ML20101M985
| ML20101M985 | |
| Person / Time | |
|---|---|
| Site: | Perry  |
| Issue date: | 08/08/1995 |
| From: | Nielsen D, Tizzano D AFFILIATION NOT ASSIGNED |
| To: | |
| Shared Package | |
| ML20101M957 | List: |
| References | |
| NUDOCS 9604080185 | |
| Download: ML20101M985 (32) | |
Text
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Environmental servim Quantma Inmtwrated }
4101 Shuffel Dnw, NW North Canton, Ohio 44720 m
216 497 9396 Telephone 216 497-0772 Fax ANALYTICAL REPORT CEI-PERRY PLANT en Donna Tizzano ILLUMINATING COMPANY QUANTERRA IN RPORATED
(
Duane Nielsen Project Manager i
l' August 8,
1995 9604080185 960402 PDR ADOCK 05000440 P
Q%anterra c
Environmental services METHOD / ANALYST
SUMMARY
i' Analytical Methods Analyst CFR136A 625 Thomas M Hula MCAWW 420.1 Steven J Poppe CFR136A 608 Norma J Basko CFR136A 624 Timothy J Lavey References CFR136A
" Methods for Organic Chemical Analysis of Municipal and Industrial Wastewater", 40CFR, Part 136, Appendix A, October 26, 1984 and subsequent revisions.
MCAWW
" Methods for Chemical Analysis of Water and Wastes",
EPA-600/4-79-020, March 1983 and subsequent revisions.
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i e
bdI
Q%anterra Environmental Senirs SAMPLE
SUMMARY
1 I
The analytical results of the samples listed below are presented on the follos!.ng pages.
l WO #
IABORATORY ID SAMPLE ITTdNTIFICATION COSMQ A5G100112-001 SANITARY SEWER PUMP CE!TTER 1
)
I e
1 s
Il l
[
i Qhanterra Emironmmtal Serviws ILLtDEINATING COMPANY 1
SANITARY SENER PUMP CENTER wo#: C05MQ103 DATE SAMPLED:
7/06/95 LAB #: A5G100112-001 DATE RECEIVED:
7/07/95 MATRIX: WATF2
- - GC/MS Volatiles - - - - - - - - - - - - - - - - -
1 OF 2
RESULT REPORTING EXTRACTION-QC PAMAMETER (ua/L)
LIMIT METHOD ANALYSIS DATE BATCH Acrolein ND 50 CFR136A 624 07/12/95 5198047 Acrylonitrile ND 50 CFR136A 624 07/12/95 5198047 Benzene ND 5.0 CFR136A 624 07/12/95 5198047 "i
Bromodichloromethane 2.6 J 5.0 CFR136A 624 07/12/95 5198047 Bromoform ND 5.0 CFR136A 624 07/12/95 5198047 Bromomethane ND 10 CFR136A 624 07/12/95 5198047 s
Carbon tetrachloride ND 5.0 CFR136A 624 07/12/95 5198047 Chlorobenzene ND 5.0 CFR136A 624 07/12/95 5198047 Chloroethane ND 10 CFR136A 624 07/12/95 5198047 2-Chloroethyl vinyl ether ND 10 CFR136A 624 07/12/95 5198047 Chloroform 3.9 J 5.0 CFR136A 624 07/12/95 5198047 Chloromethane ND 10 CFR136A 624 07/12/95 5198047 Dibromochloromethane ND 5.0 CFR136A 624 07/12/95 5198047 1,1-Dichloroethane ND 5.0 CFR136A 624 07/12/95 5198047
(
1,2-Dichloroethane ND 5.0 CFR136A 624 07/12/95 5198047 1,1-Dichloroethene ND 5.0 CFR136A 624 07/12/95 5198047 1,2-Dichloroethene (total)
ND 5.0 CFR136A 624 07/12/95 5198047 l
1,2-Dichloropropane ND 5.0 CFR136A 624 07/12/95 5198047
']
cis-1,3-Dichloropropene ND 5.0 CFR136A 624 07/12/95 5198047 trans-1,3-Dichloropropene ND 5.0 CFR136A 624 07/12/95 5198047 Ethylbenzene ND 5.0 CFR136A 624 07/12/95 5198047 Methylene chloride ND 5.0 CFR136A 624 07/12/95 5198047 L
1,1,2,2-Tetrachloroethane ND 5.0 CFR136A 624 07/12/95 5198047
}
SURROGATE RECOVERY 1
ACCEPTABLE LIMITS i
1,2-Dichloroethane-d4 106
( 76 - 114)
Toluene-d8 100
( 88 - 110) i Bromofluorobenzene 95
( 86 - 115) b NSTE: AS RECEIVED NO NOT DETECTED AT THE STATED REPORTING LIMIT J ESTIMATED VALUE. (DETECTED), BUT BELOW QUANTITATION LIMIT.
9 h.
bE Ernimmumtal Smices ILLtMINATING COMPANY SANITARY SEWER PUMP CENTER l
WO #: C05MQ103 DATE SAMPLED:
7/06/95 LAB # A5G100112-001 DATE RECEIVED:
7/07/95 MATRIX: WATER
- - GC/MS Volatiles - - - - - - - - - ----------
2 OF 2
RESULT REPORTING EXTRACTION-QC PARAMETER (ucr/L)
LIMIT METHOD ANALYSIS DATE BATCH Tetrachloroethene ND 5.0 CFR136A 624 07/12/95 5198047 Toluene 2.8 J 5.0 CFR136A 624 07/12/95 5198047 1,1,1-Trichloroethane ND 5.0 CFR136A 624 07/12/95 5198047 1,1,2-Trichloroethane ND 5.0 CFR136A 624 07/12/95 5198047 Trichloroethene ND 5.0 CFR136A 624 07/12/95 5198047 Vinyl chloride ND 10 CFR136A 624 07/12/95 5198047 i
M I?
1 i
f SURROGATE RECOVERY 3,
ACCEPTABLE LIMITS 1,2-Dichloroethane-d4' 106
( 76 - 114)
Toluene-d8 100
( 88 - 110) j i Bromofluorobenzene 95
( 86 - 115)
LJ NOTE: A5 ItECEIVED ND NOT DETECTED AT THE STATED REPORTING LIMIT J ESTIMATED VALUE. (DETECTED), BUT BELOW QUANTITATION LIMIT.
&assterra Environmental Services ILLUMINATING COMPANY SANITARY SENER PUMP CENTER
)
I NO #: C05MQ104 DATE SAMPLED:
7/06/95 LAB #: A5G100112-001 DATE RECEIVED:
7/07/95 MATRIX: WATER l
- - - - - - - - - - - - - - - - - GC/MS Semi-Volatiles - - -
1 OF 3
RESULT REPORTING EXTRACTION-QC PARAMETER (ua/L)
LIMIT METHOD ANALYSIS DATE BA__TQi Acenaphthene ND 10 CFR136A G25 07/12-07/18/95 5193005 Acenaphthylene ND 10 CFR136A 625 07/12-07/18/95 5193005 j
Anthracene ND 10 CFR136A 625 07/12-07/18/95 5193005 Benzidine ND 50 CFR136A 625 07/12-07/18/95 5193005 Benzo (a) anthracene ND 10 CFR136A 625 07/12-07/18/95 5193005 4
Benzo (b)fluoranthene ND 10 CFR136A 625 07/12-07/10/95 5193005 l
.i Benzo (k)fluoranthene ND 10 CFR136A 625 07/12-07/18/95 5193005
)
Benzo (ghi) perylene ND 10 CFR136A 625 07/12-07/18/95 5193005 Benzo (a) pyrene ND 10 CFR136A 625 07/12-07/18/95 5193005 bis (2-Chloroethoxy) methane ND 10 CFR136A 625 07/12-07/18/95 5193005 bis (2-Chloroethyl) ether ND 10 CFR136A 625 07/12-07/18/95 5193005 bis (2-Chloroisopropyl) ether ND 10 CFR136A 625 07/12-07/18/95 5193005 bis (2-Ethylhexyl) phthalate ND 10 CFR136A 625 07/12-07/18/95 5193005 4-Bromophenyl phenyl ether ND 10 CFR136A 625 07/12-07/18/95 5193005 Butyl benzyl phthalate ND 10 CFR136A 625 07/12-07/18/95 5193005 4-Chloro-3-methylphenol ND 10 CFR136A ti25 07/12-07/18/95 5193005 2-Chloronaphthalene ND 10 CFR136A 625 07/12-07/10/95 5193005 3-Chlorophenol ND 10 CFR136A 625 07/12-07/18/95 5193005 4-Chlorophenyl phenyl ether ND 10 CFR136A 625 07/12-07/18/95 5193005 Chrysene ND 10 CFR136A 625 07/12-07/18/95 5193005 Dibenzo (a, h) anthracene ND 10 CFR136A 625 07/12-07/18/95 5193005 Di-n-butyl phthalate ND 10 CFR136A 625 07/12-07/18/95 5193005 1,2-Dichlorobenzene ND 10 CFR136A 625 07/12-07/18/95 5193005 SURROGATE RECOVERY 3,
ACCEPTABLE LIMITS 2-Fluorophenol 66
( 17 - 106)
Phenol-d5 67
( 15 - 126)
'i 2,4,6-Tribromophenol 82
( 13 - 145)
Nitrobenzene-d5 66
( 36 - 148) 2-Fluorobiphenyl 68
( 38 - 106)
Terphenyl-d14 18
( 10 - 169)
NOTE: AS RECEIVED ND NOT DETECTED ATTHE STATED REPORTING LIMIT
Qhanterra Environmental Senices ILLUMINATING COMPANY
\\
SANITARY SEWER PUMP CENTER l
WO #: C05MQ104 DATE SAMPLED:
7/06/95 LAB #: A5G100112-001 DATE RECEIVED:
7/07/95 NATRIX: WATER
- - - - - - - - - - - - - - - - GC/MS Semi-Volatiles - - - - - - - - - - - - - - - - -
2 OF 3
RESULT REPORTING EXTRACTION-QC PARAMETER (ua/L)
LIMIT METHOD ANALYSIS DATE DAT_Qi 1,3-Dichlorobenzene ND 10 CFR136A 625 07/12-07/18/95 5193005 1,4-Dichlorobenzene ND 20 CFR136A 625 07/12-07/18/95 5193005 3,3'-Dichlorobenzidine ND 20 CFR136A 625 07/12-07/18/95 5193005 j
2,4-Dichlorophenol ND 10 CFR136A 625 07/12-07/18/95 5193005 Diethyl phthalate ND 10 CFR136A 625 07/12-07/18/95 5193005 2,4-Dimethylphenol ND 10 CFR136A 625 07/12-07/18/95 5193005 J
Dimethyl phthalate ND 10 CFR136A 625 07/12-07/18/95 5193005 4,6-Dinitro-ND 50 CFR136A 625 07/12-07/18/95 5193005 2-methylphenol 2,4-Dinitrophenol ND 50 CFR136A 625 07/12-07/18/95 5193005 2,4-Dinitrotoluene ND 10 CFR136A 625 07/12-07/18/95 5193005 2,6-Dinitrotoluene ND 10 CT'R136A 625 07/12-07/18/95 5193005 Di-n-octyl phthalate ND 10 CFR136A 625 07/12-07/18/95 5193005 1,2-Diphenylhydrazine ND 10 CFR136A 625 07/12-07/18/95 5193005 Fluoranthene ND 10 CFR136A 625 07/12-07/18/95 5193005 Fluorene ND 10 CFR136A 625 07/12-07/18/95 5193005 Hexachlorobenzene ND 10 CFR136A 625 07/12-07/18/95 5193005 Hexachlorobutadiene ND 10 CFR136A 625 07/12-07/18/95 5193005 Hexachlorocyclopentadiene ND 10 CFR136A 625 07/12-07/18/95 5193005
~I Hexachloroethane ND 10 CFR136A 625 07/12-07/18/95 5193005 Indeno(1,2,3-cd) pyrene ND 10 CFR136A 625 07/12-07/18/95 5193005 Isophorone ND 10 CFR136A 625 07/12-07/18/95 5193005 Naphthalene ND 10 CFR136A 625 07/12-07/18/95 5193005 Nitrobenzene ND 10 CFR136A 625 07/12-07/18/95 5193005 SURROGATE RECOVERY
).
ACCEPTABLE LIMITS 2-Fluorophenol 66
( 17 - 106)
Phenol-d5 67
( 15 - 126) 2,4,6-Tribromophenol 82
( 13 - 145)
Nitrobenzene-d5 66
( 36 - 148) 2-Fluorobiphenyl 68
( 38 - 106)
Terphenyl-d14 18
( 10 - 169)
NOTE: A5 RECEIVED ND NOT DETECTED ATTHE STATED REPOItTING LIMIT
/
ONE
$50 Ermnmmenul Senices ILLUMINATING COMPANY 3
SANITARY SEWER PUMP CENTER 4l WO #: C05MQ104 DATE SAMPLED:
7/06/95 LAB #: A5G100112-001 DATE RECEIVED:
7/07/95 MATRIX: WATER t
- - - - - - - - - - - - - - GC/MS Semi-Volatiles - - -- - - ----- ------
3 OF 3
RESULT REPORTING EXTRACTION-QC PARAMETER (ue/L)
LIMIT METHOD ANALYSIS DATE BATCH 2-Nitrophenol ND 10 CFR136A 625 07/12-07/18/95 5193005 4-Nitrophenol ND 50 CFR136A 625 07/12-07/18/95 5193005 N-Nitrosodimethylamine ND 10 CFR136A 625 07/12-07/18/95 5193005 N-Nitrosodiphenylamine ND 10 CFR136A 625 07/12-07/18/95 5193005 N-Nitrosodi-n-propylamine ND 10 CFR136A 625 07/12-07/18/95 5193005 Pentachlorophenol ND 50 CFR136A 625 07/12-07/18/95 5193005 Phenanthrene ND 10 CFR136A 625 07/12-07/18/95 5193005 Phenol ND 10 CFR136A 625 07/12-07/18/95 5193005 r?
Pyrene ND 10 CFR136A 625 07/12-07/18/95 5193005
]
1,2,4-Trichlorobenzene ND 10 CFR136A 625 07/12-07/18/95 5193005 2,4,6-Trichlorophenol ND 10 CFR136A 625 07/12-07/18/95 5193005 4
1 4
i.
SURROGATE RECOVERY l
ACCEPTABLE LIMITS 2-Fluorophenol 66
( 17 - 106)
J Phenol-d5 67
( 15 - 126) 2,4,6-Tribromophenol 82
( 13 - 145)
{!
Nitrobenzene-d5 66
( 36 - 148) 2-Fluorobiphenyl 68
( 38 - 106)
Terphenyl-d14 18
( 10 - 169)
NOTE: A5 RECEIVED NO NOT DETECTED AT THE STATED REPORTING LIMIT
Qhanterra Ewam...unaI Services ILLUMINATING COMPANY SANITARY SEWER PUMP CENTER WO #: C05MQ102 DATE SAMPLED:
7/06/95 LAB #: A5G100112-001 DATE RECEIVED:
7/07/95 MATRIX: WATER l
- - - - - - - - - - - - - - - - - - GC Semi-Volatiles -
1 OF 2
l RESULT REPORTING EXTRACTION-QC l
PARAMETER (ua/L)
LIMIT METHOD ANALYSIS DATE BATCH Aldrin ND 0.050 CFR136A 608 07/12-07/18/95 5193004 Aroclor 1232 ND 0.50 CFR136A 608 07/12-07/18/95 5193004 Aroclor 1016 ND 0.50 CFR136A 608 07/12-07/18/95 5193004 Aroclor 1221 ND 0.50 CFR136A 608 07/12-07/18/95 5193004 Aroclor 1242 ND 0.50 CFR136A 608 07/12-07/18/95 5193004 Aroclor 1248 ND 0.50 CFR136A 608 07/12-07/18/95 5193004 i
Aroclor 1254 ND 1.0 CFR136A 608 07/12-07/18/95 5193004 Aroclor 1260 ND 1.0 CFR136A 608 07/12-07/18/95 5193004 alpha-BHC ND 0.050 CFR136A 608 07/12-07/18/95 5193004 beta-BHC ND 0.050 CFR136A 608 07/12-07/18/95 5193004 delta-BHC ND 0.050 CFR136A 608 07/12-07/18/95 5193004 gamma-BHC (Lindane)
ND 0.050 CFR136A 608 07/12-07/18/95 5193004 Chlordane ND 0.50 CFR136A 608 07/12-07/18/95 5193004 4,4'-DDD ND 0.10 CFR136A 608 07/12-07/18/95 5193004 4,4'-DDE ND 0.10 CFR136A 608 07/12-07/18/95 5193004 4,4'-DDT ND 0.10 CFR136A 608 07/12-07/18/95 5193004 Dieldrin ND 0.10 CFR136A 608 07/12-07/28/95 5193004 Endosulfan I ND 0.050 CFR136A 608 07/12-07/10/95 5193004
?
Endosulfan II ND 0.10 CFR136A 608 07/12-07/18/95 5193004 Endosulfan sulfate ND 0.10 CFR136A 608 07/12-07/18/95 5193004 Endrin ND 0.10 CFR136A 608 07/12-07/18/95 5193004 i
Endrin aldehyde ND 0.10 CFR136A 608 07/12-07/18/95 5193004 i
Heptachlor ND O.050 CFR136A 608 07/12-07/18/95 5193004 SURROGATE RECOVERY 1
ACCEPTABLE LIMITS Tetrachloro-m-xylene 52
( 14 - 155)
)
Dibutylchlorendate 34
( 10 - 155)
._I ZOTE: A5 RECEIVED ND NOT DETECTED AT THE STATED REPORTING LIMIT
Qhsanterra Envimnmental Services ILLUMINATING COMPANY SANITARY SEWER PUMP CENTER l }
WO #: C05MQ102 DATE SAMPLED:
7/06/95 l
LAB # A5G100112-001 DATI RECEIVED:
7/07/95 l.
MATRIX: WATER
- - - - - - - - - - - - - - - - - - GC Sesti-Volatiles - - - -
2 OF 2
RESULT REPORTING EXTRACTION-QC PARAMETER (ua/L)
LIMIT METHOD ANALYSIS DATE BATCH Heptachlor epoxide ND 0.050 CFR136A 608 07/12-07/18/95 5193004 Toxaphene ND 1.0 CFR136A 608 07/12-07/18/95 5193004 J
l i*
I t
O 1
SURROGATE RECOVERY 3.
ACCEPTABLE LIMITS Tetrachloro-m-xylene 52
( 14 - 155)
Dibutylchlorendate 34
( 10 - 155) i i d i
NOTE: AS RECEIVED ND NOT DETECTED AT THE STATED GPORTING LIMIT 4
l l
l i
Q%anterra Envinmnuntal Servkes ILLtD(IMATING COMPANY SANITARY SEWER PUMP CENTER J
WO # C05)Q DATE SAMPLED:
7/06/95 LAB #: A5G100112-001 DATE RECEIVED:
7/07/95 3
4 MATRII: WATER
-....... -. INORGANIC ANALYTICAL REPORT - - - - -. - - - - - - - - -
REPORTING PREPARATION -
QC PARAMETER RESULT LIMIT UF_II EOD ANALYSIS DATE BATCH Phenolics ND 0.020 mg/L MCAWW 420.1 7/24-7/25/95 5205116 d
b e
NOTE: AS RECEVED ND NOT DETECTED AT THE STA1T.D REPORTINO IJMIT
a (Escnterra Environmental Sernces 9
- 1
.5 8
QUALITY CONTROL SECTION l
i i
hanterra Envinmmental QUALITY CONTROL NARRATIVE 7
l The results included in this report have been reviewed for compliance with the laboratory QA/QC plan. All data have been found to be compliant with laboratory protocol with the exception of those items noted.
The matrix spike and matrix spike duplicate (MS/MSD) contained in this quality control report were generated as part of the laboratory QA/QC program requirements. These requirements include the analysis of a MS/MSD on a one in twenty basis. Therefore, the associated batch number indicated on the MS/MSD reports may not reflect the same batch numbers as those of the samples contained in the analytical report.
Recoveries for Di-n-octyl phthalate and 2,4-Din *ophenol exc:eds the quality control acceptance limits in the Base Neutral and Acid t anpounds M5 /MSD associated with batch number 5193005. According to EPA 600 sc:ies method requir:ments, analytical data for these analytes have been verified by the check sample recoveries me2 ting quality control criteria.
The 600 Series Methods as defined in the 40 CFR part 136, Appendix A requim the analysis of a matrix spike sample at a frequency of 5% for GC/MS organics and 10% for GCS g
organics. The analytes used in the matrix spike will be those found in the analytical methods l
list.
1 I
i s
J
Q%anterra
,catal CHECK SAMPLE REPORT l
l QC BATCH:
5198047 LAB #: A5G170000-047 C PREPARATION DATE:
7/13/95 DATE ANALYZED:
7/13/95 I
- - - - - - - - - - - - - - - - - - GC/MS Volatiles - - - - - - - - - - - - - - - - - -
l SPIKE PERCENT Q/C COMPOUND RECOVERY LIMITS i
Benzene 99 (79-125)
Bromodichloromethane 106 (65-144) 8 Cromoform 95 (46-151)
Bromomethane 112 (47-160)
Carbon tetrachloride 109 (63-141)
Chlorobenzene 97 (81-121)
Chloroethane 102 (38-170) 3 2-Chloroethyl vinyl ether 91 (27-166)
Chloroform 102 (70-141)
Chloromethane 99 (36-158)
Dibromochloromethane 103 (58-140) 1,2-Dichlorobenzene 104 (18-190) 1,3-Dichlorobenzene 106 (59-156) g 1,4-Dichlorobenzene 102 (18-190) 1,1-Dichloroethane 94 (64-145) 1,2-Dicaloroethane 99 (66-150) 1,1-Dichloroethene 97 (70-143) trans-1,2-Dichloroethene 94 (58-140) 1,2-Dichloropropane 98 (71-142) cis-1,3-Dichloropropene 100 (59-140) trans-1,3-Dichloropropene 98 (53-148)
Ethylbenzene 96 (70-140)
Methylene chloride 93 (72-144) 1 1,1,2,2-Tetrachloroethane 100 (52-153)
Tetrachloroethene 100 (67-136)
Toluene 104 (79-122) 1,1,1-Trichloroethane 103 (67-137) 1,1,2-Trichloroethane 97 (70-140)
Trichloroethene 101 (76-121)
INVALID 116 (17-181)
Vinyl chloride 101 (47-156) b
a O
M Environmental Servkes
\\
CHECK SAMPLE REPORT
']
j,j QC BATCH:
5193005 LAB #: A5G120000-005 C PREPARATION DATE:
7/12/95 DATE ANALYZED:
7/18/95
- - - --- - - - - - - - - - - - - GC/MS Semi-volatiles - - - - - - - - - - - - - - - - -
SPIKE PERCENT Q/C COMPOUND RECOVERY LIMITS Acenaphthene 74 (48-113)
Acenaphthylene 80 (47-111)
Anthracene 82 (53-107)
'j Benzo (a) anthracene 83 (53-110)
L Benzo (b)fluoranthene 96 (43-110)
Benzo (k) fluoranthene 94 (36-136)
Benzo (a) pyrene 82 (28-114) is Benzo (ghi) perylene 52 (17-120)
Benzyl butyl phthalate 73 (35-110) bis (2-Chloroethyl) ether 59 (44-95) bis (2-Chloroethoxy) methane 72 (50-106) bis (2-Chloroisopropyl) ether 60 (21-122) bis (2-Ethylhexyl) phthalate 75 (30-123) gW 4-Bromophenyl phenyl ether 87 (52-114) 2-Chloronaphthalene 76 (43-111) 4-Chlorophenyl phenyl ether 81 (48-124)
Chrysene 85 (54-120)
Dibenzo (a, h) anthracene 62 (23-112)
Di-n-butyl phthalate 78 (44-115) 1,2-Dichlorobenzene 57 (43-95) 1,3-Dichlorobenzene 54 (41-92) 1,4-Dichlorobenzene 56 (37-92) 3,3'-Dichlorobenzidine 80 (19-137)
,r ]
Diethyl phthalate 57 (16-129)
~ '
^
Dimethyl phthalate 50 (10-115) 2,4-Dinitrotoluene 80 (37-131) 2,6-Dinitrotoluene 81 (40-121)
Di-n-octyl phthalate 103 (25-123)
Fluoranthene 89 (35-131)
Fluorene 80 (45-124)
Hexachlorobenzene 83 (53-110) i Hexachlorobutadiene 64 (45-96)
Hexachloroethane 46 (38-90)
Indeno (1,2,3-cd) pyrene 59 (28-112)
Isophorone 75 (44-105)
,2
!.3 Naphthalene 67 (44-99)
Nitrobenzene 66 (44-102)
N-Nitrosodi-n-propylamine 63 (31-113)
Phenanthrene 78 I';0-109)
Pyrene 63 s-159) 1,2,4-Trichlorobenzene 68 (39-136)
Q%anterra Ensimmumtal Services CHECK SAMPLE REPORT e.
(;f QC BATCH:
5193005 LAB #: A5G120000-005 C PRF9ARATION DATE:
7/12/95 DATE ANALYZED:
7/18/95
- - - - - - - - - - - - - - - - - GC/MS Semi-Volatiles - - - - - - - - - - - - - - - - -
SPIKE PERCENT Q/C COMPOUND RECOVERY LIMITS 4-Chloro-3-methylphenol 78 (30-117) 2-Chlorophenol 66 (35-111) 2,4-Dichlorophenol 79 (33-93)
]
2,4-Dimethylphenol 38 (23-74) 2,4-Dinitrophenol 72 (10-96) 4,6-Dinitro-74 (10-115' 2-methylphenol 2-Nitrophenol 60 (10-99) 4-Nitrophenol 85 (10-128)
)
{;
Pentachlcrophenol 76 (10-113)
Phenol 60 (12-116) 1 2,4,6-Trichlorophenol 93 (22-102)
D
- 4 4
6 i
t I.
5
ME Envinamental Scrwes CHECK SAMPLE REPORT QC BATCH:
5193004 LAB #s A5G120000-004 C PREPARATION DATE:
7/12/95 DATE ANALYZED:
7/17/95
- - - - - GC Semi-volatiles - - - --------------
SPIKE PERCENT Q/C COMPOUND RECOVERY LIMITS Aldrin 72 (57-145) alpha-BHC 71 (37-134) beta-BHC 74 (17-147) i delta-BHC 76 (19-140) gamma-BHC (Lindane) 70 (52-139) 4,4'-DDD 75 (31-141) 4,4'-DDE 80 (30-145) 4,4'-DDT 85 (64-144)
Dieldrin 75 (36-172)
Endosulfan I 76 (45-153)
Endosulfan II 83 (10-202) j Endosulfan sulfate 83 (26-144)
Endrin 77 (63-165)
Heptachlor 78 (66-156)
Heptachlor epoxide 84 (37-142)
)
1 I
1 89 4
i
.1
a_.
.m
.._.__m..-....__
Qhsanterra Envinmmental CHECK SAMPLE REPORT i
LAB # A5G100112 l
l INORGANIC ANALYTICAL REPORT
[
SPIKE PERCENT PREPARATION -
Q/C COMPOUND RECOVERY LIMITS ANALYSIS DATE BATCH Phenolics 98 (51-125) 7/24-7/25/95 5205116 i
i i
O l
Q%sneerra Envuonmental METROD BLANK REPORT I
,[ I, LAB #: A50170000-047 1
- - - - - - - - - - - - - - - - - - GC/MS Volatiles - - - - - - - - - - - - - - - - - - -
1 RESULT REPORTING PREPARATION -
]
PARAMETER (ua/L)
LIMIT ANALYSIS DATE BATCH Acrolein ND 50 7/12/95 5198047 Acrylonitrile ND 50 7/12/95 5198047 Benzene ND 5.0 7/12/95 5198047 Oromodichloromethane ND 5.0 7/12/95 5198047 Bromoform ND 5.0 7/12/95 5198047 Cromomethane ND 10 7/12/95 5198047 Carbon tetracnloride ND 5.0 7/12/95 5198047 Chlorobenzene ND 5.0 7/12/95 5198047 Dibromochloromethane ND 5.0 7/12/95 5198047 j
i Chloroethane ND 10 7/12/95 5198047 2-Chloroethyl vinyl ether ND 10 7/12/95 5198047 Chloroform ND 5.0 7/12/95 5198047 i
Chloromethane ND 10 7/12/95 5198047 3
1,1-Dichloroethane ND 5.0 7/12/95 5198047 1,2-Dichloroethane ND 5.0 7/12/95 5198047 l
1,1-Dichloroethene ND 5.0 7/12/95 5198047 1,2-Dichloroethene (total)
.ND 5.0 7/12/95 5198047 1,2-Dichloropropane ND 5.0 7/12/95 5198047 l
I cis-1,3-Dichloropropene ND 5.0 7/12/95 5198047
]
trans-1,3-Dichloropropene ND 5.0 7/12/95 5198047 Ethylbenzene ND 5.0 7/12/95 5198047 Methylene chloride ND 5.0 7/12/95 5198047 1,1,2,2-Tetrachloroethane ND 5.0 7/12/95 5198047 Tetrachloroethene ND 5.0 7/12/95 5198047 Toluene ND 5.0 7/12/95 5198047 SURROGATE RECOVERY 1
ACCEPTABLE LIMITS 1,2-Dichloroethane-d4 108
( 76 - 114)
Toluene-d8 98
( 88 - 110)
Bromofluorobenzene 97
( 86 - 115)
NOVE:
ND (NoNE DERCTU))
O M
Environmental METHOD BLANK REPORT LAB #: A5G170000-047
- - - - - - - - - - - - - - - - - - GC/MS Volatiles - - - - - - - - - - - - - - - - - - -
RESULT REPORTING PREPARATION -
QC PARAMETER (ua/L)
LIMIT ANALYSIS DATE BATCH 1,1,1-Trichloroethane ND 5.0 7/12/95 5198047 1,1,2-Trichloroethane ND 5.0 7/12/95 5198047 Trichloroethene ND 5.0 7/12/95 5198047 Vinyl chloride ND 10 7/12/95 5198047 i
}
s O
i
- 4 d
1
\\,
I a
SURROGATE RECOVERY 1
ACCEPTABLE LIMITS 1,2-Dichloroethane-d4 108
( 76 - 114)
Toluene-d8 98
( 88 - 110)
Bromofluorobenzene 97
( 86 - 115) g NOTE:
ND (NONE DETECTED) i h-
Q%anterra Environmental METHOD BLANK REPORT LAB #: A5G120000-005
- - - - - GC/MS Semi-Volatiles - - - - - - - - - - - - - - - - - -
RESULT REPORTING PREPARATION -
QC PARAMETER (ua/L)
LIMIT _
ANALYSIS DATE BATCH Acenaphthene ND 10 7/12-7/17/95 5193005 t
Acenaphthylene ND 10 7/12-7/17/95 5193005 Anthracene ND 10 7/12-7/17/95 5193005 Benzidine ND 50 7/12-7/17/95 5193005 Benzo (a) anthracene ND 10 7/12-7/17/95 5193005 Benzo (b) fluoranthene ND 10 7/12-7/17/95 5193005 Benzo (k)fluoranthene ND 10 7/12-7/17/95 5193005 Benzo (ghi) perylene ND 10 7/12-7/17/95 5193005 Benzo (a) pyrene ND 10 7/12-7/17/95 5193005 bis (2-Chloroethoxy) methane ND 10 7/12-7/17/95 5193005 bis (2-Chloroethyl) ether ND 10 7/12-7/17/95 5193005 bis (2-Chloroisopropyl) ether ND 10 7/12-7/17/95 5193005 bis (2-Ethylhexyl) phthalate ND 10 7/12-7/17/95 5193005
)
4-Bromophenyl phenyl ether ND 10 7/12-7/17/95 5193005 Butyl benzyl phthalate ND 10 7/12-7/17/95 5193005 j
l 4-Chloro-3-methylphenol ND 10 7/12-7/17/95 5193005 l
2-Chloronaphthalene ND 10 7/12-7/17/95 5193005 2-Chlorophenol ND 10 7/~2-7/17/95 5193005 4-Chlorophenyl phenyl ether ND 10 7/12-7/17/95 5193005 Chrysene ND 10 7/12-7/17/95 5193005 Di-n-butyl phthalate ND 10 7/12-7/17/95 5193005 1,2-Dichlorobenzene ND 10 7/12-7/17/95 5193005 1,3-Dichlorobenzene ND 10 7/12-7/17/95 5193005 1,4-Dichlorobenzene ND 20 7/12-7/17/95 5193005 3,3'-Dichlorobenzidine ND 20 7/12-7/17/95 5193005
)
SURROGATE RECOVERY 3,
ACCEPTABLE LIMITS 2-Fluorophenol 57
( 17 - 106)
Phenol-d5 50
( 15 - 126) 2,4,6-Tribromophenol 74
( 13 - 145)
Lj Nitrobenzene-d5 64
( 36 - 148) 2-Fluorobiphenyl 62
( 38 - 106)
Terphenyl-d14 80
( 10 - 169)
NOTE:
ND (NONE DDICED)
N
}
hBRt9Fra Environmental METHOD BLANK REPORT LAB #: A50120000-005
- - - - - - - - - - - - - - - - - GC/MS Semi-Volatiles - - - - - - - - - - - -
RESULT REPORTING PREPARATION -
OC PARAMETER (ua/L)
LIMIT ANALYSIS DATE BATCH 2,4-Dichlorophenol ND 10 7/12-7/17/95 5193005 Diethyl phthalate ND 10 7/12-7/17/95 5193005 2,4-Dimethylphenol ND 10 7/12-7/17/95 5193005 Dimethyl phthalate ND 10 7/12-7/17/95 5193005 Di-n-octyl phthalate ND 10 7/12-7/17/95 5193005 4,6-Dinitro-ND 50 7/12-7/17/95 5193005 I
2-methylphenol 2,4-Dinitrophenol ND 50 7/12-7/17/95 5193005 a
2,4-Dinitrotoluene ND 10 7/12-7/17/95 5193005 2,6-Dinitrotoluene ND 10 7/12-7/17/95 5193005 1,2-Diphenylhydrazine ND 10 7/12-7/17/95 5193005 Fluoranthene ND 10 7/12-7/17/95 5193005 b)
Fluorene ND 10 7/12-7/17/95 5193005
)
Hexachlorobenzene ND 10 7/12-7/17/95 5193005 Hexachlorobutadiene ND 10 7/12-7/17/95 5193005 Hexachlorocyclopentadiene ND 10 7/12-7/17/95 5193005 Hexachloroethane ND 10 7/12-7/17/95 5193005 Indeno (1,2,3-cd) pyrene ND 10 7/12-7/17/95 5193005 Isophorone ND 10 7/12-7/17/95 5193005 Naphthalene ND 10 7/12-7/17/95 5193005 Nitrobenzene ND 10 7/12-7/17/95 5193005 2-Nitrophenol ND 10 7/12-7/17/95 5193005 4-Nitrophenol ND 50 7/12-7/17/95 5193005 N-Nitrosodimethylamine ND 10 7/12-7/17/95 5193005 N-Nitrosodi-n-propylamine ND 10 7/12-7/17/95 5193005 SURROGATE RECOVERY 1
ACCEPTABLE LIMITS 2-Fluorophenol 57
( 17 - 106)
Phenol-d5 50
( 15 - 126) 2,4,6-Tribromophenol 74
( 13 - 145) 6,
Nitrobenzene-d5 64
( 36 - 148) lj 2-Fluorobiphenyl 62
( 38 - 106)
Terphenyl-d14 80
( 10 - 169)
NOTE:
ND (NONE DDECED)
Q%anterra
-a METHOD BLANK REPORT 0
l LAB #: A5G120000-005
............... - - GC/MS Senai-Volatiles - -
RESULT REPORTING PREPARATION -
QC PARAMETER (ua/L)
LIMIT ANALYSIS DATE BATCH N-Nitrosodiphenylamine ND 10 7/12-7/17/95 5193005 Pentachlorophenol ND 50 7/12-7/17/95 5193005 Phenanthrene ND 10 7/12-7/17/95 5193005 Phenol ND 10 7/12-7/17/95 5193005
[j Pyrene ND 10 7/12.7/17/95 5193005 1,2,4-Trichlorobenzene ND 10 7/12-7/17/95 5193005 2,4,6-Trichlorophenol ND 10 7/12-7/17/95 5193005 Dibenzo (a, h) anthra ~.ne ND 10 7/12-7/17/95 5193005 i
M i
t
.,3
'4 i.
t' u
f SURROGATE RECOVERY 1
ACCEPTABLE LIMITS j,
2-Fluorophenol 57
( 17 - 106)
Phenol-d5 50
( 15 - 126) 2,4,6-Tribromophenol 74
( 13 - 145)
)
Nitrobenzene-d5 64
( 36 - 148) 3-Fluorobiphenyl 62
( 18 - 106)
Terphenyl-d14 80
( 10 - 169)
NOTE:
ND (NONE DETECTED)
>+
e t
Qhsanterra Environmental METHOD BLANK REPORT i
l LAB #: A5G120000-004
- - - - - - - - - - - - - - - - - - GC Semi-Volatiles - - - -
RESULT REPORTING PREPARATION -
QC PARAMETER (uo/L)
LIMIT ANALYSIS DATE BATCH Aldrin ND 0.050 7/12-7/17/95 5193004 alpha-BHC ND 0.050 7/12-7/17/95 5193004 beta-BHC ND 0.050 7/12-7/17/95 5193004 delta-BHC ND 0.050 7/12-7/17/f5 5193004 4
gamma-BHC (Lindane)
ND 0.050 7/12-7/17/95 5193004 Chlordane ND 0.50 7/12-7/17/95 5193004 4,4'-DDD ND 0.10 7/12-7/17/95 5193004 i
4,4'-DDE ND 0.10 7/12-7/17/95 5193004 4,4'-DDT ND 0.10 7/12-7/17/95 5193004 Dieldrin ND 0.10 7/12-7/17/95 5193004 Endosulfan I ND 0.050 7/12-7/17/95 5193004 Endosulfan II ND 0.10 7/12-7/17/95 5193004 Endosulfan sulfate ND 0.10 7/12-7/17/95 5193004 Endrin ND 0.10 7/12-7/17/95 5193004 Endrin aldehyde ND 0.10 7/12-7/17/95 5193004 Heptachlor ND 0.050 7/12-7/17/95 5193004 Heptachlor epoxide ND 0.050 7/12-7/17/95 5193004 Aroclor 1016 ND 0.50 7/12-7/17/95 5193004 Aroclor 1221 ND 0.50 7/12-7/17/95 5193004
)
- ~)
Aroclor 1232 ND 0.50 7/12-7/17/95 5193004 i
Aroclor 1242 ND 0.50 7/12-7/17/95 5193004 Aroclor 1248 ND 0.50 7/12-7/17/95 5193004 Aroclor 1254 ND 1.0 7/12-7/17/95 5193004 Aroclor 1260 ND 1.0 7/12-7/17/95 5193004 Tnxaphene ND 1.0 7/12-7/17/95 5193004 Efgf0 GATE RECOVERY ACCEPTABLE LIMITS Tutrachloro-m-xylene 99
( 14 - 155)
Dioutylchlorendate 92
( 10 - 155)
I ib NOTE ND (NONE DEnrTE))
(Asaneerra a
METHOD BLANK REPORT U
3 LAB #: A5G100112 INORGANIC ANALYTICAL REPORT REPORTING PREPARATION -
QC PARAMETER RESULT T WTT UNIT ANALYSIS DATE BATCH Phenolics ND 0.020 mg/L 7/24-7/25/95 5205116 C
i I
M NOTL ND NOT DETECTED AT THE STATED REPORTING UMIT
J Qhwanterra Environinental Services j
MATRIX SPIKE REPORT
?
QC BATCH:
5195040 WO #:
A5A6D LkB #: B5G030011-001 S PREPARATION DATE:
7/12/95 MATRIX: WATER DATE ANALYZED:
7/12/95 1
- - - - - - - - - - - - - - - - - - GC/MS Volatiles -
SPIKE PERCENT Q/C COMPOUND RECOVERY LIMITS Benzene 98 (83-123)
Bromodichloromethane 104 (57-153)
Bromoform 95 (47-165) i Bromomethane 113 (76-150)
Carbon tetrachloride 106 (73-135)
Chlorobenzene 96 (85-120)
Chloroethane 100 (71-154) 2-Chloroethyl vinyl ether 51 (10-153)
Chloroform 100 (10-204)
Chloromethane 101 (44-151)
Dibromochloromethane 105 (60-146) 1,2-Dichlorobenzene 103 (18-190) 1,3-Dichlorobenzene 104 (59-156) 1,4-Dichlorobenzene 102 (18-190) 1,1-Dichloroethane 93 (53-148) 1,2-Dichloroethane
-98 (52-167) 8,1-Dichloroethene 98 (55-142) trans-1,2-Dichloroethene 95 (55-139) 1,2-Dichloropropane 96 (64-146) cis-1,3-Dichloropropene 101 (52-135) trans-1,3-Dichloropropene 100 (50-144) lt?
Ethylbenzene 93 (72-140) li Methylene chloride 89 (62-152)
{
1,1,2,2-Tetrachloroethane 96 (53-149)
Tetrachloroethene 72 (67-141)
Toluene 101 (82-122) 1,1,1-Trichloroethane 102 (33-171) 1,1,2-Trichloroethane 98 (73-138) j Trichloroethene 98 (77-124) l Trichlorofluoromethane 114 (17-181)
Vinyl chloride 103 (48-161) iU Cakulanorts are performed before roundmg to avoid round-off erTors in cakulated results t
1
(k%aneerra Eosimamental l
Services l
MATRIZ SPIKE REPCRT I.
~
j QC BATCH:
5175008 WO #:
A55LQ LAB #: A5F220034-001 S
. PREPARATION DATE:
6/24/95 MATRIX: WATER DATE ANALYZED:
7/01/95 l
l l
- - - - - - - - - GC/MS Semi-Volatiles - - - - -
I SPIKE PERCENT Q/C COMPOUND RECOVERY LIMITS Acenaphthene 82 (45-112)
Acenaphthylene 90 (30-122) l l
Anthracene 95 (18-133)
(
Benzo (a) anthracene 92 (17-130)
Benzo (b)fluoranthene 97 (29-108) l, Benzo (k)fluoranthene 92 (23-127) l Benzo (a) pyrene 78 (13-126) l Benzo (g, h,1) perylene 42 (10-128) l Benzyl butyl phthalate 102 (10-152) bis (2-Chloroethyl) ether 82 (29-103) bis (2-Chloroethoxy) methane 87 (29-130) g l
bis (2-Chloroisopropyl) ether 70 (19-150) i bis (2-Ethylhexyl) phthalate 103 (12-145) 4-Bromophenyl phenyl ether 88 (32-128) 2-Chloronaphthalene 82 (27-125) 4-Chlorophenyl phenyl ether 87 (33-131)
Chrysene 93 (20-138)
Dibenzo (a, h) anthracene 52 (18-116)
Di, u'atyl phthalate 94 (24-126) 1,2 - -4 t hlorobenzene 72 (28-103) 1,3-La.hlorobenzene 68 (31-97)
?
1,4-Dichlorobenzene 71 (33-90) 3,3'-Dichlorobenzidine 79 (10-139)
Diethyl phthalate 84 (27-110)
Dimethyl phthalate 59 (10-101) 2,4-Dinitrotoluene 89 (37-124) 2,6-Dinitrotoluene 85 (23-130)
Di-n-octyl phthalate 140 (31-110)
Fluoranthene 97 (26-123)
Fluorene 89 (32-122)
Hexachlorobenzene 83 (34-129)
Hexachlorobutadiene 73 (31-109)
Hexachloroethane 63 (32-95) rJ Indeno (1,2,3-cd) pyrene 49 (13-127)
Isophorone 94 (19-133)
Naphthalene 79 (32-111)
Nitrobenzene 83 (34-114)
N-Nitrosodi-n-propylamine 84 (10-230)
Phenanthrene 85 (30-120) i 1
~
t _
l
f Qhanterra Es2snronmental 8erVN'e5 MATRIZ SPIKE REPORT QC BATCH:
5175008 WO #:
A55LQ LAB #: A5F220034-001 S PREPARATION DATE:
6/24/95 MATRIX: WATER DATE ANALYZED:
7/01/95
- - - - - - - - - - - - - - - - - GC/MS Semi-volatiles l
1 SPIKE PERCENT Q/C COMPOUND RECOVERY LIMITS Pyrene 95 (15-185)
)
,j 1,2,4-Trichlorobenzene 75 (40-133) 4-Chloro-3-methylphenol 95 (21-120) 2-Chlorophenol 78 (10-134) 2,4-Dichlorophenol 88 (34-100) 2,4-Dimethylphenol 54 (11-78) 2,4-Dinitrophenol 9.5 (10-114) 4,6-Dinitro-18 (10-181) 2-methylphenol 2-Nitrophenol 61 (19-107) 4-Nitrophenol 100 (10-144)
Pentachlorophenol 75 (10-122)
Phenol 81 (10-107) 2,4,6-Trichlorophenol 96 (18-118) 1 l
- }J Calculations are performed before roundmg to avoid round-off errors in calculaaed resuks
O&M
~
Environinental Senices NATRIX SPIKE REPORT
' l
')
QC BATCH:
5142064 NO #:
A4LM1 LAB #: ASE190007-001 S PREPARATION DATE:
5/21/95 MATRIX: WATER DATE ANALYZED:
5/31/95 l
l l
l l
.................. GC Semi-Volatiles - - - - - -
SPIKE l
PERCENT Q/C W UND RECOVERY LIMITS l
Aldrin 104 (54-120) l[j alpha-BHC 96 (37-134) l beta-BHC 87 (17-147) delta-BHC 114 (19-140) gamma-BHC (Lindane) 90 (48-135) l 4,4'-DDD 114 (31-141) 4,4'-DDE 110 (30-145) 4,4'-DDT 116 (48-154)
Dieldrin 100 (54-143)
Endosulfan I 100 (45-153)
Endosulfan II 115 (10-202)
Endosulfan sulfate 115 (26-144) i.
Endrin 104 (64-142)
Heptachlor 102 (56-158) i T Heptachlor epoxide 112 (50-140)
!i.
t L
Le I;
L.
- 3
A I 13 1
l l,,
I e e--
1 Calculanons are performal trefore rounding to avoid roundeff errors in cakulased resuks l
Q%:nterra Environmental Services MATRIZ SPIKE REPORT 1
C05VP LAB # A5G110107-007 S PREPARATION DATE:
7/24/95 NATRIX: WATER DATE ANALYZED:
7/25/95 I
- Phenolics - - - - - - - - - -
SPIKE SPIKE / DUP PERCENT PERCE!fr Q/C RPD COMPOUND RECOVERY RECOVERY LIMITS RPD-LIMIT Phenolics 64 59 (31-142) 8.0 (0-54)
- i s*
M r.
l i
i i
k-1 1
t--
j I'
t4
- 2
.$J t'
i Calculations are perfonned before soundag to avoid round4ff errors it. calcuisted resuha 1
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Date / Time Received by: (Signature)
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Date / Time Received by: (Signature)
Relinquished by: (Signature)
Date / Time Received by: (Sigrature)
Retinquished by- (Sqnature)
Date / Time R
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Date / Time Remarks
(
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B1sd U w m 7-74S~ 5b0f Distribution Original Accompanies Shipment. Copy retumed with Report.
-