ML101750149

Indiana Michigan Power D. C. Cook Nuclear Plant Groundwater Discharge Authorization Application for the Disposal of Wastewater to the Ground or Groundwater

ML101750149
Person / Time
Site:	Cook
Issue date:	12/01/2008
From:	Indiana Michigan Power Co
To:	Office of Information Services, State of MI, Dept of Environmental Quality
References
FOIA/PA-2010-0209, GW1810102
Download: ML101750149 (174)

Text

Indiana Michigan Power D.C. Cook Nuclear Plant Groundwater. Discharge Authorization Application For the disposal of wastewater to the ground or groundwater December 1, 2008 Renewal of Permit GW1810102 Issued October 4, 2007 g- -7/

STATE OF MICHIGAN GROUNDWATER DISCHARGE AUTHORIZATION APPLICATION for the disposal of wastewater

• to the ground or groundwater

)

Permits Section Groundwater Permits Unit Water Bureau Michigan Department of Environmental Quality Jennifer M. Granholm, Governor Steven E. Chester, Director

PREFACE This document contains a set of instructions and the application form necessary to apply for a groundwater discharge authorization. The instructions are organized to allow you to determine what type of authorization is required and how to obtain it.

The instructions first list several types of groundwater discharges that are prohibited, then several types of discharges that are automatically authorized, referred to as exemptions. If the discharge you are proposing is on either of these lists, you will not need to submit an application form. All other discharge authorization requests are required to file an application form. The instructions go on to list several other specific types of discharges that can be authorized short of a full permit. If the discharge is not included among those listed, then you must apply for a permit under Rule 2218.

The application form has two parts. The first is general information, which must be filled out by all applicants. The general information section is found on Pages 14-17 of the application. The second half of the application is divided into sections that are specific to the type of authorization being sought.

Authorizations issued under Rules 2211, 2213 and 2216 are for very specific discharges, and are listed in the instructions. All remaining discharges are authorized under Rule 2218. Once you have determined what type of authorization you require and filled out the general information section, you should locate the portion of the application specific to your discharge and fill out the appropriate information. Page 18 of this document contains a detailed index listing the specific pages to be filled out for each specific discharge.

Please note: The Rules require that the applicant must provide all information necessary to make a permit decision. Applications that do not contain all necessary information will be returned as incomplete.

2 EQP5305 (Rev 12/2004)

TABLE OF CONTENTS Part I, Instructions Paqe A. GENERAL INFORMATION

1. Who m ust apply for a perm it? ............................................ . . . . . . . .. .. . . . . . . . .. . . . . . . .. . . . . . . . . .. .. . . . 4

2. P u rp o s e .............................................................................................................................. 4

3. Inform ation requirem ents for all dischargers ................................................................... 4

4. Requirements for all dischargers ......................................... 4

5. Discharge pro hibitions ........................................................................................ ...... 4

6. Isolation distances .............................................................. 5

7. C hanges to an existing discharge ............................................................................... ...... 5

8. Equivalency demonstration ........ ..... 5 B. IDENTIFICATION OF THE TYPES OF AUTHORIZATIONS

1. Exemptions ........................................................ 5

2. Discharge specific exem ptions .................................................................................... 7

3. P e rm it a utho rizatio ns .................................................................................................. .. 8 C. RULE 2218

1. Inform ation requirem ents ...... ............................................................................. 8

2. Rule 2219 - Feasibility of Alternatives ......................................................................... .9

3. R ule 2218(2) - Basis of Design .................................................................................. 10

4. R ule 2223 - Discharge Monitoring .............................................................................. 10 D. APPLICATION PROCESS

1. When do I have to apply? ....................................... ;...... .. . . . . . . . .. . . . . . . .. . . . . . . .. .. . . . . . .. .. .. . . . . . 12

2. How is the application form organized? ................................... . . . . . . . . . .. . . . . . . .. . . . . . . . .. .. .. . . . 12

3. Who must sign the application form? .. . .. .. .. . .. .. .. .. . .. .. .. . .. .. .. . .. .. 12

4. A dditional reference m aterials ..................................................................................... 13

5. Who should I call if I have questions? 7 .................................... . . . .. . . . . . . .. .. . . . . . . .. . . . . . . . . . . . . . 13

6. Where should the application form be sent? . . . . . . .. . . . . . . . . . . . . .. . ... . . . . . . . . ........... ......... 13

7. Operational Requirements ............................................. 13

8. Penalties .............................................. .. . ............................................. 13 Part II, PERMIT APPLICATION', EQP 5305 G e ne ra l info rm atio n ............................................................................................................... 14 -17 Detailed Rule Index ............................ "........................................................ 18 Rule 2 2 1 1 A utho rizatio n .............................................................................................................. 19 Ru le 2 2 13 Autho rizatio n .............................................................................................................. 23 R u le 2 2 15 A utho rizatio n .............................................................................................................. 27 Ru le 22 16 Auth o riz a tio n .............................................................................................................. 32 Rule 22 18 Autho rization ................................................................................................................ 36 R ule 22 10(y) A uthorization ................................................................................................... 40 Appendix A - Treatm ent Method Classification ................................ *.................................... 41-44 Appendix B - O perational Requirem ents ............................................................................... 45-46 3 EQP5305 (Rev 12/2004)

-A.GENERALINFORMATION- - .

1. WHO MUST APPLY FOR A PERMIT?

Section 3112(1) of Part 31, Water Resources Protection, of the Michigan Natural Resources and Environmental Protection Act of 1994, PA 451 as amended (Act 451) states that any person discharging any waste or waste effluent into the waters of this state must be in possession of a valid authorization to discharge from the Michigan Department of Environmental Quality (department).

A "person" is defined as an individual, partnership, corporation, association, governmental entity, or other legal entity.

2. PURPOSE The purpose of the Part 22 Rules is to preserve the quality of groundwater for all of its protected uses, both current and potential future uses. Section 3109(1) of Act 451 prohibits the direct or indirect discharge into any waters of the state any substance that is or may become injurious to any protected uses of those waters. The department enforces this prohibition through the "Part 22" Administrative Rules, contained at M.A.C.

R323.2201 through 2240. These rules are referenced in this document as Rule 2201 through 2240. The protected uses include public health, safety, and welfare; domestic, commercial, industrial, agricultural, recreational or other uses that may be made of such waters; the value or utility of riparian lands; and the use of the water by livestock, wild animals, birds, fish, aquatic life, or plants or the growth or propagation of those entities.

3. INFORMATION REQUIREMENTS FOR ALL DISCHARGERS Rules 2206 and 2217 require that you must provide all information for the Department to make a decision regarding an application for a groundwater discharge authorization. Ifthe information is not provided, the application will be returned as incomplete.

4. REQUIREMENTS FOR ALL DISCHARGERS Rule 2204 establishes certain requirements for all dischargers. These are:

1. The discharge must not become injurious.

2. The discharge must not cause runoff to, ponding of, or flooding of adjacent property.

3. The discharge must not cause erosion.

4. The discharge must not cause nuisance conditions.

5. The discharge must be located not less than 100 feet inside the boundary of the property where the discharge occurs, unless authorized by Rule 2210, 2211, 2213 or a lesser distance is approved by the department.

6. The discharge must be isolated from water supply wells as indicated in Rule 2204(2)(d).

7. The discharge must not create a facility under Part 201 of Act 451.

There are certain operational requirements for each type of discharge that must be met after an authorization is issued. Those requirements are found in Appendix B, Pages 45-46 of the application form.

5. DISCHARGE PROHIBITIONS Rule 2205 prohibits:

1. A discharge without an authorization under Rule 2204.

2. A discharge from a general-purpose floor drain unless authorized under Rule 221 0(v), Rule 2215 or 2218.

3. A discharge of wastewater originating from a structure within 200 feet of an available public sanitary sewer system, except for a discharge of non-contact cooling water or a discharge from a groundwater remediation activity. For sanitary sewage, an available public sanitary sewer system is defined by section i2751 (a) of Act 368 of ihe Pubiic Acts of I98o, as aiended, beingy-'3. i27,5 ia) of t Ie Michigan Compiled Laws. For any other discharge, the department must make a determination of availability based on the ability of the public sanitary sewer system to treat the wastewater and the costs associated with providing the treatment.

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• , * *,* ,*l*'..,,..'*I

6. WHAT SETBACK REQUIREMENTS MUST I MEET FOR MY DISCHARGE?

If the discharge is authorized under Rules 2216 or 2218, the point of discharge must be at least 100-feet within the property boundary, unless an alternate distance is required or allowed by the department. Also, there are requirements under Rule 2204(2)(d) for isolation distances from existing water supply wells. The following table lists those isolation requirements.

Well Type Permit Authorization - 2218, 2216 (3) All Other Authorizations 1,Ila 2000 feet 200 feet lib, Ill 800 feet 75 feet Domestic 300 feet 50 feet

7. WHAT IF I HAVE AN EXISTING PERMIT, AND THERE IS A CHANGE IN MY DISCHARGE?

Ifyou anticipate there will be a change in either the quantity or quality of your discharge, you must notify the department prior to making the change. Within 30 calendar days of receiving the notice of modification, the department will notify you whether the modification is considered minor or significant. Ifthe department determines the change is minor, you can make the changes you have identified, and the existing permit will be modified to reflect those changes. The department will send you a copy of the amended permit. Ifthe changes are determined to be significant, then you must reapply for a permit by completing the application form and submitting it to the department for review and approval.

8. HOW DO I DEMONSTRATE EQUIVALENCY?

In many instances, the Part 22 rules allow you to provide equivalent information or alternative ways of meeting the conditions of the Rules. To demonstrate equivalency, you should provide both a narrative description and technical data to show that the alternative proposed meets the intent and achieve the same purpose as the Rule in question. For example, there are specific requirements for source water for Fruit &Vegetable washwater, Rule 2211 (c), including municipal water, a water source meeting state or federal criteria, or water meeting standards of Rule 2222. An alternative water source not specified is surface water. If.you wish to use surface water, you need to describe and demonstrate, possibly through water quality testing, how the surface wate'r meets the intent of the Rule and provides equivalent environmental protection to the sources specified in the Rule.

B. IDENTIFYING THE TYPE OF AUTHORIZATION REQUIRED This section lists all of the specific discharges identified in the Part 22 Rules. You should review the list and determine if your discharge is listed, and then follow the directions for how that particular discharge receives authorization.

1. EXEMPTIONS Pursuant to Rule 2210 the activities listed below are automatically authorized and are exempt from obtaining a further authorization from the department, provided the requirements of Rule 2204 are met. You do not need to submit an application form.

(a) Sanitary sewage in either of the following circumstances ifthe sanitary sewage is not mixed with other waste:

(i). The discharge is less than 1,000 gallons per day and the disposal system is approved by the county, district, or city health department that has jurisdiction in accordance with either the requirements of the local sanitary code or the provisions of the publication entitled "Michigan Criteria for Subsurface Sewage Disposal," April 1994. Copies of the publication may be obtained without charge at the time of adoption of these Rules from the Michigan Department of Environmental Quality, Water Division, P.O. Box 30630, Lansing, Michigan 48909.

(ii) The discharge is less than 6,000 gallons per day, the disposal system is designed and constructed in accordance with the provisions of the publication entitled "Michigan Criteria for Subsurface Sewage Disposal," April 1994, and the system is approved by the county, district, or city health department that has jurisdiction. Copies of the publication may be obtained without charge at the time of adoption of these Rules from the Michigan Department of Environmental Quality, Water Division, P.O. Box 30630, Lansing, Michigan 48909.

5 EQP5305 (Rev 1212004)

(b) Controlled application of any of the following:

(i) An authorized substance to suppress dust. The following are authorized substances:

...... . .... (A )-W a te r . . . . . .. .. .... . . ..... .

(B) Calcium chloride.

(C) Lignosulfate products.

(D) Emulsified asphalt or resin stabilizers.

(E) Vegetable by-products.

(ii) A deicing substance.

(iii) A substance for a natural resource or right-of-way maintenance program.

(iv) A substance for a domestic activity.

(v) A commercially manufactured pesticide or fertilizer for its intended use.

(c) Stormwater, other than from a secondary containment facility, when discharged through surface infiltration.

(d) Stormwater from a secondary containment facility that does not contain leaks or spills if the stormwater is inspected to ensure it meets the standards established in Rule 2222.

(e) Water from a well used temporarily for dewatering at a construction site if the water pumped does not create a site of environmental contamination under part 201.

(f) A discharge from an animal feeding operation that has less than 5,000 animal units if the discharge is determined by the director of the department of agriculture or his or her designated representative, to be in accordance with generally accepted agricultural and management practices, as defined in Act No. 93 of the Public Acts of 1981, as amended, being 286.471 to 286.474 of the Michigan Compiled Laws, and known as the Michigan right to farm act. For purposes of this Rule, 5,000 animal units is equal.to 5,000 head of slaughter or feeder cattle, 3,500 mature dairy cattle, 12,500 swine weighing ýmore than 25 kilograms or approximately 55 pounds, 50,000 sheep or lambs, 2,500 horses, 275,000 turkeys, 150,000 laying hens or broilers, or 25,000 ducks. An animal feeding operation is a lot or facility, or series of lots or facilities under one ownership which are adjacent to one another or which use a common area or system for the disposal of wastes, that meets both of the following conditions:

(i) Animals, other than aquatic animals, have been, are, or will be stabled or confined and fed or maintained for a total of 45 calendar days or more in any 12-month period.

(ii) Crops, vegetation, forage growth, or postharvest residues are not sustained in the normal growing season over the portion of the lot or facility where animals are confined.

(g) Less than 50 gallons of wastewater per day from a commercial animal care facility.

(h) Observation or monitoring well development or evacuation water.

(i) Potable water used for a domestic or domestic equivalent activities other than sanitary sewage disposal.

(j) Step test or pump test water from any of the following:

(i) A potable well or well used to develop a potable water supply.

(ii) A well producing water that meets state or federal criteria for use as potable water.

(iii) A test well where the quality of the test well discharge Water is equal to or better than the background groundwater quality of the aquifer receiving the discharge.

(k) Exfiltration from sanitary sewer collection systems.

(I) Wastewater from a heat pump that has a heat exchange capacity of 300,000 Btu per hour or less if there is no chemical additive to the system.

(m) Wastewater from a portable power washer when used in either of the following circumstances:

(i) By the occupant of a household for washing buildings, vehicles, or other surfaces associated with the domestic occupation of the household.

(ii) By a commercial operator or in a commercial or'industrial setting to remove nonpolluting substances from vehicles or surfaces when no additives are used and the washing process

/ does not add significant pollutants to the water.

(n) Swimming pool drainage and backwash water discharged in accordance with sections 12521 to 12534 of Act No. 368 of the Public Acts of 1978, as amended, being 333.12521 to 333.12534 of the Michigan Compiled Laws.

(o) Water treatment filter backwash water if disposal is in accordance with plans and specifications appi oved by tihed a eia under Act , 3`G the PubiLc Acts of iL7S, as....... an,,, .... , be;,g 325.1001 et seq. of the Michigan Compiled Laws, and known as the safe drinking water act.

6 EQP5305 (Rev 12/2004)

(p) Carpet cleaning wastewater discharged. by a:noncommercial operator or by a commercial operator at.

a site receiving wastewater from not more than one location where carpet cleaning has occurred.

(q) Less than 10,000 gallons per day of noncontact cooling water that does not contain additives if the source of the cooling water is any of the following:

(i) A municipal water supply.

(ii) A water supply meeting state or federal criteria for use as potable water.

(iii) Another source of water meeting the standards of Rule 2222.

(iv) Another source approved by the department.

(r) Land application of process sludge from a wastewater treatment facility treating sanitary sewage when applied in accordance with applicable state and federal law.

(s) Land application of process sludge from an industrial or commercial wastewater treatment facility when authorized under R 299.4101 to R 299.4922, the administrative Rules implementing Part 115.

(t) Placement of other solid waste on the ground when authorized under Part 115. This provision does not apply to the disposal of wastewater generated through the operation of a facility licensed under Part 115.

(u) Wastewater associated with an environmental response activity described in any of the following paragraphs if the discharge is to the plume of groundwater contamination, including an area 100 feet hydraulically upgradient of the edge of the plume, and any additive used in the treatment process that is not part of the contamination plume meets the standards of Rule 2222:

(i) A pump test discharge that does not change the physical dimensions of the plume in groundwater or, if the dimensions are changed, the changes are accounted for in the design of the final groundwater remediation plan.

(ii) A remedial investigation, feasibility study, or remedial action discharge that is at or below the residential criteria authorized by section 20101a(1)(a) of the act, if applicable, or section 21304(a) of the act, if applicable.

(iii) A discharge for a remedial investigation, feasibility study, or remedial action above the residential criteria authorized by section 20101 a(1)(a) of the act, if applicable, or section 21304(a) of the act, if applicable, if a remediation investigation, feasibility study, or remediation plan has been approved by the department division that has compliance oversight. The remediation plan must indicate that the treatment system is designed and will be operated so that contaminated groundwater will eventually meet the appropriate land use-based cleanup criteria authorized by section 20120a(1)(a) to (d) of the act, if applicable, or section 21304(a) of the act, if applicable.

(v) Precipitation and snow melt drainage off vehicles discharged through a general-purpose floor drain in a parking structure in which maintenance activities do not occur.

(w) A discharge that has been specifically authorized by the department under a permit if the permit was not issued under this part.

(x) A discharge that occurs as the result of placing waste materials on the ground in compliance with a designation of inertness issued under part 115 or leaving contaminated materials in place in compliance with part 201 or 213.

2. OTHER DISCHARGE SPECIFIC EXEMPTIONS.

Rule 2210 (y) allows discharges other than those listed above to be exempted from permitting on a case by case basis, if the department determines the discharge has an insignificant potential to be injurious based on volume and constituents..

To apply for an exemption according to Rule 2210(y), you should fill out pages 14-17 of the application, which contain general information about the facility. You should also provide the information required on Page 40 of the application. The department will notify you whether your application qualifies .for an exemption under Rule 2210(y), or whether you must apply for a different authorization. You are not authorized to discharge until you receive approval from the department.

7 EQP5305 (Rev 12/2004)

3. IF I DON'T QUALIFY FOR AN EXEMPTION, WHAT SORT OF AUTHORIZATION DO I NEED?

The following chart lists specific discharges for which you must submit an application prior to authorization.

The chart also contains the Rule that describes the authorization and the page numbers in the application that relate to that specific authorization. Please note that there are specific qualifications that must be met for each of the authorizations listed which are contained in the Part 22 rules.

Discharge Type Volume Limitation Rule Authorization Page #

Commercial Animal Care >50 gpd but <1,000 gpd 2211(h) Notification 19, 22 Contact Cooling Water < 5,000 gpd 2213(4) Notification w/Certification 23, 25 Egg Washing < 10,000 gpd 2213(3) Notification w/Certification 23, 24 Fruit & Vegetable Washing < 50,000 gpd 2211 (d) Notification 19, 20 Gravel, sand, limestone, dolomite mining 2215(4) General Permit 27, 30 Hydrostatic Pipe Testing, Flushing None 2211(g) Notification 19, 21 Laundromat < 500 gpd 221 (b) Notification 19, 20 Laundromat < 20,000 gpd 2216(4) Permit, specific discharge 32, 35 Non-contact Cooling Water, w/additives < 10,000 gpd 2213(2) Notification w/Certification 23, 24 Non-contact Cooling Water, no additives > 10,000 gpd 2211(c) Notification 19, 20 Oil Field Brine 2215(5) General Permit 27, 30 Portable Power Wash 1,000 gal/mo/acre 2211(e) Notification 19, 21 Sanitary Sewage 6,000-10,000 gpd 221 (a) Notification 19, 20 Sanitary Sewage, above ground treatment 1<10,000 gpd 2215(1) General Permit 27, 28 Sanitary Sewage, Construct Wetland < 20,000 gpd 2216(2) Permit, specific discharge 32, 33 Sanitary Sewage, Specific Treatment < 50,000 gpd 2216(3) Permit, specific discharge 32, 34 Slaughterhouse < 2,000 gpd 2215(3) General Permit. 27, 29 Groundwater Remediation:

Pump Test Outside Plume None 2211(f) Notification 19, 21 Remediation, Outside Plume None 2213(5) Notification w/Certification 23, 26 Vehicle Wash, not open to public < 2,000 gpd 2215(2) General Permit 27, 28 Vehicle Wash, open to the public < 3,000 gpd 2215(6) General Permit 27, 31 gpd = gallons per day gal/mo/acre = gallons per month per acre

= less than

= greater than

4. WHAT IF MY DISCHARGE TYPE DOES NOT APPEAR ON ANY OF THESE LISTS?

If your discharge does not appear on any of the previous lists, either as an exemption or a specific discharge permit, you must apply for a discharge authorization under, Rule 2218. The section of the application that must be filled out specific to Rule 2218 begins on Page 36.

C. Rule 2218

1. IF I HAVE TO APPLY FOR AN AUTHORIZATION UNDER RULE 2218, WHAT TYPE OF INFORMATION MUST I PROVIDE?

Facilities that are authorized under Rule 2218 must provide the following types of information as part of the application:

-a) An evaluation of the feasibility of alternatives to discharge to the groundwater in accordance with Rule 2219.

b) The basis of design as required by Rule 2218(2).

c) The hydrogeological report as required by Rule 2221.

d) The wastewater characterization as required by Rule 2220.

e) If a standard applicable to the discharge is to be determined under Rule 2222(5), the information necessary to determine that standard, including whether a substance is a hazardous substance under part 201.

f) The groundwater, or other media, sampling and analysis plan as specified by Rule 2223.

g) A description of the discharge methods and information that demonstrate that the land treatment requirements of Rule 2233 will be met.

h) If a lagoon is included in the treatment process, information that demonstrates that the requirements of Rule 2237 will be met.

8 EQP5305 (Rev 12/2004)

Technical guidance documents have been drafted for items c,d,e,g and h above; They are identified in Part I, Section. D.4.as additional reference-materials. Sections C.2, C.3 and C.4 of these instructions.provide-gLidance.

for the other information requirements of Rule 221.8.

You are also responsible for meeting the groundwater quality standards contained in Rule 2222. You must meet the standards either in the discharge, or in the groundwater if treatment that takes place after discharging the wastewater to the ground. The standards themselves are complex, and it is strongly recommended that you schedule a pre-application meeting to discuss them with program staff. The process for requesting a meeting is found on Page 12, Section D.1 of these instructions. If you wish to investigate the standards on your own, the Part 22 Rules, including Rule 2222, are available on the Internet at the following location, http:/lwww.deq.state.mi.uslwmdlGWPlindex.html. You may also contact staff at the address or phone number found on Page 13 of these instructions for printed copies of the rules.

2. RULE 2219 - EVALUATION OF FEASIBILITY OF ALTERNATIVES TO DISCHARGE TO GROUNDWATER Prior to applying for a Rule 2218 authorization, you must conduct an evaluation of the feasibility of alternatives to discharging to the groundwater and submit that as part of the application. The analysis should contain, at a minimum, the items listed below. Feasibility includes the practical ability to implement the alternative and a

-comparison of the cost of the alternative to its benefits.

At a minimum, alternatives to the discharge that must be considered are:

(a) minimizing the volume and toxicity of the wastewater:

(b) recycling wastewater.

(c) connecting to a municipal sanitary sewer system.

(d) discharging to surface water.

Alternatives for minimizing the volume and toxicity of wastewater include pollution prevention opportunities, including the following:

(a) Equipment or technology modifications.

(b) Process or procedure modifications.

(c) Reformulation or redesign of products.

(d) Substitution of raw materials.

(e) Improvements in -housekeeping, maintenance, training, or inventory control.

The following treatment systems must be considered for substances determined to be in the discharge by the characterization required by Rule 2220:

(a) For a metal, the following:

(i) Flocculation.

(ii) Settling.

(iii) Oxidation.

(iv) Filtration.

(v) Ion exchange (vi) Reverse osmosis.

(vii) Electrolytic recovery.

(b) For a volatile substance, the following:

(i) Carbon adsorption.

(ii) Air stripping.

(iii) Aeration.

(c) For a nonvolatile substance, the following:

(i) Sorption.

(ii) Settling.

(iii) Filtration.

For a substance that degrades biologically, biological treatment in a lagoon, tank, or biological reactor or through controlled land treatment; 9 EQP5305 (Rev 12/2004)

3. RULE 2218(2), BASIS OF DESIGN At the time of application, you must submit a basis of design for the treatment system. The basis of design should include all of the following information: .tme...s.st.m. The.basis.of.design (a) The volume of wastewater to be treated per unit of time.

(b) An analysis of the.:influent, or a description of the anticipated influent, including the substances to be treated to meet the requirements of Rule 2222 and the concentrations of the substances.

(c) A description of the existing or proposed treatment, or both, including, where applicable, the'following:

(i) The treatment methods before discharge.

(ii) To the extent applicable, engineering plans depicting all of the following:

(A) A schematic flow diagram.

(B) Information on unit processes.

(C) Flow rates.

(D) Design hydraulic capacity.

(E) Pollutant loading.

(F) Detention times.

(G) Sizing of treatment units.

(H) Design calculations for major treatment units.

(I) A description of sludge management.

(iii) A discharge management plan that includes, where applicable, all of the following, information:

(A) Maximum daily and annual discharge volumes.

(B) The total discharge area.

(C) Scheduled maintenance.

(D) Vegetative cover control and removal.

(E) Load and rest cycles.

(F) Application rates.

(G) Means for even distribution of waste or wastewater.

(H) Strategies for periods of adverse weather.

(I) Monitoring procedures.

(J) Other pertinent information.

(d) For a discharge of sanitary sewage, unless the Rules provide otherwise, the treatment system must be consistent with the standards in chapter 10 of the publication entitled "Engineering Reports and Facility Plahs of the Recommended Standards for Wastewater Facilities" 1997 edition. The standards in chapter 10 are adopted by reference in the Rules. The standards may be purchased from Health Education Services, P.O. Box 7126, Albany, New York 12224, or from the Michigan Department of Environmental Quality, Water Division, P.O. Box 30630, Lansing, Michigan 48909, at a cost at the time of adoption of these Rules of $12.00, plus shipping and handling.

4. RULE 2223 - DISCHARGE MONITORING.

You are required to monitor your discharge in a manner, at a frequency, and for a substance(s) the department specifies are necessary to assess compliance with these Rules. The components of a monitoring program are:

(1) Monitoring of an indicator parameter may be used in monitoring ifthe technique accurately reflects the effect of the discharge. An indicator parameter must be representative of the environmental fate of a substance or substances in the discharge and must be one of the following:

(a) A substance in the discharge.

(b) A decomposition material of a substance.

(c) A sampling parameter that can be directly correlated to the concentration of another substance in I the discharge.

(2) Groundwater monitoring must include the.collection of water quality and water level, data from a well or group of wells that are specifically designed to adequately assess the impact of the discharge on groundwater. The design of the groundwater monitoring system must be based on all of the following:

(a) The hydrogeologic report.

(b) Considerations of the local geology.

(c) Groundwater conditions specific to each site.

(a) fne type of discharge.

1,0 EQP5305 (Rev 12/2004)

(3) At the time of application for a permit under Rule 2218, anapplicant must propose, for department...........

approval, a groundwater sampling and analysis plan that establishes criteria for collecting representative samples of groundwater. The plan must contain all of the following information:

(a) The number and location of wells to be included in the groundwater monitoring system.

(b) For each well, the depth and screened interval for each monitor well. The screened interval must be referenced to United States geological survey data.

(c) Well construction materials and installation techniques.

(d) Sampling frequency.

(e) A list of substances to be sampled.

(f) Sampling procedure, including all of the following:

(i) The method and~volume of water removed from each well during sampling.

(ii) Steps taken to prevent cross contamination between wells.

(iii) Sample handling and preservation methods.

(iv) Laboratory analysis method.

(v) Laboratory method detection level.

(vi) Quality assurance and quality control program.

(g) A description of the techniques used to present and evaluate groundwater quality monitoring data.

(h) A description of the method used to collect static water levels and.present groundwater flow data.

Static water level precision must be to 0.01 foot.

(4) A discharger must design, construct, and abandon a monitoring well as follows:

(a) A monitoring well must be located at a depth where the screened interval will intercept the path of any discharge from the site in the groundwater.

(b) If the thickness of the aquifer receiving the discharge is more than 20 feet, then at least one hydraulically downgradient monitor well location must contain a cluster well. The separation and length of the screens must be such that discrete groundwater potentiometric surface data can be collected to determine vertical gradients within the aquifer.

(c) Monitor well construction and sampling equipment materials must not influence the sampling results for the substances sampled.

(d) A monitor well must be designed to collect an adequate volume of water to allow analysis for the complete set of substances indicative of the discharge.

(e) Annular space between the borehole and the well must be grouted from the ground surface to two feet above the well screen to prevent vertical leakage of the fluids between the casing and the drill hole. When drilling through confining layers, a discharger must install double-cased wells to prevent the hydraulic connection of fluids between formations above and below the confining layer.

(f) A well must be protected against the introduction of contaminants by means of a locking device or by another method approved by the department.

(g) A well must be vented so that accurate static water levels may be collected, or well caps must be removed a sufficient amount of time before measurement so that representative static water levels can be measured. Care must be taken to prevent the introductionof contaminants through vents.

(h) The well casing must be adequately marked and protected against accidental damage.

(i) A well must be labeled so that the discharger s name, address and the well number can be determined through the life of the permit.

(j) If a monitoring well is to be permanently abandoned, a discharger must follow the plugging procedures in part 127 of Act No. 368 of the Public Acts of 1978, as amended, being 323.12701 to 323.12715 of the Michigan Compiled Laws..

(k) A discharger must receive department approval before installing, replacing, redeveloping, or abandoning a monitoring well that is part of the discharge-monitoring program.

(5) If necessary to measure compliance with a standard established under Rule 2222, the department may specify the monitoring of media in addition to groundwater.

(6) A monitoring program under this Rule must be evaluated by the department on the basis of the threat the discharge poses to protected uses given all of the following factors:

(a) The substances in the discharge.

(b) The volume of the discharge.

(c) The amount of information related to predicting the impacts of a discharge developed through the hydrogeological report prepared under Rule 2221.

11 EQP5305 (Rev 12/2004)

D. APPLICATION PROCESS At this point, you should be awareO.f the typ.q.of authorization that you willneed from the department.. This section describes the process of filing an application form with the department, formally requesting the authorization.

1. WHEN DO I HAVE TO APPLY?

For new discharges or significant changes to an existing discharge, you must submit the application at least 180 days in advance of the proposed date of discharge or significant change (Rule 2106). Permits are generally issued for five years, at which time an updated application must be submitted. For reissuance of an existing permit, you must submit the completed application form and the necessary.attachments 180 days prior to the expiration date of your current permit (Rule 2151 (1)).

It is strongly recommended, especially prior to submitting an initial application or an application for a Rule 2218 authorization, that you request a pre-application meeting with staff of the Groundwater Section, Water Division.

Technical staff will be available to discuss the proposed discharge, and can answer questions and provide information to you regarding such items as treatment alternatives, hydrogeologic studies, waste characterization, etc. It is recommended that you and/or your consultant be prepared to describe, at least in general terms, the basis of design for the proposed or existing wastewater treatment and disposal facilities.

To arrange a pre-application meeting, please contact:

Groundwater Permits Unit Chief Permits Section Water Bureau PO Box 30273 Lansing, MI 48909 Telephone: 517-373-8148 Fax: 517-241-8133

2. HOW IS THE FORM ORGANIZED?

The application form is divided into two sections.Section I, pages 14-17, consists of general information that must. be filled out by all applicants. (Occasionally, especially for general permits, not every item in Section I will be required, so please only fill out the applicable portions. For example, if you are applying for a General Permit under Rule 2215 for brine spreading, you would not fill out Item 7 which requests a CMR address).

Section II contains information that must be filled out for specific discharges. An index appears after the general information section of the application, Page 18, which lists all of the specific discharges, Rules 2213 through 2216, and other discharges, covered under Rule 2218, and directs you to the appropriate pages for each particular discharge. Many of the discharges require supporting documentation of one kind or another.

There are guidesheets available, listed on Page 13 as available reference materials, which provide guidance on how to gather and report the information in a manner that is acceptable to the Department. This does not preclude you from.using alternative methods. It only means that if the guidance is followed very carefully, the methodology for collecting and reporting the information will be acceptable.

3. WHO MUST SIGN THE FORM?

The Part 21 Rules, have very specific requirements for who mustsign an application form. For a corporation, the form must be signed by a principal executive officer of at least the level of vice president, or his/her designated representative, if the representative is responsible for the overall operation of the facility from which the discharge described in the permit application (appropriate documentation must be provided to demonstrate the position and responsibility of the designated representative). For a partnership, the form must be signed by a general partner, for a sole proprietorship, by the proprietor. For municipal, state or other public facility, the form must be singed by either a principal executive officer, the mayor, village president, city or village manager or other duly authorized employee. All signatures submitted to the department must be original signatures, or the application will be returned to you. The details of these requirements are found in Rule 2114.

12 EQP5305 (Rev 12/2004)

4. WHAT ADDITIONAL REFERENCE MATERIALS ARE AVAILABLE?

The following are a list of the acts, rules, forms and other items that can be obtained from the Groundwater Program Section to assist an applicant in filling out an application form and providing information necessary to obtain a groundwater.discharge permit or permit exemption:

1. Part 31 Water Resources Protection of Act 451

2. Part 41 Sewerage Systems of Act 451

3. Part 21 Wastewater Discharge Permits - Rules of Part 31 of Act 451

4. Part 22 Groundwater Quality - Rules of Part 31 of Act 451

5. Communities Participating in the Michigan Wellhead Protection Plan

6. Guidesheet I Guidance document for hydrogeologic studies

7. Guidesheet 11 Guidance document for irrigation management plans

8. Guidesheet III Guidance document for waste characterization

9. Guidesheet IV Guidance document for wastewater treatment and storage lagoons

10. Guidesheet V Guidance document for development of toxicology information

11. Guidesheet V1 Guidance document for the Operation and Maintenance Manual Requests for any of the above items should be made to:

Permits Section Groundwater Permits Unit Water Bureau Michigan Department of Environmental Quality P. 0. Box 30273 Lansing, Michigan 48909 Telephone: 517-373-8148 FAX: 517-241-8133 There is a charge of 5 cents per page to cover handling costs.

This information is also available electronically on the Internet at the following address:

http://www.michigani.gov/deq/0,1607,7-135-3313_4117---,00.html

5. WHAT IF I HAVE QUESTIONS?

Ifyou have questions about the form or process, please call or fax your questions to the following numbers:

Telephone: 517-373-8148 FAX.: 517-241-8133

6. WHERE SHOULD I SEND THE COMPLETED FORM?

Please provide two copies, including the signed original, of the application form and all pertinent attachments, to the following address:

Permits Section Groundwater Permits Unit Water Bureau Michigan Department of Environmental Quality P. 0. Box 30273 Lansing, Michigan 48909

7. DO THE RULES SPECIFY OPERATIONAL REQUIREMENTS?

Appendix B, Pages 45-46, provides an outline of the operational requirements that are mandated by the Part 22 Rules for each particular authorization. Please refer to the specific rule for detailed requirements.

8. PENALTIES It is against the law to knowingly discharge wastewater into the groundwater without a permit or in violation of an existing permit. It is also against the law to intentionally make false statements in a permit application. A person who commits these offenses is guilty of a felony and substantial fines, and perhaps imprisonment, are the consequences. Section 3115(2) of Act 451 contains the details of the penalties associated with violating Part 31.

The Michigan Department of Environmental Quality (MDEQ).will not discriminate against Any individual or group on the basis of race, sex, religion, age, national origin, color, marital status, disability, or political beliefs. Questions or concerns shouldbe directed to the Office of Personnel Services, PO Box 30473, Lansing, MI 48909 13 EQP5305 (Rev 12/2004)

GroundwaterDischargePermitApplication REFERENCES IN THIS DOCUMENT TO "RULES" ARE TO ADMINISTRATIVE RULES IMPLEMENTING PART 31 OF THE NATURAL RESOURCES AND ENVIRONMENTAL PROTECTION ACT, 1994 PA 451, AS AMENDED, BEING R 323.2101 TO 2192 AND R 323.2201 TO 2240.

GENERAL INFORMATION Please type or print clearly

1. DISCHARGE FACILITY NAME

2. FACILITY OWNER NAME AND MAILING ADDRESS Name Street Address or P.O. Box City, State and Zip Code Telephone No. Draft permits authorized pursuant to Rule 2210(y) and 2218 will be sent Fax No. electronically to owner. Owner Email:

3. CONTACT PERSON Name and Title Street Address or P.O. Box City, State and Zip Code Telephone No. Fax No.

4. DISCHARGE LOCATION Street Address City State Zip Code County Township Township Range Section Number First Quarter Section Second Quarter Section Additional Quarter Sections Latitude Longitude

5. FACILITY TYPE Municipal (Sanitary Only) Municipal (w/ Sanitary and Industrial Wastewater Inputs)

Industrial Commercial If Municipal, population served

6. CERTIFIED OPERATOR (NOT REQUIRED FOR 2211(c), (d), (e), (g), (h), or 2213 (2), (3), (4))

A Certified Operator is required by Section 3110 (1) of Part 31 of Act 451.

Name Certification Number City State Zip Code Telephone No.

14 EQP5305 (Rev 12/2004)

7. FOR RULE 2215, 2216 AND 2218 AUTHORIZATIONS ONLY:- .

PLEASE INDICATE WHERE THE COMPLIANCE MONITORING REPORT FORMS SHOULD BE SENT NAME STREET ADDRESS CITY STATE ZIP CODE

8. AUTHORIZATION REQUESTED:

Rule 2210(y), Site Specific Exemption NEW USE REISSUANCE Rule 2211, Notification NEW USE REISSUANCE Rule 2213, Notification with Certification NEW USE REISSUANCE Rule 2215, General Permit, Certificate of Coverage NEW USE REISSUANCE

_ Rule 2216, Specific Discharges NEW USE REISSUANCE Rule 2218, Discharge Permit NEW USE REISSUANCE IF REQUESTING A REISSUANCE OR AN AUTHORIZATION DIFFERENT THAN THE CURRENT AUTHORIZATION, PLEASE INCLUDE THE PERMIT/EXEMPTION NUMBER OF THE CURRENT AUTHORIZATION:

If the current authorization is a permit, Rules 2216 or 2218, or was issued prior to August 26, 1999, the number is: M If the current authorization is a General Permit, Rule 2215, the number is: MG If the current authorization is a site specific exemption, Rule 2 2 10 (y), or was issued prior to August 26, 1999, the number is:' GWE-_ _

tf the current authorization is a notification,, Rule 221 1,the number is:. GWN-If the current authorization is a notification/certification, Rule 2213, the number is: GWC-

9. FACILITY STANDARD INDUSTRIAL CLASSIFICATION (SIC) CODE.

This information is available through the US Department of Labor, Office of Safety and Heath Administration, at the following web address: www.osha.gov/oshstats/sicser.html

10. SITE MAPS Provide two black and white 8 1/2" X 11" maps drawn to scale that show the following:

SITE MAP 1 a) Discharge location in relation to property boundaries on a topographic map.

b) Township and county name.

c) North arrow orientation.

SITE MAP 2- All sites must include item a, include items b-e as necessary.

a. Current and proposed treatment units and discharge areas and distance to property lines.

b. Monitoring wells on site and on adjacent properties.

c. Potable wells on site and on adjacent properties.

d. Surface waters, including wetlands, lakes, rivers, streams, and drains on the property.

e. Distance between multiple disposal sites.

ATTACH SITE MAP TO THIS APPLICATION FORM 15 EQP5305 (Rev 12/2004)

11. WATER USAGE DIAGRAM Please attach an 8 % x 11 diagram shdwing V&aaife§age at the facility, from supply to discharge. Include all flows such as sanitary, process water, etc. Please also indicate where in the system additives or other substances are added to the waste stream for which this authorization is being sought. The water balance should show daily average flow rates at influent, intake and discharge points and daily flow rates between treatment units. Please use actual measurements whenever possible.

12. OWNERSHIP OF TREATMENT SYSTEM AND DISPOSAL AREA Are all parts of the treatment system and discharge areas ( e.g. treatment plant, underground piping or irrigation fields) located on property owned by the applicant? Yes No IF NO, ATTACH THEJNAME AND ADDRESS OF THE PROPERTY OWNER WHERE THE DISCHARGE WILL OCCUR, AND A COPY OF THE WRITTEN PERMISSION TO DISCHARGE ON PROPERTY NOT OWNED BY THE DISCHARGER.

13. PROXIMITY OF TREATMENT SYSTEM TO A KNOWN SOURCE OF GROUNDWATER CONTAMINATION Are there any known groundwater contamination sites within 1/4 mile of your disposal site?

Yes No Unknown IF YES, ATTACH TO THE APPLICATION FORM A DESCRIPTION OF THE LOCATION AND CONTAMINANTS BEING REMEDIATED AT THE SITE.

14. ISOLATION DISTANCE The following are isolation distances required from the discharge to adjacentwater supply wells. What is the distance from your discharge to the nearest water supply well?

WELL TYPE PERMIT AUTHORIZATION: 2218,2216(3) ALL OTHER AUTHORIZATIONS I, Ila 2000 200 lib, III 800 75 Domestic 300 50 Distance to nearest Type I, Ila water supply well Distance to nearest Type lib, III water supply well Distance to nearest Domestic water supply well

15. ADJACENT PROPERTY OWNERS List the names and addresses of all property owners adjacent to the facility, treatment systems and discharge locations. Include properties across roadways.

ATTACH ANY ADDITIONAL NAMES AND ADDRESSES TO THE APPLICATION FORM.

NAME COMPLETE MAILING ADDRESS

16. WELLHEAD PROTECTION Is your facility located in a designated wellhead protection area? Yes __ No __

If yes, please identify the community*

• Approved wellhead protection areas can be reviewed at the following web address:

http:/lwww.michigan.govldeqlO,1607,7-135-3313_3675_3695-59280--,00.html

17. SIGNATORY REQUIREMENT Pursuant to Rule 2114 of the Part 21 Rules, this application must have an original signature, and be signed by 1.6 EQP5305 (Rev 12/2004)

the appropriate representative(s) as follows:

A. For a corporation, the form must be signed by a principal executive officer of at least the level of Vice-president, or his/her designated representative, if the representative is responsible for the overall operation of the facility from which the discharge described in the permit application (appropriate documentation. must be provided to demonstrate the position and responsibility of the designated representative).

B. For a partnership, the form must be signed by a general partner.

C. For a sole proprietorship, the form must be signed by the proprietor.

D. For municipal, state or other public facility, the form must be signed by either a principal executive officer, the mayor, village president, city or village manager or other duly authorized employee.

All signatures submitted to the department must be original signatures, or the application will be returned as incomplete. The details of these requirements are found in Rule 2114.

The department reserves the right to request information in addition to that supplied with this application if necessary to verify statements made by the applicant or for the department to make a determination required by Part 31, Water Resources Protection, Natural Resources and Environmental Protection Act, 1994 PA 451, as amended (Act 451) and/or the Part 22 Rules associated with Part 31.

I certify, under penalty of law, that I have personally examined and am familiar with the information submitted in this document and all attachments. The information being submitted was collected and analyzed in accordance with the Part 22 Rules of Part 31 of Act 451, as amended. Based on my inquiry of those individuals immediately responsible for obtaining the information, I believe that the information is true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fine and imprisonment.

Print Name Title Representing Signature Date 17 EQP5305 (Rev 12/2004)

THE FOLLOWING INDEX SHOWS WHERE EACH OF THE DISCHARGE SPECIFIC PAGES ARE LOCATED.

PLEASEFILL OUT THE APPROPRIATE PAGES FOR THE SPECIFIC DISCHARGE PROPOSED-Aii-A TTACH ALL SUPPORTING DOCUMENTATION.

PERMIT INDEX, AUTHORIZATION SPECIFIC INFORMATION RULE 2211 AUTHORIZATION: RULE SPECIFIC WASTEWATER TYPE DAILY MAXIMUM DISCHARGE, GALLONS PAGES TO BE FILLED OUT (a) Sanitary Sewage 6,000 - 10,000 19, 20 (b) Laundromat < 500 19, 20, (c) Non-contact Cooling Water >10, 000 19, 20 (d) Fruit & Vegetable Washwater < 50,000 19,20 (e) Portable Power Washer 19, 21 (f) Pump test Water 19, 21 (g) Hydrostatic Test Water 19, 21 (h) Commercial Animal Care 50 - 1,000 19,22 RULE 2213 AUTHORIZATION:

WASTEWATER TYPE (2) Non-contact cooling water, < 10,000 23, 24 with additives (3)Egg washing wastewater < 10,000 23, 24 (4) Cooling water < 5,000 23, 25 (5) Groundwater remediation, 23,26 outside plume RULE 2215 AUTHORIZATION WASTEWATER TYPE 00-1 Sanitary Sewage, above ground < 10,000 27, 28 00-2 Vehicle wash, not open to public < 2,000 27, 28 01-3 Slaughterhouse < 2,000 -27 29 00-4 Gravel, sand, limestone, dolomite mining .27, 30 00-5 Oil Field Brine 27, 30 01-6 Vehicle wash, open to the public <3,000 27, 31 RULE 2216 AUTHORIZATION: **

WASTEWATER TYPE (2) Sanitary Sewage, < 20,000 32, 33' Constructed Wetland (3) Sanitary Sewage, < 50,000 32, 34 1

Specific 2216 Design (4) Laundromat wastewater < 20,000 32, 35 RULE 2218 AUTHORIZATION, WHICH COVERS DISCHARGES NOT OTHERWISE LISTED New Permits 36, 37 Reissuance Permit, No Modifications 36, 38 Reissuance Permits, With Significant Modifications 36, 39 RULE 2 210(y) AUTHORIZATION, SITE SPECIFIC EXEMPTION 40

> = GREATER THAN

< = LESS THAN

• • RULE 2216 LISTS SPECIFIC DESIGN CRITERIA THAT MUST BE MET TO IN ORDER TO QUALIFY FOR THAT AUTHORIZATION. DISCHARGERS THAT MEET THE FLOW AND WASTEWATER CRITERIA, BUT DO NOT MEET THE DESIGN CRITERIA, MUST EITHER DEMONSTRATE EQUIVALENCY WITH THE RULE 2216 CRITERIA, OR APPLY FOR A PERMIT UNDER RULE 2218.

18 EQP5305 (Rev 12/2004)

PERMIT BY RULE; NOTIFICAT!ON RULE 2211 A facility is authorized to discharge at the time a complete application is received by the department. The permittee will receive an acknowledgement letter from the department, indicating that the application was considered complete or is deficient, in which case the discharge would not be authorized.

1. RULE 2211 AUTHORIZATION REQUESTED:

Wastewater Type Daily Maximum Discharqe, Gallons, (a) Sanitary Sewage 6,000 - 10,000 (b) Laundromat < 500 (c) Non-contact Cooling Water, w/o additives >10, 000 (d) Fruit & Vegetable Washwater <50,000 (e) Portable Power Washer (f) Pump Test Water (g) Hydrostatic Test Water (h) Commercial Animal Care 50 - 1,000

2. DISCHARGE VOLUME ALL DISCHARGES:

Maximum daily discharge: gallons per day Cumulative annual discharge: gallons per year SEASONAL DISCHARGES SHOULD INCLUDE THE FOLLOWING:

Discharge period through .

3. DISCHARGE METHOD Please check the discharge method used:

LAND SURFACE DISPOSAL. DISPOSAL CODE SUBSURFACE DISPOSAL DISPOSAL CODE

_ Spray Irrigation Alfl Tile Field Algl Ridge and Furrow Alf2 ___Injection well Alg2 Flood/Sheet Irrigation Alf3 Trench Al g3

__ Drywell Al g4' Seepage Beds:

Slow/Medium Rate Alf4

_ Rapid Rate Alf5 Other - Please describe:

19 EQP5305 (Rev 12/2004)

a. .a-pl*t6 Sanitarythis Sewage, specificRule 2211(a),

disclharj  :.. 6,000-10,000

. . per ..day. Please check all system characteristics that gallons Discharge is between 6,000 and 10,000 gallons per day.

Sanitary sewage is not mixed with other.waste.

• System is, or is to be, designed in accordance with "Michigan Criteria for Subsurface Sewage Disposal."

The system has been approved by the county, district or city health department having jurisdiction.

If the facility was constructed or expanded after August 26, 1999, the flow is monitored by a meter.

b. Laundromat.Wastewater, Rule 2211(b), less than 500 gallons per day. Please check all system characteristics that apply to this specific discharge:

Discharge is less than 500 gallons per day.'

The treatment system consists of at least two 1,000 gallon septic tanks, followed by disposal to.a tile field.

_There is an operational lint filter on the wastewater discharge line.

The tile field is designed and constructed in accordance with "Michigan Criteria for Subsurface Sewage.

Disposal."

The sanitary sewage is routed to the same septic tank or tanks as the laundry wastewater.

c. Non-contact cooling water, Rule 2211(c), more than 10,000 gallons per day, no additives. Please check all system characteristics that apply to this specific discharge:

The discharge is greater than 10,000 gallons per day.

The non-contact cooling water contains no additives.

Please check which one of the following applies:

The source water is from a municipal supply.

The water source meets state or federal criteria for use as potable water.

The water source meets the standards of Rule 2222.

The water source is an alternative to the above... Department approval is required, and supporting documentation is attached.

d. Fruit & Vegetable washwater, Rule 2211(d), less than 50,000 gallons per day. Please check all system characteristics that apply to this specific discharge:

The discharge is less than 50,000 gallons per day:

There are no additives in the discharge.

There are additives in the discharge which will not cause the groundwater to exceed the standards of Rule 2222.

Please check which one of the following applies:

The source water is from a municipal supply.

The water source meets state or federal criteria for use as potable ,water.

The water source meets the standards of Rule 323.2222.

The water source is an alternative to the above. Department approval is'required, and supporting documentation is attached.

Please list all additives in the discharge, and the concentration of the additive in the effluent. The concentration can be submitted as an analysis of the wastewater, or as a mass 'balance calculation. Wastewater characterization, including the use of mass balance calculations, should follow the guidance found in Guidesheet II.

ADDITIVE ANNUAL USE RATE CONCENTRATION (Indicate how determined, A for analysis, Mfor mass balance. Please remember to include units of measurement.)

e. Portable Power Washer, Rule 2211(e). Please check all system characteristics that apply to this specific discharge:

Only household soap or detergent readily available to consumers are used for cleaning.

20 EQP5305 (Rev 12/2.004)

Additives other than soap and detergent are used only for their intended purpose and according to manufacturers directior ......

A log of all locations where discharges occur will be maintained after receiving authorization to discharge, including date, address, additive(s) used, and item(s) washed.

Washing will be limited to removal of dirt and grime from the exterior of a vehicle, equipment, or a stationary source. It will not include the undercarriage of a vehicle, or the portion of a vehicle used to contained or transported substances as a product.

Discharge will be limited to less than 1000 gallons of washwater per month per acre where discharge occurs.

Please check which one of the following applies:

The source water is from a municipal supply.

The water source meets state or federal criteria for use as potable water.

The water source meets the standards of Rule 323.2222.

The water source is an alternative to the above. Department approval is required, and supporting documentation is attached.

f. Pump test water associated with environmental remediation, Rule 2211(f), discharge outside plume.

Please check all system characteristics that apply for this specific discharge:

Discharge meets the standards of Rule 2222.

TREATMENT CODES Select and enter the appropriate treatment codes to describe treatment units, i.e., Alb, B2b (See APPENDIX A, Pages 41-44).

Treatment Unit A Treatment Unit B Treatment Unit C Treatment Unit D TREATMENT SYSTEM Please describe how the current treatment system is/will meet the standards of Rule 2222 and the number of years it has been in operation.

g. Hydrostatic testing or flushing water, Rule 2211(g). Please check all system characteristics that apply to this specific discharge:

There are no additives in the discharge.

The testing is for new pipelines or tanks.

Please check which one of the following applies:

The source water is from a municipal supply.

The water source meets state or federal criteria for use as potable water.

The water source meets the standards of Rule 2222.

The water source is an alternative to the above. Department approval is required, and supporting documentation is attached.

21 EQP5305 (Rev 12/2004)

h. Commercial animal care, Rule 2211(h), between 50 and 1000 gallons per day. Please check all system characteiristics that apply*to this specific discharge:

The discharge is between 50 and 1,000 gallons per day.

There are no additives in the discharge.

There are additives in the discharge which will not cause the groundwater to exceed the standards of Rule 2222.

The distance to the nearest surface water body is greater than 200 feet.

Please check which one of the following applies:

The source water is from a municipal supply.

The water source meets state or federal criteria for use as potable water.

The water source meets the standards of Rule 323.2222.

The water source is an alternative to the above. Department approval is required, and supporting documentation is attached.

Please list the name of all products used at the facility, and list all of the active ingredients for each of those products:

PRODUCT NAME MANUFACTURER'S NAME ACTIVE INGREDIENTS 22 EQP5305 (Rev 12/2004)

.PERMITBY RULE,. NOTIFICATION WITH DEPART.MENT C*FRT.FICATION RULE 2213 A facility is authorized to discharge when it receives a certification from the department that verifies the discharge is authorized under this part. Within 60 calendar days of receiving a complete notification form required by this Rule, the department will issue a certification or indicate why the discharger is not authorized to discharge under this Rule.

1. RULE 2213 AUTHORIZATION REQUESTED:

Wastewater Type Daily Maximum Discharge, Gallons

_ (2) Non-contact cooling water, with additives < 10,000 (3) Egg washing wastewater < 10,000

.(4) Cooling water < 5,000 (5) Groundwater remediation, outside plume

2. DISCHARGE VOLUME ALL DISCHARGES:

Maximum daily discharge: gallons per day Cumulative annual discharge: gallons peryear SEASONAL DISCHARGES SHOULD INCLUDE THE FOLLOWING:

Discharge period through IRRIGATION SYSTEMS AND SEEPAGE BEDS UTILIZING SOILS FOR TREATMENT SHOULD INLCUDE THE FOLLOWING:

Effluent application rate:

Inches per hour__ Inches per day__ Inches per week__ Inches per year__

3. DISCHARGE METHOD Please check the discharge method used:

LAND SURFACE DISPOSAL DISPOSAL CODE SUBSURFACE DISPOSAL DISPOSAL CODE

_ Spray Irrigation Alfl Tile Field Algl

_ Ridge and Furrow Alf2 Injection well Alg2 Flood/Sheet Irrigation Alf3 Trench Alg3

__ Drywell Alg4 Seepage Beds:

Slow/Medium Rate Alf4

_ Rapid Rate Alf5 Other - Please describe:

23 EQP5305 (Rev 12/2004)

2. Non-contact cooling water With add[itives, Rule 2213(2), < 10,000 gallons per day. Please check all system characteristics that apply to this specific discharge:

The discharge is less than 10,000 gallons per day The additive(s) will not cause groundwater to exceed the standards of Rule 323.2222.

Please list the name and concentration of all additives in the discharge. The concentration can be submitted as an analysis of the wastewater, or as a mass balance calculation. Wastewater characterization, including the use of mass balance calculations, should follow the guidance found in Guidesheet Ill.

ADDITIVE ANNUAL USE RATE CONCENTRATION (Indicate how determined, A for analysis, M for mass balance. Please remember to include units of measurement)

3. Egg Washing wastewater, Rule 2213(3), less than 10,000 gallons per day. Please check'all system characteristics that apply to this specific discharge:

The discharge is less than 10,000 gallons per day.

The additive(s) will not cause groundwater to exceed the standards of Rule 323.2222. For each additive, please fill out the additive information listed below.

Please check which one of the following applies:

The source water is from a municipal supply.

The water source meets state or federal criteria for use as potable water.

The water source meets the standards of Rule 323.2222.

The water source is an alternative to the above, approved by the Department.

Please list the name and concentration of all additives in the discharge. The concentration can be submitted as an analysis of the wastewater, or as a mass balance calculation. Wastewater characterization, inclliding the use of mass balance calculations, should follow the guidance found in Guidesheet III.

ADDITIVE ANNUAL USE RATE CONCENTRATION (Indicate how determined, A for analysis, M for mass balance. Please remember to include units of measurement) 24 EQP5305 (Rev 12/2004)

4. Cooling water, Rule 2213(4), <5,000 gallons per day. Please check all system characteristics that apply to this specific discharge:

The discharge is less than 5,000 gallons per day.

The discharge contains no additives.

The discharge contains an additive, and itwill not cause the groundwater to exceed the standards contained in Rule 2222.

Wastewater has been characterized according to Rule 2220 and is listed below. Wastewater characterization, including the use of mass balance calculations, should follow the guidance found in Guidesheet Ill.

If seeking a renewal of a previous authorization, the wastewater has been characterized annually and records are attached.

If seeking a renewal of a previous authorization, the material cooled does not vary substantially from that used in seeking the original authorization.

Please list all additives in the discharge, and the concentration of the additive in the effluent. The concentration can be submitted as an analysis of the wastewaterý, or as a mass balance calculation. Wastewater characterization, including the use of mass balance calculations, should follow the guidance found in Guidesheet Ill.

NOTE: The discharger must characterize the wastewater annually, and submit the records of the annual characterization at the time of reissuance.

ADDITIVE ANNUAL USE RATE CONCENTRATION (Indicate how determined, A for analysis, M for mass balance. Please remember to include units of measurement)

5. Groundwater remediation activities, clean up, discharge outside the plume, 2213(5). Please check all system characteristics that apply to this specific discharge:

The remedial action includes a groundwater extraction system designed and operated to prevent any portion of the plume above approved cleanup criteria from migrating beyond the zone of influence approved by the department division that has compliance oversight. The division having compliance oversight is:

Remediation and Redevelopment Division Geological and Land Management Division Waste and Hazardous Materials Division Water Division Other, please identify A memorandum from the chief, or his/her designated representative, of the department division responsible for compliance oversight of the remediation is included which certifies that the discharge meets the requirements of part 31, 111, 115, 201, 213, or 615, as applicable.

A performance-monitoring plan was included in the remediation plan submitted to the department division responsible for compliance oversight. The plan included the following:

Groundwater monitoring wells have been installed within 150 feet of the discharge to verify that the standards of Rule 2222 are being met in groundwater.

Effluent and groundwater sampling to verify compliance with Rule 2213(5)(f).

25 EQP5305 (Rev 12/2004)

The frequency of sampling meets the requirements of Rule 2213(5)(e)(ii).

Site map 1, required in Rule 2212(3)(m), should include the location of drinking water wells adequate to .

identify each water supply formation within 1/2 mile of the discharge. A copy of the well logs for each drinking water well identified on the map should be included.

Site map 2, required in Rule 2212(3)(m) should include all of the following information:

Groundwater flow direction.

Extent of contamination plume.

Calculated capture zone.

Location of the groundwater extraction and interception system.

Location of all observation and monitoring wells.

TREATMENT CODES Select and enter the appropriate treatment codes to describe treatment units, i.e., Al b, B2b (see APPENDIX A, Pages 41-44)'

Treatment Unit A Treatment Unit B Treatment Unit C Treatment Unit D Please provide a description of the treatment system indicating how it will-produce an effluent that will meet the standards of Rule 2222.

26 EQP5305 (Rev 12/2004)

GENERAL PERMIT RULE 2215 A facility is not authorized to discharge until it receives a Certificate of Coverage from the department that verifies the discharge is authorized under this part.

1. RULE 2215 AUTHORIZATION REQUESTED:

Wastewater Type Daily Maximum Discharge, Gallons 05-1 Above ground sewage disposal .< 10,000 (annual average) 05-2 Vehicle wash, not open to the public < 2,000 05-3 Slaughterhouse < 2,000 (annual average) 05-4 Gravel, sand, limestone, or dolomite mining 05-5 Application of oil field brine 05-6 Vehicle wash, open to public < 3,000 05-7 Hydrodemolition

2. DISCHARGE VOLUME ALL DISCHARGES:

Maxim um daily discharge: gallons per day Cumulative annual discharge: gallons per year SEASONAL DISCHARGES SHOULD INCLUDE THE FOLLOWING:

Discharge period through IRRIGATION SYSTEMS AND SEEPAGE BEDS UTILIZING SOILS .FOR TREATMENT SHOULD INCLUDE THE FOLLOWING:

Effluent application rate:

Inches per hour__ Inches per day__ Inches per week__ Inches per year__

3. CERTIFICATION OF DISCHARGE MINIMIZATION Please attach the steps identified and considered to avoid or minimize the use and discharge of pollutants according to Rule 2215(3).

4. DISCHARGE METHOD Please check the discharge method used:,

LAND SURFACE DISPOSAL DISPOSAL CODE SUBSURFACE DISPOSAL DISPOSAL CODE

_ Spray Irrigation Alfl Tile Field Algl

_ Ridge and Furrow Alf2 -Injection well Alg2 Flood/Sheet Irrigation Alf3 Trench Al g3

__ Drywell Al g4 Seepage Beds:

Slow/Medium Rate Alf4

_ Rapid Rate Alf5 Other - Please describe:

27 EQP5305 (Rev 12/2004)

05-1. Above Ground Sewage Disposal Systems, less than 10,000 gallons per day (annual average)

Rule 2215. Please check all system characteristics that apply to this specific discharge and fill appropriate blanks:

Discharge is less than 20,000 gallons per day, calculated as a daily maximum.

Discharge is less than 10,000 gallons per day, calculated as an annual average.

_ A log will be maintained on site by the discharger of the daily discharge volume of sanitary sewage. The log shall be retained for a minimum of three years, and made available upon request by the Department.

Property Ownership:

Discharge occurs on property owned by the applicant Discharge occurs on property not owned bý the applicant. Please attach written authorization to discharge on that property from the property owner.

Lagoon/irrigation System:

Anticipated date when plans and specifications for the treatment system will be submitted to the Department.

NOTE: Applicant cannot commence discharge until the Department notifies the discharger that the treatment system will meet the requirements of Rule 2204.

The lagoon system is fenced and perimeter warning signs placed around the perimeter of the lagoon.

Irrigation occurs between May 1 and October 15.

If irrigating crops for human consumption, crops will be processed prior to consumption.

Dairy animals will not be allowed to graze on fields until 30 days after the land application of wastewater.

Isolation Distance:

Effluent will not be applied within 100 feet of the property line The Department has authorized a discharge less than 100 feet from the property line. The documentation for the lesser distance is included with this application, and is found in Attachment 05-2. Vehicle Wash Not Open to the Public, less than 2000 gallons per day, Rule 2215. Please check all system characteristics that apply to this specific discharge:

Discharge is less than 2000 gallons per day.

The discharge consists of washwater with additives designed to remove non-polluting, inert substances from the exterior of vehicles, which excludes the washing of undercarriages or any portion of the vehicle that has come in contact with waste or products.

Soaps, detergents and additives are used according to manufacturers directions, and do not include volatile organic compounds, such as degreasers.

A log will be maintained on site by the discharger of the daily discharge volume of washwater with additives. The log shall be retained for a minimum of three years, and made available upon request by the Department.

Isolation Distance:

Effluent will not be applied within 100 feet of the property line.

The Department has authorized a discharge less than 100 feet from the property line. The documentation for the lesser distance is included with this application, and is found in Attachment Please check which one of the following applies:

The source water is from a municipal supply.

The water source meets state or federal criteria for use as potable water.

The water source meets the standards of Rule 2222.

Thewater source is an alternative to the above. Department approval is required, and supporting documentation is attached.

28 EQP5305 (Rev 12/2004)

05-3. Slaughterhouse Washwater with Additives, less than 2,000 gallons per day (annual average)

Rule 2215. Please check all system characteristics that apply to this specific discharge:

The discharge is less than 2,000 gallons per day calculated as an annual average.

The washwater shall only contain additives resulting from cleaning operations.

Soaps, detergents and additives are used according to manufacturers directions, and do not include volatile organic compounds, such as degreasers.

The discharger has taken steps to minimize the discharge of blood, fat, paunch and other solids.

The wastewater is transported to the discharge location in enclosed containers.

A log will be maintained on site by the discharger of the daily discharge volume of washwater with additives. The log shall be retained for a minimum of three years, and made available upon request by the Department.

Please check which one of the following applies to the facility water source:

The source water is from a municipal supply.

The water source meets state or federal criteria for use as potable water.

The water source meets the standards of Rule 2222.

The water source is an alternative to the above. Department approval is required, and supporting documentation is attached.

Location:

The facility is located in the Upper Peninsula.

The facility is located in the LowerPeninsula.

Property Ownership:

Discharge occurs on property owned by the applicant Discharge occurs on property not owned by the applicant. Please attach written authorization to discharge on that property from the property owner.

Lagoon/Irrigation System:

Anticipated date when plans and specifications for the treatment system will be submitted to the Department.

NOTE: Applicant cannot commence discharge until the Department notifies the discharger that the treatment system will meet the requirements of Rule 2204.

The lagoon system is fenced and perimeter warning signs placed around the perimeter of the lagoon.

If irrigating crops for human consumption, crops will be processed prior to consumption.

Growing Season:

Irrigation occurs between May 1 and November 15 in the Lower Peninsula, between May 1 and October 15 in the Upper Peninsula.

The discharge is less than 4,000 gallons per acre per day.

The irrigation area is vegetated to prevent erosion and provide adequate nutrient uptake.

Effluent will not be applied within 100 feet of the property line.

The Department has authorized a discharge less than 100 feet from the property line. The documentation for the lesser distance is included with this application, and is found in Attachment__

Winter Season:

_ Irrigation occurs between November 16 and April 30 in the Lower Peninsula, between October 16 and April 30 in the Upper Peninsula.

The discharge is less than 2,000 gallons per acre per week.

The maximum total winter seasonal discharge is 10,000 gallons per acre.

• The irrigation area is vegetated to prevent erosion and provide adequate nutrient uptake.

The irrigation area will be vegetated to prevent erosion and provide adequate nutrient uptake immediately after snow melt.

The slope of the discharge area does not exceed two per cent.

Effluent will not be applied within 400 feet of the property line, homes, buildings or surface water.

The Department has authorized a discharge less than 400 feet from the property line. The documentation for the lesser distance is included with this application, and is found in Attachment __

29 EQP5305 (Rev 12/2004)

05-4. Gravel, sand, limestone, or dolomite mining, Rule 2215. Please check all system characteristics that apply to this specific discharge:

The discharge consists of washwater without additives, used for the purpose of washing and sorting uncontaminated gravel, sand, limestone or dolomite.

A log will be maintained on site by the discharger of the daily discharge volume of washwater without additives. The log shall be retained for a minimum of three years, and made available upon request by the Department.

Property Ownership:

Discharge occurs on property owned by the applicant Discharge occurs on property not owned by the applicant. Please attach written authorization to discharge on that property from the property owner.

Isolation Distance:

Effluent will not be applied within 100 feet of the property line The Department has authorized a discharge less than 100 feet from the property line. The documentation for the lesser distance is included with this application, and is found in Attachment Please check which oneof the following applies:

The source water is from a municipal supply.

The water source meets state or federal criteria for use as potable water.

The water source meets the standards of Rule 323.2222.

The water source is an alternative to the above. Department approval is required, and supporting documentation is attached.

05-5. Application of Oil Field, Brine, Rule 2215. Please check all system characteristics that apply to this specific discharge:

The brine meets the requirements of R 324.705(3) of Part 615, Supervisor of Wells, 1994, PA 451, as amended.

The brine is being used for ice or dust control or soil stabilization on land.

Vehicular equipment used for the spreading of approved oil field brine is dedicated for that use or hauling fresh water.

Brine will not be applied at a site of environmental contamination for chlorides as defined under Part 201 of Act 451.

A brine application log will be maintained in the application vehicle for the previous two weeks applications of brine use that includes the information required in Section A.9 of the General

, Permit, and made available upon request by the Department or a peace officer.

A brine application log will be maintained by the discharger for a minimum of three years of brine use which shall include the information required in Section A.9 of the General Permit, and made available upon request by the Department or a peace officer.

Dust Control/Soil Stabilization:

The number of brine applications per year will be in accordance with Condition A.4.a. and' Condition A.4.b. of the General Permit.

Brine will be applied to roads and parking areas with a spreader bar delivering the brine over an eight to ten foot area.

Brine will be applied at a maximum rate of 1500 gallons per lane mile of road or 1,250 gallons per acre of land.

Brine will be applied in a manner to prevent runoff.

Ice Control:

Brine will be applied only to paved roads or paved parking ,lots.

Brine will be applied at a maximum rate of 500 gallons per lane mile or 400 gallons per acre of land.

Brine wiii be applied only when the air temperature is above 20 degrees Fahrenheit.

Brine will be applied with equipment designed to direct the discharge to the center of the pavement or high sides of curves.

Brine application equipment will be equipped with measuring devices to ensure brine applications meet the requirements of the General Permit.

30 EQP5305 (Rev 12/2004)

05-6. Vehicle Wash, open to the public, Rule 2215. Please check all system characteristics that apply to this specific discharge.

The facility was in operation as of April 1, 2001.

The discharge is less than 3,000 gallons per day.

The soaps, detergents, and other cleaning chemicals do not contain volatile organic compounds, such as degreasers.

There are no repair or maintenance activities taking place in the wash areas.

Detergents, surfactants and other additives are only used in accordance with manufacturers specifications.

Groundwater will be sampled twice per year and analyzed for the substances listed in Tables I, II and III of this General Permit.

Isolation Distance:

Effluent will not be applied within 100 feet of the property line The Department has authorized a discharge less than 100 feet from the property line. The documentation for the lesser distance is included with this application, and is found in Attachment__

Monitor Wells:

Monitor wells have been installed in accordance with Attachment II of this General Permit. A map showing the location of the wells in relation to the discharge, well logs, elevations ( referenced to USGS datum) for top of casing, ground, and well screen interval, are found in Attachment __

Please check which one of the following applies:

The source water is from"'a municipal supply.

The water source meets state or federal criteria for use as potable water.

The water source meets the standards of Rule 323.2222.

The water source is an alternative to the above. Department approval is required, and supporting documentation is attached.

05-7. Hydrodemolition, Rule 2215. Please check all system characteristics that apply to this specific discharge.

The discharge does not add additional contaminants to those present in the hydrodemolition wastewater.

There is no discharge to surface water.

The discharge is consistent with Michigan Department of Transportation contract documents for managing Hydrodemolition runoff water or other methods approved by the Department of Environmental Quality.

The discharge occurs only on property where the discharger has a legal authorization for such a discharge onthat property.

The discharger maintains, on site, a log detailing the daily process wastewater discharge activities. The log shall be available for inspection and submitted to the Department of Environmental Quality upon request: Records will be maintained for a period of three years unless otherwise required by the Department of Environmental Quality.

31 EQP5305 (Rev 12/2004)

RULE 323.2216 PERMITS FOR SPECIFIC DISCHARGES A DISCHARGE OF THE TYPE AND VOLUME SPECIFIED IN RULE 2216 THAT DOES NOT MEET THE SPECIFIC CRITERIA OF THIS RULE MUST APPLY FOR A PERMIT UNDER RULE 2218.

1. RULE 2216 AUTHORIZATION REQUESTED WASTEWATER TYPE DAILY MAXIMUM DISCHARGE, GALLONS

• (2a) Sanitary Sewage, Constructed Wetland less than 20,000 (2b) Alternative Treatment System (3) Sanitary Sewage, Rule 2216 Design less than 50,000 (4) Laundromat Wastewater less than 20,000

2. DISCHARGE VOLUME ALL DISCHARGES:

Maximum daily discharge: gallons per day Cumulative annual discharge: gallons per year SEASONAL DISCHARGES SHOULD INCLUDE THE FOLLOWING:

Discharge period through IRRIGATION SYSTEMS AND SEEPAGE BEDS UTILIZING SOILS FOR TREATMENT SHOULD INLCUDE THE FOLLOWING:

Effluent application rate:

Inches per hour __ Inches per day __ Inches per week _ Inches per year __

3. PUBLIC NOTICE Please attach a copy of the public notice, containing information required by Rule 2217(2)(b).

4. CERTIFICATION OF DISCHARGE MINIMIZATION Please attach the steps* identified and considered to avoid or minimize the use and discharge of pollutants a ccording to Rule 2217(2)(c)

5. DISCHARGE METHOD Please check the discharge method used:

LAND SURFACE DISPOSAL DISPOSAL CODE SUBSURFACE DISPOSAL DISPOSAL CODE

_ Spray Irrigation Alfl Tile Field Alg1 Ridge and Furrow Alf2 Injection well Alg2 Flood/Sheet Irrigation Alf3 Trench Alg3 Drywell Al g4 Seepage Beds:

Slow/Medium Rate Alf4

_ Rapid Rate Alf5 Other - Please describe:

32 EQP5305 (Rev 12/2004)

6a. Sanitary Sewage, Constructed Wetland, Rule 2216(2), less than 20,000 gallons per day. Please check all system characteristics that apply for this specific discharge, either already in place or are part of the proposed design of the treatment system:

The discharge is less than 20,000 gallons per day.

A minimum of 2 septic tanks are installed in series preceding the constructed wetland.

The septic tanks have a combined volume of at least 2 times the daily design flow.

The outfall to the constructed wetland is equipped with a septic tank effluent filter.

There is a system to enhance nitrification prior to discharge to the constructed wetland.

The discharge has been treated to remove oil and grease, if applicable.

The system has at least 2 wetland cells.

Each wetland cell has a length to width ratio of between 2:1 and 4:1.

The constructed wetland treatment cells have a composite bottom liner in compliance with Rule 2237.

See Guidesheet IV for lagoon construction guidance The bottom of the lagoon cell has been constructed to be level.

The wetland cell filter media consists of 1/2-inch to 1-inch washed gravel with 100% passing the 1.0-inch sieve and a maximum of 3% passing the 1/2-inch sieve.

The filter media is between 18 inches and 30 inches in depth.

The constructed wetland is insulated with at least 6 inches of mulch or other comparable substitute.

The filter surface area hydraulic loading rate is not more than 1.2 gallons per square foot per day.

The design retention time is not less than 7 calendar days.

Indigenous or sterile wetland vegetation has been planted on a 1-foot grid across each wetland cell.

The system has the capability to recirculate effluent back into the influent end of the system.

The wetland cell discharges to a tile field designed and constructed in accordance with the provisions of the publication entitled "MichiganiCriteria for Subsurface Sewage Disposal," April 1994.

The tile field has been approved by:

The county, district, or city health department that has jurisdiction.

The department.

6b. Sanitary Sewage, Rule 2216(2)(b), less than 20,000 gallons per day, alternative treatment system.

Alternative treatment system. If you are applying for an authorization for a alternative treatment system equivalent to a constructed wetland, please attach documentation that the proposed system produces an effluent of similar quality to that of the constructed wetland.

33 EQP5305 (Rev 12/2004)

7. Sanitary sewage, specific design, Rule 2216(3), less than 50,000 gallons per day.

Please check the treatment systems being proposed under this Rule:

_ Lagoon w/land treatment

__ Sequencing batch reactor Activated sludge w/denitrification Oxidation ditch Other If other, please describe:

Please check all system characteristics that apply for this specific discharge:

The discharge is less than 50,000 gallons per day.

The sanitary sewage is not mixed with any other type of wastewater.

The treatment system has sufficient hydraulic capacity to treat organic or inorganic loading so that the discharge receives physical, chemical, biological treatment or a combination of treatments to meet the standards of Rule 2222.

The facility is under the supervision of a certified operator.

Land application is in accordance with Rule 2233, requirements common to all land application.

Land application is in accordance with the specific requirements of the following Rule:

Rule 2234, Slow. rate land treatment Rule 2235, Overland flow treatment Rule 2236, Rapid Infiltration 7a. Lagoon with land treatment

_ The lagoon liner meets the requirements of Rule 2237. See Guidesheet IV for lagoon construction guidance.

The lagoon system has at least 2 cells.

The lagoon storage volume is at a minimum 1/2 of the annual influent flow.

The lagoon has security fencing and warning signs.

Wastewater disposal is by means of land application to a suitable crop in accordance with Rule 2233. See Guidesheet II for guidance regarding landapplication of wastewater.

The discharge occurs only from a cell(s) which have not received untreated wastewater for at least 30 calendar days prior to the discharge.

Lagoons without aeration

_ Cell 1 does not exceed a maximum depth of 6 feet.

_ Cell 2 does not exceed a maximum depth of 8 feet.

All additional cells do not exceed a maximum depth of 10 feet.

Lagoons with aeration A minimum of 2 mg/I of dissolved oxygen is maintained in the primary cell.

The maximum depth of secondary cells does not exceed 10 feet.

7b. Sequencing batch reactor The discharge meets the requirements of Rule 2222 in the effluent.

_ The facility has a contingency plan to deal with periods of upset, mechanical malfunctions, and routine maintenance while maintaining compliance with this part.

The sequencing batch reactor system has at least 2 treatment tanks.

7c. All other treatment systems which do not involve land treatment The treatment system has a minimum storage volume of 1/2 the annual influent flow.

The treatment system does not have a minimum storage volume of 1/2 the annual influent flow, the discharge meets the requirements of Rule 2222 in the effluent, and the facility has a contingency plan to deal with periods of upset,, mechanical malfunctions, and routine maintenance while maintaining compliance with these rules.

34 EQP5305 (Rev 12/2004)

8. Laundromat Wastewater, Rule 2216(4), less than 20,000 gallons per day. Please check all system,.....

characteristics that apply for this specific discharge:

The discharge is less than 20,000 gallons per day.

The laundromat does not have any dry cleaning operations.

The lagoon liner meets the requirements of Rule 2237. See Guidesheet IV for lagoon construction guidance.

The storage volume of the lagoon is at a minimum1/2 of the annual influent flow.

The lagoon system has at least 2 cells.

The discharge shall occur only from cells that have not received untreated wastewater for at least 30 days.

The lagoons have security fencing and warning signs.

Discharge of treated wastewater is by means of low-rate application in accordance with Rule 2233. See Guidesheet II for guidance regarding land application of wastewater.

The spray irrigation system is under pressure to enhance volatilization of organic constituents.

If aeration is not included as part of the lagoon treatment system, the following apply:

Cell 1 does not exceed a maximum depth of 6 feet.

Cell 2 does not exceed a maximum depth of 8 feet.

Additional cells do not exceed a maximum depth of 10 feet.

If aeration is included as part of the lagoon treatment system, the following apply:

The maximum depth of secondary cells does not exceed 10 feet.

A minimum of 2 mg/I of dissolved oxygen will be maintained in the primary cell.

35 EQP5305 (Rev 12/2004)

RULE 323.2218 DISCHARGE PERMITS

1. TYPE OF TREATED WASTEWATER FOR WHICH THE AUTHORIZATION IS REQUESTED. PLEASE CHECK ALL THAT APPLY Sanitary sewage Process wastewater Cooling water, greater than 5,000 gallons per day Non-contact cooling without additives, greater than 10,000 gallons per day, source water not approved by department.

Non-contact cooling water with additives, greater than 10,000 gallons per day.

Other, please describe:

2. DISCHARGE VOLUME ALL DISCHARGES:

Maximum daily discharge: gallons per day Cumulative annual discharge: gallons per year SEASONAL DISCHARGES SHOULD INCLUDE THE FOLLOWING:

Discharge period through IRRIGATION SYSTEMS AND SEEPAGE BEDS UTILIZING SOILS FOR TREATMENT SHOULD INLCUDE THE FOLLOWING:

Effluent application rate:

Inches per hour _ Inches per day _ Inches per week _ Inches per year_

3. DISCHARGE METHOD Please check the discharge method used:

LAND SURFACE DISPOSAL DISPOSAL CODE SUBSURFACE DISPOSAL DISPOSAL CODE

_ Spray Irrigation Alfl Tile Field Algl

_ Ridge and Furrow Alf2 -Injection well Alg2 Flood/Sheet Irrigation Alf3 Trench Alg3 Drywell Alg4 Seepage Beds:

Slow/Medium Rate Alf4

_ Rapid Rate Alf5 Other - Please describe:

4. TREATMENT CODES Select and enter the appropriate treatment codes to describe treatment units, i.e., Al b, B2b (see APPENDIX A, Pages 41-44)

Treatment Unit A Treatment Unit B Treatment Unit C Treatment Unit D Please provide a description of the treatment system indicating how it will produce an effluent that will meet the standards of Rule 2222.

36 EQP5305 (Rev 12/2004)

4a. New Permits - Rule 2218(3)(a)

The following information must be included in the application for a new permit. Refer directly to Rule 2218 for specific information requirements. Please indicate where the necessary information is included in this application.

Please indicate NA for those that do not apply to your discharge:

An evaluation of the feasibility of alternatives to discharge to the groundwater in accordance with Rule 2219. See instructions, Page 9. This item is found The basis of design as required by 323.2218(2). See instructions, Page 10. This item is found The hydrogeological report as required by Rule 2221. See Guidesheet I. This item is found The wastewater characterization as required by Rule 2220. See Guidesheet Ill. This item is found If a standard applicable to the discharge is to be determined under Rule 2222(5), the information necessary to determine that standard, including whether a substance is a hazardous substance under Part 201. See Guidesheet V. This item is found The groundwater, or other media, sampling and analysis plan specified by Rule 2223. See instructions, Page 10 This item is found Information is attached that demonstrates the land treatment requirements of Rule 2233 will be met. See Guidesheet II. This item is found If a lagoon is included in the treatment process, information that demonstrates that the requirements of Rule 2237 will be met: See Guidesheet IV. This item is found 37 EQP5305 (Rev 12/2004)

4b. Reissuance of current, permit, no modifications, Rule 2218(3)(c). The following information must be included in the application for the reissuance of your current permit. Please check that all items have been included:

The discharge consists of the same quantity, effluent characterization, and treatment process as previously permitted.

A narrative description of the history of facility compliance with effluent and groundwater permit limits and sampling frequency is included. This item is found _ _.

An updated site map is included. This item is found The most recent static water levels and groundwater elevations from all wells on site. This item is found A current groundwater contour map is included, with a narrative evaluation of whether changes to the existing groundwater monitoring system are warranted and the rationale for any proposed change, This

,item is found The most recent groundwater quality results are included from all Wells on site. This item is found The most recent effluent quality results are included. This item is found Please check that all of the following that apply are included:

__ If permit limits were exceeded, the steps taken to bring the facility into compliance. This item is found .

__ An evaluation of whether there are general trends in the effluent or groundwater sampling data indicating that the discharge is approaching permit limits. This item is found The discharger has provided the department, within 30 calendar days of completion of construction of the treatment facilities, a certification by an engineer licensed under Act No. 299 of the Public Acts of 1980, as amended, that a quality control and quality assurance program was utilized and that the facilities were built consistent with standard construction practices to comply with the permit and this part.

38 EQP5305 (Rev 12/2004)

4c. Reissuance of current permit, with significant modifications Rule 2218(3)(b). The following information must be included in the application for the reissuance of your current permit. Please check that all items have been included:

An evaluation of the feasibility of alternatives to discharge to the groundwater in accordance with Rule 2219 is included. See Page 9. This item is found The basis of design required by 323.2218(2) is included. See Page 10. This item is found

_ The hydrogeological report required by Rule 2221 is included. See Guidesheet I. This item is found

_ The wastewater characterization required by Rule 2220 is included. See Guidesheet Ill. This item is found If a standard applicable to the discharge is to be determined under Rule 2222(5), the information necessary to determine that standard, including whether a substance is a hazardous substance under Part 201. See Guidesheet V. This item is found The monitoring plan as specified by Rule 2223 is included. See Page 10. This item is found Information that demonstrates the land treatment requirements of Rule 2233 will be met is included. See Guidesheet II. This item is found I_ _ _t If a lagoon is included in the treatment process, information that demonstrates that the requirements of Rule 2237 will be met is included. See Guidesheet IV. This item is found A narrative description of the history of facility compliance with effluent and groundwater permit limits and sampling frequency is included. This item is found

_ An updated site map is included. This item is found, The most recent static water levels and groundwater elevations from all wells on site are included. This item is found A current groundwater contour map and a narrative evaluation of whether changes to the existing groundwater monitoring system are warranted and the rationale for any proposed change are included. This item is found

___ The most recent groundwater quality results from all wells on site are included. This item is found

-__The most recent effluent quality results are included. This item is found .

Please check that all of the following that apply are included:

If permit limits were exceeded, a description of the steps taken to bring the facility into compliance. This item is found An evaluation of whether there are general trends in the effluent or groundwater sampling data indicating that the discharge is approaching permit limits. This item is found The discharger has provided the department, within 30 calendar days of completion of construction of the treatment facilities, a certification by an engineer licensed under Act No. 299 of the Public Acts of 1980, as amended, that a quality control and quality assurance program was utilized and that the facilities were built consistent with standard construction practices to comply with the permit and this part.

39 EQP5305 (Rev 12/2004)

SITE SPECIFIC EXEMPTION RULE 2210(Y)

A facility is authorized to discharge after it receives approval from the department that states the discharge is authorized under this part.

1. Please attach a narrative description of the discharge, indicating how the volume and/or constituents in the discharge present an insignificant potential to be injurious to the groundwater.

2. DISCHARGE VOLUME ALL DISCHARGES:

Maximum daily discharge: gallons per day Cumulative annual discharge: gallons per year SEASONAL DISCHARGES SHOULD INCLUDE THE FOLLOWING:

Discharge period through

3. DISCHARGE METHOD Please check the discharge method used:

LAND SURFACE DISPOSAL DISPOSAL CODE SUBSURFACE DISPOSAL DISPOSAL CODE

_ Spray Irrigation Alfl Tile Field Alg1

_ Ridge and Furrow Alf2 __ Injection well Alg2

_ Flood/Sheet Irrigation Alf3 Trench Alg3

__Drywell Al g4.

Seepage Beds:

Slow/Medium Rate Alf4

_ Rapid Rate Alf5 Other - Please describe:

To apply for an exemption according to Rule 2210(y), you should fill out pages 14-17 of this application, which contain general information about the facility. You should also provide the above information. The department will notify you whether your application qualifies for an exemption under Rule 2210(y), or whether you must apply for a different authorization. You are not authorized to discharge until you receive approval from the department.

40 EQP5305 (Rev 12/2004),

APPENDIX A TREATMENT METHOD CLASSIFICATION The Treatment Method Classification is a three digit alphanumeric code to describe'the treatment system and a guide for operator certification. The first entry is a letter designation to indicate physical (A), chemical (B), or biological (C) treatment. The second entry describes the appropriate sub-classification, andthe last entry is a letter correlating to the specific type of treatment.

1. PHYSICAL A-la Special Classification - Minor discharges with no treatment and limited monitoring requirements. This classification applies only to discharges where no other classification applies. (Note: Proper application for certification is necessary, however no additional examination is required.)

Examples:

Hydrostatic testing of pipes and tanks Discharge of storm water from secondary containment A-lb Plain Clarification- Solids removal by gravity separation in a mechanical clarifier

,with no provision for the addition of chemical coagulant. (Note: Does not include basins intended to provide biological or chemical treatment.)

Examples:

Clarifiers with no provision for addition of coagulant Settling Tanks with tube or plate settlers with no provision for addition of coagulant A-ld Impoundment - A tank, basin, or reservoir intendedto hold wastewater to allow for a controlled discharge; may or may not provide settling of solids. (Note: Does not include basins intended to provide biological or chemical treatment.)

Examples:

Discharge flow equalization Mine tailing ponds Gravel pits used to remove solids from wastewater A-If Land Surface Disposal - Disposal of wastewater by means of application to the surface of the land with percolation into the ground i.e.) No Underdrain Examples:

Spray Irrigation Ridge and Furrow Rapid Infiltration Basin Seepage Pond 41 EQP5305 (Rev 12/2004)

A-lg Sub-surface Disposal - Tile field system used for discharge of wastewater with percolation into the ground. Does not include under-drain systems used to collect wastewater for further treatment and/or discharge.

Examples:

Septic tank - tile field system A-lh Non-contact Cooling Water - Flow measurement, visual observation, sampling, and minor testing of non-contact cooling water discharges regulated by permit. Discharge of cooling water that has mixed with untreated wastewater is excluded. Proper application for certification is required; the written examination consists of a take-home questionnaire.

Examples:

Discharge from Heat Exchangers Compressor Condensate Cooling Tower Discharge A-2b Filtration of Wastewater - Filtration. of wastewater for the purpose of removing particulate materials. Specifically for Rapid Sand Filters, but may also include such processes as pressure filters, micro-screens, and bag filters.

A-2c Air Flotation - A wastewater treatment process for separation in which fine air bubbles are utilized to raise suspended materials to the surface where they are collected.

Note: Does not include sludge thickening processes A-2d Air Stripping (Note Name Change from Gas Stripping) - Air stripping of volatile substances from wastewater or groundwater.

Note: Does not include off-gas treatment for, odor control A-2e Centrifuging - A wastewater treatment process in which a centrifuge is used to apply centripetal force to accelerate the separation of substances.

Examples:

Removal of solids from wastewater by centrifuging Separation of oil from wastewater by centrifuging Note: Does not include thickening of sludge by centrifuging A-2g Deep Well Injection - Pressure injection of wastewater into a sub-surface formation.

B. CHEMICAL B-1 b Neutralization - A chemical treatment process whereby a wastewater is neutralized (pH adjustment) to achieve a pH level required for discharge.

Addition of acid or base to meet limit in discharge permit Does not include pH adjustment intended for such purposes as precipitation, nitrification, or to enhance biological treatment.

B-2a Chemical Clarification - Coagulation and/or Precipitation for solids removal from wastewater.

42 EQP5305 (Rev 12/2004)

Chemical coagulation - The removal of suspended solids from wastewater through the addition of polymer, ferric chloride, alum, or other coagulants added to wastewater just prior to clarification.

Chemical precipitation - The removal of dissolved solids from wastewater by precipitation through the addition of a base, ferric chloride, alum or other chemical agent just prior to clarification.

Examples:

Precipitation of metals from wastewater Precipitation of phosphorus from wastewater B-2b Ion Exchange - A wastewater treatment process in which undesirable ionic materials in wastewater are exchanged for other ions on a resin material.

Note: Does not include softening of process water or boiler make-up water B-2c Oil - Water Separation - Separation of oil from water with or without chemical addition.

Examples:

Grease Traps Gravity Oil Water Separators Chemical Emulsion Breaking Oil Skimming B-2d Ultraviolet Oxidation - A wastewater treatment process in which ultraviolet radiation is used to oxidize organic contaminants (Note: Does not include UV disinfection)

B-3b Carbon Adsorption - Removal of organic compounds from wastewater by adsorption on activated carbon.

Examples:

Includes systems in which wastewater passes through a carbon bed (liquid phase adsorption)

Does not include systems in which organics are removed from the wastewater by air stripping and then from the air by carbon adsorption (vapor phase adsorption).

Does not include carbon canisters used for odor control systems.

B-3c Reduction of Hexavalent Chromium - A wastewater treatment process in which hexavalent chromium is chemically reduced to trivalent chromium.

B-3d Oxidation of Cyanide - The removal of cyanide from wastewater through the process of alkaline chlorination.

43 EQP5305 (Rev 12/2004)

C. BIOLOGICAL C-lb Aerated Lagoons - A man-made pond or lagoon with mechanical or diffused aeration intended to provide aerobic biological treatment.

Note: Includes wastewater treatment systems with a combination of aerated and non-aerated cells C-Ic Stabilization Ponds - A man-made pond or lagoon intended to provide natural biological treatment without the addition of supplementalraeration.

C-2a Disinfection - The chemical or ultraviolet radiation disinfection process to destroy pathogenic organisms in wastewater just prior to discharge.

C-2b , Trickling Filters - An attached growth wastewater treatment process in which.

wastewater is distributed over a media (usually rock or plastic) which supports the biological system and is designed to convert colloidal and dissolved organic compounds into settleable sludge.

C-2c Biological Sand Filters - Sand filtration systems intended to provide biological treatment of wastewater as well as physical filtration.

Examples:

Intermittent Sand Filters Recirculating Sand Filters C-2d Rotating Biological Contactors- An attached growth wastewater treatment process utilizing rotating plastic media designed to convert colloidal and dissolved organic compounds into settleable sludge.

C-2e Package Plant - (Note: Exam no longer offered. All new package plants will be classified C-3a or C-3b)

C-2f Constructed Wetlands - A man-made complex that simulates natural wetlands, intended to treat wastewater through microbial utilization and plant uptake of nutrients.

C-3a Activated Sludge - A suspended growth, biological treatment system designed to convert colloidal and dissolved organic compounds in wastewater into settleable sludge.

Examples:

Conventional Activated Sludge Oxidation Ditch Package Plants C-3b Sequencing Batch Reactor - A modification of the activated sludge process in which treatment occurs in batch mode and the reactor also serves as the secondary clarifier. The treatment sequence is largely computer controlled.

44 EQP5305 (Rev 12/2004)

APPENDIX B OPERATIONAL REQUIREMENTS In addition to information necessary to make a permit decision, the Part 22 Rules contain a series of operational requirements that must be followed after the discharge begins. The following is a brief overview of those requirements. The dischargershould refer to the specific rule authorization for detailed requirements.

Rule 2211 (b) Laundromat, less than 500 gallons per day (i) Septic tanks must be pumped when the sludge level reaches 25% of the tank volume.

(ii) Septic tanks must be equipped with an effluent filter.

(e) Portable power washer (i) The discharge must not cause runoff of wastewater or deposition of waste materials onto adjacent properties.

Rule 2213 (3)Egg washing, less than 10,000 gallons per day (a) The discharger must minimize the discharge of proteinaceous matter, such as egg yolks, to control odor and prevent nuisance conditions.

(4)Department approved groundwater remediation (a) The discharger shall maintain all treatment works in good working order at all times.

Rule 2216 (2) Constructed wetland, less than 20,000 gallons per day (a) Wetland vegetation shall be cultivated to maximize the rooted depth throughout the gravel filter media.

(3) Sanitary sewage, less than 50,000 gallons per day (a) Sludge resulting from the wastewater treatment process must be disposed of in accordance with part 115 or land applied in accordance with applicable state and federal law.

(b) The discharger shall maintain all treatment or control facilities or systems in good working order and operate the facilities or systems as efficiently as possible.

(c) A discharger shall have an operation and maintenance manual for the wastewater treatment facility. The manual shall include all of the following information:

(i) Function, start-up, shutdown, and periodic maintenance procedures for each unit process'and item of mechanical and electrical equipment.

(ii) The appropriate response or facility adjustment to minimize the impact of an emergency situation.

(iii) A monitoring program to monitor process efficiency.

(iv) Details of how inspections will be conducted and a schedule for the inspection of collection system and pump stations, where applicable.

(v) Periodic maintenance procedures for the collection system and pump stations, where applicable.

(vi) Procedures for the routine maintenance and inspection of lagoons and equipment used for irrigation, where applicable.

(d) Effluent may be discharged from May 1 through October 15, unless the department approves alternative dates.

45 EQP5305 (Rev 12/2004)

(e)The discharger shall inspect the lagoon facilities weekly and maintain an inspection log unless otherwise authorized by the department.

(f)

• When drawing down a cell for transfer or discharge, the discharger shall meet all of the following requirements unless otherwise authorized by the department:

(i) Water discharged or transferred shall be removed from.the surface 2 feet of the cell at a rate of less than 1 foot per day.

(ii) A discharger shall maintain a minimum of 2 feet of freeboard in all cells at all times.

(iii) A discharger shall maintain a minimum of 2 feet of water in all cells at all times.

(g) The discharger shall implement a facility maintenance program that incorporates all of the following management practices, unless otherwise authorized by the department:

(i) Vegetation shall be maintained at a height not more than 6 inches above the ground on lagoon dikes.

(ii) Not more than 10% of the water surface shall be covered by floating vegetation and not more than 10% of the water perimeter may have emergent rooted aquatic plants.

(iii) Dikes shall be inspected for evidence of erosion and animal burrowing. Damage due to erosion or animal burrowing shall be corrected immediately and steps taken to prevent occurrences in the future.

(iv) The occurrence of any of the following shall be minimized and immediate steps shall be taken to eliminate each occurrence:

(A) Scum.

(B) Floating sludge.

(C) Offensive odors.

(D) Insect infestations.

(E) Septic conditions.

(4) Laundromats, less than 20,000 gallons per day (a) Effluent may be discharged from May 1 through October 15, unless alternative dates are approved by the department.

(b) The discharger shall inspect the lagoon facilities weekly and maintain an inspection log unless otherwise authorized by the department.

(c) When drawing down a cell for transfer or discharge, the discharger shall meet all of the following requirements unless otherwise authorized by the department:

(i) Water discharged or transferred shall be removed from the surface 2 feet of the cell at a rate of less than 1 foot per day.

(ii) A discharger shall maintain a minimum of 2 feet of freeboard in all cells at all times.

(iii) A discharger shall maintain a minimum of 2 feet of water in all cells at all times.

(d) The discharger shall implement a facility maintenance program that incorporates all of the following management practices, unless otherwise, authorized by the department:

(i) Vegetation shall be maintained at a height not more than 6 inches above the ground on lagoon dikes.

(ii) Not more than 10% of the water surface shall be covered by floating vegetation and not more than 10% of the water perimeter may have emergent rooted aquatic plants.

(iii) Dikes shall be inspected for evidence of erosion and animal burrowing. Damage due to erosion or animal burrowing shall be corrected immediately and steps taken to prevent occurrences in the future.

(iv) The occurrence of any of the following shall be minimized and immediate steps shall be taken to eliminate each occurrence:

(A) Scum.

(B) Floating sludge.

(C) Offensive odors.

(D) Insect infestations.

46 ' EQP5305 (Rev 12/2004)

Metals Groundwater and effluent parameters and detection limits Parameter Groundwater Detection Limits (ug/1)

Aluminum 50 Antimony 2 Arsenic .1 Barium 5 Beryllium 1 Boron 20 Cadmium 5 Calcium 1000 Chromium 2 Chromium VI 5 Cobalt 2 Copper 2 Iron 20 Lead 1 Lithium 8 Magnesium 1000 Manganese 5 Mercury . 0.2 Molybdenum 25 Nickel 2 Potasium 100 Selenium 2 Silver 0.5 Sodium 1000 Titanium 10 Thallium 2 Vanadium 10 Zinc 4

Phenols Groundwater and effluent parameters and detection limits Parameter Groundwater Detection limits (ug/I) 2-Chlorophenol 10 4-Chloro-3-methylphenol 10 M-Cresol & P-Cresol 20 O-Cresol 10 2,4-Dichlorophenol 10 2,4-Dimethylphenol 10 2,4-Dinitrophenol 50 2-Methyl-4,6-dinitrophenol 50 2-Nitrophenol 10 4-Nitrophenol 50 Pentrachlorophenof 50 Phenol 10 2,4,5-Trichlorophenol 10 2,4,6-Trichlorophenol 10

I J

I I 3 i

7. FOR RULE 2215, 2216 AND 2218 AUTHORIZATIONS ONLY:

PLEASE INDICATE WHERE THE COMPLIANCE MONITORING REPORT FORMS SHOULD BE SENT NAME Donald C. Cook Plant- Attention Jon H. Harner, Mail Zone 5A STREET ADDRESS One Cook Place CITY Bridgman STATE MI490 ZIP CODE 49106

8. AUTHORIZATION REQUESTED:

Rule 2210(y), Site Specific Exemption NEW USE REISSUANCE Rule 2211, Notification __NEW USE REISSUANCE Rule 2213, Notification with Certification NEW USE REISSUANCE Rule 2215, General Permit, Certificate of Coverage NEW USE REISSUANCE Rule 2216, Specific Discharges NEW USE REISSUANCE X Rule 2218, Discharge Permit NEW USE X REISSUANCE IF REQUESTING A REISSUANCE OR AN AUTHORIZATION DIFFERENT THAN THE CURRENT AUTHORIZATION, PLEASE INCLUDE THE PERMIT/EXEMPTION NUMBER OF THE CURRENT AUTHORIZATION:

If the current authorization is a permit, Rules 2216 or 2218, or was issued prior to August 26, 1999, the number is: M GW1810102 If the current authorization is a General Permit, Rule 2215, the number is: MG If the current authorization is a site specific exemption, Rule 2210(y), or was issued prior to August 26, 1999, the number is: GWE-If the current authorization is a notification, Rule 2211, the number is: GWN-If the. current authorization is a notification/certification, Rule 2213, the number is: GWC-

9. FACILITY STANDARD INDUSTRIAL CLASSIFICATION (SIC) CODE. 4911 This information is available through the US Department of Labor, Office of Safety and Heath Administration, at the following web address: www.osha.gov/oshstats/sicser.html

10. SITE MAPS Provide two black and white 8 1/2" X 11" maps drawn to scale that show the following:

SITE MAP 1 a) Discharge location in relation to property boundaries on a topographic map.

b) Township and county name.

c) North arrow orientation.

SITE MAP 2 - All sites must include item a, include items b-e as necessary.

a. Current and proposed treatment units and discharge areas and distance to property lines.

b. Monitoring wells on site and on adjacent properties.

c. Potable wells on site and on adjacent properties.

d. Surface waters, including wetlands, lakes, rivers, streams, and drains on the property.

e. Distance between multiple disposal sites.

ATTACH SITE MAP TO THIS APPLICATION FORM 15 EQP5305 (Rev 12/2004)

7. FOR RULE 2215, 2216 AND 2218 AUTHORIZATIONS ONLY:

PLEASE INDICATE WHERE THE COMPLIANCE MONITORING REPORT FORMS SHOULD BE SENT NAME Donald C. Cook Plant- Attention Jon H. Harner, Mail ZQne 5A STREET ADDRESS One Cook Place CITY STATE ZIP CODE Bridgman MI 49106

8. AUTHORIZATION REQUESTED:

Rule 2210(y), Site Specific Exemption _ NEW USE REISSUANCE Rule 2211, Notification NEW USE REISSUANCE Rule 2213, Notification with Certification NEW USE REISSUANCE Rule 2215, General Permit, Certificate of Coverage NEW USE REISSUANCE Rule 2216, Specific Discharges NEW USE REISSUANCE Rule 2218, Discharge Permit NEW USE X REISSUANCE IF REQUESTING A REISSUANCE OR AN AUTHORIZATION DIFFERENT THAN THE CURRENT AUTHORIZATION, PLEASE INCLUDE THE PERMIT/EXEMPTION NUMBER OF THE CURRENT AUTHORIZATION:

If the current authorization is a permit, Rules 2216 or 2218, or was issued prior to August 26, 1999, the number is: M GW1810102 If the current authorization is a General Permit, Rule 2215, the number is: MG If the current authorization is a site specific exemption, Rule 2210(y), or was issued prior to August 26, 1999, the number is: GWE-If the current authorization is a notification, Rule 2211, the number is: GWN-If the current authorization is a notification/certification, Rule 2213, the number is: GWC-

9. FACILITY STANDARD INDUSTRIAL CLASSIFICATION (SIC) CODE. 4911 This information is available through the US Department of Labor, Office of Safety and Heath Administration, at the following web address: www.osha.gov/oshstats/sicser.html

10. SITE MAPS Provide two black and white 8 1/2" X 11" maps drawn to scale that show the following:

SITE MAP 1 a) Discharge location in relation to property boundaries on a topographic map.

b) Township and county name.

c) North arrow orientation.

SITE MAP 2 - All sites must include item a, include items b-e as necessary.

a. Current and proposed treatment units and discharge areas and distance to property lines.

b. Monitoring wells on site and on adjacent properties'.

c. Potable wells on site and on adjacent properties.

d. Surface waters, including wetlands, lakes, rivers, streams, and drains on the property.

e. Distance between multiple disposal sites.

ATTACH SITE MAP TO THIS APPLICATION FORM 15 EQP5305 (Rev 12/2004)

11. WATER USAGE DIAGRAM Please attach an 8 /2 x 11 diagram showing water usage at the facility, from supply to discharge. Include all flows such as sanitary, process water, etc. Please also indicate where in the system additives or other substances are added to the waste stream for which this authorization is being sought. The water balance should show daily average flow rates at influent, intake and discharge points and daily flow rates between treatment units. Please use actual measurements whenever possible.

12. OWNERSHIP OF TREATMENT SYSTEM AND DISPOSAL AREA Are all parts of the treatment system and discharge areas ( e.g. treatment plant, underground piping or irrigation fields) located on property owned by the applicant? Yes x No IF NO, ATTACH THE NAME AND ADDRESS OF THE PROPERTY OWNER WHERE THE DISCHARGE WILL OCCUR, AND A COPY OF THE WRITTEN PERMISSION TO DISCHARGE ON PROPERTY NOT OWNED BY THE DISCHARGER.

13. PROXIMITY OF TREATMENT SYSTEM TO A KNOWN SOURCE OF GROUNDWATER CONTAMINATION Are there any known groundwater contamination sites within 1/4 mile of your disposal site?

Yes x No Unknown IF YES, ATTACH TO THE APPLICATION FORM A DESCRIPTION OF THE LOCATION AND CONTAMINANTS BEING REMEDIATED AT THE SITE. On Site Map,* 2

14. ISOLATION DISTANCE The following are isolation distances required from the discharge to adjacent water supply wells. What is the distance from your discharge to the nearest water supply well?

WELL TYPE PERMIT AUTHORIZATION: 2218, 2216(3) ALL OTHER AUTHORIZATIONS I, Ila 2000 200 lib, III 800 75 Domestic 300 50 Distance to nearest Type I, Ila water supply well 6 Miles- Outdoor Kitchen Distance to nearest Type lib, III water supply well 3 Miles- Grand Mere State Park Distance to nearest Domestic water supply well* Greater than 1 Mile

• No Domestic' wells in Lake Twp per Lake Twp Water Superintendent

15. ADJACENT PROPERTY OWNERS List the namesand addresses of all property owners adjacent to the facility, treatment systems and discharge locations. Include properties across roadways.

ATTACH ANY ADDITIONAL NAMES AND ADDRESSES TO THE APPLICATION FORM.

NAME COMPLETE MAILING ADDRESS

16. WELLHEAD PROTECTION Is your facility located in a designated wellhead protection area? Yes __ No x If yes, please identify the community*

o Approved wellhead protection areas can be reviewed at the following web address:

http://www.michigan.gov/deq/O,1 607,7-135-3313_3675_3695-59280--,00.html

17. SIGNATORY REQUIREMENT Pursuant to Rule 2114 of the Part 21 Rules, this application must have an original signature, and be signed by EQP5305 (Rev 12/2004) 16 EQP5305 (Rev 12/2004)

the appropriate representative(s) as follows:

A. For a corporation, the form must be signed by a principal executive officer of at least the level of Vice-president, or his/her designated representative, if the representative is responsible for the, overall operation of the facility from which the discharge described in the permit application (appropriate documentation must be provided to demonstrate the position and responsibility of the designated representative).

B. For a partnership, the form must be signed by a general partner.

C. For a sole proprietorship, the form must be signed by the proprietor.

D. For municipal, state or other public facility, the form must be signed by either a principal executive officer, the mayor, village president, city or village manager or other duly authorized employee.

All signatures submitted to the department must be original signatures, or the application will be returned as incomplete. The details of these requirements are found in Rule 2114, The department reserves the right to request information in addition to that supplied-with this application if necessary to verify statements made by the applicant or for the department to make a determination required by Part 31, Water Resources Protection, Natural Resources and Environmental Protection Act, 1994 PA 451, as amended (Act 451) and/or the Part 22 Rules associated with Part 31.

I certify, under penalty of law, that I have personally examined and am familiar with the information submitted in this document and all attachments. The information being submitted was collected and analyzed in accordance with the Part 22 Rules of Part 31 of Act 451, as amended. Based on my inquiry of those individuals immediately responsible for obtaining the information, I believe that the information is true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fine and imprisonment.

Print Name Jon H. Harner Title 'Environmental Manager Representing Indiana Michigan Power - A fully owned Subsidiary of American Electric Power Signature KX' 3 Z 3 Date It /t '/'

17 EQP5305 (Rev 12/2004)

RULE 323.2218 DISCHARGE PERMITS

1. TYPE OF TREATED WASTEWATER FOR WHICH THE AUTHORIZATION IS REQUESTED. PLEASE CHECK ALL THAT APPLY x Sanitary sewage X Process wastewater Cooling water, greater than 5,000 gallons per day Non-contact cooling without additives, greater than 10,000 gallons per day, source water not approved by department.

Non-contact cooling water with additives, greater than 10,000 gallons per day.

Other, please describe:

2. DISCHARGE VOLUME ALL DISCHARGES: 00D: 2,400,000 Maximum daily discharge: 00E: 60,000 gallons per day OOD: 876,000,000 Cumulative annual discharge: d0E: 21,900,000 gallons per year SEASONAL DISCHARGES SHOULD INCLUDE THE FOLLOWING:

Discharge period N/A through N/A IRRIGATION SYSTEMS AND SEEPAGE BEDS UTILIZING SOILS FOR TREATMENT SHOULD INLCUDE THE FOLLOWING:

Effluent application rate:

Inches per hour N/A Inches per day N/A Inches per week NIA Inches per year N/A

3. DISCHARGE METHOD Please check the discharge method used:

LAND SURFACE DISPOSAL DISPOSAL CODE SUBSURFACE DISPOSAL DISPOSAL CODE

_ Spray Irrigation Alfl Tile Field Algl Ridge and Furrow Alf2 __ Injection well Alg2

_ Flood/Sheet Irrigation Alf3 Trench Alg3 Drywell Al g4 Seepage Beds:

Slow/Medium Rate Alf4

• x Rapid Rate Alf5 X Other- Please describe: Seepage Basins, Rapid Infiltration Basins.

4. TREATMENT CODES Select and enter the appropriate treatment codes to describe treatment units, i.e., Al b, B2b (see APPENDIX A, Pages 41-44)

Treatment Unit A A-lh B-lb A-if (Outfall OOD - Turbine Room Sump)

Treatment Unit B A-2b C-3a C73b, A-if (Outfall OOE - Sewage Treatment Plant)

Treatment Unit C Treatment Unit D Please provide a description of the treatment system indicating how it will produce an effluent that will meet the standards of Rule 2222.

36EP50 ReI2/04 36 EQP5305 (Rev 12/2004)

4b. Reissuance of current permit, no modifications, Rule 2218(3)(c). The following information must be included in the application for the reissuance of your current permit. Please check that all items have been included:

x The discharge consists of the same quantity, effluent characterization, and treatment process as previously permitted.

X A narrative description of the history of facility compliance with effluent and groundwater permit limits and sampling frequency is included. This item is found Tab 9 X An updated site map is included. This item is found Tab 3 & 4 X The most recent static water levels and groundwater elevations from all wells on site. This item is found Tab 10 X A current groundwater contour map is included, with a narrative evaluation of whether changes to the existing groundwater monitoring system are warranted and the rationale for any proposed change. This item is found Tab 11 X The most recent groundwater quality results are included from all wells on site. This item is found Tab 12 X The most recent effluent quality results are included. This item is found Tab 12 Please check that all of the following that apply are included:

N/A If permit limits were exceeded, the steps taken to bring the facility into compliance. This item is found X An evaluation of whether there are general trends in the effluent or groundwater sampling data indicating that the discharge is approaching permit limits. This item is found Tab 9 N/A The discharger has provided the department, within 30 calendar days of completion of construction of the treatment facilities, a certification by an engineer licensed under Act No. 299 of the Public Acts of 1980, as amended,, that a quality control and quality assurance program was utilized and that the facilities were built consistent with standard construction practices to comply with the permit and this part.

38 EQP5305 (Rev 12/2004)

Indiana Michigan Power Company Cook Nuclear Plant One Cook Place POWER Bridgman, MI49106 Mr. Greg Danneffel Michigan Department of Environmental Quality 7953 Adobe Road Kalamazoo, MI 49009-5026 February 27, 2007

Subject:

Signatory Authority

Dear Mr. Danneffel:

This letter identifies that Jon H. Harner, Environmental Manager, has signatory authority for NPDES and groundwater related issues. Signatory authority is based on job function as permitted by regulatory requirements. The objective in establishing signatory authority by position was to identify a broad class of job families so that as process improvements are made, managers who are most familiar with the work will have the appropriate signatory authority to meet environmental regulatory requirements for permits, licenses and reports.

For Nuclear Generation Facilities: l)the Manager of Site Operations (Plant Manager); 2)the.AEP Nuclear Generation Group Manager(Site Vice President); and 3) the AEP Manager of Environmental Services (Environmental Manager).

The persons holding all of the above named positions have the necessary responsibility and authority to ensure that accurate permit and license application and/or report are prepared and appropriate corporate resources are dedicated to achieve compliance with the permits for their respective functional areas.

Sincerely, JN.Jensen Site Vice President c: NDM (2007-191) 60'*-ýtoý i

Carol L Ray/BC1IAEPIN To NGGDHSMANAGERIAL 10/24/2008 01:05 PM cc NGGNDMCORRESPONDENCE, NGGDEPTSECMANAGERIAL, NGG_ENVALL bcc Subject Delegation of Authority- Environmental Manager This email contains a Correspondence Control Document doclink located at the bottom of the page.

Please click the document link to open the Correspondence Control Database to view the associated document. Thank You.

Control Number:

2008-902

Subject:

Delegation of Authority- Environmental Manager

Reference:

Click here to open --- >

Beginning Monday, Oct 27, 2008, Jon Harner, Environmental Manager, will be the Manager Sponsor for the Turbine Clean Up during the forced outage. While Jon is in this position, Douglas Foster will have full signature authority and handle all matters pertaining to the Environmental Manager (HR issues will not be delegated). You can reach Doug at extension 1599 or by contacting Carol Ray at extension 1626.

Donald C. Cook Nuclear Plant GW 1810102 Part 10, Site Map I 7 70

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Bridgman Michigan Lake Township Berrien County 1" = 0.5 mile

I Donald C. Cook Nuclear Plant I fllAbl -inlifl')

I Part 10 Site map 2 I 1 SGroundwater North "--IV Lake Michigan (West property line) Sequencing Batch (Fuel Oil)nW WellWell RP-1 WelllU-

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Red Arrow HighWay U 00 Distance from discharge OOD Distance from discharge O0E Cook Nuclear Plant South property line: 1200' South property line: 1300' Berrien County Lake Michigan: 1000' Lake Michigan: 1500' East property line: 3600' East property line: 3400' Lake Township North property line: 2600' North property line: 2600' Scale: 1" = 1000'

Cook Nuclear Plant - Bridgman Michigan North 2*

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+ Groundwater sampling well locations Distance from discharge ODD Distance from discharge ODE Cook Nuclear Plant South property line: 1200' South property line: 1300' Berrien County Lake Michigan: 1000' Lake Michigan: 1500' East property line: 3600' East property line: 3400' Lake Township North property line: 2600' North property line: 2600' Scale: 1 1250'

Outfall OOD Absorption Pond

-Area: 62,291 sq ft Max depth: 19 ft Wetted Area: 62,291 sq ft

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Michigan Department of Environmental Quality-Surface Water Quality Division Groundwater Discharge Permit Application SECTION 15 - Adjacent Property Owners "LEASE TYPE OR PRINT

\CILITY NAME PERMIT NUMBER Donald C. Cook Nuclear Plant GW1810102

15. List adjacent property owners List the names and addresses of all property owners adjacent to the facility, treatment systems, and discharge locations. List this information in the space provided below or include the information as an attachment on 8 1/2" x 11" paper. If additional space is necessary, copy this blank page and attach this information to this application.

Location Property Number Name Address NORTH Grand Mere State 11-11-0006-0002-03-1 Michigan Department of Natural PO Box 30735 Park Resources Lansing, MI 48909 Rosemary Beach 11-11-0006-0004-02-5 Rosemary Beach Corp. C/O Secretary 3415 S. 59 St.

Cicero IL 60650 Rosemary Beach 11-11-0006-0004-00-9 Franklin Real Estate c/o Indiana Michigan Power Co. PO Box 16428 Columbus OH 43216 Attn: Tax section.

Rosemary Beach 11-11-0006-0004-01-7 Caparo, William E. & Oyler, Kathryn E. 122 S. Ellsworth Pl.

South Bend, IN 46635 Rosemary Beach 11-11-0006-0004-04-1 Temmel, Edward P. 9617 E. Shore Dr.

Oak Lawn IL 60453 Rosemary Beach 11-11-0006-0004-09-2 Mcaloon, Sharon 1707 Dumont Ln Schaumburg, IL 60194 Rosemary Beach 11-11-0006-0004-05-0 West, Kathleen M. 3423 N. Seminary Ave Trustee Chicago, IL 60657 Rosemary Beach 11-11-0006-0004-10 Olofsson, Erik J. PO Box 74 Stevensville, MI 49127 rosemary Beach 11-11-0006-0004-11 Olofsson, Harold W. PO Box 299 Oak Lawn, IL 60454 Rosemary Beach 11-11-0006-0004-12 Addante, Joseph 576 Hawhorne Elmhurst IL 60126-3301 Rosemary Beach 11-11-6800-0026-10 O'Malley, Sean A. 5025 N. Central Park

+ Wyse, Jeffery D. Chicago, IL 60625 Rosemary Beach 11-11-6800-0026-09 O'Malley, Sean A. 5025 N. Central Park

+ Wyse, Jeffery D. Chicago, IL 60625 Rosemary Beach 11-11-6800-0027-02-0 Herbert, Rosemary C. 22 S. Archer Ave Mundelein IL 60060 Rosemary Beach 11-11-6800-0028-00-0 Herbert, Rosemary C. 22 S. Archer Ave Mundelein IL 60060 Rosemary Beach 11-11-6800-0028-01-8 Balka, Janet M. 3334 Louise Dr.

Lansing, IL 60438 Rosemary Beach 11-11-6800-0030-02-1 Gottschall, Bruce A. & Susan M. 5760 S. Blackstone Chicago, IL 60637 Rosemary Beach 11-11-6800-0032-01-5 Giese Marie E. 4291 Lake Road Stevensville, MI 49127 Rosemary Beach 11-11-6800-0033-00-3 Gilpin, Nancy 714 S Dearborn #8 Chicago, IL 60605 Rosemary Beach 11-11-6800-0036-00-2 Lewis, James G. Jr. 4183 Lake Ct.

Stevensville, MI 49127 Rosemary Beach 11-11-6800-0037-00-9 Kobler, Rich +Matthews, Larry. 4155 Lake Road' Stevensville, MI 49127 Rosemary Beach

.I ......

11-11-6800-0037-01-7 Gielniewski Michael Z & Teresa B. 1113 Indenendence Road Bartlett, IL 60103

Section 15 GW1810102 Adjacent Property Owners PaQe 2 of 2 Location Property Number Name Address Rosemary Beach 11-11-6800-0037-02-5 Tengerstrom Eric H. 7470 Rosemary Rd Trustee LE & Martin, Holly Stevensville, MI 49127 Rosemary Beach 11-11.-6800-0038-00-5 Tengerstrom, Eric H. 7470 Rosemary Rd Trustee LE & Martin, Holly Stevensville, MI 49127 NORTH 11-11-0005-0029-00-3 Technisand, Inc. PO Box 177 Wedron, IL 60557 NORTH 11-11-0005-0027-00-1 Technisand, Inc. PO Box 177 Wedron, IL 60557 NORTH 11-11-0005-0036-01-8 Ruff, Timothy W. 7500 Thorton Dr.

Stevensville, MI 49127 NORTH 11-11-0005-0036-06-9 Emery, Martin; Hopkins, Elwood J. & 7499 Thorton Dr.

Mable N.; Stevensville, MI. 49127 NORTH 11-11-0005-0036-02-6 Indiana Michigan Power Company C/O. PO Box 16428 Coiumbus OH 43216 Attn: Tax section.

EAST 11-11-0005-0024-00 Marshke, Dale A. 7552 Jericho Road Stevensville MI 49127 EAST .11-11-0005-0016-00 Westlake, Anita 7622 Red Arrow Highway Stevensville, MI 49127 EAST 11-11-0005-0002-01-6 Blue Jay Assoc. C/O. PO Box 16428 (VISITOR CENTER) Columbus OH 43216 Attn: Tax section.

EAST Interstate 1-94 Michigan Dept of State Highways SOUTH 11-11-0008-06-00 Indiana Michigan Power Company C/O. PO Box 16428 Colimbus OH 43216 Attn: Tax section.

SOUTH 11-11-0008-0041-00-8 Michigan Dept. of Transportation Lansing MI 48900 SOUTH 11-11-0008-0009-00-7 Franklin Real Estate C/O PO Box 16428 Columbus OH 43216 Attn: Tax section..

SOUTH 11-11-0007-0013-00-6 Lake Charter Twp. Shawnee Rd.

Bridgman, MI 49106 SOUTH 11-11-0007-0013-01-4 Lake Charter Twp. Shawnee Rd.

Bridgman, MI 49106 SOUTH 11-11-0007-0006-01-8 Indiana Michigan Power Company C/O PO Box 16428 Columbus OH 43216 Attn: Tax section.

SOUTH 11-11-0007-0004-01-5 Lake Charter Twp. Shawnee Rd.

Bridgman, MI 49106 SOUTH 11-11-0007-0001-01-6 Lake Charter Twp. Shawnee Rd.

Bridgman, MI 49106 WEST Lake Michigan State of Michigan and United States of America

Scion1 U DEFINITIONS GW1810102 NESW-NONESSENTIAL SERVICE WATER 2006-2007 ESW-ESSENTIAL SERVICE WATER Description AVG Flow MDT-MISC. DRAIN TANK Outfall in MGD oI Chemical Addiion points NA Inlet - Lake Twp Water Source 0.042 WASTEWATER FLOW DIAGRAM 001 U-1 Circ. Water 974 002 U-2 Circ. Water 1137 003 De Ice - DONALD C. COOK NUCLEAR PLANT O4IA ti eI- Rlceadrcac 0 l1ii 0013 U-2 SG Blowdown 0.240 OUTFALL agL )

00C "tg BIt Discharge 0.00001 SEQUENING BATCHE DOD TRS Discharge 0.407 __] i,.no,.o- . -I *MIEI "-T-E-o -

0.020 I . TOW SH u OT "LE OE Sewage Treatment Plant DOG RO Reject Row 0.264 L1 PHOTO h 00- TRS Emergency Overflow 000008 r &nTRMTE MTN' u, BCIGER I UM]

- . EBE.AN.

.EU CODNST SYSTE 0 T~ NELTRWASTE O"i-AN

-=PLAT*.. - I.. 'A l.. I " IMl

' oo *,e .... ** ...... " IOUTFALL' OOC. soeMeL-S).... .. . u a........

...... . / _ I_ _

.... I I I OUTFALL 001 MISC.SCCONSWly SYSTEM 0,.00.5 MOO OUTFALL 003E~

wa *O UNITI I - 2

. - E .2 OeESSEreGL.YaOL uRI. SR

-- / I I + ~~~~~~~~MOITIORmI II1 B.5....

LDG WATERTBTI I-PL.N.. OEAtNS t *-sMISC.

• II *

• L I

"-" I F ]---I I */ I -- I "1 " _ I' 003"*+

I II-AL al~~e~~NeasON I TAL,

.............. I " t 'I *

.........CRIB OFSHR 2-

..... -12_5....++V ............

0T(

• • • II

• f t ""

ENPTPSHe

' II

_fOUTFALL (oea.j SO 00D_

I,+Tr RD SYTEREJEC. E.ooPWAE PLN MNE// T EMREeeNCY DIESEL AACKET WATER DRAINS

• * ~~~~~ EURT ~ TN TURBINEA ROM SUTMPRIS*sOT LAKE MICHIGAN .4 , __s

. ODNAT TR

• Inaddition toStormwater outfall EPOCYDA EIYIER sources enlisted, typical drainage UNITIAJrT2 sources such as rooftops,Parking lots, CATHEeSea UNIT H-rC Roadways eyist as detailed in the UNITISNNlrlso5e~n DILIWuTER SeTWELLS GROUNDWATER DE)K GL2 MUNITRANSFORaR Cook Plant SWPPP.

Section 11 GWI810102 NES=OSESSENTIAL SERVICE WATER zuuti-zuu ESW-ESSENTIAL SERVICE WATER Description AVGFlow MDT-MISC. DRAINTANK Outfall in MGD WASTEWATER FLOW DIAGRAM

• Chemical Addition points NA Inlet - Lake Twp Water Source 0.042 001 U-1 Circ. Water 974 FL W 002 U-2 Circ. Water 1137 I NA . COOK NUCLEAR PLANT 003 De Ice - CKNU C PLALT. ST*LANT E MEXTENDED O0A U-1 SG Blowdown 0.116 - I KCHENWASTE I 00B U-2 SG Blowdown 0.240 "I R Io 'S FALL T 00C Hig BIt Discharge 0.00001 LATI....... P E..G1 OE*

1LhrlT OOD TRS Dscharge 0.407 eEShnlorin t IOE R E WSTRTEATaOOSLE ODE OOG SWag. Treatment RO Reject FlowPlant 0.264 020I .*' I -

......... E PHOTO--00 ...

OOH I-IiI-TRS Emergency Overflow 0.00008 ALTERNATE HEATITNGA HETISATULn I r-

._ * . *,* ..... ,_ . T"'OI'LET + ":r  ::'

ASITI CUEP CON T3 ..............

OUTFALL 003 COOENAT TANI SNTATE 00RI0S2250T *N DRIAAI PERTESS = j N" CCLITOOl TYSTSnoneN0000L00 FLOCW OUTFALL 1F021-1 lI OUTFALL

-- '00 2 -l* 0 UIS1WA INTKEOOIBSOR*

2250n 120O II OCSEG P~ IC UI

. . I .CLS C OUGLo I_ r GEERTO _TTA

• ASONOA" 100C0000ENE I0 I L MICHIGAN 0000D / M SECONDART SYSTEM UNIT IoaWs .... I.. T T

Cook Nuclear Plant Wastewater Flow Diagram GW1 810102 Makeup Plant detail Blowdown 1 x per day Neutralization Tank Acid/Caustic Regeneration Waste Makeup Plant Water to Plant Services

Cook Nuclear Plant Wastewater--flow diagram GW1810102 Sewage treatment plant detail Fire Protection (Flushing and testing water is directed to stormwater and/or groundwater)

Limestone Bed Neutralization Tank I

Wastes Portable Toilet

• Sequencing Batch Reactor or Miscellan.eous East Extended Rinsing operations Aeration Plant

SECTION 11 Waste Stream Narrative This narrative describes all outfalls discharging to Lake Michigan. Flows are based on a review of previous NPDES applications, Plant system descriptions, or previously submitted Discharge Monitoring Reports (DMR). The chemical additives described below may include a manufacturer's name as an example of the type of product used in a specific system. Indiana Michigan Power may substitute vendors of chemical additives provided that the chemical ingredients are similar. Discharge values are based on maximum release rates and volumes, dilution rates are based on a minimum number of pumps running.

OUTFALL 001 - Unit 1 Circulating Water Discharge Outfall 001 is a non-contact cooling water discharge. The majority of non-contact cooling water (Circulating Water System, -690,000 GPM) is used to condense the steam exhausting from steam driven turbines. Non-contact cooling water is drawn from Lake Michigan approximately one-half mile from shore through three 16 ft. diameter tunnels. Water enters the tunnels via intake cribs at an approximate velocity of 1.3 feet per second. The water enters to a forebay where it is screened to remove large debris that may be entrained in the-water. It is routed through the Unit I condensers and then discharged to Lake Michigan through a 16 foot diameter tunnel. The water exits the tunnels through high velocity discharges at a rate of approximately 13 feet per second approximately 1/4 mile from shore. Outfall 001 also includes internal Outfalls (as designated by the Michigan Department of Environmental Quality)

Steam Generator Blowdown (OOA, OOB), Plant Heating Boiler (OOC), Reverse Osmosis Unit (QOG), and the Turbine Room Sump Emergency Overflow (OOH) described in detail later in this document.

Outfall 001 also may contain the effluent flow from both Units' Essential Service Water (ESW) systems, both Units' Non-Essential Service Water (NESW) system, and monitor tank releases. ESW (-40,000 GPM) is Lake Michigan water taken from the forebay that is used to provide cooling to safety-related equipment. NESW (-18,000 GPM) is also Lake Michigan water taken from the forebay used for 1

non-contact cooling for various plant systems including oil coolers, a source of water for the demineralized makeup system (MIJP), and a water supply for non-safety related equipment. Monitor tank releases (-15,000 to 20,000 gallons per event) are regulated by the NRC and consist of wastewater from various system and equipment leakage that may be generated within the auxiliary building area.

Minor leakage from systems containing lube oil, hydrazine, carbohydrazide, ethanolamine or closed-loop cooling systems containing a maximum concentration of gluteraldehyde (100 ppm), methyl (bis) thiocyanate (10 ppm), tolyltriazole (60 ppm), Molybdate (1000 ppm), and nitrite (1200 ppm), may be discharged via monitor tank releases.

The non-contact cooling water for the Circulating Water, the ESW and the NESW, and Miscellaneous Sealing and Cooling Water Systems is treated for biological control using sodium hypochlorite. This same water is periodically treated using a non-oxidizing biocide to eradicate zebra mussels from the cooling systems. The biocides (Betz Spectrus CT-1300, Calgon H-130M, Calgon EVAC and NALCO Macro-Trol 9380) are polyquats, and are used as required to protect plant systems while meeting water quality based effluent limits. The treatments can be directed-to various critical plant systems from the intake structures through the entire plant cooling system, including the Circulating Water System, ESW and NESW systems and other non-contact cooling water. The biocide may be added to the systems via a chemical injection pipeline through a ring header located inside the intake crib, or directly applied at a specific system. A chemical injection pipeline may be installed and is designed to feed chemicals from inside the plant. The intake chemical injection header may be stored with chemical inside the pipe to prevent zebra mussel infestation. The header may also be leak checked using approved dyes such as fluorescein, or other indicators such as Nalco Trasar 23299. Non-contact cooling systems biocide treatments are dependent upon zebra mussel infestation. Concentrations and chemical feed points are chosen to minimize the amount of biocide required and to maximize the efficacy on zebra mussels.

Bentonite clay may be added to detoxify thebiocide prior to discharge. The plant non-contact cooling water systems may be treated concurrently or individually to allow more efficient use of chemicals. Plant systems are treated to assure safe operation of the nuclear generating units.

The piping used to apply chemicals is regularly cleaned of calcium carbonate scale buildup. A small

~:;.out- ","*k..... clcacr such as -1oQ1"stIct r r, "2700 may be uscd to rcr'mo cct rnulated carbonate scale deposits. The accumulated deposits will be discharged via Outfalls 001/003. Circulating water will dilute the weak acid prior to discharge to Lake Michigan.

2

Condensate flushes are performed periodically to purge the plant's secondary water system from layup chemistry specifications during shutdown conditions to startup chemistry specifications prior to startup of the unit. Water containing up to 4 ppm hydrazine [Betz Cortrol OS5035, Betz Cortrol OS5010, NALCO 19H], 10 ppm carbohydrazide (NALCO 1250 plus, or equivalent), 100 ppm ethanolamine (Betz Powerline 1440, Betz Powerline 1480, NALCO 92UM001), is overboarded to Outfall 001 as required to remove contaminants to meet desired startup secondary Chemistry specifications. This flowrate averages 70 GPM, but may reach 600 GPM for short periods of time. The flowrate is dependent on chemistry specification parameters and makeup water availability. The maximum output from the MUP is approximately 600 GPM or 864,000 GPD. (See Outfalls OOA, OOB for further description.)

Monitor tanks receive treated water from the auxiliary building radioactive waste removal system and other sources such as ice production and removal processes from the ice condenser systems and other radioactively contaminated wastes generated at the facility. This system handles wastes generated from the reactor coolant pump seal leakoffs, the refueling cavity water, equipment leaks, floor drains, valve stem leakoffs, system sampling, and waste sample solutions. It also handles laboratory wastes from the radiocheristry analysis in the hot chemical laboratory, system equipment drains, non-contact cooling water, ice production/removal and decontamination processes and any contaminated liquid waste.

generated in the auxiliary building area. The wastes are collected in one of several tanks and are treated when enough water is collected. The treatment utilizes a demineralizer system to minimize radioactive contaminants. A small amount of wastewater may bypass the treatment because it cannot be processed by resin.

Other special drains of non-radioactive process water systems such as Component Cooling Water system flushes with biocides such as gluteraldehyde (100 ppm), methyl (bis) thiocyanate (10 ppm), tolyltriazole (60 ppm), Molybdate (1000 ppm) and nitrite (1200 ppm), and borated icemaking/ice removal operations, can be routed directly to the plant's monitor tanks without treatment. For maintenance purposes to prevent microbial growth, Component Cooling Water flushes are performed generating approximately 281,000 gallons per year of flushwater to the monitor tanks.

Borated icemaking/ice removal operations occur for maintenance of the plant's ice condenser systems.

This process produces a solution of sodium tetraborate (approximately 2200 ppm as boron) that can be drained to the monitor tanks. This process takes place approximately every 18 months and may produce up to 70,000 gallons of sodium tetraborate solution.

3

Both the treated wastewater and the special drains are accumulated in the monitor tanks and sampled to ensure the waste meets the radiological requirements priorto being discharged into the Circulating Water System.

Periodically, due to equipment leaks and/or system upsets, a waste stream is generated that contains radioactively contaminated ethylene glycol and water. Incidental amounts of ethylene glycol generated from equipment leaks may be drained directly to the monitor tanks or treated by the radwaste processing system. Small amounts of ethylene glycol may be discharged to outfalls 001, 002, or 003.

Sulfur hexafluoride gas (SF6) is utilized in the non-contact cooling water systems at the plant to detect leaks in various components such as the condensers. The gas is injected in the cooling water stream and discharged to outfalls 001, 002 or 003 at less than 54 ul/l.

Aryl sulfate liquid (NALCO Trasar 23299) is utilized in the non-contact cooling water systems at the plant to determine flow through various parts of the system. The liquid is injected into the service water system to reach a target concentration of approximately 2 mg/I. The service water is discharged to Outfalls 001, 002, or 003, which would, in turn, discharge at less than 0.15 mg/L The liquid is also injected into the circulating water system to reach a target concentration of approximately 2 mg/I.

Control Room Air Conditioning (CRAC) testing: Approximately 1440 gallons/yr. of CRAC water may mix with ESW and then be discharged to the forebay during a monthly test of the system. CRAC water is demineralized water, and may contain up to: 2000 ppm nitrite [Calgon LCS 60, Betz Corrshield NT 4205, BETZ CORRSHTED NT 4201, Betz .Corrshield NT 4203, or equivalent], 100 ppm gluteraldehyde

[from Betz Biotrol 107 (Spectrus NX 1105), Calgon H-300, or equivalent], 60 ppm tolyltriazole [from Calgon LCS-60, Betz AZ8 101, Betz Corrshield NT 4205, BETZ CORRSHIED NT 4201, Betz Corrshield NT 4203, or equivalent], 10 ppm methyl (bis) thiocyanate (from Betz 3610), 1000 ppm molybdate from Betz Corrshield MD 4103, and Betz Ferroquest FQ7 101 and FQ7102 for CRAC HX cleaning.

4

. Three roadway storm drains route small amounts of stormwater from a small section of roadway that traverses over the Circulating Water Forebay. The three storm drains are designed to route accumulated stormwater from this small roadway to the forebay below. A small amount of de-icing compound used on this section of road could potentially enter these small (Approximately 8") gratings. Screened material collected from the plant's intakes is also stored in this area in designated trash dumpsters. Fish exudiates are now drained to the forebay as recommended by the MDEQ stormwater and NPDES inspection team (M. Fields and J. Molloy 1997).

During upset conditions it is possible to overflow the contents of the Turbine Room Sump (See Outfall 00H) to Outfalls 001, 002 and/or 003 if the flow path to the on-site absorption pond cannot be used.

OUTFALL 002 - Unit 2 Circulating Water Discharge Outfall 002 is a non-contact cooling water discharge. The majority of non-contact cooling water (Circulating Water System, -920,000 GPM) is used to condense the steam exhausting from steam driven turbines. Non-contact cooling water is drawn from Lake Michigan approximately one-half mile from shore through three 16 ft. diameter tunnels. Water enters the tunnels via intake cribs at an approximate velocity of 1.3 feet per second. The water enters to a forebay where it is screened to remove large debris that may be entrained in the water. It is routed through the Unit 2 condensers and then discharged to Lake Michigan through an 18 foot diameter tunnel. The water exits the tunnels through high velocity discharges at a rate of approximately 13 feet per second approximately 1/4 mile from shore. Outfall 002 also includes internal Outfalls (as designated by the Michigan Department of Environmental Quality)

• Steam Generator Blowdown (OA, OOB), Plant Heating Boiler (OOC), Reverse Osmosis Unit (OOG), and the Turbine Room Sump Emergency Overflow (OOH) described in detail later in this document.

Outfall 002 also may contain the effluent flow from both Units' Essential Service Water (ESW) systems, both Units' Non-Essential Service Water (NESW) system, and monitor tank releases. ESW (-40,000 GPM) is Lake Michigan water taken from the forebay that is used to provide cooling to safety-related equipment. NESW (-18,000 GPM)' is also Lake Michigan water taken from the forebay used for 5

non-contact cooling for various plant systems including oil coolers, a source of water for the demineralized makeup system (MUP), and a water supply for non-safety related equipment. Monitor tank releases (-15;000 to 20,000 gallons per event) are regulated by the NRC and consist of wastewater from various system and equipment leakage that may be generated within the auxiliary building area.

Minor leakage from systems containing lube oil, hydrazine, carbohydrazide, ethanolamine or closed-loop cooling systems containing a maximum concentration of gluteraldehyde (100 ppm), methyl (bis) thiocyanate (10 ppm), tolyltriazole (60 ppm), Molybdate (1000 ppm), and nitrite (1200 ppm), may be discharged via monitor tank releases.

The non-contact cooling water for the Circulating Water, the ESW and the NESW, and Miscellaneous Sealing and Cooling Water Systems is treated for biological control using sodium hypochlorite. This same water is periodically treated using a non-oxidizing biocide to eradicate zebra mussels from the cooling systems. The biocides (Betz Spectrus CT-1300, Calgon H-130M, Calgon EVAC and NALCO Macro-Trol 9380) are polyquats, and are used as required to protect plant systems while meeting water quality based effluent limits. The treatments can be directed to various critical plant systems from the intake structures thi-ough the entire plant cooling system, including the Circulating Water System, ESW and NESW systems and other non-contact cooling water. The biocide may be added to the systems via a chemical injection pipeline through a ring header located inside the intake crib, or directly applied at a specific system. A chemical injection pipeline may be installed and is designed to feed chemicals from inside the plant. The intake chemical injection header may be stored with chemical inside the pipe to prevent zebra mussel infestation. The header may also be leak checked using approved dyes such as fluorescein, or other indicators such as Nalco Trasar 23299. Non-contact cooling systems biocide treatments are dependent upon zebra mussel infestation. Concentrations and chemical feed points are chosen to minimize the amount of biocide required and to maximize the efficacy on zebra mussels.

Bentonite clay may be added to detoxify the biocide prior to discharge. The plant non contact cooling water systems may be treated at the concurrently or individually to allow more efficient use of chemicals.

Plant systems are treated to assure safe operation of the nuclear generating units.

The piping used to apply chemicals is regularly cleaned of calcium carbonate scale buildup. A small 07;oLnt of ..... acid c . 2So *+ Frm-oQ*._stFQ T *0n may

)scci .. o ......

+on ...... a carbonate scale deposits. The accumulated deposits will be discharged via Outfalls 002/003. Circulating water will dilute the weak acid prior to discharge to Lake Michigan.

6

Condensate flushes are performed periodically to purge the plant's secondary water system from layup.

chemistry specifications during shutdown conditions to startup chemistry specifications prior to startup of the unit. Water containing up to 4 ppm hydrazine [Betz Cortrol OS5035, Betz Cortrol OS5010,

-NALCO 19H], 10 ppm carbohydrazide (NALCO 1250 plus, or equivalent), 100 ppm ethanolamine (Betz Powerline 1440, Betz Powerline 1480, NALCO 92UM00 1), is overboarded to Outfall 002 as required to remove contaminants to meet desired startup secondary Chemistry specifications. This flowrate averages 70 GPM, but may reach 600 GPM for short periods of time. The flowrate is dependent on chemistry specification parameters and makeup water availability. The maximum output from the MUP is approximately 600 GPM or 864,000 GPD. (See Outfalls OOA, 00B for further description.)

Monitor tanks receive treated water from the auxiliary building radioactive waste removal system and other sources such as ice production and removal processes from the ice condenser systems and other radioactively contaminated wastes generated at the facility. This system handles wastes generated from the reactor coolant pump seal leakoffs, the refueling cavity water, equipment leaks, floor drains, valve stem leakoffs, system sampling, and waste sample solutions. It also handles laboratory wastes from the radiochemistry analysis in the hot chemical laboratory, system equipment drains, non-contact cooling water, ice production/removal and decontamination processes and any' contaminated liquid waste generated in the auxiliary building area. The wastes are collected in one of several tanks and are treated when enough water is collected. The treatment utilizes a demineralizer system to minimize radioactive contaminants. A small amount of wastewater may bypass the treatment because it cannot be processed by resin.

Other special drains of non-radioactive process water systems such as Component Cooling Water system flushes with biocides such as gluteraldehyde (100 ppm), methyl (bis) thiocyanate (10 ppm), tolyltriazole (60 ppm), Molybdate (1000 ppm) and nitrite (1200 ppm), and borated icemaking/ice removal operations, can be routed directly to the plant's monitor tanks without treatment. For maintenance purposes to prevent microbial growth, Component Cooling Water flushes are performed generating approximately 281,000 gallons per year of flushwater to the monitor tanks.

Borated icemaking/ice removal operations occur for maintenance of the plant's ice condenser systems.

This process produces a solution of sodium tetraborate (approximately 2200 ppm as boron) that can be drained to the monitor tanks. This process takes place approximately every 18 months and may produce up to 70,000 gallons of sodium tetraborate solution.

7

Both the treated wastewater and the special drains are accumulated in the monitor tanks and sampled to ensure the waste meets the radiological requirements prior to being discharged into the Circulating Water System.

Periodically, due to equipment leaks and/or system upsets, a waste stream is generated that contains radioactively contaminated ethylene glycol and water. Incidental amounts of ethylene glycol generated from equipment leaks may be drained directly to the monitor tanks or treated by the radwaste processing system. Small amounts of ethylene glycol may be discharged to outfalls 001, 002, or 003.

Sulfur hexafluoride gas (SF6) is utilized in the non-contact cooling water systems at the plant to detect leaks in various components such as the condensers. The gas is injected in the cooling water stream and discharged to outfalls 001, 002 or 003 at less than 54 ul/l.

Aryl sulfate liquid (NALCO Trasar 23299) is utilized in the non-contact cooling water systems at the plant to determine flow through various parts of the system. The liquid is injected into the service water.

system to reach a target concentration of approximately 2 mg/I. The service water is discharged to Outfalls 001, 002, or 003, which would, in turn, discharge at less than 0.15 mg/l. The liquid is also injected into the circulating water system to reach a target concentration of approximately 2 mg/l.

ControlRoom Air Conditioning (CRAC) testing: Approximately 1440 gallons/yr. of CRAC water may mix with ESW and then be discharged to the forebay during a monthly test of the system.. CRAC water is demineralized water, and may contain up to: 2000 ppm nitrite [Calgon LCS 60, Betz Corrshield NT 4205, BETZ CORRSHIED NT 4201, Betz Corrshield NT 4203, or equivalent], 100 ppm gluteraldehyde

[from Betz Biotrol 107 (Spectrus NX 1105), Calgon H-300, or equivalent], 60 ppm tolyltriazole [from CalgonLCS-60, Betz AZ8101, Betz Corrshield NT 4205, BETZ CORRSHIED NT 4201, Betz Corrshield NT 4203, or equivalent], 10 ppm.methyl (bis) thiocyanate (from Betz 3610), 1000 ppm molybdate from Betz Corrshield MD 4103, and Betz Ferroquest FQ7101 and FQ7102 for CRAC HX cleaning.

8

Three roadway stormdrains route small amounts of stormwater from a small section of roadway that.

traverses over the Circulating Water Forebay. The three storm drains are designed to route accumulated stormwater from this small roadway to the forebay below. A small amount of de-icing compound used on this section of road could potentially enter these small (Approximately 8") gratings. Screened material collected from the plant's intakes is also stored in this area in designated trash dumpsters. Fish exudiates are now drained to the forebay as recommended by the MDEQ stormwater and NPDES inspection team (M. Fields and J. Molloy 1997).

During upset conditions it is possible to overflow the contents of the Turbine Room Sump (See Outfall 00H) to Outfalls 001, 002 and/or 003 if the flow path to the on-site absorption pond cannot be used.

OUTFALL 003 - Deicing Discharge Outfall 003 is a deicing discharge which is used when water temperatures approach freezing temperatures. A portion of the flow from Outfall 001 and /or Outfall 002 is directed through the center intake tunnel to temper the intake water and prevent ice buildup on the intake structures which could restrict intake flow. The velocity at the other two intake structures during de-icing mode increases to approximately 1.9 feet per second. Discharge velocity will be less that 13 feet per second since a portion of the discharge is routed out the center intake tunnel.

The Essential and Non-Essential Service Water System (ESW and NESW) may be recirculated with a combination of Circulating Water Pumps in service to raise the forebay temperature to prevent frazil ice formation during cold weather periods. During shutdown conditions when normal operating heat addition is not available, portable heat addition units may be placed in the forebay to prevent frazil ice formations that may prevent flow to safety systems in the plant.

OUTFALL OOA - Unit I Steam Generator Blowdown The steam generators (part of the secondary water system) require ultra high purity water for operation.

Makeup water used in the steam generators is withdrawn from the intake forebay (or from Lake Township water supply or a blending of both sources) and treated so most natural impurities are removed through sedimentation, filtrationi, reverse osmosis, and demineralization. Impurities concentrate in the steam generators as the water is turned to steam and must be removed to protect the steam turbines and 9

heat transfer surfaces of the steam generators. The impurities are removed by continuously draining a portion of the water from the steam generators in a process called "blowdown".

In the steam generator, steam is separated from the water, further heated, and then routed to the turbines.

When the steam separates from'the water, the impurities remain in the water; concentrating in the steam generator. Blowdown consists of two forms, a liquid portion (700 gpm max) and a wet steam portion, which is exhausted to the atmosphere. The liquid portion of the steam generator blowdown is discharged to the screenhouse forebay either directly (Normal Flash Tank), or after processing through mixed beddemineralizers. Impurities in this discharge may consist of small quantities of insoluble iron and copper or impurities from the Circulating Water System used to cool the condensers should condenser tube leaks occur. Steam generator additives consist of ethanolamine (Betz Powerline 1440, Betz Powerline 1480, NALCO 92UM001)-for pH adjustment, hydrazine [Betz Cortrol OS5035, Betz Cortrol OS5010, NALCO 19H] and/or carbohydrazide (NALCO 1250 plus, or equivalent) for oxygen, scavenging.

When the units are not operating, .the steam generators are placed in wet layup conditions to protect against corrosion during storage. Layup water is periodically discharged through the outfall to. the Circulating Water Forebay. The layup water contains a maximum concentration of 400 ppm hydrazine

[Betz Powerline Cortrol OS5035, Betz Cortrol OS5010, NALCO 19H] and/or 40 ppm carbohydrazide (NALCO 1250 plus,-or equivalent), and /or 100 ppm ethanolamine (Betz Powerline. 1440, Betz Powerline 1480, NALCO 921JM00 1). The wvaste strength of this discharge is reduced through mixing with Outfalls 001, 002, or 003.

During the Sludge Lancing Process, demineralized water or secondary water is used to pressure clean.

the steam generators during outage periods. The water is recirculated through temporary filters. to remove entrained solids. The major constituent of the solids is iron oxide from the steam generators.

The water is then returned to the steam generators and can be drained to Outfalls OOA, OOB, to Outfall 001, 002, 003, OOD or 00H. The suspended solids are analyzed for radioactivity prior to disposal.

• ./.. 7 -iwi".5..

7 vuiO 1.

771 - u_5it1 7"1ei 22 Oteanli kj~entao ro~t~ftl.;*GG The steam generators (part of the secondary water system) require ultra high purity water for,operation.

Makeup water used in the steam generators is withdrawn from the intake forebay (or from Lake Township water supply or a blending of both sources) and treated somost natural impurities are removed 10*

through sedimentation, filtration, reverse osmosis, and demineralization. Impurities concentrate in the steam generators as the water is turned to steam and must be removed to protect the steam turbines and heat transfer surfaces of the steam generators. The impurities are removed by continuously draining a portion of the water from the steam generators in a process called "blowdown".

In the steam generator, steam is separated from the water, further heated, and then routed to the turbines.

When the steam separates from the water, the impurities remain in the water, concentrating in the steam generator. Blowdown consists of two forms, a liquid portion (700 gpm max) and a wet steam portion, which is exhausted to the atmosphere. The liquid portion of the steam generator blowdown is discharged to the screenhouse forebay either directly (Normal Flash Tank), or after processing through mixed bed-demineralizers. Impurities in this discharge may consist of small quantities of insoluble iron and copper or impurities from the Circulating Water System used to cool the condensers should condenser tube leaks occur. Steam generator additives consist of ethanolamine (Betz Powerline 1440, Betz Powerline 1480, NALCO 92UM001) for pH adjustment, hydrazine [Betz Cortrol OS5035, Betz Cortrol OS5010, NALCO 19H] and/or carbohydrazide (NALCO 1250 plus, or equivalent) for oxygen scavenging.

When the units are not operating, the steam generators are placed in wet layup conditions to protect against corrosion during storage. Layup water is periodically discharged through the outfall to the Circulating Water Forebay. The layup water contains a maximum concentration of 400 ppm hydrazine

[Betz Powerline Cortrol OS5035, Betz Cortrol OS5010, NALCO 19H] and/or 40 ppm carbohydrazide (NALCO 1250 plus, or equivalent), and /or 100 ppm ethanolamine (Betz Powerline 1440, Betz Powerline 1480, NALCO 92UM00 1). The waste strength of this discharge is reduced through mixing with Outfalls 001, 002, or 003.

During the Sludge Lancing Process, demineralized water or secondary water is used to pressure clean the steam generators during outage periods. The water is recirculated through temporary filters to remove entrained solids. The major constituent of the solids is iron oxide from the steam generators.

The water is then returned to the ste'am generators and can be drained to Outfalls OOA, OOB, to Outfall 001, 002, 003, 0OD or 0OH. The suspended solids are analyzed .for radioactivity prior to disposal.

1-1

OUTFALL OOC - Plant Heating Boiler A heating boiler (150,000 lb/hr capacity) operates to supply plant heating and auxiliary steam when Unit 1 and/or Unit 2 are out of service. The boiler is also fired periodically for testing purposes to ensure its availability.

During periods when not in operation, the heating boiler may be stored full of treated boiler water containing up to 400 ppm hydrazine [Betz Cortrol OS5035, Betz Cortrol OS5010, NALCO 19H] or 40 ppm carbohydrazide (NALCO 1250 plus, or equivalent) for oxygen scavenging and or 50 ppm ethanolarnine (Betz Powerline 1440, Betz Powerline 1480, NALCO 92UM001) for corrosion protection.

Prior to use, this "wet lay-up" water is drained to Outfall OOC via blowdown, which discharges to the intake forebay. The volume drained is approximately 600 gallons. This boiler may also be occasionally drained for maintenance activities, approximately 6,000 gallons of treated boiler water would be directed to Outfall 0OC or OOD/OOH for such purposes.

Impurities from the boiler water consisting primarily of insoluble iron and copper are discharged via blowdown (30 GPM) to the intake forebay during operation as needed for Chemistry control. Boiler water treatment additives consist of up to 15 ppm ethanolamine (Betz Powerline 1440, Betz Powerline 1480, NALCO 92UM001) for pH adjustment, up to 150 ppb hydrazine [Betz Cortrol OS5035, Betz Cortrol OS5010, NALCO 19H] and/or 150 ppb carbohydrazide (NALCO 1250 plus, or equivalent) for oxygen scavenging. /

Just after boiler shutdown, the boiler may be placed in dry layup. The boiler contents (up to 6,000 gallons) are drained via blowdown to the intake forebay. Boiler water treatment additives consist of up to 3 ppm ethanolamine (Betz Powerline 1440, Betz Powerline 1480, NALCO 92UM001) for pH adjustment and up to 150 ppb hydrazine [Betz Cortrol OS5035, Betz Cortrol OS5010, NALCO 19H]

and/or 150 ppb carbohydrazide (NALCO 1250 plus, or equivalent) for oxygen scavenging. The boiler is then dried out and stored empty. This process saves on chemicals and prevents unnecessary discharge of wet layup chemicals.

A smaller boiler may be installed to provide back-up heat if the permanent heating boiler was out of service. This back-up boiler may be located outdoors on the West Side of the turbine building. The blowdown line is directed to the Unit One forebay, near the same discharge point as the permanently installed heating boiler.

12

The same boiler treatment chemistry will be maintained in the back-up boiler as is used in the permanent heating boiler. The back-up boiler treatment additives consist of ethanolamine (Betz Powerline 1440, Betz Powerline 1480, NALCO 92UM001) for pH adjustment, and hydrazine [Betz Po'wverline Cortrol OS5035, Betz Cortrol OS5010, NALCO 19H] and/or carbohydrazide (NALCO 1250 plus, or equivalent) for oxygen scavenging. This boiler may be occasionally drained for maintenance activities, approximately 6,000 gallons of treated boiler water would be directed to Outfall 00C for such purposes.

Impurities from the boiler water consisting primarily of insoluble iron and copper are discharged via blowdown (30 GPM maximum) to the intake forebay during operation as needed for Chemistry control.

OUTFALL OOG - Reverse Osmosis System The Reverse Osmosis System (RO) is used to assist in the removal of dissolved solids from the lake water prior to demineralization. Reject water flow is directed to the forebay, which leads to Outfalls 001, 002, and 003. Reject water flow rates may reach up to 0.366 MGD. The RO system must maintain very clean membranes to assure efficient operation and purity of water. Several methods are used to maintain this level of cleanliness from scale and biofouling. Hydrochloric acidor sulfuric acid is fed at approximately 1.3 GPH continually when the RO is in service to lower the pH to reduce the scaling tendencies of the water. The reject water from the RO unit consists of concentrated Lake Michigan water and a small amount of acid that inhibits scale buildup in the membranes.

Approximately once per month, a flush is performed using approximately 1,000 gallons of a nominal 0.05% hydrochloric acid solution. This is followed with approximately 1,000 gallons of a nominal 0.1%

sodium hydroxide solution. This flush will dissolve any scale that deposits on the membranes. The total amount of flushing solution will average approximately 5,000 gallons per event. Sodium bisulfite is used to preserve the membranes during long-term shutdown periods: Approximately 15 lbs. of sodium bisulfite per year is used in this manner.

The chemical cleaning involves several steps and may contain citric acid, hydrochloric acid, phosphoric acid, sodium hydroxide, and a neutral pH detergent. The periodic cleaning process averages approximately 10,000 gallons per event, diverted either to the Turbine Room Sump (Outfall OOH/OOD),

through the Neutralization Tank to the Turbine Room Sump (Outfall OOH/OOD), or to the Circulating Water Forebay (Outfall 001, 002, or 003).

13

OUTFALL 00H - Turbine Room Sump Emergency Overflow Utility Wastewater from within the plant is discharged via the turbine room sump (TRS) into an on-site absorption pond (Outfall OOD). The normal disposition of these wastewaters is to an on-site absorption pond, which eventually vents via groundwater to Lake Michigan. In the unlikely event that the normal flow path to the absorption pond is not available, the overflow line (Outfall OOH) will direct the TRS flow to the plant's intake forebay. The wastewaters associated with this Outfall include:

Wastes from the makeup water treatment system.

• NESW: (144,000 GPD) The main contributor to this waste stream is the degassifier pump seal water.

Non-Essential Service Water (NESW) from Lake Michigan supplies the vacuum degassifier pumps which utilize up to 100 GPM to remove non-condensable gases (primarily carbon dioxide and oxygen) from the makeup plant water and exhausts them to the atmosphere.

Pre-filter backwash: (Estimated 98,000 GPD) Six pre-filters are backwashed with Lake Michigan water to remove the suspended matter captured on the filter media. Alum solution (aluminum sulfate 0.5 lb. per gallon) is added to the pre-filter influent as a flocculent. The alum is added via a coagulant feed pump. Approximately 50 lb./day of alum is used in this process. The alum contained in the backwash is discharged in the form of insoluble aluminum hydroxide.

Carbon filter backwash: (Estimated 42,000 GPD) Carbon filters are periodically backwashed with Lake Michigan water to the TRS. These filters primarily remove organics, chlorine and small amounts of iron.

• Demineralizerregeneration: (Estimated 50,000 gallons per regeneration) occurs 2-4 times per month when the RO is in service and more often when it is not in service. Dilute sulfuric acid and sodium hydroxide used by the system to regenerate the resin. Dilute sulfuric acid, sodium hydroxide, and contaminates from the demineralization process is discharged to the neutralization tank or TRS.

The pH is then adjusted to between 5.5 and 9.0 with suifuric acid, or sodium hydroxide prior to discharge.

• MJJP Neutralization Tank provides a place for demineralization regenerationwastes, and Reverse Osmosis Unit cleaning flushes to be neutralized prior to being discharged to the TRS and ultimately 14

the absorption pond. When the MUP resin beds are regenerated, up to 50,000 gallons of regeneration chemicals, and backwash waters are processed in the neutralization tank. The Reverse Osmosis cleaning flushes average approximately 5,000 gallons pet event. When the water is neutralized, it is pumped to the TRS via a 2,000 GPM neutralization waste pump.

" The Retention Tank is periodically blown down, discharging small volumes of solid material removed by settling. The retention tank contains a mixture of Lake Township water and filtered Lake Michigan water waiting further processing by the Makeup Plant.

" The Reverse Osmosis System (RO) Cleaning. Normal reject water flow is to Lake Michigan via Outfall 00G. The RO system must maintain very clean' membranes to assure efficient operation and purity of water. Several methods are used to maintain this level of cleanliness from scale and biofouling. Hydrochloric acid or sulfuric acid is fed at approximately 1.3 GPH continually when the RO is in service to lower the pHto reduce the scaling tendencies of the water. The reject water from the RO unit consists of concentrated Lake Michigan water and a small amount of acid that inhibits scale buildup in the membranes.

(

Approximately once per month, a flush is performed using approximately 1,000 gallons of a nominal 0.05% hydrochloric acid solution. This is followed with approximately 1,000 gallons of a nominal 0.1% sodium hydroxide solution.. This flush will dissolve any scale that deposits on the membranes.

The total amount of flushing solution will average approximately 5,000 gallons per event. Sodium bisulfite is used to preserve the membranes during long-term shutdown periods. Approximately 15 lbs. of sodium bisulfite per year is used in this manner.

The chemical cleaning involves several steps and may contain citric acid, hydrochloric acid, phosphoric acid, sodium hydroxide, and a neutral pH detergent. The periodic cleaning process averages approximately 10,000 gallons per event, diverted either to the Turbine Room Sump (Outfall OOH), through the Neutralization Tank to the Turbine Room Sump (Outfall OOH), or to the Circulating Water Forebay (Outfall 001, 002, or 003).

Waste from miscellaneous processes.

• During periods when not in operation, the heating boiler may be stored full of treated boiler water containing at most 400 ppm hydrazine [Betz Cortrol OS5035, Betz Cortrol OS5010, NALCO 19H] or 40 ppm carbohydrazide (NALCO 1250 plus, or equivalent) for oxygen scavenging and/or 50 ppm 15

• ethanolamine (Betz Powerline 1440, Betz Powerline 1480, NALCO 92UM001) for corrosion protection. Prior to use, this "wet lay-up" water is drained to the TRS. The volume drained is approximately 600 gallons.

The Circulating Water System cooling water contained in the condensers during shutdowns are periodically drained to the TRS. (Six condenser halves and 2 feedpump condensers, approximately 37,000 gallons of lake water per half).

The Component Cooling Water system (CCW) is periodically drained to allow for equipment inspection, maintenance or repair. This system uses demineralized water from the makeup plant as its source of makeup water along with a maximum of: 1200 ppm nitrite [from Calgon LCS 60, Betz Con-shield NT 4205, BETZ CORRSHIED NT 4201, Betz Corrshield NT 4203, or equivalent],. 100 ppm gluteraldehyde [from Betz Spectrus NX 1105, Calgon H-300, or equivalent], methyl (bis) thiocyanate (10 ppm) [from Betz 3610 or equivalent], 60 ppm tolyltriazole (from Betz AZ8101, Calgon LCS-60, or equivalent) ), 1000 ppm molybdate from Betz Corrshield MD 4103. The infrequent drainings release approximately 60,000 gallons of treated water to the TRS per year.

There are four Emergency Diesel Generators that are each cooled by an Emergency Diesel Generator cooling jacket water system (DJW), which employs chemical control for corrosion with a maximum of 2000 ppm nitrite [Calgon LCS 60 or Betz Corrshield NT 4205, BETZ.

CORRSHIED NT 4201, Betz Corrshield NT 4203 or equivalent], 100 ppm gluteraldehyde. [Betz Spectrus NX 1105, Calgon H-300, or equivalent], methyl (bis) thiocyanate (10 ppm) [from Betz 3610 or equivalent], 60 ppm tolyltriazole [Betz AZ8101, Calgon LCS-60, or equivalent]), 1000 ppm.

molybdate from Betz Corrshield MD 4103.

This system is drained through the floor drains to the TRS when maintenance is performed.. Each' system volume is approximately 1000 gallons. Any system leaks would also be directed to the floor drain during normal operations.

• Control Room Air Conditioning (CRAC) drains: Approximately 1440 gallons/yr. o0C(RAt. water is drained to the TRS. CRAC Water is demineralized water, and may contain up to: 2000 ppm nitrite

[Calgon LCS 60, Betz Corrshield NT 4205, BETZ CORRSHIED NT 4201, Betz Corrshield NT 4203 or equivalent], 100 ppm gluteraldehyde [Betz Spectrus NX 1105, Calgon H-300, or equivalent],

methyl (bis) thiocyanate (10 ppm) [from Betz 3610 or equivalent], 60 ppm tolyltriazole (Calgon 16

LCS-60, Betz AZ8101, or equivalent) ), 1000 ppm molybdate from Betz Corrshield MD 4103, and Betz Ferroquest FQ7101 and FQ7102 for CRAC I-X cleaning. The system may be flushed with demineralized water, and when completed, corrosion control chemicals will be added back to the system. No additions of corrosion controlling chemicals are performed during the demineralized water flush.

The Essential Service Water. systems (ESW) and Non-Essential Service Water systems (NESW) are also periodically drained to allow for equipment inspection, maintenance, or repair. These drains may discharge Lake Michigan water used for non-contact cooling into the TRS. This water may be chlorinated for zebra mussel control. During some special treatment periods, this water may contain zebra mussel biocides, used as a molluscicide for zebra mussel control. Periodically, components of the ESW or NESW systems may be chemically cleaned to remove iron deposits using vendor supplied cleaning solution such as EDTA (ethylenediaminetetraacetic acid) or ascorbic acid, acetic acid and ammonia. These wastes could either be drained to the TRS or Lake Michigan via Outfall 001,002, or 003.

During wet lay-up, the steam generators are stored full of water with up to 400 ppm of hydrazine from Betz Cortrol OS5035, Betz Cortrol OS 5010, NALCO 19H or 40 ppm carbohydrazide (NALCO 1250 plus, or equivalent) and 100 ppm ethanolamine (Betz Powerline 1440, Betz Powerline 1480, NALCO 92UM001) are added for corrosion control. Thewater may also contain up to 20 ppm boron. This water is normally drained to surface water via NPDES Outfalls O0A or 00B, but may be drained to the TRS in some instances. Drain volume will be approximately 32,000 gallons for each of the unit's four steam generators.

• The Miscellaneous Drain Tanks can be aligned to discharge to the TRS. As much as 350,000 gallons per day per unit may be directed to the TRS to control the chemistry limitations on the secondary water systems. Water chemistry is primarily the same as in the steam generators. This type of batch drain occurs in concert with condensate flushing activities, or it may occur during normal operation to adjust system chemistry. The overboarded water is normal secondary water. It may contain a mixture of ethanolamine, hydrazine [Betz Cortrol OS5035, Betz Cortrol OS5010, NALCO 19H], or carbohydrazide (NALCO 1250 plus, or equivalent). Maximum flows may approach 240 GPM as makeup plant water supplies can deliver.

17

Condensate flushes are performed periodically to clean up the plant's secondary system prior to startup, and can be discharged to the TRS. Water containing up to 4 ppm hydrazine [Betz Cortrol OS5035, Betz Cortrol OS5010, NALCO 19H], 10 ppm carbohydrazide (NALCO 1250 plus, or equivalent), .100 ppm ethanolamine (Betz Powerline 1440, Betz Powerline 1480, NALCO 92UM00 1), is overboard to the TRS as required to remove contaminants. This flow rate averages 70 GPM, but may reach 600. GPM for short periods of time. The flow rate is dependent on water demands in the plant. Maximum output from the MUP is approximately 600 GPM.

Around the plant, miscellaneous sumps collect an estimated 45,000 GPD of water from various equipment drains (ESW pipe tunnel sump). Water and condensate leaks from valves and pumps (Circulating Water condenser pit sumps, ESW pipe tunnel sump, heater drain pump room sump, screen wash pump room sump, acid and caustic room sumps, elevator pit sumps, screenhouse electrical equipment enclosure sump) will also be drained to the TRS. Steam jet air ejector drains also are directed to the heater drain pump room sump prior to pumping to the TRS. Betz FerroQuest FQ LP 7200 may be added to this sump to prevent scale buildup.

Miscellaneous floor drains are located throughout the plant to provide a safe working environment by routing spilled or leaked water to the TRS. The major chemical influx into these drains is from general floor cleaning products used to maintain the floors. Also routed to the TRS through the floor drains are fire protection water, chlorinated Lake Township water, drinking water, cooling water (ESW/NESW), and drains from bioboxes used to monitor the zebra mussel control measures and other chemical control monitors. The bioboxes will discharge chlorine and zebra mussel biocides during periods when 'the Service Water Systems are treated with previously mention biological control agents.

Chemical feed tank drains (drains are limited to emergencies only). There are eight chemical feed tanks that are approximately 200 gallons each that contain hydrazine [Betz Cortrol OS5035, Betz Cortrol OS5010, NALCO 19H] at approximately 2%, ethanolamine (Betz Powerline 1440, Betz Powerline 1480, NALCO 92UM001), at approximately 5%, carbohydrazide (NALCO 1250 plus, or equivale~t), apploxifaticly Y%.*Normal process Will beOtoýilet these .

iaLK Oh1mcS to hC icus".

whenever possible.

18

Chemical cleaning tank drains: During refueling and maintenance outages, the chemical cleaning tank, and or temporary tanks may be used to mix borax (sodium tetraborate @ approximately 2000 ppm as boron) solutions f6r ice making operations. Small portions of the system may be drained to the TRS. In the unlikely event that a full tank is drained, approximately 3500 gallons will be directed to the TRS.

Non-radiological chemical lab sink and floor drains are routed to the TRS for disposal. The drains carry water and the wastes generated while performing analyses and preparing laboratory standard including those on the attached list. Also discharged will be glassware. cleaning and normal laboratory cleaning wastes. The average volume directed to the TRS is estimated'to be 500 -1000 GPD.

Secondary sample water from continuous analyzers are routed to drains which discharge to the TRS and/or the miscellaneous drain tank. The analyzers are on the cycles that may contain as much as 150 ppb hydrazine from either a direct feed or (as a breakdown product of carbohydrazide, and 2.5 ppm ethanolamine). The analyzers measure corrosion transport at an average flow of 1440 gallons per day when in operation.

y Miscellaneous sealing and cooling water (MSCW) supplies cooling and sealing water to the TRS pumps, Condensate Booster Pumps, Circulating Water Pumps, Vacuum Priming Pumps, Drain Seal Reservoir Tanks, MSCW pump sealing water, screen wash pumps sealing water, and Drain Sample Coolers. The flow per day may reach approximately 576,000 gallons; this water is filtered and chlorinated Lake Michigan water.

o Non-essential service water supplies approximately 53,000 GPD of non-contact cooling water to various sample coolers throughout the plant's turbine building.

19

Chemical spills that enter the TRS may be neutralized within the sump to prevent a discharge to the environment. The potential for spills to the TRS exists for the following chemicals with the proposed neutralizers listed:

Chemical Associated Neutralizer Sulfuric acid Sodium hydroxide Sodium hydroxide Sulfuric acid Sodium hypochlorite Sodium thiosulfate Hydrazine NESW (lake water), Hydrogen peroxide, sodium hypochlorite.

Ethanolamine Sodium Hypochlorite, Hydrogen Peroxide, or ozone.

Ethylene glycol Hydrogen peroxide Reduction of hydrazine and ETA prior to discharge to the absorption pond may include additions of chemicals such as sodium hypochlorite, hydrogen peroxide, or ozone to the Turbine Room Sump in batches, or to the discharge piping as continuous treatment. A downstream treatment system provided by a vendor may be used to break down the hydrazine and ETA.

20

ADDITIONAL CHEMICAL LAB ANALYSES Additional Information Section I Item 11 Donald C. Cook Nuclear Plant Surface Water Permit Application Plant Chemistry Lab (To Outfall OOH/OOD)

Laboratory sink drains from the 633' Turbine lab are directed to the 90,000 gallon Turbine Room Sump.

The sump contents are normally directed to the groundwater discharge (outfall OOD). Occasionally the Emergency by-pass may be utilized and the sump's contents will be discharged to the surface water discharge (outfall OOH). The following analyses are performed in the lab. Laboratory wastes from the analyses are discarded in the sink.

Parameter Analysis Method Nitrite HACH DR-2000 Method 373, HACH DR 2010 Method 373 Hydrazine ASTM D-1385 -88 Oil and Grease EPA-600-4-79-020 Method 413.1 pH Standard Methods for the examination of Water and Wastewater, ASTM-1293 Total Phosphorus EPA-600-4-79-020 Method 365.3 Sulfate EPA-600-4-79-020 Method 375.4 Total Residual Chlorine EPA-600-4-79-020 Method 330.5 Ethanolamine (ETA) Betz Standard Operating Procedure. (Betz proprietary Method adapted from HACH Dr-2000 1,2- Naphthoguinone-4-sulfonic acid Method.)

ICP Metals Standard Methods for Examination of water and wastewater - 17t" ed. 1989, 3120B.

Tolyltriazole HACH DR-2000 Method 730 Carbohydrazide HACH DR-2000 Method 732 HACH DR-2010 Method 182 N,N Diethylhyroxylamine (DEHA) HACH DR-20 10 Method 182 Silica ASTM D 859-88 L

21

GROUNDWATER DISCHARGES OUTFALL 0OD - Turbine Room Sump Utility wastewater from within the plant is discharged via the turbine room sump (TRS) into an on-site absorption pond (Outfall 0OD). The normal disposition of these wastewaters is to an on-site absorption pond, which eventually vents via groundwater to Lake Michigan. In the unlikelyev'ent that the normal flow path to the absorption pond is not available, the overflow line (Outfall 00H) will direct the TRS flow to the plant's intake forebay. The wastewaters associated with this Outfall include:

Wastes from the makeup water treatment system.

• NESW: (144,000 GPD) The main contributor to this waste stream is the degassifier pump seal water.

Non-Essential Service Water (NESW) from Lake Michigan supplies the vacuum degassifier pumps which utilize up to 100 GPM to remove non-condensable gases (primarily carbon dioxide and oxygen) from the makeup plant water ard exhausts them to the atmosphere.

• Pre-filter backwash: (Estimated 98,000 GPD) Six pre-filters are backwashed with Lake Michigan water to remove the suspended matter captured on the filter media. Alum solution (aluminum sulfate 0.5 lb. per gallon) is added to the pie-filter influent as a flocculent. The alum is added via a coagulant feed pump. Approximately 50 lb./dayof alum is used in this process. The alum contained in the backwash is discharged in the form of insoluble aluminum hydroxide.

• Carbon filter backwash: (Estimated 42,000 GPD) Carbon filters are periodically backwashed with Lake Michigan water to the TRS. These filters primarily remove organics, chlorine and small amounts of iron.

Demineralizer regeneration: (Estimated 50,000 gallons per regeneration) occurs 2-4 times per month when the RO is in service and more often when it is not in service. Dilute sulfuric acid and sodium hydroxide used by the*'ystem to regenerate the resin. Dilute sulfuric acid, sodium hydroxide, and contaminates Irorn the cien'tineralization process is discharged. to the neutraiization tank or r.-3 The pH is then adjusted to between 5.5 and 9.0 with sulfuric acid, or sodium hydroxide prior to discharge.

22

MUP Neutralization Tank provides a place for demineralization regeneration wastes, and Reverse Osmosis Unit cleaning flushes to be neutralized prior to being discharged to the TRS and ultimately, the absorption pond. When the MUP resin beds are regenerated, up to 50,000 gallons of regeneration chemicals, and backwash waters are processed in .the neutralization tank. The Reverse Osmosis cleaning flushes average approximately 5,000 gallons per event. When the water is neutralized, it is pumped to the TRS via a 2,000 GPM neutralization waste pump.

• The Retention Tank is periodically blown down, discharging small volumes of solid material removed by settling. The retention tank contains a mixture of Lake Township water and filtered Lake Michigan water waiting further processing by the Makeup Plant.

The Reverse Osmosis System (RO) Cleaning. Normal reject water flow is to Lake Michigan via Outfall 00G. The PO system must, maintain very clean membranes to assure efficient operation and purity of water. Several methods are used to maintain this level of cleanliness from scale and biofouling. Hydrochloric acid or sulfuric acid is fed at approximately 1.3 GPH continually when. the RO is in service to lower the pH to reduce the scaling tendencies of the water. The reject water from the RO unit consists of concentrated Lake Michigan water and a small amount of acid that inhibits scale buildup in the membranes.

Approximately once per month, a flush is performed using approximately 1,000 gallons of a nominal 0.05% hydrochloric acid solution. This is followed with approximately 1,000 gallons of a nominal 0.1% sodium hydroxide solution. This flush will dissolve any scale that deposits on the membranes.

The ,total amount of flushing solution -will average approximately 5,000 gallons per event. Sodium bisulfite is used to preserve the membranes during long-term shutdown periods. Approximately 15 lbs. of sodium bisulfite per year is used in this manner.

The chemical cleaning involves several steps and may contain citric acid, hydrochloric acid, phosphoric acid, sodium hydroxide, and a neutral pH detergent.' The periodic cleaning process averages approximately 10,000 gallons per event, diverted either to the Turbine Room Sump (Outfall OOH), through the Neutralization Tank to the Turbine Room Sump (Outfall OOH), or to the CirculatingWater Forebay (Outfall 001, 002, or 003).

23

Waste from miscellaneous processes.,

During periods when not in operation, the heating boiler. may be stored full of treated boiler water containing at most 400 ppmhydrazine [Betz Cortrol OS5035, Betz Cortrol OS5010, NALCO 19H] or 40 ppm carbohydrazide (NALCO 1250 plus, or equivalent) for oxygen scavenging and/or 50 ppm ethan olarmine (Betz Powerline 1440, Betz Powerline 1480,'NALCO 92UM001) for corrosion protection. Prior to use, this "wet lay-up" water is drained to the TRS. The volume drained is approximately 600 gallons.

• The Circulating Water System cooling water contained in the condensers during shutdowns are periodically drained to the TRS. (Six condenser halves and. 2 feedpump condensers, approximately 3.7,000 gallons of lake water per half).

The Component Cooling Water system (CCW) is periodically drained to allow for equipment inspection, maintenance or repair. This system uses demineralized water from the makeup plant as its source of makeup water along with a maximum of: 1200 ppm nitrite [from Calgon LCS 60, Betz Corrshield NT 4205, BETZ CORRSHIED NT 4201, Betz Corrshield NT 4203, or equivalent], 100 ppm gluteraldehyde [from Betz Spectrus NX 1105, Calgon H-300, or equivalent], methyl (bis) thiocyanate (10 ppm) [from Betz 3610 or equivalent], 60 ppm tolyltriazole (from Betz AZ. 101, Calgon LCS-60, or equivalent) ), 1000 ppm molybdate from Betz Corrshield MD 4103. The infrequent drainings release approximately 60,000 gallons of treated water to the TRS per year.

There are four Emergency Diesel Generators that are each cooled by an Emergency Diesel' Generator cooling jacket water system (DJW), which employs chemical control, for corrosion with a maximum of 2000 ppm nitrite [Calgon LCS 60 or Betz Corrshield NT.4205, BETZ CORRSHIED NT 4201, Betz Corrshield NT 4203 or equivalent], 100 ppm gluteraldehyde [Betz Spectrus NX 1105, Calgon H-300, or equivalent], methyl (bis) thiocyanate (10 ppm) [from Betz 3610 or equivalent], 60 ppm tolyltriazole [Betz AZ 101, Calgon LCS-60, or equivalent]), 1000 ppm molybdate from Betz Corrshield MD 4i03.

SySLr JraiU.W; ~L-UUý1 ý1 U. "icidrLyL,-

system volume is approximately 1000 gallons. Any system leaks would also be directed to the floor drain during normal operations.

24

Control Room Air Conditioning (CRAC) drains: Approximately 1440 gallons/yr. of CRAC water is drained to the TRS. CRAC Water is demineralized water, and may contain up to: 2000 ppm nitrite

[Calgon LCS 60, Betz Corrshield NT 4205, BETZ CORRSHIED NT 4201, Betz Corrshield NT 4203 or equivalent], 100 ppm gluteraldehyde [Betz Spectrus NX 1105, Calgon H-300, or equivalent],

methyl (bis),thiocyanate (10 ppm) [from Betz 3610 or equivalent], 60 ppm tolyltriazole (Calgon LCS-60, Betz A28101, or equivalent) ), 1000 ppm molybdate from Betz Corrshield MD 4103, and Betz Ferroquest FQ7101 and FQ7102 for CRAC HX cleaning. The system may be flushed with demineralized water, and when completed, corrosion control chemicals will be added back to the system. No additions of corrosion controlling chemicals are performed during the demineralized water flush.

The Essential Service Water systems (ESW) and Non-Essential Service Water systems (NESW) are also periodically drained to allow for equipment inspection, maintenance, or repair. These drains may discharge Lake Michigan water used for non-contact cooling into the TRS. This water may be chlorinated for zebra mussel control. During some special treatment periods, this water may contain zebra mussel biocides, used as a molluscicide for zebra mussel control. Periodically,, components of the ESW or NESW systems may be chemically cleaned to remove iron deposits using vendor supplied cleaning solution such as EDTA (ethylenediaminetetraacetic acid) or ascorbic, acid, acetic acid and ammonia. These wastes could either be drained to the TRS or Lake Michigan via Outfall 001, 002, or 003.

During wet lay-up, the steam'generators are stored full of water with up to 400 ppm of hydrazine from Betz Cortrol OS5035, Betz Cortrol OS5010, NALCO 19H or 40 ppm carbohydrazide (NALCO 1250 plus, or equivalent) and 100 ppm ethanolamine (Betz Powerline 1440, Betz Powerline 1480, NALCO 92UM001) are added for corrosion control. The water may also contain up to 20 ppm boron. This water is normally drained to surface water via NPDES Outfalls OOA or,O0B, but may be drained to the TRS in some instances. Drain volume will be approximately 32,000 gallons for each of the unit's four steam generators.

The Miscellaneous Drain Tanks can be aligned to discharge to the TRS. As much as 350,000 gallons per day per unit may be directed to the TRS to control the chemistry limitations on the secondary water systems. Water chemistry is primarily the same as in the steam generators. This type of batch drain occurs in concert with condensate flushing activities, or it may occur during normal operation to adjust system chemistry. The overboarded water is normal secondary water. It 25

may contain a mixture of ethanolamine, hydrazine [Betz Cortrol OS5035, Betz Cortrol OS5010, NALCO 19H], or carbohydrazide (NALCO 1250 plus, or equivalent). Maximum flows may approach 240 GPM as makeup plant water supplies can deliver.

Condensate flushes are performed periodically to clean up the-plant's secondary system prior to startup, and can be discharged to the TRS. Water containing up to 4 ppm hydrazine [Betz Cortrol OS5035, Betz Cortrol OS5010, NALCO 19H], 10 ppm carbohydrazide (NALCO 1250 plus, or equivalent), 100 ppm ethanolamine (Betz Powerline 1440, Betz Powerline 1480, NALCO 92UM001), is oyerboard to the TRS as required to remove contaminants. This flow rate averages 70 GPM, but may reach 600 GPM for short periods of time. The flow rate is dependent on water demands in the plant. Maximum output from the MUP is approximately 600 GPM.

Around the plant, miscellaneous sumps collect an estimated 45,000 GPD of water from various equipment drains (ESW pipe tunnel sump). Water and condensate leaks from valves and pumps (Circulating Water condenser pit sumps, ESW pipe tunnel sump, heater drain pump room sump, screen wash pump room sump, acid and caustic room sumps, elevator pit sumps, screenhouse electrical equipment enclosure sump) will also be drained to the TRS. Steam jet air ejector drains also are directed to the heater drain pump room sump prior to pumping to the TRS. Betz FerroQuest FQ LP 7200 may be added to this sump to prevent scale buildup.

Miscellaneous floor drains are located throughout the plant to provide a safe working environment by routing spilled or leaked water to the TRS. The major chemical influx into these drains is from general floor cleaning products used to maintain the floors. Also routed to the TRS through the floor drains are fire protection water, chlorinated. Lake Township water, drinking water, cooling water (ESW/NESW), and drains from bioboxes used to monitor the zebra mussel control measures and other chemical control monitors. The bioboxes will discharge chlorine and zebra mussel biocides during periods when the Service Water Systems are treated with previously mention biological control agents.

C~cicatr~kdrcis fod drans re imfed tc emergencies on!:). Thrare ý eigt; e+i&fe tanks that are approximately 200 gallons each that contain hydrazine [Betz Cortrol 0S5035, Betz Cortrol OS5010, NALCO 19H] at approximately 2%, ethanolamine (Betz Powerline 1440, Betz Powerline 1480, NALCO 92UM00 I), at approximately 5%, carbohydrazide (NALCO 1250 plus, or 26

equivalent), approximately 2%. Normal process will be to collect these tank volumes to be reused whenever possible.

Chemical cleaning tank drains: During refueling and maintenance outages, the 'chemical cleaning tank, and or temporary tanks may be used to mix borax (sodium tetraborate @ approximately 2000 ppm as boron) solutions for ice making operations. Small portions of the system may be drained to the TRS. In the unlikely event that a full tank is drained, approximately 3500 gallons will be directed to the TRS.

Non-radiological chemical lab sink and floor drains are routed to the TRS for disposal. The drains carry. water and the wastes generated while performing analyses and preparing laboratory standards including those on the attached list. Also discharged will be glassware cleaning and normal laboratory cleaning wastes. The average volume directed to the TRS is estimated to be 500 -1000 GPD.

Secondary sample water from continuous analyzers are routed to drains which discharge to the TRS and/or the miscellaneous drain tank. The analyzers are on the cycles that may contain as much as 150 ppb hydrazine from either a direct feed or (as a breakdown product of carbohydrazide, and 2.5 ppm ethanolamine). The analyzers measure corrosion transport at an average flow of 1440 gallons per day when in operation.

Miscellaneous sealing and cooling water (MSCW) supplies cooling and sealing water to the TRS pumps, Condensate Booster Pumps, Circulating Water Pumps, Vacuum Priming Pumps, Drain Seal Reservoir Tanks, MSCW pump sealing water, screen wash pumps sealing water, and Drain Sample Coolers. The flow per day may reach approximately 576,000 gallons; this water is filtered and chlorinated Lake Michigan water.

Non-essential service water supplies approximately 53,000 GPD of non-contact cooling water to various sample coolers throughout the plantis turbine building.

27

Chemical spills that enter the TRS may be neutralized within the sump to prevent a discharge to the environment. The potential for spills to the TRS exists for the following chemicals with the proposed neutralizers listed:

Chemical Associated Neutralizer Sulfuric acid / Sodium hydroxide Sodium hydroxide Sulfuric acid Sodium hypochlorite Sodium thiosulfate Hydrazine NESW (lake water), Hydrogen peroxide, sodium hypochlorite.

Ethanolamine Sodium Hypochlorite, Hydrogen Peroxide, or ozone.

Ethylene glycol Hydrogen peroxide Reduction of hydrazine and ETA prior to discharge to the absorption pond may include additions of chemicals such as sodium hypochlorite, hydrogen peroxide, or ozone to the Turbine Room Sump in batches, or to the discharge piping as continuous treatment. A downstream treatment system providedby a vendor may be used to break down the hydrazine and ETA.

28

ADDITIONAL CHEMICAL LAB ANALYSES Additional Information Section I Item 11 Donald C. Cook Nuclear Plant Surface Water Permit Application Plant Chemistry Lab (To Outfall OOH/OOD)

Laboratory sink drains from the 633' Turbine lab are directed to the 90,000 gallon Turbine Room Sump.

The sump contents are normally directed to the groundwater discharge (outfall OOD). Occasionally the Emergency by-pass may be utilized and the sump's contents will be discharged to the surface water discharge (outfall OOH). The following analyses .are performed in the lab. Laboratory wastes from the analyses are discarded in the sink.

Parameter Analysis Method Nitrite HACH DR-2000 Method 373,

.HACH DR 2010 Method 373 Hydrazine ASTM D-1385 -88 Oil and Grease EPA-600-4-79-020 Method 413.1 pH Standard Methods for the examination of Water and Wastewater, ASTM-1293 Total Phosphorus EPA-600-4-79-020 Method 365.3 Sulfate. EPA-600-4-79-020 Method 375.4 Total Residual Chlorine EPA-600.-4-79-020 Method 330.5 Ethanolamine (ETA) Betz*Standard Operating Procedure. (Betz.

proprietary Method adapted from HACH Dr-2000 1,2- Naphthoguinone-4-sulfonic acid Method).

ICP Metals Standard Methods for Examination of water and wastewater - 17th ed. 1989, 3120B.

Tolyltriazole HACH DR-2000 Method 730 Carbohydrazide HACH DR-2000 Method 732 HACH DR-2010 Method 182 N,N Diethylhyroxylamine (DEHA) HACH DR-2010 Method 182 Silica ASTM D 859-88 OUTFALL OOE - Sanitary Waste Discharges The system operates at a designed flow of 50,000 GPD with a maximum flow capacity of 60,000 GPD.

The Sequencing Batch Reactor (SBR) system treats the wastewater and discharges to an effluent tank where it can be filtered prior to discharge to one of two seepage lagoons. The lagoons discharge into the groundwater with the ultimate disposition venting to Lake Michigan. The sludge remoyed from the digester tank basins is taken to a local POTW (public owned treatment works) for disposal or dewatered and stored as low level radioactive waste, and'disposed of as appropriate.

29

To aid in the settling process, flocculents such as ferric chloride, pH controllers such as magnesium hydroxide, or polymers (such as Axchem AF4500) are added to the process. To selectively enhance biosolids, bioaugmentation nutrients (such as Bioprime Dosfolat) are added to the process. This is a nutrient that encourages the growth of beneficial microbes in the activated sludge. Sodium hypochlorite is added in small amounts to the process to control filamentous bacteria growth if needed. Sodium hypochlorite and detergent are also added to the sand filters to clean them periodically. These are then backwashed into the equalization basin to be reprocessed by the SBR treatment process.

Plant sanitary waste consists of shower and rest room facilities, and janitor washbasins located throughout the Plant's non-radiological property. Kitchen wastes are generated from the plant cafeteria, the Cook Energy Information Center and Training buildings.

The chemistry training laboratory discharges to the sewage treatment plants through a limestone bed neutralization tank. The chemistry lab is used to train technicians on analyses performed in the plant..

The discharge from the lab carries water and wastes generated while performing analyses and preparing laboratory standards including those on the attached list. The training building HVAC system also drains through the limestone bed.

The wastewater treatment plant laboratory discharges to the sewage treatment plants. The discharge from the lab carries water and wastes generated from performing analyses and preparing laboratory

-standards used for compliance monitoring of the sewage treatment plant under groundwater discharge permit GW1810102.

Portable toilet wastes on the plant site may be collected and discharged to the sewage treatment plants.

A biodegradable deodorant is used in the portable toilets. Sludge effluent waste may also be recycled through the plants to decrease the amount of sludge for processing when possible.

Miscellaneous rinsing of waste receptacles and possible cleaning operations waste, utilizing various detergents, may be rinsed to the sewage treatment plants.

30

Rule 323.2218 Discharge permits Part 4 Treatment Codes Turbine Room Sump Outfall GOD The Turbine Room Sump (TRS) provides commingling wastes for neutralization and discharge to Outfall GOD. An on-line pH controller and isolation valve ensures that the effluent discharge is within permit limits for pH (BIb). Dilute acid or caustic. is added to the wastewater to achieve a pH level required for discharge. The effluent is discharged to an on-site absorption pond, where it percolates into the ground (A-if). Non contact cooling water, air compressor condensate also discharges to the TRS. Flow measurement, visual observation and sampling is required under the current permit.

MUP Neutralization Tank provides a place for demineralization regeneration wastes, and Reverse Osmosis Unit cleaning flushes to be neutralized prior to being discharged to the TRS and ultimately the absorption pond. When the MUP resin beds are regenerated, up to 50,000 gallons of regeneration chemicals, and backwash waters are processed in the neutralization tank. The Reverse Osmosis cleaning flushes average approximately 5,000 gallons per event.. When the water is neutralized, it is pumped to the TRS via a 2,000 GPM neutralization waste pump.

Demineralizer regeneration: (Estimated 50,000 gallons per regeneration) occurs 2-4 times per month when the RO is in service and more often when it is not in service. Dilute sulfuric acid and sodium hydroxide are used by the system to regenerate the resin. Dilute sulfuric acid, sodium hydroxide, and contaminates from the demineralization process are discharged to the neutralization tank or TRS. The pH is then adjusted to between 5.5 and 9.0 with sulfuric acid, or sodium hydroxide prior to discharge.

Chemical spills that enter the TRS may be neutralized within the sump to prevent a discharge to the environment. The potential for spills to the TRS exists for the following chemicals with the proposed neutralizers listed:.

Chemical Associated Neutralizer Sulfuric acid Sodium hydroxide Sodium hydroxide Sulfuric acid Sodium hypochlorite Sodium thiosulfate Hydrazine/Carbohydrazide NESW (lake water), Hydrogen peroxide, sodium hypochlorite.

Ethanolamine Sodium Hypochlorite, Hydrogen Peroxide, or ozone.

Ethylene glycol Hydrogen peroxide

Reduction of hydrazine and ETA prior to discharge to the absorption pond may include additions of chemicals such as sodium hypochlorite, hydrogen peroxide, or ozone to the Turbine Room Sump in batches, or to the discharge piping as continuous treatment. A downstream treatment system provided by a vendor may be used to break down the hydrazine and ETA.

OUTFALL OOE - Sanitary Waste Discharges The sequencing batch reactor is maintained by licensed operators under contract to Indiana Michigan Power. The contract manager is also a licensed wastewater operator. The system operates at a designed flow of 50,000 GPD with a maximum flow capacity of 60,000 GPD. The Sequencing Batch Reactor (SBR) system treats the wastewater using the activated sludge process (C-3a and C-3b). The treated effluent discharges to an effluent tank where it can be filtered (A-2b) prior to discharge to one of two seepage lagoons (A-1f). The lagoons discharge into the groundwater with the ultimate disposition venting to Lake Michigan. The sludge removed from the digester tank basins is taken to a local POTW (public owned treatment works) for disposal or dewatered and disposed. as low level radioactive waste.

To aid in the settling process, flocculents such as ferric chloride,.pH controllers such as magnesium hydroxide, or polymers (such as Axchem AF4500) are added to the process. To selectively enhance biosolids, bioaugmentation nutrients (such as Bioprime Dosfolat) are added to the process. This is a nutrient that encourages the growth of beneficial microbes in the activated sludge. Sodium hypochlorite is added in small amounts to the process to control filamentous bacteria growth if needed.

Sodium hypochlorite and detergent are also added to the sand filters to clean them periodically. These are then backwashed into the equalization basin to be reprocessed by the SBR treatment process.

Compliance with rule 2222:

These plant discharges meet the requirement of R323.2222.2.ii by complying with the effluent standards of part 2222, groundwater standards of part 2222, or both. A single exception exists for iron concentration in monitoring well EW 13 where iron fouling bacteria are naturally present in the groundwater. Plant effluent is in compliance with the groundwater standard for iron, but naturally occurring iron bacteria shows up in one of the monitoring wells. Upgradient monitoring well EW-8 monitoring history shows Mercury levels at 0.0035 ug/l. The remaining monitoring wells are below the 0.00 13 ug/l limit. This is not a permit exceedence since there are no limits on upgradient wells.

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2

History of CNP's Compliance with Effluent and Groundwater Permit Limits and Sampling Frequency.

Cook Nuclear Plant's groundwater discharges are in compliance with the effluent limits established in the Groundwater Permit M00988 and GW1810102. There were a few problems dealing with sample contamination in Method 1631 (low level mercury) in the first round of monitoring which resulted in high levels of mercury being detected, but these problems did not repeat in subsequent sampling. In general, concentrations of pollutants in the groundwater are far below the effluent limits and there is no indication that the concentrations of pollutants are trending upward. There are only seven parameters that have had 1 or 2 monitoring events exceeding groundwater effluent limits (total inorganic nitrogen, nitrite, phosphorus, sulfate, mercury, selenium, and silver). Background wells EW-8 and EW-16 show a similar trend for these parameters, indicating that the natural groundwater has a potential for exceeding the effluent limits and influencing the monitoring wells.

The history of Cook Nuclear Plants groundwater compliance is discussed in greater detail in the following sections:

1. Assessment of the Monitoring data for the Turbine Room Sump Discharge (Outfall 0OD) ................. 3

2. Assessment of the Monitoring data for the Sanitary Wastewater (Sequencing Batch Reactor) Discharge (Outfa ll OOE) .... ....................................... ...................................................................................................... 4

3. Assessment of the Groundwater Monitoring Data (Wells EW-1A, EW-12, EW-13, EW-19, and Background W ells EW-8 and EW -16) ...................................................................................................... 5 To *al Inorganic N itrogen (T IN) ............................................................................................................ 6 Nitrite ......................................................................................................................................................... 6 P h os p h oru s ............................... :................................................................................................................ 6 S u lfa te ....................................................................................................................................................... 6 Me rc u ry ................................................................................................................................................... 6 S e le n iu m .............................................................................................................. .................................... 7 Silver ................. ................................................ 7 The observations made are based on a review of the monitoring data for the years 2000 through July 2008. Monitoring data determined to be less than the Method Detection Limit (MDL) were treated as /

the MDL for statistical calculations. (ref USEPA SW846)

Page 1

The Turbine Room Sump and Sanitary Sewage discharges are regulated by Part A of the permit as follows:

D Part A Effluent Limitations and Monitorina Renuirements Sample Location ParameterPar AEffuet I iatonsan Limitation - MnitriaMeasurements Units Measurement Sample Type ID Frequency Effluent Flow EF-1 Process 2,400,000 gpd Daily* Direct Measurement

'Wastewater Flow (Turbine Room 876,000,000 gpy Annually Calculation Sump) (Outfall OOD)

Chloride*** mg/I Weekly Grab Ethanolamine mg/I Weekdays Grab Hydrazine ug/I Weekdays Grab PH*** 6.5 to 9.0 S.U. Weekdays Grab Effluent Quality Calculation:

EQ-1 Total Inorganic mg/I Monthly Ammonia (N) +

Process Nitrogen Nitrate (N) + Nitrite Wastewater (N)

(Turbine Room Ammonia Nitrogen mg/I Monthly Grab Sump) (Outfall Nitrite Nitrogen mg/I Monthly Grab OOD) Nitrate Nitrogen mg/I Monthly Grab Sodium*** mg/I Twice per Grab month Sulfate***

Sulfate__...._mg/_ mg/I Twice per month Grab Effluent Flow EF-2 60,000 gpd Daily* Direct Measurementi Sanitary Sewage Flow Wastewater 21,900,000 gpy Annually Calculation (Outfall OOE)

BOD5 35 mg/I Weekly Grab Chloride*** mg/I Weekly Grab Dissolved Grab Effluent Quality Oxygen*** mg/I Weekly Grab EQ-2 Phosphorus 15 mg/I Weekly Grab Sanitary Sewage PH*** 6.5 to 9.0 S.U. Weekly Grab Wastewater Sodium*** mg/l Weekly Grab (Outfall OOE)) Total Inorganic Nitrogen mg/I daily max Weekly Grab Ammonia Nitrogen mg/I .,Weekly Grab I Nitrate Nitrogen mg/I Weekly Grab

• The daily maximum is defined as the total discharge by weight, volume or concentration if specified, during any calendar day.

• • 24 hour2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br /> composite samples.

Refer to Section E., Item 1 Schedule of Activities 70 Page 2

1. Assessment of the Monitoring data for the Turbine Room Sump Discharge (Outfall OOD)

Monitoring data for the Turbine Room Sump Discharge is summarized in Table 1. The TRS is designed with the discharge piping outiets/pumps at the bottom of the tank. This configuration will allow spilled oil to remain in the TRS to be recovered instead of being discharged to the environment. The sump has a working capacity of approximately 82,855 gallons.

The absorption pond receives the effluent from the TRS. A solar powered mixing pump recirculates the pond's contents to assure proper mixing and additional biological treatment.

There is no indication that the concentrations of pollutants are trending upward in the down gradient well, Well 12.

Flow is typically less than 0.76 MGD with an average of 0.42 MGD.

Chloride in the effluent ranged from 4.3 to 21.75 mg/l. The average discharge concentration was 10.86 mg/I and 90 % of all the observations are less than 13 mg/I.

Ethanolamine in the effluent ranged from 0.08 to 15.4 mg/I. The average discharge concentration was 0.7 mg/I and 90 % of all the observations are less than 1.46 mg/l.

Carbohydrazide is used as a replacement for hydrazine for safe handling reasons. The carbohydrazide converts to Hydrazine, carbon dioxide and nitrogen in the plant's steam cycle. Hydrazine in the effluent ranged from 0.35 to 3125 ug/l[ The average discharge concentration was 54.83 ug/I and 90 % of all the observations are less than 30.15 ug/l.

The pH of the turbine room sump discharge is dependent upon the regeneration of the ion exchange resins. The cation resin is regenerated with sulfuric acidand the anion resin is regenerated with sodium hydroxide. The pH of the resultant mixture of spent regeneration solutions in the turbine room sump generally ranges from 6.3 to 8.9 S.U. [Prior to 2006, the pH effluent limit was 5.5 to 9.0 SU. Beginning June 2006 the limit was changed to 6.5 to 9.0. Therefore, the turbine room sump discharge was in compliance with the applicable effluent limit.] Sulfuric acid and sodium hydroxide are used to adjust pH prior to pumped transfer to.the TRS or absorption pond.

Total Inorganic Nitrogen in the effluent ranged from 0.4 to 17.03 mg/l. The average discharge concentration was 4.46 mg/I and 90 % of all the observations are less than 6.03 mg/I.

Ammonia in the effluent ranged from 0.10 to 8.6 mg/I. The average discharge concentration was 3.52 mg/I and 90 % of all the observations are less than 5.26 mg/I.

Nitrate in the effluent ranged from 0.05 to 13.8 mg/I. The average discharge concentration was 0.89 mg/I and 90 % of all the observations are less than 0.58 mg/I.

Nitrite in the effluent ranged from 0.03 to 0.49 mg/l. The average discharge concentration was 0.06 mg/I and 90 % of all the observations are less than 0.10 mg/I.

Sodium in the discharge averaged 525 mg/I. The sodium discharge-is the result of regenerating ion exchange resins. Both cation and anion resins are regenerated and the spent regeneration solutions neutralize each other in the turbine room sump, or in the neutralization tank. The treated effluent is controlled by an in line pH monitor that prevents discharges less than pH 6.3, and greater than pH 8.2 values. [After June 2006, these control limits were changed to 7.0 to 8.5 S.U. to comply with the new permit effluent limits.]

Page 3

Sulfate in the discharge ranged from 9 to 8360 mg/I and averaged 695 mg/I. The sulfate discharge is the J.

result of regenerating ion exchange resins. 90 percent of all the sulfate measurements were below 3055 mg/I.

2. Assessment of the Monitoring data for the Sanitary Wastewater (Sequencing Batch Reactor)

Discharge (Outfall OOE)

Monitoring data for the sanitary wastewater discharge are summarized in Table 2.

The maximum flow through the sewage treatment plant was 43,360 gpd which is below the design flow of 60,000 gpd.

The permit effluent limit for BOD 5 is 35 mg/I. All measurements are in compliance with that limit. The maximum concentration of BOD5 in the discharge was 15.04 mg/I and the monthly average concentration was 3.1 mg/I.

There is no permit effluent limit for chloride. Chloride concentrations in the discharge ranged from 95 to 161.4 mg/I. The monthly average concentration was 127.3 mg/I and 90% of all measurements were

,below 145.6 mg/l.

There is no permit effluent limit for Dissolved Oxygen. Dissolved Oxygen concentrations in the discharge ranged from 0.7 to 8.32 mg/I. The monthly average concentration was 2.9 mg/I and 90% of all measurements were below 5.1 mg/l.

The permit effluent limit for Total phosphorus is 15 mg/I. All measurements were in compliance with that limit. The maximum concentration of Total phosphorus in the discharge was 6.75 mg/I and the monthly average concentration was i.3 mg/l.

The permit effluent limit for pH is 6.5 tog9.0 S.U. All measurements were in compliance with that limit.

The pH of the discharge ranged from 6.58 to 7.6 S.U.

There is no permit effluent limit for Sodium. Sodium concentrations in the discharge ranged from 26.2 to 56.4 mg/I. The monthly average concentration was 38.2 mg/I and 90% of all measurements were below 48.6 mg/l.

There is no permit effluent limit for Total Inorganic Nitrogen (TIN). Total Inorganic Nitrogen (TIN) concentrations in the discharge ranged from 0 to 65.7 mg/I. The monthly average concentration was 16.1 mg/I and 90% of all measurements were below 46.8 mg/I.

There is no permit effluent limit for ammonia nitrogen. Ammonia nitrogen concentrations in the discharge ranged from 0.01 to 47.7 mg/l. The monthly average concentration was 2.5 mg/I and 90% of all measurements were below 8.2 mg/I.

There is no permit effluent limit for Nitrate nitrogen. Nitrate nitrogen concentrations in the discharge ranged from 0.5 to 60.6 mg/I. The monthly average concentration was 16.8 mg/I and 90% of all measurements were below 35.2 mg/l.

Page 4

3. Assessment of the Groundwater Monitoring Data (Wells EW-IA, EW-12, EW-13, EW-19, and Background Wells EW-8 and EW-16).

Groundwater is regulated by Part B of the permit as follows (limitations are for Wells EW-1A, EW-12, EW-13, EW-19):

a'm~teos,'-n', ations 1/4rqec Of Paamtes'Limit-,~n QAnaIy~sis~ apeTp Static Water Elevation USGS-F Quarterly Direct Measurement pH 6.0 to 9.0 S.U. Quarterly Grab Chloride 250 mg/I Quarterly Grab Specific Conductance umhos/cm Quarterly Grab Calculation:

Total Inorganic Nitrogen* 5 mg/I Quarterly Ammonia (N) + Nitrate (N) + Nitrite (N)

Ammonia Nitrogen mg/I Quarterly Grab Nitrite Nitrogen 0.5 mg/l Quarterly Grab Nitrate Nitrogen mg/l Quarterly Grab Total Phosphorus I mg/l Quarterly Grab Sulfate 250 mg/il Quarterly Grab Dissolved Sodium 120 mg/i Quarterly Grab Total Dissolved Solids mg/I Quarterly Grab Total Alkalinity mg/I Annually Grab Bicarbonate mg/l Annually Grab Dissolved Calcium mg/I Annually Grab Dissolved Iron mg/l Annually Grab Dissolved Magnesium 200 mg/l Annually Grab Dissolved Oxygen mg/l Annually Grab Dissolved Potassium mg/I Annually Grab Total Organic Carbon (TOC) mg/l Annually Grab Phenols mg/l Annually Grab Ethanolamine 2 mg/l Annually Grab Dissolved Aluminum 150 Ug/l Annually Grab Dissolved Barium 440 ug/I Annually Grab Dissolved Boron 1900 ug/l Annually Grab Dissolved Cadmium 2.2 ug/l Annually Grab Dissolved Chromium 11 ug/l Annually Grab Dissolved Copper 9 ug/l Annually Grab Dissolved Lead 10 ug/I Annually Grab Dissolved Manganese 530 ug/l Annually Grab Dissolved Inorganic Mercury 0.0013 ug/I Annually Grab Dissolved Nickel 52 ug/l Annually Grab Dissolved Selenium 5 ug/l Annually Grab Dissolved Silver 0.2 ug/l Annually Grab Dissolved Zinc 120 ug/I Annually Grab jHydrazine 10 ug/l Annually Grab The groundwater monitoring data is summarized in Tables 3 through 38.

Page 5

In general, the concentration of chemical constituents in the groundwater is far below the groundwater .1 limitations (in many cases by more than one order of magnitude). There are only seven parameters that have had 1 or 2 monitoring events exceeding groundwater effluent limits (total inorganic nitrogen, nitrite, phosphorus, sulfate, mercury, selenium, and silver). Background wells EW-8 and EW-16 show a similar trend for these parameters, indicating that the natural groundwater has a potential for exceeding the effluent limits and influencing the monitoring wells. Therefore, only the exceptions are discussed.

See Figure 1 for the location of Wells EW-1A, EW-12, EW-13, and EW-19.

Total Inorganic Nitrogen (TIN)

The concentration limit for TIN specified in the CNP permit is 5 mg/l. Only 1 out of 181 measurements exceeded the limit. This measurement was made on 4/18/2005 at Well 1A which is the well closest to the absorption pond. The well was resampled on 5/23/05 with the result being 3.17 mg/I suggesting a possible laboratory error. The average concentration of TIN at Well EW-1A is 2.8 mg/l. There is no upward trend in the data for any of the wells.

Nitrite The concentration limit for Nitrite specified in the CNP permit is 0.5 mg/I. Only 1 out of 195 measurements exceeded the limit. This measurement was made on 1/16/2001 at Well 8 which is the background well. Prior to June 2006 there were no Nitrite effluent limits, therefore, there was no compliance issue. The average concentration of Nitrite at Well 8 is 0.04 mg/l. The next highest concentration of Nitrite measured was 0.24 mg/I, less than half the limit. There isno upward trend in the data for any of the wells.

Phosphorus The concentration limit for Phosphorus specified in the CNP permit is 1 mg/I. Only 1 out of 220 measurements exceeded the limit. This measurement was made on 10/17/2005 at Well 1A which is the well closest to the absorption pond. This measurement was a laboratory error. Reanalysis of the same sample showed that the sample was in compliance (i.e., < 0.01). The average concentration of Phosphorus at Well 1A is 0.09 mg/I. There is no upward trend in the data for any of the wells.

Sulfate The concentration limit for Sulfate specified in the CNP permit is 250 mg/l. Only 2 out of 209 measurements exceeded the limit. These measurements were made at Well 11 on 2/15/2000 and Well 13 on 7/24/2002. Prior to June 2006 there were no sulfate effluent limits, therefore there was no compliance issue. The average concentration of Sulfate at all compliance monitoring wells ranges from 32 to 128 mg/I. There is no upward trend in the data for any of the wells.

Mercury Data from the CNP compliance monitoring wells show that groundwater in the vicinity of Cook Nuclear Plant occasionally exceeds the mercury effluent limit (0.0013 ug/l). Whenever CNP receives an analysis showing a high concentration of mercury, plant personnel immediately resample to confirm the result.

The confirmation samples show that mercury is in compliance with the effluent limit. Part of the problem may be the sensitivity of the low level mercury procedure, Method 1631.

Page 6

Nearly all of the data taken at the background well EW-8 exceed the groundwater standard. In response to a request from MDEQ, CNP began monitoring well EW-16 as the background well beginning in 2006.

Well EW-16 also shows mercury concentrations exceeding the groundwater standard up gradient of the CNP discharge and compliance monitoring wells. There is no known source of mercury from any plant processes in the vicinity of well EW-16.

Selenium The concentration limit for Selenium specified in the CNP permit is 5 ug/l. Only I out of 78 measurements exceeded the limit. This measurement was made on 7/24/2002 at Well 8 which is the background well. Selenium is generally less that the method detection limit (MDL). However, during the sampling event on 7/24/2002, three other wells showed measurable concentrations of selenium. This unusual event has not repeated and there is no upward trend in the selenium data for any of the wells, therefore, selenium should not be a concern.

Silver The concentration limit for Silver specified in the CNP permit is 0.2 ug/l. Only 1 out of 73 measurements since August 1, 2000 exceeded the limit. Silver is nearly always less that the method detection limit (MDL). Since the MDL is very close to the groundwater standard, results of the statistical analysis indicate a potential to exceed the standard. However, because silver is generally less than detectable and there is no upward trend, silver should not be a concern.

Page 7

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r-Figure la. Compliance Monitoring Well Locations Applicant: Cook Nuclear Plant Date: October 2008

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- I Figure lb. Background Monitoring Well Locations

• Applicant: Cook Nuclear Plant J Date: October 2008

Nitrata Dissolved Sulfate Sample Total Nitrite EF-1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 Location PARAMETER Flow Chloride Ethanolamine Hydrazine E powHig Inorganic 1 moi irgn Nitrogen Disle Suft E E

_______ H ig itogn Nitrogen Sodium ____ 0 LIMITS 2.400 _____ ______ _____ 6.5 9.0 _ __ ____1 U

UNITS MGD mail mail ua/l SU. S.U. mall maill mail mall maill mail mall ma/l ma/l ma/l mo/I 1 0.222 6.3 8.2 2 0.237 6.4 8.2 3 0.244 3.45 48.6 6.6 8.2 4 0.219 6.3 8.2 31 5 0.225 6.6 8.2 5.7 6 0.225 6.8 8.2 7 0.225 6.3 8.2 8 0.225 6.5 8.2 9 0.225 6.7 8.2 10 0.225 1.5 9 6.4 8.2 CIA 11 0.225 6.6 8.2 35 12 0.225 6.4 8.2 5.9 13 0.225 a

6.5 8.2 LO 14 0.225 7.4 7.6 9

15 0.225 7.4 8 CD -

16 0.225 6.6 8 0.

17 0.225 1.3 <3 6.6 8.2 18 0.225 6.3 8.2 26 19 0.225 6.3 8.2 20 0.326 6.3 8.2 EZ 9.6 21 0.426 6.6 8.2 aE 22 0.738 6.3 8.2 23 0.917 6.3 8.2 24 0.643 0.95 <3 6.3 8.2 25 0.501 6.6 8.2 0 26 0.580 6.6 8.2 365 963 27 0.305 1 6.3 8 1 0 28 0.290 7 8.2 29 0.236 6.3 8.2 19 30 0.205 6.3 8.2 31 0.}2B8 <0 7 <3 RR R9 1____ 0.322 _ ____ 6.6 7.8 ________

2 ________ 0.386 _______6.3 8.2 _ __ 283 _ ___

3 ________ 0.362 _______6.3 8.2 _ _______ 0 4 0.411 ___ ___6.3 8.2 _ __ 21 5 0.339 _______6.4 8.2 ___ _ ___ _____ _____

6 ________ 0.326 _______6.3 8.2 ____C 7 0.347 1.18 <3 6.6 8.2 ____ ____ . ____ a 8 ________ 0.293 _______6.6 8.2 ____ _______________

9 ________ 0.284 ___!__ _____ 635______ 8.2 _ ___ ___ ___ ____ ____ 33 10 _______ 0.451 ____ __ ____ _____ 668.2 _____ ____ ___ ____ ____ ____ 'X

______ 11 _ ______ 0.260 _ ___ ______ _____ 6.4 8.2 C Table 1 EQ-1 .xIs 1 of 33 Table 1 00D EQ-1

Sample EF-1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 Location PARAMETER Flow Chloride pH pH Total Nitrite Nitrate E Ethanolamine Hydrazine High oanic Ammonia iNitroge Dissolved Sulfate Low trg e Nitrogen Nitrogen dium 0

LIMITS 2.400 t6.5 U 9.0 1 UNITS MGD mall ma/Il 110/I sRU. S.U- ma/I to 12 I

01260

- - - + ~ 4-~ - -4 6.3 8.2 maei mo/I ma/l

-- +-

maI/

maOl-- 4D 13 0.262 6.4 8.2 C,

14 0.396 04 0.97 <3 6.4 8.2 ____

15 0.392 6.3 8.2 Ez U. 16 0.397 6.6 8.2 ____ __ __ ___ 5.9 54 _

____17 ____ ___ 0.389 _______6.3 8.2 _ ________ _____ 4:E

____18 ________ 0.358 _____ ______6.3 8.2 _ ___ _____ _____

____19 ________ 0.389 6.4 8.2 _ ___ _____ _____

1E

____20 ________ 0.374 6.4 8.2 _ ___ _____ _____

____21 ________ 0.402 3.27 <3 6.8 8.2 _ _______

____22 ________ 0.446 _____ ______ _____ 6.4 8.2 _ __ ____ 5.9

____23 ________ 0.424 _____ ______ _____ 6.5 8.2 ____ ____ ___ ____ ____ ____

____24 ________ 0.425 _____ ______ _____ 6.5 8.2 40

____ ____ ____ _____ _____ :2 25 ________ 0.371 _____ ______ _____ 6.6 8.2 ____ ____ ___ ____ ____ ____ 0.

___26 ___ ____ 0.415 _____ _____ ____ 6.3 8.2 ____ ____ ____ ____

____27 ________ 0.408 _____ ______ _____ 6.3 8.2 ____ ____ ____ ____

"R 281 A3 ~RR 0386 1 9l 121 <:3

<3 83 63 8.2 82 A 4QQ A2 2 0.489 1.2 <3 6.3 8.2 5.1 21 3 0.432 6.3 8.2 4 0.377 6.5 8.2 5 0.428 6.3 8.2 6 0.409 6.3 8.2 7 0.529 1.5 8.9 6.3 8.2 8 0.472 6.3 8.2 9 0.472 6.3 8.2 6.4 10 0.39& 7 8.2 38 to 11 0.291 6.3 8.2 12 0.478 0e 6.6 8.2 0

13 0.394 6.3 8.2 E 14 0.374 <0.7 <3 6.8 8.2 r=

I- 15 0.368 6.3 8.2 53

.u 16 0.561 6.6 8.2 7.7 17 0.399 6.3 8.2 18 0.471 6.3 8.2 19 0.465 6.3 8.2 20 0.456 6.8 8.2 21 0.381 1.7 9.6 6.6 8.2 22 0.416 6.3 8.2 638 23 0.451 6.6 8.2 7 24 0.466 6.3 8.2 25 0.473 6.9 8.2 Table 1 EQ-1 .xls 2 of 33 Table 1 OOD EQ-1

I Sample Location EF-i EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 4

PARAMETER Flow Chloride Ethanolamine Hydrazine pH pH j TotLw gTal Nitroge Nitroge pH IpH Ammonia it Dissolved Sulfate E LIMITS 2I 6n Low 9Sodium High Nitrogen Nitrogen E LIMITS 24011 0 659.0 1 0.

UNITS MGD mall moll ua/l S.U. SU. mall ma/I molI mall mall ma/I 26 MGD MCI/! m(3/I U04 S U SU mn/l I ma/I 0.674 6.3 8.2 O 27 0.732 6.4 8.2 C.

28 0.449 1ý3 7.5 6.3 8.2 29 0.425 6.3 8.2 35 30 0.466 6.6 8.2 5.9 31 0.392I 6.3 8.2 0.9 1 .4-.4 63-- 82 .4 .4 1 0.409 1 6.4 8.2 2 0.411 6.3 8.2 3 0.399 6.6 8.2 4 0.445 6.3 8.2 to 5 0.392 0.7 6 6.3 8.2 6 0.392 6.3 82' 5.7 V 7 CO 0.358 6.3 8.2 8 0.325 1 6.3 8.2 29 0

9 0.379 6.4 8.2 10 0,464 6.4 8.2 C4 11 0.340 <0.7 <3 6.8 8.2 12 0.379 6.3 8.2 38 13 0.322 6.6 8.2 6 ko 14 0.399 1 6.6 8.2 amoz 15 0.437 6.3 8.2 ED Z 9.

16 0.404 6.8 8.2 17 0.552 6.4 8,2 18 0.383 1.47 394 6.3 8.2 19 0.599 6.6 8.2 6.5 35 CE 20 0.506 1 6.6 8.2 0E 21 0.582 6.8 8.2 22 0.762 6.3 8 23 'o 0.811 6.3 8.2 24 0.758 6.4 8.2 25 1.329 5.3 38 6.5 8.2 4.5 26 1.560 6.3 8.2 27 1.239 1 27 6.6 8.2 C.2 T27 28 1.288 6.3 8.2 29 4 1.310 It 6.3 8.2 30 1.110 6.3 8.2 1 0.558 6.3 8.2 2 0.443 1.19 3 6.6 8.2 3 0.393 6.4 8.2 4 0.360 6.5 8.2 9.1 41 5 0.428 6.5 8.2 6 0.413 6.8 8.2 Table 1 EQ-l.xls 3 of 33 Table 1 00D EQ-1

oaldeIII r r T I r r T 1 r 1 T T Location EF-1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 PARAMETER Flow pH pH Total Ammonia Nitrite Nitrate Dsso o Chloride Ethanolamine Hydrazine Low Highon i lved Sulfate E

_ _ _ High Nitoge Ntoe Nitrogen Sodium2_ _

0 LIMITS 2.400 _____4____ 6.5 9.0 __ _ _____ ____ _____ _____

0 UNIIS M3ID molI mn/I l Ilfl'l 5RII .*11 m*/I m*ll m*/.I mn/I m A uA s U -(Z H - 11 11 11 7 0.431 R*

(n 8 0.402 6.5 8.2 9 0.517 1.5 14 6.3 8.2 67 V 10 0.445 6.5 8.2 11 0.458 6.3 8.2 "o 5.1 12 0.418 6.5 8.2 13 0.428 7.4 8 14 0.459 6.4 7.9 o: -t to 9

15 0.567 7.4 7.8 0z 16 0.653 <0.7 9 7.2 7.8 17 0.473 6.3 8.2 18 0.485 Ž0 7.6 8 8.6 31 19 0.426 6.4 8.2 20 0.438 6.3 8.2 21 0.468 6,6 8.2 02 E 22 aE 0.497 6.6 8.2 23 0.484 <0.7 <3 6.3 8.2 24 0.376 6.3 8.2 47 0

25 0.379 6.3 8.2 7.9 U-26 0.332 -6.3 8.2 27 0.364 6.4 8.2 28 0.355 6.7 8.2 29 0.358 6.3 8.2 30 0.385 <0.7 <3 6.3 8.2

,01 0.454~q 657 13.2 R7

..... 37 1 0.390 6.4 8-2 5.2 2 0.411i 6.5 8.2 3 0.457 6.3 8.2 4 0.419 7 8.2 5 0.490 6.3 8.2 0

6 V 0.353 <0.7 <3 6.6 8.2 M

7 0.467 6.7 8.2 36 8 0.429 6.3 8.2 5.3 x.-

9 C4 0.408 6.3 8.2 10 0.396 CIZ 6.3 8.2 11 0.439 6.3 8.2 0 "0 12 0.418 6.6 8.2 "Uo 13 0.404 <0.7 <3 6.3 8.2 1 1 W0 14 0.332 1 6.6 8.2 38 90, 15 0.334 6.3 8.2 5.7 16 0.190 6.3 8.2 17 0.342 6.3 8.2 Table 1 EQ-i.xls 4 of 33 Table 1 00D EQ-1

Sample Nitrite Nitrata Dissolved Sulfate EF-l Total EQ -1 EQ -1 EQ -1 EQ -i EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 Location 04 PH PH TtlAmna Ntie Ntae Dsovd Sulfate PARAMETER Flow Chloride Ethanolamine Hydrazine High Inorganic Nitrogen Nitrogen E E

_wen r _Sodium _ 0 LIMITS 12.4001 _ _ _ 6.5 9.0* _ _ 1__ _

U.

UNITS MGD mail moail Ua/l S.U. S.U. mall mall mail ma/il mail mail 18 0.562 6.3 8.2 19 0.407 6.3 8.2 20 0.487 <0.7 <3 6.3 8.2 IE 21 0.485 6.3 8.2 36 ES 22 0.395 6.8 8.2 152 23 0.417 2f 6.3 8.2 24 0.340 6.3 8.2 25 0.337 6.8 8.2 1 26 0.419 6.8 8.2 27 0.336 0.84 <3 6.6 8.2 28 0.296 6.8 8.2 53 29 0.313 7 8.2

• n A 9R0 6.R 8,2 I S.

L0 0269 65 82~ J I444 1 A 28,1 6.4 82 2 0.207 6.4 8.2 3 0.280 6.8 8.2 4 0.252 6.6 8.2 5 0.292 1.6 6.7 6.3 8.2 36 6 0.450 6.3 8.2 5.1 7 0.462 6.3 8.2 8 0.494 6.3 8.2 1 1 9 0.481 6.4 8.2 10 0.456 6.3 8.2 0 11 0.447 1.7 11.2 6.4 8.2 12 0.520 7 8.2 EZ 13 0.498 6.6 8.2 5 14 0.529 6.8 8.2 0)

W. 15 0.511 6.3 8.2 1 36 16 0.459 6.3 8.2 17 0.556 6.3 8.2 18 0.461 2.3 17.5 6.6 8.2 19 0.497 6.3 8.2 5 35 Ez 20 0.497 6.3 8.2 0

E 21 0.413 1 6.6 8.2 22 0.290 6.7 8.2 23 0.296 6.6 8.2 24 0.346 6.3 8.2 25 0.375 2.31 12.6 6.5 8.8 26 0.363 6.3 8.2 33 27 0.342 6.5 8.2 28 0.368 6.5 8.2 291 0.412 6.3 8.5 4.7 Table 1 EQ-l.xIs 5 of 33 Table 1 00D EQ-1

Sample EF-1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 Location E PARAMETER Flow Chloride Ethanolamine Hydrazine pH pH Total Inorganic Ammonia Nitrogen Nitrite Nitrogen Nit Dissolved Dod Sulfate l E Low High Nitrogen Nitrogen Sodium E

0 LIMITS 2.400 6.5 9.0 U UNITS MGD mao/ mall ua/I S.U. S.U. ma/l ma/l mal mall ma/l ma/I 30 0.420 6.7 8.7 31 0.369 6.8 8.2 I 0.410 2.1 - 9:6 .... "6: 8.2 2 0.378 6.5 8.2 48 3 0.398 6.6 8.2 5.9 4 0.308 6.8 8.2 5 0.337 6.8 8.2 6 0.348 6.8 8.2 7 0.331 6.6 8.2 8 0.324 1.4 6.9 6.4 8.2 1 1 9 0.310 6.7 8.2 46 10 0.353 6.6 8.2 380 C-4 11 0.273 6.3 8.2 12 0.331 6.5 8.2 13 0.323 <0.7 9.8 6.6 8.2 14 0.295 6.3 8.2 CD 15 0.341 6.3 8.2 0

<0 16 0.421 6.6 8.2 44 17 0.299 6.7 8.2 6.3 18 0.368 6.6 8.2 19 0.484 6.5 8.2 ol E 20 0.356 6.6 8.2 21 0,349 6.3 8.2 22 0.410 <0.7 <3 6.8 8.2 0+/-

23 0.251 6.4 8.2 42 UZ 24 0.347 6.4 8.2 6.3 25 0.341 6.4 8.2 26 0.328 6.4 8.2 27 0.364 6.8 8.2 28 1 0.366 6.6 8.2 29 0.405 0.9 <3 6.6 8.2 30 0.344 6.4 8.2 45 qt nt "4c Rq 119 5.9 1 0 .3 2 1 .. ... . . _ ....

_.. 6 64.. 8 .2 .... .... .. ..... . _......

2 0.388 6.6 8.2 3 0.332 6.4 8.2 4 0.350 6.4 8.2 o_

5 0.339 <0.7 <3 6.6 8.2 C-4 6 0.382 6.8 8.2 to 7 0.415 6.8 8.2 6.7 43 Mo 8 0.350 6.8 8.2 "o 9 0.325 6.6 8.2 to Table 1 EQ-l.xls 6 of 33 Table 1 00D EQ-1

- I 1 7 T I F I V V V Sample EF-i EQ -1 Location EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 V)

Total pH pH T Nitrite Nitrate PARAMETER Flow Chloride Etanolane Hnarganic Hydrazine Low High oanoamineAmmonia Nirgen o Nitrogen Nitrogen Dissolved Sodium Sulfate E E

0 LIMITS 2.400 6.5 9.0 0 UNIIS MtID mn/I mn/I un/I 5RII RI, ,n/II n~nrII mn/I mnll mn!l m,-t/I m,.' SU 11U/I m / m /I-/ 'nfl" 1U U.344 AR P9 11 0.356 6.3 8.2 12 0.318 <0.7 <3 6.8 8.2 in 13 0.373 7 8.2 44 14 0.296 6.8 8.2 6.6 az 15 0.314 6.8 8.2 E 16 0.384 6.3 8 17 0.310 6.6 8.2 0=(j

4) 0Ez 18 0.423 6.6 8.2 19 0.348 <0.7 <3 6.6 8.2 20 0.367 6.6 8,2 41 21 0.357 {E 6.6 8.2 6.4 22 0.412 6.3 8.2 23 0.606 2F 6.3 8.2 z" 24 0.505 6.3 8.2 25 0.493 6.3 8.2 -0 26 0.812 <0.7 141.4 6.3 8.2 44 o-.

27 0.481 6.3 8.2 281 0,400 6.6 8.2 482 291 0.399 6.3 8.2 3C 0.718t 6A R9 I 0.360U t ~ ~ ~ 6 166 4I 827 82

+

2 0.399 6.4 8.2 3 0.412 <0.7 25.1 6.4 8.2 4 0,434 6.4 8.2 5 0.353 6.4 8.2 20.8 6 0.290 6.3 8.2 N 7 0.417 6.3 8.2 1 37 8 0.204 1 6.8 8.2

.j -o o

9 0.160 6.8 8.2 10 0.345 <0.7 <3 6.6 8.2 0 11 0.328 6.8 8.2 0 12 0.307 6.3 8.2 6 E 13 0.391 6.3 8.2 41 0

14 0.327 6.3 8.2 *0 15 0.491 6.6 8.2 4)

.0 16 0.511 6.3 8.2 17 0.527 <0.7 12.1 6.3 8.2 E4 18 0.647 6.8 8.2 19 0.915 6.4 8.2 444 20 0.745 6.3 8.2 50 Zl L ______ .L ____________ ) ______ ________ __________ j ________ j ______ ________ I ______ I _______ J_______ I _______ .1._______ 1 _______ .12E Table 1 EQ-1 .xls 7 of 33 Table I 00D EQ-1

r I I r r Sample I-*"--r Total I I Nitrite r Ni~te I Dissolved I Sulfate F EF-1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 1

EQ -1 ppH Total Nitrite Nitrate Disle .4 Chlorde w pH Suft pH Inorganic Ammonia Nitrogen Nitrogen Sulfate 0

eEthanolamine Hydrazine Low High NSodium E LIMITS 2.400 6.5 9.0 UNITS I MGD mq/I mg/I ug/I S.U. S.U. mo/I mg/I mg/I mg/I mg/I mg/I 99 0 A 6.3 8.2 23 ________ 0.684 _____ ______ _____ 6.3 8.2 _ __ ____ ___ ____ ____ ____

24 ________ 0.738 <0.7 <3 6.3 8.2 ___ __ _ ___ ____ ____ ____

25 ________ 0.819 _____ ______ _____ 6.4 8.2 ____ ____ ____ ____ 6.3 41 26 ________ 0.741 _____ ______ _____ 6.4 8.2 ____ 0 27 ________ 0.664 _____ ______ _____ 6.3 8.2 _ __ ____ ____ ____ ____ _____

281________ 0.535 _____ ______ ____ 6.3 8.2 ____ ____ ____ ____ ____

291 0.245 1______ 1____ ______ ____ 6.6 1 8.2 1___ ____ ____ ____ ____ ____

301 0.532 1______ 1____ ______ ____ 6.4 1 8.2 1___ ____ ____ ____ ____ ____

31 0.468 <0.7 <3 6.5 8.2 31~441 4 I 0.660 6.6 8.2 1. 6 I 36 2 0.545 6.6 8.2 3 0.685 6.6 8.2 4 0.590 6.6 7.8 5 0.860 6.3 7.8 6 0,692 7.4 7.8 0 7 0.756 0.8 <3 6.3 8.2 V 8 0.721 6.8 8.2 1 1 "a

,9 0.781 6.3 8.2 3,8 36 cc 10 1.054 6.3 8.2 11 0.944 6.6 8.2 12 0.967 6.3 8.2 Ln 13 0.802 6.8 8.2 o: -;

14 0.682 1 8.8 6.6 8.2 Q.

15 0.855 6.3 8.2 1 E

16 0.854 6.4 8.2 6.1 35 0 17 0.853 6.4 8.2 2: 18 0.813 6.3 8.2 19 0.753 IC 6.3 8 20 0.778 6.8 8.2 IE 21 0.822 1.2 9.6 6.3 8.2 22 0.937 6.4 8.2 282 23 0.874 6.3 8.2 02 24 0.879 6.3 8 27 25 0.845 6.8 8.2 26 a) 0.956 6.8 8.2 27 0.948 6.3 8.2 28 0.838 1.6 21.2 6.4 8.2 29 0.697 7 8.2 33

-*r A 797 7 812 6:,2'

_____21 _______ 1___0.959 - _____1 ______ ____ 6.3 1 8.2 ____ ____ ____ ____ ____ ____ ___

Table 1 EQ-l.xls 8 of 33 Table 1 OOD EQ-1

- - 7 I 7 7 I F 7 F 7 7 Sample EF-1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 Location U)

PARAMETER Flow Chloride ppAmmonia H pHi Inorganic Nitrite Nitrate Dissolved Sulfate E Ethanoamine Hydrazine Low High Nitrogen Nitrogen Nitrogen Sodium E 0

L)

LIMITS UNITS 2,400 MGD mo/I ma/I uao/I 6.5 S t 9.0 SII

_________1 ma/l mall mall ma/l mall I mall MGD MCI/! man U011 SU SU M011 3 0.724 6.3 8.2 4 0.900 7 8.2 CO 5 0.760 1.86 8.9 6.3 8.2 0 6 0.722 7.6 8.2 32 V 7 0.493 7.4 8.2 6.3 8 0.551 6.3 8.2 9 0.599 7.2 8.2 10 0.388 6.3 8.2 -o 11 0.673 7.6 7.8 a.--oz 12 0.507 0.9 <3 6.3 8.2 13 0.399 7.8 8.2 U,

14 0.523 6.6 8.2

-o 15 0,305 5.7 27 .0 Lz~0 6.3 8.2 CD)

E 16 0.218 7.6 8 17 0.246 6.5 8.2 a) 18 0.207 6.5 8.2 19 0.399 <0.7 <3 6.7 8.2 _o 20 0.248 6.3 7.9 21 0.504 6.6 8.2 6.4 34 22 0.285 6.6 7.6 23 0.457 7.6 8.1 24 0.177 7.5 8.2 1 25 0.117 6.5 8.2 26 0.326 6.6 8.2 27 0.220 <0.7 <3 6.5 8.2 28 0.158 6.3 8.2 8.7 36 29 0.362 6.8 8.2 30 1 0.226 1 6.6 8.2 31 U.Zi4 7 R9 1 0.188 6.8 8.2 2 0.167 <0.7 <3 6.4 8.2 3 0.361 6.8 8.2 36 4 0.268 6.6 8.2 7.4 5 0.247 6.4 8.2 o0 6 0.158 6.3 8 7 0.063 6.4 8.2 8 0.102 6.3 8.2 9 0.210 <0.7 <3 6.3 8.2 10 0.253 7.6 8.2 18.6 48 a 11 0.097 7.5 7.6 _

12 _ 0.085 7.4 7.6 a_ ,_

13 0.075 6.4 8 0 o

Table 1 EQ-l.xls 9 of 33 Table I 00D EQ-1

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14!H Mol eutzeJpAH eulwelOue4q3 eOpolq4 MOI- U3L3VYVdVd le 4.N e 4.N IE 401 Hd Hd I 1-03. 03 .-03 1-0le.-oi L-03 L- 03: U01deoo-0 I.-03 1- O3 L-.-# eldwes

- I r -r C C 1 1 r V T Sample EF-1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 Location U) pH pH ~~~TotalNirt Ntae e-PARAMETER Flow Chloride Ethanoamine Hydrazine Low pHh Hih Inorganic oa AmnaNitrogen Ammonia Nitrite Nitrogen Nitrate Dissolved Sulfate E Nitrogen Sodium E 0

LIMITS 2.400 6.5 9.0 U UNITIS Mar) mnll mall 'In/I 5RII II mn/I mn/I mn/I mn/I mnlI mn/I UNITS MGD mrill mn1l u /I S U S U 25 0.186 63 82 U-26 1 0323 6.8 7.8 27 0.221 1<0.7 <3 6.3 7.8 28 0.280 6.4 7.8 31 1 1I .44- + + 44- + -31 1 0.330 7 8 9.4 2 _______ 0.845 6.3 8 _ __ ____

3 ________ 0.608 _ ___ ____ 6.6 8.2 ____

____4 ________ 0.356 _ ___ 7 8.2 0.309 (0

____5 ____ ___ _____ _____ 6.3 7.8 ____ ____

____6 ________ 0.361 _ ___ <0.7 5.6 6.8 8

____7 ________ 0.319 _____ ______ _____ 7.2 7.8

____8 ________ 0.406 1____ ____ 6.6 7.8 ____ 1____ 31

____9 ________ 0.354 _ ___ ____ 6.3 7.4 _ __ ____ ____ 187 10 _______ 0.323 _____ ______ ____ 7 7.5 11 ______ _ 0.343 _ ___ 7.2 7.6 _ __

12 ______ 0.312 _____ ______ _____ 6.3 7.8 _ __ 0 13 ______ _ 0.379 _ ___ <0.7 <3 7.2 7.8 0.

14 ________ 0.328 _ ___ 6.3 8 ____ ____6.3 Ea CO 9 15 ________ 0.315 1____ ____ 1______6.3 7.8 1___

16 _______ 0.333 _____ ______ _____ 7 8.2 _____34 17 ________ 0.345 _____ ______ _____ 6.5 8.2 _ __

18 ________ 0.305 _ ___ 6.3 7.4 _ __

___19 ___ ___ 0.317 _____6.3 8.2 _ __

___20 ___ ___ 0.312 _____ <0.7 5.3 6.3 8.2 EZ

____21 ________ 0.304 _ ___ ____ 6.4 8.2 _ __ 35

____22 ____ ___ 0.379 _____ _____ 6.3 8 _____143 O'j

____23 ____ ___ 0.353 __ __ ______ _____ 6.3 8 _ __ ____ 0

____24 ________ 0.321 _ ___ ____ 6.3 7.6 ____

____25 ________ 0.376 _ ___ 6.3 8.2

____26 ________ 0.819 _ ___ ____ 6.3 8.2

____27 ________ 0.420 _ ___ <0.7 4.3 6.6' 7 ________ 1___ 6.7 ____

____28 ________ 0.373 _____ ______ _____ 7 7.8 _ __ ________ 30

___29 0.316 1______ 1____ ______ ____ 6.3 8.2 _ __ ____ ____

____30________ 0.473 _____ ______ _____ 7.2 8 ____ ____ ____ ____ ____ ____

31 U.4(73 7 76 1___ ______ 0.365 _____ ______ _____ 6.3 8.2 ____ ____ ____ ____ ____ ____

2___ _______ 0.384 _______ _____ 6.3 8 _ __ ____ ____ ____ ____

3___ _______ 0.442 _ ___ <0.7 <3 6.3 7.4 ____ ____ ____ ________

4___ _______ 0.393 ______ ______ _____ 7 . 7.4 _ ___ ____ ____ ____ ____ 29 -

5___ ______ 0.368 _____ ______ _____ 7.1 8 ____ ____ ____ ____ 7.6 ._ ___ 0 61___ 0.450 1______ _____ ______ _____ 7.4 7.8 _ __-

______ ___ 7[_______ 0.317 _____ ______ _____ 7.4 8 ____ ____ ____ ____ ____ ____

Table 1 EQ-l.xls 11 of 33 Table 1 00D EQ-1

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_09' S"9 L9cO 91.

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- 4 0O*

-__ I SIMJn 0 uwn!Po8 S.,uOJ. e . I 06 9.9 _ 00t'z S11Wi11 0

oSSIU N eU0.N Hd Hd eu!zeJpAiH Ou!weloueLIG3 GPIuOlo m O- F IHJ~JVdVd lOA 84eJIIN 9W11N ___ _ HdIOl 1.-03 1.-03 1.-03 uo01-oo1 1,-O 1.-03 1.-03

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Sample EF-l I EQ -1 EQ -1 EQ EQ -1 EQ -1 EQ- EQ -1i EQ- EQ- EQ -1 EQ -1 Location PARAMETER Flow Chloride Ethanolamine Hydrazine pp H ig In otgali . itrite Nitrate Dissolved Sulfate 4)

E Ammonia Disod Sulfate HydrazHn Lo nrai moi irogen Nitrogen E LIMITS 24 I_ Low_ 9.0Sodium gh N6.5 0 LIMVIT 2.0 1 1c.'u 6).a5 .0 U UNITS MGD

- - - - 4 I mo/I

• ma/l -~-----

ua/l +

S.U. 4 S.U.

+ ---

ma/l 4

I ma/l I mall

+

I ma/l 4

mall

- 4~

ma/l

- 4 20 0.338 6.4 8.20 0.370 wE

___21 ________ _ ___ 6.4 8.20 _ __

___22 ________ 0.326 _ ___ <0.7 <3 6.3 8.20 _ _______ E

___23 ________ 0.422 _ ___ 6.6 8.20 _ __ 36

___24 0.471 ___ _ ____ 6.3 8.20 _ __ 7

___25 ________ 0.367 _ ___ 6.4 6.50 _ _______ _____

___26 ________ 0.371 _ ___ 6.8 8.20 _ ______

___27 ________ 0.381 _ ___ ____ 6.8 8.20 _ _______ _____

___28 ________ 0.376 _ ___ <0.7 <3 6.3 8.20 _ __ _____ _________ _____

___29 ________ 0.349 _____ ______ _____ 6.6 1 8.20 ____ _____ ____

___30 ______ __ . =412 _____ ______ _____ 6.8 1 8.20 ____ ____ ___ ____ _____ 37 31 0373 7 8 A AR 1-141L 7 820 4 68 I 0.333 <0.7 <3 7.2 8.20 2 0.393 9.6 <0.7 <3 6.4 8.20 3 0.362 6.3 8.20 4 0.391 6.3 820 5 0.680 11.3 <0.7 <3 6.3 8.20 3.7 3.2 <0.05 0.5 6 0.400 <0.7 <3 6.6 8.20 34 7 0.459 <0.7 <3 6.3 8.20 8 0.409 1.8 <3 6.3 8.20 9 0.388 1.8 <3 6.4 8.20 10 0.428 6.3 8.20 0 7.3 11 0.383 6.6 8.20 EZ 12 0.450 11 <0.7 <3 6.3 8.20 13 0.341 <0.7 <3 6.3 8.20 1 15.6 *0d w 14 0.391 <0.7 <3 6.3 8,20 M*0 94) 15 0.407 <0.7 <3 6.6 8.20 33 16 0.383 <0.7 <3 6.4 8.20 17 0.389 6.3 8.20 18 0.382 6.3 8.20 0-tE 19 0.419 10.5 <0.7 5.3 6.8 8.20 13E 20 0.385 <0.7 <3 6.4 8.20 9.3 39 zc 21 0.412 <0.7 3.3 6.3 8.20 22 0.414 1.1 4.6 7 8.20 23 0.342 0.8 3.3 6.6 8.20 24 0.378 6.4 8.20 .2 25 0.400 6.3 8.20 26 0.454 9.8 <0.7 <3 6.6 8.20 27 0.360 <0.7 <3 6.8 8.20 9.4 28 0.412 <0.7 <3 6.4 8.20 36 29 0.401 <0.7 <3 6.3 8.20 30 0.373 <0.7 <3 6.4 8.20

- - - ________ ___________ & .L J J 1 _______ .1. 1 1 .4.

Table 1 EQ-i.xls 13of 33 Table 1 00D EQ-1

Sample EF-1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ-1 EQ -i Location I pH pH Total Nitrite Nitrate 4)

PARAMETER Flow Chloride Ethanolamine Hydrazine Lw Nito rHigh mn Dissolved S E Low High Nitrogen Nit69gen E 6.5 9.0 imnSdu 0 LIMITS 2.400 U UNITS MGD mall ma/I ua/I S.U. S.U.- mall I mall II mall I ma/l mall mall t - - - fr ~- 4- - - I - - * * ~- * -~-- + -~ 4- -- * ~- -~

1 0.418 6.3 8.20 2 0.434 6.6 8.20 3 0.512 11.5 <0.7 <3 7 8.20 4 0.366 <0.7 <3 6.4 8.20 5 1.265 <0.7 <3 6.6 8.20 C0 6 0.363 <0.7 <3 6.4 8.20 V 7 0.430 <0.7 <3 6.4 8.20 7.3 35 8 0.381 6.4 8.20 X0 9 0.486 6.6 8.20 10 0.406 11 <0.7 <3 6.6 8.20 6 5.6 <0.05 0.4 "D 11 0.371 <0.7 4.2 6.4 8.20 0 38 12 0.441 <0.7 <3 6.4 8.20 0 13 0.375 <0.7 7.8 6.5 8.20 9.4 14 0.396 <0.7 <3 7 8.20 _=Z (0 15 0.428 6.3 8.20 9

16 0.440 6.8 8.20 17 0.451 11.5 1 <3 6.8 8.60 E 18 0.330 1.6 <3 7.2 8.20

-o 19 0.414 2.2 <3 7.2 8.50 20 0.277 1.3 <3 7 8.50 21 0.397 aE 2 <3 7 8.50 22 0.403 7 8.20 oh 23 0.360 7.8 8.20 Z 0

24 0.347 10.8 eE 1.3 <3 7.6 8.80 25 0.389 <0.7 <3 7 8.50 6.7 40 26 0.355 <0.7 <3 7.2 8.50 27 0.381 <0.7 <3 7.4 8.40 25 28 0.417 <0.7 4.8 7.4 8.20 - 29 0.373 7 8.50 1950 3751 30 0.392 7 8.50 31 0.526 4.3 1.2 30.7 7 8.50 1 0.780 . 5.8 24 7 7 8.50 ___..... ... ... ... _ . ..

2 0.709 15.4 269.5 7 8.50 3 0.709 <0.7 3.6 7 8.50 4 0.548 0.8 6.4 7 8.50 5 0.538 7 8.50 0 6 0.673 7 8.50 C14 7 0.369 9.3 0.7 <3 7 8.50 0.4 0.1 <0.05 0.3 8 0.365 <0.7 <3 7 8.50 9 0.429 <0.7 <3 7 8.50 "_

10 _ _0.367 <0.7 <3 7 8.50 4884 3430 11 0.438 <0.7 <3 7 8.50 _ e S Table 1 EQ-l.xls 14 of 33 Table I OOD EQ-1

Sample Nitrite Nitrate Dissolved Sulfate EF-1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 Total Location EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 4

pH pH ~~~TotalNirt Ntae 4)

PARAMETER Flow Chloride Ethanolamine Hydrazine pH p Inorganic Nitrogen Nitrogen SodiumSulat E

_ _ _pH__nor__n___mmoniLowiHigh Nitrogete_ _ _ ijssolvdiu E 0

I.,

LIMITS 2.400 _ L_ 6.5 9.0 UNITS MGD mo/I moll uO/I- S.U. S.U. moI ma/l mo/I ma/It- mall mq/l 4"-- -4.. .... .... .. - -" -t- - - - -

12 0.348 7.3 8.50 13 0.313 7 8.50 N Z CD 14 0.305 8.3 <0.7 <3 7.6 8.40 C

15 0.364 <0.7 <3 7.8 8.50 0z 0

16 0.422 <0.7 <3 7 8.50

0) z, 17 0.351 1.4 <3 7 8.50 18 0.386 0.8 <3 7 8.50 EO 19g0.375 7 8.50 12 C 20 0.434 7 8.50 21 0.335 9.8 0.7 <3 7.2 8.50 22 0.357 <0.7 <3 7.2 8.50 23 0.335 1.02 <3 7.2 8.50 z" 24 0.318 <0.7 <3 7 8.50 E*

25 0.530 <0.7 <3 7.2 8.50 0 6.7 40 26 0.342 7 8.50 E 27 0.383 7 8.50 28 0.352 10.3 <0.7 <3 7 8.50 29 0.420 <0.7 <3 7 8.30 30 0.382 <0.7 <3 7 8.50 t

31

• 0.403 4

<0.7 <3 7 8.50

+ 4 4---4 I 4 4. 4 4 4 11 0.331 0.74 <3 7 8.50 2 0.397 7 8.50 2205 2988 3 0.429 7.6 8.50 4 0.562 7.5 <0.7 3.7 7 8.50 CD 0

5 0.348 0.8 4.2 7 8.50 4.07 3.6 0.07 0 0.4 6 0.391 <0.7 <3 7 8.40 7 0.404 <0.7 <3 7 8.50 8 0.380 <0.7 <3 7 8.50 9 0.320 7.2 8.50 10 0.395 7.4 8.50 11 0.313 7.5 <0.7 <3 7 8.50 12 0.331 <0.7 <3

_z 7 8.50 13 0.363 0.94 <3 7.2 8.50 14 0,394 0.9 <3 7.4 8.50 0z0

.0 15 0.356 0.9 <3 7.4 8.50 E 16 0.434 7 8.50 CL 17 0.638 7.3 8.50 18 0.451 9 <0.7 <3 7 8.50 oE_

19 0.384 <0.7 Ez 8.3 7 8.50 *E 20 0.368 1 3.6 181.6 7 8.40 21 0.372 3.3 167.5 7 8.50 22 0.402 1 156.1 7 8.50 Table 1 EQ-i.xls 15 of 33 Table I 00D EQ-1

Sample Location EF-i I EQ -1 EQ -1 EQ -1 EQ- 1 EQ -1 1 Total 1 EQ-il EQ-il Nitrite EQ-i Nitmte EQ -1 Dissolved EQ -1 Sulfate EQ -1 pH pH TtlNtie Nitrate Disve Suft 4)

PARAMETER Flow Chloride Ethanolamine Hydrazine LH H Inorganic Ammonia Nitrogen Nitrogen sodium Il ILwi E

Nitrogen _, Sodium 0 LIMITS 2.400 ____ __ _ 6.5 9.0 ___ ___ (a)

UNITS MGD I mai mall ua/I S.U. S.U. maol I mOI I mall I ma/l mall mall I ---- t 4 t - I- - - 4 ~- 4-=- -t -u-- 4 4~ . 4-23 0.363 7 8.50 I-24 0.384 7.4 8.40 "1;.

25 0.337 9 <0.7 <3 8 8.70 o 26 0.341 <0.7 <3 7.2 8.40 22 0*

27 0.328 <0.7 <3 8 8.40 6.4 28 0.336 <0.7 <3 7 8.50 29 0.372 <0.7 <3 7 8.50 30 0.333 7 8~50

+ 44 I 4 4.1 4 1 4-850 I 0.367 7 8a50..

2 0.406 8.2 <0.7 <3 7.6 8.40 4.37 3.9 0.17 0.3 3 0.349 2.8 167 7 8.90 4 0.339 1.62 22.5 7 8.40 5 0.390 <0.7 7.5 7.6 8.20 6 0.364 <0.7 <3 7.8 8.20 7 7 0.340 1 7.8 8.40 8 0.348 7.8 8.50 9 0.332 10.9 <0.7 <3 7.1 8.50 10 0.348 <0.7 <3 7.1 8.30 11 0.297 0.84 14.9 7 8.40 22 12 0.330 2.01 9.23 7 8.40 13 0.399 1.2 4.2 7 8.50 1593 3700 CD 14 0.383 7 8.40 15 0.365 7 8.20 16 0.335 10 <0.7 <3 8 8.30

.0 17 0.317 1.2 9.5 7 8.40 18 0.334 1.6 14.1 7.8 8.20 19 0.332 <0.7 <3 7.6 8.20 20 0.381 1.3 7.04 7.6 8.20 EZ 21 0.355 1 7 8.30 22 0.348 7 8.40 23 0.365 9 <,7 <3 7.5 8.10 24 2F 0.370 <.7 <3 7.6 8.60 25 0.351 <.7 <3 7.6 8.00 0;

26 0.355 1.57 14.53 7 8.40 27 0.397 <.7 <3 7 8.20 28 0.336 7 8.50 29 0.375 7.8 8.20 30 0.403 10.5 <.7 <3 7 8.00 31 0.336 1 2.1 15.01 7.2 8.00 1 1___ 0.411 0 .....

___ ._ ... .. . 127 16.9"4 76 8120 *1 ..... ......

21 1 0.361 <0.7 4.96 7.6 8 31 1 0.365 <0.7 4.98 7.6 8.2 Table 1 EQ-i.xls 16 of33 Table I 00D EQ-1

Sample EF-1 EQ -1 EQ -1 EQ -1 EQ- EQ -1 EQ -1 EQ -i EQ-i I EQ -1 EQ -1 EQ -1 Location U)

PARAMETER C d Ethanoamine Hydraine pH Total Nitrite Nitrate Flow Chloe High Inorganic Ammonia Nitrogen Nitrogen Dissolved Sulfate E LoNitroen Sodium E LIMITS 2.400 6.5 9.0 I UNITS MGD mall, mall u011 011U S.U. mail mall mail Mail mail mall 4 0.318 5 U 7.2 8.4 5 0.359 1 7 9 .. ..........

6 0.474 17.8 <0.7 <3 7 8 1.4 1.0 0.1 0.3 1560 2700 V 7 0.647 <0.7 <3 7.6 8.20 ......

8 0.705 <0.7 <3 7.6 9 _ _

9 0,823 <0.7 <3 7.4 8.5 9.4 Z 10 0.824 1.1 4.5 7 8.5 11 1.104 7 8.4 (0 12 0,889 7.6 8.4 (0 13 0.763 18.25 <0.7 <3 7.4 9 0

14 0.790 <0,7 <3 7.8 8.4 Ir

....... Ea 15 01750 <0.7 <3 7 8.4 E

16 0,706 0.8 <3 7 8.5 0

17 0650 <0.7 <3 7.8 8.2 z ' "

18 0,605 7 8.0 19 0.839 7 8.0 EZ 20 '0520 21.75 <0.7 <3 7 8.4 21 1.056 0.9 <3 7.5 8.3 52 22 0.663 <0.7 <3 7,4 8.0 23 _ 0547 <0.7 <3 7.8 8.0 24 0.613 0.9 <3 7.8 8.0 ........ _ _

25 0.582 7,8 8.1 26 0,562 7 8.1 27 0,478 19 <0.7 <3 7 8.4 28 0.469 1.05 <3 7 8.50_

29 0.654 <0.7 <3 7 8.5 301 0.434 <0.7 <3 7 8.5

....... 1 0,419 <0.7 3.6 7 8.5

,,, 2 0.480 7 8.5 85.1 1875 3 0.441 7 8.5 4 0.367 6.5 <0.7 3.8 7 8.5 2.6 2.4 <0.05 0.2 5 0.,321 <0.7 <3.0 7 8.5 _ 18" 6 0.368 <0.7 3.3 7.8 8.5 7 0.304 <0.7 7.1 7 8.5 8 0.421 <0.7 5,7 7 8.5 "_

9 ........ 0.421 7 8.5 10 0.421 7 8.5 .

11 0.421 9.5 1.5 4.8 7 8.5 " .4 12 ...... 0.421 <0.7 <3.0 7 8.5 _ ,_

13 .... _ 0.488 <0.7 '

<3.0 7 8.5 ....... o0 14 .............. 0.775 < .7 <3.0 7.4 8.4 _ ........

',.. ..15 _____0.597 <0.7 <3.0 7 8.5 __ Z Table I EQ-I.xls 17of 33 Table 1 00D EQ-1

Sample Location EF-i EQ -1 EQ -1 EQ -1 EQ- EQ -1 I Total EQ-i EQ -1

- Nitrite EQ -1 N~ta EQ -1 Dissolved EQ -1 Sulfate EQ -1 PH PH PARAMETER Flow Chloride Ethanolamine Hydrazine Low High 9.0 Inorganl nirgen NirgnSdu moi Ammonia Nitrogen Nitroge i Nitragen Dissolve Sulfate 4

0 E

LIMITS 2.400 1 6.5 0 0

S 0

U 0

16 17 18 19 ___

UNITS LIMITS -t 4

I MGD 2.400 0.496 0.537 0.484

__ 0.472 1 I- ~-

mall 6.5 ___

manI 4 ____________

<0.7

<0.7

-~---

ua/I 3.3

<3.0 1

S-U.

6.5 7

7 7.2 7

4 S.U.

9.0 8.5 8.5 8.5 8.5 1

4 ma/I mall 4-_________ f ma/n

~Sodium ma/I

+ ________

-- 4 -----

mani 4- __

mn/I EZ ar 20 0.436 1.6 11.3 7 8.5 21 0.391 <0.7 <3.0 7 8.5 E 22 0.378 1.1 5.7 7.9 8.5 23 0.380 1 7.3 8.5 24 OS 0.351 1 7.2 8.4 25 0.411 8.25 <0.7 <3.0 7 8.3 0o z.

26 0.341 <0.7 <3.0 7 8.5 27 0.381 <0.96 <3.0 7 8.5

<0.7 <3.0 7 8.5 28 0.397 29 0.468 1 <0.7 <3.0 7.9 8.5 30 1 0.368 1 1 7 8.4 31 0.446 7 310 46 7 4 44 1 0.450 9 <0.7 3.5 7.6 '8_3 82.3 2 0.402 <0.7 8.2 7.3 8.5 5.4 4.9 <0.05 0.5 3 0.381 <0.7 3.5 7 8.5 4 0.377 <0.7 3.9 7 8.5 5 0.452 <0.7 <3.0 7.4 8.2 3230 7200 CO 6 0.457 7 8.5 7 0,395 7 8.5 8 0.404 10 0.84 CO

-o

<3.0 7 8.5 9 0.347 0.79 V

<3.0 7 8.4 10 0.412 <0.7 <3.0 7 8.5 11 0.612 0.73 <3.0 7 8.5 27 12 0.391 0.73 <3.0 7 8.5 13 0.400 7 8.5 14 0.387 1 7 8.5 *0 a, 15 0.423 8 <0.7 <3.0 7.2 8.5 a z 16 0.375 0.94 3.8 7.7 8.4 x0 C

17 0.381 <0.7 <3.0 7 8.4 18 0.419 1.4 9.2 7.7 8.4 o 19 0.403 <0.7 <3.0 7.4 8.5 Ez rEZ 20 0.355 7 8.5 21 0.471 1 1 7 8.5 1 1 1 I.-

22 0.363 8.5 <0.7 <3.0 7 8.5 "~0 23 0.814 <0.7 <3.0 7 8.5 aS.

24 0.374 0.72 <3.0 7 8.5 25 0.314 0.77 <3.0 7 8.5 26 0.327 0.77 <3.0 7 8.5 26 0327 - . 7LC. - JCJ Table I EQ-1.xls 18 of 33 Table I 00D EQ-1

Sample Location EF-i I EQ -1 EQ -1 EQ -1 EQi - EQ-il1 EQ-il1 EQ-1i1 EQ-1i1 EQ-il1 EQ -1 EQ -1 U,

PARAMETER Flow Chloride Ethanolamine i pH pH Total . Nitrite Nitrate Disle Suat Hydrazine Inorganic Ammonia E onEhaoaine Low High Nitrogen E LIM IT S . 1 6.5 9 .0 ___ ___ _ I Nitrogen I 4 0 C.,

UNITS MGD mo/I mo/I Ua/l s.U. S.U. mo/I I ma/I I ma/I I ma/I mo/I Ma/I 27 ________

0.315

- 4 -~ -- I 4 4 4 - ~ I t -r t -

.g.

7.6 8.5 L) 28 0.265 1 7 8.5 _

29 0.499 1 <0.7 <3.0 7.8 8.5 _

30( 0.398 11.5 <0.7 <3.0 7 8.5 1 31 0.401 <0.7 <3.0 7 8.5 I4 0 0 1 7. - 85- 44+4 1 0.396 <017 <3.0 7 8.5 2 0.389 <0.7 <3.0 7 8.5 3 0.360 7 8.5 4 0.457 7 8.5 5 0.434 7.5 <0.7 <3.0 7 8.50 6 0.403 <0.7 <3.0 7.6 8.50 7.3 25 7 0.424 <0.7 <3.0 7 8.50 8 0.399 <0.7 <3.0 7 8.50 9 0 0.404 <0.7 4.6 7 8.5 10 0.510 7 8.5 1957 2424 EZ 11 0.465 7.8 8.5 12 0.457 9.5 <0.7 <3.0 7 8.5 r,

13 0.358 <0.7 <3.0 7 8.5 14 0.364 <0.7 <3.0 7.8 8.4 0d 15 I r 0.373 1.1 <3.0 7.8 8.5 Cu 16 0.357 <0.7 <3.0 7 8.5 17 0.425 7.5 8.5 Mu 0 18 0.481 7 8.5 EZ 19 0.433 10.5 <0.7 <3.0 7 8.5 20 0.444 <0.7 <3.0 7 8.5 4.3 3.8 <0.05 0.5 DE 21 0.548 <0.7 <3.0 7 8.5 22 0.368 <0.7 <3.0 7 8.5 z

P:

23 0.418 <0.7 <3.0 7 8.5 24 0.388 7 8.5 6 25 0.485 7 8.5 1 26 0.418 12.5 <0.7 <3.0 7 8.5 1 271 0.401 0.812 7.6 7.6 8.5 28 0.342 <0.7 6.2 7 8.5 1 0.407 <0.7 <3.0 7 8.5 2 0.403 1.1 4.8 7 8.5 2434.4 3550 3 0.419 7 8.5 4 0.393 7 8.5 _

5 0.448 12 <0.7 <3.0 7.4 8.6 g 6 0.372 0.9 <3.0 7 8.5 7 0.401 <0.7 <3.0 7 8.5 1 8 0.410 1 <0.7 <3.0 7 8.5 1 7.8 27 9 1 0.379 1 0.8 <3.0 7 8.5 1 1 1 Table I EQ-l1xls 19 of 33 Table 1 00D EQ-1

1 1 T T 1 T T T T T 1 1 I I Fr~tfnn EF-I EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 PA RA M ETER pH pH Total Nirite N itrate .=.

PARAMETER Flow Chloride Ethanolamine Hydrazine Low High nirgen Ammonia Nitrogen Nitroge Dissolve Sulfate a)

Co E

L T0ow Hh Nitrogen Nitrogen Nitrogen Sodium E LIMITS 2.400 6.5 9.0 0 U3

-%1[ upli I MI.LU mali maOl uiaI SIt I 51I mn/nl mnlli mnsll ~,,.11 Mg11 SU SU m 4 M 11 - 11 11 Il U.0olf I 9 11 0.583 7 8.4 12 0.397 12 1 <3.0 7.000 8.4 13 0.330 1.1 <3.0 7 8.5 2.6 2.1 <0.05 0.5 14 0.441 0.8 <3.0 7 9 C. 15 0.457 1.6 <3.0 7 8.5 2

e 16 0.446 1 2.2 <3.0 7 8.5 1 17 0.428 7 8.4 18 0.375 7.6 8.2 19 0.394 11 <0.7 <3.0 7 8.5 20 0.392 0.08 <3.0 7 8.5 Ez 21 0.475 <0.7 <3.0 7.4 8.5 22 0.394 <0.7 <3.0 7 8.5 23 0.429 1.2 <3.0 7 8.4 24 0.372 7 8.5 .2 25 0.412 7.4 8.5 26 0.386 8.8 1 <3.0 7 8.5 27 0.345 <0.7 <3.0 7 8.5 28 0.473 <0.7 <3.0 7 8.5 29 0.383 1 <3.0 7 8.5 30 0.356 <0.7 <3.0 7 8.4 3i1 0.421 7 8*4 t t I-.-4 T~

84 I I +I 1 0.D 7 85 2 0.520 8.5 <0.7 <3.0 7 8.5 3 2.6 <0.05 0.4 3 0.410 <0.7 <3.0 7 8.5 4 0.428 <0.7 <3.0 7 8.5 5 0.424 <0.7 <3.0 7 8.5-6 0.426 <0.7 <3.0 7 8.4 7 0.344 7 8.2 8 0.383 7 8.5 9 CDI 0.434 12.7 <0.7 <3.0 7 8.5 1782 3500 10 0.401 0

<0.7 <3.0 7.4 8.0 17.4 38 11 0.485 <0.7 <3.0 7 8.4 E 12 0.485 <0.7 <3.0 7 8.5 13 1 0.319 <0.7 <3.0 7 8.5 *0 19 14 _ 0.358 7 8.5 OE 15 /0.396 7 8.5

0. 16 )0.390 11.3 1.5 <3.0 7 8.5 17 / 0.371 1.7 <3.0 7 8.5 18 / 0.383 1.6 <3.0 8 8.5 19 0.436 _ 1 2.1 <3.0 7 8.5

,'U U442 ;2 <a.O 7 as5

________ _____ -~ ... ,---... .L L .L A A I......

Table 1 EQ-i.xls 20 of 33 Table 1 00D EQ-I

Sample EF-i EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1i EQ -i EQ -i 1 EQ -1i EQ -i EQ -i Location (a PARAMETER Flow Cho IIpH id Ehnlme Hyrze Lo pH Hi pHg Total .

Inorganic Ammonia Nitrite Nitrgen Nitrate Nitrogen Disle D issleuft Suft E

r

____1__

LIMITS LIMITS uri0 1___

2.400 2.400 IvI%..u

+/-

Chloride

.L/

Ethanolamine Hydrazine

=.m II ug,1 6.5 6.5 O.U.

t I 9.0 9.0 High

.U. I mg/I maI mg/n mg/II Sodium_

mq/g I

• mLI mg/ii _

E 0

0-21 PARAMETER 0.463 7 8.5 "

22 0.407 7 8.5 Z" 23 0.448 12.5 <0.7 <3.0 7 8.5 24 0.397 <0.7 <3.0 7 8.5 25 0.357 <0.7 8 7 8.5 26 0.403 <0.7 <3.0 7.4 8.5 1 0 27 0.552 <0.7 6 7 8.5 1 1 28 0.360 7 8.4 29 0.354 7 8.5 30 0.376 11.5 <0.7 <3 7 8.5 1 0.380 0.7 <3.0 7 8.5 2 0.489 <0.7 <3.0 7 8.5 3 0.575 0.9 <3.0 7 8.5 4 0.349 <0.7 <3.0 7 8.5 5 0.339 7 8.4 _ _

6 0.459 7 8.5 7 0.383 11.4 <0.7 <3.0 7 8.5 4.2 3.8 <0.05 0.4 2820 8360 8 0.443 <0.7 <3.0 7 8.5 V_

9 0.373 <0.7 4.5 7 8.5 7.1 38 10 0.426 <0.7 5.6 7 8.5 11 0.391 <0.7 <3.0 7.6 8.5 _o _

12 0.388 7 8.5 x 13 0.273 7 8.5 0 &

14 0.335 11 <0.7 <3.0 7 8.5 -Z 15 0.332 <0.7 <3.0 7 8.5 C,9Z 16 0.412 1 <3.0 7 8.5 _ --

17 0.340 0.7 <3.0 7 8.5 &

18 0.324 1.2 <3.0 7 8.5 E Z 19 0.323 7 8.5 o ._

20 0.290 7 8.5 0 21 0.291 9.5 <0.7 <3.0 7.2. 8.5 02 22 0.289 <0.7 <3.0 7 8.5 1 <

23 0.394 <0.7 <3.0 7 8.5 24 0.427 <0.7 <3.0 7 8.5 1-25 0.372 <0.7 <3.0 7 8.5 26 0.471 7 8.5 27 0.397 7 8.5 28 0.393 12.8 <0.7 <3.0 7 8.5 __

29 0.359 <0.7 <3.0 7 8.5 30 0.371 <0.7 <3.0 7 8.5 31 0.353 <0.7 <3.0 7 8.5 1 11 0.701 <0.7 <3.0 7 8.5 Table 1 EQ-i.xls 21 of 33 Table 1 00D EQ-1

I T r r 1 r I r Oampie EF-1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 Location a-PARAMETER Flow Chloride HydrazineFlow pH Ethanolamine PARAMETE pH pH H Total Inorganic Ammonia . tNitriogee Nitrate Dissolved Sulfate E LI 20High NitrogenMNitren Nitrogen Sodium Sulfate E 0

LIMITS 2.400 6.5 9.0... .

1 IKlIMC Ii*

t -- l -- __ . F UIII I l* IVIL*[J mrlll mnll I I1"tll "*11 MJ/I mg I mg I mg" I Mgt - I mg" I mg/1 I f-- / M=*I 3 0.409 7 8.5 4 0.388 11.3 <0.7 <3.0 7 8.5 5 0.588 <0.7 <3.0 7 8.5 2.3 1.9 <0.05 0.4 6 0.692 <0.7 <3.0 7 8.5 7 0.468 1.4 6.2 7 8.5 8040 4800 8 0.456 <0.7 <3.0 7 8.5 9 0.592 7 8.5 10 0.539 7 8.5 11 0.385 11.5 <0.7 <3.0 7 8.5 12 0.482 <0.7 <3.0 .7 8.5 0 13 0.346 <0.7 <3.0 7 8.4 6.6 30 I- 14 0.345 <0.7 <3.0 7 8.5 a,

C? 15 0.311 <0.7 <3.0 7 8.5 1 16 0.420 7 8.5 17 0.432 7 8.5 0 18 0.372 10 <0.7 <3.0 7 8.5 19 0.396 <0.7 <3.0 7 8.5 20 0.399 <0.7 <3.0 7 8.5 21 0.596 1 <0.7 <3.0 7 8.5 22 0.310 <0.7 <3.0 7 8.5 23 0.316 7 8.5 24 0.440 7 8.5 25 0.317 10.5 <0.7 <3.0 7 8.5 26 0.383 <0.7 <3.0 7 8.4 27 0.427 1 <0.7 <3.0 7 8.5 28 0.494 <0.7 <3.0 7 8.5 29 0.529 <0.7 <3.0 7 8.4 30 0_385 7 8.5 1 0.330 __'_.. . ... 7 8.5's.. .. I 2 0.356 9.75 0.98 <3.0 7 8.5 4.5 4.2 <0.05 0.3 3 0.551 1 <3.0 7 8.5 4 0.579 <0.7 <3.0 7 8.5 5 0.386 <0.7 <3.0 7 8.5 o° 6 0.515 <0.7 <3.0 7 8.5 V 7 0.519 7 8.5 t 8 0.429 1 7 8.6 "V 9 0.456 10 <0.7 <3.0 7 8.5 -_

10 0.418 <0.7 <3.0 7 8.5 a 11 0.470 <0.7 <3.0 7 8.5 2 Z_

12 0.587 <0.7 <3.0 7 8.5 2498 _

13 0.439 <0.7 <3.0 7 8.5 170.4 Table I EQ-i .xIs 22 of 33 Table I 00D EQ-1

Sample EF-1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 Location pH pH Total Ammonia Nitrite Nitrate Dissolved Sulfate E PARAMETER Flow Chloride Ethanolamine Hydrazine Low High Inganic A Nitrogen Nitrogen Sodium Sulfate E 0

0 LIMITS 2.400 6.5 9.0 UNITS MGD ma/l mall unll SII SU1 mnll malI malI mall mail m/ll UNITS MGD mri/I MCA un/I S U S U 14 0.723 7 8.5 0z I-. 15 0.381 9

7 8.5 16 0.397 11 <0.7 <3.0 7 8.5 0 z

17 0.494 <0.7 <3.0 7 8.5 18 0.352 <0.7 <3.0 7 8.5 EZ 19 0.418 1.5 5.6 7.2 8.5 20 0.347 0.8 3.5 7.2 8.5 29 00 E

21 0.318 7 8.5 E 22 0.315 7 8.5 23 0.339 11.8 <0.7 <3.0 7 8.5 24 0.381 <0.7 <3.0 7 8.5 2360 25 0.463 <0.7 <3.0 7 8.5 U 26 0.447 <0.7 <3.0 7 8.5 0 27 0.595 <0.7 <3.0 7 8.5 28 0.383 1 7 8.5 29 0.352 1 7 8.5 30 0.441 9.5 <0.7 <3.0 7.2 8.5 6.4 31 0. 367 <0.7 <3 0 7 /]6 0367 <0 7 <3 0 7 86 1 0.345 <0.7 <3 7 8.5 2 0.686 <0.7 <3 7 8.5 3 0.373 <0.7 <3 7.2 8.5 4 0.388 7 8.5 5 0.380 7 8.5 6 0.337 11 <0.7 <3 7 8.5 3.86 3.3 0.49 0.1 7 0.315 <0.7 <3 7 8.5 8 0.386 1 <0.7 <3 7 8.5 1 0 9 0.346 <0.7 <3 7 8.5 z

10 0.341 <0.7 <3 7 8.5 z

11 0.444 7 8.5 12 0.461 7 8.5 13 0.345 10.5 <0.7 <3 7 8.5 14 0.362 <0.7 <3 7 8.5 15 0.427 <0.7 <3 7 8.5 *0 E

16 0.437 <0.7 <3 7 8.5 4 E.

17 0.372 <0.7 <3 7 8.5 18 0.344 7 8.5 19 0.323 7 8.2 20 0.375 10.8 <0.7 <3 7 8.5 21 0.308 <0.7 <3 7 8.5 22 0.388 <0.7 <3 7 8.5 23 0.377 <0.7 <3 7 8.5 L4 <U.0 0.302U1

-. ~~ ~ ~ ~ ~ ~ ~ ~ <3 7

___ 7___

445

____J____I____.

d____

b_____.. ___I____I____+/-____ __

Table 1 EQ-i.xls 23of 33 Table I 00D EQ-1

Sample Location EF-1 I EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ - EQ -l EQ-il EQ -1 EQ -1 EQ -1 pH pH Ni Nitrate PARAMETER Flow E Chloride Ethanolamine Hydrazine LowaHigh Nitroge __ n__ Dissolved Sulfate I I owigh itmn N on itrgen Sodium 0

LIMITS 2.400 1 1 6.5 9.0 1 UNITS MGD mo/I ma/I uo/l s.U. S.U. mg/I I mall I ma/I I ma/I ma/I ma/I 25 0.408 26 27 0.41711 0.335 10.8 1 <0.7 7

7 8.5 8.5 1474 1 2416 0

<3 7 8.5 6.1 36 28 0.416 <0.7 <3 7 8.5 U 29 0.407 <0.7 <3 7 8.5 30 0.470 <0.7 <3 7.5 8.5 31 0 386 <0.7 <3 7 8.5 31 0386 0.337

<0 7 <3 7 85 71 8*5 2 0.378 7 8.5 3 0.321 <0.7 4.08 7 8.5 4 0.362 11 <0.7 6.8 7.1 8.5 4.05 3.8 0.06 0.2 5 0.574 <0.7 3.8 7 8.5 6 0.730 <0.7 7.5 7.2 8.5 2324 3600 M 7 0.428 <0.7 <3.0 7 8.5 (0 8 0.343 7 8.5 C0 9 0.394 7 8.5 10 0.390 10.2 <0.7 <3.0 7 8.5 11 0.399 <0.7 <3.0 7 8.5 5.1 x.e 41 12 0.361 0.7 <3.0 7 8.5 13 0.305 0.9 <3.0 7 8.5 14 0.379 <0.7 <3.0 7 8.5 0

,.0 E 15 0.375 7 8.5-16 0.630 7.3 8.5 0.

17 0.482 7.3 <0.7 7.5 7.4 8.4 E 18 0.374 <0.7 343 7 8.4

_E 19 0.361 2.4 1915 7 8.5 *E 20 0.351 1.6 549 7 8.5 21 0.366 <0.7 3.4 7.6 8.4 22 0.401 1 7.8 oh 8.4 23 0.388 .u.

7 8.5 24 0.388 8.3 <0.7 <3.0 7 8.5 25 0.381 <0.7 <3.0 7.5 8.4 26 0.396 3.5 1043 7 8.5 27 0.314 <0.7 <3.0 7 8.5 28 0.419 0.82 5.9 7.4 8.5 29 0.338 7 8.7 30 0.364 7 8.5

.. .... _ 1.34

_5_.......4" °375 117 . 8 3 :4 " 30 0.06 0.

2 1.058 _ _0.95 7.06 7 8.5 30.347 <0.7 9.8 7 8.5 4

5 0.366 0.382

<0.7

<0.7

<3.0

<3.0 7

7 8.5 8.5

]

CD Table 1 EQ-l.xis 24 of 33 Table 100OD EQ-1

Toa irt iiat isle uft Sample EF-1 EQ -1 EQ -1 EQ-1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 Location r pH pH TtlNitrite Nitrate e-PARAMETER Flow Chloride Ethanolamine E Hydrazine H pH Inorganic Nitrogen Nitrogen Sodium Sul LIMIn Low High20 Nitrogen6 E LIMITS UNITS 2.400 MGD if_ mOBl _ _

ma/I

__j6.5 lin/I S U.

9.01_

StI mall

__1 moll mall

_ __I mall mall mall U

0 g/ m/ mo/ mn/Il 6 0.386 7.2 8.5 7 0.393 7 8.5 CD 8 0.362 6.75 <0.7 <3.0 7 8.5 V

9 0.388 <0.7 <3.0 7 8.5 10 0.293 <0.7 <0.7 7 8.5 11 0.021 <0.7 <3.0 7 8.5 5.56 24 _iz 12 0.327 0.95 6.9 7 8.5 o.Z:,

13 0.361 1 7 8.5 14 0.382 7 8.5 9

15 0.402 9.5 0.898 <3.0 7 8.5 0z t

16 0.403 <0.7 <3.0 7 8.5 0

17 0.354 <0.7 <3.0 7 8.5 0 18 0.415 <0.7 <3.0 7 8.5 2540 5000 Ez 19 0.431 o.a 1.14 <3.0 7.2 8.5 20 0.358 7 8.5 'E 21 0.394 7 8.5 CE 22 0.370 10 <0.7 <3.0 7 8.5 <f C) 23 0.435 <0.7 <3.0 7 8.5 0 24 0.395 <0.7 <3.0 7.2 8.5 25 0.398 <0.7 <3.0 0

7 8.6 26 0.344 <0.7 <3.0 7.8 8.5 27 0.357 7.7 8.4 28 0.406 7T4 8.4 29 0.493 7 0.85 4.3 7 8.4 30 0.575 <0.7 <3.0 7 8.5 31 n 57.q <n 7 <R n 7 RR 31 0579 <07 <30 7 1 0.512 19 19 7 RR 2 0.532 <0.7 <3.0 7 8.5 3 0.840 7 8.5 4 0.621 7 8.5 5 0.616 8.5 <0.7 <3.0 7 8.5 CD 6 0.545 <0.7 60.6 7 8.5 7 0.592 <0.7 <3.0 7 8.5 0 10 8 0.584 <0.7 <3.0 7 8.5 _*z 9 0.577 1.03 <3.0 7 8.5 10 0.346 7 8.5 11 1.252 7 8.5 '3230 2800 12 0.375 11 <0.7 <3.0 7 8.5 r, 13 0.665 <0.7 <3.0 7 8.5 3.55 3.2 <0.05 0.4 *z 9

C- 14 0.310 <0.7 <3.0 7 8.5 6.8 25 0z E 15 0.386 1 0.85 <3.0 7.6 8.5 16 U,.44 0

<U. <3 0 '-3 85

• ~ ~ L_

~ 7_ _ _

bb_ _a _ _ _ _ _ _ _i_ _ _a _ _ _ _

Table 1 EQ-l.xls 25 of 33 Table 1 00D EQ-1

Sample Sample t Total Nitrite Nit~te Dissolved Sulfate EF-1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 Location pH pH Iogan Nitrite Nitrate D C 4)

PARAMETER Flow Chloride E E

Ethanolamine Hydrazine Low High Nitrogenia Nitrogen NitrogenSodium 0

LIMITS 2.400 6.5 9.0 Nitmen I Sodium 0o UNITS MGD mg/I mg/I ug/l S.U. S.U. mg/I mg/I mg/I mg/I mg/I mg/I 0 17 0.406 7 6a5 z 18 0.722 7 8.5 19 0.441 12 <0.7 <3.0 7 8,5 20 0.326 1.4 <3.0 7 8.5 21 0.591 <0.7 <3.0 8 8.5 22 0.703 1.06 3 7.2 8.5 23 M0 0.366 1.13 3.1 7 8.5 1 24 0.371 7.4 8.5  %

25 0.475 7.2 8.3 26 0.402 11.8 0.9 <3.0 7 8.5 27 0.386 0.9 <3.0 7 8.5 28 0.290 <0.7 <3.0 7 8,5 29 0.527 -_0.7 <3.0 7 8.5 30 0.420 <0.7 <3.0 7 8.5

+ -I I- & 4 4 4- - -- 4 4 4 4 I 4 I 1 0.348 7 85 2 0.335 _ 7 8.5 I 3 0.479 10.5 0.99 <3.0 7 8.5 9.11 8.6 0.06 0.5 4 0.315 0.84 <3.0 7 8.5 5 0.324 1.14 <3.0 7 8.5 6 0.629 1.56 <3.0 7 8.5 7 0.322 1 0.8 <3.0 7 8.5 8 0.267 7 8.5 1 4) 9 1.058 7 8.5 1870 3900 10 1.339 7.8 1.1 <3.0 7 8,5 11 0.796 <0.7 <3.0 7 8.5 12 0.397 1.4 <3.0 7 8.5 Cz 13 0.421 1 <3.0 7 8,5 0

14 0.294 1 1.7 <3.0 7 8.5 15 0.284 7 8,5 E 16 0.259 7 8.5 Ez

4) 17 0.277 2.9 <3.0 7 8.5 0 z 18 0.330 9 1.9 <3.0 7 8.5 19 0.365 3.2 <3.0 7 8,5 20 0.383 1.6 <3.0 7 8,5 21 0.375 1 <3.0 7 905 8.5 22 0.291 7 8,5 23 0.274 7 8.5 24 0.293 <0.7 <3.0 7 8,5

- 25 0.285 <0.7 <3.0 7 8.5

_ 26 0.325 11 <0.7 <3.0 7 8.5 8.38 33 0 271 0.301 <0.7 <3.0 7 8.5 :2 28 0.260 1.2 <3.0 7 8.5 Table .1 EQ-1 .xls 26 of 33 Table 1 0OOEQ-1

T T T C 1 7 r 7 1 1 1 Sample EF-i EQ -1 EQ -1 EQ -1 Location EQ -1 EQ -1 EQ -1 EQ -i 1 EQ -1 EQ -i EQ -i 1 EQ -i U) pH pH Total Nitrite Nitrate Oisve Suft PARAMETER Flow Chloride Ethanolamine Hydrazine Low High nirgen Ammonia Nitroge Nitrogen Dissolved Sulfate E Li tr40en Sodium E LIMITS 2.400 6.5 9.0 0 U

UNITS MGD mo/I mall ua/I S.I. SI. mnll mall mnll mall mall mnll SU mo/I mn1l I mnil mnll ma/l mn/I 29 0.280 7 8.5 301 1 0.403 1 8,5 I7 311I 0.253 105 15_ <3 0 7 85 0263 105 15 <3 0 7 85 I 0_338 <0.7 <30 74 R:5 2 0.346 <0.7 <3.0 7 8.5 3.33 2.7 <0.05 0.6 3 0.333 <0.7 <3.0 7 8.5 4 0.360 <0.7 <3.0 7 8.5 5 0.352 7 8.5 C)

N 6 0.316 7 8.5 V 7 0.490 10.3 <0.7 <3.0 7.6 8.5 6.7 25 V 8 0.320 <0.7 <3.0 7 8.5 9 0.370 CO

<0.7 <3.0 7 8.2 a 10 0.262 <0.7 <3.0 7.6 8.0 11 0.283 <0.7 <3.0 7 8.2 12 0.324 7 8.4 13 0.368 7.6 _9z 8.0 oa 14 0.365 12.5 <0.7 <3.0 7.6 8.5 0)

CU 15 0.403 <0.7 <3.0 7.2 8.2 9 16 0.340 <0.7 <3.0 7.9 8.5 MU 17 0.326 <0.7 <3.0 7 8.5 CU 18 0.447 0.865 3.88 7 8.5 COZ 19 0.288 5%

EzCU 7.5 8.4 20 0.354 7 8.5 0*

21 0.297 13.8 0.81 <3.0 7.2 8.5 oE 22 0.374 1 <0.7 <3.0 7 8.5 23 0.641 <0.7 <3.0 7 8.4 U-24 0.652 <0.7 <3.0 7 8.4 25 0.473 1.6 <3.0 7 8.5 26 0.635 7.8 8.4 27 0.392 7 8.4 28 0.346 12 <0.7 <3.0 7.9 8.2 29 1 0.344 <0.7 <3.0 7.6 8.4 30 0.452 <0.7 <3.0 7 8.0 a3I U.414 <U.7 <3.0 7.4 8.5 1 0.477 1.2 15.2 7 8.4 2 0.310 7 8.5 3 0.494 7 8.5 4 0.572 9.3 0.82 22.2 7 8.5 6.1 20 5 0.662 <0.7 10.9 7 8.5 508 930 61 0586 1.2 4.6 7 8.5 __

71 0.401 <0.7 11.2 7 8.5 296 420 8____ 0.386 _0.83 13.8 7 8.3 Table 1 EQ-l.xIs 27 of 33 Table 1 00D EQ-1

I T T r T I T I T T T EF-1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 Location 4

PARAMETER Flow P M Row Ethanolamine HH pH Low pH H Inorganic Nitrogen Ammonia Nitrite Nitrogen Nitrate Nitrogen Dissolved dium Sulfate E E

0 0

LIMITS 2.400 U 6.5 9.0 UNITS MGU moal mall ma/l inIJ(

u aA I R~II S .U . .

RII S . U.

mraI m;911 1 n/,I ll

- ki11 I

I mnll

-Ii If I

I

~ Mg l11 mg It mg1l I V U.35o 7 10 0.417 7 8.5 11 x.

0.345 10 <0.7 <3.0 7 8.5 0 12 0.336 <0.7 <3.0 7 8.5 o 00 13 0.366 <0.7 C4z

<3.0 7 8.5 14 0.555 <0.7 <3.0 7.5 8.4 U- 15 0.205 <0.7 <3.0 7 8.5 10 16 0.280 7 8.5 9 O 17 0.222 7 8.5 EZ 18 0.214 12.3 0.8 8.1 7.6 8.5 0 (i 19 0.174 1.1 15.1 7 8.5 5.4 4.9 <0.05 0.5 00 20 0.397 1.3 22.3 7.4 8.5 1E 21 0E 0.363 <0.7 <3.0 7.2 8.4 22 0.386 <0.7 <3.0 7 8.5 23 0.428 7 8.5 269 2820 F-24 0.407 7 8.5 25 0.430 11.5 1.7 609 7 8.5 26 0.430 0.8 11.2 8.5 8.7 C-)

27 0.331 1.2 19.3 8.5 8.6 28 0.000 0.8 8.2 1 29 0u085 16 1R8R *R onf 16 18 85ZI 90 444R 1 0.0!93 RI3 RR 2 0.077 8.5 8.8 3 0.062 15.25 <0.7 5.1 8.3 8.9 4 0.000 CD 5 0.000 C 6 0.000 N 7 C-0.000 V

.t 8 0.000 9 0.000 10 0.203 1.2 11.9 8.8 8.8 11 0.483 1.7 17.9 7.6 8.6 12 0.328 16.3 1.8 24.7 7.1 8.1 0 13 0.361 <0.7 <3.0 7.1 8.3 "C

14 0.433 1.1 11.2 7.3 8.3 00 02 15 0.469 1 7.08 8.3 3679.8 3719 0 9 16 0.426 7.3 8.4 17 0.552 12.25 <0.7 3 7.5 8.3 3.99 3.2 0.1 0.7 18 0.402 <0.7 <3.0 7.4 7.9 19 0.436 1 <0.7 <3.0 7.6 8.2 6980 49 20 0.428 EZ

<0.7 <3.0 7.5 7.9 21 0 401 0.8 <3 0 74 84 21 08 <3 0 74 84 -- r Table 1 EQ-I.xls 28 of 33 Table 1 00D EQ-1

Sample EF-1 I EQ -1 EQ -1 EQ -1 EQ-1 I EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 Location PARAMETER Flow ow Chld Ethanolamine H

Hydrazine pH Low 1 pH High Total Inorganic Nitrogen Ammonia Nitrite Nitrogen Nitrate Nitrogen Dissolved Sodium Sulfate E C

E 0

LIMITS 2.400 6.5 9.0 U.

UNITS MGD 1 mall mall uoll S.U. S.U. mall I mall I mall I mall mall mall

- .. I -~ 4 - t 1- 4- 4 - - 4 ~- ----- -----

22 0.436 7.2 8.2 23 0.435 7.3 8.4 F-24 0.454 13 <0.7 <3.0 7.5 8.4 V 25 0.357 <0.7 <3.0 7.4 8.4 26 0.141 1.4 104 7.6 8.5 27 0.548 0.7 168 7.3 8.2 .-

U*

28 0.454 <0.7 10.5 7.6 8.2 29 0.531 1 7.2 8.1 30 0.649 1 7.5 8.2 31 . .... ....... I <n 7 7 ... 7R 0512 1 85 <0 7 7 75 78 1 U.4i9 <3 0 74AR Rd 2 0.068 <0.7 <3.0 8.24 8.2 5.6 29 3 0.092 <0.7 <3.0 7.88 7.9 2.78 2.3 <0.05 0.5 4 0.000 <0.7 <3.0 5 0.159 7.86 7.9 6 0.000 U, 7 0.000 7.5 <0.7 <3.0 4.3 28 8 0.000 <0.7 X 4.6 9 0.152 <0.7 <3.0 7.18 7.2 10 0.598 <0.7 <3.0 7.17 7.9 11 0.481 <0.7 3.2 7.1 7.9 12 0.567 7.25 7.9 (0

13 0.417 7.36 8.1 0

0 14 0.397 16 <0.7 <3.0 7.8 8.3 0z 9 15 0.360 <0.7 <3.0 7.7 8.3 CL 16 0.395 E

5.3 1950 7.44 8.3 o E E 17 0.499 6.8 2770 7.2 8.4 2296 3100 18 0.673 8.8 3125 7.49 8.4 o.

19 0.535 7.58 8.2 20 0.589 7.9 8.1 21 0.589 19.25 1.7 245 7.6 8.1 22 0.587 0.75 29.6 7.85 8.2 23 0.427 0.8 ao 56 7.54 8.2 24 0.570 1.1 77 7.41 8.1-25 0.994 1.2 81 7.43 8.4 26 1.172 7.3 8.4 27 1.060 7.8 8.5 C.)

28 1.071 9 1.8 153 7.5 8.5 29 1.100 0.9 67 7.22 8.4 OU U.9U 2.2 246 71.0 1 8.3 11_________

21__ _ _ _ _ _ _

1.023 0.729 1

_ __ _ 1

<0e.7

<0.7 1 79.3 23.5 1

1 7.07 7.1 1 8.

97___

8.4 1 ___

i___

1_

__ _ 1_

i i

1

_____i

___ 1 Table 1 EQ-!.xls 29 of 33 Table I 00D EQ-1

Sample Location T

EF-1 I EQ -1 r

EQ -1 I

EQ -1 EQ -1 EQ -1 r

Total EQ -1 1 EQ -1 I r Nitrite EQ -1 Nitmte EQ -1 Dissolved EQ -1 Sulfate EQ -1 PARAMETER t1p pH pH pH iInorganic TtlNitritejAmmonia Nitrate DissolveNitrogen E Flow Chloride Ethanolamine Hydrazine Low High In Ammonia Nitrogen Nitrogen DiSodium Sulfate E 0

LIMITS 2.400 6.5 9.0 U UNITS MGD I ma/l motl un/I I SU. .*.LI. mn/I mnlI mnlIl mnll mn/I mn/I 3 0.803 uaA SU SU 8.4 m A I m A I in /I in /I m /I I -"A 7.03 4 0.527 j 7.4 8.4 5 0.444 18.25 <0.7 12 7.25 (0

8.4 17.03 3.2 <0.05 13.8 988 9 6 0.541 <0.7 <3.0 7.42 8.1 7 0.494 <0.7 <3.0 7.11 8.3 7.938 35 8 0.492 <0.7 <3.0 7.6 8.2 X 9 0.484 <0.7 <3.0 7.57 8.3 1 00 10 0.392 7.49 8.2 11 0.187 8.1 8.9 12 0.423 12 0.9 <3.0 7.9 8.4 13 0.416 1.2 <3.0 7.5 8.5 14 0.385 .1.4 <3,0 7.06 8.4 (.z 15 0.417 <0.7 <3.0 7.07 8.3 16 0.383 <0.7 <3.0 7.4 8.4 1 17 0.736 7.76 8.4 18 0.663 7.47 8.4 Ez 19 0,447 12.5 <0.7 <3.0 7.5 8.2 20 0.409 1 <3.0 7.11 8.3 21 0.434 0.8 <3.0 6.9 8.4 02 22 0.433 0.7 <3.0 7.1 8.3 z 23 0.462 <0.7 <3.0 7.2 8.4 E 24 0.457 7.1 8.4 25 0.441 1 7.18 8.4 0) 26 0.517 10.5 <0.7 <3.0 7.38 8.3 27 0.439 <0.7 <3.0 7.33 8.3 28 0.208 <0.7 <3.0 7.31 8.3 29 0.000 <0.7 <3.0 30 0.266 <0.7 <3.0 8.47 8.5 31 0.492 7.25 8.3 2684 1 A0460 .. . . . _. 8.27 8.4 ' .... ' '

2 0.459 11.75 <0.7 <3.0 7.3 8.3 3 0.520 0.7 <3.0 8.4 8.4 4.56 4.3 0.08 0.2 1830 4000 4 0.481 0.8 <3.0 7.3 8.3 o_

5 0.476 <0.7 <3.0 7.1 8.4 o 6 0.111 <0.7 <3.0 6.85 8.0 7 0.335 8.17 8.8 ._

8 0.442 8.16 8.7 3

9 0.840 14.5 <0.7 <3.0 7.31 8.8 _="o 10 0.608 <0.7 <3.0 7.5 8.3 _

11 0.525 <0.7 <3.0 7.1 8.3 12 0.445 <0.7 <3.0 7.84 8.2 ____

13 0.454 <0.7 <3.0 7.36 8.7 _ -_

Table 1 EQ-i.xls 30 of 33 Table I O0D EQ-1

Sample EF-1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 Location Total r pH pH Total Nitrite Nitrate a)

L Inorganic Ammonia DissolvtSulfate E PARAMETER Flow Chloride Ethanolamine Hydrazine Low HighNitrogen E 0

LIMITS 2.400 6.5 9.0 U UNITS MGD mali mall 1 1 ua/l S.U. S.U. 1 ~-ma/l -t -

mall-- *1 -

mali 1-mall mali --

mali CO 9, 14 0.427 7.48 8.7 15 0 z 0.460 7.02 8.5 03 16 0.497 13 <0.7 <3.0 8.04 8.2 17 - 0.534 <0.7 <3.0 7.72 8.3 Ez 18 0.501 0.821 <3.0 7.6 8.3 19 0.525 <0.7 <3.0 7.7 8.2 "E 20 0.464 0.7 <3.0 7.5 8.4 7.4 7.4 40 7.5 8.4 1E 21 0.515 22 0.453 7.6 8.4 z*

4 23 0.455 12 <0.7 <3.0 7.9 7.9 24 0.400 <0.7 <3.0 7.56 8.4 25 0.436 <0.7 <3.0 7.78 8.3 26 0.373 <0.7 <3.0 7.38 8.1 1 1 0 1

C-)

27 0.635 <0.7 <3.0 7.5 8.3 7.39 8.1 28 0.444 29 0.562 7.48 8.2 3C 0.451 11 <0.7 <30 6.5 86 654 86 1 0.563 <0.7 <3.0 701 8.6 21 0.531 <0.7 <3.0 7.2 8.2 3 0.482 <0.7 <3.0 7.22 8.2 4 0.473 <0.7 <3.0 7.3 8.3 5 0.476 7.3 8.4 0 6 - 0.505 7.3 8.4 M0 7 0,428 11.5 <0.7 <3.0 7.52 8.9 V 8 0.500 <0.7 <3.0 7.48 8.4 6.85 41 9 0.500 <0.7 <3.0 7.38 8.4 10 - 0.504 1.2 4.6 7.39 8.3 6.06 6.1 <0.05 <0.10 11 - 0.450 <0.7 <3.0 7.1 8.4 N EZ 12 0.441 7.1 8.3 13 0.676 7.1 8.5 14 0.424 11.5 <0.7 <3.0 7.08 8.4

<0.7 <3.0 7.43 8.4 15 0.489 0:

9- 16 0.502 <0.7 <3.0 7.64 8.4 i--

17 0.502 <0.7 <3.0 7.2 8.2 ED 18 0.458 <0.7 <3.0 7.17 8.1 19 0.433 7.15 8.0 o-20( 0.437 7.24 8.1 "0) 21 0.478 11 <0.7 <3.0 7.07 8.3 22 0.415 1.7 5.9 7.12 8.4 23 - 0.455 <0.7 <3.0 7.7 8.4 24 0.448 <0.7 <3.0 7.6 8.4 Z*

2E- u.494 0494 n .q5 95 30 3

R OR ii',

696 Table 1 EQ-1.xls 31 of 33 Table I 00D EQ-1

- 7 r r 7 r r r V V V Sample Loc.-ti n EF-1 I EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 pH pH oran Nitrge Nitraten PARAMETER Flow Chloride Ethanolamine Hydrazine Low High Inorganic Ammonia Nitrogen Nitrogen Dissolve Sulf E Ni *.n Sodium E LIMITS 2.400 6.5 90 0 0

UNITS MGD I ma/l ma/I ua/I S LU S.U mn/i mn/ll mn/I I mnll mn/I 26 0.232

- -- 4 4 - ~-s ~ 4 U 7.54 II 7.8

.. I mrl mri. I mn/I m A mci/I 1460 mn/I 2500 27 0727 7.6 8.2 1460O 1 2500 03 28 0.386 12 <0.7 <3.0 7.24 8.4 29 0434 <0.7 <3.0 7.21 8.4 30 0.424 <0.7 <3.0 7.21 8.4 31 0.468 <0.7 <3.0 I 7.13 8.3

. <3 0 1 71 8.3 I1 4 I <0.7 .3.0 4 _____<0.7 <3.0 ____ _________

5 ________ ____<0.7 5.8 _ _______

6 ____<0.7 4.1 _ ______

7 ____<0,7 5.6 ________

8 ____<0.7 <3.0 _ __

10 _______

11 _________ ___________ a.J 12 _________________

13 _________________ ____________

• 0 14 _______ ____ ____________

0O 0 15 _______ ____ _____ ____ ____

S--

F20__

21 _______

22 __

23 ____ _________

26 _____

278 _______ ____ _____ ______ _____ ____ _____

728 29 _______

30 _____________ ______ _____ ____ ______ ____ ____ __________

4 31 4 1 1 ¶ 4 1 t Table 1 EQ-l.xls 32 of 33 Table 1 0OD EQ-1

r F - r r 1 I 1 T Sample EF-1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 EQ -1 1 EQ -1 pH pH Total Nitrite Nitrate Dissolved Sulfate r E

PARAMETER Flow Chloride Ethanolamine Hydrazine Low H Inorganic Ammonia Nitrogen Nitrogen S E S 2 h Nitrogen Sodium U0 LIMITS_ 2.400 _____ ___________ 6.5 9.0 ________ ___

IINIT* M*rl molt mn/I I in/I .qll .qll mn/I mnll mnll moll mail mail UNIT MG m 1 m u_ U S -1 1 m/ n/ nl miI m/

CNP 2008 Groundwater Permit Renewal Table I Recent Compliance Hist OOD Dischare to Abs on Pond No. Observations 1308 114 201 162 1296 1296 26 26 9 25 133 135 Minimum 0.000 4.300 0.080 3.000 6.300 7.000 0.400 O010 0.060 0.070 2.500 9.000 Average 0.425 10.864 1.474 108.819 6.900 8.310 4.463 3.525 0.132 0.928 525.287 695.593 1 Maximum 1.560 21.750 15.400 3125.000 8.800 8.980 17.030 8.600 0.490 13.800 8040.000 8360.000 90th Percentile 0.635 13.000 2.100 167.950 7.500 8.500 6.030 5.260 0.234 0.586 1955.600 3055.200 95th Percentile 0.763 16.825 3.270 393.050 7.600 8.500 8.348 5.945 0.362 0.670 2652.000 3728.600 Censored values treated as 112 the MDL No. Observations 1308 114 643 326 1296 1296 26 26 26 26 133 135 Minimum 0.00 4.30 0.08 0.35 6.30 7.00 0.40 0.10 0.03 0.05 2.50 9.00 Average 0.42 10.86 0.70 54.83 6.90 8.31 4.46 3.52 0.06 0.89 525.29 695.59 Maximum 1.56 21.75 15.40 3125.00 8.80 8.98 17.03 8.60 0.49 13.80 8040.00 8360.00 190th Percentile 0.63 13.00 1.46 30.15 7.50 8.50 6.03 5.26 0.10 0.58 1955.60 3055.20 195th Percentile 0.76 16.83 1.70 167.88 7.60 8.50 8.35 5.95 0.15 0.67 2652.00 3728.601 Table 1 EQ-i.xls 33 of 33 Table 1 00D EQ-1

Cook Nuclear Plant Groundwater Permit Renewal Application I =ocaIo EG-2 I EG- I EQ-2 I Ea2 I EQ-2 EG-2 I0- E0-2 I II EO-2 II EQ-2 1 6 -2 E I E-2 EQ-2 a Dissle o EO-2 I EQ-2 C PARA W--I Nitrte Ileaclee 0 METER II .eeWd I

=nria KIN-No- sock-11 6001F10W11 GPD PYO 44.3 01 43.7 0.5 2.28 4252 0.1 ..42_4 0.02 1.5 0.

r 3822 6.75 z 0.__

_1 46 1.4 40 0.06 0.75 32.24 31 _4 0ý03 5.13 2O.9 8.2 19._7 0.19 0.13 W

2 3342 0.34 32.9 0.88

u. z 0.

E

,3344 Y 12 33.3 0.13 2008 CK gw renewal Table 2 update.)ds Page 1 of 23 Table 200OEEQ-2

Cook Nuclear Plant Groundwater Permit Renewal Application Sample m Location E-0-2 EO-2 I E0.2 I EQ-2 I EQ-2 E-02 EO-2 EO-2 I EO-2 1 E-0-21 F-0-2 EC-2 EQ-2 EC-2 i

o PARA METER Dis Oxygem I Inorgni Nitrogen NatreleNilte Nitrocien INitogn I Ussalived Sod'"ium i Flow Flow E odlPoi4lou (Me--) (Ct)Freeiboed V teation Dike Ina E I - I - I - I - I 60000 219i00W 1.04 0.65 GPD GPY Feet SaUnsat Sat/Unset 33.39 31.7 0.N25 17250 17570 19560 18570 1550 11830 12300 331 .1 29.1 0.74 0.88 18010 1la2 19470 17140 14680 11650 9

-- 31.22 3 2615 0.97 0.06 18520 20290 16710 z 19260 U 19220 E 14730 13380 21290 3T5.41 7.6 3.21 0.13 22920 21900 21710 19270 18740 19250

~EI~91 37.6 3.5 0.13 23530 30.2 7.68 24610 23940 28580 1.0 23950 22870 29030 60.45 0.-95 13.6 25830 457 50.64 28 16.04 3.25 22780 24910 26240 053 24840 21230 19060 6&67 7.14 0.01 22250 '4 F3.25 4 11.635 3.25 25770 24210 W 0n 25310 26170

<[ 20940 z 15930 0 3-9.62 5 30.1 4.52 1.75 18460 E 42 39 1.5 1,5 17830 24000 0 22550 21640 13760 14450 21.59 02 21.2 0.19 1.5 17740 27.28 0.2 27 0.06 20510 088 20510 1is3 2008 CK gw renewal Table 2 update.xls Page 2 of 23 Table 200OEEQ-2

Cook Nuctar Plant Groundwater Permit Renewal Application I

I L I EO-2 I I

EQ-2 1I 50-2 1I IE82 I I

E8-2 I

I EC-2 I E0-2 I E0-2 I E8-2 I E-04 0-2 I E0-2 E0-2 E-2 I I PARA METER NWMe I M1-I [I I %A-YM I

. I U.r-,I IA* NI I a - ". S " I I

• Rowns

. .... IDi

... ..Ins E m9A nVII mgM mgA 23.5 0.25 23.2 0.05 21.02 0.1 20.9 0.02 0.2 23.2 m

---

7 17,22 0.1 17.1 0.03 CI 12.43 0.1 12.3 0.1 12 0.04 0.2 7.8 0,02 0

15.22 0.1 15.1 0.02 A.

z 0

e, Al 9.83 0.1 9.5 Q0,3 15.38 0.2 15 0.16

_IFI_

2008 CK gw renewal Table 2 update.xis Page 3 of 23 Table 2 ODEEQ-2

Cook Nuclear Plant Groundwater Permit Renewal Application T T -. T 1 r 1 r Sample F9-2 P0.3 I P0-32 I FM?. I Ff3.7 FT3- Ff3.9 Ff3.9 I 00.9 II 0f39 EQ-1 II 00.9 Sa-I EQ-2 IE-2 EQ-2 EQ-2 I xl PARA Io. I D-v-dl1nrooana EC-2 Nitrate Wie Dissoved Flow Flow E METER BO05 *IMIUB *IU+I Nit-I Sodium I ChoieI Phr.*- I (U-1~ (Cilc FebadVll Dike Ins 0 O-- g .. . . .. .. - .. " .. I . . I 21900000 Mon Mon~

IOPY FetSi~stSaiUnset 13.12 13 0.21 0.1 19.53 19.4 0.3

20. 13 0.1 20 70.3 1.88 0.1 22.3 35.66 0.1 35.5 0

0.0 9 0.

z 6.1 0.02 1.25 E 9.04 0.2 -8.8 1.75 01 9 IJ03 2

0. 162 .03 0.5 0--

0.1 6 0.5 10.98 0.13 10.8 0.05 0.13 0

0.

2 9M19 9.1 0.01 0.38 z

U E

a 0.13 5.9 0.02 0.86 0.*1 12.2 0.03 0.88 2008 CK gw renewal Table 2 update.xls Page 4 of 23 Tabe 2 OE EQ2

Cook Nuclear Plant Groundwater Pennit Renewal Application

,sample

>- Location EQ-2 II C~

EQ-2 II CA~

ECI-2 II ECI-2 I I EO-2 On..,

E10-2 I I =~..,

II ~

EO,2 II EO-2 IEQ-2 EO-2 a s=

PARA MFTFR I mik-d IN aIl NWals m--I Mow N8,ogeI Nitrcgf I SockwnIC*nehov ru L--I,..=,

Flow E 21900000 0 M8. "GP( etSaRne Selluneg 8.43 0.31 0.02 1.25_

10. 39 10.3 0.88 8.32 0.09 8.2 0.03 0.88 a.

12.49 0.16 12.3 0.03 IL

-2 in o

E 0E 0.1 11.1 1.25 5K72 0.1 0.75 11.19 1.25 5O.8 0.02 10.26 10.1 0.38 0.08 10.8 0.0-2 0.13 0.02 14.8 0.03 0.25 ky 2

.3 a.

2 1f3.49 134 0.01 0.83 U 0 17.61 o,-07 0.88 E 2008 CK gw renewal Table 2 update.xls Page5 o2 Table 2 OOEEQ-2

Cook Nuclear Plant Groundwater Permit Renewal Application Sample

=

>- Location EQ-2 E-0-2 I E0-2 I E60-2I E0-2 EQ-2 EQ-2 E60-2I EQ-2 I E0-2 I EQ-2 60-2 60-2 I 0-20-2

=:

PARA MFTFR M-Ibvedorg ni rh-- N"--

Nitrete 1

Nilme Nih-DI solved Sodium I ClIcride 1. 520 --

Flow Elw I 1 60000 219oo00I GPD GFY Feet Satiunsat SaliUnset moll94 M9 i002 1.13 13.91 13.8 0.053 0.63 18.1 0.06 16 0.04 0.13 0.602 0.38 12.15 0.9 11.2 0.05 0.5 8.2- 025 7.9 0.008 0.38 E z U

E 20.04 1 0. 1 199 1 .4 1.13 23.42 0.08 23.3 0.04 0.01 27.-17 2.-46 24.8 0.11 0.2 8.2-8 8.1 0.0 0.25 12.02 0.17 11,8 0.05 1.5 o.

8 "I

0 z 0

E 1211 0.:84 12 0.03 0.13 15.31 j0.086115.2 0.03 0.13 2008 CK gw renewal Table 2 update.xis Page 6 of 23 Table 2 00E EQ-2

Cook Nuclear Plant Groundwater Permit Renewal Application Sam-l aul EO-2 E-0-2 I EQ-2 I E-0-2 I EQ-2 EG-2 EO.2 I E0-2 I EG-2 I E-0-2

. IM-I NirtJe EQ-2 IEO-2 EO-2 0

PARA METER i M-va OxyWe I g ToI NWOasn

- - I - -

isow FlowFabwdValae 2190t I~ m 0

GPY, Fa S SallMaat W-13.87 0. 0.01 0.5 232 0.06- 0.02 0.01 25.06 0-.-27 24.7 0.09 0.01 23.52 0.72 22,6 0.2 0.5 o= 2 0.06 19.21 0.38 0"

.-) 18.18 0.2 17.9 0.06 0.38 E a.

20.97 028 20.6 0.09 0.25 1f8.98 0.4 18.5 0.06 0.75 1T4.73 0.7 14 0.03 0.38 16.76 2.1 14.6 0.08 A0.,25 0R 1T8.15 1.4 16.7 1.38 2 z E

P 2008 CK gw renewal Table 2 update.xls Page 7 of 23 Table 2 O0EEQ-2

Cook Nuclear Plant Groundwater Permit Renewal Application T r r I I *I 1 .7-M7. P0.2 I F41.1 I M02 I 0-12 RP0.2 FO.? P0-2 PM I1 FO.2 rn*7 I1 P0-2 1.1 I1 P0-2 E ý EQ-2 1 2 0-2 EQ-2 PARA I MslvdIi~j-O Nitraet WdaI D taiiniI-momu Flow EE METER BOO5 I *[NIMm Sodium (Meas) (FC'aDIWc) jFmeboarIeQeta5jDnD"l Cbcvnm Nitrogen NilrIxW I MUM GOODO 1219000001

_GPy I Feet JSe:VUr" SBVLk"

132=2201ýýýý 0.0 1T7.51 0.787 16.6 1.25 I 1 10 1.38 1T2.71 1.2 11.4 o.1l 0.5 16.56 3.84 12.1 0.62 0.38 0.35 6.7 0.05 0.63 12.13 1.94 10 0.19 0.5 T

a.

z 0

E 0

21.67 7.1 14.3 0.27 2.5 39.8 8.4 293 2.1 3.75 359.08 17.4 21.2 0.48 3.5 14.7 49.7 34.4 0.6 2.75 8.23 27.9 0.38 1.69 47.93 34.3 0.48 13.15 2 .9 a

o=,

T:

a.

z 0

~21 2M8 2008 CK gw renewal Table 2 update.xis Page 8 of 23 Table 2OE EC-2

Cook Nuclear Plant Groundwater Permit Renewal Application sarpe I I I E-0.2 I EQ-2 EO.2 I MQ-21 EQ-2 1 E-0-2 I I I

I E0-2 I

i E<0-2

-- II -20IEEQ-2l60-2I I EO-2 I J¢ EO-2 PARA Oleadvd I ha" iraeI W I Ussoteed MFT*R Nitm owe Amnesi NloW*D Soedmmluron ll hsoou M.,(lCIIFldMIIIIU~ E6

. . . . . m I K

• 47I84 1.35 tGP0 GPY~ Feet Sedoav Sat/un 40.4 0. 21460 24700 23950 2106 0.0 2400 21 0.01 15.3 0.04 0.88

~I1 1 19 0.38 5T84 0.01 5.8 0.0O3 0.13 a.

0.

E 1T2.84 0.01 12.8 003 0,75 18.24 0.01 18.2 0.03 0.63 71.0-5 0.01 11 0.04 0.25_

I I 4- 1 I I I --

• 4 3

4 9 sat sat 7

9 sat set 10 11 12 6.07 m (0

7.05 9 sat sat 2008 CK gw renewal Table 2 update.xls Page 9 of 23 Table 200OEEQ.-2

Cook Nuclear Plant Groundwater Permit Renewal Application 1 r ~ T T 1 7 T~1 7 r a i r 7 r I ~ 7 T Sample E0-2 E0-2 E0-2 I 5-2 I 5-2 I 5-2 F150-2 I 502 I P02 I E0 50-2 P0*-2 1=0-2 IP-2

s PARA METER BOD5 nfl 0nClised Oxyge Inoganic Nitrat Nitroom Ammram Niffoge Nilnia Nttoaen j Dissolved Sodurn CNorido Phosphonus

..... r ......

Flow Rems) 1 - t Flow iCalc) FreeboardlVegetatioI Dike Insp E

E 0

-1 18 E 19 13990 1 9.5 sat sat 20 8.8 0.018 27.9 21 2.58 22 23 9.5 sat sat 24 11740 25 26 27 0.03 30.9 124 0.25 15890 1 9.5 sat sat 28 18170 9.5 sat sat 1 13430 2 9800 3 14380 9.5 sat sat 4 14140 5 0.03 1 32.2 0.5 11850 6 15180 7 17700 8 13410 9 9180 10 15000 9.5 sat sat 11 1.21 1 7.35 17600 12 32.9 123.5 21250 13 18960 14 21400 9.5 at 9 15 16 17 5.67 115930 18 0.75 75 1206000[__ 9.5 E 19 0.01 19.7 1 0.03 1.13 19330 03 20 22480 21 20120 22 12520 23 24 25 31.2 110 1 1.13 1 17670 9.5 26 27 0.85 16.5 0.03 9.5 sat 28 19880 29 18640 30 20320 31 21470 sat sat 1 1.48 9.1 22430 2 0.65 1.5 20760 3 19180 4 7;;F 5 17410 6 12860

-7 19180 9.5 Sat Sat 8 0.83 3.02 6.4 6.4 0.63 19480 9 0.68 1.26 1.44 23890 9.5 10 11 12 ______ .9 13 ______

2008 CK gw renewal Table 2 update.xis Page 10 of 23 Table 200OEEQ-2

Cook Nuclear Plant Groundwater Pernit Renewal Application Sanple FO.2 I FA..~ I

-TE I cn, I m~ I I en,,

E PARA METER UMITS 60 M-KId NirleN~ft Nih ~

Disso0 sodur Flow Me

)

o (Calo) F,,,,, E MQ4 m9A mOA r~ri 0 ~ I n

15 16 0.94 7.23 1.54 7.5 10990 16M70 I ~'

34.5 127 17 9.5 sat sat E 14780 20 10950 21 1.5, 34.7 124 0.38 16740 a3 22 1.3f I2 35.1 120 0.38 19980 23 18080 24 20120 sat sat 25 20120 26 13270 27 15080 125.5 1.13 21010 24940 30 1.9 7.41 3.54 17.02 0.01 17 0.01 =I= 1117. 25880 31 26260 sat sat 1 22390 2 19810 3

4 16.3 30.6 2.07 28.3 0.23 39.4 117.5 2.88 26120 9.5 sat sat 20&90 4.14 6.96 0.01 6.9 0.05 31.5 124 413 12 0.63 25980 9 sat sat 13 29270 14 32540 91 2

1292701 1 1 m

E, a-E 19 18.8 41.7 9 sat sat a 20 21 0*

36260 35090 27820 32610 35320 41000 34990 28 2.64 7.16 0.7 58.06 16.7 39.1 0.26 141.5 3 36410 8.5 sat sat 2

40 3 1.4 6.85 0.86 46.21 8.35 37.7 0,16 45.8 2 358101 8.5 Sat Sat 4

5 8 8.5 Sat Sat 7

a 9

10 9 Sat Sat

.9 2008 CK gw renewal Table 2 update.xts Page 11 of 23 Table 200DEEQ-2

Cook Nuclear Plant Groundwater Permit Renewal Application 1 r - . r I I T T F I 7 F I 7 7 F I T r 1 Snaple I I I ED-2 EQ-2

- ocak FM?.2 :0-2 2 4-~4 M P-2

+

FI: -2

~ RI .2 F10-2 02---C~

+4 RIP-2 R-12

~

-(0-2

+I E0-2 EQ-2 E

PAPA Dissolvred -mga Nitune Nlf D le Flow Flow C METER nP oll L Nitrogen Nitroge Sodium ICl~onde IPhosoti (Meas) (Cdcl FraeboardlVegelatonl Dike mnup uE 0= Bms O Nit g  ! i . . . . .

• S 43360 8.5 Sat Sat 13 14 15 31910 U) 16 36140 0

15 17 37480 a 18 2.5 0.96 124 3.63 36500 E 4 42.1 0.265 131.5 3.25 41390 33790 o 21 22 23 31570 8 Sat Sat 24 1.95 2.03 40.8 25 2,65 6.85 2.26 49.755 1.1Z 0.

26 33090 27 ;at 28 29 30 g4070 26370 8.5 31 1.88 25390 1 1.82 2

3 23480 4

5 6 Sat Sat 7 1.7 6.95 3.9 27.65 0.01 27.6 0.04 8 1.64 7.24 4.7 0.035 0.01 0.025 153.5 0,63 17450 9 Sat Sat 10 at 11 16230 12 16150 13 6.8 1.37 7.83 7.8 0.03 147.5 2.25 13710 - Sat Sal 14 8.95 1.05 144 1.88 19250 15 5.73 2.29 142.5 17390 0 16 25180 17 21530 8.5 Sat Sat z E 5'

18 1 0 19 1 20 5.49 0.25 13580 9.5 Sat Sat 21 1.62 18600 22 1.15 6,16 15260 1 1 9.5 Sat Sat 23 24 25 26 27 0.01 0.03 129 0.38 17310 28 0.01 21.4 0.02 28.3 130.5 0.5 16030 8.5 29 0.1 0.86 2066 30 10540O_

1 24070 9.5 2 14770 3

4 1.01 7.23 7.2 6,72 5

6 2.12 9 1 Sat Sat 20920 9

2008 CK gw renewal Table 2 update.xls Page 12 of 23 Table 200OEEQ-2

Cook Nuclear Plant Groundwater Permit Renewal Application I LormtIrv, IFfl~7IFA-2 MIIi rei F4tL.1 O.

FA- V Fi~ 1P1,I A.1 FmA iR.13 I PM7 I .O~ I FO.2 I'l PARA Dissoived Total gi Ninao Na Drolved -= Flow METER Flow E BOOW 0S pH Damo N*lom Immoniak-o !m o Pht (MoM) (CO} FJVegreeardVEltalion DkeMg UMITS Min Max 80000 21900000 DAY UNITS 65 9.0 Mon mai l mo A MOA m2 GPD GPY Feet Sat/Und SatnUnsMa 10 14110 11 7.13 7.1 5.79 001 127.5 0.13 13470 12 2ý 204 6.9 6.9 3.26 21.735 0.01 21.7 0.025 33.4 126 0.13 18580 13 2.05 7.02 7.0 0.47 0.03 0.25 21810 9.5 Sat Sat E 14 20020 21410 E

14360 A= 17 16730 18 13310 19 30.7 1 123 0.5 17690 20 12740 21 19350 22 12280 23 12500 24 8390 25 26 27 0.83 7.36 7.4 6.5 0.01 1 00201 1 12790 1 1 2

3 7.17 7.2 21760 6 13950 12610 6.8 1 6.8 1.02 13970 9.5 9 39.2 130 0.125 14950 1 9.5 sat sat 12180 12480 9= 16510 16 1 1 1.71 7.24 7.2 21120 03

_ 1 1.27 1 7.17 T 7.2 18470 9 sat sat 18280 6 27190 9 sat sat 25070 21 16170 22 21180 23 6.185 2.55 3.6 24410 24 0.95 28940 25 23280 28 20500 27 27120 28 11970 29 20180 32 18700 31 17.05 1.52 15.5 21780 1 [0035 0.01 120 1 0.025 0.125 16630 2

9 at 2.48 7.13 1 7.13 3.64 1 9.34 1 0.01 1 9.3 1 0.03 0.75 2008 CK gw renewal Table 2 update.xls Page 13 of 23 Table 200OEEQ-2

Cook Nuclear Plant Groundwater Permit Renewal Application

-;SampW-I E62.ý EOýY`i -EO.2 2- Q-di ME2 -. Mrji FO'2 ( >-

PARA Dlssle~ ~ K~litte~'~ii~sljvied FO lw -- E .

mErER 803_L ~H-ýp 0xdgeii Njtrge lAtmola` I:NQin MilNtbr~in .Soiun .ho'nde, PI`Z4phoru ý(Mmisj "(Cab) kr~odY9~in Inip 7.DAY:I

• 3.32 7.2 7.2 4 0.04 0.01 0.03 0.63 19000 9

23300 ]_ _

17160 9 sat sat 10 16490 11 11720 12 7.6 7.6 5.61 6.85 0.01 6.8 0.04 44.6 128.5 0.38 19520 13 18140 M of 14 1.35 126 21530 2 15 17500 16 21160 9 sat sat 0 17 9 14520 18 16550 19 13030 20 2.44 3.85 0.02 3.8 0.03 42.4 126 0.13 22040 21 0.38 19500 8.5 sat set 22 23 24 15420 11320 17100 9 sat sat 27 17250 28 2.18 6.88 6.9 2.01 9.88 0.04 9.8 0.04 45.9 20590 18170 sat sýa _

2 21310 6

I _ _ _

1.22 7.18 7.2 1.47 6.33 0.5 5.8 0.38 14470 19120 8.5 sat sat

ý181 00 9

10 11 12 1 22130 18630 9 sat sat 6.73 sat 13 1 3.54 7.14 7.1 0.7 6 6.73_ 0.03 38.9 .11201 0.38 15590 ___

6___ 0.7 0.03 38.9_ 117720 _

14 5.36 7.04 7 1.31 3.8 119.5 23130 8.5 sat sat T La 14660 0 18 17 16010 14830 8 19 sat 20 0.86 "6.95 7 2.21 7.725_ 0.7 . 7 0 21 1 3.66 1 7.05 1 7.1 1 1.68 12.51 0

___ _ _ _ __ 127219 11470

__ i ~s e t set 13310 26 13840 27 40 110 1.13 23130 28 29 108.5 [ 1.44 18760 30 22520 sat set 31 170 i____ ___ ___ __

1 14740 1 1 1

,.2 3 2.07 7 7 3.87 0.1 5.725 4 0.025 112.25 0.13 16740 8,5 Sat Sat 5 -

zzz~i

______ I _____ [ ________ 15850 1 __ ~I __

St Sat 2008 CK gw renewal Table 2 update.xls Page 14 of 23 Table 2 OOEEQ-2.

Cook Nuclear Plant Groundwater Permit Renewal Application

,Locgtioft,

, Q-~ E04 'E-2 E-2. E-Q2. IEQ,2 '-E -2 -E0-22 EO2 IC- iEC-2 _ -*EQ!'":::Q2

-ýEC .E:2W'

. ToIaF *-,- -l -. -~ ~-

IMPTIMR 1 9 i.*rt *,H I.1 - Ossolaed Inorganic Nitrooen Animiinia NiIraIe~--.M5iIe'~0isaolaad

- NihOnes N8rdnen ~les ThMa I ~ fl2alcl,.~ Frea~a~Vaa~nfl8ibI,~s8 -

--7; sITT41, "DAY - .UNilTS -

7 8 13680 9 1 12050 9 Sat Sat 10

-1 1.68 6.9 6.9 2.89 14.92 0.1 148 002 33.7 0.63 21420 3.87 7.17 7.2 2.03 0.01 0.09 113.5 0.88 21770 12 25880 52 13 21080 8.5 Sat Sat 14 17940 ci 13060 a,

.1 16420 0.83 14.5 21930 2 09 1Sat -Sat E 18 1.96 6.97 7 3.6 0.01 1 0.025 110.3 0.13 22450 03

____1 __ 1 it 1____1.

.. L ____1 - F=

-218101 2270 [ -9 9 Sat Sa 21 ___

22 23 24 8, 8 3 5 5.9 2. 9 0U035 36.4 111 0.75 17160 25 3.28 0.04 111.5 1 0.5 24010 28 27 Sat Sat 28 29 C0 -7 1 4.71 1.' .3 0n03 121.5 0.75 224901N9 sat sat 1.' 0.025 ~1 1 19S401t

D3 20790 _ 9.5 sai sat 6

7 8 0.63 4.7 0.03 1 32.2 1 102.5 1 9 0.88 0.025 0.38 25710 10 23110 11 26680 12 17840 13 5, 19120 14 14080 -.

15 _ 25030 "168 295 6.76 3.33 5.3 0.015 38.7 106.5 0.125 19470 17 24350 8.5 sat sat 18 18920 19 E 19080 20 11370 19110 22 7.24 7.2 1.19 17920 23 29830 24 25 51 0.01 [ 0.01 26 27 10660 7.35 7.4 4.29 2.34 16870 17020 9 sat sat 0.12

__ __ __ __ z~I~ 15370 2008 CK gw renewal Table 2 update.xIs Page 15 of 23 Table 2 DOEEQ-2

K Cook Nuclear Plant Groundwater Permit Renewal Application

=6c9O.. d,0~ 6~ 2 0 !FM.O24F!34 I

~~2L ~E0-2 ~:~x.j~; §:47 hr. .lEd.24 ..EG-2. 60-2 0-0

. . ..... .. * ... * : 1I ¸ * -

• 1I

• ygve

'1 lInorganid ..

I<ial

--.- I

-Nufe

ýL , I -ý- ýi'c de" Ptids-Flaw:I Fo~-~

&4..jj, 7,jC6i4ý,

-*: :60000'-- 121900DOO I' d Vagitition

. I 61166 rIP

-- ý,ýI rn,& I flL. W'/ GPOD. ,IGRYI::4V"Fdet. SaVUnsat Sat/Unsat 5 3.31 7.3 7.3 2.32 3.19 0.65 109 0.88 22950 I 6 7.4 2.17 1.01 0.03 107 0.63 21920 7 24400 8 18760 9 16620 10 12850 15490 12 7.27 7.3 2.77 8,138 0,11 .8 16 17750 13 17680 14 0.25 7.19 7.2 4.91 1.94 19990 sat sat 0*

1 15 16 I

____ _______ 18570 1___I___ ) __

14710 17 10870 0

18880 0 18040 sat sat 20 21 { . {22~660 ' '

22 1.74 7.12 7.1 0.04 108 23

24. 13170 25 4.54 26 2.23 7.09 7.1 5.8 0.12 34 0.38 27 1.61 7.1 7.1 28 .17090 21940 ____ _ 8.5

___ E at 29 20380 30 2 [ -7.0-5 T 7.05 T 3.15 1 _ _ 36.2 124.2 0.75 14990 7.17 7.17 ," 3.3 3.35 0.13 16010 4 15680 5

122 14530 17160 sat 14220 9640 17290 10 1.84 7.41 7.4 3.73 35 27.7 114 1.13 20300 9 Sal sal 11 . 3.01 7.39 0.03 107 1.63 21650 2 12 T9680 9 sat sat 13 1640 14 11980 M

9

.2ý 15250 17 3.07 7.45 7.5 19280 as 0.03 36 114.5 as 18 1 1.79 7.21 7 5.03 0.025 1 117 14380 E 19 21570 8.5 sat Unsat 10 22 19510 8 sat Unsat 21 .

22 16640 10330 19260 8.5 sat Unsat 2.08 4.447 0.015 4.4 0.032 16230 25 7.405 0,01 1 7.36 107.75 0.75 22080 8.5 sat sat 18800 28 1446O 29 20900 30 85 31 16580 sat sat T

7.15 7.15 0.99 4.765 0.94 3.8 102.5 0.13 21270 [

7.23-] 7.23 1 2.53 6.645 104 0.13 15880

. ,2 1 9 20

______J

____ I ___ ____ 3 L............

2008 CK gw renewal Table 2 update.xls Page 16 of 23 Table 2 OOEEQ-2

(rN Cook Nuclear Plant Groundwater Permit Renewal Application j ~ E- 2 Eý2 '.Ed-ij2 iký E2.-tEi-2j1 ;EO-24 ,j Q2- 02 02 E0;j~ 9021 6- 2l

• a "

I PARA . issolednrai irt irt, Dsovd . lw Fo ',E UMT ;Miý pH J j'Nirgn a _ _J _ Ammoraa'

_ iNitoen ýNitrogei, Sodium. -iold Pop rs (Meas),

00 (Calc) Freeboif ijVenetationDik lns, 1(00METER 0

9Q.0 1 moif, Vmg-rfql I ms hiol-Mr maw I 16590 elt 8.5 ISatAjSatlisat Sagl-ltn~at Sat 4 14780 5 10750 6

7 1.55 4.375 0.21 4.1 - 0.065 32.8 112 0.5 8

9 7.5 0.98 14.71 . t13.6 1.08 0.03 10 11 12 13210 ___

13 Q~

14 13630 [ Sat sat 7.2 0.03 33.2 109 2.5 20090 1 1 1 I 15 12.2 0.055 107.5 Q:

16 in 17 17970 U)

• 0 18 19-20 13910 E 21 03 37.9 135.25 0.58 . 9 sal 20100 sat 22 22290 23 04 2.25 17680 24 19900 9 sat sal 25 17830 26 13670 27 22300 9 sat sat 28 25010 29 21700 30 7: 22750 20260 17880 2 1 1 1 18150 3 1 1 1 13980 sat sat 4 0.851 7.34 7.3 1 4.34 1 5.54 0.01 5.8 0.031 31 0.13 23200 9 5 4.47 7.35 7.4 1.12 19.905 9.36 10.5 0.045 121.25 0.5 29630 6 29170 7 32730 9 sat 8 17800 9 11930 10 19420 11 5 27100 9 sat 12 25650 PI 13 U) 14 15 23410 n.

E 16 0=

22150 17 19940 u) 18 2.55 7.08 8 32410 19 ____1 2.33 7.02 32190 20 31560 21 03 28840 22 20590 23 20850 24 30190 25 3.47 7.25 7.3 0.93 33.685 6.16 - 32720 26 _ _ 1 1 . I I 31380 27 3.81 7.18 7.2 1.23 25360 28 _ 32320 29 29620 30 26400 2008 CK gw renewal Table 2 update.xls Page 17 of 23 Table 200OEEQ-2

Cook Nuclear Plant Groundwater Permit Renewal Application Location tt1 EQ-2 EQ-2 EQ-2 I

EQ-2

- I I EQ-2 EO-2

...>. l-l----~-l I0-2 EO-2 I

P0-2 I -2 I

R)-2 I I-t P0-2 EP02 M0-2 ioai PARA Dsolved Inorg-ac Nilrate NiDtrit Flow Flow E o= MFTPR Bfl pnH pH Oxygen Nitrogen Anvo* Nitogen Nitrogen Sodium Chiwode Phosohorus (Mews) (Ca*c) FreeboardlVeoetafionl Dike In9o 8

=E E.

Max DAY UNITS 9.0 1 32560 2 54.4 25270 3 32.3 15.9 16.3 0.1 142 32700 Sat 4 33790 5 26830 6 29760 7 26260 8  !.12 26060 9 30010 10 11 a 12 1.91 46.675 0.01 9 Sat Sat 13 14 23650 15 16 17 7.07 7.1 is 37.043 0.02 3.75 33570 0 18 1.8 7.11 7.1 .15 40.825 0.01 E 19 20 21 22 7 M26040 9 Sat Sat 23 7.91 7.2 7.2 .5 2.75 25630 24 24.005 0.37 23.6 0.035 144.25 2.38 22260 25 26 25b30 9 z at Sat 27 27070 28 __ 208101 __1__ __I 29 23260 9 Sat Sal 30 26180 31 7.17 7.17 3.76 25.885 0.01 25.8 0.075 27180 1 21540 9 sat sat 2

22490 3 15310 4 16440 5 15250 6 19550 7 7.25 7.25 5.68 28.925 0.01 43 152.9 _ 17730 9 sat sat 8 16170 9 15880 10 14120 11 9120 .9 12 18400 13 18300 9 sat sat

.0 14 18100 15 7.38 7.38 2.71 14.04 0.01 40.8. 147.9 0 18100 E 16 17100 9 sat sat 0 17 B6ow E S.,

18 8300 19 1688O Q0 20 7.12 7.12 2.78 17.51 S.C 37.6 136.9 0 16700 21 14040 9 sat sat 22 8930 23 6670 24 8270 25 8040 26 15020 27 28 3 03 29g435

- 001 40.2 145 0.56 sat 2008 CK gw renewal Table 2 update.xis Page 18 of 23 Table 2 OOEEQ-2

Cook Nuclear Plant Groundwater Permit Renewal Application Samp* E-2 IE"-2 IE-2 EI-2 1 E0-2 E1-2 EO-2 E,-2 I EO-2 E-0-2 EQ-2 1212 S2 -2 E

PAMA Msoha d dInr Nitra Nitrite Flow Flow METER BMO5 IpHN oN OxyoanlNitroon A Nitrogen NllrooW Sodi Cholorde IPhoachoni (Memt 6 LIMITS (Callc Froeboard Vageatio* l Iknsp I UMrrS Min Max 0- 0 6.5 9.0 1 nl I n I nI mop I, Ml I GPD Feet SBtLJunsal SaUtUnr 19980 30 15810 1 13890 2 9080 3

4 5

6 7 3.78 7.2 7.2 3 24.515 0.9 23.6 0,015 43.4 132 1.63 16380 8 14860 9

9970 10 14720 sat 11 12 I 6.74 7.92 I 7.27 7.25 7.25 2.76 10.409 0.874 9.5 0.035 149.5 13150 18080 13 16660 14 17350 a,,

15 'I E

18 12.09 7.23 E 107 127101 .8 16440 21 22 11050 23 8950 24 14350 9 sat sat 25 8720 28 5 7.17 0.02 38.6 146.5 0.13 14870 27 1f4480 -9 sat 28 1 29 30 31 1

2 0.36 31.3 3 4.63 139 0.13 16650 4

5 6

7 0.93 0.015 39 144.5 0.13 18300 4.04 7.38 7.38 3.13 147.5 0.13 22740 16320 1 9 sat 12 13 .2 14 0= 15 A 7.10 2.04 14.1 3.69 40.5 134 0.13 14890 8.5 sat sat 16 7.2 7.23 2.73 18.325 8.01 10.3 17 18 17730 0E 19 10250 20 8870 21 22 2.03 1. 1 2.15 117.02[ __.4 6.4 j10.6 0_52_

j0.02 28 2008 CK gw renewal Table 2 update.xls Page 19 of 23 Table 2 00E EQ-2

Cook Nuclear Plant Groundwater Permit Renewal Application Location EQ-2 EQ-2 EC-2 E--2 I E0-2 I E0.2 EQ-2 I EQ-2 I EQ-2 I EQ-2 EQ-2 EQ-2 EC-2 EQ-2 E E

PARA METER I

BD H p Di--

Ogn Inorganic N~oe Nitrat ktr*J'lArtmw-Jl en Ntrie Dissolved I I PI~o,*ono I IFlow 0E NW Soiu

____ I Ctorke I hoah 4 mVt man GPD 9580 14660 29 2.42 7,48 7.48 4.17 17.52 0.7 16.8 0.02 51.8 161.4 16440 30 18490 31 3.48 25.36 1 2.64 22.7 0.02 1 0.38 14440 1 16380 2 10580 3 0 1200O 14120 18330 9 sat sat 6 4.51 7.14 7.14 1.17 27.895 4.57 14840 7 [ 17990 8 0 17730 0 11900 0 11090 11 0 12 1.4 12.875 0.75 12.1 0.025 49.2 13 4.39 0 145.5 1470 ___

14 19770 __

,0 15 1 14470 1 2, 16 0 17 0 E o

18 0 14190 19 14600 20 16060 9 sat sat 21 17820 22 15680 23 0 17270 24 14690 25 12280 9 sat sat 26 2.25 23.545 0.13 23.4 0.015 51 140 2 20500 27 0.93 27.195 1.07 26.1 0.025 2.88 20510 28 0 18330 29 22920 1 139*0 2

14260 3 7220 4 17520 5 130 40.7 27310 6 24200 7

18150 8 17540 9 13940 150 17130 9 sat sat 11 28320 12 10.95 7.25 7.3 1.05 23.84 4.4 19.4 28330 13 24820

-4 22800 9 sat sat 15 16870 as 16 14920 M 6E W 17 14230 18 28960 19 8,93 25390 z 133 1.88 29230 8.5 sat sat 22570 13140 16510 23730 29260 2008 CK gw renewal Table 2 update.ats Page 20 of 23 Table 2 ODEEQ-2

Cook Nuclear Plant Groundwater Permit Renewal Application Locamon EO-2 E9-2 -EQ-2 I EC-2 EQ-2 I EQ-2 EQ-2 EQ-2 I EQ-2 I EQ-2 I EQ-2 EQ-2 E--2 0

PARA METE LMT Ma Oxyen InOrganic Nirogen N*-- I W NafxNJo M[w ie I Sodium Psou Row D

I E

Mk a _

0002a 00

_(_)Fr__bV_

DAY UNITS mg/I 16.5 9.0 1 mg4 I I I I mA I nv mA m*A I molt I Wt I GPD I GPY I Feet ISatJnsat SalRJnam

---

I 8.33 7.23 1 7.2 1 0.92 147.751 12.1 1 35.6 1 0.051 47 1 136.51 1.88 30 23040 2 6.63 7.31 7.31 1.48 50.593 19.1 312 1 0.293 4861 1128 1.2 38720 9 sat Sat 3

4 5

28850 24210 30070 8 14.55 0.2 0.03 53.8 140 2.63 33390 9 14.6 13.9 0.025 136.5 4 24510 9 Sat Sat 10 29900 29990 8.5 Sat Sat 13 26360 at 14 15 183.02 e.71 6.7 2.52 60.82 0.2 60.6 0.02 7H 4 17 2.52 6.87 6.9 2.62 55.92 0.1 55.8 0.02 143 5 E

1 22480 20 24710 21 3OD04 22 1.58 7.06 7.1 3.21 33.425 0.01 33.4 0.015 42.4 24480 23 3.39 30.53 0.01 30.5 1 0.02 1 144.5 23550 24 25 24770 9 Sat 26 27 28 29 9 30 1.25 1.75 Sat Sat 4.05 7.27 7.3 3.41 13.915 4

5 1jI 12940 1 1I 2.25 7.32 7.3 4.51 9 sat sat 3.89 7.41 7.4 4 11.62 001 11.6 0.(

9 sat sat 10 11 15430 12 7930 13 7.26 1 7.3 1 4.5 18550 14 19670 15 24910 9 sat sat E 2o 16 17 18740 9 sat sat 20370 18 10550 19 E 18670 20 111 15.8 0.028 38.1 19250 21 20590 22 2.07 20 0 0.025 125.5 1.38 18450 23 2008 CK gw renewal Table 2 updateAs Page 21 of 23 Table 200OEEQ-2

Cook Nuclear Plant Groundwater Permit Renewal Application Sample

_= Location E(-2 0.-2 F0-2 0---2 R3.7 C2 P-F2 I P0--2 I P02 P-*.2 PO-2 EP02 EQ-2 EI -2 e Iowl E PARA nDved garc Nitra Wite Dissoaved Flow Flow (Men) (Calc) E METER BOD5 O..en N1 MeO Ni'booen Nibotere Sodium Chloride Phosohorus 0 s=

24 14850 25 16800 26 11590 27 19230 28 19300 29 24600 sat 30 18430 31 17790 1 11430 18270 sat 17780 4 5.02 7.03 7.03 1.01 14.805 2.19 12.6 0.015 1.25 21410 5 18440 6 21360 8.5 sat sat 7

8 9 17640 9 10 24790 11 19110 12 20630 13 20220 c6 14 21370 9 15 16 sat 17 E

18 01 19 2.97 7.43 7.4 2.32 19.583 0.35 19.2 0.033 33.3 108 6 25270 20 21 22 14670 23 24 1.14 7.46 7.5 4.69 25 2.1 7.28 7.3 2.93 17.495 0.18 17.3 0,015 1.75 22650 26 27 28 18250 29 11780 30 16520 1 18100 2 16880 3 16040 4 14230 5 13760 6 9370 7 20670 8 0.03 126 1.25 13 14730 2030 9 sat sat 9 0.025] __J _ 1.38 [20980] _ _ _ _

10 19160 8.5 sat sat 11 22830 12 13260 13 15630 09 14 sat sat 15 CD 0o o= 1.91 7.34 16 7.39 7.4 3.74 20.03 0.01 20 0.02 120.5 1.38 18220 aE 17 18 19 19120 20 21 2006 CK gw renewal Table 2 update.xls Page 22 of 23 Table 2 00E EQ-2

Cook Nuclear Plant Groundwater Permit Renewal Application i ampie

~fl.9 I FA~ FW.t-I 1 -W 2 m-,9 A.9 1 m.11 WFA.- I :M2I WL METER BOD5 0`l 01, E

Oxyme Nimow Ammffonia wowmge dowe Sodium C111odde (Mien) (Calci Freaboard Veleation Dikels E UMITS Min max 0 SO=0 21900D00 DAY UNITS 65

&*t 9.0 Mg moll mAt mm MO m9 mn* mo/ GPD GPY Feeti Sat/Unsat Sat/Unksm 22 2.15 7.34 7.3 3.01 8.928 0.01 8.9 0.018 31.5 118 1 18100 23 2.5 7.39 7.4 3.38 12.24 0.01 12.2 0.03 117 1.25 21080 24 21240 18.5 1 sat sat 21 23820 26 15420 27 146 28 1694Sola sat 292.13 177.2 .2 3.9 785 0.0ý1ý 7.8 0.0 29.8IEý 110 0.3 27260 1E 30 3.6 7.27 7.3 2.8 1 13.425 0.3 13.1 0.025 105.25 1.75 22330 31 24820 1

2 18"0 ci 3 11040 4 19440 5 17700 6 3.2 0.025 1 0.88 21580 7 '4.5 0.02 1.3 17390 8 0 21220 9 0 11680 70- 0 14170 11 12 I1__ 1 _ 1121401 1_ _

13 14 9 15 16 ID 17 4 18 79 20 21 22 23 24 25 26 F7 28 29 30 31 No. ObservatLins 293 299 159 217 302 284 268 281 1 1319 -

Murmjn 0.1 6-58 658 0.7 0 001 0.5 0003 F 4-7-70--

A 3.2 7.3 7-2 29 18.1 2.1 17.9 1.3 MaonmiD 15.04 8.07 7.6 &32 6157 47.7 81 16F04 90t1 Percentile 6.4 7.7 7.4 5.1 39.9 7.5 35.4 0.2 95th Percentile 8.3 7.8 7.5 5.7 47.8 10.A 41.6 0.6 2008 CK gw renewal Table 2 update.xls Page 23 of 23 Table 2 ODEEQ-2