ML20198A298

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Technical Procedure CP-217,rev 7,PCR 98-034, Specifications & Surveillance,Secondary Chemistry
ML20198A298
Person / Time
Site: Calvert Cliffs  Constellation icon.png
Issue date: 09/15/1998
From:
BALTIMORE GAS & ELECTRIC CO.
To:
Shared Package
ML20198A279 List:
References
CP-217, NUDOCS 9812160220
Download: ML20198A298 (24)
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Text

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kl CALVERT CLIFFS NUCLEAR POWER PLANT l i

TECHNICAL PROCEDURE CP-217 SPECIFICATIONS AND SURVEILLANCE:

SECONDARY CHEMISTRY ,

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REVISION 7 PCR 98-034 Safety Related / Non-Safety Related REFERRAL USE - PERIODICALLY REFER TO PROCEDURE DURING US i

Approvali >thority .

Effective Date M .

M 9812160220.901210 DR ADOCK'050003 7 Enclosure 3

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l . 1 Specific tions end Survrillince: S:condary Chamistry CP-217 v Revision 7 Page 2 of 24 RECORD OF REVISIONS AND CHANGES Revision PCR Number Number Summary Of Revision Or Change

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7 98-034 Added definitions of C/DR-M and 3/W.

Changed verification frequency of most in-line conductivity monitors and I conductivity balances to monthly from weekly due to their demonstrated stability.

Added Cation Conductivity AL 1 values and raised Cation Conductivity values  ;

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in Condensate, FW and SG systems when using ETA (amine with low thermal I

stability).

Changed Attachment 1 SG verification frequency for pH from weekly to monthly.

I Removed in Attachment 1 fluoride and silica analysis requirement for SG.  !

Referenced new CP-236 as replacement for guidance previously given in CP-l 224 for SG Attachment 1 and 2.

Removed in Attachment 3 Tritium and gamma activity requirements.

! l Reduced in Attachment 4 surveillance frequency of FW additives to three times a week rather than daily; with the addition of trending Specific Conductivity and Chemical Usage.

Added in Attachment 4 & 5 AOP-10 Major Condenser Tube Rupture criteria.

Added to Attachment 5 Cation conductivity Actiol. Level 1 values to establish set point control value. Then added Note 5 to clarify when further action is required. Removed on-line pH monitor requirements for Condensate sample points.

Added note on attachment 5 & 9 to perform verification check on in-line instrumentation on Condensate Demin panel within 1 shift after in-line instrumentation is brought back in service.

Changed Attachment 7 Main Steam Cation conductivity (if ETA used) Target to <0.8.

Removed old Attachment 8 Heater Drain Tank, suspended solids analysis requirement.

Reduced, in the new Attachment 8, CST surveillance frequency to monthly.

l with DO stJ1 done weekly.

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Specifications cnd Surv:illinCe: SeCOnd:ry Chemistry CP.217 s Revision 7 Page 3 of 24 TABLE OF CONTENTS 1.0 PU R PO S E .... .. . .... ... . .. .. ....... . . .

. ..... ........... ... 5 2.0 APPLICABILITY / SCOPE. .. .. -

.........................5 i

3.0 REFERENCES

AND DEFINITIONS . ... .. . . ..

........ .. .... ... .. 6

A. PROCEDURE

DEVELOPMENT.. .. . .. . . . . . . . . . . . . .

B. PROCEDURE

PERFORMANCE.. .... . . . . . . . . . . . . .

. .. .. . . . . ....6 C. DEFINITIONS.. . . . . . . . . . . . . . . . ..

... . 6

.... 6 4.0 PREREQUlSITES ..... . . . . . . . . . ............... . 7 A. RESPONSIBILITIES.. .. . . . .. . . . . .

B. SPECIFICATIONS AND SURVEILLANCE., .

. . . . . . . .. . .. . 7

.. . . . . . .. . . . . . . . .8 i 5.0 PRECAUTIONS . . .

............. . .. . 9 6.0 FERFORMANCE . . . . . . .. i

.. ......... . 9 A. SURVEILLANCE . ... .

- . . . . . . . . . . . . . . . . , . . i

. ... . .........9 -

B. SPECIFICATIONS AND SPECIAL CORRECTIVE ACTIONS.... .. . . . . . . . , . . .9 C. GENERIC CORRECTIVE ACTIONS .. . .

D. OUT-OF-SERVICE MONITOR * . . . .. . .

. . . . . . . . . . . .. . .. 9 i

. . . .11 7.0 POST-PERFORMANCE ACTIVITIES ... ...

. .... ... .... . . ... ........ .. ... ...... ...... .......... 11 8.0 BA S E S .... . .. . .... . . ... . . ..

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. .. . ....... ...... ............... 12 9.0 RECORDS......................................................................................12 ATTACHMENT 1, STEAM GENERATOR CHEMISTRY - POWER OPERATIONS (MODE 1) .

. 13

! ATTACHMENT 2, STEAM GENERATOR CHEMISTRY - HOT STANDBY (MODES 2. 3 & 4). ..~. . . .14 ATTACHMENT 3, STEAM GENERATOR CHEMISTRY - WET LAY-UP (MODES 5 & 6).. .. . .

.15 ATTACHMENT 4, FEEDWATER CHEMISTRY - POWER OPERATION (MODE. 1)..

.16 j ATTACHMENT 5, CONDENSATE CHEMISTRY - POWER OPERATION (MODE 1).. . . . . 17 i

ArtACHMENT 6, STEAM GENERATOR FEED SOURCE - HOT STANDBY (MODES 2, 3 & 4) . . .

. .18

!. ATTACHMENT 7, MAIN STEAM - POWER OPERATION (MODES 1 & 2) . .,

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.19 ATTACHMENT 8, CONDENSATE STORAGE TANK CHEMISTRY- ALL MODES .

.20 ATTACHMENT 9, INDMDUAL CONDENSATE DEMINERALIZER EFFLUENT- POWER OPERATION . 21 (MODES ATTACHMENT 10. CONDENSATE DEMINERALIZER REGENERATION SPECIFICATIONS . . 22 ATTACHMENT 11, STEAM GENERATOR BLOWDOWN ION EXCHANGER EFFLUENT . POWER OPER ATTACHMENT 12, CONDENSATE PRECOAT FILTER (MODES 1 - 5) .

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Specifications and Survsillance: Second ry Ch:mistry CP-217 Revision 7 Page 4 of 24 LIST OF EFFECTIVE PAGES

' Page No . Change No. Page No Change No. PaDe No Change No.

1 2 -

3 4

5 6

7 8

9 10 11 12 13 14 15 16 17 18 19 20 21.

22 23 24

Specifications Itnd Survrillance: S2cond:ry Ch:mistry CP-217 s Revision 7 Page 5 of 24 1.0 PURPOSE This procedure provides the Chemistry Specification and Surveillance Program for the steam generators and associated secondary systems.

2.0 APPLICABILITY / SCOPE A. - This procedure is applicable to the Plant Chemistry Unit.

B.

9 This procedure is applicable to the Chemistry Technical Services Unit and Supervision.

C.

This Chermstry Si+:4E+Rn and Surveillance Program is applicable to the following

,< systems:

1.

Steam Generators (All Modes) j

2. Condensate Storage Tanks (All Modes)
3. Feedwater(Mode 1)
4. Condensate (Mode 1)
5. Main Steam System (Modes 1 and 2)
6. Steam Generator Feed Source (Modes 2,3, and 4) 7.

Condensate Demineralizer Effluent (Modes 1 and 2) 8.

Steam Generator Blowdown ion Exchanger Effluent (Mode 1) 9.

Condensate Precoat Filters (Modes 1-5)

This program is based on Technical Specifications, BGE interpretation of industry i standards and recommendations made by Combustion Engineering. It ensures a timely response to chemical and radiochemical excursions with appropriate corrective actions.

l Remedial actions are specified to minimize corrosion degradation of components and to ensure that secondary system integrity is maintained.

D.

This procedure meets the Surveillance Requirements of Technical Specification 3/4.7,1.4  !

(ITS 3.7.14.1) and is captured PER EN-4-104.

This procedure implements the Secondary Water Chemistry Program described in ITS  !

Administrative Controls (ITS 5.5.10). I i

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Specifications and Survaillance: Secondary Chemistry CP-217 s -Revision 7 Page 6 of 24

3.0 REFERENCES

AND DEFINITIONS A. Procedure Development L

1.

Technical Specification: 3/4.4.6.2 and 3/4.7.1.4 (ITS 3.4.13 and 3.7.14) 2.

PWR SECONDARY WATER CHEMISTRY GUIDELINES: REVISION 4, Electric Power Research Institute, EPRI TR 102134,4 Nov.1996 3.

COMBUSTION ENGINEERING CHEMISTRY MANUAL, CENPD-28, Revision 3, September 1982. [

4.

GUIDELINES FOR CHEMISTRY AT NUCLEAR POWER STATIONS, institute of Nuclear Power Operations, INPO 88-021, Rev. 01, September 1991.

5. EN-4-104 Surveillance Testing.

B. Procedure Performance

1. CP-102, Generalinformation Records
2. CP-108, Chemistry Technical Evaluations
3. CP-224, Specifications and Surveillance - Unmonitored Radioactive Effluent. '

4.

CP-236, Specifications and Surveillance - Primary to Secondary Leaks.  !

1

5. CP-900 and 1000 Series for analysis of each specific parameter.

C. Definitions i ACTION LEVEL 1: A value or range of values for a chemical or radiochemical

< parameter which:

a) is inconsistent with Chemistry Section goals, l

b) indicates a potential adverse trend has developed, or c) indicates long-term impacts should be anticipated or expected

2. ACTION LEVEL 2: A value or range of values for a chemical or radiochemical parameter which:

a) exceeds a Technical Specification or other govemment regulation.

l b) indicates an adverse trend has developed, or

c) indicates short-term, adverse impccts should be anticipated or expected.

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Specifications end Survcillanox Sacond:ry Chsmistry CP-217 l .

Rsvision 7 Page 7 of 24 l

l l 3.0. I References and Definitions (Continued) '

3.

ACTION LEVEL 3: A value or range of values for a chemicalor radiochemical parameter at which it is not advisable to continue unit operation due to the potential immediate impact on system integrity.

4.

ALTERNATE AMINE: A strong base amine, other than NH 3 (or N24 H ), used for pH controlin the Secondary Systems.

5. C/DR-M: Continuously measured, daily recording of reading, instrument response verified monthly.
6. C/DR-W: Continuously measured, daily recording of reading, instrument response verified weekly.
7. DMA: Dimethylamine, an attemative amine, more volatile than NH3 and a stronger base. Reported to reduce the deposition of corrosion products on S/G tubes.

8.

ETA Ethanolamine or monoethanolamine (MEA), an attemative amine for pH control.

9. 5-AP: 5-Aminopentanol, an attemative amine for pH control.

10.

FULL-FLOW CONDENSATE POLISHING: The state where most (for example

>50%) of the condensate flow is routed through the condensate polishers.

11.

NO-FLOW CONDENSATE POLISHING: The state where the Condensate Bypass Value is open while the Demineralizer Vessels' A&E Valves are shut.

12.

PARTIAL-FLOW CONDENSATE POLISHING: The state where condensate polishers are in use, but not full-flow. I 13.

TARGET: The value or range of values for a chemistry or radiochemistry parameter which represents a goal or a predetermined waming limit. A TARGET is not a specification.

14. TECHNICAL EVALUATION: A formalized, documented assessment of a chemical or radiochemical excursion.

15.

3/W- Analysis frequency of three times per week, normally Monday, Wednesday and Friday.

4.0 PREREQUISITES A. Responsibilities

1. Technicians are responsible for samp!ing, analysis, documentation and initial notification of the SPC as indicated in this procedure and on the attachments.

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Specific:tions cnd Survrillince: Second:ry Chemistry CP-217

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' Revision 7 i Page 8 of 24 \

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4.0 Prerequisites (Continued) I

2. The SPC is responsible for; a) Ensuring all surveillance frequencies prescribed by this procedure are l met.

b) Ensuring that the GSC and the Shift Manager are notified of Action Level conditions.

c) Ensuring all Technical Evaluations required by this procedure are initiated PER CP-108.

3.

The GSC is responsible for ensuring Technical Evaluations required by this procedure are performed in accordance with CP-108.

B. Specifications and Surveillance 1.

Specifications and surveillance shall be performed per the following Attachments:

ATTACHMENT No.

STEAM GENERATOR CHEMISTRY - POWER OPERAT!ON (MODE 1 1)

STEAM GENERATOR CHEMISTRY - HOT STANDBY (MODES 2, 3 & 4) 2 l

STEAM GENERATOR CHEMISTRY- VET LAYUP (MODES 53 AND 6)

FEEDWATER CHEMISTRY - POWER OPERATION (MODE 1) 4 CONDENSATE CHEMISTRY - POWER OPERATION (MODE 1) 5 STEAM GENERATOR FEED SOURCE - HOT STANDBY 6 (MODES 2,3 AND 4) t MAIN STEAM - POWER OPERATION (MODES 1 AND 2) 7 CONDENSATE STORAGE TANK CHEMISTRY - ALL MODES 8 INDIVIDUAL CONDENSATE DEMINERALIZER EFFLUENT - POWER 9 OPERATION (MODES 1 AND 2)

CONDENSATE DEMINERALIZER REGENERATION SPECIFICATIONS 10 STEAM GENERATOR BLOWDOWN ION EXCHANGER EFFLUENT - 11 POWER OPERATION (MODE 1) l CONDENSATE PRECOAT FILTERS (MODEli 1-5) 12 i

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+_ . . . . . .- - - . _ . . _ . . . . . _ . - _ --

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Specifications end Surv:illmce: SecondIry Chemistry CP-217 Revision 7 l Page 9 of 24 5.0 PRECAUTIONS A.  !

Action Levels may be waived only after PRC or POSRC review & Approval Authority signature is obtained.

[B-345]

B.

New bulk pH additives must be evaluated for Control Room Habitability prior to'use.

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6.0 PERFORMANCE A. Surveillance

1. VERIFY surveillances in Attachments 1 - 12 are performed.

l B. Specifications and Special Corrective Actions 1.

COMPARE surveillance result to the Target, Action Level 1 Action Level 2, and Action Level 3 values listed on the respective attachments, AND PERFORM any special corrective actions required by the attachment.

C. Generic Corrective Actions 1.

VERIFY that all information is documented per applicable Chemistry Procedures.

2. IF Targetis exceeded, THEN a) NOTIFY the SPC.

b) DOCUMENT notification in appropriate record.

c) IMPLEMENT corrective actions as directed by the SPC.

3. IF Action LevelJ is exceeded, THEN:

a) RECORD the sample time as Action Level 1 time ofinitiation in appropriate record.

b) NOTIFY the SPC AND RECORD notification in appropriate record.

j c) NOTIFY the SCTS, the Shift Manager, and the Principal Engineer of i

Secondary Systems, as directed by the SPC - EXCEPT as noted in j

applicable attachment footnote - AND RECORD notification in i appropriate record.

d) RESAMPLE AND ANALYZE the affected parameter as soon as practical, or as directed by SPC, to verify entry into the Action Level 1 condition.

e) INCREASE surveillance frequency as directed by the SPC. i l

l f) RECORD the sample time when out of Action Level 1 AND NOTIFY SPC l and Shift Manager, as directed by SPC.

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_ _ . . _ _ _ _ _ _ _ _ _ . . _ . _ _ _ . _ _ _ _ _ . ._._.m _-

Specifications and Survzillance: S:condary Ch mistry CP-217 I

' Revision 7 ,

Page 10 of 24 r

, 6.0 Performance (Continued) g)  !

IF an on-line instrument trend, or, grab sample result, are below Action Level 1 threshold, THEN a parameter can be declared out of Action Level i 1.

t h)

IF a parameter has not cleared Action Level 1 during a seven day period L

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. following the Action Level 1 time of initiation, THEN PERFORM Action '

Level 2 responses for those parameters with Action Level 2 values.

i)  !

IF the parameter has not cleared Action Level 1 within seven days  !

following the Action Level 1 time ofinitiation, THEN INITIATE a Technical  !

Evaluation PER CP-108.

4. IF an Action Ley.e12 value is exceeded, THEN:

a) RECORD the sample time as Action Level 2 time of initiation in appropriate record.

L b) NOTIFY the SPC and Shift Manager, as directed by the SPC, AND RECORD notification in appropriate record.

c) NOTIFY the GSC, the SCTS and the Principal Engineer of Secondary Systems, as directed by the SPC, AND RECORD notification in i appropriate record. i

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d) AS necessary, ADVISE the Shift Managerof plant corrective actions applying to Action Level 2 for secondary systems.

(1) IF a Technical Specification is exceeded, THEN corrective actions SHALL BE performed per the applicable Technical Specification.

(2) IF a secondary system Action Level 2 condition is caused by other than a Technical Soecification parameter, THEN:

(a) REDUCE power to 5 30% within eight hours of the Action Level 2 time ofinitiation, (b) Power reduction MAY BE terminated WHEN the parameter has cleared Action Level 1 threshold AND the source of ths. impurity ingress is controHei (c) Retum to full-power MAY BE commenced WHEN I parameters clear Action Level 1.

e) RESAMPLE and ANALYZE for the affected parameter as soon as practical to verify entry into the Action Level 2 condition.

l f) INCREASE surveillance frequency as directed by the SPC. I 4

Specifications and Surv:illrnce: S:cond:ry Ch:mistry CP-217 .

  • Revision 7 Page 11 of 24 -

6.0 Performance (Continued) g)

RECORD sample time when out of Action Level 2 AND NOTIFY SPC

. and the Shift Manager, as directed by SPC.

h) INITIATE a Technical Evaluation PER CP-108 within seven days after  ;

Action Level 2 time ofinitiation.

i) IF the parameter has not cleared Action Level 1 within 100 hours0.00116 days <br />0.0278 hours <br />1.653439e-4 weeks <br />3.805e-5 months <br /> following the Action Level 2 time ofinitiation, THEN PERFORM Action Level 3 responses for those parameters with an Action Level 3 value.

5. IF an Action Leyel 3 value is exceeded, THEN:

a) RECORD the sample time as Action Level 3 time of initiation in appropriate record.

b) NOTIFY the SPC and Shift Manager, as directed by the SPC, AND RECORD notification in appropriate record.

c) NOTIFY the GSC, the SCTS and the Principal Engineer of Secondary Systems, as directed by the SPC, AND RECORD notification in appropriate record.

d) AS necessary, ADVISE the Shift Manager of plant corrective actions required by Action Level 3:

(1) INITIATE an orderly shut down within four hours of the initiation of the Action Level 3 condition, AND (2) Restart MAY proceed when chemistry parameters are within startup specifications.

e) RESAMPLE AND ANALYZE for the affected parameter as soon as practical to verify entry into the Action Level 3 condition.

f) INCREASE surveillance frequency as directed by the SPC.

g)

INITIATE a Technical Evaluation PER CP-108.

D. Out-of-Service Monitor.

IF a continuous monitor with a C/DR-W or C/DR-M Frequency is outef-service.

THEN PERFORM grab sample surveillance at least once per four hours in Modes 1, 2,3, or 4 and per SPC directions in Modes 5 & 6.

[B-133]

7.0 POST-PERFORMANCE ACTIVITIES None

Specifications and Survaillince: Secondary Chemistry CP-217 i Revision 7 Page 12 of 24 8.0 BASES PROCEDURE SECTION BASES REFERENCE 6.0.D [B-1331 INPO CY.3-3 (1984) 5.0.A [B-345) NRC 89-04 Attachments 1,2 & 3

[B-492) SOER 82-13-R04 Attachment 4 [B-507) INPO CY.4-2 (1987) 9.0 RECORDS Sample and analysis data generated by this procedure will be recorded on appropriate hardcards logs and CDM. These records will be stored and processed in accordance with CP-102, General information Records.

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ificati0ns and Surveillance: Secondary Chemistry cP417 ,

Revision 7 Page 13 of 24 t ATTACHMENT 1, STEAM GENERATOR CHEMISTRY - POWER OPERATION (MODE 1)

PARAMETER UNITS  !

FREQUENCY TARGET ACTION ACTION LEVEL 1 LEVEL 2 ACTION VALUE BEFORE VALUE BEFORE BASIS pH (IF no flow cond. polishing) LEVEL 3 10% POWER 30% POWER I C/DR-M 2 9.2, s10.2 <9.2 pH (IF fu!!-flow cond. polishing}

C/DR-M 2 8.7 <8.7 pH (IF partiai-flow cc~8 polishing) I C/DR-M 19 0 s10.0 <9_0 Cation Conductivity (IF NH/N,H or DMA cperation) pS/cm C/DR-M  ;

s 0.3 >0.8 >1.0 (1) >4.0 (1)

Cation Conductivity _(IF ETA used) pS/cm 51.0(1) s 0.8 (1)

C/DR-M s 2.0 >2.0 >1.0 (1)

Hideout Retum (sampNg) >4.0 (1) 51.0(1) s 0.8 (1)

(2)

Conductivity (specific) pS/cm C/DR-M Chloride ppb D s1.4 >10 >50 >250 s100 DMA (WHEN used) ppm M s20(3) i

<2 ETA (WHEN used) ppm M <12 5-AP (WHEN used) ppm M <12 Sodium ,

ppb D s0.8  !

Sulfate >5 >50 >250 ppb D 1100 s20(3) s1.4 >10 >50 >250 Gamma Activity 1100 120(3) pCi/g 1/72 hr (4) (4) [B 492] '

1.D.E. (131) pCi/g 1/72 hr (4) >0.1(5)

Cation Conductivity Bataiv:e 20.1(5) s0.1(S) pS/cm M i 30 %

Conductivity (specific) Datance pS/cm M i30% l Acetate (IF Attemate Amine used) ppb M t Formate (IF Altemate Amine used) ppb 19 L Ammonia ppb M ,

Tritium '

pCilg see CP-236 (4) pH Balance M i 0.2 Hydrazine ppb W NOTES:

1.

2. These Cation conductivity Action levels are based on the cation conductivity calculated from Cl & SO4 concentrations.

PERFORM assessment process.for each planned shutdown for run lengths of > 90 days. The HOR evaluation will cbe n cal documented in accord;

3.  ;
4. Clean up efforts should be sufficient to avoid or minimize this Action Level 1 transient during start-up power escalation.  !

5, REFER TO Technical Specification 3/4.4.6.2 (ITS 3.4.13) requirements and CP-236. ,

EEBEORM corrective action PER Technical Specification 3/4.7.1.4 (ITS 3.7.14). l l

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eticuttutis atit! Uuiveillafice. Secutidary Cliemistry

' CP-217 Revision 7 Page 14 of 24 ATTACHMENT 2, STEAM GENERATOR CHEMISTRY - HOT STANDBY (MODES 2, 3, a 4) t PARAMETER UNITS FREQUENCY TARGET START-UP- BASIS HOLDS pH C/DR-W r 0.7 Cation Conductivity pS/cm C/DR-W s 2.0 .

Conductivity (specific) pS/cm C/DR-W Chloride ppb D s 50 Sodium ppb D s 50 Sulfate ppb D s 50 s 100 before [B-492] l 350'F  !

Gamma Activity pCi/gm 1/72 hrC)(Z) (Z) l.D.E. (131) pCi/gm 1/72 hr 127 s 0.191 before criticality  ;

Fluoride ppb D 150 Silica ppb W NOTES:  !

1.

The Steam Generators SHOULD BE samp!cd as soon as practical, BUT no later than four hours after a reactor I 2.

IF steam generators are contaminated, THEN REFER TO CP-236. +

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P_ERFORM corrective action PER Technical Specification 3/4.7.1.4 (ITS 3.7.14). '

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_ _ . _ _ _ _ _ _ _ _ _ . _ _ . _ _ _ _ _ _ _ . _ _ . . _ _ _ _ _ _ _ _ _ _ _ _ _ . _ . _ _ _ _ _ . _ _ _ _ _ _ . . . ._._______..___.._.._____m._._. _ _ _ . _ _ _ . _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ . _ _ _ _ _ _ _ _ _ . _ _ _ _ _ _ . _ _ _ _ . . _ _ _

mcattutis atto surveillance: Secondary Cliemistry . .

CP-217 Revision 7 Page 15 of 24 ATTACHMENT 3, STEAM GENERATOR CHEMISTRY - WET LAYUP (MODES 5 & 6)(1)

PARAMETER UNITS FREQUENCY TARGET ACTION VALUE BEFORE BASIS LEVEL 1 200F Dissolved O2 (fill source) ppb before feeding t'eam 5100 >100 generators pH (2) 2 9.8 <9.8 2 8.5 Chloride ppb (2) s100 >1,000 Sodium s100 ppb (2) s100 >1,000 s100 Sulfate ppb (2) s100 >1,000 Hydrazine (WHEN used) s100 before 350*F [B-492]

ppm (2) 75 - 300 <75 Carbohydrazide (WHEN used) ppm (2) 105-420 <105 Amine (s)in use ppm (2)

Fluoride ppb (2) 1100 TIC / TOC ppb WIF pH <9.8 (3)

Silica ppm As determined by SPC I.D.E.(131) pCilg

<0.1 (4)

NOTES:

1.

maintenance, the steam generators SHOULD BE filled AND hydrazine e or added to 2 5.

2.

The until theSteam Generators SPC datermines SHALL that chemistry is stable BE THENsampled 1/W. 1/W. WHEN Steam Generators recirculation e i is established th 3.

To verifyand Conductivity pHpHdepression is due 2

Calculation software code.to CO absorption, ENTER the TIC value 2 (multiplied by 3.667), as the CO concent 4.

REFERENCE Technical Specification 3.7.1.4 (ITS 3.7.14).

.numutm anu autventance: becondary Chemistry . .

CP-217 Revision 7 Page 16 of 24 ATTACHMEN T 4, FEEDWATER CHEMISTRY - POWER OPERATION (MODE 1) (1)

PARAMETER UNITS FREQUENCY TARGET ACTION BASIS pH (IF full-flow cond. polishing) LEVEL 1 CIDR-W 29.0 pH (IF partial-flow cond. polishing) <8.8 CIDR-W 29.3 pH (IF no-flow cond. polishing) <9.3 Speciric Conductivity C/DR-W 29.7 pS/cm <9.7 CIDR-W Specific Conductivity Trending pS/cm >5.3 (2) < 1.7 D 110 %

Cation Conductivity (IF NH/N 2H,or DMA operation) Cond Bal.

pS/cm CIDR-M Cation Conductivity (;F ETA used) >0.3 (3) pS/cm Dissolved Oxygen CIDR-M ppb >0.9 (3)

Sodium CIDR-W 51.0 ppb >5.0 Chemical Usage Rate CIDR-W s0.2 gal / day >0.2 (3)

Hydrazine D ppb 3/W DMA (WHEN used) ppm 2100 <100 3/W [B-507]

ETA (WHEN used) <2.0 ppm [B-507]

3/W 5-AP (WHEN used) g <5.0 ppm [B-307]

tron 3/W

<2.5 ppb W (intgiated)t'l [B-507]

Copper <3.5 >5.0t31 ppb Ammonia W (integrated)t'l <0.2 ppb >1.013)

Specific Conductivity Balance 3/W 2250 uS/cm 3/W [B-507]

pH Balance 110 %

NOTES: W i 0.3 1.

Assessment Methodology Section 2.Feedwater Chemistry Control program is a requirement of the License R n egrated Plant 2.

3. Only IF: applies when Condensate Polishers are not in full flow use, corresponds to NH3 pH >9 3

)

FW sodium 25.0 ppb OR FW cation conductivity 21.0 US/cm, AND Condensate sodium 2100 ppb OR C a on

4. conductivity 22.0 uS/cm. THEN contact Control Room immediately to implement e>

AOP-10, for respons eak.

5. Sample SHOULD be integrated over entire week Shift Manager notification IS NOT required for Action Level 1 Fe or Cu. and is required after unit is at 80% power for greate l

afications and Surveillance: Secondary Chemistry .

CP-217 RQvision 7 Page 17 of 24 ATTACHMENT 5, CONDENSATE CHEMISTRY - POWER OPERATION (MODE 1) (6)

PARAMETER UNITS FREQUENCYD) TARGET ACTION ACTION BASIS LEVEL 1 LEVEL 2 Cation Conductivity (cond. pumps at TPSS)(2) pS/cm CIDR-M (IF NHgN2H4 or DMA operat;on) s0.30 >0.30 (4)(5)

Cation Conductivity (cond. pumps at TPSS)(2) pS/cm C/DR-M (IF ETA used) so.45 >0.45 (4)(5)

Cation Conductivity (individual HWat TPSS) pS/cm C/D8t-M (IF NH/N,H, or DMA operation) s0.30 >0.30 (5)

Cation Conductivity (individual HW at TPSS) (IF ETA pS/cm C/DR-M used) s0.50 >0.50 (5)

Dissolved Oxygen (at TPSS) ppb C/DR-W s3.5 >10 >30 Sodium (at TPSS)(2) ppb C/DR-W s0.2 >0.2 (4) pH (at TPSS)

W Sodium (at CDSS)(2)(3) ppb C/DR-W s0.2 >0.2 (4)

Specific Conductivity (at CDSS)(3) pS/cm C/DR-M Cation Conductivity (at CDSS)(2)(3)(IF NH/N 2H. or pS/cm C/DR-M DMA operation) so.30 >0.30 (4) (5)

Cation Conductivity (at CDSS) (2) (3) (!F ETA used) pS/cm C/DR-M so.45 >0.45 (4) (5)

NOTES:

1.

IF there are redundant TPSS & CDSS monitors, AND one is out-of-service, THEN the other's analyzer readings AND the 1/4 hr sampling and analysis ARE NOT required. ,

2.

3. This sampling fulfills the requirement of ITS 5.5.10, Secondarv Water Chemistry Program, Step C.

4.

Surveillance is required only when one or more Condensate O-;mineralizers are in service IF: FW sodium 25.0 ppb OR FW cation conductivity 21.0 uS/cm, AND Condensate sodium 2100 ppb OR Condens

5. conductivity 2 2.0 uS/cm. THEN contact Control Room immediately to implement AOP-10, for response to major con IF cation conductivity AL1 is caused by excess organic anions, and not Cl & SO4 concentrations, THEN no Technic required.

6.

IF in-line instrumentation is brought back into service, THEN perform verification check within one shift.

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ilications and Surveillance: Secondary Chemistry . ..

CP-217 -

Revision 7 Page 18 of 24 "

ATTACHMENT 6, STEAM GENERATOR FEED SOURCE (1)- HOT STANDBY (MODES 2,3, & 4) l PARAMETER UNITS FREQUENCY TARGET ACTION VALUE BASIS LEVEL 1 BEFORE 10% POWER

  • pH D 28.8 <8.5 Cation Conductivity pS/cm C/DR-W s0.25 Dissolved Oxygen ppb C/DR-W 5100 >100 <100 Sodium ppb C/DR-W s1 '

Chloride ppb D s1 ,

Sulfate ppb D s1

  • Hydrazine ppb D 2100 <100 >100 AND AND s 23 X DO <3 X DO Suspended Solids ppb Before initia! SG feed $100 <10 NOTES:

1.

Attachment applies 6 MAY when feeding steam apply generators to EITHER feedwater or condensate WHEN used as a steam generator feed in Modes 2, 3, j

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- fications and Surveillance: Secondary Chemistry CP-217 Revision 7 Page 19 of 24 ATTACHMENT 7, MAIN STEAM - POWER OPERATION (MODES 1 & 2)

PA9AMETER UNITS FREQUENCY TARGET BASIS Cation Conductivity (IF NHM2H4or DMA pS/cm cperation) C/DR-M 50.2 Cation Conductivity (IF ETA used) pS/cm C/DR-M 50.8 Specific Conductivity pS/cm CIDR-M 4

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'fications cnd Surveillance: Second;ry Chemistry I CP-217 Revision 7 Page 20 of 24 ATTACHMENT 8, CONDENSATE STORAGE TANKS - ALL MODES (1) '

l PARAMETER UNITS TARGET FREQUENCY (2) ACTION BASIS LEVEL 1 Chloride ppb M sMQC > 1.0 Dissolved Oxygen ppb W 5100 >100 Silica ppb M 510 Sodium ppb M sMQC > 1.0 Sulfate ppb M sMQC > 1.0 Gamma Activity pCilgm see CP-224 Tritium pCilgm see CP-224 NOTES:

1.

WHEN transferring to the CST by other than normal pathway, (DIST or COND. or Vendor DI Water System),

THEN analysis for Na, Cl, SO4, & SiO2 is required. IF parameters exceed Action Level 1 values, THEN SPC approval for transfer is required.

2.

IF either unit is starting-up and shutting down 'illEN increase frequency according to SPC instructions.

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fications and Surveillance: Secondary Chemistry CP-217 Revision 7 Page 21 of 24 t

ATTACHMENT 9, INDIVIDUAL CONDENSATE DEMINERALIZER EFFLUENT (4) - POWER OPERATION (MODES PARAMETER UNITS FREQUENCY TARGET ACTION BASIS Conductivity (specific) LEVEL 1 pS/cm CIDR-M (5) 50.1 >0.1 Cation Conductivity pS/cm CIDR-M (5) so.1 >0.1 Ammonia ppb D, IF conductivity sMQC >MQC 2 0.1 pS/cm Amine (s)in use ppm D, IF conductivity sMQC >MQC 2 0.1 pS/cm AND WHEN used Sodium ppb C/DR-W 0)(Z)(U (M s0.2 >0.2 Chloride ppb D, IF cation cond. SMQC >MQC 2 0.1 pS/cm Sulfate ppb D, IF cation cond. sMQC >MQC 2 0.1 pS/cm NOTES:

1.

Analyzer SHOULD be aligned to common erfluent, EXCEPT for the first 30 minutes of service for a new bed OR per SPC 2.

IF analyzer placing new demineralizer is out-of-service bed in service. and can not be used to analyze new bed, THEN SAMPLE steam generators for sodium within o 3.

IF analyzer is out-of-service, THEN the Feedwater or the Condensate Na analyzer reading may be used for syste by the SPC, and once per four hour sampling is not required. ,

4.

Surveillances apply only to in-service Condensate Demineralizers. Stand-by Condensate Demineralizers SHOULD be rinsed do periodica; y and maintained in a serviceable condition..

5.

IF in-line instrumentation is brought back into service THEN perform verification check within one shift. .

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a lic:tionis and Surveillance: Secondary Chemistry .

CP-217 Revision 7 Page 22 of 24 ATTACHMENT 10, CONDENSATE DEMINERALIZER REGENERATION SPECIFICATIONS t PARAMETER UNITS FREQUENCY VALUE PRIOR BASIS TO TRANSFER Conductivity (specific) pS/cm Continuously, while rinsing after 55.00) in Cation / Anion Tank Rinse regeneration Conductivity (specific) . pS/cm in Holding Tank Effluent Continuously, while rinsing 50.10WI i

NOTES:

1.

4 Value before transfer to Holding Tank for continuation of normal regeneration.

r 2.

Value before transfer to Service Vessel.

3.

IF rinse takes 2 8 hours9.259259e-5 days <br />0.00222 hours <br />1.322751e-5 weeks <br />3.044e-6 months <br />, THEN REPEAT regeneration as directed by SPC.

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Revision 7 Page 23 of 24 ATTACHMENT 11, STEAM GENERATOR BLOWDOWN ION EXCHANGER EFFLUENT- POWER OPERATION (MODE 1)

PARAMETER UNITS FREQUENCY TARGET ' BASIS Sodium ppb as directed by SPC s MQC Chloride ppb as directed by SPC sMQC Sulfate ppb as directed by SPC s MOC Fluoride ppb as directed by SPC sMQC

.ny an:eensuy *

Revision 7 '-

Pege 24 of 24 ATTACHMENT 12. CONDENSATE PRECOAT FILTERS (1) (MODES 1-5)

PARAMETER UNITS FREQUENCY TARGET BASIS Effluent Corrosion Product ppb 1/6 months .

(Fe) <1 (integrated)(2)

NOTES:

1. Surveillance is only required for in-service Precoat Filters.

2.

Sample should be integrated over 5-7 day interval to ensure sample exceeds . low detection limits.

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