ML090540698

American Radiation Services, Inc. Laboratory Analysis Report No. ARS1-08-01560

ML090540698
Person / Time
Site:	Indian Point
Issue date:	09/15/2008
From:	American Radiation Services
To:	Noggle J NRC Region 1
References
ARS1-08-01560
Download: ML090540698 (10)

Text

2609 North River Road, Port Allen, Louisiana 70767 (800) 401-4277 --

FAX (225) 381-2996 RNATIONAL American Radiation Services, Inc.

Laboratory Analysis Report ARS1-08-01560 Prepared for:

Nuclear Regulatory Commission (NRC)

James Noggle USNRC Region 1 475 Allendale Road King of Prussia, PA 19406 James.Noggle@nrc.gov Phone: 610.337.5063 Fax:

Proje" nager Review Management RA)iw Notes: American Radiation Services. Inc. assumes no liability for the use or Interpretation of any analytical mrults provided other than the cost of the analysis itself.

Reproduction of this report in less than tull requires the witten consent of the client.

Contact Person: Questions regarding this analytical report should be addressed to:

Project Manager ProjectManagers@armrad.com Phone: 225.381.2991

-Fax: 225.381.2996 LELAP Cert# 30658 NELAP Cert# E87558

INTERNATIONAL 2609 North River Road, Port Allen, Louisiana 70767 1 (800) 401-4277 FAX (225) 381-2996 ARS Sample Delivery Group:

ARS1-08-01560 Client Sample ID:

MW-66-21-(004)04-21/1410 Sample Collection Date:

04/21/08 14:10 Sample Matrix:

Aqueous Request or PO Number:

ARS Sample ID:

Date Received:

Report Date:

N/A ARSI-08-01560-001 8/12/2008 09/15/08 09:51 Analysis Analysis Analysis Descripion

.Results Error +/- 2 s MN-54 T

-70 0.795 FE-59 0.286 j

1.402 co-58

• 1.0S1 3.178 CO-60

-0.257 f

1.439 O

L i

Analysis MDC DLC iQua]

Unt 0

i units 2.660 I

1.330 1

pCl/L Analysis Test Method Analysis I

Date/finne Analysis Technician JLA Tracer/Chemr Rec/ery I

N/A i

ARS-007/EPA 901.1 8/25/08 16:06 4--

4.790 2.395 pCi/L ARS-007/EPA 901.1 I

8/25/08 16:06 JLA pCt/L ARS-007/EPA 901 1 I

8/25/08 16:06 ILA 2.590 1.295 2.660 I

1.330

__-0--.

I PC/L ARS-007/EPA 901.1 8/25/08 16:06 1

ILA N/A N/A N/A ZN-65 2468 2.376 6070 3035 pCi/L ARS-007/EPA 901.1 8/25/08 16:06 JLA N/A NB-95 0.215 0.712 2.410 1.205 pCi/L ARS-007/EPA 901 8/25/08 16:06 ILA N/A

• R95

-0.467 i

1,324 4 480 i

2 240 i

pCt/L ARS-007/EPA 901.1

,8/25/OR 16:06 3LA N/A 1

S5-134 0.907 0.817 2.720 1 1360 pCl/L i

ARS-007/EPA 903.2 8/25/08 16:06

]L N/A S *

-137 298 0.9 2030 i

.3050 pCi/L ARS-007/EPA 901.1 N/A AR1400.4679 1.6324 4.0 700.245 0

pC/L ARS 007/EPA 901.1 8/25/08 16:06 ILA N/A SLA1340 10510 0945 3.260 1.630 pCi/L ARS-007/EPA 901.1 8/25/08 16:06 ILA N/A I_

CSR-90 21.59222 9

0.390 pCi/L ARS-032/EPh 9 RW-01 8/26/08 13:46 82S 41.00%

I BA-14

-017982.3515.68 102.7001 58.350 p!/

AR-0/P

90.

/50 1-6 J.

/

H

'982.685 50568 162.621 80.080 I

pCi/L ARS-054/EPA 906.0 9/6/08 15:24 BS I

N/A Nl-63 1.5697 4.774 8.0688 I

3.9699 pCi/L ARS-022 BIS N/A.

-J NOTES: Shipment# 08-152 Project Manager Rqle~v Notes: American Radiation Services, Inc. assUrnes no liability for the use or interpretation of any analytical results providecl other than the cost of the analysis Itself. Reproduction of this report In less than full requires the written consent of the client.

LELAP Certificate# 30658 NELAP Certificate # E87558

.. RS 1INTERNATIONAL 2609 North River Road, Port Allen, Louisiana 70767 1 (800) 401-4277 FAX (225) 381-2996 ARS Sample Delivery Group:

Client Sample XD:

Sample Collection Date:

Sample Matrix:

ARSI-08-01560 MW-66-36-(004)04-21/1325.

04/21/08 13:25 Aqueous Request or PO Number:

ARS Sample ID:

Date Received:

Report Date:

N/A ARS1-D8-01560-002 8/12/2008 09/15/08 09:51 Analy Descrip MN-54 FE-59 its Analysis Analysis btan Results Error /- 2 s 0.465 0.767

-0.94 18.882 MDC DLC II Analysis 2.....

7.....

/.

I 2.570 1.285 1

pCI/L Analysis Test Method Analysis Analysis Date/Time Technician 8/25/08 16:06 JLA Tracar/Chern N/A ARS-007/EPA 901.1 5.700 i

2.850 pCI/L ARS-007/EPA 901.1 8/25/08 16:06 1

ILA N/A CO-58

-0.300 0.707 238 1606'A N/

S0190 pCi/L ARS-007/EPA 901.1 8/25/08 6

LA

"""" O

.'"'2 3...

. -- 0"3....

1. 0 i

1,.390 i

pCi/L ARS 0 7/

A 90.

8/25/08 1 : 6

3.

/

CO____60_ -1.62_3.07_2.69 pCi/L ARS 007/EPA 901.1 8/25/08 16:06 ILA N/A ZN-65

-2.234 4.053 5.670 1

2.835 1

1 pCi/L ARS-007/EPA 901.1 8/25/08 16:06

.LA N/A NB-95 0.036 0.677 2 330 1 165 pC/L I

ARS-007/EPA 901.1 I

8/25/08 16:06 iLA N/A ZR-95

-0,424 2.238 4.270 2.135 I

pCi/L I

ARS-007/EPA 901.1

] 8/25/08 16:06 JLN/A 4-1.271

,3.613 2.90 1495 I

,pCi/,

ARS-007/EPA 901.1 8/25/08 16:06 -

LA

,,N/A CS 137 0.6..

0...

82 65 p

AR 0 1

8 /

0 16:06...

A.N/A CS-137

"-0.660

"]

0.805 2.690 1.345 pCi/L ARS-007/EPA 901.1 B /25/08 16:06 JLA

ý l

N/A BA-140 1.842 3.028

-140-0.009 0.864 SR-90 16.485 1.327 H-3

. 5220.405 I.

559.443

.496.

-i*N-63..

2.496

[

4.8098 10.200 5.150 2.990 1.495 pCi/L z

ARS-007/EPA 901.1

] 8/25/08 16:06

)ILA pC

/L I ARS-D07/EPA 901.1 8/25/08 16:06 IL.JA N/A N/A 58.00%

4 0.651 0.307 1

pCi/L ARS-032/EiChrOm SRW-01 8/26/08 13:46 BJS 160.470 79.021 pdVL ARS-054/E 8.0646 3.9679 1

pCI/L ARS-022 9/6/08 19:32

) BJS N/A I

H H

BiS N/A NOTES: Shipment# 08-152 Un~~vL)l iV~ri PFoIct Maonager R Notes: American Radiation Services, Inc. assumes no liability for the use or interpretation of any ana!ytical results provided other than the cost of the analysis itself. Reproduction of this report in less than full requires the written consent of the client.

I LELAP Certificate# 30658 NELAP Certificate # E87558

5 5d/l PA1VdFAJ d

PAGE 1 of 2 NRC FORM 303 U.S. NUCLEAR REGULATORY COMMISSION LABORATORY USE ONLY (4-2004)

CONTROL NUMBER REQUEST FOR ANALYSIS AND CHAIN-OF CUSTODY LABORATORY:

• SAMPLE LOCATION (LICENSEE)

LICENSEE NUMBER DOCKET NO.

INDIAN POINT ENERGY CENTER SAMPLE SUBMITTED

1. TOTAL TYPE VOLUME WEIGHT DATE SAMPLES SUBMITTED PRIORITY

[L ROUTINE GROUND WATER 2000 ML

-2 Kg URGENT SAMPLE COLLECTION INTERVAL MONTH DAY YEAR TIME START INSPECTOR RESPONSIBLE TELEPHONE NUMBER Jim Noggle (USNRC)

. (610) 337-5063 STOP LIST DESIRED LIST DESIRED ANALYSIS TO BE PERFORMED LLD (Optional)

OTHER TYPE OF ANALYSIS (Specify)

LLD (Optional)

D GROSS ALPHA (GA)

STRONTIUM-90 (Sr90)

GROSS BETA (GB)

NICKEL-63 (Ni63)

GAMMA SPEC (GS) r-_

TRITIUM (H3)

D D CARBON-14 (C14)

D D IODINE-125 (1125)

E RELENQUISHEDBY RECEIVED BY DATE TIME REASON FOR CHANGE OF CUSTODY

,2 5SECuiti

.Sr&ace

g~§z

$ ZoPV 103d prizre Ar

/,l9,,s, FEE RECOVERABLE I

NO YES TAC NUMBER REMARKS:

Inspection Report: 1007005 NOTE: SAMPLES WILL BE DISCARDED AFTER ANALYSIS UNLESS REASON ARE NOTED IN REMARKS ABOVE.

NRC FORM303 (4-2004)

PRINTED ON RECYCLED PAPER

Ak PAGE 2 of 2 NRC FORM 303 U.S. NUCLEAR REGULATORY COMMISSIOI-k LABORATORY USE ONLY (4-2004)

CONTROL NUMBER SAMPLE RECORD - Continued LABORATORY:

SAMPLE SAMPLE NAME COLLECTION REMARKS, PRESERVATIVE NUMBER AND DESCRIPTION DATE/TIME ANALYSIS REQUESTED, ETC.

MW-66-21.-(004)

Ground Water Split Sample of MW-66-21-(004) 4'2t' c i Ic Sample is unfiltered & unpreserved. Analyze for

• I I Gamma Spec, H3, Sr90, Ni63 MW-66-36-(004)

Ground Water Split Sample of MW-66-36-(004)

Sample is unfiltered & unpreserved. Analyze tfo Gamma Spec, H3, Sr9O, Ni63 NRC 0RM33 (-200)

PINTE ON ECYLIW APE NRC FORM303 (4-2004)

PRINTED ONRECYCLED PAR

ieSERVICES.

INC.

2609 North River Road, Port Allen, Louisiana 70767 1 (800) 401-4277 FAX (225) 381-2996 QC Results Report Sample Delivery Group: ARSI-08-01560 I

Date Received: 8/12/2008 Laboratory Control Sample Evaluation aysi QC A

yte Analyss (1)

MDC Expected Report Analysis Analysis Analysis Percent L

.I Aatch Type Result Ilys I

Value Units Test Method DaeTima Technician Recovery %)

n N/A LCS Nl-63 210.12 48.8 8.0357 204.49 pCi/L ARS-022 8/28/08 20:51 BJS 103 175%-125%

Blank Evaluation Analysis QC Analysit 1(1 a)

MDC Expected Iua Report Analysis Analysis Analysis Bac ye Analyte Anl sis I (

)

DC Value Qua.l I

T______ L it/ia Techn____

ic___

_ia tch Type Results Units Test Method Dets/Tine Te-hnidan N/A MBL Ni-63

-0.141 4.68 7.9878 NA U

PCI/L ARS-022 8/29/08-5:17 BJS RER Duplicate Evaluation aly QC Analysis Analysis Analysis Analysis RER tnE atcrl Type Description Result 1 CSU I (1 a)

Result 2 CSU 2 (is)

Qual Units Test Method Dato/Timea Technician N/A LCSD Ni-63 210.12 48.8 219.354 50.926 pCI/L ARS-022 8/29/08 1:05 82S 0.09 DER Duplicate Evaluation AIyis QC Analysis 1

CSU 1 (1 a)

Result 2Analysis Analysis Analysis Analysis DER Btch Type Description Re sul t Qual Units Test Method Date/Time Technician DER A."ptanceR I/___ i-53 210.12 48 219.354.

50.92I p*i/L

-ARS-022I

_+

N/A LCSD I Ni-63 210.12 481i 1 219354 1___

t092 1______________

8/29/0.81:05, BIS 0.268<

Projbct Manager R Notes: American Radiation Services, Inc. assumes no liability for the use or interpretation of any analytical results pro0lOed other than the cost of the analysis itself. Reprouctlion of this report in less than full retuires the written consent of the client.

LELAP Certificate# 30658 NELAP Certificate # E87558

SERVICES, INC.

2609 North River Road, Port Allen, Louisiana 70767 1 (800) 401-4277 FAX (225) 381-2996 QC Results Report Sample Delivery Group: ARSI-08-01560 Date Received: 8/12/2008 Laboratory Control Sample Evaluation P

Anlyse

~.1 1

1

]

]

ILCS nae lysie CSU

{1()

MDC Epected ua Report Analysis Analysis Analysis Percent BItch T

np t Results Vauje Units Test Method DatetTirne Technician Recovery (

R)

Acnept"nse ARSI-B08-02293 LCS H3 1136.06 161:4 158.48416 1270.45 pCI/L ARS-054/EPA 906.0 9/4/08 18:01 B1S 89 75%-125%

Blank Evaluation Analysis Qc Analysis Expected 1* 1 Report 1 Analysis Analysis Analysis A~l~i C

Anallyte cSU 1 (1 a8l MDC Vled

,R epr

-Batch Type Results Vae Units Test Method

.Dote/Time Technician ARS1-B08-02293 MBL H3 67.923 94.439817 158.41962 NA U

pCi/L ARS-054/EPA 906.0 9/5/08 2:16 BIS RER Duplicate Evaluation Analysis 1 QC ee 1 Analysis RER I

Aatch ji Type sDecription Reslt I csUI (1 e)

Result 2 CSU 2 (15)

Qual Units Test lMethod Date/Time Technician RER AcceptenceR ARS1-808-02293 LCSD H3 1136.06 161.4 1143.2572 161.9636 pCi/LI ARS-054/EPA 906.0 9/4/08 22:09

1.

B2S 0.02

< 1 DER Duplicate Evaluation r n 1..

TF T

f]DER.

Analysis Qc Anlyis I

s U

i Analysis Analysis Analysis Analysis ER

.e Batch Type Description Result 2 CSU 1(I )

...It 2 (Is)

Quai Units Test Method Dote/Time Techniden D

ARSI-808-02293 LCSD H3 1136.06 161.4 1143.2572 161.9636 pCi/L ARS-054/EPA 906.0 9/4/08 22:09 BJS 0.06 D

Matrix Spike

' Analys Anlyta Analysie CSU 1 ()

Unpik e

Con. Qoel Report Analysis Analyst.is Percent Ace Bitch Type Results Activity.

Units Test Method Dte/itirns I Technician Recory(%)

Reange ARS1-BO8-02293 MS H3 13755.623 1429.035 1862.953 13970.11 pCi/L ARS-054/EPA 906.0 9/5/08 6:24 B)s 8S 60%-140D%

Proji t Manager Re(

Notes:

American Radiation Services, Inc, assumes no liability for the use or interpretation of any analytical results provided other than the cost of the analysis itself. Reproduction of this report in less than full requires the written consent of the client, LELAP Certificate# 30658.

NELAP Certificate

• E87558

E1tICAN RADIATION QC Results Re ort 2609 North River Road, Port Allen, Louisiana 70767 1 (800) 401-4277 FAX (225) 381-2996 Sample Delivery Group: ARSI-08-01560 Date Received:

08/12/08 Laboratory Control Sample Evaluation Anelyie "QC Anelyte Analysis CSU 1 (1.)

MDC Expected Report Ansly.is Analysis Analyssl PerAent Betch Type Results Value Unit.

Test Method Dete/Tinme Technician Recovery (

Ae ARS1-B08-02219 ICS Sr-90 21.729 1.699 0.531 21.34 pCi/L ARS-32/EPA 905.0 8/26/08 13:46 B3S 102 75%-125%

Blank Evaluation Analysis Qc Anlyte Analysis CSU 1(1)

MDC Expiected Qual Report Analysis Analysis Analysls Batch Type j

Results Val.e.

l Units Test Method Date/Time Technician ARS1-B08-02219 MBL Sr-90

-0.200 0.202 0.729 NA U

pCi/L ARS-032/FPA 905.0 8/26/08 13:46 B3S_

RER Duplicate Evaluation Analysit QC Analy1i1 Anely Analysis Analysis Analysis R

c Ep Betu.

Type Description Re"euit I CSU I (

R a) uRlt 2 CSU 2 (1e)

Qual Unityis TAaet Med Dete/Tn TAnaysis Unt sest 4thod Dt./Time Technician R*

Acpac ARS3- 08-02219 LCSD Sr-90 21.729 1.699 23.673 1.862 pCi/L ARS-032/EPA 905.0 8/26/08 13:46 835 0.55 DER Duplicate Evaluation Analysis TC Anlyi Aalssynlyis DR c DER Aneyh T

D t

eeslt 1 CSU I(*

Reult CSU 2 (.)

Quel Anelydie Aneiyle Afteysis Anelesic T

ype unit et Method Date/Tim.e

,Technicen c

A 2..Aan 9

APSI-B08-02219 LCSD Sr-90 21.729 _1 1.699 123.673 1.862 1

pCi/L IARS-O32/EPA 905.0 8/26/08 13:46 8.1S 1.54

< 3 Pro Ct Marnager Rý!

Notes: American Radiation Services, Inc. assumes no liability for the use or interpretation of any analytical results' provided other than the cost of the analysis itself. Reproduction of this report in less than full requires the written consent of the client.

LELAP Certificate# 30658 NELAP Certificate # E87558

A-iRS INTERNATIONAL 2609 North River Road, Port Allen, Louisiana 70767 1 (800) 401-4277 FAX (225) 381-2996 QC Results Report Sample Delivery Group:

Date Received:

ARSI-08-01560 08/12/08 Laboratory Control Sample Evaluation I

Analysis QC Anslyt.

Analysis CSU 1 (1 6)

MDC Expected Report Analysis Analysis Analysis Percent LCS Acceptance Iertch Typul te ts value Units Test Metod Date Technitin Recovery (R*e Rwge ARS1-508-02203 LCS CO-60 25281.00 495.35 210.80 25315.22 pCi/g EPA 901.1 08/19/08 ILA 100 75%-125%

ARS1-B08-02203 LCS CS-137 15370.00 345.75 130.00 15285.98 pCi/g EPA 901.1 08/19/08 ILA 101 75%-125%

ARS1-B08-02203 LCS i

"AM-241 34109.00 j1251.70 288.40 34794.33 pCi/g EPA 901.1 08/19/08 J3LA 98 75%-125%

Blank Evaluation Analysis QC t

Analysis U 1(18)

MDC Expected Report Analysis Anlysisl Analysis Batch Type Results Value Qual Units Test method Date Technician ARS1-B08-02203 MEL CO-60 0.001 0.001 0.004 NA U

pCi/g EPA 901.1 08/19/08 ILA ARS1-B08-02203 MBL CS-137 0.001 0.001 0.004 NA U

PCi/g EPA 901.1 08/19/08 ILA ARSI-B08-02203 MBL AM-241 0.000 0.003 0.007 NA UL pCi/g EPA 901.1 08/19/08 JLA RER Duplicate Evaluation Analyste QC Analysis A

A aetch Type Deeription Result 1 CSU 1 (18)

Result 2 CSU 2 (18) Quel Anelysis Anily Anelysis Anelys RER RER I

I Units Test Method.

Date Technician Accepteneeeenge AFLSI-B08-02203 LC5D CO-60 25281.00 495.35 24786.00 496.33 pCV/9 EPA 901.1 08/19/08 ILA 0.50 ARS1-B08-02203 LCSD CS-137 15370.00 345.75 14809.00 374.51 pCi/g EPA 901.1 08/19/08 3LA 0.78

< I ARS1-008-02203 LCSD AM-241 34109.00 1251.70 34780.00 1262.00 pCr/g EPA 901.1 08/19/08 JLA 0.27

< 1 DER Duplicate Evaluation Analysis QC Analysis t

Analysis Analysis Analyist Batch Type Description Result 1 CSU 1 (1.)

Reslt 2 CSU 2 (1L) Qual Units Test method Date Technician DER Aceeptencekange ARS1-B08-02203 LCSD CO-60 25281.00 495.35 24786.00 496.33 pCi/Q EPA 901.1 08/19/08 ILA 1.41

< 3 ARS1-808-02203 LCSD CS-137 15370.00 345.75 14809.00 374.51 pCi/g EPA 901.1 06/19/08 ILA 2.20

< 3 ARS1-B08-02203 LdSD AM-241 34109.00

.1251.70 34780.00 1262.00 pCI/s EPA 901.1 08/19/08 3LA 0.76

< 3 Qu u-ility ASsuranCe Notes: American Radiation Services, Inc. assumes no liability for the use or Interpretation of any analytical results provided other than the cost of the analysis itself. Reproduction of this report In less than full requires the writtet consent of the client.

LELAP Certificate# 30658 NELAP Certificate # E87558

2609 North River Road

• Port Allen, Louisiana 70767 0*APM5Rt A

ION 11 (800) 401-4277 FAX (225) 381-2996 Notes:

Comments:

1.0)

Soil and.Sludge analysis are reported on a wet basis or an as received basis unlessiotherwise indicated.

2.0)

The data in this report are within the limits of uncertainty specified in the reference method unless specified.

3.0)

Modified analysis procedures are procedures that are modified to meet the certain specifications. An example may be the use of a water method to analyze a solid matrix due to the lack of an officially recognized procedure for the analysis of the solid matrix.

4.0)

Derived Air Concentrations and Effluent Release Concentrations are obtained from 10 CFR 20 Appendix B.

5.0)

Total activity is actually total gamma activity and is determined utilizing the prominent gamma emitters from the naturally occurring radioactive decay chains and other prominent radioactive nudides. Total activity( may be lower than the actual total activity due to the extent of secular equilibrium achieved in the various decay chains at the time of analysis. The total activity is not representative of nuclides that emit solely alpha or beta particles.

6.0)

Ra-228 is determined via secular equilibrium with its daughter, Actinium 228. (Gamma Spectroscopy only).

7.0)

U-238 is determined via secular equilibrium with its daughter, Thorium 234. (Gamma Spectroscopy only).

8.0)

All gamma spectroscopy was performed utilizing high purity germanium detectors (HPGe).

9.0)

ARS makes every attempt to match sample density to calibrated density; however, in some cases, it is not practical or possible to do so and data results may be affected.

Method

References:

1.0)

EPA 600/4-80-032, Prescribed Procedures for the Measurements of Radioactivity in Drinking Water, August 1980.

2.0)

Standard Methods for Examination of Water and Waste Water, 18", 1992.

3.0)

EPA SW-846, Test Methods for Evaluating Solid Waste, Third Edition, (9/86). (Updated through 1995).

4.0)

EPA 600/4/79-020, Methods for Chemical Analysis of Water and Waste, March 1983.

5.0)

HASL 300 r

Definitions:

1.0)

BDL Analyte not detected because the value.was below the detection limit.

2.0)

ND Not detected above the detection limit.

3.0)

DetectionLimit The minimum amount of the analyte that ARS can detect utilizing the specific analysis.

4.0)

B Method Blank 5.0).

D Method Duplicate 6.0)

MS Matrix Spike 7.0).

S Spike 8.0)

RS Reference Spike 9.0)

• SC Subcontracted out to another qualified laboratory 10.0)

NR

• Not Referenced 11.0)

N/A' Not Applicable 12.0)

Reported as a calculated value 13.0)

False Positive due to interference from Bi-214 Notes:

American Radiation Services, Inc. assumes no liability for the use or interpretation of any analytical results provided other than the cost of the analysis itself. Reproduction of this report in less than full requires the written consent of the client.

LELAP Cert# 30658 NELAP Cert# E87558