ML20073H591

From kanterella
Jump to navigation Jump to search
TU Electric Comanche Peak Steam Electric Station Radiological Environ Monitoring Program 1989 Annual Rept
ML20073H591
Person / Time
Site: Comanche Peak Luminant icon.png
Issue date: 12/31/1989
From:
TELEDYNE ISOTOPES
To:
Shared Package
ML20073H577 List:
References
NUDOCS 9105070187
Download: ML20073H591 (93)


Text

{{#Wiki_filter:_ _ _ _ _ . _-. g .- i I I I I I I APPENDIX G REMP 1989 ANNUAL REPORT D I I I I I I g a i { c-1  ; j' ja2'Z8a83848886

1 l WT5:1 AWNE ISOTOPES l T U ELECTRIC COMANCHE PEAK STEAM ELECTRIC STATION l RADIOLOGICAL ENVIRONMENTAL MON!TORING PROGRAM 1989 ANNUAL REPORT I l I i 1 Prepared by l i l l l I 1 i !I l I TELEDYNE ISOTOPES l 50 Van Buren Avenue l Westwood, NJ 07675 i

I I TABLE OF CONTENTS SECTION TITLE PAGE I 1. INTR 00VCT10N.............................................. 1 A. Si te and St ati on Descri pti on. . . . . . . . . . . . . . . . . . . . . . . . . . 2 B. Objectives and Ove rvi ew of the. . . . . . . . . . . . . . . . . . . . . . . . 2 CPSES Monitoring Program

11. PROGRAM DESCRIPT10N....................................... 5 111. SAMPLING METHODS AND PROCEDURES........................... 6 A. D i re ct R ad i a t i on . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6 B. Ai r Particul ates / Ai r Iodi ne. . . . . . . . . . . . . . . . . . . . . . . . . . . 7 C. Milk.................................................. 7
o. water................................................. 8 g

E. Fish..................................................8 F. S h o r e l i n e S e d i me n t . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9 G. Vegetables............................................9 1 IV.

SUMMARY

AND DISCUSSION OF 1988'........................... 10 ANALYTICAL RESULTS I A. Direct Radiati0n..................................... 12 B. Ai r Pa rt i cul at es /Ai r Iodi ne. . . . . . . . . . . . . . . . . . . . . . . . . . 13 C. Milk................................................. 13

0. Water................................................ 14 E. Fish.................................................15 F. S h o r e l i ne S e d i me n t . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 15 G. Vegetation............................ .............. 16 I a

I I V. C O N C L U S 10 N S . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 17 VI. R E F E R E N C E S . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 19 Vll. D A T A T A B L E S . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . , 21 I I APPENDICES APPENDIX A E PA C r os s Ch ec k Prog r am . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5 9 APPENDIX B Synoosis of Ar,alytical Procedures........................ 63 APPENDIX C Exceptions to the 19P REMP..............................73 APPENDIX D Exceeded Reporting Levels................................,78 APPENDIX E Land Use Census.......................................... 80 I 1 i i I I I I I I l ni

I LIST OF TABLES TABLE TITLE PAGE 1 CP S E S Radi ol ogi cal Envi rontae nt a l . . . . . . . . . . . . . . . . . . . . . . . . . 22 Monitoring Program 2 Di rect Radi ati on - Thermolumi nescent. . . . . . . . . . . . . . . . . . . . . 24 Dosimet ry 3 Ai rborne Iodi ne-131 i n Charcoal Ca rt ridges. . . . . . . . . . . . . . 26 4 Gros s Beta i n Ai r Pa rticul ate Filters. . . . . . . . . . . . . . . . . . . . 29 5 Gamma Emi tters i n Ai r Parti cul ate Fi l ters. . . . . . . . . . . . . . . . 32 6 l o d i n e - 131 i n M 1 1 k . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3 4 4 7 Gamma Emitters in Milk................................... 35 8 Gross Beta in Ground and Drinking Water.................. 37 9 Gamma Emitters in Ground and Orinking Water.............. 38 10 Iodi ne-131 i n Ground and Dri nki ng Water. . . . . . . . . . . . . . . . . . 40 11 Tri tium i n Ground and Drink i ng Water. . . . . . . . . . . . . . . . . . . . . 41 12 Gros s Beta i n Water-Su rf ace /Dri nk i ng. . . . . . . . . . . . . . . . . . . . . 42 13 Gamma Emitters in Water-Surface Drinking................. 43 14 Iodi ne-131 i n Water-Surf ace Ori nk i ng. . . . . . . . . . . . . . . . . . . . 45 I 15 Tri tium i n Wate r-Su rf ace 0ri nking. . . . . . . . . . . . . . . . . . . . . . . . 46 16 Gamma Emitters in Surface Water.......................... 47 17 Iodi ne-131 i n Su rf ace Wa te r. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 49 18 Tri ti um i n Su r f ace Wa te r. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 50

  '                    Gamma Emitters in Fish...................................                                                    51 19 20          Gar una Emi t t e rs i n S edi me n t . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5 2
    .      21           Gamma Emitters in Vegetation.............................                                                   53 22           Summa ry of Data for the Comanche Peak SES. . . . . . . . . . . . . . . . 55 Radiological Environmental Moriitoring Program-Het Ftt9 I                                                                                                               C% e #10 iy
  .4.-A4.,.41M'ahp3 g AQ A% ,,iegwa -     4mg 44uA--      3.g.me,h w - - Ams.ugm g wm h wh A se eM. Ai.a m.

d !I e i j l i 4 a l l !I l d l 4 1 lI 4 INTRODUCTION i [ l l I i l I I I ii I

        .I 1

I I. INTRODUCTION ine Radiological E nvironment al Monitorina Proaram for the Comanene l Peak Steam Electric Station was conducted under contract with T U Electric, inis report covers the period f rom January 1, 1989 through December H, f 1969 and summarizes the results of measurements and analyses of data obtaina from samples collected durina this inserval. I Site and Station Description A. Comanchet Peak Steam Electric Station consists of two PWR units, each desi ned to operate at a power level of about 1150 megawatts (electrical). The station is located on Sauaw Creek Reservoir in Somervell County about 40 miles southwest of Fort Worth, Texas. Unit I received a low power cperating license february 6, 1990. Initial criticality of Unit 1 is espected in April, 1990. l B. Objectives and Overview of the CPSES Monitoring Program United States Nuclear Reguletory Comission (USNRC) regulations require th at nuclear power plants be designed, constructed, and operated to keep i levels of radioactive material in effluents to unrestricted areas as low as reasonably achievable (ALARA) (10 CFR 50.34). 70 assure that these criteria are met, e&ch license authorizing reactor operation includes technical specifications (10 CFR 50.36a) governino the release of radioactive effluents. I In-plant monitoring will be used to assure that these predetermined l release limits are not exceeded. and undefined processes wnich might allow undue accumulation of radioactivity However, as a precaution against unexpected in any sector of man's environment, a program for monitoring the plant environs is also included. lI j

                    - _ _ . - _ - -  -   . _ _ _ -   - - - - _ .   .- ._~ _ _ - .       __ . . _ .

I I I Samplinq locations were selected on the basis of local ecolocy, meter-olooy, physical characteristics of the recion, and demoaraphic and land use features of the site vicinity. The preoperational program was designed on the basis of the USNRC Branch Technical Position on radiolootcal environ-mental monitoring issued by the Radiological Assessment Branch, Revision 1 (November 1979)(1), the CPSES Technical Specifications, and the CPSES Of fsite Dose Calculation Manual (ODCM). In 1989 the radiological monitoring program iricluded the measurement of ambient gamma radiation by thermoluminescent dosimetry; the determination of gamma emitters in vegetation, sediment and fish; the determination of air-borne cross beta, gamma emitters, and iodine-131; the measurement of tritium and gamma emitters in surf ace water; the measurement of gross beta, tritium and gamma emitters in ground water; the measurement of gross beta, tritium, 1-131 and gamma emitters in drinking water; and the determination of gamma emitters and 1-131 in milk. i Samples were collected by CPSES Environmental Personnel. Sample ana-lyses were performed by Teledyne isotopes under contract. l I I 3

1 I I I o The regulations governing the quantities of radioactivity in reactor effluents allow nuclear power plants to contribute, at most, only a few percent increase above normal background radioactivity. Background levels at any one location are not constant but vary with time as they are influenced by external events such as cosmic ray bombardment, weapons test f allout, and seasonal variations. These levels also can vary spatially within relatively short distances reflecting variations in geological composition. Because of these spatial and temporal variations, the radiological surveys of the plant environs are divided into preoperational and operational phases. The pre-operational phase of the program of sampling and measuring radioactivity in various media permits a general characterization of the radiation levels and concentrations prevailing prior to plant operation along with an indica-tion of the degree of natural variation to be expected. The operational phase of the program obtains data which, when considered along with the data obtained in the preoperational phase, assist in the evaluation of the radio-logical impact of plant operation. l Implementation of the preoperational monitoring program fulfills the following objectives:

1. Evaluation of procedures, equipment and techniques.
2. Identification of potentially important pathways to be monitored after the plant is in operation.

I 3. Measurement of background levels and their variations along poten-tially important pathways in the area surrounding the plant. 4 Provision of baseline data for statistical comparison with future operational analytical results. I I 4

,+Adme e AM, w hMAh m MAM ehha4=ee - '"   - --          "      "^ -
                                                                                        =m- - - -

iI 4 i i l LI I e I l i I !I I PROGRAM DESCRIPTIONS lI I I I I I s

                                                                                                                         !!. PROGRAM OESCRIPTION Seventy four (74) locations aitnin a radius of 15 miles from the CPSES site were included in the monitoring prooram for 1989.                                                                     The number and I

location of monitoring ooints were oetermined by considering the locations where the highest of f. site environment al Concentrations have been preciCted i from plant effluent source terms, site hydrology, and site meterological l l conditions. Cther factors considereo were aDolicable regulations, population distribution, ease of access to sampling stations, availability of s ampl es at desired locations, security and future program integrity. The preoperational environmental radiological program for Comanche Peak is summarized in Table 1. Figures 1 and 2 show the locations of the various s ampling points. l 111. SAMPLING METHODS AND PROCEDURES To derive meaningf ul and useful data from the Radiological Environmentc' Monitoring Program, sampling methods and procedures are required which will provide samples representative of potential pathways of the area. During the preoperational phase of the program, samples are collected and analyzed not only to obtain background radiological levels, but at the same time to acquire experience with the sampling methodology and procedural format dictated by site specific requirements. A. Direct Radiation Thermoluminescent dosimeters (TL0s) were used to determine tne direct (ambient) radiation levels at monitoring points. Sampling locations were chosen according to the criteria given in the USNRC Branch Technical Position on Radiological Monitoring (Revision 1, November 1979),(1) The area arouno the station was divided into 16 radial sectors of 221/2 degrees each. TL0s were placed in 011 sectors. TL0s were located in two rings around the station. An inner ring was located at the site boundary and an outer ring 6

I

   .as located at a distance of 4 to 6 miles from the station.                                    Eleven aadi.

tional TL0s were located at points of special interest, including two control l oc ations . For routina TLD measurements, two cosimeters of CaSO4: Dy in teflon cards were deployed at each selected locatian. One set of dosimeters nas exchanced on a quarterly basis and the second set wa', exenanced on an annual basis. Additional sets of dosimeters were snipped with each excnange cycle to serve as in transit controls. For routine excnances, TLDs were shippeo by Federal Express. Individual dosimeters were calibrated by exposure to an accurately known radiation field f rom a calibrated Cs-137 source. B. Air Particulates/ Air lodine Air particulate and air iodine samples were collected f rom the 8 locations described in Table 1. tio samples were collected from St at ions N-2.2, E-0.5, SE 3.85. W-2 and NNW-4.6, which had been included in the sampling program in previous years. These locations were deleted as a part of the transition to the operational monitoring program reouired by the CPSES ODCM. Each air particulate sample was collected by dr awing air througn a 47-millimeter di ameter glass-fiber filter. Air iodine was collected by drawing air through a TEDA impregnated charcoal cartridge /(Scott NO 605018-

03) which was connected in series behind the filter. The filters ano enar-coal cartridges were collected weekly by CPSES staff, in the laboratory, air particulate filters were analyzed for gross beta activity and were composited quarterly for analysis by gamma spectrometry. Charcoal cartridges were analyzed for iodine-131.

C. Milk Milk samples were collected by CPSES staff monthly except for May through October when samples were collected bimonthly. There were two 1 7

, I { principal milk sampling locations; one inoicator location, SSE 2.2 and one control location, SW-13.5. Upon arrival at the laboratory, the milk samples were promptly analyzed for gamma emitters and for 1-131 by radiochemistry. J. Water Tne CPSES staff collected water f rom 11 locations. Surf ace water was collected at f our locations (N-19.3, ESE-1.4, h-1. 5 a nd NE- 7. 4 ) . Surface-drinting water was collected at two locations (N 9.9 and NNW-C.1). Location h-l.5 provices sampics representative of S uaw Creek Reservoir surface water at a location beyond significant influence of the plant discharge. Location ESE-1.4 provides samples representative of discharges f rom Squaw Creek Reservoir, both down Squaw Cretek and to Lake Granbury via the return line. Location k-7.4 provides samples of Lake Granbury surf ace water down stream of the discharge of the return line from Squaw Creek Reservoir. There are five groundwater locations (SSE 4.6, W 1.2, WSW 0.1, N-1.45 and N-9.8. Samples from these locations were analyzed pursuant to the 00Cl1 drinking water requirements through 04/24/89. Af ter this date, the analysis for drinking water was climinated and the samples were analyzed only for gamma emitters and tritium. This change was made as part of the transition to the operational program described by the 00Cli. 00CM Table 3.1, Note (5) states that groundwater supplies in the site area are not af fected by plant effluents and are sampled only to provide confirmation that groundwater is not af f ected by plant discharges. All samples were shipped back to the laboratory and analyzed by gamma spectrometry and composited by location quarterly for tritium analysis. Drinking water samples were also analyzed monthly for gross beta, gamma isotopic and bi-monthly for iodine -131. E. Fish Eleven fish samples were collected at two locations for the 1989 I e

, I prooram. An area 2.0 miles east northeast of the site in Squaw Creek Reservoir was chosen as the indicator location, and a location at Lake Granbury was chosen as a control locStion, fish sampling was conducted in April and October for Station NNE 8(F2) and April and September for Station ENE 2(F1). Fish were collected by CPSES staff. Available edible species were gutted at the time of collection. Samples were then froren and shipped to the laboratory for analysis. Fish were filleted in the laboratory and the edible portion I analyzed by gamma spectrometry. F. Shoreline Sediment Shoreline sediment samples were collected in February and Augus' ' rom Squaw Creek Reservoir, the indicator location. This is in an area of potential recreational usage, 1.0 mile north-northeast of the station. Samples were also collected from Lake Granbury, the control location, on the same days. Samples were also collected from Lake Granbury downstream of the discharge of the return line from Squaw Creek Reservior on the same dates. CPSES staff collected the sediment samples and thiDped them to the laboratory for analysis by gamma spectrometry. G. Food Products and Broadleaf Vegetation During the period May through December, forty-seven samples were col-lected f rom five sampling locations. Food products were collected f rom a control (13.5 miles southwest) and two indicator stations. A total of ten different types of food products were collected during this Samplino period. Broadleaf vegetation was collected from the control location and two indicator ste', ions near the site boundary, Collection of broadleaf veget a-tion started in May, 1989, as part of the transition to the operational program required by the ODCM. Broadleaf samples consisted primarily of available tree leaves; if tree leaves were unavailable, native grasses and weeds were substituted. I e

I iI I I I I I I I

SUMMARY

AND DISCUSSION OF 1989 ANALYTICAL RESULTS I I I I I I I I I 10

I I . I IV.

SUMMARY

AND DISCUSSION OF 1989 ANALYTICAL RESULTS I Data from the radiological analyses of envi ronment al media collected during the report period are tabulated and discussed below. Tne procedures and specifications followed in the laboratories for these analyses are as required in the Teledyne isotopes Quality Assurance manual, !WL-0032-395 and are detailed in Teledyne isotopes Analytical Procedures manual. Radiological analyses of environmental media characteristically approach and frequently f all below the detection limits of state-of-the-art measure-ment methods.(2) The use of "<" in the data tables symbolizes that the result is less than the lower limit of detection (LLD) as defined in Appendix B. "ND" (Not Detected) is used periodically in the tables presenting gamma analysis results for various media. It primarily appears under the "Others" column, and indicates that no other detectable gamma emitting nuclides were identified. The Teledyne Isotopes analytical methods meet the LLO require-ments addressed in the CPSES Offsite Dose Calculation Manual. I Tables 2 through 21 give the radioanalytical results for individual s ampl es. A statistical summary of the results appears in Table 22. The reported averages are based only on concentrations above the limit of detec-tion. In Table 22, the fraction (f) of the total number of analyses with detectable activity follows in parentheses. Also given in parentheses are the minimum and maximum values of detectable activity during the report period. I 4 11

I I A. Direct Radiation Envi ronmental radiation dose rates determined by thermoluminescent dosimeters (TLDs) are given in Table 2. TLD badges cf four readout areas each were deployed at each location on quarterly and annual cycles. The mean values of four readings (corrected individually for response to a known dose and for in-transit exposure) are reported. A statistical summary of the 1989 data is included in Table 22. For the quarterly analyses the average activity of the control locations was 0.16 mR/ day with a range of 0.12 to 0.18 mR/ day. The average of the indicator locations for the quarterly samples was 0.16 mR/ day with a range of 0.11 to 0.22 mR/ day. For the annual samples: The activity for the control samples was 0.13 mR/ day for each. The indicator locations had an average of 0.13 mR/ day with a range of 0.11 to 0.17 mR/ day. Oakley(3) calculates an ionizing radiation dose equivalent of 82.2 mR/ year for Fort Worth including a terrestrial component of 45.6 mR/ year and an ionizing cosmic ray component of 36.6 mR/ year (excludes neutron compo-nent). Since Oakley's values represent averages covering wide geographical I areas, the measurce ambient radiation average of 58 mR/ year for the immediate locale of CPSES is not inconsistent with Oakley's observations. Significant variations occur between geographical areas as a result of geological com-position and altitude differences. Temporal variations result from changes in cosmic ray intensity, local human activities, and factors such as ground cover and soil moisture. I I 12

I I B. Air Particulates/ Air lodine A total of 411 charcoal cartridges were analyzed for airborne iodine-131 by gamma spectrometry. No iodine-131 was detected at any of the samplina stations. Results of these measurements are presented in Table 3. A total of 410 air particulate filters were collected and analyzed for gross beta activity. For the year of 1989 the average gross beta I activity for the control location was 0.024 pCi/m3 with a range from 0.0097 to 0.051 pct /m3 For the eleven indicator locations the yearly average was 0.024 pC1/m3 with a range f rom 0.0053 co 0.055 pC1/m3 The gross beta analysis data are presented in Table 4 Air filters were composited quarterly and then analyzed by gamma spectrometry. The gamma spectrometry data is presented in Table 5. Cosmogenic beryllium-7 was detected in all 32 samples while potassium-40, a naturally occurring nuclide, was measured in four samples. The average beryllium-7 activity for the control location was 0.071 pCi/m3 with a range of 0.066 to 0.081 pCi/m3 For the indicator locations, the average beryllium-7 activity was 0.072 pCi/m3 with a range of 0.060 to 0.099 pCi/m3 Naturally occurring potassium-40 was not detected at the control I location. The average potassium 40 activity for the indicator locations nas 0.012 pCi/m3 with a range of 0.0093 to 0.015 pC1/m3 C. Milk There were a total of 38 milk samples collected in 1989; 19 from the indicator location and 19 from the control location. All samples were analyzed for iodine-131 by radiochemistry and for other gamma-emitting isotopes by gamma spectrometry. No iodine-131 was found in any of the milk samples. The lower limits of detection can be found in Table 6, 13

l Results of the gamma spectrometry measurements are cresented in Table l

7. Naturally occurring potassium 40 was detected in all of the milk samples, i

The average activity for the control location was 1379 pCi/l with a range of 1110 to 1560 pCi/1. For the indicator location the average activity was 1298 pCi/l with a range of 1150 to 1510 pCi/l, Cesium-137 was not detected in any of the samples. I D. Water Ground and drinking water simples were collected from five locations during 1989. Samples were analyzed pursuant to drinking water requirements through 04/24/89. Subsequent samples were analyzed only for gamma isotopic and tritium on a quarterly basis, pursuant to the ODCM requirements for , l groundwater. Thirty samples were analyzed f or gamma emitters by gamma i spectrometry. The gamma spectrometry analyses showed no detectable activity above the LLO for all samples, fif ty samples were also analyzed for iodine-131 with no measurable activity. Quarterly composites for each s ampling l location were analyzed for tritium. No tritium was detected. Twenty-five ground and drinking water samples were analyzed for gross beta; 16 indicator locations had measurable activity with aa average of 7.0 pC1/1 and a range of 1.0 to 10 pC1/l . All five of the control samples had measurable gross beta activity with an average of 3.0 pCi/l and a range of 2.2 to 3.9 pCi/1. Results of these analyses are contained in Table 8, 9, 10 and 11 respec-tively. Surf ace water was sampled from four locations during 1989. Samples from these locations were analyzed pursuant to drinking water requirements through 04/24/89. Subsequent samples were analyzed only for gamma isotopic on a monthly basis and tritium composite on a quarterly basis, per the 00CM requirements for drinking water. Fif ty-two samples were analyzed by gamma spectrometry. No radioactivity was detected above the lower level of l detection. Sixteen samples were analyzed for iodine-131, results were below 14

the lower limit of detection. Sixteen composited surf ace water samples were analyzed for tritium and all were below the lower level of detection. Results are presented in Tables 16, 17 and 18 respectively. Surf ace water-drinkino was collected from two stations. All s amples were analyzed for gamma emitters; results were below the lower lirri t of detection. Thirty samples were analyzed for gross beta activity. The indicator station had an average activity of 16 pCi/l with a range of 13 to 21 pCi/1, The control station had an average activity of 14 oCi/l with a range of 9.0 to 21 pct /l. The quarterly composites for tritium were below the lower limit of detec; ion. lodine-131 analyses by radiochemistry were performed on 54 s amples of surf ace water-drinking. There was no measurable activity. Results of these analyses are contained in Tables 12 15. E. Fish The results of gamma spectrometric analyses of fish samples collected during 1989 are presented in Table 19. A total of eleven samples were analyzed, six from the indicator location ENE-2 and five from the control location NNE-8. Sampling efforts concentrated on tne larger edible species of commercial and/or recreational imoortance. Cesium-137 was detected in one of the samples with an average activity of 13 pC1/kg wet. Naturally occurring potassium-40 was detected in all samples. The  ! average potassium-40 concentration for the six indicator s amples is 3485 pCi/kg wet with a range of 2730 to 4490 pCi/kg wet. The average concen-tration for the control location is 3144 pCi/kg wet with a range of 1960 to 3930 pCi/kg wet. l F. Shoreline Sediments The processes by which radionuclides and stable elements are concen-trated in bottom sediments are complex, involving physiochemical interaction 15 i

I I in the environment between the various organic and inorganic materials f rom the watershed. These interactions can proceed by a myriad of steos in which the elements are absorbed on or displaced from the surf aces of col-lodial particles enriched with Chelating organic materials. Biological action of bacteria and other benthic organisms also contribute to tne con-centration of Certain elements and in the acceleration of the sedimentation process. Results of the gamma isotopic inalyses of the sediments samDiej from the CPSES environment are given in Table 20. For 1989 three locations, one control and two indicators, were sampled semiannually. The average, fraction of detectables, and range of radionuclide concentrations are summarized in Table 22. Gamma emitters found in detectable concentrations were K-40, Pb-212, Ra-226, Bi-214, Pb-214 and Th-228 Be-7 and Cs-137. G. Food Products and Broadleaf Veoetation Results of camma spectrometric analyses of vegetation samples are contained in Table 21. A total of 47 samples were analyzxed from 5 loca-tions. Potassium-40, a naturally occurring isotooe, was found in 47 samoles. The average potassium-40 activity for the control location was 4837 pCi/k1 wet with a range of 896 to 9810 pCi/kg wet. For the indicator locations the average potassium-40 activity was 4959 pC1/kg wet with a range of 1570 to 12300 pC1/kg wet. Naturally occurring beryllium-7 was detected in twenty-one indicator samples with an average activity of 1781 pCi/kg wet; the range was 359 to 5670 pCi/kg wet. Fourteen samples from control station, SW-13.5 were found to have beryllium-7 with an average activity of 1294 pCi/kg (wet) and a range of 225-3120 pCi/kg (wet). Iodine-131, cesium-134 and cesium-137 were below the lower limit of detection in all samples. 16

!,I i

i I I !I l l 1 f

I iI I

CONCLUSIONS 1 I l l lI lI ,I ,I 4 i l I I 17

I I I V. CONCLUSIONS It can be concluded from the levels and fluctuations of radioactivity obtained in envi ronmental samples during 1989, that sensitive indicators of radioactivity for the environment around the CPSES have been selected. The atmospheric environment was sampled for airborne particulate matter, radioiodine, and direct radiation. The terrestrial environment was sampled for milk, ground-drinking water, surf ace-drinking water and food products. The aquatic environment was sampled for surf ace water, fish and shoreline I sediment. The analyses of these samples provided results which were either below the measurement detection limits or were indicative of natural ter-restrial and cosmic ray radiation levels. I I I I I I I I 18

I lI I I I I I I I I REFERENCES I I I I I . I I 19

I eI I I VI. REFERENCES I I 1. V. S. Nuclear Regulatory Commission, "An Acceptable Radiological Environmental Monitoring Program", Radiological Assessment Branch Technical Position, November 1979, Rev. 1 I I 2. National Council on Radiation Protection and Measurements,

           " Environmental Radiation Measurements", NCRP Report No. 50 Washington, D. C., December 27, 1976.

I

3. Oakley, D. C., " Natural Radiation Exposure in the United States",

ORP/SID 721 Of fice of Radiation Programs, U. S. Environmental Protection Agency, Washington, D. C., June 1972. I I I I I ' 20

I I I I I I I I I I DATA TABLES I I I I I I I  ! 21

M M M M M M M M M M M M M M m M M I Ai!L E I (Page 3 of 2) CP5E5 RADIOLOGICAL ENVIRtMeith1 AL *s>41TORIE PhotJtAM - 196's Identification t,y Analptstal Sector and Distance Sampl ing Amber of Frequency (a) holy ses f requem y {a) Media Eo(ations (Miles) C.A inertnelussaex ent (n. 8 Gamme Exposure 43 W-1.45; N-4.4; A 6.5; tes tsetry 15-9.4; ENE-I.1: h*eE-5.65; RE-l.1; 8.E-4.8; E NE-2.5; EME-5.0; E-0.5; E-1.9; E-1.5; E-4.2: E5E-1.4; ESE-4.7; 5E-1.3; 5E-3.85; 5E-4.6; 55E-1.3; 55E-4.4; 55E-4.5; 5-1.5; 5-4.2; 55W-1.1; $5W-4.4; SW-0.9; Su-4.B; 5d-12.3; W5d-1.0; WW-5.35; W5W-7.0; W-I; W-2; W-5.5; Wins-I; WNW-5.0; ecu-6.7; y w-1; m-5.7; m-9.9; , mw-I.35; Nw-4.6 { l j Gross Beta W hs l Air Partialate. 8 09.4 Gamma Spectrometry fiIter (A Mr lodine E-3.5; 55E-4.5 Gammaa spectrometry SW-12.3; Charcoal Cartred pe W w-1.0; bl.45, 5W/W5d-0.95 5/55W-l.2 s.asua 5smtrometry H 4 h-19.3; E SE-I.4; k-1.5 M (d) Surface Mater RE-7.4. e+- 3 ut 5M Ge=w Spettrametry v Growne.ater 5 55E-4.6 W-l.2; WSW-0 I #s- 3 tJ b 9.8; U 2.45. tross seta rt sew -0.l; m-9.9 SM (c ) Mater-surface 2 Gemene Spettronetry H Drink i09 -131  : v4 3 14 9

M M M M M M M m m m m m m M . M TAM E I (Page 2 of 2) CPSES EADIMollCAL EnvlROpe(nTAL peGe:IIOplem fitrapAM - 1988 Idesetif1catten by Sector and Distance Sampling Analyt sc al humber of Fregw w y (a) (Miles) Erequency (a) Analyses Medte tocattens 3 M-9.9; RW -1. hE-7.4 5A 6emma Spectrusertry 5A Sed 6 ment Fish 2 anE-8; ENE-2 SA bamma 'etreusetey 5A f Milk 2 5.u-13.5; SE-2.2 2. M I-13I w.M Pasture season Pasture 5eas. 6eena spectrosetry SM. M Pastore Seas. E-4.2; SW-13.5; E NE-9.0 991 Gamma 5sm t reunet r y m I Food Prodocts 3 m 1-1 31 y h-l.45; Su-l.0; Sw-13.5 M Gemma "sec t rumet r y M Broadleaf 3 3-131 M vegetatton (a) Frequency Codes Are w = ueenl y n = Month!y Q = Guarterly UC = Quarterty Camposite SM = Semimonthly pei = Monthly dortnq availabilsty for harvest 54

  • Scelannual A = Annual (b) Surf ace water samples from 'Awaw Creen Weservoir are suonthly composites of week l y gr an sempics. Samples fruse 1a e t,,a.wmry are monthly (tsmpesttes of mecaly grab samples when take Granbury is recetonag letdown trase 'Avaw Creen Ecserve6r; othermose they are monthly gege semples.

(c) Isrinkinq mater samples are compostte of eet ly grab samples over a 2 =cet per sed nen I-131 analys es as pee t tww 4; etweewsw they are monthly composites of meetly grab samples.

I 2 e O e e e e. A e e e e I

                                                                                                            %                             N N me ap C O O m N N en en ==                                                                                  se N N ew .= .= o e                                         s w                                                                                                                                                                                                        w o                            &. O. O. O. O. O. O. O. 3 0 0 3                                                                 D. O.           O. O. O. O. O. O. O.

3 3

                                                                                                           .%.                           O 3 O 9 O O O O O O O O O O O O O O O O 3 0i e                   e     e        e     e     e        e      e    e      e       e     e     i        e      e       e     e    e     e     e            e            .% a
                                                                                              .= g                                         + + + + + + + + + + + + + + + + + + + + + +

we c. me e Neeneamm eNemeenaom A m mme 4 e seenun m m eneNas w N e wg e a% .Ne. en. . . ==. . . en. , .=. ee. . se. . . . . em.

                                                                                                                                                                                                                                                                                               .a     ==

et m O O O O O O O O. O O O O O O O O O O O 3 D D. ** 3 3 w

                                                                                                           .n                                                                                                                                                                                                        3 I                                                                                                                                      m e w w w w m o w a w N e w ew A a a e m a 3                                   3                  3          3 1
                                                                                                                  .                     D. o. O. O. O. O. O. O. O.                                                           O. O. O. O.                           O. O.         D.           O. C.                .e I

w4 O D D C 3 O O O O O O O O O O O O 3 O O & 3 e e e e e e O. e e e e e e e e e e n O. e e e a ae + + + + + + + + + + + + + + + + + + + + + + e.

                                                                                            .s N                                       e no e 6 4                                        % e 4 ee O 4 w e se in oc A %                                                                  .n 4 A                        &

se og ,e e=

                                                                                                                                                             ==. ==. .

em =

                                                                                                                                                                                         *e.

me sie. me. N. en se en se .e en

                                                                                                                                               .                                  .                   .                          . me. . .                es. . ese.se. =. .a. en.                       .          4, e

O O O O O O O O O O O O O O O O O O O O O 3

                                                                                                                                                                                                                                                                                                                     .e e

e C 3 e m% I e we

                                                                                           == O me N == N m                                an.

a% *ee N N ** m N em om N w as a N m oN N m m es me @ e aO C. O. O. O. O. O. O. O. O. O. O. O. O. O. O. O. O. O. O. O. . O. ,,,, ID. Oe O O O O O O O O O O O O O O O O O O, O O o b ei e e e e O. e e e O. e e e e e e e e e e e e I e* W R ec e=. %

                                                                                                                                        + + + + + + + + + e + + + + + e + + + + + +                                                                                                                               0, a e*                                              am                                         eN e N w @ e e e                                                                            w%             ,e w e es           .e a w in e 4                              e-
                                                                                                                                                                                                                     .e O

se ta 0

  • OO c%

wo se. me. . .

                                                                                                                                                                   .ee se en. ese.re. en. se.                =. .e     . .      em.         . ese.en. . en. see. . .

me se en. me 4 O9 == O O O O O O O O O O O O O O O O O O O O O O 9 Da s g M ed en s

                                               #                                                                                                                                                                                                                                                                    +

W= 4N W & z ee P *

                   *=                    om    &+                                                         in                                                                                                                                                                                                      en N                     W     $                                                         %

I y w

  • a% gm .e w me ed g9 es 'JD w m os e m 80 m N O N O m w aD es % O N se == O O ee C O N a= O N s= w O *** O O N m N O er.
                             >                a%                                           e                                                                                                                                                                                                                     %

w en W E Om e .Oe O. O. O. O. O. O. O. O. O. O. O. O. O. O. O. O. O. O. O. O. O. d. w e and G$ 0 e O Oe Oe O O O O O e O O O O O O O O O O O O O O O m tes =J .ans b op e e e e a e e e e e e e e e e e e e e  % 4 we w

  • e
                                               @S                                                        60                            + + + + + + + + + + + + + + + + + + + + + +                                                                                                                               am a*                                         O%                                                                                                                                                                                                                     o I

e= 4 b O n= mM 9 @ e e @ d e @ d N @ @ ene e h e W % % @ ee n W e

                   =r                    w          e                                     == 0                                                             .= *=e                                                                                                           me                   .               e
                             >=          q                                                  3%                                       ==s. . .                              ese.em.en. ee. ese.se. N. ee. .=. N. ee. e o.em.me.                                                      e. se.       . em.          g e aen.

nad *N O O O O O O O O O O O O O O O O O O O O O O  % Eb 8s O 2 be en see *** b  % I 5 en sm  % v e C \ s

  • 4 9 8 a: e e o j Om WW b W tad % 9=

es >m e un h e e U W mO O en C a O e4 O N N == N O N == m me

  • N ** N O 9 6 4% -=

b 38% O. O. O. O. O. O. O. O. O. O. O. O. O. O. O. O. O. O. O. O. O. &

                                              =

O cc O O O O O O O O O O O O O O O O O O O O O

  • e e e e e e e e e e e e e e e e e e e e e e e.

Ce * + + + + + + + + + + + + + + + + + + + + me & Os e m % % e e N e= a me O N e e en eA N 40 I Ww we es ao .e see em a. i ese e l wo e . em. . em. mo. . en. N. es, em.N. N. se. en. es. en. se. . .e. en. l @% C O O O O O O e O O O O O O O O O O O O O O C w = l O l e t 9 i 3 e :D. 80 . e W% e e b G %ee ee.d O w *= N N N me we w m me en se me me me me me en N em en se a m% = ag e C. O. O. O. O. O. O. O. O. O. O. O. O. O. O. O. O. O. O. O. m. s Do O O O O O O O O O O O O O O O O O O O O e se 3e e e e e e e e e s e e e e e o e e e e e is e= m * * * * * * * * + + + + + + + + + + + + c

e. e e --

MN 4 == 4 % A e c Q O N w C O d e 8D N N 4 c0 m

  • Wm me ee .= e 3 es c se. N. se. en. . en. we. N. N. se. em.N. N. ese. . se. se. . . se. c w%

se O O O O O O O 9 O O O O O O O O O e O O O O e e E O S

                                                                                                                                                                                                                                                                                                            -    0
  • K e * ==

w e M I f2 .se e. O e . d. A. . A. m c0 4 M. e. e 3

  • w w me e e%. e. N en see w e == w w
e. . . ee. e. e e se e w e e a. @ e. e N. e e see m w e e e 3 as
                                                                                                          %                        est w @ @                                      4.4   .eJ       e      e    heJ 4ed O Sue N w Led teme                               e e e           bed had beuf        ane  **

en e e a e 2 E gnJ na 3 E e e e e A @ ted w na,A A A @ em 3

                                                                                                      @                             E 9 $ E 8 8 E S sad see sen kee te6 see see ke6 @ @ @ h aD                                                                                                             e    2 l

l 24 1

I . I

'I w     m e m                                           .A     e m 30                                                 .A    m               N N                                 %       > e i

O O O O N O O 3 3 N == c O = cO -e == 3 O O

                                                                                                                           %                                      *.                             3                                                                                                       3
                                                                                                                       .,, se    D. O. O.                             . O. O. O.                        C. C. O.                            O. O. O. O. O. O. O.                                              O. O.

4O O O O O O O O O O C O O O O O O O O O O

m. e e e e e e e e e e e e e e e e e e e e O.

2e a up + + + + + + + + + + + + + + + + + + * *

  • g% N e N w ses m einao es. m we. N m emN == mees m M N N a N w m
                                                                                                                                                                                                                                              =. ee, ==.en me           . ..Nus.ese. see ese em O         .         se.                    .                     .   =.                            me.         .                                                              . en. om           .

D C. O O 3. 0. 0 9 O. O O 3 O 3 D D 3 3 O O 3 O m N e m e A w w A 4 w m w w m en w w .A e w 3 3 @

                                                                                                                             .                 O. O. O. O.                                  . O. O. O. O. O. O.                                             O. O. O. O.                         O. O. O. O.

w9 O O O C C O O 3 O C C 0 0 0 D 0 D D O I J n s e e e e e e e e a e e e e e e e e O. O. 4 en a + + + + + + + + + + + + + + + + + + + + + mo N + + A N 4 a w w w 4 4 a m o N

                                                                                                                                               .e e ee                                                   e.

an e a+ e -.

                                                                                                                                                                                .= em em es                                  se
                                                                                                                                                                                                                                    ==. ==.
                                                                                                                                                                                                                                                    ==
                                                                                                                                                                                                                                                        .      =. em. e=.e.          es      em we
                                                                                                                                                                                                                                                                                             . . .             se.

em O O O 3 O O O O O O O O O O O O C O O 3 2 I C e I 5%  % N w tas e

                                                                                                                      *= 0 m

0 N O ee ** m M N en N seu m O .= N en N N me O N m% O. O. O. O. O. O. O. O. O. O. O. O. O. O. O. O. O. O. 3 O.

                                                                                                                      *=        0 0 C O O O O O O O O O O O O O O O O O O h       2O          e       e      e                 e       e      e      e       e           e                 e       e       e      e       e      e        e           e       e      e       e      e b

os Oe e + + + + + + + + + + + + + + + + + + + 'e e a 4 2 .1c w w e w e h w e N .e m N 4 e 4 y e. % am em me A. en e me em N. me me m em N.

                                                                                                                                                                                                                                                                                       .        .e .e         ee      .e
                                                                                                       =

C e,. . . . . . . . . e. . se. . . . se. . =. =. . . ea 30 0 C O O O O O O O. O O O O O O O O O O O O

                                                                                                        *=    0 . O%

W 29 es. O en en e se We e W eN es u a en e

                                                                                                       ==     es +
  • W $ m N W w
  • A W
                                                                                 ==                     .g    gg      gN       ac                           m p                                                              c                              A N                        go N                     en.                    or                    w      a4     ene m      O      N *= 0 0 ==                                     N N O O m N N O O N Q ea se me se O                     *=                          a. %      *= Q     C                                                O a                                       v r ea                               er N
  • O. O. O. O. O. O. O. O. O. O. O. O. O. O. O. O. O. O. O.

a N w a SS 4O O O O O O O O O O* O* *C D Q O O O O eOe O O O ma e inn b 5 *= e e e e e a e e e e e e e e a e e neJ w *= tc #e + + + + + + + + + + + + + + + + + + + + + e.r , w e s= e I et O e. O c0 m@ e= co e=N N 4 cc 4 N 10 a e@ N N e d N em e ao ek ed en su % e.s .=4 ce em en pe. en. me.en. . ==. em. +=. en. es. em. os. w e= ec 6 en om m . . em. . e. . se. e ned = 20 0 0 C O O O O O O O O O O O O O O O O O O

e. g3 -%

O We N w =0 0 2 e. en I w e a = 4 13 E e D a m w er a0 es one % P N N N th Pim as IP w >m I O as == ==e o O O em O *= N == 0 N N O a= 0 N = en ed er O 6 q% O. O. O. O. O. O. O. O. O. O. O. O. O. O. O. O. O. O. O. O. O.

                                                                                                            =        UN        O O O O O O O O O O O O O O O O O O O O O Q                    e       a      e                 e       e      e     e        e          e                  e      e        e      e       a      e e                  e       e      i      e       a O c.       + + + + + + + + + + + + + + + + + + + + +

Qe W3 te @ @ N O to N EO 10 0 2 e en 4 to A e @ @ M N cp I C% se me me ese . oss es .no e. e= ese se yw en. me.ame. . . . . . amo. e.e. . .=. . . se. . . ==. . . et. wo O O O O O O O O O O O O O O O O O O O O O e% w O e 40 st w w med O a N == .* es. == ** me *= N as me em en ee me em N O se em

                                                                                                                     *= %

sv O. O. O. O. O. O. O. O. O. O. O. O. O. O. O. O. O. O. O. O. O. et C C O O O O O O O O O O O O O O O O O O O O D e e e e e e e e e e e e e e e e e e e e e e c em o e + + + + + + + + + + + + + + + + + + +

                                                                                                                     >= %      4                     N e @ N                                                              es en e A A A A A 4 e @ 3D en m              .e. .d                           a=     ==    e=       N. .A      *                                         ==                                          e=

uO ee. e. en. . . . e. e. se. me. m. en. en. en. .=. em. I

                                                                                                                     =%        O O O O O O O O O O O O O O O O O O O O O se. em O

c in C M se. e. en. op m. m. e. I e N. N p e we mN em e . en a es en c4 e . s= w me a e e O w .Ne e e e A. e e e me c EP e e e == w 3 3 9 e e 3 3 3 est N @ 3 3 3 e e e 1 3 es e e io e 3 3 3 e e e e e e E

  • R 3 3 3 5 E eA M A M A M M M 3 3 3 3 3 3 3 3 3 5 E E E E 25

l I lI I . e.' __m_

                                                                    #. O. O. E.

eeer

                                                                                   ,'._O.,.,~.

cooO

                                                                                                  .U.~ S_ 0,^. ,.

cameo O. . . O. ocoe a v v vv v vvv v vvvv I v v vv

                                                            .       ESEE            E6B2           33eBe               265.

a dddb y vvv dddd v v vv ddddd vvvv v dddd vvw y I sesee I e w

                                                                     $22, dddd v vvv 25ee vv v v ddddd vvvvv
                                                                                                                       ,$,c
                                                                                                                       $dOd vvv v I         E
3 E

9 i $353 $$3B XUSBB E658 I g 557

e: -

5 dpis side $ddds sids

         . 65 $

1  % I

          . O                     -                 r e.

yea 5 a ** 8a ** 8 8.**

  • I.' e m ym83
  • 2 07 kmmE m mm Em see; g;

ec-84 na =ese seee eee I

  • r_m
         ~

3 .

                -c N

I E j gmme 0, 0, 0, mmmm e, C, 0, 0, Nmemg O, 0, 0, 0, gm ,f -

                 "                                          C                                                     ,

op coOC ocoO o0000

                                                            /         vvvv            vvvv          vvvvv                v I                                                        e e

mmmm mmmm mm m m I N O, 0, 0, 0, C, Q g o,

                                                                                            ,       30, ,G,.,                  ,0, g g             , ,

2 0000 0000 00000 0000 A vvvv vvvv vvvvv vvvv I i 8m m I.

o. *.

__mm

  • o. C. S.
                                                                                                     ~m.mm
o. a
  • o. a
                                                                                                            .            ~m
o. a. 8.o.

sees a esee esea eeeee g s- .... .... ..... ....

                                                                       ====            :: ~ g           : gg             na:g I
  • W
                                                                ~

g

~e 5555 .

A644 % A444 004 . eEE~B C0005 B gsgas 44444 CNN etes 3E58 g 444 RCR "nK %mmmm

                                                                                        -~~~                        ~g     s. C. C. %.

m0000 --- _ I 7 =0000 ~G O O O O C000 26

l I. I I - 28$2 essse s8s, 22,2

                         $    $$$$     $i$$$           $i$$       $$$$

I s 28$2 essez ssse 22,2 1 $$$$ $$$$$ is$$ $$$$ g- 9 1

                               ;882
                               $iis ssses
                                       $$esi sas, siis e,
                                                                  $si-I           B e
  • 9 9
T E82G 3s3B3 ssEB BBBS I y 5h}

aS : 3 5 $i$$ YY$$$ $$$$ $$$i

     , 5. I 5. 3-x2 I  a ~

IgS b

              "  ;~
                      $ Ei m

388G SE Es

                                                        $3s3      $23E
     ~

t 5E 8 j U$ $Ysi i$19d I  : ag r5 E , diis siid T 5 : ~ s5 a s j # N 8883 BS$3s $3s0 $380

                          $     siis    ipids           $1si       $ppi I                        +

P

                                                                                                 =
                                                                                                 ~
a. T' 8
                           $    2803    BG8Bs           8ts:       COBO                        23 a    $1si    idisi           1915       siti                        18
                                                                                               .2 I
  • II 2i g-ha sa a 8as $sa: 1 l s . i. e is. . i epis issi s, 1,
                           $    %S$$     $$$22          CESS       $$$2                        852 I                                                                                           5 ,*
                           =

r '3MN S-~ '8>h=>

                                             ~~o
                                                        =3:=
                                                        -~~o
                                                                   >>nt 8-~~

ss s sssss ssss -gw W $$ $ 8$883 BBB8 5sss 8 8 3wa ssun4

                           ~

sdsd

                                  >>>  1,A$dse       ,  ddsd
                                                        ====    ~                               gic I                        e s   ooo 1~22~

28ao8 s oooo < oou . v. :. I 27

I iI I . M mm_

                                         ,".~G. O. U. #.

03403 s.* m OCQ@ O. O.

                                                                     . mm        .

OCCC

                                                                                          .m
                                                                                  , _O. 0 0                           m_,,,

O. 0 . . 33032. a' vv vvv v vvv v vvv <vvv v I e I e E' n~~~m C. C. C. O. D. 00073 vv vvv

                                                                 ,--m 3 0. C. 0 CCCO vvvv smo-D. C. D. C.

C000 v vvv

                                                                                                                      ,O.
                                                                                                                        , h, Occcc
c. ,o.

vv v v v

                                                                                                                                 . ,c.

I c wmmm m mm I m

  • gNmmM. . O. O. *. O. *. *. O. ' . *. g m. O.
  • C.
                                                                                                                                     ~g~.

e C0003 0000 CCCC 0000C w vvvvv vvvv vvvv vvvvv I 5 5 e w a w

                                           .~mmm CCCCC
                                                                  .Mmm 0000 em,m 0000
                                                                                                                       -m+~+

00Q00 b N bbbbb bbbb bbbb bbdbb I - g

             =

a

                $~%

3 ; 0 E : e vvvvv vvvv v vv v vv v v v M 4 5 w M i - m N mMMww M mmmM mMmNm W~

             - e B
  • i o*C EE emme 3 o emee
o. .

cooco

                                                                                                                                    . o.

6

         - v             g  ,3              ogoce v      vvv             vvvv              vvvv                               vvvvv I           E"
             ~

E

                 , 2 h, 3 z    3 5

s~

  • w f -

g MMmM MMmNM g A MMM8W coo 2 Bo83 omeo oocco C e bbbbb vvvvv bbbb v vvv bbbb vvvv bbbbb vvvvv I @ b e mMmdW WWMW MMMM MMmNm 00000 0000 0000 00000 I 3 bb vvvvv bb bbbb vvvv bbbb vvvv bbbbb vvvvv g' M 9

  • mMMWW mmmm MAMNM
                                             *
  • o o o. E.ooo W. W W ocoo o o. ** -

i . ccOCO 2 00000 0C00 0000 vvvvv T I E vvvvv vvvv vvvv g V 8

                                  -          Estat                  Etts              Esta                                 stEEE
  • E '$s*24
                                                --~o Bt;>
                                                                    --~M
                                                                                      =

o-~~

2 1433%

e--~o C. I g 5 E gggg?. s

                                              ~$~- ~E o--~

333B "TTA e ~ n 2 -~ T.

                                                                                ~

3222 7777 Mo-~

                                                                                                            =
                                                                                                            ~

f ssss: 77779# % T, a ~o--~

                                                                                                                                             =

M hhhhh 8 $OOb NNNN e o oooco ---- 1 C---- - E ----- . I I 28

4 E E .. E E E TABLE 4 (PAGE 1 of 3) i U ELECikiC - 1989 REMP CUHANCHE PEAK SIEAM E1((INIC STAllDN CONC [mikA110NS OF BEIA EMilif Ri IN AIR PARilCULAIES Results in thits of 10-3 pCl/m3 +- 2 s.d. STATIONS SAMPLING PERIOD m-1.0 5W/W5W-0.95 5/551 1.2 SW-12.3 55E-4.5 E-3.5 N-1.45 N-9.4 JANUARY 01/03-01/10/89 30+-4 30+-4 31+-4 36+-4 33+-4 31+-4 40+-4 4/+-4 01/10-01/17/89 26+-4 20+-3 24+-4 23+-4 21+-4 25+-4 22+-4 24+-4 01/17-01/24/89 19*-4 23+-4 23*-4 22+-4 21+-4 21+-4 24+-4 21+-4 01/24-01/31/89 38+-4 45+-4 44+-4 51+-4 4 3+ -4 4 9+ -4 41+-4 52+-4 FEBRUARY g 01/31-02/01/89 29+-4 30+-4 28*-4 33+-4 30+-4 35+-4 31+-4 3$+-4 m 02/07-02/14/89 23+-3 26+-3 27+-3 26+-3 26+-3 30+-4 30+-4 29+-3 02/14-02/21/89 11+-3 12+-3 14*-3 12+-3 12+-3 14+-3 16*-3 15+-3 02/21-02/28/89 24+-3 21+-3 29+-3 33+-4 29+-3 35+-4 31+-4 29+-3 MARCH U7/75-03/07/89 18*-3 21+-3 21+-3 24+-3 19+-3 26*-3 25+-3 19+-3 03/07-03/14/89 20+-3 21e-3 20+-3 23+ - 3 20+-3 26+-3

  • 75+-3 03/14-03/21/89 20+-3 22+-3 21+-3 26+-3 22+-3 28+-3 28+-4 24+-3 6 1'21-03/28/89 23*-3 19+-3 15+-3 24+-3 20+-3 24+-3 23*-3 20+-3 APRIL UT/75-04/04/89 11+ .2 18+-3 14.-3 16+-3 16+-3 20+-3 1 +-3 b -3 l 04/04-04/12/89 17+-3 18+-3 14+-3 20+-3 11+-3 20+-3 22*-3 18+-3 l 04/12-04/18/89 12+-4 22+-4 15+-4 15+-4 19+-4 18+-4 20+-4 18+-4

! 04/18-04/24/89 11+-4 24+-4 20+-4 21+-4 21+-4 21+-4 28+-4 23+-4 04/24-05102/89 12+-3 15+-3 14+ ~s 20+-3 17+-3 23+-3 22+-3 20+-3 l l

  • Fit (rooted -- s mple not collected.

l l I

M M M M M M M m m m m M M IABLE 4 (Pali 2 of 3) I u ELECINIC - 1:59 ptMP COMANCHL PE AK SIEAM ELECTNIC Similtm CUNCINIRATIONS UF BETA IMllifd5 IN Ald PAgilCULAft5 Results In Units of 10-3 pCi/m3 +- 2 s.d. STATIONS 5/55W-1.2 SW-12.3 55C-4.5 E-3.5 N-1.4s #-9.4 SAMPLING pen!OD md-1.0 SW/W5W-0.95 E 21+-3 16+-3 20+-3 22+-3 15+-3 05/02-OS/09/89

  • 16+-3 15+-3 19+-3 16+-3 20+-3 22+-3 16+-3 05/11 05/16/89 13+-4 20+-3 15+-3 16+-3 21+-3 21+-3 21+-3 24+-4 In+-3 05/16-05/23/89
  • 15+-3 27+-3 28+-3 25+-3 21+-3 25+-3 29+-3 30+-3 05/23-05/30/89 2a+-3 JUNE 12+-3 12+-3 12+-3 14+-3 05/30-06/06/89 11+-3 9.5+-2.8 9.6*-2.8 15+-3 16+-3 13+-3 13+-3 14+-3 16+-3 17+-3 15+-3 06/06-06/13/89 17+-3 15+-3 14+-3 12+-3
  • 13+-3 13+-3 13+-3 15+-3 06/13-06/20/89 8.3+-2.7 9.5+-2.8 15+-0.3 13+-3
  • 7.2+-2.8 12+-3 13+-3 06/20-06/27/89 9.7+-3.0 11+-3 6.1+-2.1 13+-3 12+-3 06/27-07/03/89 12+-3 11+-3 10+-0.3 alL Y 25+-3 23+-3 27+-3 2ti+-3 23+-3 25+-3 01/03-07/11/89 26+-3 23+-3 20+-3 18+-3 16+-3 18+-3 16+-3 19+-3 19+-3 01/11-07/18/89 18+-3 29+-4 27+-4 24+-4 26+-4 21+-4 23+-4 26+-4 22+-3 07/18-07/24/89 16+-3 13+-2 16+-3 15+-3 14+-3 07/24-08/01/89 18+-3 14+-2 12+-2 AUGUST 8.0+-3.4 11+-3 12+-3 9.8+-3.3 9.6+-3.3 9.5+-3.3 lu+-3 08/01-08/08/89 9.6+-3.4 29+-4 29+-4 41+-4 27+-4 33+-5 24+-4 25+-4 23+-4 08/08-08/15/89 13+-3 11+-3 12+-3 16+-3 12+ .'

08/15-08/22/89 16+<3 14+-3 12+-3 12+-3 5.3+-2.2

  • 13*-3 12*-3 08/22-08/29/89 13+-3 8.4*-2.3 11+-3
  • Pump out of service; s mple not collected.

l

lABLE 4 (PALE 3 of 3) T U ElfCTHIC - 1989 NIMP CtJMANCHE Ff AK $TIAM EtfCirIC siAI10r; COf(ENikAllON5 Of t1 ETA frt!!TERS 14 Alu PARTICULAff 5 kesults in Units of 10-3 pCf/m3 +- 2 s.d. 5AMPLlhG PERIOD fel-1.0 SW/W5W-0.95 STAffor45 5/55W-1.2 Su-12.3 55E-4.5 i - 3. 5 5fPitrefR f.-l.45 h-9.4 08/29-09/05/89 12+-3 09/05-09/12/89 13+-3 15+-3 11+-3 12*-3 09/12-09/19/89 13+-3 10+-3 14 -3 19+-3 16*-3 16*-3 13*-3 09/19-09/26/89 28+-5 12+-3 14+-3 3E+-3 it+-3 41+-6 16+-3 11+-3 w 09/26-10/03/89 37+-4 35+-5 13+-3 10+-3 12+-3 13+-3 " 32+-4 23+-3 26+-4 20+-4 32+-4 34+-4 26+-4 1/*-3 gIOBER 30+-4 26 -4 30+-4 25+-3 35+-4 3e+-4 10/03-10/10/B9 41+-4 10/10-10/17/89 35+-4 33*-4 31+-4 38+-4 38+-4 10/17-10/24/89 19+-4 32+-4 34 -4 31+-4 10/24-10/31/89 19+-4 31+-4 30+-4 4/+-4 17+-4 20+-4 19 +-4 32+-4 3/+-4 14+-4 22*-4 22+-4 35+-4 23+-4 13+-4 35+-4 20v1MBER 20+-4 15+-4 1/*-4 20+-4 21*-4 14+-4 10/31-11/07/89 32+-4 11/07-11/14/89 36+-4 35+-4 35*-4 38+-4 11/14-11/21/89 33+-4 37+-4 35+-4 32+-4 33+-4 33+-4 11/21-11/28/89 31+-4 34+-4 33+-4 29+ - 4 43+-4 39+-4 29+-4 39+-4 30+-4 44*-5 33+-4 31+-4 43+-4 35+-4 42+-4 _ DECEMBER 38+-4 29+-4 43+-4 32+-4 35+-4 40+-4 11/28-12/05/89 22+-4 12/05-12/12/89 20+-4 19*-4 34+-4 31+-4 -4 12/12-12/19/89 4S+-5 32+-4 20+-4 25+-4 12/19-12/26/89 48+-5 <-4 18*-4 52+-5 46+-5 31+-4 34+-4 21+-4 12/26-01/02/90 47+-5 45+-5 41+-5 30+-4 39+-4 47+-5 50+-5 46+-5 29+-4 38+-4 37+-4 46+-5 4f+-7 Average 39+-4 54*-5 42+-5 37+-4 55+-9

   +- 2 s.d.                                                                                           37+-4 32+-4 44+-5 36+-4

M M M M M M m . M M . T ABL E 5 (PAE I 0F 2) T U ELECTRIC CurtANCHE PE AK STEAM ELECTRIC STAil04 CONCENIRAllC45 0F G7fmA ENITTER$* IN AIR PARTICULATE FiliERS Results in Units of E-03 pCi/m3 +- 2 s.d. K-40 Re-103 Cs-134 Cs-137 t0CA1104 COMP 05fiE PERIOD Be-7 FIRST QUARTER 9.33*-4.65 <0.5 <0.5 <0.5 NW-1.0 01/03/89-03/28/89 72.8+-7.3

                                                                                       <7           (0.5     <0.4      (0.4
           $W/W5W-0.95           01/03/89-03/28/89       82.0+-8.2
                                                                                                    <0.6     40.6      <0.5 5/55W-1.2             01/03/89-03/28/89       67.2+-6.7                     <ls
                                                                                       <10          <0.6     <0.5      <0.5 SW.12.3               01/03/89-03/28/89       80.5+-8.0 8          (0.5     (0.4      <0.5 55E-4.5               01/03/89-03/28/89       73.2+-7.3
                                                                                       <10          <0.6     <0.6      (0.6 E-3.5                 01/03/89-03/28/89       99.1+-9.9
                                                                                       <20          (0.8     <0.8      (0.8 N-1.45                01/03/89 03/28/89       82.2+-8.2 (20          <0.7     <0.7      <0.1 h-9.4                 01/03/89-03/28/89       78.3+-7.8 u

N SECOND QUARTER

                                                                                       <10          (0.8     <0.6      <0.6 NW-1.0                03/28/89-07/03/89       65.8+-8.9
                                                                                       <9           (0.7     <0.4      (0.4 SW/W5W-0.95           03/28/89-07/03/89       70.1+-7.6
                                                                                                             <0.4      (0,3 59.7+-6.0                     <8           <0.5 5/S$W-1.2             03/28/89-07/03/89 (0.3      (0.3 03/28/89-07/03/89       65.6+-6.6                     <5           (0.5 SW-12.3                                                                                                    <0.4
                                                                                       <8           (0.5     (0.3 55E-4.5              CL*25t/89-07/03/89      65.7+-6.6
                                                                                       <8           (0.6     <0.4      <0.4 E -3. 5               03/28/J9-07/03/89        68.3+-6.8
                                                                                       <20          (0.8     (0.5      (0.5 N -1.4 5             03/28/89-07/03/89       6 3. 6 + - 7.1
                                                                                       <7           (0.5     <0.5      <0.3 N-9.4                03/28/89-07/03/89        70.7+-7.1
  • AlI other game emitters were <LLO.

t

M M M M M M M M M M M M M M M I ABt t 5 (PAGE 2 Of 2) I ti Et[CIRIC 00ftANC)ff Pf AK Sit AM [t[CTRIC STATI0ft C0ft(INTRAllDNS Of GAP 9tA (MiliER5* IN AIR PARilCUL ATE f ! LIER $ Results in Units of E-03 pCI/m3 +- 2 s.d. K-40 Pu-103 is- 134 Cs-137 LOCAI10N COMPOSITE PERIOD Be-1 IHIRO QUARILR

                                                                                            <8               <0.8          <0.4         <0.5 kW-l.0              07/03/89-10/03/89           72.8+-7.9
                                                                                            <9               <0.6          <0.3         <0.4 SW/W5W-0.95         07/03/89-10/03/89          63.4*-6.9
                                                                                            <10              <0.8          <0.6         <0.6 5/55W-1.2           07/03/89-10/03/89          60.3*-7.3
                                                                                            <10              <0.8          <0.5         <0.5 5W-12.3             01/03/89-10/03/89          67.8+-7.2
                                                                                            <C               <0.6          <0.4         <0.5 5'l -4.5            07/03/89-10/03/89          60.4+-6.0
                                                                                            <9               <0.7          <o.5         <0.5 E-3.5               07/03/89-10/03/89          69.4+-7.2 12.8+-4.7        <0.7          <0.4         <0.4 N-1.45              07/03/89-10/03/89          86.3*-8.6
                                                                                            <7               <0.6          <0.5         <0.5 N-9.4               07/03/89-10/03/89          69.9+-7.5 U               FOURTH QUARIER
                                                                                            <10              <0.8          40.5         <0.4 NW-1.0              10/03/89-01/02/90           79.4+-8.4 14.7+-5.9        <0.7          <0.4         <0.4 SW/W5W-0.95         10/03/89-01/02/90           18.3+-7.9
                                                                                            <10              <0.8          <0.5         <0.5 5/55W-1.2           10/03/89-01/02/90          69.1*-7.3
                                                                                            <10              <0.8          <0.5         <0.5 5W-12.3             10/03/89-01/02/90          69.0+-7.2
                                                                                            <10              <0.5          <0.4         <0.4 55E-4.5             10/03/89-01/02/90           74.8+-7.6 12.8+-5.5        <0.7          <0.5         <0.5 E-3.5               10/03/89-01/02/90           11.6*-7.6
                                                                                            <9               <0.7          <0.5         <0.4 N-1.45              10/03/t.9-01/02/90         68.4+-7.7
                                                                                            <10              <0.8          <0.5         <0.5 N-9.4               10/03/89-01/02/9C          69.8+-9.2
  • All other gaswa emitters were <tLO.

{

I TABLE 6 l T U ELECTRIC COMANCHE PEAK STEAM ELECTRIC STATION CONCENTRATIONS OF I-131 IN MILK Results in pC1/1 +- 2 s.d. I I- MONTH COLLECTION SSE-2.2 SW-13.5 DATE _ UANUARY 01/17/89 <0.4 <0.5 FEBRUARY 02/14/89 <0.5 <0.'5 MARCH 03/14/89 <0.3 <0.3 APRIL 04/12/89 <0.3 <0.2 MAY 05/09/89 <0.3 <0.3 05/23/89 <0.2 <0.2 JUNE 06/06/89 <0.3 <0.3 06/20/89 <0.3 <0.4 JULY 07/04/89 <0.3 <0.3 07/18/89 <0.3 <0.3 AUGUST 08/01/89 <0.3 <0.3 08/15/89 <0.3 <0.3 08/29/89 <0.3 <0.3 SEPTEMBER 09/12/89- <0.2 <0.3

09/25/89 <0.4 <0.3
OCTOBER 10/10/89 <0.2 <0.3

[ 10/24/89 <0.4 <0.3 NOVEMBER ~11/21/89 <0.5 <0.2 ! DECEMBER 12/12/89 <0.3 <0.3 I - I

M M - M M M M M M M. TABLE 7 (PAGE I of 2) T U ELECTRIC COMANCHE PEAK STEAM ELECTRIC $TATION CONCENTRATIONS OF GAMMA EMITTER $* IN MILK Results in Units of pCl/l +- 2 s.d. Cs-134 Cs-137 La-140-BA-140 MONTH COLLECTION DATE K-40 STATION - SSE-2.2

                                                                             <4          <4        <6 JANUARY                01/17/89              1220+-120
                                                                             <4          <4        <10 IE8RUARY               02/14/89              1360+-140
                                                                             <4          <4        <6 MARCH                   03/14/89              1400+-140
                                                                             <5          <5        <6 APRIL                  04/12/89              1150+-120
                                                                             <4          <4        <6 MAY                    05/09/89              1190+-120                             <4        4 8 1330+-130                 44 05/23/89
                                                                                         <4        < 6 1330+-130                 <4 E$  JUNE                    06/06/89                                        <4          <4        < 9 06/20/89              1260+-130
                                                                             <4          <4        < 6 JULY                    07/04/89              1310*-130                             <4        < 6 1340+-130                 <4 07/18/89
                                                                             <4          <4        < 7 AUGUST                 08/01/89              1230+-120                             <6        <10 1210+-120                 <6 08/15/89                                        <4          <4        <8 08/29/89              1410+-140
                                                                             <4          <4        <6 SEPTEMBER              09/12/89              1340+-130                             <5        <9         i 1260+-130                 44 09/25/89
                                                                             <4          <4        <9 OCTOBER                10/10/89              1510+-150                             <4        <9 1230+-120                 <4 10/24/89
                                                                             <4          <4        <9 NOVEMBER              11/21/89              1280+-130
                                                                             <4          <4        < 7 DECEMBER              12/12/89              1290+-130 i
  • AII other gamma emitters were <tLD.

m .U M a u m

                                                               -        -      -       -      -  -       - -         = =

IABLE / (PAGE 2 of 2) i U ELECTRIC COMANEHE PEAK SILAM ELECTMic STATION EONCENTRATIONS Of GAMMA EMITTEN5* IN MILA Results in Units of pCl/l +- 2 s.d. Cs-134 C5'I3I Udll*~I#O COLLECTION 0 ATE K-40 MONTH STATION - SW-13.5

                                                                                        <4          44       <
  • JANUART 01/11/89 1460+-150
                                                                                        <4          44       < 9 FEBRUARY                       02/14/89                  1400+-140 (4          (4       ( 6 MARCH                          03/14/89                  1430*-140 (4          44       < 5 APRIL                          04/12/89                  1290+-130
                                                                                        <4          <4       < /
'J  MAY                            05/09/89                  1250+-130                              <4       < 6
  • 1280+-130 <4 05/23/89
                                                                                        <4          44       < 6 JUNE                          06/06/89                  1400*-140                              <3       <u 1440+-140                  <4 06/20/89
                                                                                        <4          <4       < 6 JULY                          07/04/89                  1560+-160                              <4       < 6 1300+-130                  <4 01/18/89
                                                                                        <4          <4       < 6 AUGUST                        08/01/89                  1460+-150                              (6       < 9 1110+-110                  <6 08/15/89                                             <4          <4       < 9 08/29/89                  1430+-140
                                                                                        <3          <4       < 6 SEPTEMBER                     09/12/89                  1220+-120                              <4       <10 1420+-140                  <4 09/25/89
                                                                                        <4          (4       <a OCIO8ER                       10/10/89                  1530+-150                              <4       < 8 1240+-120                  <4 10/24/89
                                                                                                             <10         j
                                                                                        <4          <4 NOVEMBER                      11/21/89                   1560+-160                                                  I I

(4 <4 <6 DECEMBER 12/12/89 1430+-140 l l Average

        ? s_o.
      =

All u l tie r 9 am e .1 reltter$ ar(c ( L I D.

M M M M M M M IABLE 8 i U ELECTRIC COHANCHE PEAK SIEAM ELECTRIC-SIATION CONCENTRATIONS OF GROSS BETA IN GROUND AND DRINKING WATEH* Results in Units of pct /l *- 2 s.d. MONTH COLLECTION DATE W-1.2 WSW-0.1 55E-4.6 N-9.8 N-1.45 JANUARY 01/17/89 9.2+-1.8 <1 7.4+-1.1 2.7+-1.5 8.0+-1.1 FEBRUARY 02/14/89 1.0+-0.2 <1 7.4+-l.6 3.9+-1.5 6.2+-1.5 MARCH 03/14/89 10 +-2 4.4 +-1.2 1.7+-0.8 2.3+-1.3 1.3+-1.5 APRIL 04/12/89 9.0 +-1.8 <1 7.8+-1.7 3.3+-1.5 6.9+-1.6 JULY 07/04/89 9.0 +-1.7 <0.9 9.0+-1.7 2.2+-1.3 1.3+-1.5 Average 13 +-2 s.d.

  • Drinking water analyses eliminated 04/24/90. Subsequent samples were analyzed pursuant to 00CM groundwater analysis requirements of quarterly gamma isotopic and tritium analyses.

M M M M M M M m M M M TA8LE 9 (PAGE I of 2) 1 0 ELECTRIC COMAhCHE PfAK ST[AM fLECTHIC SIATION CONCENIRAll0NS OF GAMMA EMIITER5* IN GNOUND/ DRINKING WAllN**  ! Results in Units of pCi/l +- 2 s.d. Nb/Zr-95 Cs-134 Cs-137 ea/ta-140 C OL L E C110N Mn-54 Co-58 fe-59 Co-60 In-65 DATE STATION N-1.45

                                                                            <6           <6     <6       <10 (6        (10          (6          <10                                   <10 01/17/89            <5                                          <10      <5           <6     (5
                       <5       <5        <10          <6                                       <3       < 4 02/14/89                                            <3          < 7      < 3          <3
                       <2       <3        <6                                             <5     <5       <10 03/14/89                               <10          <5          <10      <5 (5       <5                                                       <3     <3       < 6 04/12/89                               <6           <3          <8       <3 07/04/89            <3       <3                                          <6           (6     <5       <10 (5        (10          (6          <10 10/03/89            <5
 $ $1 Ail 0N W-1.2
                                                                                         <5     (5       < 8
                                <5        <10          <5          <10      <5 01/17/89            <5                                                   <5           <4     <$       (10
                       <4       <4        <10          <5          <9                           <4       < 5 02/14/89                                            <5          <8       <4           <5 (4       <4        <8                                             <3     <3       < 1 03/14/89                               < 7          <4          <7       < 4 04/12/89            <3       <3                                          < 4          <3     <4       < 6
                                          < 8           (4         < 7 07/04/89            <3       <3                                          < 5          <4     <4       <10
                                <4        < 9           (4         <8 10/03/89           <4 I   STAfl0h W5u-0.1
                                                                            < 3           <3    <3       < 6
                                <3        <8            (4         < 7 01/17/89            <3                                                   <  3          <3    (4       < 8
                                <3        < 8           <3         < 7                                   < 4 02/14/89            <3                                          <7       <  3          <3    <4
                                <3        <6            (4                                               < 7 03/14/89            <3                                          <7       < 4           <3    <3
                                <3        <8            <4 04/12/89            <3                                           <7      <  4          <4    (4       < 6
                                <3        < 7           (4                                               <10 01/04/89            <3                                           <8      <  4          <4    <4
                                <4        <9            <4 10/03/89           <3
    $1AT10N $5[-4.6
                                                                            < 4           <4    <3       < 6
                                <3         <U           (4          < 1 01/17/89           <3                                           < 7     <  3          <3    <3       < 8
                       <3        <3        < 7          <3                                               < 1 02/14/89                                                        < 9     <  4          (5    <5
                       <4       <4         < 9          <5                                               <8 03/14/89                                                        < 7     <  3          <4    <4 (3        < 7          <4 04/12/89            <3                                                                (5    <5       < 7
                                 <5        <10          (5          <10     <  5
                                                                                                         <10 07/04/89            <5                                          <10     <  6          (5    (5
                                           <!o          (5 10/03/89            (5       (5

(

M M M M M M M M M . - M M M TAetf 9 (PAGE 2 er 2i i o ELECINIC COMANCHE PEAK $1EAA ELECINIC SIAll0N CONCENTRATI0h5 0F GAMMA EMliitR5* IN 6ROUND/DRIRKinG W ATEN** Results in Units of pC6/1 +- 2 s.d. COLLECTION 2n-65 hb/fr-95 Cs-134 Cs-131 sa/t a-140 DATE Mn-54 Co-58 Fe-59 Co-60 STATION N-9.8

                                                                                         < 4           <4       <4        < t
                                             <3       < 7            <4          < 1 01/11/89                 (3
                                                                                 <10     < 6           <6       (6        <10
                                  <5         <6       (10            (6                                                   <4 02/14/89                                                    <3          <6      < 3           (3       <3
                                  <3         <3       <6                                               <4       <4        < 8 03/I4/89                                     <8             <4          <8      <4 04/12/89                 <3         <4                                                        <4       <4        ( 8
                                             <4       < 9            <4          <9      < 4 01/04/89                 <4                                                                   (4       <5        <10
                                             <4       <f4            <5          < 9     < $

10/03/89 <4 Cy

          *All other gamma emitters were LLD.
          **Drinting water analyses eliminated 04/24/90. Subsequent samples were analyzed pursuant to the OUCH ground-ater auslysis j
requirements of quarterly gamma isotopic and tritium analyses.

5

Ms M M M M M M M M M M' IABLE 10 1 U ELEC1RIC CDMANCHE PEAK SIEAM ELECIMIC STATION CONCENIHAll0NS Of I-131 IN 6ROUhD AND ORINKlhG WATEH* Hesults in Units of pC1/1 +- 2 s.d. WSW.O.I 55L-4.6 N-9.8 N-1.4$ MONIH C0ttECTION DATE W-l.2

                                                                     <0.8              <0.8                <1                <1 JANUARY             01/03/89                <0.1                                                                         <0.3
                                                <0.3                 <0.2              <0.3                <0.3 01/17/89                                     <0.5              <0.4               <0.5               <0.5 01/31/89                <0.5
                                                                     <0.5              40.5                <0.3              <0.4 FEBRUARV            02/14/89                <0.5
                                                                     <0.2              <0.2               <0.2               <0.2 02/28/89                <0.2
                                                                     <0.1              <0.1               <0.3               <0.2 MARCH               03/14/89                40.1                                                      <0.2               40.2
                                                <0.3                 <0.3              40.2 03/28/89
                                                                     <0.2              <0.2               <0.2               <0.2 APRIL               04/12/89                <0.3
                                                                     <0.5              <0.5               <0.4               <0.4 04/24/89                <0.5 4                                                                                                        <0.2               <0.2
                                                                     <0.2              <0.2 JutV                07/04/89                <0.2
                                                                    <20**             <30**              <30**              <20**

OCIO8ER 10/02/89 <20**

  • Drinking water analyses eliminated 04/24/90. Subsequent samples were analyured pursuant to the 00CM groundwater analysss requirements of quarterly gamma isotopic and trittua analyses.

This LLO was not a(televed due to

    ** Required LLD for I-131 in water if there is no drinking water pathway is 15 pct /l.

delay between sample Collection and analysis (approximately 20 days). l

I TABLE 11 T U ELECTRIC COMANCHE PEAK STEAM ELECTRIC STATION CONCENTRATIONS OF TRITIUM IN GROUND / DRINKING WATER

  • Results in pCi/l +- 2 s.d.

TRITIUM OUARTER COLLECTION PERICO LOCATION ACTIVITY 1 01/03/89-03/28/89 SSE-4.6 <2000 01/03/89-03/28/89 N-9.8 <2000 01/03/89-03/28/89 W-1.2 <2000 01/03/89-03/28/89 WSW-0.1 <2000 01/03/89-03/28/89 N-1.45 <2000 2 04/12/89-04/24/89 SSE-4.6 <2000 04/12/89-04/24/89 N-9.8 <2000 04/12/89-04/24/89 W-1.2 <2000 04/12/89-04/24/89 WSW-0.1 <2000 04/12/89-04/24/89 N-1.45 <2000 3 07/04/89 SSE-4.6 <2000 07/04/89 N-9.8 <2000 07/04/89 W-1.2 <2000 l 07/04/89 07/04/89 WSW-0.1 N-1.45

                                                                                  <2000
                                                                                  <2000 4            10/03/89                            SSE-4.6                  <2000 10/03/89                            N-9.8                    <2000 10/03/89                           W-1.2                    <2000 10/03/89                           WSW-0.1                  <2000 10/03/89                            N-1.45                  <2000
      *0rinking water analyses eliminated 04/24/90. Subsequent samples were analyzed pursuant to the ODCM groundwater analysis requirements of quarterly gamma isotopic and tritium analyses.

41

TABLE 12 T U ELECTRIC COMANCHE PEAK STEAll ELECTRIC STAT!0!i C0fiCEllTRAT!0NS OF Gr-B lii WATER-SURFACE /0R!liKliiG

         ~

Results in pCi/l +- 2 s.c. it0!iTH COLLECT:0N UNW-0.1 N-9.9 DATE JANUARY 01/17/09 18+-4 14+-4 FEBRUARY C2/14/89 21+-4 17+-4 11 ARCH 03/14/89 16+-4 14+-3 APRIL 04/12/89 19+-4 11+-3 HAY 05/09/89 16+-4 14+-3  ; I JUl4E 05/30-06/06/89 13+-3 12+-3 JULY 06/27-07/04/89 14+-3 9.0+-2.4 l JULY 07/04-07/18/89 16+-3 9.8+-2.5 AUGUST 07/24-08/01/89 16+-3 15+-3 AUGUST 08/08-08/29/89 16+-3 15+-3 SEPTEMBER 09/05-09/25/89 14+-3 11+-3 OCTOBER 10/03-10/10/89 18+-3 12+-3 I OCTOBER 10/03-10/24/89 17+-4 14+-4 fl0VEMBER 10/31-11/21/89 15+-3 14+-4 DECEMBER 11/28-12/19/89 15+-3 21+-4 AVERAGE

             +-2 s.d.

42

M M E E .E E' E E ' TABLE 13 (PACE I of 2) 1 U ELEC1RIC COMANCHE PEAK STEAM ELECINIC STATION CONCENIR ATIONS OF GAMMA EMITIEk5* IN WATER-5URFACE/DRINAlac Results in Units of pCi/I +- 2 s.d. COLLECTIOh DATE Hn-54 Co-58 Fe-59 Co-60 In-65 hb/Ir-95 Cs-134 Cs-13/ Ba/te-140 STATION - NNu-0.1 01/11/89 <3 <3 <1 <4 < 1 < 4 <3 <3 < o 02/14/89 <3 <3 <7 <3 <6 < 3 <3 <? < 9 03/14/89 <3 <3 <6 <3 <6 < 3 <3 <3 < 4 04/12/89 <3 <4 <8 <4 < 1 < 4 <4 <4 05/09/89 < 8

                     <3     <3         <8           <4          < 7         < 4         <3      <3    < 9 05/30-06/06/89     <3     <3         <8           <4          < 7         < 3         <3      <4    < 9 06/27-07/04/89     <5     <5         <9           <5          <10         <$          <5      <5    < 1 07/04-07/18/89     <3     <3         <6           <3          < 6         < 3         <3      <3    < 6

[3 07/24-08/01/89 <4 <4 <8 <5 <8 < 4 <4 <4 < 7 08/08-08/29/89 <3 <4 (B <4 <8 <4 <3 <4 <10 09/05-09/25/89 <4 <4 <8 <4 <8 < 4 <4 <4 s 9 10/03-10/10/89 <3 <4 <9 <3 < 1 < 4 <4 <4 <10 10/03-10/24/89 <4 <4 <9 <5 <9 <5 <5 <5 < 8 10/31-11/21/89 <5 <6 <10 <6 <10 < 6 <6 <6 <10 11/28-12/19/89 <4 44 <10 <4 < 9 < 4 <4 <4 <10 Average

  +- 2 5.d.

E .E E E .E E' E E E - E- . E E E E . 1ABLE 13 (PACE 2 of 2) 1 U ELEC1RIC ) l COMANCHL PIAK SifAM ELECTRIC STAliON CONCENTRATIONS Of GAHitA EMITTER $* IN WATER-5URfACf/ORIrarint Results in Units of pCi/l +- 2 s.d. COLLECTION Fe-59 Co-60 2n-65 Nb/Ir-95 Cs-134 Cs-137 Ba/La-140 DAlf Hn-54 Co-58

    $1 Ail 0N N-9.9
                                                                              < 4          44        <4      < 1
                                         <9           45          <  9 01/17/89           <4     <4
                                                      <3          <  6        < 3          <3        <3      <e
                       <3     <3         <6 02/14/89                  <4         <8           <5          <  8        4 4          <5        <4      < 6 03/14/89           <4                                                     4 4          <3        <4      < 1
                              <3         <8           <4          4  8 04/12/89           <3                                                     < 4          <3        <4      < 9
                              <3         <8           <4          < 1 05/09/89           <3                                         <  7        < 4          44        44      <10
                              <3         <9           <4 05/30-06/06/89     <3                                                     < 4          <4        <4      < 5
                              <4         (9           <4          <  9 06/27-07/04/89     <4                                                     4 3          <3        <3      < 6
                              <2         <6           <3          <  6 07/04-07/18/89     <2
                              <3         <7           <3          <  7        <3           <3        <4      < 6 07/24-08/01/89     <3                                                                            <6      <10

- j[ <5 <5 <10 46 <10 < 6 <6 08/08-08/29/89 48 <4 < 7 < 4 <4 <4 < 9 09/05-09/25/89 <3 43 < 4 44 <4 <l5

                                         <8           <4          <8 10/03-10/10/89     <4     <4
                                                      <4          < 1         < 3          <4        <4      <e
                       <3     <4         <8                                                                  <10 10/03-10/24/89            <4        <10           <5          <10         <$           <5        <5 10/31-11/21/89     <4
                                                                  <6          < 4          <4        <4      <a
                              <3        < 7           <3
    !!/28-12/19/89     <3 Average
    +- 2 s.d.

I TABLE 14 T U ELECTRIC j C0flAilCHE PEAK STEAf1 ELECTRIC STATION CONCENTRATIONS OF l-131 til WATER-SURFACE / DRINKING e<esul ts in oCi/l +- 2 s.d.

'OrlTH COLLECT!0tl NiiW- 0.1 N-9.9 DATE JAfd3ARY 01/03/89 <0.9 <0.5 01/17/89 <0.3 <0.3 C1/ 31/89 <0.5 <0.5 i

FECRUARY 02/14/89 <0.4 <0.5 02/28/89 <0.2 <0.2 ' l l

l. MARCH 03/14/89 <0.3 <0.4 l 03/28/89 <0.2 <0.2 APRIL 04/12/89 <0.2 <0.2 04/24/89 <0.4 <0.4 MAY 05/09/89 <0.3 <0.2 I

!. <0.2-  ! 05/16-05/23/89 <0.3 I JUNE 05/30-06/06/89 <0.4 <0.5 06/13-06/20/89 <0.4 <0.4 JULY- C6/27-07/04/89 <0.2 <0.2 07/04-07/18/89 <0.4 <0.3 07/24-08/01/89 <0.3 <0.2 AUGUST 08/08-08/15/89- <0.2 <0.4 08/08-08/29/89 <0.4 <0.5 SEPTEMBER 09/05-09/12/89 <0.2 <0.2 09/05-09/25/89 <0.3 <0.2 0CTOBER- 10/03-10/10/89 <0.2 <0.2 10/03-10/24/89 <0.3 <0.3 il0VEMBER 10/31-11/07/89 <0.3 <0.3 10/31-11/21/89 <0.2 <0.3 DECEltBER 11/28-12/05/89 <0.A <0.3 11/28-12/19/89 <0.3 <0.3 12/26-01/02/90 <0.2 <0.2 g 45

I I I TABLE 15 T U ELECTRIC COMANCHE PEAK STEAM ELECTRIC STATION CONCENTRATIONS OF TRITIUM IN WATER-SURFACE /0RINKING Results in pC1/1 +- 2 s.d. I QUARTER COLLECTION PERIOD LOCATION TRITIUM ACTIVITY 1 01/03/89-03/28/89 N-9.9 (2000 NNW-0.1 <2000 01/03/89-03/28/89 N-9.9 <2000 2 04/12/89-06/20/89 NNW-0.1 <2000 04/12/89-06/20/89 g N-9.9 <2000 3 06/27/89-09/25/89 l 06/27/89-09/25/89 NNW-0.1 N-9.9

                                                                                       <2000
                                                                                       <2000 4        10/03/89-12/19/89 NNW-0.1                        <2000 10/03/89-12/19/89 I

I I I I I I 4e

1 IABLE 16 (PACE 1 of 2) I U ELfCINIC COMAhCitt PE AK STEAH ELECINIC SIATION CONEENINATIONS Of *MNA LHlifER5* th SURfAEE WATER Results in Units of pCi/l +- P s.d. COLLEC110N Nb/Ir-95 (s-134 C5-137 Be/te-140 DATE Hn-54 Co-58 fe-59 Co-60 In-65

    $1ATION ESE-1.4
                                               <4          < 7         < 4          44     <4     < 5 01/17/89         <4    <4    <8
                                               <5          <8          <  5         <5     <5     <fo 02/14/89         <4    <4    <10                                                              4 5 44          < 7         < 3          <3     <4 03/14/89         <3    <3    < 7 44          <8          < 4          <4     <4     4  7 04/12/89         <3    <3    <8                                                               <s
                                               <3          < 7         < 4          <4     44 05/09/89         <4    <4    <8                                                               < 9
                                 <10           <5          <10         <5           <5     <5 05/16-06/06/89   <5    <5                                                                     < 5
                                 < 6           <3          <6          < 3          <3     <3 06/13-07/04/89   <3    <3                                                              <4     < 1
                           <3    < 7           <3          < 8         < 3          <3                                j 07/11-08/01/89   <3
                                 <6            <3          <6          < 3          <3     <3     < 9 08/08-08/29/89   <3    <3                                                                     < 8
                                 <8            <3          <6          <3           <3     <3 09/05-09/25/89   <3    <3                                                                     < 9 sm
                           <4    < 9           <5          < 9         < 5          <4     <5
 'd 10/03-10/24/89   <4                                                                           <10
                           <4    <9            <4          <8          <6           <3     <S 10/31-11/21/89   <4
                                 <9            <4          <8          < 4          <4     <4     < 9 11/28-12/19/89   <3    <3 Average
    .- 2 s.d.

STAllON N-I.5 46 <10 < 5 <5 <6 < 8 01/11/89 <5 <5 <10 < 9

                                               <4          < 7         <4           <4     <4 02/14/89         <3    <4    <8                                                               < 4

( <6 <3 <5 < 3 <3 <3 03/14/89 <3 <2 < 7 l

                                               <4          <8          < 4          <3     <4 04/12/89         <3    <3    <8                                                               < 9 l                                 < 7           <4          < 7         < 3          <4     <3 05/09/89         <3    <3                                                              <4     < 8
                                 <9            <5          < 9         < $          <4 05/16-06/06/89   <4    <4
                                               <3          <6          < 3          <3     <3     4 7 06/13-07/04/89   <3    <3    <6                                                               < 6
                                 < 7           <4          < 7         4 3          <4     <3 07/11-09/01/89   <3    <3                                                                     < 9
                                 < 7           <3          < 6         < 3          <3     <3 08/08 08/29/89   <3    <3                                                                     4 9
                                 < 7           <3          < 6         < 3          <3     <3 09/05-09/25/89   <3    <3                                                                     < 9
                                 <8            <4          <6          < 4          <4     <4 10/03-10/24/89   <3    <4
                                               <5          < 8         < 5          <4     44     <10 10/31-11/21/89   <4    <4    <9
                                               <3          < 8         < 4          <3     <<     < 7 11/28-12/19/89   <4    <4    < 8 Average
    .- 2 s.d.

E E E E E E E E E E. E' TABLE 16 (PACE 2 of 2) I U ELECINIC CONANCHE PEAK STEAN ELECTRIC 51A110n CONCENTR ATIONS Of 0AMMA EMI TIER $* IN $URF ACE MALE N Results an Units of pCi/1 +- 2 s.d. COLLECTION Co-60 In-65 Mb/Ir-95 Cs-134 Cs-131 ba/ta-140 DATE fin -5 4 Co-$e Fe-59 STATION NE-7.4

                                                                          < 7        < 4            <4     <4       < 6
                          <4           <4       <8            <4 01/17/89                          <3       < 7           <3          <6         < 3            <3      <3      < u 02/14/89             <2                                                         < 3            <3      <4      < 4
                                                <6            <3          <6 03/14/89             <3           <3
                                                              <S          <8         < 4            <4      <4      <c (4           44       <9                                                                  <10 04/12/89                                                 <5          <10        < $            <5      <5 05/09/89             <5           <5       <10                                                         <6      <10 45          <10        < 5            <5 06/06/89             <5           <5       <10                                                         <3      < 6
                                                < 7           <3          < 6        < 3            <3 07/04/89             <3           <3
                                                                          <  7       < 4            <3     <3       <e
                          <3           <3       <8            <3
    '08/01/89                                   <7            <3          <  6       4 3            <3     <3       < 9 08/29/89             <3           <3                                                           <4      <4      <10
                                       <4       <10           <5          <  9       < 5 09/25/89             44                                                                        <4     44       <10 f;                                    <4      -< 7           <4          <  8       < 5 10/24/89             <3                                                         < 6            <5     45       <10
                                                <10           <6          <10 11/21/89             c5           <5
                                                              <4          < 1        < 4            <3      <3      <a
                          <4           <3       < 7 12/12/89 Average
     +- 2 s.d.

STATION N-19.3

                                                                                     < 4            <3      <3      < 6 43       < 8           <4          <6 01/17/89             <3
                                                                          <6         < 4            <3      <3      <a
                           <3          <3       < 7           <3                                                    < 7 l     02/14/89                                                 <6          <10        <5             <6     45
                           <5          <5       <10 03/14/89                                   < 1           <3          < 1        < 3            <4      <3      < 8 04/12/89              <3          <3                                                           <3      44      < 9
                                       <3       <8            <4          < 7        < 3 05/09/89              <3                                                                       <6      <5      <10
                                       <5       <10           <5          <10        < 5 06/06/89              <5                                                        < 3            <3      <3      4 7
                           <2          <3       < 6           <3          <6 07/04/89                                   < 7           <3          < 7        < 3            <3      <3      < 9 08/01/89              <3          <3                                                                   <3      < 9
                                                < 7           <3          <6         < 3            <3 08/29/89              <3          <3                                                           <3      <3      < 9
                                                < 7           <3          < 6        < 3 09/25/89              <2          <3
                                                              <3          <s         < 4            <4      <4      <s
                           <3          <4       <8 10/24/89                                   <10           <5          <10        < 6            <5      <6      <10 11/21/U9              <5          <5                                                           <4      <3      < 9
                                                <8            <3          < 7        < 4 12/12/89             <3          <3 Average
      +- 2 s.d.
      *Att other gamma emitters were LLD.

I I TABLE 17 T U ELECTRIC C0! tat 4CHE PEAK STEAM ELECTRIC STATION C0tiCENTRAT1045 0F l-131 IN SURFACE WATER

  • Pesults in pCi/l +- 2 s.d I :10 tith COLLECTION h-l.5 DATE N-19.3 NE-7.4 ESE-1.4 JAl:UARY 01/17/89 <0.3 <0.3 <0.2 <0.3 FEBRUARY C2/14/C0 <0.5 <0.5 <0,5 <0.4 MARCH 03/14/C9 <0.2 <0.2 <0.2 <0.2 APd!L 04/12/89 <0.2 <0.2 <0.2 <0.2 MAY 05/09/89 <10 <10 <10 <10 JUtiE 06/06/C9 <10 <10 <20** <20**

JULY 07/04/89 <6 <7 <8 <8 AUGUST 08/01/89 <7 <10 <10 <9 AUGUST 08/29/89 <10 <10 <10 <10 SEPTENGER 09/25/09 (20** <10 <20** <20** OCT03ER 10/24/89 <10 <10 <10 <10 h0VEMBER 11/21/89 <20** CO** <20** <20** DECEMBER 12/19/C9 <10 <10 <10 <10

  • Surf ace water samples were analyzed pursuant to drinking water I requirements through 04/24/89. At that time, the drinking water analyses were eliminated and subsequent samples were analyzed pursuant to the 00Cl1 surface water analysis requirements of nonthly gamna-iostopic and quarterly tritiun composite.
                          **The required LLO for 1-131 in water if there is no drinking water pathway is 15 pCi/1.       This LLD was not achieved due to confusion I                          over climination of the 1-131 analysis for drinking water discussed in the above notation. TV notified Teledyne Isotopes by telephone and by letter of this discrepancy. (See letter included in Ap-pendix C).

I 49

I I TABLE 10 T U ELECTRIC CCHAtiCHE PE AK STE Att ELECTRIC STATION CDtiCEtiTRATIClis 0F TRITIUM lt' SURFACE '.iATER* Results in pCi/l +- 2 s.d. TRITIUM CUARTER COLLECT!Oli PERIOD LOCAT10ft ACTIVITY 1 01/17/G9-03/14/89 i;-19.3 <2000 01/17/89-03/14/89 ESE-1.4 <2000 01/17/89-03/14/89 11-1.5 <2000 01/17/89-03/14/89 NE-7.4 (2000 2 04/12/89-06/06/89 M-19.3 <2000 04/12/89-C6/06/89 ESE-1.4 <2000 04/12/89-06/06/89 ti- 1. 5 (200C 04/12/89-06/06/89 i4E-7.4 <2000 3 07/04/89-09/25/89 N-19.3 (2000 I 07/04/09-09/25/89 ESE-1.4 <20C0 07/04/89-09/25/89 N-1.5 (2000 07/04/89-09/25/89 i4 E - 7. 4 <2000 4 10/03/89-12/12/89 fl-19.3 <2000 10/03/89-12/19/89 ESE-1.4 <2000 10/03/89-12/19/89 fi-1.5 <2000 10/03/89-12/12/89 itE-7.4 <2000

  • Surf ace water samples were analyzed pursuant to drinking water requirements tnrough 04/24/89. At that time, drinking water analyses were eliminated and subsequent sam-I pies were analyzed pursuant to the ODCl4 surface water analystsd requirenents of nonthly gaena isotopic and quarterly tritium composite.

50

M M M M M M M M M M

  • M M M '

TABLE 19 i U ELECTRIC COMANEHL PEAK STEAM ELECTRIC STATION CONCEMIR A110MS OF GAMMA EMITIERS* IN FISH Results in pCl/kg (wet) +- 2 s.d. COLLECTION Co-58 Fe-59 Co-60 la-65 Cs-134 Cs-137 DATE STATION DESCRIPTION K-40 Mn-54 APRIL

                                                             <40         440    <100          <40    < 90    <40      <40 04/13/89        NNE-8/F-2   Crappfe        3820*-540                                      <20    < 40    <20      <20 3930+-390     <20         <20    < 50 04/13/89        NNE-8/F-2 Catfish                        <7          <9     < 20          <9     < 20    < 7      < 8 04/13/89        MNE-8/F-2 Hybrid Strip     3800+-380
                                                                         <10    < 30         <10     < 30    <10      <20 ENE-2/F1    Sand Bass      3160+-320     <10 04/21/89                                   3560+-360     <7          <9     < 20         <9      < 20    < 9      < 8 04/21/89        ENE-2/FI    Walleye
                                                                         <60    <100         <10     <100    <10      <10 ENE-2/FI    Perch          4490+-750     <60                                             <10      <10 04/21/89                                                 <10         <20    < 40         <10     < 40 04/21/89        ENE-2/F1    Catfish        3990+-390
                                                                                < 70         <10     < 30    <20      <20 ENE-2/F1    Walleye        2130+-270     <10         <30 09/18/89                                                 <7          <10    < 40         <8      < 20    < 1      13.3+-6.0 09/18/89        ENE-2/F1    Hybrid St Bass 3010+-310                                             < 20    < 8      < 9 2210+-220     <8          <10    < 30         <9 10/11/89       NNE-8/F2    Crappte                                                      < 9     < 20    < 9      < 8 NME-8/F 2
  • Sand Bass 1960+-200 <8 <10 < 30 10/11/89 h$ AVERAGE
     +-2 s.d.
     *All other gamma emitters were LLD.

E - s E' E E M IJt!ki 20 T U lt.f CTRIC (OPtAMCHE PEAK Sil AM f tECIR!C STATION CONCENTRAll0NS OF GAP 9tA EMIITER$* IN SEDIMENT Results in pCi/kg (dry) +- 2 s.d. EDILLCIl0N DATE Siri?WI Be-7 K-40 Cs-%4 Cs-131 Pb-212 81-214 Pt>-214 Ra-226 Th-??8 STATION N-9.9 02/14/89 (200 3270+-330 <20 <20 126+-13 168+-24 165+-26 <200 124+- 12 l 08/15/89 <200 4800+-480 (20 <20 212+-21 288+-100 304*-45 (400 211*- 21 STATION RE-7.4 02/14/89 <100 1860+-190 (10 <10 92+- 11.2 264+-26 217+-26 370+-140 8.1+- 0.81 08/15/89 <200 2050+-260 <20 <20 107+- 16 178+-32 202+-35 <400 106+- 15 STATION NME-1.0 i 02/14/89 274+-126 2220+-220 <10 20.6+-11.4 82.3+-8.2 188+-19 238+-24 403+-202 90.6+-11 08/15/89 (200 1740+-210 <20 <20 10l+-17 142+-31 157+-36 <400 100+- 17 vi Average +- N 2 sd

  • All other gamma entitters were LtD. f i

s

M M M M - M M M - M M IA8LE 21 (Page 1 of 2) YU ELECTRIC COMANCHE PE AK STEAM ELECTHIC STAllow CONCENTRATIONS Of GAMMA EMiliEW5* IN f000 PRODUCIS AND BROADLEAf WELEIATION Results in pCi/kg (wet) +- 2 s.d. COLLEC110N STATION DESCRIPil0N DATE 8e-7 E-40 1-131 Cs-134 ts-137

  $W-13.5           BL 3 Weeds            05/09/89          20 30+ - 200   9810+-180      < 10 * *     < e     <e FP3 Spinach           06/06/89            231+- 66     6680+-670      (20          < 9     <td FP3 Cabbage           06/06/89            437+- 69     4430+-440      <10          < 8     ( e iP3 Radishes          06/06/89         < 80            5590+-560      <30          (to     <10 BL3 Weed tus          06/06/89            965+- 97      965+- 97      < 6 **       ( 7     < 6 FP3 Cabbage           01/04/89            225+-75      3860+-390      <30          <10     < 9 FP3 Pot ates          G7/04/89         < 70            4730+-470      (20          < 9     < 9 BL3 Weed tus          07/04/89            510 -77      7660+-170      < 6**        <0      < 8 (a

'd FP3 Cabbage 08/01/89 (100 3520+-350 <20 <10 (10 FP3 Potatos 08/01/89 < 60 4450+-450 <10 < 7 <a 8t3 Blood Wd 08/01/89 548+-126 7110+-110 < 1** <lo <20 8t3 Cat Lvs 08/01/89 2290+-230 4670+-410 < 6 ** <20 <20 BL 3 Johnson 08/01/89 1030+-150 2500+-340 < 8** <20 <20 BL3 Tree sus 08/29/89 2240+-510 2600+-670 <8** <50 <50 BL3 Weed 09/25/89 1390+-180 6520+-650 <20** <10 (10 BL 3 Tree tus 10/24/89 3120+-330 3810+-390 <10 ** <20 (20 BL3 Iree tes 11/21/d9 1660+-220 72Pd+-730 <10 ** (20 27.5+-15.4 BL3 Forage grasses 12/12/89 1440+-560 896+-427 (20 ** <eo (60 N-1.45 8tl Tree tvs 05/09/89 1290+-130 5900+-590 (10 ** <10 <lo BLI Sumac tes 06/06/89 1080+-180 5380+-540 (10 ** <20 (20 BL1 Sumac tus 01/04/89 1870+-190 6290+-630 < 7** (20 (20 HL1 Grass 08/01/89 4560+-460 9360+-940 < 6** <30 (40 BLI Sumac Lf 08/01/89 1310+-130 6140+-610 < a** <10 (lo 8tl Sumac 08/29/89 1400+-300 4160+-480 < 7** <30 (30 BL1 Sumac 09/25/89 3080+-340 5850+-580 <20 ** <20 (20 BL1 Sumac Lvs 10/24/89 858+-252 4730+-410 <10 ** <<o <20 8t l Tree Lvs 11/21/89 1830+-290 1690+-770 (20 ** <30 <30 BL1 Forage grasses 12/12/89 5670+-770 5630+-120 <20** <co <10 Average +- 2 sd All other gamma esitters were tto. l adi ne-131 ny radiochemical method

M M M M M M M M M M M - M I Aet t 21 (Page 2 of 2) 10 ELECTRIC COMANCHE PEAK SIEAM ELECTRIC STATION CONCENTRAllon$ Of GAMMA EMITIER5* IN VEGETAlide Results in pCi/kg (wet) +- 7 s.d. COLLECil0N Cs-134 (s-137 DATE 8e-1 K-40 1-133 SIAIXON DESCRIPTION 4310+-430 < 10 * * < 9 < 9

     $W-1.0             812 Tree Lvs         05/09/89         979 +- 98
                                                                                              < 9**       <10   <10 06/06/89         1080+-130        8 310+ -8 30 BL2 Weed Lvs                                                          < 1**       < 8   < a BL2 Weed Lvs         01/04/89           360+-60        9830+-980 359+-78       12300+-1200     < 8 **      <10   (10 BL2 Sunflo.cr        08/01/89                                            8**      (10   (20 BL2 Cotton Gr        08/01/89           son +-106      4060+-410      <

6330+-630 <6** <20 (20 bt2 Sumac Lt 08/01/89 954+-126 3180+-330 4010+-400 < 8** <20 (20 BL2 Sumac 08/29/89 <20 <zo BL2 Sumac 09/26/89 2210+-230 1570+-170 (10 ** l 761+-125 2090+-210 <10 ** <10 (10 812 Tree tvs 10/24/89 <30 <30 11/21/89 1230+-250 6020+-600 (20 ** BL2 Iree Lvs 1870+-520 < 9** <40 <50 BL2 Forage grasses 12/12/89 2780+-480 , $2 Average +- 2 sd 2070+-210 (20 < ! < 1 FP2 Cucumbers 06/06/94 < 10 E-4_2 2770+-280 <30 < 9 <10 FP2 Peas 06/06/89 < 90

                                                                                                          <10   <10 l

f P2 Cucumbers 07/04/89 < 80 1750+-180 <30 2880+-290 <20 < 8 < 8 FP2 Squash 07/04/89 < 70 (10 <10 07/04/R9 <100 2460+-250 <40 TP2 Ok ra

                                                              < 70             2540+-250      <20         <a    <a f P2 Okra            08/01/89                                                     < 6   <6 08/29/89         < 50             2710+-270      <30 Ot r a Average +- 2 sd 4220+-420      <o0         < 6   < 6 EhE-9.0           FP1 Pecans           11/14/89         < 60 Average *- 2 sd
  • All other gamma emit ters were LL D.
      **  todine-131 by radiochemical method l

M M M M M M M M M g m taste 22 (PAGE 1 0F 4) RAD 10 TOG 1 CAL ENVIRotetEMiAL MON!TORIMG PRO 6 RAM 5tFr. arf i U ELECTRIC - COMANCHE PEAK STE AM ELECIRIC SI ATION JANUARY 01 10 DECDEER 31, 1989 NUMata OF ANALYSIS AND ECWER LIMIT 9008tROUllNE LOCATION WITH HIGHE51 ME AN CONTROL 10 CAT 10N MEDItM OR PAllWAV TOTAL MIMBER OF Att INDICATOR LOCAi!ONS ME N?.N(f)(2) ME AN( f )(2) Pf PORIED SAMPiED OF ANALYSES EfiECTION KAN RANGE ME A5UEEME NIS (LLD) (1) RANGE DIST ANCE AND DIRECilOM RANGE (UN!! 0F ME ASUREMENT) PERFORED Eftt-5 0.20(5/5) 0.16(10/10) 0 TIDs Canuma Dose-2tl - 0.16(201/201) (0.13-0.20) (0.11-0.22) (0.12-0.18) (mR/ day) NA MA -(0/52) 0 1-131 411 70 -(0/ 359) AirIodine-g31 (10-3 pCi/m ) -- N-l.45 25(51/51) 25(52/52) 0 Air Particulates Gross Beta 410 10 24(352/358) (10-3 pCi/m3) (5.3-55) (9.5-55) (9.1-51) w

 "                          Gdassa Spec 32 E-3.5                    11(4/4)               11(4/4)               0 Be-7                     -

12(28/28) (60-99) (68-99) (66-81) SW/W5W-0.95 15(1/4) -{0/4) 0 K-40 - 12(4/28) -- -- (9.3-15) M -(0/4) 0

                         " Cs-134                    -
                                                                     -(0/28)               MA l

Cs-137 -

                                                                     -(0/28)               NA                       G                     -(0/4)                O NA                    -(0/4)                0 Ro-103                   -
                                                                     -(0/28)               MA

{}} 110 ss lower inmat of detection as defined and req <eired in USNRC Bran (h Technical Position on an 4cceptable Radtolo<jical Environmental honitoring Program. Revtsten 1. November 1979. (2) (f ) is the ratio of positive results to the nundrer of samples analyzed f or the parameter of interest, means are of posttive results only.

M M M M M M - M ' M M IABLE 22 (PAGE 2 0F 4) RADIOLOGIEAl ENVIRD? MENTAL MONITORING PROGRAM

SUMMARY

I U EtECIRIC - 00MANCHI PEAK STEAM ELECTRIC STATION JANUARY 01 TO DECEMBER 31. 1989 ANALYSIS AND LOWER LIMIT MUPEER OF MIDIUM OR PAliniAY TOTAL IEDGER OF Att INDICATOR LOCAi!ONS LOCAil0N WiiH HIGHE57 MEAN CONTROL LOCATION NONROUllNE SAMPLE 0 Of ANALYSES DETECil0N KAN NAME KAN(f)(2) ME AN(f)(2) RE POR TE D (tiNIT Of K ASUREMENT) PERFORED (LLD) (1) RANGE DISTANCE AfD DIREC110N RANGE RANGE ME ASURE MENT S Milk I-131 (38) -

                                                                    -(0/19)                  MA                      NA                 -(0/19)              0 (pCi/l)                 (BY RAD 10 CHEMISTRY)                        --

Gamma Spec (38) Cs-137 -

                                                                    -(0/19)                  NA                      NA                -(0/19)               0 K-40                        -

1298(19/19) 5W-13.5 1379(19/19) 1379(19/19) 0 (1150-1510) (1110-1560) (1810-1560) Surface Water Gamma Spec (52) -

                                                                    -(0/39)                  NA                      M                 -(0/13)               0 (pCi/l)                                                              --

u Tritium (16) 2000 -(0/12) RA NA -(0/4) o e _. __ l-131 (16) -(0/12) NA NA -(0/4) 0 (BY RADIOCHEMISTRY) Ground Drinking Gamma Spec. (30) -

                                                                    -(0/24)                  R4                      NA                -(0/6)              0 Water                                                               --

(pct /1) Tritium (20) 2000 -(0/16) NA NA -(0/4) 0 Gross Beta (57) 4 7.0(16/20) W-1.2 8.0(5/5) 3.0(5/5) 0 (I.0-10) (1.0-10) (2.2-3.9) 1-131 (50) 1 -(0/40) MA NA -(0/10) 0 (BY RADIOCHEMISTRY) -- (I) LID is lower limit of detection as oefined and requsred in 'f5NRC Branch leth9f cal Potition on an Acceptable Radiological Environmental ibnitoring Pro 9 ram. Revision 1. November 1979. (2) (f) is the ratio of positive results to the number of samples analyzed for the paraeeter of interest, means are of positive results only.

M M M M M M M M M M m M M M M Y ABL E 22 (PAGE 3 0F 4) RADIOLOGICAL ENVIRose(NTAL MDalf0 RING PROGRAM 511P98 SAT T U EEECTRIC - COMANLeiE PE AK STE A't ELECTRIC STAitom jam *RY 01 TO DECEMBER 31. 1989 ss.1PetR OF ANAL 7515 A e LOWER LIMIT ComTRCt LOCATIM IE,uiPOUTimE TCTAL tapeER OF ALL IND'CATOR EOCAT10 mis LOCAT10m WITN MIGHEST MERN MEDitst OR FATHWAV M AN(f)(2) RfPORTED OF ANALYSES DETECT 104 E AM MME N AR(f)(2) SAMPE ED RA8tGE ME AstFEm mI5 (LLD) (1) PAMGE DISTANCE AM) DIRECTION RANGE (01:1T 0F fE Aste. EMENT) PERFORPED - 24 4A .[0/15) 0 Water-Serface Genuse .5per. (30' -

                                                                      -(0/15)                                                                --

Drinking (pct /l) 44 MA -(0/4) 0 Tritiuss (8) 2000 -(0/4) 4A ftA -(0/21) 0 todine-131 (54) -(0/27) -- (Bf RADIOCHEMISTRT) hMW-0.1 16(15/15) 14(15/15) 0 Gross Beta (30) 16(15/15) (13-21) (13-21) (9.0-21) Fish Gaaune Spec (II) u, (pC f /k g wet ) 3485(6/6) 3144(5/5) 0 at-40 - 3435(6/6) ENE-2/FI w (2130-4490) (1960-3930) (2730-4490) E3EE-2/E l 13(1/6) -(0/5) 0 Cs-131 - 13(1/6) -- .. Shoreline Ga- w Spec (6) Sediments R-9.9 228(2/2) 228(2/2) 0 (pCf /kg dry) Bi-214 - 19)(4/4) (142-264) (168-288) (1o8-288) m-9.9 2 35(2/2) 2 35(2/2 ) 0 Pb-214 - 204(4/4) (157-238) (165-304) (165-304) l E-9.9 169(2/2) 169(2/2) 0 I'b-212 -

                                                                      %(4/4)

(82-107) (126-212) (126-212)

M M M M WIb M M M M M M M IABLE 22 (FAE 4 0F 4) RADIOLOGICAL ENVIRose= ENTAL M04ITORI% FROGE AM 51JPetAEY T U ttECTRIC - COMANCE PEAK STEAM ELECTRIC 514T104 JAfrJART 01 TO DECEPeER 31, 1989 APALYSIS Ase)

  • Cteta Lleili supsta OF ME0llM OR PATHWAY TOTAL MIMBER OF All INDICATOR LOCATIONS LOCATION WIirt HIGM5T ME AM C0his'0L LOCA!!0m le0NROUTINE SAMPLED OF ANALYSES DETECTION EAR NAN PEAN (f)(2) M AM(f )(2) stPORTED (UNIT OF NA5UREMENT) PERFORN D (LLD) (1) RARE DISTANCE AND DIRECitom RANGE RAME ME ASUREME NT$

Shoreline It-40 - 196 (4/4) DME-1.0 4035{2/2) 4035(2/2) 0 Sedisents (l740-2220) (3270-4800) (3210-4800) (pCf /kg dry) Ra-226 - 381(2/4) RNE-l.0 403(I/2) -(0/2) 0 (310-403) - -- ib-228 - 76(4/4) 4-9.9 168(2/2) 168(2/2) 0 (8.1-106) (124-211) (124-211) Cs-131 - 21(!/4) MME-l.0 21(1/2) -(0/2) c Be-7 - 274(1/4) MM-I.G 214(1/2) -ic/2) 0 g -- - -- Vegetation Gassma Spec (41) (pCf /kg eset) K-40 - 4959(29/H) N-I.45 6113(10/10) 4831(18/18) 0 (1570-12.300) (4130-9360) (896-9610)) Be-7 - 118t(21/29) N-I.45 2294(10/10) 3294(14/18) 0 (359-5670) (858-5610) (225-3120) (s-137 -

                                                                                                    -(C/29)                                                                                                                    M                                                               MA                    -(0/18)            o (1) LLD is towar limit of detection as defined and required in USNRC Branch Techattal Fesit6cn on an Acceptable Radiological Environmental Mwitoring Program, sevision 1, november 1979.

(2) (f) is the ratio of positive results to the mueber of samples awlyree for the parameter of inte<est, an=ans are of positive results only.

I I I I I I I I I I APPENDIX A l EPA CROSS-CHECK PROGRAM I I I I I I I I $9

l I US EPA INTERLABORATOTRY COMPARISON PROGRAM 1989 I Collection Teledyne Date Media Nuclide EPA Resultfa) Isotopes Resultfb) I 01/06/89 Water Sr 89 40.00 1 5.00 37.00 2.65 Sr 90 25.00 i 1.50 26.00 2.00 01/20/89 Water Gr Alpha 8.00 5.00 8.00 1.00 Gr Beta 4.00 1 5.00 6.00 0.00 02/10/89 Water Cr 51 235.00 t 24.00 245.67 11.72 Co 60 10.00 t 5.00 12.67 1.53 Zn 65 I Ru 106 Cs 134 159.00 t 178.00 i 10.00 t 16.00 18.00 5.00 181.33 191.00 10.33 5.51 (c) 9.85 0.58 Cs 137 10.00 t 5.00 13.67 0.58 02/17/89 Water 1131 106.00 11.00 98.67 i 0.58 l 02/24/89 Water H3 2754.00 i 356.00 2866.67 251.66 03/10/89 Water Ra 226 4.90 t 0.70 5.07 0.29 l Ra 228 1.70 i 0.30 1,47 0.29 03/31/89 Air Filter Gr Alpha 21.00 i 5.00 28.67 1.15 (d) I Gr Beta Sr 90 Cs 137 62.00 t 20.00 i 20.00 t 5.00 1.50 5.00 65.67 19.67 18.00 1,53 2,08 1.00 04/18/89 Lab Perf. Gr Alpha 29.00 i 7.00 21.33 2.31 Water Ra 226 3.50 i O.50 3.47 1 0.23 3.60 t 0.50 3.60 t 0.10 I Sample A Sample B Ra 228 Gr Beta Sr89 57.00 8.00 t 5.00 5.00 53.00 t 8.00 3.61 0.00 Sr 90 8.00 i 1.50 7.67 t 0.58 I 4-Cs-134 Cs 137 20.00 i 20.00 i 5.00 5.00 19.67 1 20.00 1,53 2.65 l 04/28/89 Math Sr 89 Sr90 39.00 t 55.00 i 5.00 3.00 36.67 t 56.33 t 1.15 1.53 Cs-137 50.00 5.00 53.33 2.31 l K 1600.00 i 80.00 6.00 i 1760.00 6.33 113.58 (e) 0.58 05/05/89 Water Sr89 5.00 l Sr 90 6.00 1.50 6.33 t 0.58 2/8/90 I 60

I I US EPA INTERLABORATORY COMPARISON PROGRAM 1989 (Cont.) Collection Teledyne Date Media Nuclide EPA Result (a) Isotopes Result (b) 06/09/89 Water Ba 133 49.00 1 5.00 33.00 3.61 (f) l Co 60 Zn 65 31.00 165.00 i 17.00 5.00 30.00 1 165.33 1 2.65 0.58 Ru 106 128.00 1 13.00 113.67 17.50 I Cs 134 Cs 137 39.00 1 20.00 5.00 5.00 34.00 22.00 2.65 3.61 06/23/89 Water H3 4503.00 450.00 4466.67 152.75 08/25/89 Air Filter Gr Alpha 6.00 t 5.00 8.33 0.98 Cs 137 10.00 i 5.00 12.00 1.00 09/22/89 Water Gr Alpha 4.00 t 5.00 5.00 5.00 Gr Beta 6.00 i 5.00 8.00 t 0.00 10/06/89 Water Ba 133 59.00 t 6.00 51.00 t 4.36 (g) Co 60 30.00 1 5.00 30.67 2.08 l Zn 65 Ru 106 129.00 t 161.00 i 13.00 16.00 128,33 t 139.00 1 2.89 15.72 (g) Cs 134 29.00 t 5.00 23.67 1 1.15 l Cs 137 59.00 t 5.00 61.67 1 1.53 10/20/89 Water H3 3496.00 i 364.00 3433.33 57.74 11/10/89 Water Ra 226 8.70 i 1.30 8.47 0.49 I Ra 228 8.57 i 1.40 8.57 1.46 I I I I I 2/8/90 I 61

I I US EPA INTERLABORATORY COMPARISON PROGRAM 1989 (Cont.) Footnotes: (a) EPA Results Expected laboratory precision (1 sigma). Units are pCL/ liter for water, and milk except K is in mg/ liter. Units are total pCi for att paruculate filters. (b) Teledyne Results Average 1 one sigma. Units are pC1/ liter for water and milk except K is in mg/ liter. Uruts are total pC1 for air paruculate filters. (c) 'the three Zn 65 measurements were 184,175 and 185 pC1/ liter. These wert measured on three detectors ustng the same aliquot. The other reported results (Cr 51. Co 60. Ru-106 Cs 134. Ca 137) were all within two standard deviations of the EPA results. nts I would indicate that the diluuon tnade was correct (except that possibly the Zn 65 was not well mixed). Other parameters wert investigated, ne branching intensity, decay factor, and detection einciencies were checked. Since one of the Co 00 gattuna ray I energies is only 60 kev from Zn 65, the detector emetencies must be correct. There is no otutous reason for the devtauon. Another aliquot will be prepared from the original solution and will be counted. I (d) ne EPA deposits activtty on the filter over a small diameter (nearly a point sourcel whereas our calibration is based on a deposit nearly 2 inches in diameter. In order to correct to potnt source geometry our pracuce has been to divide our results by 1.2 We I h) neglected to do it on this test, Dert is no apparent reason why the potasatum was h h. Arte separate detectors were used and the K 40 value for each was wrectly dMded 0.86 to corrvert to potassium in mO/ liter. (f) There is no apparent resson why Ba 133 was low by 5.54 standard deviation while the other isotopes were withtn i 2 standani deviations. The detector efnctencies and Ba. I 133 branching intensities were checked and found to be correct. On 10/31/89,300 ml of the original, trradiated sample was counted giving 43.9 i 5.8 pCi/ liter Ba 133. (g) This EPA sample was counted in two geometries; one in diluted stage, the other undiluted. There was no significant difference. Comparing detector efficiencies between two annual sets did not reveal arry significant difference, nus there is no apparent reason why our results differed as much as they did. I I I I I I ai.iw I 62

   ,_,4.tm,,.-= ,a4,mA"-6MSw""                                                               ,m, . L has 4e -ee M A --44   "**M'*****

\

I I

I

I
 ,           I I

lI I APPENDIX B ,l SYNOPSIS OF ANALYTICAL PROCEDURES

I iI t

I t 63

I I APPEtiDlx B APPLICABLE PROCEDURES I I fM BER TITLE DATE PAGE PRO 032-10 Determination of Gross Beta 03/01/87 65 in Air Particulate filters PRO 032 35 Determination of Tritium in Water 12/30/87 66 by Liquid Scintillation Determination of Radiciodine 08/01/88 67 I PRO 032-11 in Milk and Water Samples Environmental Thermoluminescent 09/04/87 68 PRO-342-17 Dosimetry (TLD) Determination of Gamma Emitting 10/26/84 69 PRO-042-5 Radioisotopes I PRO 032-1 Determination of Gross Alpha and/or Gross Beta in Water Samples 03/21/86 71 I I I I I e4

1 i iI l l GROSS BETA ANALYSIS Of SAMPLES

                                                                                                                                                                             +

Air ParticulStes After a delay of five or more days, allowing for the racon-222 ano

radon-220 (thoron) caughter products to decay, the filers are counted in a gas flow proportional counter. An unused air particulate filter, supplieo by I TV Electric, is counted as the blank.

Calculations of the results, the two sigma error and the lower limit of detection (LLD). RESULT (pCi/m3 ) = ((5/T) - (B/t))/(2.22 Y E) 2 2 TWO SIGMA ERROR (pC1/m ) 3

                                                                      = 2((S/T ) + (B/t ))l/2 (2.22          /            V E) l                     LLD (pCi/m3 )

where:

                                                                      =4.66(Bl/2)/(2.22 V E t) 5 = Gross counts of sample including blank B = Counts of blank

, a E = Counting efficiency T = Number of minutes sample was counted l g t = Number of minutes blank was counted V = Sample aliquot size (cubic meters) I l l l 65

 .__.-_.m-__.__..____.______                             _      _ - _ _ _ _ _ . . - _ _ - -                               _ _ - .       _ . _ . . .

!f II ANALYSIS OF WATER SAMPLES FOR TRIT!UM One milliliter of water is added to 20 mi of liquid scintillation ' The sample is inserted into a Liquid Scintillator Solution in a 25 mi vial. l 1 1 and counted for 100 minutes. Calculations of the results, the two sigma error and the lower limit i of detection (LLD). l RESULT (pCi/l) = ((S/T) - (B/t))/(2.22 V E ) TWO SIGMA ERROR (pCi/f) = A2((mu g2T S IB/J (S/t ))1/2 2 i(2.22')Y' /(1.t?. i :--)- A V E ') . LLO(pCi/t) = 4.66 (B1 /2)/(2.22 V E t) where S = Gross counts of sample B = Counts of blank E = Counting efficiency T = Number of minutes sample was counted t = Number of minutes blank was counted . V = Sample aliquot size (f) 1 l% 6 -

I I ANALYSIS OF SAMPLES FOR 100!NC 131 I Milk or Water Two liters of sample are first equilibrated with stable iodide carrier. A batch treatment with anion exchange resin is used to remove iodine from the sample. The iodine is then stripped from the resin with sodium hypochlorite solution, is reduced with hydroxylamine hydrochloride and is extracted into carbon tetrachloride as free iodine. It is then back extracted as iodide into sodiurn bisulfite solution and is precipitated as palladium iodide. The I precipitate is weighed for chemical yield and is mounted on a nylon planchet for low level beta counting. The chemical yield is Corrected by measuring the stable iodide content of the milk or the water with a specific ion electrode. Calculations of results, two sigma error and the lower limit of detection (LLD) in pCi/l: RESULT = (N/At-8)/(2.22 E V Y OF) TWO SIGMA ERROR = 2((N/At+B)/At)l/2(2.22 E V Y OF) l LLO = 4.66(8/At)l/2 /(2.22 i V Y DF) where: N = total counts from sample (counts) l At = counting time for sample (min) B = background rate of counter (cpm) l l 2.22 = dom /pC1 1

                         = volume or weight of s mple analyzed V

l l- Y = chemical yield of the mount or s mple counted DF = decay factor from the collection to the counting date E = ef ficiency of the counter for 1-131, corrected for self absorption effects by the formula i E = E (exp-0.0061M)/(exp-0.0061Mg ) 3 E 3

                         = ef ficiency of the counter determined from an l-131 Standard mount l

M = mass of Pd!2 on the standard mount, mg 3 M = mass of Pd!2on the sample mount, mg 6h

I 1 i l ENVIRONMENTAL DOS! METRY Teledyne Isotopes uses a CaSO4 :Dy thermoluminescent dosimeter (TLD) which I the company manufactures. This material has a high light output, negligible thermally induced signal loss (f ading), and negligible self dosing. The energy response curve (as well as all other features) satisfies NRC Reg. Guide 4.13. Transit doses are accounted for by use of separate TL0s. Following the field exposure period the TLDs are placed in a Teledyne Isotopes Model 8300. One fourth of the rectangular TLD is heated at a time and the measured light emission (luminescence) is recorded. The TLD is then annealed and exposed to a known Cs-137 dose; each area is then read again., This provides a calibration of each area of each TLD af ter every field use. The transit controls are read in the same manner. Calculations of results and the two sigma error in net milliRoetgen (mR): l RESULT = 0 = (0 1+02+03+04 )/4 TWO S!GMA ERRORg = 2((O 20)2+(0 -0)2+(0 3 40)2+(0 0)2)f 3)W where 0 3

                    = the net mR of area 1 of the TLO, and similarly for 0 , 0 , and 0 4 2   3 i

Og =I g K/Rg-A Ig = the instrument reading of the field dose in area 1 K = the known exposure by the C5-137 source R y = the instrument reading due to the Cs-137 dose on area 1 l l A = average dose in mR, calculated in similar manner as above. ! u of the transit control TLDs lI I

I I

a lI

I GAMMA SPECTROMETRY OF SAMPLES Milk and Water A 1.0 liter Marir4111 beaker is filled with a representative aliavot of the I s ample . The ,aple is then counted for at least 1000 minutes with a shielded Ge(Li) detector coupled to a mini-computer-based data acquisition system which performs pulse height analysis. Dried Solids Other Than Soils and Sediments A large quantity of the s mple is dried at a low temperature, less than 100*C, As much as possible (up to the total sample) is loaded into a tared 1-liter Marinelli and weighed. The sample is then counted for at least 1000 minutes with a shielded Ge(L1) detector coupled to a mini-computer-based data acquisi-tion system which performs pulse height analysis. Fish As much as possible (up to the total samole) of the edible portion of the sample is loaded into a tared Marinelli and weighed. The senple is then counted for at least 1000 minutes with a shielded Ge(L1) detector coupled to a I mini-computer based data acquisition system which performs pulse height analysis. Soils and Sediments Soils and sediments are dried to a low temperature, less than 100*C. The soil or sediment is loaded fully into a tared, standard 300 cc container and I weighed. The sample is then counted for at least six hours with a shielded Ge(Li) detector coupled to a mini-computer based data acquisition system which performs pulse height analysis. Charcoal Cartridges (Air lodine) Charcoal cartridges are counted up to five at a time, with one positioneo on ! I the f ace of a Ge(Li) detector and up to four on the side of the Ge(Li) detector. Each Ge(L1) detector is calibrated for both positions. The detection limit for !-131 of each charcoal cartridge can be determined (assum. I ing no positive I 131) uniquely from the volune of air which passed througn it. In the event I-131 is observed in the initial counting of a set, each charcoal cartridge is then counted separately, positioned on the face of the detector. lI 1 Air Particulate I The four or five (depending on the calendar month) air particulate filters for a monthly composite for each field station are aligned one in front of another and then counted for at least six hours with a shielded Ge(Li) detector coupled to a mini-computer-based data acquisition system which performs pulse height analysis. 69

l l I I A mini-computer sof tware program defines peaks by certain changes in the l slope of the spectrum. The program also compares the energy of each peak with I I a library of peaks for isotoDe identification and then performs the radio-activity calculation using the appropriate fractional gamma ray abundance, half life, detector ef ficiency, and net Counts in the peak region. The I calculation of results, two sigma error and the lower limit of detection (LLD) in pCi/ volume or pCi/ mass: 1

                                                                                                                                                                         )

RESULT = (S-B)/(2.22 t E y F DF) I TWO SIGMA ERROR = 2(S+B)1/2/ (2.22 t E V F OF)

                                                                       = 4.66(B)I/2/(2.22 t E V F 0F)

I LLD where: $ = Area, in counts, of sample peak and background (region of spectrum of interest) B = Background area, in counts, under sample peak, deter-mined by a linear interpolation of the representative backgrounds on either side of the peak t = length of time in minutes the sample was counted 2.22 = dpm/pCi I E = detector efficiency for energy of interest and geometry of sample V = saple aliquot size (liters, cubic meters, kilograms, or gr ams) F = fractional gamma abundance (specific for each emitted gamma) DF = decay factor from the collection to the counting date I 70

I 1 I DETERMINATION OF GROS $ alpha AND/OR GROSS BETA ACTIVITY IN WATER SAMPLES

1.0 INTRODUCTION

The procedures described in this section are used to measure the overall radioactivity of water samples without identifying the radioactive species present. No chemical separation techniques are involved. One liter of the sample is evaporated on a hot plate. Different volumes may be used if the sample has a significant salt content as measured by a conductivity meter, or if unusual sensitivity is desired. If requested by the customer, the sample is filtered through No. 54 filter paper before evaporation, removing particles greater than 30 microns in size. Af ter evaporating to a small volume in a beaker, the sample is rinsed into a 2-inch diameter stainless steel planchet which is stamped with a concentric ring pattern to distribute residue evenly. Final evaporation to dryness takes place under heat lamps. Samples which appear to be hygroscopic are dried again under heat lamps just prior to counting. Residue mass is detemined by weighing the planchet before and after mounting the sample. The planchet is counted for alpha and/or beta activity on an automatic proportional counter. Results are calculated using empirical self-absorption curves which allow for the change in effective counting efficiency caused by the residue mass. l l l 71

I 1 2.0 DETECTION CAPABILITY Detection capability depends upon the sample volume actually repre. sented on the planchet, the background and the efficiency of the counting instrument, and upon self-absorption of alpha and beta particles by the mounted sample. Because the radioactive species are not identified, no decay corrections are made and the reported activity refers to the cuunting time. The minimum detectable level (MOL) for water suples is nominally l 1.6 picoeuries per liter for gross beta at the 4.66 sigma level (1.0 pCi/l at the 2.83 sigma level), asstning that 1 liter of suple is used and that 1/2 gram of suple residue is mounted on the planchet. These figures are based upon a nominal counting time of 50 minutes and upon representative values of counting efficiency and background of 0.2 and 1.2 cpm, respectively. The MOL for gross alpha activity is nominally 2.3 picoeuries per litec at the 4.66 sigma level (1.4 pCi/t at the 2.83 sigma level) also assuming thot 1 liter of suple is used and that 1/2 gra of smole residue is mounted on the planchet. These figures are based upon a nominal 200 minute counting time ard upon a representative efficiency of 0.02 and a background of 0.1 cpm. The MDL becomes significantly lower as the mount weight decreases because of reduced self-absorption. At a zero mount weight, the 4.66 sigma MOL for gross beta is 0.9 picrocuries per liter and the MOL for gross alpha is 0.3 picoeuries per liter. These values reflect a beta counting efficiency of 0.38 and an alpha counting ef ficiency of 0.18. 72

 -a----a.mmeenm-smu se e m e su s - -munsm-e e2--- a+wm-eew sm wmemsus                              ama-seLM M amasai-       -^Mam 4

l i

I i

l l l l l l APPENDIX C EXCEPTIONS TO THE 1989 REMP l l l l l I I I n

                                                                                                                                   \

APPEN0ix C REMP PROGRAM EXCEPTIONS FOR SCHEDULED SAMPLING AND ANALYSIS DURING 1989 Date of Reasons for Loss / Location Cescription Sampling Exception Sta-hE-4.8 Direct Radiation First Quarter TLD missino, vandalized St a- SE- 3. 84 Direct Radiation First Quarter TLD missing, vandalized Sta-NE-4.8 Direct Radiation Second Quarter TLD missino, vandalized Sta-NE-4.8 Direct Radiation Annual Replacement, put in field on 07/10/69 l St a-SE-3. 8 5 Direc; Radiation Annual Repl acement, put in field on 04/07/89 Sta NW-1.0 Air Filter 05/02/89-05/09/89 Pump out of service Sample not collected Service power off* Sta NW-1.0 Air Filter 05/16/89-05/23/89 Pump out of service Sample not collected Service power off* Sta-NW-1.0 Air Filter 06/13/89-06/20/89 Pump out of service Sample not collected Service power off* Sta-hW-1.0 Air Filter 06/20/89-06/27/89 Pump out of service Sample not collected Service power off* St a-E-3.5 Air Filter 08/22/89-08/29/89 Pump out of service Sample not collected Pump vanes broken Sta-N-1.45 Air Filter 03/07/89-03/14/89 Fit crooked. Sample not collected i St a-NW-1.0 Air charcoal 05/02/89-05/09/89 Pump out of service Service power off* S t a-NW- 1.0 Air charcoal 05/16/89-05/23/89 Pump out of service Service power off* Sta-NW-1.0 Air charcoal 06/13/89-06/20/89 Pump out of service Service power off* Sta-NW-1.0 Air charcoal 06/20/89-06/27/89 Pump out of service Service power off* 74

APPEh0!X C I REMP PROGRAM EXCEPTIONS FOR SCHEDULED SAMPLlhG AND ANALYS15 DURING 1969 l Date of Reasons for Loss / Location Description samplino Exception dta-M-1.0 Air charcoal 05/09/89-05/16/69 deouired LLD for 1-131 not acnieved due to delay in shipment Sta E-3.6 Air enarcoal 08/22/89 08/29/89 Pump out of service

I Pump vane broken No tree lys available i Sta-SW 13.5 Venetation 12/12/89 l

l Collected forage grasses Air enarcoal 12/12/89-12/19/89 Requirea LLD for l-131 I Sta N-1.45 not achieved due to low sanple volume re-sulting from removal of power from the pump S t a- N- 1. 4 5 Vegetation 12/12/69 No tree Ivs available Collected forace I grasses Sta-SW-1.0 12/12/89 No tree lys availaole Ve9etation I Collectea forace grasses Required LLD's for I-131 I Stations W 1.2 WSW-0.1, SSE , 0, N 9.8 Groundwater 10/03/89 not acnieved due to delay between sample collection and Malysis Stations NE-7.4, Surface Water 06/06/89 Required LLD for 1-131 ESE-1.4 not achieved." St ations N-1.5 Surface Water 09/25/89 Required LLD for 1-131 NE-7.4, not achieved" I ESE-1.4 St ations N-1.5 Surf ace Water 11/21/89 Required LLD for 1-131 l I N-19.3, NE-7.4, ESE-1.4 not acnievea" 75

4

                                                               /PPENDIX C I                                           REMP PROGRAM EXCEPTIONS FOR SCHEDULED SAMPLING AND Atu. LYSIS DURikG 1989 I

I I I I

  • Severe electrical storms striking system tripping service power. System fuses reset except for final service power to this station.
               **The required LLD for 1-131 in water if there is no drinking water pathway is 15 oCi/1. This LLO was not achieved due to confusion over elimination of the I-131 analysis for drin91ng water for these locations. TV notified Teledyne Isotopes Dy telephone and by letter of this discrepancy. TU letter CPSES-I               8901210 is attached.

76

I I == r

                                                                                     =         =

71/ ELECTRIC CPSES 8901210

 , I                                                                                                   December 13, 1989 No Response Required Dr. David Martin Teledyne Isotopes 50 Van Buren Ave.

Vestwood, New Jersey 07675 SUBJ ECT: CPSES STEAM ELECTRIC STATION LLD REQUIREMENTS

Dear Dr. Martin:

In reference to our phone conversation of December 8,1989, we request that an LLD requirement of 15 pCL/L on Iodine 131 be met on Camina Isotopic for all waters submitted by this company. Thank you again for your cooperation, If you have any questions please call me at 817 897 5337, Sincerely, w s ' /,'ely sEssej/-l' { Wues Chuck Curry Environmental Technician, Sr. ec: E. J. Schmitt 009 D C. Kay 009 CCS E06 I - I l l P.O. Son D00 Oka stoes, Tesas 1604bil47 7 7_ . . _ _ _ _ _ _ _ _

AW#mmpAW-N NA.WhM Mh.44 h MWM

                                                 - -                                              - m -*

4 I I I I I I I I I APPENDIX D l EXCEEDED REPORTING LEVELS I I - I I I 78

1 4 iI i I i APPENDIX D 1

EXCEEDED REPORTING LEVELS
1 l

l r j . i 1989 None of the analytical measurements exceeded any notification , level. I I I i i I I I l l 79

_4.k.a h h' -_aSa.m.hAJ"' 'mAM.h.am,&-" !I I l l I I l l APPENDIX E 1 l LAND USE CENSUS I lI I . 80

i LAND USE CENSUS The Land Use Census for 1989 was conducted in August 1989. It indentifies receptors within a five (5) mile radius of the plant in each of the sixteen (16) meteorologi cal sectors. The Land Use Census includes the following items: Title

1. Population by Sector and Distance
2. Nearest Resident by Sector and Distance
3. Nearest Garden by Sector and Distance
4. Nearest Milk Animal by Sector and Distance
5. A Map with an Accompanying Map Legend
6. Environmental Sampling Locations Public Use Areas I Listed below are public use areas within the five (5) mile radius and the approximate attendance for the areas in 1988:
1. Camp Arrowhead - 3500
2. Dinosaur State park - 219,000
3. Glen Lake Camp - 6,175
4. Cedar Brake Girl Scout Camp - 250
5. Squaw Creek Park - 46,900
6. Kellers Camp - 6,000 March to November
7. Tres Rios Camp - 40,000
8. Oakdale Camp and Fish - 5200
9. Oakdale Park - 69,000
10. Creation Science Museum - 12,000 lI 81

I i I l Populations By Sector and Distance 1

g Sestor Distanca.1511esi 4-1 1-2 2-3 3-4 4-5 Total N - - 3 22 55 88 l l
 =                            NNE                              -                           -

12 55 17 84 NE - - 68 86 222 368 ENE - - 46 7 22 75 E - - 22 173(1) 34(2) 229 ESE - - 7 86 91 184 ) SE - - 43 22 36 101 t l SSE - 24 22 22 2544 2616 l 5 - 19 7 31 91 148

                        ' SSW                                  -

3 5 3 43 54 SW - 98 5 36 22 161 I WSW - 134 3 7 - 144 W - 54 5 36 7 146 WNW - 3 7 19 74 183 NW - - - - - 0 NNW - - 3 29 7 39 TOTAL - 335 254 634 3269 4484 Baa d on an average of 2.4 residents per house. (Obtained from North l I central Temas Council of-Governments, 1944 based on an average from 2.6 for eingle family, 1.8 for mobile home and 2.66 for multi family residences. l l 1 (1) Includes permanent residents at Happy Hills Children's Home. (2) Includes permanent residents at Camp Arrowhead. I i 82

l

                              .- - .--          ._- - ~ _

l l l Nearest Resident by Sector and Distance 5 ester Distance.1511esi i N

2. 2 NNE 2. 3 NE 2. 3 l -

E

2. ,
2. 4 I - 2. .

SE I SSE 2.1

1. 6 5 1. 6 SS. 1. g I .. 1. .

WSW 1. . W 1. 5 g 2. . NW None NNW 2. 7 I - l 83

      - . . _ - . - . . - - - - - . - ~ - -        -

Nearest Garden by Sector and Distance I 5esist Distance.1511esi N None NNE

2. 4 NE
2. 7 ENE
2. 5 E
3. 5 ESE
2. 3 SE
2. 5 ,

SSE

2. S e S
1. 9 SSW Nones SW 1. 6 e WSW 1. 3 W
1. 5 WNW 3. 8 I NW None NNW 4. 5 m

Denotes change from previous year I l l l l l 84

I I Nearest Milk Animal by Sector and Distance Easter Distance Hiles SSE 2. 2 WNW 4. 9 NNE 4. 5 All other Sectors None I I I I I I I . I I I L I I I 85

L I EVALUATION OF 1989 LAND USE CENSUS I The results of the 1989 1and Use Census were reviewed for impact on the Radiological Environmental Monitoring Program (REMP). The sampling program requirements that could be affected by changes in land use ares (1) Milk - ODCM Table 3.12-1 requires that samples be obtained from milking I animals in three locations within 5 km having the highest potential dose. If none are available, samples are acceptable f rom milking animals in locations 5 to 8 km distant where doses are calculated to be greater than 1 mrem per year. A sample is also required at a control location. Currently, milk samples are collected at one indicator location (SSE-2,2) and at a control location. (2) Food Products - ODCM Table 3.12-1 requires that one sample of each principal class of food product be collected f rom any area that is irrigated with water _ in which liquid plan: wastes have been discharged. Currently, food products are sampled from two indicator locations: (ENE-9.0, Pecans; E-4.2, vegetables) and one control location. (3) Broadleaf Vegetation - ODCM Table 3.12-1 requires a sample of broadleaf vegetation from each of two of fsite locations of highest predicted annual average D/Q if milk sampling is not performed at all required locations. I currently, broadleaf vegetation samples are collected at two indicator locations (N-1.45 and SW1.0) and one control location. These locations are near the site boundary in sectors where broadleaf is available and D/Q is greatest. Based on these requirements, the milk animals identified at locations NNE-4.5 and VNW4.0 were evaluated f or possible inclusion in the RDfP. The land owners at these locations were contacted by Chemistry and Environmental Personnsi and it was determined that these milk animals are not milked and tre not available for sampling. Also, the goats identified at location NE-3.9 are considered " brush goats" and are not available for sampling. Therefore, no changes to the milk sampling locations of the REMP are required. Of the gardens that were identified, no new gardens were identified that are irrigated with water in which liquid plant vastes are discharged. Therefore, no change to the REMP is required. Finally, since broadleaf vegetation is currently collected at the site boundary, no changes to broad leaf sampling locatione are required. There are no identified locations closer to the plant. Evaluation Performed by: . Date: 7' /f

  • iT g .1th hys1crt 86

M M M M M-M M M M , M - I i ENVIRONMENTAL SAMPLING LOCATIONS Sample sampling Location Sample Sample Sampling tocation Sampling Location Type

  • Point (Sector-Miles) Type
  • Point ($cttor-Miles) Type
  • Point (Sector-Miles)

R14 E-4.2 R R40 kW-5.7 R Al N-1.45 A nW-9.9 R RIS ESE-1.4 a R41 A2 R-9.4 A a R42 anW-1.35 R A3 E-3.5 A R16 ESE-4.7 A SE-1.3 R R43 hhW-4.6 A4 55E-4.5 A RIF N-1.5 SW AS 5/55W-1.2 A R18 SE-3.85 R SW1 N-9.9 SW/UW R19 SE-4.6 a SW2 A6 SW-12.3 A N-19.3 SW A R20 55E-1.3 H SW3 A7 SW/W5W-0.95 SW4 NE-7.4 SW NW-1.0 A R21 55E-4.4 R A8 R22 55E-4.5 R SW5 ESE-1.4 5W 5-1.5 R SW6 NhW-0.1 SW/DW R23 R24 T-4.2 R 6WI W-1.2 GW/DW R 6W2 W5W-0.1 GW/DW R25 55W-1.1 GW/DW 55W-4.4 W GW3 55E-4.6 R26 GW/UW SW-0.9 R GW4 4-9.8 R1 N-1.45 R R27 GW/DW SW-4.8 R GWS N-1.45 R2 N-4.4 R R28 nmE-1.0 55 d29 SW-12.3 a 551 R3 N-6.5 R W5W-1.0 R 552 N-9.9 55 N-9.4 R R30 55 R4 R31 W5W-5.35 R 553 NE-7.4 l R5 NNE-1.1 R MI 55E-2.2 M NNE-5.65 a R32 W5W-7.0 R R6 R M4 S W - 13. 5 M NE-1.7 A R33 W-1.0 R7 F1 ENE-2.0 f NE-4.8 R R34 W-2.0 R R8 T2 anE-8.0 f ENE-2.5 R R35 W-5.5 R 23 A9 WNW-1.0 a fPl EnE-9.0 IP RIO ENE-5.0 R R36 IP WNW-5.0 R IP2 E-4.2 E-0.5 R R37 #P all R38 WNW-6.7 R FP3 SW-13.5 E-1.9 R R12 NW-1.0 R et ! N-1.45 et E-3.5 R R39 R13 8L2 SW-1.0 8L 8L 3 SW-13.5 BL GW - Groundwater F - f ish

  • Types: A - itr Sample 55 - Shore Line Sediment IP - food Product R - lirect Radiation et - Broad teaf veget at ion SW - Surface Water M - Milk DW - D inting Water

_ - _ _ _ J 7

I c.

                                                                         ..,"                        y mn -
3. %
                                                                      ,Ih                  -.-9                                                                                               k                                        h e:#                                                                                                                                                  s :*

I

  • 44 i
                                                                                               , / " , ' \ r'~                     .

su d E

                                                                                                                  ;;'. )/ . ~ .,                       y                                       o                            o           s.

I

                                                                                   . 5                                                                                                                                    -
                                                                    - g %w'(7 ,          -

r r. :, b, so E .S

                                                             %*t                                             l           W r* '
  • i C
                                                                                                                                                                                              =                           :;

o y q' .p ny/ f .

                                                                                                                                                                                              ~                             g 4; <, - ; ~(                              i &

4 i. I

                                                                                                                                                                                              ,c
                                                                             -s
                                                                                                                             '}                         t
                                                           ?                   % h,                                            ,       ;p                                                      9 i'~l'                                                                                                          }

t y-'A - w, ,,

                 ~

g

                             .s j,-v.

___ s p/ s s

                                                                                                  '*"=,,,                              -

I p w _ .a -

m. , y . .
,        _-g .n.
2. m y;

a nq w4= q , Q g ~o . 3, k

                                                                                                                                                                                                                ,v. u         .
                                                                                                                                                                                                                                           ~ >y . y ; g, /             a- .-~                       _+.

c J (l a flt i 'M Ab N I &;* A

                                                                             . .-             :f A,\ Ig4               s 'W,               hh *% p ',,                                                                                                                                   ,--                                         l;, Y   -

8 p

                                                                                                                                              \                                                     't -<       y,                                            t, .           ,                                           ,

s 4 fe'd,c}/' V t J,L, d ' 4

                         ,                                                                                      /                                                                                                                                .e                     *%-    ,

m ( l'f.Q _ % $, $'T[ {p,s . 5_.$ LG

                                                                                                                                                                                 &           '              ['                             'f.C~q'1)1[m -                                                              .

I . . ~ i

                                                                                                                                                                                                                                                                     . + u. x, 3-                                                                 c WI
                            ..c..
                                    % ~$ k .s . E'
                                                                                                                             ;'1 k-                ,
                                                                                                                                                              ,s.
                                                                                                                                                                            ;Oc s
                                                                                                                                                                                                                   . .'                              *D'                          N ' J .,,; . i ( ' .'. . !
                     /,.              'J,rs                 3(-

g .3 & i( , ,s - w  : #-

                                                                                                                                                                                                                                                                                                                                ; . ,' - -ej
            ' ,j f,                   m,                                           -
                                                                                                                                                            . ,rj' , A f                                                                           t-              p,. ; p ,#

I 3

                                                                                                                                                                                                                                  ,s                                     ,./                                          1,                   -
             %n                                                                               , 4* .                                       ,.

r l g:f - ,

                 %.' ~ . " * , , ,C-y/.                           f .                            y .                                   e

[ (h . A i

                                               --= .c &                                                                ..-                   ~,y                              mL7 _                             -

f " f  ? .- b g- 5,p . A a. s, . a_ ::- -7,

          ,e'                                                #                                                                                                -                            se                               g I
          .< ,.y.2,_,,, 2 4. ., J.,                                                                "g %       ,

e, . e.,

                                                                                                                                                                                                                                                                                                                              ,.f'
  • 4 '
                                                  'V                                                                                  T            .6,
                                                                                                                                                               '~
                                                                                                                                                                                                                                                 .,                            .i . ~ J s1     (p
                                                                                                                                                                                   . :n -            . )' ;,)/y                               * ^
                                                                                                                                                                                                                                                                                  , f-_ ,,q1f , ;i'\ h I
                                                                 /) y.                                                               x ;.-

L, - s - y4

                                                                                                                ,                                                                               .,.                           !                                                 ~

gw 4L _ 2 m s -y,

                                                                                                                                                                                              -- q
                                                                                                                                                                                                   \-                                         jj                                      :.
a. ,,y%-f. - . .-

s

                                                                                                                                                                              ,- f ,i                                                                                         ".                                         ;n        -y w'~ ^
           $e..) (~ '~ii ' ..' ' h A\ ^                                                            t                                                                  ' V'
                        ..3Q,f j: .;j.

8' -' I. A' , .:

                                                                                                                                                                                                                / ,s_ ' unf-p ~i f 8
                                                                                                                                                                                              .w -

i {g -Q - .

                                                                                                                     -.                                                                                               \
           -                      n                  .,'*                                    ,,y                                                                          ',,                                                        s.

t, i t ? -.

                                                                                                                                                                                             +y-                                                                            - d[ Q, , 'j ,

r ,

                                                                                                                                                                                                         . . e*,                                       if*                                                                 ,,-

4 c;;r jy a s . . ~ ,Aj 1 , ' , . mg_ . , ,.y N; p , w :z. - ',9 -

                                                  ~y'<'p                                                                                                                                                                                   %g.
                                                                     ,G. L~i ' / >. , .' . , J, a ,, .a, r

f, s -

                                               %, 9                      ,
                                                                                ,            y                         x          -                            .         2r.,             .a         f3  g,
                                                                                                                                                                                                                .a. <
  • ss eqa
                                                                                                                                                                                                                                                                          . , w..i T'* ' - f: ' ; b.
                                                                                                                                                                                                                                                                                                                                                    <6 8          /                          *
                                                            ,p         / " 7,                                           i        (                               -
                                                                                                                                                                            ,f     / '                    4          k             ,,*:
                                                                                                                                                                                                                                     ', h' . \                                                                  ,
                                                                                                                                                                                                                                                                                                                             *-                      4
                                                                  , , , u. . ' c M ^. )~
                                                                                                           ,,[ , *' % f' ',' _' ' . - . If b ~ .. . .Q
c. r . -c.

3 ,, +Mu 'g. .L, , L ^

             ,r (I
                          .. ,                           ,-                                        ,                                        ,                 .                               -                                                        ..                                                                    c-
3 g .;,,

1% i

                                           ;;w       ]A
                                              . L L p czy n 1 y r.p, .M (m.a m'e                                                                         A
                                                                                                                                                                                           ,'            53
                                                                                                                                                                                                              ,     ...n n .:

g . v .s :

                                                                                                                                                                                                                                                                                ,l
                                                                                                                                                                                                                                                                                                                      > -s 1.rt a

{

                                                                           . $Y                                       ..              . -

v, 4 7 4

                                                                                                                                                                                                                                                                                   . , \'

[,.'

                                                                                                                                                                                                                                                               -- --                                                          _}}