ML20002D538

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IE Insp Rept 50-155/76-14 on 760618.No Noncompliance Noted. Major Areas Inspected:Metallographic Samples from Code Safety Valve Nozzle Examined at Battelle Memorial Labs. Topical Rept Re Nozzle Cracking Reviewed
ML20002D538
Person / Time
Site: Big Rock Point File:Consumers Energy icon.png
Issue date: 07/12/1976
From: Cook R, Little W
NRC OFFICE OF INSPECTION & ENFORCEMENT (IE REGION III)
To:
Shared Package
ML20002D537 List:
References
50-155-76-14, NUDOCS 8101210317
Download: ML20002D538 (6)


See also: IR 05000155/1976014

Text

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UNITED STATES NUCLEAR REGULATORY COMMISSION

OFFICE OF INSPECTION AND EMFORCl@ LENT-

REGION IIIr

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-Report of Operations Inspection

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IE Inspection' Report No. 050-155/76-14

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Licenece:

Consumers Power Company

212 West Michigan' Avenue

Jackson, Michigan' 49210

L icense No.-DPR-6~

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Big Rock Point: Nuclear Plant;

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Charlevoix,~ Michigan

~ Category:

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Type of Licensee:

BWR GE 240 MWt

Type of Inspectioc:

Special, Announced

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Date of-Inspection:

. June 18, 1976

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Principal. Inspector:

.R.

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'(Dafe)_

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Accompanying Inspectors: None

Other Accompanying Personnel: None

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Reviewed By:

W. S. Littic, Chief

7//.//M.

Nuclear Support Section

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SU} DIARY ~0F FINDINGS

Inspec t ion . Summ:sry

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Inspection of June 18, 1976, (76-14):

Examined at Battelle Memorial-

Institute (BMI) Columbus Laboratories metallographic samples' removed

from a plant code safety. valve nozzle. Reviewed topical report

pertinent to cracking found in safety valve nozzles and discussed

results with licensee and BMI personnel.

Enforcement Items

. None.

Licensee Action on Previously Identified Enforcement Items

None inspected.

Other Significant Items

A.

Systems and Components

None.

B.

Facility items (Plans and Procedures)

None inspected.

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C.

Managerial Items

None.

D.

Noncompliance Identified and Corrected by Licensee

None.

E.

Deviations

None.

F.

Status of Previously Identified Unresolved Items

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None inspected.

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A management interview was conducted with Mr. Noble, consumers Power

Technical Services Administrator and Dr. Berry, EMI Associate.Mancger,

at the completion of the inspection on June 18, 1976, The following

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items were discussed.

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A.

Comparison of nozzle material micro-structure uith steriotype

material was discussed. The licensee stated that metallographic

examinations would be performed _on material representative of

the nozzles presently install d.

(Paragraph 2, Report Details)

B.

.The susceptibility for failure of the installed nozzles being

related to material physical properties was discussed. The

licensee agreed to explore further the physical properties and

heat treat history of the presently installed nozzles to

establish the. propensity for unanticipated failure.

(Paragraph

2, Report Details)'

C.

The susceptibility of the installed nozzle material to stress

corrosion cracking was discussed. The licensee indicated that

constant strain rate tests may be considered contingent upon

the findings from Items A and B above.

(Paragraphs 2 and 4,

Report Details)

D.

The time required for crack nucleation and propogation in the

safety valve nozzles was discussed. The licensee stated that

a proposed periodic inspection schedule would be developed for

timely detection of possible cracking.

(Paragraphs 3 and 4,

Report Details)

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REPORT.DSTAILS.

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Persons Co'ntacted

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D. Noble, Consumers-Power. Technical Services-Administrator-

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.N. Boyd, BMIE Manager.of: Corrosion and-Electrochemicalfand

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Technology'Section'

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W. Berry, BMI Associate Manager _of Corrosion'and Electrochemical

.and: Technology Section

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2.

General

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During inservice inspection'of_the' drum' code' safety valves to

determine the set, point pressures; theilicensee performed'aidye

penetrant _ test:(PPT) of the sealLwelded: area of the' safety-valve ~ -

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nozzles. The' DPT was performed because .the licensee:had ; pre-

viously. been informed that' corrosion crackin'g had. occurred 'in'

this area at anotherc facility. - Therefore, the licensee opted

to perform an- examination \\ of; their safety valve. nozzles.

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Th'e results of the examination revealedLinside diameter circum--

ferential cracking.in the= heat affected zone of.~the' nozzle. base-

material. . One nozzle showedievidence of-longitudinal' cracking-

in the nozzle ~ throat area about 1 to.2 inches below the seating

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surface.

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The nozzles were replaced in all the installed-codeDsafety valves:

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and the valvesLwere refurbishyp. This maintenance was cov'ered-

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during a previous inspection.-

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Two of the nozzles which were removed were sentito Battelle-

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Memorial Institute (BMI) Columbus. Laboratories, Columb'us, Ohio, for

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further metallographic examinations to establish'more: insight

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into the cause of the crack indications. Only"one of the; nozzles,a

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the one nozzle with longitudinal throat indications, was destruc-

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tively examined. An inspection was performed at BMI to review

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othe results of the metallographic examinations.

2.

Meta 11ography

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The' nozzle mmterial is classified as a 19-9DL staini s steel'

with an ASTM A4:8-71 designation. .The material composition of

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this high temperatare iron base alloy is 19Cr-9Ni-1.40Mo

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l.35W-0.40Cb-0.25T!..

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Metallographic examinations revealed that the circumferenef al'

cracks on the I. D. surface adjacent ~ to the weld -area wercapproxi-

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mately four inches in length and. penetrated.the base metal about 0.~115'

inch. The nozzle wall thickness at this location is 0.625 inch. A

relatively large number of small axially oriented . (longitudinal)'

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cracks were detected'in the throat area. .These cracks were-

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nominally '!/8 to 3/8 inch in length and the maximum depth of any of

these cracks metallographically examined was 0.029 inch.

During the metallographic examinations branches of an O. D. circum--

ferentially oriented crack adjacent to the seal weld were dis-

covered. The cut through the seal weld to. remove the nozzle

appears to have gone through .the O. D. crack ~ 1eaving only some of

the branch crccking in the nozzle base material. The deepest

branch crack depth examined is 0.040 inch. ilowever , it is believed

that the main crack was much deeper.

Intergranular attack was also

noted in the nozzle base material adjacent to the cut.

It is-

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speculated that the O. D. cracking may have been induced from

contained chlorides.

Photomicrographs and physical exmination of samples from the I. D.

cracks (seal weld and throat areas) revealed that the nozzle

material has been sensitized; probably through a stress relieving

process. To compare the degree of sensitization is quite sub-

jective, however, the lower portions of the nozzle in the welded

heat affected zone appeared to.be more sensitized than.that in the

nozzle throat area. The amount of sensitization does not appear to

be as dramatic as the sensitization that is experienced in 19-9DL

which has been solution annealed at 1850 F and aged at 1300 F for

four hours.

Hardness tests were performed across the nozzle cross section.

The

hardness was found to be approximately Re 19 to 20 with the surface

being slightly harder (Rc 29);-probably from cold working induced

during the fabrication. The nozzle material, 19-9DL, may tend to

stress crack if not stress relieved after fabrication. A typical

stress relief at 1200 F for four hours results in 'ardness of

nominally Rc 20 to 29 which is compatibic with the hardness of'the

rc=oved nozzle. However, the actual annealing process and th*

methodology for stress relieving is not completely known at this

time for either the nozzles removed or the nozzles installed.

There appears to be some similarity between the longitudinal cracks

and the circumferential crack. Both crack orientations show signs

of intergranular crack propogation.

Carbide percipitate was note:

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within the grains at the crack locations.

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.Because it'is known that 19-9DL stainless steel can exhibit' inter-

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granular . attack when heated ~ to sensitized 'at '120'0"F,- the cracks are

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classified as:intergranular stress - corrosion cracking. -The

cracks do show some semblence -to stress; corrosion . cracking experi-

enced -in Type ;304 stainless steel which has been sensitized and

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exposed.to:the operating environment of BoilingfWater Reactors.

It 'is ' surmised : that the installed:19-9DL nozzle- raterial should

exhibit similar. type crack propogation-andicorrosion'sensitivitic'- -

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as-Type 304 stainless steel.'

llowever,' some; vital physical

properties such as-impact test 'r'esults,:which would enhance a

more confident comparison to Type 304' stainless. steel are not-

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completely 'known for; the' installed: nozzle material. .Thc licensee

plans ~to procure information pertinent to the.19-9DLoinstalled

nozzle material to allow' performance comparisons.with other more

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commonly used-stainless steel alloys.

3.

Fractography-

A section of the I. D. circumferential crack was openedjfor'further-

examination. A light photomacrograph of one'of the fracture

surfaces and the sample were examinel. 'A dull-black or dark brown?

oxide extended from the I. D. surface'.to a depth of about~ 1/16

inch.

Progressing'toward the outside diameters a dark bluc.

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tarnished surface (band) existed adjacent to the dull bla'ck oxide.

A frosty metallic zone existed . adjacent to the dark 1 blue tarnish.

The observations suggest that . intermittent crack propogations -has

transpired. The~ black' oxide indicates early crack propogation and.

may have occurred one to-two years ago'

The blue tarnish indicates

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crack growth in the near past which may-have occurred nominally

three months ago.

The frosty metallic area, indicates crack growth

which probably occurred just prior to theLlast. shutdown.

Scanning electron microscope examinations-were' performed'and

confirmed the above observations.

4.

Crack Morphology

The physical cause of the intergranular stress corrosion cracking

is attributed to the sensitization of 19-?DL material"which make

the safety valve nozzles susceptible to this type of attack. The

sources of the stresses necessary to induce cracking ar,e probably

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from residual stress'from the seal welding process, surface. stresses

f rom fabrication of the nozzles, and hoop stresses. from operating

pressure. Thermal gradient stresses during.startup and/or shutdown

transients are believed to be the cause of-the strong indications

of intermittent crack propogation after what may be considered an

" incubation period".

A slowly applied strain. rate during transient

conditions'may also have~ contributed to the crack. morphology.

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