ML13289A204
Text
S58 080213 800 - NPDES CORRESPONDENCE February 13, 2008 State of Tennessee Department of Environment and Conservation Division of Water Pollution Control Enforcement & Compliance Section 6th Floor, L & C Annex 401 Church Street Nashville, Tennessee 37243-1534
Dear Mr. Patrick Cromer:
SEQUOYAH NUCLEAR PLANT - DISCHARGE MONITORING REPORT FOR JANUARY 2008 Enclosed is the January 2008 Discharge Monitoring Report for Sequoyah Nuclear Plant.
Please contact me at (423) 843-7332 if you have any questions or comments.
Sincerely, Diedre B. Nida Chemistry/Environmental Support Manager Signatory Authority for Timothy P. Cleary Site Vice President Sequoyah Nuclear Plant AH Enclosure cc (Enclosure):
Chattanooga Environmental Assistance Center Division of Water Pollution Control State Office Building, Suite 550 540 McCallie Avenue Chattanooga, Tennessee 37402-2013 U.S. Nuclear Regulatory Commission ATTN: Document Control Desk Washington, D.C. 20555 cc:
D. J. Bodine, POB 2A-SQN A. A. Ray, WT 7C-K C. R. Church, POB 2B-SQN J. D. Smith, OPS 4A-SQN T. P. Cleary, OPS 4A-SQN G. R. Signer, WT 6A-K D. E. Pittman, BR 4T-C EDMS, WT CA-K (Enclosure)
DMR0801.doc
Tennessee Valley Authority, Post Office Box 2000, Soddy-Daisy, Tennessee 37384-2000 February 13, 2008 State of Tennessee Department of Environment and Conservation Division of Water Pollution Control Enforcement & Compliance Section 6 th Floor, L & C Annex 401 Church Street Nashville, Tennessee 37243-1534
Dear Mr. Patrick Cromer:
SEOUOYAH NUCLEAR PLANT - DISCHARGE MONITORING REPORT FOR JANUARY 2008 Enclosed is the January 2008 Discharge Monitoring Report for Sequoyah Nuclear Plant. Please contact me at (423) 843-7332 if you have any questions or comments.
Sincerely, Diedre B. Nida Chemistry/Environmental Support Manager Signatory Authority for Timothy P. Cleary Site Vice President Sequoyah Nuclear Plant Enclosure cc (Enclosure):
Chattanooga Environmental Assistance Center Division of Water Pollution Control State Office Building, Suite 550 540 McCallie Avenue Chattanooga, Tennessee 37402-2013 U.S. Nuclear Regulatory Commission ATTN: Document Control Desk Washington, D.C. 20555
PERMITTEE NAME/ADDRESS (Include Facility Name/Location if Different)
NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPDES)
MAJOR Form Approved.
Name TVA - SEQUOYAH NUCLEAR PLANT DISCHARGE MONITORING REPORT (DMR)
(SUBR 01) 0MB No. 2040-0004 Address P.O. BOX 2000 -
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DISCHARGE NUMBER DIFFUSER DISCHARGE Facijity TVDA
-_ EQUOYA~H NUCLEAkR PLANT Location HAMILTON COUNTY MONITORING PERIOD EFFLUENT LYEARLMOLDAY YEA MO AY
- NO DISCHARGE L
ATTN: Diedre B. Nida From 08 0
1 ToL08 01 31 NOTE: Read instructions before completing this form.
PARAMETER QUANTITY OR LOADING QUALITY OR CONCENTRATION NO.
FREQUENCY SAMPLE E X EFOFTT Y P AVERAGE MAXIMUM UNITS MINIMUM AEGEMAXIMUM UNITS AAYI
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~~information, the information submitted is, to the best of my knowledge and belief, true, 43 8373 Site Vice Presidentaccurate, and complete. l am aware that there are significant penalties for submitting false SIGNATURE OF PRINCIPAL EXECUTIVEI information, including the possibility of tine and imprisonment for knowing violations.
OFFICER OR AUTHORIZED AGENT AREA INUMBER YEAR M
A TYPED OR PRINTED CODE COMMENTS AND EXPLANATION OF ANY VIOLATIONS (Reference all attachments here)
No closed mode operation. The following information is included in anattachment: CCW data EPA Form 3320-1 (REV 3199)
Previous editions may be used Page 1 of 2
DMR Attachment CCW Data CCW TRENCH Extractable Petroleum Date/Time Collected Hydrocarbons Analysis Date/Time Analyst Method 01/08/2008 @ 1110
<0.10 mgIL 01/10/2008 @2238 RDH TN EPA 8015
- 01/08/2008 @1110 0.41 mgIL 01/18/2008 @0930 RDH TN EPA 8015
- 01/08/2008 1115
<0.10 mg/L 01/18/2008 @ 0940 RDH TN EPA 8015
.*01/23/2008 0915
<0.10m 01/24/2008 @ 1845 NGW TN EPA 8015
- Backup sample - past hold time, for info only
- Resample
PERMITTEE NAME/ADDRESS (Include FacilityvName/Location if Different)
NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPDES)
MAJOR Form Approved.
Name TVA - SEQUOYAH NUCLEAR PLANT----
DISCHARGE MONITORING REPORT (DMR)
(SUBR 01) 0MB No. 2040-0004 Address P.O. BOX 2000 ITEOM(CE!sB-ZATN0026450 101 G F -FINAL SODDY - DAISY TN 37384 L
PERMIT NUBRDISCHARGE NUMBER]
DIFFUSER DISCHARGE Facility TVA -SEQUOYAH NUCLEAR PLANT Location HAMILTON COUNTY OITRING PERD EFFLUENT YEAR MO DAY YEA~R IMO IDAY NO DISCHARGE I
ATTN: Diedre B. Nida From 08 0
1 To 0
1 3
I 0-1 I
~~~NOTE: Read instructions before completing this form.
PARAMETER QUANTITY OR LOADING1 QUALITY OR CONCENTRATION No. FREQUENCY SAMPLE AVERAGE MAXIMUM UNITS MINIMUM
~~~~~~~~~~~~~~EX OF TYPE AVERAGE UNITS MINIMUM
~~~AVERAGE MAXIMUM UNITS AAYI CHLORINE, TOTAL RESIDUAL SAMPLE I*0.100319 0
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DEG CONTIN CLT EFFLUENT GROSS VALUE REQUIREMENT DAL MX C/HR u
S SAMPLE YUU MEASUREMENT PERMIT REOUIREMENT SAMPLE MEASUREMENT PERMIT REQUIREMENT SAMPLE MEASUREMENT PERMIT REQUIREMENT SAMPLE MEASUREMENT PERMIT REQUIREMENT SAMPLE MEASUREMENT REQUIREMENT NAME/TITLE PRINCIPAL EXECUTIVE OFFICER I Certify under penalty of law that this document and all attachments were prepared under my TELEPHONE DATE lirec--n or superviaion in accordance wiih a aystem designed to assure that qualified personnelJ/,
gC Timothy P. Cleary properly gather and evaluate the information aubmitted. Based on my inquiry of the person or
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OFFICER OR AUTHORIZED AGENT AREA NUMBER YEAR MO DAY TYPED OR PRINTED CODE COMMENTS AND EXPLANATION OF ANY VIOLATIONS (Reference all attachmients here)
The following injections occured: 1. Biodetergent 73551 (max. calc. conc. was
.017mg/L--limit 2.Omg/L)
EPA Form 3320-1 (REV 3199)
Previous editions may be used Page 2 of 2
PERMITTEE NAME/ADDRESS (Include Facility Name/Location if Different)
NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPDES)
MAJOR Form Approved.
Name TVA - SEQUOYAH NUCLEAR PLANT----
DISCHARGE MONITORING REPORT (DMR)
(SUBR 01) 0MB No. 2040-0004 Add ress P.O. BOX 2000 Il~jT~aO~qE!LB-LA TN0026450 101 T F -FINAL SO
_aDDY AIY TN_37384 PERMIT NUMBER IDISCHARGE NUMBER BIOMONITORING FOR OUTFALL 1 01 Facility TVA -SEOUOYAH NUCLEAR PLANT Location HA'MILTON COUNTY MOI RNG ER DEFL N
YA MO DYYEAR MO DAY NO DISCHARGE 7
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Read instructions before completing this form.
PARAMETER QUANTITY OR LOADING QUALITY OR CONCENTRATION NO.
FREQUENCY SAMPLE E X OFX T Y PEY P
AVERAGE MXMM UIS MINIMUM AVERAGE
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______PERMIT IC25 STATRE 7DAY CHR SAMPLE Monitoring 23 PIMEPHALES MEASUREMENTNoReird______
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~information, the information submitted is, to the best of my knowledge and belief, true,________________________
Site Vice Presidentaccurate, and complete, I am aware that there are significant penalties for submitting false SIGNATURE OF PRINCIPAL EXECUTIVE information, including the possibility of fine and imprisonment for knowing violations.
OFIE RATORZDAET AEA NUMBER YER MO DAY TYPED OR PRINTED
________CODos COMME~NTS AND -EXPLANATION OF ANY VIOLATIONS (Reference alf attachments here)
Toxicity was not sampled in January 2008.
EPA Form 3320-1 (REV 3/99)
Previous editions may be used Page 1 of 1
PERMITTEE NAME/ADDRESS (Include FacilityName/Location ifDifferent)
NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPDES)
MAJOR Form Approved.
Name TVA - SEQUOYAH NUCLEAR PLANT DISCHARGE MONITORING REPORT (DMR)
(SUBR 01)
OMB No. 2040-0004 Address P.O. BOX 2000 INTEROmClE S-B-2A).........L TN0026450 103 G F-FINAL SODDY - DAISY TN 37384 PERMIT NUMBER ISHRENM R
LOW VOL. WASTE TREATMENT POND Facility TVA -SEQUOYAH NUCLEAR PLANT Location HAMILTON COUNTY MONITOINGPERIOD EFFLUENT YvEARL_ MO DAY 1 YEARLMO DOAYK NO DISCHARGE 77 '
ATTN: Diedre B. Nida From 08 01 01 To 08 01 3
NOTE: Read instructions before completing this form.
PARAMETER 1
QUANTITY OR LOADING QUALITY OR CONCENTRATION NO.
FREQUENCY SAMPLE EX OF TYPE AVERAGE MAXIMUM UNITS MINIMUM AVERAGE MAXIMUM UNITS ANALYSIS iPH SAMPLE AVERAGE UNITS 8.6 0
13_31 GRAB MEASUREMENT 1
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0 0
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-REQIUIREMENT EFFLUENT GROSS VALUE MO AVG A
MX PERMIT_
SAMPLE MEASUREMENT PERMIT REQUIREMENT SAMPLE MEASUREMENT PERMIT REQUIREMENT SAMPLE MEASUREMENT PERMIT REQUIREMENT NAME/TITLE PRINCIPAL EXECUTIVE OFFICER I Certify under penalty of law that this document and all attachments were prepared under my TELEPHONE DATE direction or supervision in accordance with a system designed to assure that qualified personnel Timothy P. Cleary properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the Chem./Env. Support Manager
- 423 843-7332 08 02 13 information, the information submitted is, to the best of my knowledge and belief, true, 423_843_7332____02 accurate, and complete. I am aware that there are significant penalties for submitting false SIGNATURE OF PRINCIPAL EXECUTIVE TYPED__
OR__PRINTED_
inf
,ormation, including the possibility of fine and imprisonment for knowing violations.
OFFICER OR AUTHORIZED AGENT AREA NUMBER YEAR MO DAY TYPED OR PRINTED
__CODE COMMENTS AND EXPLANATION OF ANY VIOLATIONS (Reference all attachments here)
EPA Form 3320-1 (REV 3/99)
Previous editions may be used Page 1 of 1
PERMITTEE NAME/ADDRESS (Include FacilitvName/Location if Different)
NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPDES)
MAJOR Form Approved.
Name TVA - SEQUOYAH NUCLEAR PLANT----
DISCHARGE MONITORING REPORT (DMR)
(SUBR 01) 0MB No. 2040-0004 Address P.O. BOX 2000 INEOMCESB-LA)..........TNOO2450 107 G F -FINAL SODDY - DAISY
.TN 37384 PERMIT NUMER DISCHARGE NUMBER]
METAL CLEANING WASTE POND
- Facjii, TVA -SEOUOYAH NUCLEAR PLANT Location HAMILTOIN CTOUNTY MONIT1IKRNGPERIODEFUN YEAR -LMO DALYARDAY AY NO DISCHARGE ATTN: Diedre B. Nida From _ 08_
01 ]01] To 0
1 3
NOTE: Read instructions before completing this torm.
PARAMETER 1QUANTITY OR LOADING QUALITY OR CONCENTRATION NO.
FREQUENCY SAMPLE I ________
~~~
~~~~~~~~~~~~~~~~~~
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00530 1
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PERMIT REPORT REPORT MGD DAILY CALCTD IEFFLUENT GROSS VALUE RQIENT MO AVG DAILY MX NAME/TITLE PRINCIPAL EXECUTIVE OFFICER I Certify under penalty of law that this document and all attachments were prepared under my
>-'TELEPHONE DATE Timothy P. Cleary
- h~drection or suevso nacrac with a system designed to assure that qualified personnel TimothyP. Clery proerly gaher an evalute theinformation submitted. Based on my inquiry of the person or persona who manage the system, or those persons directly responsible for gathering the Chem./Env. Support Manager 2
4-32 0
2 13 Site Vice President
~~information, the information submitted is, to the best of my knowledge and belief, true, 423____843____7332__________02_
Site Vice Presidentaccurate, and complete. Ilam aware that there are significant penalties for submitting false SIGNATURE OF PRINCIPAL EXECUTIVE I_______
TYPED_______
OR____PRINTED________information, including the possibility of fine and imprisonment.for knowing violations.
OFFICER OR AUTHORIZED AGENT AREA INUMBER YEAR MO DAY T Y P E D O R P RIN T E D
_ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _C O D E COMMENTS AND EXPLANATION OF ANY VIOLATIONS (Reference all attachments here)
No Discharge this Period EPA Form 3320-1 (REV 3/99)
Previous editions may be used Page 1 of 1
PERMITTEE NAME/ADDRESS (Include FacilitvName/Location ifDifferent)
NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPDES)
MAJOR Form Approved.
Name TVA - SEQUOYAH NUCLEAR PLANT DISCHARGE MONITORING REPORT (DMR)
(SUBR 01) 0MB No. 2040-0004 Address P.O. BOX 2000
___ess P.f!EOMLEB AITN0026450 110G FF-FINAL SODDY-DAISY TN 37384 --
UPER~MIT NUMBER DISCHARGE NUMBER RECYCLED COOLING WATER Facility TVA -SEQUOYAH NUCLEAR PLANT Location HAMILTON COUNTY MONITORING ERIQP EFFLUENT YEAR MO DAY I YEARI MO DAY I
O ISHAG
.. NO DISCHARGE X-]
ATTN: Diedre B. Nida From 08 01 01 To 08 01 31 NOTE: Read instructions before completing this form.
PARAMETER QUANTITY OR LOADING IQALITY OR COCENTRATION NO.
FREQUENCY SAMPLE EX OF TYPE AVERAGE
_______________MAXIMUM MINIMUM AVERAGE MAXIMUM UNITS TEMPERATURE, WATER DEG.
SAMPLE 4
04 CENTIGRADE MEASUREMENT 04_04 00010 Z
0 0
PERMIT DEG C 38.3 DEG C DAILY GRB-INSTREAM MONITORING REQUIREMENT DAILY MX PH SAMPLE 12 MEASUREMENT 00400 1
0 0
PERMIT 6.0 9.0 Su WEEKLY GRAB EFFLUENT GROSS VALUE REQUIREMENTMINIMUM MAXIMUM SOLIDS, TOTAL SUSPENDED SAMPLE 19 MEASUREMENT 00530 1
0 0
PERMIT 30 MGIL
- DAILY, COMPOS EFFLUENT GROSS VALUE REQUIREMENT DAILY MX OIL AND GREASE SAMPLE 19 MEASUREMENT 19 00556 1
0 0
PERMIT 15 MG/L DAILY GRAB EFFLUENT GROSS VALUE RUM DAILYMX FLOW, IN CONDUIT OR THRU SAMPLE 03 TREATMENT PLANT MEASUREMENT 03 50050 1
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0 0
PERMIT 0.10 MGIL WEEKLY GRAB-4' REQUIREMENT EFFLUENT GROSS VALUE DAILY MX SAMPLE MEASUREMENT PERMIT REQUIREMENT
[ NAME/TITLE PRINCIPAL EXECUTIVE OFFICER I Certify under penalty of law that this document and all attachments were prepared under my TELEPHONE DATE ydirtion or supervision in accordance with a system designed to assure that qualified personnel Timothy P. Cleary properly gather and evaluate the information submitted. Based on my inquiry of the person or hL--
persons who manage the system, or those persons directly responsible for gathering the Chem./Env. Support Manager 423 843-7332 08 02 13 Site Vice President
~information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false SIGNATURE OF PRINCIPAL EXECUTIVE TYPED_______________________information, including the possibility of fine and imprisonment for knowing violations.
OFFICER OR AUTHORIZED AGENT AREA NUMBER YEAR MO DAY TYPED OR PRINTED
_coos COMMENTS AND EXPLANATION OF ANY VIOLATIONS (Reference all attachments here)
No Discharge this Period EPA Form 3320-1 (REV 3199)
Previous editions may be used Page 1 of 1
PERMITTEE NAME/ADDRESS (Include Facility Name/Location if Different)
NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPDES)
MAJOR Form Approved.
Name TVA -SEQUOYAH NUCLEAR PLANT DISCHARGE MONITORING REPORT (DMR)
BMB No. 2040-0004 (SUBR 01)
M o
0-04 Address P.O. BOX 2000 (INTEROFFICESB-2TN0026450 110 T F -FINAL SODDY - DAISY TN 37384 PERMIT NUMBER DISCHARGE NUMBER RECYCLED COOLING WATER Facility TVA - SEQUOYAH NUCLEAR PLANT Location HAMILTON COUNTY
-MONITORINGPERIOD EFFLUENT YEAR O
YEARYEAR MODAmY NO DISCHARGE ATTN: Diedre B. Nida From 08 01 01 To 0
31 NOTE: Read instructions before completing this form.
PARAMETER QUANTITY OR LOADING T
QUALITY OR CONCENTRATION NO.
FREQUENCY SAMPLE EX OF TYPE AVERAGE MAXIMUM UNITS MINIMUM AVERAGE MAXIMUM UNITS ANALYSIS IC25 STATRE 7DAY CHR SAMPLE 23 CERIODAPHNIA MEASUREMENT TRP3B 1
0 0
PERMIT 45.2 PERCENT SEMI OPO REQUIREMENT EFFLUENT GROSS VALUE MINIMUM A
IC25 STATRE 7DAY CHR SAMPLE PIMEPHALES MEASUREMENT 23 TRP6C 1
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PERMIT 45.2 PERCENT SEMI REQUIREMENT 4.
EFFLUENT GROSS VALUE AN SAMPLE MEASUREMENT PERMIT REQUIREMENT SAMPLE MEASUREMENT
- PERMIT, REQUIREMENT SAMPLE MEASUREMENT PERMIT REQUIREMENT SAMPLE MEASUREMENT PERMIT REQUIREMENT SAMPLE MEASUREMENT PERMIT REQUIREMENT NAME/TITLE PRINCIPAL EXECUTIVE OFFICER I Certify under penalty of law that this document and all attachments were prepared under my TELEPHONE DATE direction or supervision in accordance with a system designed to assure that qualitied personnel Timothy P. Cleary properly gather and evaluate the information submitted, Based on my inquiry ot the person or persons who manage the system, or those persons directly responsible tor gathering the Chem./Env. Support Manager 423 843-7332 08 02 13 intormation, the intormation submitted is, to the beat of my knowledge and belief, true, Site Vice President accurate, and complete. I am aware that there are significant penalties for submitting false SIGNATURE OF PRINCIPAL EXECUTIVE information, including the possibility of fine and imprisonment for knowing violations.
OFFICER OR AUTHORIZED AGENT AREA NUMBER YEAR MO DAY TYPED OR PRINTED CODE COMMENTS AND EXPLANATION OF ANY VIOLATIONS (Reference all attachments here)
No Discharge this Period EPA Form 3320-1 (REV 3199)
Previous editions may be used Page 1 of 1
PERMITTEE NAME/ADDRESS (Include FacilityName/Location ifDifferent)
NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPDES)
MAJOR Form Approved.
Name TVA-SEQUOYAH NUCLEAR PLANT -
DISCHARGE MONITORING REPORT (DMR)
(SUBR 01) 0MB No. 2040-0004 Address P.O. BOX 2000 (INTEROFFICESB-LA....450 116 G F -FINAL SODDY - DAISY =TN 37384 JPERMITNUMBER I DISCHARGE NUMBE BACKWASH Facility TVA-SEOUOYAH NUCLEAR PLANT Location HAMILTON COUNTY---
MON1TQITORIG-.PERIOD EFFLUENT YEAR MO DAY YEARL MO itDAY NODISCHARGE ATTN: Diedre B. Nida From[ 08 01 01 To 08 01 31 NOTE: Read instructions before completing this form.
PARAMETER QUANTITY OR LOADING QUALITY OR CONCENTRATION NO.
FREQUENCY SAMPLE
_______EX OF TYPE AVERAGE MAXIMUM UNITS MINIMUM AVERAGE MAXIMUM UNITS ANALYSIS DEBRIS, FLOATING (SEVERITY)
SAMPLE 9A 0
1/31 VISUAL MEASUREMENT 01345 1
0 0
PERMIT REPORT PASSO SEE VISUAL
~REPORT Pns~
EFFLUENT GROSS VALUE R
TEQIREMN MO TOTAL FAIL=1 PERMIT OIL AND GREASE VISUAL SAMPLE 0
0 1 I 31 VISUAL MEASUREMENT 84066 1
0 0
PERMIT REPO T
YES=1 SEE VISUA EFFLUENT GROSS VALUE REQUIREMENT MOTOTAL N0 SAMPLE MEASUREMENT PERMIT REQUIREMENT SAMPLE MEASUREMENT PERMIT REQUIREMENT SAMPLE MEASUREMENT
-PERMIT REQUIREMENT SAMPLE MEASUREMENT PERMIT REQUIREMENT SAMPLE MEASUREMENT PERMIT REQUIREMENT NAMErTITLE PRINCIPAL EXECUTIVE OFFICER II Certify under penalty of law that this document and all attachments were prepared under my
/
____________TELEPHONE DATE direction or supervision in accordance with a system designed to assure that qualified personnel Timothy P. Cleary properly gather and evaluate the information submitted. Based on my inquiry of the person or personswho manage the system, or those persons directly responsible for gathering the Chem./Env. Support Manager information, the information submitted is, to the beat of my knowledge and belief, true,
_423 843-7332
_08
__02 13 accurate, and complete. I am aware that there are significant penalties for submitting false SIGNATURE OF PRINCIPAL EXECUTIVE information, including the possibility of tine and imprisonment for knowing violations.
OFFICER OR AUTHORIZED AGENT AREA YEAR MO DAY TYPED OR PRINTED CODE COMMENTS AND EXPLANATION OF ANY VIOLATIONS (Reference all attachments here)
Operations performs visual inspections for floating debris and oil and grease during all backwashes.
EPA Form 3320-1 (REV 3199)
Previous editions may be used Page 1 of 1
PERMITTEE NAME/ADDRESS (IncludeFacilityName/Location ifDifferent)
NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPDES)
MAJOR Form Approved.
Name TVA - SEQUOYAH NUCLEAR PLANT DISCHARGE MONITORING REPORT (DMR)
(SUBR 01) 0MB No. 2040-0004 Address P.O. BOX 2000 JiN~N~ O TE g
B-LA)-
TN0026450 117 G F-FINAL SODDY -DAISY TN 37384 PERMIT NUMBER DISCHARGE NUMBER BACKWASH Facility TVA -SEQUOYAH NUCLEAR PLANT Location HAMILTON COUNTY MONIT RIN PER D
EFFLUENT IYEAR I MO I DAY i IYEAR MO DAY NODISCHARGE 77 ATTN: Diedre B. Nida From 08R 01 0
To 08 01 31 NOTE: Read instructions before completing this form.
PARAMETER QUANTITY OR LOADING QUALITY OR CONCENTRATION NO.
FREQUENCY SAMPLE EX OF TYPE AVERAGE MAXIMUM UNITS MINIMUM AVERAGE MAXIMUM UNITS DEBRIS, FLOATING (SEVERITY)
SAMPLE 0
9A 0
1/31 VISUAL MEASUREMENT 01345 1
0 0
PERMIT REPORT PASS=O SEE VISUAL
- REQIUIREMENT FAIL=1
M EFFLUENT GROSS VALUE MO TOTAL I
OIL AND GREASE VISUAL SAMPLE 0
94 1 I 31 VISUAL MEASUREMENT 84066 1
0 0
PERMIT REPORT YES=1 SEE VISUAL EFFLUENT GROSS VALUE MO TOTAL NO=O PERMIT SAMPLE MEASUREMENT PERMIT REQUIREMENT SAMPLE MEASUREMENT PERMIT REQUIREMENT SAMPLE MEASUREMENT PERMIT REQUIREMENT SAMPLE MEASUREMENT PERMIT REQUIREMENT SAMPLE MEASUREMENT PERMIT REQUIREMENT NAME/TITLEPRINCIPAL EXECUTIVE OFFICER I Certity under penalty of law that this document and all attachments were prepared under my TELEPHONE DATE direction or supervision in accordance with a system designed to assure that qualified personnel TiL..(
-i" Timothy P. Cleary properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the Chem./Env. Support Manager 423 843-7332 08 02 13 Site Vice President information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false SIGNATURE OF PRINCIPAL EXECUTIVE information, including the possibility of fine and imprisonment for knowing violations.
OFFICER OR AUTHORIZED AGENT AREA NUMBER YEAR MO DAY TYPED OR PRINTED C
COMMENTS AND EXPLANATION OF ANY VIOLATIONS (Reference all attachments here)
Operations performs visual inspections for floating debris and oil and grease during all backwashes.
EPA Form 3320-1 (REV 3/99)
Previous editions may be used Page 1 of 1
PERMITTEE NAME/ADDRESS (Include FacilityVNarne/Location if Different)
NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPDES)
MAJOR Form Approved.
Name W
TA - SEQUOYAH NUCLEAR PLANT----
DISCHARGE MONITORING REPORT (DMR)
(SUBR 01) 0MB No. 2040-0004 Add ress P.O. BOX 2000
___TN0026450 118 G F-FINAL~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~
1 (INTEROFFICE SB-BA)..........TN065FIA SODDY - DAISY _TN 37384 PERMITNUMBER DISCHARGE NUMBER WASTE WATER & STORM WATER Facility TVA -SEOUOYAH NUCLEAR PLANT Location HAMILTO COUNTY DONITOING PERIQ EFFLUENT
____LARLMO~~~~~~~~~~~~LDAYJ YEAR~~~~-7 MO DY-*
NO DISCHARGE FXX ATTN: Diedre B. Nida From F 08 0
To F 08 ]JO-1 1 31
~ ~~~~~~~~~~~~~~~NOTE:
Read instructions before completing this form.
PARAMETER QUANTITY OR LOADING QUALITY OR CONCENTRATION1 NO.
FREQUENCY SAMPLE AVERAGE MAXIMUM UNITS MINIMUM AVERAGE MAXIMUM UNITS AAYI OXYGEN, DISSOLVED (DO)
SAMPLE
- E OFTP MEASUREMENT 19 00300 1
0 0
PERMIT 2.0 MG/L TWVICE/,
GRAB EFFLUENT GROSS VALUE REQUIREMENT IDAILY MN WEEK SOLIDS, TOTAL SUSPENDED SAMPLE
~*
MEASUREMENT 19 00530 1
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GRAB-EFFLUENT GROSS VALUE REQUIREMENT DAI XWE SOLIDS, SETTLEABLE SAMPLE**2 MEASUREMENT 2
00545 1
0 0
PERMIT 10MLIL ONCE/
GRAB EFFLUENT GROSS VALUE RQRENTDAILY MX MONTH
!FLOW, IN CONDUIT OR THRU SAMPLE
'TREATMENT PLANT MEASUREMENT 0
50050 1
0 0
PERMIT REPORT REPORT MGD*
ONCE/
ESTIMA EFFILIEN GRSS VLUEREQUIREMENT MO AVG DAILY MXBAC SAMPLE MEASUREMENT PERMIT REQUIREMENT SAMPLE MEASU REMENT PERMIT REQUIREMENT SAMPLE MEASUREMENT PERMIT REQUIREMENT NAME/TITLE PRINCIPAL EXECUTIVE OFFICER I Certify under penalty of law that this document and all attachments mere prepared under my 0
T TELEPHONE DATE direction or supervision in accordance with a system designed to assure that qualified personnel
/
/
I-Timothy P. Cleary properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible tor gathering the Chem./Env. Support Manager1 2
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2 1
Site Vice President
~information, the information submitted is, to the best of my knowledge and beliet, true,42 83732 0
02 1
Site Vice Presidentaccurate, and complete. I am aware that there are significant penalties for submitting false SIGNATURE OF PRINCIPAL EXECUTIVEI information, including the possibility ot tine and imprisonment for knowing violations.
OFFICER OR AUTHORIZED AGENT AREA NUMBER YEAR MO DAY TYPED OR PRINTED COD COMMENTS AND EXPLANATION OF ANY VIOLATIONS (Reference all attachments here)
During this reporting period, there has been no flow from the Dredge' Pond other than that resulting from rainfall.
EPA Form 3320-1 (REV 3/99)
Previous editions may be used Page 1 of 1
S58 080313 800 - NPDES CORRESPONDENCE March 13, 2008 State of Tennessee Department of Environment and Conservation Division of Water Pollution Control Enforcement & Compliance Section 6 th Floor, L & C Annex 401 Church Street Nashville, Tennessee 37243-1534
Dear Mr. Patrick Cromer:
SEQUOYAH NUCLEAR PLANT - DISCHARGE MONITORING REPORT FOR FEBRUARY 2008 Enclosed is the February 2008 Discharge Monitoring Report for Sequoyah Nuclear Plant.
Please contact me at (423) 843-7332 if you have any questions or comments.
Sincerely, Diedre B. Nida Chemistry/Environmental Support Manager Signatory Authority for Timothy P. Cleary Site Vice President Sequoyah Nuclear Plant AH Enclosure cc (Enclosure):
Chattanooga Environmental Assistance Center Division of Water Pollution Control State Office Building, Suite 550 540 McCallie Avenue Chattanooga, Tennessee 37402-2013 U.S. Nuclear Regulatory Commission ATTN: Document Control Desk Washington, D.C. 20555 cc:
D. J. Bodine, POB 2A-SQN A. A. Ray, WT 7C-K C. R. Church, POB 2B-SQN J. D. Smith, OPS 4A-SQN T. P. Cleary, OPS 4A-SQN G. R. Signer, WT 6A-K D. E. Pittman, BR 4T-C EDMS, WT CA-K (Enclosure)
DMR0802.doc
Tennessee Valley Authority, Post Office Box 2000, Soddy-Daisy, Tennessee 37384-2000 March 13, 2008 State of Tennessee Department of Environment and Conservation Division of Water Pollution Control Enforcement & Compliance Section 6"' Floor, L & C Annex 401 Church Street Nashville, Tennessee 37243-1534
Dear Mr. Patrick Cromer:
SEQUOYAH NUCLEAR PLANT - DISCHARGE MONITORING REPORT FOR FEBRUARY 2008 Enclosed is the February 2008 Discharge Monitoring Report for Sequoyah Nuclear Plant. Please contact me at (423) 843-7332 if you have any questions or comments.
Sincerely, Diedre B. Nida Chemistry/Environmental Support Manager Signatory Authority for Timothy P. Cleary Site Vice President Sequoyah Nuclear Plant Enclosure cc (Enclosure):
Chattanooga Environmental Assistance Center Division of Water Pollution Control State Office Building, Suite 550 540 McCallie Avenue Chattanooga, Tennessee 37402-2013 U.S. Nuclear Regulatory Commission ATTN: Document Control Desk Washington, D.C. 20555 Pr, r'Ld dpa"
PERMITTEE NAME/ADDRESS (Include Facility Name/Location if Different)
NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPDES)
MAJOR Form Approved.
Name TVA - SEQUOYAH NUCLEAR PLANT----
DISCHARGE MONITORING REPORT (DMR)
(SUBR 01) 0MB No. 2040-0004 Address P.O. BOX 2000-
_ _NTj0~qE B2)TN0026450 101 G F -FINAL SODDY - DAISY TN
_L37384 PERMIT NUMBER
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DISCHARGE INUME R DIFFUSER DISCHARGE Facility TVA -SEQUOYAH NUCLEAR PLANTT Location
-HAMILTON COUNTY MONITORING PERIQD EFFLUENT ATTN: Diedre B. Nida' From 08 02 0
To 108 02 29 N
ICAG NOTE. Read instructions before completing this form.
PARAMETER QUANTITY OR LOADING QUALITY OR CONCENTRATION No.
FREQUENCY SAMPLE
~~~
~~~
~~~~~~~~~~
OF TYPE F
~
~~~~~~~~~~AVERAGE MAXIMUM UNITS MINIMUM AVERAGE MAXIMUM UNITS AAYI TEMPERATURE, WATER DEG.
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QS NAME/TITLE PRINCIPAL EXECUTIVE OFFICER I Certify under penally of law that this document and all attachment s were prepared under my (7,QTELEPHONE 1
DATE
____ ~~~~~~~~~~~~direction or supervision in accordance with a system designed to assure that qualified personnel
)..,;~r Timothy P. Cleary properly gather and evaluate the information submitted. Based on my inquiry of the person or A4~-'L' I persons who manage the system, or those persons directly responsible for gathering the Chem./Env. Support Manager 423 843-7332 08 03 12 information, the information submitted is, to the best of my knowledge and belief, true, Site Vice Presidentaccurate, and complete. I am aware that there are significant penalties for submitting false SIGNATURE OF PRINCIPAL EXECUTIVE information, including the possibility of tine and imprisonment for knowing violations.
OFFICER OR AUTHORIZED AGENT AREA NUMBER YEAR MO DAY TYPED OR PRINTED
_________________CODE COMMENTS AND EXPLANATION OF ANY VIOLATIONS (Reference all attachments here)
No closed mode operation. The following information is included in anattachment: 1. CCW data 2. Veliger monitoring data EPA Form 3320-1 (REV 31991 Previous editions may be used Page 1 of 2
DMR Attachment CCW Data CCW TRENCH Extractable Petroleum Date/Time Collected Hydrocarbons Analysis Date/Time Analyst Method 02/13/2008 @ 1040 0.41 mg/I 02/15/2008 @ 1027 RDH TN EPA 8015 CCW CHANNEL Extractable Petroleum Date/Time Collected Hydrocarbons Analysis Date/Time Analyst Method 02/13/2008 @1030
<0.13 mg/I 02/15/2008 @1039 RDH TN EPA 8015
SQN ZM Graph Sequoyah Nuclear Zebra Mussel Graph 350 30 ~~~~~~~~~~~~~~~~~~MMean#
of ZM/m3 28
% Settlers 300 26 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~..W Temp. (0C) 24 250~~~~~~~~~~~~~~~~~~~~~~~2 0~~~~~~~~~~~~~~~~~~~~~~~~~2 U)0
()
18 200 -
16~
N
~~~~~~~~~~~~~~~~~~~~~~~~~14~
'~150 E
~~~~~~~~~~~~~~~~~~~~~~~~~10 z
100 8
6 504 2
Sample Date Page 1
SON Clam Graph Sequoyah Nuclear Asiatic Clam Graph 500 30 Mean# of Asiatic Clamsfm3 450 Water Temp. (C) 25 400 ME 350 2
E cu 300 o
~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~Cu Cu 250 -15 E
Ci 0
200 --
100 5
50-J~i llp u
I I
I III I
I0 0
Sample Date Page 1
Mean# of NTS Mean # of Water Temp.
M Water Temp.
SUBLCTOEr A
Sample Date 3
% Settlers Sample Date Asiatic LOCATION Gravid Asiatic COLLECTED BY ZM/m C)
ClanS/M 3
f C)
LOCATION Clam 11/16/2007 0
0 15 11/16/2007 44 15 Inplant RCW Dickie Adcock 11/18/2007 0
0 15 11/18/2007 60 15 Inplant ROW Dickie Adcock 11/19/2007 0
0 14 11/19/2007 29 15 Inplant RCW Dickie Adcock 11/20/2007 15 0
15 11/20/2007 45 15 Inplant ROW Dickie Adcock 11/27/2007 0
0 14 11/27/2007 15 14 Inplant ROW Dickie Adcock 12/6/2007 0
0 12 12/06/2007 14 12 Inplant ROW Dickie Adcock 12/10/2007 0
0 12 12/06/2007 0
12 Inplant ROW Dickie Adcock 12/21/2007 0
0 10 12/21/2007 0
10 Inplant ROW Dickie Adcock 12/28/2007 0
0 9
12/28/2007 0
9 Inplant ROW Dickie AdCock 01/03/2008 0
0 8
01/03/2008 0
8 Inplant ROW Dickie AdCock 01/11/2008 0
0 9
01/11/2008 0
9 Inplant ROW Dickie Adcock 01/18/2008 0
0 8
01/18/2008 0
8 Inplant ROW Dickie Adcock 01/25/2008 0
0 6
01/25/2008 0
6 Inplant ROW DiCkie Adcock 02/01/2008 0
0 7
02/01/2008 0
7 Inplant ROW Dickie AdCock 02/08/2008 0
0 9
02/08/2008 0
9 Inplant ROW Dickie Adcock 02/15/2008 0
0 8
02/15/2008 0
8 Inplant ROW Dickie Adcock 02/22/2008 0
0 8
02/22/2008 0
8 Inplant ROW DiCkie Adcock 02/29/2008 0
0 8
02/29/2008 0
8 Inplant ROW DiCkie Adcock 03/07/2008 0
0 10 03/07/2008 0
10 Inplant ROW Dickie AdCock
PERMITTEE NAME/ADDRESS (IncludeFacilityName/Location ifDifferent)NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPDES)
MAJOR Form Approved.
NERmeTTEA EQUOA NUCLEA PIcldeacLAtyNamel~ctiDISCHARGE MONITORING REPORT (DMR)
BMB No. 2040-0004 Nae TVA - SEQUOYAH NUCLEAR PLANT -
(SUBR 01)
Address P.O. BOX 2000F-FIA Address PO BOXMOO___________
ITN0026450 101 G F-FINAL
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SODDY - DAISY TN 37384 PERMIT NUMBER DISCHARGE NUMBER DIFFUSER DISCHARGE Facilitvy TVA -SEQUOYAH NUC LEAR PLANT
____________________EFFLUENT Location HAMILTON COUNTY IOIT N
ERO YEAR MO DAY YEAR i MO I DAY NO DISCHARGE ATTN: Diede B. NidaFrom 08 02 01 Tol 08 02 29 ATTN: Diedre B. Nida From 08 02 1 01 To F08 1 02 1 29 NOTE: Read instructions before completing this form.
PARAMETER
~~~~~~~~~~~~~~QUANTITY OR LOADING1 QUALITY OR CONCENTRATION NO.
FREQUENCY SAMPLE EX OF TYPE
________________ANTITY OR LOADING QUALITY OR CONCENTRATION NO, ANALYSIS AVERAGE MAXIMUM UNITS MINIMUM AVERAGE MAXIMUM UNITS CHLORINE, TOTAL RESIDUAL SAMPLE NT 0.013 0.019 19 0
18/29 GRAB MEAS UREMENT 50060 1
0 0
PERMIT 0.10 0.10 MGIL WEEK-CALCTD EFFLUENT GROSS VALUE REQUIREMENT MO AVG INST MAX DAYS TEMPERATURE - C, RATE OF SAMPLE 00 29/29 CALCTD CHANGERATURE -C, RATE OF MEASUREMENT 62 82234 1
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DEG CONTIN CALCTD EFFLUENT GROSS VALUE REQUIR NIE RnnME CUHROUS MEASUREMENT PERMIT REQUIREMENT SAMPLE MEASUREMENT PERMIT
.REQUIREMENT SAMPLE MEASUREMENT PERMIT REQUIREMENT SAMPLE MEASUREMENT PERMIT REQUIREMENT SAMPLE MEASUREMENT RE QUIREM ENT 1__
-AME!TI~TLE PRINCIPAL EXECUTIVE OFFICER I Certify under penalty of law that this document and all attachments were prepared under myDATE
__NAMVTI__direction or supervision in accordance with a system designed to assure that qualitied personnel \\'
Timothy P. Cleary properly gather and evaluate the information submitted.
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/Mhem.Env Support Manager 423 843-7332 08 03 12 information, the information submitted is, to the best of my knowledge and belief,
- true, Site Vice President
- accurate, and complete. I am aware that there are significant penalties for submitting false SIGNATURE OF PRINCIPAL EXECUTIVE information, including the possibility of fine and imprisonment for knowing violations.
OFFICER OR AUTHORIZED AGENT AREA NUMBER YEAR MO DAY TYPED OR PRINTED CODE COMMENTS AND EXPLANATION OF ANY VIOLATIONS (Reference all attachments here)
The following injections occured: 1. Biodetergent 73551 (max. calc. conc. was 0.017mg/L--Iimit 2.Omg/L)
EPA Form 3320-1 (REV 3199)
Previous editions may be used Page 2 of 2
PERMITTEE NAME/ADDRESS (Include FacilityName/Location ifDifferent)
NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPDES)
MAJOR Form Approved.
Name TVA - SEQUOYAH NUCLEAR PLANT DISCHARGE MONITORING REPORT (DMR)
(SUBR 01) 0MB No. 2040-0004 Address P.O._BOX 2000
___NE~~E2~
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F-FINAL (INTEROFFICE SB-LA)0265 1FIA SODDY -DAISY TN 37384 PERMIT NUMBER DISCHARGE NUMBER BIOMONITORING FOR OUTFALL 101 Facilitv TVA - SEQUOYAH NUCLEAR PLANT Location HAMILTON COUNTY MONITO ING PERI D
EFFLUENT YEAR MO DAY YEAR MO IDAY
- NODISCHARGE ATTN: Diedre B. Nida From 08 02 01 To 08 02 29 NOTE: Read instructions before completing this form.
PARAMETER QUANTITY OR LOADING 1
QUALITY OR CONCENTRATION NO.
FREQUENCY SAMPLE EX OF TYPE AVERAGE MAXIMUM UNITS MINIMUM AVERAGE MAXIMUM UNITS ANALYSIS 1C25 STATRE 7DAY CHR SAMPLE monitoring 23 CERIODAPHNIA MEASUREMENT Not Required TRP3B 1
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_____direction or supervision in accordance with a system designed to assure that qualified personnel
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OFFICER OR AUTHORIZED AGENT AREA NUMBER YEAR MO
)DAY TYPED OR PRINTED CODE COMMENTS AND EXPLANATION OF ANY VIOLATIONS (Reference all attachments here)
Toxicity was not sampled in February 2008.
EPA Form 3320-1 (REV 3199)
Previous editions may be used Page 1 of 1
PERMITTEE NAME/ADDRESS (Include Facility Name/Location if Different)
NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPDES)
MAJOR Form Approved.
Name TVA - SEQUOYAH NUCLEAR PLANT DISCHARGE MONITORING REPORT (DMR)
(SUBR 01) 0MB No. 2040-0004 Address P.O. BOX 2000 (INTEROFFICE SIB_---_-_--
-TN0026450 103 G F-FINAL SODDY -DAISY TN 37384 PERMIT NUMBER DISCHARGE NUMBER LOW VOL. WASTE TREATMENT POND Facility TVA -SEOUOYAH NUCLEAR PLANT EFFLUENT Location HAMILTON COUNTY-MONITORINGERIOD EFFLUENT YEAR:[D A
Y YEAR MO DAY NO DISCHARGE LI ATTN: Diedre B. Nida From 08 J2 J
To 08 02 29 ATTN: Diedre B. Nida From 08 To mNOTE: Read instructions before completing this form.
PARAMETER 1
QUANTITY OR LOADING QUALITY OR CONCENTRATION NO.
FREQUENCY SAMPLE EX OF TYPE ANALYSIS AVERAGE MAXIMUM UNITS MINIMUM AVERAGE MAXIMUM UNITS PH SAMPLE 7.9 8.7 12 0
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4/29 GRAB MEASUREMENT 00530 1
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PERMIT 380 1250 LBS/DY 30 100 MGIL WEEKLY GRAB JEFFLUENT GROSS VALUE PAMOAX MO AVG DAILY MX OIL AND GREASE SAMPLE
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4/29 GRAB MEASUREMENT 2
00556 1
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PERMIT 190 250 LBS/DY 15 20 MOIL WEEKLY GRAB REQUIREMENT 192 50
'EFFLUENT GROSS VALUE MO AVG DAILY MX MO AVG DAILY MX iFLOW, IN CONDUIT OR THRU SAMPLE 1.044 1.381 03 0
29 /29 TOTALZ TREATMENT PLANT MEASUREMENT 50050 1
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PERMIT REPORT REPORT MGD SEE
, TOTALZ REQUIREMENT EFFLUENT GROSS VALUE R
E MO AVG DAILY MX PERMIT SAMPLE MEASUREMENT PERMIT777 REQUIREMENT SAMPLE IMEASUREMENT PERMIT REQUIREMENT SAMPLE MEASUREMENT PERMIT REQUIREMENT NAME/TITLE PRINCIPAL EXECUTIVE OFFICER I Certify under penalty of law that this document and all attachments mere prepared under my TELEPHONE DATE direction or supervision in accordance with a system designed to assure that qualified personnel Timothy P. Cleary properly gather and evaluate the information submitted. Based on my inquiry of the person or
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persons who manage the system, or those persona directly responsible for gathering the CCiem./Env. Support Manager information, the intormation submitted is, to the best of my knowledge and belief, true, 423 843-7332 08 03 12 Site Vice President accurate, and complete. I am aware that there are significant penalties for submitting false SIGNATURE OF PRINCIPAL EXECUTIVE iormation, including the possibility of fine and imprisonment for knowing violations.
OFFICER OR AUTHORIZED AGENT AREA i NUMBER YEAR MO DAY TYPED OR PRINTED I
CODE COMMENTS AND EXPLANATION OF ANY VIOLATIONS (Reference all attachments here)
EPA Form 3320-1 (REV 3199)
Previous editions may be used Page 1 of 1
PERMITTEE NAME/ADDRESS (Include Facility Name/Location if Different)
NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPDES)
MAJOR Form Approved.
Name TVA - SEQUOYAH NUCLEAR PLANT DISCHARGE MONITORING REPORT (DMR)(SB 010M No24-04 Address P.O. BOX 2000
___TN002(L6L4-
.A50 10 G F -FINAL (ITEO FF
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NOTE: Read instructions before completing this form.
PARAMETER
~~~~~~~~~~~~QUANTITY OR LOADING QUALITY OR CONCENTRATION NO.
FREQUENCY SAMPLE EX OF TYPE AVERAGE MAXIMUM UNITS MINIMUM AVERAGE MAXIMUM UNITS AAYI PH SAMPLE
- 1 MEASUREMENT 1
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PERMIT 6090Su DIY GA EFFLUENT GROSS VALUE MIMUMAMM SOLIDS, TOTAL SUSPENDED SAMPLE MEASUREMENT 19 00530 1
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~~~~~~~~~~direction or supervision in accordance with a system designed to assure that qualified personnel Timothy P. Cleary properly gather and evaluate the information submitted, eased on my inquiry of the person orf
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____________________________________information, including the possibility of fine and imprisonment for knowing violations.
OFFICER OR AUTHORIZED AGENT AREA NUMBER YEAR MO DAY TYPED OR PRINTED CODE COMMENTS AND EXPLANATION OF ANY VIOLATIONS (Reference all attachments here)
No Discharge this Period EPA Form 3320-1 (REV 3/99)
Previous editions may be used Page 1 of 1
PERMITTEE NAMEIADDRESS (Include Facility Name/Location if Different)
NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPDES)
MAJOR Form Approved.
Name TVA - SEQUOYAH NUCLEAR PLANT DISCHARGE MONITORING REPORT (L)MR)
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~ ~~~~~~~~~~~~~~~~~~~~~~~~~NOTE.
Read instructions before completing this form.
PARAMETER QUANTITY OR LOADING QUALITY OR CONCENTRATION NO.
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NAME/TTLE PRINCIPAL EXECUTIVE OFFICER I Certify under penally of law that this document and all attachments were prepared under m TELEPHONE DATE
- -direction or supervision in accordance with a system designed to assure that qualified persone 7, /
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__________________________423_843_7332____12 Site VicePresidentaccurate, and complete. I am aware that there are significant penalties for submitting false SGAUEO RNIA XCTV information, including the possibility of fine and imprisonment for knowing violations.
OFFICER OR AUTHORIZED AGENT AREA NUMBER YEAR MO DAY TYPED OR PRINTED CODE COMMENTS AND EXPLANATION OF ANY VIOLATIONS (Reference all attachments here)
No Discharge this Period EPA Form 3320-1 (REV 3199)
Previous editions may be used Page 1 of 1
PERMITTEE NAME/ADDRESS (Include FacilityvName/Location if Different)
NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPDES)
MAJOR Form Approved.
Name TVA - SEQUOYAH NUCLEAR PLANT-DISCHARGE MONITORING REPORT (DMR)
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OFFICER OR AUTHORIZED AGENT AREAI NUMBER YEARI MO DAY TYPED OR PRINTED IIICODE COMMENTS AND EXPLANATION OF ANY VIOLATIONS (Reference all attachments here)
No Discharge this Period EPA Form 3320-1 (REV 3199)
Previous editions may be used Page 1 of 1
PERMITTEE NAME/ADDRESS (Include Facilitv Name/Location if Different)
NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPDES)
MAJOR Form Approved.
Name TVA - SEQUOYAH NUCLEAR PLANT DISCHARGE MONITORING REPORT (DMR)
(SUBR 01) 0MB No. 2040-0004 Address P.O. BOX 2000 llLEOMCE SD-LA)..........TN0026450 116 G F -FINAL SODDY - DAISY _TN 37384 PERMIT NUMBER DISCHARGE NUMBER BACKWASH Facilitv TVA - SEOUOYAH NUCLEAR PLANT Location HA~MILTON COUNTY MONITORING PERIO EFFLUENT YEAR MOI DAY YEAR MO DAY i"
NO DISCHARGE ATTN:
Diedre B. Nida From To 08 02 29
~ ~~~~~~~~~~~~~~~~~~~~~~~NOTE:
Read instructions before completing this form.
PARAMETERf QUANTITY OR LOADING QUALITY OR CONCENTRATION NO.
FREQUENCY SAMPLE
-~~~~~~~~~
-~~~~~~~~EX OF TYPE AVERAGE AIU UNITS I
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~~~~~~~~direction or supervision in accordance with a system designed to assure that qualified personnel Timothy P. Cleary properly gather and evaluate the information submitted. Based on my inquiry of the person or Cr~
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OFFICER OR AUTHORIZED AGENT ARA NMER YEAR MO DAY TYPED OR PRINTED CD COMMENTS AND EXPLANATION OF ANY VIOLATIONS (Reference all attachments here)
Operations performs visual inspections for floating debris and oil and grease during all backwashes.
EPA Form 3320-1 (REV 3199)
Previous editions may bre used Page 1 of 1
PERMITTEE NAME/ADDRESS (Include Facility Name/Location if Different)
NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPDES)
MAJOR Form Approved.
Name TVA - SEQUOYAH NUCLEAR PLANT----
DISCHARGE MONITORING REPORT (DMR)
(SUBR 01) 0MB No. 2040-0004 Address P.O. BOX 2000 ITROFCBL~
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Location HAMILTON COUNTY M NTRGPERIOD EFFLUENT YEAR MO DAY
~
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PARAMETER QUANTITY OR LOADING QUALITY OR CONCENTRATION NO.
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-TELEPHONE DATE direction or supervision in accordance with a system designed to assure that qualified personnel k-Timothy P. Cleary properly gather and evaluate the information submitted. Based on my inquiry of the person or 2
persons who manage the system, or those persons directly responsible for gathering the hem./Env. Support Manager 423 843-7332 08 03 12 Site Vice President
~information, the information submitted is.10o the best of my knowledge and belief, true, Site Vice Presidentaccurate, and complete. I am aware that there are significant penalties for submitting false SIGNATURE OF PRINCIPAL EXECUTIVE information, including the possibility of fine and imprisonment for knowing violations.
OFFICER OR AUTHORIZED AGENT AREA NUMBER YEAR MO DAY TYPED OR PRINTED
____________________________L_________
________CODE COMMENTS AND EXPLANATION OF ANY VIOLATIONS (Reference all attachments here)
Operations performs visual inspections for floating debris and oil and grease during all backwashes.
EPA Form 3320-1 (REV 3199)
Previous editions may be used Page 1 of 1
PERMITTEE NAIME/ADDRESS (Include FacilitV Name/Location if Different)
NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPDES)
MAJOR Form Approved.
Name TVA - SEQUOYAH NUCLEAR PLANT-DISCHARGE MONITORING REPORT (DMR)
(SUBR 01) 0MB No. 2040-0004 Address P.O. BOX 2000
_ITEROMCE SB-?ATN0026450 118 G F-FINAL SODDY - DAISY TN 37384 PERMIT NUMBER DISCHARGE NUMBER WASTEWATER & STORM WATER Facility TVA -SEQUOYAH NUCLEAR PLANT Location HAMILTON COUNTY MONITORING PERIOD EFFLUENT YEA MO DA
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~ ~~~~~~~~~~~NOTE.
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PARAMETER QUANTITY OR LOADING QUALITY OR CONCENTRATION No.
FREQUENCY SAMPLE I
~~~~EX OF TYPE AVERAGE MAXIMUM UNITS MINIMUM AVERAGE MAXIMUM UNITS ANALYSIS
~OXYGEN, DISSOLVED (DO)
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REQUIREMENT SAMPLE MEASUREMENT PERMIT REQUIREMENT SAMPLE MEASU REMENT PERMIT REQUIREMENT NAME/TITLE PRINCIPAL EXECUTIVE OFFICER I Certify under penalty of law that tnis document and all attachments were prepared under my
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accurate, and complete. I am aware that there are significant penalties for submitting false SIGNATURE OF PRINCIPAL EXECUTIVE information, including the possibility of fine and imprisonment for knowing violations.
OFFICER OR AUTHORIZED AGENT AREA NUMBER YEAR MO DAY TYPED OR PRINTED I.
CODE COMMENTS AND EXPLANATION OF ANY VIOLATIONS (Reference all attachments here)
During this reporting period, there has been no flow from the Dredge Pond other than that resulting from rainfall.
EPA Form 3320-i (REV 3/99)
Previous editions may be used Page 1 of 1
S58 080414 800 - NPDES CORRESPONDENCE April 14, 2008 State of Tennessee Department of Environment and Conservation Division of Water Pollution Control Enforcement & Compliance Section 6th Floor, L & C Annex 401 Church Street Nashville, Tennessee 37243-1534
Dear Mr. Patrick Cromer:
SEQUOYAH NUCLEAR PLANT - DISCHARGE MONITORING REPORT FOR MARCH 2008 Enclosed is the March 2008 Discharge Monitoring Report for Sequoyah Nuclear Plant.
Please contact me at (423) 843-7332 if you have any questions or comments.
Sincerely, Diedre B. Nida Chemistry/Environmental Support Manager Signatory Authority for Timothy P. Cleary Site Vice President Sequoyah Nuclear Plant AH Enclosure cc (Enclosure):
Chattanooga Environmental Assistance Center Division of Water Pollution Control State Office Building, Suite 550 540 McCallie Avenue Chattanooga, Tennessee 37402-2013 U.S. Nuclear Regulatory Commission ATTN: Document Control Desk Washington, D.C. 20555 cc:
D. J. Bodine, POB 2A-SQN A. A. Ray, WT 7C-K C. R. Church, POB 2B-SQN J. D. Smith, OPS 4A-SQN T. P. Cleary, OPS 4A-SQN G. R. Signer, WT 6A-K D. E. Pittman, BR 4T-C EDMS, WT CA-K (Enclosure)
DMR0803.doc
Tennessee Valley Authority, Post Off ce Box 2000, Soddy-Daisy, Tennessee 37384-2000 April 14, 2008 State of Tennessee Department of Environment and Conservation Division of Water Pollution Control Enforcement & Compliance Section 6th Floor, L & C Annex 401 Church Street Nashville, Tennessee 37243-1534
Dear Mr. Patrick Cromer:
SEQUOYAH NUCLEAR PLANT - DISCHARGE MONITORING REPORT FOR MARCH 2008 Enclosed is the March 2008 Discharge Monitoring Report for Sequoyah Nuclear Plant. Please contact me at (423) 843-7332 if you have any questions or comments.
Sincerely, Diedre B. Nida Chemistry/Environmental Support Manager Signatory Authority for Timothy P. Cleary Site Vice President Sequoyah Nuclear Plant Enclosure cc (Enclosure):
Chattanooga Environmental Assistance Center Division of Water Pollution Control State Office Building, Suite 550 540 McCallie Avenue Chattanooga, Tennessee 37402-2013 U.S. Nuclear Regulatory Commission ATTN: Document Control Desk Washington, D.C. 20555 Pr~ntec ad recydor papler
PERMITTEE NAME/ADDRESS (Include Facility Name/Location if Different)
NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPDES)
MAJOR Form Approved,.
Name TVA - SEQUOYAH NUCLEAR PLANT DISCHARGE MONITORING REPORT (DMR)
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PARAMETER QUANTITY OR LOADING QUALITY OR CONCENTRATION NO.
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NAME/TITLE PRINCIPAL EXECUTIVE OFFICER I Certify under penally of law that this document and all attachments were prepared underm TELEPHONE DATE direction or supervision in accordance with a system designed to assure that qualified personnmel/
Timoth P. Clary properly gather and evaluate the information submitted. Based on my inquiry of the person or
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OFFICER OR AUTHORIZED AGENT AREA NUMBER YEAR MO DAY TYPED OR PRINTED ICODE COMMENTS AND EXPLANATION OF ANY VIOLATIONS (Reference all attachments here)
No closed mode operation. The following information is included in an attachment: 1. CCW data 2. veliger monitoring data EPA Form 3320-1 (REV 3199)
Previous edifions may be used Page 1 of 2
DMR Attachment CCW Data CCW TRENCH Extractable Petroleum Date/Time Collected Hydrocarbons Analysis Date/Time Analyst Method 03/20/2008 @ 1056 0.24 mg/I 03/26/2008 @ 1113 RDH TN EPA 8015 CCW CHANNEL Extractable Petroleum Date/Time Collected Hydrocarbons Analysis Date/Time Analyst Method 03/20/2008 @ 1045
<0.10 mg/I 03/26/2008 @ 1124 RDH TN EPA 8015
Mean # of Water Temp.
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% Settlers
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0 1 5 11/18/2007 60 1 5 Inplant ROW Dickie Adcock 11/19/2007 0
0 14 11/19/2007 29 15 Inplant ROW Dickie Adcock 11/20/2007 1 5 0
1 5 11/20/2007 45 1 5 Inplant ROW Dickie Adcock 11/27/2007 0
0 14 11/27/2007 1 5 14 Inplant ROW Dickie Adcock 12/6/2007 0
0 12 12/06/2007 14 12 Inplant ROW Dickie Adcock 12/10/2007 0
0 1 2 12/06/2007 0
12 Inplant ROW Dickie Adcock 12/21/2007 0
0 1 0 12/21/2007 0
1 0 Inplant ROW Dickie Adcock 12/28/2007 0
0 9
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9 Inplant ROW Dickie Adcock 01/03/2008 0
0 8
01/03/2008 0
8 Inplant ROW Dickie Adcock 01/11/2008 0
0 9
01/11/2008 0
9 Inplant ROW Dickie Adcock 01/18/2008 0
0 8
01/18/2008 0
8 Inplant ROW Dickie Adcock 01 /25/2008 0
0 6
01/25/2008 0
6 Inplant ROW Dickie Adcock 02/01/2008 0
0 7
02/01/2008 0
7 Inplant ROW Dickie Adcock 02/08/2008 0
0 9
02/08/2008 0
9 Inplant ROW Dickie Adcock 02/1 5/2008 0
0 8
02/1 5/2008 0
8 In plant ROW Dickie Adcock 02/22/2008 00 8
02/22/2008 0
8 In plant ROW Dickie Adcock 02/29/200 8 0
0 8
02/29/12008 0
8 In plant ROW Dickie Adcock 03/07/2008 0
0 1 0 03/07/2008 0
1 0 Inplant ROW Dickie Adcock 03/14/2008 0
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1 0 Inplant ROW Dickie Adcock 03/21/2008 30 0
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1 2 03/28/2008 75 1 2 Inplant ROW
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13 04/04/2008 119 1 3 Inplant ROW
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PERMITTEE NAME/ADDRESS (Include FacilityvName/Location if Different)
NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPDES)
MAJOR Form Approved.
Name TVA - SEQUOYAH NUCLEAR PLANT DISCHARGE MONITORING REPORT (DMR?)
(SUBR 01) 0MB No. 2040-0004
-Address P.O. BOX 2000-------------T 0240)F-FIA
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- NO DISCHARGE ATTN: Diedre B. Nida From 08 Tol 08 1 03 1:3~~~~~~~~~~~~~~~~~~~~1 NOTE: Read instructions before completing this form.
PARAMETER QUANTITY OR LOADING QUALITY OR CONCENTRATION NO.
FREQUENCY SAMPLE EX OF TYPE AVERAGE MAXIMUM UNITS MINIMUM AVERAGE MAXIMUM UNITS AAYI CHLO)RINE, TOTAL RESIDUAL SAMPLE 0.013 00219 0
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-iection or supervision in accordance with a system designed to assure that qualified personnel Timothy P. Cleary properly gather and evaluate the information submitted. Based on my inquiry of the person or L.
7 persons who manage the system, or those persons directly responsible for gathering the a
ChmEnv. Support Manager
.423 843-7332 08 04 1 1 Site Vice President
~information, the information submitted is, to the best of my knowledge and belief, true, Site Vice Presidentaccurate, and complete. I am aware that there are significant penalties for submitting false SIGNATURE OF PRINCIPAL EXECUTIVE
____________________________________information, including the possibility of fine and imprisonment for knowing violations.
OFCRRAUH IZDGETARA NME YAR O
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COMMENTS AND EXPLANATION OF ANY VIOLATIONS (Reference all attachments here)
The following injections occured: 1. Biodetergent 73551 (max. calc. conc. was 0.018mg/L--limit 2.OmgIL)
EPA Form 3320-1 (REV 3199)
Previous editions may be used Page 2 of 2
PERMITTEE NAME/ADDRESS (Include FacilityvName/Location if Different)
NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPDES)
MAJOR Form Approved.
Name TVA - SEQUOYAH NUCLEAR PLANT DISCHARGE MONITORING REPORT (DMR)
(SBO1 MB No. 2040-0004 Address P.O. BOX 2000------------N0265FIA ll~jTROFFILE
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PARAMETER QUANTITY OR LOADING QUALITY OR CONCENTRATION NO.
FREQUENCY SAMPLE Ex OF TYPE AVERAGE
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OFFICER OR AUTHORIZED AGENT AREA INUMBER YEAR M
A TYPED OR PRINTED CODE COMvMENTS AND EXPLANATION OF ANY VIOLA'TIONS (Reference all attachments here)
Boron was collected on 01/09/2008 @ 1128.
EPA Form 3320-1 (REV 3/99)
Previous editions may be used Page 1 of 1
PERMITTEE NAME/ADDRESS (Include Facility Name/Location if Different)
NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPDES)
MAJOR Form Approved.
Name TVA - SEQUOYAH NUCLEAR PLANT DISCHARGE MONITORING REPORT (DMR)
(SBO1 MB No. 2040-0004 Address P.O. BOX 2000 2-IA
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~ ~~~~~~~~~~~~~NOTE:
Read instructions before completinq this form.
PARAMETER QUANTITY OR LOADING QUALITY OR CONCENTRATION NO.
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OFFICER OR AUTHORIZED AGENT AREA NUMBER YEAR MO DAY TYPED OR PRINTED I
_I___
CODE COMMENTS AND EXPLANATION OF ANY VIOLATIONS (Reference all attachments here)
Toxicity was not sampled in March 2008.
EPA Form 3320-1 (REV 3/99)
Previous editions may be used Page 1 of 1
PERMITTEE NAME/ADDRESS (Include Facility Name/Location if Different)
NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPDES)
MAJOR Form Approved.
Name TVA -SEQUOYAH NUCLEAR PLANT ----
DISCHARGE MONITORING REPORT (DMR)
(SUBR 01)
OMB No. 2040-0004 Address P.O. BOX 2000------------TN06513F-FIA
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- NO DISCHARGE ATTN: Diedre B. Nidla From 08 3
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PARAMETER QUANTITY OR LOADING QUALITY OR CONCENTRATION NO.
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OFFICER OR AUTHORIZED AGENT AREA NUMBER YEAR MO DAY LTYPED OR PRINTED CODE COMMENTS AND EXPLANATION OF ANY VIOLATIONS (Reference a/Iattachments here)
EPA Form 3320-1 (REV 3/99)
Previous ed/ftions may be used Page 1 of 1
PERMITTEE NAME/ADDRESS (Include Facility Name/Location if Different)
NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPDES)
MAJOR Form Approved.
Name TVA -SEQUOYAH NUCLEAR PLANT-DISCHARGE MONITORING REPORT (DMR)
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OFFICER OR AUTHORIZED AGENT AREA NUMBER YEAR MO DAY TYPED OR PRINTED CODE COMMENTS AND EXPLANATION OF ANY VIOLATIONS (Reference all attachments here)
No Discharge this Period EPA Form 3320-1 (REV 3199)
Previous editions may be used Page 1 of 1
PEIRMITTEE NAME/ADDRESS (Include Facilitv Name/Location if Different)
NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPDES)
MAJOR Form Approved.
'Name TVA -SEQUOYAH NUCLEAR PLANT-DISCHARGE MONITORING REPORT (DMR)
(SUBR 01) 0MB No. 2040-0004 Address P.O. BOX 2000 I
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PARAMETER QUANTITY OR LOADING QUALITY OR CONCENTRATION NO.
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OFFICER OR AUTHORIZED AGENT AREA NUMBER YEAR MO DAY TYPED OR PRINTED
_____________________________CODE COMMENTS AND EXPLANATION OF ANY VIOLATIONS (Reference all attachments here)
No Discharge this Period EPA Form 3320-1 (REV 3199)
Previous editions may be used Page 1 of 1
PERMITTEE NAME/ADDRESS (Include FacilityvName/Location if Different)
NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NF'DES)
MAJOR Form Approved.
Name TVA - SEQUOYAH NUCLEAR PLANT DISCHARGE MONITORING REPORT (DMR)
(SBOl MB No. 2040-0004 Address P.O. BOX 2000
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PARAMETER QUANTITY OR LOADING QUALITY OR CONCENTRATION NO.
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OFFICER OR AUTHORIZED AGENT AREA NUMBER YEAR MO DAY TYPED OR PRINTED I_______________
CODE COMMENTS AND EXPLANATION OF ANY VIOLATIONS (Reference all attachments here)
No Discharge this Period EPA Form 3320-1 (REV 3199)
Previous editions may be used Page 1 of 1
PERMITTEE NAMEIADDRESS (Include Facility Name/Location if Different)
NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPDES)
MAJOR Form Approved.
Name TVA - SEQUOYAH NUCLEAR PLANT DISCHARGE MONITORING REPORT (DMR)
(SUBR 01) 0MB No. 2040-0004 Address P.O. BOX 2000 16L
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~ ~~~~~~~~~~~~~~~~~~~~~~NOTE:
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PARAMETER QUANTITY OR LOADING QUALITY OR CONCENTRATION NO.
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PARAMETER QUANTITY OR LOADING QUALITY OR CONCENTRATION NO.
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OR____PRINTED________information, including the possibility of fine and imprisonment for knowing violations.
OFFICER OR AUTHORIZED AGENT AE NUBR YEAR MO DAY COMMENTS AND EXPLANATION OF ANY VIOLATIONS (Reference all attachments here)
Operations performs visual inspections for floating debris and oil and grease during all backwashes.
EPA Form 3320-1 (REV 3/99)
Previous editions may be used Page 1 of 1
PERMITT-EE NAME/ADDRESS (Include FacilityvName/Location if Different)
NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPDES)
MAJOR Form Approved.
Name TVA - SEQUOYAH NUCLEAR PLANT----
DISCHARGE MONITORING REPORT (DMR)
(SUBR 01) 0MB No. 2040-0004 Address P.O. BOX 2000 N -
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PARAMETER QUANTITY OR LOADING QUALITY OR CONCENTRATION NO.
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Site Vice President
~~information, the information submitted is, to the best of my knowledge and belief, true, 423____843___7332_________04_______
Site Vice Presidentaccurate, and complete. I am aware that there are significant penalties for submitting false SIGNATURE OF PRINCIPAL EXECUTIVEI information, including the possibility of fine and imprisonment for knowing violations.
OFFICER OR AUTHORIZED AGENT AREA INUMBER YEAR MO DAY TYPED OR PRINTED
_____________________________coD COMMENTS AND EXPLANATION OF ANY VIOLATIONS (Reference all attachments here)
During this reporting period, there has been no flow from the Dredge Pond other than that resulting from rainfall.
EPA Form 3320-1 (REV 3199)
Prev/ous editions may be used Page 1 of 1
S58 080514 800 - NPDES CORRESPONDENCE May 14, 2008 State of Tennessee Department of Environment and Conservation Division of Water Pollution Control Enforcement & Compliance Section 6th Floor, L &CAnnex 401 Church Street Nashville, Tennessee 37243-1534
Dear Mr. Patrick Cromer:
SEQUOYAH NUCLEAR PLANT - DISCHARGE MONITORING REPORT FOR APRIL 2008 Enclosed is the April 2008 Discharge Monitoring Report for Seq uoyah Nuclear Plant.
Please contact me at (423) 843-7332 if you have any questions or comments.
Sincerely, Stephanie A. Howard Principal Environmental Engineer Signatory Authority for Timothy P. Cleary Site Vice President Sequoyah Nuclear Plant AH Enclosure cc (Enclosure):
Chattanooga Environmental Assistance Center Division of Water Pollution Control State Office Building, Suite 550 540 McCallie Avenue Chattanooga, Tennessee 37402-2013 U.S. Nuclear Regulatory Commission ATTN: Document Control Desk Washington, D.C. 20555 cc:
D. J. Bodine, POB 2A-SQN A. A. Ray, WT 7C-K C. R. Church, POB 2B-SQN J. D. Smith, OPS 4A-SQN T. P. Cleary, OPS 4A-SQN G. R. Signer, WT 6A-K D. E. Pittman, BR 4T-C EDMS, WT CA-K (Enclosure)
DMR0804.doc
Tennessee Valley Authority, Post Office Box 2000, Soddy-Daisy, Tennessee 37384-2000 May 14, 2008 State of Tennessee Department of Environment and Conservation Division of Water Pollution Control Enforcement & Compliance Section 6Th Floor, L &CAnnex 401 Church Street Nashville, Tennessee 37243-1534
Dear Mr. Patrick Cromer:
SEQUOYAH NUCLEAR PLANT - DISCHARGE MONITORING REPORT FOR APRIL 2008 Enclosed is the April 2008 Discharge Monitoring Report for Sequoyah Nuclear Plant. Please contact me at (423) 843-6700 if you have any questions or comments.
Sincerely, 2
Stephanie A. Howard Principal Environmental Engineer Signatory Authority for Timothy P. Cleary Site Vice President Sequoyah Nuclear Plant Enclosure cc (Enclosure):
Chattanooga Environmental Assistance Center Division of Water Pollution Control State Office Building, Suite 550 540 McCallie Avenue Chattanooga, Tennessee 37402-2013 U.S. Nuclear Regulatory Commission ATTN: Document Control Desk Washington, D.C. 20555
PERMITTEE NAME/ADDRESS (Include Facility Name/Location if Different)
NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPDES)
MAJOR Form Approved, Name TVA-SEQUOYAH NUCLEAR PLANT-DISCHARGE MONITORING REPORT (DMR)
(SUBIR 01) 0MB No. 2040-0004 Address P.O. BOX 2000 (INTEROFFICE SB-2A) -
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ATTN~~~~~
Stephanie A. Howard From Al I To
~~~~~~~~~~~~~~~~~~~~NOTE: Read instructions before comoletingj this form.
PARAMETER
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.00010 I
0 0
C~PKI.,
i
~OT<
DEG. C.
>EKE EFFLUENT GROSS VALUE EURMN-,
~TEMP. DIFF. BETWEEN SAMP. &
SAMPLE
- -2.7 04 0
30 /30 CALCTID UIPSTRM DEG.C MEASUREMENT 100016 1
5 0
,PMT
- i**--
- k******.
3 DEG.C.
EFFLUENT GROSS VALUE RQIEET 2 ~.--
~DIY X~
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- ~.
- 7.6
- 8.2 12 0
5/30 GRAB MEASUREMENT
'00400 1
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PErIY-
- ~60
~Su WEKY GA EFFLUENT GROSS VALUEREIEEN 7M IW MAX M
SOLIDS, TOTAL SUSPENDED
~~~SAMPLE 18 31 19 0
2 /30 GRAB MEASUREMENT 00530 1
0 0
- i**
'oeMGIL MNHLY GA EFFLUENT GROSS VALUE OIL AND GREASE SAMPLE
- ~*
- <5
<5 19 0
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100556 1
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~
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EFFLUENT GROSS VALUE ~
~
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~FLOW, IN CONDUIT OR THRU SAMPLE 0
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0 ROD 50050 1
0 0
-PRIE, A**
hEQT 4
G C~**~
OTN ROD EFFLUENT GROSS VALUEREURFN C'
NAME/TITLE PRINCIPAL EXECUTIVE OFFICER -I Certify under penally of law that this document and all attachments were prepared under my--
fi ITELEPHONE DATE direction or supervision in accordance with a system designed to assure that qualified personnl/TI~IjP.L&4'Le-c Timothy ~P.
Cleary properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the systemT or those persons directly responsible for gathering the Principal Environmental Engineer 423 843-6700 08 05 1
Site Vice President
~information, the information submitted is, to the best of my knowledge and belief, true, Site Vice Presidentaccurate, and complete. l am aware that there are significant penalties for submitting false SIGNATURE OF PRINCIPAL' EXECUTIVE
_______________________________________ -nformation, including the possibility of fine and imprisonment for knowing violations.
OFFICER OR AUTHORIZED AGENT AREA NUMBER YEAR MO DAY TYPED OR PRINTED CODE COMMENTS AND EXPLANATION OF ANY VIOLATIONS (Reference all attachments here)
No closed mode operation. The following information is included in anattachment: 1.CCOWdata 2. veliger monitoring data EPA Form 3320-1 (REV 3199)
Previous editions may be used Page 1 of 2
DMR Attachment CCW Data CCW TRENCH Extractable Petroleum Date/Time Collected Hydrocarbons Analysis Date/Time Analyst Method 04/09/2008 @ 1101 0.31 mg/I 04/12/2008 @ 0735 CLS TN EPA 8015 CCW CHANNEL Extractable Petroleum Date/Time Collected Hydrocarbons Analysis Date/Time Analyst Method 04/09/2008 @ 1210
<0.10 mg/I 04/12/2008 @ 0723 CLS TN EPA 8015
Mean# of NTS Sample Date Men f%
Settlers WtrTm.Sample Date Asiatic SU OE:Ma fWtrTm.Water Temp.
LOCATION SB Gra vid Asiatic COLLECTED BY ZM/M 3 fCc)
Clams/in 3 CC)
LOCATION clam 11/16/2007 0
0 1 5 11/16/2007 44 1 5 Inplant RCW Dickie Adcock 11/18/2007 0
0 1 5 11/18/2007 60 1 5 Inplant ROW Dickie Adcock 11/19/2007 0
0 14 11/19/2007 29 15 Inplant ROW Dickie Adcock 11/20/2007 1 5 0
1 5 11/20/2007 45 1 5 Inplant ROW Dickie Adcock 11/27/2007 0
0 14 11/27/2007 15 14 Inplant ROW Dickie Adcock 12/6/2007 0
0 12 12/06/2007 14 12 Inplant ROW Dickie Adcock 12/10/2007 0
0 12 12/06/2007 0
12 Inplant ROW Dickie Adcock 12/21/2007 0
0 1 0 12/21/2007 0
1 0 Inplant ROW Dickie Adcock 12/28/2007 0
0 9
12/28/2007 0
9 Inplant ROW Dickie Adcock 01/03/2008 0
0 8
01/03/2008 0
8 Inplant ROW Dickie Adcock 01/11/2008 0
0 9
01/11/2008 0
9 Inplant ROW Dickie Adcock 01/18/2008 0
0 8
01/18/2008 0
8 Inpiant ROW Dickie Adcock 01/25/2008 0
0 6
01/25/2008 0
6 Inplant ROW Dickie Adcock 02/01/2008 0
0 7
02/01/2008 0
7 Inplant ROW Dickie Adcock 02/08/2008 0
0 9
02/08/2008 0
9 Inplant ROW Dickie Adcock 02/1 5/200 8 0
0 8
02/1 5/2008 0
8 In plant ROW Dickie Adcock 02/22/2008 0
0 8
02/22/2008 0
8, Inplant ROW Dickie Adcock 02/29/2008 0
0 8
02/29/2008 0
8 Inplant ROW Dickie Adcock 03/07/2008 0
0 10 03/07/2008 0
1 0 Inplant ROW Dickie Adcock 03/14/2008 0
0 1 0 03/14/2008 0
1 0 Inplant ROW Dickie Adcock 03/21/2008 30 0
12 03/21/2008 0
12 Inplant ROW B. Love /Dick Adcock 03/28/2008 30 0
12 03/28/2008 75 1 2 Inplant ROW Dickie Adcock 04/04/2008 29 0
1 3 04/04/2008 119 1 3 Inplant ROW Dickie Adcock 04/11/2008 72 0
16 04/11/2008 302 16 Inplant ROW Dickie Adcock 04/18/2008 30 0
15 04/18/2008 104 1 5 Inplan't ROW Dickie Adcock 04/25/2008 29 0
1 5 04/25/2008 72 1 5 Inplant ROW Dickie Adcock 05/02/2008 14 0
1 7 05/02/2008 58 17 Inplant ROW Dickie Adcock
PERMITTEE NAMEIADDRESS (Include FacilityvName/Location if Different)
NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPDES)
MAJOR Form Approved.
Name TVA - SEQUOYAH NUCLEAR PLANT DISCHARGE MONITORING REPORT (DMR)
(SUBR 01) 0MB No. 2040-0004 Address P.O. BOX 2000
- ~
TOO65G (INTEROFFICE SB-LA) -__
-T-45-0 101 G F -FINAL SODDY -DAISY TN 37384 PEMTNUBRDISCAG UBR DIFFUSER DISCHARGE Facilitv TVA -SEQUOYAH NUCLEAR PLANT Location HAMILTON COUNTY MONITORING PERIQ EFFLUENT F
YEAR IMO IDAY YEA.MO DAYNO DISCHARGE E~:
ATTN: Stephanie A. Howard rom 1 08 1 04 1 01 J TOLNLNL~~~~~~~~~~~~~~o J NOTE: Read instructions before completing this form.
PARAMETERQUNIYOLODNQULTORCNETAINN.FEUNYSM E
CHLORINE, TOTAL RESIDUAL SAMPLE
.100319 2
30 GA 50060 1
0 0
/.
~MT, 1
4 GLWEK.CLT EFFLUENT GROSS VALUEREURMNT TEMPERATURE - C, RATE OF SAMPLE 062 0
30 /30 CALCTD CHANGE MEASUREMENT 82234 1
0 0
'~U~E DEG
~ ~
CONTIN CLT EFFLUENT GROSS VALUE DAL X
CIHR
~
os SAMPLE MEASUREMENT SAMPLE MEASUREMENT iRQIEMENT SAMPLE MEASUREMENT SAMPLE MEASUREMENT NAM~TITE PRNCIAL EECUIVE FFI ERICetif ne eat flwta hs ouetada-atcmnswrepeae ne yTLPOEDT drecRtionTo uevso nacrac ihasse eindt sueta ulfe esne NAME/ITLE RINCPAL EECUTVE OFICERinCermtify, underupenalhpsiblty of la fhttin ouen and allpattacmentsfo knwere preparedonder myIERO AUTHOIZEDAGEN TEEHNEDT The fllowng ijectons ocure:
1.Biodtrinfomtin the5 inomationlc submtte iastohebs of0 8mygknowledtOge an belef true 50M
_max___________
as______________________3_____5M_(lwdtectoneve analytical method was <0.020mg/L--Iimit 0.050mg/L)
E-PA Form 3320-1 (REV 3/99)
Previous editions may be used Page 2 of 2
PERMITTEE NAME/ADDRESS (include Facility Name/Location if Different)
NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPDES)
MAJOR Form Approved.
Name TVA -SEQUOYAH NUCLEAR PLANT-DISCHARGE MONITORING REPORT (DMR)
- 01) 0MB No. 2040-0004 Address P.O. BOXD 2000 T O24011T F-F
`ITEROFFICE SB-~.A -N-0-6 101 T F-FINAL SODDY -DAISY TN 37384 PERMIT NUMBER DISCHARGE NUMBER BIOMONITORING FOR OUTFALL 101 Facilitty TVA -SEQUOYAH NUCLEAR PLANT Location HAMILTON COUNTY M
NIT RING PERIOD EFFLUENT YEAR MO DAY YEAR IMO IDAY NO DISCHARGE I
ATT~~i Stephanie A. Howard From I 0-1]
Tol 08 1 04 1 30 1 ~~~~~~~~~~~~~NOTE:
Read instructions before completing this form.
PARAMETER QUANTITY OR LOADING QUALITY OR CONCENTRATION NO.
FREQUENCY SAMPLE EX OF TYPE AVERAGE MAXIMUM UNITS MINIMUM AVERAGE MAXIMUM UNITS ANALYSIS IC25 STATRE 7DAY CHR SAMPLE*
> 1 00. 0 23 0
1 /180 COMPOS CERIODAPHNIA MEASUREMENT TRP3B 1
0 0
EMT4Z*****
PERCENT SE CMQ EFFLUENT GROSS VALUEREIRET Y,__PMT____
IC25 STATIRE 7DAY CHR SAMPLE
>1 00.0 23 0
1 /180 COMPOS PIMEPHALES MEASUREMENT TRP6C 1
0 0
PEMT7 5Z.~
PRETSEE COPO EFFLUENT GROSS VALUERQURANTMMN M
PE IT_
SAMPLE MEASUREMENT REQIREENT
<min U
SAMPLE MEASUREMENT SAMPLE MEASUREMENT SAMPLE MEASUREMENT SAMPLE MEASUREMENT NAME/TITLE PRINCIPAL EXECUTIVE OFFICER I Certify under penalty of law that this document and all attachments were prepared under my
~
/
TELEPHONE DATE P. Cleary
~~~direction or supervision in accordance with a system designed to assure that qualified personnel Timothy PClayproperly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the.PicplEvrnetlnger 42 83-70 8
05 1
Site Vice President information, the information submitted is ' to the best of my knowledge and belief, true, PrincipalEnvironmentalEnineer_423_843_6700_______1 Site Vice Presidentaccurate, and complete. I am aware that there are significant penalties for submitting false SIGNATURE OF PRINCIPAL EXECUTIVEI information, including the possibility of fine and imprisonment for knowing violations.
OFFICER OR AUTHORIZED AGENT AREA NUMBER YEAR MO DAY TYPED OR PRINTED I_________________CODE COMMENTS AND EXPLANATION OF ANY VIOLATIONS (Reference all attachments here)
Toxicity was sampled April 13-18, 2008. Report is attached.
EPA Form 3320-1 (REV 3/99)
Previous editions may be used Page 1 of 1
May 12, 200 8 Ruth Ann Hurt, SB 2A-SQN SEQUOYAH NUCLEAR PLANT (SQN) TOXICITY BIOMONITORING, NPIDES PERMIT NO.
TN0026450, COMPLIANCE TOXICITY TESTS, APRIL, 2008 Attached are two copies of the subject report for submission to the state of Tennessee and a copy of the report for your records. The report provides results of compliance testing using fathead minnows and daphnids. Outfall 1 01, samples collected April 13 -
18, showed no toxic effects to fathead minnows or daphnids. The resulting IC25 values for both species were > 1 00 percent. Exposure of daphnids to intake samples resulted in no significant differences from controls during this study period, but fathead minnow survival was significantly reduced when exposed to intake samples.
Fathead minnows were also exposed to UV treated Outfall 10 1 and intake samples since fish pathogens present in intake water have been the suspected cause of interference (anomalous dose response and high variability among replicates) in previous toxicity testing at Sequoyah. Although dose response and survival in these tests we-re not affected enough to jeopardize test acceptability or compliance with permit limits, fish survival was improved by UV treatment of intake and effluent samples prior to exposures. These results suggest that fish pathogen interference was a likely cause of mortality observed in untreated effluent and intake samples.
Call me at (256) 386-2755 if you have any questions or comments following your review of the report.
Cynthia L. Russell Biologist Environmental Engineering Services-West CEB 2L-M CLR:RMS Attachment cc (Attachment):
Sherrard, R. M., PSC IX-C Files, ER&TA, CEB IlB-M SQN April 2008m
TENNESSEE VALLEY AUTHORITY TOXICITY TEST REPORT INTRODUCTION I EXECUTIVE
SUMMARY
Report Date: May 12, 2008
- 1. Facility / Discharger: Sequoaah Nuclear Plant / TVA
- 2. County / State: Hamilton / Tennessee
- 3. NPDES Permit #: TN0026450
- 4. Type of Facility: Nuclear-Fueled Electric Generating Plant
- 5. Design Flow (MGD): 1,579
- 7. 1Q10: 3A
- 8. Outfall Tested: 1011
- 9. Dates Sampled. April 13-18. 2008
- 10. Average Flow on Days Sampled (MGD): 1549. 1569, 1561. 1560. 1568, 1565 1 1. Pertinent Site Conditions: Towcrbrom 960 (chlorination) was injected from April 13-18, 2008. The dates and times for the Towerbrom 960 injection are in the following table.
Injection Location Date/Start Time (ET)
Date/Ending Time (ET)
Raw Cooling Water (RCW) 4/13/08 0000 4/18/08 2359 Essential Raw Cooling Water 4/14/08 1925 4/15/08 1245 (ERCW) Train A &B 4/15/08 1455 4/18/08 2359
- 12. Test Dates: April 15-22. 2008
- 13. Test Type: Short-term Chronic Definitive
- 14. Test Species: Fathead Minnows (Pimephales promelas)
Dap~hnids (Ceriodaphnia dubia)
- 15. Concentrations Tested (0 ): Outfall 101: 11.3, 22.6, 45.2, 72.6, 100 Intake: 100.0 Pimephalespromelas: UV treated Outfall 101: 11.3. 22.6. 45.2. 72.6. 100 UV treated Intake: 1 00.0 Page 1 of 10-5
- 16. Permit Limit Endpoint (%): Outfall 10 1: IC2
= 45.2%
- 17. Test Results: Outfall 1 01: Pimephales promelas. Ic2 5 > 1 00%
Ceriodaphnia dubia.: Ic2 5 > I 00%
UV treated Outfall 1 01: Pimephales promelas: IC.2 5 > I100%/
- 18. Facility
Contact:
Stephanie Howard Phone #: (423) 843-6713
- 19. Consulting / Testing Lab: Environmental Testing Solutions. Inc.
- 20. Lab
Contact:
Jim Sumner Phone #: (828) 350-9364 2 1. TVA
Contact:
Cynthia L. Russell Phone #: (256) 386-2755
- 22. Notes: Outfall 1 01 samples collected April 13-1 8, 2008, showed no toxic effects to fathead minnows or daphnids. The resulting IC25 values, for both species, were
>100 percent. Exposure of daphnids to intake samples resulted in no significant difference from the control during this study period, but fathead minnow survival was significantly reduced when exposed to intake samples.
Fathead minnows were also exposed to UV treated Outfall 10 1 and intake samples since fish pathogens present in intake water have been the suspected cause of interference (anomalous dose response and high variability among replicates) in previous toxicity testing at Sequoyah. Although dose response and survival in these tests were not affected enough to jeopardize test acceptability or compliance with permit limits, fish survival was improved by UV treatment of intake and effluent samples prior to exposures. These results suggest that fish pathogen interference was a likely cause of mortality observed in untreated effluent and intake samples.
Page 2 of 105
METHODS
SUMMARY
Samples:
- 1. Sampling Point: Outfall 101., intake
- 2. Sample Type: Composite
- 3. Sample Information:
Date Date Date (MM/DD/YY)/
(MM/DD/YY)/
Arrival Initial (MM/DD/YY)/
Sample Time (ET)
Time (ET)
Temp.
TRC*
Time (ET)
ID Collected Received (OC (mg/L)
Last Used By 04/13/08 0808 to 04/15/08 1137 101 04/14/08 0708 04/14/08 1428 0.9/1.2'
<0.10 04/16/08 1120 04/13/08 0708 04/15/08 1120 Intake 04/14/08 0822 04/14/08 1428 1.1
<0.10 04/16/08 1120 04/15/08 0822 04/17/08 1121 101 04/16/08 0632 to 04/16/08 1413 1.1/1.6t
<0.10 04/18/08 1203 04/15/08 0732to 04/17/08 1215 Intake 04/16/08 0652 04/16/08 1413 2.1
<0.10 04/18/08 1203 04/16/08 0652 04/18/08 1203 04/17/08 0725 to 04/19/08 1210 101 04/17/08 0725 04/18/08 1332 2.0/1.4'
<0.10 04/20/08 1207 04/18/08 0625 04/21/08 1213 04/19/08 1210 04/17/08 0740 to0410820 Intake 04/17/08 0740 04/18/08 1332 1.1
<0.10 04/20/08 1207 04/21/08 1213
- TRC = Total Residual Chlorine
~Sarnples were collected in two 2.5 gallon cubitainers. Temperature was measured in each cubitainer upon arrival.
- 4. Sample Manipulation: Samples from Outfall 1 0.1and intake were warmed to test temperature (25. 0 +/- 1. O'C) in a warm water bath.
Aliquots of Outfall 10 1 and Intake samples were UTV-treated througha 40-watt Smart UV Sterilizer (manufactured by Emperor Aqiuatic.
Inc.~) for 2 minutes.
Page 3 of 105
Pimep hales promelas Ceriodaphnia dubia Test Organisms:
- 1. Source:
Aguatox, Inc.
In-house Cultures
- 2. Age:
19.25 - 19.75 hours8.680556e-4 days <br />0.0208 hours <br />1.240079e-4 weeks <br />2.85375e-5 months <br /> old
<24-hours old Test Method Summary:
- 1. Test Conditions:
Static, Renewal Static, Renewal
- 2. Test Duration:
7 days Until at least 60% of control females have 3 broods
- 3. Control / Dilution Water: Moderately Hard Synthetic Moderately Hard Synthetic
- 4. Number of Replicates:
4 1 0
- 5. Organisms per Replicate: 10 1
- 6. Test Initiation: (Date/Time)
Outfall 10 1 04/15/08 1115 ET 04/15/08 1 100 ET UV Treated Outfall 10 1 04/15/08 1137 ET
- 7. Test Termination: (Date/Time)
Outfall 101 04/22/08 1138 ET 04/22/08 1003 ET UV Treated Outfall 10 1 04/22/08 1153 ET
- 8. Test Temperature: Outfall 101:
Mean = 24.70C Mean = 24.90C (24.2 - 25.2nC (24.6 - 25.20 C)
Test Temperature: UV-Treated Outfall 10 1:
Mean 24.70C (24.2 - 25.20
- 9. Physical / Chemical Measurements:
Alkalinity, hardness, total residual chlorine, and conductivity were measured at the laboratory in each 1 00% sample. Daily temperatures were measured in one replicate for each test concentration. Pre-and post-exposure test solutions were analyzed daily for pH and dissolved oxygen.
1 0. Statistics:
Statistics were performed according to methods prescribed by EPA using ToxCalc version 5.0 statistical software (Tidepool Scientific Software, McKinneyville, CA').
Page 4 of 105
TOXICITY TEST RESULTS (see Appendix C for Bench Sheets)
I Results of a Pimephales promelas Chronic! 7-day Toxicity Test.
(Genus species)
(Type / Duration)
Conducted April 15 -22, 2008 using effluent from Outfall 10 1.
Test Percent Surviving Solutions time interval used - das)
(% Effluent) 1 2
3 4
5 6
7 Control 100 100 100 100 100 100 100 11.3%
100 100 100 100 100 100 100 22.6%
100 100 100 100 100 100 100 45.2%
100 100 93 93 93 93 88 72.6%
100 100 98 98 98 95 93 100.0%
100 100 100 98 95 95 93 Intake 100 100 93 83 60 48 48 Test Solutions Mean Dry Weight (mg)
(% Effluent) 12(replicate numbe
__2 3
4 M ean Control 0.846 0.810 0.748 0.835 0.810 11.30o 0.802 0.825 0.813 0.798 0.810 22.60o 0.838 0.712 0.793 0.863 0.802 45.2%
0.872 0.722 0.728 0.591 0.728 72.6%
0.791 0.742 0.621 0.773 0.732 100.000 0.787 0.617 0.873 0.825 0.776 Intake 0.439 0.530 0.525 0.236 0.433 IC25 Value: > 100%
Calculated TU Estimates: < 1.0 TUc*
Permit Limit: 45.20o Permnit Limit: 2.2 TUc 95% Confidence Limits:
Upper Limit: NA Lower Limit: NA__
- TUa = 100/LC50: TUc = 100/ IC25 Page 5 of 105
TOXICITY TEST RESULTS (see Appendix C for Bench Sheets)
- 2.
Results of a Ceriodaphnia dubia Chronic/ 7-day Toxicity Test.
(Genus species)
(Type / Duration)
Conducted April 15-22. 2008 using effluent from Outfall 101.
Percent Surviving Test (time interval used - days Solutions Efluint 1
2 3
4 5
6 7
C%
Effluentr 0
Control 100 100 100 100 100 100 100 11.3%
100 100 100 100 100 100 100 22.6%
100 100 100 100 100 100 100 45.2%
100 100 100 100 100 100 100 72.6%
100 100 100 100 100 100 100 100.0%
100-100 I100 100 100 100 100 Test Solutions Reproduction (#young/female/7 days)
(% Effluent)
Data re plicate nmer)
I1 2 13 4
5 6
7 8
9 110 Mean Control 35 33 32 34 32 34 33 28 32-32 32.5 11.3%
36 37 39 36 40 34 36 37 33 37 36.5 22.6%
38 39 36 40 3 6 3 8 40 3 8 4 1 4 1 38.7 45.2%
4 1 35 3 8 42 39 3 7 3 8 40 3 9 4 1 39.0 72.6%
3 9 3 8 42 3 8 4 1 3 9 3 8 4 1 42 3 8 39.6 100.0%
43 3 8 40 42 4 1 3 9 4 1 3 9 44 38 4.
IC25 Value: > 1 0000 Calculated TU Estimates: < 1.0 TUc*
Permit Limit: 45.20o Permit Limit: 2.2 TUc 95% Confidence Limits:
Upper Limit: NA Lower Limit: NA
- TUa =100/LC 50: TUc 100/ IC25 Page 6 of 105
TOXICITY TEST RESULTS (see Appendix C for Bench Sheets)
- 2.
Results of a Ceriodaphnia dubia Chronic/ 7-day Toxicity Test.
(Genus species)
(Type / Duration)
Conducted April 15-22, 2008 using water from Intake Percent Surviving Test (time interval used - days Solutions So~lutins 1
2 3
4 5
6 7
CoEffluentr 10 1
Control 100 100 100 100 100 100 100 Test Solutions Reproduction (#young/female/7 days)
(%s Efflueint)
Data re hate numer)
(% Ef1l2e3 4
5 6
7 8 19 10 Mean Control 33 33 33 37 31 35 33 32 33 33 33.3 Intake 141 40 139 41 39 39 42 37 36 39 39.3 IC25 Value: > 1 00%
Calculated TU Estimates: < 1.0 TUc*
Permit Limit: N/A Permit Limit: N/A 95% Confidence Limits:
Upper Limit: NA Lower Limit:_NA
- TUa I 100/LC5o: TUce 100/IC2 5 Page 7 of 105
TOXICITY TEST RESULTS. UV-TREATED (see Appendix C for Bench Sheets)
- 3.
Results of a Pimephales promelas Chronic/ 7-day Toxicity Test.
(Genus species)
(Type / Duration)
Conducted April 15-22, 2008 using effluent from UV Treated Outfall 101.
Test Percent Surviving Solutions time interval used - dys
(% Effluent) 1 2
3 4
5 6
7 Control 100 100 100 100 100 100 100 11.3%
100 100 100 100 100 100 100 22.6%
100 100 100 100 100 100 100 45.2%
100 100 100 100 100 100 100 72.6%
100 100 100 100 100 100 100 100.0%
100 100 100 100 100 100 100 Intake 100 100 100 100 100 100 100 Test Solutions Mean Dry Weight (mg)
(% Effluent) plicate nu er_
_2 3
4 Mean Control 0.866 0.672 0.838 0.847 0.806 11.3%
0.792 0.867 0.743 0.787 0.797 22.6%
0.841 0.682 0.840 0.808 0.793 45.2%
0.912 0.833 0.709 0.867 0.830 72.6%
0.785 0.809 0.812 0.888 0.824 100.0%
0.767 0.810 0.804 0.776 0.789 Intake 0.871 0.770 0.878 0.869 0.847 IC 25 Value: > 1000 Calculated TU Estimates: < 1.0 TUc*
95% Confidence Limits:
Upper Limit: NA Lower Limit; NA
- TUa = 100/LC5 0: TUc =100/ IC 25 REFERENCE TOXICANT TEST RESULTS (see Appendix A and D)
Species Date Time Duration Toxicant Results (C 25)
Pimephalespromelas April 15-22, 2008 1202 7-days KCI 0.59 g/L Ceriodaphnia dubia April 8-15, 2008 1507 7-days NaCI 1.07 g/L Page 8 of 105
PHYSICAL/CHEMICAL
SUMMARY
Water Chemistry Mean Values and Ranges for Pimep hales promelas and Ceriodaphnia dubia Tests, Non-treated Sequoyah Nuclear Plant Effluent (S QN), Outfall IO11, April 1 5-22, 2008.
Test Sample ID Temperature (CC)
Dissolved Oyen (mg/L) pH (S.U.)
Conductance Alkalinity Hardness Total Residual Initial Final Initial Final Initial Final (Rmhos/cm)
(mg/L CaCO 3) (mg/L CaCO 3)
Chlorine (mg/L)
Control 24.7 24.6 7.7 7.5 7.78 7.43 319 61 92 24.6 - 24.9 24.4 -
24.8 7.5 8.0 6.4 7.9 7.49 - 7.97 7.18 - 7.54 303 343 59 63 90 94 11.3%
24.8 24.5 7.8 7.4 7.66 7.50 305 24.7 -
25.0 24.2
- 24.7 7.5 8.0 6.6 7.9 7.58 7.84 7.30 - 7.70 290 312 24.9 24.4 7.8 7.4 7.62 7.41 290 22.6%
24.7 - 25.0 24.2 - 24.7 7.6 -
8.0 6.4- -
7.9 7.55 - 7.71 7.14 - 7.54 278 -
298 24.9 24.5 7.8 7.4 7.60 7.38 256 45.2%
24.7 - 25.0 24.2 - 24.6 7.5 7.9 6.2 7.8 7.54 - 7.70 7.03 - 7.52 243
- 266 4!
24.9 24.5 7.8 7.3 7.56 7.32 212 1~2 72.6%
24.8-25.1 24.3-24.7 7.5-8.0 5.9-7.8 7.50-7.64 7.01-7.48 207-215 25.0 24.5 7.8 7.4 7.52 7.30 168 53 64
<0.10 100.0%
24.8 - 25.2 24.3 -
24.7 7.6 8.1 6.4 7.8 7.46 - 7.60 7.01 - 7.42 166 -
172 53 54 61 65
<0.10 -
<0.10 Intake 25.0 24.6 7.9 7.4 7.51 7.29 167 54 62
<0.10 24.8-25.1 24.4 - 24.9 7.6 8.2 6.5 7.8 7.45 - 7.60 7.01 -
7.41 162 172 52 55 57 65
<0.10
<0.10 Control 24.8 24.8 7.7 7.7 7.78 7.58 319 61 92 24.7 - 24.9 24.6 - 25.0 7.5 8.0 7.4 -
7.9 7.49 - 7.97 7.45 - 7.70 303 343 59 63 90 94 11.3%
24.9 24.9 7.8 7.6 7.62 7.57 305 24.8 -
25.0 24.8 -
25.1 7.5 8.0 7.4 7.9 7.54 -
7.70 7.46 - 7.67 290 -
312
~
22.6%
24.9 24.9 7.8 7.7 7.62 7.54 290 24.8 - 25.0 24.7 - 25.1 7.6
- 80 7.4 7.9 7.55 -
7.71 7.42 - 7.63 278 298 24.9 24.9 7.8 7.7 7.60 7.52 256 45.2%
24.8
- 25.0 24.8
- 25.1 7.5 7.9 7.5 8.0 7.54 -
7.70 7.42 - 7.62 243 -
266 25.0 24.9 7.8 7.7 7.56 7.48 212
.2 72.6%
24.8
- 25.1 24.7 -
25.1 7.5 8.0 7.4 7.9 7.50 -
7.64 7.38 - 7.56 207 -
215 100.0%
25.0 24.9 7.8 7.7 7.52 7.45 168 53 64
<0.10 24.8
_ 25.1 24.8 - 25.2 7.6 8.1 7.5 7.9 7.46 - 7.60 7.36 - 7.54 166 -
172 53 54 61 65
<0.10
<0.10 Intake 25.0 24.9 7.9 7.7 7.51 7.46 167 54 62
<0.10 24.8 -
25.1 24.8 - 25.0 7.6 -
8.2 7.6 8.1 7.45 -
7.60 7.42 - 7.55 162 -
172 52 55 57 65
<0.10 -
<0.10 Overall temperature C0C)
Average Minimum Maximum Pimep hales promelas 24.7 24.2 25.2 Ceriodaphnia dubia 24.9 24.6 25.2 Page 9 of 105
PHYSICAL/CHEMICAL
SUMMARY
Water Chemistry Mean Values and Ranges for Pimep hales promelas Tests, UV-treated Sequoyah Nuclear Plant Effluent (SQN), Outfall 101, April 15-22, 2008.
Test Sample ID Temperature CC)
Dissolved Oxgen (ing/L) pH (S.U.)
Conductance Alkalinity Hardness Total Residual Initial Final Initial Final Initial Final (fmhos/cm)
(mg/L CaCO3) (mg/L CaCO3)
Chlorine (mgIL)
Control 24.8 24.6 7.8 7.3 7.62 7.40 319 61 89 24.6 - 24.9 24.3 -
24.7 7.6 8.0 6.0 7.9 7.54 - 7.69 6.98 -
7.58 304 334 59 62 86 92 11.3%
24.9 24.5 7.8 7.2 7.62 7.41 305 24.6 - 25.1 24.3 - 24.7 7.7 8.0 5.6 7.8 7.54 - 7.68 6.96 - 7.57 298
- 316 25.0 24.5 7.9 7.2 7.61 7.39 288 22.6%
4 24.7 - 25.1 24.2 - 24.7 7.7 8.0 5.6 7.7 7.54 - 7166 6.96 - 7.54 272
- 299 25.0 24.5 7.9 7.1 7.59 7.35 257 45.2%
24.7 -
25.1 24.2 -
24.6 7.6 8.0 5.3 7.7 7.52 - 7.63 6.94 - 7.51 248 -
264 4:
7 25.0 24.5 7.9 7.2 7.54 7.32 215 72.6%
24.7 - 25.2 24.3 - 24.6 7.6 8.1 5.4 7.7 7.49 - 7.58 6.89 - 7.48 211 221 100.0%
25.0 24.5 7.9 7.1 7.51 7.27 172 53 64
<0.10 100.0%
24.7 - 25.2 24.3 - 24.7 7.7 -
8.1 5.6 7.7 7.46 - 7.54 6.89 -
7.41 169 178 51 54 61 69
<0.10
<0.10 Intake 25.0 24.5 7.9 7.2 7.49 7.27 169 52 66
<0.10 Intake
- 2.
45795 24.8-25.2 24.3 - 24.7 7.7 8.1 6.3 7.7 7.44 - 7.54 6.93 - 7.44 166 174 50 54 65 67
<0.10
< 0.10 Overall temperature CC)
Average Minimum Maximum Pimephales promelas 24.7 24.2 25.2 Page 10 of 105
SUMMARY
/ CONCLUSIONS Outfall 1 01 samples collected April 13-18, 2008, showed no toxic effects to fathead minnows or daphnids. The resulting IC25 values, for both species, were >100 percent.
Exposure of daphnids to intake samples resulted in no significant difference from the control during.this study period, but fathead minnow survival was significantly reduced when exposed to intake samples.
Fathead minnows were also exposed to UV treated Outfall 1 01 and intake samples since fish pathogens present in intake water have been the suspected cause of interference (anomalous dose response and high variability among replicates) in previous toxicity testing at Sequoyah. Although dose response and survival in these tests were not affected enough to jeprietest acceptability or compliance with permnit limits, fish survival was improved by UV treatment of intake and effluent samples prior to exposures. These results suggest that fish pathogen interference was a likely cause of mortality observed in untreated effluent and intake samples.
Page 11 of 105
Appendix A ADDITIONAL TOXICITY TEST INFORMATION
SUMMARY
OF METHODS
- 1. Pimephales promelas Tests were conducted according to EPA-821-R-02-013 (October 2002) using four replicates, each containing ten test organisms, per treatment. Test vessels consisted of 500-nL plastic disposable cups, each containing 250-mL of test solution.
- 2. Ceriodaphnia dubia Tests were conducted according to EPA-821-R-02-013 (October 2002) using ten replicates, each containing one test organism, per treatment. Test vessels consisted of 30-mL polypropylene cups, each containing 15-mL of test solution.
DEVIATIONS IMODIFICATIONS TO TEST PROTOCOL
- 1. Pimephales promelas None
- 2. Ceriodaphnia dubia None DEVIATIONS / MODIFICATIONS TO PRETEST CULTURE OR HOLDING OF TEST ORGANISMS
- 1. Pime-phales Promelas None
- 2. Ceriodaphnia dubia None Page 12 of 105
PHYSICAL AND CHEMICAL METHODS
- 1. Reagents, Titrants, Buffers, etc.: All chemicals were certified products used before expiration dates (where applicable).
- 2. Instruments: All identification, service, and calibration information pertaining to laboratory instruments is recorded in calibration and maintenance logbooks.
- 3. Temperature was measured by SM 2550 B.
- 5. The pH was measured by SM 4500 H+ B.
- 6. Conductance was measured by SM 251 0 B.
- 7. Alkalinity was measured by SM 2320 B.
- 8. Total hardness was measured by SM 2340 C.
- 9. Total residual chlorine was measured by ORION Electrode Method 97-70.
QUALITY ASSURANCE Toxicity Test Methods: All phases of the study including, but not limited to, sample collection, handling and storage, glassware preparation, test organism culturing/acquisition and acclimation, test organism handling during test, and maintaining appropriate test conditions were conducted according to the protocol as described in this report and EPA-821 -R-02-013. Any known deviations were noted during the study and are reported herein.
REFERENCE TOXICANT TESTS (See Appendix D for control chart information)
I. Test Type: 7-day chronic tests with results expressed as IC2 5 values in g/L KCI or NaCl.
- 2.
Standard Toxicant: Potassium Chloride (KCI crystalline) for Pimephales promelas.
Sodium Chloride (NaCl crystalline) for Ceriodaphnia c/tbia.
- 3. Dilution Water Used: Moderately hard synthetic water.
- 4.
Statistics: ToxCalc software Version 5.0 was used for statistical analyses.
Page 13 of 105
REFERENCES
- 1. NPDES Permit No. TN0026450.
- 2. USEPA. Short-Term Methods for Estimating the Chronic Toxicity of Effluents and Receiving Waters to Freshwater Organisms, EPA-821-R-02-013 (October 2002).
- 3.
Standard Methods for the Examination of Water and Wastewater, 20th Edition, 1998.
- 4. Quality Assurance Program: Standard Operating Procedures, Environmental Testing Solutions, Inc (most current version).
Page 14 of 105
Sequoyah Nuclear Plant Biomonitoring April 15 - 22, 2008 Appendix B Diffuser Discharge Concentrations of Chemicals Used to Control Microbiologically Induced Corrosion and Mollusks, During Toxicity Test Sampling Page 15 of 105
Table B-i. Sequoyah Nuclear Plant Diffuser (Outfall 101) Discharge Concentrations of Chemicals Used to Control Microbiologically Induced Corrosion Mollusks, During Toxicity Test
- Sampling, March 12,1998 -April 18, 2008 Date Sdi Towerbrom PCL - 222 PCL-401 CL33Cuprostat-H1O
- ~yM~ri~
g/L nigfLmg/L mg/L PF
~f
~~ng/L ~TRC Pbsh~
Copolymer DMD mg/L
%~~
~~~~~~~~~~~~~Azole 03/12/1998 03/13/1998 03/14/1998 02/25/19998 Af 02/26/1999 i 02/27/19998 OO~
02/28/1999..
08/18/1999.018A6 0.02 08/19/1999 001 0.02 OEM 08/20/1999802 0.021012 08/21/19998.2
.*O~&
0.0249 08/22/19998*
0.022...
0.024 08/23/19998.2
- .OO~*
0.024 08/24/19998.1 0.023 Page 16 of 105~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~......
Table B-I. Sequoyah Nuclear Plant Diffuser (Outfall 101) Discharge Concentrations of Chemicals Used to Control Microbiologically Induced Corrosion Mollusks, During Toxicity Test
- Sampling, March 12, 1998 -April 18, 2008 Date Soi~n Tower-brom...
CL 2
PCL-401 CL33 Cpostat-
{10 I chrto mg/L TgLmg/b PF TRC P opae Copolymer DMI mgL Qa TRC
~~~~~~~~~~~~~Azole 01/31/2000 0002......
0009
< 0.0 2
....... O.-0.009..
02/01/2000::::
0.011 0.028 028 02/02/2000 0.028 4A60.009 AO..
12/14/2000
- 00087 0.020 12/15/2000 0.0106 O~
00209 0-0 02i'05/2000
<0 0.036 O~O2~0.020 12/17/2000::,'
... *000362 0.0209 08/27/2001
< 0.0096
~
Q0.019 11/28/2001
- 0.0089 0.019 07128/2000 0.0128 f024 0.02.
2/130/2001
< 0.0088
. 0024 0.021 2/314/2001
< 0.013452 024 0.0219 Page1 1700 of0.0105 0.019 0,0143 i~
0.020 12/12/2000
~~~~~~~~0.020 12/13/2000
< 0.0120
~~~0.020 12/14/2000
< OM87
~~~~0.020 J~~~~~~~~~~~~~~~~~~~~~~~~~~l ~
~~~~~......
Sol Jo St Aud ZZ0,0
.LOO'O>
W OZ/1 13 10 lZOO E I 10,0>
00 /01/tO 6 1 0 '0 >
O O Z /6 0 /t7O IZOO LI 10'0>
EOOZ/80/tO I ZOO 68 10,0>
W OULO/tO ELOO'O>
woz/go/to.
600'0 NW tlW 0,0>
E O O Z /L I/ 10 tEOO'O>
EOOZ/91/10 OZOO E900,0>
WOZSI/10 OZOO 81 10,0>
EOOZ/tll/lo 610'O 900,0>
WOZ/ET/10 900,0>
EOOZ/ZI/101 8 1 0,0 Z t,0 0 '0 >
Z O O Z / I 1/0 I 10,0 tm -O 8
ZOOZ/01/01 810,0 tlZIOO ZOOZ/60/01 i','-
Z600'0>
810,0
............. 0...
ZOOZ/80/01 810,0
-XV-D-V ZOOZ/LO/01 X..................
L6tOO'O>
ZOOZ/90/011 ZOOZ/60/80 610'0 1900'0>
... ZOOZ/80/80 610'0 LOIO'O>
ZOOZ/LO/80 810,0 Z600'0 ZOOZ/90/80 wN 810,0 8900'0>
ZOOZ/W 80 8900'0>
zooz/to/go ZOOZ/01/90
...... I.............
ZOO J Of ZOOZ/60/90
................. I...........
.........O 610,0 ZOOZ/80/W ZOO ZOOZ/LO/W A
ZOOZ/90/90 ZOOZ/W/W I t,00,0 >
800,0
- ------- -0 00 to/W I t700'O >
800,0 ZOOZ/8z/zO UOO It,00,0 >
ZOOZ/LZ/ZO EZ0,0 Etltoo ZOOZ/9z/zo EZO'O t,00,0 zooz/Z/zo t700'O >
ZOOZ/tZ/ZO t,10,0
.......z 6800'0 ZOOZ/LO/10 Zt,00'0 >
ZOOZ/90/10 Zt,00'0 >
ZOOZ/50/10 tloo tlZIOO ZOOZ/t,0/10 tloo
- Responsibilities--.
ztOOO ZOOZ/EO/10 ZOO aw. -.10.0 6LOO'O.....
QlOzv
-Uiw lpwfjodoD a i A d T5W
-v5LU X
-julsoldn OJECI 10 d
wojqjomoj 80OZ 'SI PdV-8661 'Z I q3JUW
'2uijdtuuS Isol fjjoixoL 2uun(l 's)jsnjjoW uoisouoo panpul XjjuodojoiqojotW joiluoD Oi posfl sjvoiwoiqD Jo suOlp,.jjuoouoD ;)jijpqosi(j (101 Ilujlno) iosnjjlCj iuujdm3jz)nN qu,onb3S -I-S 31q,
Table B-i (continued). Sequoyah Nuclear Plant Diffuser (Outfall 101) Discharge Concentrations of Chemicals Used to Control Growth of Microbiologically Induced Bacteria and Mollusks, During Toxicity Test Sampling, March 12, 1998 -April 18, 2008 Date oix~
Towerbrom PCL-222 PCL-401 CL463~ Cuprostat-H 130
~o~hlo~ite mg/L m/vmg/L mgi PF m/
~~g/L TRC Phosp.......
Copolymer DA gi Q~
- ~~~~~~TC...
m/AzLe 06/15/2003
< 0004 5-06/16/2003
< 00037 p070.020 02 06/17/2003 1<
00048 0.014-4 08/06/2003
< 0.00484 f5 0.02014~2 08/07/2003
<.. 0012 fK5 0.020 08/208/2003
<000153ie 0.020 t.0 10/03/2003
<0.004350S 02 108/06/2003
<0.004350 05 0.020 108/07/2003
<0.0090515 0.020-
.2 108/08/2003
<0.010684 0.020 05 108/09/2003 0.0181 0.022 108/108/2003 0.0183 0.026 0024...
l02/0/2004
< 0.0093 0.0210 009 102/02/2004:
<0.00434 0.026009 102/03/2004
<0 00349&60 0090 102/04/2004
<00124062 00209 102/06/2004 0.0105812 0.092 0..01 105/106/2004
<00146833 0013242 05/08/2004
- 000.00930.
0.021.
05/09/2004
.<0.01034
- .*t00.0209 07/04/2004
<0.02134
&5 0.019-07/05/2004
<0.008524 0
0.0209 00 07/07/200
<0.02524 0.019 0...0.....
0/8204 023....7001 00 07/09/2004 0.018205
.5 0.0209 00 Page 19 of 105~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~.......
Table B-1. Sequoyah Nuclear Plant Diffuser (Outfall IO 1) Discharge Concentrations of Chemicals Used to Control Microbiologically Induced Corrosion Mollusks, During Toxicity Test
- Sampling, March 12,1998 -April 18, 2008 PCL-401
- 0 -36.
Cuprostat-X..
"Umm Date Towerbrom mg/L mg/L
/L 73551 W.P.0-000.0.,
mg C
TR Copolymer Azole m /L EO/PO ow 11/07/2004
i
<0.0187 0.014 11/08/2004 0.030 11/09/2004
<0.0233 0.016 11/10/2004
<0.0149 0.016 11/11/2004 0.0149 0.017 11/12/2004,....
<0.0253 0.017 02/06/2005
<0.0042 0.010 X.:
02/07/2005
<0.0116 0.010 02/08/2005
<0.0080 A
0.010 02/09/2005 0.0199 0.010 WX 02/10/2005
<0.0042 0.010 W..
02/11/2005 0.0155 0.010 OM7 06/05/2005 0.0063 06/o6/2005 0.0043 06/07/2005 0.0103 06/08/2005 0.0295 06/09/2005 0.0129 06/10/2005 0.0184
- V 07/17/2005 "02 0.0109 0.009 07/18/2005 0.0150 0.009 07/19/2005 6
0.009 07/20/2005...
0.0209 0.009 0.014 07/21/2005 0.0242 0.009 0.014 07/22/2005 0.0238 om 10/30/2005 0.0068 10/31/2005 0.0112 11/01/2005 0.0104 11/02/2005 0.0104 11/03/2005 0.0117 11/04/2005 0.0165 3
11/14/2005 0.0274 11/15/2005.........
11/16/2005 0.0234 11/17/2005 0.0231 11/18/2005 11/19/2005
........ 0.0116 Page 20 of 105
Table B-i (continued). Sequoyah Nuclear Plant Diffuser (Outfall 101) Discharge Concentrations of Chemicals Used to Control Growth of Microbiologically Induced Bacteria and Mollusks, During Toxicity Test Sampling, March 12, 1998 -April 18, 2008 Date S~diuni~
Towerbro PCL.~222 PCL-401 CL33 Cuprostat-PF IMO aco IISM MSW Hyp~~c1~Lodt~~
mg/L m~L mgLnfg/
L
/L
~
?hsht oolymer DMD AOle
~
r
~
mg/L ut mI TRC
~~~~~
~
~~~~~~~~~~~~~~~~
Phosphat 1l1/1 2/2006 0.0055-11/13/2006 0.0068 f,3 11/14/2006
.0.0143
~
11/15/2006 0.0068 11/16/2006..
0..
0267 ff3-11/17/2006 0.0222-11/26/2006 0.0188-11/27/2006 0038ns 11/28/2006 00120 11/29/2006 00288 11/30/2006 00376 12/01/2006 00187 05/28/07 0015.
05/29/07 0015.
05/31/07 0103 0.015 06/029/07 030.
015 12/304/07 023084 12/05/07 01585 12/06/07 0162~~~~~~~~~~~~~~~~~~~~~~~~~00
.1 12/07/07 017 04/13/08 0.03950 04/142/87..
010241 04/17/08 00120 1204/18 08 0149 Page 21 of 105
~
~
~
~
~
~ ~ ~ ~ ~ ~~~~~~~~................
Sequoyah Nuclear Plant Biomonitoring April 15 -22, 2008 Appendix C Chain of Custody Records and Toxicity Test Bench Sheets Page 22 of 105
Toxicity Test Scheduling Instruction SOP-I.0 Toxicity Testing Scheduling and Testing Communication Documentation Initial that Information orc TVA Contract PoetSeiiain Tox.
Lab.
amlrPoetSeicton (I~~u~~-
(i\\
~TVA/Facility name:
Sequoyah Nuclear Plant Permit number:
TN0026450 Project name:
SQN Tax. Compliance Tests Date and time scheduled with Jau30208@14 Contract lab:
~Environmental Testing Solutions
~~
~\\
Contract lab:
~~~(ETS)
Point of contact:
Jim Sumner U
~~~Date and time scheduled with au30208@12 Test Date and Type (chronic or Arl1,20/crnc Test Species: ~FH (w/ & w/o UV treatment), CD 1.01I-1I1. 3, 22.6, 45.2, 72.6, 1 0010%;
I100.0%intalke-l100%
UV 101-11.3, 22.6, 45.2, 72.6,
~~~~~~~~~~UV I100.0%intake-100%
Treatments that will occur at lab:
UV Treated FR only Sample collectors:
Chievales Williams Date and time scheduled with January 30, 2008 @ 1417 and volumes: Sample 1 Sample 2 Sample 3 Sampling poinlts advlms 10 1-2.5 gal 10 1-2.5 gal; 101-5 gal (composite samplers to be set Intake 2.5 intake-2.5 Intake 2,5 on April 13, 2008.)
gal gal; gal Delivery method:
Private Courier Contact information for delivery:
STOP- (Reviewed and verify all information is correct and all parties involved agree).
Document by using electronic mail at least seven (7) calendar days prior to test initiation. All e-mails are attached and represents a person sign off that the information is correct.
Sign off:.;'
EES-W Toxicologist and/or AM&M Senior Toxicologit______________
BIOMONITORING CHAIN OF CUSTODY RECORD Page 1 of 1 Client: TVA Eniomna etn ouin n.
Delivered By (Circle One):
(I'~~~~~~~~~~niomna esigSltoIc Project Name: Sequoyah NP Toxicity 351 Depot Street.
FedEx UPS Bus Client P.O. Number: N/A Asheville, NC Other (specify'): Sonic Delivery FacilityISampled: Sequoyah NP 28801 General Comments:
NPDES Number: TN0026450 Phone:
828-350-9364 Collected By: Chevy Williams, Roy Quinn Fax:
828-350-9368 Field Identification!
Grab/Comp.
Collection Date/Time Container Flow
/00431t Sample Description Number &
MGD Rain Event?
Volume (Mark as Appropriate)
Laboratory' Use C ollected Date Time Yes If Yes, No Trace ETS Log Arrival By Time Appear-Inches Number Temp.
ance
~~~~
~~(IC)_
SQN-101-TOX Comp 04/13/08-04/14/08 0808-2 (2.5gal)
NA X
D~NO A'
j\\3
~
SQN-INT-TOX Cop 04/13/08-04/14/08 0922-1 (2.5 gal)
NAX V
A-
~Sample Custody - Fill In From Top Down 4,+OA i*."
iJ...4od.1 Relinquished By (Signature):
Date/Time Received By (Signature):
Date/TimY Chevy Williams 04/14/08 ICA45 Sonic Delivery 04/14/08
/C',.'. s-Sonic Delve04/14/08 ES04/14/08 Instructions: Clients should fill in all areas except those in the "Laboratory Use" block. Biomonitoring samples are preserved by storing them at 60C and shipping them in ice. The hold time for each sample is 36 hours4.166667e-4 days <br />0.01 hours <br />5.952381e-5 weeks <br />1.3698e-5 months <br /> from the time of collection. Therefore, please collect and ship in such a way that the laboratory will receive the samples with ample time to initiate testing within that time frame. Samples shipped overnight on Friday via FedEx or UPS must be marked for Saturday delivery or they will not arrive until the following Monday.
Environmental Testing Solutions, Inc.
tI' Page Whole Effluent Toxicity Sample Receipt Log (J1 Date Time Received Received Sample Project Sultple Samplename end decription Stete Corments received received by front temperature ('C) number number 04-14-08 1428 i Sunmer TVA Courier 0.9/1.2 3810 080414.01 TVA-SeuoyahNulearPLnt-Outfal 101 TN 04-14-08 1428 J. Sunmer TVA Courier 1.1 3810 080414.02 TVA -Sequoyah Nuclear Plant -Intake TN 04-14-00
BIOMONITORING CHAIN OF CUSTODY RECORD Page 1 of 1 Client: TVA Environmental Testing Solution, Inc.
Delivered By (Circle One):
Project Name: Sequoyah NP Toxicity 351 Depot Street.
FedEx UPS Bus Client P.O. Number: N/A Asheville, NC Other (specify): Sonic Delivery Facility Sampled: Sequoyah NP 2880 1
General Comments:
NPDES Number: TN0026450 Phone:
828-350-9364 Collected By: Chevy Williams, Roy Quinn Fax:
828-3 50-9368 Field Identification /
Grab/Comp.
Collection Date/Time Container Flow Sample Description I
I IWNumber &
MGD Rain Event?
Laboratory Use Volume (Mark as Appropriate)
Date Time Yes If Yes, No Trace ETS Log Arrival By Time Appear-inches Number Temp.
ance SQN-101-TOX Comp 04/15/08-04/16/08 0732-2 (2.5gal)
NA X
(
f.C..
ll i.
SQN-lNT-TOX Comp 04/15/08-04/16/08 0652.
1 (2.5 gal)
NA oevqiW4 Sample Custody - Fill In From Top Down
-4. Cu...,4o 4.e.L c*'-cJB.
Relinquished By (Signature):
Date/Time Received By (Signature):
Date/Time Chevy Wiliards 04/16/08 Sonic Delivery 04/16/08 Sonic Deli Iy 04/16/08 ETS 04/16/08
Environmental Testing Solutions, Inc.
Page 71 Whole Effluent Toxicity Sample Receipt Log Date
'ime Received Received Sample Project Sample Sampie name and description State CO.11m1ents received received by from temperature CC) number number 04-16-08 0932 K. Keenan Fed -Ex 1.4 3814 080416 01 Duke Energy Corporation -Allen Stearn Station NC 04-16-08 0952 K. Keenan Fed -Ex 0.9 3815 080416.02 Duke Energy Corporation -Rivrbend Steam Station NC 04-16-00 0952 K. Keenan Fed -Ex 06 3816 080416.04 Tritest, Inc. -Cioldsboro WWTP-Outfall 001 NC 04-16-08 0952 K. Keenan Fed -Ex 0.6 3817 080416.04 Tritest Inc. -Goksboro WWPTP -Outfall 002 NC 04-16-08 0952 K. Keenan Fed -Ex 03 3818 080416.05 Osiford Mills East NC 04-16-08 0952 K. Keenan Fed -Ex 0.3 3889 080416.06 GuitfordMdLsEast-Secondary Clarifiers NC 04-16-08 0952 K. Keenan Fed -Ex OS 3820 080416.07 TVA-Colbert ossilPlant - ofall001 AL 04-16-08 0952 K. Keenan Fed -Ex 0.4 3820 080416 08 TVA -Colbert FossilPlant -Upstream AL 04-16-08 1030 K. Keenan UPS 0.6 3821 080416.09 Enviro Chemists - South Mills Water Association WTP NC 04-16-08 1030 K Keenan UPS 0.4 3822 080416.09 City of Henderson -Nutbrush Creek WWTP NC 04-16-08 1030 K. Keenan UPS 0.4 3823 080416 10 City of Henderson -Nutbrush Creek WWTP -lans NC 04-16-08 1030 K. Keenan UPS 0,4 3824 080416.11 City of Henderson - Nutbrush Creek WWTP -Kennansetal NC 04-16-08 1030 K. Keenan S
04 3825 080416.12 CityefHe3nderson-Nutbruh Creek WWTP -Walmart NC 04-16-00 1413
- 2. Sumer TVA Courier 1.1/1.6 3840 080416.13 TVA -SequTyaNNucea-Plant-Outfall 101 TIl 04-14-08 1413 J. Suimner TVA Courier 2.1 3810 080416 14 [VA -Sequoyah Nuclear Plant -Intake TN 04-16-04
BIOMONITORING CHAIN OF CUSTODY RECORD Page 1 of 1 Client: TVA Environmental Testing Solution, Inc.
Delivered By (Circle One):
Project Name: Sequoyah NP Toxicity 351 Depot Street.
FedEx UPS Bus Client P.O. Number: N/A Asheville, NC Other (specify): Sonic Delivery Facility Sampled: Sequoyah NP 28801 General Comments:
NPDES Number: TN0026450 Phone:
828-350-9364 Collected By: Chevy Williams, Roy Quinn Fax:
828-350-9368 Field Identification /
Grab/Comp.
Collection Date/Time Container Flow Sample Description Number &
MGD Rain Event?
Laboator Us Volume (Mark as Appropriate)
Collected Date Time Yes If Yes, No Trace ETS Log Arrival By Time Appear-Inches Number Temp.
ance SQN-l01-TOX Comp 04/17/08-04/18/08 0725-2 (2.5gal)
NA X
.'4L X
4I 0625
~~~~~~~08U44&6 (L
SQN-rNT-TOX Comp 04/17/08-04/18/08 0740-1(2.5 gal)
NA X
0640 Sample Custody - Fill In From Top Down Relinquished By (Signature):
Date/Time Received By (Signature):
Date/Time Chevy,Wi liarns 04/18/08 Sonic Delivery 04/18/08 Soi/c D4 e e4 010 Sonic Delivery~
04/18/08 ETS 04/18/08
~~A~rc~~ec
~
~
\\33 L
Cd Envwronmental Testing Solutions, Inc.
Oi Page__
Whole Effluent Toxicity Sample Receipt Log Date Ti'ne Received Received Sample Project Sample Samplenameand description State Commentu received ree-ived by from temperature ('C) number number r 04-18-08 1332 1 Suniaer TVA Courier 20/1.4 3810
.080418 01 ETVA -Squoyah Nuclear Plant -Outall 108 TN 04-18-08 1332 J. Suminer TVA Courter 11 3810 080418.02 T`VA-SequoyaNuclearPlant -itake TN 04-10-03
I Environmental Testing Solutions, Inc.
Page 1 of 6 Chronic Whole Effluent Toxicity Test (EPA-821-R-02-013 Method 1000.0)
I Species: Pimephalespromelas Client: TVA County: Hamilton Facility: Sequovah Nuclear Plant Treatment: Non-treated NPDES#: TN 0026450 Outfall: 101 Project I IO I
Dilution preparation information:
Comments:
Dilution prep (%)
11.3 22-6 45.2 726 100 Effluent volume (mL) 282.5 1130 1815 2500 Diluent volume (ml-)
2217.5
^0
'1370 685 Total volume (mL) 2500 2500 2500 2500 2500 I
Test organism information:
Test information:
Organism age:
1i.2s, O~ h Randomizing template:
100 Date and times organisms 04-14-09 1%*00 Incubator number:
I were born between:
Organism source:
A-To)L 1kTLN\\
o4 -I-OR Artemia lot number:
Transfer bowl information:
pH Temperature =
0C Total drying time:
- 1.
W 41-'L Date / Time in: oq'l--o Rt M
Average transfer volume:
(a Date / Time out: osk-noo 17-c Oven temperature:
c Dailyfeeding and renewal information:
Day Date Morning Afternoon Test initiation, Control water Sample numbers Analyst feeding feeding time renewal, or batch used used time termination time I
1150 illcs o-un-ot o a o 1'4. o O
1 0\\70 0
rc Il
.e 04-A-ri-oc 6q Lj
- 0 I
'A o+ 0 okoo 1qOc(
1202.
o4.i3-o0 9 o0c141.-
-k 1-4 0 - L -O 0100 IA 0 0 I%2 A,ro Z4i
-o\\-
I oq-zo-cie o
is IO IS O+1iO k I\\
t\\
4O 6
0, tS-4 115' 1ii.DaA Oa 1cAE I4-O2L IL~-tZ-O0
-s--
- i 1\\3RZI U
I Control information:
Acceptance criteria Summary of test endpoints:
% Mortalit:
O
<20%
7-day LC50 Io(7'.
Avera e wei ht ernitial larvae:
oM NOEC I ml Average weight per surviving larvae:
- 0. CID 0.25 mg/larvae LOEC ChV
>Io007.
IC25
> ioo7.
Page 30 of 105
Environmental Testing Solutions, Inc.
Page 2 of 6 Species: Pimephalespromelas Date:
o4-IS-a8 Client: TVA / Sequoyah Nuclear Plant - Non-treated Survival and Growth Data Day CONTROL 11.3%
22.6%
A B
C D
E F
G HI I
J K
L I
to
/0 /0 70 1
-I
_-t 1-rb r o t
I to IC) /1
/0 to0 10 10 10 IC )
O 10 2 1 ID0 I0) 1
(
/
t/o I(
IC)
/0/lo IC) 1(
1 2D 10 I
I0101
/1
/I 10
/0
/)O to o I 0 I'D (0
10 Ir 10 /0 lo
/0 b
to 10 1
0 lO (I
1 10
/0 1
I C) (0 IO 10 lb
(
lb Ij (t
IC)0
/0
/I (0
/0
/0 0
/0 t/ o
/to
/0/0 b
/0
/
/0
/0 A
Pan weight (mg)
Color identification:
iQI-440.JO 1NtL
-11 61.T j
1533LA N.4I.. 11L15 14l.o3 AI3 13.98 IL4S Analyst: L B = Pan + Larvae weight (mg)
Sl 1.4 22.70
-M ts.StSS) UAA Z Io.43 M4% zz lt.,x,% UA I Analyst:
L4" UM
.0 -L.J(.3 Larvae weight (mg)= A - B 8.ri6
&I O 11.58 & VS, 9.01 SaS ).13 1.q% 9.14 1711 1A3 r*63 I
Weight per initial number v
1, of larvae (mg)
,,O4 C / Initial number of larvae
- IN 1
V 0
b O
0' O'
b Average Percent weight per reduction 47
& 2-i 7.
initial from control O, 810
- 6. 81 0 number of
(%)
I larvae (m)
Comment codes: c - clear, d = dead, fg = fungus, k = killed, m = missing, sk sick, sm = unusually small, Ig = unusually large, d&r = decanted and returned, w = wounded.
I
~~~~~~~~~~~~~~~~~~~~~~~~~Calculation and data reviewed:
k Comments:
Page 31 of 10
Environmental Testing Solutions, Inc.
Page 3 of 6 Species: Pimephales promelas Client: TVA / Sequoyah Nuclear Plant - Non-treated Date: -'I-tIS-09 Survival and Growth Data Day 45.2%
72.6%
100%
M N
0 P
Q R
S T
U V
W X
1 0 10 Ito 1I 10 10 IU (to I t)
I (C
10 1
10 l0 to 10 (0
10 l
Q
/
to
/0
/
I0 2g iOl o
11 i
I /0
/O IC
/)
/0 3
r 3
)o 10 r0 1I I oIo
/0
- 0
'I
'0 JO 10
/0 o
10
/0
'I) 10
/Q.I-10
/0 I
5 10
/0
/0 U1 0
/0 'i JO
'f 1 I0
/0 7
1 ~~~Jo IC) 97 1
q
$qrgIq Iq
~/
A Pan weight (mg)
Color identification: %14AW*IQ 14.1 jL P1% its%
1I4.
IsxI 14.46 I'S 144-7lc i 1 lrL\\.0 15.0%O ISA1 L4..
Analyst: I
__SA_
A Pan Larvae weight (mg) rag4 v.
t4 IV )4.
)'4.ii J
Ii4.
I "9.
tsq i t4J Analyst:
MM Larvae weight (mg)= A - B I12 1-TL 1..2z S.C im I-At 17.
2 s-.1' A v11I.-
II R.13 e.-Z Weight per initial number
\\N of larvae (mg) 45 A
= C / Initial number of larvae l
A
(
b A '
1 0
0 o
l 0'
Average Percent weight per reduction initial from control O. 1 2
/0.)
- 0.
31 number of
(%)
larvae (g Comment codes: c = clear, d = dead, fg - fungus, k = killed, m = missing, sk = sick, sm = unusually small, Ig = unusually large, d&r = decanted and returned, w = wounded.
Calculations and data reviewed:
Comments:
5 eog\\
%&L PA-W46eWI, el`-Mh-e P4F14.
RWIN40WS _N T bleb I MAC e-FFL-0" 6"t iNTMOL W 9k AMIJILZAFc lA rU~et>
Page 32 of Id
Environmental Testing Solutions, Inc.
Page 4 of 6 Species: Pimephalespromelas Client: TVA / Sequoyah Nuclear Plant - Non-treated Date:
0'4-'S S6 Survival and Growth Data Day 100% Intake Y
Z AA BB 1
10
/0 I0
/0 I(0 fI 1
/O 3
/o__
to 4
5-kf r AIF Q 5
~~q 1ts k 410 5
I
~~~~~~~~~~~~S.SL~
AII G
5 5 3
A Pan weight (mg) r Color identification: 1iAW tA.
I tfL*
Analyst:-client B = Pan + Larvae weight (mg) zo.$& IBt-So MO 114-w Analyst: MMI Larvae weight (mg) = A - B
______________S.30 S. %S Weight per initial number of larvae (mg)
C / Initial number of larvae 40 t
I 0
0 Average Percent weight per reduction initial from control O.
number of
(%)
larvae (mg)
Comment codes: c = clear, d = dead, fg = fungus, k = killed, m = missing, sk sick, sm unusually small, Ig = unusually large, d&r decanted and returned, w = wounded.
Calculations and data reviewed:
Comments:
I Page 33 of 10
TVA / Sequoyah Nuclear Plant, Outfall 101 - Non-treated
- a April 15-22, 2008 Statistical Analyses (Il
.3,' Environmental Testing Solutions.inc.
Larval Fish Growth and Survival Test-7 Day Survival Start Date:
4/15/2008 Test ID:
PpFRCR Sample ID:
TVA /Sequoyah Nuclear Plant, Outfall 101 End Date:
4/22/2008 Lab ID:
ETS-Envir. Testing Sol.
Sample Type:
DMR-Discharge Monitoring Report Sample Date:
Protocol:
FWCHR-EPA-82 I -R-02-013 Test Species:
PP-Pimephales pronelas Comments:
Non-treated Conc-%
I 2
3 4
D-Control 1.0000 1.0000 1.0000 1.0000 11.3 1.0000 1.0000 1.0000 1.0000 22.6 1.0000 1.0000 1.0000 1.0000 45.2 1.0000 0.9000 0.9000 0.7000 72.6 1.0000 0.9000 0.8000 1.0000 100 0.9000 0.8000 1.0000 1.0000 Transform: Arosin Square Root Rank I-Tailed Number Total Conc-%
Mean N-Mean Mean Min Max CV%
N Sum Critical Resp Number D-Control 1.0000 1.0000 1.4120 1.4120 1.4120 0.000 4
0 40 11.3 1.0000 1.0000 1.4120 1.4120 1.4120 0.000 4
18,00 10.00 0
40 22.6 1.0000 1.0000 1.4120 1.4120 1.4120 0.000 4
18.00 10.00 0
40 45.2 0.8750 0.8750 1.2253 0.9912 1.4120 14.199 4
12.00 10.00 5
40 72.6 0.9250 0.9250 1.2951 1.1071 1.4120 11.347 4
14.00 10.00 3
40 100 0.9250 0.9250 1.2951 1.1071 1.4120 11.347 4
14.00 10.00 3
40 Auxiliary Tests Statistic Critical Skew Kurt Shapiro-Wilk's Test indicates non-normal distribution (p <= 0.01) 0.84818864 0.884
-0.6760745 1.16084056 Equality of variance cannot be confirmed Hypothesis Test (I-tail, 0.05)
NOEC LOEC ChV TU Steel's Many-One Rank Test 100
>100 1
Treatments vs 0-Control Maximur Likelihood-Prohit Parameter Value SE 95% Frducial Limits Control Cli-Sq Critical P-valse Mu Sigmna Iter Slope 1.27414145 0.56913392 0.15863894 2.38964395 0
6.59494317 7.81472778 0.09 2.94791372 0.78484222 7
Intercept 124394095 1.01467616
-0,7448244 3.23270626 TSCR Point Probits 95% Fidocial Limits ECOI 2.674 13.2463943 0.00037079 29.4709841 ECOS 3.355 45.3903092 4.83309592 86.1712267 ECIO 3.718 87.5181143 50.3972396 2287.3461 EC15 3.964 136.294103 75.7448833 67622.7886 EC2O 4.158 193.808963 96.3464778 1084316.72 EC25 4.326 262.147478 116.213218 11945654.9 EC40 4,747 561.146453 180.769874 485165095 EC50 5.000 886.979795 233.559799 485165195 EC60 5.253 1402.01051 300.726925 485165195 EC75 5.674 3001.10884 455.757808 485165195 EC8O 5.842 4059.32305 536.985968 485165195 EC85 6.036 5772.32087 649.794482 485165195 EC90 6.282 8989.37254 825.503063 485165195 EC95 6.645 17332.6195 1175.94644 485165195 EC99 7.326 59392.2837 2279.34489 485165195 sqn101_04-I5-O8dcta
TVA / Sequoyah Nuclear Plant, Outfall 101 - Non-treated April 15-22, 2008 Statistical Analyses Environmental TestingSolutions, Inc.
Larval Fish Growth and Survival Test-7 Day Growth Start Date:
4/15/2008 Test ID:
PpFRCR Sample ID:
TVA / Sequoyah Nuclear Plant, Outfall 101 End Date:
4/22/2008 Lab ID:
ETS-Envir. Testing Sol.
Sample Type:
DMR-Discharge Monitoring Report Sample Date:
Protocol:
FWCHR-EPA-821-R-02-013 Test Species:
PP-Pimephales promelas Comments:
Non-treated Conc-%
1 2
3 4
D-Control 0.8460 0.8100 0.7480 0.8350 11.3 0.8020 0.8250 0.8130 0.7980 22.6 0.8380 0.7120 0.7930 0.8630 45.2 0.8720 0,7220 0.7280 0.5910 72.6 0.7910 0.7420 0.6210 0.7730 100 0.7870 0.6170 0.8730 0.8250 Transform: Untransformed 1-Tailed Isotunic Conc-%
Mean N-Mean Mean Min Max CV%
N t-Stat Critical MSD Mean N-Mean D-Control 0.8098 1.0000 0.8098 0.7480 0.8460 5.414 4
0.8098 1.0000 11.3 0.8095 0.9997 0.8095 0.j980 0.8250 1.498 4
0.004 2.410 0.1355 0.8095 0.9997 22.6 0.8015 0.9898 0.8015 0.7120 0.8630 8.275 4
0.147 2.410 0.1355 0.8015 0.9898 45.2 0.7283 0.8994 0.7283 0,5910 0.8720 15.765 4
1.450 2.410 0.1355 0.7452 0.9202 72.6 0.7318 0.9037 0.7318 0.6210 0.7910 10,462 4
1.388 2.410 0.1355 0.7452 0.9202 100 0.7755 0.9577 0.7755 0.6170 0.8730 14.361 4
0.609 2.410 0.1355 0.7452 0.9202 Auxiliary Tests Statistic Critical Skew Kurt Shapiro-Wilk's Test indicates normal distribution (p > 0,01) 0.93530476 0.884
-0.5773312 0.65667479 Bartlett's Test indicates equal variances (p 0.06) 10.5668974 15.0862722 Hypothesis Test (I-tail, 0.05)
NOEC LOEC ChV TU MSDu MSDp MSB MSE F-Prob df' Dunnett's Test 100
>100 1
0.1354619 0.16728855 0.00571994 0.00631874 0.49915776 5, 18 Treatments vs D-Control Linear Interpolation (200 Resamples)
Point SD 95% CL(Exp)
Skew ICOS 35.533 ICIO
>100 IC1S
>100 1C20
>100 1C25
>100 IC40
>100 IC50
>100 sqn10]_04-15-08data
TVA Sequoyah Nuclear Plant, Intake - Non-treated April 15-22, 2008 o
~
Statistical Analyses Environmental Testing Solutions, Inc.
Larval Fish Growth and Survival Test-7 Day Survival Start Date:
4/15/2008 Test ID:
PpFRCR Sample ID:
TVA / Sequoyah Nuclear Plant, Intake End Date:
4/22/2008 Lab ID:
ETS-Envir. Testing Sol.
Sample Type:
DMR-Discharge Monitoring Report Sample Date:
Protocol:
FWCHR-EPA-821 -R-02-013 Test Species:
PP-Pimephales promelas Comments:
Non-treated Conc-%
1 2
3 4
D-Control 1.0000 1.0000 1.0000 1.0000 100 0.5000 0.5000 0.6000 0.3000 Transform: Arcsin Square Root 1-Tailed Conc-%
Mean N-Mean Mean Min Max CV%
N t-Stat Critical MSD D-Control 1.0000 1.0000 1.4120 1.4120 1.4120 0.000 4
- 100 0,4750 0.4750 0.7591 0.5796 0.8861 16.957 4
10.144 2.353 0.1515 Auxiliary Tests Statistic Critical Skew Kurt Shapiro-Wilk's Test indicates normal distribution (p > 0.01) 0.79137957 0.749
-1.1776705 3.92758425 Equality of variance cannot be confirmed
-ypothesis Test (1-tail, 0.05)
MSDu MSDp MSB MSE F-Prob df Heteroscedastic t Test indicates significant differences 0.06820701 0.0699559 0.852525 0.00828539 5.3E-05 1, 6 Treatments vs D-Control sqnl01_04-15-08daia
TVA I Sequoyah Nuclear Plant, Intake - Non-treated April 15-22, 2008 Statistical Analyses Environmental Testing Solutions, Inc.
Larval Fish Growth and Survival Test-7 Day Growth Start Date:
4/15/2008 Test ID:
PpFRCR Sample ID:
TVA / Sequoyah Nuclear Plant, Intake End Date:
4/22/2008 Lab ID:
ETS-Envir. Testing Sol.
Sample Type:
DMR-Discharge Monitoring Report Sample Date:
Protocol:
FWCHR-EPA-821-R-02-013 Test Species:
PP-Pimephales promelas Comments:
Non-treated Conc-%
1 2
3 4
D-Control 0.8460 0.8100 0.7480 0.8350 100 0.4390 0.5300 0.5250 0.2360 Transform: Untransformed 1-Tailed Isotonic Conc-%
Mean N-Mean Mean Min Max CV%
N t-Stat Critical MSD Mean N-Mean D-Control 0.8098 1.0000 0.8098 0,7480 0.8460 5.414 4
0.8098 1.0000
- 100 0.4325 0.5341 0.4325 0.2360 0.5300 31.791 4
5.228 1.943 0.1402 0.4325 0.5341 Auxiliary Tests Statistic Critical Skew Kurt Shapiro-Wilk's Test indicates normal distribution (p > 0.01) 0.87680268 0.749
-1.3643531 2.29151784 F-Test indicates equal variances (p = 0.09) 9.83858776 47.4672279 Hypothesis Test (1-tail, 0.05)
MSDu MSDp MSB MSE F-Prob df Homoscedastic t Test indicates significant differences 0.14021648 0.17316022 0.28463513 0.01041363 0.0019608 1, 6 Treatments vs D-Control Linear Interpolation (200 Resamples)
Point SD 95% CL(Exp)
Skew IC05*
10.732 1.627 5.191 17.900 0.1896 ICIO*
21.465 3.254 10.382 35.799 0.1896 IC15*
32.197 4.881 15.572 53.699 0.1896 1C20*
42.929 6.508 20.763 71,598 0.1896 1C25*
53.661 8.136 25.954 89.498 0.1896 1C40*
85.858 JC50
>100
- indicates IC estimate less than the lowest concentration sqn 10]_04-15-08data
TVA / Sequoyah Nuclear Plant, Outfall 101 - Non-treated April 15-22, 2008 Pimephalespromelas Chronic Whole Effluent Toxicity Test EPA-821-R-02-013, Method 1000.0 Quality Control Verification of Data Entry, Calculations, and Statistical Analyses Environmental Testing Solutions, Inc.
Project number:
3810 Reveiwed by:
Not for Compliance Assessment, Internal Laboratory QC Cuaccetraijue
(%()
RcylleRrte Ini itial-sb-r Fi. at numtarh f A P..eigt B= P v Larvae Larvweiight1mg)
WeightSuniviig Mean wcigbt I Oefficint nfvariatiua Weightlut/Iitiatnumber Mean sronival MWan neight I Cmrirut ufr Pefrcnt rItuetiur frui Alikae larvae (mg) ightlmg)
A-B nanmber oftael(mg)
Surviving umbro I ~0iniii pl o.nrvinn oflarvae (ing) h%)
Initial.naiber f
-'ariatlu iu=.,nu' COnl (%)
lrva.e (mg) lo-.,,i I.I 1%g))
lrvae hog)
A I0 10 15 8
2427 846 0.846 0846 Control a
1 10 1340 21.50 81t 0810 0.810 54 0810 108.0 8.818 5.4 Not applicable C
10 10 1422 2170 7.48 0148 0748 D
10 10 1477 23 12 835 0.835 0.835 E
10 10 1473 22.75 802 0802 0802 F
10 10 15 34 23.59 8.25 0.825 0 810 L5 0825 108.8 0.810 1.5 8.0 G
10 10 14.76 22.89 8.13 0813 0.813 N
10 10 12.45 2043 798 0.798 0798 8
10 10 14,03 22.41 8.38 0.838 0838 22.6%
3 10 10 15.13 22.25 7,12 0.712 0802 83 0.712 108.0 0.802 8.3 1.0 K
I0 10 13.98 2191 793 0.793 0793 L
10 tO 14.50 2313 8.63 0.863 0.863 M
10 10 14.12 22.84 8.72 0872 0872 4 5.2 N
10 9
1385 21.07 7.22 0.802 0.832 3.9 0722 45.2%
0832 39 87.5 0.728 15.8 10.1~~~~~~~~~~~~~~~~~~~
i 1.
0 10 9
13.51 2079 7.28 0809 0.728 P
10 7
1485 20.76 591 0.844 0591 10 10 1329 21.20 7.91 0791 0.791 72.60 R
lo 9
14.48 21 90 7.42 0824 0.791 30 0742 92.5 0.732 10.8 9.6 S
10 8
13 38 1959 6621 0.776 0.621 T
I0 tO 1479 2252 7.73 0.773 0.773 U
tO 9
14.30 22.17 7.87 0.874 0787 100%
V to 1506 21 23 6.17 0.771 0836 58 0617 92.5 0.776 14.4 4.2 W
10 10 15.92 2465 8.73 0.873 0873 X
10 10 14.19 22.44 8.25 0.825 0.825 Y
10 5
15.66 2005 439 0,878 0439 Z lo 5
1320~~~~~2 18 so 5.30
- 1.
069 0.53 100%lIntalue Z
10 5 ____AA 20 5.30 0900 128 0.530 47.5 0.433 31.8 46.6 AA 10
____6 15.24 2049 5.25 0875 0525 BB 10 3
14.24 1660 2.36 0787 1
1 0.236 Outfall 101 MSD =
Minimum Significant Difference Dannett's MSD salne:
0.1355 PMSD Percent Minimum Significant Difference PMSSD:
16.7 PMSD is a measure of test precision The PMSD in the minimum percent difference between the contrel and treatment that can be declared statistically significant in a whole efliuent tuuicity test Intake:
Du.nett's MSD value:
8.1402 Lower PMSD bound determined by USEPA(IOth percentile) = 12%.
PMSD:
17.3 Upper PMSD bound determined by USEPA (90th percentile) - 30%.
Lower and upper PMSD bounds were determined from the I0th and 90th percentile, respectively, of PMSD data from EPA's WET Interlaboratoiy Vat iability Study (USEPA, 2001u, USEPA, 200 1 b)
USEPA 2 0 0lu, 2001b. FinalRepert Inierlaboratory Variability Study ofEPAShort-term Chronicand Acute Whole EffluentToxicity TestMethods. Volumes i und2-Appendix EPA-821-B-01-004 andEPA-821-B-.01005. US Environnseotal Protectiun Ageicy, Ciocionati, OfI
Environmental Testing Solutions, Inc.
Page 5 of 6 Species: Pimephalespromelas Date:
0LA-IS00 Client: TVA / Sequoyah Nuclear Plant - Non-treated Daily Chemistry:
Day 0
2 A nalyst Concentration Parameter
-N CONTROL pH (SS.U.)
DO (mg/L) 1.4 Conductivity
((imhos/cm )2Iij 31 Iei~~i 2
Alkalinity 1
5
~iPi
\\
I iii ~
L I
11.3%
DO~~~~~(mgCa
/L)
V Hardness l
2.% D CaCO
(
L)
Temperature(0 C)
( Q W
.Q
-LA A0 21 Z.PC L
2.-.
4%H (S.mU.)
tt-.
I 1.8
-I -(A 3 11.3%
DO (mg/L)
'I.5 n.1 Conductivity 2I3 (prnhos/cm) 3 1030 Temperature(0 C)'Q 714.
2Le.t 2'4.
22.6%
DO(mg/L)
ConductivityI s~~iP
~
~
s Temperature ('Q
-Ls. O CL
- L \\*7 k
I ~ ~
~
52
___________________Q(75~
.8 1
.1 117.
pH (&.U.)
'I. (Z 7,k4 t
- oJ ra PO 3
, 3 72.6%
I DO (mg/L)
Conductivity
'aLO8s~8 LJI[i~~~Oi~iP 1
Temperature (C) pH(S. U.)
i I
I 7S 100%~
DO (mg/L) 1 7
7 Conductivity
((irhos/cra) it~Ba~
b
~
Z ~
Alkalinity (mg CaCO3/L) 3 i~~
s~~0
~
~
L Hardness (gCaCO3/L) to's I
I(0BJ1~$~~f
~
0 TR chlor' 40.1 Temperature ('C) ~15 - L-24
.(
\\4.3 I z,7
-c q
4 11 pH (S.U.)
-1.a 1c 7cS t*O 1753 it 100% Intake IDO(mg/lL)
X. 2 73
?q
- 1.
(7_
1 7 Conductivity
((imhos/cm) i LO S5I~~j (0
Alkalinity l
(mg CaCO3iZ)
Sz Hardness igiE d
(mg CaCO3/L)
Temperature('C) I7
\\
Z(
~
I~
l 2*C L*
c, Page 39of 105 7 Iitill Ii Fna n t a l B F a Initial-I Fia
3 Environmental Testing Solutions, fIn.
Page 6 of 6 Species: Pimephalespromelas Date:
0+-iS-OR Client: TXA I Sequoyah Nuclear Plant - Non-treated Day I
_______4 6
Analyst U4.6-Concen-Parameter tration CONTROL
_pH (S.U.)
- 1.
3 DO (mg/L)
Conductivity 320to 303 3
(pmhos/cm)
Alkalinity (Mg CaCO 3IL)
Hardness (mg CaCO 3/L) 4 Temperature( 0 C)
(
-4 cA
?A.
- u.
V4.
pH (S.U.)
I Io Tw 11.3%
DO (mg/L) 360 Io Conductivity
-600
(~Lmhos/crn)
Temperature c) 2'iQ V
v4-2L
'8
- 2.
2S.0 2'4.
.pH (S.U.)
SS 22.6%
DO (rngiL)
Conductivity
(~imho /cm)79 Temperature (0 C) 2V.
.5 VA
-l 2
'LI.q
-1.
L'LS Z'4S pH (S.U.)
1-l 45.2%
DO (mg/L)
Conductivity
- ZA4oI (pimho s/cm) 3 Temperature (0 C) 2A.4 t'4S LA.
2+
V3[
2U
.0 pH (S.U.)
'S 5
- 7.
-(A14t51 S
72.6%
DO (mg/L)
A Conductivity LI31 I
(p~~~~(~mhos/cm)
Temperature (0 C)
'AI*
'A4
- 24.
7JbS-,
pH (S. U.)
7*CI
,rNcl I
I 100%
DO ng/L 1.m Conductivity
_ nhrs/cm)
S Alkalinity 10% CaCO3/L)
Hardness d
I
~
~~~~~TR Chlorine (mg/L)
- e. 0. f--)
Z. Li 2j ztb Temperature ('Q
-M L-0*C y
'r~b2, p S.U.)
7 14
'I. W" 100%
DO (mg/L)
L/
pB ~
IntakeInae Conductivity P-el A
I
~
~~~~Alkalinity (mg C0/L)
Ss Hardness (mg CaCO3/L) 103 TR chlorine (mg/L)
<0a.10Em
~
F~
or Temperature(0 C)
(I A.k 7L'(
,o q
Z75.O 2q.
75 s I.5 Initial Initial Final Page 40 of 105 Cp ce C'l OS'T A IV
TVA I Sequoyah Nuclear Plant, Outfall 101 - Non-treated CD April 15-22, 2008 Pimephalespromelas Chronic Whole Effluent Toxicity Test EPA-821-R-02-013, Method 1000.0 Daily Chemical Analyses Environmental Testing Solutions, Inc.
Project number:
3810 Reviewed by:
Concentration Parameter D
Da 1Da 2
D 3
Da 4 Da 5
Da 6 Initial Final Initial Final Initial Final Initial Final Initial Final Initial Final Initial Fijial pH (SU) 7.92 7.51 7.49 7.54 7.70 7.41 7.86 7.53 7.83 7.33 7.97 7.52 7.69 7.18 DO (mg/L) 8.0 7.9 7.6 7.9 7.8 7.8 7.9 7.5 7.8 7.1 7.6 7.8 7.5 6.4 Conductivity (ftmhos/cm) 322 343 322 320 310 303 314 Control Alkalinity (mg/L CaCO,)
59 62 63 Hardness (mg/L CaCOA) 92 94 90 Temperature (QC) 24.8 24.6 24.6 24.8 24.7 24.6 24.7
- 24.
24.9 24.4 24.7 24.5 24.8 24.5 pH (SU) 7.66 7.52 7.84 7.53 7.63 7.39 7.58 7.51 7.70 7.30 7.60 7.53 7,61 7.70 11.3%
DO (mg/L) 7.9 7.7 7.9 7,9 7.5 7.7 7.9 7.6 8.0 6.8 7.6 7.7 76 6.6 Conductivity (1imhos/cm) 312
____3
______3_12
_____12_
300 290 299
_Temerature 24.9 24.4 24.7 24.7 24.7 24.6 24.7 24.4 24.9 24.2 24.8 24.7 25.0 24.5 pH (SU) 7.67 7.51 7.55 7.49 7.64 7.39 7.58 7.54 7.71 7.30 7.60 7.51 7.61 7.14 DO (mg/L) 7.9 7.7 7.8 7.9 7.6 7.6 7.8 7.7 8.0 6.8 7.6 7.7 76 6.4 22.6/
Conductivity (ihos/cm) 293 291 295 298 283 278 293 Temperature (oC) 25.0 24.5 24.7 24.7 24.8 24.4 24.8 24.5 24.9 24.2 24.8 24.3 25.0 24.5 pH (SU 7.64 7.50 7.54 7.45 7.63 7.36 7.57 7.52 7.7 7.30 7.56 7.47 7,58 703 DO (mg/L) 7.9 7.6 7.9 7.7 7.9 76.9 7.6 7.7 7.5 6.2 Conductivity (Itmhoslcm) 266 258 257 261 249 243 26)
Temperature (C) 25.0 24.5 24.7 24.6 24.8 24.6 24.8 24.5 24.9 24.2 24.9 24.6 25.0 24.5 pH (SU) 7.62 7.46 7.50 7.43 7.58 7.30 7.52 7.48 7.64 7.19 7.54 7.40 7.55 701 DO (mg/L) 8.0 7.6 7.9 7.8 7.8 7.6 7.9 7.6 7.9 6,9 7.6 7.6 7.5 59 72.6%
Conductivi mhos/cm 215 214 210 214 211 207 215 Temperature 'C) 25.0 24.5 24.8 24.7 24.8 24.7 24.8 24.3 24.9 24.4 24.9 24.6 25.1 24.5 PR (SU) 7.58 7.42 7.46 7.42 7.54 7.29 7.48 7.39 7.60 7.18 7.46 7.38 7.51 7.01 DO (mg/L) 8.1 7.5 7.8 7.8 7.8 7.8 7.9 7.5 7.9 6.9 7.7 7.61 7.6 6.4 Conductivity ('Imbos/cm) 169 167 167 169 167 166 172 100/
Alkalinity (mgIL CaCO3) 53 54 53 Hardness (mg/L CaCO3 )
65 61 65 Total Residual Chlorine (mg/L)
<0.10
<0.10 0.10
_Temperature CC) 25.2 24.3 24.9 24.7 24.9 24.5 24.8 24.7 25.0 24.4 24.9 24.6 25.1 245 pH (SU) 7.57 7.34 7.45 7.40 7.53 7.28 7.47 7.41 7.60 7.17 7.45 7.41 7.50 7.01 DO (mg/L) 8.2 7.3 7.9 7.8 7.9 7.8 8.0 7.6 8.0 6.8 7.8 7.8 7.6 6.5 Conductivity (mhos/cm) 162 165 168 167 168 16 172 100% Intake Alkalinity (mg/L CaCO 3) 52 54 55 Hardness (mg/L CaCO3) 57 65 63 Total Residual Chlorine (mg/L)
<0.10
<0.10
<0.10 Temperature (0C) 25.1 24.5
- 24.
24.9 24.9 24.5 24.8 24.6 25.0 24.4 25.0 24.6 25.1 24.5
Environmental Testing Solutions, Inc.
Page 1 of 7 I
Chronic Whole Effluent Toxicity Test (EPA-821-R-02-013 Method 1002.0)
Species: Ceriodaphnia dubia Client: TVA County: Hamilton Facility: Seguovah Nuclear Plant Treatment: Non-treated NPDES#: TN 0026450 Outfall: 101 Project#:
- 3&10 Dilution preparation information:
Comments:
Dilution prep (%)
11.3 22.6 45.2 72.6 100 Effluent volume (nL) 282.5 1130 1815 2500 Diluent volume (mL) 2217.5 1370 685 0
Total volume (mL) 2500 2500 2500 2500 2500 Test organism information:
Test information:
Organism age:
I4 L
jvzRo) OLD Randomizing template:
A)tZA'LQ.
Date and times organisms 4
Incubator number and 2
were born between:
o0-iSo* tr0o,-
10zcre shelf location:
Organism Source Cups: %
lb I
4 f I S1.91 1 lI/4C/'5 YCT batch:
03-1q-or Culture board: oq.OBAOCA eP
% I
?V '4 1. /
-I OR I0 Transfer bowl information:
pH = Thi1 Temperature = 2'.4.R Selenastrum batch:
O 2.'4. OR Daily rene wal information:
Day Date Test initiation, Control water Sample numbers Analyst renewal, or batch used used termination time 0
IkO c 0-n-of 0otq Ni oI 4-D I
~
~ ~~~~~~1 04 16-04 1 00q 0 4L0-Q1*t 04aq I q.
- 1.4 orz 2
o'i-r1-01 Ib2.
0+11-Oi
( pao4 1o. G 4 t%
J I4.t8.08 too I o0- a-A 4 0ct OJ IO 10E4 64*16*o&A 0p40q
.0% 40-.
A(
7 I
Control information:
1 2
Acceptance criteria Summary of test endpoints:
% of Male Adults:
674
- 01.
- 20%
7-day LC50
>O
% Adults having 3rd Broods:
Žr. 80%
NOEC I
% Mortality:
- 01.
- 07.
- 20%
LOEC
> 1007.
Mean Offspring/Female:
32.S 1
ŽP15.0 offspring/female ChV
> I 007.
% CV:
S7 t.7.
< 40.0 %
IC25
,007.
I Page 42 of 105
Environmental Testing Solutions, Inc.
Page 2 of 7 I
Species: Ceriodaphnia dubia Client: Secuoyah Nuclear Plant - Non-treated Date:
cP-iS-O3 CONTROL - 1 Survival and Reproduction Data Replicate number Day 1
2 3
4 5
6 7
8 9
10 I
Young produced O
n O
C) 0 Adult mortality t
U.
U v--
L-
`-
Adult mortality tL 3
Young produced [
O O
O 1
_C O
O
~~~~~~~Adult mortality L_
\\-
L 4
Young produced f
{
]5
{
'4 CU Adult mortality L
{ j
_____Ungproduced O
O 2 [
I I Adult mortality L-
\\-
U 6
Young produced I L ITW I
-Z 0
1 O
I
~
~~~~~~~~Adult mortality
\\_
VYoun_ \\--ce I
L-
\\-- 5 1
I i d I
Total young produced 3$ S 2
.3 32 3q 33 j2z 32-332.
Final Adult Mortality I-1-
U
'C7 U
U--
L-.-
Xfor 3 d Broods Y
iX X-
`--
Note: Adult mortality (L live, D = dead)
Concentration:
I% Mortality:
- 07i, Mean Offspring/Female:
62.s CONC: 11.3%
Survival and Reproduction Data Replicate number Dav 1
2 3
4 5
6 7
8 9
10 1
Young produced 0
O O
C O
Adult mortality L I-U 2
Youngproduce, C ) I n0
~
)0 0 Adult mortality L
L I
-II.
3 Young produced p
o I
~~~~~~~~Adult mortalilyIt 2
Young produced
'A Lkll 1
Adult mortality I,
sJ Young produced IOT O
L_
o[
1O 1
01 0
Adult mortality IJL-UI_
4 Young produced ITJ.
5 O
o c
iTt5 C)
O
_I Adult mortality U
L_
7 Young produced 10to
'oT 2o1s
-1 I
I Jo A___
I__
I_
Total young produced f3 W
J-?
- 2.
3 Z
1 33 31 1 Final Adult Mortality XI I Note: Adult mortality (L = live, D = dead)
Concentration:
% Mortality:
07.
Mean Offspring/Female:
3(.!&
% Reduction from Control:
-12.371 Page 43 of 105
Environmental Testing Solutions, Inc.
Page 3 of 7 Species: Ceriodaphnia dubia Client: Sejuoyah Nuclear Plant - Non-treated Date:
p I-0 CONC: 22.6%
Survival and Reproduction Data Replicate number Da 1
2 3
4 5
6 7
8 9
10 1
Young produced O
c Adult mortality L
j L
2 Young produced c]
T Adult mortality J
U j 3
Young produced 1
I I
I 5
1 I
Adult mortality L
4 Young produced Le Adult mortality Youngproduced lJ 0 L5 (t 0 [oTOoL+/- O
-I2__
Adult mortality
\\.-J\\--
6 Ica t R 20 D1 2
Young produced
{
0 "o
10
--FAoduult mortalityU U
U.
7 (Young produced Il i
L 20I~
SJ I1C Total young produced 33't Li 13' 6 3S 38
- 4.
'iLiI Final Adult Mortality I
IIT I
c-I L.
'.C L
Note: Adult mortality (L Ilive, D dead)
Concentration:
% Mortality:
01.
I Mean Offspring/Female:
38.1
% Reduction from Control:
- Iq. ii.
CONC: 45.2%
Survival and Reproduction Data Replicate number Day 3
4 5
6 7
8 9110 1
Young produced 1 7
I 0
0 OC OU
.O 0
C Adult mortality L-U L-L-..-
L.
2 Young produced 1
O o
C Adult mortality L-L-
Young produced 151 Cl
]o C)1 01 L
Adult mortality U-L 4
~Young produced 5EC\\1:15 L
Adult mortality L I L-Young produced t5 0
ub l o
of 0
I S I '
Adult mortality U
6
~ Young produced I
%41 1 0 1O nT 's '?
T O
Adult mortality
[
U L
4 I
~
~ ~~~~7 Young produced
(
(1 g
20 Is 2 C I
1 I 1 I 1
t Total young produced I
Final Adult Mortality L
I 7
UJ U E Note: Adult mortality (L = live, D = dead)
Concentration:
% Mortality:
7.
Mean Offspring/Female:
- 3i.0
% Reduction from Control:
-2o.07.
I Page 44 of 105
Environmental Testing Solutions, Inc.
Page 4 of 7 Species: Ceriodaphnia dubia Client: Seiuovah Nuclear Plant - Non-treated Date:
o%-,S-O, CONC: 72.6%
Survival and Reproduction Data Replicate number Day 1
2 3
4 5
6 7
8 9
10 I
Young produced O
c c
j
)
O C)
Adult mortality t
u
. 3 2
Young produced Cd O
0ool OrO O
O Adult mortality t-1 _
L-
_I, Young produced 1I o
COf CTCCIo1O Adult mortality Jt-I L-I_\\-
\\
4 Young produced r
O L
5 1 ~
Adult mortality 5 { Young produced 1[ I0_[ l I
Ii O I_ LS 19 Ito Adult mortality L-I L-I I
I L-IV?-
FLI 6
Young produced 0j
/{
tE Adltmotliy I
k--
7]
Young produced [
-l 1
61 4fZ.
IO ~I 'j, 21 I 2
9*
I Total young produced 30 fr 4 Z 3 Rg 3 LI 4q LI 38 Final Adult Mortality I
L-
-\\U7C C
Note: Adult mortality (L = live, D dead)
Concentration:
% Mortality:
07.
Mean Offspring/Female:
3'. to
%Reduction from Control: - 2.87I CONC: 100%
Survival and Reproduction Data Replicate number Day1 3
4 5
6 17 9
1 1
Young produced C
<1
)
Adult mortality 1
5 6
7 8
9 1
2 Young produced O
oiOlccLo
__)
Adult mortality L-L-
C[LIItU 4
3 Young produced QPO Adult mortality L -__
L L-5 r" Young produced [A O
f T
'4 1
Adult mortality J C
C Young produced O
x 1
LA
'3 o
0 C)
Adult mortality L
I
~~~~~6 Young produced
)
~
5O O
(
Adult mortality 7
Youngproduced 7
1
-22 1
-L Z29 )
It 1.I Total young produced L)3 3k ch o
t2 39 LI 1 39 qq FinalAduitMortality L
12?
L L
U L L
Note: Adult mortality (L = live, D = dead)
Concentration:
% Mortality:
7, Mean Offspring/Female:
'0-J
% Reduction from Control:
I Page 45 of 105
Environmental Testing Solutions, Inc.
Page 5 of 7 S
Species: Ceriodaphnia dubia Client: Secuovah Nuclear Plant - Non-treated Date:
oC4-$'--O CONTROL -2 Survival and Reproduction Data Replicate number Day 1
2 3
4 5
6 87 9
10 I
Young produced O
0 O
O o
O O
Adult mortality L
L U
s-U 2
AYoung producedl ctIJ l
\\. j6 Adult mortality 3
Young produced C
LIO ojO O
Adult mortality
[
Young produced L q
S II 1
Adult mortality [U
_L-L 61 Youngproduced o
T o
o 10 1
Os LQ Adult mortality Young produced O
L T I,
0 T
~~~~~~Adult~mortality C
Total young produced 2 )
353 31 a1 35 33 3
33 33 Final Adult Mortality I
L I
.I.._
Note: Adult mortality (L = live, D dead)
Concentration:
J
~~~~~~~~~~~~ ~~~~~~~~%
Mortality:
Iof Mean Offspng/Female:
3 I
CONC: 100% Intake Survival and Reproduction Data Replicate number Day 1
2 3
4 5
6 7
8 9
10
_Young produced Q
Adult mortality
\\-_L-L-
2 ] Young produced q 0 ]
0 Adult mortality I
L LL L.
L L-I 3
Young produced I
O Adult mortality ]-
i C -V C L U..
4 Young produced I.
LA lo o
o c T T___
Adult mortality II-5 Young produced j
L2 3 t I
Adult mortality X
I
~
~~~~~~~Young produced I L
O 0
)O 0
(0 1
Adult mortality C
I 7
Y~~~~~~~oung produced I
g
\\
Z I O t
)
I z o Total young produced
-41 4
-3 L4 3
3i q 2.
36 31 Final Adult Mortality 1
'Z C
I Note: Adult mortality (L = live, D = dead)
Concentration:
% Mortality:
7.
Mean Offspring/Female:
Jiw.
Reduction from Control:
- I&.O7.
Page 46 of 105
TVA Sequoyah Nuclear Plant, Outfall 101 April 15-22, 2008 Statistical Analyses Environmental Testing Solutions, Inc.
Ceriodaphnia Survival and Reproduction Test-Reproduction Start Date:
4/15/2008 Test ID:
CdFRCR Sample ID:
TVA / Sequoyah Nuclear Plant, Outfall 101 End Date:
4/22/2008 Lab ID:
ETS-Envir. Testing Sol.
Sample Type:
DMR-Discharge Monitoring Report Sample Date:
Protocol:
FWCHR-EPA-821-R-02-013 Test Species:
CD-Ceriodaphnia dubia Comments:
Non-treated Conc-%
1 2
3 4
5 6
7 8
9 10 D-Control 35.000 33.000 32,000 34.000 32.000 34.000 33.000 28.000 32.000 32.000 11.3 36.000 37.000 39.000 36.000 40.000 34.000 36.000 37.000 33.000 37.000 22.6 38.000 39.000 36.000 40.000 36.000 38.000 40.000 38.000 41.000 41.000 45.2 41.000 35,000 38.000 42.000 39.000 37.000 38.000 40.000 39.000 41.000 72.6 39.000 38.000 42.000 38.000 41.000 39.000 38.000 41.000 42.000 38.000 100 43.000 38.000 40.000 42.000 41.000 39.000 41.000 39.000 44.000 38.000 Transform: Untransformed 1-Tailed Isotonic Conc-%
Mean N-Mean Mean Min Max CV%
N t-Stat Critical MSD Mean N-Mean D-Control 32.500 1.0000 32.500 28.000 35.000 5.847 10 37.800 1.0000 11.3 36.500 1.1231 36.500 33.000 40.000 5.667 10
-4.579 2.287 1.997 37.800 1.0000 22.6 38.700 1.1908 38.700 36.000 41.000 4.726 10
-7.098 2.287 1.997 37.800 1.0000 45.2 39.000 1.2000 39.000 35.000 42.000 5.406 10
-7.442 2.287 1.997 37.800 1.0000 72.6 39.600 1.2185 39.600 38.000 42.000 4.325 10
-8.128 2.287 1.997 37.800 1.0000 100 40.500 1.2462 40.500 38.000 44.000 5.107 10
-9.159 2.287 1.997 37.800 1.0000 Auxiliary Tests Statistic Critical Skew Kurt Kolmogorov D Test indicates normal distribution (p > 0.01) 0.82764852 1.035
-0.188985
-0.4219705 Bartlett's Test indicates equal variances (p 0.99) 0.58125877 15.0862722 Hypothesis Test (1-tail, 0.05)
NOEC LOEC ChV TU MSDu MSDp MSB MSE F-Prob df Dunnett's Test 100
>100 1
1.99735188 0.06145698 85.12 3.81481481 4.7E.12 5, 54 Treatments vs D-Control Linear Interpolation (200 Resamples)
Point SD 95% CL Skew IC05
>100 ICIO
>100 IC15
>100 1C20
>100 1C25
>100 1C40
>100 IC50
>100 sqn]OI_04-lS-08data
TVA / Sequoyah Nuclear Plant, Intake 0 ~-~~ei April 15-22, 2008 Statistical Analyses Environmental Testing Solutions, Inc.
Ceriodaphnia Survival and Reproduction Test-Reproduction Start Date.
4/15/2008 Test ID:
CdFRCR Sample ID:
TVA / Sequoyah Nuclear Plant, Intake End Date:
4/22/2008 Lab ID:
ETS-Envir. Testing Sol.
Sample Type:
DMR-Discharge Monitoring Report Sample Date:
Protocol:
FWCHR-EPA-821 -R-02-013 Test Species:
CD-Ceriodaphnia dubia Comments:
Non-treated Conc-%
1 2
3 4
5 6
7 8
9 10 D-Control 33.000 33.000 33.000 37.000 31.000 35.000 33.000 32.000 33.000 33.000 100 41.000 40.000 39.000 41.000 39.000 39.000 42.000 37.000 36.000 39.000 Transform: Untransformed 1-Tailed Isotonic Conc-%
Mean N-Mean Mean Min Max CV%
N t-Stat Critical MSD Mean N-Mean D-Control 33.300 1.0000 33.300 31.000 37.000 4.914 10 36.300 1.0000 100 39.300 1.1802 39.300 36.000 42.000 4.653 10
-7.732 1.734 1.346 36.300 1.0000 Auxiliary Tests Statistic Critical Skew Kurt Shapiro-Wilk's Test indicates normal distribution (p > 0.01) 0.91478437 0.868 0.27528238 0.39658886 F-Test indicates equal variances (p = 0.75) 1.24896264 6.54108953 Hypothesis Test (1-tail, 0.05)
MSDu MSDp MSB MSE F-Prob df Homoscedastic t Test indicates no significant differences 1.34568502 0.04041096 180 3.01111111 4.OE-07 1, 18 Treatments vs D-Control Linear Interpolation (200 Resamples)
Point SD 95% CL Skew IC05
>100 ICIO
>100 IC15
>100 1C20
>100 tC25
>100 1C40
>100 1C50
>100 sqn]01_04-15-08data
TVA I Sequoyah Nuclear Plant, Outfall 101 April 15-22, 2008 41 Verification of Ceriodaphnia Reproduction Totals Environmental Testing Solutions. Inc.
Control-i 72.6%
Re licate number DRelicate number Day i
2 3
4 5
6 7
8 9
Ta 1
2 3
4 5
6 7
8 Total I
0 0
0 0
0 0
0 0
0 0
0 1
0 0
0 0
0 0
0 0
0 0
0 2
0 0
0 0
0 0
0 0
0 0
0 2 _
2 0
0 0
0 0
0 0
0 0
0 0
3 0
0 0
0 0
0 0
00 0
0 3 _
0 0
0 0
0 0
0 0
0 0
0 4
4 4
4 5
4 4
5 3
4 4
41 4
5 5
5 4
5 4
4 4
6 4
46 5
0 0
0 0
0 15 0
12 12 14 1 53 5
0 14 0
15 17 0
0 15 18 16 95 6
14 14 14 13 12 0
13 0
0 0
80 6
17 0
17 0
0 14 16 0
0 0
64 7
17 IS 14 16 16 15 15 13 16 14 151 7
17 19 20 19 19 21 18 22 18 18 191 Total 35 33 32 34 32 34 33 28 32 32 325 Total 39 38 42 38 41 39 38 41 42 381 396 11.3%
100%
Day R
licate number TDR icate number Total D
2 3
4 5
6 7
8 9
10 1
2 3
4 5
6 7
8 9
10 1
o0 0
0 0
0 0
0 0
0 0
0 1
0 0
0 0
0 0
0 0
0 0
0 2
0 0
0 0
0 0
0 0
00 0
2 0
0 0
0 000 0
00 0
3 0
0 0
0 0
0 0
0 00 0
3 00 0
0 0
0 0
0 00 0
4 4
6 4
4 4
4 5
5 4
4 44 4
5 5
4 5
4 4
4 6
6 5
48 5
0 0
15 15 17 13 0
14 13 14 101 5
0 0
0 0
17 16 16 14 16 15 94 6
16 15 0
0 0
0 15 0
0 0
46 6
17 14 18 15 0
0 0
0 0
0 64 7
16 16 20 17 19 17 16 18 16 19 174 7
1 21 1 19 18 22 1 20 19 21 19 22 18 199 Total 36 37 40 34 36 37 33 37 365 Total 143 38 40 42 41 39 41 39 44 38 405 22.6%
Control-2 Re licate number Replicate number Day 1
2 3
4 56789Total Day 1
2 3
4 56 7
8 9
10 Total 1
10 0
0 0
0 0
0 0
0 0
0 1
0 0
0 0
0 0
0 0
0 0
0 2
0 0
0 0
0 0
0 0
0 0
0 2
0 0
00 0
0 00 0
0 0
3 0
0 0
0 0
0 00 0
0 0
3 0
0 0
0 0
0 00 0
0 0
4 6
4 5
4 4
5 5
5 4
5 47 4
4 5
4 4
4 4
5 4
4 5
43 5
1 5
0 0
16 0
0 15 16 0
17 79 5
14 13 0
16 13 15 14 14 0
12 III 6
1 0 18 15 0
15 15 0
0 16 0
79 6
0 0
15 0
0 0
0 0
15 0
30 7
1 7 17 16 20 17 18 20 17 21 19 182 7
15 15 14 17 14 16 1 14 14 14 16 149 Total 138 39 36 40 36 38 40 38 41 41 387 Total 33 33 33 37 31 35 33 32 33 33 333 45.2%
100% Intake Day Replicate number Daylicate numberotal Dy 1 21314 5
6 7
8 9
TtalDa 112 3
4 5
6 7
8
-9 Total 1
0 0
0 0
0 0
0 0
0 0
0 t
0 0
0 0
0 0
0 0 1 0 0
2 0 0 0
0 0
0 0
0 0
0 0
2 0
00 0
0 0
0 0
0 3
0 0
0 0
0 0
0 0
0 0
0 3
0 0
0 0
0 0
0 0
0 0
0 4
5 4
4 5
6 4
4 4
5 5
46 4
6 4
4 5
5 5
5 4
5 4
47 5
15 0
16 0
0 0
0 17 15 14 77 5
17 15 0
14 15 15 16 13 0
15 120 6
1 0 14 0
17 15 13 17 0
0 0
76 6
0 0
17 0
0 0
0 0
13 0
30 7
21 17 18 20 18 20 17 19 19 22 191 1
]
7 18 21 18 22 19 19 21 20 18 20 196 Total 41 35 38 42 39 37 38 40 39 41 390 Total 1 411 40 39 41 39 39 42 37 36 39 393
TVA I Sequoyah Nuclear Plant, Outfall 101 April 15-22, 2008 0
Ceriodaphnia dubia Chronic Whole Effluent Toxicity Test EPA-821-R-02-013, Method 1002.0 i- -*
Quality Control Verification of Data Entry, Calculations, and Statistical Analyses Environmental Testing Solutions, Inc.
Project number:
3810 Reveiwed by:
Concentration Replicate number Survival Average reproduction eiient of Percent reduction from
(%)
1 2
3 4
5 6
7 8
9 10
(/)
(offspring/female) variation 1%)
pooled controls (%)
Control - 1 35 33 32 34 32 34 33 28 32 32 100 32.5 5.8 Not applicable 11.3%
36 37 39 36 40 34 36 37 33 37 100 36.5 5.7
-12.3 22.6%
38 39 36 40 36 38 40 38 41 41 100 38.7 4.7
-19.1 45.2/
41 35 38 42 39 37 38 40 39 41 100 39.0 5.4
-20.0 72.6%
39 38 42 38 41 39 38 41 42 38 100 39.6 4.3
-21.8 100%
43 38 40 42 4]
39 41 39 44 38 100 40.5 5.1
-24.6 Control - 2 33 33 33 37 31 35 33 32 33 33 100 33.3 4.9 Not applicable 100% Intake 41 40 39 41 39 39 42 37 36 39 100 39.3 4.7
-18.0
)utfali 101:
MSD =
Minimum Significant Difference
)unnett's MSD value:
1.997 PMSD Percent Minimum Significant Difference
'MSD:
6.1 PMSD is a measure of test precision. The PMSD is the minimum percent difference between the control and treatment that can be declared statistically significant in a whole effluent toxicity test.
ntake:
)unnett's MSD value:
1.346 Lower PMSD bound determined by USEPA (1 0 t percentile) = 13%.
'MSD:
4.0 Upper PMSD bound determined by USEPA (90tl percentile) = 47%.
Lower and upper PMSD bounds were determined from the 10th and 90th percentile, respectively, of PMSD data from EPA's WET Interlaboratory Variability Study (USEPA, 2001 a; USEPA, 2001b).
JSEPA. 2000. Understanding and Accounting for Method Variability in Whole Effluent Toxicity Applications Under the National Pollutant Discharge Elimination Program. EPA-833-R-00-003. US Environmental Protectiois igency, Cincinnati, OH.
ISEPA. 2001a, 200b. Final Report: Interlaboratory Variability Study of EPA Short-term Chronic and Acute Whole Effluent Toxicity Test Methods, Volumes 1 and 2-Appendix. EPA-821-B-0l-004 and EPA-82 1 -B-01-005. US onvironmental Protection Agency, Cincinnati. OH.
Environmental Testing Solutions, Inc.
Page 6 of 7 Species: Ceriodaphnia dubia Date: ____is_-O_
Client: Secuovah Nuclear Plant - Non-treated Daily Chem istry:__
Dai~~~~~~~~~~~~~~~a i
O Da1~~~~~~~~~~~~~~~~~
1 2
Analyst A
Concentration Parameter CONTROL pH (S.U.)
-AL DO (mg/L)
Conductivity (jtmhos/cm)
Alkalinity (mg CaCO3/L)
Hardness (mg CaCO3/i)\\
TemTperature (OC)
L q.,I
-r
-I (I'LA 4 1
7 q 1 pH (S.U.)
I
. wo 1 VA I -(A 3 11.3%
DO (mg/L)
Conductivity s.3 2..-
(Lmhos/cm)
Temperature(0 C) 1/4.
M'4.1 1 A
2M.
1.4k pH (S.U.)
1.10 22.6%
DO(mglL) 1-iA 9l
- i.
1.7 Conductivity Z 3 (4.mhos/cm)
- o Temperature ('C) 1 1 4.
pH(S.U.)
I-1o6 4.L1 3
14 45.2%
DO (mg/L)
Conductivity (gmrho s/cm)
T 2`
Temperature (C)
- tq.
re pH (S.U.)
Wi-
'151.
-)- S1o 72.6%
DO (mg/L) p 0 n A 1.
Conductivity
' IS
-Z 4 (imhos/cm Temperature (C) 1.4.
1, 0 pH(S.U.)
1.S 1*54 '
100%
DO (mg/L) 4 7.
Conductivity 6
1 (jirmhos/cm)
Alkalinity (mg CaCO,/L) 5 Hardness (mg CaCO3fL)
Temperature( 0C)
(QL' 4
i ZSZ. I pH (S.U.)
I1 1.'.I 1.43 1.41
- 1.
".4 100% Intake DO (mg/L) 7A Conductivity 162.
(imhos/cm)
Alkalinity (mg CaCO 3/L)
Hardness (mg CaCO3fL)
-1 (I
Temperature (QC) 2Aj 6
2 LS I
2S. I 7 7 Page 51 of 105 Initial Final Initial Final
5 Environmental Testing Solutions, Inc.
Page7 of7 Species: Ceriodaphnia dubia S
Client: Se uovah Nuclear Plant - Non-treated Date:
____- _s___O_
Anlyt m
043 64LA W
I' Concen-Parameter tration 1
I CONTROL HJ(S(U.)O Conductivity 3C Alkalinity (mg CaCO3 /L Hardness (mg CaCO 3/L)
Temperature (OC)
L
.7
-i
~
AA.
2'4.
11.3%
DO (mg[L) 0 Conductivity 3 12.
(jimhos/cm)
A
'ta Temperature (C)
-,A.E isO Its.O 5*0 1.I iS.0 i.S.
pH (S.U.m)
SE h7. 0
.+
22.6%
DO(mg/L)
I 8
(pnmhos/cm)
Temperature (0) 2AL&
?A.
L$.O L1 15.0 1A8 PR (S.U:)
I 17*0 i*,r'7
~Z I
45,2%
DO (mg/L)
C3onductivityac9 s~Zb
~~~~~Temperature (TC) rL*
tZ)qIUO
) ~
I1S.0 SS -0125*
'3, 726 H (S.U.)
7S 3SLS~
72.6%
DO amgiL)
I
~
~~~~~Temperature (oC) 9L(4
-S~
I1'
)~2*
5*
~
S
'LS I
pH (S. U,)
9-4
.10
',3 100%
DO (mg/L)
'I
(~imhos/cm)
,r 72 Alkalinity (m CaCo,/L 5
Hardness (m CaCO,/L) 1
~
~~~TR Chlorine (mg/L 4 aj~jt~~~FBB; 0(
Tmerature (TC)
'14 U -I ZS t28 S.0 L -
Z-pH S.U.)
- 7.
1
- 1. 3 k*L(
c\\'
- SD In0k DO(mg/L)
- 8.
(~-
-1.Io
'Thea Page52fIntake 1 Alkalinity Hardness (m CaCO3IL) 6 TR chlorin
< O. lo 1
I ~
~
~~~~
Temperature (oC) 2.q, C 7-S 0.
- ~8 L*
I trItS Z~
I Page 52 of 105ia Final Initial Final Initial Final Initial ia
TVA / Sequoyah Nuclear Plant, Outfall 101 - Non-treated April 15-22, 2008 Ceriodaphnia dubia Chronic Whole Effluent Toxicity Test EPA-821-R-02-013, Method 1002.0 Daily Chemical Analyses Project number-3810 Environmental Testing Solutions, Inc.
Pjtmr3 Reviewed by:
Concentration Parameter Da 0 D
I Da 2 Da 3 Da 4Da 5
Da 6 Initial Final Initial Final Initial Final Initial Final Initial Final Initial Final initial Final pH (SU) 7.92 7.45 7.49 7.60 7.70 7.54 7.86 7.70 7.83 7.59 7.97 7.59 7.69 7.57 DO (mg/L) 8.0 7.9 7.6 7.6 7.8 7.9 7.9 7.8 7.5 7.6 7.6 7.5 7.4 Conductivity (Anhos/cm) 322 343 322 320 310 303 314 Control Alkalinity (mgIL CaCO3) 59 62 63 Hardness (mgIL CaCO3) 92 90 Temperature (0C) 24.7 24.7 24.7 24.9 24.7 24.6 24:7 25.0 24.8 24.8 24.8 24.6 24.9 24.8 H (SU) 7.66 7.46 7.54 7.59 7.63 7.53 7.58 7.67 7.70 7.59 7.60 7.57 7.61 7.57 DO (mgIL) 7.9 7.8 7.9 7.7 7.5 7.9 7.9 7.8 8.0 7.5 7.6 7.4 7.6 7.4 Conductivity (Amhos/cm) 312 309 312 312 300 290 299
_Temperature CC) 24.8 24.9 24.8 25.1 24.9 24.8 24.8 25.0 25.0 24.8 25.0 24.9 25.0 25.0 pH (SU) 7.67 7.42 7.55 7.57 7.64 7.52 7.58 7.63 7.71 7.56 7.60 7.57 7.61 7.50 DO (mg/L) 7.9 7.9 7.8 7.7 7.6 7.9 7.8 7.8 8,0 7.5 7.6 7.5 7.6 7.4 Conductivity (tmhos/em) 293 291 295 298 283 278 293 Temperature (C) 24.8 24.9 24.8 25.0 24.9 24.8 24.8 24.8 25.0 24.7 25.0 24.8 25.0 25.1 p1I (SL) 7.64 7.42 7.54 7.53 7.63 7.49 7.57 7.62 7.70 7.56 7.56 7.53 7.58 7.50 4 DO (mg/L) 7.9 7.9 7.9 7.7 7.7 8.0 7.9 7.8 7.9 7.5 7.6 7.6 7.5 7.5 Conductivity (
oImhos/cm) 266 258 257 261 249 243 260 Temperature (CC) 24.8 24.8 24.9 25.0 24.9 24.8 24.9 25.0 24.9 25.0 24.8 25.0 25.1 pH (SU) 7.62 7.38 7.50 7.51 7.58 7.45 7.52 7.56 7.64 7.49 7.54 7.50 7 55 7.48 DO nmg/L) 8.0 7.9 7.9 7.8 7,8 7.9 7.9 7.8 7.9 7.5 7.6 7.6 7.5 7.4 72.60/
Conductivity (~tmhos/cm) 215 214 210 214 211 207 215 Temperature (0 C) 24.9 25.0 24.8 24.7 25.0 24.7 24.9 25.1 25.1 24.9 25.1 24.9 25.0 25.0 pH (SU) 7.58 7.36 7.46 7.47 7.54 7.41 7.48 7.54 7.60 7.44 7.46 7.44 7.51 7.46 DO (mg/L) 8.1 7.8 7.8 7.9 7.8 7.8 7.9 7.8 7.9 7.5 7.7 7.7 7.6 7.6 Conductivity (g scm) 169 167 167 169 167 166 172 100%
Alkalinity (mgIL CaCO3) 53 54 53 Hardness (mg/L CaCO3) 65 61 65 Total Residual Chlorine (mg/L)
<0.10
<0.10
<0.10 Temperature (C) 24.9 24.9 24.8 25.1 25.1 24.9 24.9 24.8 25A1 24.9 25.1 24.8 25.0 25.2 H (SU) 7.57 7.42 7.45 7.47 7.53 7,43 7.47 7.55 7.60 7.46 7.45 7.42 7.50 7.46 DO (mg/L) 8.2 7.6 7 7.
7.8 7.9 8.1 8.0 7.6 8.0 7.7 7.8 7.8 7.6 7.6 Conductivity (mhoscm) 162 165 168 167 168 165 172 100% Intake Alkalinity (mgIL CaCO3) 52 54 Hardness (mgIL CaCO3) 57 65 63 Total Residual Chlorine mL
<0.10 0.10
<0.10
_ Temperature CC) 24.9 24.9 24,8 25,0 25.1 24.9 24.9 24.9 25.0 24.8 25.1 24.8 25.0 24.9
Environmental Testing Solutions, Inc.
Page I of 6 Chronic Whole Effluent Toxicity Test (EPA-821-R-02-013 Method 1000.0)
Species: Pimephalespromelas Client: TVA County: Hamilton Facility: Secuoyah Nuclear Plant Treatment: UV-treated NPDES #: TN 0026450 Outfall: 101 Project #:
3810 Dilution re arion in ormaion:
Comments:
Dilution prep (%)
11.3 22.6 45.2 72.6 100 Each concentration was treated Effluent volume (mL) 282.5 1130 1815 2500 for 2 minutes with a UV sterilizer Diluent volume (mL) 2217.5 1370 685 0
to remove pathogenic Total volume (mL) 2500 2500 2500 2500 2500 interferences.
Test organism information:
Test information:
Organis age:
I. is A4o.as Randomizing template:
_LL Date-and times organisms 04-IcA- 09 1koo Incubator number:
5.
were born between:
Organism source:
ATOA. e,*c" Pe O4-1408 Artemia lot number:
B6 o'4'/
Transfer bowl information:
pH =
Temperature Cc Total drying time:
7.8q 2~~~~*
1 Z Date / Time in: OA I0 Average transfer volume:
Date / Time out: o'AZ.
i
- 8. ~
Oven temperature:
Dailyfeeding and renewal information:
Day Date Morning Afternoon Test initiation, MHS Sample numbers Analyst feeding feeding time renewal, or batch used used jr4- -*OQ time termination time 0
0q.
1ot
-'k1131 OA-cn-ae oaq t i. cl'o ti-08 6'OO e12o 4cA -of
- Ii?
o 4 "-
I 2~~~~~~+l08
(~
o)i-i 04-13-0P f Os OA 1.%' -k-I 3____ oA i
1 0 25 04-ob____0_o3 04l4 16 A
4 a
0A oeoo 1q4 QL%-%*bb4 0
(-o.A Io
\\
o04 rO-06 050
)oo'L-1 A-16tA Contro inI raio Actn crierav-Sut ar i
o f test endpois 7
04--n-ov I
3 Ai Control information:
Acceptance criteria Summar of t t edpints:
% Mortalit:
7<
20%
7-day LC50
> loc7, Average weight per initial larvae:
ROC.
NOEC 100 7.
Average weight per surviving larvae:
- 0.
0o(
Ž 025 mg/larvae LOEC
> too!
ChV IC25
> oo7, Page 54 of 105
I Environmental Testing Solutions, Inc.
Page 2 of 6 II Species: Pimephalespromelas Date:
O 0qrS_0p Client: TVA I Sequoyah Nuclear Plant - UV-treated I
Survival and Growth Data Day CONTROL 11.3%
22.6%
A B
C D
E F
G H
I J
K L
Io t o I
o to Io LQ 10 t0o l0 IO Io 2 ~
I~1 10 to IM C
r (0 lo I 0 to I /
10 IC t 3 ~
1 0 /I o
I 0 1 ()
I(
r
/ (
/D rg r0 1(
I I
~~~~~~~
1
' 10 lo to lo
/0 lo 10 10 10 r
0 10 to
/6
/0 el
/6)
/6 b
/6
/0
/0 b
/
7 ISA 10 I___
I (0(0(0 10 (0
o
/O 10(0 I
A Panweiht (gColor identification:
INd
)C(~~
P 150 3 15*1
/0
/0 14.66 (0 S1 1-4 01 04.1 /033 1 5-93 0
/0 A J41.,01 Analyst:
hCA M A = Pan + Larvae weight An)alyst:
I-12S VS,%t3 1t1 ZZ ThIO zi.'4J J Zl3 ?_'V4 ZoA' rz.4 xI. I Larvae weight (mg) = A - B
,~~r, IL.71I-at IM IA2 e-4118.b.r(Q 1.911a\\~ I*2Igco Igo Weight per initial number gO oflarvae(mg)
'O A,'
1 3
qp C/Initial number of larvae
\\6 c
- t.
b b'
0'o b
~
o Average Percent weight per reduction initial from control 0
.11 number of
(%)
larvae (mg)
Comment codes: c = clear, d = dead, fg fungus, k = killed, mr missing, sk = sick, sm unusually small, Ig = unusually large, d&r = decanted and returned, w = wounded.
i Calculations and data reviewed:
Comments/-
I Page 55 of 1
Environmental Testing Solutions, Inc.
Page 3 of 6 Species: Pimeplalespromelas I
Client: TVA i Sequoyah Nuclear Plant - UV-treated Date:
o 4-IS ot Survival and Growth Data Day 45.2%
72.6%
100%
M N
0 P
Q R
S T
U V
W X
I I
0 (0(010
'c r
/Ob
/010101010 O
r 0
to r
lo
/O to
/ O IC) I o 0
I 1
2~~~~~~~~
/t0 10 1t0 10 10 rOIQ
/0 10 1
13 10 JO 1
u I o 0 r I C I C o 1
(
rg IC) I r I
I Ih
/~~~2 IO
/o IC)
I 0
r0 O
r0 h
)
I Q 0
0 1
rg I O I 0 1 C O
C) 0 to I
I
__t
_It O
/0 I0
/
/O
/3
/O I 0 I
/0
/0 A Pan weight (mg)
Colo identification:
- 1.
1j3615 HI c=
IlC IL.Ll.t,\\
lrQS)B Analyst:
A B = Pan + Larvae weight (mg)I'M ol M
zs Zso4
.i.4A Z
Analyst:
~
L Larvae weight (mg) = A - B Weight per initial number
/i' of larvae (mg) 4 0%
V B
X
= C / Initial number of larvae 4'
Average Percent weight per reduction
-'o7 initial from control d. g'J
-33*0.
- 0. t28
-Lt number of
(%)
larvae m Comment codes: c = clear, d = dead, fg fungus, k = killed, m = missing, sk sick, sm = unusually small, Ig = unusually large, d&r = decanted and returned, w wounded.
I
,Calculationsanddatareviewed Comments:
I Page 56 of 10
Environmental Testing Solutions, Inc.
Page 4 of 6 Species: Pinephalespromelas Client: TVA / Sequoyah Nuclear Plant - UV-treated Date:
I'-
iS-R Survival and Growth Data Day 100% Intake Y
Z AA BB Io
- I0 2
I
~~~~~~~~/0
/0 /0 /C 10 10
(
10
/O t0
/O
/0 4
tro to to
/O 7
/0 (1l
/0 10 A
Pan weight (mg) b Color identification:
M plrpk l
ii 1 141S 15.'41 Analyst:
B = Pan + Larvae weight (mg)s~.7It~j z)I Analyst:
Larvae weight (mg) = A - B Weight per initial number k
of larvae (mg) co
= C / Initial number of larvae Average Percent weight per reduction
\\ @7 initial from control
- 0. R&4 1 number of
(%)
larvae (mg)
Comment codes: c clear, d = dead, fg = fungus, k = killed, m = missing, sk = sick, sm = unusually small, Ig = unusually large, d&r = decanted and returned, w = wounded.
Calculations and data reviewed:
4 Comments:
I Page 57 of 10
TVA / Sequoyah Nuclear Plant, Outfall 101 - UV-treated April 15-22, 2008 Statistical Analyses Environmental Testing Solutions, Inc.
Larval Fish Growth and Survival Test-7 Day Growth Start Date:
4/15/2008 Test ID:
PpFRCR Sanple ID:
TVA/Sequoyah Nuclear Plant, Outfall 101 End Date:
4/22/2008 Lab ID:
ETS-Envir. Testing Sol.
Sample Type:
DMR-Discharge Monitoring Report Sample Date:
Protocol:
FWCIIR-EPA-821-R-02-013 Test Species:
PP-Pimephales promelas Comments:
UV-treated Conc-%
1 2
3 4
D-Control 0.8660 0.6720 0.8380 0.8470 11.3 0.7920 0.8670 0.7430 0.7870 22.6 0.8410 0.6820 0.8400 0.8080 45.2 0.9120 0.8330 0.7090 0.8670 72.6 0.7850 0.8090 0.8120 0,8880 100 0.7670 0.8100 0.8040 0.7760 Transform: Untransformed 1-Tailed Isotonic Conc-%
Mean N-Mean Mean Min Max CV%
N t-Stat Critical MSD Mean N-Mean D-Control 0.8058 1.0000 0.8058 0.6720 0.8660 11.161 4
0.8099 1.0000 11.3 0.7973 0.9895 0.7973 0.7430 0.8670 6.453 4
0.181 2.410 0.1131 0.8099 1,0000 22.6 0.7928 0.9839 0.7928 0.6820 0.8410 9.512 4
0.277 2.410 0.1131 0.8099 1.0000 45.2 0.8303 1.0304 0.8303 0.7090 0.9120 10.487 4
-0.522 2.410 0.1131 0.8099 1.0000 72.6 0.8235 1.0220 0.8235 0.7850 0.8880 5.424 4
-0.378 2.410 0.1131 0.8099 1.0000 100 0.7893 0.9795 0.7893 0.7670 0.8100 2.656 4
0.352 2.410 0.1131 0.7893 0.9745 Auxiliary Tests Statistic Critical Skew Kurt Shapiro-Wilk's Test indicates normal distribution (p > 0.01) 0.9139455 0.884
-0.9393307 0.42655275 Bartlett's Test indicates equal variances (p 0.32) 5.84704399 15.0862722 Hypothesis Test (1-tail, 0.05)
NOEC LOEC ChV TU MSDu MSDp MSB MSE F-Prob df Dunnett's Test 100
>100 1
0.11311518 0.14038496 0.00114064 0.00440593 0.92965513 5, 18 Treatments vs D-Control Linear Interpolation (200 Resamples)
Point SD 95% CL(Exp)
Skew ICO0
>100 IClO
>100 IC15
>100 1C20
>100 1C25
>100 1C40
>100 IC50
>100 sqnl 01__04-J15-O8data-uv
TVA / Sequoyah Nuclear Plant, Intake - UV-treated April 15-22, 2008 Statistical Analyses Ul i--:-
pil1-2,20 Environmental Testing Solutions. Inc.
Larval Fish Growth and Survival Test-7 Day Growth Start Date:
4/15/2008 Test ID:
PpFRCR Sample ID:
TVA / Sequoyah Nuclear Plant, Intake End Date:
4/22/2008 Lab ID:
ETS-Envir. Testing Sol.
Sample Type:
DMR-Discharge Monitoring Report Sample Date:
Protocol:
FWCHR-EPA-821 -R-02-013 Test Species:
PP-Pimephales promelas Comments:
UV-treated Conc-%
1 2
3 4
D-Control 0.8660 0.6720 0.8380 0.8470 100 0.8710 0.7700 0.8780 0.8690 Transform: Untransformed 1-Tailed Isotonic Conc-%
Mean N-Mean Mean Min Max CV%
N t-Stat Critical MSD Mean N-Mean D-Control 0.8058 1.0000 0.8058 0.6720 0.8660 11.161 4
0.8264 1.0000 100 0.8470 1.0512 0.8470 0.7700 0.8780 6.078 4
-0.796 1.943 0,1007 0.8264 1.0000 Auxiliary Tests Statistic Critical Skew Kurt Shapiro-Wilk's Test indicates normal distribution (p > 0.01) 0.76526457 0.749
-1.5087627 1.15292051 F-Test indicates equal variances (p = 0.38) 3.05166674 47.4672279 Hypothesis Test (1-tail, 0.05)
MSDu MSDp MSB MSE F-Prob df Homoscedastic t Test indicates no significant differences 0.10067529 0.12494607 0.00340313 0.00536846 0.45626166 1, 6 Treatments vs D-Control Linear Interpolation (200 Resamples)
Point SD 95% CL(Exp)
Skew 1C05
>100 IC10
>100 IC15
>100 1C20
>100 1C25
>100 IC40
>100 1C50
>100 sqn 101_04-15-O8data-uv
TVA / Sequoyah Nuclear Plant, Outfall 101 - UV-treated April 15-22, 2008 0
0 Pimephalespromelas Chronic Whole Effluent Toxicity Test EPA-821-R-02-013, Method 1000.0 Quality Control Verification of Data Entry, Calculations, and Statistical Analyses Environmental Testing Solutions, Inc.
Project nouober:
3810 Reveiwed by:
Not for Complionce Assessment, Internal Loboratory QC CoiCetrotius (%)
Repiite I.intial Fomb ir sa! somber of A = Pno -eight B Pao I Lor-Larva night (mg) Weight suriviag Moon. cight Cofficientoforiati-Wigt / Isiti1l numlber Meao sr-isot M.An iseighI Ci ewirst
,f Pccot redtlimno fio t-rvc I rv(e 1mg) scigbt(mg)
-A-B number ofblrie(mgl Srsnivi.gaumber of r m e,""n.
ofto-slemg
(%(
m)itifi umxber of variatioo sisir lange (gl) 0 I%'
Jar(%l taCo (.lo) rmowoL I
A 10 10 14.64 23.30 866 0866 0.866 Controt B
I0 10 1533 2205 6.72 0,672 0.806 11.2 0673 100.0 0.806 11.2 Not applicoble C
10 10 1517 23.55 838 0838 0.838 D
I 10 1482 2329 8.47 0847 0.847 E
10 10 14.88 2280 7.92 0.792 0.792 11.3%
F t0 10 1451 2318 8.67 0.867 0.797 6.5 0867 108.0 0.797 6,8 1.1 G
10 10 1401 21 44 743 0743 0.743 H
10 10 1446 22.33 7,87 0.787 0787 I
10 10 14.33 22.74 841 0.841 0.041 22.6%
J 10 10 13.83 2065 6.82 0682 0793 95 0682 180.0 0.793 9.8 1.6 K
10 10 14.54 2294 8,40 0840 0840 L
10 10 13.03 21.11 8.08 0.808 1
0.808 M
to 10 15.89 2501 9.12 0.912 0.912 N
10 10 1476 2309 833 0833 0830 05 0833 180.8 0.830 18,5
.3.0 45.2%
0.5.J.
o 10 10 15.38 22.47 709 0.709 0.709 P
10 10 13.35 22.02 8.67 0867 0867 Q
to 10 1511 22.96 7.85 0.785 0.785 72.6%
R 10 10 14.22 22.31 8.09 0.809 0824 54 0.809 180.8 0.824 5.4
-2.2 O
10 10 1441 22.53 8.12 0.812 0.812 T
10 10 14.16 23.04 888 0888 0.888 U
10 10 1402 2169 7.67 0.767 0.767 100%
V IS tO 13 II 21.21 8)0 0810 0.789 27 08)0o100.0 0.789 2.7 2.0 W
10 10 14 93 22.97 8.04 0.804 0804 X
10 10 1286 20.62 776 0776 0776 Y
IO 10 1427 22.98 871 0.871 0871 1800/ Intake 10 1407 21 77 7.70 0.770 0.770 100% Intake~ ~ ~~~~0I
"~53878%78 0 947 6 1 098100.0 0.847 6.1
-5.1 AA 10 10 1473 23.53 879 0878 0.878 NB 10 10 1541 24 10 869 0869 0.869 Otfull 001:
MSD Minimum Significant Difference Donnett's MSD value:
8.1130 PMSD =
Percent Minimum Significant Difference PMSD:
14.0 PMSD is a measure of test precision. The PMSD is the minimum percent difference between the control and treatment that can be declored statistically sigoificant in a whole eftlueni toxicity test Intake:
Durneltts MSD value:
0.1007 Lower PMSD bouod determined by USEPA (lOth percentile) 12%.
PMSD:
12.5 Upper PMSD bound determtned by USEPA (90th percentile)= 30%.
Lower and upper PMSD bounds were determined from the I Oth and 90th percentile, respectively, ofPMSD data fron EPA's WET Itterlaboratory Variability Study (USEPA. 200 1 a, USEPA. 2001 b)
USEPA 2001a, 200th Final Report: Interlaboratory Variability Study ofEPA Short-term Chronic and Acute Whole Effluent Toxicity TestMethods, Volumes I and 2-Appendix. EPA-82t-B-01-004 and EPA-821-B-0l.005. US Environmentol Protection Agency, Cincinnati, Ott
Environmental Testing Solutions, Inc.
Page 5 of 6 Species: Pimephalespromelas Date:
5eA vs-OR Client: TVA / Sequoyah Nuclear Plant - UV-treated Daily Chemistry:
Day 0
2 Analyst I IIL Concentration Parameter CONTROL pH (S.U.)
-A.I
.is
- i1.
t
(.
t-W DO (mg/L)
I A (75 iI~~_I7 Conductivity 32k
?10
(~mos/cm)
Temperature(0 C)
-Lk iS iAIu8
-ZIA 1A pH (S. U.)
1.6o 7el 7*E tA4
- ~II 7
11.3%
DO (mg/L) 11 A Conductivity J~I~~~~3~19iBS
\\
42mhoscm)DO (mg/0 Temperature( 0 C) 1.Q *k i
i.s o pH (S.T u
e) C.
to'.s(
TL0O
?-'l 22.6%nk DO (mgL)
-8.00
-1.11 S (
Conductivity L010
'XCHJZB
~
a9 (A
oslcm) 211L Temperature (OC)
_ LSA IN. i
~
I
-M.
- 1 pH (S.U.)
-1b.
1
.c)-L LO 7
45.2%
DO (mg/L) 4.0 C 2~
Conductivity
(~mhos/cm
-zcl Temperature ('C) 35-%
'Z\\
- __41illZ~*
LS - Q 2F
- pH (&UU)
-I. St
.(
I,7
_17.l 1.58 1
72.6%
DO (mg/L) 6.0
-IM
.u I
8.0 Conductivity nta FInal nalFn (JIhos/cm 21 Temperature ('Q
-LS r
LJb
'S 7j Z.*
pH (S.U.)
S4c r.3 100%
DO (mg/L)
- 8.
.\\'177 (18*
17 Conductivity 7
lf
~0
(( mos/cm)
-Z Temperature ("C)
-Ls.
2(.
'Li
- I rt
.6 1s 0(
pH (S.U,)
-J.S'6 1,414 7-t 11.S4 100% Intake IDO (mgL)
S.
7 1
_r~1 7*1 1 8.0 11 Conductivity IkD9 U 10~jl~
~ ~
q I~~
g to
(~mos/cm)
Temperature (oC) IZ) -M L-L(q I
Z' 7*
1 C-Initial Iia nitial Fnl
)IiilI ia NAJ 0 bN2 ALALI PJtHTq 1LCCbIS to~~(o Page6l of 105 LMLCICb
Environmental Testing Solutions, Inc.
Page 6 of 6 Species: Pimephalespromelas Date:
pL4.lS-o8 Client: TVA I Sequoyah Nuclear Plant - UV-treated Day 3
4 5
6 Analyst
_______u-L4 &A Concen-Parameter tration CONTROL pH (S.U.)
- ,too DO(m/L)
Conductivity 3cY4 Temperature (g/L)
Z. A-6 pH (S. U.)
1 *Sta la3)7.4 1,~3 14, to o 1~
1~I d~~
11.3%
DO (mg/L)
-1 B
8 Conductivity 9
Temperature (OC 50 1
'Q)
- ~1~C*
) ~d
~
It*
I510%
DO (mg/L) 1
.5
.0 Io.1
'P l Temperature ('Q
-Z ak I*
1 L~*.-~.
I2~~
- ~~
I C*
_RY LS.U.)
I
.8
?41 49~c 1006%
DO (mgIL)
Conductivity~t*\\
I~~~~
- a~~~~
5 Temperature (OC Q IS
\\.
I`S*
tc.t I
q 1*to 3 *-
I L6*
pH (S-U.)
-1 A %a II7,S3
.5, 11 (O
11 '3Ig
-II.SCJ
-,cQ AJ6e 1006%
DO (m )
0
.o 31_
1 1
I
~~~~~~~Conductivity 1l Ii-71-0H~
a~
(mos/cm)
IV*
Temperature (OC Q
l-is.
k
-Zs 7
3'1 IItC*
Intake e ll_______________
Conductivity Vj (otmhos/cm)
V17-110il1~
~
8i~i~
Temperature (OCQ 15S 1 1S. I
)*
IN I C 7
1 7*\\
1
_5 Initial FialI nitial Final Initial Final nta il zm
-A
'k eLL ON)STNesr kUCL\\
- 5,gd t ze_(AU &M-teh Page62 of 105 (IC-b
TVA I Sequoyah Nuclear Plant, Outfall 101 - UV-treated April 15-22, 2008 Pimephalespromelas Chronic Whole Effluent Toxicity Test EPA-821-R-02-013, Method 1000.0 Daily Chemical Analyses Project number:
3810 Environmental Testing Solutions, Inc.Revw by:
Reviewed hyZy-L-Concentration Parameter Day 0 Da 1Da 2
Da 3 Da 4 Da 5 Da 6 Initial Final Initial Final Initial Final Initial Final Initial Final Initial Final Initial Final pH (SU) 7.65 7.48 7.66 7.58 7.63 7.40 7.54 7.55 7.69 7.30 7.60 7.54 7.56 6.98 DO (mgIL) 7.9 7.5 7.7 7.7 8.0 7.8 7.8 7.6 7.9 6.9 7.8 7.9 7.6 6.0 Conductivity (jimhos/cm) 321 334 320 332 311 304 314 Control Alkalinity (mg/L CaCO3) 61 59 62 Hardness (mg/L CaCO3) 86 92 88 Temperature (0C) 24.9 24.5 24.8 24.7 24.9 24.6 24.9 24.4 24.9 24.3 24.6 24.7 24.9 24,7 P11 (SU) 7.65 7.49 7.65 7.57 7.64 7.39 7.56 7.53 7.68 7.37 7.60 7.53 7.54 6.96 DO (mg/L) 7.9 7.4 7.8 7.6 8.0 7.7 7.9 7.5 7.8 6.9 7.8 7.8 7.7 5.6 Conductivity (~tmhos/cn) 301 316 310 314 299 299 298 Temperature (0C) 25.1 24.7 24.9 24.5 24.9 24.6 25.0 24.5 25.0 24.3 24.6 24.6 25.0 24.5 pH (SU) 7.64 7.48 7,63 7.54 7.64 7.37 7.55 7.52 7.66 7.33 7.6]
7.50 7.54 696 DO (mg/L) 8.0 7.4 7.7 7.7 8.0 7.7 8.0 7.5 7,9 7.1 7.7 76 78 5.6 Conductivity (limhos/cm) 272 290 294 299 283 283 294
_Temperature (C) 25.1 24.7 24.9 24.5 25.0 24.7 25.0 24.5 25.0 24.2 24.7 24.6 25.0 24.5 pH (SI) 7.62 7.44 7.60 7.51 7.63 7.33 7.53 7.48 7.63 7.25 7.59 7.47 7.52 6.94 DO (mg/L) 8.0 7.4 7.6 7.7 8.0 7.7 8.0
- 7.
7.9 6.9 7.8 7.5 7.7 5.3 Conductivity (umhos/cm) 248 260 258 264 252 253 262 Temperature (C) 25.1 24.6 24.9 24.3 25.0 24.6 25.1
- 24.
25.1 24.2 24.7 24.6 25.0 24.6 H (SU) 7.58 7.41 7.57 7.48 7.58 7.32 7.49 7.45 7.56 7.24 7.52 7.43 7.49 6.89 DO (mg/L) 8.0 7.4 7.6 7.7 8.0 7.7 8.1 7.5 7.8 6.8 8.0 7.6 7.8 5.4 Conductivity (ptnhos/cm) 211 219 212 219 212 211 221 Temperature (C) 25.2 24.6 24.9 24.6 25.0 24.4 25.1 24.3 25.1 24.4 24.7 24.6 25.1 24.6 pH (SU) 7.54 7.39 7.52 7.41 7.54 7.27 7.46 7.40 7.53 7.16 7.49 7.39 7.46 6.89 DO (mg/L) 8.0 7.4 7.7 7.4 8.0 7.6 8.1 7.5 8.0 6.7 7.9 7.7 7.8 5.6 Conductivity (I.mhos/cm) 173 172 169 173 171 170 178 Alkalinity (mg/b CaCO3) 53 51 54 Hardness (mgIL CaCO3) 61 61 Temperature (C) 25.2 24.6 24.9 24.6 25.0 24.7 25.1 24.5 25.1 24.3 24.7 24.5 25.1 24.6 pH (SU) 7.53 7.34 7.50 7.44 7.54 7.27 7.44 7.35 7.50 7.17 7.46 7.39 7.45 6.93 DO (mgIL) 8.0 7.5 7.7 7.7 8.0 7.6 8.1 7.4 7.9 6.7 7.9 7.4 7.9 6.3 Conductivity (mhos/cm)
-166 169 166 172 170 169 174 1000 Intake Alkalinity (mg/L CaCO 3) 50 52 54 Hardness (mg/L CaCO3) 67 65 65
_ emperature( 0C) 25.2 24.6 24.9 24.5 25.1 24.6 25.1 24.5 25.1 24.3 24.8 24.7 25.1 24.5
Page Page Iof of
., Environmental Testing Solutions. Inc.
Total Residual Chlorine (Orion Electrode Method, Orion 97-70)
Matrix: Water, MDL = 010 Ing/L Meter: Accumet Model AR25 pH/Ion Meter Analyst Iodide reagent:
O Date analyzed Acid reagent: u Calibration:
-C~*~l 0.10 mg/L I
1.00 mg/L Reference standard number
--. Ss1 t rIj)S1.9 Note. For samples with a residual chlorine of > 10 mg/L, the calibration range must be adjusted to bracket the chlorine levels of the samples.
Laboratory control standard:
Reference standard True value (TV)
Measured value (MV)
% RS = MV / TV x 100 number (mg[L)
(mg/L)
(acceptable range = 90 to 110%)
T-N)CA51p) 0.50 01J 1 Duplicate sam le precision:
Sample Sample ID Sample characteristics Residual chlorine
%RPD = ((S - D) /[(S+D)12]) x 100 numbermg (acceptablerange=+/-+10%)
~~~
S '-o~~~~~~~~~~~oooO4~~~~~~~~~l
_'gk Duplicate D___________
Sample measurements:
Sample Sample ID Sample characteristics Residual chlorine number (mg/L) nuA Blank (shouldbe=<0.lOmg/L)
NoO81a 04 L'. 0 u
s tA c
co Y OVC OC0O 0o&t4la.&
Y-r-4~ SS C
i ico-tO\\Or o0 Ftoq Ck 4 0.4v v
sr 3r (000010S 0Ao'.~AbOS t
(.i
~~ iS
-9CC
~~~.~ cbJI volooo t~e jI Oboc\\~~~~~,ob oh3~~~~c~t o
oy3 Loooomicll cOo tnmbe (mg/)
(mg/b))O (acetal rag 90 to10%
0\\
j~~~~~~~~~~~
~~~~~~ate reviwed 0
-I-O ok t
j 1
~~~~Note: All samplts were analyzed in-excess of EPA~kommended holdirfg time (I 5 minutes) uelies; itherwise noted.
Reference standard True value (TV)
Measured value (MV)
% RS MV TV 100 number (mgfL)
(mg/L)
(acceptable range = 90 to 110%)
Page 64 of 105 Reviewed by Date reviewed
-\\0
Page Page a
of I~~~
E Cnvironmental Testing solutions, Inc.
Total Residual Chlorine (Orion Electrode Method, Orion 97-70)
Matrix: Water, MDL = 0.10 mg/L Meter: Accumet Model AR25 pH/Ion Meter Analyst Iodide reagent:
Date analyzed 0%4. Wet Acid reagent:
Calibration:
0.10 mg/L I
1.00 mg/L Reference standard number Note: For samples with a residual chlorine of > 1.0 mg/L, the calibration range must be adjusted to bracket the chlorine levels of the samples.
Laboratory control standard:
Reference standard True value (TV)
Measured value (MV)
% RS - MV / TV x 100 number (mg/L)
(mg/L)
(acceptable range = 90 to 110%)
c~rJS'jI9S 0.50 Duplicate sample recision:
Sample Sample ID Sample characteristics Residual chlorine
%RPD = {(S - D) /[(S+D)/2]) x 100 numherm/L (acceptable range 10%)
Duplicate D
0 AX) I
-t Sample measurements:
Sample Sample ID Sample characteristics Residual chlorine number I__
(mgIL)
Blank (shouldbe=< 0.10mg/L)
-41 LaIL1
.lt 4kt4.LtY 04 tcO 000 3. aj 0&c0'41\\. I k-W 4 cjo KXO3 Note. All samples were analyzed in excess of EPA recommended holding time (15 minutes) unless otherwise noted.
Laboratory control standard:
Reference standard True value (TV)
Measured value (MV)
% RS MV / TV x 100 number (mgfL)
(mg/L)
(acceptable range = 90 to 110%) I N-~lS C's
'5 -1,P0.50 0 5 L Reviewed by I ZI IZI Page 65-of 105 Date reviewed
Page RI Page _
of EnvironmentaTesting Solutions, Inc.
I Total Residual Chlorine (Orion Electrode Method, Orion 97-70)
Matrix: Water, MDL = 0. 10 mg/L Meter: Accumet Model AR25 pH/Ion Meter Analyst Iodide reagent:
I fA 2.z Date analyzed OA - %S.IbE Acid reagent:
Lt-j (.
1(3 Calibration:
0.10 mg/L 1.00 mg/L Reference standard number
~
Nc$S-1
\\651C Note. For samples with a residual chlorine of > 1.0 mg/L, the calibration range must be adjusted to bracket the chlorine levels of the samples.
Laboratory control standard:
Reference standard True value (TV)
Measured value (MV)
% RS = MV!/ TV x 100 number (mg/L)
(mgIL)
(acreptable range = 90 to 110%)
It&
"1 0.50 O.S76 Io$2507 Duplicate sample precision:
Sample Sample ID Sample characteristics Residual chlorine
%RPD = ((S - D) /[(S+D)12]} x 100 numher mL (acceptable range=+ 10%)
OUUc\\i$.
oA wG b AILLS 5 b tt CZ L e
S <-0 0 0
~
0(LoL Duplicate D
le measurements:
Sample Sample ID Sample characteristics Residual chlorine number (mgL)
~jj Blank (shouldbe=<O lOmg/L)
K
- 0.
O Odc1S O&
w-41' A0JUA50,1 WW-n 2 N10 C, 6 LO(L, LLeA(L-o.ccj o oo 0r 7 H cawizoef Li4~
k AQr-~
-eA flp
'0.0-s000011!*
0o40 v.A.Q2..
6(jiQrQ rIOf.e.
C__eA____________
600 2L4 0464A-01--.
-4GQ Q i TAAI~e PAe.
m-r 04er Le k, 6Y4
-Le-S 0
O00 Z5 Note. All samples were analyzed in excess of EPA recommended holding time (15 minutes) unless otherwise noted.
Laboratory control standard:
Reference standard True value (TV)
Measured value (MV) o RS MV / TV x 100 number (mg/L)
(mg/L)
(acceptable range = 90 to 110%)
I talks SI 0.50
- 6. 530 o
io o7J Reviewed by Page 66 of 105 Date reviewed
43 Page I@O Page _
of I~~~~
Environmental Testing Solutions, Inc.
Total Residual Chlorine (Orion Electrode Method, Orion 97-70)
Matrix: Water, MDL = 0.10 mg/L Meter: Accumet Model AR25 pH/Ion Meter Analyst F
Iodide reagent:
Date analyzed Acid reagent:
Calibration:
0.10 mg/L I
1.00 mg/b Reference standard number Note: For samples with a residual chlorine of > 1.0 mgIL, the calibration range must be adjusted to bracket the chlorine levels of the samples.
Laboratory control standard:
Reference standard True value (TV)
Measured value (MV)
% RS = MV / TV x 100 number (mg/L)
(mg/I.)
(acceptable range = 90 to 110%)
A 0.50
/
Duplicate sample precision:
Sample Sample ID Sample characteristics Residual chlorine
%RPD = {(S - D) /[(S+D)12]) x 100 number (mg/b)
(acceptable range= +/- 10%)
I~~Lfi I
C. 0 Duplicate
- jSM D
Sample measurements:
Sample Sample ID Sample characteristics Residual chlorine number (mg/L)
Blank (should be= < 0.0Img/L) 0.<_
rzR YA n. ojjJ
/2 QQLJ/3
~___
C 1 1 0 21 000 5V,9~-~
09 09 %l 7
~3 ii w -
r'J Note. All samples were analyzed in excess of EPA recommended holding time (15 minutes) unless otherwise noted.
Laboratory control standard:
Reference standard True value (TV)
Measured value (MV)
% RS = MV / TV x 100 number (mg/b)
(mg/b)
(acceptable range= 90 to 110%)
0.50 7K Reviewed by Page 67 of 105 Date reviewed j
Pa Pe of I~~~~
EnvArcnmental Testing Solut onr.I~
Alkalinity (SM 2320 B)
Matrix: Water, RL = 1.0 mg CaCO3/L Analyst Time initiated 1500 Date analyzed Titrate samples to Time completed U tOO pH = 4.50 S.U.
Titrant normality and multiplier determination:
pH of Normality Normality (N) of H2SO4 pH Factor or Multiplier Deionized Titrant check Begin End Total
= (5 ml Na2CO3 x 0.05)fE (Nx 50000)1 100 ml sample water reference standard ml ml ml
= 0.25/E nnNx 500
= 4.5 S.U.
number number (E)
(acceptable range =0.0180 -0.0220) h.O is'iz.-(
OSt9 0-ld3 ra O. o0 5
.0S ZO.\\V' cor.
orsl O
4 0.0-0.1 = 0 -I gAL Laboratory control standard:
Reference standard True value Sample Alkalinity (MV)
% RS = MV I TV x 100 number (TV) volume Begin End Total Multiplier (mg CaCO3IL)
(acceptable range (Mg CaCO3/L) I (ml) mlmi ml ml
-90 to 110%)
-I 97.0 o
I Duplicate sa ~le precision..
Sample Alkalinity
%RPD =
Sample Sample ID volume Begin End Total Multiplier (mg CaCO3L)
((S -D) I[(S+D)/2]) x 100 number (ml) ml mI ml (acceptable range = +/- 10%)
S
.~~~,
1 Cam g
j
&-?-crO 1 )(f5 K
(
(-l-~
100 tAB
- (.(#
.8 Io.
S Duplicate (B)
C.OO a-1i 33.3
.7 to -
D CI Mlatrix spike recovery:
Reference standard Spike value Sample Spike alkalinity (A)
(mCaCO3I)
(ml ml ml ml number (SV) volume Begin End Total Multiplier (mg CaCO3/L)
INS-Srvj5 50 100
- 97. 10 VB I a)P t 0 -
UO0 j
Sample alkalinity (B)
Measured spike value (MY)
% R MV / SV x 100 (mg CaCO3/L)
MV = A - B (acceptable range (mg CaCO3fL)
= 75 to 125%)
Sample measurements:
Sample volume Begin End Total Alkalinity Sample number Sample ID (ml) ml ml ml Multiplier (mg CaCO3IL) ot~~(y U
1.iu Hr-O 00
- 1.
4k v3 3.,
to.I ;.
6-fS (Y)-h) 1 0.0 C
______5.___9 S.tH i 8. 5 OS 014 0A.
I vjcr k \\ lib 5.a, 3
QQo txs '5A (1.sc
)
I l
'RctI Ct -3 086 oS. O.
cAcw'AE I
3b.3
'4 11 3.N i) v-to 0 k Oqog.Ci rj LALI.9
-3. 3 130C IOS O'.ii 0 3 3
C>Q 33 3, '
OPage 68 of 105 Reviewed by:Daerved.cIZ-O
Page r\\
Page i
of 5
< EnvrronnmentalTesting Solurinrc. InC.
Alkalinity (SIM 2320 B)
Matrix: Water, RL = 1.0 mg CaCOJ/L Analyst L
Time initiated [7l~ 777j Date analyzed Titrate samples to Time completed j
(
3jJ pH = 4.50 S.U.
Titrant normality and multiplier determination:
pH of Normality Normality (N) of H2SO4 pH Factor or Multiplier Deionized Titrant check Begin End Total (5 ml Na 2CO 3 x 0.05)IE (N x 50000)! 100 ml sample water reference standard ml ml ml
= 0.25/E N x 500
= 4.5 S.U.
number number (acceptable range = 0.0180 - 0.0220)
Laboratory control standard:
Reference standard True value Sample Alkalinity (MV)
/ RS = MV I TV x 100 number (TV) volume Begin End Total Multiplier (mg CaCO3/L)
(acceptable range (mg CaCO3/L)
(ml) ml ml ml 90 to 110%)
Duplicate sample precision.._
R2~sSS5 3 S 100 10 3
i9~Aaint Sample Alkalinity
%RPD =
Sample Sample ID volume Begin End Total Multiplier (mg CaCO 3/L.)
{(S -D) /t(S+D)/21) x 100 number (ml) ml ml ml (acceptable range= +/-10%)
L~~)1 4oe.
- 100 13.0 I
- 0.
1.1 iO Duplicate (B)
D L&
Malrix spike recovery_
Reference standard Spike value Sample Spike alkalinity (A) number (SV) volume Begin End Total Multiplier (mg CaCO3IL)
(MgCaCO3 L)
(ml ml ml ml
-T-N5S535o0 00 l
20.0
$. 9 0.;I-o LO O Sample alkalinity (B)
Measured spike value (MV)
% R MV I SV x 100 (mg CaCO3IL)
MV A - B (acceptable range (mg CaCO3iL) 75 to 125%)
II
'-L9 C
Sample measurements:
Sample volume Begin End Total Alkalinity Sample number Sample ID (ml) ml ml ml Multiplier (mg CaCO3/L) lOG
- a.
d.L. I Li LVVl{)
too I
o.I.
Lj*
90o g. G5
~5 3~.9 1.9f Oa 0-1 10. 02-Z
- 14.
(DOC) a 0 80 q12.o$
. rjS 1q.,l
- 14. -d§ O
&-i Ca 71
/
I I
_1 I
al.l 3.0 U
ge69uf10
-eviswedby:
n~0 Da 0 4 Page 69 of 105 Reviewed by:
~ 7 j j Date reviewed:F A -G
Page Page of Alkalinity (SM 2320 B)
Matrix: Water, RL =1.0 mg CaCO3/L Analyst Time initiated Date analyzed L pjS Titrate samples to Time completed 1'-14 pH = 4.50 S.U.
Titrant no and ulti ler determination:
pH of Normality Normality (A) of H2S04 pH Factor or Multiplier Deionized Titrant check Begin End Total (5 ml Na 2CO3 x 0.05)IE (N x 50000)! 100 ml sample water reference standard ml ml ml
= 0.25/E
=Nx 500
'4.5 S.U.
number number (acceptable range = 0.0180 - 0.0220)
A- -.I n umberI n umber
__o AL
_o B~r u.*yYr4or4 -0.0-0.0 Laboratory control standard:
i Reference standard True value Sample Alkalinity (MV)
/ RS MV TV x 100 number (TV) volume Begin End Total Multiplier (mg CaCOjfL)
(acceptable range (mg CaCOVL) ml ml ml ml 90 to 110%)
I f~JS S535 1
100 100 I. O
- a. 3 -9.3 IDAi
.0 Duplicate sample precision:
Sample Alkalinity
%RPD =
Sample Sample ID volume Begin End Total Multiplier (mg CaCOj/L)
((S -D) I[(S+D)/21) x 100 number
- 1) ml ml ml (acceptable range=
10%)
)L)OO w
tco o
d3 ai.'
(4e
().'
I4 Duplicate (B) to.q 334 (4.1
('M D
Matrbz spike recovery:
Reference standard Spike value Sample Spike alkalinity (A) number (SV) volume Begin End Total Multiplier (mg CaCO 3fL)
(mgCaCO3/L)
(ml) ml ml ml 7T N $55 3 5 LOtO X 1.
38.i III 10.4 110 I
Sample alkalinity (B)
Measured spike value (MV)
% R MV / SV x 100 (mg CaCO3/L)
MV = A - B (acceptable range (mg CaCO3'L) 75 to 125%)
(DD (O
a.C)/
ple measurements:
Sample volume Begin End Total Alkalinity Sample number Sample ID (ml) ml ml ml Multiplier (mg CaCO3/L) o*\\. ~~~~8
~~~7 L3 1~~00 t,0
`0-58 C~c D
q-3C 13-Ok
~*
0 ~ ~
~
~
~
~
Dit z*3~
iAV\\\\\\5 V\\Jo (4~J ll Page 70
- ^r b*w 1
V I
Tj 3
I
_J ___
\\~~
j~
-. I --
^
Page )3 Page P
of A g
F~~~~~~~
Eniom 9
JtTP~n Soui. Inc.
Alkalinity (SM 2320 B)
Matrix: Water, RL = 1.0 mg CaCO3/L Analyst Time initiated Date analyzed fUXj ZIZ Titrate samples to Time completed pH = 4.50 S.U.
Titrant normality and multiplier determination:
pH of Normality Normality (N) Of H2SO4 pH-Factor or Multiplier Deionized f
k Total (5 ml Na2 CO3 x 0.05)E A(Nx 50000)! 100 ml sample water reference standard ml ml ml Q,25IE Nx 500 4.5 S.U.
number number (acceptable range = 0.o--f8*
220k-Laboratory controlstandard:
Reference standard True value Sample Alkalinity (MV)
% RS I VI TV x 100 number (TV) volume Begin End Total Multiplier (mg CaCO3/L)
(acceptable range (mg CaCO~fL)
(Ml ml ml ml
= 90 to 110%)
Refere100 100 of 11 (5.
C
),
s lepecson.
Sample Alkalinity
%RPD =
Sample Sample ID volume Begin End Total Multiplier (mg CaCO3fL)
{(S - D) I[(S+D)/2]) x 100 number (ml) ml ml ml (acceptable range 10%)
6SO l O
-'--z
-0\\ S X
33*
3 t-5 t2 O
11 A S 130 Duplicate (B) 3D j
____130__
Matrix spike recovery:
Reference standard Spike value Sample Spike alkalinity (A-)-'
number (SV) volume Begin End Total Multiplier (mg CaCO3/L)
(mg CaCO3/L) m ml ml ml Sample alkalinity (B)
Measured spike value (MV)
% R = MV / SV x 100 (mg CaCO3/L)
MV A - B (acceptable range (MgCaCO/L) 75 to 125%)
le measurements:
Sample volume Begin End Total Alkalinity Sample number Sample ID (Ml) ml ml ml Multiplier (mg CaCO3IL)
W04 )'N.'3 U-iftel S
1 -
0.0 5 3* 12j
\\Q1-6 08 ulI' -
ylyo z
1 I
GT
- 0.
q e 15D Oa o 0'4 1. o0 Z
0I__
LiC Oa_
_I'
_ -_3
}
3q 0%,14 3 ell3r~p I
o'AiS~~,41.C 1A)%
1r?-3 36 o
Lz~
.232 j
'1
(
I
~~~8q).
i-TA -jt (U p
- CO2 I&0~
I doqlto.8 fl. - O.a' I
UP 3___
Page 71 of 105 Reviewed by:
Datereviewed: d
- o&
Page Page of 4 1
Fry ~~~~~~ovronmentlres Tcrng Solutions.
inc.
Alkalinity (SM 2320 B)
Matrix: Water, RL = 1.0 mg CaCO 3/L Analyst Time initiated Date analyzed
[ieTitrate samples to Time completed pH = 4.50 S.U.
Titrant normality and multiplier determination:
pH of Normality Normality (N) of
- nmeSO, pH Factor or Multiplier Deion-ii-rd-44TtraL pt check Begin End Total (5 ml Na2CO3 X 0-05)/E (N=ilx 50000)/ 100 ml sample water reference stlan Ta-M-I il
= 0.25/E
=Nx5O0 4.5 S.U.
number number I
I aT-aerangeerng
= 0.0180 -0.0220)
Laboratory control standard:
Reference standard True value Sam T
Alkalinity (MV)
% RS = MV / TV x 100 number (TV) volume Begin End Total Multiplier (mg CaCO3'L)
(acceptable range 1P4 SS~EJ~-
(mg CaCO 3IL)
(ml) ml 4
m
=.90 to 110%)
=33i 100 100
____3_________________
I Duplicate sa le precision:
Sample 0,O Alkalinity
%RPD Sample Sample ID volume Begin End Total Multiplier (mg CaCO3/L)
((S - D) I[(S+D)/2)J x 100 number (ml) ml ml ml (acceptable range=
10%)
I Lfl3~9 L~Z 9' DLL)C~34i 100i 10 Duplicate (B)
D Matrix spike recovey___
Reference standard Spike value Sample Spike alkalinity (A) number (SV) volume Begin End Total Multiplier (mg CaCOi/L)
(mgCaCO3/L) ml ml ml ml A______
1/03 1"5 a1.
L3 Sample alkalinity (B)
Measured spike value (MV)
% R = MV / SV x 100 (mg CaCO 3fL)
MV = A - B (acceptable range (mg CaCO3L)
= 75 to 125%)
Sample measurements:
Sample volume Begin End Total Alkalinity Sample number Sample ID ml I
ml Multiplier (Mg CaCO 3/L) t3 68;a.
4 4
4C tLX?2(e 90 Ji
.9-.
2-I
.3 v si-
__As__-
AO_-6 O
u
.1 ILI 3
072-NA
,tZ
___?L SI~i
'5C' 6)
OkC$-llI..
2 3bti' 3v'.9 J 2_
!5L1 Page 72 of 105 Reviewed by:
LIn I I
Date reviewed:
OP&O-
Page 6
Page ____Of ____
j~~~~~~~; Environinental Testing SaI~tions, Inc.
Alkalinity (SM 2320 B)
Matrix: Water, RL = 1.0 mg CaCOJ/L Analyst Time initiated Date analyzed Titrate samples to Time completed pH = 4.50 S.U.
Titrant normalit and multiptier determination:
pH o'-
~
)Normality Normality (N) of H2SO4 pH Factor or Multiplier Deionized Titrant in--L0n*
in I End Total (5 ml Na 2CO 3 x 0.05)IE
= (Nx 50000)! 100 ml sample water reference standard ml m
= 0.25/E
=Nx 500 j4.5 S.U.
number number (E)
_(a___________0)
Laboratory control standard:
Reference standard True value Sample Alkalinity (MV)
% RS = MV / TV x 100 number (TV) volume Begin End Total Multiplier (mg CaCO3IL)
(acceptable range (Mg CaCO3/L)
(Ml) ml ml ml 90 to 110%)
)~~55~~3(
100 100 1
L ol Duplicate sam le precision:
Sample Alkalinity
%RPD =
Sample Sample ID volume Begin End Total Multiplier (mg CaCO3/L)
{(S -D) /[(S+D)/21) x 100 number (Ml) ml ml ml (acceptable range =~ 10%)
opAoI.1t
'A -)
1
,QZ 11
-sQ o/
q i z 40
)Oq S
Duplicate (B)
( -3 64 D 63 Matrix spike recovery:
Reference standard Spike value Sample Spike alkalinity (A) number (SV) volume Begin End Total Multiplier (mg CaCO3/L)
(mg CaCO3[)
Ml ml ml ml Sample alkalinity (B)
Measured spike value (MV)
/ R MV / SV x 100 (mg CaCO3/L)
MV A-B (acceptable range (mg CaCO3/L)
=75 to 125%)
Sample measurements:
Sample volume Begin End Total Alkalinity Sample number Sample ID ml ml ml ml Multiplier (m
CaCO3fL)
U O
rOL4I8.ol\\
(t/4--~pv
\\AJ I3
~
H) c93 i
O a cq) 3 L
- 39) 4, Pae7 f1.O2R 30Le e.ebD 6e2-
_reew_
d Page 73 of 105 Revieeud by:
Date reviewed:
c'- 2c-rob O
Page iI Page I
ofi I
- ~~~~~:
~~
Environmental Testing 5o11j1,ons. Inc.
Total Hardness (SM 2340 C)
RL 1.0 mg CaCO3/L Analyst
'j~
Time initiated Date analyzed o
Time completed
[
33 Titrant normality and multip her determination:
Titrant Normality check Begin End Total Normality (AM of EDTA pH Factor or Multiplier reference standard ml ml ml
= 0.21E
= (Nx 50000)/ 50 ml sample number number (E)
(acceptable range = 0.0180 - 0.0220)
= N x 1000 Ir~J~rS znTss1r3 O.0 Ct.8 9.2 o.c)
'I O'oL Laboratory control standard:
Reference standard True value Sample Hardness (MV)
% RS = MV / TV x 100 number (TV) volume Begin End Total Multiplier (mg CaCO3/L)
(acceptable range (mg CaCO3IL) ml m
ml ml
=90 to 110%)
Sr
$a5rKm5~P 40 50 11l It-%
O
'X.4 L(I V a-a NI Duplicate sample precision:
Sample Hardness
%RPD Sample Sample ID volume Begin End Total Multiplier (mg CaCO3/L)
{(S -D) /((S+D)/21) x 100 number (m
ml I m I ml 01-ol-o@
fYt+.& \\
UQ
'E0 It.% lt.3
- 4. 5 aoq
__ S J,
uplicate (B)
'50 1(0.3 Ao _b
- 1.0.4.
D C, Matr&t spike recov Reference standard Spike value Sample Spike hardness (A) number (SV) volume Begin End Total Multiplier (mg CaCO3L)
(gCaCO3/Q ml M
ml B
Z\\Js~~T~t-5.C5b L40 50 I(O-3 ~a.9 U -IP
- t.0 q I14 Sample hardness (B)
Measured spike value (MV)
% R MV / SY x 100 (mg CaCO3IL)
MV = A - B (acceptable range (mg CaCO3IL) 75 to 125%)
9 Li 8
~Zo
-/
S m le measurements:
Sample measurements:
___Sample volume Begin End Total Hardness Sample number Sample ID (ml) ml ml ml Multiplier (mg CaCO3/L)
TV ND Blank C50 b.0 0.0 0-0 O.N I (should be =
_ Img CaCO3
~-tdJp~
c~s~n I
i
~-*~c L~~6i 94I q
__________o i
A Aj C
- L9 2 M2
-I38
.1 OCO\\
6
.A Oi I X VJC T 18.1yU.
)
1 C/
Page 741 Note: If >15ml of titrant is used, sample must be diluted.
Reviewed by n tp rpvipnxvpri
Page Page _
_ of__
- ~
~
~~~~~
Etviromntrneto Testing Solutions, Inc.
Total Hardness (SM 2340 C)
RL - 1.0 mg CaCG3/L Analyst 1~-j-Time initiated i2.
I Date analyzed 0 _jcjy.
Time completed Ijr3j Titrant normality and multiplier determination:
Titrant Normality check Begin End Total Normality (N) of EDTA pH Factor or Multiplier reference standard ml mi ml
= 0.21E
= (Nx 50000)/ 50 ml sample number number (E)
(acceptable range = 0.0180 - 0.0220)
=N x 1000 IAMaoo 0I0 6 o
q(
- 9.
7 o.ov' 1 Laboratory control standard:
Reference standard True value Sample Hardness (MV)
% RS = MV / TV x 100 number (TV) volume Begin End Total Multiplier (mg CaCOsIL)
(acceptable range (mg CaCO3/L) m lI ml mlI 90 to 110%)
s',SS57k6 40 50 4 -3go).q 3
Duplicate samvle precision:
Sample Hardness
%RPD =
Sample Sample ID volume Begin End Total Multiplier (mg CaCO3/L)
((S -D) /l(S+D)/2]} x 100 number (ml) ml mil ml 0 4 -1_
1 41.3 4
Duplicate (B)
D Matrix spike recover__
Reference standard Spike value Sample Spike hardness (A) number (SV) volume Begin End Total Multiplier (mg CaCO3/L)
_ (mg CaCO3/L) m ml ml ml 1
Ifi SaE (O
!0 so
(
A3 R9.6 (o,*
91o.-1 Sample hardness (B)
Measured spike value (MV)
% R = MV / SV x 100 (mg CaCO3/L)
MV = A - B (acceptable range (mg CaCO3iL) 75 to 125%)
le measurements:
Sample volume Begin End Total Hardness Sample number Sample ID (ml) ml ml ml Multiplier m CaCO3IL)
TV=ND Blank b_
0 0-3 3-0 d.LI (should be = 0 mgCaCO3/L)
Page75e)*-3e)
'Ic~
4 JI Not I >
frn is u
.a.
hdbIt I
OcdA 1 z
L 03 U).
O&OIA 6 - 13
-3 1 DuI A,-
. OL Id Z,z
(.
Ira Page e
75 T-)Pelh I
ntp rPlPIfip1 j
^vJld-O Note: If >15ml offitrant is used-samnle must he dilutd evewd
Page i
Page of Z
_i:I
~~~~~~Environnmental Testing Solutions. ISO.
Total Hardness (SM 2340 C)
RL I.0 mg CaCO 3/L Analyst Z i-ZI7 Time initiated Date analyzed j~q Time completed aifant normality and multiplier determination:
Titrant IifnItt-ekesL.
BZgin End Total Normality (A) of EDTA pH Factor or Multiplier reference standard ml I
- ---- l=
0.2/E (Nx 50000)/ 50 ml sample number number j(E)
(acceptable rangN x0*1~180
-0.0220)
= N x1000 Laboratory control standard:
Reference standard True value Sample Hardness (MV)
% RS = MV / TV x 100 number (TV) volume Begin End Total Multiplier (mg CaCO3/L)
(acceptable range (mg CaCO3IL)
(mI) ml ml ml
= 90 to 110%)
40 50 1-.2 1q.2 2-C
.4i IO.1 Duplicate sample precision:
Sample Hardness
%R-PD Sample Sample ID volume Begin End Total Multiplier (mg CaCO3/L)
((S - D) /l(S+D)/21) x 100 number
'A (mI) ml ml ml Duplicate (B)
D:i J
S Matrix spike recovery:
Reference standard Spike value Sample Spike hardness (A) number (SV) volume Begin End Total Multiplier (mg CaCO3/L)
(mgCaCO3IL)
(ml) ml ml ml sS SS-~Plk~b ~
3 a
e l
~0 (3 (15 5,7 lsi Sample hardness (B)
Measured spike value (MV)
% R = MV!/ SV x 100 (mg CaCO:fL) (B)
A - B (acceptable range (gCaCO3/
= 75 to 125%)
Smle ?measurements:
Sample volume Begin End Total Hardness Sample number Sample ID (ml) ml ml mll Multiplier (mg CaCO3JL)
TV = N---
(should be mg CaCO3/L) a~~d
\\1, \\
1 A lotl\\s ars
.s s, o;
b6 % \\
-, 5 30 3v,
O a l&O
. OI.
3.1 Ogb
Ž1L)OC/
I 3b~-'
3LLL id bOkwl1l 7
41,3 4 3 -<19z ab-fl1qI. O t q3,Q 6.o 1 ___
Oa t4 1o, U1
- TVA, Po -
5T23A______
Page 7600
-5 Note If >15ml of titrant is used, sample must be diluted.
Reviewed by:
Date reviewed AQ 4
Page
}.L Page of "f
~
Envrronmentaltestinq Solufions. Inc-.
Total Hardness (SIM 2340 C)
RL = 1.0 mg CaCO 3/L Analyst 7 Time initiated Date analyzed D
Time completed [ji*Lfjj Titrant normality and multiplier determination:
Titrant Normality check Begin End Total Normality (Ng) of EDTA pH Factor or Multiplier reference
-an-ar ml_
0.2/E (Nx 50000)1 50 ml sample number number (E)
(ace-p blerange 0.0180 - 0.0220)
=N x 1000 Laboratory control standard:
Reference standard True value Sample Hardness (MV)
% RS = MV I TV x 100 number (TV) volume Begin End Total Multiplier (mg CaCO3IL)
(acceptable range (mg CaCO3/L)
(m)ml ml ml
= 90 to 110%)
)f~1 ss-le~
~ 1 40 50 do*4
/O Io.s -
Duplicate Sam le precision:
Sample A.3 Hardness
%RPD Sample Sample ID volume Begin End Total Multiplier (mg CaCO3/L)
((S -D) /[(S+D)/211 x 100 number (Ml) ml ml ml q
I C~~-up Ot S
Duplicate (B) 4-q D
r Matrix spike recov Reference standard Spike value Sample Spike hardness (A) number (SV) volume Begin End Total Multiplier (mg CaCO3/L)
(mgCaCO3/L)
(ml) ml ml ml Sample hardness (B)
Measured spike value (MV)
% R MV!/ SV x 100 (mg CaCO 3IL)
MV = A - B (acceptable range (mg CaCO3/L) 75 to 125%)
Sample measurements:
Sample volume Begin End Total Hardness Sample number Sample ID (ml) ml ml ml Multiplier (mg CaCOIL) should be 0 mg CaCOs/L) 3.0 cl"\\t4IA\\
1jr~A-S~6 x~
1-7j I(
/Lq"
~dh 08 O 4 C
13 j A -
I QP" I 0, j 1Q( 4 0&04 tSJcM~U tIS oto/io.
6I.
i
- q.)3 *.I o1l8.oz 3
1 q 5 2-
-~~7-og I
n~jij
)3ii 7
I
- 0~~~-R i
i L
I 1
/~~~~*7
~~n~*z cr~~sl I
P- -
O kAl J--
4 i
J i"*
/uols) --
jW la)
Page 771I\\0O& A I Note. If >15ml oftitrant is used, sample must be diluted.
Reviewed by:
Date reviev-ed I
..s -
Page Page L4 of 14 I~~~~~~~
-, nironmentMlTestinq SolutioflS. Inc.
Total Hardness (SM 2340 C)
RL = 1.0 mg CaCO 3/L Antialyst Time initiated 77iZ7 Date analyzed Time completed Titrant normality and multipher determination:
Titrant Normality check Begin End Total Normality (N) of EDTA pH Factor or Multiplier re ence standard ml ml ml
- 0.21E (Nx 50000)/50 ml sample numb number (E)
(acceptable range = 0.0180 - 0.0220)
=Nx 1000 Laboratory controls andard:
Reference standard Tr value Sample Hardness (MV)
% RS = MV / TV x 100 number (T
volume Begin End Total Multiplier (mg CaCO.3 L)
(acceptable range (mg CaC'O (ml) ml ml ml
= 90 to 110%)
40 50 Duplicate sam he precision:
Sample Hardness
%RPD =
Sample Sample ID volume Begi End Total Multiplier (mg CaCO3L)
((S - D) /I(S+D)/2)) x 100 number
__ _ __)l~!L ml nml ml Duplicate (B)
D Matrix spike recovery:
Reference standard Spike value Sample Spike hardness (A) number (SY) volume Begin End Total Multi er (mg CaCO3/L)
(mgCaCO3IL)
(l ml ml ml Sample hardness (B)
Measured spike value (MV)
MV / SV x 100 (mg CaCO3IL)
MV = A - B (acce ble range m CaCO3/L)
=75 to 5%)
Sample measurements:
Sample volume Begin End Total Hardness Sample number Sample ID m(M) ml I ml ml Multiplier (mg CaCO /L)
I
_______~----cl TV = ND b
gCC L
I
__-_I_
Pap 78 iil3
-0 Note If >1 5ml of titrant is used, sample must be diluted.
Reviewed by:
Date reviewed
,v.I - -i.n
^9
Sequoyah Nuclear Plant Biomonitoring April 15 - 22, 2008 Appendix D Reference Toxicant Test and Control Chart Page 79 of 105
Pimeph ales promelas Chronic Reference Toxicant Control Chart ET Organism Source: Aquatox, Inc.
- 4a Environmental Testing Solutions, Inc.
1.2 I
I I
I I
I I
I I
USEPA Control Limits (+/-2 Standard Deviations) 1.0 0.8 0.6 0.4 1.2 USEPA Warning and Control Limits (7-5 thand 90 thPercentile CVs) 0.8 0.6 ea 0.4 N
1.2 Laboratog' Warning and Control Limits (J0 th and 2 5th Percentile CVs) 1.0 0.8 0.6 -.
0.4 Test date 7-day IC2. = 25% inhibition concentration. An estimation of the concentration of potassium chloride that would cause a 25% reduction in Pimephales growth for the test population.
Central Tendency (mean IC25)
Warning Limits (mean IC25 +/-
A.10 or SA.75)
Pa e
80 of 1 b
ntrol Limits (mean IC2
+/-
or 2 Standard Deviations) 1~~~80~~of 1R SA' A90'
00 0
Pimephales promelas Chronic Reference Toxicant Control Chart Environmental Testing Solutions, Inc.
State and USEPA Laboratory Laboratory USEPA USEPA Test number Test date 7-day IC25 CT S
Control Limits SA.1 Warning Limits SA.2 Control Limits SA.75 Warning Limits SA.90 Control Limits CV (gIL KCI)
(gl. KCI)
CT -2S CT + 2S CT - SA CT + Si,,
CT - SA.,s CT + SA.5 CT -SA.7s CT + SA.75 CT -SAM CT + SA.y 07-31-07 0.68 2
08-07-07 067 0.67 0.01 0.66 0.68 0.08 0.59 0.75 0.14 0.53 0.81 0.26 0.42 0.93 0.30 0.37 0.97 0.01 3
08-14-07 0.64 0.66 0.02 0.63 0.70 0.08 0.58 0.74 0.14 0.52 0,80 0.25 0.41 0.91 0.30 0.36 0.96 0.03 4
09-11-07 0.61 0.65 0.03 0.59 0.71 0.08 0.57 0.73 0.14 0.51 0.78 0.25 0.40 0.90 0.29 0.36 0.94 0.05 5
10-02-07 0.67 0.65 0.03 0.60 0.71 0.08 0.58 0.73 0.14 0.52 0.79 0.25 0,41 0.90 0.29 0.36 0.95 0.04 6
10-09-07 0.64 0.65 0.03 0.60 0.70 -
0.08 0.57 0.73 0.14 0.51 0.19 0.2$
0.40 0.90 0.29 0.36 0.94 0.04 7
10-16-07 0.66 0.65 0.02 0.60 0.70 0,08 0.57 0.73 0,14 0.52 0.79 0.25 0.41 0.90 0.29 036 0.95 0,04 8
10-30-07 0.60 0.65 0.03 0.59 0.71 0.08 0.57 0.72 0.14 0.51 0.78 0.25 0.40 0.89 0.29 036 0.94 005 9
11-06-07 0.72 0.65 0.04 0.58 0.73 0.08 0.58 0.73 0.14 0,52 0.79 0.25 0.41 0.90 0.29 0,36 0.95 006 10 11-13-07 0.72 0.66 0.04 0.58 0.75 0.08 0.58 0.74 0.14 0,52 0.80 0.25 0.41 0.91 0.30 0.36 0.96 0.06 11 12-04-07 0.52 0.65 0 06 0.53 0.77 0.08 0.57 0.73 0.14 0,51 0.79 0.25 0.40 0.90 0.29 0,36 0.94 0.09 12 01-08-08 0.65 065 0.06 0.54 0.76 0.08 0.57 0.73 0.14 0.51 0.79 0.25 0.40 0.90 0.29 0.36 094 0.09 13 01-15-08 0.64 0.65 0.05 0.54 0.75 0.08 0.57 0.73 0.14 0,51 0.78 0.25 0.40 0.89 0.29 0.36 094 0.08 14 01-29-08 0.64 0.65 0.05 0.55 0.75 0.08 0.57 0.73 0.14 0,51 0.78 0.25 0.40 0.89 0.29 0.36 094 008 15 02-05-08 0.65 0.65 0.05 0.55 0.75 0.08 0.57 0.73 0.14 0.51 0.78 0.25 0.40 0.89 0.29 0.36 0.94 0.08 16 02-12-08 0.64 0.65 0.05 0.55 0.74 0.08 0.57 0,73 0.14 0.51 0.78 0.25 0.40 0.89 0.29 0.36 0.94 007 17 02-19-08 0.64 0.65 0.05 0.55 0.74 0.08 0.57 0.72 0,14 0,51 0.78 0.25 0.40 0,89 0.29 0.36 0.94 0.07 18 03-04-08 0.71 0.65 0.05 0.56 0.75 0.08 0.57 0.73 0.14 0,51 0.79 0.25 040 0.90 0.29 0.36 0.94 0.07 19 03-11-08 0.69 0.65 0,05 0.56 0.75 0.08 0.57 0.73 0.14 0.52 0.79 0.25 0.40 0.90 0.29 0.36 0.95 007 20 04-15-08 0.59 0.65 0.05 0.55 0.74 0.08 0.57 0.73 0.14 0.51 0.79 0.25 0.40 0.90 0.29 0.36 0.94 0.07 Note:
7-d IC25 7-day 25% inhibition concentration. An estimation of the concentration of potassium chloride that would cause a 25% reduction in Piniephales growth for the test population.
CT Central tendency (mean IC2 5).
S = Standard deviation of the IC2, values.
Laboratory Control and Warning Limits Laboratory control and warning limits were established using the standard deviation of the IC25 values corresponding to the 10th and 25th percentile CVs.
These ranges are more stringent than the control and warning limits recommended by USEPA for the test method and endpoint.
SA.5 = Standard deviation corresponding to the 10 0 percentile CV. (SA 1 0.12)
SA.15 = Standard deviation corresponding to the 25h percentile CV. (SAs2s 0.21)
USEPA Control and Warning Limits SASS = Standard devistion corresponding to the 750 percentile CV. (SA.S = 0.38)
SA.9s = Standard deviation corresponding to the 900h percentile CV. (SASS = 0.45)
CV - Coefficient of variation of the IC25 values.
JSEPA 2000. Understanding and Accounting for Method Variability is Whole Eflnuent Toxicity Applications Under the National Pollutant Discharge Elimination Program EPA-833-R-00-003.
US Environmental Protection Agency. Cincinnati, OH Organisms ohans'edfronh Aoamlox. bnc.
atoxt4-15-08
Precision of Endpoint Measurements Pimephales promelas Chronic Reference Toxicant Data Environmental Testing Solutions, Inc.
Test number Test date Control Control Mean CT CV CT MSD PMSD CT Survival Growth
(%)
(mg/larvae) for Control Growth
(%)
for Control
(%)
for PMSD (mg/larvae)
Growth CV (%)
1 07-31-07 100 0.686 7.9 0.08 11.0 2
08-07-07 100 0.854 0.770 11.5 9.7 0.13 15.7 13.4 3
08-14-07 97.5 0.900 0.813 13.1 10.8 0.13 14.4 13.7 4
09-11-07 100 0.831 0.818 6.3 9.7 0.14 17.4 14.6 5
10-02-07 100 0.918 0.838 4,9 8.7 0.17 18.1 15.3 6
10-09-07 100 0.772 0.827 7.9 8.6 0.08 10.2 14.5 7
10-16-07 100 0.662 0.803 13.6 9.3 0.08 12.8 14.2 8
10-30-07 100 0.771 0.799 12.0 9.6 0.16 20.1 15.0 9
11-06-07 100 0.624 0.780 6.4 9.3 0.09 14.7 14.9 10 11-13-07 100 0.603 0.762 14.2 9.8 0.10 16.8 15.1 11 12-04-07 100 0.756 0.761 7.9 9.6 0.11 14.5 15.1 12 01-08-08 100 0.821 0.766 2.7 9.0 0.03 3.4 14.1 13 01-15-08 100 0.842 0.772 10.5 9.1 0.14 17.0 14.3 14 01-29-08 97.5 0.728 0.769 5.4 8.9 0.07 9.0 13.9 15 02-05-08 100 0.818 0.772 7.2 8.8 0.07 9.1 13.6 16 02-12-08 100 0.709 0.768 2.4 8.4 0.05 6.8 13.2 17 02-19-08 100 0.833 0.772 6.1 8.2 0.13 15.5 13.3 18 03-04-08 100 0.731 0.770 6.0 8.1 0.07 9.0 13.1 19 03-11-08 97,5 0.695 0.766 5.1 8.0 0.07 10.5 12.9 20 04-15-08 100 0.999 0.778 9.0 8.0 0.11 11.1 12.8 Note:
CV = Coefficient of variation for control growth.
Lower CV bound determined by USEPA (10' percentile) = 3.5%.
Upper CV bound determined by USEPA (9 01h percentile) = 20%
MSD = Minimum Significant Difference PMSD = Percent Minimum Significant Difference PMSD is a measure of test precision. The PMSD is the minimum percent difference between the control and treatment that can be declared statistically significant in a whole effluent toxicity test.
Lower PMSD bound determined by USEPA (10"' percentile) = 12%.
Upper PMSD bound determined by USEPA (90"t percentile) = 30%.
CT = Central Tendancy (mean Control Growth, CV, or PMSD)
USEPA. 2000. Understanding and Accounting for Method Variability in Whole Effluent Toxicity Applications Under the National Pollutant Discharge Elimination Program. EPA-833-R-00-003. US Environmental Protection Agency, Cincinnati, OH.
7PA. 2001a, 2001b. Final Rcport: Interlaboratory Variability Study of EPA Short-term Chronic and Acute Whole Effluent Toxicity Test Methods, Volumes I and 2 endix. EPA-821-B-01-004 and EPA-821-B-01-005. US Environmental Protection Agency, Cincinnati, OH.
Organisms obtained from Aquatox, Inc.
atox04-15-08 Page 82 of 105
Pimephales promelas Chronic Refercncc Toxicant Control Chart
. T j">
Precision of Endpoint Measurements Environmental Testing Solutions, Inc.
Organism Source: Aquatox, Inc.
1.25 Z
1.00 F
0.75 9.~
0.50 o
0 USEPA Acceptance Criteria (> 0.25 mg per surviving larvae) 3 0
'J4 Kentucky Acceptance Limit (< 30.0%)
o -
3 10 30 USEPA Upper PMSD Bound (90t percentile < 30.0%)
20 10 Test date Control Reproduction, Coefficient of Variation (CV), or Percent Minimum Significant Difference (PMSD) PMSD is the minimum significant difference between the control and treatment that can be declared statistically significant.
Central Tendency (mean Control Growth, CV, or PMSD) age 83v orf lontrol Limits (mean Control Growth, CV, orPMSD +/- 2 Standard Deviations)
Environmental Testing Solutions, Inc.
Pace I of Potassium Chloride Chronic Reference Toxicant Test (EPA-821-R-02-013 Method 1000.0)
Species: Pimephales promelas I.
PpKCICR Test Number:
VSC Dilution preparation information:
Comments:
KCI CHM number:
CAti -A'+\\
Stock preparation:
50 g KCI/L: Dissolve 50 g KCI in 1-L Deionized water Dilution prep (mg/L) 450 600 750 900 1050 Stock volume (mL) 9 12 15 18 21 Diluent volume (mL) 991 988 985 982 979 Total volume (rL) 1000 1000 1000 1000 1000 Test organism information:
Test information:
Organism age:
20 t Randomizing template:
rL&e*3 Date and times organisms o-A-L0,-09 1%aO Incubator number and were born between:
shelf location:
Organism source:
ATo_-
___rc__
o_
o k-a Artemia lot number:
Qato2LOW Transfer bowl information:
pH =
SU Temperature =
'C Total drying time:
-I._
2A Date / Time in: ca4 v2-ot IZO o Average transfer volume:
6*
Date / Time out: wA'zl61 ry~o Oven temperature:
Dailyfeeding and renewal information:
Day Date Morning Afternoon Test initiation, MHS Analyst feeding feeding time renewal, or batch used time termination time 0I O
loc~-\\C~ob
\\p 1230 (z-,VO (50 a
2 O-A-vI O-bf oa 4
-\\4*0~~~~0 o
11~
O 1
cg-i6-o A 6
nt
-ot o'bb c5L)
.l-Lk Control in ormation:
Acceptance criteria Summary of test endpoints:
% Mortality:
O Z 20%
7-day LC5o ie'9.9 Average weight per initial larvae:
4 NOEC 4iSo Average weight per surviving larvae:
0.-A 2Ž 0.25 mg/larvae LOEC (aD ChV ICPg 84of10 Page 84 of 105
Environmental Testing Solutions, Inc.
Page 2 of 5 C
Species: pimephalespromelas PpKCICR TestNumber: kSO Survival and Growth Data Day Control 450 m KCI/L 600 mr KCI/L A
B C
D E
F G
H I
J K
L 0
, Oto0I 010 10 0
I ob0 1
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o I 0 10 I___I
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o to It I
I
/ID U to
/O
/O 0
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/O lo f
/
I
/
A =Pan weight (mg)
Tray color code:: c UpI1 B = Pan + Larvae weight (mg)
ZV45 12 71,11 2 51-N 7I 44:5'z U.
174 -bl M2. 1 l
zrcrS t Z7 3tu zles' Analyst: M)JA C = Larvae weight (mg)
=A-B 42 IC'A 903sl~
s l\\.&21-o,o*l s.Ai e8c~A
'4A~i j1.12-g.c\\ -i
?i.S Weight per initial number A
of larvae (mg)
O'
\\ID A
=C / Initial number of larvae V
O Average Percent weight per reduction initial from control 0LAI
,'I.5 39 2
0,137 numberof
(%)
larvae (mg)
Comment codes: c = clear, d = dead, fg fungus, k = killed, m. missing, sk sick, sm unusually small, Ig = unusually large, d&r = decanted and returned, w = wounded.
Calculations and data reviewed:
Comments:
Page 85 of 105
Environmental Testing Solutions, Inc.
Page 3 of 5 Species: Pimephalespromelas PpKCICRTestNumber:
ISO Survival and Growth Data Day 750 m KCI/L 900 m KCIIL 1050 m KCI/L 0
0N P
Q R
S T
U V
W x
0 0
0
/0(0 1
1010
/0 lb It 0
1 0 10 I o C)
O 10 to/O C
it o
0 1
1 1
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rl
~
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4~~~~z z.
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S
-1 A = Pan weight (mg)
Analyst:
M"hA I
I~
15 1-4n ISA6 140 Ltl 5 )M4 a
B = Pan + Larvae weight (mg)
Analyst:
Alt 2.0.14 11.M4 M
r-c-9 I t
C = Larvae weight (mg)
=A-B t4.3(
0 +i-t#
5.Yo 2t
- 3.
2*
z Weight per initial number of larvae (mg)
V 4
=C/Lnitial number of larvae
'9 Z 2 3r o
C)
L)
Average Percent weight per reduction initial from control C
14I4 8 Ok~t~
. 7-1 2
-12.1 7.
- o. o I
-'S 7 number of
(%)
larvae (m
Comment codes: c = clear, d = dead, fg fungus, k = killed, m = missing, sk sick, sm = unusually small, 1g = unusually large, d&r = decanted and returned, w = wounded.
Calculations and data reviewed: 4 Comments:
I Page 86 of 105
Pimephales promelas Chronic Reference Toxicant Test EPA-821 -R-02-0 13, Method 1000.0
~~~~ ~~~~~~~ ~~Quality Control Li-7~~~
I
~Verification of Data Entry, Calculations, and Statistical Analyses Test number:
PpKCICR 9150 Q Environmental Testing Solutions: Inc.
Test dates:
April 15-22, 2008 Reveiwed by:
Coetoa(aigL Relikaic tI~lOtiaulce of Finil aurobe-f A=Pm o69itighlg)
B - Pm+L-rve LArae weightlnig) Weight/S-aring Mean eioghtl (Coeffieieniofoneai-io Weight (Iitial numitee o
nri Mean-vight/llitiil
.okfiemiic f Poeccut rooloorio.
fror KQI rs larvae 19mewight (me)
-A-unberoflaivae(ng)
Suneivingnnmberof (M-.uoi-grht om of lneeemgl M%)
iumber-f larvae vAriAtiso()oato.%
lIrva 1mg)
(
r.,.i()1g)
A I0 10 14.35 23.83 9.48 0.948 U.948 Control B
1O 10 12.00 22.43 10.43 1.043 0.999 90u 1.043 100.0 0.999 9.0 Not applicable C
10 10 12.14 21.17 9.03 0.93 0.903 D
10 10 14.14 25.16 tl.02 1.102 1.102 E
10 10 14.24 24.32 10,08 1.008 1.008 450 F
10 10 14~ 13 22.62 8.49 0.849 0.915 8.1 0.849 100.0 0.915 8.1 8.4 G
I10 10O 14.28 22.89 8.61 0.861 0.861 H
tO~I 1 0 14.33 23.74 9.41 0.941 0.941 1 0 8
14.08 21.30 7.22 0.903 0.722 600 tO~~~~~~~~
1 0 14.3 5 22.3 6 8.01 0.81 084 600 0.848 6.8 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~07787.5 0.739 5.6 26.1
_________________ L I10 8
14.41 21.56 7.15 0.894 0.715 M
10 4
14.37 18.47 4.10 1.025 0.410 N
10 6
- 14. 95 19.31 4,36 0.727 0.43 6 750 0.834 15.9 55.0 0.448 13.4 55.2 0
1 0 5
14.11 18.21 4.10 0.-820 0,410
_________________ P 1 0 7
14.78 20.14 5.36 0.766 0.536 Q,
I0 4
14.61 17.49 2,88 0.720 0.288 900 It___
0 4
14.50 18.16 3.66 0,915 0.632 36.9 03645.0 0.272 26.4 72.7 I
0 6
14.77 17.09 2.32 037 0.232
_________________ T_
ItO 4
13.96 15.99 2.03 0.508 0.203 U
1 0 1
14.40 15.01 0.61 0.610 0.061 1050 ~
V 1 0 0
0.00 0.00 0.00 0,000 0600.0
.0 1050 w
0 0.00 0.00 0.00 0.000.1 0.000 2.5 0.015 200.0 98.5 X
1 0 0
0.00 0.00 0.00 0.000 0.000 Dunnett's MSD value:
0.1104 MSID Minimum Significant Difference PMSD3:
11.1 PMSD Percent Mininunm Significant Difference PMSD io a measure of test precision. The PMSD is the minimunm percent difference between the control and treatment that can be declared statistically significant in a whole effluent toxicity test.
Lower PMSD3 bound determined by USEPA (10th percentile) = 12%.
Upper PMSD hound determined by USEPA (90th percentile) = 30%.
Lower and upper PMSD bounds were determined from the I Oth and 90th percentile, respectively, of PMSD data from EPA's WET Interlaboratory Variabili ty S tudy (USEPA, 200 1a; US EPA, 200th ).
USEPA. 200Is, 2001b. Final Report: Interlaboratory Variability Study of EPA Short-temo Chronic and Acute WhoiceEffluent Toxicity Test Methods, Volumes land 2-Appendix. EPA-821.B-01-004 and EPA-821-B-01-005. US Environmental Protection Agency. Cincinnati, OH.
O)rganimsno oblained front Aqoattox, Inc, atox04-15-08
CD Statistical Analyses
.~Environmental Testing Solutions, Inc.
Larval Fish Growth and Survival Test-7 Day Survival Start Date:
4/15/2008 Test ID:
PpKCICR Sample ID:
REF-Ref Toxicant End Date:
4/22/2008 Lab ID:
ETS-Envir. Testing Sol.
Sample Type:
KCL-Potassium chloride Sample Date:
Protocol:
FWCHR-EPA-821-R-02-01 3 Test Species:
PP-Pimephales promelas Comments:
Conc-mg/L 1
2 3
4 D-Control 1.0000 1.0000 1.0000 1.0000 450 1.0000 1.0000 1.0000 1.0000 600 0.8000 1.0000 0.9000 0.8000 750 0.4000 0.6000 0.5000 0.7000 900 0.4000 0.4000 0.6000 0.4000 1050 0.1000 0.0000 0.0000 0.0000 Transform: Aresin Square Root Rank 1-Tailed Number Total Conc-mg/L Mean N-Mean Mean Mi Max CV%
N Sum Critical Resp Number D-Control 1.0000 1.0000 1.4120 1.4120 1.4120 0.000 4
0 40 450 1.0000 1.0000 1.4120 1.4120 1.4120 0.000 4
18,00 10.00 0
40 600 0.8750 0.8750 1.2188 1.1071 1.4120 11.906 4
12.00 10.00 5
40
- 750 0.5500 0.5500 0.8368 0.6847 0.9912 15.736 4
10.00 10.00 18 40
- 900 0.4500 0.4500 0.7351 0.6847 0.8861 13.697 410.00 10.00 22 40
- 1050 0.0250 0.0250 0.1995 0.1588 0.3218 40.840 4
10.00 10.00 39 40 Auxiliary Tests Statistic Critical Skew Kurt Shapiro-Wilk's Test indicates normal distribution (p > 0.01) 0.90808922 0.884 0.72032328 0.47949075 Equality of variance cannot be confirmed Hypothesis Test (1-tail, 0.05)
NOEC LOEC ChV TU Steel's Many-One Rank Test 600 750 670.820393 Treatments vs D-Control Trimmed Spearman-Karber Trim Level EC50 95% CL 0.0%
5.0%
794.25 752.88 837.89 10.0%
800.96 757.45 846.96 20.0%
807.84 755.68 863.60 Auto-2.5%
789.93 750.11 831.86 Organisms obtained from Aquatox, Inc.
atox04-1 5-08
00~~~~I 0,,
i~
Statistical Analyses f t Environmentat Testing Solutions.lnc.
Larval Fish Growth and Survival Test-7 Day Growth Start Date:
4/15/2008 Test ID:
PpKCICR Sample ID:
REF-Ref Toxicant End Date:
4/22/2008 Lab ID:
ETS-Envir, Testing Sol.
Sample Type:
KCL-Potassium chloride Sample Date:
Protocol:
FWCIIR-EPA-821-R-02-013 Test Species:
PP-Pimephales promelas Comments:
Conc-mg/L 1
2 3
4 D-Control 0.9480 1.0430 0.9030 1.1020 450 1.0080 0.8490 0.8610 0.9410 600 0.7220 0.8010 0.7170 0.7150 750 0.4100 0.4360 0.4100 0.5360 900 0.2880 0.3660 0.2320 0.2030 1050 0.0610 0.0000 0.0000 0.0000 Transform: Untransformed 1-Tailed Isotonic Conc-mg/L Mean N-Mean Mean Min Max CV%
N t-Stat Critical MSD Mean N-Mean D-Control 0.9990 1.0000 0.9990 0.9030 1.1020 9.020 4
0.9990 1.0000 450 0.9148 0.9157 0.9148 0.8490 1.0080 8.131 4
1,664 2.180 0.1104 0.9148 0.9157
- 600 0.7388 0.7395 0.7388 0.7150 0.8010 5.632 4
5.140 2.180 0.1104 0.7388 0.7395 750 0.4480 0.4484 0.4480 0.4100 0.5360 13.378 4
0.4480 0.4484 900 0.2723 0.2725 0.2723 0.2030 0.3660 26.362 4
0.2723 0.2725 1050 0.0153 0.0153 0.0153 0.0000 0.0610 200.000 4
0.0153 0.0153 Auxiliary Tests Statistic Critical Skew Kurt Shapiro-Wilk's Test indicates normal distribution (p > 0.01) 0.94532621 0.805 0.30619595
-1.1083028 Bartlett's Test indicates equal variances (p = 0.49) 1.43 829 9.2103405 Hypothesis rest (1-tail, 0.05)
NOEC LOEC ChV TU MSDu MSDp MSB MSE F-Prob df Dunnett's Test 450 600 519.615242 0.11038579 0.11049628 0.07053608 0.00512794 0.00183321 2, 9 Treatments vs D-Control Linear Interpolation (200 Resamples)
Point mg/L SD 95% CL(Exp)
Skew IC05*
266.80 114.92 37.99 612.08 0.3314 IC10 463.34 76.70 118.13 549.57
-1,2730 IC15 505.91 45.10 290.66 594.58
-1.4288 1C20 548.48 33.85 428.48 632.66
-0.5955 IC25 591.05 27.09 488.26 643.12
-0.7030 IC40 671.89 15.56 621.78 722.15 0.0988 IC5O 723.43 15.70 680.20 777.17 0.5577
- indicates IC estimate less than the lowest concentration Organisms obtainedfrom Aquatox, Inc.
atox04-15-08
I Environmental Testing Solutions, Inc.
Page 4 of 5 Species: pimephalespromelas PpKCICR Test Number: IS 0 Daily ChemistrY:
Df 0
1 2
Concentration Parameter CONTROL pH (S.U.)
7
-1 tw(A o
Conductivity (4mo cm)
LZ 3c3 Alkalinity 40CaCOg 5K Conductivity Hardness (mg CaCt3/Li Temperature pH (S.U.)
1 7.9 c
1 1.3 4 l*
1'1.
of
-~
DO(mgIL)
___.0 750 mg KCIJL Conductivity 1101
(~mos/cm ro l)
Temperature
-tA 2A-,
pH (S.U.)
7.9\\
t
-I, vs
.*80
?l~
DO (mg/L) ke CC7)t
- 18.
1 900 mg KCI/L Conductivity 1 3 D 1330 (hos/cm)
Temperature 7LI.6 / -~.s
__H (S. U.)
RanI IS 7~7 1
.~p 118 7b DO (mg/L)
~
.0 11, i
1 1
3, C 750 mg KCK L Conductivity 01.016 0 P e hos/cm90 of10 Temperature
-LA.%0 14 l-vA -S2*5
\\1*
(0c) pH (S.U.)
I.bkVI.(o I I Ut 1.L DO (mg/L)
-I I B
7-
- 0.
?
900 mg KCI/L Conductivity 11810 1~~bi
~
1C/
~~fF 880
((Lmhos/cm)
Temperature 11A.7L~
L\\.
L(*
C*
pH (S.U.)
-1.
-1o' 16 t*O 17 1 )3 DO (mgfL) 4.0 S. 0 a
1
?
1050 mg Conductivity 20o kcIA5 KCI/L
(~mos/cm)
Temperature
'c*
c.,
?lC STOCK Conductivity 1b0l (prnhos/cm) 13 initial IIFinal Initial Fn Initial
(
ia Page 90 of 105
j Environmental Testing Solutions, Inc.
Page S of 5 Species: Pimephalespromelas PpKCICR Test Number:
L5 3
4 6
Analyst IMM
/I (AsVt Concentration Parameter CONTROL pH(S.U.)
-I8$.
1 i.83 3 21 41L DO(m L) 7.9 1.5 7.%
Conductivity,
& C3 (iimhos/cm) 7300 Alkalinity (mg CaCO 3/L)
Hardness (mg CaCO 3/L)
Temperature 14 VAM C )
I Z
(
pH(S.U.)
-I1 Il4ac 7
m 831 DO (mgfL) 1.1
-1.8 F1 I
450 mg KCIL Conductivity (limhos/cm)
Temperature tAI pH(S.U.)
1.89 9 5'I
-I. ty'l VV:I Ijc5 DO (mg/L)
S'Q 78 w
600 mg KCI/L Conductivity 0S4
([imhos/cm)
Temperature pH(S.U.)
-7. -ka-1 190 i1 A7k-
____1 9
750 mg KCIIL DO(mg/L) 1, P7eI Conductivity toSC)
I (A LO
(~mhos/cm)
Temperature
%Z l
zt v.4.
-zA.
(0c)
IS-0 7C41
_V4. I-Lq.1 zZi 1 pH (S.U.)
_0 DO (mg/L) 7.8 900mg KCI/
Conductivity CJmhos/cm) i 0iO Temperature Z
z
.5 7_q 1 7 q.9 9
pH (S.U.)
('V 7A
-z'-I.81
- 2.
2'IA.
v S iN.*
i I loo~DO(mgfL)
.C
(~,
- I j7
/b 1050 mg Conductivity ZlQI7C'36R~
a(
il i~~~
oX KCI/L
(~mos/cm) z11 o7 Temperature L.
2*
7*
ZI Z*
I CS C"C)
'zq -
STOCK Conductivity (C1mhos/cm)
Initial Final I nitial Final Initial Initial Page 9lof105 j4 CtL ezrte
Ceriodaphnia dubia Chronic Reference Toxicant Control Chart
,' Environmental Testing Solutions, Inc.
1.14
~
USEPA Control Limits (+/-L 2 Standard Deviations) 1.12 1.10 1.08 1.06 1.04 1.02 2.5 USEPA Warning and Control Limits (75 and 90 Percentile CVs) 2.0z
... ~ ~ ~ ~ ~ ~~~~~.
1.5 Q
t 1.0 0.5 1.4 1.3
~Laboratory Warning and Control Limits (10 thand 25 thPercentile CVs) 1.3 1.2 1.1 1.0.
0.9 0.8 I
I
-110
?
Vf9 O
'ND e "
"M, o
2-N 8p O
O-,0-O Test date 7-day IC2 5 = 25% inhibition concentration. An estimation of the concentration of sodium chloride that would cause a 25% reduction in Ceriodaphnia reproduction for the test population.
Central Tendency (mean IC 25)
Warning Limits (mean IC 2 5 + SAAID or SA.75) age 92 ofl iaontrol Limits (mean IC25 +/- SA25' SA.90' or 2 Standard Deviations)
Chronic Reference Toxicant Control Chart Environmental Testing Solutions, Inc.
State and USEPA Laboratory Laboratory USEPA USEPA Test number Test date 7-day IC25 CT S
Control Limits SA16 Warning Limits 5 As Control Limits Ski7 Warning Limits SA.9 Control Limits CV (g/L NaC1)
(g/L NaCI)
CT-2S CT`+2S CT -S&1s CT + SAi CT - SAz2 CT + SA25 CT -S&is CT+ SA.is CT-SA.90 CT +SA,9 1
11-07-06 1.06 2
12-12-06 1.09 1.08 0.02 1.04 1.12 0.09 0.99 1.17 0.18 0.90 1.26 0.49 0.59 1.56 0.67 0.41 1.75 0.02 3
01-09-07 1.07 1.08 0.02 1.05 1.11 0.09 0.99, 1.16 0.18 0.89 1.26 0.48 0.59 1.56 0.67 0.41 1.75 0.01 4
02-06-07 1.09 1.08 0.01 1.05 1.11 0.09 0.99 1.17 0.18 0.90 1.26 0.49 0.59 1.57 0.67 0.41 1,75 0.01 5
03-06-07 1.09 1.08 0.01 1.06 1.11 0.09 1.00 1.17 0.18 0.90 1.27 0.49 0.60 1.57 0.67 0.41 1.75 0.01 6
04-03-07 1.10 1.08 0.01 1.06 1.11 0.09 1.00 1.17 0.18 0.90 1.27 0.49 0.60 1.57 0.67 0.41 1.76 0.01 7
05-08-07 1.10 1.09 0.01 1.06 1.11 0.09 1.00 1.17 0.18 0.90 1.27 0.49 0.60 1.58 0.67 0.41 1.76 0.0!
8 06-05-07 1.10 1.09 0.01 1.06 1.11 0.09 1.00 1.17 0.18 0.90 1.27 0.49 0.60 1 58 0.67 0.4!
1.76 0.01 9
07-10-07 1.06 1.08 0.02 1.05 1.12 0.09 1.00 1.17 0.18 0.90 1.27 0.49 0.60 1.57 0.67 0.41 1.76 0.01 10 08-07-07 1.10 1.09 0.02 1.06 1.12 0.09 1.00 1.17 0.18 0.90 1.27 0.49 0.60 1.57 0.67 0.41 1.76 0.0!
11 09-05-07 1.08 1.09 0.01 1.06 1.11 0.09 1.00 1.17 0.18 0.90 1.27 0.49 0.60 1.57 0.67 0.41 I 76 0.01 12 10-02-07 1.06 1.08 0.02 1.05 1.11 0.09 1.00 1.17 0.18 0.90 1.27 0.49 0.60 1.57 0.67 0.41 1.76 0.0!
13 11-06-07 1.06 1.08 0.02 1.05 1.11 0.09 0.99 1.17 0.18 0.90 1.27 0.49 0.59 1.57 0.67 0.41 1.75 0.02 14 11-06-07 1.07 1.08 0.02 1.05 1.11 0.09 0.99 1.17 0.18 0.90 1.26 0.49 0.59 1.57 0.67 0.41 1.75 001
.15 12-04-07 1.07 1.08 0.02 1.05 1.11 0.09 0.99 1.17 0.18 0.90 1.26 0.49 0.59 1.57 0.67 0.41 I 75 0.01 16 01-08-08 1.09 1.08 0.02 1.05 1.11 0.09 0.99 1.17 0.18 0.90 1.26 0.49 0.59 1.57 0.67 0.41 1.75 0.01 17 01-08-08 1.09 1.08 0.01 1.05 1.11 0.09 0.99 1.17 0.18 0.90 1.27 0.49 0.59 1.57 0.67 0.41 1.75 0.01 18 02-05-08 1.07 1.08 0.01 1.05 1.11 0.09 0.99 1.17 0.18 0.90 1,26 0.49 0.59 1.57 0.67 0.41 1.75 0.01 19 03-04-08 1.07 1.08 0.01 1.05 1.11 0.09 0.99 1.17 0.18 0.90 1.26 0.49 0.59 1.57 0.67 0.41 1.75 0.01 20 04-08-08 1.07 1.08 0.01 1.05 1.11 0.09 0.99 1.17 0.18 0.90 1.26 0.49 0.59 1.57 0.67 0.41 1.75 001 Note:
7-d1 lC2 day 25% inhibition concentration. An estimation of the concentration of sodium chloride that would cause a 25% reduction in Ceriodaphnia reproduction for the test population CT Central tendency (mean IC25).
S = Standard deviation of the IC25 values.
Laboratory Control and Warning Limits Laboratory control and warning limits were established ustng the standard deviation ofthe IC25 values corresponding to the 10th and 25th percentile CVa.
These ranges are more stringent than the control and warning limits recommended by USEPA for the test method and endpoint.
SA.0 = Standard deviation corresponding to the 10Ih percentile CV. (SA1
= 0.08)
SA.25 = Standard deviation corresponding to the 2 5a percentile CV. (SA25 = 0.17)
USEPA Control and Warning Limits SA.75 = Standard deviation corresponding to the 755t percentile CV. (SA.75 = 0.45)
SA.90 = Standard deviation corresponding to the 90 '0 percentile CV. (Skis = 0.62)
CV = Coefficient of variation of the IC25 values.
USEPA 2000 Understanding and Accounting for Method Variability in Whole Effluent Toxicity Applications Under the National Pollutant Discharge Elimination Program. EPA-833-R-00-003. US Environmental Protection Agency, Cincinnati, 011 04.05.05
Precision of Endpoint Measurements AN Ceriodaphnia dubia Chronic Reference Toxicant Data
>~_~
Environmental Testing Solutions, Inc.
est TControl Control Mean CT CV CT MSD PMSD CT number Survival Reproduction for Control Mean for Control
(%)
(offspring/female)
Reproduction
(%)
Reproduction
(%)
for PMSD (%)
(offspring/female)
Cv (%)
1 11-07-06 100 31.0 6.3 2.4 7.8 2
12-12-06 100 28.0 29.5 6.7 6.5 2.2 8.0 7.9 3
01-09-07 100 27.6 28.9 4.9 6.0 2.4 8.6 8.1 4
02-06-07 100 29.9 29.1 7.6 6.4 2.9 9.8 8.6 5
03-06-07 100 30.1 29.3 6.0 6.3 2.6 8.7 8.6 6
04-03-07 100 33.1 30.0 4.4 6.0 2.2 6.6 8.3 7
05-08-07 100 32.0 30.2 8.5 6.3 2.7 8.4 8.3 8
06-05-07 100 28.4 30.0 7.5 6.5 2.5 8.7 8.3 9
07-10-07 100 29.3 29.9 6.0 6.4 2.5 8.5 8.3 10 08-07-07 100 28.7 29.8 7.5 6.5 2.9 10.0 8.5 11 09-05-07 100 29.7 29.8 5.7 6.5 2.5 8.4 8.5 12 10-02-07 100 29.5 29.8 9.4 6.7 2.4 8.2 8.5 13 11-06-07 100 28.0 29.6 6.1 6.7 2.5 8.8 8.5 14 11-06-07 100 30.4 29.7 5.6 6.6 2.2 7.2 8.4 15 12-04-07 100 31.8 29.8 5.5 6.5 2.5 7.9 8.4 16 01-08-08 100 30.3 29.9 6.6 6.5 2.2 7.3 8.3 17 01-08-08 100 31.8 30.0 4.9 6.4 2.4 7.7 8.3 18 02-05-08 100 31.3 30.1 6.4 6.4 2.8 9.1 8.3 19 03-04-08 100 31.5 30.1 8.0 6.5 2.7 8.5 8.3 20 04-08-08 100 29.6 30.1 7.7 6.6 2.6 8.8 8.4 Note:
CV = Coefficient of variation for control reproduction.
Lower CV bound determined by USEPA (10th percentile) = 8.9%.
Upper CV bound determined by USEPA (90'h percentile)= 42%
MSD = Minimum Significant Difference PMSD = Percent Minimum Significant Difference PMSD is a measure of test precision. The PMSD is the minimum percent difference between the control and treatment that can be declared statistically significant in a whole effluent toxicity test.
Lower PMSD bound determined by USEPA (1 0 h percentile) 13%.
Upper PMSD bound determined by USEPA (9 0'h percentile) 47%.
CT = Central Tendancy (Mean Control Reproduction, CV, or PMSD)
USEPA. 2000. Understanding and Accounting for Method Variability in Whole Effluent Toxicity Applications Under the National Pollutant Discharge Elimination Program. EPA-833-R-00-003. US Environmental Protection Agency, Cincinnati, OH.
USEPA. 200 Ia, 2001 b. Final Report: Interlaboratory Variability Study of EPA Short-term Chronic and Acute Whole Effluent Toxicity Test Methods, Volumes 1 and 2-Appendix. EPA-821-B-0l-004 and EPA-821-B-01-005. US Environmental Protection Agency, Cincinnati, OH.
04-08-08 Page 94 of 105
Ceriodaphnia dubia Chronic Reference Toxicant Control Chart I~~~~~~~eicahi Chroni Li Precision of Endpoint Measurements u.-
Environmental Testing Solutions, Inc.
40 35 a
30
~ c~D25 O
20 o
15 Minimum Acceptance Criteria (> 15.0 offspring per surviving female) 40 North Carolina Acceptance Limit (< 40.0%)
0
';:a 30 Kentucky Acceptance Limit (< 30.0%)
"o -~20 20 I
I I..
30 eti 20 10 0
I I
I I
I6I I
30~~~~~~~~~~~~~Q Test date
-'---Control Reproduction, Coefficient of Variation (CV), or Percent Minimum Significant Difference (PMSD) PMSD is the minimum significant difference between the control and treatment that can be declared statistically significant.
Central Tendency (mean Control Reproduction, CV, or PMSD) age 9 of 1 ontrol Limits (mean Control Reproduction, CV, or PMSD +/- 2 Standard Deviations)
Environmental Testing Solutions, Inc.
Page 1 of 6 Sodium Chloride Chronic Reference Toxicant Test (EPA-821-R-02-013 Method 1002.0)
Species: Ceriodaphnia dubia I
CdNaCLCR #:
Dilution preparation information:
Comments:
NalCHM number
- CIA R 17-0 Stock preparation:
100 g NaCI/l (dissolve 50 g NaCI in 500 ml deionized water)
Dilution prep (rg/L) 600 800 1000 1200 1400 Stockvolume(mL 9
12 15 18 21 Diluent volume (mL) 1491 1488 1485 1482 1479 I
Total volume (mL) 1500 1500 1500 1500 1500 Test or anism source information:
Test information:
Organism age
< 24-hours old Randomizin ternlate color:
Date and times organisms were born c+4-oln 4oTo m a
r0o Incubator number and shelf between:
location:
'z Culture board:
Replicate number:
1 2
3 4
5 6
7 8
9 to YWT batch:
Culture board number:
I I L B
SI I 'I I 4
Transfer bowl information:
H= 3.t SU Ternerature =
'.44 "C
Selenastrum batch:
b Daily renewal information:
Day Date Test initiation and feeding, MHSW Analyst renewal and feeding, or batch used termination time 0
I I
-og-~~
\\SO?
oc2 M-Cs-02 3
UA-11-ok q&-
4 04_12_0\\cl S
osk 1
5 O~l, &- O&
J-42os I
s ocl-n~~ap I~Zo I
6 O+ 1+04 1 4 t) 7 04-ts-0 1'5' I
Control information:
Acceptance criteria Summary of test endpoints:
% of Male Adults:
<20%
7-day LC5 0 iIOC
% Adults having 3 d Broods:
ŽOr 80%
NOEC IoN I
% Mortality:
-5
- 20%
LOEC Mean Offspring/Female:
Žb 15.0 offspring/female ChV
,o'IS.
% CV:
< 40.0 %
IC,,________
Page 96 of 105
now`=,"
Environmental Testing Solutions, Inc.
Page 2 of 6 Species: Ceriodaphnia dubia CdNaCLCR #:
I__
CONTROL Survival and Reproduction Data Replicate number Day I
2 3
4 6
7 8
9 lo 1
Young produced S
0 O
Ig 0l Adult mortality
\\
2 Young produced J 2
CSungproduce I-E 1
3~
T OuO~
'-"-IO~~~
I Adult mortality L.
L. +
3 Young produced Adult mortality I J J L
L V
i 4
Young produced 3_
)
If ti \\
\\I 1 I
\\
Adult mortalil L-I L
5 Young produced IZ,()
o lo
\\3 a
1 6} Adult mortality 1 4L
~
1 " I ' _
7 Young produced jI7 L
i V
j ji
'5 Totalyoung produced 23S
-L Z-3c 1 2>
0 31 a30 i33 Final Adult Mortality
\\-
Q
\\-
\\L X for P Broods
...x. i....-,
x Note: Adult mortality (L = live, D = dead), SB split brood (single brood split between two days), CO - carry over (offspring carried over with adult during transfer).
Concentration:
I% Mortality:
67 Mean OffspnWl emale:
2j *o 600 mg NaCl/L Survival and Reproduction Data Replicate number Day 2
__ 3 I
5 6
7]
8[ 9 10 1
Young produced 30 -
L 0
Ic_
Adult mortality_
'LL L
2 Young produced Cj7 7 a
Adult mortality 3
Young produced C)
C:
c c
0 cO c
O Adult mortality 1
L.
k-t-
I
~~~~~~~4 Young produced+
IS S
4 3
C 1b 1:3 1
3 Adult mortality [
_ L L
4 Young produced l 1
III'-
Adult mortality L
13 P
[Youn~~~~~~~~~produced 7
_A It 1
L I I
ulmortalit II-U I
l_ _
I-
_I 6
Young produced tO I6 1
2 Jits '31 t10 IJ 1
TotalYoung produced I
-a j
a Total young produced 2 (
30 3
34.
4v
-L-3i 2.\\
Final Adult Mortality I
L-L IL I,
L-IL-IL Note: Adult mortality (L = live, D = dead), SB split brood (single brood split between two days), CO = carry over (offspring carried over with adult during transfer).
Concentration:
1%
Mortality:
Mean Offspring/Female.,
i Page 97 of 105 R
e d
u ct ion fronontrol.
-c;
Environmental Testing Solutions, Inc.
Page 3 of 6 Species: Ceriodaphnia dubia CdNaCLCR #: -- I'A 800 mg NaCIJL Survival and Reproduction Data Replicate number Da 1
2 3
4 1 5 6
7 8
9 10 I
I Young produced j
0 0
0 Q
0 0{
0 Adult mortality t
J L
2 Youngproduced
__I Adult mortality 3
Young produced O
o T Adult mortality L_
I J 4
Young produced
'A Adult mortality e
6 Young produced I a2.
iO
'bO O
r 'f Adult mortality I L.
I 6
Young produced Adult mortality I r
7 Young produced I 'A A~L 5
1 C
Total young produced 1 q
zo, 21 35s
-a 3C
-r-
,N Final Adult Mortality
\\
\\
Note: Adult mortality (L = live, D = dead), SB split brood (single brood split between two days), CO = carry over (offspring carried over with adult during transfer).
Concentration:
% Mortality:
C1.
Mean Offspring/Female:
2 920.0
% Reduction from Control:
1*0?I 1000 mg NaClfL Survival and Reproduction Data Replicate number Day 1
2 3
4 5
6 7
8 9
10 Adult mortality 2
Young produced I
_0 1
Adult mortality 2
Young produced d
0 0
C c
c I
Adult mortality I L
J jL 1
I '
3 [Young produced I
~
~
i
[oI o
c o
Adult mortality L
- I -
Young produced Adult mortality 6
Young produced I) 1 1
'I f1 I T '3 Adult mortality
[
- I L
_ _ ___I I
Young produced LS T
12 Z
'A
-L3 I
1$
3 Total young produced
-Z 21
-L S 32 2
78 25 7
2 Final Adult Mortality U J L.
Nore: Adult mortality (L = live, D dead), SB = split brood (single brood split between two days), CO = carry over (offspring carried over with adult during transfer).
Concentration:
% Mortality:
01 Mean Offspring/Female:
21 '4 1Page 98 of 105 O/o Reductionr from Control:
147
Environmental Testing Solutions, Inc.
Page 4 of 6 Species: Ceriodaphnia dubia CdNaCLCR 1200 mg NaCIJL Survival and Reproduction Data Replicate number Day 1
2 3
4 5
6 7
8 9
10 I
1 ~~Young produce 0IO O
01 1
Adult mortality L J Young produced c
L-Adult mortali L-L 4
Young produced O
o O
O e.
Adult mortality I
4
~~~~~~~Young produced o
o 03 j
Adult mortality
.- 1 V-6 Young produced sSO O
Adult mortality j U S
I 7
Young produced I
IL A
c Adult mortality Ii L tJ L
L
-LI i-.
I
~7]1 Young produced L\\
- 2.1
'A
_____1 Total young produced 117 7
\\
-b z..
'S 13 ho Final Adult Mortality L
Note: Adult mortality (L = live, D dead), SB = split brood (single brood split between two days), CO cany over (offspring carried over with adult during transfer).
Concentration:
I
~
~~~~~~~~~~~~~~~~~~~%
Mortality Mean O
rinFemale:
I
% Reduction from Control:
.7.1 1
1400 mg NaCIL Survival and Reproduction Data Replicate number Day 3_46_
1 2
3 4
5 6
7 8
9 10 1
Young produced J_
Adult mortality t-Young produced 10 n
O OC1 o
I Adult mortality I C
C C
I 3
Young produced Adult mortality L
C
_ L L..
L L
L 2
Young produced 1 0
l IL Adult mortality LL L
L L
L 1 Young produced 1
)
0L10 0 0I c
Adult mortality L
L L
L L
6 Young produced JO C
OILIO J
[L Adult mortality i'.
L I
5 Young produced IL 0
3 fT-LIo oOfOfc Total young produced L
C Final Adult Mortality L-L I ~~~~~Note: Adult mortality (L = live, D =dead), SB split brood (single brood split between two days), CO carry over (offspring carried over with adult during transfer).
6 Young produced Itr
'3r of olol~Concentration:
% Mortalit:
I7.
Mean Offspring/Fernale:
1.
j Pa-e 99 of 105
% ReductionYfrom Control:
)
C
~~ 7
~~~Verification of Ceriodaphnia Reproduction Totals Environmental Testing Solutions, Inc.
Control __________________1000 mg NaCII Day
~~~~Re ficate number TtlDyReplicate numberIoa Da 1-3 4
5 a-6 y--j8 Tota Da
-j 3
4 5
6 7
8 9
10 Toa I
0 0
0 0
0 0
0 0
0 0
0 1
0 0
0 0
0 0
0 0
0 0
0 2
0 0
0 00 0
00 0
0 0
2 0
0 0
0 00 0
0 0
0 0
3 0
0 00 00 0
000 0
3 0
0 0
00 0
00 0
0 0
4 3
3 3
3 3
4 3
5 3
3 33 4
3 3
3 3
4 3
3 3
4 4
33 0
0 0
0 0
010 0
00 0
5 0
0 0
0 0
00 0
0 0
0 6
1 10 114 12 1 1
13 li13 206 to 11 9
10 12 12 1 1 10 I10 13 108 7
1 12 1
13 16 16 1
5114I 437 15 131 12 12 113 14 12 13 133
~
~
~
~~~----3-3 29 3
-0
-8 27
-2 28
-28 Toa 82 2
2 03 9
3 03 9
o28 28 7
242 32 28 28 25 27 30 27 600 mg NaCIJL 1200 mg NaCIIL Day Replicate number TtlDyReplicate number Total 2 314 5
Total Day -y---2-3 4
5 6
7 8
9 10 I
0 10 0
0 0
0 0
0 0
0 0
I 0
0 0
0 0
0 0
0 0
0 0
2 0
0 00 0000 000 0
0 2
00_0 00 00 0
00 0
3 0
0 0
0 0
0 0
0 0
0 0
3 0
0 0
0 0
0 0
0 0
0 0
4 5
33 34 43 3
33 34 4
3 12 0
0 3
33 12 0
17 5
0 o
0 0h0 0o o
li0 5
_0 o3V o
0h11Th 6
6 13 10 12 12 14 1 1 10 1
12 10 117 6
6 9
6 4
7 2
5 5
8 3
55 7
16 1315 1516 14 14 1316 1
146 7
8 4
07 6
2 4
7 3
5 46 Total 3426 30 30 34 29 27 29 31 27 297 Total 17 15 7
4 16 7
2 3
13 t
124 800 mg NaCIJL
______1400 mg NaCIIL Day ~
Replicate number Total Day-Replicate number Total Day 1
2 3
4 5
6 7
8 9
10 ay 1
2 3
4 15 6
7 8
9 10 1
0 0
0 0
0 0
0 0
0 0
0 1
0 0
0 0
0 0
0 0
0 0
0 2
00 00 0
00 0
0 0
0 2
0 00 0
000 0
00 0
3 0
0 0
0 0
0 0000 0
3 0
00 00 00 0
00 0
4 3
4 4
4 3
3 4
3 3
3 34 4
0 0
0 2
0 1
3 1
1 3
11 5
00 00 00 0
00 0
0 5
1063 02 00 000 6
6 12 1 1 10~ 1 4
1 1
1 1 1 1 12 10I 1 2
114 6
2 3
0 0
0 2
0 3
1 1
1 2 7
14 4
3 2
1 5 1
1 142 7
0 0
312 2
0 4010 0
1 1
Total 29 2927 3
2 2630 8
9 9
20Total 3
3 634437442 4
40 a
aa aa a
a a
a
r9 Ceriodaphnia dubia Chronic Reference Toxicant Test EPA-821-R-02-013, Method 1002.0 liii Verification of Data
~Quality Control
-~ ~~~~~Vrfctono aaEntry, Calculations, and Statistical Analyses Environmental Testing Solutions, iTsnnme:c.aIC 7
Test dates:
April 08-15, 2008 Reveiwed by:
Concentration Replicate number
______Survival Average reproduction Coefficient of Percent reduction from
~(mg/L NaCI) 1 2
3 4
5 6
7 8
9 10
(%)
(offspring/female)
Yarimtion %)control
(%)
Control 28 25 32 28 30 31 29 30 30 33 100 29.6 7.7 Not applicable 600 34 26 30 30 34 29 27 29 31 27 100 29.7 9.3
-0.3 800 29 29 27 35 28 26 30 28 29 29 100 29.0 8.3 2.0 1Q00 28 27 24 25 32 28 28 25 27 30 100 27.4 8.8 7.4 1200 17 15 7
14 16 7
12 13 13 10 100 12.4 28.0 58.1 1400 3
3 6
4 4
3 7
4 2
4 100 4.0 37.3 86.5 Dunnett's MSD value:
2.593 MSD =
Minimum Significant Difference PMSD:
8.8 PMSD =
Percent Minimum Significant Difference PMSD is a measure of test precision. The PMSD is the minimum percent difference between the control and treatment that can be declared statistically significant in a whole effluent toxicity test, Lower PMS D bound determined by USEPA (10Ot percentile) 13%.
Upper PMSD bound determined by USEPA (9 0th~ percentile) =47%.
Lower and u pper PMSD bounds were determined from the 10th and 90th percentile, respectively, of PMSD data from EPA's WETr Interlaburatory Variability Study (USEPA, 2001 a-,USEPA, 200 1b),
USEPA. 2001 a, 2001 b. Final Report: Interiaboratory Variability Study of EPA Short-term Chronic and Acute Whole Effluent Toxicity Test Methods, VolumeslIand 2-Appendix. EPA-821I-B-0 1-004 anldEPA-82 1-B-0 1-005-US Environmental Protection Agency, Cincinnati, OH.
~B
~
Statistical Analyses
('
i__
__~z*s
, Environmental Testing Solutions, Inc.
Ceriodaphnia Survival and Reproduction Test-Reproduction Start Date:
4/8/2008 Test ID:
CdNaCICR Sample ID:
REF-Ref Toxicant End Date:
4/15/2008 Lab ID:
ETS-Envir. Testing Sol.
Sample Type:
NACL-Sodium chloride Sample Date:
Protocol:
FWCHR-EPA-821-R-02-013 Test Species:
CD-Ceriodaphnia dubia Comments:
Conc-mg/L 1
2 3
4 5
6 7
8 9
10 D-Control 28.000 25.000 32.000 28.000 30.000 31.000 29.000 30.000 30.000 33.000 600 34.000 26.000 30.000 30.000 34.000 29.000 27.000 29.000 31.000 27.000 800 29.000 29.000 27.000 35.000 28.000 26.000 30.000 28.000 29.000 29.000 1000 28.000 27.000 24.000 25.000 32.000 28.000 28.000 25.000 27.000 30.000 1200 17.000 15.000 7.000 14.000 16.000 7.000 12.000 13.000 13.000 10.000 1400 3.000 3.000 6.000 4.000 4.000 3.000 7,000 4.000 2.000 4.000 Transform: Untransformed Rank I-Tailed Isotonic Conc-mg/L Mean N-Mean Mean Min Max CV%
N Sum Critical Mean N-Mean D-Control 29.600 1.0000 29.600 25.000 33.000 7.671 10 29.650 1.0000 600 29.700 1.0034 29.700 26,000 34.000 9.262 10 103.50 75.00 29.650 1.0000 800 29.000 0.9797 29.000 26.000 35.000 8.289 10 90.50 75.00 29.000 0.9781 1000 27.400 0.9257 27.400 24.000 32.000 8.806 10 78.00 75.00 27.400 0.9241
- 1200 12.400 0.4189 12.400 7.000 17.000 27.988 10 55.00 75.00 12.400 0.4182
- 1400 4.000 0.1351 4.000 2.000 7.000 37.268 10 55.00 75.00 4.000 0.1349 Auxiliary Tests Statistic Critical Skew Kurt Kolmogorov D Test indicates non-normal distribution (p <=0.01) 1.06443608 1.035 0.13583268 0.20973463 Bartlett's Test indicates equal variances (p = 0.30) 6.04413986 15.0862722 Hypothesis Test (1-tail, 0.05)
NOEC LOEC ChV TU Steel's Many-One Rank Test 1000 1200 1095.44512 Treatments vs 0-Control Linear Interpolation (200 Resamples)
Point mgfL SD 95% CL Skew IC05 904.0625 119.866905 500 1008.5744
-1,506]
ICIO 1009.53333 33.8804056 909.793846 1026.79054
-4.1474 IC15 1029.3 11.0645749 1010.98453 1044.77374
-2.3204 IC20 1049.06667 9.00623974 1031.52481 1064.62874
-0.0865 IC25 1068.83333 8.76984615 1051.34159 1084.63576
-0.0832 IC40 1128.13333 9.83797147 1107.13978 1146.30303
-0.1673 IC50 1167.66667 11.7104665 1143.50156 1187.52409
-0.1347 04-08-08
0 Statistical Analyses N
Environmental Testing Solutions, Inc.
ftub CALCOLATIOA. OWL4.
Ceriodaphnia Survival and Reproduction Test-Reproduction Start Date:
4/8/2008 Test ID:
CdNaCICR Sample ID:
REF-Ref Toxicant End Date:
4/15/2008 Lab ID:
ETS-Envir. Testing Sol.
Sample Type:
NACL-Sodium chloride Sample Date:
Protocol:
FWCHR-EPA-821I-R-02-013 Test Species:
CD-Ceriodaphnia dubia Comments; Conc-mg/L 1
2 3
4 5
6 7
8 9
10 D-Control 28.000 25.000 32.000 28.000 30.000 31.000 29.000 30.000 30.000 33.000 600 34.000 26.000 30.000 30.000 34.000 29.000 27.000 29.000 31.000 27.000 800 29.000 29.000 27,000 35.000 28.000 26.000 30.000 28.000 29.000 29.000 1000 28.000 27.000 24.000 25.000 32.000 28.000 28.000 25.000 27.000 30.000 1200 17.000 15.000 7.000 14.000 16.000 7.000 12.000 13.000 13.000 10.000 1400 3.000 3.000 6.000 4.000 4.000 3.000 7.000 4.000 2.000 4.000 Transform: Untransformed I-Tailed Conc-mg/L Mean N-Mean Mean Min Max CV%
N t-Stat Critical MSD D-Control 29.600 1.0000 29.600 25.000 33.000 7.671 10 600 29.700 1.0034 29.700 26.000 34.000 9.262 10
-0.088 2.287 2.593 800 29.000 0.9797 29.000 26.000 35.000 8.289 10 0.529 2.287 2.593 1000 27.400 0.9257 27.400 24.000 32.000 8,806 10 1.940 2.287 2.593
- 1200 12.400 0.4189 12.400 7.000 17.000 27.988 10 15.166 2.287 2.593
- 1400 4.000 0.1351 4.000 2.000 7.000 37.268 10 22.572 2.287 2.593 Auxiliary Tests Statistic Critical Skew Kurt Kolmogorov D Test indicates non-normal distribution (p <= 0.01) 1.06443608 1.035 0.13583268 0.20973463 Bartlett's Test indicates equal variances (p = 0.30) 6.04413986 15.0862722 Hypothesis Test (1-tail, 0.05)
NOEC LOEC ChV TU MSDu MSDp MSB MSE F-Prob df Dunnett's Test 1000 1200 1095.44512 2.59342303 0.08761564 1222.73667 6.43148148 5.5E-33 5, 54 Treatments vs D-Control 04-08-08
Environmental Testing Solutions, Inc.
Page 5 of 6 Species: Ceriodaphnia dubia CdNaCLCR #:
i'4 Daily Chemistry:
Dav 0 ______2 Y__
Analyst 1 "W j
X-)
S IU~
y Concentration Parameter pH (S. U.)
~*'
) ~R 51)~57 1
~.
1.~
DO (mh/)
8.
CONTROL Conductivity I
~~~~~(jirhos/cm)3) 1689~~3*1 Igghlga 1
I
~~~~~~~(
mhoslcm)
Alkalinity (mg CaCO3/L) 5 Hardness (mg CaCO,/>
/L) 9L9~
I~~~gs~
d Temperature pH (S.U.)
(e~S I.i 3L~ II.p
~C I-8 DO (mg/L) 8.0I I?
1 600 mg NaCl/L Conductivity 1363 0
( mhos/cm) i) L~O Temperature PgeA f15 A
pH (SU.)
7,17 I-Latp
-I kA -A qQ5 800 mg NaCl/L Conductivity (mhos/cm) i~~Lo~i so, Itc)ei
?a Temperature S-t7AL4 pH (S.U.)
A.
-I 7-tA3
?(C 17~3
) ~I If~
DO (mg/L) t
_.b 11/r 3C 8-0 1000 mg NaCl/L Conductivity (mhs/cm a) i'?065 0~a
~
t
~seisg 75 Temperature
-L 7 ~LSJ4 rlS zq A 7~'
(1)Q pH(S.U.)
M -*a T
-1
) 74 I 7.t Lt 3_1
~~
DO (mg/L)
-I
- 1 1I)~1 1.
.9 1200 mg NaCUL Conductivity
((mhos/cm )
lu Iifif~~lo
~
aa Temperature V 9~t(.k 7-*
pH (S.U.)
-1.r 1
-3U36
=~F 33 DO (mg/L) 13 r1~
Iao 11.9 1400 mg NaCUL Conductivity
(~ios/cm) lot( ~~aE~~
~~
3300 Temperature Z*
I7l9Itlg Z*a t*
C~
STOCK Cond ctivity
((inihouscm) 010~0 ~
Initial Final Initial ia ntl nl Page 104 of 05
)AwA cetL CONSTA 0WI r a b %)L-TP4 t-e
Environmental Testing Solutions, Inc.
Page 6 of6 Species: Ceriodaphnia dubia CdNaCLCR#:
iLA 3
4 5
6 Analyst m4t Concentration Parameter H (S.U.)
I-CH 8.0
.0
-*.q i-q
.1 DO (mg/L) l.C 1
9, 1
CONTROL Conductivity
- ~~~~~~~~~~~~a 600~li mgC NaCI/L Conductivity 5(~imhos/cm)
Alkalinity 5
(mg CaCO3/L)
Hardness Iag CaCOt/L)vt Temperature
-VA
&o4 p H ( S.U.) o w DO (mg/L)
I 8.0 1.9
'*L1 1
1 9'o 100 mg NaCI/L Conductivity (4tmhos/cm)
Temperature (0C)
-I'S 0*
2(,
2L
-Ls 0 l*
-L*
H (S.U.)
_ _ _ _ _ _ _ _ _ (
C )
_ _ 4 1__
_ _ _1
-IA D_
1__
DO (mg/ )
I-Lo 1..
- 14.
1.
100 mg NaCIJL Conductivity 3c 0a)
(~mhos/cm )
~
80Iiii 98 iBIP 8c Temperature
( 0C)
_______~
4-5*
LL.
C pH(S.U.) qenItt 18.(
1799 795 7~
8 17Q i74 DO (mg/IL)
I.-I 1
- 77*1 1177
?
I ~
1000 mg NaCI/L Conductivity (Vmh s/cm)
Temperature I
Z t
z'.i
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AB I
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.15
.70 1
- 9L 7.9 Ct 1
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-75 1
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-T-UV 1 I.9 I
-95 79 7
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Temperature 214.1
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Initial jjFinal Initial IIFnlIInitial Fn Initial ia PaPge 105 -of105
PERMITTEE NAME/ADDRESS (Include Facility Name/Location if Different)
NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPDES)
MAJOR Form Approved.
Name TVA - SEQUOYAH NUCLEAR PLANT DISCHARGE MONITORING REPORT QDMR)
(SUBR 01) 0MB No. 2040-0004 Address P.O. BOX 2000 Z _ I
_LNTOFFI(LE S13-2,A)..
TN0026450 103 G FFINAL SODDY -DAISY TN 37384 PERMIT NUMBER DISCHARGE NUMBER LOW VOL. WASTE TREATMENT POND Facility TVA -SEQUOYAH NUCLEAR PLANT Location HAMILTON COUNTY M )NITaRING PERIOD EFFLUENT YEAR MO DAY YEAR I MO I DAY NO DISCHARGE J
ATTN: Stephanie A. Howard From 08 04 01 To 08 04 30 NOTE: Read instructions before completing this form.
PARAMETER QUANTITY OR LOADING QUALITY OR CONCENTRATION NO.
FREQUENCY SAMPLE EX OF TYPE AVERAGE MAXIMUM UNITS MINIMUM AVERAGE MAXIMUM UNITS
~~~~ANALYSIS PH SAMPLE 7.6 8.9 12 0
13I30 GRAB MEASUREMENT
/00400 1
0 0
PEMT6090suTHE/
RA EFFLUENT GROSS VALUE SU SOLIDS, TOTAL SUSPENDED SAMPLE 66 80 26 7
9 5/30 GRAB MEASUREMENT 26 00530 1
0 0
LBS/DY MGILW KLY EFFLUENT GROSS VALUE OIL AND GREASE SAMPLE
<47
<58 26
<5
<6 19 0
5/30 GRAB MEASUREMENT 00556 1
0 0
TLBSDY EFFLUENT GROSS VALUE FLOW, IN CONDUIT OR THRU SAMPLE 1.138 1.473 MO AV DAILY0 30/30 TOTALZ TREATMENT PLANT MEASUREMENT 03 50050 1
0 0
IMGD SlEERA EFFLUENT GROSS VALUE AVG DAI.Y 1MV MIT MEASUREMENT SAMPLE MEASUREMENT PERI SAMPLE MEASUREMENT NAME/TITLEPRINCIPALEXECUTIVEOFFICERI certify under penalty of law that this document and all attachments were prepared under my TELEPHONE DATE direction or supervision in accordance with a system designed to assure that qualified personnel W)C'&C4
.)c Timothy P. Cleary properly gather and evaluate the information submitted. Based on my inquiry of the parson or persons who manage the system, or those persons directly responsible for gathering the Principal Environmental Engineer 423 843-6700 08 05 13 information, the information submitted is, to the best of my knowledge and belief, true, 423_843_6700________3 accurate, and complete. I am aware that there are significant penalties for submitting false SIGNATURE OF PRINCIPAL EXECUTIVE information, including the possibility of fine and imprisonment for knowing violations.
OFFICER OR AUTHORIZED AGENT AREA NUMBER YEAR MO DAY TYP~ED OR P'RINTED COPE COMMENTS AND EXPLANATION OF ANY VIOLATIONS (Reference all attachments here)
EPA Form 3320-1 (REV 3199)
Previous editions may be used Page 1 of 1
PERMITTEE NAME/ADDRESS (Include Facility NamelLocation if Different)
NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPDES)
MAJOR Form Approved.
Name TVA - SEQUOYAH NUCLEAR PLANT DISCHARGE MONITORING REPORT (DMR)
(SUBR 01) 0MB No. 2040-0004 Address P.O. BOX 2000
_LINTI O[
E
-2LA)FTN0026450 107 G I F-FINAL SODDY - DAISY-TN 37384 L
PERMIT NUMBER DISCHARGENUMBER METAL CLEANING WASTE POND Facility TVA -_SEOUOYAH NUCLEAR PLANT Location HAMILTON COUNTY MONITORING PERIQQ EFFLUENT DA YEAR MO DANODISCHARGE ATTN: Stephanie A. Howard From 08 04 01 To 08 04 30
.C NOTE: Read instructions before completing this form.
PARAMETER QUANTITY OR LOADING QUALITY OR CONCENTRATION NO.
FREQUENCY SAMPLE EX OF TYPE AVERAGE MAXIMUM UNITS MINIMUM AVERAGE MAXIMUM UNITS PH SAMPLE 12 MEASUREMENT 12 00400 1
0 0
PEMT
$.OF SU EFFLUENT GROSS VALUE SOLIDS, TOTAL SUSPENDED SAMPLE 19 MEASUREMENT 00530 1
0 0
I PERMIT "l***.1****
MGIL EFFLUENT GROSS VALUE UIR OIL AND GREASE SAMPLE 19 MEASUREMENT 00556 1
0 0
P***
MGIL EFFLUENT GROSS VALUE PHOSPHORUS, TOTAL (AS P)
SAMPLE 19 MEASUREMENT 00665 1
0 0
P W
MGIL EFFLUENT GROSS VALUE COPPER, TOTAL (AS CU)
SAMPLE 19 MEASUREMENT 01042 1
0 0
MGIL EFFLUENT GROSS VALUE IRON, TOTAL (AS FE)
SAMPLE 19 MEASUREMENT 01045 1
0 0
PEMI l
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MGIL EFFLUENT GROSS VALUE FLOW, IN CONDUIT OR THRU SAMPLE TREATMENT PLANT MEASUREMENT 03 50050 1
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MGD EFFLUENT GROSS VALUE NAME/TITLE PRINCIPAL EXECUTIVE OFFICER I Certify under penalty of law that this documen and all attachments were prepared under my TLPOEDT Pirection or supervision in accordance with a system designed to assure that qualified personnel TELEPHONE DATE Timothy P. Cleary properly gather and evaluate the information submitted. Based on my inquiry of the person or who manage the system, or those persons directly responsible for gathering the Principal Environmental Engineer 423 843-6700 08 05 13 information, the information submitted is, to the best of my knowledge and belief, true, 423_843_6700_______13 Site Vice President accurate, and complete. I am aware that there are significant penalties for submitting false SIGNATURE OF PRINCIPAL EXECUTIVE I
information, including the possibility of fine and imprisonment for knowing violations.
OFFICER OR AUTHORIZED AGENT AREA NUMBER YEAR MO DAY TYPED OR PRINTED CODE COMMENTS AND EXPLANATION OF ANY VIOLATIONS (Reference all attachments here)
No Discharge this Period EPA Form 3320-1 (REV 3199)
Previous editions may be used Page 1 of 1
PERMITTEE NAME/ADDRESS (Include Facility Name/Location if Different)
NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPDES)
MAJOR Form Approved.
Name TVA - SEQUOYAH NUCLEAR PLANT DISCHARGE MONITORING REPORT (DMR)
(SUBR 01)
OMB No. 2040-0004 Address P.O. BOX 2000 (INTEEROFFICE SB-2A)
TN0026450 110 G F-FINAL SODDY -DAISY_
TN 37384 E
PERMIT NUMBER DISCHARGE NUMBER RECYCLED COOLING WATER Facility TVA -SEQUOYAH NUCLEAR PLANT Location HAMILTON COUNTY M NITRIN PERIQD EFFLUENT DAY DAY AY Y.
NO DISCHARGE ATTN: Stephanie A. Howard From 08 04 01 To 9f i 4
39 NOTE: Read instructions before completing this form.
PARAMETER QUANTITY OR LOADING QUALITY OR CONCENTRATION NO.
FREQUENCY SAMPLE EX OF TYPE ANALYSIS AVERAGE MAXIMUM UNITS MINIMUM AVERAGE MAXIMUM UNITS TEMPERATURE, WATER DEG.
SAMPLE 04 04 CENTIGRADE MEASUREMENT 00010 Z
0 0
PERMT-E
- rD DEG C DEG C
,INSTREAM MONITORING
~PH SAMPLE 12
- AiLY=MX
=
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, 3/4 su EFFLUENT GROSS VALUE SOLIDS, TOTAL SUSPENDED SAMPLE 19 MEASUREMENT 00530 1
0 0
UR T
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-L_
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!00556 1
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RM*
MG/L EFFLUENT GROSS VALUE U
E IFLOW, IN CONDUIT OR THRU SAMPLE TREATMENT PLANT MEASUREMENT 03
/50050 1
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PA A
EFFLUENT GROSS VALUE MAIY ICHLORINE, TOTAL RESIDUAL SAMPLE 19 MEASUREMENT 19 50060 1
0 0
PEMI MG/L EFFLUENT GROSS VALUE
____OE SAMPLE MEASUREMENT NAME/TITLE PRINCIPAL EXECUTIVE OFFICER I Certify under penally of law that this document and all attachments were prepared under my
{jjJ/TELEPHONE DATE direction or supervision in accordance with a system designed to assure that qualified personnel Timothy P. Cleary properly gather and evaluate the information Submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the Principal Environmental Engineer 423 843-6700 08 05 13 Site Vice President nformation, the information submitted is,to the best of my knowledge and belief, true, accurate, and complete I am aware that there are significant penalties for submitting false SIGNATURE OF PRINCIPAL EXECUTIVE information, including the possibility of fine and imprisonment for knowing violations.
OFFICER OR AUTHORIZED AGENT AREA NUMBER YEAR MO DAY TYPED OR PRINTED CODE COMMENTS AND EXPLANATION OF ANY VIOLATIONS (Reference all attachments here)
No Discharge this Period EPA Form 3320-1 (REV 3199)
Previous editions may be used Page 1 of 1
PERMITTEE NAME/ADDRESS (Include Facility Name/Location if Different)
NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPDES)
MAJOR Form Approved.
Name TVA - SEQUOYAH NUCLEAR PLANT DISCHARGE MONITORING REPORT (DMR)
(SUBR 01) 0MB No. 2040-0004 Address P.O. BOX 2000
_ITEsE 13?A TN0026450 110 T F-FINAL SODDY -DAISY TN 37384 PERMIT NUMBER DISCHARGE NUMBER RECYCLED COOLING WATER Facility TVA -SEQUOYAH NUCLEAR PLANT Location HAMILTON COUNTY M
NITORING PERIQ0 EFFLUENT YEAR MO DAY YEAR i MO i DAY NO DISCHARGE FX7 ATTN: Stephanie A. Howard From 08 4 Lq1 To 0
4J 9J NOTE: Read instructions before completing this form.
PARAMETER QUANTITY OR LOADING QUALITY OR CONCENTRATION NO.
FREQUENCY SAMPLE EX OF TYPE AVERAGE MAXIMUM UNITS MINIMUM AVERAGE MAXIMUM UNITS AAYI IC25 STATRE 7DAY CHR SAMPLE 23 CERIODAPHNIA MEASUREMENT TRF`3B 1
0 0Cllli
~
~
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~
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REQUIREMENT SAMPLE MEASUREMENT SAMPLE MEASUREMENT SAMPLE MEASUREMENT SAMPLE MEASUREMENT 977 NAME~ITLE PRICIPAL EXECUTIE OFFIC direction drpnlyo a ht hsdcmn n l tahmnswr rprdudrmor supervision in accordance with a system designed to assure that qualified pensne Ii
- CLi EEHOEDT Timothy P. Cleary prprygather and evaluate the information submitted. Based on my inquiry of the person or pesons who manage the system, or those persons directly responsible for gathering the Principal Environmental Engineer 2
4-7 0
1 inomtothe information submitted is, to the best of my knowledge and belief, true, 2
4-70 0
5 1
Site Vie Presdent acurateand complete. I am aware that there are significant penalties for submitting false SIGNATURE OF PRINCIPAL EXECUTIVE inomtoincluding the possibility of fine and imprisonment for knowing violations.
OFFICER OR AUTHORIZED AGENT AE UB YEAR MO DAY TYPED OR PRINTED COM R
COMMENTS ANDEXPLANATION OF ANY VIOLATIONS (Referenceallatahment all attachments here)
No Discharge this Period EPA Form 3320-1 (REV 399)
Previous editions maytbe used Page 1 of i
PERMITTEE NAME/ADDRESS (Include Facility Name/Location if Different)
NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPOES)
MAJOR Form Approved.
Name TVA - SEQUOYAH NUCLEAR PLANT DISCHARGE MONITORING REPORT (DMRJ
- 01)
OMB No. 2040-0004 Address P.O. BOX 2000 jZZ JTI~EROmICESB-2_
TN0026450 116 G.
F-.FINAL SODDY -DAISY-TN 37384 PERMIT NUMBER I DISCHARGE NUMBER BACKWASH Facility TVA - SEQUOYAH NUCLEAR PLANT Location HAMILTON COUNTY MONITORIN PERIOD EFFLUENT YEAR MO DAY YEAR MO.
DY NO DISCHARGE ATTN Stehani A. owad Frm 08 04 0
To 08 04 30 NOTE: Read instructions before completing this form.
PARAMETER QUANTITY OR LOADING QUALITY OR CONCENTRATION NO.
FREQUENCY SAMPLE EX OF TYPE AVERAGE MAXIMUM UNITS MINIMUM AVERAGE MAXIMUM UNITS FLOATING (SEVERITY)
SAMPLE 9A 0
1 130 VISUAL MEASUREMENT 01345 1
0 0
P T
, PASS0S EFFLUENT GROSS VALUE FAIL=1 L AND GREASE VISUAL SAMPLE 0
94 0
1 30 VISUAL MEASUREMENT 84066 1
0 0
IYES=*
- 1 EL EFFLUENT GROSS VALUE NEO=RME 1O T
LER SAMPLE MEASUREMENT SAMPLE MEASUREMENT SAMPLE MEASUREMENT
> ~~~~~~~~~1~~~~~~MIT~
~
~
~
~~~~~MNM sa SAMPLE MEASUREMENT SAMPLE MEASUREMENT L~~~~~~~~~~~~~~~_~~~~~7 NAME/TITLE PRINCIPAL EXECUTIVE OFFICER I Certify under penalty of law that this document and all attachments were prepared under my d
TELEPHONE DATE direction or supervision in accordance with a system designed to assure that qualified personnel Timothy P. Cleary properly gather and evaluate the intormation submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the Principal Environmental Engineer 423 843-6700 08 05 13 Site Vice President intormation, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete I am aware that there are significant penalties for submitting false SIGNATURE OF PRINCIPAL EXECUTIVE information, including the possibility of fine and imprisonment for knowing violations.
OFFICER OR AUTHORIZED AGENT AREA YEAR MO DAY TYPED OR PRINTED CODE COMMENTS AND EXPLANATION OF ANY VIOLATIONS (Reference all attachments here)
Operations performs visual inspections for floating debris and oil and grease during all baCkwashes.
EPA Form 3320-1 (REV 3199)
Previous edit/ons may be used Page 1 of 1
PERMITTEE NAMEIADDRESS (Include Facilit Name/Location if Different)
NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPDES)
MAJOR Form Approved.
Name TVA - SEQUOYAH NUCLEAR PLANT DISCHARGE MONITORING REPORT (DMR)
'SUBR 01) 0MB No. 2040-0004 Address P.O. BOX 2000 (INE"TEROFFICLES11B-LA) tN.2.4.
117 G I F-FINAL SODDY -DAISY TN 37384 F
PERMIT NUMBER DISCHARGE NUMBER BACKWASH Facility TVA -SEQUOYAH NUCLEAR PLANT Location HAMILTON COUNTY -
C MONITORING PERIQ EFFLUENT YEAR MO DAY YEAR MO DAY l
I DAY I YEAR I MONO DISCHARGE E ATTN: Stephanie A. Howard From 08 04 01 To 8
NO DICHRG ATT-Stephanie A. Howard From 0=1 TO1 08 1 04 NOTE: Read instructions betore completinc this torm.
PARAMETER QUANTITY OR LOADING QUALITY OR CONCENTRATION NO.
FREQUENCY SAMPLE EX OF TYPE ANALYSIS AVERAGE MAXIMUM UNITS MINIMUM AVERAGE MAXIMUM UNITS ANAYSI DEBRIS, FLOATING (SEVERITY)
SAMPLE 0
9A 0
1/30 VISUAL MEASUREMENT 01345 1
0 0
- a' REPORT ~ PASS=0 EFFLUENT GROSS VALUE FAIL=1 OIL AND GREASE VISUAL SAMPLE j0 1I30 VISUAL MEASUREMENT 84066 1
0 0
P~f1MIT YESV-1ISA EFFLUENT GROSS VALUE REQIRNE=I SAMPLE MEASUREMENT SAMPLEON 1WM MEASUREMENT SAMPLE MEASUREMENT MEOUIREMENT i~~~
SAMPLE MEASUREMENT PERMN SAMPLE MEASUREMENT P~~~~~~~~ERNIIT<~~~~~~~~~~~~~~~~~~~~NWI SAMPLE MEASUREMENTV NAME/TITLE PRINCIPAL EXECUTIVE OFFICER I Certify under penalty of law that this document and all attachments were prepared under myTELEPHONE DATE direction or supervision in accordance with a system designed to assure that qualified personnel Timothy P. Cleary properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persona directly responsible for gathering the Principal Environmental Engineer 423 843-6700 08 05 13 information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false SIGNATURE OF PRINCIPAL EXECUTIVE Tnformation, including the possibility of tine and imprisonment for knowing violations.
OFFICER OR AUTHORIZED AGENT AREA NUMBER YEAR MO DAY TYPED OR PRINTED CODE COMMENTS AND EXPLANATION OF ANY VIOLATIONS (Reference all attachments here)
Operations performs visual inspections for floating debris and oil and grease during all backwashes.
EPA Form 3320-1 (REV 3/99)
Previous editions may be used Page 1 of 1
PERMITTEE NAME/ADDRESS (Include Facility Name/Location if Different)
NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPDES)
MAJOR Form Approved.
Name TVA - SEQUOYAH NUCLEAR PLANT DISCHARGE MONITORING REPORT (DMR)
RMB No. 2040-0004
~~~~~~~~~~~~~(SUBR 01)
Address P.O. BOX 2000 LNTEROFHCqE SB-2A)
TN0026450 118 G INAL SODDY - DAISY TN 37384
-PERMIT NUMBER DISCHARGE NUMBER]
WASTEWATER & STORM WATER Facility TVA - SEQUOYAH NUCLEAR PLANT Location HAMILTON COUNTY MQNIT RIN PERI 0 EFFLU ENT YEAR MO DAY YEAR MO DAY NO DISCHARGE Fi]j..
ATTN: Stephanie A. Howard From 08 04 01 To 08 04 30 NOTE: Read instructions before comoletinr this form.
PARAMETER QUANTITY OR LOADING QUALITY OR CONCENTRATION NO.
FREQUENCY SAMPLE EX OF TYPE AVERAGE MAXIMUM UNITS MINIMUM AVERAGE MAXIMUM UNITS OXYGEN, DISSOLVED (DO)
SAMPLE 19 MEASUREMENT 00300 1
0 0
'E*T 2.0 MGIL EFFLUENT GROSS VALUE RT SOLIDS, TOTAL SUSPENDED SAMPLE 19 MEASUREMENT 00530 1
0 0
T MGIL EFFLUENT GROSS VALUE SOLIDS, SETTLEABLE SAMPLE 25 MEASUREMENT 00545 1
0 0
PR Ti MLIL EFFLUENT GROSS VALUE FLOW, IN CONDUIT OR THRU SAMPLE ITREATMENT PLANT MEASUREMENT 03 50050 1
0 0
MGD EFFLUENT GROSS VALUE SAMPLE MEASUREMENT SAMPLE MEASUREMENT SAMPLE MEASUREMENT NAMEfTITLE PRINCIPAL EXECUTIVE OFFICER I Certify under penalty of law that this document and all attachments were prepared under my TELEPHONE DATE
~~~-----~~~~~~~~~~~drcto or supervision in accordance with a system designed to assure that qualified personnel aCC i
~~~Timothy P. Cleary prprygather and evaluate the information submitted. Based on my inquiry of the person or proswho manage the system, or those persons directly responsible for gathering the Principal Environmental Engineer 2
4-7 0
1 i
~ ~~~~~~~~~~~informatonthe nformation submitted is, to te best of my knowledge and belietre 43 84-70 8
5 1
Site Vice Presidentaccurate, and complete. I am aware that there are significant penalties for submitting false SIGNATURE OF PRINCIPAL EXECUTIVEI information, including the possibility of fine and imprisonment for knowing violations.
OFFICER OR AUTHORIZED AGENT AREA NUMBER YEAR MO DAY TYPED OR PRINTED CODE PEMI A-COMMENTS ANDEXPLANATION OF ANY VIOLATIONS (Referenceallatahment all attachments here)
During this reporting period, there has been no flow from the Dredge Pond other than that resulting from rainfalln EPA Form 3320-1 (REV 3i99)
Previous editions may be used Page 1 of 1
S58 080611 800 - NPDES CORRESPONDENCE June 11, 2008 State of Tennessee Department of Environment and Conservation Division of Water Pollution Control Enforcement & Compliance Section 6th Floor, L & C Annex 401 Church Street Nashville, Tennessee 37243-1534
Dear Mr. Patrick Cromer:
SEQUOYAH NUCLEAR PLANT - DISCHARGE MONITORING REPORT FOR MAY 2008 Enclosed is the May 2008 Discharge Monitoring Report for Sequoyah Nuclear Plant.
Please contact me at (423) 843-6700 if you have any questions or comments.
Since rely, Stephanie A. Howard Principal Environmental Engineer Signatory Authority for Timothy P. Cleary Site Vice President Sequoyah Nuclear Plant AH Enclosure cc (Enclosure):
Chattanooga Environmental Assistance Center Division of Water Pollution Control State Office Building, Suite 550 540 McCallie Avenue Chattanooga, Tennessee 37402-2013 U.S. Nuclear Regulatory Commission ATTN: Document Control Desk Washington, D.C. 20555 cc:
D. J. Bodine, POB 2A-SQN A. A. Ray, WT 7C-K C. R. Church, POB 2B-SQN J. D. Smith, OPS 4A-SQN T. P. Cleary, OPS 4A-SQN G. R. Signer, WT 6A-K D. E. Pittman, BR 4T-C EDMS, WT CA-K (Enclosure)
DMR0805.doc
Tennessee Valley Authority. Post Office Box 2000, Soddy-Daisy, Tennessee 37384-2000 June 11, 2008 State of Tennessee Department of Environment and Conservation Division of Water Pollution Control Enforcement & Compliance Section 6t' Floor, L & C Annex 401 Church Street Nashville, Tennessee 37243-1534
Dear Mr. Patrick Cromer:
SEQUOYAH NUCLEAR PLANT - DISCHARGE MONITORING REPORT FOR MAY 2008 Enclosed is the May 2008 Discharge Monitoring Report for Sequoyah Nuclear Plant. Please contact me at (423) 843-6700 if you have any questions or comments.
Sincerely, Stephanie A. Howard Principal Environmental Engineer Signatory Authority for Timothy P. Cleary Site Vice President Sequoyah Nuclear Plant Enclosure cc (Enclosure):
Chattanooga Environmental Assistance Center Division of Water Pollution Control State Office Building, Suite 550 540 McCallie Avenue Chattanooga, Tennessee 37402-2013 U.S. Nuclear Regulatory Commission ATTN. Document Control Desk Washington, D.C. 20555 Pri ved on -ecycdeO pa~po
PERMITTEE NAME/ADDRESS (Include Facilitv Name/Locat ion if Different)
NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPDES)
MAJOR Form Approved.
Name TVA - SEQUOYAH NUCLEAR PLANT DISCHARGE MONITORING REPORT (DMR)
OSB 1
MB No. 2040-0004 Address P.O. BOX 2000
__EEML LBATN0026450 101 G IF -FINAL SODDY
- DAISY TN 378 PERMIT NUMBER___
IDISCHiARGE NUMBER]
DIFFUSER DISCHARGE Facility TVA -SEQUOYAH NUCLEAR PLANT Location HAMILTON COUNTY MONITORING PERIOD EFFLUENT ATTN: Stephanie A. Howard From 08 05 01 T*0*5 1NO DISCHARGE 7j 08-LO5 ~~~~~~~~~
01
~~~NOTE: Read instructions before completing this form.
PARAMETER QUANTITY OR LOADING QUALITY OR CONCENTRATION NO.
FREQUENCY SAMPLE EX OF TYPE AVERAGE MAXIMUM UNITS MINIMUM AVERAGE MAXIMUM UNITS ANALYSIS TEMPERATURE, WATER DEG.
SAMPLE 24.2 04 0
31 / 31 MODELD CENTIGRADE MEASUREMENT 00010 Z
0 0
~
~
- ~DG E
INSTREAM MONITORINGPE it TEMPERATURE, WATER DEG.
SAMPLE 32.2 04 0
31 /31
'RCOIRDR CENTIGRADE MEASUREMENT 00010 1
0 0
,,ERT'
- /-
- REOT DEG. C.
SfI2-EE CK RE EFFLUENT GROSS VALUE EQRENT-2
-;2 DALPX 2-ITEMP. DIFF. BETWEEN SAMP. &
SAMPLE
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31/31 CALCTD UPSTRIM DEG.C MEASUREMENT 00016 1
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19 0
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0 0
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- A7***~
0 MGIL MNhY GA EFFLUENT GROSS VALUE R~~MN OIL AND GREASE SAMPLE
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1 /31 GRAB MEASUREMENT 00556 1
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- 2.
MGIL MNHY GA EFFLUENT GROSS VALUE
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ALM FLOW, IN CONDUIT OR THRU SAMPLE 159 03 0
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22PEMI 1****
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- OTNROD EFFLUENT GROSS VALUERQIEMNVX (OS NAME/TITLE PRINCIPAL EXECUTIVE OFFICER 11 Certify under penalty of law that this document and all attachments were prepared under my i
1,.J.
~
TELEPHONE DATE direction or supervision in accordance with a system designed to assure that qualifiled personnel
' L)4 LOaL..
L 'L/,-
ca-&.
Timothy P. Cleary properly gather and evaluate the information submitted. Based on my inquiry of the person or 4
persons who manage the system, or those persons directly responsible for gathering the PicplEvrnetlEgne Site Vice President
~~information, the information submitted is, to the best of my knowledge and belief, true, rnia niomna nier 423 843-6700 08 06 1 1 Site Vice President accurate, and complete. I am aware that there are significant penalties for submitting false SIGNATURE OF PRINCIPAL EXECUTIVEI
_________________________________information, including the possibility of fine and imprisonment for knowing violations.
OFFICER OR AUTHORIZED AGENT AREA INUMBER YEAR MO DAY TYPED OR PRINTED
_________________jCODE COMMENTS AND EXPLANATION OF ANY VIOLATIONS (Reference all attachments here)
No closed mode operation. The following information is included inan attachment: 1. CCW data 2. veliger monitoring data EPA Fom320-1 (REV 3/99)
Previous editions may be usedPae1o2
DMR Attachment CCW Data CCW TRENCH Extractable Petroleum Date/Time Collected Hydrocarbons Analysis Date/Time Analyst Method 05/14/2008 @ 1520 0.30 mg/I 05/16/2008 @ 1244 RDH TN EPA 8015 CCW CHANNEL Extractable Petroleum Date/Time Collected Hydrocarbons Analysis Date/Time Analyst Method 05/14/2008 @ 1515
<0.10 mg/I 05/16/2008 1255 RDH TN EPA 8015
Mean # of Water Temp.
Men fWater Temp.
SUB NTS Sample Date 3
% Settlers Sample Date Asiatic LOCATION Gravid Asiatic COLLECTED BY ZM/m Cc)
ClaMS/rn 3 Cc)
LOCATION Clam 11/16/2007 0
0 1 5 11/16/2007 44 15 Inplant ROW Dickie Adcock 11/18/2007 0
0 15 11/18/2007 60 1 5 Inplant ROW Dickie Adcock 11/19/2007 0
0 14 11/19/2007 29 1 5 Inplant ROW Dickie Adcock 11/20/2007 15 0
15 11/20/2007 45 15 Inplant ROW Dickie Adcock 11/27/2007 0
0 14 11/27/2007 1 5 14 Inplant ROW Dickie Adcock 12/6/2007 0
0 12 12/06/2007 14 12 Inplant ROW Dickie Adcock 12/10/2007 0
0 12 12/06/2007 0
12 Inpiant ROW Dickie Adcock 12/21/2007 0
0 1 0 12/21/2007 0
1 0 Inplant ROW Dickie Adcock 12/28/2007 0
0 9
12/28/2007 0
9 Inplant ROW Dickie Adcock 01/03/2008 0
0 8
01/03/2008 0
8 Inplant ROW Dickie Adcock 01/11/2008 0
0 9
01/11/2008 0
9 Inplant ROW Dickie Adcock 01/18/2008 0
0 8
01/18/2008 0
8 Inplant ROW Dickie Adcock 01/25/2008 0
0 6
01 /25/2008 0
6 Inplant ROW Dickie Adcock 02/01/2008 0
0 7
02/01/2008 0
7 Inplant ROW Dickie Adcock 02/08/200 8 0
0 9
02/08/2008 0
9 Inplant ROW Dickie Adcock 02/1 5/2008 0
0 8
02/1 5/2008 0
8 In plant ROW Dickie Adcock 02/22/2008 0
0 8
02/22/2008 0
8 Inplant ROW Dickie Adcock 02/29/2008 0
0 8
02/29/2008 0
8 Inplant ROW Dickie Adcock 03/07/2008 0
0 1 0 03/07/2008 0
10 Inplant ROW Dickie Adcock 03/14/2008 0
0 1 0 03/14/2008 0
1 0 Inplant ROW Dickie Adcock 03/21/2008 30 0
12 03/21/2008 0
12 Inplant ROW B. Love / Dick Adcock 03/28/2008 30 0
1 2 03/28/2008 75 1 2 Inplant ROW Dickie Adcock 04/04/2008 29 0
13 04/04/2008 119 1 3 Inplant ROW Dickie Adcock 04/11/2008 72 0
16 04/11/2008 302 16 Inplant ROW Dickie Adcock 04/18/2008 30 0
15 04/18/2008 104 1 5 Inplant ROW Dickie Adcock 04/25/2008 29 0
1 5 04/25/2008 72 1 5 Inplant ROW Dickie Adcock 05/02/2008 14 0
1 7 05/02/2008 58 17 Inplant ROW Dickie Adcock
PERMITTEE NAME/ADDRESS (Include FacilityvName/Location if Different)
NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPDES)
MAJOR Form Approved.
Name P/TA - SEQUOYAH NUCLEAR PLANT----
DISCHARGE MONITORING REPORT (DMR)
(SUBR 01) 0MB No. 2040-0004 Address P.O. BOX 2000
__E~11`(EqBL)TN0026450 101 G F -FINAL SODDY -DAISY TN 37384 PERMIT NUMBER DSHRGE NUMBER DIFFUSER DISCHARGE Facilitvy TVA -SEQUOYAH NUCLEAR PLANT-Location HAMILTON COUNTY MONITORING PER!OD EFFLUENT YEAR MO DAY YEAR MO DAY NO DISCHARGE El ATTN: Stephanie A. Howard From 08 05 01 To 08 05 3 LO5 1 31
~~NOTE: Read instructions before completing this form.
PARAMETER QUANTITY OR LOADING QUALITY OR CONCENTRATION NO0. FREQUENCY SAMPLE EX OF TYPE AVERAGE MAXIMUM UNITS MINIMUM AVERAGE MAXIMUM UNITS AAYI CHLORINE, TOTAL RESIDUAL SAMPLE
- 0.027 0.042 19 0
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SAMPLE MEASUREMENT SAMPLE MEASUREMENT REQUIREMENT SAMPLE MEASUREMENT SAMPLE MEASUREMENT NORJV¶ I
NAME/TITLE PRINCIPAL EXECUTIVE OFFICER I Certify under penalty of law that this document and all attachments were prepared under my
.ITELEPHONE DATE direct ion or supervision in accordance with a system designed to assure that qualified personnel.~~'1j1..g Timothy P. Clearyproperly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the Principal Environmental Engineer 42 83-70 8
06 1
Site Vice President information, the information submitted is,to the best of my knowledge and belief, true,
____423____843___6700___________
Site Vice Presidentaccurate, and complete. I am aware that there are significant penalties for submitting false
-SIGNATURE OF PRINCIPAL EXECUTIVE information, including the possibility of fine and imprisonment for knowing violations.
OFFICER OR AUTHORIZED AGENT AREA NUMBER YER MO DAY TYPED OR PRINTED CODE COMMENTS AND EXPLANATION OF ANY VIOLATIONS (Reference all attachments here)
The following injections occured: 1. Biodetergent 73551 (max. calc. conc. was 0.039mg/L--limit 2.0mg/I) 2. MSW 101 (max. calc. conc. was 0.1 12mg/I--limit 0.2mg/L) 3. H-150M (max. calc. conc. was 0.039mg/L--limit 0.050mg/L) 4. H-i 50M (low detection level analytical method was <0.020mg/I--limit 0.050mg/I)
EPA Form 3320-1 (REV 3/99)
Previous editions may be used Page 2 of 2
PERMITTEE NAME/ADDRESS (Include FacilityvName/Location if Different)
NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPDES)
MAJOR Form Approved.
Name TVA - SEQUOYAH NUCLEAR PLANT----
DISCHARGE MONITORING REPORT (DMR)
(SU8R Dl)
OMB No. 2040-0004 Address-P.O.jBOX 2000
__TNFI(EB-A0026450 101 T F -FINAL SODDY - DAISY TN 37384 PERMIT-NUBER DISCARGE ~NUMB~ER BIOMONITORING FOR OUTFALL 101 Facililty TA -_SEgOUOYAH N[UCLEAR PLANT Location HAMILTON CO-UNTY----------
M NIT9RING PERIOD EFFLUENT ATTN: Stephanie A. Howard From 08~~~~~YEA 05 0.T.8.5 3
NO DISCHARGE ATTN: Stephanie A. Howard From - 08 L-0-5L-0-11 To LC
~ ~~~~~~~~~~~~~~NOTE:
Read instructions before completing this form.
PARAMETER QUANTITY OR LOADING QUALITY OR CONCENTRATION NO.
FREQUENCY SAMPLE EX OF TYPE AVERAGE MAXIMUM UNITS MNUMAVERAGE MAXIMUM UNITS ANALYSIS 1C25 STATIRE 7DAY CHR SAMPLE Monitoring 2
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NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPDES)
MAJOR Form Approved.
Name TVA - SEQUOYAH NUCLEAR PLANT----
DISCHARGE MONITORING REPORT (DMR)
(SUBIR 01)
OMB No. 2040-0004 Address PI0. BOX 2000
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ATTN: Stephanie A. Howard From _08 L 05_L 0IJ To F 087 05 31
~ ~~~~~~~~~~~NOTE:
Read instructions betore completinq this form.
PARAMETER QUANTITY OR LOADING QUALITY OR CONCENTRATION NO.
FREOUENCY SAMPLE Ex OF TYPE AVERAGE MAXIMUM UNITS MINIMUM AVERAGE MAXIMUM UNITS AAYI PH-SAMPLE
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PERMITTEE NAME/ADDRESS (Include Facilitv Name/Location if Different)
NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPDES)
MAJOR Form Approved.
Name TVA - SEQUOYAH NUCLEAR PLANT----
DISCHARGE MONITORING REPORT (DMR)
(SUB3R 01) 0MB No. 2040-0004 Address p'0. BOX 2000............TN065 (INTEROFFICE SB-2A)
)
IA SODDY -DAISY TN 37384 PERMIT NUMBER DISCHARG~ENUMB~ER METAL CLEANING WASTE POND Facility TVA -SEQUOYAH NUCLEAR PLANT Location HAMILTON COUNTY MONIT RIN PERIQ EFFLUENT YEAR IMO -
DA:Yl YEAR? MO DAY NO DISCHARGE ATTN: Stephanie A. Howard From 08 05 31
~~~~~~~~~~~~~~~~~~~~~~NOTE:
Read instructions before completinq this form, PARAMETER QUANTITY OR LOADING QUALITY OR CONCENTRATION NO.
FREQUENCY SML EX OF TYPE AVERAGE MAXIMUM UNITS MINIMUM AVERAGE MAXIMUM UNITS ANALYSIS SOISTTLHUPEDDSAMPLE 1
MEASUREMENT 1
04050 1
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- 19 MEASUREMENT 00566 1
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NAME/TTLE PRINCIPAL EXECUTIVE OFFICER I Certify under penally of law that this document and all attachments were prepared under my
]
TELEPHONE DATE properly gather and evaluate the information submitted. Based on my inquiry ot the 'person or persona who manage the system, or those persona directly responsible for gathering the Principal Environmental Engineer 423 843-6700 08 06 1 1 Site Vice President
~information, the information submitted is, to the best of my knowledge and belief, true,________________________
Site Vice Presidentaccurate, and complete. I am aware that there are significant penalties for submitting false SIGNATURE OF PRINCIPAL EXECUTIVE
-information, including the possibility of fine and imprisonment for knowing violations OFFICER OR AUTHORIZED AGENT ARE NUMBER YEAR MO DAY TYPED OR PRINTED
-COEDAEL COMMENTS AND EXPLANATION OF ANY VIOLATIONS (Reference all attachments here)
No Discharge this Period EPA Form 3320-1 (REV 3/99)
Prev/ous editions may be used Page 1 of 1
PERMITTEE NAME/ADDRESS (Include FacilityName/Location ifDifferent)
NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPDES)
MAJOR Form Approved.
Name TVA - SEQUOYAH NUCLEAR PLANT DISCHARGE MONITORING REPORT (DMR)
(SUBR 01) 0MB No. 2040-0004 Ad2re6ss P.45i20 110 G F-FINAL AINTEROFFICE SB-?A TNB)264 50 110 G ---
SODDY - DAISY TN 37384 PERMIT NUMBER DISCHARGE NUMBER RECYCLED COOLING WATER Facility TVA -SEOUOYAH NUCLEAR PLANT Location HAMILTON COUNTY MONITQRIN PERIOD EFFLUENT YEAR.MO DAY YEAR MO DAY NO DISCHARGE ATTN: Stephanie A. Howard From 08 05 01 To 08 05 31 ATTN:
Stephanie A. Howard
~~~~~~~~~~~~~~~~~~~~~~~~~~~~~NOTE:
Read instructions before completing this form.
PARAMETER QUANTITY OR LOADING QUALITY OR CONCENTRATION EX OF TYPE AVERAGE MAXIMUM UNITS MINIMUM AVERAGE MAXIMUM UNITS TEMPERATURE, WATER DEG.
SAMPLE CENTIGRADE MEASUREMENT 04 04 00010 Z
0 0
DEG C INSTREAM MONITORING PH SAMPLE 12 MEASUREMENT 00400 1
0 0
jSuW EFFLUENT GROSS VALUE SOLIDS, TOTAL SUSPENDED SAMPLE 19 MEASUREMENT 1
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~
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- 19 MEASUREMENT 50060 1
0 0
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.0MGILWEKY RA-EFFLUENT GROSS VALUE EURNT 5V-DAL X
SAMPLE MEASUREMENT NAM/TTLEPRNCIPAL EXECUTIVE OFFICER I Certify under penally of law that this document and all attachments were prepared under my
~
~
jJTELEPHONE DATE directrio or supervision in accordance with a system designed to assure that qualified personnel Q41aA Timothy P. Cleary propeirly gather and evaluate the information submitted. Based on my inquiry of the person or
/j'
' t' persons who manage the system, or those persona directly responsible for gathering the Principal Environmental Engineer 42 83-00 8
06 1
information, the information submitted is,to the best of my knowledge and belief, true, 423____843___6700_________06_______
Site Vice President accurate, and complete. I am aware that there are significant penalties for submitting false SIGNATURE OF PRINCIPAL EXECUTIVE information, including the possibility of fine and imprisonment for knowing violations.
OFFICER OR AUTHORIZED AGENT AR EA NUMBER YEAR MO DAY TPED OR PRINTED CODE COMMENTS AND EXPLANATION OF ANY VIOLATIONS (Reference all attachments here)
No Discharge this Period EPA ~Form 3320-1 (REV 3199)
Previous editions may be used Page 1 of 1
PERMITTEE NAME/ADDRESS (Include Facility Name/Location if Different)
NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPDES)
MAJOR Form Approved.
Name W
TA -SEQUOYAH NUCLEAR PLANT ----
DISCHARGE MONITORING REPORT (DMR)
(SUIBR 01) 0MB No. 2040-0004 Address P.O. BOX 2000 A!NtTEROFFIE SB-?AN02 5
1 10 T F -FINAL SODDY - DAISY TN 37384 L
PER
.MIT NUME ICAG UBR RECYCLED COOLING WATER Facility TVA -SEQUOYAH NUCLEAR PLANT Location HAMILTON COUNTY MONITORING PERIQ EFFLUENT YEA MO DYYER M
- NO DISCHARGE xl ATTN:
Stephanie A. Howard From 08 05 1 01
~ ~~~~~~~~~~~~~~~~~~~~NOTE:
Read instructions betore completing this form.
PARAMETER QUANTITY OR LOADING QUALITY OR CONCENTRATION NO.
FREQUENCY SAMPLE EX OF TYPE AVERAGE MAXIMUM UNITS MINIMUM AVERAGE MAXIMUM UNITS ANALYSIS IC25 STATRE 7DAY CHR SAMPLE*
2 CERIODAPHNIA MEASUREMENT 2
TRP3B 1
0 0
EFFLUENT GROSS VALUE EURMN
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.A ULU IC25 STATRE 7DAY CHR SAMPLE
- 23 PIMEPHALES MEASUREMENT TRP6C 1
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,EU~ET
~
~
~
4 SAMPLE MEASUREMENT SAMPLE MEASUREMENT SAMPLE MEASUREMENT SAMPLE MEASUREMENT SAMPLE MEASUREMENT NAME/TITLE PRINCIPAL EXECUTIVE OFFICER I Certify under penalty of law that this document and all attachments were prepared under my
',IJTELEPHONE DATE direction or supervision in accordance with a system designed to assure that qualified personnel pn4L.LlAkI/uiA Ž-____________
persons who manage the system, or those persons directly responsible tor gathering the Principal Environmental Engineer 423 843-6700 08 06 1 1 Site Vice President
~information, the information submitted is ' to the best of my knowledge and belief, true, Site VicePresidentaccurate, and complete. I am aware that there are significant penalties for submitting false SIGNATURE OF PRINCIPAL EXECUTIVE infrmaion inludng he ossbility of fine and imprisonment for knowing violations.
OFFICER OR AUTHORIZED AGENT AREA NUMBER YEAR MO DAY CODE COMMENTS AND EXPLANATION OF ANY VIOLATIONS (Reference all attachments here)
No Discharge this Period EPA Form 3320-1 (REV 3199)
Previous editions may be used Page 1 of I
PERMITTEE NAME/ADDRESS (Include FacilityVName/Locationif Different)
NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPDES)
MAJOR Form Approved.
Name TVA - SEQUOYAH NUCLEAR PLANT ----
DISCHARGE MONITORING REPORT (DMR)
(SUBR 01)
OMB No. 2040-0004 Address P.O. BOX 2000 (I~NLTEROFFIC~E SB-LA).T..0..2..4..0.116 G
F-IA SODDY -DAISY TN 37384 PEMTNME ICAG UBR BACKWASH Facility TVA -SEQUOYAH NUCLEAR PLANT Location HAMILTON CTOUNTY MONITORIN PRO EFFLUENT YEAR MO DA YAMDAYAY
- NO DISCHARGE AT-TN: Stephanie A. Howard Firom 08 0
1 To 0
5 3
NOTE: Read instructions before completing this form.
PkRAMETER
~~~~~~QUANTITY OR LOADING QUALITY OR CONCENTRATION NO.
FREQUENCY SAMPLE EX OF TYPE AVERAGE MAXIMUM UNITS MINIMUM AVERAGE MAXIMUM UNITS ANALYSIS
- DEBRIS, FLOATING (SEVERITY)
SAMPLE
~
~
~~~~~~~0 9A 0
1 I 31 VISUAL MEASUREMENT 81406 1
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~~~~
d~irection or supervision in accordance with a system designed to assure that qualified personnel Timothy P. Cleary properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the PicplEvrnetlEgne 2
4-70 0
6 1
Site Vice President information, the information submitted is,to the best of my knowledge and belief, true, PrincipalEnvironmntalEngineer_423 843_6700____06___
Site Vice Presidentaccurate, and complete. I am aware that there are significant penalties for submitting false SIGNATURE OF PRINCIPAL EXECUTIVE
________________________information, including the possibility of fine and imprisonment for knowing violations.
OFFICER OR AUTHORIZED AGENT AREA NUMBER YEAR MO DAY TYPED OR PRINTED CODE COMMENTS AND EXPLANATION OF ANY VIOLATIONS (Reference al/ attachments here)
Operations performs visual inspections for floating debris and oil and grease during all backwashes.
EPA Form 3320-1 (REV 3199)
Previous editions may be used Page 1 of 1
PERMITTEE NAME/ADDRESS (Include Facility Name/Location if Different)
NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPDES)
MAJOR Form Approved.
Name W
TA -SEQUOYAH NUCLEAR PLANT----
DISCHARGE MONITORING REPORT (DMR)
- 01) 0MB No. 2040-0004 Address P.O. BOX 2000 1
I
__~0FqE93E..........
TN0026450 117G FFIAL SODDY -DAISY TN 37384 P-ERMTNUBRDISCHARGE NUMBERj BACKWASH Facility-TVA -SEQUOYAH NUCLEAR PLANT------
Location HAMILTON COUNTY MONITORINI-GPERI~ D EFFLUENT YEAR MO DAY YEAR MO DAY NO DISCHARGE ATTN:
Stephanie A. Howard ToLO8LO5L31 I
~ ~~~~~~~~~~~~~~~~~~~~~NOTE:
Read instructions before completing this form.
PARAMETER QUANTITY OR LOADING QUALITY OR CONCENTRATION NO.
FREQUENCY SAMPLE EX OF TYPE AVERAGE MAXIMUM UNITS MINIMUM AVERAGE MAXIMUM UNITS AAYI DEBRIS, FLOATING (SEVERITY)
SAMPLE
- 0 9A 0
1 / 31 VISUAL MEASUREMENT 01345 1
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SAMPLE MEASUREMENT SAMPLE MEASUREMENT PERMMTmi SAMPLE MEASUREMENT SAMPLE MEASUREMENT SAMPLE MEASUREMENT NAME/TITLE PRINCIPAL EXECUTIVE OFFICER ~I Certify under penalty of law that this document and all attachments were prepared under my f
N j
~TELEPHONE DATE P. Cleary l~~~irection or supervision in accordance with a system designed to assure that qualified personnel
~I4~~,J6.t~
Timothy PClayproperly gather and evaluate the information submitted, Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the Principal Environmental Engineer 423 843-6700 08 06 1 1 Site Vice President
~information, the information submitted is, to the best of my knowledge and belief, true, Site Vice President
~
accurate, and complete. I am aware that there are significant penalties for submitting false SIGNATURE OF PRINCIPAL EXECUTIVE intormation, including the possibility of fine and imprisonment for knowing violations.
OFFICER OR AUTHORIZED AGENT AREA NUMBER
-YEAR MO DAY TYPED OR PRINTED
~~~~~~~~~~~~~~~~~~~~~~~~CODE COMMENTS AND EXPLANATION OF ANY VIOLATIONS (Reference all attachments here)
Operations performs visual inspections for floating debris and oil and grease during all backwashes.
EPA Form 3320-1 (REV 3/99)
Previous editions may be used Page 1 of 1
PERMITTEE NAME/ADDRESS (Include Facility Name/Location if Different)
NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPDES)
MAJOR Form Approved.
Name TVA - SEQUOYAH NUCLEAR PLANT -
DISCHARGE MONITORING REPORT (DMR)
(SUBR 01) 0MB No. 2040-0004 Address P.O.BO 2000
-T--0--2--4--0 118 G F -FINAL INTEROFFIE S.B-LA)..........TN065I SODDY -DAISY TN 37384 NUMBER
-DSCARENUBE]WASTEWATER
&STORM WATER Facility TVA - SEQUOYAH NUCLEAR PLANT ------
EFUN Location HAMILTON COUNTY MONITORING PERIOD EFUN YEAR MOTo DAYA MO DAY NO DISCHARGE
[~7 ATTN:
Stephanie A. Howard 08 05 31
~~~~~~~~~~~~~~~~~~~~~~~~~NOTE; Read instructions before completing this form.
PARAMETER QUANTITY OR LOADING QUALITY OR CONCENTRATION NO.
REQUENCY SAMPLE EX OP TYPE AVERAGE MAXIMUM UNITS MINIMUM AVERAGE MAXIMUM UNITS AAYI OXYGEN, DISSOLVED (DO)
SAMPLE
- 1 MEASUREMENT 1
00300 1
0 0
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9 MEASUREMENT 1
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AC SAMPLE MEASUREMENT SAMPLE MEASUREMENT SAPLE MESREMENT NAME/TITLE PRINCIPAL EXECUTIVE OFFICER I Certify under penalty of law that this document and all attachments were prepared under my Fr/
lTELEPHONE DATE piroperly gahr aueviind i ealuateathe winforato submitemd.sigsed ton mysinuirye o thaqulfed personne orIkCrfV~
~Timothy P. Clea~ry piroeto rl suphervso ind eaccordane winomthoa sysmitem.
desiged tonm assuire o
thaqulfed personnel persons who manage the system, or those persons directly responsible for gathering the Principal Environmental Engineer 423 843-6700 08 06 1 1 Site Vice President
~information, the information submitted is,to the best of my knowledge and belief, true, SieViePrsdetaccurate, and complete. l am aware that there are significant penalties for submitting false SIGNATURE OF PRINCIPAL EXECUTIVE L
i~~~~~~~~~~nformation, including the possibility of tine and imprisonment for knowing violations.
OFFICER OR AUTHORIZED AGENT AREA NUMBER YEAR MO DAY L -
TYPED OR PRINTED I______________________________
_________________CODEt COMMENTS AND EXPLANATION OF ANY VIOLATIONS (Reference alt attachments here)
During this reporting period, there has been no flow from the Dredge Pond other than that resulting from rainfall.
EPA Form 3320-1 (REV 3/991 Previous editions maybe used Page 1 of 1
S58 080715 800 - NPDES CORRESPONDENCE July 15, 2008 State of Tennessee Department of Environment and Conservation Division of Water Pollution Control Enforcement & Compliance Section 6 th Floor, L & C Annex 401 Church Street Nashville, Tennessee 37243-1534
Dear Mr. Patrick Cromer:
SEQUOYAH NUCLEAR PLANT - DISCHARGE MONITORING REPORT FOR JUNE 2008 Enclosed is the June 2008 Discharge Monitoring Report for Sequoyah Nuclear Plant.
Please contact me at (423) 843-6700 if you have any questions or comments.
Sincerely, Stephanie A. Howard Principal Environmental Engineer Signatory Authority for Timothy P. Cleary Site Vice President Sequoyah Nuclear Plant AH Enclosure cc (Enclosure):
Chattanooga Environmental Assistance Center Division of Water Pollution Control State Office Building, Suite 550 540 McCallie Avenue Chattanooga, Tennessee 37402-2013 U.S. Nuclear Regulatory Commission ATTN: Document Control Desk Washington, D.C. 20555 cc:
D. J. Bodine, POB 2A-SQN A. A. Ray, WT 7C-K C. R. Church, POB 2B-SQN J. D. Smith, OPS 4A-SQN T. P. Cleary, OPS 4A-SQN G. R. Signer, WT 6A-K D. E. Pittman, BR 4T-C EDMS, WT CA-K (Enclosure)
DMR0806.doc
Tennessee Valley Authority, Post Office Box 2000, Soddy-Daisy, Tennessee 37379-2000 July 15, 2008 State of Tennessee Department of Environment and Conservation Division of Water Pollution Control Enforcement & Compliance Section 6"h Floor, L & C Annex 401 Church Street Nashville, Tennessee 37243-1534
Dear Mr. Patrick Cromer:
SEQUOYAH NUCLEAR PLANT - DISCHARGE MONITORING REPORT FOR JUNE 2008 Enclosed is the June 2008 Discharge Monitoring Report for Sequoyah Nuclear Plant. Please contact me at (423) 843-6700 if you have any questions or comments.
Sincerely, Stephanie A. Howard Principal Environmental Engineer Signatory Authority for Timothy P. Cleary Site Vice President Sequoyah Nuclear Plant Enclosure cc (Enclosure):
Chattanooga Environmental Assistance Center Division of Water Pollution Control State Office Building, Suite 550 540 McCallie Avenue Chattanooga, Tennessee 37402-2013 U.S. Nuclear Regulatory Commission ATTN: Document Control Desk Washington, D.C. 20555 Printed on recycded paper
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