ML19308B309

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Requests Util Plans for Accurately Quantifying Oxygen Concentration of RCS within 15 Days.Info Needed to Verify Chemistry Control Program Will Accurately Predict Corrosive Activity of Primary Coolant
ML19308B309
Person / Time
Site: Crane Constellation icon.png
Issue date: 11/15/1979
From: Jay Collins
NRC - TMI-2 OPERATIONS/SUPPORT TASK FORCE
To: Arnold R
METROPOLITAN EDISON CO.
References
NUDOCS 7912280351
Download: ML19308B309 (3)


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November 15, 1979 Docket No. 50-320 fietropolitan Edison Company ATTN: Mr. R. C. Arnold Senior Vice President P. O. Box 480 141ddletown, PA 17057

Dear Mr. Arnold:

On September 17, 1979, the NRC staff requested Metropolitan Edison Company to provide a program detailing plans for controlling primary system chemistry and indicating the limits to be maintained on all contaminants at various reactor coolant conditions. This request was prompted by the staffs' concern about the potential effects of corrosion on reactor coolant system components and on the primary system integrity throughout the recovery mode.

Met-Ed's response, October 16, 1979, enclosed a report prepared by B&W setting forth recommendations and requirements for controlling chemistry and corrosion in the Thl-2 reactor coolant system.

In reviewing this program the staff found that with the limits prescribed for coolant chemistry the potential for chloride stress and general stress corrosion would be minimized. However, when reviewing the sensitivity of the sample analysis instrument it was found that the minimum oxygen detection capability of the gas chromatograph was 4cc/kg or approximately 5 ppm.

Dissolved oxygen in the presence of high chloride concentrations contribute to an environment conducive to accelerating chloride stress corrosion and chloride stress corrosion cracking of sensitized areas. The B&W report recognizes the high chloride concentrations existing in the Tr4I-2 reactor coolant system and submits that if oxygen concentrations are maintained below 0.1 ppm the potential for stress corrosion is greatly reduced. The staff concurs with this.

Nevertheless, since our evaluation was based on maintaining oxygen at levels less than 0.1 ppm, and minimum detectable oxygen is 5 ppm, we cannot conclude that Met-Eds' chemistry control program has provided the sensitivity necessary to accurately predict the corrosive activity of the primary coolant nor will it suffice to indicate when cor-osion mitigating actions should be taken.

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Mr. R. C. Arnold 2

November 16, 1979 On this basis, you are requested to provide within 15 days from the date of this letter your plans for accurately quantifying the oxygen concentration of the reactor coolant system. Your proposal for oxygen analysis should include a complete description of the technique, procedure, and equipment to be used along with sensitivity values and tolerances.

In the event that the oxygen concentration cannot be quantified with reasonable certainty you should be prepared to discuss the measures to be taken to mitigate the consequences of chloride stress induced cracking of the reactor coolant system piping and its effects on the long term cooldown and recovery operations at TMI-2.

ohn T. Collins Deputy Director, THI Support cc:

J. G. Herbein, Vice President Nuclear Operations E. G. Wallace, Licensing Manager C. P. Hiller, Manager Support Services and Logistics J. B. Logan, Superintendent Unit 2 G. A. Kunder, Unit 2 Superintendent - Technical Support J. J. Colitz, Manager Plant Engineering R. F. Wilson, Director TMI-2 Recovery, Acting I. R. Finfrock, Jr.

R. W. Conrad G. F. Trowbridge, Esquire J. B. Lieberman, Esquire Ms. Mary V. Southard, Chairperson, Citizens for a Safe Environment John T. Collins, Deputy Director, NRC, TMI Support t

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IE Mail & Files (For appropriate distribution)

Central files Public Document Room (PDR) local Public Document Room (LPDR)

Nuclear Safety Information Center (NSIC)

Technical Information Center (TIC)

REG:I Reading Room Commonwealth of Pennsylvania Ms. Mary V. Southard, Chairperson, Citizens for a Safe Environment L

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