ML090540702

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American Radiation Services, Inc. Laboratory Analysis Report No. ARS1-08-01563
ML090540702
Person / Time
Site: Indian Point  Entergy icon.png
Issue date: 09/15/2008
From:
American Radiation Services
To: Noggle J
NRC Region 1
References
ARS1-08-01563
Download: ML090540702 (10)
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Text

2609 North River Road, Port Allen, Louisiana 70767 (800) 401-4277 -- FAX (225) 381-2996 RNATIONAL American Radiation Services, Inc.

Laboratory Analysis Report ARS1-08-01563 Preparedfor.

Nuclear Regulatory Commission (NRC)

James Noggle USNRC Region 1 475 Allendale Road King of Prussia, PA,19406 James. Noggle@nrc.gov Phone: 610.337.5063 Fax:

1))'h Fr x &A il1\a" . -

~#nager Review4 Management Revi*

Notes: Arnencan Radiation Services, Inc. assumes no liability for (he use or intarpretation of any anflytifal results provided other than the mots of the analysis itself.

Reproduction of this report in less than fut requires the written consent of the client.

Contact Person: Questions regarding this analytical report should be addressed to:

Project Manager ProjectManagers@amrad.com Phone: 225.381.2991 Fax: 225.381.2996 LELAP Cert#.30658 NELAP Cert# E87558

2609 North River Road, Port Allen, Louisiana 70767 1 (800) 401-4277 FAX (225) 381-2996 INTERNATIONAL ARS Sample Delivery Group: ARS1-08-01563 Request or PO Number: N/A Client Sample ID: MW-66-21-(005)07-29/1148 ARS Sample ID: ARS1-08-01563-001 Sample Collection Date: 07/29/08 11:48 Date Received: 8/12/2008

. Sample Matrix: Aqueous Report Date: 09/15/08 10:19 Afal5ysis

  • " A nalys' f Analysis T ,.MC Qu~al Analysis I Analysis Analysis
  • ,Analysis I AnislyalO Analysis Tracer/Chem
  • l~C Date/rime Technician Dep o. Reslts E 2 . ............. ......... Units Test Method RecoNer t N/A MN-54 -o.784 00.782 2.600 1.300 S pCi/L I ARS-007/EPA 901.1 8/21/08 16:01 )LA FE-59 0 952 1.529 5.140 2.570 pCi/L ARS-007/EPA 901.1 8/21/08 16:01 JLA N/A CO-58 -0.573 0.778 2.600 1.300 i pCVL .1 ARS-007/EPA 901.1 8/21/08 16:01 " LA . N/A O-60 0622 . 0.650 2.240 1 1.120 1 pCi/L. ARS-007/EPA 901.1 8/21/08 16:01 31A N/A ZN-65 0.000 2.499 1 8.400 4.200 ' PCi/L ARS-007/EPA 901.1 8/21/08 16:01 .LA N/A NB-95 J -0.738 1.953 2.81D 1.405 CA 8 N/A ZR-95 0783 1264 4.240 2.120 ' pCI/L I ARS-007/EPA 901.1 8/21/08 16:01 ILA N/A

-0.289 1.169 2.960 1.480 pci/L ARS-007/EPA 901.1 8/21/08 16:01 3LA N/A CS-134 C-137 -0.783 0858 1 2.850 1.425 pCI/L t ARS-007/EPA 901.1 8/21/08 16:01 JLA N/A BA-140 S " i 4.539 I .537 10.400 5.200 pCi/L AR5-O07/EPA 901.1 8/21/08 16:01 2LA N/A ARS O-EPA 901.8/21/08 1 . . A......

LA-140 -0.601 12 3.310 I 1.655 J pCI/I ARS-007/EPA 901.1 8/21/08 16:01 21LA j N/A SR'90 1.005 730.*23o*10 *!

0.216

  • 130 666 0.588 163239 j 0.277 7,9.400 .

pCi/L p/I .

I ARS-032/Eichrom SRW-01 ARS-054/EPA 906.0

{

8/28/08 17:35 9/8/(0 8:39 I 8JS BS 58,00%

N/S i

NI-63 3.0899 4.4642 7.4175 3.6493 pCl/L ARS-022 8910/09 2:05 B3S N/S

____ _* __ _ Ij__ _ - _ _ i _ _ _ _ ___/___

I NOTES: Shipment# 08-152 rý=A ci ~ Rri ,1 c5 £1 P5roct Manager keCýr -

Notes: American Radiation Services, Inc. assumes no liability for the use or interpretation of any analytical results provided other than the cost of the analysis Itself. Reproduction of this report in less than full requlres the written consent of the client.

LELAP Certificate# 30658 NELAP Certificate I E87558

2609 North River Road, Port Alien, Louisiana 70767 1 (800) 401-4277 FAX (225) 381-2996

- INTERNATIONAL ARS Sample Delivery Group: ARSI-08-01563 Request or PO Number: N/A Client Sample ID: MW-66-36-(005)07-29/1205 ARS Sample ID: ARSI-08-01563-002 Sample Collection Date: 07/29/08 12:05 Date Received: 8/12/2008

. Sample Matrix: , Aqueous Report Date: 09/15/08 10:19 Analysis Analysls Anlss Anlss .Analysis Anaysi iL Analyi Tracer/Chern Descripthon Results Error +/- 2 s M l " Ua! Units I Test MethOd - Date/Time Technician I MN-54 0.282 1 0.685 " 2.340 1.170 pCiL ARS-007/SPA 901.1 1-8/21/08 16:00 1 LA $ N/A N/A FE-59 1.794 1.079 3.5S0 1.775 pCiL ARS-007/EPA 901.1 8 /21/08 16:00 ILA ILA N/A it CO-58 ___ ____ 0.007 0.686 2.260 1.130 I pCi/L ARS-007/EPA 901.1 8/21/08 16:00 t ILA N/A CO-60 0.008 0.687 F 2.450 1.225 1 pCI/I ARS-007/EPA 901.1 I 8/21/08 16:00 )LA N/A ZN-6S _ "0.101 1.311 j 4.500 2.250 pCi/Li ARS-007/EPA 901.1 8/21/08 16:00 " LA N/A NB-95 -0.715 0.732 2.440 1.220 pCi/L ARS-007/EPA 901.1 8/21/08 16:00 .A N/A ZR-95 -0.232 6.055 1 4.030 2.015 pCi/L I ARS-007/EPA 901.1 8/21/08 16:00 ILA. N/A CS-134 -0.438 2.482 2.540 1.270 pCi/L ARS-007/EPA 901.1 8/21/08 16:00 -- A N/A C13.270 0.681 2.300 1.150 pCV'L j ARS-007/EPA 901.1 8/21/08 16:00 ILA N/A BA-140 -4.173 26.705 10.300 5.150 pCI/L ARS-007/EPA 901.1 8/21/08 16:00 LA I N/A LA- 140 1 r2.118 2.508 I 3.430 1.715 pCi/L ARS-007/EPA 901.1. 8/21./08 16:00 ILA - N/A SR-90 14.269 1.149 0.566 0.267 j pCi/L ARS-032/Eilchrom SRW-01 8/28/08 17:35 BS 6600%

H-3 4630.409 499.979 160.739 j 79.153 pCi/ I ARS-054/EPA 906.0 9/8/08 12:47 N/S NI-63 7.4-21 4 .7 7.4096 i 3.6455 - , CI- AR--022 9/10/0-8 6I:4 8)5 N/S

--- -----. me......

NOTES: Shipment# 08-152 -

  • Prdject Manager R* n.. .

Notes; American RodiaLion Services, Inc, assumes no liability for the use Or Interpretation of any analytical results provided other than the cost of the analysis itself. Reproduction of this report In less than full requires the written consent of the client.

LELAP Certificate# 30658 NELAP Certificate # E87558

NRC FORM 303 St U.S. NUCLEAR REGULATORY COMMISSION LABORATORY USE ONLY PAGE 1 of 2 (4-2004) CONTROL NUMBER REQUEST FOR ANALYSIS AND CHAIN OF CUSTODY LABORATORY:

SAMPLE LOCATION (LICENSEE) LICENSEE NUMBER DOCKET NO.

INDIAN POINT ENERGY CENTER SAMPLE SUBMITTED "

  1. TOTAL TYPE -VOLUME WEIGHT DATE SAMPLES SUBMITTED PRIORITY fl ROU~iNE GROUND WATER 2000 ML -2 Kg I [] URGENT SAMPLE COLLECTION INTERVAL MONTH DAY YEAR TIME START INSPECTOR RESPONSIBLE TELEPHONE NUMBER STOP:

Jim Noggle (USNRC) (610) 337-5063 LIST DESIRED LIST DESIRED ANALYSIS TO BE PERFORMED LLD (Optional) OTHER TYPE OF ANALYSIS (Specify) LLD (Optional)

[Z GROSS ALPHA (GA) F-7 STRONTIUM-90 (Sr90)

] GROSS BETA (GB) NICKEL-63 (Ni63)

RELENQUISHED BY RECEIVED BY DATE TIME REASON FOR CHANGE OF CUSTODY

-56COIRI s~ro~"wq:1-$ r- 8-6-2006 /030 Prer /'? jlA, FEE RECOVERABLE NO YSTAC NUMBER REMARKS:'

NOTE: SAMPLES WILL BE DISCARDED AFTER ANALYSIS UNLESS REASON ARE NOTED IN REMARKS ABOVE.

NRC FORM303 (4-2004) PRINTED ON RECYCLED PAPER

NRC FORM 303 U.S. NUCLEAR REGULATORY COMMISSION a LABORATORY USE ONLY PAGE 2 of 2 (4-2004) CONTROL NUMBER SAMPLE RECORD - Continued LABORATORY:

SAMPLE SAMPLE NAME COLLECTION REMARKS, PRESERVATIVE NUMBER AND DESCRIPTION DATE/TIME ANALYSIS REQUESTED, ETC.

MW-66-21-(005), Ground Water Split Sample of MW-66-21-(005) Sample is unfiltered &unpreserved. Analyze fo c, _ _ Gamma Spec, H3, Sr9O, Ni63 MW-66-36-(005) Ground Water Split Sample of MW-66-36-(005) Sample is unfiltered & unpreserved. Analyze to

__ Gamma Spec, H3, Sr9O, Ni63 NR ,OMO (420)PITDONRCCE AE NRC FORM303 (4-2004) PRINTED ON RECYCLED PAPER

2609 North River Road, Port Allen, Louisiana 70767 1 (800) 401-4277 FAX (225)'381-2996

  • OA1 RCNRDATION SERVICES, INC.

QC Results Report Sample Delivery Group: ARSI-08-01563 Date Received: 8/12/2008 Laboratory Control Sample Evaluation Antclysis Q* Analyt. Analysis CSU I C) DC Expacted Report Analysis Analysis Analysis BItch Type Resul*s I Valeu Units Testrasthod Date/Time Technidan Percent Recovery Acc Accaptanca N/A LCS Ni-63 237.73 55.2 8.6999 204.44 pCi/L ARS-022 9/9/08 13:28 BIS 116 75%-125%

Blank Evaluation Antlychs N/A Aays 1QC1 yp Type

_atch MBL Analyt.

Ni-63 1Analysis R__ut_

'1.023 I Casis IEpected 4.5347

( )

Ip.~

7.6916

  • ile NA U ReotAIay" Report Units pCi/L An(lysis Test Method ARS-022
  • Analysis Data/Tim 9/9/08 21:58 aj AWslyala
  • Tedhnician B)S RER Duplicate Evaluation Analysis Batchs QC Type Analysis Description etst 1 +/- CSU I( (1) Result2 CSU 2 (is) Q.*l Analysils Units Analysis Tea Maehod Arnlysi Date/Tin.

Analytis Techinician R

RER cRER Acpanc.R N/A LCSD Ni-63 237.73 55.2 229.996 53.406 pCl/L ARS-022 9/9/08 17:42 BI5 0,07 DER Duplicate Evaluation Analys QC alyi sI (1 ) Result 2 CSU 2 () Qua Analys is Analyysi Analysis DER NAtch IType IDes 27iption 5 229.9Un96t 5e.T6t Method Dat9/Tim974.5. echn/ia8 20 N/A ILCS0 NIM-63 237.73 1 55.2 1229.996 153.466 1 PCI/L ARS-022 9/9/08 17A42 -035 0.20<

Projnect mi"nager Rlk" Notes: American Radiation Services, Inc. assumes no liability for the use or interpretation of any analytical results provided other than the cost of the analysis itself. Reproduction of this report in less than full requires the written consent of the client.

LELAP Certificate# 30658 NELAP Certificate

  • E87558

2609 North River Road, Port Allen, Louisiana 70767 1 (800) 401-4277 FAX (225) 381-2996 MERICAN RADIATION SERVICES, INC.

QC Results Report Sample Delivery Group: ARSI-08-01563 Date Received: 8/12/2008 Laboratory Control Sample Evaluation Analysis QC Anetyte Analysis I (1 et Expected Qual Report Analylo Analylis Analysli Percent LCS

.61.4 Batch Type Results I MDc I value Units I TeWt Method Dote/Time Tachnici.n Recovery (%) AccIltlnce ARS1-B08-02293 LCS H3 1136.06 " 16 158.48416 1270.45 pCi/.L ARS-054/EPA 906.0 9/4/08 128:01 B35 89 75%-125%

Blank Evaluation A

Anlysis

&Btch QC Typ

] o 1 Analysisi je Results CSu (1s) MDC Expected value lReport.

Unit.

Analysis Test Method Analysis Date/Tkne Analysi Technician ARS1-B08-02293 M8L H3 67.923 94.439817 158.41962 NA U pCVL ARS-054/EPA 906.0 9/5/08 2:16 BIS RER Duplicate Evaluation Anallysis Qc Analysis Reut1 CU1 (1 e) Result 2 AnSU Unt Anlyi Anaysi ,Aayi ER Ac Botch Type Description Res 1ult CSU CSU 2(1 Qs s) alUnito Teat Method Date/Tim. Technic ien ER AcceR*llRtn tn.R j I_IF I_ I _ I_ _ F11 I n_ .

ARS1-808-02293 LCSD H3 13136.06 161.4 1143.2572 161.9636 pCi/L ARS-054/EPA 906.0 9/4/08 22:09 BJS .0.02 <I DER Duplicate Evaluation Analysis Batch Anlyi TQC1Analysias Tp Q-yI Dc I .

ascripsion r

Result I I

CSU 1 (1I)

I Result 2 I

CSU 2 (1.) Qual

[A~n-.i.iT

[ Units T

T AsOlysi.

Meth Moisod

] Anlyi Asyao Ata/lysi I

[Analyst.

Technicayn DE DDER DceRtnc arpne ARS1-808-02293 LCSD H3 1136.06 161.4 1143.2572 161.9636 pCi/LI ARS-054/EPA 906.0 9/4/08 22:09 BIS 0.06 < 3 Matrix Spike Anlyal Anl QC naly* A (1 ) Unspiked Report Analysis Analysis Analysis Percent LCS Spike Con. Qul ___ A nc.

Botch Type Results Activity Unit. Test I iMethod Dote/Time Technicton Recovery(%) Acceptonce Range ARS1-808-02293 MS H3 13755.623 1429.035 1862.953 13970.11 pCC/L ARS-054/EPA 906.0 9/5/08 6:24 83S 85 609/o-140%

Proj ct Manager l Note": American Radiation Services, Inc. assumes no liability for the use or interpretation of any analytical results provided other than the cost of the analysis itself. Reproduction of this report in less than foll requires the written consent of the client.

LELAP Certificate# 30658 - NELAP Certificate # E87558

2609 North River Road, Port Allen, Louisiana 70767 1 (800) 401-4277 FAX (225) 381-32996 AMERICAN RADIATION SERVICES INC QC Results Report Sample Delivery Group: ARSI-08-01563 Date Received: 08/12/08 Laboratory Control Sample Evaluation Analysis BRtch Qc Type Ana1te Analysi Results sC I (1 6) DC Expected Value If Report

,Units AnalysisI Test Method Analysis I

Analysis TeR T Percent LCS 9

ARS1-808-02253. LCS Sr- 0 23.536 1.834 0.541 20.835 pCI/L ARS-032/FPA 905.0 8/28/08 14:29 BIS 113 75%-125%

Blank Evaluation Analysis Qc AnalYtO Analysis su I (I.) MDC Expected i l Report "Analysis Analysis Analysis Batch Type Result. Vlue. Qul Units Test Method Dste/Time Technician ARS1-B08-02253 MBL] Sr-90 0.065 0.180 0.618 NA U pCI/L ARS-032/EPA 905.0 8/28/08 14:29 BIS RER Duplicate Evaluation Analysis Ietch Type Description Result ] CSU 1 (1 e) Result 2

[Units CSU 2 ( Xe) QulAnaly is M Analysis Test Method DAnaelysis Di/Tene Analysis Technician RA_ _.pt RER ARS1-B08-02253 LCSD Sr-90 23.536 1.834 21.025 1.649 pCi/L ARS-032/EPA 905.0 8/28/08 14:29 8S1 0.72 < 1 DER Duplicate Evaluation 1 QC a Al i AnalysisAnlysie Alysi 1 D DR E R Anlysi Retch Descrip oType Bton e CSU I 1 1 Result 2 CSU 2 (1.) Q unl i lysis.

Anysl Test Method Dete/Ti. Technigan E. cceptnceR Units ARS1-B08-02253 LCSD Sr-90 23.536 1.834 21.025 1.649 pCi/L ARS-032/EPA 905.0 8/28/08 14:29 831S 2.04 < 3 Proect Manager Revi Notes: American Radiation Services, Inc. assumes no liability for the use or interpretation of any analytical results provided other than the cost of the arlalysis itself. Reproduction of this report in less than full requires the written consent of the client.

LELAP Certificate# 30658 NELAP Certificate # E87558

2609 North River Road, Port Allen, Louisiana 70767 1 (800) 401-4277 FAX4aa5) 381-2996 QKI.'RS I INTERNATIONAL QC Results Report Sample Delivery Group: ARSI-08-01 563 Date Received: 08/12/08 '

Laboratory Control Sample Evaluation Analysis Retch QC Type nlt

[ Analysis Results S

CS I MC Expected Valcueo Qa Report Units Analysis Test Method Analysis Date Analysis Technician Percent Recovery (%)

LCS Acceptance Range ARS1-808-02204 LCS CO-60 .24779.00 495.75 200.80 25315.22 pCi/g EPA 901.1 .08/18/08 ILA 98 75%-125%

ARS1-B08-02204 LCS CS-137 15083.00 359.87 137.80 15285.98 pCi/g EPA901.1 08/18/08 ILA 99' 75%-125%

ARS1-B08-02204 LCS AM-241 34007.00 1235.00 277.10 34794.33 pCi/g EPA901.1 08/18/08 ILA 98 75%-125%

Blank Evaluation Anaiysis Q Aflyte Analysis CSU 1i(1) MDC Expected Report Analysis Analysis Analysis Batch Type Results 1 Value Units Test Method Data Technician ARSI-808-02204 MBL CO-60 -0.001 0.005 0.005 NA U pCi/g EPA901.1 08/18/08 JLA ARSI-B08-02204 MEL CS-137 0.001 0.001 0.004 NA U pCi/g EPA901.1 08/18/08 ILA ARSI-B08-02204 MEL AM-241 -0.001 0.014 0.006 NA U pCi/g EPA 901.1 08/18/08 JLA RER Duplicate Evaluation Analysis QC Analysis Qa myi RF ROE batch Type Description Result I 1ca al 2CU2(s Analysis Analysis Analysis Analysis RR Units Test Method Date Technician RER AccltanceeRange ARSI-808-02204 LCSD CO-60 24779.00 495.75 25129.00 492.32 pCI/g EPA 901.1 08/18/08 JLA 0.35 < 1 ARS1-BO-02204 LCSD CS-137 15083.00 359.87 15425.00 341.69 pCi/g EPA 901.1 08/18/08 JLA 0.49 < I ARS1-808-02204 LCSD AM-241 34007.00 1235,00 34050.00 1247.60 pCi/g EPA 901.1 08/18/08 1LA 0.02 < I DER Duplicate Evaluation\

Analysis Qc Analysis Result 1 rSU 1 (1 6) Result 2 CSU2 ( Is AnalysI Analyasi Analysis Analyss DER DER batch Type Description Units Test Method Date Technician AcceptanceRage.

ARS1-B08-02204 LCSD CO-60 24779.00 495.75 25129.00 492.32 pCI/g EPA 901.1 08/18/08 31LA 1.00 " 3 APRS1-B08-02204 LCSD CS-137 - 15083.00 " 359.87 15425.00 341.69 pCl/u EPA 901.1 08/18/08 ILA 1.38 < 3 ARS1-BOB-02204 LCSD AM-241 34007.00 1235.00 34050.00 1247.60 pCi/O EPA 901.1 08/18/08 ILA 0.05 < 3 QulyAssurance Notes: American Radiation Services, inc. assumes no liability for the use or interpretation of any analytital results provided other than the cost of the analysis itself. Reproduction of this report in less than full requires the written consent of the client.

LELAP Certificate# 30658 NELAP Certificate # E87558

2609 North River Road - Port Allen, Louisiana 70767 RS AMENANCA1 RDIAION (800) 401-4277 FAX (225) 381-2996 SEAVICES, INC.

Notes:

Comments:

1.0) Soil and Sludge analysis are reported on a wet basis or an as received basis unless otherwise indicated.

2.0) The data in this report are within the limits of uncertainty specified inthe reference method unless specified.

3.0) Modified analysis procedures are procedures that are modified to meet the certain specifications. An example may be the use of a water method to analyze a solid matrix due to the, lack of an officially recognized procedure for the analysis of the solid matrix.

4.0) Derived Air Concentrations and Effluent Release Concentrations are obtained from 10 CFR 20 Appendix B.

5.0) Total activity is actually total gamma activity and is determined utilizing the prominent gamma emitters from the naturally occurring radioactive decay chains and other prominent radioactive nuclides. Total activity may be lower than~the actual total activity due to the extent of secular equilibrium achieved In the various decay chains at the time of analysis. The total activity is not representative of nuclides that emit solely alpha or beta particles.

6.0) Ra-228 is determined via secular equilibrium with its daughter, Actinium 228. (Gamma Spectroscopy only).

7.0) U-238 is determined via secular equilibrium with its daughter, Thorium 234. (Gamma Spectroscopy only).

8.0) All gamma spectroscopy was performed utilizing high purity germanium'detectors (HPGe).

9.0) ARS makes every attempt to match sample density to calibrated density; however, in some cases, it is not practical or possible to do so and data results may be affected.

Method

References:

1.0) EPA 600/4-80-032, Prescribed Procedures for the Measurements of Radioactivity in Drinking Water, August 1980.

2.0) Standard Methods for Examination of Water and Waste Water, 18t 1992.

3.0) EPA SW-846, Test Methods for Evaluating Solid Waste, Third Edition, (9/86). (Updated through 1995).

4.0) EPA 600/4/79-020, Methods for Chemical Analysis of Water and Waste, March 1983.

5.0) HASL 300 Definitions:

1.0) BDL Analyte not detected because the value was below the detection limit.

2.0) ND Not detected above the detection limit.

3.0) Detection Limit The minimum amount of the analyte that ARS can detect utilizing the specific analysis.

4.0) B Method Blank 5.0) D Method Duplicate 6.0) MS Matrix Spike 7.0) S Spike 8.0) RS Reference Spike 9.0) *SC Subcontracted out to another qualified laboratory 10.0) NR Not Referenced 11.0) N/A Not Applicable 12.0) . Reported as a calculated value 13.0) False Positive due to interference from Bi-214 Notes: American Radiation Services, Inc. assumes no liability for the use or interpretation of any analytical results provided other than the cost of the analysis itself. Reproduction of this report in less than full requires.the written consent of the client.

LELAP Cert# 30658 NELAP Cert# E87558

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