~-~----- ATIN: Stephanie A. Howard QAY 31 NO DISCHARGE D ... NOTE* Read instructions before comoletina th1s form X PARAMETER QUANTITY OR LOADING QUALITY OR CONCENTRATION NO. FREQUENCY SAMPLE EX OF TYPE AVERAGE MAXIMUM UNITS MINIMUM AVERAGE MAXIMUM UNITS ANALYSIS DEBRIS, FLOATING (SEVERITY) SAMPLE ******** ******** ******** ******** 1 I 31 VISUAL MEASUREMENT
** 0 9A 0 01345 1 0 0 PERMIT REQUiREMENT
- ic
******** REPORT PASS=O SEE VISUAL EFFLUENT GROSS VALUE FAIL=1 *c
- MOTOTAL PERMIT OIL AND GREASE VISUAL SAMPLE MEASUREMENT
******** 0 94 ******** ******** ******** .... 0 1 I 31 VISUAL 84066 1 0 0 PERMIT REQUIREMENT ........... REPORT YES=1 ******** ' ******** ********. .... SEE VISUAL EFFLUENT GROSS VALUE NO=O ~ MOTOTAL PERMIT SAMPLE MEASUREMENT PERMIT I REQUIREMENT ~* ,,_
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NAME/TITLE PRINCIPAL EXECUTIVE OFFICER I Certtfy under penally of law that this document and all attachments were prepared under my TELEPHONE DATE dtrectton or superv1ston in accordance wtlh a system des1gned to assure that quahf1ed personnel Christopher R. Church properly gather and evaluate the 1nformatton subm1tted Based on my .nqu1ry of the person or persons wno manage the system, or those persons d1rect1y responstble for gathenng lhe Environmental Manager SON & WBN 1nformat1on. the mformallon submitted IS , to the best of my knowledge and behef. true, 423 843-7001 10 01 07 Sequoyah Site Vice President accurate. and complete I am aware thai there are s1gmficant pena1t1es for submltltng false mformat1on. includmg the possibility of f1ne and 1mpnsonment for knowtng v1o1a110ns SIGNATURE OF PRINCIPAL EXECUTIVE 1
-~6~~ I OFFICER OR AUTHORIZED AGENT NUMBER YEAR MO DAY ~PED OR PRINTED COMMENTS AND EXPLANATION OF ANY VIOLATIONS fReference all attachments he!
Operations performs visual inspections for floating debris and oil and grease during all backwashes. EPA Form 3320*1 (REV 3/99) Prev1ous editions may be used Page 1 of 1
PERMITTEE NAME/ADDRESS NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM {NPOESJ (Include Fac1fltV Name!Locat1on 1f Different) MAJOR Form Approved
. DISCHARGE MONITORING REPORT fDMRJ Name
- TVA* SE~~~~~~~ ~~N!_ __ _ (SUBR 01) OMS No. 2040*0004
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~~~-~~w~~~~~~w ____ _ l---p_.;;...;.R~.;..;~....;~-~-~-~5-a0-eR-~II D!SCHAB!i: ~~M~ER I F- FINAL BACKWASH I~~~R I ~~ ~~~~~N~~NTI _________ _ EFFLUENT ATTN: Stephanie A. Howard From NO DISCHARGE D ... NOTE. Read instructrons before comoletlna this.form
~
PARAMETER QUANTITY OR LOADING QUALITY OR CONCENTRATION NO. FREQUENCY SAMPLE EX OF TYPE AVERAGE MAXIMUM UNITS MINIMUM AVERAGE MAXIMUM UNITS ANALYSIS DEBRIS, FLOATING (SEVERITY) SAMPLE MEASUREMENT
******** ******** .. ******** ******** 0 9A 0 1 I 31 VISUAL 01345 1. 0 0 'PERMIT REQUIREMENT ******** ******** .... *****'~'** ******** REPORT PASS=O SEE VISUAL EFFLUENT GROSS VALUE FAIL=1 MOTOTAL' PERMIT OIL AND GREASE VISUAL SAMPLE ******** 0 ******** ******** **"'***** 1 I 31 VISUAL MEASUREMENT 94 ** 0 84066 1 0 0 ~pERMIT '******** RE;PORT. YES=1 ****'**** *******'* ******** .... SEE VISUAL REQUIREMENT NO=O EFFLUENT GROSS VALUE MO*TOTAr ,.*
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REAVIReMEN.T* :'*I*. JttptttuW Ct.~eu-J NAME/TITLE PRINCIPAL EXECUTIVE OFFICER I Cert1fy under penally of law thatth1s document and all allachments.were prepared under my TELEPHONE DATE d1rect1on or superv1s1on an accordance WJth a system des1gned to assure that quallf1ed personnel Christopher R Church properly gather and evaluate the 1nformation submitted Based on my inquiry of the person or persons who manage the system, or those persons directly respon~1bte for gathering the Environmental Manager SON & WBN information. the anformallon subm11ted IS , to the best of my knowledge and behef. true. 423 843-7001 10 01 07 Sequoyah Site Vice President accurate. and complete I am aware that there are stgmficant penalties for subm11tmg false mformat1on. anctud1ng the poss1b1hty of f1ne and 1mprisonment for knowmg v1olations SIGNATURE OF PRINCIPAL EXECUTIVE l
--~~~I OFFICER OR AUTHORIZED AGENT NUMBER YEAR MO DAY TIPED OR PRINTED COMMENTS AND EXPLANATION OF ANY VIOLATIONS £Reference all attachments het Operations performs visual inspections for floating debris and oil and grease during all backwashes.
EPA Form 3320*1 (REV 3/99) Prev1ous editions may be used Page 1 of 1
PERMITIEE NAME/ADDRESS (Include Facllttv Name/LocatiOn tf Dtfferent) NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPDESJ Form Approved MAJOR Name TVA* SEOUOYAH NUCLEAR PLANT DISCHARGE MONITORING REPORT fDMRJ OMB No 2040-0004 id~ess=P:Q. =
= ======
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=== (SUBR 01}
F- FINAL WASTEWATER & STORM WATER Fa~~-M~EOUo~~UC~AA~m----- ~~~=~Ttro~~~========== EFFLUENT PAY 31 NO DISCHARGE IXX I .... ATTN: Stephanie A. Howard NOTE Read mstructions before comoletmo th1s form X PARAMETER QUANTITY OR LOADING QUALITY OR CONCENTRATION NO. FREQUENCY SAMPLE EX OF TYPE AVERAGE MAXIMUM UNITS MINIMUM AVERAGE MAXIMUM UNITS ANALYSIS OXYGEN, DISSOLVED (DO) SAMPLE ******** ******** ******** ********
** 19 MEASUREMENT 00300 1 0 0 PERMIT. ********. ********* **** I' ******** ********
I . ~.Qi** ... MG/L .lWICEI GRAB REQUI"EMENT EFFLUENT GROSS VALUE DAILY,MN WEEK SOLIDS, TOTAL SUSPENDED SAMPLE ******** ******** ******** ********
** 19 MEASUREMENT 00530 1 0 0 PERMIT REQ~JREMENT ******** ******** .... **~*** ******** 100 MG/L TWICE/ GRAB EFFLUENT GROSS VALUE DAILYMX WEEK SOLIDS, SETTLEABLE SAMPLE ******** ******** ******** ******** ** 25 MEASUREMENT 00545 1 0 0 *.*PERMIT REQUIREMENT . .... ******"* '******** 1.0 MUL ONCE/ GRAB EFFLUENT GROSS VALUE DAILY MX MONTH FLOW, IN CONDUIT OR THRU SAMPLE MEASUREMENT 03 TREATMENT PLANT I
50050 1 0 0 *PERMIT REPORT REPORT MGD ******** ******** ******** t ONCE/ ESTIMA REQUIREMENT EFFLUENT GROSS VALUE MOAVO DAILY.MX : ' BATCH SAMPLE MEASUREMENT PERMIT ' REQUIREMENT SAMPLE MEASUREMENT
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REQUI.REMENT J~~a~cL NAME/TITLE PRINCIPAL EXECUTIVE OFFICER 1 Cert1fy under penally of law that thiS documel)l and all attachments were prepared under my TELEPHONE DATE d1rect1on or superv1s*on in accordance w1lh a system des1gned to assure lhal qualif1ed personnel Christopher R Church property gather and evaluate the informat1on submztted Based on my 1nquzry of the person or persons who manage the system. or those persons d1rectly responsible fOI' gathering the Environmental Manager SON & WBN mformat1on. the rnformatron submtlled IS . to the best of my knowledge and bel1ef. true. 423 843-7001 10 01 07 Sequoyah Site Vice President accurate. and complete I am aware that there are s1gntf1cant penalt1es for subm*tllng false znformahon. including the poSSibility o! !me and 1mpnsonment for knowtng VIOlations SIGNATURE OF. PRINCIPAL EXECUTIVE I TYPED OR PRINTED OFFICER OR AUTHORIZED AGENT
~~~~I NUMBER YEAR MO DAY COMMENTS AND EXPLANATION OF ANY VIOLATIONS tReference all attachments het During this reporting period, there has been no flow from the Dredge Pond other than that resulting from rainfall.
EPA Form 33~0-1 (REV 3/99) Previous edittons may be used Page 1 of 1
Page 2 of2 Shipment Receipt Address Information Ship to: Ship from: Mr. Patrick Cromer Ruth Ann Hurt TDEC- Div. of Water TVA Pollution 6th Floor, L & C Annex SEQUOYAH NUCLEAR PLANT 40 1 Church Street Nashville, TN SODDY DAISY, TN 372431534 37379 us us 4238436700 4238436714 Shipping Information Tracking number: 798297133424 Ship date: 0 I /13/201 0 Estimated shipping charges: 5.18 Package Information Service type: Priority Overnight Package type: FedEx Pak Number of packages: I Total weight: 2LBS Declared value: O.OOUSD Special Services: PickJip/Drop-off: Use an already scheduled pickup at my location Billing Information Bill transportation to: Sender Your reference: P.O. no.: Invoice no.: Department no.:
- Thank you for shipping online with Fedex ShipManager at fedex.com.
Please Note FedEx will not be responsible for any cta1m in excess of $100 per package, whether the result of loss, damage, delay, non-delivery, misdelivery. or m1s1nformation. unless you declare a higher value, pay an additional charge, document your actual toss and file a timely Claim. Limitations found in the current FedEx Service Guide apply. Your right to recover from FedEx for any loss, includ1ng intrinsic value of the package, loss of sales, income interest, profit, attorney's fees. costs. and other forms of damage whether direct, incidental, consequential, or speical is limited to the greater of $100 or the authonzed dedared value. Recovery cannot exceed actual documented loss. Max1mum for items of extraordinary value is $500, e.g., jewelry, precious metals, negotiable Instruments and other items lised in our Service Guide. Written claims must be filed within strict time limits; Consult the applicable FedEx Service Guide for deta11s The estimated shipp1ng charge may be d1fferentthan the actual charges for your shipment Differences may occur based on actual we1ght, dimensions. and other factors. Consult the applicable Fed~~~ Guide or the FedEx Rate Sheets for deta11s on how shipping Charges are calculated https://www .fedex.corn/shipping/html/en/PrintiFrame.html 01/13/2010
Page 2 of2 Shipment Receipt Address Information Ship to: Ship from: Mr. Mike Kelley Ruth Ann Hurt Chattanooga EAC - Div. of TV A Water State Office Building, Suite SEQUOY AH NUCLEAR 550 PLANT 540 McCallie Avenue Chattanooga, TN SODDY DAISY, TN 374022013 37379 us us 423-843-6700 4238436714 Shipping Information Tracking number: 798297136022 Ship date: 01/13/2010 Estimated shipping charges: 5.18 Package Information Service type: Priority Overnight Package type: FedEx Pak Number of packages: 1 Total weight: 2LBS Declared value: O.OOUSD Special Services: Pickup/Drop-off: Use an already scheduled pickup at my location Billing Information Bill transportation to: Sender Your reference: P.O. no.: Invoice no.: Department no.: Thank you for shipping online with Fedex ShipManager at fedex.com. Please Note FedEx will not be responsible for any clarm rn excess of $100 per package, whether the result or loss, damage, delay. non-delivery, misdelivery, or mrsinformation, unless you declare a higher value, pay an addrtional Charge, document your actual loss and file a timely claim. Lrmrtations found in the current FedEx Service Guide apply. Your right to recover from FedEx for any loss, including intrinsic value of the package, loss of sales. income interest, profit, attomey's fees. costs. and other forms of damage whether direct, incidental, consequential, or speical is limited to the greater of $100 or the authorized declared value. Recovery cannot exceed actual documented loss. Maximum for items of extraordinary value is $500, e.g., jewelry, precious metals, negotiable instruments and other items lised in our Service Guide. Wntten claims must be filed within strict time limits; Consult the applicable FedEx Service Gurde for details The estimated shipprng charge may be different than the actual charges for your shipment Drfferences may occur based on actual weight, dimensions, and other factors. Consult the applicable ~X~.l!tc;!LG..\!l~te. or the FedEx Rate Sheets for details on how shipping charges are calculated https://www .fedex.com/shipping/html/en/PrintiFrame.html 01/13/2010
Page 2 of2 Shipment Receipt Address Information Ship to: Ship from: To whom it may concern: Ruth Ann Hurt Nuclear Regulatory TVA Commission ATTN: Docutnent Control SEQUOYAH NUCLEAR Desk PLANT Washington, DC SODDY DAISY, TN 20555 37379 us us 423-843-6700 4238436714 Shipping Information Tracking number: 798297138426 Ship date: 01/13/2010 Estimated shipping charges: 5.18 Package Information Service type: Priority Overnight Package type: FedEx Pak Number of packages: I Total weight: 2LBS Declared value: O.OOUSD Special Services: Pickup/Drop-off: Use an already scheduled pickup at my location Billing Information Bill transportation to: Sender Your reference: P.O. no.: Invoice no.: Department no.: Thank you for shipping online with Fedex ShipManager at fedex.com. Please Note FedEx will not be responstble for any claim m excess of $100 per package, whether the result of loss. damage, delay, non-delivery, mtsdetivery, or misinformation, unless you dedare a higher value. pay an addthonal charge. document your actual loss and file a timely da1m. Limitations found in the current FedEx Serv1ce Gu1de apply. Your right to recover from FedEx for any loss. indud1ng intrinsic value of the package, loss of sales, income 1nterest. profit. attorney's fees, costs, and other forms of damage whether direct, incidental, consequential, or speicalts limited to the greater of $100 or the authorized dedared value Recovery cannot exceed actual documented toss Max1mum for items of extraordtnary value is $500. e.g, Jewelry, precious metals. negottable 1nstruments and other items llsed in our Service Guide. Written da1ms must be filed within strict time limtts; Consult the applicable F edEx Service Gu1de for deta11s The estimated shipping charge may be dtfferent than the actual charges for your shipment. Differences may occur based on actual weight, dimensions, and other factors. Consult the applicable EedEx Servtc;_~ide or the Fed Ex Rate Sheets for details on how shipping charges are calculated https://www.fedex.com/shipping/html/en/PrintiFrame.html 01113/2010}}