ML20127K071

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Ack Receipt of Insp Repts 50-440/85-08 & 50-441/85-06 on 850205-08 & Responds to Open Item 3 Re Confirmatory Measurements.Info Provided Re Gamma isotopic,Sr-89 & Sr-90 & Tritium Measurements.Open Item 3 Considered Closed
ML20127K071
Person / Time
Site: Perry  FirstEnergy icon.png
Issue date: 06/18/1985
From: Edelman M
CLEVELAND ELECTRIC ILLUMINATING CO.
To: Schumacher M
NRC OFFICE OF INSPECTION & ENFORCEMENT (IE REGION III)
References
PY-CEI-OIE-0065, PY-CEI-OIE-65, NUDOCS 8506270249
Download: ML20127K071 (25)
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P O. BOX 5000 - CLEVELAND. oHlo 44101 - TELEPHONE (216) 622-9800 - ILLUMINATING BLDG. - 55 PUBLIC SOUARE Serving The Best Location in the Nation MURRAY R. EDELMAN vicE PRESIDENT June 18, 1985 NUCLE A R PY-CEI/01E-0065 L Mr. Martin C. Schumacher, Chief Independent Measurements and Environmental Protection Section U. S. Nuclear Regulatory Commission Region III 799 Roosevelt Road Glen Ellyn, IL. 60137 Perry Nuclear Power Plant Docket Nos. 50-440; 50-441 Close out of NRC Open Item 50-440/85008-03; 441/85006-03

Dear Mr. Schumacher,

This letter is to acknowledge receipt of Inspection Report 50-440/85008; 50-441/85006 attached to your letter of February 28, 1985. This report identifies areas examined by Dr. M. J. Oestmann during the inspection conducted on February 5, 1985 through February 8, 1985 at the Perry Nuclear Power Plant.

Attached to this letter is information provided to close Open Item 50-440/85008-03; 441/85006-03 on Confirmatory Measure-ments, as requested in the inspection report.

If there are any questions, please feel free to call.

Very truly o es, Murray R. Edel an Vice President Nuclear Group g MRE:nje i l

Attachments ec: J. Grobe Dr. M. J. Oestmann U.S. Nuclear Regulatory Commission Document Control Desk Washington, D.C. 20555 8506270249 850618 JUN 201985 PDR ADOCK 05000440 G PDR

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1 OM12A: CHI-39 Page : 4 - IAST Rev. : 0 Attachment 1 Form: OM12A: CHI-39-1 Non-Program Sample Analysis and Activities Data Sheet Log Number b I~/f40 Date I! U REQUEST DATA SECTION:

Analysis / Activity e i r m Ab r % p as o r e me M *. aks t

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Date Results Needed 6/> I 9 6 ecs ., , res n m-~

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  • Crirl RESULTS SECTION: sm jsc%p. g pl , , , .g ,

EU Sc. bmL,a c .,a., peM..A skeo s M[M@it-RO05Gt100 @ Sr . 9 0.4/,,t .2 . 9 E - 5 I 2.9 E - 6

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Spe c4,.~ F, Se, e s 9 s pK 4 omi2 c cv2-2 3 h,odo. - O't,9 o (Sr -9 9, io) O m 2 A : CRI 9 5 Q SA'S : 9'h'Q', $$,[',',I,,',,'., ,' ,o'8/,*,~,( ,,

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3 Attachments YES NO Pages + Arr .

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CHIA 4/S/amh .

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INSTRUCTIONS FOR ANALYSES OF TEST SAMPLES Radiological and Environmental Sciences Laboratory 550 Second Street Idaho Falls, Idaho 83401

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Count all samples for 1 hour1.157407e-5 days <br />2.777778e-4 hours <br />1.653439e-6 weeks <br />3.805e-7 months <br /> or unt.11 20,000 counts have been recorded.

Calculate the resuits and uncertainties in pCi/mL for liquid samples and PC1/ total sample for particulate filters.

/// ,

Report of Office theInspection results to the andU.Enforcement, S. Nuclear Regulatgry Commispion, Attn: /f/4Wt/ EIA16Reg @4

[ ion-hM ,1./1 s

/

Perform the analyses checked below.

I. Liquid Sample

.j 1. Determine the gamma eritters in /O mL of sample.

2. Determine the strontium-89 and strontium-90 content by analyzing

//) mL of sample.

3. Determinethetritiumcontentbygistilling '2-O mL and l analyzing a ,/h mL portion -f8 the distillate.
4. Correct the results for decay to / // k( .

l II. Liquid Sample f,

1. Determine the gross beta activity on mL of the sample.

Report the result as of the date of counting.

III. Particulate Filter

1. Quantitatively recover the contents of the bottle containing the filter and determine the strontium-89 and strontium-90 activities in the entire sample.
2. Correct the results for decay to .

IV. Other l- .

L A

.h sT US DOE OFF SITE RADIOACTIVE MATERIAL SHIPMENT RECORD f h Styoment From I/tl '

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[ *tf/ Log No to r 54ao na , , - . , ,

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,f /g d ///.. Y,4/2,- F f yr/ 5'8 '^C"**'"-

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Charge No.  ! Collect O Prepai W WN .b6N bbd.

Fe#A*' , d h .'O Carrier (s) ~ f t ii 'MI /

v4t/) A / Soie use O INEL Long HaulO Other Y MM ' Md  % isr46 , .

A Consignee is Authorized to Receive Shipment Contignee Nobtied Y Dat _

Materiaits)-(Prnpar DOT Shipping Nast.e) .

A l-I @ t d N//

7F<". [ N M [!f Chemical Fo,pp Weight "V #O ' Vol. = I N " I b' s

DOT identification No. - A[/N Container Used (deskbe): C(I IfIb b'# b W

Physical Form: Solid O LiquiVVaas O Type of shipment Packaging:

$ id -

u) ~ Limited Quantity in ustnalO g g s) \ Rad. Article [] , POT Spec. >,

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6 g',) # N Ag L] Ap L1

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Type A b BO Bcu) O

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i Highway Route Size

'/ / d'h , Controlled O weight

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Tot A / Y / r*- Empty O *"*P"'"d*"~-

Seal No.(s) /  %

FISSILE MATERIALS: No[A'phcable p I Fissile Shipment O Fissile Exempt O qO Fissile Materials U - gms Pu gms Other Fissile Exempt O Class i0 Crass <>O Trans inoe-Class ill O Coni,ois.

(No more than packages may be loaded on any v hicle or storage location)

ACCOUNTABLE NUCLEAR MATERIALS: Not Apphcable Applicable O DOEINRC F 741 No Remarks b

> tee downs Adequate D ' Remarks. ' ' " 7 * 'j,, LABELS Radiation:(surface) / i ~ I U mrem /hr (3 feet) mrem /hr "' '

Contamination- (Averaged over ny 300 cm2 Package Surface) "*

Beta Gamma < 2 'disimmt100 cm2 nuo ni O 5 Alpha / /O - '

destmin!t00 cm2 # 9 f Addihonal Surveys' Vehicle O Dri e,O oinesf 39 9> >Y wy O Remarks:

n -, i. , _i e , ,

% Loader; hN Th(d M M f8 I Date .1/ I C VEHICLE PLACARD (s)  %

Seat Apphcator; Date /' '

Safety insp -

_ Date None Requirert Radioactive 0 f 1

,, a eyor (Package (s)) ' ]Ni M *- 5 .,

h iii,

{ (Driver and Vehicle) Date

)? (Fissile and/or Accountabte Nuclear Material only)

Safeguards Rep ; ,

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  • Date Secunty Rep Bl Date This is to cert that the above-named inaterials are properly ctassified. described. packaged, marked, and labeled, and tr> proper condition lo osporta ac n the applicable regu 4 " of the Department of Tra spor tion and DOE D ,9m Originator: rea Supervisor /#d Y' I Y Dattff-7 [/T Datt.

E Carner Rep a/  !/ Date E Trafhe Agent  !! Oiganstatio.) Date Released -

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(DinFCTIONS ON HEVFDSE elDEI i

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  • GAMMA SPECTRUM ANALYS I S CANBERRA SPECTRAN-F V2.07 SOFTWARE 25-MAY-8507:34105

[ ANALYS I S PARAMETERS MCA UNIT NUMBER: 1 / ADC UNIT NUMBER: 1.0

( DETECTOR NUMBER: 1 / GEOMETRY NUMBER: 10 SPECTRUM SIZE: 4096 CHANNELS ORDER OF SMOOTHING FUNCTION: 5 r NUMBER OF BACKGROUND CHANNELS: 3 ON EACH SIDE OF PEAK PEAK CONFIDENCE FACTOR: 95.0%

IDENTIFICATION ENERGY WINDOW: +- 2.00 KEV ERROR UUOTATION: 2.00 SIGMA UNCERTAINTY MULTIPLET ANALYSIS NOT PERFORMED REGULAR OUTPUT Sf'EC1RAL DATA READ DIRECTLY FROM MULTICHANNEL ANALYZER ANO:

/

ANALYZED BY: GAD SAMPLE DESCRIPTION: CONFIRMATORY MEASURE

. GEOMETRY DESCRIPTION: 14.4 ml Liouid Off-Gas Vial SAMPLE SIZE 1.0000E+01 ml / CONVERSION FACTOR: 1.0000E+00 STANDARD SIZE: 1.4400E+01 ml ANALYSIS LIBRARY FILE: ANLOO9 COLLECT STARTED ON 7-MAY-85 AT 17:40:00 COLLECT LIVE TIME: 43200. SECONDS REAL TIME: 43268. SECONDS

( DEAD TIME: 0.16 %

DECAYED TO 116. DAYS, 5.6667 HOURS BEFORE THE START OF COLLECT i

ENERGY CALIBRATION PERFORMED 11-MAR-85 EFFICIENCY CALIBRATION PERFORMED 24-MAY-85

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,, 25-MAY-8507:34805 PEAK ANALYSI S PK CENTROID ENERGY FWHM BACKGND NET AREA ERROR NUCLIDES CHANNEL KEV KEV COUNTS COUNTS  %

1 1321.45 661.76 16 75. 654. 9.0 CS-137 2 2344.75 1173.24 2.0 42. 436. 11.0 CO-60,CO-56 3 2663.57 1332.54 2.0 25. 431. 10.6 CD-60 ERROR QUOTATION AT 2.00 SIGMA PEAK CONFIDENCE LEVEL AT 95.0%

)

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23-MAY-8507:34703 SAMPLE: CONFIRMATORY MEASURE DATA COLLECTED ON 7-MAY-85 AT 17:40:00 DECAYED TO 116. DAYS, 5.6667 HOURS BEFORE THE START OF COLLECT.

RADIONUCLIDE ANALYSIS REPORT NUCLIDE ACTIVITY CONCENTRATION IN uCi/ml DECAY MEASURED ERROR CORRECTED ERROR CO-60 1.15E-05 +-1.27E-06 1.20E-05 +-1.32E-06 CS-137 1.20E-05 +-1.08E-06 1.21E-05 +-1.09E-06 g ___________________ ___________________

TOTAL 2.35E-05 t-1.67E-06 2.41E-05 +-1.71E-06 ESAR = 1.61 MEV/ DISINTEGRATION MAXIMUM PERMISSABLE ACTIVITY = 6.20Ef01 UC/ml TOTAL MEASURED ACTIVITY = 2.41E-05 (+-1.71E-06) UC/ml

% TECH. SPEC. = 0.00 (+-0.00)

ERROR QUOTATION AT 2.00 SIGMA Io e

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_r~, _ _ - - . _ - - , _,.._,.m.. . - _ _ _ - _ , ,e,., -,,-.---y,_,,

,,m-,,.y-.,_.,,.y,. -

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  • GAMMA SPECTRUM ANALYSI S
  • CANBERRA SPECTRAN-F V2.07 SOFTWARE 25-MAY-8507:46t42 ANALYS IS PARAMETERS MCA UNIT NUMBER: 2 / ADC UNIT NUMBER: 1.0 DETECTOR HUMBERt 1 / GEOMETRY NUMBER 10 SPECTRUM SIZE! 4096 CHANNELS ORDER OF SMOOTHING FUNCTION! 5 NUMBER OF BACKGROUND CHANNELS! 3 ON EACH SIDE OF PEAK PEAK CONFIDENCE FACTORt 95.0%

IDENTIFICATION ENERGY WINDOW! +- 2.00 KEV LRROR QUO 1ATIONt.2.00 SIGMA UNCERTAINTY MUL11PLET ANALYSIS NOT PERFORMED F.LGULAR UUTPUT SPECIRAL DATA READ DIRECTLY FROM MULTICHANNEL ANALYZER ANil

( ANALYZED BY! OAD SAMPLE DESCRIPTION! CONFIRMATORY MEASURE i - GEOMETRY DESCRIPTION! 14.4 ml Liouid Off-Gas Vial SAMPLE SIZEt 1.0000E+01 ml / CONVERSION FACTOR! 1.0000E+00 STANDARD SIZE! 1.4400E+01 ml ANALYSIS LIBRARY FILE! ANLOO9 COLLECT S1ARTED ON 0-MAY-85 AT 17830 00 COLLECT LIVE TIMEt 43200. SECONDS REAL TIME! 43288. SECONDS DEAD TIMEt 0.20 %

DECAYED TO 117. DAYS, 5.5000 HOURS BEFORE THE START OF COLLECT ENERGY CALIBRATION PERFORMED 11-MAR-85 EFFICIENCY CALIBRATION PERFORMED 24-MAY-85 l

. 25-MAY-8307746842 PEAK ANALYSIS PK CENTROID- ENERGY FWHM BACKGND NET AREA ERROR NUCLIDES CHANNEL KEV KEV COUNTS COUNTS  %

1 182.78 92.71 1.4 396. 233. 29.2 2 1321.55 661.74 1.8 83. 825. 7.9 CS-137 3 2346.18 1173.42 2.2 33. 492. 10.0 CO-60,CD-56 4 2664.96 1332.55 2.0 15. 452. 9.9 CD-60 .

ERROR QUOTATION AT 2.00 SIGMA PEAK CONFIDENCE LEVEL AT 95.0%

to t

i

. _ _ , _ _ . _ - _ _ . - - . _ . _- . . _ , - ~ - - - . - , - - - - _ . - _ . .

+.

.'25-MAY-8507:46742 l .

SAMPLE: CONFIRMATORY MEASURE DATA COLLECTED ON B-MAY-85 AT 17:30:00 DECAYED TO 117. DAYSr 5.5000 HOURS BEFORE THE START OF COLLECT.

7 RADIONUCL IDE ANALYSIS REPORT j NUCLIDE ACTIVITY CONCENTRATION IN uCi/ml DECAY MEASURED ERROR CORRECTED ERROR

(

CO-60 1.07E-05 +-1.07E-06 1.12E-05 +-1.11E-06 CS-137 1.25E-05 +-9.84E-07 1.26E-05 +-9.91E-07

( ___________________ ___________________

TOTAL 2.32E-05 +-1.45E-06 2.37E-05 +-1.49E-06 1

EBAR = 1.56 MEV/DISINTEORATION MAXIMUM PERMISSABLE ACTIVITY = 6.40E+01 UC/mi TOTAL MEASURED ACTIVITY = 2.37E-05 (+-1.49E-06) UC/mi

% TECH. SPEC. = 0.00 (+-0.00)

/ ERROR QUOTATION AT 2.00 SIGMA 7

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  • GAMMA SPECTRUM ANALYSIS
  • CANBERRA SPECTRAN-F V2.07 SOFTWARE 25-MAY-8507:51:39 ANALYSIS PARAHETERS MCA UNIT NUMBER: 4 / ADC UNIT NUMBER: 1.0

( DETECTOR NUMBER: 1 / GEOMETRY NUMBER: 10 SPECTRUM SIZE! 4096 CHANNELS ORDER OF SMOOTHING FUNCTION: 5 NUMBER OF BACKGROUND CHANNELS: 3 ON EACH SIDE OF PEAK PEAK CONFIDENCE FACTOR: 95.0%

IDENTIFICATION ENERGY WINDOW: +- 2.00 KEV ERROR QUOTA 110N:.2.00 SIGMA UNCERTAINTY MULTIPLET ANALYSIS NOT PERFORMED REGULAR OUTPUT SPECTRAL DATA READ DIRECTLY FROM MULTICHANNEL ANALYZER AN3 ANALYZED BY: GAD SAMPLE DESCRIPTION: CONFIRMATORY MEASURE GEOMETRY DESCRIPTION: 14.4 ml Liould Off-Gas Vial SAMPLE SIZE! 1.0000E+01 ml / CONVERSION FACTOR: 1.0000E+00 STANDARD SIZE: 1.4400E+01 ml ANALYSIS LIBRARY FILE! ANLOO9 COLLECT STARTED ON 15-MAY-85 AT 14:14:00 COLLECT LIVE TIME: 43200. SECONDS REAL TIME: 43397. SECONDS DEAD TIME: 0.45 %

DEC AYEli TO 124. DAYS, 2.2333 HOURS BEFORE THE START OF COLLECT ENERGY CALIBRATION PERFORMED 1-APR-85 EFFICIENCY CALIBRATION PERFORMED 24-MAY-85

(

., . 23-MAY-8507851:37

~

l PEAK ANALYSI S PK CENTROID ENERGY FWHM BACKGND NET AREA ERROR NUCLIDES CHANNEL KEV KEV COUNTS COUNTS  %

1 471 13 238.39 1.1 335. 224. 29.1 PB-212 2 1318.76 661.39 1.6 77. 661. 9.0 CS-137 3 2343.37 1172.75 1.9 35. 476. 10.2 CO-60 4 2662.46 1332.01 2.2 20. 399. 10.8 CO-60 ERROR QUOTATION AT 2.00 SIGMA

( PEAK CONFIDENCE LEVEL AT 95.0%

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25-MAY-8507851839 SAMPLE: CONFIRMATORY MEASURE DATA COLLECTED ON 15-MAY-85 AT 14:14:00 '

DECAYED TO 124. DAYS, 2.2333 HOURS BEFORE THE START OF COLLECT.

RADIONUCLIDE ANALYSIS REPORT NUCLIDE ACTIVITY CONCENTRATION IN uCi/ml I

DECAY MEASURED ERROR CORRECTED ERROR

! CO-60 1.18E-05 +-1.20E-06 1.24E-05 +-1.26E-06 CS-137 1 15E-05 +-1.03E-06 1.16E-05 +-1.04E-06

( ___________________ ___________________

l TOTAL 2.34E-05 +-1.59E-06 2.40E-05 +-1.63E-06 4

EBAR = 1 65 MEV/ DISINTEGRATION MAXIMUM PERMISSABLE ACTIVITY = 6.07E+01 UC/ml i TOTAL MEASURED ACTIVITY = 2.40E-05 (+-1.63E-06) UC/ml i

% TECH. SPEC. = 0.00 (+-0.00) j ERROI. QUOTATION AT 2.00 SIGNA 1

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OM12A : CHI-45 Page : 15 Rev. : 0 Attachment 2 Fo rm: OM12A: CHI-45-la Sheets a-c Sr-89, 90 Data Sheet Sample id en t if ica t ion b d., a 6 h,4t re 3

Sample date, time N/Jw/ D C Q iloc2 t 0

Sample volune used_for analysis (normally 200ml) lO ml A Sr-89,90 standard carrier per 2m1, 93.4 mg B (standardized value)

Sr-89,90 separation date, time Olmteles at iits t 3

Wha tma n 54 2 f 11 t e r pa pe r w igh t , (used for Sr) 40 1 mg C Sr-89,90 ppt we igh t '14.1 mg D Final Sr-89,90 ppt w igh t = D-C 39. t mg E Sr-89,90CYF=f I.16 F cpm /

Sr-89 efficiency using E, see FIGURE 2 h5 dpm C cpm /

Efficiency factor G x 0.01 0,9 s apm a cpm /

Sr-90 ef ficiency using E, see FIGllRE 3 79.'l dpm I cpm /

Ef ficiency factor I x ODI O.295 dpm J Sr-89,90 count date, time krAV)BsGriew t 2

Sr-89,90 gross counts 4 T 2. 67 counts K Sr-89.90 duration of count 60 minutes L Sr-89,90 gross cpm = {K SS 4. s epm M Background at Sr count time 2l cpm N Sr-89,90 net cpm = M-N 633.'I cpm 0

/ 21 ( 2. d g -l

, _g Sr-89 decay constant +.-M B--se-lO 4-hou r St-89

OMllA : CHI-45 Page

  • 16 Rev. : U Attachment 2 (Cont.)

Fo rm: OM12A : CH I-4 5-l b Sr-89, 90 Data Sheet (Cont.)

Y '> u s t..ndard carr ter per 2m1 2b 3 mg P

(.,tandardized value)

Y-W deparat idir da te. time 2 #lAf[8 Q OQS1 t 3

Wha tt.a n $4 2 f ilte r 'pa pe r w igh t (used for yttrium) 39. T mg Q Y-90 ppt weight f/, L mg R

//, 7 mg S Final Y-90 pp{ wight = R-Q Y-90CYF=h 2.26 T Y-90 efficiency using S, see FIGURE 4 49 '

U Ef ficiency f actor U x 0.01 0.%% v Y-90 count date, time J 'ifAW[95Cdi l 57 t 4

Y-90 gross counts (e b % o counts W Y-90 duration of count (30 minutes x

' cpm Y Y-90grosscpm=f 11 0 "1 '

Background at Y count time 21 cpm Z Y-90 net cpm = Y-7 ,,

98.7 A A

Y-90 decay constant

/,80 f v a:~~

  • ^ " '^

2 "ue-l Y-90

( ,

Decay time Sr-90 (t4 -t3) in minutes JNO mins B B

Decay correction for Sr-90 =' , Y-90(Bg) I.049 C C

2t%1 mins D Decay time Sr-90 (t3 -t g) in minutes D Decay correction for Sr-90 = g,,- Y-90(DD } E Decay time Sr-89 (t 2 ~t " ' F 0

Decay c.orrection for Sr-89 = Sr-89(FF) L4 , et V G e G

(

Conversion from dpm to uci '

2.22 x'10 H H

=

OM12A: CHI-45 Page . 17 Rev. . O Attachment 2 (Cont.)

Fo rm: OM12A: CHI-45-Ic Sr-89, 90 Data Sheet (Cont.)

Calculations:

Sr-90 uci/mi 0 t 0 "

^A C VxE E ^

  • bl

= [ BB.T ]x[ t.uw ]x[ t LC ]xl 1.14, j

[ o.% lx[ o.in ]xl l* lxl2 2 tit ]

= 2.W L -5 =1 1

5 Sr-89 uci/mi 0 t 0 = 0 x F -1 fi x

M f x c

G AxHxg [1 H g

=

( Sh <)x( l.lb ) _ _

( 2.7 st 5) x ( 0.2s 't) x (9 94 )

( to )x(e ws )x(z.tsac) ( o.ws ) _

= 3. 2 T E -M Sr-90, Y- 1/mi 0 t 0= I*

= )x2

=

'A . ,.

0 i l

' i

  • OM12A : CHI-45  :'

.i 9 Page : 15

<t Rev. : 0 1

Attachment 2 -

' Forn: OM12A: CHI-45-la

[ Sheets a-c 4

Sr-89, 90 Data Sheet Sample identification bor < m o de ,- s ccq . a j '

12 cp t Sample date, time !I. TAN 9s' 0 Sample volume used for analysis' 10 el A j (norma:ly' 200::)

Sr-89,90 s tanda rd ca rrier per 2-/1, c/ 9 q mg B j

(standardized value) -

Sr-89,90 separation date, time < S mJv S3- ,, f r t g

Wa tman 54 2 f ilte r pa pe r we igh t , (usedfoYsr) ,

, 3 <7 t, mg C

(

') f , 79.9 mg D Sr-89,90_ ppt weight ,

., , +'J.. sa' Final Sr-89,90 ppt we igh t = D-C 3 9. 1 mg E j- Sr-89,90CYF=f _

/. 2 (,.

cpe/

F Sr-89 efficiency using E, see FIGURE 2 4,/ g- dpm G cpm /

Ef ficiency - f actor G x 0.01 . .W- 'dpm H 4

.I cpm /

I Sr-90 ef ficiency using E, see FIGURE 3 'A 9. 3 dpm I cpm /

Ef ficiency factor I x 0.01 ,

,293 dpm J

} s Sr-89,90 count date, time cl m A Y s r 12 t'I t 2

Sr-89,90 gross counts -

T2729 counts K

,e Sr-89,90 duration of count , l. gr .< minutes L r  ;

~

K 5'/6 ^ cpm M Sr-89,90 gross cpm = p ,

t.

fl/

'lij'l pm N

-Background at Sr count time

.i. f 5'16 cpm 0 Sr-89,90 net, cpm = M-N A i ,

,, g ,'5.710 x-10 4 hour-1 Sr-89 Sr-89decap'tonstant- '

l, 3^1 F 2 dn.j~ '

Q 2

OMilA: CHI-45 Page . 16 Rev. : O Attachment 2 (Cont. )

Form: OM12A : CHI-45-lb Sr-89, 90 Data Sheet (Cont.)

Y-90 s tanda rd carrier per 2ml 263 mg P

(. standardized value) 2 7 m,9 P ts s' 09 >~ 7 1 3

.Y-90 . separation date, time 39 f ec Q yna te.an 54 2 f l ite r pa per we igh t (used for yttrium) 4/F,9 mg R Y-90 ppt weight

9. 4 mg S Final Y-90 ppt we igh t = R-Q Y-90 CYF = E 2. 9 T S

4/ C/ U Y-90 ef ficiency using S, see FIGURE 4 c/ t/ v Efficiency factor U x 0.01 t

Y-90 count date, time 23m/7 rF r 11 c i 4 5 yj g counts W Y-90 gross counts-6o minutes X Y-90. duration of count W 7 (. cpm Y I ~Y-90 gross eps = 7 17 cpm 2 Background at Y count time Y-90 net cpm = Y-Z 79 A 680E-Z~*' ' -l g 4 1-.002 a 10 ' Luut Y-90 Y-90 decay constant 2 '-/ O mins B Decay time Sr-90 (t -t 3) in minutes B

. Decay correction for Sr-90 = , Y-90(B B C 2/7.39 mins D Decay time Sr-90 (t3 -t ) in minutes

- Y-90(DD} b Decay correction for.Sr-90 = E F

Decay. time Sr-89 (t - t 0 n m a es // 7 F Decay correction for Sr-89 = Sr-89(Fy) 4 97 Gg 6 H 2.22 x 10 H Conversion from dpm to uci m.- c..- .._._ - ,,n-.__. - . . , _ .

1 OMi lA : CHI-45 Page . 17 Rev. : 0 Attachment 2 (Cont.)

Form: OM12A : CHI-45-Ic Sr-89, 90 Data Sheet (Cont.)

Calculations:

Sr-90 uci/ml O t 0 = AA xC CxTxF VxE Ex AxH

= l 79 lxl I.o# lx{ 2 c ] x [ f. 2 0 }

[ w9 ]x{ Cie jx[ (0 J x [ 2.2 2('}

=

= .? O 3 E - C 1 II C Sr-89 uci/ml O t 0 = 0 x F -

I x I '/

+

x G AxHxH H [ H d ,

= (526 )x( / ; c ) (.f e!c-O x ( . 2 9 3 )

i x ( 4 'i ? )

( wr )

( /> )x( .~s' )x(;.;2q 3 = 232F 'I Sr:90, Y-90 uc1/ml Q t 0= *

=

( )x2

!y .

j e%4d

~

PAGE: 1 USER: 1 ID:H-3 BKGD PRESET TIME: 10.00 WED 08 MAY 1985 17:37 l SAMPLE REPEAT: 2 CYCLE REPEAT: 1 SCR:N RS232:N Hr: 2 AOC:N OCF:N RCM:N 2 PHASE MONITOR:N CHANNEL I-LL: 0 UL: 1000 2 SIGMA: 2.00 DVG SUB: 0.00 BKG 2SIG: 0.00 LSR: 0 DATA CALC: CPM, UNKNOWN REPLICATES: 1 NORM FACIOR:0 1.00000 I HALF LIFE (DAYS):N SAM POS CH CPM 2SIG% TIME EL TIME AVG Hs ERR 1 **- 1 1 36.20 10.51 10.00 11.05 117.0 Hs: 116, if8 1 --- 1 1 30.90 11.38 10.00 21.97 !16.0 He: 117, 115 SAM AVG CPM (RilG) 1: 33.55< 7.90)

PAGE: !

USER: 5 ID:H-3 CONF MEA PRESET TIME: 60.00 WED 08 MAY 1985 18:07 SAMPLE REPEAT: 2 CYCLE REPEAT: 1 SCR:N RS232: N Hs: 2 AOC:N OCF:N RCM:N 2 PHASE MONITOR:H 0.00 LSR:

CHANNEL 1-LL: 0 UL:1000 2 SIGMA: 2.00 PKG SUD: 33.55 BKG 2SIG:

O SINGLE LABEL DPM, SET UP DN THU 28 OCT 1982 09:04 UNKNOWN ID:H-3 OUENCH CURVE UNKNOWN REPLICATES: 1 UNKNOWN NORM FACTOR:0 1.00000 UNKNOWN UNITS:DPM OUENCH MODE:H CALCULATE COEFF:N HALF LIFE (DAYS): 4503.530 1 C:-0.0000068 D:-0.0000000333 OUENCH COEFF.A: 4.140551 B:-0.0037587 l

STANDARD ID:SCN-231 0UENCH LIMITS LOW:7.000 HIGH:264.0 l TIME EL TIME AVG Hs ERR l SAM POS CH CPM 2SIG%

1 *-- 1 1 203646.45 1.98 0.05 0.50 61.5 He: 61. 62

%EFF: 48.23 IS01 DPH :422262.9 1 --- 1 1 201286.45 1.41 0.10 0.96 62.0 He: 63, 61

%EFF:48.11 IS01 DPM :418412.5

%RNG: 0.5 SAM AVG IS01 DPM :420337.7 2 --- 2 1 50.53 4.69 60.00 63.47 97.5 Hs: 99, 96

%EFF: 39.59 IS0! DPM :127.6434 2 --- 2 1 49.07 4.78 60.00 125.66 97.5 Hs: 98.- 97

%EFF: 39.59 IS01 DPM :123.9400 l' XRNG: 1.5 SAM AVG IS01 DPM :125.7917 3 ---~3 1 47.98 4.86 60.00 188.11 99.0 Hs: 97. 101

%EFr: 19.23 ISO' DPM :122.3104 3 --- 3 1 49.13 4.78 60.00 250.24 99.0 Hs: 99, 99

%EFF: 39.23 IS01 DPM :125.2424

%RNG:- 1.2 SAM AVG IS01 DPM :123.7764 4 **- 4 1 43.80 5.18 60.00 312.60 98.5 He: 98, 99

%EFF: 39.35 IS01 DPM :111.3098  ;

4 **- 4 1 44.72 5.11 60.00 374.66 98.0 H s: 98, 98

%EFF:39.47 IS01 DPM :113.2961

%RNG: 0.9 SAM AVG IS01 DPM :112.3030 5 --- 5 1 46.05 5.00 60.00 437.01 97.0 Hs: 97, 97

%EFF:39.71 IS01 DPM :115.9736 5 ~~- 5 1 46.80 4.95 60.00 499.07 97.5 Hs: 97, 98

%EFF:39.59 IS01 DPM :118.2189

%RNG: 1.0 SAM AVG IS01 DPM :117.0963

l l

I -- '

.,,.,..o;

-n-.--- . -n = w- m .tr>v ". : : n -

s , ,; , s;** . *

  • 4' z _ *
-f' r.?. j ' '

.z e.

  • 3{e.- , ., , ,

~

  • .,: .4 ..,,?..>.w..

s f%m.C2 92. M ~ Q '.l ' .>; *

c:&M __9. : r.

4.u.:z -%i-OM12A: CHI-47

( )

Page : 5 - LAST Rev. : 0

' Attachment 1 Form: OM12A: CHI-47-1 Tritium Data Sheet Sample Identification bd *<aM hio Au 44Uws?. h -p s Sample date and time n-Iw-e.vo % cc t y

Gaseous sampling initial flow rate tJ A cc/ min A Gaseous sampling final flow rate cc/ min B Gaseous sampling stop date and time t 2

Total gaseous sampling period (t 2 -t --

C AveragegaseoussampleflowrateA+b) cc/ min D 2

Gaseous sample volume (C X D) cc.E Gaseous sample rig efficiency (later) F Total gaseous sample volume (E X F) v cc G Tritium standard source count date & time 6 -m M- e s s i s v'i Tritium standard source dpm 4 to 3 51.7 dpm Tritium standard source Hi 61 Sample count date and time b-N -M G ie:io t Sample dpm t .15. 8 dpm I 3 Sample H# 97. 6

() _

Tritium decay coef ficient 1.539E - 4 days d CALCULATIONS I -

Liquid Sample, H-3 uci/mi = (1ml)(2.22E 6 dpm/uci). _ - (e $(t 3 t 1-) )

(12re )

= (1ml)(2.22E 6) (ek"*)(N (1.ons , - ))

- f. Ti f - S uci/ml H-3 I (250 ml) (t 3 -t))

Gaseous Sample, H-3 uci = (iml)(G)(2.22E 6 dpm/uci) (e 1

, ~ ,..-.:. -

. ig . - .

. t  ;; .

1g ( ,; } ( 6) u

. . _ NA

.q ue m

wg-3 .: . , ;: :4,'> , .

.'.3 r q~ . - ,

  • L . s. -

Jy

' Q g ~!.;; f{ ? :s~.l. L l %:yf.y

^ '

'3 . ,

, lgT *+ ^y .> ~.r'.

-(_ -

.s

.c. .-' ,

  • l *i ., .l

,  ;.y , :*

'\ ,,

. d h,*[ [*"*

  • g
    • f

,- . ' *h p . "I f.'d f 1 jf 3p .

.d.k ~ t j .' g? .,

(.* .

3M9MQMWsegnME9t!N

. .m - . . . . . , . , - - -- .

g- , - .j .. ,3.; ..

,.r..- ,

., 4

s.
  • s , . s.

~

i' ?$r9y:N:f,0bkk.w$-! i l:5 '

x.j..

f.

.a

-=- .

. w ,. v< .

OM12A
CHI-47

[ Page : 5 - IAST Rev. : 0

/ Attachment 1

- Form: OM12A: ' CHI-47-1 Tritium Data Sheet Sample Identification ( _, C .', a . . N u.,-e. L b.Q.u.#.

Sample date and time n-g .cc q 4 i>co t 3

Gaseous sampling initial flow rate t) A cc/ min A Caseous sampling final flow rate  ! cc/ min B Gaseous sampling stop date and time t 2

Total gaseous sampling period (t 2 -t C AveragegaseoussampleflowrateA+$) cc/ min D 2

Gaseous sample volume (C X D) cc E Gaseous sample rig ef ficiency (later) F Total gaseous sample volume (E X F) v cc G Tritium standard source count date & time 8 - M W- M CL .P -M" rF 4 Tritium standard source dpm  % 2. o m .1 dpm Tritium standard source Hf 61 Sample count date and time 6-fw-es @ ae: co t Sample dpm i a v, . e dpm I 3

(, ) Sample Hf 99 Tritium decay coefficient 1.539E - 4 days" K CALCULATIONS I

Liquid Sample, H-3 uc5m1 = (Iml)(2.22E 6 dpm/uci) (e A(t 3 -

t)) 1 W.6 )

~

= (1ml)(2.22E 6) (e ( ..ce )( - ))

- 5. 6 8 E - 5' uci/ml H-3

.. . m; -

I (250 ml)

(t 4 --.. -Gaseous Sample, H-3 uci/

1ml)(G)(2.22E 6 dpm/uci) (e 3 t))-

1 3 f. . j, )( )( . .

.i!?M'O h'3j.7l6hW' '

q'. < .; f3n a.:;C;g[df%' ' -w".6- . WP.7 f.p Gid'

'l - - . .: . MJ@'.[,/

.=c Ab #, - :uc 21 E-3. . . u .Q;ad. f ~

R .?;'... 2 ; L* n.--;d ), N ~j -l- \ ,

. . _ > . t l. _o,*.. lt_* l .M MTQ'? % ~ '

h j'Ty'y&t. n.

. . l.

_.g'

,
.,s %.. -

' Y ho l b ..h

-a ~ -- s: >

.~ . c.w - *

~

._3. ; - s - - < -

I  !~+'  ;.

y* -. I M .'; 3

1. , ,; ,

s ,

.1. +,7..6, ; ,m *rg

.4.. L q-*

..t a... +.).m';.'..

s', . '.

. g q5'?

g s*=.-

..i J.(. c

.3...

1

.e. . , , , ,.. .

. . . , w , , .f . ' . ,

  • Ai ,; v s + 1 3-
  • g 4
2. .

,e~ L

. c . , .f . 9

.....~;r-gr,

--4 - . - ,-

g i a

[' . '- . ,s a

.. . g .. xWsx.. ? "i'?' " P W M 'A% # 3 " ' " -W ^ &. : WW

%iQW'

1

  • .'+-o. ,4 . . . . . _ . . . = .3 ,

t (.:.:t'M,7 gi$. - "-

~; .

  • 1_
,;.QD  : ..: , . s.'i t,G jd. k ' ' '

- 'c -- ~.

x .n. ,..' =.e p .  ;

v. s . -

. , op : - a j

( i OM12A: CHI-47 Page : 5 - IAST Rev. : 0

/ Attachment 1 Form: 'OM12A: CHI-47-1

, J .t . -

)

1 Tritium Data Sheet l Sample Identification C.d .', . A . , Af , . w., d,'dC,2 sa-ge \

Sample date and time t, - n.3-M G o co t g

Gaseous sampling initial flow rate nA cc/ min A Gaseous sampling final flow rate cc/ min B Gaseous sampling stop date and time t 2

Total gaseous sampling period (t -t C

Average gaseous sample flow rate 2 A + E) cc/ min D 2

Gaseous sample volume (C X D) cc E Gaseous sample rig efficiency (later) F Total gaseous sample volume (E Y. F) v cc G Tritium standard source count date & time R..M Y-e.5 G>is o, Tritium standard source dpm 916 3 w 1.7 dpm

. Tritium standsrd source HP 62.

.' Sample count date and time 8 - r.i Aw - M cc .w nn t Sample dpm ii 2. 3 dpm I 3 Sample H#

() 9f.T Tritium decay coefficient 1.539E - 4 days- K CALCUIATIONS I

A(t 3 -t))

Liquid Sample, H-3 uci/ml - (Iml)(2.22E 6 dpm/uci) .(e 1

( #s2.3 ) )( - )

3

=

(Iml)(2.22E 6)

(e ( (l.ose) )

= 5. / 6 E - 5 uci/ml B-3 4

~ ' -

I (250 ml) (t

= (1ml)(G)(2.22E 6 dpm/uci) (e Gaseous Sample, H-3 uci 3 -t)) 1

~ )Q.f ' n ' }u%n~, ., . , x. . .wf ;.p y,,;;,

.?, _ , , . . ..

( ._, _

,.e . Qg;;;;,.

.g . Es g

?YW:g 4 W 9 af ; F, % j,g,.y t

.1 - g(Iml) ( ,:) .(259 mg);.,

e, m e j Q

=g.

,gJE)(,

' m.).. _

. 3 :-n n , 2E 6) JF(' 7.o' ' . -;g.

' ~4,.);:?

s~. " i.E V. i' "~

$M7 vln fhi-l'?

s , W, * ,

- ' ' !XJU .' # -dT+! 9- * ' )--AA--

t~J+l m B-3'. .*l;:N2.<dRe, ,

m.

w. vi N:. e' $, J. >O. rk.r,a ' ', w- l/f -- - - -
  1. o .. .
m. y c e . ;. t . . . .

.s n ., , . y :-

[

' . , s , M[w . .,*

9 5 -

['-

A, .,i / .' .1

, , 4 , ,' .a .-

f... ,~.7' -[(.[ Q .E;l$f . h E. +

,, :s .

..m.. ..... .

4 L?%enM%ns#%

f

, .. c -- . u z. . o , . ., . . . ,

- . .- .,. w.gme . . . - . .. . m . , s, . _ -~ ,. y .3 ,.a.

5.Y~'

i

' Y:d's eg' ;- _,- .1 3.,.: 0 s . '.' i$~

e. @

4,7 .. .,$.'8..{.;.f9

..n..

. @g[:.f.yz,.$ d! ( f %. T ,..' '

_- m

~: 4 q . :. ...

>,' ire g 4, ,. ./ L '.., -

'N'-,. . - '.+n ..,"

[. '? .,Ca , eIh ? %]

  • a % [.

s.i* M - ~~b'.+ -.- . " -

,t e de..

-y % : ;-.:. W',

,W6'  ;.5. m .>,. ?Jf.%{* *;;T- ..- ,M 'ii.' ' . .

.A :v,.

. ..X n c.::W i. 3' L'.Q. 4 ..~ gr.c=p A ~ ; '- - -"% ~

OM12A: CHI-47

[ .\

Page : 5 - IAST Rev. : 0 Attachment 1

  • Form: 0H12A: CHI-47-1 b

Tritium Data Sheet Sample Identification C d.k L., M a 3 vee d U \ n.. 2s.-p.1 '

Sample date and time // -Iro- G r 9.9 a oc, t Gaseous sampling initial flow rate /2A cc/ min A Gaseous sampling final flow rate cc/ min B Gaseous sampling stop date and time t 2

Total gaseous sampling period (t 2 -t C AveragegaseoussampleflowrateA+d) cc/ min D 2

Gaseous sample volume (C X D) cc E Gaseous sample rig ef ficiency (later) F Total gaseous sample volume (E X F) cc G v

Tritium standard source count date & time Tritium standard source dpm w 1 o % ', i. 1 dpm Tritium standard source Hf f,1 Sample count date and time 9 - m t. Y- B r @ o .2 c o t Sample dpm // 7. / dpm 7 3

( i Sample Hf 4 7. r Tritium decay coef ficient 1.539E - 4 days  %

CALCUL.ATIONS I

Liquid Sample, H-3 uci/mi = (Iml)(2.22E 6 dpm/uci) (e A(t 3 -t)) 1 I ## # ) )(

=

(1ml)(2.22E 6) (e(i. cn-( 1.org t.a h-)) (in J s-

= f. 3 ') E -5 uci/ml H-3 I (250 ml)

~ '

Gaseous Sample, H-3 ml = (Iml)(G)(2.22E 6 dpm/uci) (e f\ (t 3 -t)) 1

(

t . -" k' Inl) ,' h u-. n. .w ~ e.n. m. . , w w w m m,.y

. =

'S %*

n , . -

  • i' y n,e.q; pay;y y

_' (. 3

.r,..

. ...-w-r.....,,, --

4 ,. .

. , r,_.

  • kf. , . * * ) ,- ., . a 1 *, ,

o r M g s.q Qgg;g ; 3 [yd gy$ d$ g,.,

q$~ "A .bj*,l.,g$%g$@ng;3[I$ jW4Wsh@% 1 JP@Sig73f v  %

yW .

- wt s . , .

y?f

4

.i. ..eg

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