ML042020068

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Enclosure 1, Calvert Cliffs Nuclear Power Plant Radioactive Effluent Release Report and Dose Report.
ML042020068
Person / Time
Site: Calvert Cliffs  Constellation icon.png
Issue date: 07/15/2004
From:
Constellation Energy Group
To:
Office of Nuclear Reactor Regulation
References
Download: ML042020068 (20)
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Text

ENCLOSURE (1)

CALVERT CLIFFS NUCLEAR POWER PLANT RADIOACTIVE EFFLUENT RELEASE REPORT AND DOSE REPORT Calvcrt Cliffs Nuclear Power Plant, Inc.

July 15, 2004

CALVERT CLIFFS NUCLEAR POWER PLANT EFFLUENT AND WASTE DISPOSAL 2003 ANNUAL REPORT SUPPLEMENTAL INFORMATION Facility - Calvert Cliffs Nuclear Power Plant Licensee - Calvert Cliffs Nuclear Power Plant, Inc.

REGULATORY LIMITS A. Fission and Activation Gases

1. The instantaneous release rate of noble gases in gaseous effluents shall not result in a site boundary dose rate greater than 500 mRem/year to the whole body or greater than 3000 mRem/year to the skin (Offsite Dose Calculation Manual (ODCM) 3.11.2.1).
2. Gaseous Radwaste Treatment System and the Ventilation Exhaust Treatment System shall be used to reduce gaseous emissions when the calculated gamma-air dose due to gaseous effluents exceeds 1.20 mRad or the calculated beta-air dose due to gaseous effluents exceeds 2.40 mRad at the site boundary in a 92 day period (ODCM3.11.2.4).
3. The air dose at the site boundary due to noble gases released in gaseous effluents shall not exceed (ODCM 3.11.2.2):

10 mRad/qtr, gamma-air 20 mRadlqtr, beta-air 20 mRad/year, gamma-air 40 mRad/year, beta-air

4. All of the above parameters are calculated according to the methodology specified in the ODCM.

B. lodines and Particulates with Half Lives Greater than Eight Days

1. The instantaneous release rate of iodines and particulates in gaseous effluents shall not result in a site boundary dose-rate in excess of 1500 mRem/year to any organ (ODCM 3.11.2.1).
2. The Gaseous Radwaste Treatment System and the Ventilation Exhaust Treatment System shall be used to reduce radioactive materials in gaseous effluents when calculated doses exceed 1.8 mRem to any organ in a 92 day period at or beyond the site boundary (ODCM 3.11.2.4).
3. The dose to a member of the public at or beyond the site boundary from iodine-131 and particulates with half lives greater than eight days in gaseous effluents shall not exceed (ODCM 3.11.2.3):

15 mRem/qtr, any organ 30 mRem/year, any organ less than 0.1% of the above limits as a result of burning contaminated oil.

4. All of the above parameters are calculated according to the methodology specified in the ODCM.

1

CALVERT CLIFFS NUCLEAR POWER PLANT EFFLUENT AND WASTE DISPOSAL 2003 ANNUAL REPORT SUPPLEMENTAL INFORMATION C. Liquid Effluents

1. The concentrations of radionuclides in liquid effluents from the plant shall not exceed the values specified in 10 CFR Part 20, Appendix B, Table II, Column 2 for unrestricted areas (ODCM 3.11.1.1).
2. The liquid radwaste treatment system shall be used to reduce the concentration of radionuclides in liquid effluents from the plant when the calculated dose to unrestricted areas exceeds 0.36 mRem to the whole body, or 1.20 mRem to any organ in a 92 day period (ODCM 3.11.1.3).
3. The dose to a member of the public in unrestricted areas shall not exceed (ODCM 3.11.1.2):

3 mRem/qtr, total body 10 mRem/qtr, any organ 6 mRem/year, total body 20 mRem/year, any organ

4. All of the liquid dose* parameters are calculated according to the methodology specified in the ODCM.

II. MAXIMUM PERMISSIBLE CONCENTRATIONS A. Fission and Activation Gases Prior to the batch release of gaseous effluents, a sample of the source is collected and analyzed by gamma spectroscopy for the principal gamma emitting radionuclides. The identified radionuclide concentrations are evaluated and an acceptable release rate is determined to ensure that the dose rate limits of ODCM 3.11.2.1 are not exceeded.

B. Iodines and Particulates with Half Lives Greater than Eight Days Compliance with the dose rate limitations for iodines and particulates is demonstrated by analysis of the charcoal and particulate samples of the station main vents. The charcoal samples are analyzed by gamma spectroscopy for quantification of radioiodines. The particulate samples are analyzed by gamma spectroscopy for quantification of particulate radioactive material. All of the above parameters are calculated according to the methodology specified in the ODCM.

C. Liquid Effluents The Maximum Permissible Concentrations (MPCs) used for radioactive materials released in liquid effluents are in accordance with ODCM 3.11.1.1 and the values from 10 CFR Part20, Appendix B, Table 11, Column 2 including applicable table notes. In all cases, the more restrictive (lower) MPC found for each radionuclide is used regardless of solubility.

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CALVERT CLIFFS NUCLEAR POWER PLANT EFFLUENT AND WASTE DISPOSAL 2003 ANNUAL REPORT SUPPLEMENTAL INFORMATION

m. TECHNICAL SPECIFICATION REPORTING REQUIREMENTS A. Calvert Cliffs Nuclear Power Plant (CCNPP), Technical Specification 5.6.3
1. 2003 Dose Assessment Summary Actual Percent I Of CM Value ODCM limit Limit Liquid Waste:

Maximum Annual Organ Dose (mRem)X 0.02 l T.W [ 20F Maximum Whole Body Dose (mRem) I l.()2 l .0% l Gaseous Waste:

Noble Gases:

Maximum Quarterly Gamma Air Dose (mRad) 0.002 0.01% 10 Maximum Quarterly Beta Air Dose (mRad) 0.01 Uo.(:)5 20 lodines and Particulates:

2 Maximum Annual Organ Dose (mRem) 0.05 0.2% 30 The controlling pathway was the fish and shellfish pathway with adult as the controlling age group and the gastrointestinal tract representing the organ with the highest calculated dose during the calendar year of 2003.

2 The controlling pathway was the child-infant-thyroid pathway representing the organ with the highest calculated dose during the calendar year of 2003. There is currently no milk pathway.

2. 40 CFR 190 Total Dose Compliance Based upon the calendar year 2003 and the ODCM calculations, the maximum exposed individual would receive less than 1% of the allowable dose. During the calendar year 2003, there were no on-site sources of direct radiation that would have contributed to a significant or measurable off-site dose. The direct radiation contribution is measured by both on-site and off-site thermoluminescent dosimeters (TLDs). The results of these measurements did not indicate any statistical increase in the off-site radiation doses attributable to on-site sources. Therefore, no increase in the calculated offsite dose is attributed to the direct exposure from on-site sources. A more detailed evaluation will be reported in the Annual Radiological Environmental Operating Report.
3. Solid Waste Report Requirements During 2003, the types of radioactive solid waste shipped from Calvert Cliffs were dry compressible waste and dewatered resins which were shipped in High Integrity Containers (HICs) within NRC approved casks, Sealand containers, and steel boxes.

Appendix A provides a detailed breakdown of the waste shipments for 2003 per the categories specified in Technical Specification 5.6.3. At CCNPP, methods of waste and materials segregation are used to reduce the volume of solid waste shipped offsite for processing, volume reduction and burial.

3

CALVERT CLIFFS NUCLEAR POWER PLANT EFFLUENT AND WASTE DISPOSAL 2003 ANNUAL REPORT SUPPLEMENTAL INFORMATION

4. Offsite Dose Calculation Manual (ODCM) and Process Control Program (PCP)

Changes The ODCM was revised on 28-Aug-2003. A copy is attached. The PCP was revised three times in 2003: in January, February, and November. Copies of the changes to the PCP are available on request.

B. Radioactive Effluent Monitoring Instrumentation There were no effluent pathways unmonitored for more than 30 consecutive days in 2003.

C. Independent Spent Fuel Storage Installation (ISFSI), ISFSI Technical Specification 6.1 There were six (6) casks of spent fuel transferred to the ISFSI during 2003. No quantity of radionuclides was released to the environment during the ISFSI operation in 2003.

Additional information regarding the ISFSI radiation-monitoring program is included in the Annual Radiological Environmental Operation Report.

IV. AVERAGE ENERGY Not Applicable.

V. MEASUREMENTS AND APPROXIMATIONS AND TOTAL RADIOACTIVITY A. Fission and Activation Gases

1. Batch Releases Prior to each batch release of gas from a pressurized waste gas decay tank or containment, a sample is collected and analyzed by gamma spectroscopy using a Germanium (Ge) detector for the principal gamma emitting noble gas radionuclides.

The total activity released is based on the pressure/volume relationship (gas laws).

2. Continuous Releases A gas sample is collected at least weekly from the main vents and analyzed by gamma spectroscopy using a Ge detector for the principal gamma emitting noble gas radionuclides. The total activity released for the week is based on the total sample activity decay corrected to the sample time multiplied by the main vent flow for the week.

Prior to and after each containment purge, a gas sample is collected and analyzed by gamma spectroscopy using a Ge detector for the principal gamma emitting noble gas radionuclides. The total activity released is based on containment volume and purge rate. Alternatively, total activity released is based on continuous radiation monitor response, grab samples and purge flow rate.

A monthly composite sample is collected from the main vents and analyzed by liquid scintillation for tritium. The total tritium release for the month is based on the sample analysis and the main vent flow.

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-I CALVERT CLIFFS NUCLEAR POWER PLANT EFFLUENT AND WASTE DISPOSAL 2003 ANNUAL REPORT SUPPLEMENTAL INFORMATION B. Iodine and Particulates

1. Batch Releases The total activities of radioiodines and particulates released from pressurized waste gas decay tanks, containment purges, and containment vents are accounted for by the continuous samplers on the main vent.
2. Continuous Releases During the release of gas from the main vents, samples of iodines and particulates are collected using a charcoal and particulate filter, respectively. The filters are removed weekly and are analyzed by gamma spectroscopy using a Ge detector for significant gamma emitting radionuclides. The total activity released for the week is based on the total sample activity decay corrected to the midpoint of the sample period multiplied by the main vent flow for the week. The weekly particulate filters are then composited to form monthly and quarterly composites for the gross alpha and strontium-89 and strontium-90 analyses.

C. Liquid Effluents I1. Batch Releases Prior to the release of liquid from a waste tank, a sample is collected and analyzed by gamma spectroscopy for the principal gamma emitting radionuclides. To demonstrate compliance with the requirements addressed in Section I.C.1 above, the measured radionuclide concentrations are compared with the allowable MPCs; dilution in the discharge conduit is considered, and an allowable release rate is verified.

The total activity released in each batch is determined by multiplying the volume released by the concentration of each radionuclide. The actual volume released is based on the difference in tank levels prior to and after the release. A proportional composite sample is also withdrawn from each release, this is used in turn to prepare monthly tritium and quarterly gross alpha, iron-55, strontium-89, and strontium-90 samples for analysis.

There were major changes to the liquid radwaste system in calendar year 2003.

Beginning in February, a vendor supplied advanced radwaste processing system was used for processing water from contaminated areas of the auxiliary and containment buildings. The advanced processing system is comprised of a bank of ultrafilters followed by four ion-exchangers. The advanced radwaste processing system is much more effective in removing radioactive contaminants from liquid waste.

2. Continuous Releases To account for activity from continuous releases, a sample is collected and analyzed by gamma spectroscopy for the principal gamma emitting radionuclides. The measured radionuclide concentrations are compared with the allowable MPC concentrations in the discharge conduit, and an allowable release rate is verified.

When steam generator blowdown is discharged to the circulating water conduits, it is sampled and gamma isotopic analysis is performed at a minimum of three times per week and these samples are used in turn to prepare a weekly blowdown composite 5

4 CALVERT CLIFFS NUCLEAR POWER PLANT EFFLUENT AND WASTE DISPOSAL 2003 ANNUAL REPORT SUPPLEMENTAL INFORMATION sample based on each day's blowdown. These results are multiplied by the actual quantity of blowdown to determine the total activity released. The weekly composite is also used to prepare monthly composites for tritium analysis.

During periods of primary-to-secondary leakage, the secondary system becomes contaminated and subsequently, contaminates the turbine building sumps. The low-level activity water (predominantly tritium) contained in the turbine building sumps is discharged to the circulating water conduits. This water is sampled weekly and composited. The composite sample is analyzed at least monthly for tritium and principal gamma emitting radionuclides. The results are multiplied by the actual quantity of liquid released to determine the total activity released.

D. Estimation of Total Error Total error for all releases was estimated using, as a minimum, the random counting error associated with typical releases. In addition to this random error, the following systematic errors were also examined:

I. Liquid

a. Error in volume of liquid released prior to dilution during batch releases.
b. Error in volume of liquid released via steam generator blowdown.
c. Error in amount of dilution water used during the reporting period.
2. Gases
a. Error in main vent release flow.
b. Error in sample flow rate.
c. Error in containment purge release flow.
d. Error in gas decay tank pressure.

Where errors could be estimated they are usually considered additive.

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CALVERT CLIFFS NUCLEAR POWER PLANT EFFLUENT AND WASTE DISPOSAL 2003 ANNUAL REPORT SUPPLEMENTAL INFORMATION VI. BATCH RELEASES 2003 IST 2ND 3RD 4TH QUARTER QUARTER QUARTER QUARTER A. Liquid

1. Number of batch releases 2.10E+01 1.70E+01 8.OOE+00 1.30E+O1
2. Total time period for batch releases (min) 3.96E+04 6.22E+03 2.52E+03 4.87E+03
3. Maximum time period for a batch release (min) 1.63E+04 6.49E+02 5.35E+02 5.94E+02
4. Average time period for batch releases (min) 1.88E+03 3.66E+02 3.15E+02 3.75E+02
5. Minimum time period for a batch release (min) 2.53E+01 2.80E+01 1.90E+01 2.37E+O1
6. Average stream flow during periods of effluent into a flowing stream (liters/min of dilution water) 4.66E+06 5.43E+06 4.62E+06 4.56E+06 B. Gaseous
1. Number of batch releases 2.20E+01 1.20E+01 2.OOE+00 2.00E+OO
2. Total time period for batch releases (min) 7.47E+03 8.89E+03 1.20E+03 1.75E+03
3. Maximum time period for a batch release (min) 1.50E+03 1.89E+03 1.1 OE+03 1.11 E+03
4. Average time period for batch release (min) 3.40E+02 7.41E+02 6.02E+02 8.77E+02
5. Minimum time period for a batch release (min) 5.OOE-0O1 1.OOE+01 1.04E+02 6.46E+02 7

CALVERT CLIFFS NUCLEAR POWER PLANT EFFLUENT AND WASTE DISPOSAL 2003 ANNUAL REPORT SUPPLEMENTAL INFORMATION VII. ABNORMAL RELEASES 2003 IST 2ND 3RD 4TH QUARTER QUARTER QUARTER QUARTER A. Liquid

1. Number of releases 2. Total activity released (Curies) B. Gaseous
1. Number of releases 2. Total activity releases (Curies) 8

APPENDIX A CALVERT CLIFFS NUCLEAR POWER PLANT EFFLUENT AND WASTE DISPOSAL 2003 ANNUAL REPORT TABLE 1A - REG GUIDE 1.21 GASEOUS EFFLUkAN I - SUMMAIIUN Uk' ALL RELEASES 1ST 2ND EST. TOTAL A. FISSION AND ACTIVATION GASES UNITS QUARTER QUARTER ERROR,%

1. Total Release Ci 1.16E+02 1.49E+01 il.20E+01
2. Average release rate for period piCi/sec 1.49E+01 1.90E+00
3. Percent of Tech. Spec. limit (1) 1.72E-03 2.3 I E-04
4. Percent of Tech. Spec. limit (2)  % 9.64E-04 1.67E-04
5. Percent of Tech. Spec. limit (3) _ 2.51 E-02 3.27E-03
6. Percent of Tech. Spec. limit (4) ___ 1.25E-02 1.64E-03
7. Percent of Tech. Spec. limit (5) _ 5.07E-02 7.95E-03
8. Percent of Tech. Spec. limit (6)  % 2.53E-02 3.98E-03 B. IODINES
1. Total Iodine- 131 Ci 1.33E-03 1.98E-04 +/-6.50E+00
2. Average release rate for period piCi/sec 1.71E-04 2.51E-05
3. Percent of Tech. Spec. limit (7) _ 4.06E-04 5.97E-05
4. Percent of Tech. Spec. limit (8)  % 1.00E-02 1.49E-03
5. Percent of Tech. Spec. limit (9)  % 5.00E-03 7.44E-04 C. PARTICULATES
1. Particulates with half lives greater than 8 days Ci (10) (10) N/A
2. Average release rate for period pCi/sec (10) (10)
3. Percent of Tech. Spec. limit (7) (10) (10)
4. Percent of Tech. Spec. limit (8)  % (10) (10)
5. Percent of Tech. Spec. limit (9) _ (10) (10)
6. Gross alpha radioactivity Ci (10) (10) N/A 3RD 4TH EST. TOTAL A. FISSION AND ACTIVATION GASES UNITS QUARTER QUARTER ERROR, %
1. Total Release Ci 1.79E+01 1.17E+O1 il.20E+01
2. Average release rate for period pCi/sec 2.25E+00 1.47E+00
3. Percent of Tech. Spec. limit (1)  % 4.41E-04 2.95E-04
4. Percent of Tech. Spec. limit (2)  % 1.82E-04 1.14E-04
5. Percent of Tech. Spec. limit (3) ___ 6.35E-03 4.23E-03
6. Percent of Tech. Spec. limit (4)  % 3.17E-03 2.12E-03
7. Percent of Tech. Spec. limit (5) _ 7.82E-03 4.93E-03
8. Percent of Tech. Spec. limit (6)  % 3.91 E-03 2.47E-03 B. IODINES
1. Total Iodine- 131 Ci 1.81E-04 1.07E-04 i6.50E+00
2. Average release rate for period 1pCi/sec 2.28E-05 1.35E-05
3. Percent of Tech. Spec. limit (7)  % 5.42E-05 3.21E-05
4. Percent of Tech. Spec. limit (8)  % 1.37E-03 8.09E-04
5. Percent of Tech. Spec. limit (9)  % 6.83E-04 4.05E-04 C. PARTICULATES
1. Particulates with half lives greater than 8 days Ci (10) (10)/A
2. Average release rate for period pCi/sec (10) (10)
3. Percent of Tech. Spec. limit (7) (10) (10)
4. Percent of Tech. Spec. limit (8) (10) (10)
5. Percent of Tech. Spec. limit (9)  % (10) (10) _ _
6. Gross alpha radioactivity Ci (10) (10) N/A A-l

APPENDIX A CALVERT CLIFFS NUCLEAR POWER PLANT EFFLUENT AND WASTE DISPOSAL 2003 ANNUAL REPORT TABLE IA - REG GUIDE 1.21 GASEOUS EFFLuENT 16 - bUMAMATIUN 01, ALL RELEASES IST 2ND EST. TOTAL D. TRITIUM UNITS QUARTER QUARTER ERROR, %

1. Total Release Ci 4.58E+00 2.91E+00 +/-1.32E+01
2. Average release rate for period jpCi/sec 5.89E-01 3.70E-01 3RD 4TH EST. TOTAL D. TRITIUM UNITS QUARTER QUARTER ERROR,%
1. Total Release Ci 3.65E+00 8.66E-01 +/-1.32E+01
2. Average release rate for period pCi/sec 4.59E-01 1.09E-01 NOTES TO TABLE 1A (1) Percent of I.A.1 whole body dose rate limit (500 mRem/year)

(2) Percent of I.A.1 skin dose rate limit (3000 mRem/year)

(3) Percent of I.A.3 quarterly gamma-air dose limit (10 mRad)

(4) Percent of I.A.3 yearly gamma-air dose limit (20 mRad)

(5) Percent of I.A.3 quarterly beta-air dose limit (20 mRad)

(6) Percent of I.A.3 yearly beta-air dose limit (40 mRad)

(7) Percent of I.B.I organ dose rate limit (1500 mRem/year)

(8) Percent of I.B.3 quarterly organ dose limit (15 mRem)

(9) Percent of I.B.3 yearly organ dose limit (30 mRem)

(10) Less than minimum detectable activity which meets the lower limit of detection (LLD) requirements of ODCM Surveillance Requirement 4.11.2.1.2.

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APPENDIX A CALVERT CLIFFS NUCLEAR POWER PLANT EFFLUENT AND WASTE DISPOSAL 2003 ANNUAL REPORT TABLE IC-REG GUIDE 1.21 GASEOUS EkELUEN1T - UKUUIN) LEVEL RELEASES CONTINUOUS MODE BATCH MODE IST 2ND 1ST 2ND UNITS QUARTER QUARTER QUARTER QUARTER

1. FISSION AND ACTIVATION GASES Argon -41 Ci (2) (2) 8.08E-03 6.30E-03 Krypton -85 Ci 2.13E+01 (2) 1.59E+00 6.38E+00 Krypton -85m Ci 5.97E-02 (2) 6.37E-03 4.02E-04 Krypton -87 Ci (2) (2) 2.85E-03 1.94E-05 Krypton -88 Ci (2) (2) 8.93E-03 1.39E-04 Xenon -131m Ci 9.03E-01 (2) 7.88E-03 3.5 1E-02 Xenon -133 Ci 8.91E+01 6.75E+00 6.97E-01 7.89E-01 Xenon -133m Ci 8.15E-01 (2) 8.88E-03 6.13E-03 Xenon -135 Ci 1.55E+00 9.52E-01 9.13E-02 1.17E-02 Xenon -135m Ci (2) (2) 5.29E-03 (2)

Xenon -138 Ci (2) (2) 3.71E-04 (2)

Total for Period Ci 1.14E+02 7.71 E+00 2.43E+00 7.23E+00

2. HALOGENS Iodine -131 Ci 1.33E-03 l 1.98E-04 l (1) 1 (1)

Iodine -133 Ci 1.21E-03 1. IIE-03 l (1) (1)

Bromine -82 Ci . (2) (2) f (1) (1)

Total for Period Ci 2.54E-03 1.3 1E-03 (1) (1)

CONTINUOUS MODE BATCH MODE 3RD 4TH 3RD 4TH UNITS QUARTER IQUARTER lQUARTER QUARTER

1. FISSION AND ACTIVATION GASES Argon -41 Ci (2) (2) 9.38E-04 1.47E-03 Krypton -85 Ci (2) (2) 5.50E-01 1.18E-01 Krypton -85m Ci (2) (2) 6.12E-05 1.20E-04 Krypton -87 Ci (2) (2) (1) (1)

Krypton -88 Ci (2) (2) (1) (1)

Xenon -131m Ci (2) (2) 1.86E-03 5.17E-03 Xenon -133 Ci 1.43E+01 I.OOE+01 1.27E-01 2.76E-01 Xenon -133m Ci 1.OOE+00 (2) 1.13E-03 2.18E-03 Xenon -135 Ci 1.90E+00 1.26E+00 1.76E-03 3.41 E-03 Xenon -135m Ci (2) (2) (1) (1)

Xenon -138 Ci (2) (2) (1) (1)

Total for Period Ci 1.72E+0I 1.13E+01 6.83E-01 4.07E-01

2. HALOGENS Iodine -131 Ci 1.81E-04 l 1.07E-04 l (1) l (1)

Iodine -133 Ci J 1.42E-03 J 6.03E-05 J (1) (1)

Bromine -82 Ci (2) l (2) (1) (1)

Total For Period Ci 1.60E-03 l 1.68E-04 (1) (1)

A-3

APPENDIX A CALVERT CLIFFS NUCLEAR POWER PLANT EFFLUENT AND WASTE DISPOSAL 2003 ANNUAL REPORT TABLE IC - REG GUIDE 1.21 GASEOUS EkTLUEN IS - RKUUND LEVEL RELEASES CONTINUOUS MODE BATCH MODE IST 2ND IST 2ND UNITS QUARTER QUARTER QUARTER QUARTER

3. PARTICULATES Manganese -54 Ci (2) (2) (1) (1)

Iron -59 Ci (2) (2) (1) (1)

Cobalt -58 Ci (2) (2) (1) (1)

Cobalt -60 Ci (2) (2) (1) (1)

Zinc -65 Ci (2) (2) (1) (1)

Strontium -89 Ci (2) (2) (1) (1)

Strontium -90 Ci (2) (2) (1) (1)

Molybdenum -99 Ci (2) (2) (1) (1)

Cesium -134 Ci (2) (2) (1) (1)

Cesium -137 Ci (2) (2) (1) (1)

Cerium -141 Ci (2) (2) (1) (1)

Cerium -144 Ci (2) (2) (1) (1)

Gross Alpha Radioactivity Ci (2) (2) (1) (1)

Total For Period Ci (2) (2) (1) (1)

CONTINUOUS MODE BATCH MODE 3RD 4TH 1 3RD 4TH UNITS QUARTER QUARTER QUARTER QUARTER

3. PARTICULATES Manganese -54 Ci (2) (2) (1) (1)

Iron -59 Ci (2) (2) (1) (1)

Cobalt -58 Ci (2) (2) (1) (1)

Cobalt -60 Ci (2) (2) (1) (1)

Zinc -65 Ci (2) (2) (1) (1)

Strontium -89 Ci (2) (2) (1) (1)

Strontium -90 Ci (2) (2) (1) (1)

Molybdenum -99 Ci (2) (2) (1) (1)

Cesium -134 Ci (2) (2) (1) (1)

Cesium -137 Ci (2) (2) (1) (1)

Cerium -141 Ci (2) (2) (1) (1)

Cerium -144 Ci (2) (2) (1) (1)

Gross Alpha Radioactivity Ci (2) (2) (1) (1)

Total For Period Ci (2) (2) (1) (1)

NOTES TO TABLE iC (1) Iodines and particulates in batch releases are accounted for with the main vent continuous samplers when the release is made through the plant main vent.

(2) Less than minimum detectable activity which meets the LLD requirements of ODCM Surveillance Requirement 4.11.2.1.2.

A-4

APPENDIX A CALVERT CLIFFS NUCLEAR POWER PLANT EFFLUENT AND WASTE DISPOSAL 2003 ANNUAL REPORT TABLE 2A - REG GUIDE 1.21 LIQUID EFFLuEN7 s5 - s UNIMAIIUN (UT ALL RELEASES IQ1ST 2ND EST. TOTAL UNITS QUARTER QUARTER ERROR, %

A. FISSION AND ACTIVATION PRODUCTS

1. Total Release (not including tritium, gases, alpha) Ci 1.76E-02 2.42E-02 1.03E+01l
2. Average diluted concentration during period pCi/ml 4.27E-10 1.09E-09
3. Percent of Tech. Spec. limit (1) _ 8.09E-02 2.24E-03
4. Percent of Tech. Spec. limit (2)  % 4.05E-02 1.12E-03
5. Percent of Tech. Spec. limit (3)  % 1.49E-02 8.07E-03

[

6. Percent of Tech. Spec. limit (4) _ 7.45E-03 4.03E-03 B. TRITIUM
1. Total Release J Ci 2.52E+02 1.37E+02 l+/-1.03E+01
2. Average diluted concentration during period lpCi/ml 1.48E-07 l 8.44E-08
3. Percent of applicable limit (5) l  % l 4.94E-03 l 2.81E-03 C. DISSOLVED AND ENTRAINED GASES
1. Total Release Ci 8.37E-02 1.35E-03 +/-1.03E+01
2. Average diluted concentration during period jtCi/ml 2.03E-09 7.86E- II 1 3RD 4TH EST. TOTAL l UNITS QUARTER QUARTER ERROR, %

A. FISSION AND ACTIVATION PRODUCTS

1. Total Release (not including tritium, gases, alpha) Ci 1.47E-02 1.00E-02 l.03E+01 l
2. Average diluted concentration during period pCi/mI 1.26E-09 4.50E-10
3. Percent of Tech. Spec. limit (1)  % 3.01E-03 5.05E-03
4. Percent of Tech. Spec. limit (2)  % 1.51 E-03 2.53E-03
5. Percent of Tech. Spec. limit (3) 1.00E-02 1.68E-02
6. Percent of Tech. Spec. limit (4)  % 5.02E-03 8.42E-03 B. TRITIUM
1. Total Release Ci 9.68E+01 3.20E+02 +/-i.03E+O1
2. Average diluted concentration during period pCi/ml 7.78E-08 3.06E-07
3. Percent of applicable limit (5)  % 2.59E-03 1.02E-02 C. DISSOLVED AND ENTRAINED GASES
1. Total Release Ci 5.02E-04 3.27E-03 +/-1.03E+01 1 2. Average diluted concentration during period I VCi/ml I 5.43E-11 I 1.66E-10 I A-5

APPENDIX A CALVERT CLIFFS NUCLEAR POWER PLANT EFFLUENT AND WASTE DISPOSAL 2003 ANNUAL REPORT TABLE 2A - REG GUIDE 1.21 LIQUID EFFLuETS I S - SUMMAJIU N OF A'LL RELEASES I QUIST 2ND EST. TOTAL l UNITS QUARTER QUARTER ERROR,%

D. GROSS ALPHA RADIOACTIVITY

1. Total Release Ci (6) (6) +/-5.40E+01 E. VOLUME OF WASTE RELEASED (prior to dilution) liters 7.79E+07 1.07E+08 +/-l.30E+00 F. VOLUME OF DILUTION WATER USED DURING PERIOD (7) liters 8.90E+lII 1.1lE+12 +/-l.64E+01 3RD I 4TH IEST. TOTAL UNITS l QUARTER QUARTER l ERROR, %

D. GROSS ALPHA RADIOACTIVITY

l. Total Release Ci (6) (6) +/-5.40E+01 E. VOLUME OF WASTE RELEASED (prior to dilution) liters 8.28E+07 8.36E+07 +/-1.30E+00 F. VOLUME OF DILUTION WATER USED DURING PERIOD (7) liters l.20E+12 1.20E+12 +/-l.64E+01 NOTES TO TABLE 2A (1) Percent of I.C.3 Quarterly Organ Dose Limit (10 mRem) to maximum exposed organ (2) Percent of I.C.3 Yearly Organ Dose Limit (20 mRem) to maximum exposed organ (3) Percent of I.C.3 Quarterly Whole Body Dose Limit (3 mRem)

(4) Percent of I.C.3 Yearly Whole Body Dose Limit (6 mRem)

(5) Limit used is 3 x 10-3 [,Ci/ml (6) Less than minimum detectable activity which meets the LLD requirements of ODCM Surveillance Requirement 4.1 1.1.1.1.

(7) Includes dilution water used during continuous discharges.

A-6

APPENDIX A CALVERT CLIFFS NUCLEAR POWER PLANT EFFLUENT AND WASTE DISPOSAL 2003 ANNUAL REPORT TABLE 2B - REG GUIDE 1.21 LIQUID EFFLUENTS CONTINUOUS MODE BATCH MODE 1ST 2ND 1ST 2ND NUCLIDES RELEASED Units QUARTER QUARTER QUARTER QUARTER Beryllium - 7 Ci (1) (1) (1) (1)

Sodium - 24 Ci (1) (1) (1) 2.49E-06 Chromium - 51 Ci (1) (1) 1.45E-03 9.32E-05 Manganese - 54 Ci (1) (1) 3.04E-04 4.17E-05 Iron -55 Ci (2) (2) 2.97E-03 1.42E-02 Cobalt - 57 Ci (1) (1) 3.19E-05 7.91E-06 Cobalt-58 Ci (1) (1) 5.99E-03 2.38E-03 Iron - 59 Ci (1) (1) 8.36E-06 6.30E-06 Cobalt - 60 Ci (1) (1) 1.44E-03 2.93E-04 Zinc - 65 Ci (1) (1) (1) (1)

Strontium - 89 Ci (1) (1) (1) 4.78E-04 Strontium - 90 Ci (1) (1) (1) (1)

Strontium - 92 Ci (1) (1) (1) (1)

Niobium - 95 Ci (1) (1) 1.02E-03 1.91E-04 Zirconium - 95 Ci (1) (1) 6.34E-04 1.34E-04 Niobium - 97 Ci (1) (1) (1) (1)

Zirconium - 97 Ci (1) (1) (1) (1)

Molybdenum - 99 Ci (1) (1) (1) (1)

Technetium - 99m Ci (1) (1) (1) (1)

Ruthenium- 103 Ci (1) (1) (1) (1)

Rhodium- 105 Ci (1) (1) (1) (1)

Ruthenium - 105 Ci (1) (1) (1) (1)

Silver- IIOm Ci (1) (1) 4.95E-04 4.19E-04 Tin - 113 Ci (1) (1) 4.63E-05 4.34E-06 Tin-117m Ci (1) (1) 5.44E-04 5.33E-04 Antimony- 122 Ci (1) (1) (1) (1)

Antimony- 124 Ci (1) (1) (1) 5.50E-04 Antimony- 125 Ci (1) (1) 1.40E-03 4.71E-03 Tellurium- 125m Ci (1) (1) (1) (1)

Tellurium - 132 Ci (1) (1) (1) (1)

Iodine - 131 Ci (1) (1) 5.3 1E-04 5.04E-05 Iodine- 132 Ci (1) (1) (1) (1)

Iodine- 133 Ci (1) (1) (1) 1.08E-05

[odine- 135 Ci (1) (1) (1) (1)

Cesium- 134 Ci (1) (1) 2.47E-05 3.19E-05 Cesium- 136 Ci (1) (1) (1) (1)

Cesium- 137 Ci (1) (1) 1.56E-04 1.06E-04 Barium- 140 Ci (1) (1) (1) (1)

Lanthanum- 140 Ci (1) (1) (1) (1)

Cerium- 144 Ci (1) (1) 2.25E-04 (1)

Europium- 154 Ci (1) (1) 2.03E-04 (1)

Europium-155 Ci (1) (1) 1.47E-04 (1)

Tungsten- 187 Ci (1) (1) (1) (1)

Total For Period Ci (1) (1) 1.76E-02 2.42E-02 A-7

APPENDIX A CALVERT CLIFFS NUCLEAR POWER PLANT EFFLUENT AND WASTE DISPOSAL 2003 ANNUAL REPORT TABLE 2B - REG GUIDE 1.21 LIQUID EFFLUENTS CONTINUOUS MODE BATCH MODE 3RD 4TH 3RD 4TH NUCLIDES RELEASED Units QUARTER QUARTER QUARTER QUARTER Beryllium - 7 Ci (1) (1) (1) (1)

Sodium - 24 Ci (1) (1) (1) (I)

Chromium - 51 Ci (1) (1) (1) (1)

Manganese - 54 Ci (1) (1) 2.66E-04 1.33E-04 Iron - 55 Ci (2) (2) 4.49E-03 5.431E-03 Cobalt - 57 Ci (1) (1) 3.OOE-05 6.29E-06 Cobalt - 58 Ci (1) (1) 3.96E-03 2.08E-03 Iron - 59 Ci (1) (1) 4.33E-05 (1)

Cobalt - 60 Ci (1) (1) 1.13E-03 7.72E-04 Zinc - 65 Ci (1) (1) (1) (1)

Strontium - 89 Ci (1) (1) 5.27E-06 8.12E-07 Strontium - 90 Ci (1) (1) 1.64E-06 2.53E-07 Strontium - 92 Ci (1) (1) (1) (1)

Niobium - 95 Ci (1) (1) 1.06E-03 3.83E-04 Zirconium- 95 Ci (1) (1) 5.52E-04 1.41E-04 Niobium - 97 Ci (1) (1) (1) (1)

Zirconium - 97 Ci (1) (1) (1) (1)

Molybdenum - 99 Ci (1) (1) (1) (1)

Technetium - 99m Ci (1) (1) (1) (1)

Ruthenium- 103 Ci (1) (1) (1) (1)

Rhodium- 105 Ci (1) (1) (1) (1)

Ruthenium- 105 Ci (1) (1) (1) (1)

Silver- liOm Ci (1) (1) 4.74E-04 8.34E-04 Tin - 113 Ci (1) (1) (1) 2.06E-06 Tin - 117m Ci (1) (1) (1) (1)

Antimony- 122 Ci (1) (1) (1) (1)

Antimony - 124 Ci (1) (1) (1) (1)

Antimony- 125 Ci (1) (1) 2.57E-03 1.67E-04 Tellurium- 125m Ci (1) (1) (1) (1)

Tellurium - 132 Ci (1) (1) (1) (1)

Iodine- 131 Ci (1) (1) 7.62E-06 1.51E-05 lodine- 132 Ci (1) (1) (1) (1)

Iodine- 133 Ci (1) (1) 4.88E-06 (1)

Iodine- 135 Ci (1) (1) (1) (1)

Cesium- 134 Ci (1) (1) 3.25E-06 1.96E-05 Cesium- 136 Ci (1) (1) (1) (1)

Cesium - 137 Ci (1) (1) 2.92E-05 2.62E-05 Barium- 140 Ci (1) (1) (1) (1)

Lanthanum- 140 Ci (1) (1) (1) (1)

Cerium- 144 Ci (1) (1) (1) (1)

Europium - 154 Ci (1) (1) (1) (1)

Europium- 155 Ci (1) (1) (1) (1)

Tungsten- 187 Ci (1) (1) (1) (1)

Total For Period Ci (1) (1) 1.47E-02 1.OOE-02

APPENDIX A CALVERT CLIFFS NUCLEAR POWER PLANT EFFLUENT AND WASTE DISPOSAL 2003 ANNUAL REPORT TABLE 2B - REG GUIDE 1.21 LIQUID EFFLUENTS CONTINUOUS MODE BATCH MODE IST 2ND 1ST 2ND NUCLIDES RELEASED Units QUARTER QUARTER QUARTER QUARTER Krypton - 85 Ci (1) (1) 7.38E-03 (1)

Xenon- 131m Ci (1) (1) 7.04E-04 (1)

Xenon- 133 Ci (1) (1) 7.52E-02 1.35E-03 Xenon- 133m Ci (1) (1) 3.27E-04 (1)

Xenon-135 Ci (1) (1) (1) (1)

Total For Period Ci (1) (1) 8.36E-02 1.35E-03 CONTINUOUS MODE BATCH MODE 3RD 4TH 3RD 4TH NUCLIDES RELEASED Units QUARTER QUARTER QUARTER QUARTER Krypton- 85 Ci (1) (1) (1) (1)

Xenon-131m Ci (1) (1) (1) (1)

Xenon - 133 Ci (1) (1) 5.02E-04 3.27E-03 Xenon- 133m Ci (1) (1) (1) (1)

Xenon- 135 Ci (1) (1) (1) (1)

Total For Period Ci (1) (1) 5.02E-04 3.27E-03 NOTES TO TABLE 2B (1) Less than minimum detectable activity which meets the LLD requirements of ODCM Surveillance Requirement 4.11.1.1.1.

(2) Continuous mode effluents are not analyzed for Fe-55.

A-9

APPENDIX A CALVERT CLIFFS NUCLEAR POWER PLANT EFFLUENT AND WASTE DISPOSAL 2003 ANNUAL REPORT TABLE 3A CALVERT CLIFFS NUCLE POWER PLANT EFFLUENT AND WASTE DISPOSAL ANNUAL REPORT 2003 SOLID 'ASTE AND IRRADIATED FUEL SHIPMENTS A. SOLID WASTE SHIPPED OFFSITE FOR BURIAL OR DISPOSAL (NOT IRRADIATED FUEL)

1. Type of Waste Units 12-Month Pcriod Est. TIotal Error %

a) Dewatered spent resin m 3

7.6UE+0T) 2.00E+01 Ci 2.70E+02 b) Dry compressible M3 8.59E+02 5.0OE+01 waste, contaminated Ci 1.23E+00 equipment, etc.

c) Irradiated components, m3 0.'OOE+00 N/A control rods, etc. Ci 0.00E+00 d) other (Cartridge m3 0.OOE+00 N/A Filters) Ci 0.00E+00

2. Estimate of Major Nuclides (By Type of Waste - Only nuclides >1 % are reported) a) Mn-54 1.71E+00%

Fe-55 8.42E+00%

Co-58 4.63E+01%

Co-60 4.47E+00%

Ni-63 8.12E+00%

Cs-134 9.97E+00%

Cs-137 1.74E+01%

b) Cr-51 8.07E+00%

Mn-54 1.44E+00%

Fe-55 2.59E+01%

Co-58 3.48E+01%

Co-60 5.73E+00%

Ni-63 9.48E+00%

Nb-95 6.04E+00%

Zr-95 4.70E+00%

c) N/A d) N/A A-10

APPENDIX A CALVERT CLIFFS NUCLEAR POWER PLANT EFFLUENT AND WASTE DISPOSAL 2003 ANNUAL REPORT

3. Solid Waste Disposition Number of Shipments Mode of Transportation Destination 31 Motor Surface Transit Duratek, Inc.

Oak Ridge, TN 7 Motor Surface Transit RACE, LLC Memphis, TN 3 Motor Surface Transit Studsvik Processing Facility Ervin, TN B. IRRADIATED FUEL SHIPMENTS (DISPOSITION)

N/A A-lI

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