ML090510316

Orise Report for Analyses of Nine Water Samples from Set Seven

ML090510316
Person / Time
Site:	Indian Point
Issue date:	04/18/2008
From:	Condra D Oak Ridge Institute for Science & Education
To:	Kottan J NRC Region 1
References
DCN 1748-LR-07-0, IR-07-003
Download: ML090510316 (13)

Text

J TT Ay OAK FuIDGE INSTITUTE FOR SCIENCE AND EDUCATION April 18 2008 ivr. Jim~gottan U.S" ;Nuclear RCgulatory C(.ommission Region I 475 Allendale Road King: of Prussia, PA 19406 I

SUBJECT:

REPORT FOR ANALYSES OF NINE WATER SAMPLES FROM SET SEVEN FROM THE INDIAN POINT POWER STATION, BUCHANAN, NEW YORK

[INSPECTION REPORT NO. 050-247/2007-0031 [RFtTA NO.07-005(2)]

DCN 1748-LR-07-0

Dear Mr. Kottan:

The Oak RidgeIinstitute for Sciene and Education (ORISE) received set seven, consistingof ninc water samnples, associated. witl, the.Indian Point Power S.tationi on Maich *10, 2008.8.Sample anialysis wxias initiated based pon.the information in RF1A 07ý005(2). Sample.identification and collection data for the samPles addressed in this report are presented in Table.1. Gammna spectroscopy, total radiostrontium, nickel-63,and tritiium data are provided in Tables 2 through 5, respectively. The pertinent procedure references are provided in eacd specific table.

ORISE's Quality Control (QC) requirements were met for these analyses. The QC files are available for your rev'iew upon request..

MNy c'ontact.in.lormali1n is listed, below. You may also contact \\Vadce vey at 865,5-76,9184 withlan v ques.tions or comments.

Sincerely, Dale.Condra, Manager Labýoiqrtory RD C: WP I: a r Enclo6ures c:

T. Carter, FSME/DWMtEP/DD/SP T-8F5 E. IKno.x-Davin, NRC/F SME/TWEN 8A23 S Roberts, ORISE J. Noggle, NRC Region I j.. \\hite, NPRC Region 1 E..Abekquist, QRISE J. Comimskey,INRC Region I File 1748 Distribution approval and:concurrence f Iiiitials. / i

-il cnicaiL :Managemr ' C

.In Mfemiber Q'a4 r

I~.

• QTaga Voice: 865.241.3242 Fax: 865.241.3248 oE-nail: Dale.Condrqa orau.orR

TABLE 1 SAMPLE IDENTIFICATIONS AND COLLECTION DATA INDIAN POINT POWER STATION BUCHANAN, NEW YORK ORISE NRC Region I Collection Date Collection Sample ID Nample ID Time 1748W0044 MW-66-21-(003) 1/14/2008 11:33 1748W0045 MW-66-36-(003) 1/14/2008 11:40 1748W0046 MW-67-39-(003) 1/11/2008 16:44 1748W0047 MW-67-105-(003) 1/.11/2008 15:15 1748W0048 MW-67-173-(003) 1/11/2008 13:35 1748W0049 MW-67-219-(003) 1/11/2008 12:05 1748W0050 MW-67-276-(003) 1/11/2008 13:00 1748W0051 MW-67-323-(003) 1/11/2008 13:52 1748W0052 MW-67-340-(003) 1/11/2008 13:15 Indian Point Power Station 1748-LR-07-0

0.

0

~0 0

0 TABLE 2 CONCENTRATIONS OF SELECTED GAMMA EMITTING RADIONUCLIDES IN WATER SAMPLES BY GAMMA SPECTROSCOPY CP1, REVISION 16 INDIAN POINT POWER STATION BUCHANAN, NEW YORK ORISE NRC Region I Radionuclide Concentrations, TPUs, and MDCsa (pCi/L)

Sample ID Sample ID Co-58 Co-60 Cs-134 Cs-137 1748W0044 MW-66-21-(003) 1.6

+ 6.1 b 7.5

-0.4 +/- 4.6 5.1 3.5

+/- 3.8 5.1 7.1

+/- 3.4 5.5 1748W0045 MW-66-36-(003) 5.7 +/- 5.9 8.3

-1.4 +/- 4.5

, 5.3

-2.9

+ 5.7, 6.0 1.5

+/- 4.4

, 5.2 1748W0046 MW-67-39-(003) 1.6

+/- 2.3

, 6.1 0.9 +/- 3.6

, 4.4

-0.2 +/- 2.7, 4.1

-0.2 +/- 3.1 3.7 1748W0047 MW-67-105-(003)

-1.2 +/- 6.0 6.6 2.7 +/- 3.2

, 4.3

-2.3

+/- 3.7, 4.1

-1.7

+/-

3.3 3.8 1748W0048 MW-67-173-(003)

-4.3 +/-

6.6 7.5

-1.0 +/- 4.7

, 5.2 0.2

+/- 4.4, 5.3 2.8

+/-

3.0

, 4.9 1748W0049 MW-67-219-(003) 0.3 +/- 6.6 8.5 0.6 +/- 4.5

, 5.5

-1.4

+/- 5.6, 6.0 3.3

+/-

4.2 5.2 1748W0050 MW-67-276-(003)

-2.1 +/- 5.6

, 6.4

-0.9 +/- 3.5

, 4.1

-1.7

+/-.3.7, 4.3 1.0

+/-

3.1 3.7 1748W0051 MW-67-323-(003) 1.6 +/- 6.0

, 6.9

-0.8 +/- 3.4

, 4.2

-1.9

+/- 3.5, 4.0 0.8

+/-

3.3 3.9 1748W0052 MW-67-340-(003)

-4.3 +/-

5.7 6.1 1.9 +/- 3.5

, 4.4 1.9

+/- 3.7, 4.3

-1.1

+/- 3.2 3.7

'The lvfDCs are after the comma.

bUncertainties represent the 95% confidence level, based on total propagated uncertainties.

-J

TABLE 3 CONCENTRATIONS OF TOTAL RADIOSTRONTIUM IN WATER SAMPLES BY LOW BACKGROUND BETA COUNTING AP4, REVISION 14; CP3, REVISION 2 INDIAN POINT POWER STATION BUCHANAN, NEW YORK*

Radionuclide ORISE NRC Region I Concentrations, TPUs, and Sample ID Sample ID MDCSa (pCi/L) 1748W0044 MW-66-21-(003) 0.66

+/-

0 4 8b 0.77 1748W0045 MW-66-36-(003) 15.4

+/-

1.2 0.8 1748W0046 MW-67-39-(003) 26.1

+/-

1.6 0.8 1748W0047 MW-67-105-(003) 0.81

+/-

0.52 0.83 1748W0048 MW-67-173-(003) 0.02

+/-

0.50 0.89 1748W0049 MW-67-219-(003)

-0.17

+/-

0.42 0.79 1748W0050 MW-67-276-(003)

-0.17

+/-

0.42 0.77 1748W0051 MW-67-323-(003)

-0.14

+/-

0.45 0.83 1748W0052 MW-67-340-(003) 0.07

+/-

0.43 0.76

'fhe MDCs are after the comma.

bUncertainties represent the 9 5% confidence level, based on total propagated uncertainties.

Indian Point Power Station 1748-LR-07-0

TABLE 4 CONCENTRATIONS OF NICKEL-63 IN WATER SAMPLES BY LIQUID SCINTILLATION ANALYSIS AP12, REVISION 6; CP4, REVISION 3 INDIAN POINT POWER STATION BUCHANAN, NEW YORK Radionuclide ORISE NRC Region I Concentrations, Sample ID Sample ID TPUs, and MDCSa I_

(pCi/L) 1748W0044 MW-66-21-(003) 2.8

+/-_

2.9b 4.9 1748W0045 MW-66-36-(003) 6.6

+/-

3.0 4.9 1748W0046 MW-67-39-(003) 2.9

+/-

2.9 4.9 1748W0047 MW-67-105-(003) 7.8

+/-

3.1 4.9 1748W0048 MW-67-173-(003) 3.4

+/-

2.9 4.9 1748W0049 MW-67-219-(003) 7.5

+/-

3.1 4.9 1748WO050 MW-67-276-(003) 6.6

+/-

3.0 4.9 1748W0051 MW-67-323-(003) 0.4

+/-

2.9 4.9 1748W0052 MW-67-340-(003) 3.2

+/-

2.9 4.9

'The MDCs for each radionuclide are after the comma.

bUncertainties represent the 95%/o confidence level, based on total propagated uncertainties.

Indian Point Power Station 1748-LR-07-0

TABLE 5:

CONCENTRATIONS OF TRITIUM IN WATER SAMPLES BY LIQUID SCINTILLATION ANALYSIS AP2, REVISION 16; CP4, REVISION 3 INDIAN POINT POWER STATION BUCHANAN, NEW YORK ORISE NRC Region I Radionuclide Concentrations, Sample ID Sample ID TPUs, and MDCsa (pCi/L) 1748W0044 MW-66-21-(003) 890

+/-

1 3 0 b 170 1748W0045 MW-66-36-(003) 7,360

+/-

410 170 1748W0046 MW-67-39-(003) 4,720

+/-

290 170 1748W0047 MW-67-105-(003) 2,700

+/-

210 170 1748W0048 MW-67-173-(003) 920

+/-

130 170 1748W0049 MW-67-219-(003) 1,300

+

150 170 1748W0050 MW-67-276-(003) 1,150

+/-

140 170 1748W0051 MW-67-323-(003) 530

+/-

120 170 1748W0052 MW-67-340-(003) 690

+/-

120 170

'The MDCs are after the comma.

Uncertainties represent the 95% confidence level, based on total propagated uncertainties.

Indian Point Power Station 1748-LR-07-0

TABLE 5 CONCENTRATIONS OF TRITIUM IN WATER SAMPLES BY LIQUID SCINTILLATION ANALYSIS AP2, REVISION 16; CP4, REVISION 3 INDIAN POINT POWER STATION BUCHANAN, NEW YORK ORISE NRC Region I Radionuclide Concentrations, Sample ID Sample ID

. TPUs, and MDCSa (pCi/L) 1748W0044 MW-66-21-(003) 890

+/-

130 b 170 1748W0045 MW-66-36-(003) 7,360

+/-

410 170 1748W0046 MW-67-39-(003) 4,720

+/-

290 170 1748W0047 MW-67-105-(003) 2,700

+/-

210 170 1748W0048 MW-67-173-(003) 920

+/-

130 170 1748W0049 MW-67-219-(003) 1,300 i

150 170 1748W0050 MW-67-276-(003) 1,150

+/-

140 170 1748W0051 MW-67-323-(003) 530

+/-

120 170

• 1748W0052 MW-67-340-(003) 690

+/-

120 170

'The MDCs are after the comma.

bUncertainties represent the 9 5 % confidence level, based on total propagated uncertainties.

Indian Point Power Station 1748-LR-07-0

OAKRIDES AH

-OAK RIDGE INSTITUTE FOR SCIENCE AND EDUCATION April 18, 2008 Mr. Jim Kottan U.S. Nuclear Regulatory Commission Region I 475 Allendale Road King of Prussia, PA 19406

SUBJECT:

REPORT FOR ANALYSES OF NINE WATER SAMPLES FROM SET SEVEN FROM THE INDIAN POINT POWER STATION, BUCHANAN, NEW YORK

[INSPECTION REPORT NO. 050-247/2007-003] [RFTA NO.07-005(2)]

DCN 1748-LR-07-0

Dear Mr. Kottan:

The Oak Ridge Institute for Science and Education (ORISE) received set seven, consisting of nine water samples, associated with the Indian Point Power Station on March 10, 2008. Sample analysis was initiated based on the information in RFTA 07-005(2), Sample identification and collectiondata for the samples addressed in this report are presented in Table 1. Gamma spectroscopy, total radiostrontium, nickel-63, and tritium data are provided in Tables 2 through 5, respectively. The pertinent procedure references areprovided in each specific table.

ORISE's Quality Control (QC) requirements were met for these analyses. The QC files are available for your review upon request.

My contact information is listed below. You may also contact Wade'Ivey at 865.576.9184 with any questions or comments.

Sincerely, Dale Condra, Manager Laboratory 00 RDC:W-PI:ar Enclosures

. W c:

T. Carter, FSME/DWMEP/DD/SP T-8F5 E. Knox-Davin, NRC/FSME/TWFN 8A23 S Roberts, ORISE J. Noggle, NRC Region I J. White, NRC Region I E. Abelquist, ORISE J. Commiskey, NRC Region I File 1748

-Distribution approval and concurrence:

Initials Technical Management Team Member "7"nl Quality Manager

--,,A -,,rATT Voice: 865.241.3242 Fax: 865.241.3248 E-mail: Dale.Condra @orau.org

TABLE 1 SAMPLE IDENTIFICATIONS AND COLLECTION DATA INDIAN POINT POWER STATION BUCHANAN, NEW YORK ORISE NRC Region I Collection Date Collection Sample ID Sample ID Time 1748W0044 MIW-66-21-(003) 1/14/2008 11:33 1748W0045 MW-66-36-(003) 1/14/2008 11:40 1748W0046 MW-67-39-(003) 1/11/2008 16:44 1748W0047 MW-67-105-(003) 1/11/2008 15:15 1748W0048 MW-67-173-(003) 1/11/2008 13:35 1748W0049 MW-67-219-(003) 1/11/2008 12:05 1748W0050 MW-67-276-(003) 1/11/2008 13:00 1748W0051 MW-67-323-(003) 1/11/2008 13:52.

1748W0052 MW-67-340-(003) 1/11/2008 13:15 Indian Point Power Station 1748-LR-07-0

0~

0 0

0~~

0.

0 TABLE 2 CONCENTRATIONS OF SELECTED GAMMA EMITTING RADIONUCLIDES IN WATER SAMPLES BY GAMMA SPECTROSCOPY CP1, REVISION 16 INDIAN POINT POWER STATION BUCHANAN, NEW YORK ORISE NRC Region I Radionuclide Concentrations, TPUs, and MDCsa (pCi/L)

Sample ID Sample ID Co-58 Co-60 Cs-134 Cs-137 1748W0044 MW-66-21-(003) 1.6

+ 6.1 b 7.5

-0.4 +/- 4.6 5.1 3.5

+ 3.8 5.1 7.1

+/- 3.4 5.5 1748W0045 MW-66-36-(003) 5.7

+

5.9 8.3

-1.4. +

4.5

, 5.3

-2.9

+/- 5.7, 6.0 1.5 +/- 4.4 5.2 1748W0046 MW-67-39-(003) 1.6

+

2.3 6.1 0.9 +/- 3.6

, 4.4

-0.2

+/- 2.7, 4.1

-0.2 +/-

3.1

, 3.7 1748W0047 MW-67-105-(003)

-1.2 +

6.0 6.6

.2.7 +/- 3.2

, 4.3

-2.3

+/- 3.7

, 4.1

-1.7 +/- 3.3 3.8 1748W0048 MW-67-173-(003)

-4.3 +

6.6 7.5

-1.0 +/- 4.7

, 5.2 0.2

+/- 4.4, 5.3 2.8 +/- 3.0 4.9 1748W0049 MW-67-219-(003) 0.3

+/-

6.6 8.5 0.6 +/-

4.5 5.5

-1.4

+/- 5.6 6.0 3.3

+/-

4.2 5.2 1748W0050 MW-67-276-(003)

-2.1

+/-

5.6 6.4

-0.9 +/- 3.5

, 4.1

-1.7

+ 3.7

, 4.3 1.0

+/-

3.1

, 3.7 1748W0051 MW-67-323-(003) 1.6

+

6.0 6.9

-0.8 +/- 3.4

, 4.2

-1.9

+/- 3.5, 4.0 0.8 +/- 3.3 3.9 1748W0052 MW-67-340-(003)

-4.3 +

5.7 6.1 1.9 +/-

3.5

, 4.4 1.9

+/- 3.7, 4.3

-1.1

+/- 3.2 3.7

'The MDCs are after the comma.

bUncertainties represent the 95% confidence level, based on total propagated uncertainties.

-TI 0

TABLE 3 CONCENTRATIONS OF TOTAL RADIOSTRONTIUM IN WATER SAMPLES BY LOW BACKGROUND BETA COUNTING AP4, REVISION 14; CP3, REVISION 2 INDIAN POINT POWER STATION BUCHANAN, NEW YORK Radionuclide ORISE NRC Region I Concentrations, TPUs, and Sample ID Sample ID MDCSa (pCi/L) 1748W0044 "MW-66-21-(003) 0.66

+/-

0,4 8b 0.77 1748W0045 MW-66-36-(003) 15.4

+/-

1.2 0.8 1748W0046 MW-67-39-(003) 26.1

+/-

1.6 0.8 1748W0047 MW-67-105-(003) 0.81

+/-

0.52 0.83 1748W0048 MW-67-173-(003) 0.02

+/-

0.50 0.89 1748W0049 MW-67-219-(003)

-0.17

+

0.42 0.79 1748W0050 MW-67-276-(003)

-0.17

+/-

0.42 0.77 1748W0051 MW-67-323-(003)

-0.14 0.45 0.83 1748W0052 MW-67-340-(003) 0.07

+/-

0.43 0.76

'The MDCs are after the corimma.

bUncertainties represent the 95% confidence level, based on total propagated uncertainties, ladian Point Power Station 1748-LR-07-0

TABLE 4 CONCENTRATIONS OF NICKEL-63 IN WATER SAMPLES BY LIQUID SCINTILLATION ANALYSIS AP12, REVISION 6; CP4, REVISION 3 INDIAN POINT POWER STATION BUCHANAN, NEW YORK Radionuclide ORISE NRC Region I Concentrations, Sample ID Sample ID TPUs, and MDCSa (pCi/L) 1748W0044 MW-66-21-(003) 2.8

+/-

2.9 b 4.9 1748W0045 MW-66-36-(003) 6.6

+/-

3.0 4.9 1748W0046 MLW-67-39-(003) 2.9

+/-

2.9 4.9 1748W0047 MW-67-105-(003) 7.8

+/-

3.1 4.9 1748W0048 MW-67-173-(003) 3.4

+/-

2.9.

4.9 1748W0049 MW-67-219-(0o3) 7.5

+/-

3.1 4.9 1748W0050 MW-67-276-(003) 6.6

+/-

3.0 4.9 1748W0051 MW-67-323-(003) 0.4

+/-

2.9 4.9 1748W0052 MW-67-340-(003) 3.2

+/-

2.9 4.9

'The MDCs for each radionuclide are after the comma.

bUncertainties represent the 95% confidence level, based on total propagated uncertainties.

Indian Point Power,

ntaton 1748-1,R-07-0

TABLE 5 CONCENTRATIONS OF TRITIUM IN WATER SAMPLES BY LIQUID SCINTILLATION ANALYSIS AP2, REVISION 16; CP4, REVISION 3 INDIAN POINT POWER STATION BUCHANAN, NEW YORK ORISE NRC Region I Radionuclide Concentrations, Sample ID Sample ID TPUs, and MDCsa (pCi/L) 1748W0044 MW-66-21-(003) 890

+

13 0b 170 1748W0045 MW-66-36-(003) 7,360

+/-

410 170 1748W0046 MW-67-39-(003) 4,720

+/-

290 170 1748W0047 MW-67-105-(003) 2,700

+/-

210 170 1748W0048 MW-67-173-(003) 920

+

130 170 1748W0049

\\IW-67-219-(003) 1,300

+

150 170 1748W0050 MW-67-276-(003) 1,150

.140 170 1748W0051 MW-67-323-(003) 530

+

120 170 1748W0052 MW-67-340-(003) 690

+

120 170

'The MDCs are after the comma.

bUncertainties represent the 95% confidence level, based on total propagated uncertainties.

Indian Point Power Station 1748-LR-07-0