ML20209G624

From kanterella
Jump to navigation Jump to search
Proposed Tech Spec Change 78,deleting Limiting Condition for Operation 3.3.3.6,Surveillance Requirement 4.3.3.6 & Associated Bases,Based on Analysis Which Indicates That Detectors Provide No Significant Margin of Safety
ML20209G624
Person / Time
Site: Sequoyah  Tennessee Valley Authority icon.png
Issue date: 01/21/1987
From:
TENNESSEE VALLEY AUTHORITY
To:
Shared Package
ML20209G615 List:
References
NUDOCS 8702050412
Download: ML20209G624 (54)


Text

{{#Wiki_filter:/ l ENCLOSURE 1 Proposed Technical Specification Changes SEQUOYAH NUCLEAR PLANT UNITS 1 AND 2 (TVA SQN TS 78) Proposed changes to delete LCO 3.3.3.6, SR 4.3.3.6, and associated bases (units 1 and 2) of the technical specifications. List of Affected Pages Unit 1 3/4 3-54 B 3/4 3-3

                                                                  ~~

Unit 2 3/4 3-55 B 3/4 3-3 8702050412 870121 PDR ADOCK 05000327 p PDR

(

       )

O INSTRUMENTATION CHLORINE DETECTION SYSTEMS LIMITING CON 0! TION FOR CPERATION 3.3.3. Two indeoendent chlorine detection systems, with their alar./ trip setpoint adjusted to actuate at a chlorine concentration of less han or equal to 5 r m, shall be OPERABLE. APPLICABILITY: LL MODES ACTION: -

a. With one chlo 'ne detection system inoper le, restore the inoperable detection syste. to OPERABLE status wi in 7 days or within the next 6 hours initiate a d maintain operat4 n of the control room emergency ventilation system 1 the recircul ion mode of operation,
b. With both chlorine dete ion s' stem inoperable, within I hour initiate and maintain operation of " control room emergency ventilation system in tr.e recirculati de of operation,
c. The provisions of Sp ification 0.4 are not applicable.
d. The provisions Specification 3.0. are not applicable in Mode 6.

SURVEILLANCE RC' IREMENTS

                        -                                             x 4.3.3.~    Each chlorine detection system shall be demonstrat        GPERABLE by perf mance of a CHANNEL CHECK at least once per 12 hours, a "HANNEL FUNCTICNAL Te i at least once per 31 days and a CHANNEL CALIBRATION at le t once per 8 months.
                    %$        Spac.s he ca.b~t on  be < N e.ch SEQUOYAH - UNIT 2                       3/4 3-55

i s .

   -4 INSTRUMENTATION CHLORINE DETECTION SYSTEMS LIMITING CONDITION FOR OPERATION 3.3.3.6                 independent chlorine detection systems, with their alarm /                  p setpoints a usted to actuate at a chlorine concentration of less th                              or equal to 5 pp              shall be OPERABLE.

APPLICABILITY: A MODES ACTION:

a. With one chlor detection system inopera e, restore the inoperable detection system OPERABLE status withi 7 days or within the next 6 hours initiate an maintain operatio of the control room emergency ventilation system in he recirculat n mode of operation.
b. With both chlorine' detect n sy ems inoperable, within I hour initiate and maintain operation of t ontrol room emergency ventilation system in the recirculation e of operation,
c. The provisions of Spec cation 3. 4 are not applicable,
d. The provisions of pecification 3.0.3 e not applicable in MODE 6.

SURVEILLANCE REOUJR MENTS ~

                                                /
         ~

4.3.3.6 ach chlorine detection system shall be demonstrated OPER E by perfor ance of a CHANNEL CHECK at least once per 12 hours, a CHANNEL NCTIONAL TES at least once per 31 days and a CHANNEL CALIBRATION at least once 18 iths. (5 5pCC.thtcakion de,Qd 6 SEQUOYAH - UNIT 1 3/4 3-54

 *-,.%.. w- e-   -w w a . . , _ , .                                ,m               -          -   ~ . . re.+. . ,     e    ~~

INSTRUMENTATION BASES 3/4.3.3.4 METEOROLOGICAL INSTRUMENTATION The OPERABILITY of the meteorological instrumentation ensures that sufficient meteorological data ia available for estimating potential radiation doses to the public as a result of routine or accidental release of radioactive materials to the atmosphere. This capability is required to evaluate the need for initiating protective measures to protect the health and safety of the public and is consistent with the recommendations of Regulatory Guide 1.23, "Onsite Meteorological Programs," February 1972. 3/4.3.3.5 REMOTE SHUTDOWN INSTRUMENTATION The OPERABILITY of the remote shutdown instrumentation ensures that sufficient capability is available to permit shutdown and maintenance of HOT STANDBY of the facility from locations outside of the control room. This capability is required in the event control room habitability is lost and is consistent with General Design Criteria 19 of 10 CFR 50. 3/4.3.3.6 CHLORYDETECTION5TStfWs-

                                    -n i s -;. u.4ic d om        Lela W Thr-ORERQILITY f the chlorine detection system ensup.s. that- suf ficient capability is a                                         t Tprotective action in the event of an acciden to    promptly bshl    in    detec@This capability is required to alcase.

protect control room personn W ah fr coQent with the recommendations of Regulatory GuideJ 95r* Protection of Nuclear P3We t Control Room Operators Ag /ainst an Accidental Chlorine Release," February 1975. 3/4.3.3.7 ACCIDENT MONITORING INSTRUMENTATION The OPERABILITY of the accident monitoring instrumentation ensures that sufficient information is available on selected plant parameters to monitor and assess these variables following an accident. This capability is consistent with the recommendations of Regulatory Guide 1.97, " Instrumentation for Light-Water-Cooled Nuclear Power Plants to Assess Plant Conditions During and Following an Accident," December 1975. Sequoyah has four separate methods of determining safety valve position (i.e. , open or closed),

a. Acoustic flow monitors mounted on each safety valve line (one per valve).

A flow indicating module in the main control room is calibrated to detect failure of a valve to reclose. An alarm in the main control room will actuate when any valve is not fully closed,

b. Temperature sensors downstream of each safety valve (one per valve). Tem-perature indication and alarm are provided in the main control room.
c. Pressurizer relief tank temperature, pressure and level indication, and alarm in main control roon.
d. Pressurizer pressure indication and alarm in the main control room.
                . SEQUOYAH - UNIT 2                    8 3/4 3-3

r INSTRUMENTATION BASES design basis for the facility to determine if plant shutdown is required pursuant to Appendix "A" of 10 CFR Part 100. This instrumentation is

       -        consistent with the recommendations of Regulatory Guide 1.12. " Instrumentation for Earthquakes," April 1974.

3/4.3.3.4 METEOROLOGICAL INSTRUMENTATION The OPERABILITY of the meteorological instrumentation ensures that ' sufficient meteorological data is available for estimating potential radiation doses to the public as a result of routine or accidental release of radioactive

        *~~~   materials to the atmosphere. This capability is required to evaluate the need for initiating protective measures to protect the health and safety of the public and is consistent with the recommendations of Regulatory Guide 1.23, "Onsite Meteorological Programs," February 1972.

3/4.3.3.5 REMOTE SHUTDOWN INSTRUMENTATION The OPERABILITY of the remote shutdown instrumentation ensures that sufficient capability is available to permit shutdown and maintenance of HOT STANDBY of the facility from locations outside of the control room. This capability is required in the event control room habitability is lost and is consistent with General Design Criteria 19 of 10 CFR 50. 3/4.3.3.6 CHLORINE DETECTION SYSTEMS The OPh'%s i s kc4os cLele HLE . he chlorine detection system ensures that sufDs: lent capibility is availab prongLtly detect and in,l Atiat-1.;ve action in the event of an accidental chlorThe- p. ikircapability is required to protect control room s s consTitenLwith the recommendations of Regulatory G Protection of Nuclear Power Plant-Co trol Room Operators Againit-errTccidental Chlorine Release," February 1975. 3/4.3.3.7 ACCIDENT MONITORING INSTRUMENTATION The OPERABILITY of the accident monitoring instrumentation ensures that sufficient information is available on selected plant parameters to monitor and assess these variables following an accident. This capability is consistent with the recommendations of Regulatory Guide 1.97, " Instrumentation for Light-Water-Cooled Nuclear Power Plants to Assess Plant Conditions During and Following an Accident," December 1975.

    \

SEQUOYAH - UNIT 1 B 3/4 3-3 m- _

r-6 e ENCLOSURE 2 Proposed Technical Specification Changes SEQUOYAH NUCLEAR PLANT UNITS 1 AND 2 (TVA SQN TS 78) Justification to delete LCO 3.3.3.6, SR 4.3.3.6, and associated bases (ur.its 1 and 2) of the technical specifications. i

r 4 Description of Change Delete Limiting Condition for Operation 3.3.3.6, " Chlorine Detection Systems," its associated surveillance requirements (SR 4.3.3.6), and bases. Reason for Change Various problems with the detectors which are regulatory, administrative, and economic in nature coupled with analysis which concludes that the detectors are unnecessary. These detectors have shown a trend of unreliability and continued maintenance problems for their operational lifetime. It is estimated that Sequoyah expends approximately $23,400 per year in maintenance manpower alone on these detectors (i.e., surveillance testing). These detectors have been directly involved in the need for four (4) licensee event reports (LER) over the past two years. LERs 1-84050, 1-84062, 1-85033, and 1-86021 were all generated due to control room isolations, an emergency safety features (ESP) actuation, caused by false or inadvertent signals from these detectors. The combination of maintenance, administrative, and regulatory costs coupled with analysis that evaluates that this detection system is no longer necessary presents adequate reason for change. Justification for Change control room habitability is not jeopardized by hazardous chemicals. TVA has performed a detailed calculation / evaluation, ENDES Calculation TI-ESC-27, " Main Control Room Habitability During Hazardous Chemical Releases at or Near the Plant." (See attachment 1) The purpose of this analysis was to evaluate the habitability of the main control room (MCR) during a postulated hazardous chemical release, utilizing the guidelines presented in Regulatory Guide 1.78. This evaluation considers, tabulates, and evaluates the effect of releases of potentially hazardous chemicals stored or transported on or near (within five miles) the site. The results of the analysis lead to the conclusion that MCR habitability is not jeopardized by accidental release of the chemicals considered. RRT:CLH 12/17/86

l- .- .' A%f i EN DES CALCULATIONS 77.Ecs-27

 .(    TITLE MAIN CONTROL ROOM HABITABILITY DURING HAZARDOUS                                       sv3ST <S)    "'^*$8Y182 CHEMICAL RELEASES AT OR NEAR THE PLANT                                                        SAasECgiopS)

PREPARING ORGANIZATION REV (FOR MEDS USE) MEDS ACCESSION NUMBER EN DES-NEB 801216E O 005Gr \lEB '801212 3 0 0

                                                       =a A .mCA.LE DESie.       .RANce - o,ECT DOCUMENTS              IDENTIFIERS
                               $"E2                         350927F0018 ds)B45 '85 0924 23 5 RS KEY NOUNS Chemical Release, Habitability,MCR, Toxic Gas                    Ra REV              RO            R1                     R2                  R3          STATEMENT OF PROBLEM DATE 12/9/80             9-14-85                                                       Evaluate the habitability of the main control room during a
    ,  '"5'^^*'h'            hh%%                                                             postulated hazardous chemical release, utilizing the guidelines presented in Regulatory Guide Y.CH ") ECKED         $                                                                 1 78.

LG l-.

       .%TR = 2.0 L ATTACHM ENTS MICROFILM ED:

uST ALL FAGES

  • 5.1-5.8,15.2-15 .4 ADDED By THIS REv 16.1-16.6.18.1- 18.5 LIST ALL PAGES
  • DE1.ETED av nuS REv: 12-15.1 LIST ALL PAGES
  • CH ANGED BYTIES REY: 1-3, 5, 19 ABSTRAG"r The habitability of the main control room was evaluated utilizing the approach outlined in Regulatory Guide 1.78. Potential hazards resulting frca chemicals stored on or near the site or chemicals that are transported by the site by barge, rail, or road were considered.

Two types of accidents were considered. The first is a maximum concentration accident. This type of accident was evaluated using the computer program CHI 224, as outlined in TI-863 141or assumptions for this method were Pasquill Stability Class G and adverse wind

      , directions. The second type of accident was a maximum concentration-duration accident.

This type of accident assumed a leak frem the largest relief valve and was evaluated in cecordance with positions C.5 and C.6 of Regulatory Guide 178. Results of the analysis indicated:

1. Chemicals shipped by rail and road will not affect MCR habitability since all major roads and rail lines lie outside the 5-mile radius specified in Regulatory Guide 178.
2. There are no industrial or military facilities within the 5-mile radius specified in Regulatory Guide 178.

3 Hazardous chemicals barged past the site are transported less frequently than the minimum frequency of 50 barges per year required for consideration as specified in Regulatory Guide 178.

4. None of the chemicals stored onsite in quantities greater than 100 pounds affect MCR habitability on the rupture of the single largest container.

It was concluded that MCR habitability is not jeopardized by accidental release of the chemicals considered. TvA los97 (ENDES 7 78) 'Use revision log (form TVA 10034)if more room is required (continued)

                                                                                                 ~
                . . . - . . . _ _ - . . . . . . . _ ,                               g                            ,

q l

                                                                                                                            \

TI-ECS-27 (Continued) Revision 1 of this analysis deletes the reference to the onsite chlorine storage tank and related hazard analysis since chlorine is no longer stored onsite in a significant quantity. The revision also adds analyses for aussonia and hydrazine due to the addition of the new storage area by ECN L6208. l I 4 I i l i i i s l E75266.07 NEB-Sep. 23, 1985 t

   -.7-.-...-..                    - . _

r __ _ . _

   .i* .-                                                                                         sacer    /     or    l9 SEduo%2R AIKLEAA OtAn)T insisi reatrt?ot room                                         Tr-Er5 - 7 9 2I HAB ITM IL I T1/ UA1052 H A~EA0 no u S t'//E>n/(Al AfMME
   ,                                                                         Rl t .hP s?ll.q]ex coeurga[W aarg }///5/20 varn-A Er         c u ento 6 8   e.v. /I//d/S'd Broblem Slalement: Galuafc fie habilabill                                                    ccotrol room durin3 a          posfulateel                howdous              chem       %

ical release, afil,yng

                                                                                           -                    o f 0+       main the guidelines presen+4 in 2eguIdo<3 Guide ),98 Solu lion :

I. ~0 ll roads Qncl railIraps o f the in the yicini}k 2.t of the Ge+uo3nkflucine Plan + are Itsled in 5echon Gegoogah FS ARjand, major-roa.ds QrdraiI lines are l0CQ}ed 04 fS$bE YA# r~f" Y h5 YYY lA d45NL ]!lS* as p. /t 3 ) 00

  • f0 I0')

Rt l See also referene 16,e. SE [0CliU3 (included

2. 7bert are iso indyS/ rial or mllllpr3 (aciliheS Ioc4led wolkn lhe E mile raclius of -the 5 ppuovak flaclear plan + to heck could
     'e                      cause a potenfAl horord fo (ne plant (See memo                                      fro m R. 0. Carn chan lo in,1v.Sr;<ouse, p3                   Ilo).

3, 7he ina/priq/s baryd past fhe hjuoggk Auloar Plad are ),' sled in 'the inomo 0% 2.0.Carnshn do in,tV Sprou t e, Y ygl1-l2, and. ref's /5fIto (irtcludel as pages /ro./ -/6.S*). See. page /to.lo for- explaination .

4. The c$ emir 4/s sfored onsde in penit/es ej rso fer 1Aan 100 lbs w :

RI Sulfusic Ocid C,I, bnn t. ( Lelete S+ eve per. Ruclell Sedium f/3dror/de /Hfrojen pes) ^//nl$r Oluminum Sulfate hn\n\cnia.

                                 $od/um flyochlorife Om moniq       llydroxide Sodiummf bdahe Senzol-rineole                         S!!      24ferente i 2 for souue R

g II %dra tine. See also referenc.e l'1 v  ? Oluminum Sulica fe (included as pp je.I-j8.7 ) E., I30ric -)cid

               $                 ly A namid l?                 r//y /<ne. G/y col Co< bon ();oride            _ _ _ _ _ _
     .      ..                                                                                   m er       .2  o,     19
                    $Q/) McP              IJAR ITABit IT Y                                               T I-El 5 -? ) 21
       ,_                                                                       02 el1slw         ee n urse 2 ~9 cue /2/4120
                                                                                 #As 9 h de;-     cureneo N      one ////o/Srd The following chomicats                q<e s+orod s        solids Grd w;II not affect incR habi}nb,I> F :

3 Glu minu m SuIfa+e. QIuminu rn Silica te Gori c Acid The following clemicals have vapor pc ossures of less fhon to Tore af 101*F(Ao'c) and wiIl no+ affect- incR hobdab,li+3, (Gef 11) Salfuric Ocid Sodium fl ydro xide E}hylene Glycol 7he reminis3 chemicals wilI be evelu&d b3 ko me+hsds . The first wil( be 4.s a maximum concen+ra Hon a cciden+. This lype of acciden+ +akes 4he laryst cforage vasel o f ibe cAen,ical and assumes 4 hat +h e +otal conien/s o / /d e vessel cIre empfid q+ one burst. This +3pe of Occidenf will be evaluAfed by the. con,pufu prog rom C//l.U4, as ou+ lined in TI - elo3. Th # second method is q ma rim um concen fra lion - du relion a eciden+. This -lye. of accident assu me; a lack from fAe larg<st relt<f val /e.. This Fype of accident wilI be evalu&d in accordonee wl+h pos1 Fion C,5 and G o f 2opla10<3 Guids 1.12.

                                %cnta lisdroxide                and A m m o nia.

y I4 ommonia ll3 droxide is spilt iho }Ar hazard is +Aa+ j anmonja gas is off. 1 E The large$ lienof ammonia is 4 4000 gallon st saurce

             $                       4anIc     loca f ed fn -lh a futbh e bull din                 TI-870
                                      ~

I evaluo ks +his +ank. TA e conclusion o f

2. _ _ __ .__. __
   .-      ..                                                                         s uv             3    o,  lY
               '.S QN        rnu2            NABirAAlurY                                               rl- Ecc,-n 21 RI' e M v bglw co. uno /299om /2/6/90
                                                                          #M 9-6 ISS c,. reno N our /3['/o N<o TI-970 is + hat annonia will not affect MCR habitehdity.

Rt 55' sal. cleums et ammonia are s+0 red af 4he nen hiso, severs)d a/ included as PP is2 -1 ste, rage she code C,HI22.4 cided by Ec4 LG207. Computer- analysis, using 3 show that even if one, cirum vapori2.ed instantaneoosly3 rhe. resulting amm fumes would not presenT a ha2.ard +o MCA personnelonia , rag raammum Sadtummol g bdde.- Beneofria roleconcewtrahon would be (YTh</skold li,n',t Wlue) There is no TL V listed in eilher ce fotonel I or rderone e 2 for sodiummolyhdq le - b ongo+riazole . Sedium mo)s hdde is lisFod in -lhe +ectof celevence .q and is describ<d as 9 rmodecotfe. shoc+ term ccc;+ ant. Since no TLV is ](Sfed and the Chemical is stored in 55 gAl Ion dturnS jn s Id + th e service building , If is as,surnsd tha+ q rap +u rt o f one clrum u,I( ha re no e44ec+ on enana controI toom

      ,.                        habildiIiig                                                                          -

( C3 anomid The TLV for cyanamid is by/m3per c d erence I. I M w nce Q lisk it as a sliS + hor inodocat<. pcoblein i 4 ; n h e,lo d o c inf ostod. 03 aramid i.s s }or< din a S53aIlon drum loce /#d in the s ervice buildiq. Due to the fotf O fil is 5fccod in a closod buildiny artlin c,55 3allon eon lainor, if is a ssum od f1,si c3oramid w.)I not q&cf inwn con +rol econ, habdab> IHy .

    ~-

n 2

             &                                                                                                           r
             =
                                                                                ~
   .'      ..                                                                        sa        4 or     l9' san inct                 HABITABlLITY                                         T1-E(S-n 90
     ,m                                                                              coeurto$Y onc &/{o/90
       .                                                                             cwcento  d our /h/oko (Qfbon Diotide Oatbon Diot/de (S . sbed in a 21                 Son      dank   lorn4ed on +he' south end of ike conhol buildinq Th e inkke is loca+ed on the north and of 4he conMo[ builcling. On
     ,                                                   there r s fcludel +ke inp+ and ou fpul- for L.,                            +L e?o3eslo-Il,for-compu         proscarn CHl224. The distances + rom lhe f4nA fo . -the /ntakes a re 55 4(14,76mberhcal and 333 ftGoI.s m) (2eferences 3 ard4) . The maximam concentmi.

a re IA,830 m3)ma -for.2 m/sec wiedspeed and 6019 m3h3 Sov . 5~m/sec windsfeed. The TNU-for ca sbon clioxide is 18,400 mym3 per Eegulafoc3 Gu o ct e 1,78. Ihr +4e inaximum con cen+<a +, on -du <alio n accident the melkod 044 lined In

                                   ^ Diffusion 04 Ven++d 6ases Groun,d Bui1 dings ' by Hali4sh and used in Tr-ecs -a s. See pg ]                foe a c4ucal ca Iculalion.

The resulis of the calcc<lafionshowed thg+ +ke conanfrakon would be .01107o bg volume -{or a restimum concen+<akon-durakon accu 1ont. The tenicib l inn b 9 volume rs I 96 Therelate i + is conclud+d Ha+ eashon dioxide will noV al-fect inC2 hahnaMh Sodiu,n Sgpochlor,fe

e. $ Sedfu,,, hyglor;te ;3 3%<,d os an gepo so[u pon jn p_goco
            !                      jallon knks /org/ed in -Hs sodium Apo cklorIie bu dcha <
            @                      treference 7), Per cowersq/;on wdh 5 tea Rudell on 12480, 2

_ E _ - _ _ _ _ _ __ _- --_ - - _ _ _ - --

 . . . ..                                                                 surv   5     o,    /q SGAl     Mct        H AB,lTARIOTY                                    T I -E(S - 21 91 RI'    d s'11 9 ) W eo m rea 2 9 P o,re I2 20
                                                        ,e u,-d            cucuo 4f    om a4cho
                       +he sodium })3pockfor!te       is   af a ph 0-f // a+ }hiS concenfra+ ion. 0+this ph, -fhe formafton a4 Clz w;\\

not occu r upon a spill. The yh would have io be loasced lo abut 4 befoce ang significant amoun4s o f Clz will be. released. 74 eon /3 wdh k eac4c,phof4 weald be fo dilule de sola/ran a;& an acidit solalion. No anom+ of dilulion % w a ler w'>ll a ccompiish +Ais. TAerek i f is concluhd fia+ sodfum h390 ch lo<i+e wi n 1 ac>4 a (bc+ rnc/2 R\ h abikbilif . Chlocine - Chlorine. is no lonsen stored ansife. in slopific.antguantifies. Small lab quantities a1e exenf from this annivsis per Rs I.95-g Chlac:ne is s 40c*d on s sie in a looo lh cylied+r r M ecac+ loca+ ion c-f Me tank is no+ krow , ~ fo re. Q the ionk rupture wa s assumsd +o he, ve curred

  • a+ gcound level benm1h the in Fekes e compu+n inp+

l, and ou+ pat 1s includd on po assumpHon is f fha + chloane wouId

                                                                    -14. 7he inc<de                                   e a . problem because 5f a fke low concen+<afi , .9xtr% /m'.Q         3   maxim u m conc <n+(aiion -
                   - duration acciden+ os not consignes due 1o Me /ger vessel O and the s         .

amounf o-f Clz sforedy 0 asumly a n 90n

                   > disk           on +Arou3k out fke rMM bg -f Ae veohlalion sysu .

T T Lv fo r- Chlor.ine h 45 g/d ll 3dia erne flyd<wne has a TLV e f l,3 m3 m3 / (feference.1). 7he laeys f container of hydra eine i.s a Aso callon

                                                              '        +an k in 4h e 7arhine butlding The exacHoca fion o(}ke sonk. w)}k,n +ke I",Q'MkWoWl?

however, )+is assumed k + apon a bemk or rupiure , the liguid wou1d drain in to the sump in the lu<b'ne buiIding, and the vapors w,Il de dispersed by +he 44 bine buildin3 enhaus+ sysiem. I( +ke a haust sy s+em is in ope enbie., a +ke vagocs asll be conMined inside +he -+ucbine buiIding. fE (?e+ 9,9, and10). EF os -lhon assumed 4hef 3h drazine will not kt aKed inc2 habilablily if this tank rup+vres. Hy&caz;ne

        !                 is also s%ced in a yacA shage area. See the j
                          -Collodng pages.

s eev C. I o, I9 r r-r:cs -23 [U c co - rto e Mom 9 /s /x-

                                                                                                       ^

CHECKfD _ g DATE __ As A aesoer av Ecn L sros, .sevEanL ss-catton oiws: of AQUA H10MZIAJE (357o of cot) talLL BE 57012ED I,U R 2400FT' s ro:LA(.rE SitGD Mi>Roxt/1ATELY mod FT (42.fo.7 n~) FROPI 72+E. IMCS. Al/L IA> TAKES . IN Oildatl ro PilGPAllE r/rE USQD F0/L 77ttS ECiG i S QiUP SITE lDGlLSo k k n L AEQGESTED Tl+AT 7W/S ANALYSIS DETE9/1siUE rus PikiMuiy ,uMasil oP H ya tir12iA> E bA u M.S 60H-/cn Coulo SP)L.L tvi77 tour'

   ,         JEcM/?Diz/Ah           / LICA cps /2nTDR sn1ST7 U

Flies r, CALCULATE '*/R Pott 't S & i 12 3. As DETAILED lio TI .5~87 Ro : l ' -hN S/q=27rr:jgu. expf ay[/ ex . p{ae,2. _% exp{ (E+hf} g7j. (SEE T'r-587 Fog. dei'iNm04 OF MER.MS ) Y:o 2. = 4 2.6.7 % q: 11 %. h=o E= 15.8 % ay= 45%

u. = l */s I O X eg ex ._(ITB-of P_O5B+of a o n6 s>()(') t(" 5P - t (ii)' z (.)'
     . s                          _
          !.                            (IE Bf _

expl l j/ E U'P - = 0.002.LclZ. h3 j T16)(4 5 )(o) __ _

s cer C. Lo, I4 TT - recs -27 Ill. p compurro PM DATE 4 / 3,/8f ewecxto /A ~ oart ' 4 -- Q " tJaxr, c A Lc.u LAT15. TYRE Mass FLoal l Art oF H y.D 9.A L) ME INTo TwE. air.. A55uns A i+or CA1 of: 95*F AND, PER. NoRJacr os7o, A seitt Ic.n DEEP. Mira A STORAGE M.GA. OF ZA oo Fr*, TWE LlQo tD vo toe E too0LO DE I CXx .o 52BI f.f__ x 2A oo Fr5 7A 8 GAL = W OR VotuMe = 5'O 9 G-ALLOMS Gor SINCE G o tu rio d it 3 5 */o H'/ DEAZ.t ME , TME NUMBER, C: c.ourma sec, sat or n.s,s(tA2.ix;e is . or ca.ms T o . M GAL * ^ t DRu H  : 3 0.6 , S A'l 35 31 b9.Uh5 ' EE GA L (Ac.rwoucrn 71 oRums wou co Resocr io A spill BeePeA. TPrA ld j CM; A N A L'I Z.E TH IS c,ASE Foi'l C ONSERVATl $M. ) PER NORIEG- G570, APPENDIX.y TWE. V/&90it fi1EMUR.E ol= H'l O RA2 INE AT- 40*C. IS 30. 0 *~m. N3 (0.58 PSI A AssuhE THE. M'/ 0 AA2 lME BEGIMS E FFECrly E Ly a j DI FF US I M C- 10T0 mE air IMM EDI ATEL'i A60VE TWE SVRFACE Ol' TWE SPILL , SAN k hFr) ABovE (7, 3

n . _ .

                                                                                                        . i s cer     6,3_ or    14
                                                                                    -rr _ rre s-n li       l

(- ccourco Of oarc _i ,l"5 / Ts f CHECNED AI DATE *

  • Tife DIFFOSIVITY OF TWE PR.ec.ESS lS GlyEh3 Oy EQW ll-L OF PJIF I B '.

Y T' i i b = 0.COGA + MA Ma f(V3+V[3f A Y W W E (L E r D: D1 F FosiV) T'l (p73i ) (udL:e

                                   'T :  TEMP        (* R.)     [9fr*r = 554 /2) =              SSA/

C p: 575 TEM PRESSV RE (atmos) = / V = sotEtutNt vot.ose (grr3 z9. i &naz n) = za.3 caig ( RtF ;L & H) tr 3ZAMYDRA2r M = no t acu cA9_ waisar(c 3Mno)=ze.3gic) , (9.EF 21it) D=(O'00'}( } 3205

  • 2s.9 U) 29.1')Y3 +(299)Y'5 FT L D: O,(o04 l
Tnta. Mass i=touiLATE 01
- H1BRAL\ME IMTt TWE. Aik 2
                 )S    (yW Eh)      (yf  E Q t3'   Ii-9    OF   REF    i 6 '.

l 3: l 0 l

                    - - = _ .            . = -
                                                           =

SMEET hN oF TT-t cA-2 7 (41 c Co - urE. cJf o rt o/3/yr CHECNED [M DATE DM3 A p i _p g _- t $ R,T - x,- x , j wette D: DtFFOSI VIT'/ g)  :- O. 'o 04 Mg= MoLEcotA(L WEIG-MT k te note) = 3 E.Of

L400 A = AREA DF SP)LL (FT*)

R o = 04iv. Gnw C_o/Amur(I",F'$_,g g,  : 1 TetF T = T EM P (. F--) = 554 P= VAPog. PflessoRc(PstA) = 0 T8 C 7., 7 DisTAA;CE A6ove SPILL TO ArMos Pets 9s (j= r) = h 1 LS M pT A = (O.f.04 an. )(31.of ts-mott)(teco Fr') [056 Pst Lu=-Fr I b54T tenete.eg)( 55'i A) (Y+"7

                                                                                       /(44~   FT Lah A5       /09.1 7        gg    O A / 3,717        /sec. = Q (WWE(Le G            souRct srRENs Stucs,    F Ro M      SYrEE T 5.I;        X/q O.oonAL                            A3 g  Twc-   coucanntAno/J,              ~X.,   A r nrr=         MC R.          Atit INThKE. to00LD       BE     1: N ^        /Q.

j = n,7n 9/mc xo.ocun$=3144 y3/3 ~. i z

suter T. T or I4 i 3 Pc% '?_'l ski (' Cowurrodoarc 9,/-)/Sf CHECKEo h " CATE

                                                                                            }"

CAucu'Are wre (tam or aui'oue io rim MCil IF A concE971?AT7 O N OF 31.4 4 A 3 15 consi7%rty P R s.S ENT A-r TwE M Cil A l d IN TAKE : FILos AP9ENDiy A , sweats /3.3- /8.5' :

                                                 -Bt
                                                                             *"i#

t = A (1 - e

                                                        )

WWE(LE C= tone.enTRArtON OF P c ttui-AMT lN5i bE s c a. (7/w) _ A= c_o AceNTRArioM OF P c t.LU TAkT IN V SoPPLN MS 'd fo~3 ) f3 = FL.ou.) iLATE OF SUPPL 1 ANS ExWAOST Alit ( V = VOLUME OF MCilHE (,- )

                                                                    /uk)

( ) t  : rtME Eq'a J. , A6cvE, CAM AL%o GE SOLVED Foll t: tV B A b [( A-C] G#N T 1 l Thr.=iePcI?.s, t us aus- so 'us 3- Ano TT Asavc , ! 71+E_ CoucENTRArloJJ tM T W E. MCfL CAM GE PouM0 g AT AM'/ TIM E ' 3 oR , T+HI TIME TO (LEt4cM s i Au'l c.lvs /J coMCEMril ArloM CAN DIE FouMo .

         !=

s cer 5. G o, 19 rr - t= e e ,- n cts comrco /4 oATc d 3 /9 r cwce co Af__eirc 2Aldr Acc.ofteinG- 70 " U g gre L HAhou M6- 0 F AGuEous H 'l D RA2.iN E So Luri o >as " O L iu Cne/mcALs, , l en s-) Tite Tt+EES n otD LIM IT VA LU G ( TLV ) o r H't citA2 iMs T%T SH-o u t0 W o r e t!L IExceG0G0 iM A/J 8- \tGL BAN 1S 3 PPM ( 3 A Mh ). T/tE. REFEEENCE A LSo STATES TWAT GEME(LALLN A600T 4 PPM (F7- o*J CAO 6E DETECTED Tinousa oco(L Ano /nito fLe s pip AToki lEL\TAnou. Smce e c aic e a s c a A3 l..) TOLEllATE 3 PPh (3 9"%//uJ) FOR RA) &~ 11-D DIL boottXDh'/ , coNSERVhn VEL'l AS5uhE Thil T~ cNL'l TIDI CE THIS VrtLUG 3 (6 Pt iM oR 7.6~0h') LOC 0LD BG 77tf 70Xl C LIMIT TO /AICitthC / 77tTE MCl? ofallA 70125 Usr Eq% E (Swter 5.5) To CALCULATE rwE TIME REo'0 To AEAch TWE: TLV Foll AN 9-H'l g t4oftKDA'l[399/d)) BETECTPrOLE C. ORE.OTRATio,0

           ,    ( T. 2 "D/a~') 3 AMD ASSOMED           Toxic      LINIT(7.8 "0/xh s

2

           ?      -

s EEr W 7 or jo 1 i-C-Cc.,2 1 (Lt (1 cc,MPUTED DATE h32 CHFCKED MMw OATE 4 USE EQ' O 1 (STREET F 5) TO Diri EtthWE. TWE ConLEDTA-Hnou & MnMUTES AFTEfL TH-E DETECTi4GL.E C oh CEA)TRATIo M OF 5' 2 k'] /s llEAc>tED . {Mors: Two MtUUTSS is 72+G 77h E Il150utl LED F0K A TilAth59 OPERATDR. To PuT A 5 ELF- coa >inI CEO BREikTHIUG th0NLNTUS /A)To OPERAT70A), AER RG l.22). VALUES TD 6E USE0 pop Ecogr/oA) .2I~ (s/t s.v) AAE: coNcERTRArlou oF 1,s 3 A y Pottur%uT IM AlfL SOPPLf 3/4V t=Lo v> AArn. OF svPPL't . S> AND 5 x M us7 hrR. = 90 . Io n.u/ 3)dw VOLUME OF MCL * #~3 Y> HAblTR&lLI1'Y 2.DNE bSOS concGMTRAT10A) Ol= C y foLLOTANT /A> AtcRwa 3.9,52 &7g nD/g. ( TIP15 To AEACH CONC 2 A)TRAT10,0 = (unn.^.ow e) USW6 EQN _LL (SH 5 7 ) l A \ t = l in13 A -C. )

                                        /      Fo R. \

Fo(L. Cr 3.9 e)[m3 (TLYmg_ O A , ) , t: / 2, . O 4.lis .

                                         /osracracte T g
     ~

C= 5. ?-. ' QconccurMricas), t= /(o 4 4 OPESATCO 5

     }          l~ ] b <>.                JNCAfhCIMTGO)       (* 2> 6. 0 'S.

s I

j sat? 5 fd or J9 TT - ECS -2 7 fli COMPUTED d DATE 9 3 Y cuexro at - om 7-o- N YALUES TO 17E USED r-cA Eo'/0 I [ Set T.7) Arte A , r3 L v = s AME As rog_ so'n IE k Q) TihG 70 DEVICG fuY AGTGLTIOD AFTEll eh' DAEA77t/N& - (l b.4 jg,y

                                                                                                -i .2 ) r'mg C o k C GMTRA-T10 ^.)   IA)

- C, m es.itz = (w~bn) usino- tou I. (si+ 5 5) :

                                                         -et C=A             I-   ev
                                                           /TlhE m PuT CM FOR   t = / 9 M gggt pAcx Antg_
                                                               #-T*/I?yL), C = :r. 8                  $3 SUMMAD OF EdC                           E. L li- REsotts :

l rime EXPiEED ONCE CoACEur9ATion g,isagicANce i PotturA47 G.T PritTS IN hcilH-E luTo MCR. INTAK.E

                     / t. o siA)                               39 1/4                7%Os %Eewo TfD M m, l                     /fo.4 sie                                 s.2.9                                    **

l

                      / 8 4 Mi^)                              r.B'/d8/J              ^'?dfMfn 25 8 Mi^)                                7 8^B/4                   740f4l @ &n CON CLUSICA)         .
                                        'C r 15 ,    Tl+V S ,    Co htLUDED T)+AT Upon A 2
        ?       RUP ruRE OF 3l ORuns OF H'l0RA2 tME AT T)+E YA R.D
        $       STORAGE. /WE A, OPERATOR S A A:. 1 15 Nor TEoPA9Bl2_ED                                     .
       @        TE1          Wo0LD ftRVEMct2SvFF(ICIEA)T        TIMEove ToR.COM
OP IGOLATE TWE AND EvsM 2.5 AtR A IN.pacTom g o u n orse:Go A ersa. m spitL ocevas ) .

saur b o, l9 50N m CR HA6ITABILITY T1-Ecs -22 20 coeuno A W om I'7 6)@ e ceno W om I 4/a q o

                 /1llr03en Aiflofen /s skred in an l1,000 ft3 cyl,ncler. The mact locaffon el the c3lirdu is unboun. /)iko3en is no+ cr foric
                        $4bslonce, however i Hs   an    a sphy xian+. If lle t'n }iro Jank.

were empfied inib S /MCA, We <Qsu }kn3 concen ha kan o4- Og weald be: Volume of mc2 is 2')0D00[t' of whick 797o J, /l/z and 209o is 0, . If &e ll,0cv R' af tue was release in Ike tYlC2, + hen 20*lo of II,0004t 3 would be 1% ac}ual Op displaced,=h00 R 3 Th e concendra ko n o / cO leff (n the n1c2 wouif b e ) O (240,ooD -2,200 _ 290,000 - -

 ,                    0 eCP{cXP,H () cont lub40 $$ Nz w:\l nol be a pob kn, lo.

(. .- Mff h41s}4 ball OLSCWming Y'k4Y [kf /Y/g drawn in do N fM(d is even1 drs F<ht<4 t cowsAM A *Ae room 63 FA# vo,lila ha sssIrm 3 Conctusica u is +he conclusion 0-f Mrs Tz is hl,ck +he main roi,hi i room haMabi I,'43 w1n no+ be j papardis#d by on3 chemicai sh >gged % or stored on-or aff .slle.

         ?

s ... s 0

         ~
                 = : ~- -         -
                                         =====-            =   =-

s ter 7 or 19 S@0 mC2. n ABITARitiry Tl -6TS- 2 ) 20 computto cart /N" h~ cutcuto Y cast /)l/ol4R

                                                              ,(DNTROL BUILOIN4 h?$eA&$         -
                                                         &~M4W *
                                                            -       m eg 4        332 Oo/,rm)

PLM Vjev

                            & 2S2 -                                      2nrdw FCR. m CR.

anr.- 5r' ORA -- SversarJ YIEW G Ep for (Ej 9,2ef5) maamum concen+m+ ion -c{urdion actidonf. D= 2.M tr) (3,Ils +,1 R )* ( 5ee TI-ECS -2G for defen dion of Verms) 2 2 L= L 333 + 55 ' - 3 37 4'+ Ac. = ,3 49 Az for o f" R:L/fc = 337/gyay = relief vent bef 4) 5 70,5 m = I.O for minimu m dilukon (ce+5'). D = 2.9 2 ( 3,ll, +. , )(570#)f = 904 2 0= fc.e. (See TI-EC6-% for dehn>kion o-f 4eem.s) Ke

     ~

E intake = lD* 90*6'"'OIA% N 3 VOI"mt a

            =

ii .

5. . . ,

j i 1 80/12/06. 10.37.40.  ; PROGRAM CHI 224Z j x HAZARDOUS CHEMICAL IS  ? ETHYLENE GLYCOL  !, i. ,i N0LECULAR WEIGHT OF ETHYLENE GLYCOL IS ? 62.07 i !! IHITIAL QUANTITY IN GRAMS OF CHEMICAL UAPORIZED  ? 230744 i' i! ENTER HORIZONTAL AND UERTICAL DISTANCES (IH METERS) '!

j. OF SOURCE FROM RECEPTOR ? 0,15 j!
! PASQUILL STABILITY CLASS (E,F,0R G) IS ? G  ;

HINDSPEED (IH M/SEC) IS ? .2 i ENTER UOLUME (IH CUBIC METERS) 0F HABITAB,ILITY AREA ? 8209 ! 'l ENTER FLOW RATE (M^3/ MIN) ENTERING HABITABILTY AREA? 90.6 3 ll ll EXHAUST FLOW RATE ASSUMED TO EQUAL ENTERING FLOW RATE. 3, b IS ISOLATION CAPABILITY CLAIMED (YES OR HO) ? H0 $ 4 9 .i !f [ Q*W I 19 ? ! u $++. lJl D 4i' j' . ) i< i

                                                                                        ' ~.  .
 ,                                                                                                   :i
 ;                                                   .                                               i, I                                                                                                  '

TIME . CHI /Q MASS CONC. -

;      MIN                   M^-3      . GRAMS         MG/M^3        -

I:

1. 1.68126E-18 1.24844E-5 1.52002E-6 I' 1' 2. 5.04417E-37 1.23474E-5 1.50413E-6 i,
3. 1.11488E-62 1.22119E-5 1.48762E-6 i'
4. 1.11488E-62 1.20778E-5 1.47129E-6 I 5. 1.11488E-62 1.19452E-5 1.45514E-6  :.

! 6. 1.11488E-62 1.18141E-5 1.43917E-6  ! ! 7. 1.11488E-62 1.16844E-5 1.42337E-6 . i 8. 1.11488E-62 1.15562E-5 1.40775E-6 i 9. 1.11488E-62 1.14293E-5 1.39229E-6 i 10. 1.11488E-62 1.13039E-5 1.37701E-6 i 1 l 11. 1.11488E-62 1.11798E-5 1.36190E-6 . ,

12. 1.11488E-62 1.19571E-5 1.34695E-6 it i 13. 1.11488E-62 1.09357E-5 1.33216E-6  !

l 14. 1.11488E-62 1.08157E-5 1.31754E-6 ' l 15. 1.11488E-62 1.06970E-5 1.30308E-6 1 i 16. 1.11488E-62 1.05795E-5 1.28877E-6

17. 1.11488E-62 1.04 k

,  ? . E i L

                                                                                            ~s is_y o            !'
                                                                                $9+

o 99 3  ! i'

PROGRAM CHI 224Z p_gg,g g Q'o o-6_L9_

 'A'AZARDOUS CHEMICAL IS                      ? CARBON DIOXIDE                                                     $b /2-8'80
 , MOLECULAR WEIGHT OF                     CARBON DIOXIDE                IS   ? 44 Y M//c/94 JNITIAL QUANTITY IN GRAMS OF CHEMICAL VAPORIZED                                                    ? 20562747 ENTER HORIZONTAL AND VERTICAL DISTANCES (IN METERS) 0F SOURCE FROM RECEPTOR ?. 101.5,16.8 PASOUILL STABILITY CLASS (E,F OR G) IS ? O WINDSPEED (IN M/SEC) IS ? .2 ENTER VOLUME (IN CUBIC METERS) 0F HABITABILITY AREA ? 8209 ENTER FLOW RATE (14^3/ MIN) ENTERING HABITABILTY                                                AREA? 90.6 EXHAUST FLOW RATE ASSUMED TO EQUAL ENTERING FLOW RATE.

IS ISOLATION CAPABILIT CLAIMED (YES OR NO) ? NO TIME CHI /O MASS CONC'. MIN M^-3 GRAMS MG/M*3

1. 3.3.1262E-18 7.9lO50E-10 9.63638E-Il
2. 5 . 671.10 E-15 .l.54.785E-6 1. 88555 E-7
3. 3.33019E-12 1.06116G-3 1.29268E-4
4. 6.70775E-10 .256829 3.12862E-2
  ~5.                             4.63437E-8                      22.2016                   2.70454

(- 6 . 1.09827E-6 699.087 85.161

7. 8.92762E-6 8307.81 - 10J 2.04
8. 2.48924 E-5 39907.6 4861.45
9. -

2.38070E-5 .88811.4 10818.8

10. 7.80996E-6 116705. 14216.7 II. 8.78818E-7 121740. 14830.
12. 3.39199E-8 120914. .14729.5 13 . 4.49072E-10 119602. 14569.6 I4. 2.03931E-12 118289. 14409.7
15. 3.17657E-15 116991. 1425.1.5
16. .l .697 22E-18 115707. 14095.1
17. 3. lJ 045 E-22 l14437. 13940.4
18. l .95531 E-26 113181. 13787.4
    .19 .                        4.21613 E-31                     111938.                    13636.
20. 3.Il830E-36 110709. 13486.4 21 . 7.91093E-42 109494 13338.3
22. 6.88405E-48 .108292. 13191.9
23. 2.0547.8E-54 107104. 13047.1 24 2.10375E-61 105928. . 12903.9
25. 8.30926E-65 104765. 12762.3
26. 8.30926 E-65 103615. 12622.2
27. 8.30926 E-65 102478.
  • INTERRUPTED
  • STOP cTERMINATED*

oun

PRbGRA[ CH h24k T/-dTS-27 /20 Of !1 of-$ SAZAR'DOUS CHEMICAL IS  ? CARBON DIOXIDE M-8'80

      .40LECULAR WEIGHT OF       CAR 8ON DIOXIDE    IS     ? 44 W        /2//o/go IgITIALQUANTITYINGRAMSOFCHEMICALVAPORIZED                       ? 20564747 ENTER HORIZONTAL AND VERTICAL DISTANCES (IN METERS) 0F SOURCE FROM RECEPTOR ? 10 l'. 5, I 6.8 PASQUILL STABILITY CLASS (E F,0R G) IS ? G WINDSPEED (IN M/SEC) IS ? .5 ENTER VOLUME (IN CUBIC METERS.) 0F HABITABILITY AREA 7 8209 ENTER FLod RATE (M^3/ MIN) ENTERING HABITABILTt               AREA? 90.6 EXHAUST FLOW RATE ASSdMED TO EQUAL ENTERING FLOW RATE.

IS ISOLATION CAPABILITY CLAIMED GES OR NO) ? NO TIME CHI /O MASS CONC. MIN M*--3 GRAMS MG/M*3

1. .l.57092E-L3 1.94028E-5 2.36360E-6
2. 4.63437E-8 9.15901 1.1.1573
3. . 1.70407E-6 8227.45 1002.25 4." 7.80996E -6 47237.8 5.754.4
3. 4.46141 E-9 49407.5 6018.7

("6. 3 .17657 E-15 48865.8 5952.72

7. . 2.81908E-24 48329.5 5887.38
8. 3.ll830E-36 47799. 5822.75 9 4.29924E-51 47274.3 5758.84
10. 8.30926E-65 46755.4 5695.63
11. 8.30926E-65 46242.2 5633.11
12. 8.30926E-65 45734.6 5571.28
13. 8.30926E-65 45232.6 5510.12 14 8.30926E-65 44736.1 5449.64
        .1 5 .            8.30926E-65       44245.              5389.82
16. 8.3 Q926 E-65 43759.4 5330.66
17. 8.30926E-65 43279.1 5272.15
18. 8.30926E-65 42804 5214.28
19. 8.30926E-65 42334.2 5157.04
20. 8.30926E-65 41869.5 5100.43
21. 8.30926E-65 41409.9 5044.45
22. 8.30926E-65 40955.3 498.9.08
23.
  • INTERRUPTED
  • STOP cTERMINATED*

(- l l l

Ti-85-27 20 0O l%

 .         80/12/08. 16.13.27.                                                     29tP /A-s-fo PROGRAM      CHI 224Z                                                     Q jgog HAZARDOUS CHEMICAL IS          ? CHLORINE MOLECULAR WEIGHT OF        CHLORINE     IS     ? 70.9 4

INITIAL QUANTITY IN GRAMS OF CHEMICAL VAPORIZED  ? 272155

                                                                                  <() [f /

ENTER HORl20NTAL.AND VERTICAL DISTANCES -(IN METERS) 0F SOURCE FROM RECEPTOR ?. 0.15

        .PASQUILL STABILITY CLASS (E,F,0R G) IS ? G Q _(%o' f f

MINDSPEED (IN M/SEC) IS ? O ENTER VOLUME (IN CUBIC METERS.) 0F HABITABILITY AREA 7 209 ENTER FLod RATE (it*3/ MIN) ENTERING HABITABILTY ARE ? 90.6 EXHAUST FLud RATE ASSUMED TO EOUAL ENTERING FLOW ATE. IS ISOLATION CAP.ABILITt CLAIMED (YES OR NO) ? O TIME CHI /O MASS CONC. MIN M^~3 GRAMS MG/M*3

1. 3.89019 E-12 9.6348 -5 J.17369E-5
2. 3 . 89019 E-l.2 l.90 OE .4 2.32293E -6
3. 3.89019E-12 2.8 .96E-4 3.45957E-6
4. 3.89019 E- 12 3. 6278E-4 4.58372E-5
5. 3.89019E- 12 4 . 67547E-4 5.69554E-5
6. 3.89019E-12 .57 al 4E-4 6.79515E-5
7. 3.890J 9E-12 6.47090E-4 7.88269E-5
8. 3.89019 E-12 .7.35387E-4 8.95830E-5 3.89019E-1
9. 8.22714E-4 1.00221 E-4
10. 3.89019E-1 9.09083 E-4 1.10742E-4 II. 3.89019 E 2 9.94503 E-4 1.21.148E-4
12. 3.89019 12 1.07899E-3 1.3.1439E-4
13. 3.8901 E .12 1.16254E-3 1.41618 E-4
14. 3.89 9E-12 1.24518E-3 1.51685 E-4
15. 3.89 19E-12 .l.32691E-3 1.61641E-4
16. 3. 01.9E-12 .l .40775E-3 1.71488E-4
17. 3 89019E-12 1.48769E-J 1.81227E-4
18. .89019 E-12 1.56676E-3 1.9085 9E-4
19. 3.89019E-12 1. 64496E-3 2. 00385 E-4
20. 3.89019E-12 1. 7 223 l E-3 2.09807E-4
21. J .89019E-12 1. 79880E-3 2.19.126E-4
22. 3.89019 E-12 1.87446E-3 2.28342E-4 23 . 3 .89.019 E-l.2 .l.94928E-3 2.37456E -4
24. -
                            .3.89019E-12        2.02328E-3        2.46471E-4 l           25.               3.89019E-12        2.09647 E-3       2.55387E-4
26. 3.89019E-12 2.16 886E-3 2.64205E-4
27. 3.89019E-12 2.24045E-3 2.72926E-4 i 28. 3.890J 9E-l.2 2.31.126E-3 2.81552E-4
2. 3.89019E- 12 2.38.129E-3 2.90083 E -4 J. 3.89019E .12 2.45055E-3 2.98520E-4 l 31. 3.89019E-12 2.51905E-3 3.06865E-4
32. 3.89019 E -12 2.56680E-3 3.151.18E-4 33.___ _ __._3. 89019 E-12 _ 2.65380E-3 - 3. 23280P -i ,_ _

sr. ..v, vive-12 ...., ave-3 .,, w e-4 40 0 +' . 41 3.89019E-12 2.97796E-3 3.550435-4 3.62767E-4 hwa g.g. 3.89019E-12 3.0406.7E-3 OP,8

42. 3.89019E-12 3.10269E-3 3.70407E-4 MN0/E 43 3. I 6403E-3 3.17962E-4 44 3.89019E-12 3.&9019E-l.2 3.22470E-3 3.85435E-4
45. 3.2847tE-3 3.92825E-4 7/-dF(5 -2 7 46 3.890l9E-12 47, 3.89019E.12 3.34405E-3 4.00135E-4 /

3.89019E-12 3.402.74E-3 4. 07364E-4 ' 48 3. 46079E-3 4.14514E-4 49 3.89aI9E-12 3.890J 9E-12 3.51820E-3 4 21585E-4 N 50 3.57499E-3 4.28579E-4 [q 51 3.89019E-12 3.89019E-12 3.63114E-3 4.35496E-4

52. 3.89019E-12 3.68669E-3 4. 42337E-4 ,4 53 3.74162E-3 4.49103E-4 54 3.890J 9E-12 b Alp 3.89019E-12 3.79595E-3 4.55795E-4
55. 3.89019E-12 3.84968E-3 4.62413E-4 W' 56 3. 90282E-3 4.68958E-4 57 3.89019E-12 3.89019E-12 3.95538E-3 4. 75432E-4
58. 3. 890.19E-12 4.00736E-3 4.81835E-59 4.05878E-3 4.88.167 4 60 3.89019E.12 4.9443 -4 3.89019E-12 4 10962E-3 61 4.15 991 E-3 5. 006 4E-4
62. 3.89019E.12 5.0 3.890195-12 4. 20965E-3 50E-4 63 5 64 3.890l 9E-12 4.25884E-3 809E-4 3.89019E 12 4.30.749E-3 5 18802E-4
65. 3.890.19E-12 4.3 5561E-3 .24 728E-4 66 5.30590E-4 67 3.89019E-12 4.40320E-3 3.890J 9E-12 4.45027E-3 .5.36387E-4 68 4.49682E- 5.42121E-4 69 3.8901.9E-12 3.890J 9E-12 4.54286E 5.47791E-4 70 71 3.89019E-12 4.58839 -3 5. 534 00E-4 72 3.89019E-12 4.6334 E-3 5. 5894 7E-4 73 3.89019E-12 4.677 7E-3 4.7 5. 64433E-4
           ' 74                        3.B9019E-1.2           4         02E-3           5.69858E-4 3.890J 9E-1:2                6559E-3              5.75225E-4
75. 3.89019E-12 .80868E-3 5.80532E-4 76 .85.129E-3 5.85781 E-4 77 3.89019E-12 t

78 3.89.019E-1.2 4.89344E-3 5.90972E-4 79

3. 890.19E-1 4.935.13E-3 5.96107E-4 80 3.890J 9E-1 4.97636E-3 6.0II85E-4 81 3.89019E 12 . 5.01.713E-3 6.06207E-4 3.89019 -12 5.05.746E-3 6. l i l 74E-4 82 6. I'6087E-4 83 3.8901 3.89 9E-12 E-12 5. 09734E-3 5.13679E-3 6.20946E-4 84 3.8 19E-12 5.17581E-3 6.25751E-4 85 3. 9019E-12 5.2.1439E-3 6.30504E-4 86 5.25256E-3 6.35205E-4 87 .89019E-12
                                     .89019E-12           5.29030E-3                6.39853E-4 88                                                5.32763E-3                6. 4445 l E-4 89                          3.89019E-12 3.89019E-12             5.36455E-3               6.48999E-4 90                         3.89019E-12            5.40lO7E-3                6.53496E-4 91,                                               5.43718E-3                6.57944E-4 1 -

92.- 3.89019E-12 3.890l 9E-12 5. 47290E-3 6.62344E-4 93 6.66695E-4 94 3.89019E-12 5.50822E-3 95 3.89019E-12 5.54316E-3 6. 70998E-4 9 3.89019E-12 5. 57772E-3 6. 75254E-4 3.89019E-12 5.61.189E-3 6. 79463E-4 3.89019E-12 5.64569E-3 6.83627E-4 98 , 5.67912E-3 6.87744E-4 99 3.890.19E-12 3.89019E-12 5.71218E-3 6.91816E-4 100. , 3.89019E-12 5.74488E-3 6.95844E-4 3.8901.9E ,12 5. 77722E-3 6. 99827E-4

                                                    ,15. 80920E-3               7.03 767E-4
7. 07 663E-A_

f e ,' _

10l [' ' ' '3 . 89019 E-12 5.84084E-3 7.ll516E-4 9q {d. ofil '

    .102.                3.89019 E-12          5.87213E-3     . 7.15328E -4 103.              3.89019E-12           5.90307E-3       7.1.9097 E -4               /2-I-Io
      .104               3.89019E-12           5.93367E-3       7.228252-4                  /#//g/80 105.              3.89019E-12          .5 .96394 E -3    7.26512E-4 106.               3.89019E-12           5.99388E-3       7.30159E-4          T/-675-Z7 RO 107.               3.890J 9 E-12         6.02348E-3       7. 33.7 66E -4 108.              3.89019 E- 12         6.05276E-3       7.37333 E-4 1.09.             3.89019E-12          6.08173E-3        7.40861 E -4 11.0.             3.89019E-12           6.11037E-3       7.44350E-4 111.              3.890J 9 E-12         6.13870E-3       7.4780.l E -4     Ss 1.12.             3.89019E-12           6.16671E-3       7.5J 214E-4     'ss        /

113. 3.89019E-12 6.19442E-3 7.54589E-4 sdP 114, 3.89.019E-12 6. 22183 E-3 7. 57928E-4 es\ ,;f ;. l.15. 3.89019 E-12 6.24893E-3 7.61230E-4 \t f3

     ' t .1 6 .          3.890J 9 E-l.2        6.27574E-3      .7 . 64495 E -4       C\\ &

117. 3.89019E-12 6.30225E-3 7.67725 E-4 g-l18. 3.89019E-12 6.32848E -3 7.70919E-4 119. 3.89019E-12 6.35 441 E-3 7.74079E-4

     .1 2 0 ,            3.89019E-12           6.36 006E-3      7.77203E-4
      .121 .             3.89019E-12           6.40543E-3      .7.80293 E -4 1 22.            .3 . 89.0.19 E- 1.2 . .6.43052E-3       7.83350E 123.              3.890l9E-12           6.45533 E-3      7.86372 124.              3.89019E-12           6.47987E-3       7.8936 -4 125.              3.89019E-12           6.5C415E-3       7.923 9E-4 126.              3.89019 E-l.2         6.52815E-3      .7 . 9   43 E -4
 ._    127.              3.a9019E-12           6.5E189E-3       7. . 135 E -4 128.              3.89019E-12           6.57538E-3       8 00996E-4 129.              3.89019E,12           6.59860E-3          .03825E-4 130.              3 .890.19 E-1.2       6.62157E-3       8.06623E-4 131.              3.89019 E-l.2         6.64429E-3       8.09390E -4 132.             . 3'. 89 0.19 E- 12    6.66675E-3       8.12127E-4 133.            . 3.89.0.19 E-12        6.66897E-        8.14 834E-4 134               3.89019E-12           6 71095 3        8.17512E-4 135,              3.89019E-12           6.7326 -3        8.20159E-4 136.              3.89019 E-12          6.754 E-3        8.22778E-4 137.              3.89019 E-12          6.7.7 45E-3      8. 25368E -4
      .138,             3.89019E- 12           6. 647E-3    8.27930E-4 139.              3.89019E-l.2          6     1727E-3    8.30463 E -4 140.              3.89019E-12             .83784E-3      8.32969E-4 141.              3.89al 9 E-l.2        6.85818E-3       8.35447E-4 142.              3 .89019 E-1.2        6.87830E-3       8.37898E-4 143.              3.89019E-12           6.89820E-3       8. 403 22E-4 144              3.89019E-             6. 91.788E -3    8.42719E-4 145.             3.89019E 12           6.93735E -3      8.45090E-4
 .    .146.              3.890.19 -12          6.95 660E-3      8.47436E-4 147,              3.890. E-12           6.97564E-3       8.497 55E -4 148.              3.89 19E-12           6.99447E-3       8.52049E-4 149.             3.      Ol9E-12       .7 . 01309E -3   8.54317E-4 150.              3    9019E-12        7.0315lE-3       8.56561E-4 151.                .89019E-12          7.04973E-3      8.58780E-4 152.             3.890J 9E-12           7.06775E-3
                                                       .        8. 609.7 5E -4 153.             3.89019E-12           7.08557E-3       8.63146E-4 154               3.89019E-12           7.10319E-3      8.65293E-4 155.             3.89019E-12           7.12062E-3       8.67416E-4 156,              3.89019E .12         .7 .13786E -3    8. 69516E -4 157.              3.89019E-12          7.15 491 E-3     8.7tS93E-4 158.             3.89019E-12            7.17177E-3      8.73647E-4 159.              3.89019 E-12          7.18845E-3      8.75679E -4 160               3.89019E-12           7.20494E-3      8. 77688 E -4 I      .          3.89019E-12           7. 22126E-3     8.79676E-4
2. 3.89019E-12 7.23739E-3 8.81641E-4 163. 3.89019E-12 7.25335E-3 8.83585E-4 164 3.890lvE-12 7.26913E-3 8.85508E-4 165..__. . _. 3.89019E .12 . . 7.28474E-3 8. 87409 E-4_ _
                    .._ . . - .-." 3.89019 E -12    ~7.31545E-3      8.91150E-4             j$_ o-p m
      .' l 6 8 . '                3.89019 E-12       7.33055E-3      8.92989E -4 169                      3.89019E-12        7.34548E-3      8.94808E-4                   /2/8/#d 170.

171. 3.89019E-12 3.89019E-12 7.36025E-3 7.37486E-3 8.96608E-4 8.98387E-4 W fpf g

  • 172. 3.89019E-12 7.38931 E-3 9. 00147E-4
    . 173.                     3.890.19 E-12      7.40360E-3      9.01888E-4         77-575-27 40 174                      3 .8901.9 E- 12    7.417.73E-3     9.03610E-4
  • 175. 3.89019E-1.2 J .4317 t E -3 9.05313 E -4 176. 3.89019E-12 .7. 44554E -3 9.06997E-4 177. 3.89019E-12 7.45921E-3 9.08662E-4 N .

178. 3.89019 E-12 7.47273E-3 9.10310E-4 \ ?3 179. 3.89019 E-12 7.48610E-3 9.1193 9E-4 4 180. 3.8901.9E-12 7.49933E-3 9.13550E-4 Y 0 h 181. .3.89019E-12 .7.51241E-3 9.15144E-4 db [b 182. 3.89019E-12 7.52535E-3 9.t6.72CE-4  % 183. 3.89019E-12 7.53815E-3 9. lB 239E-4 Ol 184 3.890J 9E-1.2 . .7. 55081 E-3 9.19820E -4 185. 3.8901.9E-12 7. 56332E-3 9. 21345 E -4 (k 186. 3.89019E-12 7.57570E-3 9.22853E-4 187. 3.89019 E-12 7.58795E-3 9.24345E-188. 3.89.0.19 E-12 7.60006E-3 9.25820 189. 3.890l9E-12 7.61203E-3 9.2727 -4 190. 3.89019E-12 . 7.62388E-3 9.287 2E-4 191. 3.890.19E-12 7.63559E-3 9.3 49E-4 1.92. 3.89019E-12 7.647.18E-3 9. 560E-4 193. 3 .890.19 E-l.2 7.65864E-3 9 32956E-4 194 3.89019E-12 7.66997E-3 .34337 E-4 195. 3.89019E-12 7.68118E-3 9.35702E-4 196. 3.89019E-l.2 7.69 227E-3 .9.37053E-4 197. 3 .890.19 E-12 7.70323E-3 9.38389E-4 198. . 3.890.19 E-12 7.71408E-3 9.39710E-4 199. 3.89019E .12 .7.72480E- 9.4 t o.16E-4 200. 3.89019E-1.2 7.73541 3 9.42308E-4 201 . 3.89019E-12 7.7459 -3 9.43586E -4 202. 3.89019E-12 7.756 7E-3 9.44850E-4 203. 3.890.19E .12 7.7 54E-3 9.46.100E-4 204. 3.89019 E-12 7. 669E-3 .9. 47 337E -4 205. 3.89019E-12 7 8672E-3 9.4855 9E-4 206. 3.89019E-12 .79665E-3 9.49769E -4 207, 3.89019E-12 7.80647 E-3 9.50965E-4 208. 3.89019E-12 7.81618E-3 9.52148E-4 209. 3 . 89019 E-l.2 7.82578E-3 9.53318E-4 210. 3.89019 Er l 7.83528E-3 9.54475 E-4 211. 3.89019E 2 7.8 4468E-3 9. 55619E -4 212. 3.89019 -12 7. 85397 E-3 9.5675lE-4 213. 3.8901 E-12 7.86316E-3 9. 57&71 E-4 214 3.89 9 E-l 2 7.87225E-3 9. 58978E -4 215. 3.8 19E .12 7.88.124E-3 9.60073 E-4 216. 3. Ol9E-12 7.89013E-3 9. 6115 6E -4 217. 3.89019E-12 7.89892E-3 9.62227E-4 218. .89a19E-12 7.90762E-3 9.63286E-4 21 9 . 3.89 0J 9 E-1.2 7.91622E-3 9. 64334E-4 220. 3.89 019 E- 12 .7.92472E-3 9.65370E-4 22.1. 3.89019E-12 7.93314E-3 9. 66395 E-4 222. 3.89019E-12 7.94146E-3 9.67408E-4 223. 3.89019E-12 7.94968E-3 .9. 684 l l E-4 224, 3.89019E-12 .7.9 5.782E-3 9.69402E -4 225. 3.89019E-12 7.96587E-3 9.70383E-4 226. 3.89019E-12 7.97383E-3 9.71353E-4 227 3.89019E-12 7.98171E-3 9.72312E-4 22 . 3.89019E-12 7.98950E-3 9.73261 E-4

9. 3.89019E-12 .7. 99720E -3 9.7Al 99E-4 0, 3.89019E-12 8.0048tE-3 9.75127E-4 23 1 . 3.89019E-12 8.01235E-3 9.76044E-4 j
   /
  • v
                                                                                                                                                               \             te D           r R, b 3

233. 3.890195fl2 8 '.'02 717E 9. 77850E -4 234 3.89019E-12 8.03446E-3 9.78738E r b,, gggg )g_ 235. 3.89019E-12 8.04167 E-3 9.7961 -4 /2/7 236, 3.89019E-12 8.04879E-3 9.80 4E-4 ddf n/,o/po /9o 237. 3.89019E-12 8.05585E-3 9. 343E-4 23 8. 3.8901.9 E-12 8.06282E-3 .82193 E -4 T7 -E~cS-27 #8 239. 3.89019E-12 8.06972E-3 9. 83033 E-4 240. 3.89019E-12 8.07654 E-3 9.83864E-4 241. 3.80019E-12 8.08328E- 9.84686E-4 24 2. 3.89019E-12 8.06996 3 9.85498E-4 24 3 . 3.890.19 E-12 8.096 c-3 9.86302E -4 244 3.890l>E-12 8.1 08E-3 9.B7097E-4 245. 3.89019E-12 8 0954E-3 9.87884E-4 246. 3.69019E-12 .1159 2E-3 9. 88 66 l E-4 247. 3.89019E-12 8.12224E-3 9.89431E-4 248. 3.89019E-1 8.12848E-3 9.901.9 l E -4 249. 3.89019E- 8.13466E-3 9.90944E-4 250. 3.89019 -12 8.14077E-3 9.91688E-4 ENTER VOLUME (IN CUB METERS.) 0F HABITABILITi AREA 7 STOP ofERMINATED* READY. BYE NEB LO OFF 16.17.05. SBd 16.060

   -fl0 m.       6728
     )6v m e.

O e h ,  %,sa., - - - - . - - . - . - - - - + + -- -- - - - ~ = = = * * - - ^ ~ - - " __--9 -- - - -

 +++ m ***:::::::::++ m s+::::====================: m +~

w

                                                                                    ~
                                                                                        ~          * ~ ' - ' -
                                                                              ++
 ++   TVA PROGRAM 26269 -CHI 220 REY. 1 JUNE 1984

, ++- /6DL OF 19

 ++ THIS PROGRAM HAS BEEN INDEPENDENTLY VERIFIED AND++                                 - --
 **   DOCUMENTED PER EP 3.23                               JUNE 1984          ++

co USERS MUST SUBMIT PROGRAM USER'S MANUAL REQUEST ++ g g p Ql C+ FORMS TO KATHY FRITZ , W9A1 C-K ++

 ++                                                                           ++         ( ,jb f gl 39 l p 97
 + m ++++ m +++ m + m m m m m ++++ m + m
  • m + m + g gg _g HAZARDOUS CHEMICAL IS  ? AMMONIA -

MOLECULAR WEIGHT OF AMMONIA IS  ? 17.031 INITIAL QUANTITY IN GRAMS OF CHEMICAL VAPORIZED  ? 140310 ENTER HORIZONTAL AND VERTICAL DISTANCES (IN METERS) OF SOURCE FROM RECEPTOR ? 426.7,15.8 PASQUILL STABILITY CLASS (E,F,OR G) IS ? G WINDSPEED (IN M/SEC) IS?() . ENTER VOLUME (IN CUBIC METERS) DF HABITABILITY AREA ? 8209. ENTER FLOW RATE (M^3/ MIN) ENTERING HABITABILTY AREA? 90.6 EXHAUST FLOW RATE ASSUMED TO EQUAL ENTERING FLOW RATE. IS ISOLATION CAPABILITY CLAIMED (YES OR NO) ? NO TIME CHI /O MASS CONC. MIN M^-3 GRA.MS MG/M^3

53. 2.69130E-25 7.20816E-19 8.78080E-20 54 2.85807E-23 8.07995E-17 9.84280E-18 -
55. 2.32902E-21 6.97199E-15 8.49311E-16
56. 1.45634E-19 4.63267E-13 5.64341E-14
57. 6.98780E-18 2.37151E-11 2.88891E-12
58. 2.57281E-16 9.35762E-10 1.13992E-10
59. 7.26880E-15 2.84794E-8 3.46929E-9
60. 1.57582E-13 6.69047E-7 8.15016E-8
61. 2.62145E-12 1.21439E-5 1.47934E-6
62. 3.34630E-11 1.70512E-4 2.07714E-5
63. 3.27775E-10 1.85483E-3 2.25950E-4
64. 2.46364E-9 .015662 1.90791E-3
65. 1.42091E-8 .102918 1.25372E-2
66. 6.28847E-8 .528092 6.43309E-2
67. 2.13556E-7 2.12568 .258944
63. 5.56505E-7 6.75477 .822849
69. 1.11279E-6 17.097 2.08271
70. 1.70745E-6 34.906 4.25216
71. 2.01035E-6 58.5195 7.1287
72. 1.81629E-6 82.5721 10.0587
73. 1.25918E-6 101.28 12.3377 74 6.69849E-7 112.191 13.6668
75. 2.73436E-7 116.647 14.2097 max Concentration
76. 8.56495E-8 117.443 14.30664
77. 2.05865E-8 116.738 14.2208
78. 3.79689E-9 115.584 14.0801
                                                                                        */ dmdSP*ed m al ^^
79. 5.37358E-10 114.336 13.9282
80. 5.83563E-11 113.084 13.7756
81. 4.86296E-12 111.843 13.6245
82. 3.10959E-13 110.616 13.4749
83. 1.52579E-14 109.401 13.327 84 5.74479E-16 108.2 13.1807 85' oINTERRUPTED+
  ***+E
  .4               :::::::::':::=============================: m *+d"^~~'~                                                              '
                                                                                                                                          ~~~
                                                                                                             ++        /5.3 op gi

. ++ TVA PROGRAM 26269 -CHI 224 REY. 1 JUNE 1984 ++

  ++

THIS PROGRAM HAS BEEN INDEPENDENTLY VERIFIED AND++

  ++ DOCUMENTED PER EP 3.23                                       JUNE 1984
  ++

USERS MUST

  ++ FORMS TO KATHY FRITZ , W9A1  SUBMIT   PROGRAM    USER'S            MANUAL      REQUEST
                                                                                                             ++
                                                                                                             ++         j g_m_pg C-K                                            ++

[yhf g 7q gg-

  ++ ::::::::::: m m m m m m :::::::: m m s m m                                                                                                .-

HAZARDOUS CHEMICAL IS  ? AMMONIA 8/k5 9-T-b3 MOLECULAR WEIGHT OF AMMONIA IS  ? 17.031 INITIAL QUANTITY IN GRAMS OF CHEMICAL VAPORIZED  ? 140310 ENTER HORIZDNTAL AND VERTICAL DISTANCES (IN METERS) DF SOURCE FPDM RECEPTDR ? 426.7,15.8 PASQUILL STABILITY CLASS (E,F,OR G) IS ? G WINDSPEED (IN M/SEC) IS ?

                                                   )                              ,

ENTER VOLUME (IN CUBIC METERS) DF HABITABILITY ARER ? 8209. ENTER FLOW RATE (M^3/ MIN) ENTERING HABITABILTY AREA? 90.6 EXHAUST FLOW RATE ASSUME'D TO EQUAL ENTERING FLOW RATE. IS ISOLATION CAPABILITY CLAIMED (YES OR ND) ? NO TIME CHI /O MASS CONC. MIN M^-3 GRAMS MG/M^3

27. 2.85807E '23 4.13755E-17 5.04026E-18
28. 1.45634E-19 2.36658E-13 2.88290E-14
29. 2.57281E-16 4.76900E-10 5.80947E-11
30. 1.57582E-13 3.40189E-7 4.14410E-8
31. 3.34630E-11 8.65100E-5 1.05384E-5
32. 2.46364E-9 7.93014E-3 9.66030E-4
33. 6.28847E-8 .266931 3.25168E-2 34 5.56505E-7 3.41036 .415441
35. 1.70745E-6 17.6229 2.14678
36. 1.81629E-6 41.7792 5.08944 37 6.69849E-7 57.0958 6.95526
38. 8.56495E-8 60.3291 7.34914 max coHCenh'at-i ors
39. 3.79689E-9 60.0198 7.31146
40. 5.83563E-11 59.3728 W/winck speed,s .LA/3 7.23265
41. 3.10959E-13 58.7213 7.15328
42. 5.74479E-16 58.0767 7.07476
43. 3.67960E-19 57.4392 6.9971 44 8.17116E-23 56.8087 6.9203
45. 6.29104E-27 56.1852 6.84434
46. 1.67926E-31 55.5684 6.76921
47. 1.55406E-36 54.9585 6.69491
48. 4.98625E-42 54.3552 6.62142
oINTERRUPTED+
                                                                       "~~~~'~~             "^*~~~ ~'-
  +++ m **::::::::::::::::::::::::::::::==+::::::::::::=
  *+.                                                              ++
  ++ TVR PROGRAM 26269 -CHI 224 REY. 1 JUNE 1984                   ++             ,$.O OF l9
  ++ THIS PROGRAM HAS BEEN INDEPENDENTLY VERIFIED AND++                            "~-"

c+ DOCUMENTED PER EP 3.23 JUNE 1984 ++ C+ 3 _ g - p ([ g USERS MUST SUBMIT PROGRAM USER'S MANUAL REQUEST ++

 ++ FORMS TO KATHY FRITZ , W9A1         C-K                        ++

C+ ++ h4Df 8f14f85' c m m m m m m m .. m + m e::::: m m m . m m + .

                                                                                              ~q~O'  r,-

HAZARDOUS CHEMICAL IS  ? AMMONIA h5 i MOLECULAR WEIGHT OF AMMONIA IS  ? 17.031 INITIAL QUANTITY IN GRANS OF CHEMICAL VAPORIZED  ? 140310 ENTER HORIZONTAL AND VERTICAL DISTANCES (IN METERS) OF SOURCE FROM RECEPTOR ? 426.7,15.8 PASQUILL STABILITY CLASS (E,F,OR G) IS ? G IJINDSPEED (IN M/SEC) IS?(h .. ENTER VOLUME (IN CUBIC METERS) DF HABITABILITY AREA ? 8209 ENTER FLOW RATE (M^3/ MIN) ENTERING HABITABILTY AREA? 90.6 EXHAUST FLOW RATE ASSUMED TO EQUAL ENTERING FLOW RATE. IS ISOLATION CAPABILITY CLAIMED (YES OR NO) ? NO TIME CHI /O MASS CONC. MIN M^-3 GRAMS MG/M^3

11. 2.32902E-21 1.52062E-15 1.85239E-16
12. 1.57582E-13 1.42432E-7 1.73507E-8 ~
13. 1.42091E-8 2.14134E-2 2.60852E-3 14 1.70745E-6 7.14249 .870081
                                                                                ~
15. 2.73436E-7 24.1751
16. 5.83563E-11 24.4569 2.94495 hTax concenteation 2.97928 :
17. 1.65975E-17 24.1885 2.94658 gjpggSpeej _ .T ug
18. 6.29104E-27 23.923 2.91424
19. 3.17780E-39 23.6604 2.88225
20. 2.13921E-54 23.4007 2.85061
21. 1.77004E-64 23.1438 2.81932
22. 1.77004E-64 22.8898 2.78838
23. 1.77004E-64 22.6385 2.75777
24. 1.77004E-64 22.39 2.7275
25. 1.77004E-64 22.1443 2.69756
26. 1.77004E-64 21.9012 2.66795
27. 1.77004E-64 21.6608 2.63867 2'
  • INTERRUPTED
  • j

m u < u...." TI-EtS-n ito Ifo-*SI9 tkITED STATES cOVERN31ENT d

   .                                                                                                        /kY/N 12po/80
     . Memorandum                                                        Tsunsssss vittsy Aurnontry TO       :

DES '800929 004 M. N. Spr'ouse, Manager of Engineering Design, WilA9 C-K FRO 31  :

                        ,f                                                                                                       c. '

R. D. Carnathan, Director of Co:::=erce, 226 SPE-K ,,[f F DATE  : September 25, 1980 9

SUBJECT:

EROWNS IIRRY, SEQ,UOYAH, WATTS 3AR, AND EELLEFONTE HUCLEAR PLANTS - HAZARDOUS MATERIALS STORED OFFSITE Ei, . . .3A_..__ f& [//278 /D0DA AW C.- , , . _ _ Per your memorandum request of August 18, 1980, C- " update of the survey of hazardous caterials stored offsite near thewe have cc=pleted our - ' Sequoyah IAtclear Plant. ( O No industrial facilities have located within a five-mile radius of the QJ..'.-T..M 4 nuclear plant since the Final Safety Analysis Report (FSAR) was prepared ~~ in 1974. The volunteer Army At=:anition Plant in Chattanooga which manufactured TUT has been closed since March 1977 and the land may be _ transferred to local officials for industrial developnent or other use .L. /4 g, i JAR' The review of the industrial the other nuclear plants is underway. facilities within a five-mile radius of gy,j. j If we can be of further assistance, please let me know. CSV! J.i'W RFC

                                                                     %2.m   / Ralph D. Carnathan
                                                                                                                    "*'T REB:C.Purkey                                                                                                           _

7 ' 9/29/80 - GFD: MPG EA%.. ..;n...o 0;.ggy cc: D. B. Bowen, 6204 MIB-K #d# AGAR'8 CFFI-w R. W. Cantrell, 204 GB-K (2) " W. R. Dahnke, Bellefonte CONST (2) R. M. Hodges , W7Cl26 C-K f - - - , , "" d 6 om,i MEDS, E4B37 C-K ' i Hua L. M. Mills, 400 CST 2-C -

                                                                                                    - ' R-Je        .t H. H. Mull, E7B24 C-K
                                                                                                 #     Md l                       f.G. F Dilworth, W10C126 C-K------Piease handle.--MNS [_                          ms          f G. G. Stack, Sequoyan wm @)                                     --

F. Van Meter,. 500 SPT-K (4) J. E. Wilkins, Watts Bar Nuclear CONST (3) c

                                                                                     -- - ~ -s~.L.                ~P ptc
     -                                               NEB MASTER FILE

_a L _ __ _ _ _ - . - - ---- --_-

     =   . - . . _ . _ _ _ .               - _ . .        _ .. -.                   . . .       .                     -        ..

I21'F 17 TI-ECS-27 RI /G.) el= 19 e

                                                                                                                   & 8'h L 4 l M S
                                             ,                                                        .            fh t R ' - 3 '~

Cq p %s/c/sr [ ^"'"k'.J.Klaes q May 7, 1985 R W11C106 C-K fh C "' C *

  • I_ a== l

_ =_,

                                         .                                                          w   s.o.

F R Thomas C. Fisher, Jr. 6430 0 ^""" l- oina l- =s M 2D46 OCH-K [ aa= C* BFN, SQN, WBN, BLN HAZARDOUS MATERIAL SHIPMENTS BY BARGE In regard to my 45D to you dated July 27, 1984, the only barge shipment category which could contain chlorine is WBC 2819 (Basic chemicals not elsewhere classified). There are less than 50 barge loads (shipments) per year of WBC 2819 passing Watts Bar Nuclear Plant. Thus chlorine is clearly shipped less than 50 times per year. Our source is the' Waterborne Commerce of the United States statistics, U.S. Army Corps of Engineers. AThomas _1A1.as C. Fisher, 'Jr'.

                                                                                                                    )

TCF:SF cc: C. Paul Jones. W9B102 C-K Thomas L. Majors, 2D49 OCH-K w l M a2 (0$l40) taitt0FMI M419G SLIP L j

 . '                                                                                                         \

RF i: ' / (.:. FI-EC_S-21 fil /6.E oF l9 LM eluln

                                                             '                                                                                                       ~

Sks 9-9-8F

                                                         *erw;                                                                                                         OArt F

0 .o,L. J. Klaes 7 N July 27, 1984 R

                                                                    ,a
                                                                                                                                                         '               l-    "'-        "1 Wil C106 C-K                                                                                            _
                                                            ...                                                                                                        w.m.o Thomas C. Fisher, Jr.

[ 6430 0 ^*"" o ns ut M 2D46 OCH-K = E = BROWNS FERRY NUCLEAR PLANT, SEQUOYA3 NUCLEAR PLANT, WATTS BAR NUCLEAR PLANT AND BELLEFONTE NUCLEAR PLANT - HAZARDOUS MATERIAL STORAGE AND SHIPMENTS Attached is a copy of a list of hazardous chemicals transported by barge and truck. We have contacted the railroads and expect to receive a list of hazardous chemicals transported by rail in the near future. When all of the information is received, we will compile it and send it to R.O. Barnett in reference to his memo of 1/11/84. 6%am Lcc / -+. /G'm.L

                                                                                                                   #               Thomas C. Fisher, Jr.

RJR:SF Attachments cc: C. Paul Jones, W9B102 C-K Thomas L. Maiors. 2D49 OCH-K _Th 49t%.e.p4  % e TW 450(0$553 mitt 0FFict uno% 3 LIP j

    .                                                                  TI- N.CS~21 LI          ygp HAZARDOUS CHEMICAL MATERIALS TRANSPORTED BY TRUCK N Th9/%T The investigation of hazardous' chemical materials transported                    II common carrier trucks within a five (5) mile radius of TVA's Nuclear Power Plants (Watts Bar, Sequoyah, Bellefonte, and Browns Ferry) reveals that minimal or practically no hazardous materials pass any of the plants.

The closest roadways to Watts Bar and Sequoyah Plants in Tennessee are Highway Nos. 27 and 58 which parallel each other in a northeast and southwest direction. The Roadways are within 5 miles of both plants. A telephone conversation with a Tennessee Department of Transportation-Hazardous materials representive - indicated that no major hazardous chemical-would travel Highway Nos. 27 and 58 because these roadways are narrow and are not major interstates. The only chemicals transported on these routes would be small amounts of fertilizer for local use and possibly gasoline or diesel fuel. Thestaterepreshativeindicatedthatsmallamountsofmany hazardous chemicals are transported by trucks, but these movements would utilize the major interstate roadway (Highway No. 75) which is well out of the five (5) mile radius of the nuclear plants. The same situation is believed to be true regarding the Browns Ferry and Bellefonte Plants located in, northern Alabama. The closest roadway in a five mile radius of these plants are Highway Nos. 72 and 72A. Conversations with - various management personnel from chemical industries located in Decatur and Muscle Shoals, Alabama indicated that none of the industrial plants used Highway Nos. 72 and 72A. Reasons cited by industry personnel were the roadways are much too narrow (two lane traffic only) and are not suitable for interstate traffic and end markets are in different directions from both nuclear plant sites. Thus there is no need to pass by the power plants. e J

1,! l r i 7 ' j'; l q- ,< j

                                                                                                                                                                 .                                   i ll                ,7
                                                                                                                                                                                                                                        -f i               /G.V op 19 c         .                             d                     .

rr-e cs-z, ei

    ~

c # $9/sr a , m 1 w

    .                                    !                           .     .                                                                             I e.r                                           g                    a     as      ;

e . . i% { ( A.,:.f$ e4

  !                                                                                                                                                                                                                                                                                           ?.'?

2 '.. , .

                                                                                                                                                                                                                                                                           .,,.l.

C

           } '. -

1

                       . L .h 4        -h.               }     3 3
                                                                                   ,)                               .                                                       .                             .
                                                                                                                                                                                                                             .           ,-    v. ..       =

afc;-h

  .t                                                                                                                                                                                                                                           .a-c-4     .           3 .

e , .

u. a, ., , Wm .
                                                                                                                       '                                                                                        '=

[f: I..- -

                                                         ~i.                                                                                                                                              .h                        's ..),.'

e,

                                                                                                                    -                                                                       s
                                                                                                                .                  ,.                                                                                       ;       .                      4 fn       ; .# .-     '

n . .

s. , . . . .w. . .

a.g m .

                                                                                                         ~m  .
                                                                                                                                    ,                                                   u.v:;. s.

m..w ., , g y' e w t...*,  : ,1 '- -

                                                                                                    ,                .                          .                              . . a. .. ; i
                                                                                                                                                                                                                     .    .r             a c ,1S                             ,-
                     #:; .:.                   u, -                                                                                                                                                                .
                                                                                                                                                                                                                                               ..                              a f-

_f \ J ) $ h h h d U d k 3 3 ) .d . v, F +. . l

                                                                                                                                                                                                                                              ..     .                      n,
                                                                                                                                                                                                                                                                      > fp d-     ,

p i . t ag

    =

y-g t i!Nd'2G 4-oa ece  %? GC iSl???3 cccc ewew k ' k g l

p. ;'. .- a c.4 ie,qt is e t 51113
 \%                                    ! .3            r           e c c + :D                                       m$                                                                     1                     F                    n E      '- T E
                                         .           gE94^s
                                                  .~tA+4e iGQs s,+                ,Q     9mmv9i,   q q ry       gQ      g 4 *" "v @8;* " U          '

u  ; --

                                                                                                                                                                                                                                                                                    .y
                                                                                                                                                                                                                                                                                         ~

s-n

                                      ,-                                                                                                                                                                                                                                                ' k1 i                         .*f                                                                                                                                                                                                                 ~
  • l k0 3- m a

L l 24 3 g x T'.s- c

                                                                                                                                                                                                                                                       .                           . v. s
                                                                                                                                                                                                                                                                                      .m Dks                                 i                                      I                                                                    l                   l                                                                                                                  5 J*                                i                N Regi                                        J.                                                                                                         a                  4-                                                 2 9 3                                                                                   D~ T+g                                    u.Lis.]Anl tm," wl";,,l e                   n i                                                                        s,                                                                                                r I g!g $ s1 y1s "
                                                                                                                                            -on-vz                                    1   ;                                                                                           -

1 'i 11 T1 m I# l - J

  ,kn 'w                                                                                                                                                                                                                                                                         -
                                                                                                                                                                                                                                                                                          ,e i.

s ,s . .u-1L . J. %w . .. 5' N. EM lw i d h I a I u lll, i dk c- l

                                                                                                                          ,                             l                 l I l I hl.          ..

I" m a (; i i. l -

  ;                               7,-                                                         _
  .                              p                                                             -

r- - ~+

                                 )                                                                                                          ]
                                                                                                                                                                                                                                          ]                                                     ;

[___ _ - - _ . _ - . . . _ __. _ . _ _

i pi, -a,o.;. -

                                                                                                          ; ! , i i.
t. - -
                              . . ld.                                                                                                                                         -
                                                                                                                                                                                                                        /6.t og                          19
                                        !w s

3 I rr- Ecs-2.7 A

                                         'd Cd ek9)W (p                                     }                        ,

4f E 9-D E 3 a 4 t 3;. t

g. <..
                                        'W                                                                                                                                                                                     ..a.w g.

t

, . a e .' H i' h!. '- '
                                                                                                                                                                      ~
                                                                                                                                                                                                                   '.'       E$b gj p

i M 1 1

                                                                            )  J J J 1        )      ]         4 4                           .
g. y  ;

g - q {q . n  : . g

                                                                                                                                                                                                                                               )

g _- u. - m.:#., .

                                                                                                                                                                                                                  .s .                           .,
                       ;i {

e  ;-: c wy g gg, ru gs (.' ; . -:

                                                                                                                                       ~

f.f ....3 ..

                                                                                                                  .  ;                     ; :. e.r;   .
                                                                                                                                                                   .c
                                                                                                                                                                      ; 7 :g
                                                                                                                                                                                     .c     aggt3                              }s;$5 b
            '.                                                                 \                            b
                                                                                                                                                                                                     .) .;*' Q    v' b

3 - s J } h _

                                                                                                                                                                          .h    -
                                                                                                                                                                                     ._.h a  _

y;.c a-

                                         ).
                                                                                                                                     -                                     -                        ~                   ~

m ~ v

      ,                               l                                                                                                                  .                                           .

r .. ,

                                                                                                                                                                                                           .      .,.. s e*T,,
                                                                                                                                                                                                                                                .m

_,.0,

     'h
                                                                                                                                                                          , ,- (Q..'                        '. ?;               ,.~l A, I

l

                                       .g             , w. p+Irz.
                                                         + e +l e *l m-t . .u4. ,a am m- ,,-l l l u-    .
                                                                                                                                                                                                                .+

n.. e. 3 V e- - - - A re v.- - - ..

                             . s ws.sMct j          .

aamq= ~ ~

                                       - I! ' m. s e,a ,a t4, ,8 A,d, *
  • d 2,, 2,, "7 ; g g" *g $' g y 7'
  • n o4
  • Q g' g
                                                                                                                                                  .        n' d,       S g'T
                                                                                                                                                                                                                                       ' ~ m.

j2!

                              *' O
                                                         -.                                4 7                                                                           Qs                                         _;,._ ;
         ] !

I hhRSRI ##5 / hen 6 e (' 4 4 4 '4 aJ 4. .a ,; avyry, j,

                                                                                                                                                                                                                                 ~x4  .

f ' h,2;, y. l3 3;t u.r.r (- gg "Jl k . 19 x i

                                                                                                                                                                                                                                 .r.

M .s.. .

                                                                                                                                                                                                                                 - .              8 3 h., p! ~R<        o N       CI .ue--   r bj,nb,x
  • e 5,r e2 d p

[ " *  :-

                                                              ~ c c"; %,s ec' <Cs                                                                             N, O._,

5-I - .a d, i

                                    ;y; i ;a ~~. ~' '~

c-1o ~%~e n ~ e -. ~

                                                                                                                    ;'        m~ -+w , x w g                                         w
                                                                                                                                                                                             ,                                 c m.q.!:

jg . i a -

                                                                                                                                                                                                                 ,                 ..r. .. ;

S~ y,y t q 2"

    %BC                                     ;qV,                                                                                                                                                                                        .

3nTc' m 1 9 ve '

                                  . g 3, . ,

jNb f q E !R

   !           i L

g el , . , . l l I I .__ I I I I . l l l i lil -._ ._ I

                               %l             ~
                               -              g                                                                                                                                                                                                  .,
                              -)
                                                                                                           )
                                                                                                                                                                                                   )                                         .. -;
                                                                                                                                                                                                                                                 .3 l                                                                --^

m - j

_..______..:.--:.._....__....c_-__.. . . _ . . . . _ _ ._ . s ter //o /o e, I9 ' SmuosAw M tR. Ihraniury r-r -- acs-n a; CCWUTE0 Q OATE k l . cuccxto 4M oair '7 'f - % C I 1 8M.6E TRAFFIC., NEAR. h ovo'tAH )duc LE M . M a r i

                     % a x A g.3 :

YHe heho op pp. 17-ie i=non RD CnRrAri+nr> ro htN SPAouse parea e--zq-go / isTs 1978 0pr5) RECrk2 DING- HAZARD 005 SHIPMENTS PASSING- $2Gv01AM BY BARGE. '7~HE ONLv Cl+SMicdLS LI,SrED ID TkE h5MO INit/CH CovLD PoSS/6LY PRESEDY A TCXIC. GAS T?fAEAT 70 MCA HnBITAB/LITY JS CODE 28/9,

                       " OASIC CH&MICALS, NEC  (NEC =VAtor &LSGwitedE CLASS /FIEb *) .          A SUBSEQu2Nr /2/!/83 PHONE ConvmRsATIOM BETwenn                    C l.d. PhEKEA ANO k) ABusvins, Aurytck oF T1te MEMO, CDNPIAM20 Tl+AT 8kNC,15
         .             sitj???E473            0F T)+IS Ckr560KY M 1U07 EkCEED l                       50 / yR , T}t G FR20 t)ENCY CONS!DEt?GD ,S/GN)f/CALT l                        o'/ RG / 7 2.

l heRE I2ECENT* BAR&F_ SW)AbfENT DATA C04YKI,UEA) IA) REP /fo (PP /6.2., /6N, /6 5,) OF Tit /S ANAL'/5/$

                         /S NOT MucH 0/FFERENT FAQM 1 REVIOUS                            0                 DATA.

I?EF/5(P16.]0F T1PIS ANAL'/ SIS ALSO CohrtRh5 2819, 'Bnsie. Caen)iests, NaC , ocas THAT CODE NOT HA ve how 7)+A A) 50 SH/PMENTSyl'fA. .

                        .tr- IS TituS           co,uctuoso      THAT BAME sp-sphEnr5 OF CttwMICALS             P/tSSINCr SEcuovM h)ucLEAR. h Rr reescur m me. c,ss rnwr ro ace stinimeiury.
           ?

6 i

_ e =wnum- 4 * - "

    , .m ** ' n 5 u '                                                                            .l T a 4 I 9
  '     UNITED STATES GOVERNMENT                                         7 /-fG-27 Ro               jb W Memorandum                                           -

rtuxzsszs vittzY nrm @Y To  : DES '800902 016 M. N. Sprouse, Manager of Engineering Design, WilA9 C-K' FROM  : Ralph D. Carnathan, Director, Division of Commerce, 226 SPB-K DATE  : August 29, 1980

SUBJECT:

BROWNS FERRY, SEQUOYAH, WATTS BAR, AND BELLEFONTE NUCLEAR PLANTS - HAZARDOUS SHIPMENTS

                                                              /p (p'ezrrom/x 7)

In response to your request of August 18, 1980, for a listing of hazardous

                    =aterials which are frequently shipped past the various nuclear plant sites,

'. attached is a list of the total traffic which passed the Sequoyah Nuclear 2 Plant during calendar year 1978, the latest year for which information is' ' available. C, . c:: In comparing the total traffic to the attachment which you sent listing _ materials which the NRC considers to be hazardous, there seems to be nonO passing the Sequoyah Nuclear Plant. We are unable to further identify tYe ~~ commodities except as shown. However, tho'se commodities having at lease. N -- 50 barges a year include manganese ore, coal, salt, pulpwood, residual -- O '. '. fuel oil and asphalt, and tar and pitches, none of which appear in you - attachment. Information on the other plants will be forthcoming. dQ A_A?$ g' - w Ralph D. Carn b an t3[p _ WAB:BJP I p Attachment ENGINEER 1;.*G DESIGN MANAGER'S CFFl i 9/2/80 - RMP: MPG * *** cc ( Attachment): l '" D. B. Bowen, 6204 MIB-K R. W. Cantrell, 204 GB-K (2) 'l C " l j , pare, i W. R. Dahnke, Bellefonte CONST (2) iw= l

                        /G. F. Dilworth ; U10C12f>_C-K . Plea.se,_ handle ._--MNS          i           l R. M. Hodges , W7C126 C-K                                     /              I MEDS, E4B37 C-K                                            #       **        '

L. M. Mills, 400 CST 2-C H. H. Mull, E7B24 C-K J/gg' y'(g # 4:.,/ G. G. Stack, Sequoyah CONST (4) F. Van Meter, 500 SPT-K (4) y/cc, - J. E. Wilkins, Watts Bar Nuclear CONST ( 3) ~ ~ ~ ~ i NEB MASTER FILE

77-EU-n eo Pg.Ie- M9 WOW TENNESSEE RIVER TRAFFIC PASSING SEOUOYAH NUCLEAR PD.NT 0 6 (Tennessee River Mile 484.5) Calendar Year 1978 Code Commodity Net Tons

                                                              ~

0107 Wheat ,773 1011 Iron ore 14,390

                                                                        ~

1061 Manganese ore 152,043 1121 Coal 182,021 1411 Limestone 2,800 .: 1491 Salt 146,036 2062 Molasses 7,985 2415 Pulpwood 317,407 2611 Pulp 32,039 2621 Newsprint 20,882 2631 Paper and Paperboard 7,141 2810 Caustic Soda 7,811 2819 Basic Chemicals, NEC 42,174 (Methyl, Methacrylate) (37,137)

 .                   2871       Nitrogenous Chemical Fertilizers                            -

4,825 2879 Fertilizers and Materials, NEC 10,491

                  *2915       ' Residual Fuel Oil                                                132,681
                  *2918         Asphalt, Tar and Pitches                                         151,379 2920       Coke                                                              14,640 3291       Miscellaneous Nonmetallic Minerals                                     346 3312       Slag                                                               2,918 3314       Iron and Steel Ingots                                              1,186 3315       Iron and Steel Bars                                                1,504 1                      3316       Iron and Steel Plates                                              3,473 331'8     Ferroalloys                                                         2,800 3319      Primary Iron and Steel                                                    35 3411       Fabricated Metal Products                                             125 3511-     Machinety                                                              575 3611       Electrical Machinery                                                  150 3711       Motor Vehicles                                                        235 7

3791 Miscellaneous Transportation Equipment 125 l j Total 1,262,990 Source: Corps of Engineers, Department of the Army

                     *Fla==able licuids_ as _ classified _in _the " Cede of_ Federal F.er:.latic s".._  __ ..

3

s/9 s-

                                                                         , u i-             a                                                  /* M~W i
!                                                                                                                                                             l 1                                                                                                                                                             l een es ,ee.e ,                                                                                                                     1

! == mm ==x==xT 84040600030 i Memorandum TEWESSEE VAUEY ALTTH0mY l 8 DOC '84 0313 004

1. W. Cantrell, Manager of Engineering Design (Acting), W11A9 C-E
                                 " *                                                                                                           ~

Charles Bonine, Jr., Manager of Construction,17324 C-E '

                                       ' March 13, 1984 EUT' BROWNS TERRY NUCLEAR PLANT (BFN), SEQUOYAH NUCLEAR FLANT (SQN), 'JATTS SAA NUCLEAR FLANT (WBN), AND BELLETCICT NUCLEAR FLA!iT (BLN) - HA2.ARDOUS CREMICAL STORACE I

In response to your January 30 subject memo (CEB 840130 013), following is j a listing of hasardous construction material stored at VEN and SLN. Freieer Material Quantity Storante Location I j W8N Muristic acid 165 gets Rut 7 ELN Acetone  ! - SS gal Const Storage Shed drva Anhydrous Aamonia 2 - 300-lb Concrete 34tch

                                                                                                  ~
                                                                                                    .      como gas               Plant
                            " .7.14 ' .            I bottles Carbon Dioxide                       85 lb cos;                 const Bottle
                                            , _,                                                           gas bottles            Storage Shed j                  ~ _ ' _ ~ _ _ Heliuun                                         6 - 220-cu ft              Coast Bottle
                     ._n                                                                                  coep gas               Storage Shed
                                ."'                                                  I
                                                                                     .g                   bottles
                       !^                                   Nitrogen
  • g IA 45 - 224-cu ft const Bottle

_, ~7 coep gas Storage $ bed

                                                                               ,hh                        bottles Sulfuri                      d       21 - 55 gal dru:ss               Warehouse Shed D           I 3

_ , ,d4 N -

                                                                                 .? N3                              Chart       ntne, Jr.

S. Cor, 'dellef nte CONST C. Wadewits, Watts Bar N. CONST DES '84 0314 027 MEDS W5863 C-E 3/13/84 - MFC . , ce: SEE OTHER SIDE FOR IN DES Princlpelly prepared by R. A. Fedde, Ext. 3735. DISTRIEUTIM CK6073.M2 I e i l

  -   --    .-       . ~ . . - . . . _ -                             , --           - - - -                      -
                                                                                                       / 2'. 2- oF 19
         ~

TE- ECS-27 RI ca eks/w \ l /;M S-?-9[ } 4 I 1 l 3/13/84 - 390 es jL I. Barnett. W90124 ^" *1aase headia.- 41C l

                                                 .. _._., wr uu            - -
6. L Ba11, 4206 IE34 L M. Badges.1127 IEEE
  • L L P1 arse.104 ISTA4 '

J. P. Timeyard. H3D124 C4 me: IEDs. M5363 M CE814 0326 00 8  : 208 QM - 3/26/84 cc: J. A. Raulston, W1 y6 C4 - Th1e infaranttoe ie supplied is respeces to  ! act M* W3 C4 \ an inf rami repet by L. J. Klaas of your staff. Input by oths.rs is still pending. j

                                                                                                              -ace                 ,

I l -. i I d e 8 J

                                                                                       ^^
           ~

A P P t=uD iv A . <<1 /9.3 o, 79 TI - G CS-2.7 R.1 ccourco_Gf_e1e s //r/9e

c. c... Dw c.1, -/u/ar PAcetisM : mMo rite sooAmM T$T BEFIMES TWE coAlcEDT9.AT1oM O F- A PO L Lu r6 A1T wirHiA) A coMTROL voLost WITH RES PECT TO TIMs . Assume coucgunagne IS ZERO AT T1h 2 iltG90, CONC. IN GUPPLY AlR. l5 CCMSTRMT, 1+0Mo &EDEous MI x Tu(LC IM Cc4TR6L vouumg, Ana prov.,
                 /M s%D 007 ARE E00AL.

SoLvT1on ; [ cat t ExuAVST M AIA C(m

  • 8(*

i=' o* c< (  ; GCM 4  ; SUPPLY Aa 3 ~_1 nn V (.4) ABa '= 'o d aft t A = w h Y p oMia & f u d b q D (~y-) A N/~3) e=fl~ c.: N cf p s4 Ao.At., c-he h (*%3)

 ~

v = u h q a d A (~.3) q=44pA u sek

                                                 'u> u a t M Ar &

cw cla = L.va,n n a Q M f % dx

                              % t , ek, nd                  db Ami k., tA.oce&diud.u arpa h tA4          c = Q/vq ("t   ps/+f 3     A r.A., e_ht.,dA, f .ts & A %

(i %. e ed -~4 .6su d w% th &+ 9aag4aww. 6 -cLt. uduvaa) Je clu.u ta-J.Lv AdC ak eM tib p J.L%d sdva 6. cv Lt G k:r ) x. A ( $ ) = S A (_ *- *4 ) H m ,s a. u a+ ts. p a g a t e g f " T.k .s e e. A

         ;5 s

a h(Q) n clt (+) = BA dt (~g )

         ~

c _b

o o s ar /9.4 o, M r r - 0:CA-r) R)

     ~

co m reo Yeare ll1fl8$ emooMMf o.1, shz/er-sfMt. , % tlu coaurn 4 JJ:2ni in th.

                & oA .2                    hwt* Tk ad                                                t     k %, u a4 %, wt&A                                 c: o/v a t4., MJ Au 4  T4         'c,  c                       cA e (%3 ~                        "v ( ;\) a*(+)= pa at H syn ,

dQ = d.c (B A - $a A O) d9--F 3y Q =- B A q,. cLt ! Te A.id A> L b A 1 $ % cys#b hA b/(s NI g.t e.5e de=e 5v9EG=ev 1 h 0) b M $M ae at ev do dt + YeG

                                                             =              BA 6 "

M'h t3J4, d ,et h e a GeV = (g)TaA e ~s v g 2 61 V h OfL Q= " A 4' Mt. & E I $

           =

e  !* )$,( c9 sntti )k r r - r= cs -7, ai

 .~.                                                              co-1,    G P .. i h r/a r e,.ce co 4 % oire 3/22 /6T~

SM 3 clt, &&.0 m t - o, q =a m (A o = VA + d a d e -yA

                                                      - as bl owct. ,           Q: VA - VA e.

8

                     ^             Q=     VA(l-e.,4) w       o= cv Cv=VA(1.e.. gy_      _ar)          .

1 cA- Eck r 1 C. = A (l - e " ) l( .

             ~

p h, W th (Je9 _ tyAf :C ad AM pt 6 C= A - A e _. e_t _ A e. V - A -C

e. j _

d A- c-G A et ev = A-C g In kd- ^ (A c)

           !                G_t,

_  : In /_ A g i V (A-t 1_ fD g I Ac)z f=~dld E 1

( .

 !#                                                                        snet   'lY    or f9 GOAl    FHrf    I-/Ae/TAbll/ry                                        T1 -et s -D   RI
   ,                                             12.1) d nIz9Ief eemna !?W a,re 13-9-20 1
                                                     /h- 9 91 -8 7 eneno GA oan Uholso
                                                                                   .%WM     5 42S/ 8).

(2E7ElSt/LES I)"~iwshold L,eni+ Values for Gom, calli,sJanus and P%sical 0 +n+5 in 1ke. Wochoom G'n vironen4n+' b +he Amn. cs n ('onfrunce o { Governrnonk( Jedusfrial Ik3 ents& i D Dan $mous Proc o rHos n -f Tsdu dtia l tria locca I, , 4 6 EdHio n , bn N.Trvio s $5.

3) 5 9,0 Orwg 4710930- Series A ') son Deso 5 47 tase o -Snw.s
5) "Ddhston a4 ven-l#d Gas Oround Buildioss , by 14lasky G) Ole foorolou and Alomic E~nnaw '

lo)62, b s USAEC

2) .5QAl 0(w B) SON DrwQ2 tac 5-Snies 4 W 863-5 *r.' s ,

9)SQN Drv>$ O m saw or~q 4,awx A'1 LJ310 -Sen*#s

                                           -sarus                                       -
             ,ll) CEl 00h book o l Chemish) ord Oh           f sics ,5yh gd,
12) Bob denson , persoral con #rs<fioh o n H- D-80,Ndcl%f bo W* f, cka knoo B') Regvlo.%gg.bv'ide I. "iaA:supFons for Evalvo.bg n e-
                    %%Idi\;          oE a Alvc. Isar. Pows <- P/s.n + con kor' Room DucJn           P,3.A;te.k4     Hawdous             Chd cx \ klec.sc "

14d ih v\a. %g GJ,b.a 195 ' h4ec.Inon o 0 Ouch be- ~PI% + 3 Con 4rol Poom Opvuhoes hey,'as b o. . . /lcc's d u h l C_blecioc. h.lco.s e. " RI 15) 45D from r. c.. Fisher to L T. Klaes clated 5-7.es, (inc.luded as p. lG,. I ) . 16') 4 50 from T.C. 1:isken to L.T klaes datel. 7-2.1-95, (iwcluded as p p. is.2. - sc:,.s') .

17. Memo Stom C. bine to RW Cantce)) dated 2-n-es, C j_ (oes s9osiv o27)(iuluded as pp is.l-12.7.).

j 18. H uAr TMusrta , s.p. )+xnAN, sectioy 11-3, nna.o B Eorrio n i M'6 Mw tt u. , m r 2. . I i

e. e ENCLOSURE 3 Proposed Technical Specification Changes SEQUOYAH NUCLEAR PLANT UNITS 1 AND 2 (TVA SQN TS 78) Determination of no significant hazards considerations for proposed changes for deletion of chlorine detector requirements.

 = :- : = z- - _ u .__...       -

a

     ,e e

Attachment E SIGNIFICANT HAZARDS CONSIDERATIONS 4

1. Is the probability of an occurrence or the consequences of an accident previously evaluated in the safety analysis report 4 significantly increased?

No. The purpose for the detectors is to ensure main control room (MCR) habitability in case of a chlorine release at, or near, the site. This is accomplished by initiation of MCR isolation from these detectors. TVA's analysis TI-ECS-27 " Main Control Room Habitability During Hazardous Chemical Releases at or Near the Plant" concludes that this situation is no longer credible due to the cessation of I storage of significant quantities of chlorine on site. This, coupled with the evaluation that no significant quantities of chlorine are transported or stored within five miles of the site, assures that the probability of the scenario previously evaluated by the safety

;                            analysis is not significantly increased by the removal of these detectors.

j 2. Is the possibility for an accident of a new or different type than j evaluated previously in the safety analysis report created? l

No. These detectors are designed and installed for the expressed i

purpose of providing MCR Isolation due to chlorine release. The physical removal of these detectors and their sensing lines does not 4 affect the operation of the NCR emergency ventilation system or the i MCR isolation functions for other events. Thus, removal of this function does not create the possibility of another type of accident. { j 3. Is the margin of safety significantly reduced?

l. No. The margin of safety afforded by these detectors is provided by t

their isolation function only. Since this function is no longer i needed, as evaluated by TI-ECS-27 (attached) to ensure MCR l habitability, the margin of safety is not significantly reduced. The control room will continue to meet the requirements of Criteria 19 j " Control Room" Appendix A to 10CFR50, " General Design Criteria for , Nuclear Power Plants." The margin of safety for the design bases l LOCA is not reduced since the physical arrangement of the system l precludes any increase in radiation exposure due to the removal of the detectors. i 6}}