05000530/LER-2010-002

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LER-2010-002, Condition Prohibited by Technical Specification Resulting from Containment Spray Nozzle Obstruction
Docketmonth Day Year Year Sequential Rev Month Day Year Numbernumber No. None
Event date: 10-13-2010
Report date: 06-27-2012
Reporting criterion: 10 CFR 50.73(a)(2)(i)(B), Prohibited by Technical Specifications

10 CFR 50.73(a)(2)(v), Loss of Safety Function

10 CFR 50.73(a)(2)(vii), Common Cause Inoperability
5302010002R01 - NRC Website

1. REPORTING REQUIREMENT(S):

This LER is being submitted pursuant to 10 CFR 50.73(a)(2)(i)(B) to report a condition prohibited by Technical Specification (TS) Limiting Condition for Operation (LCO) 3.6.6, Condition B. Specifically, on October 13, 2010, Palo Verde personnel determined that Containment Spray (CS) nozzles on each of two separate CS train A and B spray headers were obstructed. The obstructions existed for a period greater than allowed by Technical Specification (TS) 3.6.6 "Containment Spray System.

This condition is also being reported under 10 CFR 50.73(a)(2)(vii) as a common cause inoperability of independent trains because both trains contained boric acid deposits that obstructed the spray nozzles.

2. DESCRIPTION OF STRUCTURE(S), SYSTEM(S) AND COMPONENT(S):

The CS system consists of two independent trains of equal capacity, each capable of meeting the design basis requirement. Each train includes a CS pump, a shutdown cooling heat exchanger, spray headers, nozzles, valves, and piping. Each train is powered from a separate Engineered Safety Feature (ESF) bus.

The CS [EDS: BP] system, as a subsystem of the Safety Injection [EDS: BP] system, is an ESF designed to ensure that heat removal can be attained during post accident periods. During a Design Basis Accident (DBA), one CS train is required to maintain the containment peak pressure and temperature below the design limits, to remove iodine from the containment atmosphere to maintain concentrations below those assumed in the safety analysis, and to provide hydrogen mixing. To ensure these requirements are met, assuming the worst case single active failure occurs, two CS trains are required to be operable. TSs require a train's CS headers to be filled to a minimum level (113 feet elevation) in order for the headers to be OPERABLE.

3. INITIAL PLANT CONDITIONS:

On October 13, 2010, Palo Verde Unit 3 was defueled. There were no major structures, systems, or components inoperable at the start of the event that contributed to the event.

4. EVENT DESCRIPTION:

On October 13, 2010, upon completion of Surveillance Test 73ST-9SI02, "CS Nozzle Air Test," Engineering personnel determined the following spray nozzles were obstructed:

(1) Train A header (100' elevation) 3SI-A-430, on the end of the header (2)Train A header (120' elevation) 3SI-A-413, on the end of the header (3)Train A header (120' elevation) 3SI -A-413, second nozzle from the end of the header (4)Train B header (100' elevation) 3SI-B-440, first nozzle from the supply header (5)Train B header (100' elevation) 3SI-B-441, first nozzle from the supply header (6)Train B header (100' elevation) 3SI-B-438, first nozzle from the supply header (7)Train B header (100' elevation) 3SI-B-439, on the end of the header TS Surveillance Requirement (SR) 3.6.6.6 requires verification that each CS system spray nozzle (total of 620 nozzles) is unobstructed. The surveillance test for the CS system uses low pressure air to conduct the test. Each obstruction discovered in Unit 3 consisted of a friable boric acid deposit which fragmented easily while probing the deposit with a pipe cleaner.

The CS headers are periodically refilled to maintain the minimum level for the header to be OPERABLE per TSs. Prior events have occurred in which the headers were overfilled during the refill evolutions. The boric acid deposits were the result of boric acid solution that was not removed from low points that entrapped water in the CS headers following past CS header overfill events. The borated water subsequently evaporated causing boric acid to precipitate and form obstructions in the nozzles. The nozzles were cleaned and verified to be unobstructed prior to entering Mode 4.

5. ASSESSMENT OF SAFETY CONSEQUENCES:

Since the boric acid deposits were friable and easily removed using a pipe cleaner during the inspections, it is expected that CS header water and associated header pressure would dissolve or easily remove the boric acid deposits out of the nozzles if an actual CS event occurred.

Even if the boric acid deposits were not displaced or dissolved by CS header water pressure and the nozzles remained obstructed, the remaining spray nozzles that were not obstructed in the CS system would have provided the required spray flow. Therefore, each train would have achieved its safety function to rapidly reduce the containment pressure and temperature following a Loss of Coolant Accident (LOCA) or Main Steam Line Break (MSLB) as required by 10 CFR 50 Appendix A General Design Criteria (GDC) 38, Containment Heat Removal. Additionally, each train would have also met its safety function to control the concentrations of fission products, hydrogen, oxygen, and other substances that may have been released into the containment atmosphere following a LOCA as required by GDC 41, Containment Atmosphere Cleanup. Therefore, the blockage would not have prevented the fulfillment of any safety function and did not result in a safety system functional failure as defined by 10 CFR 50.73(a)(2)(v). Since the safety functions would have been met, post-accident radiological releases would not have exceeded those evaluated in the associated safety analyses.

The condition described in this LER did not result in any challenges to fission product barriers or in any offsite releases. Therefore, there were no actual adverse safety consequences or implications as a result of this event and the event did not adversely affect the safe operation of the plant or health and safety of the public.

6. CAUSE OF THE EVENT:

The root cause of the CS nozzle obstructions was boric acid solution was not removed from low points that entrapped water in the CS headers after these headers were overfilled with borated water during past CS header overfill events. The borated water subsequently evaporated causing boric acid to precipitate and form obstructions in the nozzles.

7. CORRECTIVE ACTIONS:

As described above, the obstructed nozzles were cleaned. The nozzles successfully passed the surveillance test procedure prior to entering Mode 4 at the end of the outage.

Actions to prevent recurrence include inspection, cleaning, and flushing of CS headers with low points that entrap water to remove boric acid residue in each of the three units.

Additionally, the operating procedure for recovery from shutdown cooling to normal operations was revised to initiate corrective actions to drain the affected CS headers following overfill events.

8. PREVIOUS SIMILAR EVENTS

A prior similar event was reported in 2007 under LER 50-530/2007-001-00 in which two CS A train nozzles were obstructed by boric acid deposits. The cause of the prior event was a lack of procedural guidance to detect and respond to a CS header overfill event. The respective operator log procedure was revised to require draining of the header if water from the vertical risers approaches the spill over to the CS header. The corresponding safety injection system operating procedure was changed to provide directions for draining the header. Based on experience to that point, the corrective actions did not consider the potential for future nozzle obstruction caused by the borated water that remained in the header.