ML20237H816
| ML20237H816 | |
| Person / Time | |
|---|---|
| Site: | Calvert Cliffs  |
| Issue date: | 08/12/1987 |
| From: | Martin T NRC OFFICE OF INSPECTION & ENFORCEMENT (IE REGION I) |
| To: | Tiernan J BALTIMORE GAS & ELECTRIC CO. |
| References | |
| NUDOCS 8708250161 | |
| Download: ML20237H816 (2) | |
Text
.
12 AUG 1987 Docket Nos. 50-317 50-318 Baltimore Gas and Electric Company ATTN: Mr. J. A. Tiernan Vice President Nuclear Energy P. O. Box 1475 Baltimore, Maryland 21203 Gentlemen:
Subject:
Results of Non-Radiological Chemistry Standards Inspection Activities for All Region I Licensees.
Routine safety inspections were conducted by this office during the period 1985 to 1986 at USNRC Region I licensees in the area of non-radiological water chemistry laboratory operations.
The purpose of this report is to present results of all licensees inspected, as well as results of measurements made by Brookhaven National Laboratory.
Each licensee is identified by a code.
Your code is 14.
No reply to this letter is required.
Sincerely, l
0 ginal Signed y 7
dhdd Thoma T. Martin, Director
()
Divisi.on of Radiation Safety and Safeguards
Enclosure:
Combined Results of Non radiological Standards Comparison Inspection Activities for Region I Licensees i
l 0FFICIAL RECORD COPY LTR RAD RESULTS - 0037.0.0 06/09/87 8708250161 870812 ggQb PDR ADOCK 05000317 g(
G PDR
Baltimore Gas and Electric Company 2
cc w/ encl:
M. Bowman, General Supervisor, Technical Services Engineering Thomas Magette, Administrator, Nuclear Evaluations Public Document Room (PDR)
Local Public Document Room (LPDR)
Nuclear Safety Information Center (NSIC)
NRC Resident Inspector State of Maryland (2) bec w/ encl:
Region I Docket Room (with concurrences)
Management Assistant, DRMA (w/o encl)
DRP Section Chief T. Kenny, SRI, Salem S. McNeil, LPM, NRR Robert J. Bores, DRSS D
0 h
RI: DSS RI:DRSS F I-RSS RI:DRSS R :D SS Kottan/geb/mlb Zibulsky Fi iak Bellamy Mar in f/pf/87 6/l$/87 jf)k/87 G/h/87 6/ /7 0FFICIAL RECORD COPY LTRS RAD RESULTS - 0002.0.0 08/18/87
1 U.S. NUCLEAR REGULATORY COMMISSION REGION I l
Combined Results of Non-Radiological Standards Comparison Irspection Activities for Region I Licensees Inspectors:
M Harvey Zibulsky, Chem 4At, Effluents Radiation ProtectionSection,JP&,RJB,DRSS T. T. krff&
James J. Kottan, Ra'diation Laboratory Specialist, Effluents Radiation Prote ion Sectio, EP&RPB, DRSS
/A)/,(
C(J b '\\
/
Approved By:
g Walter J~. Phsciak, hieM Effluents Radiation i
I Protection Secti
, EP&RPB, DRSS
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Details 1.
Introduction Region I has implemented an inspection orogram in the area of non-radio-
]
logical water chemistry.
As part of this inspection program, licensees i
l are required to analyze test standards prepared by Brookhaven National Laboratory (BNL) for NRC Region I.
The data from the first round of this part of the inspecti). program are now available from all power reactors in Region I and are Iresented here.
l The data as presented permits each Region I nuclear power plant chemistry laboratory to compare its performance with all other Region I nuclear power plant laboratories. The data for the BNL known values are also presented so that comparison of the average from all Region I sites to the known value may be made.
The data were taken from inspection l
reports, but are coded here. The letter transmitting this report identified the individual code (s) for each addressee.
Section 3.0 lists the inspection reports data were taken from.
The data are presented in Appendix B.
2.
Data Analysis The data were analyzed as follows.
1.
The analytical data from al', Regicn I sites were entered into a data base at BNL. The analytical data consisted of each licensee's result for each analyte at each aralyzed concentration.
2.
At each concentration a grand average and standard deviation were calculated using the data from all sites.
3.
A range consisting of the grand average plus or minus two standard l
deviations was established. Any values outside of this range were considered outliers.
4.
A new grand average and standard deviation were calculated excluding the outliers determined in step 3.
5.
A range consisting of the grand average plus or minus two standard deviations was again established.
Any values outside this range were considered outliers.
l 6.
The above process was repeated until a range was obtained with no outliers.
This range was used for the data comparison.
A sample calculation is presented in Appendix A.
1 l
It must be recognized that the data used to generate the averages are not of equal weight.
For example, some laboratories were permitted to rea,1alyze the standards if problems could be identified and corrected during the inspection. Also some of the BNL standards were diluted to different final concentrations by the licensees prior to analysis to allow l
them to analyze within their calibration range.
The results were then 1
normalized back to the original dilution in order to enable comparison.
l In addition, all methods of analysis for a particular analyte were grouped together.
3.
References:
Site Docket No.
Inspection No.
Beaver Valley #1 50-334 85-07 l
Beaver Valley #2 50-412 86-14 1
Calvert Cliffs #1 50-317 86-08 Calvert Cliffs #2 50-318 86-08 i
l FitzPatrick 50-333 85-23 Ginna 50-244 85-14 Ct. Yankee 50-213 85-24 Hope Creek 50-354 85-59 Indian Pt. #2 50-247 86-07 i
Indian Pt. #3 50-286 86-04 Limerick 50-352 86-10 Maine Yankee 50-309 85-33 Millstone #1 50-245 86-04 Millstone #2 50-336 86-04 Millstone #3 50-423 86-13 l
Nine Mile Pt. #1 50-220 85-10 i
Oyster Creek 50-219 86-16 Peach Bottom #2 50-277 85-28 Peach Bottom #3 50-278 85-26 Pilgrim 50-293 85-23 Salem #1 50-272 86-03 Salem #2 50-311 86-03 Seabrook 50-443 86-22 Shoreham 50-322 86-11 Susquehanna #1 50-387 85-27 Susquehanna #2 50-388 85-22 Three Mile Island #1 50-289 85-17 Vermont Yankee 50-271 85-38 Yankee Atomic 50-29 85-21
l l
/
1 Appendix A Sample Calculation l
The chloride measurements at approximately 30 ppb were chosen for this example.
Step 1 i
The following data were in the BNL'd3ta base for chloride at approximately l
~30 ppb.
Site No.
Value (ppb) Site No.
Value (ppb)
Site No.
Value (ppb) j i
1 30.7 16 27.1 31*
26.7 i
2 30 17 39.3 32*
71 1
3 30.2 18 28.8 33 act analyzed t
4 24.3 19 28 j
5 30.9 20 29.3 1
6 30.9 21 23.3 J
,7 32.7 22 28.9 1
0 38.3 23 not analyzed
)
9 32 24 30.7 10 34.2 25 not analyzed 11 37 26*
41.3 12 28.7 27 33
_j 13 not analyzed 28 l
14 30.7 29 52
- ncrmalized data l
1 15*
43.35 30 29.7 I
Step 2 A grand average and standard deviation were calculated for all 28 values:
i Grand average ='33.6804 I xi n
Standard deviation = 9.5116 I (xi-x)2 y*
~
~
n-1 Step 3 From step two above, a range of 52.7036 - 14.6572 was established.
The value I
from site 32 was determined to be an outlier.
Step 4 A new grand average and standard deviation were calculated excluding the outlier determined in' Step 3.
grand average = 32.2981' (n=27) standard deviation - 6.1966
j l
)
Appendix A
]
Sample Calculation (continued) l Step 5 From step 4 above a re.nge of 44.6914 - 19.9048 was established.
The value from site 29 was determined to be an outlier.
l Step 6 The above process was completed through seven more iterations as follows:
n x,
s range outlier sites 26
- 31. 04 4.8796 41.2996 - 21.7812 5, 15 24 30.6417 3.8514 38.3444 - 22.9390 17 23 30.2652 3.4571 37.1794 - 23,3510 8, 21 21 30.2143 2.7368 35.6880 - 24.7406 4, 11 19 30.1684 1.9542 34.0768 - 26.2600 10 18 29.9444 1.7419 33.4283 - 26.4605 None Thus out of a total of 28 va'iaes 10 were outliers. The range of 33.4283 -
26.4605, whic'. contained no catliers, was used for final comparison.
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