ML090540698

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American Radiation Services, Inc. Laboratory Analysis Report No. ARS1-08-01560
ML090540698
Person / Time
Site: Indian Point  Entergy icon.png
Issue date: 09/15/2008
From:
American Radiation Services
To: Noggle J
NRC Region 1
References
ARS1-08-01560
Download: ML090540698 (10)


Text

2609 North River Road, Port Allen, Louisiana 70767 (800) 401-4277 -- FAX (225) 381-2996 RNATIONAL American Radiation Services, Inc.

Laboratory Analysis Report ARS1-08-01560 Preparedfor:

Nuclear Regulatory Commission (NRC)

James Noggle USNRC Region 1 475 Allendale Road King of Prussia, PA 19406 James.Noggle@nrc.gov Phone: 610.337.5063 Fax:

Proje" nager Review Management RA)iw Notes: American Radiation Services. Inc. assumes no liability for the use or Interpretation of any analytical mrults provided other than the cost of the analysis itself.

Reproduction of this report in less than tull requires the witten consent of the client.

Contact Person: Questions regarding this analytical report should be addressed to:

Project Manager ProjectManagers@armrad.com Phone: 225.381.2991

-Fax: 225.381.2996 LELAP Cert# 30658 NELAP Cert# E87558

2609 North River Road, Port Allen, Louisiana 70767 1 (800) 401-4277 FAX (225) 381-2996 INTERNATIONAL ARS Sample Delivery Group: ARS1-08-01560 Request or PO Number: N/A Client Sample ID: MW-66-21-(004)04-21/1410 ARS Sample ID: ARSI-08-01560-001 Sample Collection Date: 04/21/08 14:10 Date Received: 8/12/2008 Sample Matrix: Aqueous Report Date: 09/15/08 09:51 Analysis Analysis Analysis MDC O. L DLC iQua]i Analysis Unt Analysis Analysis Analysis Tracer/Chemr Descripion .Results Error +/- 2 s 0 . i units Test Method I Date/finne Technician Rec/ery I MN-54 T -70 0.795 2.660 I 1.330 1 pCl/L i ARS-007/EPA 901.1 8/25/08 16:06 JLA N/A 4--

FE-59 0.286 j 1.402 4.790 . 2.395 pCi/L ARS-007/EPA 901.1 I 8/25/08 16:06 ; JLA N/A pCt/L ARS-007/EPA 901 1 I 8/25/08 16:06 ILA co-58 *1.0S1 3.178 2.590 1.295 N/A


.-.--------...---............ -_--.-.--- .-- __-0--. --.-

CO-60 -0.257 f 1.439 2.660 I 1.330 I PC/L ARS-007/EPA 901.1 8/25/08 16:06 1 ILA N/A ZN-65 2468 2.376 6070 3035 pCi/L ARS-007/EPA 901.1 8/25/08 16:06 JLA N/A NB-95 0.215 0.712 2.410 1.205 pCi/L ARS-007/EPA 901 8/25/08 16:06 ILA N/A

*R95 -0.467 i 1,324 4 480 i 2 240 i pCt/L ARS-007/EPA 901.1 ,8/25/OR 16
06 3LA N/A 1 S5-134  ! 0.907 0.817 2.720 1 1360  ! pCl/L i ARS-007/EPA 903.2 8/25/08 16:06 ]L .. N/A S-137
  • 298 0.9 2030 i .3050 pCi/L ARS-007/EPA 901.1 N/A AR1400.4679 SLA1340 ._ ........

1.6324 0945 I_

10510 700.245 4.0 3.260_ 1.630 0

pC/L pCi/L ARS 007/EPA ARS-007/EPA 901.1

__ 901.1_ _ _

8/25/08 8/25/08 16:06

__ 16:06 ILA_

ILA _ ....

N/A N/A BA-14 -017982.3515.68 102.7001 58.350 p!/ AR-0/P ARS-032/EPh 90. . /50 1-6 J. /

CSR-90 21.59222 9 0.390 pCi/L 9 RW-01 8/26/08 13:46 82S 41.00% I H '982.685 50568 162.621 80.080 I pCi/L ARS-054/EPA 906.0 9/6/08 15:24 BS I N/A Nl-63 1.5697 4.774 8.0688 I 3.9699 pCi/L ARS-022 BIS N/A.

.. -J ........... .. ..... .....

NOTES: Shipment# 08-152 Project Manager Rqle~v Notes: American Radiation Services, Inc. assUrnesno liability for the use or interpretation of any analytical results providecl other than the cost of the analysis Itself. Reproduction of this report In less than full requires the written consent of the client.

LELAP Certificate# 30658 NELAP Certificate # E87558

.. RS 1INTERNATIONAL 2609 North River Road, Port Allen, Louisiana 70767 1 (800) 401-4277 FAX (225) 381-2996 ARS Sample Delivery Group: ARSI-08-01560 Request or PO Number: N/A Client Sample XD: MW-66-36-(004)04-21/1325. ARS Sample ID: ARS1-D8-01560-002 Sample Collection Date: 04/21/08 13:25 Date Received: 8/12/2008 Sample Matrix: Aqueous Report Date: 09/15/08 09:51 Analy its Analysis Analysis MDC II DLC  ! Analysis Analysis Analysis Analysis Tracar/Chern Descrip btan ... ........ ..........

Results ... -

Error /- -...

2s 22.570 7.....

1.285 1

/.I pCI/L Test Method Date/Time Technician MN-54 0.465 0.767 ARS-007/EPA 901.1 8/25/08 16:06 JLA N/A FE-59 -0.94 18.882 5.700 i 2.850 pCI/L ARS-007/EPA 901.1 8/25/08 16:06 1 ILA N/A CO-58 """"

O *

- -0.300

! 0.707

. -- 0"3 ....

238

.'"'21.

3... 0 i S0190 1,.390 i pCi/L pCi/L ARS-007/EPA ARS 0 7/ 901.1.

A 90 8/25/08 1606'A 8/25/08 1 : 66 3.LA N//

CO____60_ -1.62_3.07_2.69 pCi/L ARS 007/EPA 901.1 8/25/08 16:06 ILA N/A ZN-65 -2.234 4.053 5.670 1 2.835 1 1 pCi/L ARS-007/EPA 901.1 8/25/08 16:06 .LA N/A NB-95 0.036 0.677 2 330 1 165 pC/L I ARS-007/EPA 901.1 I 8/25/08 16:06 iLA N/A ZR-95 -0,424 2.238 4.270 2.135 I pCi/L I ARS-007/EPA 901.1 ] 8/25/08 16:06 JLN/A 4-1.271 ,3.613 2 .90 1495 I ,pCi/, ARS-007/EPA 901.1 8/25/08 16:06 - LA

,,N/A CS 137 CS-137 -

"-0.660 0.6.. 0...

.. "] ... 82 0.805 .... ......65 2.690 1.345 p -

pCi/L .. AR 0 ARS-007/EPA . 1 901.1 8/25/08 B / 0 16:06...

16:06 JLAA.N/Aý l N/A BA-140 1.842 3.028 10.200 5.150 pCi/L z ARS-007/EPA 901.1 ] 8/25/08 16:06 )ILA N/A

-140-0.009 0.864 2.990 1.495 pC /L I ARS-D07/EPA 901.1 8/25/08 16:06 IL.JA N/A 4 -

SR-90 16.485 1.327 0.651 0.307 1 pCi/L ARS-032/EiChrOm SRW-01 8/26/08 13:46  ! BJS 58.00%

H-3 . 5220.405 I. 559.443 160.470 79.021 pdVL ARS-054/E 9/6/08 19:32 ) BJS N/A I

-i*N-63 ..

........... ." .496.

2.496 [ 4.8098 H '. "* -- H 8.0646 3.9679 1 pCI/L ARS-022 BiS N/A NOTES: Shipment# 08-152 Un~~vL)l iV~ri PFoIct Maonager R Notes: American Radiation Services, Inc. assumes no liability for the use or interpretation of any ana!ytical results provided other than the cost of the analysis itself. Reproduction of this report in less than full requires the written consent of the client.

  • I LELAP Certificate# 30658 NELAP Certificate # E87558

5 5d/l PA1VdFAJ d PAGE 1 of 2 NRC FORM 303 U.S. NUCLEAR REGULATORY COMMISSION LABORATORY USE ONLY (4-2004) CONTROL NUMBER REQUEST FOR ANALYSIS AND CHAIN-OF CUSTODY LABORATORY:

  • SAMPLE LOCATION (LICENSEE) LICENSEE NUMBER DOCKET NO.

INDIAN POINT ENERGY CENTER SAMPLE SUBMITTED

  1. TOTAL TYPE VOLUME WEIGHT DATE SAMPLES SUBMITTED PRIORITY

[L ROUTINE GROUND WATER 2000 ML -2 Kg URGENT SAMPLE COLLECTION INTERVAL MONTH DAY YEAR TIME START INSPECTOR RESPONSIBLE TELEPHONE NUMBER Jim Noggle (USNRC) . (610) 337-5063 STOP LIST DESIRED LIST DESIRED ANALYSIS TO BE PERFORMED LLD (Optional) OTHER TYPE OF ANALYSIS (Specify) LLD (Optional)

D GROSS ALPHA (GA) STRONTIUM-90 (Sr90)

- GROSS BETA (GB) NICKEL-63 (Ni63)

GAMMA SPEC (GS) r-_

" TRITIUM (H3) D D CARBON-14 (C14) D D IODINE-125 (1125) E RELENQUISHEDBY RECEIVED BY DATE TIME REASON FOR CHANGE OF CUSTODY

  1. ,2 5SECuiti .Sr&ace $ ZoPV
g~§z 103d prizre Ar /,l9,,s, FEE RECOVERABLE I NO YES TAC NUMBER REMARKS

Inspection Report: 1007005 NOTE: SAMPLES WILL BE DISCARDED AFTER ANALYSIS UNLESS REASON ARE NOTED IN REMARKS ABOVE.

NRC FORM303 (4-2004) PRINTED ON RECYCLED PAPER

Ak PAGE 2 of 2 NRC FORM 303 U.S. NUCLEAR REGULATORY COMMISSIOI-k LABORATORY USE ONLY (4-2004) CONTROL NUMBER SAMPLE RECORD - Continued LABORATORY:

SAMPLE SAMPLE NAME COLLECTION REMARKS, PRESERVATIVE NUMBER AND DESCRIPTION DATE/TIME ANALYSIS REQUESTED, ETC.

MW-66-21.-(004) Ground Water Split Sample of MW-66-21-(004) 4'2t' c i Ic Sample is unfiltered & unpreserved. Analyze for

  • I I Gamma Spec, H3, Sr90, Ni63 MW-66-36-(004) Ground Water Split Sample of MW-66-36-(004) Sample is unfiltered & unpreserved. Analyze tfo Gamma Spec, H3, Sr9O, Ni63 NRC 0RM33 (-200) PINTE ON ECYLIW APE NRC FORM303 (4-2004) PRINTED ONRECYCLED PAR

2609 North River Road, Port Allen, Louisiana 70767 1 (800) 401-4277 FAX (225) 381-2996 ieSERVICES.INC.

QC Results Report Sample Delivery Group: ARSI-08-01560 I Date Received: 8/12/2008 Laboratory Control Sample Evaluation aysi QC A yte Analyss (1) MDC Expected Report Analysis Analysis Analysis Percent L .I Aatch Type Result Ilys I Value Units Test Method DaeTima Technician Recovery %) n N/A LCS Nl-63 210.12 48.8 8.0357 204.49 pCi/L ARS-022 8/28/08 20:51 BJS 103 175%-125%

Blank Evaluation Analysis tch Bac QC ye Type Analyte Analysit Anl Results sis 1(1 a)

I ( )

MDC DC Expected Value IuaQua.l Report Units I Analysis T______

Test Method L Analysis it/ia Dets/Tine Analysis ic___

Techn_____ia Te-hnidan N/A MBL Ni-63 -0.141 4.68 7.9878 NA U PCI/L ARS-022 8/29/08-5:17 BJS RER Duplicate Evaluation aly QC Analysis Analysis Analysis Analysis RER tnE atcrl Type Description Result 1 CSU I (1 a) Result 2 CSU 2 (is) Qual Units Test Method Dato/Timea Technician N/A LCSD Ni-63 210.12 48.8 219.354 50.926 pCI/L ARS-022 8/29/08 1:05 82S . 0.09 DER Duplicate Evaluation AIyis Btch N/A QC Type LCSD I Analysis Description i-53 I/___

Ni-63 Re sul t 210.12 210.12 1 CSU1 (1 a) 48 "

481i Result 2Analysis 219.354.

1 219354 1___

50.92I

_ Qual Units p*i/L 1______________

_+ Analysis Test Method

" -ARS-022I t092 Analysis Date/Time 8/29/0.81:05, Analysis Technician BIS DER 0.268<

DER A."ptanceR Projbct Manager R Notes: American Radiation Services, Inc. assumes no liability for the use or interpretation of any analytical results pro0lOed other than the cost of the analysis itself. Reprouctlion of this report in less than full retuires the written consent of the client.

LELAP Certificate# 30658 NELAP Certificate # E87558

2609 North River Road, Port Allen, Louisiana 70767 1 (800) 401-4277 FAX (225) 381-2996 SERVICES, INC.

QC Results Report Sample Delivery Group: ARSI-08-01560 Date Received: 8/12/2008 Laboratory Control Sample Evaluation BItch nae T

P Anlyse lysie CSU {1() ~1 .1MDC 1 Epected ua ] Report ] Analysis ILCS Analysis Analysis Percent np t Results Vauje Units Test Method DatetTirne Technician Recovery ( Acnept"nse R)

ARSI-B08-02293 LCS H3 1136.06 161:4 158.48416 1270.45 pCI/L ARS-054/EPA 906.0 9/4/08 18:01 B1S 89 75%-125%

Blank Evaluation Analysis A~l~i Qc C Anallyte Analysis cSU 1 (1 a8l MDC Expected Vled 1* ,R1 Report epr 1 Analysis Analysis Analysis

-Batch Type Results Vae Units Test Method .Dote/Time Technician ARS1-B08-02293 MBL H3 67.923 94.439817 158.41962 NA U pCi/L ARS-054/EPA 906.0 9/5/08 2:16 BIS RER Duplicate Evaluation Analysis ji1 QC Aatch sDecription Type Reslt I csUI (1 e) Result 2 CSU 2 (15) Qual ee Units Test lMethod 1 Analysis I RER Date/Time Technician RER AcceptenceR ARS1-808-02293 LCSD H3 1136.06 161.4 1143.2572 161.9636 pCi/LI ARS-054/EPA 906.0 9/4/08 22:09 1. B2S 0.02 < 1 DER Duplicate Evaluation r Analysis n

Batch 1.. Qc Type Anlyis Description Result 2 TF I

CSU 1(I ) ...It2 s iU (Is)

T Quai Analysis Units Analysis Test Method f]DER.Analysis Dote/Time Analysis Techniden D ER .e ARSI-808-02293 LCSD H3 1136.06 161.4 1143.2572 161.9636 pCi/L ARS-054/EPA 906.0 9/4/08 22:09 BJS D 0.06 Matrix Spike

' Analys Anlyta Analysie CSU 1 () Unpik e Con. Qoel Report Analysis Analyst.is Percent Ace Bitch Type Results Activity. Units Test Method Dte/itirns I Technician Recory(%) Reange ARS1-BO8-02293 MS H3 13755.623 1429.035 1862.953 13970.11 pCi/L ARS-054/EPA 906.0 9/5/08 6:24 B)s 8S 60%-140D%

Proji t Manager Re( -

Notes: American Radiation Services, Inc, assumes no liability for the use or interpretation of any analytical results provided other than the cost of the analysis itself. Reproduction of this report in less than full requires the written consent of the client, LELAP Certificate# 30658. NELAP Certificate

  • E87558

2609 North River Road, Port Allen, Louisiana 70767 1 (800) 401-4277 FAX (225) 381-2996 E1tICAN RADIATION QC Results Re ort Sample Delivery Group: ARSI-08-01560 Date Received: 08/12/08 Laboratory Control Sample Evaluation Anelyie "QC Anelyte Analysis CSU 1 (1.) MDC Expected Report Ansly.is Analysis Analyssl PerAent Betch Type Results Value Unit. Test Method Dete/Tinme Technician Recovery ( Ae ARS1-B08-02219 ICS Sr-90 21.729 1.699 0.531 21.34 pCi/L ARS-32/EPA 905.0 8/26/08 13:46 B3S 102 75%-125%

Blank Evaluation Analysis Qc Anlyte Analysis CSU 1(1) MDC Expiected Qual Report Analysis Analysis Analysls Batch Type Results * . Val.e. j l Units Test Method Date/Time Technician ARS1-B08-02219 MBL Sr-90 -0.200 0.202 0.729 NA U pCi/L ARS-032/FPA 905.0 8/26/08 13:46 B3S_

RER Duplicate Evaluation Analysit QC Analy1i1 Anely Analysis Analysis Analysis c REp Type Description Re"euit I CSU I ( a)R uRlt2 CSU 2 (1e) Qual Unityis Unt sest Med TAaet 4thod Dete/Tn Dt./Time TAnaysis Technician R* Acpac Betu.

ARS3- 08-02219 LCSD Sr-90 21.729 1.699 23.673 1.862 pCi/L ARS-032/EPA 905.0 8/26/08 13:46 835 0.55 DER Duplicate Evaluation "

Analysis TCAnlyi Aalssynlyis DR c DER Aneyh T T D t eeslt 1 CSU I(* Reult CSU 2 (.) Quel Anelydie Aneiyle Afteysis Anelesic ype unit et Method Date/Tim.e ,Technicen c .

A 2..Aan 9 APSI-B08-02219 LCSD Sr-90 21.729 _1 1.699 123.673 1.862 1 pCi/L IARS-O32/EPA 905.0 8/26/08 13:46 8.1S 1.54 < 3 Pro Ct Marnager Rý!

Notes: American Radiation Services, Inc. assumes no liability for the use or interpretation of any analytical results' provided other than the cost of the analysis itself. Reproduction of this report in less than full requires the written consent of the client.

LELAP Certificate# 30658 NELAP Certificate # E87558

A-iRS INTERNATIONAL 2609 North River Road, Port Allen, Louisiana 70767 1 (800) 401-4277 FAX (225) 381-2996 QC Results Report Sample Delivery Group: ARSI-08-01560

-. Date Received: 08/12/08 Laboratory Control Sample Evaluation I Analysis QC Anslyt. Analysis CSU 1 (1 6) MDC Expected Report Analysis Analysis Analysis Percent LCS Acceptance Iertch Typul te ts value Units Test Metod Date Technitin Recovery (R*e Rwge ARS1-508-02203 LCS CO-60 25281.00 495.35 210.80 25315.22 pCi/g EPA 901.1 08/19/08 ILA 100 75%-125%

ARS1-B08-02203 LCS CS-137 15370.00 345.75 130.00 15285.98 pCi/g EPA 901.1 08/19/08 ILA 101 75%-125%

ARS1-B08-02203 LCS i "AM-241 34109.00 j1251.70 288.40 34794.33 pCi/g EPA 901.1 08/19/08 J3LA 98 75%-125%

Blank Evaluation Analysis QC t Analysis U1(18) MDC Expected Report Analysis Anlysisl Analysis Batch Type Results Value Qual Units Test method Date Technician ARS1-B08-02203 MEL CO-60 0.001 0.001 0.004 NA U pCi/g EPA 901.1 08/19/08 ILA ARS1-B08-02203 MBL CS-137 0.001 0.001 0.004 NA U PCi/g EPA 901.1 08/19/08 ILA ARSI-B08-02203 MBL AM-241 0.000 0.003 0.007 NA UL pCi/g EPA 901.1 08/19/08 JLA RER Duplicate Evaluation Analyste QC Analysis A A aetch Type Deeription Result 1 CSU 1 (18) Result 2 CSU 2 (18) Quel Anelysis Anily Anelysis Anelys RER RER I I Units Test Method . Date Technician Accepteneeeenge AFLSI-B08-02203 LC5D CO-60 25281.00 495.35 24786.00 496.33 pCV/9 EPA 901.1 08/19/08 ILA 0.50 ARS1-B08-02203 LCSD CS-137 15370.00 345.75 14809.00 374.51 pCi/g EPA 901.1 08/19/08 3LA 0.78 <I ARS1-008-02203 LCSD AM-241 34109.00 1251.70 34780.00 1262.00 pCr/g EPA 901.1 08/19/08 JLA 0.27 < 1 DER Duplicate Evaluation Analysis QC Analysis t Analysis Analysis Analyist Batch Type Description Result 1 CSU 1 (1.) Reslt 2 CSU 2 (1L) Qual Units Test method Date Technician DER Aceeptencekange ARS1-B08-02203 LCSD CO-60 25281.00 495.35 24786.00 496.33 pCi/Q EPA 901.1 08/19/08 ILA 1.41 <3 ARS1-808-02203 LCSD CS-137 15370.00 345.75 14809.00 374.51 pCi/g , EPA 901.1 06/19/08 ILA 2.20 <3 ARS1-B08-02203 LdSD AM-241 34109.00 .1251.70 34780.00 1262.00 pCI/s EPA 901.1 08/19/08 3LA 0.76 < 3 Quu-ility ASsuranCe " . .

Notes: American Radiation Services, Inc. assumes no liability for the use or Interpretation of any analytical results provided other than the cost of the analysis itself. Reproduction of this report In less than full requires the writtet consent of the client.

LELAP Certificate# 30658 NELAP Certificate # E87558

2609 North River Road

  • Port Allen, Louisiana 70767 A ION 11(800) 401-4277 FAX (225) 381-2996 0*APM5Rt Notes:

Comments:

1.0) Soil and.Sludge analysis are reported on a wet basis or an as received basis unlessiotherwise indicated.

2.0) The data in this report are within the limits of uncertainty specified in the reference method unless specified.

3.0) Modified analysis procedures are procedures that are modified to meet the certain specifications. An example may be the use of a water method to analyze a solid matrix due to the lack of an officially recognized procedure for the analysis of the solid matrix.

4.0) Derived Air Concentrations and Effluent Release Concentrations are obtained from 10 CFR 20 Appendix B.

5.0) Total activity is actually total gamma activity and is determined utilizing the prominent gamma emitters from the naturally occurring radioactive decay chains and other prominent radioactive nudides. Total activity( may be lower than the actual total activity due to the extent of secular equilibrium achieved in the various decay chains at the time of analysis. The total activity is not representative of nuclides that emit solely alpha or beta particles.

6.0) Ra-228 is determined via secular equilibrium with its daughter, Actinium 228. (Gamma Spectroscopy only).

7.0) U-238 is determined via secular equilibrium with its daughter, Thorium 234. (Gamma Spectroscopy only).

8.0) All gamma spectroscopy was performed utilizing high purity germanium detectors (HPGe).

9.0) ARS makes every attempt to match sample density to calibrated density; however, in some cases, it is not practical or possible to do so and data results may be affected.

Method

References:

1.0) EPA 600/4-80-032, Prescribed Procedures for the Measurements of Radioactivity in Drinking Water, August 1980.

2.0) Standard Methods for Examination of Water and Waste Water, 18", 1992.

3.0) EPA SW-846, Test Methods for Evaluating Solid Waste, Third Edition, (9/86). (Updated through 1995).

4.0) EPA 600/4/79-020, Methods for Chemical Analysis of Water and Waste, March 1983.

5.0) HASL 300 r Definitions:

1.0) BDL Analyte not detected because the value.was below the detection limit.

2.0) ND Not detected above the detection limit.

3.0) DetectionLimit The minimum amount of the analyte that ARS can detect utilizing the specific analysis.

4.0) B Method Blank 5.0) . D Method Duplicate 6.0) MS Matrix Spike 7.0). S Spike 8.0) RS Reference Spike 9.0) *SC Subcontracted out to another qualified laboratory 10.0) NR

  • Not Referenced 11.0) N/A' Not Applicable 12.0) Reported as a calculated value 13.0) False Positive due to interference from Bi-214 Notes: American Radiation Services, Inc. assumes no liability for the use or interpretation of any analytical results provided other than the cost of the analysis itself. Reproduction of this report in less than full requires the written consent of the client.

LELAP Cert# 30658 NELAP Cert# E87558