ML19210A414

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Model Plant Sys Tech Specs Re Secondary Water Chemistry Limiting Conditions for Operation
ML19210A414
Person / Time
Site: Crane Constellation icon.png
Issue date: 06/01/1976
From:
Office of Nuclear Reactor Regulation
To:
Shared Package
ML19210A411 List:
References
NUDOCS 7910290636
Download: ML19210A414 (4)


Text

,

HODEL (B)

- - ~ - - - -

. TECHNICAL SPECIFICATIONS PLANT SYSTEMS SECONDARY WATER CHEMISTRY LIMITING CONDITION FOR OPERATION 3.xxx The secondary water chemistry shal.1 be maintained within the limits of Table 3.xx.

APPLICABILITY: Modes 1, 2 and 3.

ACTION:

With the condenser condensate total cation conductivity exceeding a.

its Steady State Limit but within its Transient Limit, restore the conductivity to within its Steady State Limit within 7 days; or, be in HOT SHUTDOWN within the next 12 hours1.388889e-4 days <br />0.00333 hours <br />1.984127e-5 weeks <br />4.566e-6 months <br />.

b.

Wit.h the condenser condensate total cation conductivity exceeding its Transient Limit, restore the conductivity to within the Transient' Limit within 96 hours0.00111 days <br />0.0267 hours <br />1.587302e-4 weeks <br />3.6528e-5 months <br /> or be in HOT SHUTDOWN within the next 12 hours1.388889e-4 days <br />0.00333 hours <br />1.984127e-5 weeks <br />4.566e-6 months <br />.

With the total cation conductivity of the final.feedwater to any stearp c.

generator exceeding its Steady State Limit but within its Transient Limit, verify at least once per 24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br /> that the pH and maximum total solids in the final feedwater are within the limits of Table 3.XX.

and restore the conductivity to within its Steady State Limit within 7 days; or, be in HOT SHUTDOWN within the next 12 hours1.388889e-4 days <br />0.00333 hours <br />1.984127e-5 weeks <br />4.566e-6 months <br />.

~

d.

With the pH. and/or maximu.m total solids of the final feedwater to any.

steam generator exceeding its limit (s), restore the out-of-limit parameter (s) to within its limit (s) within 72 hours8.333333e-4 days <br />0.02 hours <br />1.190476e-4 weeks <br />2.7396e-5 months <br /> or be in HCT SHUTC0WN within the next 12 hours1.388889e-4 days <br />0.00333 hours <br />1.984127e-5 weeks <br />4.566e-6 months <br />.

With the total cation conductivity of the final feedwater to any steam e.

generator exceeding its Transient Limit, restore the conductivity to within its limit within 72 hours8.333333e-4 days <br />0.02 hours <br />1.190476e-4 weeks <br />2.7396e-5 months <br /> or be in HOT SHUTDOWN within the next 12 hours1.388889e-4 days <br />0.00333 hours <br />1.984127e-5 weeks <br />4.566e-6 months <br />.

SURVEILLANCE REOUIREMENTS

4. xxx The secondary water chemistry parameters shall be determined to be within the limits at least once per 24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br /> by analyzing the condenser condensate and steam generator final feedwater for total cation conductivity.

1469 196 9"

3/4-X

PLANT SYSTEMS BASES 3/4.xxx _

$ECONDARY WATER CHEMISTRY-Centamination of the steam generator secondary coolant can cause Generally, the mos,t potential tube degradation and impair tube integrity.

severe contamination results from condenser inleakage of causticforaing impurities that may accumulate on the secondary side of the steam gen-erator, or on the high heat flux surfaces of the steam generator tubes can lead to the potential for intergranular stress corrosion cracking.

Monitoring of the condenser condensate by cation conductivity is an

~

The leakage rate effective means of detecting condenser tube inleakage.

can then be determined by comparing the cation concentration in the. con-The den 5 ate with the cation concertration in the condenser cooling water.

cation conductivity of the steam generator final feedwater will indicate when blowdown is required to remove the accumulation of caustic forming Monitor-impurities and the scale forming solids in the steam generator.

ing the pH and free hydroxide the final feedwater provides a means to initiate balance of corrective actions needed to restore the operating secondary coolant. Monitoring the total solids in the final feedwater will indicate the potential accumulation of solids and the necessity for blowdown to minimize sludge buildup.

Controlling the secondary water chemistry within the specified limits will control the potential accumulation of corrosive impurities in the These limits provide st um generator and minimize tube degradation.

reasonable assurance that the conditions in the steam generator will minimize the potential for tube degradation during all conditions of These measures ensure the continued operation, and postulated accidents.

protection of the steam generator tubing,thich is an essential part of the reactor coolant pressure boundary.

\\469

\\91 3/4-X

TABLE 3. xx, SECONDARY k'ATER CHEMISTRY LIMITS Total Cation Conductivity Maximum. Total umhos/cm2 0 25*C pH 0 25'C Solids Water Sample Steady State Transient Location Limits Limits Limits Limits Condenser 1( )

1()

H.A.

H.A.

Condensate Final Feedwater 1( )

1 ( )*

(,) spas ( )

1()

g g

  • Maybeincreasedto(

) for the first (-

.) hours during.startup from. HOT SHilTDOWN.

f x

.i',

t O

O W

i

_4 D

~

CD

e TABLE 1.1 OPERATIONAL MODES REACTIVITY

% RATED AVERAGE COOLANT MODE CONDITION, K THERMAL POWER

  • TEMPERATURE eff 1.

POWER OPERATION

> 0.99

> 5%

> (305)*F 2.

STARTUP

> 0.99

< 5%

- (305)*F 3.

HOT STANDBY

< 0.99 0'

>(305)'F 4.

HOT SHUTDOWN

< 0.99 0

(305)*F->T

> 200*F avg 5.

COLD SHUTDOWN

< 0.99 0

1 200*F 6.

REFUELING **

1 0.95 0

1 140*F

  • Excluding decay heat.
    • Reactor vess41 head unbolted or removed and fuel in the vessel.

1469 199 B&W-STS 1-7 June 1. 1976