ML101940096

Nrc/Harris Split Sample Results

ML101940096
Person / Time
Site:	Harris
Issue date:	07/08/2009
From:	Mulligan V American Radiation Services
To:	Wade Loo NRC/RGN-II
References
FOIA/PA-2010-0209 ARS1-09-01568
Download: ML101940096 (16)

Text

V.

2609 North River Road, Port Allen, Louisiana 70767 (800) 401-4277 -- FAX (225) 381-2996

d. VINTERNATIONAL American Radiation Services, Inc.

Laboratory Analysis Report ARS1-09-01568 Preparedfor:

Nuclear Regulatory Commission (NRC)

Wade Loo USNRC Region 2 61 Forsyth St. S.W.

Suite 23T85 Atlanta, Ga 30303-8931 wade.loo@nrc.gov Phone: 404-562-4727 Fax: 404-562-4955 Otut r-r\s: N. ý r rt rl.

Project Manager R4ý144 -(. Management Re &w Not": Amexica Radatllon Serces, Inc. asuoms no iabtfty for the use or inerprtatlion of " analyticalresu ts provided other than the cost of the sn*tysfs its ".

Repoducton of Ofs repor1 in less then U requires the wolhen consent of the client.

Contea Person: Questions regarding this analytkal report should be addressed to:

Project 14anager Project4anagers@amrad.com 6

Phone: 225.381.2991 Fax: 225.381.2996 LELAP Cart# 01949 NELAP Cert# E87558

A 2609 North River Road

• Port Allen, Louisiana 70767

-rR S IINTERNATIONAL 1 (800) 401 -4277

• Fax (225) 381-2996 July 8, 2009 Nuclear Regulatory Commission Wade Loo 61 Forsyth St. S.W. Suite 23T85 Atlanta, Ga 30303-8931 Sample ID(S): BDL-MWI, BDL-MW2, BDL-MW3, BDL-MW5, BDL-MW6, BDL-MW8 ARS SDG: ARSI-09-01568 Dear Mr. Loo; On May 21, 2009, ARS International received 6 aqueous sample(s) to be analyzed for Gamma Spectroscopy, 5 aqueous samples to be analyzed for Tritium, and I for Strontium-90.

The samples were processed and counted using the appropriate counting equipment and QA/QC for this type of analysis. Results of the analysis and QA/QC are attached in the data package.

The samples and QA/QCs were counted with a count time sufficient to meet quality control parameters for counting equipment were within acceptance criteria and statistical sound detection limits.

If you have any questions please do not hesitate to call at 225.381.2991 or email ProjectManagersaamrad.com.

S'ncerely,\

Virge&i Mulligan Laboratory Director ARS International

2609 North River Road e Port Allen, Louisiana 70767 1 (800) 401-4277 9 Fax (225) 381-2996 INTERNATIONAL COVER PAGE Statement of Work for Analytical Laboratories PROJECT SAMPLE IDENTIFICATION CROSS-REFERENCE TO ARS SAMPLE LABORATORY IDs SAMPLE ARS ID NUMBER(s) SAMPLE ID NUMBER(S)

BDL-MWI ARSI-09-01568-001 BDL-MW2 ARSI-09-01568-002 BDL-MW3 ARSI 01568-003 BDL,-MW5 ARSI-09-01568-004 BDL-MW6 ARS 1-09-01568-005 BDL-MW8 ARS1-09-01568-006 SAMPLE RECEIPT The samples were received in good condition. The samples were screened for radioactive contamination as per procedure ARS-062 "Sample Receiving".

ANALYTICAL METHODS The Gamma Spectroscopy determinations were performed using American Radiation Services procedure ARS-007/EPA 901.1, "Gamma Emitting Radionuclides in Water." The tritium analyses were performed using American Radiation Services procedure ARS-054, "Tritium In Water". ". The Strontium-90 analyses were performed using American Radiation Services procedure ARS-032, "Total Strontium by Eichrom Resin Seperation."

ANALYTICAL RESULTS The result data that are flagged with "U" indicates that the activity is below the MDC.

For Strontium analyses, the LCS fell outside the acceptance criteria biased low; RER and DER didn't meet acceptance criteria due to low bias of LCS; however the LCSD is well Within the acceptance criteria. The data is being reported per technical review.

2609 North River Road 9 Port Allen, Louisiana 70767 1 (800) 401-4277 9 Fax (225) 381-2996 ab...*-f INTERNATIONAL American Radiation Services Project Manager/Laboratory Director's Comments:

"I certify that this sample data package is in compliance with SOW requirements, both technically and for completeness, other than the conditions detailed above. Release of the data contained in this sample data package and the computer-readable EDD, as applicable, submitted on diskette or by modem, has been authorized by the Laboratory Manager or the Manager's designee, as ,erified by the following signature."

"I certify that this electronic image and all hardcopiesproducedfrom this image accuratelyrepresentthe data and is in compliance with the NRC specific requirements, both technically andfor completeness, other than the conditions detailedabove or in the sample data package narrative.Release, by submission through email, the data containedin this electronic image andthe computer-readableEDD (as applicable), has been authorizedby the laboratoryManager/TechnicalDirector or the Manager'sdesignee."

1,4 1 X i Laboratory Director, ARS International * - -'3 Signat e Title Date

2609 North River Road, Port Allen, Louisiana 70767 1 (800) 401-4277 FAX (225) 381-2996 INTERNATIONAL ARS Sample Delivery Group: ARS1-09-01568 Request or PO Number: N/A Client Sample ID: BDL-MWl ARS Sample ID: ARSI-09-01568-001 Sample Collection Date: 05/14/09 Date Received: 05/21/09 Sample Matrix: Aqueous Report Date: 07/06/09 NOTES:

Project Manager Revie~Y~(

Not"s: American Radiation Services, Irc. aIuMtlm Mo libility For the use or Interpretato of any analtytcal resuirs provkjed other than the COst of the anatis itsef. ReproductiOn Of this report i lessthan full reqtdres the written consent of the American Radiation Services, Inc.

LELAP Certificate# 01949 NELAP Certificate # E87558

260 (No)tie Road,27PotAlln Lo22 ian 70729 67 1 (600) 401-4277 FAX (225) 381-2996 INTERNATIONAL ARS Sample Delivery Group: ARS1-09-01568 Request or PO Number. N/A Client Sample ID: BDL-MW2 ARS Sample ID: ARS1-09-01568-002 Sample Collection Date: 05/14/09 Date Received: 05/21/09 Sample Matrix: Aqueous Report Date: 07/06/09 Anlss Analysis AnvlsAalssalyts AalssTicr/hr uaa/Cl Anlyi I~

De _ciption Results Error +/- 2 Units TAnalysis et t hod _ Anaysi Date/lme Anlsi Technician Recovery MN-54 -0.4-4 2.533 3.930 1.965 U pCI/L ARS-OO6/EPA 901.1 06/11/09 18:17 ILA N/A CO-58 -0.062 2.019 3.460 1.730 U PCVL . ARS"OO6/EPA 901.1 06/11/09 18:17 ILA N/A FE-59 -0.057 0.041 7.380 3.690 U pCI/I ARS-006/EPA 901.1 06/11/09 18:17 JLA N/A CO-60 -1.984 11.974 4.510 2.255 U PIO/L fARS-006/EPA 901.1 06/11/09 18:17 1.ILA N/A ZN-65 -0.161 6.005 8.920 4.460 U PCI ARS-006/EPA 901.1 06/11/09 18:17 ILA N/A NB-95 0.332 2.230 3.790 1.895 U pC/L I ARS-006/EPA 901.1 06/11/09 18:17 JLA N/A ZR-95 4.177 3.585 , 2.890 U PIUI I ARS-006/EPA 901.1 06/11/09 18:17 JLA N/A CS-134 1.375 2.209 3,670 1 1.835 U pCl/L ARS-006/EPA 901.1 06/11/09 18:17 ILA N/A CS-137 0.660 2.141 3,710 1.855 U IWL !ARS-006/EPA 901.1 06/11/09 18:17, ,LA N/A BA-140 -5.318 26.684" 15.000 1 7.500 I U PCI/L +i ARS-006/EPA 901.1 06/11/09 18:17 iLA N/A LA-140 0.776 2.715 4.680 2.340 U CI/I .O A.11 0 1018:17 9

H-3 .--......

520.944 1 127.666 184.586 1 91.178 A.--...-........

PCI/L ARS-054/EPA 906.0 06/15/09 03:09 8s.. N/A NOTES:

Project Manager Review t)

Notes: American RadiStlin Sericas, Inc. assumes no Ilability for the use or interpretation oaany analytical results provided other than the cost of the analysis Itself. Reproduction of this report in ies than full requires the written consesnt of the American Radiation Services, Inc.

LELAP Certificate# 01949 NELAP Certificate

• E87558

2609 North River Road, Port Allen, Louisiana 70767 1 (800) 401-4277 FAX (225) 381-2996 INTERNATIONAL ARS Sample Delivery Group: ARSI-09-01568 Request or PO Number: N/A Client Sample ID: BDL-MW3 ARS Sample ID: ARS1-09-01568-003 Sample Collection Date: 05/14/09 Date Received: 05/21/09 Sample Matrix: Aqueous Report Date: 07/06/09 Analysis Description Aj;1y$ l Results AnalysiCl Err o +1-2M 2 s Analysis U/- i Anelys$

n Method Test r AnaAsis ot e_i __ _ TA Analysis diniclan Re o wery Trecer/Chem MN-54 0.011 2.576 4.360 2.i80 U pCl/L ARS-006/EPA 901.1 06/11/09 18:18 JLA N/A C0-58 -0.390 8.380 3.970 1 1.985 U pCi/L ARS-006/EPA 901.1 06/11/09 18:18 JLA N/A FE-59 1.612 4.733 8.030 4.015 U pC/L ARS-006/EPA 901.1 06/11/09 18:18 JLA N/A CO-60 0.868 2.641 4.460 2.230 U pC/L 1 ARS-006/EPA 901.1 06/11/09 18:18 JLA N/A ZN-65 -0.011 5.265 8.980 4.490 U pCI/L ARS-006/EPA 901.1 06/11/09 18:18 JLA N/A NS-95 -2.627 205.03.0 4.390 2.195 U PO/L ARS-006/EPA 901.1 06/11/09 18:18 JLA N/A ZR-95 0.978 4.108 6.910 3.455 U POL ARS-006/EPA 901.11 06/11/09 18:18 JLA N/A CS-134 0.659 2.844 4.780 2.390 U I__L ARS-006/EPA 901.1 1 06/11/09 18:18 JLA N/A CS-137 0.190 2.829 4.770 . 2.385 U pCVL ARS-006/EPA 901.1 06/11/09 18:18 JLA N/A BA-140 1.314 10.033 17.000 . 8.500 U pCVL ARS-006/EPA 901.1 06/11/09 18:18 JLA N/A LA-140 -3.700 8.290 6.300 3.150 U pci/L ARS-006/EPA 901.1 i 06/11/09 18:18 JLA N/A SR-90 0.077 0.078 0.260 0.123 U pCI/L ARS-032/EkuhSreni. 1 06/16/09 16:33 2S 83%

H-3 1056.951 163.759 184.19 90.987 pCVL ARS-054/EPA 906.0 06/15/09 08:17 BJS N/A NOTES:

Project Manage r v ew U Notes. Anerican Radiation Services, Inc. assumes no liability for the use or interpretation of any analytlcal results provkJed other then the cost of the analysis itself. Reproduction of this report in less than full requires the written consent of the American Radiation Services, Inc.

LELAP Certificate# 01949 NELAP Certificate

• E87558

269Nrt ie Ro00),01-ort FAllX(2u2i5) 707g67 1 (800) 401-4277 'AX (225) 381-2996 INTERNAMINAL ARS Sample Delivery Group: ARSI-09-01568 Request or PO Number: N/A Client Sample ID: BDL-MWS ARS Sample ID: ARS1-09-01568-004 Sample Collection Date: 05/14/09 Date Received: 05/21/09 Sample Matrix: Aqueous Report Date: 07/06/09 Analysis Analysis Results Analysis Error +/- 2 MDC 1 -

t* Qual units Analysis Test MethDate/m Analysis Analysis Technldan Tramer/Chem Recovery MN-54 0.000 2.598 4.420 2.210 U 0CIL ARS-006/EPA 901.1 06/11/09 18:19 ILA N/A CO-SB -0.159 2.095 3.570 1.785 U pC/Li ARS-006/EPA 901.1 06/11/09 18:19 JILA N/A FE-59 -1.430 92,545 7.830 3.915 U PCI/LI ARS-006/EPA 901.1 06/11/09 18:19 JILA N/A CO-60 -1.109 14.5S7 4.330 2.165 U pCI/L I ARS-006/EPA 901.1 06/11/09 18:19 ILA N/A ZN-65 -2.266 192.260 6.840 3.420 U CIVL ARS-006/EPA 901.1 1 06/11/09 18:19 JILA N/A NB-95 -1.091 12.628 4.030 2.015 U pCi/L ARS-006/EPA 901.1 06/11/09 18:19 JILA N/A ZR-95 1.602 3.878 6.500 3.250 U PCI/L ARS-006/EPA 901.1 06/11/09 18:19 JILA N/A CS-134 -0.589 23.569 4.250 2.125 U pCV/L ARS-O0EEPA 901.1 06/11/09 18:19 ILA N/A CS-137 1.191 2.672 4.580 2.290 U pCI/L ARS-006/EPA 901.1 06/11/09 18:19 ILA N/A BA-140 0.161 8.812 15.000 7.500 U pC/L ARS-006/EPA 901.1 06/11/09 18:19 JLA N/A LA-140 -1.180 3.090 5.240 2.620 U pCiL ARSf006/EPA 901.1 06/11/09 18:19 JLA N/A 1096.201 166.624 183.758 90.769 pCS/LI ARS-054/EPA 906.0 06/15/09 13:25 83S N/A

( NOTES:

Project ManagerRve Notes: AmerIcan Radiation Services, Inc. asswnes no liability fRrthe use or interpetatlon of any analytical results provided other than the cM of the analysi itself. Reproducion of this report In less than full redgmesthe wrlttmn -onsenl of the American Radiation Saneaws, Inc.

LELAP Certificate# 01949 NELAP Certificate # E87558

269NrtL ie R800),401P42 t FAllX Louiian 707967 1 (800) 401-4277 lAX (225) 351-2996 iNTERNATIONAL ARS Sample Delivery Group: ARS1-09-01568 Request or PO Number: N/A Client Sample ID: -BDL-MW6 ARS Sample ID: ARS1-09-01568-005 Sample Collection Date: 05/14/09 Date Received: 05/21/09 Sample Matrix: Aqueous Report Date: 07/06/09 Analylsis Analysi Analysis MDCoic Analyvs Quall iReslts I Error +/-*2 s D , DLC Anialysis AnalysIs Analysis Tracer/Chem Units Tat Method . Date/Time Te-chnician Recovery MN-54 -2.917 4.386 4.140 2.070 U pCi/L ARS-006/EPA 901.1 06/11/09 18:20 JILA N/A CO-58 0.000 2.188 3.710 1.855 U pCi/L ARS-006/EPA 901.1 06/11/09 18:20 3LA N/A FE-59 -3.032 230.430 7.970 j 3,985 U pCVL ARS-006/EPA 901.1 06/11/09 18:20 ILA N/A CO-60 0.136 2.317 4.010 2.005 U pCi/L ARS-006/EPA 901.1 06/11/09 18:20 ILA N/A ZN-65 -3.235 5.456 9.060 4.530 U PCI/L ARS-006/EPA 901.1 06/11/09 18:20 ILA N/A N8-95 -0.553 4.165 3.990 1.995 U PCVL ARS-D06/EPA 901.1 06/11/09 18:20 1LA N/A ZR-95 1.448 T 3.931 6.580 3.290 U pCVL ARS-006/EPA 901.1 06/11/09 18:20 ILA N/A CS-134 -0.034 I 2.562 4.350 i 2.175 U PCI/iL ARS-006/EPA 901.1 06/11/09 18:20 ILA N/A CS-137 -0.785 20.065 4.190 1 2.095 U PCI/L ARS-'006/EPA 901.1 1 06/121/09 18:20 ILA N/A BA-140 1.091 8.802 15.100 7.550 U PCI/L ARS-006/EPA 901.1 1 06/11/09 18:20 .LA N/A LA-140. -2.123 8.978 5.720 2.860 U pCl/L ARS-006/EPA 901.1 06/11/09 18:20 1LA N/A H-3 1552.790 204.344 182.822 90.307 pCIVL ARS-054/EPA 906.0 ] 06/15/09 18:33 BiS N/A NOTES:

CA~t Project Manager Review 0U Notes: American Radiation Services, lnc. masumes no liability for the use or interpretation of any analytical rmeilts provided other then the cost of the analysIs Itself. Reproduction of this report In iet than full requires the written consent of the American Radiation Services, Inc.

LELAP Certiflcate# 01949 NELAP Certificate # E87558

2609 North River Road,, Port Alien, Louisiana 70767 1 (800) 401-4277 FAX (225) 381-2906 tIN TERNATIONAL ARS Sample Delivery Group: ARS1-09-01568 Request or PO Number: N/A Client Sample ID: BOL-MW8 ARS Sample ID: ARS1-09-01568-006 Sample Collection Date: 05/14/09 Date Received: 05/21/09 Sample Matrix: Aqueous Report Date: 07/06/09 Analysis Anlysis Analysi _ - ( Analy sAisatms AnaAlysis Analysi Tra-er/Chai rResults Error +/- 2[s - n Test Nethod Date/lme Techcan R MN-54 1.083 2.195 3.670 1.835 U PCI/L ARS-006/EPA 901.1 06/.12/09 17:24 , ILA N/A CO-58 -0.105 1.965 3.370 1.685 U PC/L ARS-006/EPA 901.1 06/12/09 17:24 LN/A FE-59 1.580 3.760 6.S70 3.285 U PC/L ARS-006/EPA 901.1 06/12/09 17:24 ILA N/A CO-60 -2.017 11.775 4.590 2.295 U pCI/L i ARS-006/EPA 901.1 06/12/09 17:24 JLA N/A ZN-65 -2.493 34.420 8.180 4.090 U pCI/L. ARS-006/EPA 901.1 1 06/12/09 17:24 ILA N/A NB-95 -0.060 9A153 3.820 1.910 U pCl/L ARS-006/EPA 901.1 06/12/09 17:24 JLA N/A ZR-95 3.194 3.111 5.040 2.520 U pa/L I ARS-006/EPA 901.1 06/12/09 17:24 ]LA N/A CS-134 -0.177 2,296 3.930 i 1.965 U PC/L i ARS-006/EPA 901.1 06/12/09 17:24 ILA N/A CS-137 0.33S 2.225 3.88,0 1.940 U pcI/L. ARS..006/EPA 901.1 06/12/09 17:24 .LA N/A aA-140 1.471 8,024 15.100 7.550 U EI.L ARS-006/EPA 901.1 06/12/09 17:24 ILA N/A LA-140 -0.761 3.114 5.360 2.680 U pCiL ARS-006/EPA 901.1 06/12/09 17:24 J-A N/A H-3 S6.95 1 105,415 177.434 87.645 U pC/L ARS-054/EPA 906.0 06/15/09 23:41 BiS N/A NOTES, - ..-...

NOTES:

Project Manager Review U K)

Note: American Radiation Services, Inc. assumes no liability for the use or interpretation of any analytical results provided other than the cogt of the analysis Itself. ReproduCtion of this report in less than hl requires the written consent of the American Radiation Services, Inc. -

LELAP Certificate# 01949 NELAP Certificate # E87558

A 2609 North River Road, Port Allen, Louisiana 70767 1 (800) 401-4277 FAX (225) 381-2996

~gRS INTERNATIONAL QC Results Report Sample Delivery Group: ARS1 01568 Date Received: 05/21/09 Laboratory Control Sample Evaluation AIkifif Batch c

Type APset1d W emIt.

Repot Analysis Anotyas 1 Anelysni Percent LCA value Units Test Method Deate/Time Technicmia Recovery (%) Range A!SI-509-02160 LCS C0-60 24897.000 501.530 225.700 25394,583 pCi/g EPA 901.1 6/11/09 17:42 ILA 98 75%-125%

AItS1-809-02160 LCS CS-137 15371.000 367.090 140.100 15365.617 PCi/O EPA 901.1 6/11/09 17:42 JLA 100 75%-125%

AkS1;809-02160 LCS AM-241 34699.000 1259.900 276.700 34896.700 pCi/g EPA 901.1 6/11/09 17:42 LA 99 75%-125%

Blank Evaluation Anlss Q AnialtmAelytee CI, Cu 1(1a) Hoc Expected Report seyl Analy sis Analysi s Batch Type i vsalo Que Unite Test Method Date/Time Teceildan AP.S1-809-02160 MBL CO-60 0.000 0.004 0.016 NA U pCVg EPA 901.1 6/11/09 17:42 ILA AkS14-09-02160 MBL CS-137 0.000 0.005 0.017 NA U PO/N EPA 901. 1 6/11/09 17:42 ILA AR5s1-09-02160 MBL AM-241 -0.002 0.010 0.023 NA U PC0/g EPA 901.1 6/11/09 17:42 JILA RER Duplicate Evaluation SAtls QC Tp Analysis Raevst I CSU I (I a) Retit 2 cSu 2 (1) l AQu Analysis AalysisR AcAeptlcsseRn Batch Type Description Q Umnits Test Method Dete/Time Techndden e ARS1-809-02160 LCSD CO-60 24897.000 501.530 25160.000 497.650 pCi/g EPA 901.1 6/11/09 17:42 ILA 0.26 < 1 0

ARS1-B09-02160 LCSD CS-137 15371.000 367.090 14664.000 326.430 P /0 EPA 901.1 6/11/09 17:42 JLA 1.02 < 1 ARS1-B09-02160 LCSD AM-241 34699.000 1259.900 34685.000 12710.000 P0/9 EPA 901.1 6/11/09 17:42 JLA 0.00 DER Duplicate Evaluation Analysis Batch QC Analysli Tyfpe -Descriptio Re1sit I MU1(14) R1mdt2 s 12(1,,

Qumd An Any MR DER D'R uit Test Melthod Dati/Titme Techrmddm go ARS1-B09-02160 LCSD CO-60 24897.000 501,530 25160.000 497.650 pCi/g EPA 901.1 6/11/09 17:42 'ILA 0.74 <3 ARS1-B09-02160 LCSD CS-137 15371.000 367.090 14664.000 326.430 p0/g EPA 901.1 6/11/09 17:42 ILA 2.88 < 3 ARS1-B09-02160 LCSD AM-241 34699.000 1259.900 34685.000 12710.00 pCO/ EPA 901.1 6/11/09 17:42 JA 000 < 3 ProjectManagerReviw U Notes: Amnerk*n Radiatlon Services, Inc, assumes no liability for the uie or interpretation of any analytical resultsprovidedother than the cost of the analysis kseaf. Reproduction of this report in lea than full requires the written consent of tI*e LELAp Certificate# 01949 NELAP Certificate # E87558

2609 North River "nad, Port Allen, Louisiana 70767 1 (800) 401-4277 FAX (225) 381-2996 WA AERICAN RADIATION SERVICES, INC.

QC Results Report Sample Delivery Group: ARSI-09-01568 Date Received: 05/21/09 Laboratory Control Sample Evaluation

• ' t (Expected RepOrt Analysis Analysis Analysis PelCB Analysis Batch QC TylI AAa to A nlyhnas value I U) t mTt Method Data/jnme Technidan Recovery ( R)ane JARSI-e09-02125 LCS Sr-90 19.73 1 5 0.465 20.64 pCl/L ARS-032/EPA 905.0 6/16/09 16:33 BJS 96 7S%-125%

Blank Evaluation InalrsAs I Bth

_T ARS1-809-02125 Q

TpR MOL yp - "t Sr-90 Analysis 0.106 CSU (I 0.14 Analysis 4Cd 0.474 val ue-NA 1

Analysis1(

Rp" u n its-T pCIi/

asy n t)eExpec Tst Method e st ARS-032/EPA 905.0 te/Te I

/T e 6/16/09 16:33 Teciian BJS RER Duplicate Evaluation Anayis QC Analysis Resul I Cal I (10) ROSR

• cu2 Analysis Analysis Analysis TeAnalysis Rs A.=e.tan Batch 1 1 *w Toosmth" DOte/Time Techniidan m ARS1-B09-02125 LCSD Sr-90 19.73 1.5 14.30 1.1 pCI/ ARS-032/EPA 905.0 6/16/09 16:33 1 IS 2.07 < 1 DER Duplicate Evaluation Analysis QC Anyalys s 1 1 1I 1 Unit, Analysis An vale Analysis 1An.*i, I einl DER AcceptandeR Botch Type i ascrlptan I 1 (1 . t: I* Testnltod I Diste/a/nTh ARS1-8og-02125 LCSD Sr-90 19.73 1.5 14.3 11.1 PCI/L ARS-032/EPA 905.0 6/16/09 16:33 BJS 5.78 < 3 Project Manager Review # 1C U Notes: American Radiation Sericna, Inc. assuines no liability for the usa or Interpretation of any analytical results provided other than the meotof the analysis itself. Reproduction of this report In less than hull requires the written consent of the LELAP Certificate# 30658 NELAP Certificate

• E87558

gRS INTERNATIONAL 2609 North River Road, Port Allen, Louisiana 70767 1 (800) 401-4277 FAX (225) 381-2990 QC Results Report Sample Delivery Group: ARSI-09-01568 Date Received: 5/21/2009 Laboratory Control Sam ple Evaluation _ _. _ Report An ___A y__

AAelySyt IsU Q¢AUdysV 1 (1 9) LDCpcfed Q"eUnte A.Maiyeho Deeyswe Te-ya -- y Lcc 1 _ n ot c h_ I_ Ty p e _ I_ Re s_ 1_1_It_ V ON"_ T 90 6 0 I /t I I ARSI-509-02126 ILC H3 1360.904 187.652 182341 1234.408] I [ ARS-054/E-A 906-0 6/14/09 1:28 BS 110 75%-125%

Blank Evaluation aaar TAQ T AAot~to slym l u ( Expected VAlue aApnt Units AlyMethod Test Deat/TI'me Anahol Technician ARSI-009-02126I MBIL H3 -4.944 108.695 184.804 NA p0/L ARS-054/EPA 906/0 6/14/09 11:44 s5 RER Duplicate Evaluation Anlxx QC I AnalIs I AIel Tnlyl Analysis r -- -- -

a(1) Remlt2 c a2(] QJkI T Mei ho Anaayni Act aetch Type DUnIt ReTuft I C"J Teat Meshed J Date/Time Tedilci-en A J ARS1-509-02126 LCS H3 1360.904 187.652 1235.804 178.721 pC/. ARS-0S4/EPA 906.0 6/14/09 6:36 BS 0.34 <

DER Duplicate Evaluation Analyt Ancall ult I I ( ) Result; 2 li Qum AnI- Analysis AnelYW Analyals OER ea Batch [ Type Demolption t I (it) I TeR( Method ilDate/Time Techdmies, I I ARSI-B09-02126 LCS H3 1360.904 187.652 1235.804 178.721 [W6.0 PCiL ARS-054/EPA 6/14/09 6:36 BS I.97 < 3 Project Manager Review Notes: American Radiation Services, Inc. asumen no liabilty for the ust or Interpretation of any analytical rnuJht provided other than the cost of the anaysis itslif. Reproduction of this report In less than full requires the written consent of ARS LELAP Certificate# 01949 NELAP Certificate # E87558

A 52609 North River Road

• Port Allen, Louisiana 70767 1(800) 401-4277

• Fax (225) 381-2996 INTERNATIONAL Notes:

Comments:

1.0) Soil and Sludge analysis are reported on a wet basis or an as received basis unless otherwise indicated.

2.0) Data in this report are within the limits of uncertainty specified in the reference method unless otherwise specified.

3.0) Modified analysis procedures are procedures that are modified to meet the certain specifications. An example may be the use of a water method to analyze a solid matrix due to the lack of an officially recognized procedure for the analysis of the solid matrix.

Modified analyses are indicated by the subsequent addition of "m" to the procedure number (i.e. 900.OM).

4.0) Derived Air Concentrations and Effluent Release Concentrations are obtained from 10 CFR 20 Appendix B.

5.0) Total activity Is actually total gamma activity and Is determined utilizing the prominent gamma emitters from the naturally occurring radioactive decay chains and other prominent radioactive nuclides. Total activity may be lower than the actual total activity due to the extent of secular equilibrium achieved In the various decay chains at the time of analysis. The total activity is not representative of nuclides that emit solely alpha or beta particles.

6.0) Ra-228 is determined via secular equilibrium with its daughter, Actinium 228. (Gamma Spectroscopy only).

7.0) U-238 is determined via secular equilibrium with its daughter, Thorium 234. (Gamma Spectroscopy only).

8.0) All gamma spectroscopy was performed utilizing high purity germanium detectors (HPGe).

9.0) ARS makes every attempt to match sample density to calibrated density; however, in some cases, It is not practical or possible to do so and data results may be affected.

Method

References:

1.0) EPA 600/4-80-032; Prescribed Procedures for the Measurements of Radioactivity in Drinking Water, August 1980.

2.0) Standard Methods for Examination of Water and Waste Water, 18', 1992.

3.0) EPA SW-46; Test Methods for Evaluating Solid Waste, Third Edition, (9/86). (Updated through 1995).

4.0) EPA 60014f79-020; Methods for Chemical Analysis of Water and Waste, March 1983.

6.0) HASL 300 6.0) ARS-040; An LCSD is not reported with this process. The criteria for the LCS/LCSD analysis for reproducibility have not been established for Low Level Tritium analysis. A prepared standard for Low Level Tritium has not been developed. As a result. the standard we use Is based on the dilution of a verified conventional tritium standard. The volume required for Low Level Tritium analysis, in addition to the lack of an available Low Level Tritlum standard, Introduce variability into the LCS/LCSD analysis that does not represent the actual sample analysis. The preferred measure for reproducibility'is to run a duplicate analysis of a sample.

Definitions:

1.0) ND Not detected above the detection limit (non-detect).

2.0) MDC (Minimum Detectable Concentration) minimum concentration of the analyte that ARS can detect utilizing the specific analysis 3.0) MBL Method Blank 4.0) DO Duplicate Original 5.0) DUP Method Duplicate 6.0) MS/MSD Matrix Spike/Matrix Spike Duplicate 7.0) S Spike 8.0) RS Reference Spike 9.0) *SC Subcontracted out to another qualified laboratory 10.0) NR Not Referenced 11.0) N/A Not Applicable 12.0)

• Reported as a calculated value 13.0) False Positive due to interference from Bi-214 14.0) U Activity is below the MDC 15.0) LCS/LCSD Laboratory Control Standard/Laboratory Control Standard Duplicate Notes: ARS International assumes no liability for the use or interpretation of any analytical results provided other than the cost of the analysis itself. Reproduction of this report in less than full requires the written consent of ARS International.

LELAP Cert#30658 NELAP CerW E87558

a ai PAGE OF '2-NRC FORM 303 (4-2004)

U.S. NUCLEAR REGULATORY COMMISSION LABORATORY USE ONLY REQUEST FOR ANALYSIS AND CONTROL NUMBER CHAIN OF CUSTODY LABORATORY - ORISE SAMPLE LOCATION (LICENSEE) LICENSE NO. DOCKET NO.

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