SVP-04-099, Renewal of National Pollutant Discharge Elimination System (NPDES) Permit No. Il 0005037
| ML043270466 | |
| Person / Time | |
|---|---|
| Site: | Quad Cities  |
| Issue date: | 11/17/2004 |
| From: | Tulon T Exelon Generation Co, Exelon Nuclear |
| To: | Document Control Desk, Office of Nuclear Reactor Regulation |
| References | |
| SVP-04-099 | |
| Download: ML043270466 (121) | |
Text
Exelokn Exelon Generation Company, LLC www.exeloncorp.com Nuclear Quad Cities Nuclear Power Station 22710 206"' Avenue North Cordova, IL 61242-9740 SVP-04-099 November 17, 2004 U. S. Nuclear Regulatory Commission ATTN: Document Control Desk Washington, D.C. 20555 Quad Cities Nuclear Power Station, Units 1 and 2 Facility Operating License Nos. DPR-29 and DPR-30 NRC Docket Nos. 50-254 and 50-265
Subject:
Renewal of National Pollutant Discharge Elimination System (NPDES)
Permit No. IL 0005037 In accordance with Technical Specifications, Appendix B, Section 2.2, "Reporting Related to the NPDES Permits and State Certifications," enclosed is the application for renewal of the NPDES Permit for Quad Cities Nuclear Power Station.
Should you have any questions concerning this letter, please contact Mr. W. J. Beck at (309) 227-2800.
Respectfully, Ti ty J. Tulon Site Vice President Quad Cities Nuclear Power Station
Attachment:
Renewal Application for NPDES Permit No. IL 0005037 cc: Regional Administrator - NRC Region IlIl (w/o Attachment)
NRC Senior Resident Inspector - Quad Cities Nuclear Power Station (w/o Attach.)
cc)ol
Attachment Renewal Application for NPDES Permit No. IL 0005037
Exelkn.mA Exelon Generation Company, LLC www.exeloncorp.com Nuclear Quad Cities Nuclear Power Station 22710 206th Avenue North Cordova, IL 61242-9740 SVP-04-098 November 17, 2004 Certified Mail Mr. Blaine Kinsley Illinois Environmental Protection Agency DWPC Permit Section #15 1021 North Grand Avenue East P. 0. Box 19276 Springfield, Illinois 62794-9276
Subject:
Quad Cities Nuclear Generating Station Application to Renew NPDES Permit No. IL 0005037 In accordance with the requirements of Title 35 of the Illinois Administrative Code, Subtitle C, Chapter I - Pollution Control Board, Section 309.104 and the requirements of 40 CFR 122.21, Exelon Generation Company, LLC, Quad Cities Generating Station hereby submits two copies of Consolidated Permit Application Forms 1 and 2C with associated attachments for the renewal of Quad Cities NPDES Permit No. IL0005037.
As allowed by the IEPA with previous NPDES permit renewals submitted October 12, 1994 and November 8, 1999, the only Form 2C, Part V-A pollutants reported are those required by the station's existing NPDES permit. Additionally, pollutants categorized as GCIMS Fraction Compounds in Part V-C are not reported for any outfalls, as requested by Quad Cities Station in a correspondence to the IEPA on September 10, 2004. Relief from sampling for these pollutants was requested and granted by the IEPA with the previous two NPDES Permit renewals submitted October 12, 1994 and November 8, 1999.
Pollutant levels for all permit-required parameters were derived from station data reported on Discharge Monitoring Reports (DMRs) from January 2003 through December 2003. In most cases, only one analysis was conducted for all other pollutant parameters identified on Form 2C.
Long-term flow averages requested on Form 2C, Item V.1 have been computed by averaging the monthly flow averages reported on the January 2003 through December 2003 DMRs for each outfall. Mass load values were calculated using long-term average flows.
Included with application Forms 1 and 2C are several Attachments as follows: Attachment 1, Requested Permit Changes. The requests are bulleted under each outfall number for clarity. , Area Topographic Map and Site Area Map as requested in Form 1, XI. , Site Water and Wastewater Flow Diagram as requested in Form 2C section IIA. , Listing of water treatment additives that have the potential of being discharged by way of the various outfalls with associated Material Safety Data Sheets (MSDSs). Attachment 5 is a copy of a correspondence to your office dated September 10, 2004 requesting the waiver of selected analyses.
Q:\5VP\SVP 20U0498.doc
Illinois Environmental Protection Agency November 17, 2004 Page 2 of 2 In regards to compliance with Section 316(b) of the Clean Water Act, USEPA final rule published July 9, 2004, 69 Federal Register 41575 through 41683, Section 125.95 of the new rule requires detailed studies and other information to establish what intake structure technology or other measures will be used to comply with the rule. Ordinarily, this material is to be submitted with the facility's next application for renewal of its NPDES permit. For permits that expire less than four years after the rule was published on July 9, 2004 (that is, before July 9, 2008), the operator may have up to three and half years to submit the information under the rule, so long as it is submitted "as expeditiously as practicable" in accordance with 40 CFR 125.95(a)(2)(ii). Quad Cities Generating Station's current NPDES permit expires on May 31, 2005, well before July 9, 2008. Therefore, Quad Cities is submitting to IEPA, under separate cover, a request for a schedule to submit the required 316(b) information pursuant to 40 CFR 125.95(a)(2)(ii). Our letter will request that Exelon Generation Company, LLC, be allowed to submit the information called for by Section 125.95 as expeditiously as practicable, which, for the reasons provided, will require until January 7, 2008. A copy of this letter is included as Attachment 6.
Please contact Mark Stuhlman at (309) 227-2765 if you have any questions regarding this application.
Sincerely, T2ty J. Tulon e Vice President Quad Cities Generating Station Forms and Attachments:
EPA Form 1 EPA Form 2C : Requested Permit Changes : Area Topographic Map and Site Area Map : Site Water and Wastewater Flow Diagram : List of Water Treatment Additives and MSDS Sheets : Copy of Letter Requesting Waiver : Copy of Letter Requesting 316(b) Schedule cc: Quad Cities Regulatory Assurance Vicki Neels Mark Stuhlman John Petro Jim Bolte Larry LaJeone Letterbook Q:\SVP\SVP 2O04\098.doc
Please prntj or iype in.-h-e unshaded areas only Form Apprvovd. 0MBS No. 2040-0086: - _
(fill-in areas are spoaded for elite Wep.ILe.. 12c GENERAL' FORM j -'U.S. ENV Otead thi I J4! L'D'0'6 0 If a preprinted.1ebe1Ifsas 6 28 1I0' en providacd affix:
I finthe designated space. ReView the inform-:~'
ation carefully; it any of. It it Incorrect, cross~
through It and -enter the "correct dlata In the:
appropriate fitr-Jn area below. Also, if any of,
.the preprinied data Is absent (die area to the' left of the label1 spce jutsr -the ,nfbimatloon that should appear), please proivide* It In -0he prbper fill -4n- anrealIs) ,bilow.~ If the label *)s.'
.complete pnd correct. you need not comiplete.;
Items I, Ill. YV,and -VIl (exceot VI-B~which-;
must be conmpleted re'gardless). Complete,'ill'
-items If no label has ,been 'provided. FRefer tb1 the instructions...for ;detailed . Item. descrip<
I ..slons add *for--ihi Qlegl authorizations .undir.
wh.ich. this data Is c~ d*..
II. POLLUTANT CHARACTERISTICS' INSTRUCTIONS: Complete A throu h J to'ditermin&kihether~ysi need to submit.ariy~pii ap lieinfrm oteEA. you anrswer 'yes" to any questions, you must submit this form and the supplemental form 'listed In the parentheisisfllowilng the questio'n. Mark 'X7iln the boixtn the third collumn if -the supplemenital form Isattached. If -you answer toua In" iusilon, you need in6t sbhayfteefrs o.ny si~t fyu clly is excludled from perm'it requirements; see Section Cof the Inisitruit~ioni, See also, Section W'of ilie, In'siructoiots for definition fblld-of a dt-9111.
- SrcclriC OUCSTIONS
- 1] ki..1 e.Y1aC * -,sPcI
- .:*' V-iCQUESTI Ohs.'ysP0J, ARK.
A. -Is this facility O'publicly ownedl .treatmennt~,orki so~il;lfciiV(fhreitn ... or. propos-d wvhich results in a discharge to ivaters'of-the U.S.?.incdeosmnr1 amlfeigoprtrsr (FORM2A-. .. ~ X . *. ..:aquatk'nlmalproductiors.facility which tesults f
- . ~ discharg. towAirsrofthe U.S,? (FORM 28) ; .4" C. is this a facility which currently results in.discharges D. Is this a proposed faciliW fother than those described lo waters of the'U.S. ~other than' those describiedl in X *In A4 Wo 8.#6bv)'whchy wil resuli in's dischargei to. X
'Aor( above7 (FORM 2C1 . ~ ~ 2 S. ~ teers ofth U.S.?'(FORM 2D) - ' ___
.E. Does or will this facility tret strorF outra 0.yuoosfeo nJetfthsaiit r hazardous wastes? IFORM 31 X-aigwthnOeqate ieo he wyell ..bore`
U. Do you or will you inject at tIs laii n roue water or other fluids which are brought to the'surface H.Q'orrWl yuIecathifcltyjudfrpe in connection wvitho conventional oil or natural gas pro. . 'iipoessAc smnn fsulfur by the'Fac dluctiari. Inject fluids used for ernhanced recoveiry' I, ~ ~ i~~~~~go fieasIi~o~u-ilor natural.gai.-or*. inject -f iclus jor~storaqi of liquid ~~t&~.
iwydiocarbcini? WFORMt4V . " _ .:;A: r4.'4 I stutclt rposed stationary jource wh!nich isr:PoM'hihs
.one 6f the 2 industrialcaerisite nteen s-shi aiiyapooedsaieyaoc wchi.
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-III NAME OF FACII2ITY UI
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IV. FACILITY CONTACT.-
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lbI VI. FACILITY LOCATION_
A. STREET. ROUTE NO. OR OTHER sPECcsvac IDENTIFJER '
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I I i i i I £ i i II C I I i5 iI J6 Co r'do v a EPA Form 3510-1 (8.90)COTNENRVRS CONTINUE ON REVERSE
X. EXISTING ENVIRONMENTAL PERMITS cont.
A. NPDES (Dischargesto Surface Water)
ILR109537 Notice of Coverage Under Construction Site Activity Storm Water General Permit E. Other (Specify)
CENCR-OD-S-297290 U.S. Army Corps of Engineers Rock Island District Maintenance Dredging Permit 2002-EA-5001 Quad Cities Dredged Material Sedimentation Ponds
EPA l.D. NUMBER (copy from Item I of form 1) Form Approved.
OMB No. 2000-0059Approval Please print or type In the unshaded areas only. IILD060862810 I expires 12-31-85 FORM . ..... '-:. .. ENVIRONMENTAL PROTECTION AGENCY-'
. q-n- A S:sw ^;vv '^w' ^'tiixPPUICAT ON FORiPERMTrTODIS nisARGILWAsTWTR->;<
2C - .,'l : EXISTiNG MANUFACTURING, COMMERCIAL, MINiNG AND SOLViCULTURAL PERATIONS-'-`-
.' 9,s oi9',
'olidatedPermits Program 9,'
I. OUTFALL LOCATION 2 I For each outfall list the latitude and longitude to the nearest 15 seconds and the name of the receiving water.
A OL. u.5 . . LATITUDE _ _ . C. ,LONGITUDE ... '- U: .DRECEIVING WA NUMBER (lit) 'I. DEG. 2. MIN :3. SEC. "A. DEG ^2. MIN.-. ^3. SEC. '
0011002 41 43 30 90 18 45 Mississippi River B01 41 43 30 90 18 45 Mississippi River Col 41 43 30 90 18 45 Mississippi River A02 41 43 30 90 18 45 Mississippi River It. FLOWS, SOURCES OF POLLUTION, AND TREATMENT TECHNOLOGIES',9. ;.... ,.;-...
A. , Attach a line drawing showing the water tlow through the facility. Indicate sources ot Intake water, operations contributing wastewater to
-the etiluentand treatment units labeled to correspond to the rnore detailed in Item B. Constructa water balance on the line
, drawing by showing average lows betwee intakes opeations treatment units, and outfals.IfI ater balncriiiannot be deteriijned:
- .. .. : (e.g. for cehaidininihg activities) provide a pictorial description of the nature and amount of any source of water and any collectioor
-*treatment measures * :-'@ ; ,; ' , Y .
B. . -. For each outfall, provide a description of: (1)All operations contributing wastewater to the effluent, including process wastewater, sanitary
.*wasteitrcooling
- water and storm waier runoff; (2)The average flow contribiuitedy each operation and (3)'Theireatrient received b the wastewater.' Continue 'on additionai sheets If nees ar j, . .v. Y
- 2. OPERATION(S) CONTRIBUTING FLOW^- u 3 TREATMEN -.
1.OUTFALL "NO Nb.AVERAGE (1.
C eSCra. OPERATIONl (VisQ FLOW IPTION~ ~ ~-~AL b.LIST CODES 2 FROM 001/002 Open Cycle Diffusers 1016.4 MGD Discharge to Surface Water 4-A Main Condenser Cooling water 972.4 MOD ____
House Service Water 44 MGD
.Radwaste Treatment System Blowdown .055 MGD Wastewater Treatment Plant .051 MGD Sanitary Waste Treatment Plant .004 MGD . ._.
House Service Water Strainer Backwash .126 MGD Intake Screen Backwash .508 MGD Units 1 and 2 Oil / Water Separators Intermittent __l_____
Fish Culture Facilities Intermittent Crib House Floor Drain Sump . ._______
BOt Wastewater Treatment Plant .051 MGD Oil/Water Separation, X-X Crib House Floor Drain Sump .050 MGD Equalization X-X Aux. Boiler 8bowdown - Seasonal Coagulation, Flocculation 2-D t1-Root and Floor Drains Intermittent Multimedia Filtration t-0 Portable Demineralizer Rinse Water Intermittent Drying Beds 55-H uFrIL Lus LuLT(errtuenrguiaennes suo-caregones) *-:* tr * ;^ ; -^,;,. ,Z ;. '....
Form 245) PAGE 1_ OTIU N EES EPA Form 351 D-2C (Rev. 2-85) PAGE I OF 4 CONTINUE ON REVERSE
II CONTINUED FROM THE FRONT C. except for storm runoff, leaks, or spills, are any of the discharges described in Items Il-A or B intermittent or seasonal?:
- I X Y ES (comaletethefoliowino table) O N1Nt': to Section- i)
- 3. FREQUENCY _________ 4k FLOW::
2, OPERATION(S) a. DAYSPER b, MONTHS aFL RATE - b.TOTAL VOLUME (specff'
- 1. OUTFALL CONTRIBUTING FLOW(list) WEEK (pcf PERYEAR (SPaCdfy.: 1.OGEM2MXMMILNTR i Whur
.AIU
. ;, DUR (i~ daysj)
NUMBER (list) . : . average) average) ; AVERAGE DAILY.: AVERAGE: DAILY A02 Radwaste Treatment System Blowdown 1 12 0.055 0.057 55,000 gal 56550 gal 1 ill. PRODUCTION - -
A. Does an eI onpromulgatedby EPA under Section 4 of the CeanWaterAct apply to your facility?-::
F X 7YES (completeItem Ill-B) . F1 1 6 go to Section IV0 B. Are limitations in te applicable effluent guideline expressed in terms of production (or other measure ofoeain . . 2: *i'
-: IIYES (complete Itern II-C Q:- X INO (o 16 Section IV :0 Nii----: -j.;:. t:
C. If you answered 'yes' to Item IjH-B, list the quanti/y which represents an actual measurement of your level of production, expressect in terms and units used in the appiicable effluent guideline. and indicate the affected ouffaiis..: :0 :i2 : : 5 :;i-" -': 'iii0"2:;: :: \ ;S'
- : .:t. AVERAGE DAILY PRODUCTION YES (complet ltemTIll-C : -.--
((oitotSctionaI ::f-I : 2. AFFECTED ::.
- a. OUANTITY PER DAY b. UNITS OF MEASURE C.OPERATION PRODUCT. MATERIAL. ETC. (specify) : OUTFALLS (list outfa numbers N/A N/A N/A NA IV. IMPROVEMENTS -
A. Are you now required by any Federal, State or Local authority to meet any implementation schedule for the construction, upgrading or operation of ..
wastewater treatment equipment or practices or any other environmental programs which may affect the discharges described in this application?7This.
includes, but is not limited to, permit conditions, administrative or enforcement orders, enforcement compliance schedule letters, stipulations, court orders, and grant or loan conditions.'
F ES(cimplete the following table X N got te vB)
- 1. IDENTIFICATION OF 2. AFFECTED OUTFALLS -. 4. FINAL COM-CONDITION :3. BRIEF DESCRIPTION OF PROJECT PLIANCE DATE Na. NO. b.SOURCEOFDISCHARGE N/A N/A N/A N/A N/AJCTD B.UOIIUNAL You may vwsn to anacn additional sneets oescrioing any adaitionaI water poiiution controi programs (°ootner environmenral projecTs:
which may affect your discharges) you now have underway or which you plan. Indicate whether each program is now underway or planned, and . :
indicate your actual or planned schedules for constructionC..
F1M-lARK X IF DESCRIPTION OF ADDITIONAL CONTROL PROGRAMS IS ATTACHED.
EPA Form 3510-2C (Rev. 2-85) PAGE 2OF 4 CONTINUE ON PAGE 3
EPA I.D. NUMBER (copy from Item 1 ol form 1) Form Apprpved OMB No. 2000-0059 Approval Please print or type In the unshaded areas only. I ILD060862810 I expires 12-31-85 FORM .- .'... 'U.S. ENVIRONMENTALPROTECTIONAGENCY .-". S4> .?:
.;-sr;-'
-.- E
,V'APPUCATION FOR PERMITTO DISCHARGE WASTEWATER T EXISTING MANUFACTURING, COMMERCIAL, MINING AND SILVICULTURAL OPERATIONSv-;
NPDES -'ConsolidatedPemtPrrm
- 2. OPERATION(S) CONTRIBUTING FLOW`':;-,o. FLOW. s TREATMENT:.
1.OUTFALL . . . AVERAGE DIST:CODES b FROb N(ls)a PERATION (list) a DESCRIPTOLITCDSFM C01 Sanitary Waste Treatment Plant .004 MGD Grinding, Equalization. 1-L X-X Sedimentation, Trickling Filter or 1-U 3-H Rotating Biological Contactor, X-X Sedimentation, Disinfection, 1-U 2-F Aerobic Digestion, Drying Beds 5-A 5-H Landfill (radioactive burial) 5-0 A02 Radwaste Treatment System Blowdown .055 MGD Filtration or Demineralization, 1-0 2-J Laundry Wastewater, Floor Drains, Reuse/Recycle of Treated Effluent 4-C Equipment Drains, Reactor Water On-Site Storage of Sludge X-X Filter Backwash from Reactor Cleanup and Landfill (radioactive burial) 5-0 Condensate Demineralizers, Laboratory Wastewater .'
ftl. .. J~~~d. ~l ~JL~5 Jf,.,. W4..~
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eL~~ t.--JlI~i% L EPA oUrm 351 sIC (Rev. 2,)PA G E- O.F 4 . O'N . FO P >
1; . ; " ;
EPA Form 3510-2C (Rev. 2-85) PAGE 1 OF 4 (CONTINUED FROM PAGE 1)
EPA I.D. NUMBER (copy from Item 1 of form 1) FonrlAprowd OMB No. 2000-0059 Approval CONTINUED FROM PAGE 2 I ILD060862810 expires 12-31-85 V. INTAKE AND EFFLUENT.CHARACTERISTICS e .
U' I A, B& C:. .See Instnuctions before proceeding *,Complete one set of tables for each outfall - Annotate the outfall number in the space provided.
'NOTE: 'TabtesV-A, V-B,'and V-C are incuded onseparate sheets number V-1thro ghv. *.
- . .,Use the space below to list any of the pollutants listed In Table 2c-3 of the instructions. which you know or have reason to believe Is
..discharg
- a. dorrr aybedischarge oanyou rever p tani'youlist'nefydes ;be thereasons yo ' elve Itto.ese and report anyanalytical data Inyouri obssession l . e;, .
1.:POLLUTANT ; .. 2.;S0URCE : -'> *...POLLUTANT<2.SOURCE .
N/A N/A N/A N/A VI. POTENTIAL DISCHARGES NOT COVERED BY ANALYSIS Is any pollutant listed in Item V-C a substance or a component of a substance which you currently use or manufacture as an Intermediate or final .
product or byproduct7 ? ' ' j f 9 'C ' '
F lYES (list allsupollutants below) '
&A r X (go iNO to itemW-B) VR N/A r~u~j urq I Wi Ij- -. 1 nr.VcnQQ tMA Formn 3510-2%. triev. Z-85J PAGEt JUF %~` I#INUCL WIN
II CONTINUED FROM THE FRONT
[VII. BIOLOGICAL TOXICITY TESTING DATA:.::: -? E;: l _ i Do you have knowledge or reason to believe that any biological test for acute or chronic toxicity has been made on any of you discharges or on a receiving water in relation to your discharge within the last 3years? F 1NO-(go to SectionViii)
FIYES (identify thetes(sanddescribetheirpurposes below)
N/A LVIII. CONTRACT ANALYSIS INFORMATION Were any of the analyses reported in Item V performed by a contract laboratory or consulting firm?-:
XZlZYES (list the name, address, and telephone number of, and, NO (go to Section IX) pollutants analyzed by, each such laborato yor firm below) -________.:_:.____-:_:____:_.:
C. TELEPHONE D. POLLUTANTS ANALYZED A. NAME B. ADDRESS (area code & no.) (list)
Severn Trent Labs St. Louis 13715 Rider Trail North, (314) 298-8566 Outfall A02: All Analyses Earth City, Missouri 63045 TestAmerica Incorporated 704 Enterprise Drive (319) 277-2401 Outfall 001 1002: All Analysis Cedar Falls, Iowa 50613-0625 Outfall B01: All Analysis Outfall C01: All Analysis Intake: All Analysis IX.CERTIFICATION -
I certify under penalty of law that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel property gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system or those persons directly responsible for gathering the information submitted is, to the best of my knowledge and belief, true, ..
accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fine and:
imprisonment for knowing violations.
A. NAME & OFFICIAL TITLE (type orprint) B. PHONE NO. (area code & no.)
Timothy J. Tulon / Site Vice President Quad Cities Generating Station (309) 227- 3600 C. SIGNATURE D. DATE SIGNED 751-2 For EPA~/ (Rv PAe 4O EPA Form 3510-2C (Rev. 2- PAGE 4OF 4
PLEASE PRINT OR TYPE IN THE UNSHADED AREAS ONLY. You may report some or all of EPAI.D. NUMBER (copy from lteml of Form 1) Fonm Awoved this Information on separate sheets (use the same format) Instead of completing these pages.
SEE INSTRUCTIONS ILD 060862810 88A~wna, 0M9 No. 2000-0059 D ee 1t-24 V. INTAKE AND EFFLUENT CHARACTERISTICS (continued from page 3 of Form 2-C)
PART A - You must provide the results of at least one analysis for
- a. MAXIMUM DAILY VALUE _ . ...........
- 1. POLLUTANT d. NO. OF 4 .5. MLLL....... ANAL-(t) (2) MASS YSES TRABU I --
- b. Chemical Oxygen Demand (COD) -
- c. Total Organic Carbon =
- d. Total Suspended Solids (TSS) -
- e. Ammonia I. Flow VALUE 1436 VALUE 1422 VALUE 1016.4 365 MGD VALUE g.Temperature VALUE 34.8 4.828.4 VALUE VALUE 26.9 121 OCVALUE h.Temperature VALUE 46.17 43.2 VALUE 39.3 122 . VALUE (summer) _ _ _ _ _ _ _ _
- INIMUM MAXIMUM M 7.7 8.8 52 STANDARD UNITS PART B - Mark X in column 2-a for each pollutant you know or have reason to believe Is present. Mark X in column 2-b for each pollutant you believe to be absent. If you mark column 2a for any pollutant %hIch Is limited either directly, or indirectly but expressly, In an effluent limitations guideline, you must provide the results of at least one analysis for that pollutant. For other pollutants forvwhich you mark column 2a. you must provide quantitative data or an explanation of their presence In you discharge. Complete one table for each outfall. See Instructions for additional details and requirements.
- 1. POLLUTANT 2. MARK X' 3. EFFLUENT . - 4.UNITS - 5. INTAKE (opekmao AND CAS b.B c BE, a. MAXIMUM DAILY VALUE b. MAXIMUM 30 DAY VALUE c.LONG TERM AVRG. d. NO. OF a. CONCEN b. MASS a. LONG TERM d. NO. OF UEVED uEVED NUMBER r PRE- A. __IF . VALUE aw.abte)e ANAL- TRATION AVEBAGEY ALUE ANAL-(ffavalate) . S Ii) A (2)MASS (ll (2)MASS (I) 12)ASS YSES (1)CONCENl (2)MASS YSES a.Bromide (2495967-9) x < 2.5 l< 21204.65 1 mg/L Ibs/day < 2.5 I b.Chlorine, Total Residual X 0.02 169.637 < 0.02 < 169.637 < 0.02 < 169.637 52 mg/L Ibs/day c.Color x 25. 1 Pt-Co 30 1 d Fecal Conlform X
- a. Fluoride (16984-48-8) X .
< 0.20 <- 1696.372 . 1 mg/L Ibs/day < 0.20 IT-I.9NItrate-Nitrite X =.0 < 8481.858 l 1 mgtA Ibs/day 1.4 (as F&.
V-a r,.uA INIV... ONTINUE cr rU.
.. .I. -U.. J_-. s-o, rAurC V-1 CONTINUE ON REVERSE
ITEM V-B CONTINUED FROM FRONT
- 1. POLLUTANT 2. MARK 'X' 3. EFFLUENT 4.UNITS 5. INTAKE (oLIona AND CAS b.EE ".8E- a. MAXIMUM DAILY VALUE b. MAXIMUM 30 DAY VALUE c.LONG TERM AVRG. d. NO. OF a. CONCEN b. MASS a. LONG TERM d. NO. OF NUMBER LIEVEDLIEVED PRE- AB-_
(if avai ab~e) VALUE '7 available) ANAL- TRATION AVERA VALUE ANAL-(if a vailable) SENT SENT (1) (2) MASS (I) (2\ MASS (I) (2) MASS YSES (TAICONCEN (2) MASS YSES
_ _- CONCENTATION . .CCNCENTRATION CONCENTRATION TRATION
- g. Nitrogen, Total Organic (as N) X < 1.0 < 8481.9 1 mgtL lbs/day 1.4 1
- h. Oil and Grease X < 5.0 < 42409 4 mgtL lbs/day < 5.0 4 I. Phosphorus (as P), Total (7723-14-0) X 0.22 1866.009 1 mg/L lbs/day 0.20 1 J. Radioactivity (1) Alpha. Total X < 1.3 1 pCitL 1.9 1 (2) Beta, Total X 4.0 1 pCi/L 2.8 1 (3) Radium, Total X 1.2 1 pCitL 1.4 1 (4)Radium 226, 0.3 1 pCI/L 0.1 1 Total ____0_ _3_ _ ___ ___ ___L____ ___ __
(14808-79-8) X 31 262937.6 1 mg/L lbs/day 31 1 I. Sulfide (as S) X < 1.0 < 8481.858 1 mg/L lbs/day < 1.0 1
- m. Sulfite (as S03)
(14266-46-3) X
- n. Surfactants X < 0.050 < 424.093 1 mg/L lbs/day < 0.050 1
- o. Aluminum, Total lbstday (7429-90-5) X 1.3 11026.415 1 mg/L lsdy 1.4 1 psBarium. Total x 0.059 500.430 1 mgL Ibs/day 0.058 1 (7440-39-3) X009 50401 m/
(74402ron8)otal X < 0.10 < 848.186 1 mg/L lbs/day < 0.10 1
- r. Cobalt, Total X < 0.020 < 169.637 1 mg/L lbs/day < 0.020 1 (7440-48-4) _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _
s74r3on8To6)al X 1.5 12722.787 1 mg/L lbs/day 1.6 1 (7439-95M4) X 21 178119.02 1 mg/L lbs/day 21 1 uTM73y8denum, X < 0.050 < 424.093 1 mg/L lbs/day < 0.050 1 v.ta Manganese, Toa (7439-96-5) X 0.18 1526.734 1 mg/L lbs/day 0.17 1 (w7.4T40n315a)l X < 0.10 < 848.186 1 mg/L lbs/day < 0.10 1
- x. Titanium, Total X < 0.050 < 424.093 1 mgL Ibs/day < 0.050 (7440-32-6) D , ___________ g _ _ _ _ _ _ __ _______
EPA Form JDIU-ZGL triev. -oaJ 1--e v-= NUNl I II-UN W., Wrot a-@
EPA I.D. NUMBER (copy from Item I of Form 1)OUTFALL NUMBER Formt AA"ived.
OMB No 20OcOS-W9 Ap.ro-aI CONTINUED FROM PAGE 3 OF FORM 2-C PART C -
ILD 060862810 001/002 I expfts 12-31-8.5 If you are a primary industry and this outfall contains process wastewater. refer to Table 2c-2 In the instructions to determine which of the GCIMS fractions you must test for. Mark X- In column 2-a for all such GC/MS fractions that apply to your Industry and for ALL toxic metals, cyanides, and total phenols, If you are not required lo mark column 2-a (secondary Industries, nonprocess wastewater outtalls, and non-required GC/MS fractions) mark *X' In column 2-b for each pollutant you know or have reason to believe Is present.
Mark *X In column 2-c for each pollutant you believe Is absent. If you mark column 2a for any pollutant, you must provide the results of at least one analysis for that pollutant. If you mark column 2b for any pollutant, must provide the results of at least one analysis for that pollutant if you know or have reason to believe It will be discharged in concentrations of 10 ppb of greater.
If you mark column 2b for acrolein, acrylonfitle, 2,4 dinitrophenol, or 2-methyl-4,6 dinitrophenol, you must provide the results of at least one analysis for each of these pollutants which you know or have reason to believe that you discharge in concentrations of 100 ppb or greater. Otherwise, for pollutants for which you mark column 2b, you must either submit at least one analysis or briefly describe the reasons the pollutant Is expected to be discharged. Note that there are seven pages to this part; please review each carefully. Complete one table (all 7pages) for each outfall. See Instructions for additional details and requirements.
- 1. POLLUTANT 2. MARK X 3. EFFLUENT 4.UNITS 5. INTAKE (mtian AND CAS
- TEST UE.ED- C.-E9 a. MAXIMUM DAILY VALUE b. MAXIMUM 30 DAY VALUE - c.LONG TERM AVRG. d. NO. OF a. CONCEN b. MASS- a. LONG TERM d. NO. OF NUMBER OtAR. IURE Ae _ __ ___ VALUEVEO r___ ANAL- TRATION AVERAG VALUE ANA (ffavalable) ED SENT SEWsR V (2)MASS - TIt (2) MASS "I) M Ss it)CONCEN- (2) MASS YSES METALS, CYANIDE, AND TOTAL PHENOLS IM. Antimony. Total (7440-38-0) X 0.10 848.19
< I mg/L Iis/day < 0.10 1 2M. Arsenic, Total < 005 24 (7440-38-2) - X = < 0.0050 < 42.4 1 mg/L lbs/day < 0.0050 1_
3M.BerylumTotal x < 0.010 < 84.82 1 mg/ ltbs/day < 0.010 (7440-41-7) .1 4M. Cadmium. Total = X.020 < 169.64 1 mg/i (7440-4-9) . lbs/day < 0.020 1
_ < 0.020 < 169.64 .;1 I
___ _stday<
_ _ 0.020 SM Chromium. Total X 0.1 <0 < 169.64
_ < 1 mg/ lbs/day 0.00 1 (74409-47r) X 0.020 < 169.64
< 1 mg/L lbs/day < 0.020 1 7M. Lead. Total X < 0.05 < 844.19 1 mgA Ibs/day < 0.10 (7439-92.1) X = < 0.10 19 1 8M. Mercury, Total- < 0.00020 < 1.696 1 mg/L tbs/day < 0.050 1 9M. Nickel, Total x < 0.050 < 44.09 lbs/day (7440.020 < 420)91 mg/i. lbs/day < 0.0050 69.6 (7439922-4;X< 1 . 2mg/L lbs/day < 0.0020 ..
IlOM. Selenium. 1 Total (7782-49-2). X < 0.0050 < 42.41 Mg____
1~
______ ___ It_____<__00 IIM.Sliver. Total .< 000 < 196 (740224).020___ <____ 169___64____ ____ mg/L lbs/day -c 0.020 1' 12M. Thalilium. Total x< 10 81861 mg/L (7440-28-0) ______ < 8481.8
- lbis/day < 1.0 1 13M. Zinc, Total X _ 0.020 < 169.64 1 (7440-66-6) mgIL lbs/day < 0.020 1 14M. Cyanide. Total 0.010o 84.82 (57-12-5) _ _ __ _ _
ISM. Phenols, Total -x0.020 <c '169.64-DIOXIN .
2,3,7_8-Tetra- I X_7DESCRIBE RESULTS chlorodtbenzo-P-Dioxin (1784-01-6) ens EPA F-orm iuets -........
-arm J317OZC D..e........
(HeV. e on, Z-0s} DRUn Y~t -A~ - -Iu unAI'InflC.VC~fl MA%$rt:
V-.J SUN I WdUr UN rnrVtCsar
CONTINUED FROM THE FRONT
- 1. POLLUTANT 2. MARK 'X' 3. EFFLUENT 4.UNITS 5. INTAKE (oponat)
AND CAS a.TEST- b.BE- c- BE- a. MAXIMUM DAILY VALUE b. MAXIMUM 30 DAY VALUE c.LONG TERM AVRG. d. NO. OF a. CONCEN b. MASS a. LONG TERM d. NO. OF NUMBER BING XI~R-I PRE- ILIEVED RE-I UEVED Afl- (d available) VALUE ifavailable)I ANAL- TRATION AVERAGE VALUE ANAL-()OCN 2M (it available) ED SENT SENT (1) (2) MASS (1) (2) MASS (I) (2) MASS YSES TRATION (2) MASS YSES
? CCETR~ ON TCRATIN ON~A GC/MS FRACTION - VOLATILE COMPOUNDS IV. Acrolrin (107-02-8) X 2V. Acrylonrlrile (107.13-1) X 3V.Benzene (71-43-2) X 4V. Bis (CNmxomeft4y)x Elw (542-88-1) x S.Brorroformn (75-25-2) X 6V.Carbon letraeNoride (56-23-5) x 7V.Chlorotbenzne X (108-90-7) 8V. Chiorodibrofxo-methane (1248-1) X 9V. Chloroettane X (75-00-3) 1OV.2-Choethylviryl X erther(I 10-75-8) .
tIV.Chloroform X (67-66-3) 12V.DicNornobromo methane (7S274) x 13V.Dichlorodhilluo-x methanl (75-71-8) X 14V3 I--DlcNoroetarane X (75-34-3)
ISV. 1t2-Dichloroethane X (107-04-2) 16V. 1.l-Dichloroethylene X (75-35-4)
I7V. IR-Dic~hlorooproanex (78-87-5) X 18V.1.3-Dkichoro-propylene (542-75-6) X W9V.Ethylbenzene x (100-41-4) 2OV.Methl4bomid X (74-839) 21V. MelhylclNoride x (74-87-3) V mrA trurtn Iau-ztS knav. 4z0al r~uc - %1%u19111ur- %ji rmuric v-a
EPA 1.D. NUMBER (copy from Item 1 of Form 1) OUTFALL NUMBER fbrm Aqwd.
OMB No. 2000-0059 Aproval CONTINUED FROM PAGE V-4 ILD 060862810 001/002 explr" 12-31-85
- 1. POLLUTANT 2. MARK 'X' 3. EFFLUENT l 4.UNITS 5. INTAKE (op.'0 AND CAS L. TEST. b.BE- C.BE- a. MAXIMUM DAILY VALUE b. MAXIMUM 30 DAY VALUE c.LONG TERM AVRG. d. NO. OF a. CONCEN b. MASS a. LONG TERM d. NO. OF NUMBER OUIRn.AE p~.A0. (Nfavaffabe VAU 7v ANAL- TRATION E L...AL.
(f avaable) ED SENT jSEW (Tt7M2 MASS (2) MASS (1) (2) MASS YSES (T)ACONCEN- (2) MASS YSES GCIMS FRACTION - VOLATILE COMP UNDS (continue) 092) 23V, 1.1221T7. l-cIJreaa79-34-5 X. ___,_._._.
_V. . .-
(127.18-4)-
25V. Tdwu (I08-&83) X 26V. 1.2.Trrrs-ddoo. x ei 0(156-w.) _ .
27V. I.I.1.TrIW ooetans x (71.554) ._ _ _ __ _ . . .. .
2SV.1,.2-TrthoorWm X 2WV.Tfth~oroey4ee (79-M4-). , ...
32V.Trt rofrof.. . ..
m-7549 .__._._ . X 31V.VhWtd, X (75-01-4) _ _ _ _ _ _ _ _ _ __ _ _ _ _
GCIMS FRACTION - ACID COMPOUNDS IA. 2Clmop*wid x (95-57-8) _ _ _ _ _ _ _ _ _ _ _ _ _ _ _
2A. 2.4-Dkndlmoph" .
(120-32) _ _
3k 2.4Dlmde8 4phe. . .
(1054-9)
A. 4.6-ODWro-Oaesr -- x (534.52.1) _ _ _ _ _ _ _ _ _ _
(51.28-5)
(8-75-5) _ _
8A.P*-Creel ad (59-507)
- l l_' . .
11kA24.4. 6Td~rohw -- , 'x --
(88-082) _ __ _ _ _ _ __ _ _ _ _ _ __ ___ _ ._ _ __ ___ __ __ _ ..... _ __ __ _ ___ . : _ __ __ _
EPA Form 3510-2C (Rev. 2d85) PAGE V-5 CONTINUE ON REVERSE
CONTINUED FROM THE FRONT
- 1. POLLUTANT 2. MARK 'X' 3. EFFLUENT 4.UNITS 5. INTAKE (optcinal)
AND CAS arTEST- b. BE- C.8B-INGRE LIVD IiEVEDI
- a. MAXIMUM DAILY VALUE b. MAXIMUM 30 DAY VALUE c.LONG TERM AVRG. d. NO. OF a. CONCEN b. MASS a. LONG TERM d. NO. OF NUMBER j C IR- IPRE. __ _ (ifavailable) fIEA VALUE tifavailabte) ANAL- TRATION AVERAG E VALUE ANAL-(ffavailable) IED SENT ISENTI 1)(2) MASS (I) (2)MASS (1) 2)AS YSES (ICNE- ()AS YSES GCtMS FRACTION - BASE/NEUTRAL COMPOUNDS I B. Acenaphthene x (8332-9) _ _ _ _ _ __ _ _ _ _
2B. Acenaphthylere X (208-96-8) _ . .
3(Aacene X..
4*. Benzidine (92-87-5) X
- 58. 1e3zo (a) ardxacw_
(5 &-
- 53) _ _ _ _ _ _ _ _ _ _ _ _
68j. Benzo (a) pyene X (50-32-8) .
- 78. 3.41-8eoflueorthene (205-99-2) X .
- 88. Benzo(gN) peryieri (191-24-2) .
xe
- 98. Benzo (k) xluoranth (20748- 9) _
10B.Sis (2chNoroethoe-y) X meouwne (1ll-91-1) _
I1B. Bis (2-choroelhyl) X etWef(I11-1-4) 12B.Bis(2-cNhroiso- X propyl) ether (102-60-1) .
13E.Bis (2-ethythex 5 4) X .
phghatre (117-81-7) 148.4-Bromopher"t phen; X ether (101-5.-3) 15B.Buys4benzylphraiale X (85-68-7) __ _ __ _
168.2-Co ronaphialene X (91-58-7) 178. 4-Corophenyl phenylX ehe (7005-72-3) _
188. Chrysene X (218-01-9) 198.Diberzo (a.h) anftacene (53-70-3) X 208.1.2-Dichlorobzeru x (9S-S01) 218. 1,3-Dichtorobenzenre X (541-73-1)
EPA =rur aC; CDAe rotrm I_
jal0-Zr_ Ir~ za85 knev. £G~) rP...j rmkjr: VAg V-O rnIAJNI INUe l~ UNt s .,~
CONTIINUE tDN PAGE: V-7
EPA l.D. NUMBER (copy from Item I ofFom 1)l0UTFALL NUMBER Form AAdOv.
OM9 No. 200-0ooS9 Aprovmi CONTINUED FROM PAGE V-6 E ILD 060862810 1 001/002 etks 12-3185
- 1. POLLUTANT 2. MARK X' _ _ 3. EFFLUENT . 4.UNITS 5. INTAKE (opilx AND CAS TEST. b BE. c.BE. E. a. MAXIMUM DAILY VALUE b. MAXIMUM 30 DAY VALUE c.LONG TERM AVRG. d. NO. OF a. CONCEN b. MASS a. LONG TERM d. NO. OF NUMBER ING RE. UtVEO LIEVED JaraLabt..
Nva 7ab/) VALUEav__ ANAL- TRATnON AVERAE ANAL-(lrvalable) ED (2) MASS (T) (2) MASS (I) (2) MASS YSES (l CONCEN. (2) MASS YSES GCIMS FRACTION - BASEINEU RAL COMPOUNDS (continued)
_ QMMMAT_ _ _IB 229. t.4- Dieobvrze X ..
23Et.3S- tDkh be-iredne (91-94.1)
. x-2.9 _le .hf~
(844&62).X 258.Dmdt" thata X (131.11.3) 268. DI-N t phth6alale X (84-74-2) 279. 2.4-Dhw . X.
288. 2.6-O~iwolvlkme (6W-20.2) X 30B. 12-DWWei4.M* ~
hy&zfrW4 (122.667) _________
319. Fluoranwe -
328. aoe (rb73u7) X ....
(116-74.1) ,
338. Hexa 348. He.achw nmoty e ne .
xo-(87-68-3) 368 d~rene6rrr _ _ . .
S79.tndeno (l.2,Scd) -.. X . . . .. .... ..
Djre(193-39-5) ._._._..
Ex
_ _ _ X . ,.. - . . . . .. . .__ .. ..
398. NsvhtW*ene ' X (91.20-3) _ _ _ _ _ _ _ _ _ _ _ _
408 Mb bewww .. x 41.N-Nhmco~rdmer-at n (62-75-9) _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _
429. N-NtodtN .
popt4amn*~e (62144.7) = ________
EPA Fotrm 3510-2C (Rev. 2-U5) PAGE V-7 CONTINUE- ON REVERSE
CONTINUED FROM THE FRONT
- 1. POLLUTANT 2. MARK 'X 3. EFFLUENT 4.UNITS 5. INTAKE (optknaL AND CAS a.TEST- b. EE- c. EE- a. MAXIMUM DAILY VALUE b. MAXIMUM 30 DAY VALUE c.LONG TERM AVRG. d. NO. OF a. CONCEN b. MASS ING RE- IVDLEE a. LONG TERM d. NO. OF NUMBER I LIEV av. ilable) VALUE I l:avaiabe) ANAL- TRATION AVERAE VALUE ANAL-(ilavailable) ED SENT SENT MASS
_ CONCENRATITT (2) C NRATION CONCENTRATIONTRO (2) MASS YSES (I)COCEN- (2)MAS YSES GCIMS FRACTION - BASE/NEUTRAL COMPOUNDS continued) 438. N-Nitrosodi-phenylamine (86-30-6) X 448 Pn8 hx (85-01-8) _
458. Pyrtne (129-00-0) X 4688.1Z4-Trlchloro-bemene (120-82-1)
GCIMS FRACTION - PESTICIDES 1P. Aldrin X (309-00-2) 2P. o-BHC x (319-84-6) 3P. 0-BHC x (319-85-7) 4P. O-BHC x 5P. O-BHC x (319-86-8) = _ ________
6P. Chlordane x (57.74-9) 7P. 4,4'-DDT X = = _ L
_ _ _ _ _ _ _ 1 _ _
x (50 29-3) _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _
8P. 4,4'-DDE X (72.55-9) __ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _
9P. 4,4'-DDD x (72-54-8) _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _
lOP. Dieldrin x (60-57-1) X _ _ _ _ _
11P. 0-Endosulfan X (115-29-7) ___ _ _ _
12P. O-Endosulfan X (115-29-7) _
13P. Endosullan X Sulfate (1031-07-8) I 14P. Endrin X (72-20-8) . _
15P. Endrin Aide- x hyde (7421-93-4) _ X 16P. Heptachlor X (76-44-8) _Rv RR_ _ _ Dl_ .F V.R ____lT_ _II IC_______
-r -r~M -a I u-x %rwe. zuoo} r- v-o 1SAN I IN'Ut: UNl rmur. Vv
IEPA I.D. NUMBER (copy from Item 1 of Form 1)IOUTFALL NUMBER FormAppved.
OMB fl. 2000O59Approval CONTINUED FROM PAGE V-8 lILD 06086281 0 l 001/002 - xp/lBs 12-31-e5
- 1. POLLUTANT 2. MARK X 3. EFFLUENT _4.UNITS 5. INTAKE (ctb52 AND CAS a.TEST- b.6EC . BE- a. MAXIMUM DAILY VALUE b. MAXIMUM 30 DAY VALUE c.LONG TERM AVRG. d. NO. OF a. CONCEN b. MASS a. LONG TERM d. NO. OF NUMBER RE- PREN UEVEAS2 _ _ j abe) VLUE faIaLeJ ANAL- TRATION AVERAGE VALUE ANAL.
(if avaffabte) ED SENTSEW(2) MASS (I(2) MASS (1) (2)MASS YSESNE. 2 MS GCIMS FRACTION - PESICIDEs (conlinued) 17P. HetlaN Epoif x (1024-573) 18P. PCB-1242 (53469-21-9) X 19P. PCB-1254 X (11097-69-1) X 20P. PCB-1221 X (11104-28-2) X 21P. PCB-1232 (11141-16-5) X 22P. PCB-l 248 X (12672-29-6) X 23P. PCB-1260 X (11096-82-5) X 24P. PCB-1016 _
(i2674-11-2) X 25P. Toxaphene X (8001-35-2)
EPA FOT .a35z tnev. 4-04) PAGE V-S EPA Form 3510-2C (Rev. 2-85)
PLEASE PRINT OR TYPE IN THE UNSHADED AREAS ONLY. You may report some or all of EPAI.D. Ny FomAoved this Information on separate sheets (use the same format) Instead of completing these pages.
SEE INSTRUCTIONS ILD 060862810 OM8A-1-4O- 9 V. INTAKE AND EFFLUENT CHARACTERISTICS (continued from page 3 of Form 2C)
PART A - You must provide the results of at least one analysis for every
- a. MAXIMUM DAILY VALUE b. MAXIMUM 30 DA _ ............
- d. NO. OF a. CONCEN MASS
- 1. POLLUTANT fiavafIlaNa
- + - 4 LL2kM. - ANAL- TRATION ANAL-(1) (2) MASS _ 1) (2) MASS _-) (2) MASS (tOUNC.LN I (2) MASS
___IrItIt YSES
.FtAT.
- YSES=.C
b; Chemical Oxygen Demand (COD) l
d.Total Suspended Solids 8.8 3.75 5.5 2.34 2.6 1.11 52 mgAI. bs/day
( TSS)_ _ _ _ _ _ __ _ _ _ __ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _
- e. Ammonia I. no VALUE 0084 VALUE 0067 VALUE 0.051 52 VALUE
- g. Temperature VALUE VALUE VALUE -C VALUE (wrnter) h Temperature VALUE VALUE VALUE - VALUE -
(summer) . ._ . _. _. _. _. _. _. _
MINIMUM MAIMUMMIIUMAMM _
1.pH* NIS I. p ~U M~ i M M MI M M A ~ M U ZSTANDARD UNITS PART B - Mark WXin column 2-a fr each pollutant you know or have reason to believe is prsent. Mark X in column 2-b for each polluant you believe to be absent. If you mark column 2a for any pollutant which Is limited either directly, or Indirectly but expressly, In an effluent limitations guideline, you must provide the results of at least one analysis for that pollutant For other.
pollutants for which you mark column 2a. you must provide quantitative data or an explanation of their presence In you discharge. Complete one table for each outfall. See Instructions for additional details an requirements..
1.POLLUTANT 2. MARK X -3. EFFLUENT UNITS 5. INTAKE AND CAS b BE .cBE. a. MAXIMUM DAILY VALUE b. MAXIMUM 30 DAY VALUE c.LONG TERM AVRG. d. NO. OF a. CONCEN b. MASS a. LONG TERM d. NO. OF N UE VE_ LIEVED Lacae) .t M m ~ ANAL- TRATION RA VALUE ANAL-(Wfavaifable) sCr C (1) A2rMAoN(I) (2)M ASS. I- (. (T)AASSN- YSES SE (AM (1) ClNCFN. (2)MSS SES (24959B67e9) X < 2.5 < 1.064 -1 mg/L Ibs/day l l l
- b. Chlorine, Total -X Residual l l _lll e:Color . x 1 1 Pt-Co
- d. Fecal Coliform X
- a. Fluoride (1698448.8) X < 0.20 < 0.085 1 mA Ibs/day I. Nitrate-Nitrite X < 1.0 < 0.426 1 (a s AO _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _
EPA Form 3510-2C (Rev. 2-85) PAGE V-1 CONTINUE ON REVERSE
ITEM V-B CONTINUED FROM FRONT
- 1. POLLUTANT 2. MARK 'X' 3. EFFLUENT 4.UNITS 5. INTAKE (opriona AND CAS b. BE- C.BE- a. MAXIMUM DAILY VALUE b. MAXIMUM 30 DAY VALUE c.LONG TERM AVRG. d. NO. OF a. CONCEN b. MASS a. LONG TERM d. NO. OF NUMBER LIEVEDLIEVED (it available) VALUE 7avaidabte) ANAL- TRATION AVERAGEVALUE ANAL-(if available) SENT SENT (NI CONCENTRATION (2) MASS (1) (2) MASS IO)
CONCENTRATION_
(2) MASS YSES (I) COoNCEN- (2)MASS YSES
- . .CONCENTRATION TRATIO
- g. Nitrogen, Total Organic (as N) x 1.4 0.596 1 mg/L lbs/day h.Oil and Grease X < 5.0 < 2.128 12 mg/L lbs/day 1.Phosphorus (as P), Total1 mgI lb/a (7723-14-0) X < 0.10 < 0.043 1 mg/L Ibs/day I. Radioactivity (1)Alpha, Total x < 1.1 1 pCUL (2) Beta, Total x 4.7 1 pCi/L (3) Radium, Total x 1.9 1 pCUL (4) Radium 226, X < 0.3 1 pCiL
- k. Sulfate (14808-79-8)
(as SOX) 32 13.6 1 mg/L Ibsday L.Sulfide (as S) X < 1.0 < 0.426 1 mg/L lbs/day
- m. Sulfite (as S3O)
(14266-46-3) _ X .
n.Surfactants X < 0.050 < 0.021 1 mg/L lbs/day
- o. Aluminum, Total X 0.23 0.098 1 mg/L Ibsday (7429-90-5) x02 .9 gI b/a
- p. Barium. Total1 mgI lbda (7440-39-3) X 0.035 0.015 1 mg/L Ibsday
- q. Boron, Total X < 010 < 0.043 1 mg/L Ibs/day (7440-42-8) .
r.Cobalt, Total (7440-48-4) X < 0.020 < 0.009 1 mg/L lbs/day s,Iron, Total1 mgI lb/a (7439-89-6) x < 0.10 < 0.043 1 mg/L lbsday I. Magnesium. Total1 (7439-95-4) x 19.0 8.09 1 mgL Ibsday
- u. Molybdenum, Total (7439-98-7) x < 0.050 < 0.021 1 mg/. lbs/day
- v. Manganese, Total lbs/day (7439-96-5) x < 0.010 < 0.004 1 mg/L bs/day
- w. Tin, TotalX < 0.00 < 0.043 1 mg/L Ibs/day (7440-31-5) x < 01 .4 gI b/a
- x. Titanium, Total < 000 < 0011 m/ b/a (7440-32-6) x I c 0.5 gI. ls/a I I011 EPA Form 3510-2C (Rev. 2-85) PAGE V-2 CONTINUE ON PAGE V-3
NUMBER (copy EPA 0068from item lof Form N Form, 4vovd.
CONTINUED FROM PAGE 3 OF FORM 2-C PART C -
IEPA008D.11UBER 0MB No. 2000-0059 AWyov exlb~s 12-31.85 If you are a primary industry and this outfall contains process wastewater, refer to Table 2c-2 In the instnuctions to determine which of the GC/MS fractions you must test for. Mark *X- In column 2-a for alt such GC/MS fractions that apply to your Industry and for ALL toxic metals, cyanides, and total phenols. If you are not required to mark column 2-a (secondary Industries, nonprocess wastewater outfails, and non-required GOUMS fractions), mark *X in column 2-b for each poliutant you know or have reason to believe Is present. Mark *X' In column 2-c for each pollutant you believe is absent. If you mark column 2a for any pollutant, you must provide the results of at least one analysis for that pollutant. If you mark column 2b for any pollutant, you must provide the results of at least one analysis for that pollutant if you know or have reason to believe it will be discharged In concentrations of 10 ppb of greater. If you mark column 2b for acrolein, acrytonitrile, 2,4 dinitrophenol, or 2-methyt-4,6 dinitrophenol, you must provide the results of at least one analysis for each of these pollutants which you know or have reason to believe that you discharge In concentrations of 100 ppb or greater. Otherwise, for pollutants for which you mark column 2b, you must either submit at least one analysis or briefly describe the reasons the pollutant Is expected to be discharged. Note that there are seven pages to this part; please review each carefully. Complete one table (all 7 pages) for each outfall. See Instructions for additional details and requirements.
- 1. POLLUTANT 2. MARK 'XI 3. EFFLUENT 4.UNITS l 5. INTAKE ( 2.na.
AND CAS a.TEST- bBE- cBE.
ING RE-ILIEVWDILUEVEO a. MAXIMUM DAILY VALUE b. MAXIMUM 30 DAY VALUE c.LONG TERM AVRG. d. NO. OF a. CONCEN b. MASS a. LON TERM d. NO. OF NUMBER In. PRE UFEDafa1bfe)
. AB- L ALiavatble ANAL- TRATION AVERAG VALUE ANAL-(if avaTAabOe) E - l sF t SFN (2) MASS YSES (1)CONCEN (2) MASS (I) (1) l () MASS (2) MASS YSES METALS, CYANIDE, AND TOTAL PHENOLS T I -__
I M.Antimony, Total (7440-36-) x 0.10 < 0.043 1 mg/L lbs/day As440-38-2)TaX < 0.0050 < 0.0021 1 mg/L lbs/day 3M. Beryllium. Total (7440-41.7) x = c .010 c 0.004 1 mg/. lbs/day
_______0 < 6.004_ __Mg__L _bsday 4M. Cadmium, Total X _ c X _ <7440-47-9)0.020 < 0.0085 . 1 mg/ I lbs/day ..... __
5M. Chrmium. Total (440-47-)
- - M -.
_ X I c 0.020 c 0.0085 1 mg/I lbs/day 6M. Cper . Total (7440-50-B) _ X c 0.:020 c 0.009 1 mg/L lbs/day .
= 05 021 mI/
7M. Lead, Toa .0 0.0421 1 mg/. lbs/day .
74 9 2-)X < 0.10 < i______
7M.M (7439-97-6) X c__ 0.0020 < 0.00009 1 mg/L lbs/day 9M. Nickel, Total < .5 < 0.21 mgL tsda (7440782-4) X b.50 < 0.5021 1 mg/L lbs/day IM.elncum, Ttl(77082-49-) = _____ 0.0050 0.010 c 0.002o . . 1/dy=
12IM. Siflver. Total
< c I 1X mg/L lbs/day (740-2-0)X o < OA~ 1 mg/I. lbs/day 13M. Thium, Total 1. -C0451 15M. Zinc. Total (7440-66-6)
= Xc 0.020 c 0.009 I mg/L lbs/day 14M. Cyanide. Totalx -C 000 - 0004 m/I lbda____
(57-12-5) X < 000 < 0044 mA b/a I5M. Phenols, Tota X -<C000 0.009 4 mg/I. lbs/day_____ ___
DIOXIN 2.3,7,8-Tetra- - DI iDESCRIBE RESULTS chlorodibenzo-P- . I X .
Dioxin (1764-01-6) om31-U~e. zuj r#__ V. _,
EP Form EPA 3510-2L; (Rev. 2-0bl I-Auit V-J burr a arfiuc urn navcna
.1
CONTINUED FROM THE FRONT ________________________ ___________
- 1. POLLUTANT 2. MARK 'X 3. EFFLUENT 4.UNITS 5. INTAKE (o001al)
AND CAS a TEST- b.BE- I C.BE- a. MAXIMUM DAILY VALUE b. MAXIMUM 30 DAY VALUE c.LONG TERM AVRG. d. NO. OF a. CONCEN b. MASS a. LONG TERM d. NO. OF ING FE-I LIEVEDI LIEVED NUMBER OUIR- PRE- IEVEC (if avalVabLe) VALUE avafabteJ ANAL- TRATION AVERAG VALUE ANAL-(ifavailable) ED SENT SENT (1) (2) MASS (1) (2) MASS (1) YSES (I) CONCEN.
_ CONCENTRATION CONCENTRATION CONCENTRATION (2) MASS TRATION (2) MASS YSES GC/MS FRACTION - VOLATILE COMPOUNDS IV. Acrotein (107-02-8) X 2V. Arlontrile (107-13-1) X 3V. Beniene (71-43-2) X 4V. Bis (Chloromelhyt) X Ether(542-88-1) _
SV. Bromdorom, (75-25-2) X 6V. Carbon tetrxor X (56-23-5) 7V.CNwrobenerre _ x (108.90-71 ev. Chiororobrono.
methane (124-48-1) X 9V. Chloroet.hane (75-00-3)
I y. 2-CNorehytviny4 ether (I 10-75-8) X l IV. Chloroformx (67-66-3) X 12V.Dichlorobromo- X methane (75-27-4) 13V. Dichlorodifluorso v methane (75-71-8) 14V 1.1-Dioroetune (75-34-3) x I5V. 1.2-Dichioroethane X (107-06-2) 16V. 1,1-Dichoroethylenex (75-35-4) X 17V. 1.2-DicNoropropane X (78-87-5) _
18V. 1t3-DichkoroX propylene (542-75-6) X 19V. Ethylbenzene X (100-41.4) 20V. Methylbromiece (74-83-9) x 2 IV. Methylchorlde (74-87-3) X COA CFnrr ICIlC' 10-, v -01 DA flClEAtr rr u- - .- < \n..-- o.J I-u -- v Usue
& Utat rluc V-:
EPA l.D. NUMBER (copy from Item 1 of Form l)lOUTFALL NUMBER Form AoMved.
OMB No. 2000-0S9 Appoval CONTINUED FROM PAGE V4 E ILD 060862810 1 Bo0 expires 12-3145
- 1. POLLUTANT 2. MARK X. 3. EFFLUENT 4.UNITS 5. INTAKE (meb AND CAS a.TEST- e BE- cBE- a. MAXIMUM DAILY VALUE b. MAXIMUM 30 DAY VALUE c.LONG TERM AVRG. d. NO. OF a. CONCEN b. MASS a. LONG TERM d. NO. OF NUMBER RE UEVED UEVED *_ avaabe) VALUEW_ t avcbdab ANAL- TRATION AVERAGE VALUE ANAL-(ifavafable) ED SEtT SENT I')j (2)UASS (I) (2)MASS (1) (2)MASS YSES (1?COGE- (2)MASS YSES GC/MS FRACTION - VOLATILE COMPOUNDS (continut) - 7 .. . .
22V.UMe8A diue (7!
00-2) - - - _ _ _ _ _ _
23V. 1.122.-TeWl dietanf(79-345) - , .
24V. TetrAoetr,4 x (127-184) . __ _ _
25V.Tcd8M (10-88-3) X 26V. 1.2-TrM-&fcora.
et4 (15 -5) _ _ . _
27V. 1.1.1-T,1d -Th --
(71-554) . -.
28V. 1.1,2-T,2o-eTdw (78-XS) - _ - . - . - . . .
275t16 V.T- X .- , __- _ = _
30V. TrlcNvfqs x_
nf" 549-. ) _____ ____.,,_.._
3lV.WlnydtoId . x (75-01-4) . , _. . .. . ...
GC/MS FRACTION - ACID COMPOUNDS IA 24chloed - _
(9!S-57-8) X____
2k 2.4-0k2,r4OD .
(120-82) _
3A. 2.4-1me8t4phnc _ , - _ - .
(534-52-I) __ ,_ ,_ _ _ _ _ _ _ _
S2,4-DhVrohwt. cI (51-28-5) X 7A 4npd X Po--Maad X _
(595>5GT)__,
9A Pa o.op.no. .
(57 - 5) _ _ _ _ _ _ _
10k880-M2) )
tlt . 4.6T X _ .pbu~o (85 - ). _ _ _ _ _ _ ,, _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ A _ _ _ _ _ _ _ _ei*
ez EPA FOtrm 35102C (Rev. 2-05) PAGIE v-s CONTINUE ON RE:VERSE
CONTINUED FROM THE FRONT
- 1. POLLUTANT 2. MARK X 3. EFFLUENT 4.UNITS 5. INTAKE (rtona/
AND CAS a.TEST-r b. BE- C. BE- a. MAXIMUM DAILY VALUE b. MAXIMUM 30 DAY VALUE c.LONG TERM AVRG. d. NO. OF a. CONCEN b. MASS a. LONG TERM d. NO. OF ING RE-' LIEVED I EVED (fvial NUMBER ATION PRE AB- . CEN T VALUE 'a vailable)
RANiabte) ANAL TRATION AVERLU ANAL-(i vial) ED ISENT ISENT (1) (2) MASS (I) (2)MASS (1) (2)MASS YSS()OCN- ()AS YE
_ _ __ _ _ _ _ I__ _ _ CONCENTRATEN _ _____ ____
GC/MS FRACTION - BASE/NEUTRAL COMPOUNDS IB. Acenaphthefle X (83-32-9) _
- 28. Acenaphlhylene X (208-96-8) _
- 38. Antracone X (120-12-7) .
- 43. Benzidine (92-87-5) X
- 58. Benzo (a) anthracene X (56-55-3) _
- 68. Benzo (a) pyrene Y (50-32-8) .
7B. 3.4-Benzolluoranthene X (205-99-2) 8.Benzo (ghf)peyenex (191-24-2) X
- 98. Benzo (k) flluranthene X (207-08-9) .
108. Bis (2chloroethox-y) X methane (111-91-1) _
118. Bis (2-choroethyl) X ether (111-44-4) 128. Bis (2-chioroiso-propyl) ether (102-60-1) X 138. 81s (2-athytheqyl) X phthaiate (117-81-7) 148. 4-Bronophenyl pheny X ether (101-55-3) 158. Butyl benzyl phthalate X (85-68-7) 168. 2-Chloronaphthalene X (91-58-7) 17B. 4-Chlorophenyt phenyl X ether (7005-72-3) 18B. Chrysene X (21841-9) 19B. Dibenzo (a.h) anthracene (53-70-3) X 20B. 12-Dclorobenzene X (95-50-1) 213.1.3-Dichlorobeozrue X (541'73-')
~rDACA trA .~or U-ACLtflOV.
urin oa Iu-Zr_
ruff" 00 inv. ^^O~
Z-tujI rRU -0 P-AGEi v-e
-O U CONTINUEI
^N P.A.^- -
ON PAGEF V-7
EPA I.D. NUMBER (copy from Item 1 of Form 1) OUTFALL NUMBER Form Appved.
ILD 060862810 OMB No.200"09o AWyval CONTINIJED FROM PAGE V-6 Bol *uplrs 12-31-aS
- 1. POLLUTANT 2. MARK X' ____ .EFFLUENT
&____ 4.UNITS
__________ ___ 5. INTAKE cA AND CAS a TET bE.c. BE. a. MAXIMUM DAILY VALUE b. MAXIMUM 30 DAY VALUE c.LONG TERM AVRG. d. NO. OF a. CONCEN b. MASS a. LONG TERM d. NO. OF NUMBER OL~t UEV P ABLIEvg (OIC E
OUIR.ale SEN _____Jf1)
SET 0 F(2) MASS NvSfnabte)ENMATSENSTSSENE
() a~e (2) MASS ALENvaAEAGEDE (I) (2)MASS NL YSS(1 TRATTON AERA ONEAT 2 MS NL ANAMAS VE GCIMS FRACTION - BASE/NEUTRAL COMPOUNDS cotinued)_____
10am48nh(19I)X (8446.2) 1 259. 0"egrA O1isatsO (131.11.2) 279. 2 4-Dfriltolore (121.14-2) X 306. 1.2.DlpwfA-hy*2Ie4 (I122-M67)X -
(206.44-M___ ___
329. Pkiorene(M673-7)X 339.Hewsc~ovobwizee (118-74.1) x 349. H.,xacdoobuated (87-663) s x 368.Heys&Jor0Q~wm (67.'72.) _ _ _ _ _ _ _ _ _
379.Wsm n(I 2.3-0d)-
p~ue(193-39-5) x 3 h_ . -x _ _ _ _
398. NaphftfMle' (91.20-3) _ _ _ _ __ _ _ _ _ _ _ _ _ __ _ _ __ _ _ _
419.N-N1VB0Mod*si~4 amn*e(62-759) _ _ _ _ _ _ _ __ _ _ _ _
429. N-Nimodoo-N-4 prCP~w im (6(21.6 .7)X__ _ _ __ _ _ __ _ _ _ _
EPA Form 3510-2C (Rev. 2-85) PAGE V-7 CONTINUE ON REVERSE
CONTINUED FROM THE FRONT
- 1. POLLUTANT 2. MARK 'X' 3. EFFLUENT 4.UNITS 5. INTAKE (opiinat)
AND CAS a. TEST.1 b. SE- c. eE- a. MAXIMUM DAILY VALUE b. MAXIMUM 30 DAY VALUE c.LONG TERM AVRG. d. NO. OF a. CONCEN b. MASS a. LONG TERM d. NO. OF IING RE- UEVEO LIEVED (iI AU vilbe NL NUMBER QGUIR- UE- AB- (favailable) VALUE ANAL- TRATION AVERAGE VALUE ANAL-(if available) ED SENT SENT C AI ON M OASS (I) (2) MASS (1) (2) MASS YSES (1) CONCEN- (2) MASS YSES
_OCNTA10 ONQFNTRATIQN CONCENTRATION TRATION _SE GCIMS FRACTION - BASE/NEUTRAL COMPOUNDS continued) .
438. N-Nitrosd-X phenytamine (86-30-6) X 44E. Phenanftrene Y (85-01-8)
I 45B. Pyrene (129-00-0) X 468. 1,24-TricNhio- X benzeee (120-82-1) T __ _
_x GC/MS FRACTION - PESTICIDES 1P. Aldrin X (309-00-2) 2P. D-BHC x (319-84-6) X _ _ _ _ _ _ _
3P. o-BHC x (319-85-7)C = = X _ ________
4P. O-BHC (58-89-9) __ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ __ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _
5P. O-BHC (319-86-8) x 6P. Chlordane x (57.74-9) 7P. 4,4'-DDT x (50-29-3) _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _
8P. 4,4'-DDE X (72-55-9) __ _ _ _ _ _ _ _ _ _ _ _
9P. 4,4'DD XI (72-54-8) __ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _
lOP.5Di1ldrin x (60-57-1) _ _ _ _ _ _ _ _ _ _ _ __ _ _ _
11P. O-Endosulfan x (115-29-7) 12P. O-Endosulfan (115-29-7) . X 13P. Endosulfan Sulfate (1031-07-8) X .
14P. Endrin X (72-20-8) __ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _
15P. Endrin Alde- X hyde (7421-93-4) _
16P. Heptachlor X (76-44-8) x _ I _ _ _
EPA Form 3510-2C (Rev. 2-85) PAGE V-8 CONTINUE ON PAGE V-9
EPA I.D. NUMBER (copy from Item 1 of Form 1) OUTFALL NUMBER Form Apo.ve.
ILD 060862810 OMB No. 2000 0059Approval CONTINUED FROM PAGE V-8 1 BO0 e0Vfs 12-31-85
- 1. POLLUTANT 2. MARK 'X' 3. EFFLUENT 4.UNITS 5. INTAKE AND CAS a GTEST. . B!E- cBE' a. MAXIMUM DAILY VALUE b. MAXIMUM 30 DAY VALUE c.LONG TERM AVRG. d. NO. OF a. CONCEN b. MASS a. LONG TERM d. NO. OF NUMBER O UIR. PREve 1 AUJ VALUE rayawable ANAL- TRATION AVERA (yavaaable) SENT ANAL-ED SENs T (I (2) AS(I) (2) MASS II) YSES (2) MASS (T)CONCEN. (2) MASS YSES GCIMS FRACTION - PESTICIDES (cont nued) 17P.HeptncN EpoXd x (1024-57.3) _
18P. PCB-1242 x (53469-21-9) _
19P.PCB-1254 x (11097-69-1) 20P. PCB-1221 x (11104-28-2) _ .
21P. PCB-1232 x (11141-16-5) _
22P. PCB-1248 x (12672-29-B) 23P. PCB-1260 x (11096-82-5) _
24P.PCB.101B X (12674.11-2) 25P. Toxaphene X (8001-35-2)
LEA Form 312U-Z (ReV. 4-84) PAUt VY-EPA Form 3510-2C (Rev. 2-85)
PLEASE PRINT OR TYPE IN THE UNSHADED AREAS ONLY. You may report some or all of EPA I.D. NUMBER (copy from Item 1 ofForr 1) FomAnioved this Information on separate sheets (use the same format) Instead of completing these pages.
OMS No. 2000-s59 SEE INSTRUCTIONS ILD 060862810 Ar~mroaexpires 12-31-85 V. INTAKE AND EFFLUENT CHARACTERISTICS (continued from page 3 of Form 2-C) OUTFALL NO.
I-Cal PART A - Vn, ~
ye.,tq rnvrl i e th i-e n~vie nr ver n~j~s~n Inthe thie rnmnlept nne tahle finr a(h nutfel 5Ree InqtnitMInne fewreritInnn dretails.
- 2. EFFLUENT _ 3.UNITS 4. INTAKE (c2yna1)
- a. MAXIMUM DAILY VALUE b. MAXIMUM 30 DAY VALUE c.LONG TERM AVRG. d. NO. OF a. CONCEN b. MASS
- 1. POLLUTANT (f)avalabe VALUE favaae a. LONG TERM d. NO. OF ANAL- TRATION 'AVERA LLIE ANAL.
(1) (2) MASS (Ij (2) MASS (0) .YSES (2) MASS - (1) CONCEN- (2) MASS YSES a.Bhela)Le COCFT.~O QCoEcNsTRA7 C(WCFNTAATX
- a. Biochemical OD)en 36.0 1.20 21.2 0.71 9.4 0.31 41 mg/L' Demand (SOD) Ibs/day
- b. Chemical Oxygen Demand (COD) - -
d) Total Suspended Sods 29.5 0.98 22.2 0.74 11.6 0.39 44 mg/. Ibs/day
- e. Ammonia VLEVLEVALUE VALUE
. Flow ; 0.007 VALUE 0.005 VALUE 0.004 45 MGD
- g. Temperature VALUE . VALUE VALUE VALUE (Mnter)
OC
- h. Temperature VALUE - ; VALUE VALUE VALUE (summer) , , , , . . .
UU MINIMUM MAXImum I.pH 44. STANDARD UNITS PART B - Mark 'X in column 2-a for each pollutant you know or have reason to believe is present. Mark X n column 2-b tor eachpollutantyoubelievetobeabsent.tyoumarkcolumn2aorany pollutant which Is llmited either directly, or Indirectly but expressly, In an effluent limitations guideline, you must provide the results of at least one analysis for that pollutant. For other pollutants for wMich you mark column 2a, you must provide quantitative data or an explanation of their presence In you discharge. Complete one table for each outfall. See Instructions for
- additional details anc requirements. - :
- 1. POLLUTANT 2. MARK 'X 3. EFFLUENT - - 4.UNITS - 5.
S INTAKE (crjl AND CAS b. BE- c. BE. a. MAXIMUM DAILY VALUE b. MAXIMUM 30 DAY VALUE c.LONG TERM AVRG. d. NO. OF a. CONCEN b. MASS a. LONG TERM d. NO. OF NUMBER PUEVED VAE favfabVe) ANAL-' TRATION - AVERAGE VALUE ANAL-(9favalable) SENT SENT II) (2) MASS (1) (2) MASS - ('I .12) MASS YSES . Cn. (21MASS YSES a.Bromide (24959467-9) x < 2.5 < 0.083 1 mg/L Ibs/day . _.
biesina a X > 3.5 > 0.117 > 3.5 > 0.117 3.4 0.113 mg/.
R esidual__ _ _ _ _ _ _ _ _ _ _ _ _ _ __ _ _ _ _ _ __ _ _ _ _ _ _ __
152 Ibs/day
- c. Color X 75 1 Pt-Co
- d. FecalColiform X < 1 < 1 < 1 45 rov 1Xmrd
- e. Fluoride X < 0.20 < 0.007 (16984-48-8) .. .20 0 -1 MA Ibs/day
< mm.. Y INlaeNtlex .52 1.736 1 mgAI. lbs/day_____ ___
(as P4 __ - -___-__
EPA Form 3510-2C (Rev. 2-85) PAGE V-1 WCONTiiNUt UN1 Ht~VrtH:
ITEM V-B CONTINUED FROM FRONT
- 1. POLLUTANT 2. MARK X 3. EFFLUENT 4.UNITS 5. INTAKE (opt i)
AND CAS b. BE C.BE- a. MAXIMUM DAILY VALUE b. MAXIMUM 30 DAY VALUE c.LONG TERM AVRG. d. NO. OF a. CONCEN b. MASS a. LONG TERM d. NO. OF LIEVED LIEVED NUMBER AB-PRE- LIEVED . (it av7able) VALUE avaiabe ANAL- TRATION AVE RAG VALUE ANAL-(itavailable) SENT SENT C(2) MASS CEA (2) MASS CO (1ETRATIO (2)MASS YSES () CONCEN- (2) MASS YSES
__- CONCERpNCcENTRATIO N CONCENTRATIONYE TRATION _SE
- g. Nitrogen, Total Organic (as N) x 11.9 0.397 1 mg/L lbs/day
- h. Oil and Grease X < 5.1 < 0.170 4 mg/L lbs/day 1.Phosphorus (as P), Total (7723-14-0) 10.8 0.361 1 mg/L lbs/day J.Radioactivity (1) Alpha, Total x < 1.9 1 pCi/L (2) Beta, Total X 32.8 1 pCi/L (3) Radium, Total x 3.4 1 pCi/L (4) Radium 226, Total__
x < 0.1 _ _ _ _ ___ _ _ _ _ _ __ _ _ _ _ ___
1 pCi/L _ _ _ ___ _ _ _ _ __ _ _ _
k.Sulfate (as SO) X 57 1.9 1 mg/L Ibs/day (14808-79-8) 1.Sulfide (as S) x < 1.0 < 0.033 1 mg/L lbs/day
- m. Sulfite (as S0 3 ) %
(14266-46-3)
- n. Suriactants x 0.0972 0.003 1 mg/L lbs/day (7429-90-5) x < 0.10 < 0.003 1 mg/L lbs/day p Barium Total x 0.020 0.001 1 mg/L lbs/day
- q. Boron, Total X 0.10 0.003 1 mg/L Ibs/day (7440-42-8) . .
- r. Cobalt, Total Xbs/day (7440-48-4) x < 0.020 < 0.00 1 1 mg/L lbda s.Iron, Total (7439-89-6) x 0.19 0.006 1 mg/L lbs/day t.Magnesium, Total 1 mg/L lbs/day (7439-95-4) x 22 0.73 L. Molybdenum, Total (7439-98-7) X < 0.050 < 0.002 1 mg/L Ibs/day
- v. Manganese, Totallb/a (7439-96-5) x 0.031 0.001 1 mg/L Ibs/day w.Tin, Total (7440-31.5) x < 0.10 < 0.003 1 mg/L lbs/day x Titanium, Total X < 0.050 < 0.002 1 bs/day (7440-32-6) (R 0 0 PAGE V-2 1 CNIU EPA Form 3510-2C (Rev. 2-85) -PAGE V-2 CONTINUE ON PAGE V-3
EPA I.D. NUMBER (copy from Item lot Fom 1, OUTFALL NUMBER For'm Approved.
OMB No. 2000-0 59 Approval CONTINUED FROM PAGE 3 OF FORM 2-C I ILD 060862810 COI -1 eggres 12-3t45 PART C - if you are a primary Industry and this outfall contains process wastewater, refer to Table 2c-2 In the Instructions to determine which of the GC/MS fractions you must test for. Mark X In column 2-a for all such GC/MS fractions that apply to your Industry and for ALL toxic metals, cyanides, and total phenols. If you are not required to mark column 2-a (secondary Industries, nonprocess wastewater outfalls, and non-required GC/MS fractions), mark WXIn column 2-b for each pollutant you know or have reason to believe Is present. Mark *X In column 2-c for each pollutant you believe Is absent. If you mark column 2a for any pollutant, you must provide the results of at least one analysis for that pollutant. If you mark column 2b for any pollutant, you must provide the results of at least one analysis for that pollutant If you know or have reason to believe It will be discharged in concentrations of 10 ppb of greater. If you mark column 2b for acrolein, acrytonitrile, 2,4 dinitrophenol, or 2-methyl-4,6 dinitrophenol, you must provide the results of at least one analysis for each of these pollutants which you know or have reason to believe that you discharge In concentrations of 100 ppb or greater. Otherwise, for pollutants for which you mark column 2b, you must either submit at least one analysis or briefly describe the reasons the pollutant Is expected to be discharged. Note that there are seven pages to this part; please review each carefully. Complete one table (all 7 pages) for each outfall. See Instructions for additional details and requirements.
- 1. POLLUTANT 2. MARK X 3. EFFLUENT 4.UNITS 5. INTAKE t AND CAS a.TEST- t. 8- c.IBE-a. MAXIMUM DAILY VALUE b. MAXIMUM 30 DAY VALUE c.LONG TERM AVRG. d. NO. OF a. CONCEN b. MASS a.
ING RE- timvoI UmVo LONG TERM - d. NO. OF NUMBER W. I ,. P A ya8be) VALUE r avafef . ANAL- TRATION AERA LUE ANAL-available) - ED - SEN SENT - ( (2)MASS (r) (2)MASS it) (2)MASS YSES ; -()CNCENn (2)MASS ySES METALS, CYANIDE, AND TOTAL PHENOLS I M.Antimony. Total X 0.10 c 0.003 1 000
_740_6_______0 __ _ _ _ _ _ __ _ _ _ _ _ _mg/L. lbs/day 2M. ArsenIc, Total-(7440-38-2) X < 0.0050 cs 0.0002 1 mg/L lbs/day . _
3M. Beryiium, Total 1
=X = 0.020 < 0;000 1 mg/L lbs/day ._
(7440-41-7) . x c 0.010 0.000 . . . _ .__... ._=
4M. Cadmium, Total 1 (7440-3) _ xc 0.00267__X c 0.00020 0.020
.. < 0.00067 _________ 1 1__9_ mg/L lbs/day
'M. Chromium, Total X 0.020 c 0.0007 1 mg/L lbs/day (7440-47-3) ______
6M. Copper, Total X 0.i 0 000 .
(7440.50-8) __0_020______ _ __m __ __ _ __ _ __ _
1I___ mg/U g__
lbs/day 7M. Lead, Total (7439-92-1)__
X _ 0.10 < 0.0033 I mg/L Ibs/day 8M. Mercury, Total x<oooo. .0011 m/ b/a (7439-97-6) t7 0.00<
<40.Tha0mul,To <x 0._______
.c0.0007 1 1' mg/L myIbs/L lbsda da'y==
9M. Nickel, Total X < 0.050 < 0.002 1 mg/L lbs/day (7440-02-0) _ _ _ _ _ _ _ _ _
I1OM. Selenium,. b/a Toal(7782-49-2) X < 0.0050 < 0.0002 I__mg__ ______
IIM. Silver. Total (7410-22-4) x < 0.020 < 0.0007 1 mg/L lbs/day ___
12M. Thallium, Total 1 i/L lbs/a (7440-28-0)x 10 < 003mgL_ __
13M. Zinc, Total013 0041 (7440-66-6) m 14M. Cyanide, Total 4 (57.12-5) x 0.019 0.001mg. lb/a S~~. 'Tota 0.00 EPAForm 351 U-Z(Rev. 2-85) AEV3CNINEO EES t:FA Form Mo-zu (Fiev. z-as) I PAGE V-3 CONTINUE ON REVERSE
CONTINUED FROM THE FRONT
- 1. POLLUTANT 2. MARK 'X' 3. EFFLUENT 4.UNITS 5. INTAKE (option y AND CAS a.TEST- b. BE- c. BE- a. MAXIMUM DAILY VALUE b. MAXIMUM 30 DAY VALUE c.LONG TERM AVRG. d. NO. OF a. CONCEN b. MASS a. LONG TERM d. NO. OF ING RE- I UEVED I IEVED NUBRl_ R- A-(if ava iIble) VALUE avatable ANAL. TRATION AVERAG .VALUE. ANAL-(if available) ED SENT SENT ) (2) MASS (1) (2) MASS (1) (2) MASS YSES (1) COCEN- (2) MASS YE
_ CONCENTRATION TCOCEN IAT CON ENTRATION .E
__LTCO_
GC/MS FRACTION - VOLATILE COMPOUNDS 1V.Acrolein (107-02-8) X 2V. Acrylormtrile (107-13-1) X 3V. Benzene (71-43-2) X 4V. Bis (CNhlromethyl) X Ether(542-88-1) .
SV.Bromolorm X (75-25-2) 6V. Carbon tetralcNoride X (56-23-5) _
7V. CNorobenzene (108-90-7) x 8V.Chlorodibromo-methane (124-48-1) X 9V.Chioroethane (75-00-3) x 10V.2-Chloroethylvinyl X ether(110-75-8)
I1V. Chloroform X (67-66-3) 12V.Dlchlorobromo- X methane (75-27-4) x 13V.Dichlorodifluoro- .
methane (75-71-6) X 14V.11-Dichloroethane X (75-34-3) .
15V.1.2-DOchloroethane X (107-06-2) 16V.1.1-Dichloroethyiene X (75-35-4) 17V.1.2-Dlcoropropane (78-87-5) x 18V.1,3-Dichioro.
propylene (542-75-6) X 19V.Ethylbervene X (100414) .
2WV.Methyl bromide x (74-83-9) 21V. Methy chlorkle x (74-87-3)
EPA Form 3510-2C (Rev. 2-85) PAGE V-4 CONTINUE ON PAGE V.5
EPA I.D. NUMBER (copy trom Item 1 of Form 1 OUTFALL NUMBER Form ApPoved.
CONTINUED FROM PAGE V-4
- 1. POLLUTANT AND CAS
- 2. MARK 'X' l I ILD 060862810 I a. MAXIMUM DAILY VALUE b. MAXIMUM 30 DAY VALUE
- 3. EFFLUENT 1 C01 1 4.UNITS OMB Ab. 20000059 Aprvat e*xps t2-31-85
- 5. INTAKE (oraL T b . E c.LONG TERM AVRG. d. NO. OF a. CONCEN b. MASS a. LONG TERM d. NO. OF NUMBER* ING RE-IU;EPEE VED UE Jlabne) .ywir abre ANAL- TRATION AVERAC EVALUE ANAL-(Wavafable) ED SENT SEr (2)MZSS MASI (2)MASS 0) (2)MASS YSES RCC*CEN- (2)MASS GCIMS FRACTION -VOLATILE COMPOUNDS (continmed . . . . . .
22V.Me Nrida(75 0921t.. t X ._ __
c~Hroed (79-34.5) , - .
24V. TetrxOetb_
(127.18-4) -
25V.ue"(t0&8&-3) X 26V. 1.2-Trum-ddora-ehli(15405) .'. X .__._._._.
27v. 1.t.1-T oXw _ _ _
(71.5 4 _ _ _ _ _ _ _ _ _ _
2w.
9VTrd4One _X .
3901V.
T r1 ,__ _ _ X . _ _ ___ ___.=
30V.TVrcko,oj -
GCIMS FRACTION -ACID COMPOUNDS ._.
(95-574)X_ _ _ _ _ _ __ _ _
2A. 2 4-04cNOV0plM0 lAk2.4-D Feft00*,v X (10547-9) _ _ _ . .
4A 4.6-DWtaD--crssoI . .X (534-52-1) ___Xl__ _ _
SA 2.4-DhVV00Wld (51-28-5) 7rA4-N2tnd X..
(100-0-7) tA P4 :ro-M-aesd X (59-5A.7) _ _ _. _a._. A __ _ _ A .
(88-M2) 18-5-)
EPA Form351G-2C (ReV.Z-5) PlAGEf V-5 CONTINUE ON REVERSE
CONTINUED FROM THE FRONT
- 1. POLLUTANT 2. MARK 'X. 3. EFFLUENT l 4.UNITS 5. INTAKE (optional)
AND CAS aTEST- b. BE- c. BE- a. MAXIMUM DAILY VALUE 2rG E- LIEVEDI LIEVED(iavlal
- b. MAXIMUM 30 DAY VALUE c.LONG TERM AVRG. d. NO. OF a. CONCEN b. MASS a. LONG TERM d. NO. OF NUMBER aIou/- PlE. LED (if ava iAable) VALUE avaabte) ANAL- TRATION AVERAGE VALUE ANAL-(if available) ED SENT SENT (I) (2) MASS C E A (2) MASS (1) (2) MASS YSES (T)RIONCEN- (2) MASS YSES GC/MS FRACTION - BASEINEUTRAL COMPOUNDS IB. Aceraphthre = X (83-32-9)X 2a.Acenaphlhylere X (208-986-8) X 3B.Antracene X
/120-12-7) X________
4B.Benzidine (92-S7-5) X S. Benzo (a) anthracene X (56-55-3) _ _ _ _ _ _ _ _ _ _ _ _ _ _ __ _ _
- 65. benzo (a)pyene X (50-32-8) X 75.3,4-Ber ofluoan thmte X (205-99-2) X
- 85. Benzo (ghl)perylene X (191-24-2) X 9B. Benzo (k) fluoranthene X (207-08-9) X ,
10B.Bis (2chloroethox-y) X methane(III-91.1) X I1B.Bis (2-choroethyl) x ether (111-44-4) X 12B.Bis (2-choroiso-propyl)ether (102-60-1) 138.Bis (2-ethylhexq) X phthalate (117-81-7) X 14B.4-Bromophenyl phenyl X ethet (101-55-3) 15B.Butylbenzyl phthatate X (85-68-7) X 16B.2-Chloronaphthalene X (81-58-7)X 17B.4-Chtorophenyl phenyl X ether(7005-72-3) 185. Chyenex (218-01-9) X 19B.Dibenzo (a~h) anthracene (53-70-3) X 20B. 1,2-Dichlorobenzene X (95-SO-1) 21B. 1.3-DicNorobenzene X (541-73-1)
EPA Form 351 0-2C (Rev. 2-85) PAGE V-6 CONTINUE ON PAGE V-7
EPA I.D. NUMBER (copy 1mom Item 1 of Form 1) OUTFALL NUMBER Fbr A~vved.
0MB No.200"059AWipva1 CONTINUED FROM PAGE V-6 ILD 06086281 0 1 COl exp*9s 12-31-85
- 1. POLLUTANT 2. MARK X ____ ____ 3. EFFLUENT __________ ___4.UNITS 5. INTAKE (qvta5 AND CAS 4L TEST- b. BE. I . BE- a. MAXIMUM DAILY VALUKE b. MAXIMUM 30 DAY VALUE c.LONG TERM AVRG. d. NO. OF a. CONCEN b. MASS a. LONG TERM d. NO. OF NUMBER ING RS. UEVED LIEVEDMaaaNlAEGEV NUBR OUIR. PRE. AB. VAia~).~~ILifat!L.. ANAL- TRATION '.YLUE... ANAL-(INAvaable) 93SENT SENT C (l )j 2)MASS (I) I 2MS SES Y2MS (I) CONCEN. (2)MASS YE GC/MS FRACTION - BASE/NEUTRAL COQMPOUNDS(ctnud__________
(108-487) bwvodne (91-941) X _ _ _ _ _ _ _
4 2 9.OlelI'llphdlate (844-62) 268. MD alvax _____
279.224-DWIotakmi x 289. 2.6-Dkftvlokme (6W820-2)
M.D -Oct1p& uai 308. V.-Do~perrA.
htq~szb"(1224-%7)X 319.Fkmnw~t9Wvm -
329 Fkiwo m(S873-7)X 3318. Hed mb e -
(118-74-1) 358. HexadiOrO400l.x p-Wft-dn (7-47.4) 379.hkdeno (1.2.3-cd) pyrome(193-39-5) 388. hopiuon (78-59-1) X 398. Naptfteenx (91.20-3) _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _
408 .Nlotmatenz (98-95-3) x 419. N-N~od9memi4.
wmneo(62.75-9).-
428. N-Nlfro"-.
propan**m(521 -"47)X CO A C. 'ICIfl2f* 10.. OO-2 1-
~IStl GONIINUP. ON REVERSE
CONTINUED FROM THE FRONT
- 1. POLLUTANT 2. MARK 'X. 3. EFFLUENT 4.UNITS 5. INTAKE (opton va)
AND CAS &TESTJ bBEFv.cE- a. MAXIMUM DAILY VALUE b. MAXIMUM 30 DAY VALUE c.LONG TERM AVRG. d. NO. OF a. CONCEN b. MASS a. LONG TERM d. NO. OF NIUMB ER OUIR. PRER I (if avaK7able) VALUE (ifavaflable) ANAL- TRATION AVERA E VALUE ANAL-(itavailable) ED SENT SENT CON MASAS (C) (2)MASS (1) (2)MASS YSES (1) CONCEN- (2) MASS YSES
_ _ CONCENRTO CCNTRAION ~ ~ CONENRATION _E TRATIONYE GCtMS FRACTION - BASE/NEUTRAL COMPOUNDS (ontinued) 436. N-Nitrosodi-pheanyamine (85-30-6) X 448. Phenanthrene X (85-01-8) 458. Pyrene (129-00-0) X 466. 1,2.4-TrchiorXo- x benzene (120-82-1)
GC/MS FRACTION -PESTICIDES 1P. Aldrin X (309-00-2) I 2P. O-BHC X (319-84-6) X 3P. O-BHC X (319-85-7) _ _ _ I _
4P. O-BHC X (58-89-9) .
5P.O-BHCX (319-86-8) X 6P. Chkordane X (57 .74-9) _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _
7P. 4,4'-DDT X (50-29-3) 8P. 4,4'-DDE X (72-55-9) 9P. 4,4'-DOD X (72-54-8) _
1OP. Dieldrin X (60-57-1) _
11P. O-Endosulfan X (115-29-7) 12P. O-Endosulfan X (115-29-7) 13P. Endosullan X Sulfate (1031-07-8) 14P. Endrin X (72-20-8) 1 _
15P. Endrin Alde- X hyde (7421-93-4) _ _ _ l l 16P. Heptachlor X (76-44-8) ___ . _ _ _ __ _
rrupAv-O CONTIUE ON PAGE V-
-~r rui-..- vuv - ni. -1 rmAu V-0 CONTINUE ON PAGE V-9
EPA l.D. NUMBER (copy from Item I of Form t)lOUTFALL NUMBER FoMAppmVed.
OMB No. 20000-09 Apprv CONTINUED FROM PAGE V-8 E ILD 060862810 1l C0 efws 12-3185
- 1. POLLUTANT 2. MARK 'X 3. EFFLUENT 4.UNITS 5. INTAKE (otbfln AND CAS , TEST b. BEVED UEV-E a. MAXIMUM DAILY VALUE b. MAXIMUM 30 DAY VALUE c.LONG TERM AVRG. d. NO. OF a. CONCEN b. MASS a. LONG TERM d. NO. OF NUMBER OUIR. ABG Ae ._ __ ffvlabte) VALUE r ANAL TRATION LUI ANAL-
____avalabe)
(if )C- ED avaifATabN SENT ss
-RAT SET (I) (2) MASS (I (2) 2 MASS CONSE(IM)TI (2)MASS (2MSS YSES YES __________
(I)CONCEN- (2)MASS YSES GCIMS FRACTION - PESTICIDES (continued) 17P.Hqepata Epo~f x (1024-573) A 18P. PCB-1242 x (53469-21-9) _ .
19P. PCBt1254 x (11097.69-1) 20P. PCB-1221 x (11104-28-2) 21P.PCB-1232 x (11141-16-5) _ _ _ . .
22P. PCB-1248 x (12672-29-6) A 23P. PCB-1260 X (11096-82-5) 24P. PCB-1016 X (12674-11-2) 25P. Toxaphene x (8001.35-2) _ _ .
EPA Form 3510-2C (Rev. 4-84) PAGE V-9 EPA Form 3510-2C (Rev. 2-85)
PLEASE PRINT OR TYPE IN THE UNSHADED AREAS ONLY. You may report some or all of EPA I.D. NUMBER (copyfrom ItemI of Form 1) FormApped this Information on separate sheets (use the same format) Instead of completing these pages.
SEE INSTRUCTIONS ILD06086281 0 OvS No. 2000-00S9 V. INTAKE AND EFFLUENT CHARACTERISTICS (continued from page 3 of Form 2-C) OUTFALL NO.
I A02 PART A - You must provide the results of at least one analysis 1TAKE ora
- a. MAXIMUM DAILY VALUE d. NO. OF a. CONCEN a. LONI I TERM d. NO. OF
- 1. POLLUTANT MiafaffaNey
- 4. .i
- ANAL. TRATION AVERAG E-VALUE ANAL-(1) (2) MASS _ (I) . (2) MASS )1) (2) MASS YSES seecu_
(2) MASS YSES
J. Chemical Oxygen Demand (COD) .
c Total Organic Carbon (TOC) .
d.Total Suspended Solids 6.1 2.80 5.9 2.71 3.2 1.47 30 mg/L lbs/day
- e. Ammonia I. Fl VALUE 0057 VALUE 0.056 VALUE 30 MGD VALUE
- g. Temperature VALUE VALUE VALUE o VALUE Wfnter) VALUE__cVALUE hI Temperature VALUE VALUE VALUE 0 VALUE Osurn~mer) , ,, ... C .... :
I pH MINIM STANDARD UNITS PART B - Mark *X-in column 2 a for each pollutant you know or have reason to believe Is present. Mark X In column 2-b for each pollutant you believe to be absnt. I you m ark column 2a for any pollutant which Is limited either directly or Indirectly but expressly. In an effluent limitations guideline you must provide the results of at least one analysis for that pollutant For other pollutants for which you mark column 2a. you must provide quantitative data or an explanation of their presence In you discharge. Complete one table for each outfall. See Instructions for additional details an requirements.
.1. POLLUTANT 2. MARK X - 3. EFFLUENT 4.UNITS 5. INTAKE (cna AND CAS b. BE. BE a. MAXIMUM DAILY VALUE b. MAXIMUM 30 DAY VALUE c.LONG TERM AVRG. d. NO. OF a. CONCEN b. MASS a. LONG TERM d. NO. OF
- NUMBER PuE. AEgv yai*raF ia ANAL- TRATION AVRAGE VALUE ANAL-f(7avalabe) SENT SENT (T) (2)MASS (I(2) MASS (I) (2)MASS YSES (ICCNCEN-. (2)MASS. YSES a; Bromide (24959-67-9) X _ _
- b. Chlorine, Total Residual X ll cColor X 15 1 Pt-Co
- d. Fecal Collform X t;Fluorlde x < 0.10 < 0.046 1 mg/.. Ibs/day (16984-48-8) I.. I . Ibs/day __. ____ ___ --- L . .
I;Nitrate-Nitrite. X007 0001 MA b/a (as M~x007 0001 m/ b/a ___ ___
EFA Form 351113-ZE; (Helf. Z-a5) PAGEif V-11 CONTINUE ON REVERSE
ITEM V-B CONTINUED FROM FRONT
- 1. POLLUTANT 2. MARK 'X' 3. EFFLUENT 4.UNITS 5. INTAKE (optinal AND CAS b. BE- C. BE- a. MAXIMUM DAILY VALUE b. MAXIMUM 30 DAY VALUE c.LONG TERM AVRG. d. NO. OF a. CONCEN b. MASS a. LONG TERM d. NO. OF NUMBERLEVED LIEVED (iavailabe) ANAL- TRATION AVERAGE VALUE ANAL-(if available) SENT SENT (1) (2) MASS (I)ASS 1 52 (1) (Z) MASS YSES (1) iCONCEN- (2) MASS YSES
- CONCENTRATION . -CONCENTRATION .CONCENTRATION YSSTRATIO _SE
- g. Nitrogen, Total1 Organic (as N) X < 0.10 < 0.046 1 mg/L Ibs/day
- h. Oil and Grease X 5.0 2.295 5.0 2.294875 < 5.0 < 2.294875 14 mg/L lbs/day 1.Phosphorus (as P), Total (7723-14-0) X .
i Radioactivity -
(1)Alpha, Total X < 2.0 1 pCi/L (2) Beta, Total X 967 1 pCi/L (3)Radium, Total x < 0.17 1 pCi/L (4)Radium 226, < 0.053 1 pCi/L Total __<_0_05______/
- k. Sulfate (as SO,)
k.1Sulfate ) X < 0.50 o.1 0.2 .1 mg/L lbs/day I. Sulfide (as S) x
- m. Sulfite (as SO,)
(14266-46-3) _ X
- n. Surfactants X
- o. Aluminum, Total1 (7429-90-5) X = < 0.200 < 0.092 1 mg/ Ibs/day
- p. Barium, Total (7440-39-3) x < 0.200 < 0.092 1 mg/L lbs/day
- q. Boron, Total 1 mg/L lbs/day (7440-42-8) X < 10 < 4.59 1 mg/L Ibs/day
- r. Cobalt, Total 1 m/ b/a (7440-48-4) X < 0.050 < 0.023 1 mg/L Ibs/day
- s. Iron, Total1 (7439-89-6) X 1.62 0.744 1 mg/L Ibs/day t.Magnesium, Total 5.0 < 2.29 1 mg/L lbs/day (7439-95-4) X < 0.0 < 2.29 1 mg/L Ibs/day uPMolybdenum, (Rcv 1 lbs/day Ttal (7439-98-7) x <~ 0.040 < 0.018 1 MA b/a v.Manganese. Total (7439-96-5) x 0.036 0.016 1 mg/L lbs/day
- w. Tin, Total1 (7440-31-5) x < 0.100 < 0.046 I m/ b/a x.Titanium, Totallb/a (7440-32-6) X .< 0.050 < 0.023 1 mg/I.. ls/a EPA Form 351 O-2C 1Rev. 2-R51
- B - \ /
PAr'F! V.1, IU -ni.
JP ~Jn SUNil I INj.U11 I'NMarC V-J)
EPA I.D. NUMBER (copy trom Item 1 of Form 1)IOUTFALL NUMBER FWM Aarvd OMB No. 2000-00594cAyWva rCONTlNUIFD FROM PAGE 3 OF FORM 2-C I IL006086281 0 Ij A02 enples 12-31-8.
PART C- if you are a primary Industry and this outfall contains process wastewater, refer to Table 2c-2 In the Instructions to determine which of the GCIMS fractions you must test for. Mark *X in column 2-a for all such GC/MS fractions that apply to your Industry and for ALL toxic metals, cyanides, and total phenols. If you are not required to mark column 2-a (secondary Industries.
nonprocess wastewater outfalls, and non-required GC/MS fractions), mark *X' In column 2-b for each pollutant you know or have reason to believe Is present. Mark *X In column 2-c for each pollutant you believe Is absent. If you mark column 2a for any pollutant, you must provide the results of at least one analysis for that pollutant. If you mark column 2b for any pollutant, must provide the results of at least one analysis for that pollutant if you know or have reason to believe it will be discharged In concentrations of 10 ppb of greater. If you mark column 2b for acrolein. acrylonitrile, 2.4 dinitrophenol, or 2-methyl-4,6 dinitrophenol, you must provide the results of at least one analysis for each of these pollutants which you know or have reason to believe that you discharge In concentrations of 100 ppb or greater. Otherwise, for pollutants for which you mark column 2b, you must either submit at least one analysis or briefly describe the reasons the pollutant Is expected to be discharged. Note that there are seven pages to this part; please review each carefully. Complete one table (all 7 pages) for each outfall. See
- - Instructions for additional details and requirements. - _
1.POLLUTANT 2. MARK' I- 3. EFFLUENT l_ 4.UNITS 5. INTAKE (opctk-AND CAS . TEST b. B E. a. MAXIMUM DAILY VALUE b. MAXIMUM 30 DAY VALUE c.LONG TERM AVRG. d. NO. OF a. CONCEN b. MASS a. LONG TERM d. NO. OF NUMBER C OUiR. v - *uevRE aO yese) VALUE vrm ate)L ANAL- TRATION AERAEB vALUE ANAL-(i mavalable) EDI SEW :r (I (27MASS (I) (2)MASS (1) (2)MASS YSES (1)COCE- (2)MASS YSES METALS, CYANIDE AND TOTAL PHENOLS _________
IM.Antimony, Total X < 0.060 < 0.028 1 mgAL lbs/day (7440-3"-) ____
2M. Arsenic. Total X _ 0.200 c 0.0918 1 mg/. lbs/day (7440-38-2) X < 0.0050 < 0.0021. 1 mg bs/day ,
3M. Beryllium. Total <005 .0
__4_4__-7 _ =_c0.0050 _X < 0.00229 . ._. _1 mg/L !bs/day . =
4M. Cadmium, Total (7440-43-9).
X0.0050 < 0.0 0229 1 mg/9. lbs/day ._ ._ .
(744-s8=X-c005c.01417). .___
SM. Chromi=um, < 0.01t0 c 0.004609 __ __
1
.__..___..1'__ g/~~ b6da. . ngA lbs/day =
(744047.3) 6M. Copper. Total (7440-50-8) X = < 0.025 < 0.011 1 _. mg/U lb-sday 7M. Led. Total (7439.92-1)
X 0.100 < 0.04591 ______
1 mg/V lbs/day .
8M. Mercury, Total X < 0.00020 < 0.00009 1 mgbs/day (7439-97.6) _ _____
9M. Nickel, Total 0.4 0011 (7440-02.0). X < 0.006 0.003 1 mgA. lbs/day 1OM. SelenIum, Xx 0.009 0.091 : 1 mg/L lbs/day Total (7782-49-2) l l00___Im_
IIIM. Silver. Total1 (7440-22A4). x *0 0.010 _<____000 00_ _ _ _ _________ mg/I.. lbs/day _______
12M. Thallium, Total - '.20 <-O09lb r~s/day (7440-28-) .0 .01 gL lb 13M. Zinc. Total 0091 m/ b/a (7440-68-8 x < 0.020 < 0___009__ __ ______ lbs ______ __
t4M. Cyanide. Total 0.006 0.003 1 Mg/L -bsda 15M. Phenols. Total: X 0.089 0.041 1 mg/L lbs/day DIOXIN . * . .-
2,3.7,8-Tetra- I. I - IDESCRIBE RESULTS chorodlbenzo-P- *~ X I EP'A 1-arm 351 U-ZU (HOV. Z-UD) PAUE V.3 CONTINUE ON REVERSE
(
CONTINUED FROM THE FRONT
- 1. POLLUTANT 2. MARK 'X' l 3. EFFLUENT 4.UNITS 5. INTAKE (op tal)
AND CAS a.TEST- b. BE- I c. BE- a. MAXIMUM DAILY VALUE b. MAXIMUM 30 DAY VALUE c.LONG TERM AVRG. d. NO. OF a. CONCEN b. MASS a. LONG TERM d. NO. OF ING RE- LIEVEDLIEVED (ifavailable) VALUE ttpavailable) ANAL- TRATION AVERAG VALUE ANAL (if available) ED I SENT SENT (1A (2) MASS (1) (2) MASS (1) (2) MASS YSES (1) CONCEN. (2) MASS YSES
_ CONCENTRATION CONCENTRATION __TRATIO_
GC/MS FRACTION - VOLATILE COMPOUNDS .
IV. Acrolein (107-02-8) X 2V.Acryionitrile (107-13-1) X 3V.Benzene (71-43-2) X 4V. Bis (Chioromethy!)
Ether(542-88-1)
SV. Bronmolorm X (75-25-2) 6V.Carbon tetrachloride X (56-23-S) 7V.Chlorobenzene X (108-90-7) 8V. Chlorodibromo.
methane (124-48-1) X gV.Chloroethane X (75-00-3) 1W. 2-Chloroethytvinyl X ether(110-75-8) ttIV. Chloroform X (67-66-3) 12V.Dichlorobromo- X methane (75-27-4) 13V.Dichlorodilluorox mettiane (75-71-8) X 14V.1.1-Dichloroethane X (75-34-3) .
tSV. 1t2-DNchloroethane X (107-06-2) 16V.1.1-Dichioroethyiene X (753S-4)3 17V.1,2-Dictioropropanx (78-87-5) x 18V. 1,3-Dichloro-propylene (S42-75-6) X 19V.Ethyibenzene X (100-41-4) _
20V.Me~thybromide (74-83-9) x 21V. Methvl chloridex (74-87-3) X EPA Form 3510-2C (Rev. 245) PAGF V.4 *ltU r~r v tJAl fntAI r W l I IllUa UN r~ua V-:D
EPA l.D. NUMBER (copy from Item I ot Form tJ OUTFALL NUMBER Fo"m Appfvved.
CONTINUED FROM PAGE V-4
- 1. POLLUTANT 2. MARK 'X' ILD060862810 E
- 3. EFFLUENT A02 1 4.UNITS OMB No. 2000-0059 App exp7res 12-31-8
- 5. INTAKE (
AND CAS I TEST. b. BE- cBE- a. MAXIMUM DAILY VALUE b. MAXIMUM 30 DAY VALUE c.LONG TERM AVRG. d. NO. OF a. CONCEN b. MASS a. LONG TERM d. NO. OF INGME LIEVED LIEED Tt~RE. Sa.ln)VALUE lwayaraieJ ANAL- TRATION AVERAC AU ANAL-NYavaMabe) ED sENT SENT (2)M. (2)MASS (1) (2) YSMES S()CONCEW (2)MA YSES GCIMS FRACTION - VOLATILE COMPOUNDS (conlled) ._._.
22W.LM*4ew odeim7
__X 23V. 1.1.2.2-TobX-c&oroelwte (7934-5) X___
24V. T7,e x (127.84) ..
25V.T1owu (1068-.3) X 26V. 1t2.Trao-ddro. X 8Ye"(156-60-4) X.
27v. 1.tt-Tu~ctHan x (71 X . ._ -
28V. 1.12-Trldoraf8wo X 29V.VTrinh4drert GCIMS FRACTION -ACID COMPOUNDSS tA.2-Chctopheno .
(95-57-_)
2A.2.4-DOorowd. X (120.83-2.
3A 2.4-Dietypheral x (105-87.9) ._.
4k 4 6-DI __x._...
e sc (534-.52.1)
Sk 2.4-2W. . .
(51-285) X _
6-k 2-I'topuftI (9&75-5) _
ftA.4-~PhtdoX ICA Rwol(108-95-2)X tOA8ttOmm : .2 = = . .. .
I1IA24.8-T'ItorPhev X (58062) : _ __.... __ __ _ _ _ ____ _ _ ______ __ .__ __.___.
EPA Fotrm 3510-2C (Rev. 2-85) PAGE V-5 CONTINUE ON REVERSE
CONTINUED FROM THE FRONT
- 1. POLLUTANT 2. MARK 'X 3. EFFLUENT 4.UNITS 5. INTAKE (optional AND CAS a.TEST- b. BE- c. DE- a. MAXIMUM DAILY VALUE b. MAXIMUM 30 DAY VALUE c.LONG TERM AVRG. d. NO. OF a. CONCEN b. MASS a. LONG TERM d. NO. OF NUMBER (iNUMlBdER ING RE- LIEVED LIEVED EDR SRENT SETAB-CRCN (if avaitable) VALUE favaitabte ANAL- TRATION AVERAGE VALUE(2) MASS ANAL-YE
((1avai)bbe) ED SENT SENT (2) MASS (1) (2) MASS (1) (2)MASS YSES (t) CONCEN- YSES GC/MS FRACTION - BASE/NEUTRAL COMPOUNDS 1B.Acenaphthene X (83-32-9) _
2B. Acenaphthylene X (208-96-8)
- 35. tracene (120-12-7) x 4B. Benzidine (92-87-5) X
- 58. Benzo (a) anthracene X (56-55-3) 6B.Eenzo (a) pyrene X (50-32-8) 7B.3,4-Benzoflaorantheoe Y (205-99-2) x
- 38. Benzo (ghl) perylX (191-24-2) .
- 96. Bento (k)fluorantheme X (207-08-9) 108. Bis (2chloroethox-y) X methane (111-91-1) 11B. Bis (2-chtormethyl) X erher(11144-4) 125. Bis (2-chlorolsoX pfopyl) ether (102-60-1) X 135. 9is(2-ethylheryl) X phthalate (117-81-7) 148. 4-Bromophenyl phenyl X ether (101-55-3) _
158. Butylbenzyl phthalate X (85-68-7) 165. 2-CNoronaphthalene X (91-58-7) 17B.4-CNorophenyl phenyl X ether (7005-72-3) 18B.Chrysene X (218-01-9) _
- 19. Dibentzo(a,h) anthracene (53-703) . X 208. 1.2-Dichlorobenzene X (95-50-1) .
215. 1.3-Dichlorobenzeme X (541-73-1)
FnrmNU r-I tv-vt IAnv UNint' Vi
-r w 1
-rr -z I-l. .-.. rMAtjit V-0t COLNITINUE ON PAUL V-7
EPA l.0. NUMBER (copy frmm Item I of Form t, OUTFALL NUMBER Form AWved.
CONTINUED FROM PAGE V-6 I ILD060862810 t]I A02 I OVMNo. 200-0059 Appnrval expes 12-31-85
- 1. POLLUTANT 2. MARK X l 3. EFFLUENT 4.UNITS 5. INTAKE (pna AND CAS &TEST.UE- cSBE- a. MAXIMUM DAILY VALUE b. MAXIMUM 30 DAY VALUE c.LONG TERM AVRG. d. NO. OF a. CONCEN b. MASS a. LONG TERM d. NO. OF NUMSER RE- UEVDF EEo
^avatabe) V E ravlabel ANAL- TRATION AVERAG VALUE ANAL-(ifavalabte)
NUM ER GtR- PRlE. A& (1-)
ED SENT SENT (2)MASS (I) _2__AS____CNCE_2__AS (2) MASS (1) (M_ YSES (1)CONCEN- (2)MASS YSES GC/MS FRACTION - BASEINEUTRAL COMPOUNDS continued) ____ _ ___ _ ___
228. 1.4->cHoobwtzw* X (106-46.7) . .
2MB.33D - . X . _
btsnzete.S1-94 t}
248. Die" tt . X .
(54-662) 2fiB. amevy o~wda-268. DMN-bAltphdt . X .
(tJ474-2)i..
278. 2.4- l -_XOl _ . .-.
(121-t4-2) . . _
28B. 2b6--toXok.le (117-246-) _ . .
30B.U12.IPhw~.
h)d*ar (1224i.-7) x .... - ..
319.Plurviene-328. Fluorset(5-73-7) . X -
3M. ._. . . . em 33.H xdtenzens-1 (11 6-74-I)__
x - X- - -
34B.HetadtobAdW .
(t7-64-3), '_.
3f51.H eX.*c.r0.ydO-3fi8. Hex c . :,,, x ..
(6772-1) _ ._. .
378 . Xdo .3- . .
pM&I(193-39-5) _ . . '
38_. w. _so _
(7 5-656-1) : _ _ _ _ _ _ _ _ _ _ _ _ _
39B. Nplaer _ _ X (91-26-3) 408., NtfoemitX __ _ _ _ _ __ ___
tt9. N-Nltrosoaso x wuh (62275-9) X 42B. NNlod-N.
promn _ X
.62.147) tPA -orMl t5tZC{eV.Z-OD HAUrt V-1 CONTINUE UN REzVERSEF
CONTINUED FROM THE FRONT
- 1. POLLUTANT 2. MARK X . 3. EFFLUENT 4.UNITS 5. INTAKE (opton /2 AND CAS a. TEST- b.EBE c.8E a. MAXIMUM DAILY VALUE b. MAXIMUM 30 DAY VALUE c.LONG TERM AVRG. d. NO. OF a. CONCEN b. MASS a. LONG TERM d. NO. OF NUM ING RE LVED LIEVED (if available) VALUE availableJ ANAL- TRATION AVERAG VALU E ANAL-(if available) ED SENT jSENT COCNTAIO SS (1) (2)MASS (1) (2)MASS YSES ()CONCE (2)MASS YSES I C1,1EE~'TR-TIO CONCENTRATION _ _ESTRAnQN YE GCIMS FRACTION - BASE/NEUTRAL COMPOUNDS continued) 433. N-Nitrsomfi.
phenylamine (86-30-6) X 448. Phenantihrene X (85-01-8)X 455. Pyrene (129-00-0) X 46B. 1,2,4-Trichloro- X benzene (120-82-1) X GC/MS FRACTION - PESTICIDES IP. Aldrin X (309-00-2) _
2P. 0-BHC X (319-84-6) .
3P. OB5H7FC x (319-85-7) _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _
4P. 0-3BHC X (58-89-9) _ _ _ _ _ _ _ _ _ _ _ _ __ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _
5P o-BHC (319-86-8) X 6P. Chlordane X (57-74-9) 7P, 4,4'-DDT x (50-29-3) _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _
8P. 4,44-ODE X (72-55-9) _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _
9P. 4,4 -DODD (72-54-8) X_ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _
l OP. Diledrin X (60-57-1) X 11 P. O-Endosulfan X (115-29-7) _ _ i 12P. O-Endosulfan X (115-29-7) 13P. Endosulfan X Sulfate (1031-07-8) _
14P. Endrin X (72 8) _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _
15P. Endrin Aide. X hyde (7421-93-4) X 16P. Heptachlor X (76-44-8) X a I IUV-2
- -A . -11 to-,
%-.. '----ai ,
-- UUN14 I INUL1 UN rAtir- V-Y
EPA l.D. NUMBER (copy from Item I of Form 1)IOUTFALL NUMBER FormnAppmved.
OMB No. 2000-O9 Aval CONTINUED FROM PAGE V-8 ILD060862810 A02 . eifrs 12.31-85
- i. POLLUTANT 2. MARK 'X' 3. EFFLUENT 4.UNITS 5. INTAKE (ookiaI)
AND CAS ia-RE EE- UE- B a. MAXIMUM DAILY VALUE b. MAXIMUM 30 DAY VALUE c.LONG TERM AVRG. d. NO. OF a. CONCEN b. MASS a. LONG TERM d. NO. OF NUMBER EvlRE . .EEDUEED_____
________ __ V a-ral ANAL- TRATION AYEREALUE ANAL-NUMaVlbleR ED IENTSENT CA- (2)MASS (I) (2)MASS (II (2)MASS YSES (1)CONCEN. (2 MASS YSES GCIMS FRACTION - PESTICIDE S(continued) _
17P.HePtahbrEpEx V (1024-57.3)
I8P. PCB-1242 x (53469-21-9) _
19P. PCB1254 .
(11097-69-1) _ .
20P. PCB-1221 x (11104.28.2) 21 P. PCB-1232 x (11141-16-5) _ _ _ _ _ __ _ _ _ _ _ _ _ _ _ _
22P. PCB-1248 _
(12672-29-6) X 23P. PCB-1260 x (11096-82-5) _ _ _
24P. PCB-1016 x (12674-11-2) _ .
25P. Toxaphene (8001-35-2) ._ I _ _ _ _
EPA Form 3510-2C (Rev. 4-84) PAUE V-9 EPA Form 3510-2C (Rev. 2-85)
Attachment 1 Requested Permit Changes Requested Modifications/Corrections:
In addition to the preceding information required for renewal, Exelon wishes to provide the following comments relative to proposed modifications to the existing permit. Please include these requests in your deliberations regarding Quad Cities NPDES permit renewal.
(1) Rcquest that P11 be eliminated as a parameter for Outfalls 001/002. Based on the historical information that Quad Cities Station has collected over the years, pH has always been within the 6 to 9 range, with the only exception being certain instances when algal activity in the Mississippi River causes the influent pH to be above 9. As indicated on Attachment 4, Quad Cities Station does not add any wastewater additives to the subwastestreams associated with Outfalls 00 1iO02 that would affect pH levels, and therefore we believe that there is no significant justification for continuing pH monitoring of this outfall.
(2) Request to have the monitoring frequency for Total Suspended Solids (TSS) and Flow reduced to 2x/month (from the current lx/week) for Outfall B01 -Wastewater Treatment System. Based on the excellent compliance record for the station's Wastewater Treatment System. This change would be consistent with the current sampling frequency on the station's Sanitary Waste Treatment Plant.
(3) Request that Oil and Grease be eliminated from the monitoring requirements for Outfall A02-Radwaste Treatment System Blowdown. The majority of the water discharged (approximately 95%) is processed floor drain water that has been filtered to remove solids, and then sent through resin to remove most of the radioactivity (conductivity
<1 umho/cm). The remainder of the water is from the laundry sample tank that consists primarily of water from washing masks and personal clothing that has become radioactively contaminated which has been filtered to remove solids. Equipment drain water is not routinely discharged. Equipment drain water that is discharged is water that has been treated the same as floor drain mentioned above, but has failed limits for storage (ie.. Total Organic Carbon > 100 ppb, Silica > 50 ppb). The Oil and Grease compliance history for this outfall over the past three years has been exemplary. Of the last 45 Oil & Grease analysis performed on this outfall, only two have been greater than the limit of detection (LOD) of 5.0 mg/L (the highest recorded value was 5.5 mg/L). Based on Quad Cities history of compliance with this parameter, we believe there is sufficient justification for this request.
(4) We request that the Agency review Quad Cities excellent compliance record and follow through with any other appropriate monitoring parameter and/or frequency reductions as deemed appropriate.
Q:\SVP\SVP 2004\098.doc
Attachment 2 Page 1 of 2
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Topographic Map Location:
USGS Map Exelon Generation Co, LLC 410 43' 30"N, 900 18' 45"W (WGS84/NAD83) Quad Cities Generating Station Cordova quadrangle Cordova, Illinois 61242 Projection is UTM Zone 15 NAD83 Datum Permit No. 1L0005037 1:24K / 25K Series 1:100,000 Scale Page 2 of 2 Site Area Map Location:
Exelon Generation Co, LLC Quad Cities Generating Station Cordova, Illinois 61242 Permit No. IL0005037
Exelon Generation Company, LLC Attachment 3 Quad Cities GeneratingStation Water Flow Schematic 10/28/04 Rinse Water Misc. Wastes Nuclear Boiling Water Reactor Steam Electric Generating Process Floor Iir Sump ce Water Pump &
tackwash Screen Discharge SeScreen 3ackwash House It Bay Legend
-F Flowpaths Alternate Routes
- Outfall Number
- Sample Point (Average Flowrate, MGD) Mississippi River
Attachment 4 Water Treatment Additives Quad Cities Generating Station November 11, 2004 Raw Water Treatment Chemicals
- 1. Sodium Hypochlorite
- 2. Sodium Bromide
- 3. Sodium Bisulfite
- 4. Sodium Hexametaphosphate (SHMP)
- 5. Depositrol BL5400 (HEDP)
- 6. Depositrol BL 5323 (HEDP/PAA)
- 7. Nalclean 2568 (special use scale remover)
Wastewater / Sanitary Waste Treatment Chemicals
- 1. Aluminum Sulfate
- 2. Calcium Hypochlorite (Sanuril 115)
- 3. Sodium Bicarbonate
- 4. Bacterial Cultures (Bio-Systems B500-F Blue)
- 5. Aquafix D-Foam 9970 Outfalls 001/002-Open Cycle Diffusers No treatment applied to this discharge as wastewater. The station's circulating water is treated with sodium hypochlorite and sodium bromide for biofouling control and Depositrol BL5400 (a 60% HEDP liquid scale inhibitor) for scale control. The station performs sequential chlorination only, in accordance with permit Special Condition No. 4. Quad Cities continues to utilize a dechlorination system, which relies upon the addition of sodium bisulfite to the condenser cooling water outlet. Dechlorination is necessary in order to consistently meet the 0.05 mg/L Total Residual Oxidant (TRO) limitation, which applies whenever bromine-based biocides are used.
The station's service water is treated with sodium hypochlorite and sodium bromide for biofouling control, Depositrol BL5323 (a blend of 14.4% HEDP and 28.8% HPS-1 copolymer.
HPS-1 is a derivative of polyacrylic acid) for scale inhibition and silt dispersion, and SHMP (a polyphosphate corrosion inhibitor containing 35% sodium hexametaphosphate) for corrosion inhibition.
Quad Cities also has obtained prior Agency approval to use the following products for water treatment and/or biofouling control within the station's safety and non-safety-related service water systems: Nalclean 2568 (special use scale remover for non-safety-related biocide piping),
Devoe Bar-Rust 235 and Devoe ABC #3 (anti-fouling coatings for safety-related system).
Please refer to Agency correspondence dated February 2, 1998 and March 8, 1999 (respectively) for further information regarding the use of these products.
Q:.v\SVVP 2004\098.doc
Outfall BOI-Wastewater Treatment System Aluminum sulfate is used in the station's wastewater treatment system to assist in the settling of solids.
Outfall COI-Sanitary Waste Treatment System Calcium hypochlorite (Sanuril 115) tablets are used for disinfection purposes in the sewage treatment system. Sodium Bicarbonate is added to various stages of treatment, as needed, to control effluent pH. Bio-Systems B500-F Blue (or similar bacterial product) is added to the aerobic digester to increase bacterial culture activity. Aquafix D-Foam 9970 (or similar defoam product) is added to the aerobic digester to control foaming.
Outfall A02-Radwaste Treatment System Blowdown No chemical additives are routinely used in this system.
Q:\SVP\SVP 2004\098.doc
Vertex Chemical Corporation
- .VERTEX MATERIAL SAFETY DATA SHEET
. I II I PRODUCT NAME: SODIUM HYPOCHLORITE 6-16% DATE: 01/21/04 l MANUFACTURERS NAME: Vertex Chemical Corporation REGULAR TELEPHONE NUMBER. Dupo, IL (618) 286-5207 9909 Clayton Road, Suite 219 Camanche, IA (563) 243-2000 St. Louis, Missouri 63124 Memphis, TN (901) 775.1382 (314) 991-4005.
DATE REVIEWED: 01/21/04 EMERGENCYTELEPHONENUMBER: (314)991.4005 St. Louis 1-800-424-9300 CHEMTREC CALLC TCONLY INTE EVENTOF
-CHEMICAL EMERGENCES INVOLVING A SPILL LEAK. IrE EXPOSUIT OR ACCIDENT INVOLVING CHECAL&
NATIONAL EMERGENCY RESPONSE CENTER: 14800424-8802 SECTION 1. PRODUCT IDENTIFICATION TRADE NAME AND SYNONYMS: Liquid Bleach, Soda Bleach, VERTEX CSS (EPA Reg. No. 9616-11), VERTEX CONCENTRATE'm (EPA Reg. No. 9616-8), VERTEX CSS-10> (EPA Reg. No. 9616-9), VERTEX CSS-12Th (EPA Reg. No. 9616-7), VERTEX Germicidal Ultra Bleach (EPA Reg. No. 9616-13)
CHEMICAL FAMILY: Oxidizing Agent (Hypochlorite) [will readily produce a molecular alteration when in contact with certain chemicalsimaterials (see reactivity data.)]
CAS NO. 7681-52-9 FORMULA: NaOCI MOLECULAR WEIGHT: 74A5
- PPING NAME AND HAZARDOUS CLASS-(DOT): Hypochloritesolution, 8 Corrosive Material, UNI791, PG 111, RQ (Sodium Hypochlorite)
F: Vertex Chemical Corporation, 3101 Carondelet Road, Dupo, IL 62239; Vertex Chemical Corporation, 2825 Channel Ave, Memphis TN 38113; Vertex Chemical Corporation 2619 Camanche Industrial Park Drive, Carnanche, IA 52730:: Sodium hypochlorite registered with NSF International, Maximum Use Dosages are 175 mg/L (CSS-6), 105 mg/L (CSS-e0 and VERTEX CONCENTRATE), and 84 mglL (CSS-12).
SECTION I. EMERGENCY RESPONSE INFORMATION HEALTH HAZARDS: See Page 2,Section VI FIRE OR EXPLOSION: See Page 3,Section IX IMMEDIATE PRECAUTIONS: WASH FROM EYES: See Page 2,Section V, First Aid, See Page 3,Section X, Hazardous Reactivity-1 See Page 4,Section XI, Spill, Leak & Disposal Procedures SPILLS OR LEAKS: See Page 4,Section XI, Spill, Leak & Disposal Procedures FIRST AID: See page 2,Section V SECTION11ll. COMPONENTS EXPOSURE LIMITS, MG/M3 OSHA i ACGIH OTHER' roMP(WINT CACNAQ 0/hy weipht P1.I mV I AMT A7Al SODIUM HYPOCHLORITE 7681-52.9 6-16 'NONE NONE NONE CORROSIVE/O. XIDIZER SODIUM CHLORIDE 7647-14-5 5-13 NONE NONE NONE NONE.
SODIUM HYDROXIDE 1310-73-2 0.2-4.0 2MG/M3 2MGIM3 NONE -- CORROSI IVE WATER 7732-18-5 BALANCE NONE NONE NONE NONE i . ...
Page 1 of 4
- n Vertex Chemical Corporation MATERIAL SAFETY DATA SHEET I I PRODUCT NAME: SODIUM HYPOCHLORITE 6-16% DATE: 01/21/04 I
_ TION IV. PHYSICAL PROPERTIES Concentration 6% NaOCI l1%NaOCI 13% NaOCI Molecular Weight 74.45 74.45 74.45 Specific Gravity 1.115 1.173 1.211 pH 12.31 12.95 13.05 Freeze Point, IF 200 -1op -12 0F 0
Boiling Point, F 219 F0 222 F 225 0F Viscosity @77 0F (centistokes) 1.10 1.53 1.83 Vapor Pressure @ 50'C (KPa) 6 6.2 7.5 Vapor Pressure 055 0C (KPa) 7.63 7.63 9.34 Vapor Density NA NA NA Evaporation Rate NA NA NA Solubility Soluble in Water Same as 6% Same as 6%
Color Clear Yellow Same as 6% Same as 6%
Odor Pungent Chlorine Bleach OdorSame as 6% Same as 6%
Appearance Banana-Colored Clear Liquid Same as 6% Same as 6%
I SECTION V. FIRST AID MEASURES I If Inhaled: Remove to fresh air. Give artificial respiration if not breathing. Administer Oxygen if breathing is difficult. Get immediate medical attention.
jLCase Of Eye
Contact:
Immediately flush eyes thoroughly and continue to repeatedly flush eyes with constantly running water for 15 minutes, lifting the e and lower eyelids occasionally. Get immediate medical attention.
In Case Of Skin
Contact:
Immediately flush skin thoroughly and continue to repeatedly flush skin with constantly running water for 15 minutes. Remove contaminated clothing and shoes; wash before reuse. Get immediate medical attention.
If swallowed: Do not induce vomiting. If conscious, give water or milk, or milk of magnesia. Do not give baking soda or acid antidotes. Do not give anything by mouth to an unconscious or convulsing person. Get immediate medical attention.
I SECTION VI. HEALTH HAZARD INFORMATION Primary Routes Of Exposure: Skin or eye contact, inhalation. Avoid eye or skin contact, inhalation.
Signs And Symptoms Of Exposure:
Inhalatnn Inhalation of fumes or mists causes respiratory tract irritation and irritation of mucous membranes. If sodium hypochlorite is mixed with ammonia or other chemicals, evolution of chlorine or chlorine based compounds results. These gases can produce pulmonary edema.
Never mix with any other chemicals.
Fye Cnntsart Liquid and mists may severely irritate or damage the eyes.
'kin Cnnita: The liquid will irritate the skin, causing redness and possibly inflammation, or chemical bums to broken skin.
Swnalnwed: Mists and liquid are extremely corrosive to the mouth and throat, mucous membranes and stomach. Swallowing the liquid burns the tissues, causes severe abdominal pain, nausea, vomiting, circulatory collapse, confusion, delirium, coma, and collapse. Swallowing large quantities can cause death.
Chronic Effects of Exposure: Irritation effects increase with strength of solution and time of exposure. Prolonged or repeated exposure can lead to constant irritation of eyes and throat. Prolonged or repeated contact may cause dermatitis and sensitization.
)cal Conditions Generally Aggravated By Exposure: Asthma or other pre-existing lung/respiratory illnesses.
Page 2 of 4
Vertex Chemical Corporation
- - Al tI AL SAIETIY IJATA SllIEL I l LPRODUCT NAME: SODIJUM HYPOCHLORITE 6-16% - DATE: 01/21/04 CrlON VII. TOXICITY DATA Oral: For5%SolutionRatLD50 - 13 G/KG Dermal: RatLDSO >3.0G/KG For 12.5% solution rat LD50 = 5 G/KG -' Inhalaton: No Data Available"-
Carcinogenicity: This material is not considered to be a carcinogen by the National Toxicology Program, the International Agency for Research of Cancer, or the Occupational Safety and Health Administration. '
Other Data: None SECTIONVIII. PERSONALPROTECTION Ventilation: Local mechanical exhaust ventilation to minimnize exposure to vapors or mist at the point of use.
Respiratory Protection: Wear a NIOSH-approved respirator appropriate for the vapor or mist concentration at the point of use- Appropriate respirators may be a full face-piece or a half mask air-purifying cartridge respirator equipped for acid gases/mists, a self-contained breathing apparatus in the pressure demand mode, or a supplied-air respirator..
Eye Protection: Chemical goggles and full face-shield unless a fuil face-piece respirator is also worn. It is generally recognized that contact lenses should not be worn when working with chemicals because contact lenses may contribute to the severity of an eye injury. In a laboratory situation, where rinning water is immediately available and an eyewash nearby, for handling of sixteen (16)ounces or less of product, safety glasses are acceptable eye protection Protective Clothing: Long-sleeved shirt, trousers, rubber boots, rubber gloves, and rubber apron. In a laboratory situation, where running water is immediately available and an eyewash nearby, for handling of sixteen (16) ounces or less of product, rubber gloves can be omitted. Hands should be rinsed immediately until slick feeling is gone from skin if sodium hypochlorite exposure occurs.
Other Protective Measures: An eaewash and safety shower should be nearby and ready for use.
SECTION IX. FIRE AND EXPLOSION INFORMATION Flash Point, Deg F: 'Not Flammable Flammable Limits In Air, % AutoignitionTemperature: N/A Method Used: N/A Lower N/A Upper NIA nmable Limits (% by volume): Lower Explosive level: LEL N/A Upper Explosive Limit. UEL NiA tinguishing Media: This material is not combustible. Use extinguishing media appropriate for surrounding fire.
Special Fire Fighting Procedures: Fire fighters should wear self-contained breathing apparatus and full protective clothing. Use water spray to cool nearby containers and structures exposed to fire.
Unusual fire and explosion hazards: Containers of this 'materialcan explode as oxygen is liberated under high heat or fire conditions. Toxic fumes similar to chlorine gas are liberated by contact with acids, ammonia, some detergent cleaners, organic materials, oxidizing agents and some reducing agents. See Special Precautions Section for TLV of elemental chlorine. Highly exothermic reactions with organic materials and oxidizable materials may cause fires inadjacent, heat sensitive materials: Do not store where contact may result with organic or oxidizable materials, e.g., sawdust, paper waste, or others.
NFPA Rating: Hypochlorite is not rated by the National Fire Protection Association. Vertex, with the help of the Chlorine Institute, has assigned the following estimated rating based on NFPA standards: '
Health -2 ' Reactivit '-I Fire-o Snecific Hazard - Corrosive SECTION X. HAZARDOUS REACTIVITY Stability: Stable Polymerization: Will Not Occur Stability decreases with increased concentration, heat, light exposure,-decrease in pH and contamination with heavy metals such as nickel, cobalt, copper and iron. DECREASE IN pH AND/OR CONTAMINATION CAN RESULT IN EVOLUTION OF CHLORINE (TOXIC) GAS.
CONDITIONS TO AVOID: EXCESSIVE HEAT, EXPOSURE TO LIGHT, REDUCED ALKALINITY, AND CONTAMINATION OF ANY KIND.
REDUCED ALKALINITY OR CONTAMINATION CAN RESULT IN EVOLUTION OF CHLORINE (TOXIC) GAS.
STRONG OXIDIZING AGENT: in contact with the following incompatible, oxidizable materials, chemical reaction will occur allowing hazardous gases to evolve.
Incompatible Materials To Avoid: Ether, ammonia, acids, oxidizing agents, reducing agents, oxidizable or combustible materials such as wood, cloth or I organic materials, heavy metals such as iron, copper, magnesium, aluminum, tin, manganese, zinc, chromium, nickel, and their alloys. DO NOT MIX THIS PRODUCT WITH ANY OF THE FOREGOING OR HAZARDOUS GASES CAN RESULT.'
- rdous Decomposition Products
Page 3 of 4
Vertex Chemical Corporation MATERIAL SAFETY DATA SHEET I PRODUCT NAME: SODIUM HYPOCHLORITE 6-16% DATE: 01/21/04 tTION Xl. SPILL LEAK AND DISPOSAL PROCEDURES I Action To Take For Spills Or Leaks: Wear alkali-resistant slicker suit and complete protective equipment including goggles, rubber gloves, rubber boots, and a self-contained breathing apparatus in the pressure demand mode or a supplied-air respirator. If the spill or leak is small, a full face-piece air-purifying cartridge respirator equipped with acid gases/mists filters may be satisfactory. In any event, always wear eye protection. For small spills or drips, mop or wipe up and dispose of in DOT-approved waste containers. For large spills, contain by diking with soil or other non-combustible absorbent material and dispose according to federal or local regulations. Keep non-neutralized material out of sewers, storm drains, surface waters, and soil. This product is very toxic to aquatic life.
Comply with all applicable governmental regulations on spill reporting, and handling and disposal of waste.
Disposal Methods: Dispose of contaminated product and materials used in cleaning up spills or leaks in a manner approved for this material. Consult appropriate federal, state and local regulatory agencies to ascertain proper disposal procedures.
NOTE: Empty containers can have residues, gases and mists and are subject to proper waste disposal, as above.
SECTION XII. SPECIAL PRECAUTIONS Storage and Handling Precautions: Store in a cool, dry, well-ventilated place away from incompatible materials. Keep container tightly closed and vented when not in use.
Do not use pressure to empty container. Wash thoroughly after handling. Do not get in eyes, on skin, or on clothing. Store in original containers only at temperatures below 85 Degrees Fahrenheit. Do not store near acids, oxidizable materials, or organics. Do not store on wooden floors.
Repair and Maintenance Precautions: None ATTENTION: When empty, the container may still be hazardous. Because containers, even after they have been emptied, still retain product residues (vapor, liquid or solid), all labeled hazard precautions MUST BE OBSERVED. If "emptied" product containers of 110 gallons or greater volume are to be j ipped, DOT requires the containers be triple rinsed (or equivalent) to remove any residue and DOT placards be removed or covered with plain placards Irre they can be shipped as empty containers.
Other Precautions: Containers, even those that have been emptied, will retain product residue and vapors. Always obey hazard warnings and handle empty containers as if they were full. Do not mix or contaminate this product with ammonia, acids, hydrocarbons, alcohols, ethers, reducing agents, oxidizers, cleaning agents or other products which may liberate chlorine or other toxic vapors. For elemental chlorine, the OSHA PEL is .5 PPM TWA and I PPM STEL; the ACGIH TLV is I PPM TWA, with a STEL of 3 PPM. This product degrades with age. Use it within one month of receipt. It is a violation of federal law to use this product in a manner inconsistent with its labeling. EPA pesticides regulations apply, and EPA registration is required when used for disinfecting or sanitation purposes. THIS PRODUCT IS LISTED ON THE TOXIC SUBSTANCES CONTROL ACT (TSCA)
INVENTORY OF CHEMICAL SUBSTANCES.
SECTION XIII. REGULATORY INFORMATION TSCA Inventory Status: Listed on inventory. SARA - 313 Listed Chemicals: No RCRA Hazardous Waste No.: N/A CERCLA: Yes ReportableQuantity: 100pounds Vertex sodium hypochlorite is regulated under many federal and local laws, including OSHA, TSCA, RCRA, FIFRA, CERCLA and EPCRA. It is NOT on the list of Extremely Hazardous Substances, 40 CFR Part 355 Appendix A, nor on the "337 Toxic Chemicals" list, 40 CFR 372.
SECTION XIV. NOTICE Vertex Chemical Corporation ("Vertex") expressly disclaims all express or implied warranties of merchantability and fitness for a particular purpose, with respect to the product or information provided herein.
All information appearing herein is based upon data obtained from the manufacturer and/or recognized technical sources. While the information is believed to be accurate, Vertex makes no representations as to its accuracy or sufficiency. Conditions of use are beyond Vertex's control, and, therefore, users are responsible to verify this data under their own operating conditions to determine whether the product is suitable for their particular purposes, and they assume all risks of their use, handling, and disposal of the product, or from the publication or use of, or reliance upon, information contained herein.
information relates only to the product designated herein, and does not relate to its use in combination with any other material or in any other process.
END OF NISDS.
Page 4 of 4
BiohidTm 401 TETRA isMSDS Sheet complies with the style format specified by ANSI Z400 1-1993 SECTION 1: CHEMICAL PRODUCT - COMPANY IDENTIFICATION TETRA Technologies, Inc. (218) 367-1983 25025 1-45 North (800) 327-7817.
The Woodlands, Texas 77380 (800) 424-9300 - CHEMTREC (24 Hour Emergency Response)
(800) 222-1222 POISON CONTROL SUBSTANCE: Sodium Bromide Solution TRADE NAMESISYNONYMS: .- 'BioRid"' 40i, Liquid Sodium Bromide, NaBr.
CHEMICAL FAMILY: Inorganic Salt MSDS CREATION DATE: 03 AUG 98 MSDS REVISION DATE: 21 FEB 03 SECTION 2: COMPOSITION, INFORMATION ON INGREDIENTS COMPONENTS CAS NUMBER RTECS NUMBER PERCENTAGE Sodium Bromide 7647-156 - VZ3150000 - 1-46%-
Water 7732-18-5 54-99%
PROBABLE CONTAMINANT: Sodium Chloride.
SECTION 3: HAZARDS IDENTIFICATION '
, NFPA RATINGS: (SCALE 04): HEALTH=1 FIRE=O REACTIVITY=0 EMERGENCY OVERVIEW: Odorless, clear liquid. Avoid contact with eyes, skin and clothing. Keep container tightly closed. Wash thoroughly after handling. Use only with adequate ventilation.
POTENTIAL HEALTH EFFECTS:
INHALATION: May cause irritation.-
SKIN, EYE CONTACT: May cause Irritation.
INGESTION: May cause vomiting,-digestive disorders, high blood pressure, headache, kidney damage, paralysis, and coma.
CARCINOGEN STATUS:
OSHA: No NTP: No IARC: No SECTION 4: FIRST AID MEASURES INHALATION: Remove from exposure area to fresh air. Get medical attention immediately.
SKIN CONTACT: Remove contaminated clothing and shoes. Wash affected area with soap and large amounts of water. Get medical attention, if needed.
EYE CONTACT: Flush eyes with large amounts of water. Get medical attention immediately.
INGESTION: If large amount is swallowed, or adverse affects occur, get medical attention.
NOTE TO PHYSICIAN: Sodium chloride, oral, intravenous, diuretics.
SECTION 5: FIRE FIGHTING MEASURES FIRE AND EXPLOSION HAZARD: Negligible fire hazard.
EXTINGUISHING MEDIA: Use extinguishing agent appropriate for surrounding fire.
FIREFIGHTING: Move container from fire area if possible. Avoid breathing vapors or dust; keep upwind.
HAZARDOUS COMBUSTION PRODUCTS: May generate bromine'gas in the presence of strong oxidizing agents.
TETRA Technolcgles, Inc.
Pagelof3 DATA SHEET SAFETY DATA MATERIAL SAFETY SHEET I - Page I of 3 TETRA Te6n01091e3, Inc.
BioRid m 401 TETRA rhis MSDS Sheet complies with the style format specified by ANSI Z400 1-1993 SECTION 6: ACCIDENTAL RELEASE MEASURES OCCUPATIONAL SPILL:
Do not touch spilled material. Stop leak if you can do it without risk. For small spills, take up with sand or other absorbent material and place into containers for later reclamation or disposal. For larger spills, dike far ahead of spill for later disposal. Keep unnecessary people away. Isolate hazard area and deny entry.
SOIL SPILL:
Dig holding area such as lagoon, pond or pit for containment. Dike flow of spilled material using soil or sandbags or concrete. Use cement powder or fly ash to absorb liquid mass. Neutralize spill with suitable agent.
WATER SPILL:
Add suitable agent to neutralize spilled material to pH 7. Use mechanical dredges or lifts to extract immobilized masses of pollution and precipitates.
SECTION 7: HANDLING AND STORAGE Observe all federal, state, and local regulations when storing this liquid. Store in a tightly closed container. Store away from incompatible substances.
SECTION 8: EXPOSURE CONTROLS, PERSONAL PROTECTION EXPOSURE LIMITS: No occupational exposure limits established by OSHA/ACGIH/NIOSH.
VENTILATION: Provide local exhaust ventilation system.
EYE PROTECTION: Wear safety glasses with splash shields or safety goggles/shield.
) CLOTHING AND GLOVES: Wear appropriate chemical resistant clothing and gloves.
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES DESCRIPTION: Odorless, clear liquid.
MOLECULAR FORMULA: NaBr in water.
MOLECULAR WEIGHT: 102.90 for pure sodium bromide..
SPECIFIC GRAVITY: 1.01 -1.53 @ 680 F (20 0 C)
WATER SOLUBILITY: Miscible with water in all proportions.
pH: 5.5 - 8.5 @ 5% solution SOLVENT SOLUBILITY: Slightly to moderately soluble in alcohol.
SECTION 10: STABILITY AND REACTIVITY REACTIVITY: Stable under normal temperature and pressures.
INCOMPATIBILITIES: Strong oxidizing agents.
HAZARDOUS DECOMPOSITION: May generate bromine gas in the presence of strong oxidizing agents.
POLYMERIZATION: Will not occur under normal temperatures and pressures.
SECTION 11: TOXICOLOGICAL INFORMATION TOXICITY DATA: No data are available for Sodium Bromide Solution.
The following toxicity data is for Sodium Bromide (100%):
TDLO: 3,150 mg/kg, oral, 6 weeks-continuous, rat LD50: 7,000 mg/kg, oral, mouse LDLO: 5,020 mg/kg, subcutaneous, mouse II Reproductive effects data - See Registry of Toxic Effects of Chemical Substances (RTECS) file.
CARCINOGEN STATUS: None.
TETRA Technologies, Inc.
Page 2 of 3 MATERIAL DATA SHEET SAFETY DATA MATERIAL SAFETY SHEET Page 2of 3 TETRA Technologies, Inc.
BioRid"'m 40i TIETRA rhis MSDS Sheet complies with the style format specified by ANSI Z400 1-1993 SKIN CONTACT, EYE CONTACT: No data available.
INHALATION: Dusts may cause mucous membrane irritation.
INGESTION: Moderately toxic by ingestion. Acute/Chronic exposure may cause gastrointestinal, skin and nervous system irritation.
SECTION 12: ECOLOGICAL INFORMATION No data available.
SECTION 13: DISPOSAL INFORMATION:
Observe all federal, state and local regulations when disposing of this liquid.
SECTION 14: TRANSPORT INFORMATION DOT Shipping Name-ID Number Non-regulated.
SECTION 15: REGULATORY INFORMATION TSCA STATUS: Yes SARA SECTION 302, 304, 313: None SARA SECTIONS 311/312 HAZARD CLASSIFICATION. None EINECS STATUS: Yes
_ CERCLA SECTION 103: No CALIFORNIA PROPOSITION 65: No SECTION 16: OTHER INFORMATION Individuals handling this product should be Informed of the recommended safety precautions and should have access to this information.
This information relates to the specific product designated and may not be valid for such product used in combination with any other materials or in any other processes. Such information is to the best of our knowledge and belief, accurate and reliable as of the date compiled. However, no representation, warranty or guarantee is made as to its accuracy, reliability, or completeness. It is the users' responsibility to satisfy themselves as to the suitability and completeness of such information for their own particular use. We do not accept liability for any loss or damage that may occur from the use of this information nor do we offer warranty against patent infringement.
TETRA Technologies, Inc. reserves the right to refuse shipment of this product to any consumer who fails to demonstrate the ability to consistently handle and use it safely and in compliance with all applicable laws, rules and regulations. Such demonstration may require on-site inspection of any or all storage, processing, packaging and other handling systems that come in contact with it.
Customers are responsible for compliance with local, state and federal regulations that may be pertinent in the storage, application and disposal of this product.
TETRA Technologies, Inc.
DATA SHEET Page 3of 3 MATERLL SAFETY MATERIAL SAFETY DATA SHEET Page 3 of 3 TETPA Technologies, Inc.
MATERIAL SAFETY DATA SHEET PRODUCT: SODIUM BISULFITE SOLUTION SECTION 1 - MANUFACTURER INFORMATION MANUFACTURER/DISTRIBUTOR:
PVS CHEMICALS, INC. (Illinois) - . l 12260 S. Carondolet Chicago, Illinois 60633 (773) 933-8800 (for product information)
(773) 933-0957 (fax)
- FOR TRANSPORTATION EMERGENCY ONLY, DAY OR.NIGHT, CALL***
- CHEMTREC, 1-800-424-9300***
PREPARATION/REVISION DATE: 3-1-96 CONTACT: Manager of Environmental Affairs SECTION 2 -- PRODUCT IDENTITY/HAZARDOUS INGREDIENTS INFORMATION Product name: Sodium Bisulfite Solution Chemical name/synonyms: Sodium Bisulfite, Aqueous Solution; Sodium Acid Sulfite; Sodium Hydrogen Sulfite Chemical formula: NaHSO.
CAS number: 7631-s- - - - . .
Product Code:
HAZARDOUS INGREDIENTS: Yes rno nent CAS No 2-2h w Sodium Bisulfite 7631-90-5 . 27-42%-
Exposure limits:
ACGIH TLV:5 mg/rn, 8-hr TWA Other: no information : -
NON-HAZARDOUS INGREDINTS CASF No by wt.
Water- 7732-18-5 -- Balance -
OSHA 29 CFR 1910.1200 EVALUATION:.Hazardous 1 4 . . .
1 MSDS, SODIUM BISULFITE: PAGE 1 OF 5
,,
- t, i')
- EN SECTION 3 -- PHYSICAL/CHEMICAL CHARACTERISTICS APPEARANCE AND ODOR: Clear, pale yellow liquid with an odor of sulfur dioxide.
BOILING POINT: >100 0C MELTING POINT: no information VAPOR PRESSURE (REID): 78 mm Hg @ 37.7 'C VAPOR DENSITY (AIR = 1): no information SPECIFIC GRAVITY (WATER = 1): 1.26 to 1.37 @ 25 0C PERCENT VOLATILE BY VOLUME (%) @ 55 GC: no information EVAPORATION RATE (BUTYL ACETATE = 1): <1 pH: 3 to 4 SOLUBILITY IN WATER: Complete SECTION 4 -- FIRE AND EXPLOSION HAZARD DATA FLASH POINT (CLOSED CUP METHOD): N/A FLAMMABLE LIMITS IN AIR, % BY VOLUME: N/A LOWER: N/A UPPER: N/A EXTINGUISHING MEDIA: Use water, foam, dry chemical, or CO2 fire extinguishers as appropriate to fight surrounding fires.
SPECIAL FIRE FIGHTING PROCEDURES: Wear protective clothing and protective equipment as appropriate for surrounding fire. Keep 3 ___gtanks or contairnzrs carl. -'-ad with atc-.* *.ear se'-- --- - i" contained breathing apparatus for major exposure when release of SO2 gas is possible.
UNUSUAL FIRE AND EXPLOSION HAZARDS: Releases sulfur dioxide gas when heated.
SECTION 5 -- REACTIVITY DATA STABILITY: Stable HAZARDOUS POLYMERIZATION: will not occur INCOMPATIBILITY (CONDITIONS AND MATERIALS TO AVOID): Material is stable when properly handled. Reacts with oxidizing agents and with heat to form toxic sulfur dioxide (SO2 ) gas. Avoid sources of heat.
HAZARDOUS DECOMPOSITION PRODUCTS: Decomposes with heat or oxidizing agents to release toxic SO2 gas.
MSDS, SPE4 SODIUM BIStJLFITE: PAGE 2 OF 5
0 SECTION 6 -- HEALTH HAZARD DATA PRIMARY ROUTES OF ENTRY: Inhalation, ingestion, direct contact HEALTH EFFECTS (ACUTE AND CHRONIC):
INHALATION: Inhalation will- irritate and may damage -upper respiratory tract and lungs.
INGESTION: May irritate gastrointestinal tract. Concentrated solutions may cause burns to the digestive tract.
DIRECT-CONTACT: Contactwith liquid, mist, or vapor can cause immediate-irritation or'mild corrosive burns to all human tissue.
EYE 'CONTACT: Contact- with :eyes may result in permanent damage.-
CARCINOGENS (NTP, IARC, OR OSHA): No MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: None known.
SECTION 7 -- FIRST AID INHALATION: Remove victim to fresh air. If not breathing, perform artificial respiration and get medical attention.-
INGESTION: Drink copius quantities of water or milk. -Do not.
induce vomiting. Get immediate medical attention.
DIRECT CONTACT: Wipe -off, excess. Flush immediately with
__ to.. few~ >e 'f.t. 15 minutes while .removing _ contaminated clothing. Get immediate medical attention. Wash clothing before re-use. Destroy contaminated shoes.
DIRECT EYE CONTACT: Flush immediately with water for at-least 15 minutes. Forcibly hold. eyelids apart to ensure complete-irrigation of eye/lid tissue.' Get immediate medical attention.
SECTION 8 -- PRECAUTIONS FOR SAFE STORAGE, HANDLING AND USE PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: Keep storage tanks and contpirers out of the-sun and away form sources. of heat and ignition to prevent decomposition and release of S02 gas.
Containers should be kept tightly closed to prevent oxidation of the product. In cold weather, store product at temperatures above 50 0 F to avoid crystallization. Do not strike containers or fittings with tools or hard objects.. Emptied container retains vapor and product residue.
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Contain spill in order to prevent contamination of sewage system or waterway. If possible, neutralize on a dry basis with sodium carbonate or sodium bicarbonate; then flush with water in accordance with applicable regulations.
WASTE DISPOSAL METHODS: Dispose of spilled, neutralized, or waste product, contaminated soil and other contaminated materials in licensed landfill or treatment facility in accordance with all 0 MSDS, SODIUM BISULFITE: PAGE 3 OF 5
IL local, state and federal regulations. 0 SECTION 9 -- EXPOSURE CONTROL INFORMATION VENTILATION: Provide ventilation to control exposure levels below airborne exposure limits. Use local exhaust ventilation.
Reference NFPA Standard 91 for design of exhaust systems.
RESPIRATORY PROTECTION: Use NIOSH/MSHA approved, full-face respirator with canister approved for sulfuric acid/sulfur trioxide vapor and mist. Consult respirator manufacturer to determine appropriate equipment. If concentrations are high or unknown, use self-contained breathing apparatus.
PROTECTIVE GLOVES: Wear impervious rubber gloves.
EYE PROTECTION: Wear splash proof chemical safety goggles.
Eyewash fountains recommended in all storage and handling areas.
Do not wear contact lenses.
OTHER PROTECTIVE EQUIPMENT: Wear protective clothing to prevent skin contact. Full face shild and rubber footwear should be used.
Acid resistant hood and full body suit recommended. Safety shower recommended in all storage and handling areas.
T-ORK/HYCI2N-handling.
TRACTTCES: A7.-:A Wreathing mist. UTSe .1--ore'I .4amr 0
OTHER PRECAUTIONS: None SECTION 10 -- REGULATORY INFORMATION DOT:
Proper shipping name: Bisulfites, inorganic, aqueous solutions, N.O.S. (Sodium Bisulfite, solution)
Haz:rd Class: 8 UN Number: UN 2693 Packing Group: III SARA TITLE III HAZARD CLASSIFICATIONS:
ACUTE: - No CHRONIC: No FIRE: No REACTIVITY: No PRESSURE: No MSDS, SODIUM BISULFITE: PAGE 4 OF 5
OTHER RATINGS:
(hazard index key: 4=severe, 3-serious, 2=moderate, 1=slight, 0=minimal)
HMIS: Health=l, Flammability-0, Reactivity-1, CORROSIVE (COR)
NFPA: Health=l, Flammabilitya0, Reactivity-i OTHER INFORMATION:
CERCLA RQ: 5000 lbs.
WHMIS: lt TOXICITY:
Corrosive.
96 hr LC,, (mosquito/fish): 240 ppm MSDS, SODIUM BISULFITE: PAGE 5 OF 5
SODIUM POLYPHOSPHATE GLASSY SOLUTION httpl/www.rhodia-phosphates.com/msds/000008002000010001 0056E00017.HTM Rhodia Material Safety Data Sheet SODIUM POLYPHOSPHATE GLASSY SOLUTION.
Date Prepared: 2117/00 Supersedes Date: 2/27/96 ODC ADCOPI, DESRPI N. ~
RHODIA INC.
RHODIA SPECIALTY PHOSPHATES CN 7500 259 Prospect Plains Road Cranbury NJ 08512-7500 Emergency Phone Numbers:
FOR EMERGENCIES INVOLVING A SPILL, LEAK, FIRE, EXPOSURE OR ACCIDENT CONTACT: CHEMTREC (800-424-9300 within the United States or 703-527-3887 for international collect calls) or Rhodia CAERS (Communication and Emergency Response System) at 800-916-3232.
For Product Information:
(800) 243-5052 Chemical Name or Synonym:
SODIUM POLYPHOSPHATE SOLUTION 2.OMPSITION/INFORMATION ON INGREDINS CompnentOSHA Component - CAS Reg Number Hazad Percentage SODIUM POLYPHOSPHATES 68915-31 -1 N .30 - 50 ALTERNATE CAS # (SODIUM HEXAMETAPHOSPHATE) 10124-56-8 N WATER *7732-18-5 N 50 - 70 3~jAZ RDS IDENTIFICTI.
A. EMERGENCY OVERVIEW::
Physical Appearance and Odor:
0colorless I liquid, odorless.
Warning Statements:
Based on currently available data, this product does not meet the regulatory definition of a hazardous substance.
However, good industrial hygiene practices should be' used in handling it.
0311912003 8:47 AIN
--_1--
SODIUM POLYPHOSPHATE GLASSY SOLUTION http:H/www.rhodia-phosphates.comnmsds/000008002000010001 0056E000 17.HTM B. POTENTIAL HEALTH EFFECTS:
Acute Eye:
May cause irritation.
Acute Skin:
May cause slight transient irritation, on prolonged contact.
Acute Inhalation:
Low acute inhalation toxicity.
Acute Ingestion:
Ingestion of large quantities may cause nausea, vomiting, diarrhea, abdominal cramps, decreased blood pressure, decreased heart rate, coma.
Chronic Effects:
This product does not contain any ingredient designated by IARC, NTP, ACGIH or OSHA as probable or suspected human carcinogens.
- 4. FIRST AIDZ MEASURES<<m FIRST AID MEASURES FOR ACCIDENTAL:
Eye Exposure:
Hold eyelids open and flush with a steady, gentle stream of water for at least 15 minutes. Seek medical attention if irritation develops or persists or if visual changes occur.
Skin Exposure:
In case of contact, immediately wash with plenty of soap and water for at least 5 minutes. Seek medical attention if irritation develops or persists. Remove contaminated clothing and shoes. Clean contaminated clothing and shoes before re-use.
Inhalation:
If respiratory irritation or distress occurs remove victim to fresh air. Seek medical attention if respiratory irritation or distress continues.
Ingestion:
If victim is conscious and alert, give 2-3 glasses of water to drink and induce vomiting by touching back of throat with a finger. Do not induce vomiting or give anything by mouth to an unconscious person. Seek immediate medical attention. Do not leave victim unattended. Vomiting may occur spontaneously. To prevent aspiration of swallowed product, lay victim on side with head lower than waist. If vomiting occurs and the victim is conscious, give water to further dilute the chemical.
MEDICAL CONDITIONS POSSIBLY AGGRAVATED BY EXPOSURE:
Inhalation of product may aggravate existing chronic respiratory problems such as asthma, emphysema or bronchitis. Skin contact may aggravate existing skin disease.
NOTES TO PHYSICIAN:
All treatments should be based on observed signs and symptoms of distress in the patient. Consideration should be given to the possibility that overexposure to materials other than this product may have occurred.
Ingestion of large quantities of phosphate salts (over 1.0 grams for an adult) may cause an osmotic catharsis resulting in diarrhea and probable abdominal cramps. Larger doses such as 4-8 grams will almost certainly cause these effects in everyone. In healthy individuals most of the ingested salt will be excreted in the feces with the 2 of 9 03/19/2003 8:47 Al
SODIUM POLYPHOSPHATE GLASSY SOLUTIJON http:llwww.rhodia-phosphates.comnmsds/0000080020000100010056E00017.HTM diarrhea and, thus, not cause any systemic toxicity. Doses greater than 10 grams hypothetically may cause systemic toxicity. Treatment should take into consideration both anionic and cation portion of the molecule. The following treatments should be considered for the specific group(s) of phosphate salts found in this product:
--All phosphate salts, except calcium salts, have a hypothetical risk of hypocalcemia, so calcium levels should be monitored.
-Ammonium salts have a hypothetical risk of ammonia toxicity. In addition to calcium levels, ammonia and phosphate levels should be monitored.
--Potassium salts have a hypothetical risk of hyperkalemia which can cause cardiac arrhythmia. In addition to-calcium levels, potassium and phosphate levels should be monitored. Also consider continuous EKG monitoring to detect hyperkalemia.
--Sodium salts have a hypothetical risk of hypernatremia. In addition to calcium levels, sodium and phosphate levels should be monitored.
FIRE HAZARD DATA:
Flash Point:
Not Applicable Extinguishing Media:
Not combustible. Use extinguishing method suitable for surrounding fire. -
Special Fire Fighting Procedures:
Firefighters should wear NIOSH/MSHA approved self-contained breathing apparatus and full protective clothing.
Unusual Fire and Explosion Hazards:
Not combustible.
Hazardous Decomposition Materials (Under Fire Conditions):
oxides of phosphorus oxides of sodium
_AEASURESAN M ____- _ )
_so > w s ml .___ .
Evacuation Procedures and Safety:
Wear appropriate protective gear for the situation. See Personal Protection information in Section 8.
Containment of Spill:
Dike spill using absorbent or impervious materials such as earth, sand or clay. Follow procedure described below under Cleanup and Disposal of Spill.
Cleanup and Disposal of Spill:
Absorb with an inert absorbent. Sweep up and place in an appropriate closed container (see Section 7: Handling and Storage). DO NOT RETURN MATERIAL TO ITS ORIGINAL CONTAINER.
Environmental and Regulatory Reporting:
3 of 9 03/19/2003 8:47 AD
SODIUM POLYPHOSPHATE GLASSY SOLUTION http://www.rhodia-phosphates.comlmsds/0000080020000100010056E000 17.HTM Prevent material from entering public sewer system or any waterways.
Minimum/Maximum Storage Temperatures:
Not Available Handling:
Keep containers closed when not being used.
Storage:
Store in an area that is cool, dry.
- 8. EXPOSURECONTROLS/PERSONALPROTECTIO Introductory Remarks:
These recommendations provide general guidance for handling this product. Because specific work environments and material handling practices vary, safety procedures should be developed for each intended application. While developing safe handling procedures, do not overlook the need to clean equipment and piping systems for maintenance and repairs. Waste resulting from these procedures should be handled in accordance with Section 13:
Disposal Considerations.
Assistance with selection, use and maintenance of worker protection equipment is generally available from equipment manufacturers.
Exposure Guidelines:
No exposure limits were found for this product or any of its ingredients.
Engineering Controls:
Where engineering controls are indicated by use conditions or a potential for excessive exposure exists, the following traditional exposure control techniques may be used to effectively minimize employee exposures: local exhaust ventilation at the point of generation.
Respiratory Protection:
When respirators are required, select NIOSH/MSHA approved equipment based on actual or potential airborne concentrations and in accordance with the appropriate regulatory standards and/or industrial recommendations.
Eye/Face Protection:
Eye and face protection requirements will vary dependent upon work environment conditions and material handling practices. Appropriate ANSI Z87 approved equipment should be selected for the particular use intended for this material.
It is generally regarded as good practice to wear a minimum of safety glasses with side shields when working in industrial environments.
tSkin Protection:
Skin contact should be minimized through use of gloves and suitable long-sleeved clothing (i.e., shirts and pants).
Consideration must be given both to durability as well as permeation resistance.
Work Practice Controls:
Personal hygiene is an important work practice exposure control measure and the following general measures 4of 9 03/19/2003 8:47 AN,
SODIUM POLYPHOSPHATE GLASSY SOLUTI]ON Sttp://www.rhodia-phosphates.comI/msds/00000800200001 0001 0056E00017.HTM should be taken when working with or handling this material:
(1) Do not store, use, and/or consume foods, beverages, tobacco products, or cosmetics in areas where this material is stored.
(2) Wash hands and face carefully before eating, drinking, using tobacco, applying cosmetics, or using the toilet.
(3) Wash exposed skin promptly to remove accidental splashes of contact with this material.
- .9,',
f-IC HEMICA PRO ~ t Physical and Chemical properties here represent typical properties of this product. Contact the business area using the Product Information phone number in Section 1 for its exact specifications.
Physical Appearance:
colorless / liquid.
Odor:
odorless.
pH:
5.5 to 8 at I wlwt%/1.
Specific Gravity:
1.5 at 20 C (68 F).
Water Solubility:
miscible Melting Point Range:
Not Available Boiling Point Range:
Not Available Vapor Pressure: -
Not Available Vapor Density: . -
Not Available Chemical Stability:
This material is stable under normal handling and storage conditions described in Section 7.
t Conditions To Be Avoided:
none known Materials/Chemicals To Be Avoided:
none known 5 of9 0311912003 8:47 AN
- ]l -
SODIUM POLYPHOSPHATE GLASSY SOLUTION http://www.rhodia-phosphates.con/msds/000008002000010001 0056E000 17.HTM The Following Hazardous Decomposition Products Might Be Expected:
Decomposition Type: thermal oxides of phosphorus oxides of sodium Hazardous Polymerization Will Not Occur.
Avoid The Following To Inhibit Hazardous Polymerization:
not applicable TOXICOLOGICAL IF RVAI U, Acute Eye Irritation:
Toxicological Information and Interpretation:
eye - eye irritation, rabbit. Mildly irritating. Unwashed.
eye - eye irritation, rabbit. Non-irritating. Washed. Data for sodium polyphosphates.
Acute Skin Irritation:
No test data found for product.
Acute Dermal Toxicity:
No test data found for product.
Acute Respiratory Irritation:
No test data found for product.
Acute Inhalation Toxicity:
No test data found for product.
Acute Oral Toxicity:
Toxicological Information and Interpretation:
LD50 - lethal dose 50% of test species, 3053 mg/kg, rat. Data for sodium polyphosphates.
Chronic Toxicity:
This product does not contain any substances that are considered by OSHA, NTP, IARC or ACGIH to be "probable" or "suspected" human carcinogens.
- 12. ECOLOGICAL INFORMATION --
Ecotoxicological Information:
No data found for product.
Chemical Fate Information:
No data found for product.
6of 9 03/19/2003 8:47 AP
SODIUM POLYPHOSPHATE GLASSY SOLUTION httpJlwww rhodia-phosphates.comI/msdsA)0000800200001000 10056E00017.HTM 3'DISPOS L -'-
Waste Disposal Method:
Chemical additions, processing or otherwise altering this material may make the waste management information presented in this MSDS incomplete, inaccurate or otherwise inappropriate. Please be advised that state and local requirements for waste disposal may be more restrictive or otherwise different from federal laws and regulations.
Consult state and local regulations regarding the proper disposal of this material.
EPA Hazardous Waste - NO LT4 ANSPO T T O Transportation Status: IMPORTANTI Statements below provide additional data on listed DOT classification.
The listed Transportation Classification does not address regulatory variations due to changes in package size,!
mode of shipment or other regulatory descriptors.
US Department of Transportation Shipping Name:
NOT REGULATED V15REGLATORY NOMTO Inventory Status Inventory Status UNITED STATES (TSCA) Y CANADA (DSL) Y EUROPE (EINECS/ELINCS) Y AUSTRALIA (AICS) Y JAPAN (MITI) Y SOUTH KOREA (KECL) Y Y = All ingredients are on the inventory.
E All ingredients are on the inventory or exempt from listing.
P One or more ingredients fall under the polymer exemption or are on the no longer polymer list. All other ingredients are on the inventory or exempt from listing.
N = Not determined or one or more ingredients are not on the inventory and are not exempt from listing.
FEDERAL REGULATIONS Inventory Issues:
All functional components of this product are listed on the TSCA Inventory.
SARA Title Ill Hazard Classes:
7of 9 03/19/2003 8:47 Al
1L-SODIUM POLYPHOSPHATE GLASSY SOLUTION http://www.rhodia-phosphates.com/msds/0000080020000 10001 0056E000 17.HTM Fire Hazard - NO Reactive Hazard - NO Release of Pressure - NO Acute Health Hazard - NO Chronic Health Hazard - NO SARA Extremely Hazardous Substances (EHS)/CERCLA Hazardous Substances Ingredient CERCLA/SARA RQ SARA EHS TPQ ALTERNATE CAS # (SODIUM HEXAMETAPHOSPHATE) 5 000 lbs OTHER FEDERAL REGULATIONS:
FDA Status:
This product meets the compositional requirements of:
21 CFR 182.6760 SODIUM HEXAMETAPHOSPHATE STATE REGULATIONS:
This product does not contain any components that are regulated under California Proposition 65.
National Fire Protection Association Hazard Ratings--NFPA(R):
0 Health Hazard Rating--Minimal 0 Flammability Rating--Minimal 0 Instability Rating--Minimal National Paint & Coating Hazardous Materials Identification System--HMIS(R):
0 Health Hazard Rating--Minimal 0 Flammability Rating--Minimal 0 Reactivity Rating--Minimal Reason for Revisions:
Regulatory Review and Update.
Key Legend Information:
ACGIH - American Conference of Governmental Industrial Hygienists OSHA - Occupational Safety and Health Administration TLV - Threshold Limit Value PEL - Permissable Exposure Limit TWA - Time Weighted Average STEL - Short Term Exposure Limit NTP - National Toxicology Program IARC - International Agency for Research on Cancer ND - Not determined RPI - Rhone-Poulenc Established Exposure Limits
-Disclaimer:
the information herein is given in good faith but no warranty, expressed or implied, is made.
8of 9 03119/2003 8:47 At
GE etz GE Betz, Inc. Material Safety Data Sheet 4636 Somerton Road Trevose,PA 19053 Issue Date: 09-JUL-2002 Business telephone: (215) 355-3300 EMERGENCY TELEPHONE (Hlealth/Accident): (800) 877-1940 1 PRODUCT IDENTIFICATION PRODUCT NAME:
DEPOSITROL BL5400 PRODUCT APPLICATION AREA:
WATER-BASED DEPOSIT CONTROL AGENT.
2 COMPOSITION / INFORMATION ON INGREDIENTS Information for specific product ingredients as required by the U.S. OSHA HAZARD COMMUNICATION STANDARD is listed. Refer to additional sections of this MSDS for our assessment of the potential hazards of this formulation.
HAZARDOUS INGREDIENTS:
CAS# CHEMICAL NAME 2809-21-4 PHOSPHONIC ACID,(1-HYDROXYETHYLIDINE)BIS- (HEDP)
Corrosive (eyes) 10294-56-1 PHOSPHOROUS ACID (PHOSPHONIC ACID)
Corrosive No component is considered to be a carcinogen by the National Toxicology Program, the International Agency for Research on Cancer',-or the Occupational Safety and Health Administration at OSHA thresholds for carcinogens. -
3 HAZARDS IDENTIFICATION EMERGENCY OVERVIEW DANGER May cause moderate irritation to the skin. Corrosive to the eyes.
Inhalation of vapor or mist may cause severe nose, throat, and respiratory tract irritation.
DOT hazard: Corrosive to steel
__________________ - - - IA.
Emergency Response Guide #153 Odor: Mild; Appearance: Colorless To Yellow, Liquid Fire fighters should wear positive pressure self-contained breathing apparatus(full face-piece type). Proper fire-extinguishing media:
dry chemical, carbon dioxide, foam or water
- f******
POTENTIAL HEALTH EFFECTS ACUTE SKIN EFFECTS:
Primary route of exposure; May cause moderate irritation to the skin.
ACUTE EYE EFFECTS:
Corrosive to the eyes.
ACUTE RESPIRATORY EFFECTS:
Inhalation of vapor or mist may cause severe nose, throat, and respiratory tract irritation.
INGESTION EFFECTS:
May cause severe irritation or burning of the gastrointestinal tract.
TARGET ORGANS:
No evidence of potential chronic effects.
MEDICAL CONDITIONS AGGRAVATED:
Not known.
SYMPTOMS OF EXPOSURE:
May cause redness or itching of skin, irritation, and/or tearing of eyes (direct contact).
4 FIRST AID MEASURES SKIN CONTACT:
Wash thoroughly with soap and water. Remove contaminated clothing.
Thoroughly wash clothing before reuse. Get medical attention if irritation develops or persists.
EYE CONTACT:
URGENT! Immediately flush eyes with plenty of low-pressure water for at least 20 minutes while removing contact lenses. Hold eyelids apart. Get immediate medical attention.
INHALATION:
If nasal, throat or lung irritation develops - remove to fresh air and get medical attention.
INGESTION:
Do not feed anything by mouth to an unconscious or convulsive victim. Do not induce vomiting. Immediately contact physician.
Dilute contents of stomach using 3-4 glasses milk or water.
NOTES TO PHYSICIANS:
Material is corrosive. It may not be advisable to induce vomiting.
Possible mucosal damage may contraindicate the use of gastric lavage.
5 FIRE FIGHTING MEASURES
FIRE FIGHTING INSTRUCTIONS:
Fire fighters should wear positive pressure self-contained breathing apparatus (full face-piece type).
EXTINGUISHING MEDIA:
dry chemical, carbon dioxide, foam or water HAZARDOUS DECOMPOSITION PRODUCTS:
Thermal decomposition (destructive fires) yields elemental oxides.
FLASH POINT:
> 200F > 93C SETA(CC)
MISCELLANEOUS:.
Corrosive to steel UN3265;Emergency Response Guide #153 6 ACCIDENTAL RELEASE MEASURES PROTECTION AND SPILL CONTAINMENT:
Ventilate area. Use specified protective equipment. Contain and absorb on absorbent material. Place in waste disposal container.
Flush area with water. Wet area may be slippery. Spread sand/grit.
DISPOSAL INSTRUCTIONS:
Water contaminated with this product may be sent to a sanitary sewer treatment facility,irL accordance with any local agreementa permitted waste treatment facility or discharged under a permit. Product as is - Incinerate or land dispose in an approved landfill.
7 HANDLING & STORAGE HANDLING:
Acidic. Corrosive(Eyes). Do not mix with alkaline material.
STORAGE:
Keep containers closed when not in use. Do not freeze. If frozen, thaw and mix completely prior to use.:
8 EXPOSURE CONTROLS I PERSONAL PROTECTION EXPOSURE LIMITS CHEMICAL NAME PHOSPHONIC ACID,(l-HYDROXYETHYLIDINE)BIS- (HEDP)
PEL (OSHA): NOT DETERMINED TLV (ACGIH): NOT DETERMINED PHOSPHOROUS ACID (PHOSPHONIC ACID)
PEL (OSHA): NOT DETERMINED TLV (ACGIH): NOT DETERMINED ENGINEERING CONTROLS:
adequate ventilation PERSONAL PROTECTIVE EQUIPMENTi --
Use protective equipment in accordance 'with 29CFR 1910 Subpart I RESPIRATORY PROTECTION:
A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA'S 29 CFR-1910.134 AND ANSI Z88.2REQUIREMENTS MUST BE FOLLOWED-WHENEVER WORKPLACE CONDITIONS WARRANT A RESPIRATOR'S USE.
USE AIR PURIFYING RESPIRATORS WITHIN USE LIMITATIONS ASSOCIATED WITH THE EQUIPMENT OR ELSE USE SUPPLIED AIR-RESPIRATORS.
If air-purifying respirator use is appropriate, use a respirator with dust/mist filters.
SKIN PROTECTION:
- ~ __it _
PVC gloves-- Wash off after each use. Replace as necessary.
EYE PROTECTION:
splash proof chemical goggles 9 PHYSICAL & CHEMICAL PROPERTIES Specific Grav.(70F,21C) 1.453 Vapor Pressure (mmHG) - 18.0 Freeze Point (F) < -30 Vapor Density (air=l) < 1.00 Freeze Point (C) < -34 Viscosity(cps 70F,21C) 85 % Solubility (water) 100. 0 Odor Mild Appearance Colorless To Yellow Physical State Liquid Flash Point SETA(CC) > 200F > 93C pH As Is (approx.) < 1.0 Evaporation Rate (Ether=l) < 1.00 NA - not applicable ND = not determined 10 STABILITY & REACTIVITY STABILITY:
Stable under normal storage conditions.
HAZARDOUS POLYMERIZATION:
Will not occur.
INCOMPATIBILITIES:
May react with strong oxidizers.
DECOMPOSITION PRODUCTS:
Thermal decomposition (destructive fires) yields elemental oxides.
INTERNAL PUMPOUT/CLEANOUT CATEGORIES:
"B" 11 TOXICOLOGICAL INFORMATION Oral LD50 RAT: 2,000 mg/kg NOTE - RAT LD50: 2,400 mg/kg per alternate source Dermal LD50 RABBIT: >7,940 mg/kg NOTE - RABBIT LD50: 10,000 MG/KG ALTERNATE SOURCE Skin Irritation Score RABBIT: 0 Eye Irritation Score RABBIT: CORROSIVE 90 Day Feed Study RAT: NOEL:10,000 ppm NOTE - Hemopoeitic effects at 30,000 ppm 90 Day Feed Study DOG: .062-1%
NOTE - 2 year-feed study. Reversible anemia developed at 1% in diet.
90 Day Feed Study DOG: 20-60 mg/kg NOTE day study. No pathological effects.
Ames Assay BACTERIA: NEGATIVE NOTE - +/- metabolic activation Non-Ames Mutagenicity : NEGATIVE NOTE - Mouse Lymphoma Assay +/- metabolic activation 12 ECOLOGICAL INFORMATION
AQUATIC TOXICOLOGY Bluegill Sunfish 96 Hour Static Acute Bioassay LC50= 1440; No Effect Level= 880 mg/L Ceriodaphnia 48 Hour Static Renewal Bioassay (pH adjusted)
No Effect Level- 31.3; LC50= 113 mg/L Daphnia magna 48 Hour Static Renewal Bioassay (pH adjusted)
LC50 755. No Effect Level= 420 mg/L Fathead Minnow 96 Hour Static Renewal Bioassay (pH adjusted)
LC50= 3040; No Effect Level= 1370 mg/L Grass Shrimp (Palaemonetes pugio) 96 Hour Static Acute Bioassay LC50= 2675 mg/L Midge larvae (Chironomus-tentans) 48 Hour Static Acute Bioassay LC50 14850 mg/L Mysid Shrimp 48 Hour Static Renewal Bioassay (pH adjusted)
LC50. 319 mg/L Rainbow Trout 96 Hour Static Acute Bioassay LC50= 610; No Effect Level- 250 mg/L Sheepshead Minnow 96 Hour Static Acute Bioassay LC50 3630; No Effect Level- 170 mg/L BIODEGRADATION BOD-28. (mg/g): 1 BOD-5 (mg/g): 1 COD (mg/g): 300 TOC (mg/g): 70 13 DISPOSAL CONSIDERATIONS If this undiluted product is discarded as a waste, the US RCRA hazardous waste identification number is D002=Corrosive(pH, steel).
Please be advised; however, that state and local requirements for waste disposal may be more restrictive or otherwise different from federal regulations. Consult state and local regulations regarding the proper disposal of this material.
14 TRANSPORT INFORMATION DOT HAZARD. Corrosive to steel UN / NA NUMBER: UN3265 DOT EMERGENCY RESPONSE GUIDE #: 153 15 REGULATORY INFORMATION TSCA:
All components of this product are listed in the TSCA inventory.
CERCLA AND/OR SARA REPORTABLE QUANTITY (RQ):
No regulated constituent present at OSHA thresholds SARA SECTION 312 HAZARD CLASS:
Immediate (acute)
SARA SECTION 302 CHEMICALS:
No regulated constituent present at OSHA thresholds SARA SECTION 313 CHEMICALS:
No regulated constituent present at OSHA thresholds CALIFORNIA REGULATORY INFORMATION CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT (PROPOSITION 65) CHEMICALS PRESENT:
No regulated constituent present at OSHA thresholds MICHIGAN REGULATORY INFORMATION No regulated constituent present at OSHA thresholds 16 OTHER INFORMATION NFPA/HMIS CODE TRANSLATION Health 3 Serious Hazard Fire 1 Slight Hazard Reactivity 0 Minimal Hazard Special CORR DOT corrosive (1) Protective Equipment B Goggles,Gloves (1) refer to section 8 of MSDS for additional protective equipment recommendations.
CHANGE LOG EFFECTIVE DATE REVISIONS TO SECTION: SUPERCEDES MSDS status: 28-JAN-1997 ** NEW **
23-JUN-1997 28-JAN-1997 03-MAY-2000 12 23- JUN-1997 27-SEP-2000 4,11 03-MAY-2000 30-MAY-2001 2,8,11 27-SEP-2000 31-MAY-2001 15 30-MAY-2001 02-AUG-2001 12 31-MAY-2001 23-AUG-2001 4,12 02-AUG-2001 09-JUL-2002 12 23-AUG-2001 I
GEBetz GE Betz, Inc. Material Safety Data Sheet 4636 Somerton Road Trevose, PA 19053 Issue Date: 03-JAN-2002 Business telephone: (215) 355-3300 EMERGENCY TELEPHONE (Health/Accident): (800) 877-1940 1 PRODUCT IDENTIFICATION PRODUCT NAME:
DEPOSITROL BL5323 PRODUCT APPLICATION AREA:
WATER-BASED CORROSION INHIBITOR/DEPOSIT CONTROL AGENT.
2 COMPOSITION / INFORMATION ON INGREDIENTS Information for specific product ingredients as required by the U.S. OSHA HAZARD COMMUNICATION STANDARD is listed. Refer to additional sections of this MSDS for our assessment'of the potential hazards of this formulation.
HAZARDOUS INGREDIENTS:
CAS# CHEMICAL NAME 2809-21-4 PHOSPHONIC ACID,(l-HYDROXYETHYLIDINE)BIS- (HEDP)
Corrosive (eyes) -
No component is considered to be a carcinogen by the National Toxicology Program, the International Agency for Research on Cancer, or the Occupational Safety and Health Administration at OSHA thresholds for carcinogens.
3 HAZARDS IDENTIFICATION EMERGENCY OVERVIEW CAUTION May cause slight irritation to the skin. May cause moderate irritation to the eyes. Mists/aerosols may cause irritatio'nto upper respiratory tract.
DOT hazard is not applicable '
Emergency Response Guide is not applicable Odor: Slight; Appearance: Yellow, Liquid
-- - I---
Fire fighters should wear positive pressure self-contained breathing apparatus(full face-piece type). Proper fire-extinguishing media:
dry chemical, carbon dioxide, foam or water POTENTIAL HEALTH EFFECTS ACUTE SKIN EFFECTS:
Primary route of exposure; May cause slight irritation to the skin.
ACUTE EYE EFFECTS:
May cause moderate irritation to the eyes.
ACUTE RESPIRATORY EFFECTS:
Mists/aerosols may cause irritation to upper respiratory tract.
INGESTION EFFECTS:
May cause slight gastrointestinal irritation.
TARGET ORGANS:
No evidence of potential chronic effects.
MEDICAL CONDITIONS AGGRAVATED:
Not known.
SYMPTOMS OF EXPOSURE:
May cause redness or itching of skin.
4 FIRST AID MEASURES SKIN CONTACT:
Wash thoroughly with soap and water. Remove contaminated clothing.
Get medical attention if irritation develops or persists.
EYE CONTACT:
Remove contact lenses. Hold eyelids apart. Immediately flush eyes with plenty of low-pressure water for at least 15 minutes. Get immediate medical attention.
INHALATION:
If nasal, throat or lung irritation develops - remove-.to fresh air and get medical attention.
INGESTION:
Do not feed anything by mouth to an unconscious or convulsive victim. Do not induce vomiting. Immediately contact physician.
Dilute contents of stomach using 3-4 glasses milk or water.
NOTES TO PHYSICIANS:
No special instructions 5 FIRE FIGHTING MEASURES FIRE FIGHTING INSTRUCTIONS:
Fire fighters should wear positive pressure self-contained breathing apparatus (full face-piece type).
EXTINGUISHING MEDIA:
dry chemical, carbon dioxide, foam or water HAZARDOUS DECOMPOSITION PRODUCTS:
Thermal decomposition (destructive fires) yields elemental oxides.
FLASH POINT:
> 200F > 93C P-M(CC) 6 ACCIDENTAL RELEASE MEASURES
PROTECTION AND SPILL CONTAINMENT:
Ventilate area. Use specified protective equipment. Contain and absorb on absorbent material. Place in waste disposal container.
Flush area with water. Wet area may be'slippery. Spread sand/grit.
DISPOSAL INSTRUCTIONS:
Water contaminated with this product may be sent to a sanitary sewer treatment facility,in accordance with any local agreementa permitted waste treatment facility or discharged under a permit. Product as is - Incinerate or land dispose in an approved landfill.
7 HANDLING & STORAGE HANDLING:
Acidic. Do not mix with alkaline material.:-
STORAGE:
Keep containers closed when not in use. Do not freeze. If frozen, thaw and mix completely prior to use.
8 EXPOSURE CONTROLS / PERSONAL PROTECTION EXPOSURE LIMITS CHEMICAL NAME PHOSPHONIC ACID,(l-HYDROXYETHYLIDINE)BIS- (HEDP)
PEL (OSHA): NOT DETERMINED TLV (ACGIH): NOT DETERMINED ENGINEERING CONTROLS:
adequate ventilation PERSONAL PROTECTIVE EQUIPMENT:
Use protective equipment in accordance with 29CFR 1910 Subpart I RESPIRATORY PROTECTION:
A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA'S 29 CFR 1910.134 AND ANSI Z88.2 REQUIREMENTS MUST BE FOLLOWED WHENEVER WORKPLACE CONDITIONS WARRANT A RESPIRATOR'S USE.
USE AIR PURIFYING RESPIRATORS WITHIN USE LIMITATIONS ASSOCIATED WITH THE EQUIPMENT OR ELSE USE SUPPLIED'AIR-RESPIRATORS.
If air-purifying respirator use is appropriate, use a respirator with dust/mist filters.
SKIN PROTECTION:
neoprene gloves-- Wash off after each use. Replace as necessary.
EYE PROTECTION:
splash proof chemical goggles 9 PHYSICAL & CHEMICAL PROPERTIES Specific Grav.(70F,21C) :L.256 ., Vapor Pressure (mmHG) - 18.0 Freeze Point (F) 25 iVapor Density (air=l) k 1.00 Freeze Point (C) -4 Viscosity(cps 70F,21C) 90 % Solubility (water) 100.0 Odor Slight Appearance 'Yellow Physical State I'Li quid' Flash Point P-M(CC) > 200F > 93C I pH As Is (approx.) 2.2
Evaporation Rate (Ether=1) < 1.00 NA = not applicable ND = not determined 10 STABILITY & REACTIVITY STABILITY:
Stable under normal storage conditions.
HAZARDOUS POLYMERIZATION:
Will not occur.
INCOMPATIBILITIES:
May react with strong oxidizers.
DECOMPOSITION PRODUCTS:
Thermal decomposition (destructive fires) yields elemental oxides.
INTERNAL PUMPOUT/CLEANOUT CATEGORIES:
"B" 11 TOXICOLOGICAL INFORMATION Oral LD50 RAT: >2,000 mg/kg NOTE - Estimated value Dermal LD50 RABBIT: >2,000 mg/kg NOTE - Estimated value 12 ECOLOGICAL INFORMATION AQUATIC TOXICOLOGY Daphnia magna 48 Hour Acute Toxicity (Estimated)
LC50= 1180; No Effect Level= 750 mg/L Fathead Minnow 96 Hour Acute Toxicity (Estimated)
LC50= 1790; No Effect Level= 310 mg/L BIODEGRADATION BOD-28 (mg/g): 31 BOD-5 (mg/g): 9 COD (mg/g): 416 TOC (mg/g): 152 13 DISPOSAL CONSIDERATIONS If this undiluted product is discarded as a waste, the US RCRA hazardous waste identification number is Not applicable.
Please be advised; however, that state and local requirements for waste disposal may be more restrictive or otherwise different from federal regulations. Consult state and local regulations regarding the proper disposal of this material.
14 TRANSPORT INFORMATION DOT HAZARD: Not Applicable UN / NA NUMBER: Not applicable DOT EMERGENCY RESPONSE GUIDE #: Not applicable i 15 REGULATORY INFORMATION
TSCA:
All components of this product are listed in the TSCA inventory.
CERCLA AND/OR SARA REPORTABLE QUANTITY (RQ):
No regulated constituent present at OSHA thresholds USDA FEDERALLY INSPECTED MEAT AND POULTRY PLANTS:
This product contains ingredients that have been determined as safe for use in systems for cooking or cooling containers of meat and/or poultry and in systems with no food contact. (GS, G7)
SARA SECTION 312 HAZARD CLASS:
Immediate (acute)
SARA SECTION 302 CHEMICALS:
No regulated constituent present at OSHA thresholds SARA SECTION 313 CHEMICALS:
No regulated constituent present at OSHA thresholds CALIFORNIA REGULATORY INFORMATION CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT (PROPOSITION 65) CHEMICALS PRESENT:
No regulated constituent present at OSHA thresholds MICHIGAN REGULATORY INFORMATION No regulated constituent present. at OSHA thresholds 16 OTHER INFORMATION NFPA/HMIS CODE TRANSLATION Health 1 Slight Hazard Fire 1 Slight Hazard Reactivity 0 Minimal Hazard Special NONE No special Hazard (1) Protective Equipment B Goggles,Gloves (1) refer to section 8 of MSDS for additional protective equipment recommendations.
CHANGE LOG EFFECTIVE DATE REVISIONS TO SECTION: SUPERCEDES MSDS status: 03-SEP-1997 ** NEW **
16-JAN-2001 15 03-SEP-1997 03-JAN-2002 3,4 16-JAN-2001
- 1
MATERIAL SAFETY DATA SHEET PRODUCT
- 1 NALCO NALCLEAN 2568
. EMERGENCY TELEPHONE NUMBER(S)
- i800 424.93n0 124 Hntijm , CHFMTRFC
- 1. I CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: NALCLEAN@ 2568 APPLICATION: SCALE REMOVER COMPANY IDENTIFICATION: Nalco Company 1601 W. Diehl Road Naperville, Illinois 60563-1198 EMERGENCY TELEPHONE NUMBER(S): (800) 424-9300 (24 Hours) .CHEMTREC NFPA 704MIHMIS RATING -
HEALTH: 212 FLAMMABILITY: I/1 INSTABILITY: 0/0 OTHER:
0 = Insignificant 1 = Slight 2 = Moderate 3 = High 4 = Extreme
- 2. COMPOSITION/INFORMATION ON INGREDIENTS Our hazard evaluation has identified the following chemical substance(s) as hazardous. Consult Section 15 for the nature of the hazard(s).
-- Hazardous Substance(s) - CAS NO % (w/w)
Sulfamic Acid 5329-14-6 60.0- 100.0 Mercaptobenzothiazole -149-30-4 1.0- 5.0
- 3. l HAZARDS IDENTIFICATION
- EMERGENCY OVERVIEW**
DANGER Corrosive. May cause tissue damage. May cause sensitization by skin contact.
Do not get in eyes, on skin, on clothing. Do not breathe dust. Do not take internally. Use with adequate ventilation.
Keep container tightly closed and in a well-ventilated place. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. After contact with skin, wash immediately with plenty of water.
Wear a face shield. Wear chemical resistant apron, chemical splash goggles, impervious gloves and boots.
Not flammable or combustible. May evolve oxides of carbon (COx) under fire conditions. May evolve oxides of sulfur (SOx) under fire conditions. May evolve oxides of phosphorus (POx) under fire conditions.
PRIMARY ROUTES OF EXPOSURE:
Eye, Skin HUMAN HEALTH HAZARDS - ACUTE:
gYE CONTACT:
Corrosive. Will cause eye burns and permanent tissue damage.
Nalco Company 1601 W. Diehl Road
- Naperville, Illinois 60563-1198
- - (630)305-1000 1
. 1/10
- is MATERIAL SAFETY DATA SHEET N ALCO
)0 PRODUCT NALCLEAN 2568 EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours) CHEMTREC SKIN CONTACT:
Corrosive; causes permanent skin damage. Repeated or prolonged contact may cause skin sensitization.
INGESTION:
May cause burns to mouth and gastro-intestinal tract.
INHALATION:
Dust may cause severe respiratory tract irritation.
SYMPTOMS OF EXPOSURE:
Acute:
A review of available data does not identify any symptoms from exposure not previously mentioned.
Chronic:
A review of available data does not identify any symptoms from exposure not previously mentioned.
AGGRAVATION OF EXISTING CONDITIONS:
Skin contact may aggravate an existing dermatitis condition.
HUMAN HEALTH HAZARDS - CHRONIC:
No adverse effects expected other than those mentioned above.
- 4. l FIRST AID MEASURES EYE CONTACT:
PROMPT ACTION IS ESSENTIAL IN CASE OF CONTACT. Immediately flush eye with water for at least 15 minutes while holding eyelids open. Get immediate medical attention.
SKIN CONTACT:
Immediately flush with plenty of water for at least 15 minutes. Get immediate medical attention.
INGESTION:
DO NOT INDUCE VOMITING. If conscious, washout mouth and give water to drink. Get immediate medical attention.
INHALATION:
Remove to fresh air, treat symptomatically. If breathing has stopped, trained personnel should begin artificial respiration or, if the heart has stopped, cardiopulmonary resuscitation (CPR) immediately. Get medical attention.
NOTE TO PHYSICIAN:
Based on the individual reactions of the patient, the physician's judgement should be used to control symptoms and clinical condition.
- 5. FIRE FIGHTING MEASURES FLASH POINT: None LOWER EXPLOSION LIMIT: Not flammable Nalco Company 1601 W. Diehl Road - Naperville, Illinois 60563-1198 (630)305-1000 2/10
MATERIAL SAFETY DATA SHEET PRODUCT PINALCO NALCLEAN 2568
,EMERGENCY TELEPHONE NUMBER(S)
, (800) 424-9300 (24 Hours) *CHEMTREC UPPER EXPLOSION LIMIT: Not flammable EXTINGUISHING MEDIA:
Use extinguishing media appropriate for surrounding fire.
FIRE AND EXPLOSION HAZARD:
Not flammable or combustible. May evolve oxides of carbon (COx) under fire conditions. May evolve oxides of sulfur (SOx) under fire conditions. May evolve oxides of phosphorus (POx) under fire conditions.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE FIGHTING:
In case of fire, wear a full face positive-pressure self contained breathing apparatus and protective suit.
- 6. l ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS:
Keep people away from and upwind of spill/leak. Do not touch spilled material. Ensure clean-up is conducted by trained personnel only. Use personal protective equipment recommended in Section 8 (Exposure Controls/Personal.
Protection).
METHODS FOR CLEANING UP:'
For powder: Sweep up and shovel. Reclaim into recovery or salvage drums.
ENVIRONMENTAL PRECAUTIONS:
Do not contaminate surface water., Prevent product from entering drains.
- 7. l HANDLING AND STORAGE HANDLING:
Do not get in eyes, on skin, on clothing. Avoid generating dusts. Do not take internally.
STORAGE CONDITIONS:
Keep in dry place. Store the containers tightly closed.
UNSUITABLE CONSTRUCTION MATERIAL: .-
Corrosive to steel, 'copper and alloys., Other common metals' II ts. AI * -O I IA1-U0UIr_ %,UN' r f n ^bOI- TI A 2I I KUL01IrI¶-LJPIPAL I-KU I ZL, I 1UN4~
at
. . - .- I OCCUPATIONAL EXPOSURE LIMITS:
Exposure guidelines have not been established for this product. Available exposure limits for the substance(s) are shown below.
ACGIH/TLV:
Substance(s)
Respirable Nuisance TWA: 3 mglm3 Particulates Inhalable (Total) Nuisance TWA: 10 mglm3 Particulates Nalco Company 1601 W. Diehl Road I Naperville, Illinois 60563-1198
, -(630)305-1000
.3/10
- - In MATERIAL SAFETY DATA SHEET
- tNALCO PRODUCT NALCLEAN 2568 EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours) CHEMTREC OSHA/PEL:
Substance(s)
Respirable Nuisance TWA: 5 mg/m3 Particulates Inhalable (Total) TWA: 15 mg/m3 (total dust)
Nuisance Particulates Substance(s)
AIHA/WEEL:
Substance(s)
Merca ptobenzothiazole ENGINEERING MEASURES:
General ventilation is recommended. Local exhaust ventilation may be necessary when this material is heated or a mist is created.
RESPIRATORY PROTECTION:
Respiratory protection is not normally needed. Where concentrations in air may exceed the limits given in this section, the use of a nuisance dust mask is recommended.
HAND PROTECTION:
Impervious gloves SKIN PROTECTION:
Wear impervious apron and boots.
EYE PROTECTION:
Wear a face shield with chemical splash goggles.
HYGIENE RECOMMENDATIONS:
Keep a safety shower available. Keep an eye wash fountain available. If clothing is contaminated, remove clothing and thoroughly wash the affected area. Launder contaminated clothing before reuse.
HUMAN EXPOSURE CHARACTERIZATION:
Based on our recommended product application and personal protective equipment, the potential human exposure is: Moderate
- 9. PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL STATE Powder APPEARANCE Light blue ODOR Sulfurous BULK DENSITY 80 Ib/ft3 kOLUBILITY IN WATER Partial pH (3 %) 0-2 MELTING POINT /205 0C Nalco Company 1601 W. Diehl Road
- Naperville, Illinois 60563-1198 (630)305-1000 4/10
.I. MATERIAL SAFETY DATA SHEET
.- ljPRODUCT
- NALCO NALCLEAN 2568
, , , ,- , EMERGENCYTELEPHONE NUMBER(S)
- 0UU0) 0Z4 nours) 424-9UU CE-ItV I KEE.
VOC CONTENT 1.06 % Calculated Note: These physical properties are typical values for this product and are subject to change.
- 10. STABILITY AND REACTIVITY STABILITY:
Stable under normal conditions.
HAZARDOUS POLYMERIZATION:
Hazardous polymerization will not occur. I CONDITIONS TO AVOID:
Moisture MATERIALS TO AVOID:
Contact with strong alkalies (e.g. ammonia and its solutions, carbonates, sodium hydroxide (caustic), potassium hydroxide, calcium hydroxide (lime), cyanide, sulfide, hypochlorites, chlorites) may generate heat,' splattering or boiling and toxic vapors. Sulfamic acid will react with chlorine or fuming nitric acid.
HAZARDOUS DECOMPOSITION PRODUCTS':
Under fire conditions: Oxides of carbon, Oxides of sulfur, Oxides of phosphorus
- 11. lTOXICOLOGICAL INFORMATION.
The following results are for the product.
ACUTE ORAL TOXICITY:
Species LD50 Test Descriptor Rat 3,160 mg/kg -Product SENSITIZATION:
Mercaptobenzothiazole can cause an allergic reaction in sensitive individuals. - Repeated or prolonged contact may cause sensitization in some individuals.
CARCINOGENICITY:
None of the substances in this product are listed as carcinogens by the International Agency for Research on Cancer (IARC), the National Toxicology Program (NTP) or the American Conference of Governmental Industrial Hygienists (ACGIH).
HUMAN HAZARD CHARACTERIZATION:
Based on our hazard characterization, the potential human hazard is: High
- 12. ECOLOGICAL INFORMATION ECOTOXICOLOGICAL EFFECTS:
The following results are for the product.
- Nalco Company 1601 W. Diehl Road - Naperville, Illinois 60563-1198
,(630)305-1000 5/10
_1IL MATERIAL SAFETY DATA SHEET 04 NALCO PRODUCT NALCLEAN 2568 EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours) CHEMTREC ACUTE FISH RESULTS:
Species Exposure LC50 Test Descriptor Bluegill Sunfish 96 hrs 10 - 100 mg/I Product Rainbow Trout 96 hrs 10 - 100 mg/l Product Rating: Slightly toxic ACUTE INVERTEBRATE RESULTS:
Species Exposure LC I50 EC 50 Test Descriptor Daphnia matna 48 hrs 12 mg/I Product Acartia tonsa 48 hrs 12 mg/l Product Corophium volutator 240 hrs. 2,826 mg/l Rating:
AQUATIC PLANT RESULTS:
Species [ Exposure EC50/LC50 Test Descriptor Marine Algae (Skeletonema 72 hrs 0.99 mg/I (EC50) Product costatum)
Rating:
MOBILITY:
The environmental fate was estimated using a level IlIl fugacity model embedded in the EPI (estimation program interface) Suite TM, provided by the US EPA. The model assumes a steady state condition between the total input and output. The level IlIl model does not require equilibrium between the defined media. The information provided is intended to give the user a general estimate of the environmental fate of this product under the defined conditions of the models. If released into the environment this material is expected to distribute to the air, water and soil/sediment in the approximate respective percentages; I Air I Water I Soil/Sediment
<5% 1 50% 1 50 - 70%
The portion in water is expected to be soluble or dispersible.
BIOACCUMULATION POTENTIAL This preparation or material is not expected to bioaccumulate.
ENVIRONMENTAL HAZARD AND EXPOSURE CHARACTERIZATION Based on our hazard characterization, the potential environmental hazard is: Moderate Based on our recommended product application and the product's characteristics, the potential environmental exposure is: Low If released into the environment, see CERCLA/SUPERFUND in Section 15.
113. l DISPOSAL CONSIDERATIONS t If this product becomes a waste, it is not a hazardous waste as defined by the Resource Conservation and Recovery Act (RCRA) 40 CFR 261, since it does not have the characteristics of Subpart C, nor is it listed under Subpart D.
Nalco Company 1601 W. Diehl Road
- Naperville, Illinois 60563-1198 (630)305-1000 6 /10
. MATERIAL SAFETY DATA SHEET PRODUCT PINALCO NALCLEAN 2568 - -
.EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours) CHEMTREC As a non-hazardous waste, it is not subject to federal regulation. Consult state or local regulation for any additional handling, treatment or disposal requirements. For disposal, contact a properly licensed waste treatment, storage, disposal or recycling facility.
- 14. 1TRANSPORT INFORMATION I The information in this section is for reference only and should not take the place of a shipping paper (bill of lading) specific to an order. Please note that the proper Shipping Name / Hazard Class may vary by packaging, properties, and mode of transportation. Typical Proper Shipping Names for this product are as follows.
LAND TRANSPORT:
i . . A A M . S Proper Shipping Name: ISULFAMIC ACID MIXTURE, SOLID Technical Name(s):
UN/ID No: UN 2967 Hazard Class - Primary: 8 Packing Group: III Flash Point: None AIR TRANSPORT (ICAO/IATA):
Proper Shipping Name: SULPHAMIC ACID, MIXTURE, SOLID Technical Name(s):
UN/ID No: UN 2967 Hazard Class - Primary:
Packing Group: Il ,
IATA Cargo Packing Instructions: 823 IATA Cargo Aircraft Limit: 100 KG (Max net quantity per package)
MARINE TRANSPORT (IMDG/IMO):
Proper Shipping Name: SULPHAMIC ACID, MIXTURE, SOLID Technical Name(s):
UN/ID No: UN 2967 :-
Hazard Class - Primary:
Packing Group: I II . .. . . . .
l15. l REGULATORY INFORMATION -! - - l NATIONAL REGULATIONS, USA:
OSHA HAZARD COMMUNICATION RULE, 29 CFR 1910.1200: - ,
Based on our hazard evaluation, the following substance(s) in this product is/are hazardous and the reason(s) is/are shown below.
Sulfamic Acid: Irritant Mercaptobenzothiazole: Dermal Sensitizer, Corrosive Nalco Company 1601 W. Diehl Road
- Naperville, Illinois 60563-1198
- (630)305-1000-7/10
- I-MATERIAL SAFETY DATA SHEET "NALCOPRODUCT NALCLEANA 2568 EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours) CHEMTREC CERCLAISUPERFUND, 40 CFR 117,302:
Notification of spills of this product is not required.
SARA/SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (TITLE III) - SECTIONS 302, 311, 312, AND 313:
SECTION 302 - EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355):
This product does not contain substances listed in Appendix A and B as an Extremely Hazardous Substance.
SECTIONS 311 AND 312 - MATERIAL SAFETY DATA SHEET REQUIREMENTS (40 CFR 370):
Our hazard evaluation has found this product to be hazardous. The product should be reported under the following indicated EPA hazard categories:
X Immediate (Acute) Health Hazard X Delayed (Chronic) Health Hazard Fire Hazard Sudden Release of Pressure Hazard Reactive Hazard Under SARA 311 and 312, the EPA has established threshold quantities for the reporting of hazardous chemicals.
The current thresholds are: 500 pounds or the threshold planning quantity (TPQ), whichever is lower, for extremely hazardous substances and 10,000 pounds for all other hazardous chemicals.
SECTION 313 - LIST OF TOXIC CHEMICALS (40 CFR 372):
This product contains the following substance(s), (with CAS # and % range) which appear(s) on the List of Toxic Chemicals Hazardous Substance(s) CAS NO % (w/w)
Mercaptobenzothiazole 149-30-4 1.0- 5.0 TOXIC SUBSTANCES CONTROL ACT (TSCA):
The substances in this preparation are included on or exempted from the TSCA 8(b) Inventory (40 CFR 710)
NSF NON-FOOD COMPOUNDS REGISTRATION PROGRAM (former USDA List of Proprietary Substances & Non-Food Compounds):
NSF Registration number for this product is : 062339 This product is acceptable for use as an acid cleaner (A3) in and around food processing areas, where its use is not intended for direct food contact. Use of this product in food processing or handling facilities requires that all food products and packaging materials be removed or protected prior to product use. A potable water rinse of cleaned surfaces is required after use of this product. When used according to manufacturer's instructions, the cleaner shall neither exhibit a noticeable odor nor leave a visible residue. This product is acceptable for treating boilers, steam lines, and/or cooling systems (G7) where neither the treated water nor the steam produced may contact edible products in and around food processing areas.
FEDERAL WATER POLLUTION CONTROL ACT, CLEAN WATER ACT, 40 CFR 401.15 / formerly Sec. 307, 40 CFR 116.4 / formerly Sec. 311:
None of the substances are specifically listed in the regulation.
Nalco Company 1601 W. Diehl Road - Naperville, Illinois 60563-1198 (630)305-1000 8/10
. MATERIAL SAFETY DATA SHEET
- NALCO NALCLEAN 2568
..-. - EMERGENCY TELEPHONE NUMBER(S)
- - (800) 424-9300 (24 Hours) CHEMTREC CLEAN AIR ACT, Sec. 111 (40 CFR 60, Volatile Organic Compounds), Sec. 112 (40 CFR 61, Hazardous Air Pollutants), Sec; 602 (400CFR 82, Class I and 11Ozone Depleting Substances)
None of the substances are specifically listed in the regulation.
CALIFORNIA PROPOSITION 65:
This product does not contain substances which require warning under California Proposition 65.;'
MICHIGAN CRITICAL MATERIALS:'
None of the substances are specifically listed in the regulation.
STATE RIGHT TO KNOW LAWS:
The following substances are disclosed for compliance with State Right to Know Laws:
Sulfamic Acid -- 5329-14-6 NATIONAL REGULATIONS, CANADA:
WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM (WHMIS):
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information'required by the CPR.
WHMIS CLASSIFICATION:
D2A - Materials Causing Other Toxic Effects - Very Toxic Material, E - Corrosive Material CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA):
The substances in this preparation are listed on the Domestic'Substances List (DSL), are exempt, or have been reported in accordance with the New Substances Notification Regulations.
INTERNATIONAL CHEMICAL CONTROL LAWS AUSTRALIA All substances in this product comply with the National Industrial Chemicals Notification & Assessment Scheme (NICNAS) and are listed on the Australian Inventory'of Chemical Substances (AICS).
NEW ZEALAND This'product's trade name is registered with the Environmental Risk Management Authority (ERMA).
- 16. OTHER INFORMATION Due to our commitment to Product Stewardship, we have evaluated the human and environmental hazards and
- exposures of this product.: Based on our recommended use of this product, we have characterized the product's general risk. This information should provide assistance for your own risk management practices. We have evaluated our product's risk as follows:
- The human risk is: Moderate '
- The environmental risk is: Low Nalco Company 1601 W. Diehl Road Naperville, lllinois 60563-1198
'(630)305-1000 9/10
MATERIAL SAFETY DATA SHEET NALC O PRODUCT NALCLEAN 2568 EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours) CHEMTREC Any use inconsistent with our recommendations may affect the risk characterization. Our sales representative will assist you to determine if your product application is consistent with our recommendations. Together we can implement an appropriate risk management process.
This product material safety data sheet provides health and safety information. The product is to be used in applications consistent with our product literature. Individuals handling this product should be informed of the recommended safety precautions and should have access to this information. For any other uses, exposures should be evaluated so that appropriate handling practices and training programs can be established to insure safe workplace operations. Please consult your local sales representative for any further information.
REFERENCES Threshold Limit Values for Chemical Substances and Physical Agents and Biological Exposure Indices, American Conference of Governmental Industrial Hygienists, OH., (Ariel Insight# CD-ROM Version), Ariel Research Corp.,
Bethesda, MD.
Hazardous Substances Data Bank, National Library of Medicine, Bethesda, Maryland (TOMES CPS# CD-ROM Version), Micromedex, Inc., Englewood, CO.
IARC Monographs on the Evaluation of the Carcinogenic Risk of Chemicals to Man, Geneva: World Health Organization, International Agency for Research on Cancer.
Integrated Risk Information System, U.S. Environmental Protection Agency, Washington, D.C. (TOMES CPS# CD-ROM Version), Micromedex, Inc., Englewood, CO.
Annual Report on Carcinogens, National Toxicology Program, U.S. Department of Health and Human Services, Public Health Service.
Title 29 Code of Federal Regulations, Part 1910, Subpart Z, Toxic and Hazardous Substances, Occupational Safety and Health Administration (OSHA), (Ariel Insight# CD-ROM Version), Ariel Research Corp., Bethesda, MD.
Registry of Toxic Effects of Chemical Substances, National Institute for Occupational Safety and Health, Cincinnati, OH, (TOMES CPS# CD-ROM Version), Micromedex, Inc., Englewood, CO.
Ariel Insight# (An integrated guide to industrial chemicals covered under major regulatory and advisory programs),
North American Module, Western European Module, Chemical Inventories Module and the Generics Module (Ariel Insight# CD-ROM Version), Ariel Research Corp., Bethesda, MD.
The Teratogen Information System, University of Washington, Seattle, WA (TOMES CPS# CD-ROM Version),
Micromedex, Inc., Englewood, CO.
Prepared By: Product Safety Department Date issued: 02/21/2004
- ersion Number: 1.7 Nalco Company 1601 W. Diehl Road
- Naperville, Illinois 60563-1198 (630)305-1000 10/10
- 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: ALUMINUM SULFATE, HYDRATE MANUFACTURER: GEO SPECIALTY CHEMICALS, INC.
9213 Arch Street Pike Little Rock, AR 72206 (501) 888-1211 24-HOUR EMERGENCY TELEPHONE: CHEMTREC 1-800-424-9300 Aluminum Sulfate, Hydrate complies with the standards of the American Water Works Association B403-93. It has beenf certified by the National Sanitation Foundation (NSF) under ANSIINSF 60 for use in the treatment of drinking water at a maximum dosage of 150mg/L (dry basis).
- 2. COMPOSITION / INFORMATION ON INGREDIENTS COMPONENTS CAS NUMBER % (by Weight) TWA/CEILING Al.(So0). 10043-01-3 57.0% min 2 mg/m' 0UA033H FI4O 7732-18-5 balance
- 3. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW: White to light tan colored ground crystalline solid. Causes eve and skin irritation. Harmful if swallowed. Avoid breathing dust. - - - -
POTENTIAL HEALTH EFFECTS: Eyes: May cause irritation and inflammation of the eye. Concentrated solutions (over 20%) may cause severe eye damage or bums.
Skin: May cause skin irritation or bums if the product is wet or in the presence of perspiration.
Ingestion: May cause abdominal pain, nausea, and/or vomiting. Concentrated solutions (over 20%) can cause burns of the mouth, bleeding stomach, incoordination, muscle spasms, and/or kidney injury.
Inhalation: Dusts are severely irritating to the mucous membranes and respiratory tract.
CHRONIC EFFECTS/ CARCINOGENICITY: No evidence of additional adverse effects from repeated or prolonged Aluminum sulfate, Hydrate Issue Date: February 12,2004 Page: I of 5 MSDS# 0130
MATERIAL SAFETY DATA SHEET GEO SPECIALTY CHEMICALS, INC.
exposures is noted from available information.
This product does not contain any ingredient designated by IARC, NTP, ACGIH, or OSHA as a probable human carcinogen.
- 4. FIRST AID MEASURES Eyes: In case of contact, immediately flush with plenty of water for at least 15 minutes holding eyelids open. Use an eyewash fountain if available. Get medical attention if irritation persists, preferably an Ophthalmologist.
Skin: Immediately wash skin with plenty of soap and water while removing contaminated clothing and shoes. Wash contaminated clothing separately before reuse.
Ingestion: If person is conscious and alert, give two or more glasses of water or milk to drink. If available, give one tablespoon of Syrup of Ipecac to induce vomiting. If vomiting has not occurred in 20 minutes, the same dose of Syrup of Ipecac may be repeated one additional time. Alternately, induce vomiting by touching the back of the throat with a finger. Never give anything by mouth or induce vomiting in an unconscious or convulsing person. Get medical attention.
Inhalation: Remove patient to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen and get medical attention.
NOTES TO PHYSICIANS:
All treatments should be based on observed signs and symptoms of distress in the patient.
Consideration should be given to the possibility that overexposure to materials other than this product may have occurred.
Aluminum soluble salts may cause gastroenteritis if ingested. Treatment includes the use of demulcents.
- 5. FIREFIGHTING MEASURES Flanunable Properties:
FLASH POINT [C (F)]: Noncombustible FLAMMABLE LIMITS IN AIR: Not applicable AUTOIGNITION TEMPERATURE (C (F)]: Not applicable Under fire conditions greater than 650'C (1202'F), product decomposes to give off sulfur trioxide, an oxidizing agent which will support combustion. Sulfur trioxide will react with water to form sulfuric acid.
Extinguishing Media:
Not combustible. Use appropriate extinguishing media for material that is supplying fuel. Use water Aluminum sulfate, Hydrate Issue Date: February 12, 2004 Page: 2of5 MSDS# 0130
MATERIAL SAFETY DATA SHEET GEO SPECIALTY CHEMICALS, INC.
spray to cool the surrounding area and to maintain fire temperature below decomposition temperature.
Fire Fighting Instructions: .
Wear a NIOSHJMSHA approved self-contained breathing apparatus and full protective clothing. Dike area to prevent runoff and contamination of water sources.
- 6. ACCIDENTAL RELEASE MEASURES Vacuum or sweep material and place in appropriate containers for disposal. Avoid dust generation. Stand upwind if possible to evade any fugitive dust. Residual spillage should be cleaned from hard surfaces as appropriate. If spilled on the ground, the affected area should be'scraped clean and the material placed in proper containers for disposal. Do not flush material to public sewer systems or any waterways. Wear suitable protective clothing and equipment during clean up activities. Ensure adequate decontamination of tools and equipment following clean up.
Large spills should be handled according to a predetermined plan. Fori assistance in developing a plan, call 1-800-453-2586.
- 7. HANDLING AND STORAGE Avoid breathing dusts. Do not swallow. Avoid contact with eyes, skin and clothing.
Store in a cool area in tightly closed containers. -
- 8. EXPOSURE CONTROLS I PERSONAL PROTECTION Facilities storing or utilizing this material should maintain an eyewash fountain, safety shower, and sink in the work area.
Provide adequate ventilation. Use local exhaust as needed to maintain airborne exposure below control limits.
Where the exposure limits are or may be exceeded, use a NIOSH/MSHA approved respirator for acid dusts. Use positive pressure supplied air or self-contained breathing apparatus for emergency or other conditions where a higher level of protection is required.
Chemical safety goggles, long-sleeved clothinig,'rubber glov'es and boats should be worn.
- 9. PHYSICAL AND CHEMICAL PROPERTIES Physical Form: Crystalline solid Color: White to light tan Odor: , None.-
Melting Point: Loses water of hydration @ 88EC (190EF)
Bulk Density: 65 lbs/fe Water solubility (@20EC): 87.3 grams/1 00 grams water pH: 3.5 (1% Aqueous solution)
Aluminum sulfate. Hydrate Issue Date: February 12. 2004 Page: 3of5 MSDS# 0130
Il-MATERIAL SAFETY DATA SHEET GEO SPECIALTY CHEMICALS, INC.
- 10. STABILITY AND REACTIVITY Chemical Stability: Stable at ambient temperatures and atmospheric pressure.
Conditions to Avoid: Avoid high temperatures greater than 650'C (1202'F), because the product decomposes to form aluminum oxide and sulfur trioxide.
Incompatibility with Other Materials: Reacts with strong alkali to form aluminum hydroxide. Weakly corrosive to carbon steel. On contact with moisture, an acidic solution forms.
Hazardous Decomposition Products: Thermal decomposition produces aluminum oxide and sulfur oxides.
Hazardous Polymerization: Will not occur.
- 11. TOXICOLOGICAL INFORMATION Oral LD, (rats): > 2000 mglkg body weight Dermal LD, (rabbits): > 5000 mg/kg body weight Inhalation LC_, (rats): No information is available Skin Effects (rabbits): Non-irritating Eye Effects (rabbits): Severe irritant
- 12. ECOLOGICAL INFORMATION No information is available.
- 13. DISPOSAL CONSIDERATIONS Dispose of in accordance with Local, State and Federal regulations.
- 14. TRANSPORT INFORMATION Transportation Status: DOT
< RQ: Not Regulated
> RQ: Proper Shipping Name: Environmentally hazardous substances, solid, n.o.s.
(Aluminum Sulfate, Hydrate)
Hazardous Class: 9 ID No: UN 3077 i Packing Group: III Label: Class 9 Reportable quantity (RQ) under 49 CFR 172.101 Appendix: RQ = 5000 lbs as 100% Al,(SO),
Aluminum sulfate, Hydrate Issue Date: February 12, 2004 Page: 4 of 5 MSDS# 0130
MATERIAL SAFETY DATA SHEET GEO SPECIALTY CHEMICALS, INC.
- 15. REGULATORY INFORMATION TSCA Inventory Status: The components of this product are listed on the TSCA Inventory.
SARA Title III Section 302 Extremely Hazardous Substance List: Not listed Section 313 Toxic Chemicals: Not listed Reportable Quantity (RQ) under US EPA CERCLA: RQ = 5000 lbs as 100% Al2(SO4),
RCRA Hazardous Waste: Not listed
- 16. OTHER INFORMATION National Fire Protection Association Rating (NFPA):
Health - 1 Fire- 0 0 - Minimum Reactivity - 1 1 - Slight 2 - Moderate Hazardous Materials Identification System (HMIS): 3 - High/Serious Health- I 4 - Extreme/Severe Fire- 0 Reactivity - 1 MSDS Status: Revised February 12, 2004. Supersedes January 22, 1997.
For additional technical information call 1-800-453-2586.
The information herein is given in good faith but no warranty, expressed or implied, is made.
Aluminum sulfate, Hydrate Issue Date: February 12, 2004 Page: 5ofS MSDS# 0130
SANURIL 115 Material Maeril Safety Saety Data ata Sheet hee SANUIL 15
.I. . I
- SANURIL-115
- - -- Mixed Halogen Formulation N33mon Material Safety Data Sheet IM1141-Tv I 1. GENERAL PRODUCT INFORMATION I Product Name ............... SANURIL* 115 US EPA Reg. No. ............... 48482-5 Synonyms ............... Calcium hypochlorite and 1-bromo-3-chloro-5,5-dimethylhydantion Product Use ............... Disinfecting agent for wastewater NIOSH' Ratings ............... 3 HIGH HEALTH HAZARD 0 NON COMBUSTIBLE
- 2. MODERATELY. REACTIVE
- Ratings based upon lIdentification System for Occupationally Hazardous Materials (1974)'
DEPARTMENT OF TRANSPORTATION INFORMATION Proper Shipping Name ............... Calcium Hypochlorite, Hydrated Mixture RQ Hazard Class ............... Oxidizer UN Number ............ ; UN2880 Shipping Class ............ 55 -
MANUFACTURER INFORMATION Company Name ......... Severn Trent Services, Inc.
Street Address I 110 Industrial Boulevard 1..........
City, State, Zip .......... Sugar Land, Texas 77478 Emergency Phone ............ 1-800-424-9300 Office Phone .(281) 240-6770 Toll Free: 1-800-621-9189 Date Prepared .4118/1990 Last Revision: 08/07/2000
Calcium Hypochlorite 69.30% N/A' NIA 7778-54-3 1-bromo-3-chloro-5,5-dimethylhydantoin 0.94% 10 15 126-06-7 TLV/PEL OF MIXTURE (If known) N/A
- 3. PHYSICAL PROPERTIES Boiling Point ....... None; dry solid Vapor Density ........ N/A Melting Point .......... N/A' Vapor Pressure .N/A
-Specific Gravity .......... 1.8min (tablet) Percent Volatiles .N/A Solubility in Water ........... 6% by weight (min) pH ........... ; (1% solution)
-8.3 Density (@ 20'C) . 1.0 Color .White solid tablet Odor e Slight chlorine. N-bromo compounds have a stench like odor.
It is not as "sweet' as chlorine.
- 4. ECOLOGICAL INFORMATION *- -
Ecotoxicological Information:
Highly toxic, 10-1 pprn (fish) 96-hour TLM LC50
- 15. FIRE AND EXPLOSION DATA Flash Point ................ N/A Explosive Limit ............. Lower N/A Auto Ignite Temperature ................ N/A Upper. N/A Flammability Limits In Air ................ N/A Extinguishing Media ............. Water ONLY Severn Trent Services, Inc. Page 2
SANURIL 115 Material Safety Data Sheet
- 5. FIRE AND EXPLOSION DATA (Cont.)
Special Fire Fighting Procedures:
This product is a strong oxidizer. Use ONLY water in the event of a fire or a violent reaction may result by contamination. Wear self-contained breathing apparatus.
Unusual Hazard Information:
Contamination with organics, acids, alkalis, and strong reducing agents will result in fire or rapid decomposition. Spontaneous decomposition temperature for this product is 350'F. In large fires fueled by other materials, the product may smolder for prolonged periods emitting dense black smoke.
- 6. HEALTH HAZARD INFORMATION This section describes the nature of the hazardous effects resulting from exposure to this product.
Routes of Exposure:
Ingestion: Highly toxicby ingestion. May cause severe inflammation and erosion to the lining of the esophagus and stomach. Promptly induces vomiting.
Eye
Contact:
Mild to moderate exposure to dust causes irritation of the eyes. Severe exposure can cause permanent (irreversible) damage.
Skin
Contact:
Mild to moderate exposure to dust may irritate the skin. Greater exposure can cause severe irritation.
Inhalation: Mild to moderate exposure to dust causes irritation to the mucous membranes of the respiratory passages (nasal and throat).
Effects of Overexposure:
Acute: Ingestion may result in erosion of the esophagus and stomach. Vomiting, gastric bleeding and possible circulatory collapse. Exposure may cause temporary or permanent tissue damage to skin, eyes, and respiratory passages.
Chronic: Prolonged and intensive exposure may result in tissue damage to body surfaces unless promptly treated.
Emergency and First Aid Procedures:
Eyes: IMMEDIATELY flush eyes with large amounts of water for at least 15 minutes, holding lids apart to ensure flushing of entire eye surface. SEEK MEDICAL ATTENTION.
Skin: Wash with plenty of soap and water. Remove contaminated clothing and footwear.
Wash clothing before reuse. Footwear should be decontaminated before reuse.
Seek medical attention if symptoms persist.
Inhalation: Get person out of contaminated area to fresh air. If breathing has stopped, resuscitate and administer oxygen if readily available. SEEK MEDICAL ATTENTION.
Ingestion: NEVER give anything by mouth to an unconscious person. Drink large amounts of water. DO NOT induce vomiting. Call a physician immediately!
- 7. REACTIVITY DATA Conditions contributing to instability:
Contamination with flammables, organics may cause fire or explosion. Acids will release chlorine and bromine gas.
Incompatibility (Materials to avoid):
Acids, flammables, organic materials, readily oxidizable materials and strong reducing agents.
Severn Trent Services, Inc. Page 3
SANURIL 115 Material Safety Data Sheet Hazardous decomposition or byproducts:
Chlorine gas, hydrogen bromide, bromine and hydrogen chloride.
Hazardous polymerization:
This product is not known to'polymerize.
- 18. SPILL OR LEAK PROCEDURES (DEVELOP SPILL PLAN)
Neutralizing Chemicals:
Sodium sulfite, sodium bisulfite or sodium metabisulfite.
Steps to be Taken if Material Is Released andlor Spilled:
Wear appropriate protective gear: rubber gloves and boots. Chemical splash goggles and breathing apparatus if necessary. Avoid contact with clothing-fire may result.
Dilute spill area with large quantities of water, at least 100 gallons of water per pound of material. Avoid contact with resulting solution. Neutralize with sodium sulfite, sodiuJm bisulfite or sodiurm metabisulfite. Collected neutralized solution should be disposed of through sewage treatment plant. Prior approval from plant personnel as well as Local, State and Federal environmental agencies should be obtained. File environmental spill notifications if necessary.
Waste Disposal Methods:
DO NOT dispose of material in dry form in waste container-fire may result. Proceed with spill procedure as outlined above.'
Additional Precautions:
Do not attempt to recover solid material. Do not dispose of material in waste
- -container. Do not reuse empty container, but place in trash collection.
l19.' INDUSTRIAL HYGIENE CONTROL MEASURES Ventilation Requirements:
Work in well ventilated areas. Storage area should be well ventilated.
Specific Personal Protective Equipment:
Respiratory protection is not required under normal use, however when necessary, use NIOSH/MSHA approved respirator following manufacturers recommendations.
NIOSH approved dust mask is essential where dusting may occur.
Eye Protectior:' Chemical safety glasses should be worn.
Protective Gloves: Gloves should be worn. Rubber or other chemically resistant materials are recommended as suitable material.
Other Clothing and Equipment: Protective clothing should be worn'so as to minimize skin contact. Avoid contact with clothing.' Fire may result from contact of dry material with cloth or flammables.
SeenTetSrics n.Pg Severn Trent Services, Inc. Page 4
- 10. SPECIAL PRECAUTIONS Danger:
Highly corrosive. Causes skin and eye damage. May be fatal if swallowed. DO NOT get in eyes or on clothing. Wear goggles and CLEAN protective gloves when handling. Irritating to nose and throat. DO NOT breath dust and fumes. Wash thoroughly with soap and water after handling. Remove and wash contaminated clothing before reuse.
This product is toxic to fish. Do not discharge into lakes, streams, ponds or public waters unless in accordance with an NPDES permit.
Strong oxidizing agent. Mix this product only with water. Use clean dry utensils.
Open container only where adequate ventilation is available. Do not add this product to any dispensing device containing remains of any other product. In case of contamination/decomposition, do not reseal container. If possible, isolate container in open air and flood with large volumes of water.
I11. STORAGE AND DISPOSAL Storage:
Keep product dry and in a tightly closed container when not in use. Store in cool, dry, well ventilated area, keeping it away from heat sources and/or open flames.
Handle container with care-DO NOT drop, roll or skid. In case of decomposition, isolate container (if possible) and flood with large amounts of water to dissolve all material. Follow "Spill and Leak Procedures' as outlined in Section 8 of this Data Sheet.
Keep in original container. DO NOT store/transfer/repack this product in any other container without the approval/authorization of Severn Trent Services, Inc.
Disposal:
Follow "Spill and Leak Procedures" as outlined in Section 8 of this Data Sheet DO NOT reuse empty container. Wash thoroughly with water and discard clean container in a safe place.
Do not contaminate food or feed by storage, disposal or cleaning of equipment.
All information, recommendations and suggestions appearing herein concerning our products are based upon tests and data believed to be reliable; however, it is the user's responsibility to determine the safety, toxicity and suitability for his own use of the products described herein. Since the actual use by others is beyond our control, no guarantee, expressed or implied, is made Severn Trent Services, Inc., as to the effects of such use, the results to be obtained or the safety and toxicity of the products nor does EIC assume any liability arising out of use by others, of the products contained herein.
The information herein is not to be construed as absolutely complete since additional information may be necessary or desirable when particular or exceptional conditions or circumstances exist or because of applicable laws or government regulations. Nothing herein contained is to be construed as a recommendation to infringe any patent.
Printed in U.S.A. © Severn Trent Services, Inc., 2001 EIC-6224 Severn Trent Services, Inc. Page 5
MSDS NUMBER: MSDS-960 ISSUE DATE: 09/17/02 PAGE I OF 5 PRODUCT AND COMPANY IDENTIFICATION Church & Dwight Co., Inc.
469 N. Harrison Street Product Name Princeton, NJ 08543 SODIUM BICARBONATE -Informiation Phone:
(BAKING SODA) 1-609-683-5900 (USA)
Medical Emergencv Phone:
1-888-234-1828
- 2. COM POSITION/INFORMATION ON INGREDIENTS Chemical Ingredient (% by Weidht CAS Number SbdiumI Bicarbonate' 100% 144-55-8 Not hazardous under OSHA Standard 29 CFR 1910.1200.
Not a WHMIS controlled substance.-' --
- 3. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW White crystalline powder; no odor.,
Not a fire hazard.
No significant health or environmental effects associated with this material.
HMIS Rating Health 0 Fire - 0 Reactivity 0 Potential Health Effects EYE: Not an eye irritant.
SKIN CONTACT: Not a skin irritant.
INGESTION: Material is practically non-toxic. Small amounts (1-2 tablespoonfuls) swallowed during normal handling operations are not likely to cause injury as long as the stomach is not overly full; swallowing larger amounts may cause injury (see Note in Section IV).
INHALATION: None known.
Potential Health Effects (cont'd)
SUBCHRONIC EFFECTS/CARCINOGENICITY: Based on published studies on its effects in animals and humans, sodium bicarbonate is not teratogenic or genotoxic. Only known subchronic effect is that of a marked systemic alkalosis. Not classified as carcinogenic by NTP, IARC, OSHA, ACGIH orNIOSH.
I
( 469 H. Hardiso SL
- Prinecton, NJ 08543 I Yelephone: 800 .
453 CHURCH 6' DWIGHT CO., I N C.
Specialty Products Division
I a
-~ a a . 3 .
MSDS NUMBER: MSDS-960 ISSUE DATE: 09/17/02 PAGE 2 OF 5
- 4. FIRST AID MEASURES EYES: Check for and remove contacts. Flood eyes with clean flowing water, low pressure and luke warm (not hot) if possible, occasionally lifting eyelids.
INGESTION: If large amounts of this material are swallowed, do not induce vomiting.
Administer water if person is conscious. Never give anything by mouth to an unconscious person.
NOTE TO PHYSICIAN: Large doses may produce systemic alkalosis and expansion in extracellular fluid volume with edema.
- 5. FIRE FIGHTING MEASURES FLAMMABLE PROPERTIES FLAMMABLE LIMITS FLASHPOINT: Not combustible LFL: Not applicable METHOD USED: Not applicable UFL: Not applicable EXTINGUISHING MEDIA: Non-combustible material. Use extinguishing media appropriate for surrounding fire.
FIRE-FIGHTING INSTRUCTIONS: Carbon Dioxide may be generated making necessary the use of a self-contained breathing apparatus (SCBA) and full protective equipment (Bunker Gear).
Carbon dioxide is an asphyxiant at levels over 5% w/w. Sodium oxide, another thermal decomposition product existing at temperatures above 15640 F is a respiratory, eye, and skin irritant. Avoid inhalation, eye and skin contact with sodium oxide dusts.
UNUSUAL FIRE AND EXPLOSION HAZARDS: None known.
- 6. ACCIDENTAL RELEASE MEASURES Scoop up into dry, clean containers. Wash away uncontaminated residue with water.
- 7. HANDLING AND STORAGE Store in cool, dry areas and away from incompatible substances (see Section 10).
Sodium Bicarbonate reacts with acids to yield carbon dioxide gas which can accumulate in confined spaces. Do not enter confined spaces until they have been well ventilated and carbon dioxide and oxygen levels have been determined to be safe.
i 469 N.Harrison St.
Specialty Products Division
MSDS NUMBER: MSDS-960 ISSUE DATE: 09/17/02 PAGE 3 OF 5
- 8. EXPOSURE CONTROLS/PERSONAL PROTECTION RESPIRATORY PROTECTION: Dust mask required if total dust level exceeds 10 mg/m3 .
PROTECTIVE GLOVES: General purpose for handling dry product. Impervious gloves when working with solutions.
EYE PROTECTION: Safety glasses when handling bulk material orwhen dusts'are generated.
OTHER PROTECTIVE CLOTHING OR EQUIPMENT: Full cover clothing. Apron where splashing may occur when working with solutions.
- 9. PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE: White crystalline powder.
ODOR: None.
PHYSICAL STATE: Solid pH AS IS: Not Applicable pH (I% SOLN. w/v): 8.2 VAPORPRESSURE: Not applicable.
VAPOR DENSITY: Not applicable.
BOILING POINT: Not applicable.
- FREEZING/MELTING POINT: Not applicable.
SOLUBILITY IN WATER: 8.6 g/l 00 ml @ 20'C.
BULK DENSITY (g/cc): 62 Ib/Ft3
% VOLATILE: Not applicable.
VOLATILE ORGANIC COMPOUNDS: Not applicable.
MOLECULAR WEIGHT: 84.02
- 10. STABILITY AND REACTIVITY CHEMICAL STABILITY: Stable.
CONDITIONS TO AVOID: Temperatures above 65 0C (150'F).
INCOMPATIBILITY WITH OTHER MATERIALS: Reacts with acids to yield carbon dioxide.
Also may yield free caustic in presence of lime dust (CaO) and moisture (i.e., water, perspiration).
HAZARDOUS DECOMPOSITION PRODUCTS: Heating above 1000C may cause dangerous levels of carbon dioxide gas to be present in confined spaces. Yields sodium oxide if exposed to temperatures above 850'C. Avoid inhalation, eye and skin contact with sodium oxide.
HAZARDOUS POLYMERIZATION: Not applicable.
469 H. Harrion St. Prnceton NJ053 Telephone: 800 221 0453 CHURCH & DWIGHT CO., INC.
Specialty Products Division
S .
MSDS NUMBER: MSDS-960 ISSUE DATE: 09/17/02 PAGE 4 OF 5 II. TOXICOLOGICAL INFORMATION EYE EFFECTS: The material was minimally irritating to unwashed eyes and practically non-irritating to washed eyes (rabbits).
SKIN EFFECTS: Not a skin irritant or dermally toxic. Not a contact sensitizer.
ACUTE ORAL EFFECTS: Acute Oral-rat LD50 = 7.3 g/kg.
ACUTE INHALATION: LC"0 (rat) > 4.74 mg/I.
- 12. ECOTOXICOLOGICAL INFORMATION AQUATIC TOXICITY:
Daphnids: EC50 = 4100 mg/.
Bluegill: LC50 = 7100 mg/I.
Rainbow Trout: LC50 = 7700 mg/I.
PERSISTENCE: This product is not expected to persist in the environment.
BIOACCUMULATION: This product is not expected to bioaccumulate.
- 13. DISPOSAL CONSIDERATIONS Bury in a secured landfill in accordance with all local, state and federal environmental regulations.
Empty containers may be incinerated or discarded as general trash.
- 14. TRANSPORTATION INFORMATION D.O.T. SHIPPING NAME: Not regulated TECHNICAL SHIPPING NAME: Sodium Bicarbonate D.O.T. HAZARD CLASS: None U.N./N.A. NUMBER: None HAZARDOUS SUBSTANCE/RQ: None D.O.T. LABEL: None
- 15. REGULATORY INFORMATION CLEAN AIR ACT SECTION 61 1: Material neither contains nor is it manufactured with ozone depleting substances (ODS).
FEDERAL WATER POLLUTION CONTROL ACT (40 CFR 401.15): Material contains no intentionally added or detectable (contaminant) levels of EPA priority toxic pollutants.
FOOD AND DRUG ADMINISTRATION: Generally Recognized As Safe (GRAS) direct food additive (21 CFR 184.1736).
US DEPARTMENT OF AGRICULTURE: List of Proprietary Substances - Permitted Use Codes 3A, JI, Al, GI, and LI.
( 469 N. Harrison St
- Princeton. NJ 08543 61 Telephone: 800
- 221
- 0453
)
CHU RCH 6' DWI G H T CO., INC.
Specialty Products Division
MDNBRM S9IU MSDS NUMBER: MSDS-960 DE 1 02 ISSUE DATE: 09/17/02 .PAGE5 OF 5 CERCLA REPORTABLE QUANTITY: None OSHA: Not hazardous under 29 CFR 1910.1200 RCRA: Not a hazardous material or a hazardous waste by listing or characteristic.
SARA TITLE III:
Section 302, Extremely Hazardous Substances: None Section 311/312, Hazardous Categories: Non-hazardous Section 313, Toxic Chemicals: None Sodium Bicarbonate is reported in the EPA TSCA Inventory List.
This material is listed on the Canadian DSL.
Not classified as carcinogenic by NTP, IARC, OSHA, ACGIH or NIOSH.
This material is neither a volatile organic compound nor does it contain VOCs.
NATIONAL STOCKING NUMBER: 6810002646618, Contract No. DLA 40086C1 831 NSF STANDARD 60: Corrosion and Scale Control in Potable Water. Max use 200 mg/I.
EUROPEAN INVENTORY (EINECS): 205-633-8 JAPANESE INVENTORY (MITI): 1-164 AUSTRALIAN INVENTORY (AICS): Carbonic acid, monosodium salt.
- 16. OTHER INFORMATION SUPERSEDES DATE: 07/02/02 REASON FOR REVISION: Conversion to a 16 Section Format and added Ecotoxicological information.
For additional non-emergency health, safety and environmental information telephone 609.279.7705 or write to:
Church & Dwight Co. Inc.
R & D Technical Regulatory Affairs 469 North Harrison Street Princeton, New Jersey 08543 This Product Safety Data Sheet is offered solely for your information, consideration and investigation. Church & Dwight Co., Inc.
provides no warranties, either express or implied, and assumes no responsibility for the accuracy or completeness ofdata contained herein. Church & Dwight Co., Inc. urges persons receiving this information to make their own determination as to the information suitability for their particular application.
( 469 N.Harrlson St.
- Pnnceton, N) 08543 0: Ttlephone: 800
- 221
- 0453 )
CH U RC H &' DWI G HT C O., I N C.
Speciulty Products Division
BIO-SYSTEMS- . INTERNATIONAL M.S.D.S.
1, Identification of the substancelpreparation and companvlundertakina.
NAME BIO-SYSTEMS B500-F BLUE MSDS No B500-F BLUE USA Synonyms: bacterial products.
Common uses: waste water treatment and drain cleaner Supplied by: BIO-SYSTEMS International 1238 E. Inman Pkwy Tel: 608-365-9550 Beloit, WI Fax: 608-365-9467 53511 Emergency No. 800-232-2847 Emergency No. (24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br />) 608-365-9550
- 2. Composition/information on inaredients.
' Contains:' ' " '
Bacterial Cultures less than 1% by weight.
Blend of naturally occurring ingredients as a carrier including, corn and wheat bran and kelp.; 79%
Hazardous Ingredient I JImu .% Coc _' Classification Exposure CAS EINECS Slika. Amorphous 20 007631869 -
- 3. Hazards Identification.
Classification:
Bacterial culture non pathogenic
- 4. First Aid measures.
-Immediate medical attention is required in case of exposure by inhalation, contact with skin or eyes, or if swallowed.
Exposure Route Symptom: Treatment Inhalation Same as exposure to dust. Remove from-exposure, rest and keep warm. In severe cases, or if recovery is not rapid or complete seek medical attention.
Skin Contact Redness and irritation -Drench the skin with plenty of water.
Remove contaminated, clothing and wash before reuse. If large areas of the skin are damaged or if irritation persists seek medical attention.
Eye Contact Same as dust Irrigate thoroughly with water for at least 10 minutes. Obtain medical attention.
MSDS No. B500-F USA Page 1 of 4 Version No. 3.0 Revised March, 2003
B500-F USA Ingestion Irritation of gastrointestinal tract, nausea, Wash out mouth with water. Do not diarrhea induce vomiting. If patient is conscious, give water to drink. If patient feels unwell seek medical attention.
Immediate Treatment I Antidote: symptomatic treatment Delayed Effects: bacterial infection
- 5. Fire Fighting measures.
Suitable Extinguishers: water Unsuitable Extinguishers:
Hazardous Combustion Products: none in normal use. Large dust accumulations can be explosive, similar to a grain dust explosion. If dust is created, static electriciity may accumulate and create a fire hazard.
Special Equipment for Fire Fighting: self contained breathing apparatus
- 6. Accidental Release measures.
Personal Precautions: Wear appropriate PPE - See section 8 Environmental Precautions: The bacteria and carriers are naturally occurring and should not pose an environmental risk.
Clean up Procedure: Vacuum or sweep up avoiding generation of dust. Place in suitable labelled containers and hold for waste disposal. Wash spill site with water. If bacterial contamination is an issue use chlorine to kill the bacillus spores.
- 7. Handlina & Storage.
Handlina Ventilation: Good general ventilation.
Recommended procedures & equipment: avoid creating dust Storage Temperature range: 0 deg Cto 40 deg Cfor product viability only.
Humidity range: less than 40% for long term exposure of unprotected product for product viability only.
Keep away from: See section 10 Suitable storage Media: original container with closed lid Precautions against static discharge: recommended.
- 8. Exposure Controlsipersonal protection.
Exposure standards:
Component LTEL (8h TWA) STEL (15 mins) Type None Personal Protective Equipment:
Respiratory: Dust mask Hand: Wash hands after use. Gloves recommended Eye: Safety glasses or goggles recommended.
MSDS No B500-F USA Page 2 of 4
-. B500-F USA
,Skin: - Wash after exposure. Overalls and boots recommended Environmrental controls: ' Users should be aware of environmental considerations and their duties under the environmental protection act.
Hygiene Measures: Always wash thoroughly after handling chemicals.
- 9. Physical & Chemical Properties.
Appearance Blue powder free flowing Odor Yeast like odor pH Neutral 6.0 to 7.0 in water dispersion Boiling Point/range Not Applicable Melting Pointlrange Not Applicable Flash point Not Applicable Flammability Not flammable under normal conditions of storage and handling.
Autoignition temperature Not Applicable Explosive limits Na except in presence of large dust cloud Oxidizing Properties Non" Vapour Pressure 'Not Applicable Relative density 0.6 to 0.8 Solubility in water Not soluble. Disperses in water.
Solubility in solvent Not soluble Partition coefficient Not Applicable Viscosity Not Applicable Vapour density Not Applicable Evaporation rate Not Applicable Conductivity Not Applicable
- 10. StabilityA&Reactivity.
Stability: Stable under normal storage and handling conditions.
Conditions to avoid: Accumulations of product in enclosed spaces and generation of dust.
Materials to avoid: Acids and Alkalies may inactivate the bacterial cultures.
Hazardous decomposition products: oxides of carbon, silicon dioxide, carbon dioxide, and traces of incompletely burned carbon products.
11, Toxicological Information.
Toxological effects: Low Acute oral toxicity although ingestion will cause irritation of the gastrointestinal tract and may result in nausea and diarrhea. .May cause mild mechanical irritation to eyes, skin and mucous membranes. May cause irritation from allergic reaction, especially to people that have a history of allergic reaction. '
LDLO IDo0 oral-rat skin-rabbit
B500-F USA Environmental Effects: Minimal impact under normal conditions of use and storage. The bacterial cultures are naturally occurring soil type organisms. The carriers are naturally occurring materials.
Mobility: disperses in water Degradability: contents are biodegradable Bioaccumulative potential: Not Known Aquatic Toxicity: Not Known
- 13. Disposal considerations.
Substance: Via an authorized waste disposal contractor to an approved waste disposal site, observing all local and national regulations.
Container: As substance.
- 14. Transport Information. Not regulated for transport UN number Class Primary Hazard Subsidiary Hazard Packing Group Emergency Action Code H.l. Number Marine Pollutant Proper Shipping name Water treatment compounds, bacterial culture.
- 15. Regulatory Information.
Label Name BIO-SYSTEMS B500-F BLUE Symbols no risk or safety phrases stipulated Risk Phrases no risk or safety phrases stipulated Safety Phrases no risk or safety phrases stipulated E.C. No Additional labeling:
Use of this material may be governed by the following regulations: - (users are advised to consult these regulations for further information).
The information contained in this data sheet does not constitute an assessment of workplace risks.
- 16. Other Information.
This material must not be used for direct contact with food:
Further details may be available upon request from your local BIO-SYSTEMS Corp. distribution site.
Other The product has been shown to be free of Salmonella and Shigella using the procedures outlined by AOAC and USDA.
Legal Disclaimer:
The above information in this MSDS was obtained from sources which we believe are reliable.
HOWEVER, THE INFORMATION IS PROVIDED WITHOUT ANY WARRANTY, EXPRESSED OR IMPLIED, REGARDING ITS CORRECTNESS. The conditions or methods of handling, storage, use and disposal of the product are beyond our control and may be beyond our knowledge. FOR THIS AND OTHER REASONS, WE DO NOT ASSUME RESPONSIBILITY AND EXPRESSLY DISCLAIM LIABILITY FOR LOSS, DAMAGE OR EXPENSE ARISING OUT OF OR IN ANY WAY CONNECTED WITH THE HANDLING, STORAGE, OR USE OF THIS PRODUCT.
MSDS No B500-F USA Page 4 of 4
Material Safety Data Sheet AQUAFIX, Inc.2o05/04 S.end Section 1- Product and Company Identificationl Product Name: D-Foam 3000 -- - -
AQUAFIX, Inc P.O. Box 8682 Madison, WI 53708-8682
- p. 888-757-9577
. -866-636-1493 --- ---
Section 2- Composition and Information on Ingredients l
.Chemical Family: polyglycol Product contains no known hazardous components as listed In 29 CFR 1900.1000 Chemical Name: Oxirane, methyl-polymer CAS #900311-6 100%
s :.
Section 3 - First Aid Measures . ---1. - ~ I: -:1..
Eye Contact- Immediately rinse eyes with plenty of water. Remove any contact lenses and continue rinsing for at least 15 minutes. If Irritation persists, consult a physician.
Skin Contact- In keeping with good hygiene practices, wash exposed areas with soap and water.
Inhalation- Remove to fresh air.-
Ingestion- If Swallowed, dilute with water and INDUCE VOMITING. Call a physician Immediately
. 0 , . .. . ..- - . .....
I. .,
[Section 4- Fire and Explosion Data Flammable Limits In air, % by volume, ND Flash Point-Greater than 300 degrees F, PMCC Auto Ignition-Temperature not available Combustion-Produces carbon dioxide, carbon monoxide, smoke, and fumes Fire Fighting Instructions-Use dry chemical, foam, carbon dioxide or water fog Fire Fighting Protection-Wear self-contained breathing apparatus and protective clothing.
Section 5-Accidental Release Measures I Accidental Spill - Wipe surface to prevent slippery surface. Soak up with an inert absorbent material and dispose of in an appropriate waste container for combustible waste.
Large Spill- Contain spill and dispose of in accordance with local, state and federal regulations.
Section 6- Handling and Storage Store in a cool, dry place. Store In a tightly closed container Section 7- Exposure Controls/PersonalProtection Ventilation- Keep adequate ventilation Eye Protection- Eye irritant, wear eye protection.
Skin Protection- Use gloves if prolonged contact is expected.
Respiratory- Inhalation of vapors may result In respiratory Irriatatlon Working with- Wash hands with soap and water.
Section 8- Physical and Chemical Properties Description-Liquid Specific Gravity- 1.02 @ 25 degrees Celsius pH-7.0 Vapor Density-Greater than 1 Color-Slightly Cloudy Odor -mild polyol volitale-Less than 1%
Section 9-Stability and Reactivity Data Chemical Stability- The product Is stabile incompatibility- None Conditions to avold- Keep away from extreme heat, sparks, open flame and strong oxidizers.
HazardousPolymerization - Thermal Decompostion my produce carbon oxides.
Corrosive Properties- Not Corrosive Oxidizer Properties- Not an oxidizer
[ Section 10-Disposal Concerns Dispose of In accordancewith state, local, and federal regulations
[Section 11- Regulatory Information HMIS Ratings - Health 1,Fire-1, Reactivity-O Additional Regulatory Remarks - The Information In the MSDS was obtained from sources which we believe to be reliable. However, the Information Is provided without any warrantyexpressed or Implied regardingIts correctness. Some Information presented and conclusions drawn herein are from sources other than direct test data on the substance Itself. This MSDS was preparedand Is to be used only for this product. No representation,warrantyor guaranteeof any kind, express or Implied, Is made as to Its accuracy, reliabilityor completeness and we assume no responsibilityfor any loss, damage orexpense, direct of consequential, arisingout of use. It Is the user's responsibilityto satisfy himself as to the suitablenessand completeness of such Information for his own particularuse.
Attachment 5 E Exel n,,
Exelon Generation www.exeoncorp.com Nuclear Quad Cities Generating Station 22710 206th Avenue North Cordova, IL 61242-9740 Tel 309-654-2241 SVP-04-079 CERTIFIED MAIL RETURN RECEEPT REQUESTED September 10, 2004 Mr. Blaine Kinsley Permit Writer, Quad Cities Station IEPA Permit Section Illinois Environmental Protection Agency Water Pollution Control, Permit Section #15 1021 North Grand Ave. East PO Box 19276 Springfield, IL 62794-9276
Subject:
Renewal of NPDES Permit No. ILA005037 Quad Cities Nuclear Power Station Dear Mr. Kinsley Exelon Generation Co., LLC, Quad Cities Nuclear Power Station, would like to request an exemption from the sampling and analysis for pollutants categorized as GC/MS Fraction Compounds in Part V-C of the Consolidated Permit Application for the subject NPDES permit application. Relief from this sampling requirement was requested and granted by the Agency in February 1998 in preparation for the previous NPDES permit application, per 40 CFR, Part 122, Subpart B, Section 122.21. Based on the above information, we believe that this request is appropriate and would like to thank you in advance for your consideration in this matter.
If you have any questions, please contact Mark Stuhlman at (309) 227-2765.
Sincerely, SitE Vice President Quad Cities Station TJlMS/tsr cc: J. Bolte, NGG Environmental Mark Stuhlman Letterbook Q:-\SvSYP 2004=J79vAc .... ... ..
bet_-f ...... A . * *.-. -
Attachment 6 Exe k n M Exelon Generation Company. LLC www.exeloncorp.com Nuclear Quad Cities Nuclear Power Station 22710 206' Avenue North Cordova. IL61242-9740 SVP-04-097 November 17, 2004 Certified Mail Mr. Al Kellar Illinois Environmental Protection Agency Manager, DWPC Permit Section #15 1021 North Grand Avenue East P. 0. Box 19276 Springfield, Illinois 62794-9276
Subject:
Quad Cities Generating Station Request for Schedule to Submit Information to Comply with the Phase II 316(b) Rule (40CFR Part 125 Subpart J)
By this letter Exelon Generation Company, LLC, ("Exelon') requests a schedule for submitting the information required by USEPA's New Phase II 316(b) Rule for cooling water intake structures for the Quad Cities Generating Station ("Quad Cities"). We ask that we be allowed to submit to you the information required by 40 CFR 125.95 by no later than January 7, 2008. For the reasons described below, this date is as "expeditious as practicable" for Quad Cities to develop, prepare and submit the required information.
As you know, on July 9, 2004, USEPA published its final rule prescribing how "existing facilities" may comply with Section 316(b) of the Clean Water Act. 69 Fed. Reg. 41575, 41683 (July 9, 2004). For most existing facilities, this rule wvill require a large amount of data to establish "best technology available" for the facility's intake structure and to demonstrate compliance with the rule.
Quad Cities is a "Phase II existing facility" within the meaning of 40 CFR 125.91. As such, it is required to comply with the Phase II rule, and in particular to submit the studies and information required by 40 CFR 125.95.
Section 125.95 of the new rule requires detailed studies and other information to establish what intake structure technology or other measures will be used to comply with the rule. Ordinarily, this material is to be submitted with the facility's next application for renewal of its NPDES permit. See 40 CFR 125.95, 122.21(r)(1)(ii), 122.21(d)(2). Forpermits that expire less than four years after the rule was published on July 9, 2004 (that is, before July 9, 2008), the operator may have up to three and half years to submit the information, so long as it is submitted "as expeditiously as practicable." See 40 CFR 125.95(a)(2)(ii). The facility may have even longer, until the end of the permit term, under 40 CFR 122.21 (d)(2)(i), if the permitting agency agrees.
Q.1SVPVSVP 2004\097.doc
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Illinois Environmental Protection Agency November 17, 2004 Page 2 of 5 The current NPDES permit for Quad Cities expires on May 31, 2005, well before July 9, 2008.
We, therefore, request that Exelon be allowed to submit the information called for by Section 125.95 for Quad Cities as expeditiously as practicable, which, as explained below, will require until January 7, 2008.
In order to satisfy the "expeditiously as practicable" requirement, Exelon began taking steps regarding data collection and analysis even before the rule was published. We began as early as May 2004, by organizing our internal 316(b) team and utilizing an outside consultant to help understand and analyze the Phase II Rule requirements and determine our data collection needs.
This process included compiling and assessing previously collected impingement data as well as ongoing collection of impingement data relative to the data collection requirements of the Phase II Rule. Quad Cities also began to analyze compliance alternatives and related costs. As required by the Rule, Quad Cities has begun compiling and organizing its cooling water system data, existing intake technology information and source water flow information. Since the Rule's publication, Exelon also assessed and obtained management approval of an internal budget to implement 316(b) activities related to Quad Cities Station. Exelon is coordinating and working with the national Utilities Water Act Group and the Illinois Environmental Regulatory Group regarding rule requirements and implementation. Despite our early start, we will still need until January 7, 2008, to complete the studies and collect the information, and prepare the submittal required by 40 CFR 125.95. Our detailed schedule is explained below.
Proposal for Information Collection Under 40 CFR 125.95(a)(1), we must submit to you a Proposal for Information Collection
("PIC"). The PIC must contain the items listed in 40 CFR 125.95(b)(1), including a description of proposed and/or implemented technologies, operational measures, and/or restoration measures to be evaluated, a list and description of historical studies characterizing impingement mortality and entrainment and/or the physical and biological conditions in the vicinity of the cooling water intake structures and their relevance to the proposed study. For existing data, it must demonstrate the extent to which the data are representative of current conditions and that the data were collected using appropriate quality assurance/quality control procedures. The PIC must also include a summary of past or ongoing consultations with federal, state and wildlife agencies and a copy of their written comments, as well as a sampling plan for any new field studies describing all methods and quality assurance/quality control procedures for sampling and data analysis.
Impingement Mortality and/or Entrainment Characterization Study The Rule requires an Impingement Mortality and/or Entrainment Characterization Study for affected facilities. The study must include (i) taxonomic identifications of all life stages of fish, shellfish, and any species protected under federal, state, or tribal law that are in the vicinity of the cooling water intake structures and are susceptible to impingement and entrainment; (ii) a characterization of all life stages of fish, shellfish, and any protected species, including a description of the abundance and temporal and spatial characteristics in the vicinity of the cooling water intake structures, based on sufficient data to characterize annual, seasonal, and diel variations in impingement mortality and entrainment (e.g., related to climate and weather
- \SVP\SVP200409.do
Illinois Environmental Protection Agency November 17, 2004 Page 3 of 5 differences, spawning, feedings, and water column migration). These may include historical data that are representative of current operation of the facility and of biological conditions at the site.
We must also document the current impingement mortality and entrainment of all life stages of fish, shellfish, and protected species and provide an estimate of impingement mortality and entrainment to be used as the "calculation baseline." See 40 CFR 125.95(b)(3)(iii). This may include historical data representative of the current operation of the facility and of biological conditions at the site. Impingement mortality and entrainment samples to support the calculations must be collected during periods of representative operational flows for the cooling water intake structure, and the-flows associated with the samples must be documented.
Quad Cities is currently analyzing its past and ongoing data collection in order to determine what, if any, additional sampling may be needed in order to satisfy this requirement. We estimate that we will need until March 31, 2005, to complete this analysis. If the Station determines that additional sampling and study should be conducted, we estimate that we will complete these activities by December 31, 2006.
Quad Cities' PIC submittal will directly follow our analysis of whether any additional sampling should be conducted, which is scheduled to be completed by March 31, 2005. We estimate that will need until April 15, 2005, to finalize and submit the PIC to IEPA.
We will be interested in learning and understanding your reaction to the PIC. Consistent with the rule, we will ask that you either approve it or advise us of any needed changes within 60 days following our submittal. See 40 CFR 125.95(a)(1), 125.95(b)(1). In order to expedite your review and understanding of our PIC, we will be available to meet and discuss our PIC with you in person.
Evaluation of Compliance Alternatives - Comprehensive Demonstration Study While we are assessing and implementing any additional sampling obligations, we will also be continuing to evaluate available 316(b) compliance alternatives for Quad Cities, including the possibility of using design and construction technologies and/or operational measures; restoration measures; and/or site- specific requirements. In addition, we must prepare a Verification Monitoring Plan to confirm our results. Below are descriptions of these requirements. We estimate that we will need until May 2007, to complete the required analysis and internally prepare and review our CDS. Following the preparation of the CDS, we will develop our Quad Cities NPDES permit renewal application and engage in any needed meetings and/or other dialogue with IEPA and USEPA. We plan to complete these steps by no later than December 1, 2007 so that we will submit our 316(b) Phase II requirements to EPA by no later than January 7, 2008.
Design and Construction Technologv Plan Any Design and Construction Technology Plan must explain the technologies and/or operational measures that we have in place and/or have selected to meet the requirements of the rule.
Q.\SVP\SVP 2004\097.doc.
. .~ . *.. .,,E.... S..
Illinois Environmental Protection Agency November 17, 2004 Page 4 of 5 This Design and Construction Technology Plan must contain a large amount of information, as described in 40 CFR 125.95(b)(4)(A)-(D). This information includes (A) a narrative description of the design and operation of all design and construction technologies and/or operational measures, including fish handling and return systems, and information that demonstrates the efficacy of the technologies and/or operational measures; (B) a narrative description of the design and operation of all design and construction technologies and/or operational measures and information that demonstrates the efficacy of the technologies and/or operational measures for entrainmnent; (C) calculations of the reduction in impingement mortality and entrainment of all life stages of fish and shellfish that would be achieved by the technologies and/or operational measures we have selected; and (D) design and engineering calculations, drawings, and estimates prepared by a qualified professional to support the descriptions described above.
Technology Installation and Operation Plan (TIOP)
Assuming we decide that the best way to comply with the Phase II rule is to use design and construction technologies and/or operational measures, in whole or in part, we must submit to you the following information, in accordance with 40 CFR 125.95(b)(4)(ii): (A) A schedule for the installation and maintenance of any new design and construction technologies; (B) a list of operational and other parameters to be monitored and the location and frequency that we will monitor them; (C) a list of activities we will undertake to ensure to the degree practicable the efficacy of installed design and construction technologies and operational measures and our schedule for implementing them; (D) a schedule and methodology for assessing the efficacy of any installed design and construction technologies and operational measures in meeting applicable performance standards or site-specific requirements, including an "adaptive management plan" for revising design and construction technologies, operational measures, operation and maintenance requirements, and/or monitoring requirements in the event our assessment indicates that applicable performance or site-specific requirements are not being met; and (E) if we choose the compliance alternative in 125.94(a)(4) (wvedge-wire screens or a technology approved by the state), documentation that the appropriate site conditions described in 125.99(a) or (b) exist at our facility.
Restoration Plan If we determine that we will use restoration measures to comply with the new rule, in whole or in part, we must provide you a Restoration Plan. This must include the information described in 40 CFR 125.95(b)(5). It must include a plan using an adaptive management method for implementing, maintaining, and demonstrating the efficacy of the restoration measures that we select and for determining the extent to which the restoration measures, or the restoration measures in combination with design and construction technologies and operational measures, have met the applicable performance standards.
Site-Specific Reqiuirements If we determine that site-specific requirements are appropriate because the cost of complying with the Phase II rule will be "significantly greater" than either the cost that EPA considered in its rulemaking or the benefits of complying with the rule, we will have to submit the information Q:\SVP\SVP 2004\097.doc
Illinois Environmental Protection Agency November 17, 2004 Page 5 of 5 described in 40 CFR 125.95(b)(6). This includes a Comprehensive Cost Evaluation Study and, for the cost-benefit analysis, a Benefits Evaluation Study. We must also include a Site-Specific Technology Plan describing and justifying the site-specific requirements.
Verification Monitoring Plan Finally, we must prepare a Verification Monitoring Plan. See 40 CFR 125.95(b)(7). This is a plan to conduct, at a minimum, two years of monitoring to verify the full-scale performance of the proposed or already implemented technologies and/or operational measures.
Conclusion Despite our early efforts, we recognize that collecting, generating, compiling, and analyzing the large amount of information required by the Phase II 316(b) rule will require a substantial effort.
This may require us to generate significant new biological information and perform complex technical analysis of compliance alternatives. We hope to coordinate closely with your Agency as we collect the necessary information, perform our analyses, and determine what combination of technology, operational measures, or restoration measures will best meet the Phase II rule for Quad Cities. We hope that your staff will be available to consult with us over the next few months as we complete these efforts.
For the above reasons, we request that we be allowed until January 7, 2008, to submit the information required for a permit application by the Phase II Rule, 40 CFR Part 125 Subpart J.
Sincerely, thy J. Tulon te Vice President Quad Cities Generating Station Cc: Blaine Kinsley, IEPA Permit Section Vicki Neels Mark Stuhlman John Petro Robert King Larry LaJeone Letterbook Q:ASVP\SVP 2004\097.doc
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