ML030990400

Application for Renewal of National Pollutant Discharge Elimination System Permit, Sections I Through Iii.B

ML030990400
Person / Time
Site:	Cook
Issue date:	03/28/2003
From:	Gebbie J Indiana Michigan Power Co
To:	Document Control Desk, Office of Nuclear Reactor Regulation
References
AEP:NRC:2401-08, MI0005827
Download: ML030990400 (187)

Text

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Donald C. Cook Nuclear Plant Unit 1 and 2 Application for Renewal of National Pollutant Discharge Elimination System Permit March 28, 2003 O
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NPDES Permit Renewal

Indiana Michigan Power Company Cook Nudear Plant One Cook Plant Nidgnan Ml149106 616 465 5901 INDIANA MI~CHIGAN POWER CERTIFIED MAIL #7000 0520 0014 6367 3082 Mr. Greg Danneffel, District Supervisor Michigan Department of Environmental Quality Surface Water Quality Division 7953 Adobe Road Kalamazoo, MI 49009 March 28, 2003

Subject:

NPDES Permit MI0005827 Application

Dear Mr. Danneffel:

Enclosed is the Industrial and Commercial Wastewater Discharge Application for renewal of the Donald C. Cook Nuclear Plant National Pollutant Discharge Elimination System (NPDES) Permit.

This application is being submitted 180 days prior to the expiration of the present permit.

During the term of the present permit, several permit modifications were made to improve Cook Nuclear Plant operations.

We appreciate your efforts in these permit modifications.

If there are any questions, please contact me at (269) 456-5901 ext. 1153 or Blair Zordell at (269) 465-5901 ext. 2006.

Sincerely, X1 /

John Carlson Environmental Manager Enclosure c: US NRC per App. B. T.S.

2003-387

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NPDES Permit K. D. Mack C. E. Hawk MDEQ File w/o Attachments Annual Operating Report NDM (2003-387), Mail Zone 1 2003-387

Section I

D EA.

Michigan Department of Environmental Quality - Water Division

_ AWASTEWATER DISCHARGE PERMIT APPLICATION SECTION I - General Information This information is required by the Part 21 Rules of Michigan Act 451, Public Acts of 1994, as amended, Part 31 A municipality, business, or industry

, hich violates the Part 21 Rules may be enjoined by action commenced by the Attorney General in a court of competent jurisdiction See the facing page for instructions on completing pages 1 and 2. To submit additional information see page ii, item 8 PL EASE TYPE OR PRINT NPDES PERMIT NUMBER DEQ USE 1

M0005827 ONLY Permit ID#: '"

Applicant Name Indiana Michigan Power Company Z

Address Address 2 or P.O. Box One Cook Place City State ZIP Code Bridgman Ml 49106 Telephone (with area code)

FAX (with area code)

(269) 465-5901 (269) 466-2550 Facility Name 1 Donald C Cook Nuclear Plant Facility Name 2 Facility Name 3 Street Address (do not use a P.O Box Number) flOne rook Place S

City State ZIP Code Bridgman Ml 49106 Telephone (with area code)

FAX (with area code)

(269) 465-5901 (269) 466-2550 First Name Last Name O Application Contact John Carlson Title Business Facility Contact Environmenal Manager 0 Discharge Monitoring Reports Address 1 Address 2 Donald C Cook Nuclear Plant One Cook Place Storm Water Billing City State Zip Code Bridgman MI l

49106 D Biosolids Billing Telephone (with area code)

FAX (with area code) e-mail address (269) 465-5901 x 1153 (269) 466-2550 jpcartson@aep corn First Name Last Name 0 Application Contact Blair Zordell Title Business 5 Facility Contact Environmental Specialist Sr Addrss 1Address 2

oDischarge Monitoring Reports Address 1Adrs2 Donald C. Cook Nuclear Plant One Cook Place o Storm Water Billing City l State Zip Code Bridgman I Ml 49106 o Biosolids Billing Telephone (with area code)

FAX (with area code) e-mail address 1 (269) 465-5901 x 2006 (269) 466-2550 bkzordell@aep com First Name Last Name o Application Contact o Facility Contact o Discharge Monitoring Reports o Storm Water Billing o Biosolids Billing Title Business Address 1 Address 2 City IState Zip Code Telephone (with area code)

I FAX (with area code)

I e-mail address I__

I 1

EQP 4659-A (Rev 1/03)

I Michigan Department of Environmental Quality-Water Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION I - General Information PLEASE TYPE OR PRINT CILITY NAME uonald C Cook Nuclear Plant NPDES PERMIT NUMBER M10005827 I---------

5.

PERMIT ACTION REQUESTED (Check one box only) (see instructions page iv, item 5)

M NEW USE a proposed discharge OR an existing discharge that is currently unpermitted.

0 REISSUANCE of current permiL El MODIFICATION of current permit. Attach a description of the proposed modification.

Note: Applications for New Use discharges and applications for either Reissuance or Modification that include an increased loading of pollutants to the receiving water must submit a Rule 98 Demonstration with the application See Item 6 below.

6.

RULE 98 - ANTIDEGRADATION DEMONSTRATION (see instructions page iv, item 6)

In accordance with Rule 323 1098 of the Michigan Water Quality Standards, the permittee must submit an antidegradation demonstration for any new or increased loading of pollutants to the surface waters of the state. For assistance completing this item call the Permits Section.

Will this discharge be an increased loading of pollutants to the surface waters of the state?

Ea Yes, submit an antidegradation demonstration (refer to Rule 323.1098 on page 4 of the appendix for instructions).

E0 No, Continue with Item 7.

7 ADDITIONAL FACILITY INFORMATION (see instructions on page iv, item 7)

A Is the treatment facility within municipal boundanes?

El Yes B

County Bemen C

1/4, %4 l/4 Section SW NW 106 D

Latitude ED No o

CERTIFIED OPERATOR Does the faclity have a properly cerbfied operator?

0 Yes E

No (see instructions on page iv)

Operator's Name Blair Zordell Operator's Telephone (269) 465-5901 x 2006 Cerbification Number 4537 Certification Classification(s). A-ld, A-1h, A-2e, B-1b.

9.

OTHER ENVIRONMENTAL PERMITS Provide the information requested below for any other federal, state or local environmental permits in effect or applied for at the time of submittal of this application form, including, but not limited to, permits issued under any of the following programs Air Pollution Control, Hazardous Waste Management, Wetlands Protection, Soil Erosion and Sedimentation Control, and other NPDES permits. To submit additional information see page ii, item 8.

Issuing Agency Permit or COC Number Permit Type MDEQ-Air Quality Division 544-97 Air Use Permit MDEQ-Air Quality Division 460-93 Air Use Permit MDEQ-WMD M 00988 Discharge To Groundwater Berrien County Drain Commission 3449R Soil and Erosion Permit MDEQ-Geological and Land Management Division 02-11-0111-P Part 325 /353 USEPA MID098647621 Hazardous Waste Waste ID

,men County Drain Commission 3298 Soil and Erosion Permit MDEQ-Geological and Land Management Division 01-11-0069-P 98-12-0414-P Crit Dne/Sub Lands

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I 4 9

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2 EQP 4659-A (Rev 1/03)

Michigan Department of Environmental Quality-Surface Water Quality Division Wastewater Discharge Permit Application SECTION I - General Information PLEASE TYPE OR PRINT

ACILITY NAME Donald C. Cook Nuclear Plant NPDES PERMIT OR COC NUMBER I M10005827

9.

OTHER ENVIRONMENTAL PERMITS Provide the information requested below for any other federal, state, or local environmental permits in effect or applied for at the time of submittal of this application form; including, but not limited to, permits issued under any of the following programs: Air Pollution Control, Hazardous Waste Management, Wetlands Protection, Soil Erosion and Sedimentation Control, and other NPDES permits. To submit additional information see page ii. item 8.

Issuing Agency Permit or COC Number Permit Type MDEQ -Geological and Land 94-BR-321 -C Right of Way Vegetation Control-Critical Management Division Dune Permit US Army Corps of Engineers 69-056-004-7 Dept of the Army Permit MDEQ -Geological and Land 02-11-0045-P Part 323 Shorelands Protection and Management Management Division Part 353 Sand Dune Protection and Management.

2a EQP 4659-A (Rev 1/03)

Michigan Department of Environmental Quality-Water Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION I - General Information PLEASE TYPE OR PRINT l:ACILITY NAME NPDES PERMIT NUMBER Donald C. Cook Nuclear Plant M10005827

10. WATER FLOW DIAGRAM AND NARRATIVE DESCRIPTION Provide a flow diagram (using 81/2" x 11-paper if possible) showing the wastewater flow through the facility (from intake through discharge) including all processes, treatment units and bypass piping and include a narrative description that explains the diagram. Show all operations contributing wastewater and the locations of flow meters, chemical feeds, monitoring points and discharge points. The water balance shall show daily average flow rates at intake and discharge points and approximate daily flow rates between treatment units including influent and treatment rates Use actual measurements whenever available, otherwise use the best estimate.

Show all significant losses of water to products, atmosphere and discharge In addition provide a flow diagram for any storm water discharges from secondary structures that are required by state or federal law, and for 'storm water runoff from any Site of Environmental Contamination pursuant to Part 201 of the Michigan Act Do not send blueprints.

Do the treatment facility processes descnbed above, include any lagoons or ponds used for wastewater treatment or storage, En Yes El No If yes, include the ponds or lagoons in the flow diagram.

Municipal Facilities - Include a narrative that briefly describes the history of the wastewater treatment facility and collection system, including the original construction, the facility improvements that have been made, future plans for upgrade, the location of all constructed emergency overflows and other pertinent information.

Industrial and Commercial Facilities - The line diagram shall include all operations contributing wastewater including process and production areas, sanitary flows, cooling water and storm water runoff. Also include a narrative that provides a brief description of the nature of the business and the manufactunng processes ATTACH THIS INFORMATION TO THIS APPLICATION. PLEASE DO NOT BIND THIS INFORMATION.

11 MAP OF FACILITY AND DISCHARGE LOCATION Provide a detailed map on 81/2" X 11-paper showing the location of the existing or proposed facility, wastewater and biosolid treatment system(s),

and wastewater monitoring and discharge points into receiving waters (including bypasses)

Include the exact location of the wastewater monitoring and discharge point(s) and all areas through which the discharge flows (e g wetlands, open drains, storm sewers), if applicable, between the discharge point and the receiving water. If the discharge is to a storm sewer, label the storm sewer and show its flow path to the receiving water. Also include the location of any water supply intakes or wells and groundwater monitoring wells This map shall be a United States Geological Survey Quadrangle (7 5 minute series) or other map of comparable detail, scale and quality (which shows surface water bodies, roads, bathing beaches and other pertinent landmarks). The minimum area this map shall encompass is approximately one mile beyond property boundaries.

ATTACH THIS INFORMATION TO THIS APPLICATION.

12. CONTRACT LABORATORY THAT PROVIDE ANALYTICAL SUPPORT Provide the name and address of each contract laboratory or consulting firm that performed any analyses submitted as part of this application. To submit additional information see page ji, item 8.

Laboratory Name Laboratory Name John E Dolan Labs General Engineering Labs Street Address Street Address 4001 Bixby Road 2040 Savage Road City City Groveport, Ohio Charleston, South Carolina Telephone (with area code)

Fax (with area code)

Telephone (with area code)

Fax (with area code)

(614) 836-4236 (614) 836-4168 (843) 556-8171 (843) 766-1178 Analysis Performed Analysis Performed Metals, TOC, S04, BOD5, Cyanide, TSS, NH3 Metals, TOC, S04, BOD5, Cyanide, TSS, NH3 Laboratory Name Laboratory Name Belmonte Park Environmental Laboratones Cook Nuclear Plant Street Address Street Address 11 E Main St.

One Cook Place City City Dayton, Ohio Bridgman. Michigan vlephone (with area code)

Fax (with area code)

Telephone (with area code)

Fax (with area code) l (937) 837-3744

-TNA (269) 465-5901 (269) 466-2550 Analysis Performed Analysis Performed Table 2 Analyses I pH, TRC, Temp, Ethanolamine, Hydrazine, S04, Metals, TSS I

3 EQP 4659-A (Rev 1/03)

Waste Flow Diagram & Narrative

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t Section I, Item 10 WASTEWATER FLOW DIAGRAM DONALD C. COOK NUCLEAR PLANT I

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Section I, Item 10 Stormwater discharges from Secondary Structures NPDES Permit M10005827 Asphalt I

Roadway rSurrp j

Transformer 12 TR-SACB Location South side of protected area East of Secuity complex Construction Concrete floor and curbing I

Volume 205 gallons Asphalt j

23 gallons per Inch rRoadway Transformer 12 TR-OB1 and 12-TR-1B2.

____ --- i Location North side of protected area North of Office building complex.

Construction Concrete floor and curbing Volume 509gallonseachTotal1018gallons 102 gallons per inch StLrm i

X l2 l

001S StormDrain Transformer 12 TRCAB Location East side of protected area West of RPAC Construction Concrete floor and curbing O~iS IVolume 254 gallons i

i ° ni i30 gallons per inchi i Bulk Chemical Unloading area.

L--------

Location West side of protected area between screenhouse and office building Construction Concrete curbing wth polyethylene liner covered with stone and asphalt Actual Volume 18,275 gallons Working Volurre 90 gallons or 2 gallons per Inch (below stormgrate) approx 314 gallons (using stone asa border) or52 gallons per inch for liquid above storm grate Stonearea. approximately110'xSinsize.

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SECTION I, ITEM 10 Cont'd NPDES Waste Stream Narrative This narrative describes all outfalls discharging to Lake Michigan. Flows are based on a review of previous NPDES applications, Plant system descriptions, or previously submitted Discharge Monitoring Reports (DMR). The chemical additives described below may include a manufacturer's name as an example of the type of product used in a specific system. Indiana Michigan Power may substitute vendors of chemical additives provided that the chemical ingredients are similar. Discharge values are based on maximum release rates and volumes, dilution rates are based on a minimum number of pumps running.

OUTFALL 001 - Unit 1 Circulating Water Discharge Outfall 001 is a non-contact cooling water discharge. The majority of non-contact cooling water (Circulating Water System, -690,000 GPM) is used to condense the steam exhausting from steam driven turbines. Non-contact cooling water is drawn from Lake Michigan approximately one-half mile from shore through three 16 ft. diameter tunnels. Water enters the tunnels via intake cribs at an approximate velocity of-1.3 feet per second. The water enters to a forebay where it is screened to remove large debris that may be entrained in the water. It is routed through the Unit 1 condensers and then discharged to Lake Michigan through a 16 foot diameter tunnel. The water exits the tunnels through high velocity discharges at a rate of approximately 13 feet per second approximately 1/4 mile from shore. Outfall 001 also includes internal Outfalls (as designated by the Michigan Department of Environmental Quality) steam generator Blowdown (OOA, OOB), Plant Heating Boiler (00QC), Reverse Osmosis Unit (OOG), and the Turbine Room Sump Emergency Overflow (OOH) described in detail later in this document.

Outfall 001 also may contain the effluent flow from both Units' Essential Service Water (ESW) systems, both Units' Non-Essential Service Water (NESW) system, and monitor tank releases. ESW (-40,000 GPM) is Lake Michigan water taken from the forebay that is used to provide cooling to safety-related equipment. NESW (-18,000 GPM) is also Lake Michigan water taken from the forebay used for 1

I non-contact cooling for various plant systems including oil coolers, a source of water for the demineralized makeup system (MUP), and a water supply for non-safety related equipment. Monitor tank releases (-15,000 to 20,000 gallons per event) are regulated by the NRC and consist of wastewater from various system and equipment leakage that may be generated within the auxiliary building area.

Minor leakage from systems containing lube oil, hydrazine, carbohydrazide, ethanolamine or closed-loop cooling systems containing a maximum concentration of gluteraldehyde (100 ppm), methyl (bis) thiocyanate (10 ppm), tolyltriazole (60 ppm), Molybdate (1000 ppm), and nitrite (1200 ppm), may be discharged via monitor tank releases.

The non-contact cooling water for the Circulating Water, the ESW and the NESW, and Miscellaneous Sealing and Cooling Water Systems is treated for biological control using sodium hypochlorite. This same water is periodically treated using a non-oxidizing biocide to eradicate zebra mussels from the cooling systems. The biocides (Betz Spectrus CT-1300, Betz CT-4, Calgon H-130M, Calgon EVAC and NALCO Macro-Trol 9380) are all polyquats, and are used as required to protect plant systems while meeting water quality based effluent limits. The treatments can be directed to various critical plant systems from the intake structures through the entire plant cooling system, including the Circulating Water System, ESW and NESW systems and other non-contact cooling water. The biocide may be added to the systems via a chemical injection pipeline through a ring header located inside the intake crib, or directly applied at a specific system. A chemical injection pipeline is installed inside the intake piping and is designed to feed chemicals from inside the plant. The intake chemical injection header may be stored with chemical inside the pipe to prevent zebra mussel infestation. The header may also be leak checked using approved dyes such as fluorescein, or other indicators such as Nalco Trasar 23299. Non-contact cooling systems biocide treatments are dependent upon zebra mussel infestation. Concentrations and chemical feed points are chosen to minimize the amount of biocide required and to maximize the efficacy on zebra mussels. Bentonite clay may be added to detoxify the biocide prior to discharge. The plant non-contact cooling water systems may be treated concurrently or individually to allow more efficient use of chemicals. Plant systems are treated to assure safe operation of the nuclear generating units.

The piping used to apply chemicals is regularly cleaned of calcium carbonate scale buildup. A small amount of weak acid cleaner such as Betz FerroQuest FQ LP 7200 may be used to remove accumulated carbonate scale deposits. The accumulated deposits will be discharged via Outfalls 001/003. Circulating water will dilute the weak acid prior to discharge to Lake Michigan.

2

Condensate flushes are performed periodically to purge the plant's secondary water system from layup chemistry specifications during shutdown conditions to startup chemistry specifications prior to startup of the unit. Water containing up to 4 ppm hydrazine [Betz Cortrol OS5035, Betz Cortrol OS5010, NALCO 19H], 10 ppm carbohydrazide (NALCO 1250 plus, or equivalent), 100 ppm ethanolamine (Betz Powerline 1440, Betz Powerline 1480, NALCO 92UM001), is overboarded to Outfall 001 as required to remove contaminants to meet desired startup secondary Chemistry specifications. This flowrate averages 70 GPM, but may reach 600 GPM for short periods of time. The flowrate is dependent on chemistry specification parameters and makeup water availability. The maximum output from the MUP is approximately 600 GPM or 864,000 GPD. (See Outfalls OA, 0GB for further description.)

Monitor tanks receive treated water from the auxiliary building radioactive waste removal system and other sources such as ice production and removal processes from the ice condenser systems and other radioactively contaminated wastes generated at the facility. This system handles wastes generated from the reactor coolant pump seal leakoffs, the refueling cavity water, equipment leaks, floor drains, valve stem leakoffs, system sampling, and waste sample solutions. It also handles laboratory wastes from the radiochemistry analysis in the hot chemical laboratory, system equipment drains, non-contact cooling water, ice production/removal and decontamination processes and any contaminated liquid waste generated in the auxiliary building area. The wastes are collected in one of several tanks and are treated when enough water is collected. The treatment utilizes a demineralizer system to minimize radioactive contaminants. A small amount of wastewater may bypass the treatment because it cannot be processed by resin.

Other special drains of non-radioactive process water systems such as Component Cooling Water system flushes with biocides such as gluteraldehyde (100 ppm), methyl (bis) thiocyanate (10 ppm), tolyltriazole (60 ppm), Molybdate (1000 ppm) and nitrite (1200 ppm), and borated icemaking/ice removal operations, can be routed directly to the plant's monitor tanks without treatment. For maintenance purposes to prevent microbial growth, Component Cooling Water flushes are performed generating approximately 281,000 gallons per year of flushwater to the monitor tanks.

Borated icemaking/ice removal operations occur for maintenance of the plant's ice condenser systems.

This process produces a solution of sodium tetraborate (approximately 2200 ppm as boron) that can be drained to the monitor tanks. This process takes place approximately every 18 months and may produce up to 10,000 gallons of sodium tetraborate solution.

3

Both the treated wastewater and the special drains are accumulated in the monitor tanks and sampled to ensure the waste meets the radiological requirements prior to being discharged into the Circulating Water System.

Periodically, due to equipment leaks and/or system upsets, a waste stream is generated that contains radioactively contaminated ethylene glycol and water. Incidental amounts of ethylene glycol generated from equipment leaks may be drained directly to the monitor tanks or treated by the radwaste processing system. Small amounts of ethylene glycol may be discharged to outfalls 001, 002, or 003.

Sulfur hexafluoride gas (SF6) is utilized in the non-contact cooling water systems at the plant to detect leaks in various components such as the condensers. The gas is injected in the cooling water stream and discharged to outfalls 001, 002 or 003 at less than 54 ul/l.

Aryl sulfate liquid (NALCO Trasar 23299) is utilized in the non-contact cooling water systems at the plant to determine flow through various parts of the system. The liquid is injected into the service water system to reach a target concentration of approximately 2 mg/I. The service water is discharged to Outfalls 001, 002, or 003, which would, in turn, discharge at less than 0.15 mg/I. The liquid is also injected into the circulating water system to reach a target concentration of approximately 2 mg/L.

Control Room Air Conditioning (CRAC) testing: Approximately 1440 gallons/yr. of CRAC water may mix with ESW and then be discharged to the forebay during a monthly test of the system. CRAC water is demineralized water, and may contain up to: 2000 ppm nitrite [Calgon LCS 60, Betz Corrshield NT 4205, BETZ CORRSHIED NT 4201, Betz Corrshield NT 4203, or equivalent], 100 ppm gluteraldehyde

[from Betz Biotrol 107 (Spectrus NX 1105), Calgon H-300, or equivalent], 60 ppm tolyltriazole [from Calgon LCS-60, Betz Copper-Trol Cu-1, Betz Corrshield NT 4205, BETZ CORRSHIED NT 4201, Betz Corrshield NT 4203, or equivalent], 10 ppm methyl (bis) thiocyanate (from Betz 3610), 1000 ppm molybdate from Betz Corrshield MD 4103 and 25 ppm aryl sulfate (from NALCO 22199).

4

Three roadway storm drains route small amounts of stormwater from a small section of roadway that traverses over the Circulating Water Forebay. The three storm drains are designed to route accumulated stormwater from this small roadway to the forebay below. A small amount of de-icing compound used on this section of road could potentially enter these small (Approximately 8") gratings. Screened material collected from the plant's intakes is also stored in this area in designated trash dumpsters. Fish exudiates are now drained to the forebay as recommended by the MDEQ stormwater and NPDES inspection team (M. Fields and J. Molloy 1997).

During upset conditions it is possible to overflow the contents of the Turbine Room Sump (See Outfall OOH) to Outfalls 001, 002 and/or 003 if the flow path to the on-site absorption pond cannot be used.

OUTFALL 002 - Unit 2 Circulating Water Discharge Outfall 002 is a non-contact cooling water discharge. The majority of non-contact cooling water (Circulating Water System, -920,00 GPM) is used to condense the steam exhausting from steam driven turbines. Non-contact cooling water is drawn from Lake Michigan approximately one-half mile from shore through three 16 ft. diameter tunnels. Water enters the tunnels via intake cribs at an approximate velocity of 1.3 feet per second. The water enters to a forebay where it is screened to remove large debris that may be entrained in the water. It is routed through the Unit 2 condensers and then discharged to Lake Michigan through an 18 foot diameter tunnel. The water exits the tunnels through high velocity discharges at a rate of approximately 13 feet per second approximately 1/4 mile from shore. Outfall 002 also includes internal Outfalls (as designated by the Michigan Department of Environmental Quality) steam generator Blowdown (OOA, OOB), Plant Heating Boiler (OOC), Reverse Osmosis Unit (OOG), and the Turbine Room Sump Emergency Overflow (OOH) described in detail later in this document.

Outfall 002 also may contain the effluent flow from both Units' Essential Service Water (ESW) systems, both Units' Non-Essential Service Water (NESW) system, and monitor tank releases. ESW (-40,000 GPM) is Lake Michigan water taken from the forebay that is used to provide cooling to safety-related equipment. NESW (-18,000 GPM) is also Lake Michigan water taken from the forebay used for 5

non-contact cooling for various plant systems including oil coolers, a source of water for the dernineralized makeup system (MUP), and a water supply for non-safety related equipment. Monitor tank releases (-15,000 to 20,000 gallons per event) are regulated by the NRC and consist of wastewater from various system and equipment leakage that may be generated within the auxiliary building area.

Minor leakage from systems containing lube oil, hydrazine, carbohydrazide, ethanolamine or closed-loop cooling systems containing a maximum concentration of gluteraldehyde (100 ppm), methyl (bis) thiocyanate (10 ppm), tolyltriazole (60 ppm), Molybdate (1000 ppm), and nitrite (1200 ppm), may be discharged via monitor tank releases.

The non-contact cooling water for the Circulating Water, the ESW and the NESW, and Miscellaneous Sealing and Cooling Water Systems is treated for biological control using sodium hypochlorite. This same water is periodically treated using a non-oxidizing biocide to eradicate zebra mussels from the cooling systems. The biocides (Betz Spectrus CT-1300, Betz CT-4, Calgon H-130M, Calgon EVAC and NALCO Macro-Trol 9380) are all polyquats, and are used as required to protect plant systems while meeting water quality based effluent limits. The treatments can be directed to various critical plant systems from the intake structures through the entire plant cooling system, including the Circulating Water System, ESW and NESW systems and other non-contact cooling water. The biocide may be added to the systems via a chemical injection pipeline through a ring header located inside the intake crib, or directly applied at a specific system. A chemical injection pipeline is installed inside the intake piping and is designed to feed chemicals from inside the plant. The intake chemical injection header may be stored with chemical inside the pipe to prevent zebra mussel infestation. The header may also be leak checked using approved dyes such as fluorescein, or other indicators such as Nalco Trasar 23299. Non-contact cooling systems biocide treatments are dependent upon zebra mussel infestation. Concentrations and chemical feed points are chosen to minimize the amount of biocide required and to maximize the efficacy on zebra mussels. Bentonite clay may be added to detoxify the biocide prior to discharge. The plant non contact cooling water systems may be treated at the concurrently or individually to allow more efficient use of chemicals. Plant systems are treated to assure safe operation of the nuclear generating units.

The piping used to apply chemicals is regularly cleaned of calcium carbonate scale buildup. A small amount of weak acid cleaner such as Betz FerroQuest FQ LP 7200 may be used to remove accumulated carbonate scale deposits. The accumulated deposits will be discharged via Outfalls 002/003. Circulating water will dilute the weak acid prior to discharge to Lake Michigan.

6

Condensate flushes are performed periodically to purge the plant's secondary water system from layup chemistry specifications during shutdown conditions to startup chemistry specifications prior to startup of the unit. Water containing up to 4 ppm hydrazine [Betz Cortrol OS5035, Betz Cortrol OS5010, NALCO 19H], 10 ppm carbohydrazide (NALCO 1250 plus, or equivalent), 100 ppm ethanolamine (Betz Powerline 1440, Betz Powerline 1480, NALCO 92UM001), is overboarded to Outfall 002 as required to remove contaminants to meet desired startup secondary Chemistry specifications. This flowrate averages 70 GPM, but may reach 600 GPM for short periods of time. The flowrate is dependent on chemistry specification parameters and makeup water availability. The maximum output from the MUP is approximately 600 GPM or 864,000 GPD. (See Outfalls OA, 00B for further description.)

Monitor tanks receive treated water from the auxiliary building radioactive waste removal system and other sources such as ice production and removal processes from the ice condenser systems and other radioactively contaminated wastes generated at the facility. This system handles wastes generated from the reactor coolant pump seal leakoffs, the refueling cavity water, equipment leaks, floor drains, valve stem leakoffs, system sampling, and waste sample solutions. It also handles laboratory wastes from the radiochemistry analysis in the hot chemical laboratory, system equipment drains, non-contact cooling water, ice production/removal and decontamination processes and any contaminated liquid waste generated in the auxiliary building area. The wastes are collected in one of several tanks and are treated when enough water is collected. The treatment utilizes a demineralizer system to minimize radioactive contaminants. A small amount of wastewater may bypass the treatment because it cannot be processed by resin.

Other special drains of non-radioactive process water systems such as Component Cooling Water system flushes with biocides such as gluteraldehyde (100 ppm), methyl (bis) thiocyanate (10 ppm), tolyltriazole (60 ppm), Molybdate (1000 ppm) and nitrite (1200 ppm), and borated icemaking/ice removal operations, can be routed directly to the plant's monitor tanks without treatment. For maintenance purposes to prevent microbial growth, Component Cooling Water flushes are performed generating approximately 281,000 gallons per year of flushwater to the monitor tanks.

Borated icemaking/ice removal operations occur for maintenance of the plant's ice condenser systems.

This process produces a solution of sodium tetraborate (approximately 2200 ppm as boron) that can be drained to the monitor tanks. This process takes place approximately every 18 months and may produce up to 10,000 gallons of sodium tetraborate solution.

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Both the treated wastewater and the special drains are accumulated in the monitor tanks and sampled to, ensure the waste meets the radiological requirements prior to being discharged into the Circulating Water System.

Periodically, due to equipment leaks and/or system upsets, a waste stream is generated that contains radioactively contaminated ethylene glycol and water. Incidental amounts of ethylene glycol generated from equipment leaks may be drained directly to the monitor tanks or treated by the radwaste processing system. Small amounts of ethylene glycol may be discharged to outfalls 001, 002, or 003.

Sulfur hexafluoride gas (SF6) is utilized in the non-contact cooling water systems at the plant to detect leaks in various components such as the condensers. The gas is injected in the cooling water stream and discharged to outfalls 001, 002 or 003 at less than 54 ul/l.

Aryl sulfate liquid (NALCO Trasar 23299) is utilized in the non-contact cooling water systems at the plant to determine flow through various parts of the system. The liquid is injected into the service water system to reach a target concentration of approximately 2 mg/l. The service water is discharged to Outfalls 001, 002, or 003, which would, in turn, discharge at less than 0.15 mg/I. The liquid is also injected into the circulating water system to reach a target concentration of approximately 2 mg/L.

Control Room Air Conditioning (CRAC) testing: Approximately 1440 gallons/yr. of CRAC water may mix with ESW and then be discharged to the forebay during a monthly test of the system. CRAC water is demineralized water, and may contain up to: 2000 ppm nitrite [Calgon LCS 60, Betz Corrshield NT 4205, BETZ CORRSHIED NT 4201, Betz Corrshield NT 4203, or equivalent], 100 ppm gluteraldehyde

[from Betz Biotrol 107 (Spectrus NX 1105), Calgon H-300, or equivalent], 60 ppm tolyltriazole [from Calgon LCS-60, Betz Copper-Trol Cu-i, Betz Corrshield NT 4205, BETZ CORRSHIED NT 4201, Betz Corrshield NT 4203, or equivalent], 10 ppm methyl (bis) thiocyanate (from Betz 3610), 1000 ppm molybdate from Betz Corrshield MD 4103 and 25 ppm aryl sulfate (from NALCO 22199).

8

Three roadway storm drains route small amounts of stormwater from a small section of roadway that traverses over the Circulating Water Forebay. The three storm drains are designed to route accumulated stormwater from this small roadway to the forebay below. A small amount of de-icing compound used on this section of road could potentially enter these small (Approximately 8") gratings. Screened material collected from the plant's intakes is also stored in this area in designated trash dumpsters. Fish exudiates are now drained to the forebay as recommended by the MDEQ stormwater and NPDES inspection team (M. Fields and J. Molloy 1997).

During upset conditions it is possible to overflow the contents of the Turbine Room Sump (See Outfall OOH) to Outfalls 001, 002 and/or 003 if the flow path to the on-site absorption pond cannot be used.

OUTFALL 003 - Deicing Discharge Outfall 003 is a deicing discharge which is used when water temperatures approach freezing temperatures. A portion of the flow from Outfall 001 and /or Outfall 002 is directed through the center intake tunnel to temper the intake water and prevent ice buildup on the intake structures which could restrict intake flow. The velocity at the other two intake structures during de-icing mode increases to approximately 1.9 feet per second. Discharge velocity will be less that 13 feet per second since a portion of the discharge is routed out the center intake tunnel.

The Essential and Non-Essential Service Water System (ESW and NESW) may be recirculated with a combination of Circulating Water Pumps in service to raise the forebay temperature to prevent frazil ice formation during cold weather periods. During shutdown conditions when normal operating heat addition is not available, portable heat addition units may be placed in the forebay to prevent frazil ice formations that may prevent flow to safety systems in the plant.

OUTFALL OOA - Unit 1 Steam Generator Blowdown The steam generators (part of the secondary water system) require ultra high purity water for operation.

Makeup water used in the steam generators is withdrawn from the intake forebay (or from Lake Township water supply or a blending of both sources) and treated so most natural impurities are removed through sedimentation, filtration, reverse osmosis, and demineralization. Impurities concentrate in the steam generators as the water is turned to steam and must be removed to protect the steam turbines and 9

heat transfer surfaces of the steam generators. The impurities are removed by continuously draining a portion of the water from the steam generators in a process called "blowdown".

In the steam generator, steam is separated from the water, further heated, and then routed to the turbines.

When the steam separates from the water, the impurities remain in the water, concentrating in the steam generator. Blowdown consists of two forms, a liquid portion (700 gpm max) and a wet steam portion, which is exhausted to the atmosphere. The liquid portion of the steam generator blowdown is discharged to the screenhouse forebay either directly (Normal Flash Tank), or after processing through mixed bed demineralizers. Impurnties in this discharge may consist of small quantities of insoluble iron and copper or impurities from the Circulating Water System used to cool the condensers should condenser tube leaks occur. Steam generator additives consist of ethanolamine (Betz Powerline 1440, Betz Powerline 1480, NALCO 92UM001) for pH adjustment, hydrazine [Betz Cortrol OS5035, Betz Cortrol OS5010, NALCO 19H] and/or carbohydrazide (NALCO 1250 plus, or equivalent) for oxygen scavenging.

When the units are not operating, the steam generators are placed in wet layup conditions to protect against corrosion during storage. Layup water is periodically discharged through the outfall to the Circulating Water Forebay. The layup water contains a maximum concentration of 400 ppm hydrazine

[Betz Powerline Cortrol OS5035, Betz Cortrol OS5010, NALCO 19H] and/or 40 ppm carbohydrazide (NALCO 1250 plus, or equivalent), and /or 100 ppm ethanolamine (Betz Powerline 1440, Betz Powerline 1480, NALCO 92UM001). The waste strength of this discharge is reduced through mixing with Outfalls 001, 002, or 003.

During the Sludge Lancing Process, demineralized water or secondary water is used to pressure clean the steam generators during outage periods. The water is recirculated through temporary filters to remove entrained solids. The major constituent of the solids is iron oxide from the steam generators.

The water is then returned to the steam generators and can be drained to Outfalls OA, OOB, to Outfall 001, 002, 003, 0OD or OOH. The suspended solids are analyzed for radioactivity prior to disposal.

OUTFALL OOB - Unit 2 Steam Generator Blowdown The steam generators (part of the secondary water system) require ultra high purity water for operation.

Makeup water used in the steam generators is withdrawn from the intake forebay (or from Lake Township water supply or a blending of both sources) and treated so most natural impurities are removed 10

through sedimentation, filtration, reverse osmosis, and demineralization. Impurities concentrate in the steam generators as the water is turned to steam and must be removed to protect the steam turbines and heat transfer surfaces of the steam generators. The impurities are removed by continuously draining a portion of the water from the steam generators in a process called "blowdown".

In the steam generator, steam is separated from the water, further heated, and then routed to the turbines.

When the steam separates from the water, the impurities remain in the water, concentrating in the steam generator. Blowdown consists of two forms, a liquid portion (700 gpm max) and a wet steam portion, which is exhausted to the atmosphere. The liquid portion of the steam generator blowdown is discharged to the screenhouse forebay either directly (Normal Flash Tank), or after processing through mixed bed demineralizers. Impurities in this discharge may consist of small quantities of insoluble iron and copper or impurities from the Circulating Water System used to cool the condensers should condenser tube leaks occur. Steam generator additives consist of ethanolamine (Betz Powerline 1440, Betz Powerline 1480, NALCO 92UM001) for pH adjustment, hydrazine [Betz Cortrol OS5035, Betz Cortrol OS5010, NALCO 19H] and/or carbohydrazide (NALCO 1250 plus, or equivalent) for oxygen scavenging.

When the units are not operating, the steam generators are placed in wet layup conditions to protect against corrosion during storage. Layup water is periodically discharged through the outfall to the Circulating Water Forebay. The layup water contains a maximum concentration of 400 ppm hydrazine

[Betz Powerline Cortrol OS5035, Betz Cortrol OS5010, NALCO 19H] and/or 40 ppm carbohydrazide (NALCO 1250 plus, or equivalent), and /or 100 ppm ethanolamine (Betz Powerline 1440, Betz Powerline 1480, NALCO 92UM001). The waste strength of this discharge is reduced through mixing with Outfalls 001, 002, or 003.

During the Sludge Lancing Process, demineralized water or secondary water is used to pressure clean the steam generators during outage periods. The water is recirculated through temporary filters to remove entrained solids. The major constituent of the solids is iron oxide from the steam generators.

The water is then returned to the steam generators and can be drained to Outfalls OA, 00B, to Outfall 001, 002, 003, 0OD or OOH. The suspended solids are analyzed for radioactivity prior to disposal.

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OUTFALL QOC - Plant Heating Boiler A heating boiler (150,000 lb/hr capacity) operates to supply plant heating and auxiliary steam when Unit 1 and/or Unit 2 are out of service. The boiler is also fired periodically for testing purposes to ensure its availability.

During periods when not in operation, the heating boiler may be stored full of treated boiler water containing up to 400 ppm hydrazine [Betz Cortrol OS5035, Betz Cortrol OS5010, NALCO 19H] or 40 ppm carbohydrazide (NALCO 1250 plus, or equivalent) for oxygen scavenging and or 50 ppm ethanolamine (Betz Powerline 1440, Betz Powerline 1480, NALCO 92UM001) for corrosion protection.

Prior to use, this "wet lay-up" water is drained to Outfall COC via blowdown, which discharges to the intake forebay. The volume drained is approximately 600 gallons. This boiler may also be occasionally drained for maintenance activities, approximately 6,000 gallons of treated boiler water would be directed to Outfall 00C or OOD/OOH for such purposes.

Impurities from the boiler water consisting primarily of insoluble iron and copper are discharged via blowdown (30 GPM) to the intake forebay during operation as needed for Chemistry control. Boiler water treatment additives consist of up to 15 ppm ethanolamine (Betz Powerhne 1440, Betz Powerline 1480, NALCO 92UM001) for pH adjustment, up to 150 ppb hydrazine [Betz Cortrol OS5035, Betz Cortrol OS5010, NALCO 19H] and/or 150 ppb carbohydrazide (NALCO 1250 plus, or equivalent) for oxygen scavenging and 25 ppm aryl sulfate (from NALCO 22199) for flow testing purposes.

Just after boiler shutdown, the boiler may be placed in dry layup. The boiler contents (up to 6,000 gallons) are drained via blowdown to the intake forebay. Boiler water treatment additives consist of up to 3 ppm ethanolamine (Betz Powerline 1440, Betz Powerline 1480, NALCO 92UM001) for pH adjustment and up to 150 ppb hydrazine [Betz Cortrol OS5035, Betz Cortrol OS5010, NALCO 19H]

and/or 150 ppb carbohydrazide (NALCO 1250 plus, or equivalent) for oxygen scavenging. The boiler is then dried out and stored empty This process saves on chemicals and prevents unnecessary discharge of wet layup chemicals.

A smaller boiler may be installed to provide back-up heat if the permanent heating boiler was out of service. This back-up boiler may be located outdoors on the West Side of the turbine building. The blowdown line is directed to the Unit One forebay, near the same discharge point as the permanently installed heating boiler.

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The same boiler treatment chemistry will be maintained in the back-up boiler as is used in the permanent heating boiler. The back-up boiler treatment additives consist of ethanolamine (Betz Powerline 1440, Betz Powerline 1480, NALCO 92UM001) for pH adjustment, and hydrazine [Betz Powerline Cortrol OS5035, Betz Cortrol OS5010, NALCO 19H] and/or carbohydrazide (NALCO 1250 plus, or equivalent) for oxygen scavenging. This boiler may be occasionally drained for maintenance activities, approximately 6,000 gallons of treated boiler water would be directed to Outfall 00C for such purposes.

Impurities from the boiler water consisting primarily of insoluble iron and copper are discharged via blowdown (30 GPM maximum) to the intake forebay during operation as needed for Chemistry control.

OUTFALL QOG - Reverse Osmosis System The Reverse Osmosis System (RO) is used to assist in the removal of dissolved solids from the lake water prior to demineralization. Reject water flow is directed to the forebay, which leads to Outfalls 001, 002, and 003. Reject water flow rates may reach up to 0.360 MGD. The RO system must maintain very clean membranes to assure efficient operation and purity of water. Several methods are used to maintain this level of cleanliness from scale and biofouling. Hydrochloric acid or sulfuric acid is fed at approximately 1.3 GPH continually when the RO is in service to lower the pH to reduce the scaling tendencies of the water. The reject water from the RO unit consists of concentrated Lake Michigan water and a small amount of acid that inhibits scale buildup in the membranes.

Approximately once per month, a flush is performed using approximately 1,000 gallons of a nominal 0.05% hydrochloric acid solution. This is followed with approximately 1,000 gallons of a nominal 0.1%

sodium hydroxide solution. This flush will dissolve any scale that deposits on the membranes. The total amount of flushing solution will average approximately 5,000 gallons per event. Sodium bisulfite is used to preserve the membranes during long-term shutdown periods. Approximately 15 lbs. of sodium bisulfite per year is used in this manner.

The chemical cleaning involves several steps and may contain citric acid, hydrochloric acid, phosphoric acid, sodium hydroxide, and a neutral pH detergent. The periodic cleaning process averages approximately 10,000 gallons per event, diverted either to the Turbine Room Sump (Outfall 00HI00D),

through the Neutralization Tank to the Turbine Room Sump (Outfall 00H/00D), or to the Circulating Water Forebay (Outfall 001, 002, or 003).

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OUTFALL 00H - Turbine Room Sump Emergency Overflow Utility wastewater from within the plant is discharged via the turbine room sump (TRS) into an on-site absorption pond (Outfall OOD). The normal disposition of these wastewaters is to an on-site absorption pond, which eventually vents via groundwater to Lake Michigan. In the unlikely event that the normal flow path to the absorption pond is not available, the overflow line (Outfall OOH) will direct the TRS flow to the plant's intake forebay. The wastewaters associated with this Outfall include:

Wastes from the makeup water treatment system.

NESW: (144,000 GPD) The main contributor to this waste stream is the degassifier pump seal water.

Non-Essential Service Water (NESW) from Lake Michigan supplies the vacuum degassifier pumps which utilize up to 100 GPM to remove non-condensable gases (primarily carbon dioxide and oxygen) from the makeup plant water and exhausts them to the atmosphere.

• Pre-filter backwash: (Estimated 98,000 GPD) Six pre-filters are backwashed with Lake Michigan water to remove the suspended matter captured on the filter media. Alum solution (aluminum sulfate 0 5 lb. per gallon) is added to the pre-filter influent as a flocculent. The alum is added via a coagulant feed pump. Approximately 50 lb./day of alum is used in this process. The alum contained in the backwash is discharged in the form of insoluble aluminum hydroxide.

Carbon filter backwash: (Estimated 42,000 GPD) Carbon filters are periodically backwashed with Lake Michigan water to the TRS. These filters primarily remove organics, chlorine and small amounts of iron.

Demineralizer regeneration: (Estimated 50,000 gallons per regeneration) occurs 24 times per month when the RO is in service and more often when it is not in service. Dilute sulfuric acid and sodium hydroxide used by the system to regenerate the resin. Dilute sulfuric acid, sodium hydroxide, and contaminates from the demineralization process is discharged to the neutralization tank or TRS.

The pH is then adjusted to between 5.5 and 9.0 with sulfuric acid, or sodium hydroxide prior to discharge.

MUP Neutralization Tank provides a place for demineralization regeneration wastes, and Reverse Osmosis Unit cleaning flushes to be neutralized prior to being discharged to the TRS and ultimately 14

the absorption pond. When the MUP resin beds are regenerated, up to 50,000 gallons of regeneration chemicals, and backwash waters are processed in the neutralization tank. The Reverse Osmosis cleaning flushes average approximately 5,000 gallons per event. When the water is neutralized, it is pumped to the TRS via a 2,000 GPM neutralization waste pump.

• The Retention Tank is periodically blown down, discharging small volumes of solid material removed by settling. The retention tank contains a mixture of Lake Township water and filtered Lake Michigan water waiting further processing by the Makeup Plant.

The Reverse Osmosis System (RO) Cleaning. Normal reject water flow is to Lake Michigan via Outfall 00G. The RO system must maintain very clean membranes to assure efficient operation and purity of water. Several methods are used to maintain this level of cleanliness from scale and biofouling. Hydrochloric acid or sulfuric acid is fed at approximately 1.3 GPH continually when the RO is in service to lower the pH to reduce the scaling tendencies of the water. The reject water from the RO unit consists of concentrated Lake Michigan water and a small amount of acid that inhibits scale buildup in the membranes.

Approximately once per month, a flush is performed using approximately 1,000 gallons of a nominal 0.05% hydrochloric acid solution. This is followed with approximately 1,000 gallons of a nominal 0.1 % sodium hydroxide solution. This flush will dissolve any scale that deposits on the membranes.

The total amount of flushing solution will average approximately 5,000 gallons per event. Sodium bisulfite is used to preserve the membranes during long-term shutdown periods. Approximately 15 lbs. of sodium bisulfite per year is used in this manner.

The chemical cleaning involves several steps and may contain citric acid, hydrochloric acid, phosphoric acid, sodium hydroxide, and a neutral pH detergent. The periodic cleaning process averages approximately 10,000 gallons per event, diverted either to the Turbine Room Sump (Outfall OOH), through the Neutralization Tank to the Turbine Room Sump (Outfall OOH), or to the Circulating Water Forebay (Outfall 001, 002, or 003).

Waste from miscellaneous processes.

During periods when not in operation, the heating boiler may be stored full of treated boiler water containing at most 400 ppm hydrazine [Betz Cortrol OS5035, Betz Cortrol OS5010, NALCO 19H] or 40 ppm carbohydrazide (NALCO 1250 plus, or equivalent) for oxygen scavenging and/or 50 ppm 15

ethanolamine (Betz Powerline 1440, Betz Powerline 1480, NALCO 92UM001) for corrosion protection. Prior to use, this "wet lay-up" water is drained to the TRS. The volume drained is approximately 600 gallons.

The Circulating Water System cooling water contained in the condensers during shutdowns are periodically drained to the TRS. (Six condenser halves and 2 feedpump condensers, approximately 37,000 gallons of lake water per half).

The Component Cooling Water system (CCW) is periodically drained to allow for equipment inspection, maintenance or repair. This system uses demineralized water from the makeup plant as its source of makeup water along with a maximum of: 1200 ppm nitrite [from Calgon LCS 60, Betz Corrshield NT 4205, BETZ CORRSHIED NT 4201, Betz Corrshield NT 4203, or equivalent], 100 ppm gluteraldehyde [from Betz Spectrus NX 1105, Calgon H-300, or equivalent], methyl (bis) thiocyanate (10 ppm) [from Betz 3610 or equivalent], 60 ppm tolyltriazole (from Betz Copper-Trol Cu-1, Calgon LCS-60, or equivalent) ), 1000 ppm molybdate from Betz Corrshield MD 4103, and 25 ppm aryl sulfate (from NAL6O 22199). The infrequent drainings release approximately 60,000 gallons of treated water to the TRS per year.

There are four Emergency Diesel Generators that are each cooled by an Emergency Diesel Generator cooling jacket water system (DJW), which employs chemical control for corrosion with a maximum of 2000 ppm nitrite [Calgon LCS 60 or Betz Corrshield NT 4205, BETZ CORRSHIED NT 4201, Betz Corrshield NT 4203 or equivalent], 100 ppm gluteraldehyde [Betz Spectrus NX 1105, Calgon H-300, or equivalent], methyl (bis) thiocyanate (10 ppm) [from Betz 3610 or equivalent], 60 ppm tolyltriazole [Betz Copper-Trol Cu-1, Calgon LCS-60, or equivalent] ), 1000 ppm molybdate from Betz Corrshield MD 4103, and 25 ppm aryl sulfate [from NALCO 22199].

This system is drained through the floor drains to the TRS when maintenance is performed. Each system volume is approximately 1000 gallons. Any system leaks would also be directed to the floor drain during normal operations.

Control Room Air Conditioning (CRAC) drains: Approximately 1440 gallons/yr. of CRAC water is drained to the TRS. CRAC Water is demineralized water, and may contain up to: 2000 ppm nitrite

[Calgon LCS 60, Betz Corrshield NT 4205, BETZ CORRSHIED NT 4201, Betz Corrshield NT 4203 or equivalent], 100 ppm gluteraldehyde [Betz Spectrus NX 1105, Calgon H-300, or equivalent],

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methyl (bis) thiocyanate (10 ppm) [from Betz 3610 or equivalent], 60 ppm tolyltriazole (Calgon LCS-60, Betz Copper-Trol Cu-1, or equivalent) ), 1000 ppm molybdate from Betz Corrshield MD 4103, and 25 ppm aryl sulfate (NALCO 22199). The system may be flushed with demineralized water, and when completed, corrosion control chemicals will be added back to the system. No additions of corrosion controlling chemicals are done during the demineralized water flush.

The Essential Service Water systems (ESW) and Non-Essential Service Water systems (NESW) are also periodically drained to allow for equipment inspection, maintenance, or repair. These drains may discharge Lake Michigan water used for non-contact cooling into the TRS. This water may be chlorinated for zebra mussel control. During some special treatment periods, this water may contain zebra mussel biocides, used as a molluscicide for zebra mussel control. Periodically, components of the ESW or NESW systems may be chemically cleaned to remove iron deposits using vendor supplied cleaning solution such as EDTA (ethylenediaminetetraacetic acid) or ascorbic acid, acetic acid and ammonia. These wastes could either be drained to the TRS or Lake Michigan via Outfall 001, 002, or 003.

During wet lay-up, the steam generators are stored full of water with up to 400 ppm of hydrazine from Betz Cortrol OS5035, Betz Cortrol OS5010, NALCO 19H or 40 ppm carbohydrazide (NALCO 1250 plus, or equivalent) and 100 ppm ethanolamnine (Betz Powerline 1440, Betz Powerline 1480, NALCO 92UM001) are added for corrosion control. The water may also contain up to 20 ppm boron. This water is normally drained to surface water via NPDES Outfalls OOA or 00B, but may be drained to the TRS in some instances. Drain volume will be approximately 32,000 gallons for each of the unit's four steam generators.

The Miscellaneous Drain Tanks can be aligned to discharge to the TRS. As much as 350,000 gallons per day per unit may be directed to the TRS to control the chemistry limitations on the secondary water systems. Water chemistry is primarily the same as in the steam generators. This type of batch drain occurs in concert with condensate flushing activities, or it may occur during normal operation to adjust system chemistry. The overboarded water is normal secondary water. It may contain a mixture of ethanolamine, hydrazine [Betz Cortrol OS5035, Betz Cortrol OS5010, NALCO 19H], or carbohydrazide (NALCO 1250 plus, or equivalent). Maximum flows may approach 240 GPM as makeup plant water supplies can deliver.

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Condensate flushes are performed periodically to clean up the plant's secondary system prior to startup, and can be discharged to the TRS. Water containing up to 2 ppm hydrazine [Betz Cortrol OS5035, Betz Cortrol OS5010, NALCO 19H], 10 ppm carbohydrazide (NALCO 1250 plus, or equivalent), 100 ppm ethanolamine (Betz Powerline 1440, Betz Powerline 1480, NALCO 92UM001), is overboard to the TRS as required to remove contaminants. This flow rate averages 70 GPM, but may reach 600 GPM for short periods of time. The flow rate is dependent on water demands in the plant. Maximum output from the MUP is approximately 600 GPM.

Around the plant, miscellaneous sumps collect an estimated 45,000 GPD of water from various equipment drains (ESW pipe tunnel sump). Water and condensate leaks from valves and pumps (Circulating Water condenser pit sumps, ESW pipe tunnel sump, heater drain pump room sump, screen wash pump room sump, acid and caustic room sumps, elevator pit sumps, screenhouse electrical equipment enclosure sump) will also be drained to the TRS. Steam jet air ejector drains also are directed to the heater drain pump room sump prior to pumping to the TRS. Betz FerroQuest FQ LP 7200 may be added to this sump to prevent scale buildup.

Miscellaneous floor drains are located throughout the plant to provide a safe working environment by routing spilled or leaked water to the TRS. The major chemical influx into these drains is from general floor cleaning products used to maintain the floors. Also routed to the TRS through the floor drains are fire protection water, chlorinated Lake Township water, drinking water, cooling water (ESW/NESW), and drains from bioboxes used to monitor the zebra mussel control measures and other chemical control monitors. The bioboxes will discharge chlorine and zebra mussel biocides during periods when the Service Water Systems are treated with previously mention biological control agents.

Chemical feed tank drains (drains are limited to emergencies only). There are eight chemical feed tanks that are approximately 200 gallons each that contain hydrazine [Betz Cortrol OS5035, Betz Cortrol OS5010, NALCO 19H] at approximately 2%, ethanolamine (Betz Powerline 1440, Betz Powerlne 1480, NALCO 92UM001), at approximately 5%, carbohydrazide (NALCO 1250 plus, or equivalent), approximately 2%. Normal process will be to collect these tank volumes to be reused whenever possible.

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Chemical cleaning tank drains: During refueling and maintenance outages, the chemical cleaning tank, and or temporary tanks may be used to mix borax (sodium tetraborate @ approximately 2000 ppm as boron) solutions for ice making operations. Small portions of the system may be drained to the TRS. In the unlikely event that a full tank is drained, approximately 3500 gallons will be directed to the TRS.

Non-radiological chemical lab sink and floor drains are routed to the TRS for disposal. The drains carry water and the wastes generated while performing analyses and preparing laboratory standard including those on the attached list. Also discharged will be glassware cleaning and normal laboratory cleaning wastes. The average volume directed to the TRS is estimated to be 500 -1000 GPD.

• Secondary sample water from continuous analyzers are routed to drains which discharge to the TRS and/or the miscellaneous drain tank. The analyzers are on the cycles that may contain as much as 150 ppb hydrazine from either a direct feed or (as a breakdown product of carbohydrazide, and 2.5 ppm ethanolamine. The analyzers measure corrosion transport at an average flow of 1440 gallons per day when in operation.

• Miscellaneous sealing and cooling water (MSCW) supplies cooling and sealing water to the TRS pumps, Condensate Booster Pumps, Circulating Water Pumps, Vacuum Priming Pumps, Drain Seal Reservoir Tanks, MSCW pump sealing water, screen wash pumps sealing water, and Drain Sample Coolers. The flow per day may reach approximately 576,000 gallons; this water is filtered and chlorinated Lake Michigan water.

Non-essential service water supplies approximately 53,000 GPD of non-contact cooling water to various sample coolers throughout the plant's turbine building.

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Chemical spills that enter the TRS may be neutralized within the sump to prevent a discharge to the environment. The potential for spills to the TRS exists for the following chemicals with the proposed neutralizers listed:

Chemical Associated Neutralizer Sulfuric acid Sodium hydroxide Sodium hydroxide Sulfuric acid Sodium hypochlorite Sodium thiosulfate Hydrazine NESW (lake water), Hydrogen peroxide, sodium hypochlorite.

Ethanolamine Sodium Hypochlorite, Hydrogen Peroxide, or ozone.

Ethylene glycol Hydrogen peroxide Reduction of hydrazine and ETA prior to discharge to the absorption pond may include additions of chemicals such as sodium hypochlorite, hydrogen peroxide, or ozone to the Turbine Room Sump in batches, or to the discharge piping as continuous treatment. A downstream treatment system provided by a vendor may be used to break down the hydrazine and ETA.

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ADDITIONAL CHEMICAL LAB ANALYSES Additional Information Section I Item 11 Donald C. Cook Nuclear Plant Surface Water Permit Application Plant Chemistry Lab (To Outfall OOEHOOD)

Laboratory sink drains from the 633' Turbine lab are directed to the 90,000 gallon Turbine Room Sump.

The sump contents are normally directed to the groundwater discharge (outfall 00D). Occasionally the Emergency by-pass may be utilized and the sump's contents will be discharged to the surface water discharge (outfall OOH). The following analyses are performed in the lab. Laboratory wastes from the analyses are discarded in the sink.

Parameter Analysis Method Nitrite HACH DR-2000 Method 373, HACH DR 2010 Method 373 Hydrazine ASTM D-1385 -88 Oil and Grease EPA-600-4-79-020 Method 413.1 pH Standard Methods for the examination of Water and Wastewater, ASTM-1293 Total Phosphorus EPA-6004-79-020 Method 365.3 Sulfate EPA-600-4-79-020 Method 375.4 Total Residual Chlorine EPA-6004-79-020 Method 330.5 Ethanolamine (ETA)

Betz Standard Operating Procedure. 9Betz proprietary Method adapted from HACH Dr-2000 1,2-Naphthoguinone-4-sulfonic acid Method.

ICP Metals Standard Methods for Examination of water and wastewater - 17' ed. 1989, 3120B.

Tolyltriazole HACH DR-2000 Method 730 Carbohydrazide HACH DR-2000 Method 732 HACH DR-2010 Method 182 N,N Diethylhyroxylamine (DEHA)

HACH DR-2010 Method 182 Silica ASTM D 859-88 21

GROUNDWATER DISCHARGES OUTFALL OOD - Turbine Room Sump Utility wastewater from within the plant is discharged via the turbine room sump (TRS) into an on-site absorption pond (Outfall 00D). The normal disposition of these wastewaters is to an on-site absorption pond, which eventually vents via groundwater to Lake Michigan. In the unlikely event that the normal flow path to the absorption pond is not available, the overflow line (Outfall OOH) will direct the TRS flow to the plant's intake forebay. The wastewaters associated with this Outfall include:

Wastes from the makeup water treatment system.

NESW: (144,000 GPD) The main contributor to this waste stream is the degassifier pump seal water.

Non-Essential Service Water (NESW) from Lake Michigan supplies the vacuum degassifier pumps which utilize up to 100 GPM to remove non-condensable gases (primarily carbon dioxide and oxygen) from the makeup plant water and exhausts them to the atmosphere.

• Pre-filter backwash: (Estimated 98,000 GPD) Six pre-filters are backwashed with Lake Michigan water to remove the suspended matter captured on the filter media. Alum solution (aluminum sulfate 0.5 lb. per gallon) is added to the pre-filter influent as a flocculent. The alum is added via a coagulant feed pump. Approximately 50 lb./day of alum is used in this process. The alum contained in the backwash is discharged in the form of insoluble aluminum hydroxide.

Carbon filter backwash: (Estimated 42,000 GPD) Carbon filters are periodically backwashed with Lake Michigan water to the TRS. These filters primarily remove organics, chlorine and small amounts of iron.

Demineralizer regeneration: (Estimated 50,000 gallons per regeneration) occurs 24 times per month when the RO is in service and more often when it is not in service. Dilute sulfuric acid and sodium hydroxide used by the system to regenerate the resin. Dilute sulfuric acid, sodium hydroxide, and contaminates from the demineralization process is discharged to the neutralization tank or TRS.

The pH is then adjusted to between 5.5 and 9 0 with sulfuric acid, or sodium hydroxide prior to discharge.

22

MUP Neutralization Tank provides a place for demineralization regeneration wastes, and Reverse Osmosis Unit cleaning flushes to be neutralized prior to being discharged to the TRS and ultimately the absorption pond. When the MUP resin beds are regenerated, up to 50,000 gallons of regeneration chemicals, and backwash waters are processed in the neutralization tank. The Reverse Osmosis cleaning flushes average approximately 5,000 gallons per event. When the water is neutralized, it is pumped to the TRS via a 2,000 GPM neutralization waste pump.

The Retention Tank is periodically blown down, discharging small volumes of solid material removed by settling. The retention tank contains a mixture of Lake Township water and filtered Lake Michigan water waiting further processing by the Makeup Plant.

The Reverse Osmosis System (RO) Cleaning. Normal reject water flow is to Lake Michigan via Outfall 00G. The RO system must maintain very clean membranes to assure efficient operation and purity of water. Several methods are used to maintain this level of cleanliness from scale and biofouling. Hydrochloric acid or sulfuric acid is fed at approximately 1.3 GPH continually when the RO is in service to lower the pH to reduce the scaling tendencies of the water. The reject water from the RO unit consists of concentrated Lake Michigan water and a small amount of acid that inhibits scale buildup in the membranes.

Approximately once per month, a flush is perforned using approximately 1,000 gallons of a nominal 0.05% hydrochloric acid solution. This is followed with approximately 1,000 gallons of a nominal 0.1% sodium hydroxide solution. This flush will dissolve any scale that deposits on the membranes.

The total amount of flushing solution will average approximately 5,000 gallons per event. Sodium bisulfite is used to preserve the membranes during long-term shutdown periods. Approximately 15 lbs. of sodium bisulfite per year is used in this manner.

The chemical cleaning involves several steps and may contain citric acid, hydrochloric acid, phosphoric acid, sodium hydroxide, and a neutral pH detergent. The periodic cleaning process averages approximately 10,000 gallons per event, diverted either to the Turbine Room Sump (Outfall OOH), through the Neutralization Tank to the Turbine Room Sump (Outfall OOH), or to the Circulating Water Forebay (Outfall 001, 002, or 003).

23

Waste from miscellaneous processes.

During periods when not in operation, the heating boiler may be stored full of treated boiler water containing at most 400 ppm hydrazine [Betz Cortrol OS5035, Betz Cortrol OS5010, NALCO 19H] or 40 ppm carbohydrazide (NALCO 1250 plus, or equivalent) for oxygen scavenging and/or 50 ppm ethanolamine (Betz Powerline 1440, Betz Powerline 1480, NALCO 92UM001) for corrosion protection. Prior to use, this "wet lay-up" water is drained to the TRS. The volume drained is approximately 600 gallons.

The Circulating Water System cooling water contained in the condensers during shutdowns are periodically drained to the TRS. (Six condenser halves and 2 feedpump condensers, approximately 37,000 gallons of lake water per half).

The Component Cooling Water system (CCW) is periodically drained to allow for equipment inspection, maintenance or repair. This system uses demineralized water from the makeup plant as its source of makeup water along with a maximum of: 1200 ppm nitrite [from Calgon LCS 60, Betz Corrshield NT 4205, BETZ CORRSHIED NT 4201, Betz Corrshield NT 4203, or equivalent], 100 ppm gluteraldehyde [from Betz Spectrus NX 1105, Calgon H-300, or equivalent], methyl (bis) thiocyanate (10 ppm) [from Betz 3610 or equivalent], 60 ppm tolyltriazole (from Betz Copper-Trol Cu-1, Calgon LCS-60, or equivalent) ), 1000 ppm molybdate from Betz Corrshield MD 4103, and 25 ppm aryl sulfate (from NALCO 22199). The infrequent drainings release approximately 60,000 gallons of treated water to the TRS per year.

There are four Emergency Diesel Generators that are each cooled by an Emergency Diesel Generator cooling jacket water system (DJW), which employs chemical control for corrosion with a maximum of 2000 ppm nitrite [Calgon LCS 60 or Betz Corrshield NT 4205, BETZ CORRSHIED NT 4201, Betz Corrshield NT 4203 or equivalent], 100 ppm gluteraldehyde [Betz Spectrus NX 1105, Calgon H-300, or equivalent], methyl (bis) thiocyanate (10 ppm) [from Betz 3610 or equivalent], 60 ppm tolyltriazole [Betz Copper-Trol Cu-1, Calgon LCS-60, or equivalent] ), 1000 ppm molybdate from Betz Corrshield MD 4103, and 25 ppm aryl sulfate [from NALCO 22199].

This system is drained through the floor drains to the TRS when maintenance is performed. Each system volume is approximately 1000 gallons. Any system leaks would also be directed to the floor drain during normal operations.

24

Control Room Air Conditioning (CRAC) drains: Approximately 1440 gallons/yr. of CRAC water is drained to the TRS. CRAC Water is demineralized water, and may contain up to: 2000 ppm nitrite

[Calgon LCS 60, Betz Corrshield NT 4205, BETZ CORRSHIED NT 4201, Betz Corrshield NT 4203 or equivalent], 100 ppm gluteraldehyde [Betz Spectrus NX 1105, Calgon H-300, or equivalent],

methyl (bis) thiocyanate (10 ppm) [from Betz 3610 or equivalent], 60 ppm tolyltriazole (Calgon LCS-60, Betz Copper-Trol Cu-1, or equivalent) ),1000 ppm molybdate from Betz Corrshield MD 4103, and 25 ppm aryl sulfate (NALCO 22199). The system may be flushed with demineralized water, and when completed, corrosion control chemicals will be added back to the system. No additions of corrosion controlling chemicals are done during the demineralized water flush.

The Essential Service Water systems (ESW) and Non-Essential Service Water systems (NESW) are also periodically drained to allow for equipment inspection, maintenance, or repair. These drains may discharge Lake Michigan water used for non-contact cooling into the TRS. This water may be chlorinated for zebra mussel control. During some special treatment periods, this water may contain zebra mussel biocides, used as a molluscicide for zebra mussel control. Periodically, components of the ESW or NESW systems may be chemically cleaned to remove iron deposits using vendor supplied cleaning solution such as EDTA (ethylenediaminetetraacetic acid) or ascorbic acid, acetic acid and ammonia These wastes could either be drained to the TRS or Lake Michigan via Outfall 001, 002, or 003.

During wet lay-up, the steam generators are stored full of water with up to 400 ppm of hydrazine from Betz Cortrol OS5035, Betz Cortrol OS5010, NALCO 19H or 40 ppm carbohydrazide (NALCO 1250 plus, or equivalent) and 100 ppm ethanolamine (Betz Powerline 1440, Betz Powerline 1480, NALCO 92UM001) are added for corrosion control. The water may also contain up to 20 ppm boron. This water is normally drained to surface water via NPDES Outfalls OA or OOB, but may be drained to the TRS in some instances. Drain volume will be approximately 32,000 gallons for each of the unit's four steam generators.

The Miscellaneous Drain Tanks can be aligned to discharge to the TRS. As much as 350,000 gallons per day per unit may be directed to the TRS to control the chemistry limitations on the secondary water systems. Water chemistry is primarily the same as in the steam generators. This type of batch drain occurs in concert with condensate flushing activities, or it may occur during normal operation to adjust system chemistry. The overboarded water is normal secondary water. It may contain a mixture of ethanolamine, hydrazine [Betz Cortrol OS5035, Betz Cortrol OS5010, 25

NALCO 19H], or carbohydrazide (NALCO 1250 plus, or equivalent). Maximum flows may approach 240 GPM as makeup plant water supplies can deliver.

Condensate flushes are performed periodically to clean up the plant's secondary system prior to startup, and can be discharged to the TRS. Water containing up to 2 ppm hydrazine [Betz Cortrol OS5035, Betz Cortrol OS5010, NALCO 19H], 10 ppm carbohydrazide (NALCO 1250 plus, or equivalent), 100 ppm ethanolamine (Betz Powerline 1440, Betz Powerline 1480, NALCO 92UM001), is overboard to the TRS as required to remove contaminants. This flow rate averages 70 GPM, but may reach 600 GPM for short periods of time. The flow rate is dependent on water demands in the plant. Maximum output from the MUP is approximately 600 GPM.

Around the plant, miscellaneous sumps collect an estimated 45,000 GPD of water from various equipment drains (ESW pipe tunnel sump). Water and condensate leaks from valves and pumps (Circulating Water condenser pit sumps, ESW pipe tunnel sump, heater drain pump room sump, screen wash pump room sump, acid and caustic room sumps, elevator pit sumps, screenhouse electrical equipment enclosure sump) will also be drained to the TRS. Steam jet air ejector drains also are directed to the heater drain pump room sump prior to pumping to the TRS. Betz FerroQuest FQ LP 7200 may be added to this sump to prevent scale buildup.

Miscellaneous floor drains are located throughout the plant to provide a safe working environment by routing spilled or leaked water to the TRS. The major chemical influx into these drains is from general floor cleaning products used to maintain the floors. Also routed to the TRS through the floor drains are fire protection water, chlorinated Lake Township water, drinking water, cooling water (ESW/NESW), and drains from bioboxes used to monitor the zebra mussel control measures and other chemical control monitors. The bioboxes will discharge chlorine and zebra mussel biocides during periods when the Service Water Systems are treated with previously mention biological control agents.

Chemical feed tank drains (drains are limuted to emergencies only). There are eight chemical feed tanks that are approximately 200 gallons each that contain hydrazine [Betz Cortrol OS5035, Betz Cortrol OS5010, NALCO 19H] at approximately 2%, ethanolamine (Betz Powerline 1440, Betz Powerline 1480, NALCO 92UM001), at approximately 5%, carbohydrazide (NALCO 1250 plus, or equivalent), approximately 2%. Normal process will be to collect these tank volumes to be reused whenever possible.

26

Chemical cleaning tank drains: During refueling and maintenance outages, the chemical cleaning tank, and or temporary tanks may be used to mix borax (sodium tetraborate @ approximately 2000 ppm as boron) solutions for ice making operations. Small portions of the system may be drained to the TRS. In the unlikely event that a full tank is drained, approximately 3500 gallons will be directed to the TRS.

Non-radiological chemical lab sink and floor drains are routed to the TRS for disposal. The drains carry water and the wastes generated while performing analyses and preparing laboratory standard including those on the attached list. Also discharged will be glassware cleaning and normal laboratory cleaning wastes. The average volume directed to the TRS is estimated to be 500 -1000 GPD.

Secondary sample water from continuous analyzers are routed to drains which discharge to the TRS and/or the miscellaneous drain tank. The analyzers are on the cycles that may contain as much as 150 ppb hydrazine from either a direct feed or (as a breakdown product of carbohydrazide, and 2.5 ppm ethanolamine. The analyzers measure corrosion transport at an average flow of 1440 gallons per day when in operation.

• Miscellaneous sealing and cooling water (MSCW) supplies cooling and sealing water to the TRS pumps, Condensate Booster Pumps, Circulating Water Pumps, Vacuum Priming Pumps, Drain Seal Reservoir Tanks, MSCW pump sealing water, screen wash pumps sealing water, and Drain Sample Coolers. The flow per day may reach approximately 576,000 gallons; this water is filtered and chlorinated Lake Michigan water.

Non-essential service water supplies approximately 53,000 GPD of non-contact cooling water to various sample coolers throughout the plant's turbine building.

27

Chemical spills that enter the TRS may be neutralized within the sump to prevent a discharge to the environment. The potential for spills to the TRS exists for the following chemicals with the proposed neutralizers listed:

Chemical Associated Neutralizer Sulfuric acid Sodium hydroxide Sodium hydroxide Sulfuric acid Sodium hypochlorite Sodium thiosulfate Hydrazine NESW (lake water), Hydrogen peroxide, sodium hypochlorite.

Ethanolamine Sodium Hypochlorite, Hydrogen Peroxide, or ozone.

Ethylene glycol Hydrogen peroxide Reduction of hydrazine and ETA prior to discharge to the absorption pond may include additions of chemicals such as sodium hypochlorite, hydrogen peroxide, or ozone to the Turbine Room Sump in batches, or to the discharge piping as continuous treatment. A downstream treatment system provided by a vendor may be used to break down the hydrazine and ETA.

28

ADDITIONAL CHEMICAL LAB ANALYSES Additional Information Section I Item 11 Donald C. Cook Nuclear Plant Surface Water Permit Application Plant Chemistry Lab (To Outfall 00HU00D)

Laboratory sink drains from the 633' Turbine lab are directed to the 90,000 gallon Turbine Room Sump.

The sump contents are normally directed to the groundwater discharge (outfall 00D). Occasionally the Emergency by-pass may be utilized and the sump's contents will be discharged to the surface water discharge (outfall OOH). The following analyses are performed in the lab. Laboratory wastes from the analyses are discarded in the sink.

Parameter Analysis Method Nitrite HACH DR-2000 Method 373, HACH DR 2010 Method 373 Hydrazine ASTM D-1385 -88 Oil and Grease EPA-600-4-79-020 Method 413.1 pH Standard Methods for the examination of Water and Wastewater, ASTM-1293 Total Phosphorus EPA-600-4-79-020 Method 365.3 Sulfate EPA-600-4-79-020 Method 375.4 Total Residual Chlorine EPA-600-4-79-020 Method 330.5 Ethanolamine (ETA)

Betz Standard Operating Procedure. 9Betz proprietary Method adapted from HACH Dr-2000 1,2-Naphthoguinone-4-sulfonic acid Method.

ICP Metals Standard Methods for Examination of water and wastewater - 17 h ed. 1989, 3120B.

Tolyltriazole ACH DR-2000 Method 730 Carbohydrazide HACH DR-2000 Method 732 HACH DR-201I Method 182 N,N Diethylhyroxylamine (DEHA)

HACH DR-2010 Method 182 Silica ASTM D 859-88 OUTFALL GOE - Sanitary Waste Discharges The system operates at a designed flow of 50,000 GPD with a maximum flow capacity of 60,000 GPD.

The Sequencing Batch Reactor (SBR) system treats the wastewater and discharges to an effluent tank where it can be filtered prior to discharge to one of two seepage lagoons. The lagoons discharge into the -

groundwater with the ultimate disposition venting to Lake Michigan. The sludge removed from the digester tank basins is taken to a local POTW (public owned treatment works) for disposal or dewatered and stored as low level radioactive waste, and disposed of as appropriate.

29

To aid in the settling process, flocculents such as ferric chloride, pH controllers such as magnesium hydroxide, or polymers (such as Axchem AF4500) are added to the process. To selectively enhance biosolids, bioaugmentation nutrients (such as Bioprime Dosfolat) are added to the process. This is a nutrient that encourages the growth of beneficial microbes in the activated sludge. Sodium hypochlorite is added in small amounts to the process to control filamentous bacteria growth if needed. Sodium hypochlorite and detergent are also added to the sand filters to clean them periodically. These are then backwashed into the equalization basin to be reprocessed by the SBR treatment process.

Plant sanitary waste consists of shower and rest room facilities, and janitor washbasins located throughout the Plant's non-radiological property. Kitchen wastes are generated from the plant cafeteria, the Cook Energy Information Center and Training buildings.

The chemistry training laboratory discharges to the sewage treatment plants through a limestone bed neutralization tank. The chemistry lab is used to train technicians on analyses performed in the plant The discharge from the lab carries water and wastes generated while performing analyses and preparing laboratory standards including those on the attached list. The training building HVAC system also drains through the limestone bed.

The wastewater treatment plant laboratory discharges to the sewage treatment plants. The discharge from the lab carries water and wastes generated from performing analyses and preparing laboratory standards used for compliance monitoring of the sewage treatment plant under groundwater discharge permit M00988.

Portable toilet wastes on the plant site may be collected and discharged to the sewage treatment plants.

A biodegradable deodorant is used in the portable toilets Sludge effluent waste may also be recycled through the plants to decrease the amount of sludge for processing when possible.

Miscellaneous rinsing of waste receptacles and possible cleaning operations waste, utilizing various detergents, may be rinsed to the sewage treatment plants.

30

Site Map

Donald C. Cook Nuclear Plant Part 11 M10005827

Donald C. Cook Nuclear Plant Part 11 M10005827

JrFMt2OO3 OFALtOOI3 00

"-I

Adjacent Property Owners

Michigan Department of Environmental Quality-Water Division WASTEWATER DISCHARGE PERMIT APPLICATION PLEASE SECTION I - General Information PLEASE TYPE OR PRINT I -ACILITY NAME NPDES PERMIT NUMBER K I maid C Cook Nuclear Plant I M10005827 13 LIST ADJACENT PROPERTY OWNERS List the names and addresses of all property owners adjacent to the facility, treatment systems, and discharge locations To submit additional information see page ii, item 8.

Name Address City State ZIP Code Tengerstrom, Eric H 3415 S, 591h St Cicero IL 60650 Gielniewski. Michael Z & Teresa B 4500 Lake Rd Stevensville Ml 49127 Vesely, Alan Kobler, Rich+Matthews 5004 S. Long Ave Chicago IL 60638 Lewis, James G Jr 4183 Lake Ct Stevensville Ml 49127 Gilpin, Clark and Nancy 4291 Lake Rd Stevensville Ml 49127 Giese, Marie E.

3180 N Lakeshore Dnve Chicago IL 60657 Gottschall, Bruce A & Susan M 5216 Blackstone Dr Chicago IL 60615 Balka, Ronald A & Janet M 3334 Louise Dr Lansing IL 60438 Michigan Dept of Natural Resources PO Box 307358 Lansing Ml 48909 Franklin Real Estate c/o PO Box 60 Ft Wayne IN 46801 3mmel, Edward P.

9617 E. Shore Dr Oak Lawn IL 60453 Caparo, WIlliam E. & Oyler, Kathryn 122 S. Ellsworth PI South Bend IN 46635 Rosemary Beach Coro 3415 S 59'h St Cicero IL 60650 Lake Charter Twp 3220 Shawnee Road Bridgman Ml 49106 ln'diana Michigan Power PO Box 60 Ft Wayne IN 46801 Technisand, Inc PO Box 177 Wedron IL 50557

14. STORM WATER DISCHARGES A

Is the storm water from this facility discharged to the waters of the state either directly or through a separate storm water drainage system?

0D Yes 0 No B Is the discharge (see definitions on page ill of the application)

O Non-Regulated Storm Water o Regulated Storm Water C. Is any of the storm water discharged from

[

Secondary containment structures that are required by state or federal law o

Areas identified on Michigan's list of Sites of Environmental Contamination, pursuant to the Natural Resources and Environmental Protection Act, PA 451 of 1994, Part 201 (formerly 307)

. His completesSection I. TWTDS requesting authorization for domestic wastewaters or biosolids should complete

`,-

Section II. All other applicants should complete Section IlIl.

If assistance is needed completing this application, contact the Permits Section, telephone number: 517-373-8088.

4 EQP 4659-A (Rev 1/03)

FACILITY NAME NPDES PERMIT NUMBER Donald C Cook Nuclear Plant M10005827 I

13.

LIST ADJACENT PROPERTY OWNERS List the names and addresses of all property owners adjacent to the facility, treatment systems, and discharge locations information see page ii, item 8.

Name Address City State To submit addition; ZIP Code Ruff, Tmothy 7500 Thorton Dr Stevensville Ml 49127 Emery, Martin; Hopkins, Elwood J 7499 Thorton Dr.

Stevensville Ml 49127 Indiana Michigan Power PO Box 24400 Canton OH 44701 Blue Jay Association PO Box 2000 St. Joseph Ml 49085 Michigan Dept of Transportion Lansing Ml 48900 Franklin Real Estate c/o PO Box 60 Ft. Wayne IN 46801 I

This completesSection I. TWTDS requesting authorization for domestic wastewaters or biosolids should complete Section II. All other applicants should complete Section IlIl.

If assistance is needed completing this application, contact the Permits Section, telephone number: 517-373-8088.

Section II

Michigan Department of Environmental Quality-Water Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION 11 - Sanitary Wastewater Section il is to be completed by Publicly Owned Treatment Works discharging treated or untreated sanitary and industrial wastewater to the surface waters Section It is also to be completed by all privately owned treatment facilities discharging treated sanitary wastewater to the surface

\\y waters The privately owned treatment facilities in this category generally include Mobile Home Parks, Campgrounds, Condominiums, Hotels and Motels, Nursing Homes, etc A. Facility Information PLEASE TYPE OR PRINT FACILITY NAME NPDES PERMIT NUMBER

1.

SERVICE AREA INFORMATION A List the source(s) of water supply in the area served by sewers Identify groundwater wells, surface water intakes and the name(s) of any surface water(s) from which intake water is drawn.

Publicly Owned Treatment Works shall provide the following information:

B List the governmental jurisdictions (cities, townships, villages, etc ) that this facility serves (applicants should include themselves) What is the population in each jurisdiction? Is the jurisdiction's collection system separate, combined or both? If the collection system is both separate and combined, what percentage is combined' To submit additional information see page ii, item 8 Name Population Served Type of Collection System Percent Combined C. Provide the total population served by this facility.

Privately Owned Treatment Works shall provide the following information:

D. Provide the number of residential units served by this facility E. Describe the service area (mobile home park, condominium, nursing home, industrial facility, etc)

2.

BIOMONITORING FOR ACUTE AND CHRONIC TOXICITY Publicly Owned Treatment Works (POTWs) meeting one or more of the following cnteria must submit with this application the results of whole effluent toxicity (WET) tests for each of the facility's discharge points excluding combined sewer overflows: 1) POTWs with a design flow rate greater than or equal to one (1) million gallons per day, 2) POTWs with an approved Federal Industrial Pretreatment Program (FIPP); and/or

3) POTWs required to develop a FIPP At a minimum, these results must include quarterly WET testing for a 12-month period prior to this application, or at least annually from the 5 years pnor to this application. In addition, submit with this application the results of any other WET tests from the past 5 years If a WET test in the past 4-% years revealed toxicity, provide all the information on the cause of toxicity or the results of all toxicity reduction evaluations, if any were conducted ForWETTest Guidance and Requirements see page 14 of the N.P.D.E.S. Permit Application Appendix.

5s EQP 4659-B (Rev 1/03)

Michigan Department of Environmental Quality-Water Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION II,- Sanitary Wastewater B. Outfall Information l iTRUCTIONS FOR COMPLETING SECTION II, ITEM B.1.

I This item requests detailed information on each outfall at the facility. For this item, outfall refers to the discharge of treated wastewater. Fill in the Outfall Number in the top right hand box identifying the outfall by number, e g., 001, 002, etc (applicants with existing NPDES permits should refer to the facility's current NPDES permit for outfall number identification). For each outfall provide the location, the expected and/or measured volume of effluent discharged, the frequency of discharge and the flow variation of the discharge.

A WATERSHED:

Identify the receiving stream's watershed Each receiving stream will eventually discharge into one of the Great Lakes or one of the connecting waters (i e. Detroit River, St Mary's River, St. Clair River). Indicate from which river the discharge eventually discharges to the Great Lakes. For example: Sycamore Creek is tributary to the Red Cedar River, which is tributary to the Grand River, which discharges to Lake Michigan. Consequently a discharge to the Sycamore Creek is a discharge to the Grand River Watershed.

B. RECEIVING WATER: Identify the exact location of the wastewater discharge point(s) and all areas through which the discharge flows (e g. storm sewers, open drains, wetlands), if applicable, between the discharge point and the receiving water. Examples of receiving waters are rivers, creeks, drains, etc C. COUNTY I TOWNSHIP: Provide the county and township where the outfall is located.

D. STATE PLANAR COORDINATES: Provide the location of the discharge to the receiving water in State Planar Coordinates. Report State Planar Coordinates using quarter-quarter section, quarter section, section, town and range (e g, NE 1/4, SE 1/4, Section 34, T1N, R12E)

E LATITUDE / LONGITUDE: Provide the latitude and longitude of the discharge accurate within 15 seconds (e g., Latitude = 42°27'15-,

Longitude = -83O02'30") or accurate within 0 004 decimal degrees (e g, Latitude = 42 454167, Longitude -83 041667).

F. FACILITY ANNUAL AVERAGE DESIGN FLOW: Enter the Annual Average Design Flow that the facility is designed to treat in millions of gallons per day (MGD)

Seasonal dischargers shall enter the total volume (million gallons per year (MGY) of wastewater the facility is designed to treat and discharge per year. This number will be used in determination of appropriate effluent limitations.

Also provide the actual annual average facility flow and the maximum daily facility flow for the past three years.

G. SEASONAL DISCHARGE: A discharge is considered to be seasonal if the facility treats and then stores wastewater throughout the year or portion of the year and discharges it a few days, weeks or months a year. Provide the dates the facility discharges the treated wastewater (e.g., October 15 through November 10) and the average discharge flows (e g., 5 MGD).

H. CONTINUOUS DISCHARGE: A discharge is any discharge that is not a seasonal discharge. Provide the approximate hours per day and the number of days per year that the discharge occurs from this outfall. Batch Dischargers shall provide the peak batch flow rate, the number of batches per day, the per batch minimum, average and maximum volumes in gallons, and the per batch minimum, average and maximum batch discharges in minutes.

6 EQP 4659-B (Rev 1/03)

Michigan Department of Environmental Quality-Water Division WASTEWATER DISCHARGE PERMIT-APPLICATION SECTION I I-Sanitary Wastewater B Outfall Information Ki 'nplete a separate Section II. B. Outfall Information (pages 7 - 15) for each outfall at the facility. Make copies of Section II. B. for each additional outfall that discharges treated wastewater PLEASE TYPE OR PRINT

[FACILITY NAME NPDES PERMIT NUMBER OUTFALL NUMBER 1.

OUTFALL INFORMATION (see page 6 for Instruction on completion of this page)

A Watershed B

Receiving Water C.

D.

E F.

G H

County Township

%4, 1/4 Section Town Range Latitude Longitude Facility Annual Average Design Flow Seasonal Discharge MGY (Continue with Item G.)

Continuous Discharge MGD (Continue with Item H)

Seasonal Discharge List the discharge penods (by month) in the space provided below. (for further guidance see the directions for Item G on page 6)

From Through Discharge Volume (MGD)

Annual Total (MGY)

From Through Discharge Volume (MGD)

From Through Discharge Volume (MGD)

From Through Discharge Volume (MGD)

Continuous Discharge How often is there a discharge from this outfall (on the average)

Hours/Day Days/Year Provide the actual facility flows for the past three years Three Years Ago Two Years Ago Last Year Annual Average Daily Flow (MGD)

Maximum Daily Flow in a Single Day (MGD)

Batch dischargers must provide the following additional information:

Is there effluent flow equalization' D

Yes Cl No Batch Peak Flow Rate Number of batches discharged per day.

Minimum Average Maximum Batch Volume (gallons)

Batch Duration (minutes) 7 EQP 4659-B (Rev 1/03)

Michigan Department of Environmental Quality-Water Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION 11 - Sanitary Wastewater B. Outfall Information dNT

-ASE TYPE OR PF

.,,;ILITY NAME INPDES PERMIT NUMBER IOUTFALL NUMBER 2

2 EFFLUENT CHARACTERISTICS - CONVENTIONAL POLLUTANTS Existing TWTDS must provide effluent testing data for the parameters listed below. (See pages l and iil for sampling definitions, including "maximum daily concentration' and "maximum monthly concentration' )

New TWNTDS must provide estimated effluent concentrations for the parameters listed below.

For analytical requirements, see page ii number 5. If Alternate Test Procedures have been approved for any parameter listed below, see item 9 on page ii for additional instructions.

El Check this box if additional information is included as an attachment. To submit additional information see page ii, item 8.

5 aim u maximu

/>si>

,,-M-..<EDal t 0 D aily:

M o n t niy N u m er o F

parameter i'

Conc entrationr Uits-Analyses)

SampleTypen Biochemical Oxygen Demand - five day (BODs) mg/El 2 Grab 0/

it s

El Grab BODs, Lowest % Removal EDo 24 HraComp mgEl Grab Carbonaceous BOD5 (CBODs) mg/

24 Hr Comp El Grab Carbonaceous BOD 5, Lowest % Removal DoNotUse

_El 24 Hr Comp mg/l El Grab Ammonia Nitrogen (as N)

________El 24 Hr Comp-AI Suspended Solids mg/l El Grab El 24 Hr Coin Total Susoended Solids. Lowest % Removal El Grab l 24 Hr Comn mg/I El Grab Total Dissolved Solids 24 Hr Comp mg/I El Grab Total Phosphorus (as P)

El 24 Hr Comp max. 7-day counts/100 ml Fecal Coliform Bacteria (report geometric means)

Grab l pg/

Total Residual Chlorine mg/l Grab min daily mvGd l

mg/I El Grab Dissolved Oxygen l_ 24 Hr Comp minimum maximum El Grab pHstandard unitsEl 24 Hr Comp El Grab Temperature E

El24 Hr Comp El Grab El 24 Hr Comp El Grab El 24HrComp El Grab El 24 Hr Comp El Grab E l 2 4 H r C o m p E1 Grab El 24 Hr CompI El Grab El 24 Hr Como El Grab F1 24 Hr CnmnI L

_______I

~I I

r 8

EQP 4659-B (Rev 1/03)

Michigan Department of Env,

-mental Quality-Water Division WASTEWATER DISCHAKiE PERMIT APPLICATION SECTION 11 - Sanitary Wastewater B. Outfall Information PLEASE TYPE OR PRINT FACILITY NAME NPDES PERMIT NUMBER OUTFALL NUMBER 3

EFFLUENT CHARACTERISTICS -TOXIC POLLUTANTS Existing Publicly Owned Treatment Works (POTWs) with a design flow greater than or equal to 1 0 MGD or an approved Federal Industrial Pretreatment Program (FIPP), or required to develop a FIPP or otherwise required by the permitting authority to provide the Information, must provide effluent testing data for the pollutants listed below. Any effluent testing data for pollutants not specifically listed must be included using the In the blank rows provided on page 15. Provide the results of a minimum of three effluent analyses for each outfall through which effluent is discharged using approved methods pursuant to 40 CFR Part 136. Do not include information on combined sewer overflows in this section.

At a minimum, effluent testing data must be based on at least three pollutant scans for each outfall discharging effluent to waters of the state. For analytical requirements, see page II number 5.

All existing POTWs must provide (unless already provided as specified above)- the results of at least one effluent analysis (taken in the last 5 years) for any chemical that Is known or believed to be present in facility effluent that is listed in Tables 2, 3 and 4 of the appendix; a measured or estimated effluent concentration for any chemical that is known or believed to be present that Is listed in table 5 of the appendix; a measured or estimated concentration for any toxic or otherwise injurious chemical known or believed to be present in facility effluent that is not previously identified in this application; and, results of all other effluent analyses that have been performed within the past 5 years for any chemical listed In Tables 2. 3, 4 and 5.

New POTWs must provide: An estimated effluent concentration for any chemical expected to be present in facility effluent that Is listed In Tables 2, 3, 4 and 5 of the appendix, and an estimated effluent concentration for any toxic or otherwise injurious chemical known or believed to be present in facility effluent that is not previously identified In this application.

Note If the effluent concentrations are estimated, place an E In the Analytical Method" column. In accordance with Rule 323.1211(7), facilities whose supply water contains toxic pollutants that are withdrawn from and discharged to the same body of water may qualify for intake credits for those toxic pollutants. See Rule 1211(7) for qualification and demonstration requirements.

All effluent data submitted in response to this part should be recorded on pages 9 -15. To submit additional information see page ii, item 8.

If Alternate Test Procedures have been approved for any parameter listed below, see Item 9 on page ii for additional Instructions.

SAMPLE DATE l

l l

l l____l_________________

Con<d 'tj7 -GConc;av Conc. e-Cone a ~t Cono.

Conc.-

I Cone.'

Conc.

"Conc.% ;

M Conce Sample-l Analyticl-PARAMETER NO. A;-j

', f'<ug/l)o.

Z (wg/l) g(

'(ughI),-

e Metd Q

(

') D METALS (TOTAL RECOVERABLE), CYANIDE, PHENOLS, AND HARDNESS Antimony 7440360 Arsenic 7440382 Beryilium 7440417 Cadmium 7440439 Chromium 7440473 Copper 7440508 Lead 7439921 Mercury (EPA 7439976 M ethod 1631) 9 EQP 4659-B (Rev 1/03)

Michigan Department of Env, mental Quality-Water Division WASTEWATER DISCHAKjE PERMIT APPLICATION SECTION 11 - Sanitary Wastewater B. Outfall Information PLEASE TYPE OR PRINT FACILITY NAME NPDES PERMIT NUMBER

=U UTFALL NUMBER SAMPLE DATE 4

'~;~CSI~

Colc.,,,,,'Cnc Cn.

Coc Conc.>', 7onConc onc>

cConc. Conc.,,,,~Conc.-

SampleIY ;Analyhcic~-

PARAMETER J(N?

-u.CA 5

i)

Method '

t DL Nickel 7440020 Selenium 7782492 Silver 7440224 Thallium 7440280 Zinc 7440666 Cyanide 57125 Total phenolic None compounds None Hardness (as None CAC0 3)

SAMPLE DATE -

C

'51' VOACcnL Conc.E' -

Conc.

-, Conc. '+Cpnc.

'Conc.- -concJ

'Conc.ORGANI COMConc.O SUNDAnalyt

~PARAMEEV o'~~

(gI)"Nug/1)>~ ~'ug0iY (uI) iz~)/

(g W juI) uh

~hj

(~

lv-.~ 'y&

M thd-1j"Ql jD VOLATILE ORGANIC COMPOUNDS Acrolein 107028 Acrylonitnle 107131 Benzene 71432 Bromoform 75252 Carbon 56235 tetrachloride563 Chlorobenzene 108907 Chlorodibromometh 124481 ane Chloroethane 75003 2-chloro-ethylvinyl 110758 ether

(

'0 EQP 4j

' (Rev 1/03)

Michigan Department of Envi

-mental Quality-Water Division WASTEWATER DISCHAKjE PERMIT APPLICATION SECTION 11 - Sanitary Wastewater B. Outfall Information C

PLEASE TYPE OR PRINT FACILITY NAME

=NPDES PERMIT NUMBER

=OUTFALL NUMBER SAMPLE DATE

i CAST 2'_Conc.

, Conc_

.,,Con,'

Conc.

C o nl c:

Conc.'::,Cn AConc.,

CnConc.

n S

Talytic PAAETER~

<N(6KI 119 u)P

(~I uI)

~gIl UI)

Ug/1li) 4 ~~t<

<ugIt

~~I

`~TYIe',4

'Method', ~QŽZD Chloroform 67663 Dichlorobromo-75274 methane 1.1-dichloroethane 75343 1,2-dichloroethane 107062 Trans-1,2-dichloro-156605 ethylene 1,1-75354 dichloroethylene 1,2-dichloropropane 78875 1,3-dichloro-542756 propylene Ethylbenzene 100414 Methyl bromide 74839 Methyl chloride 74873 Methylene chloride 75092 1,1,2,2-tetra-79345 chloro, ethane Tetrachloroethylene 127184 Toluene 108883 1t1,1-71556 trichloroethane 715 1,1,2-90 trichloroethane 790 Trichloroethylene 79016 Vinyl chloride 75014 I1I EQP 4659-B (Rev 1/03)

Michigan Department of Env mental Quality-Water Division WASTEWATER DISCHAI-jE PERMIT APPLICATION SECTION 11 - Sanitary Wastewater B. Outfall Information PLEASE TYPE OR PRINT FACILITY NAME NPDES PERMIT NUMBER lOUTFALL NUMBER SAM PLE DATE I

I 1 1

_ 1 CAS.>-

Cc Conc.

Con' CAnX 5 Ar Conc.,

C n

Conc.

• onc

,Conr u 1Sa(u/pel rAna Ly ACID-EXTRACTABLE COMPOUNDS P-chloro-m-creso None 2-chlorophenol 95578 2,4-dichlorophenol 120832 2,4-dimethylphenol 105679 4,6-dinitro-o-cresol 534521 2,4-dinitrophenol 51285 2-nitrophenol 88755 4-nitrophenol 100027 Pentachlorophenol 87865 Phenol 108952 2.4,6-88062 trichlorophenol 886 SAMPLE DATE 4

[ARAM TER Q1Conc."

Con.

C Cnn....

I Conc.

e A n aCInc:

(g 1

yt I c<C PAAEE

~

No.<`

(ug:l) ug/I) 5(ug/I),~

(ug/1)

(ugh) /

uh) u/)<igI uh) ug/1)V

_Llype JMto L

BASE-NEUTRAL COMPOUNDS Acenaphthene 83329 Acenaphthylene 208968 Anthracene 120127 Benzidine 92875 Benzo(a)-

56553 anthracene563

( 2 EQP 4_ ' (Rev 1/03)

(7 Michigan Department of Env

-mental Quality-Water Division WASTEWATER DISCHAkE PERMIT APPLICATION SECTION 11 - Sanitary Wastewater B. Outfall Information C

PLEASE TYPE OR PRINT FACILITY NAME NPDES PERMIT NUMBER lOUTFALL NUMBER SAMPLE DATE 4 T

,,CAS C

,-n, Conc.-

Conc.

u,,Conc. Cone-' ;,Conc.

-u I Conc.

Conc.

-Sarnple-Analytic,.

MtRA ETE%< N:;u(igIY i)i~f (iuii/I). wi/)

2 uupV

,l)

(JII<

ag__________

0 2g/ 7,Typi'17 M"lethod" QL DJIL Benzo(a)pyrene 50328 3,4 benzo-205992 fluoranthene 259 Benzo(ghi)perylene 191242 Benzo(k)fluoranthe 207089 ne Bis (2-chloroethoxy) 111911 methane__

Bis (2-chloroethyl)-

111444 e th e r__

Bis (2-chloroiso-108601 propyl) ether__

Bis (2-ethylhexyl) 171 phthalate 117817 4-bromophenyl 101553 phenyl ether Butyl benzyl 85687 phthalate 85687 2-918 chloronaphthalene 91587 4-chlorophenyl 7005723 phenyl ether 7005723_____

Chrysene 218019 Dt-n-butyl phthalate 84742 DI-n-octyl phthalate 117840 Dibenzo(ah) 53703 anthracene 1,2-950 dichlorobenzene 95501 1,3-513 dichlorobenzene 541731 1,4-166 dichlorobenzene 106467 3,3-91941 dichlorobenzidlne 914I_

13 EQP 4659-B (Rev 1/03)

Michigan Department of Env mental Quality-Water Division WASTEWATER DISCHAtisE PERMIT APPLICATION SECTION 11 - Sanitary Wastewater B Outfall Information PLEASE TYPE OR PRINT FACILITY NAME NPDES PERMIT NUMBER OUTFALL NUMBER SAMPLE DATE 4 =

~

W2,islCASK',3/4ttrl wCo p

c 3/4Cnc CAn.~ 4Conc.<c3 Conc.

C Conc.

>.Conc.-

ConcConc.

Sample,'

Analytic-PARAMETER"72 NO,.,,

(gI uh (gl7.

(gI~~~(gI (gI)

(g)

~

gi (g

Tipe

-eho §QL DL Diethyl phthalate 84662 Dimethyl phthalate 131113 2,4-dinitrotoluene 121142 2,6-dinitrotoluene 606201 1,2-126 diphenylhydrazine 122667 Fluoranthene 206440 Fluorene 86737 Hexachlorobenzene 118741 Hexachlorobutadien 87683 e

Hexachiorocyclo-77474 pentadiene744 Hexachloroethane 67721 Indeno(1.2,3-139 cd)pyrene 193395 Isophorone 78591 Naphthalene 91203 Nitrobenzene 98953 N-nitrosodi-n-None propylarnine N-625 nitrosodimethylamr 62759 N-nitrosodiphenylami 86306 Phenanthrene 85018 Pyrene 129000 C

Q 14 EQP 47 ' (Rev 1/03)

(

Michigan Department of Env

'mental Quality-Water Division WASTEWATER DISCHALjE PERMIT APPLICATION SECTION 11 - Sanitary Wastewater B. Outfall Information

(

PLEASE TYPE OR PRINT FACILITY NAME NPDES PERMIT NUMBER OUTFALL NUMBER SAMPLE DATE 4

<.nCAS Conc.

'-Conc.,J-Cone.,

Conc.

^ Conc ; Cone.,%Cc Conc.7, Conc.',

!>Conc-

-C Sample

Analytic, PARAMETER 7-No.

fg (bzg/l)

(ugui):

'-(ugiI)

s Method QL.

DL 1,2,4-120821 trichlorobenzene 102

=_____

_______=

=

=

==________________

====___

1 5 EQP 4659-B (Rev 1/03)

Michigan Department of Environmental Quality-Water Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION 11 - Sanitary Wastewater C. Combined Sewer System Information A'EASE TYPE OR PRINT

,ILITY NAME NPDES PERMIT NUMBER 1

COLLECTION SYSTEM INFORMATION Complete this item if there are outfalls at the treatment facility or along the collection system from which discharges of untreated or partially treated wastewater occur. If there are more than 10 outfalls, make copies of page 17.

A Estimate the percentage of the collection system that is combined B System Map Provide a map that shows all CSO discharge points C. System Diagram Provide a diagram, either in the above map or on a separate drawing, of the combined sewer collection system that includes the locations of major trunk line sewers, both combined and separate sanitary; the locations of points where separate sanitary sewers feed into the combined sewer system; the locations of in-line and off-line storage structures; locations of flow regulating devices and the locations of pump stations.

2.

OUTFALL INFORMATION A Identify the outfall by number (e g 001, 002, etc ). Applicants with existing NPDES permits should refer to their current NPDES permit for outfall number identification, provide the name of the receiving water to which the outfall discharges.

B Enter the county and city/township (where applicable) in which the outfall is located C Provide the location in State Planar Coordinates.

D Describe the location using latitude and longitude (accurate within 15 seconds)

Note: If the outfall discharges effluent from a retention treatment basin attach a summary of influent and effluent data from the last five years A

Outfall Number Receiving Water B.

County City or Township C.

A,/4 Section Town Range D.

Latitude (accurate within 15 seconds)

Longitude (accurate within 15 seconds)

A.

B.

C.

D.

A.

B.

C.

D.

16 EQP 4659-C (Rev 1/03)

Michigan Department of Environmental Quality-Water Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION 11 - Sanitary Wastewater C. Combined Sewer System Information UINT ASE TYPE OR PF f ILITY NAME NPDES PERMIT NUMBER OUTFALL INFORMATION - Continued Use this sheet to describe additional ouffalls Make additional copies of this page if necessary.

A.

Outfall Number Receiving Water B

County City or Township C

1,/

Section Town Range D.

Latitude (accurate within 15 seconds)

Longitude (accurate within 15 seconds)

A Outfall Number Receiving Water B

County City or Township C.

/4 Section ITown Range D.

Latitude (accurate within 15 seconds)

Longitude (accurate within 15 seconds)

A Outfall Number Receiving Water B

County City or Township C.

Y4 Section ITown Range D

Latitude (accurate within 15 seconds)

Longitude (accurate within 15 seconds)

A Outfall Number Receiving Water B

County City or Township C

1/4, Section Town Range D.

Latitude (accurate within 15 seconds)

Longitude (accurate within 15 seconds)

A Outfall Number l

Receiving Water AI B

County City or Township C.

4, Y4 Section Town Range D.

Latitude (accurate within 15 seconds)

Longitude (accurate within 15 seconds) 17 EQP 4659-C (Rev 1/03)

Michigan Department of Environmental Quality-Water Division WASTEWATER DISCHARGE PERMIT-APPLICATION SECTION 11 - Sanitary Wastewater D. Non-Domestic Wastewater Information rLEASE TYPE OR PRINT CILITY NAME NPDES PERMIT NUMBER

1.

SEPTAGE - Does this facility accept septage?

El No, continue with Item 2 below.

a1 Yes, on a separate sheet, describe the allocation of the Maximum Allowable Headworks Loading (MAHL) capacity to domestic wastewater, nondomestic wastewater and septage. The MAHL should include the treatment plant's design and current loading, and at a minimum, the number of gallons and concentrations of the following pollutants, BOD, TSS, P04, and NH3 attributable to each wastewater.

2 INDUSTRIAL AND COMMERCIAL SOURCES A. Does this facility receive any nondomestic wastewater from any industnal or commercial facilities? (Nondomestic wastewater refers to water carned wastes other than human and household wastes )

El No, continue with Section II E.

El Yes, continue with B below.

B. Provide the following information

1) Estimate the average volume of non-sanitary wastewater received by this facility:

gallons/day

2) Describe the type of nondomestic wastewater(s) received by this facility in the space provided below (check all that are appropriate).

Wastewater Type Volume (MGD)

Wastewater Type Volume (MGD)

Industrial Process Wastewater Landfill leachate Contact cooling water Trucked Industnal Wastewater Noncontact cooling water Other C. Is an Industnal Pretreatment Program (IPP) currently required by the DEQO Note: Applicants with an Industnal Pretreatment Program must also complete Item 5 on page 19 El No, continue with Item 3. below.

El Yes, provide the most recent approval date for the following elements of your program Continue with Item 3. below Sewer Use Ordinance Interjurisdictonal Agreements Procedures Other Legal Authonty Enforcement Response Plan Local Limits

3.

RESOURCE CONSERVATION AND RECOVERY ACT (RCRA) WASTEWATER Does the treatment works receive or has it in the last three years received RCRA hazardous waste by truck, rail or dedicated pipe?

El No, continue with 4 below.

El Yes, provide the following information on a separate sheet The method that the waste is received (truck, rail, or dedicated pipe), the waste's

'EPA Hazardous Waste Number, and the amount of waste received in either mass or volume

4.

REMEDIATION WASTEWATER Does the treatment facility receive (or has it been notified that it will receive in the next 5 years) wastes from remedial activities?

E No, continue with Section I.E E Yes, provide a list on a separate sheet that contains the following information for each current and future remediation site

1) Describe the site and type of facility at which the CERCLA/RCRA/or other remedial waste originates or will originate.

2) List the hazardous constituents that are or are expected to be received at the POTW Indude data on volume and concentration if known

3) Descnbe in detail any treatment the waste receives before being discharged to the POTW.

4) Provide the schedule that the remediation wastewater is discharged to the POTW.

l 8 EQP 4659-C (Rev 1/03)

Michigan Department of Environmental Quality-Water Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION 11 - Sanitary Wastewater D. Non-Domestic Wastewater Information 1RINT D' EASE TYPE OR F LITY NAME INPDES PERMIT NUMBER 5

SIGNIFICANT INDUSTRIAL USER (SIU) INFORMATION Supply the following information for each SIU that discharges to the treatment plant. Make additional copies of this page when necessary.

A SIU location information Company Facility Address City State Zip B Describe all of the industrial processes that affect or contribute to the SIUs discharge C. Describe all of the principal processes and raw materials that affect or contnbute to the SIU's discharge D. Flow Rate. What are the average daily volume(s) of wastewater discharged to the collection system Are the discharge(s) conbnuous or intermittent.

Type of Wastewater Volume of Discharge (gpd)

Continuous or Intermittent Process Wastewater Non-Process Wastewater E Pretreatment Standards. Indicate whether the SIU is subject to one or both of the following El Local Limits El Categorical Pretreatment Standards Category Subcategory Category Subcategory Category Subcategory Category Subcategory F. Describe any problems at the treatment plant or in the collection system (e g upsets, pass through, interference, blockages) attributed to waste discharged by this SIU during the last three years.

19 EQP 4659-C (Rev 1/03)

I Michigan Department of Environmental Quality-Water Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION 11 - Sanitary Wastewater E. Biosolids Information ZINT EASE TYPE OR PF

.ACILITY NAME INPDES PERMIT NUMBER w)

1.

BIOSOLIDS HANDLING Provide total English dry tons per 365-day period of residuals handled under the following practices Amount generated at the facility:

Amount sent to municipal solid waste landfill.

Amount received from off-site Amount sold or given away in a bag or other container for application to the land.

Amount treated on-site (including blending)

Amount Transported to another POTW Amount used or disposed by another practice:

Transport Company Amount applied to land in bulk form:

Receiving POTW Amount fired in incinerator

2.

BIOSOLIDS STORAGE Enter the volume of residual storage capacity at this facility.

Cl million gallons or El cubic feet

3.

BIOSOLIDS CHARACTERISTICS Report one year residuals monitoring data, and in no case less than three sampling events for the following parameters Provide the actual analytical data sheets as an attachment. Analytical methods shall be in accordance with R 323 2406 (2) Methods for Biosolids.

77 r%.w.

Avera.ge.

l, ". A, - "I t

l otal Solid!

"'
Z' -

""-

"z"'

-,"'O'

-,, "

'-T

_"
"

'

"
e r., " -o, " !, " --, 4

- -
' Z-d I

rt-i Aerag~e ' g

¢-, Monthly -

Concentratgont

<E 4 S;

lak

'I, tS-Q A_ Maxiimuum>

I Concentration A

l

_ _ _ @_ it l

Units~

K Number of 7 analyses:

SaipeType~

"ei I, A o, I Analytical-

, t, Methods B Quantifications 1

4 Level

,~ Iced-~

, Level -I 4o 1S S A dJ 4 Is I

4 4

l-'

4-El Grab F1 Comoosite J

Total Arsenic Mg/kg a Grab E l C o m p o s ite Total Cadmium Mg/kg E Grab Total Copper Mg/kg El Grab El Composite Total Lead Mg/kg El Grab Mg/kgEl composite Total Mercrybe Mg/kg 0 Grab Total Mercuy Mg/kg El Composite Total Molybdenum Mg/kg EC p

Grab El Grab sit Total Nickel Mg/kg El Grab Total Selenium Mg/kg El Grab Ammonium______El Composite Grab Tota Zin Mg/g El Grab Total Zinc M g/kg

~~~E l C om posite Total Kjeldahl Nitrogen Mg/kg El Grab E C o m p o s ite Ammonium Nitrogen Mg/kg El Co p sterab__

I Iotal Phosphorus I Total Potassium Mg/kg 1-E Grab IF rnmnnqitis t

I -I-

- I-, --

Mg/kg OE Grab I

Crnmnnanct I

I I.

20 EQP 4659-C (Rev 1/03)

Michigan Department of Environmental Quality-Water Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION 11 - Sanitary Wastewater E. Biosolids Information V ASE TYPE OR PRINT A

.ACILITY NAME NPDES PERMIT NUMBER I

4 POLLUTANTS OF CONCERN Are there currently or is there potential for pollutants (other than parameters listed on the previous page) to be present in the residuals at concentrations that would make them unsuitable for land application?

El No, continue with Item 5.

El Yes, on a separate sheet provide representative analytical data for those pollutants.

5 ADDITIONAL BIOSOLIDS MONITORING DATA Report any biosolids monitoring data from the last permit cycle for parameters not specifically listed on the previous page. Include the actual analytical data sheets as an attachment Upon submittal review, additional monitoring may be required if the Water Division has reason(s) to suspect that the information provided (or not provided) does not adequately characterize the residuals proposed to be land applied. For assistance completing this item call the Permits Section To submit additional information see page ii, item 8 Aveirage Monthly, Maximum

-Units Number.

-n I

ytical-uantifcation

.rer Concentrations Concentration v

Analyses

. Sample Type-Method -

Level a

Grab ElComposite E Grab El Composite El Grab El Composite El1 Grab CEl Composite El Grab El Composite El Grab

__ Composite ElGrab ElComposite ElGrab E l C om posite 6

LAND APPLICATION SITE LIST Provide the following information for every new or existing site that may be used in the next five years (biosolids permit cycle). Each listed site should have been submitted to the MDEQ on a Site Identification Form (with attachments) since January 1, 1998 or the required information should be included with this form. Additional sites may be added to the Land Application Site List during the biosolids permit cycle by submitting a completed Site Identification Form with the appropnate attachments and waiting the required ten day notification period To submit additional information see page ii, item 8 Site identification Number 1,Latitude ILc ngitude-

'AONew Sit CPLR Site_`:

El El El El1 El E

El El[

El 21 EQP 4659-C (Rev 1/03)

Michigan Department of Environmental Quality-Water Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION 11 - Sanitary Wastewater F Signature Page CD' EASE TYPE OR PRINT

lLITY NAME INPDES PERMIT NUMBER

1.

CERTIFICATION Rule 323.2114(1-4) promulgated under the Michigan Act, requires that this application be signed as follows A. For a municipal, state, or other public facility, by a pnncipal executive officer or ranking elected official (such as the mayor, village president, city or village manager or clerk)

B. For an organization, company, corporation or authority, by a principal executive officer.

C For a partnership, by a general partner.

D For a sole proprietor, by the proprietor.

Note: If the signatory is not listed above, but is authonzed to sign the application, please provide documentation of that authorization 71 certify under penalty of law that / have personally examined and am familiar with the information submitted in this application and all attachments and that, based on my inquiry of those individuals immediately responsible for obtaining information, I believe that the information is true, accurate and complete I am aware that there are signrifcant penalties for submitting false information, including the possibility of fine and impnsonment."

Print Name Title Representing Signature Date If the application is for a privately owned treatment system serving a mobile home park, campground, apartment complex, condominium, nursing home, pnson, or other facility for treatment of domestic wastewater from two or more residences, a principal executive officer or a ranking elected official from the local unit of government shall sign the permit application in the space provided The signature is only a certification that the local unit of government is aware of its responsibilities as set forth in Section 3109(2) of Michigan Act 451, P A. of 1994, as amended The refusal of the local unit of government to sign the application does not reduce its liability under the statute.

This Is to certify that I am aware of and recognize the responsibilties of the municipality as set forth in Section 3109(2) of Michigan Act 451, PA. of 1994. as amended" Print Name Title Representing Signature Date This completesSection II. Return the completed application, (Sections I, II and any attachments) to the appropriate This completes Section 11. Return the completed application, (Sections 1, 11 and any attachments) to the appropriate district office. See pages 2 and 3 of the appendix for district office addresses and a map of district boundaries.

If assistance is needed completing this application, contact the Permits Section, telephone number: 517-373-8088.

22 EQP 4659-C (Rev 1/03)

Section III.A

DE-Michigan Department of Environmental Quality-Water Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater Section III is to be completed by all facilities classified as Industrial or Commercial facilities. Industrial and Commercial facilities include but are not limited to facilities that discharge or propose to discharge a wastewater generated by; a production process, a service provided or through a remediation project Municipal and public facilities are not required to complete Section III (unless requesting authorization for discharges other than sanitary wastewater)

A. Facility Information rDOL I IC r1P 1.fl RIN IJLr-mu I 1I I---

FACILITY NAME n-Hls r: Cookc Nuleah-r Plant NPDES PERMIT NUMBER I M10005827

-ulcl A.

oer uvw-

1.

BUSINESS INFORMATION A Provide up to four (4), Standard Industrial Classification (SIC) or North American Industry Classification System (NAICS) codes, in order of economic importance, which best describe the major products or services provided by this facility.-

I 1. 4911 l2 l 3 l 4 B. Indicate if this facility is a primary industry (refer to Table 1 of the appendix to determine if this facility is a primary industry) 0 Yes, this facility is a primary industry. Indicate the primary industry as identified in Table I of the appendix: Steam Electnc C] No, this facility is not a primary industry, continue with Item C C. Is this facility a concentrated animal feeding operation or an aquatic animal production facility?

o Yes, contact the Permits Section, telephone number: 517-373-8088 03 No, continue below.

2 WATER SUPPLY AND DISCHARGE TYPE A. Identify all water sources entering the facility and treatment system and provide average flows. The volume may be estimated from water supply meter readings, pump capacities, etc Provide the name of the source where appropriate (i e., Grand River, Lake Michigan, City of Millpond). To submit additional information see page ii, item 8 PNam sand I lt.fion nf Source Average Volume or Flow Rate Indicate Units Municipal Supply Surface Water Intake Private Well Other (specify)

Lake Township 0.368 MGD Lake Michigan 2029 MGD NA NA NA NA NA NA B. Identify water discharged by the facility and treatment system and provide average flows If water is first used for one purpose and then is subsequently used for another purpose, indicate the type and amount of the last use. For example, if water is initially used for noncontact cooling water and then for process water, indicate the amount of process water. The amount of water from sources should approximate the amount of water usage If they are different, provide an explanation.

Process Wastewater Contact Cooling Water Noncontact Cooling Water Groundwater Clean Up Average Flow Rate Indicate Units 0.809 MGD NA NA 2029 MGD NA NA Average Flow Rate Sanitary Wastewater Regulated Storm Water High Pressure Test Water Other:

0 022 MGD 5 169 (Calc)

MGD NA NA NA NA Indicate Units Note: For A and B above, indicate units either as MGD (million gallons per day), MGY (million gallons per year), GPD (gallons per day), or other appropriate unit 23E P 4 5 -C(eI/3 23 EQP 4659-C (Rev 1/03)

Michigan Department of Environmental Quality-Water Division

,WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information 3TRUCTIONS FOR COMPLETING SECTION III, ITEM B 1. eE This item requests detailed information on each outfall at the facility. Fill in the Outfall Number in the top right hand box identifying the outfall by number, e.g., 001, 002, etc. (applicants with existing NPDES permits should refer to the facility's current NPDES permit for outfall number identification). For each outfall provide the location, the type of wastewater, the expected and/or measured volume of effluent discharged, the frequency of discharge and the flow variation of the discharge.

A WATERSHED Identify the receiving stream's watershed Each receiving stream will eventually discharge into one of the Great Lakes or one of the connecting waters (i e. Detroit River, St Mary's River, St Clair River). Indicate from which river the discharge eventually discharges to the Great Lakes. For example: Sycamore Creek is tributary to the Red Cedar River, which is tributary to the Grand River, which discharges to Lake Michigan. Consequently a discharge to the Sycamore Creek is a discharge to the Grand River Watershed.

B. RECEIVING WATER.

Identify the exact location of the wastewater discharge point(s) and all areas through which the discharge flows (e g storm sewers, open drains, wetlands), if applicable, between the discharge point and the receiving water. Examples of receiving waters are rivers, creeks, lakes, etc.

C. COUNTY / TOWNSHIP: Provide the county and township where the outfall is located.

D. STATE PLANAR COORDINATES: Provide the location of the discharge to the receiving water in State Planar Coordinates Report State Planar Coordinates using quarter-quarter section, quarter section, section, town and range (e g., NE 1/4, SE 1/4, Section 34, T1N, R12E).

LATITUDE I LONGITUDE: Provide the latitude and longitude of the discharge accurate within 15 seconds (e.g., Latitude = 42027'15' Longitude = -83002'30") or accurate within 0 004 decimal degrees (e.g, Latitude = 42 454167, Longitude -83.041667).

F. WASTEWATER TYPES: Indicate the type(s) of wastewater the facility is requesting authorization to discharge. Check as many types of wastewater as are appropriate for this outfall. If a water is used in multiple areas, such as water that is first used for noncontact cooling, and then for another use, such as process water, indicate the final use only. For other common wastewater types see 'Table 9 - Other Types of Wastewater' in the appendix.

G. MAXIMUM DESIGN FLOW RATE: When reporting the Maximum Design Flow Rate, provide the design flow for this specific outfall, (e g., batch treatment system flow, package treatment system flow, or some other finite treatment system flow). Please provide an explanation if 'Pollution Prevention' measures are expected to provide flow reductions.

H. MAXIMUM AUTHORIZED DISCHARGE FLOW: Provide the maximum discharge flow rate that the facility is expecting to discharge in the next five years. NOTE: Discharges of flows greater than the Discharge Flow Rates authorized in the permit constitute a violation of Act 451 of 1994, as amended, Part 31, and are subject to the penalties specified therein.

I.

SEASONAL DISCHARGE: A discharge is considered to be seasonal if the facility treats and then stores wastewater throughout the year or a portion of the year and discharges it a few days, weeks or months a year. Provide the dates the facility discharges the treated wastewater (e g, October 15 through November 10) and the average discharge flows (e.g., 5 MGD).

J.

CONTINUOUS DISCHARGE:

Provide the average number of hours per day and the number of days per year that the discharges occur. Batch dischargers shall provide the peak batch flow rate, the number of batches per day, the per batch minimum, average and maximum volumes in gallons, and the per batch minimum, average and maximum batch discharges in minutes.

HA40TE: The units are as follows-GPD = gallons per day, MGD = millions of gallons per day, MGY = millions of gallons per year.

24 EQP 4659-C (Rev 1103)

Section III.B

Michigan Department of Environmental Quality-Surface Water Quality Division D

l WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information homplete a separate Section III.B. - Outfall Infornation (pages 26-31) for each outfall at the facility. Make copies of this blank section

.the application for additional outfalls as necessary.

PLEASE TYPE OR PRINT FACILITY NAME NPDES PERMIT NUMBER OUTFALL NUMBER Donald C. Cook Nuclear Plant M10005827 INTAKE

1.

OUTFALL INFORMATION (see page 25 for instruction on completion of this page)

A B

C.

D.

E F.

J.

G.

H I.

Watershed Lower St Joseph Receiving Water Lake Michigan County Township Berren Lake

/4, %4

%4 Section Town Range SW NW 06 1 06S 19W Latitude Longitude 41 58' 30' 86 34' 30' Type of Wastewater Discharged (Check all that apply to this outfall):

E] Contact Cooling a

Sanitary Wastewater L Groundwater Cleanup El Storm Water (regulated)

El Noncontact Cooling L Process Wastewater D Hydrostatic Pressure Test L Storm Water (not regulated)

El Storm water subject to effluent guidelines (indicate under which category)

Di Other - specify (see 'Table 8 -Other Common Types of Wastewater in appendix)

What is the maximum Facility Design Flow Rate.

2369 MGD What is the maximum discharge flow authorized for this outfall Seasonal Dischargers MGY Continue with Item H.

Continuous Dischargers INTAKE MGD Continue with Item I.

Seasonal Discharge List the discharge periods (by month) and the volume discharged in the space provided below From Through Discharge Volume Annual Total From Through Discharge Volume From Through Discharge Volume From Through Discharge Volume Continuous Discharge How often is there a discharge from this outfall (on the average)?

INTAKE Hours/Day Days/Year Batch dischargers must provide the following additional information:

Is there effluent flow equalization?

Li Yes Li No Batch Peak Flow Rate:

Number of batches discharged per day Minimum Average Maximum Batch Volume (gallons)

Batch Duration (minutes)

I

Michigan Department of Environmental Quality-Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information DLEASE TYPE OR PRINT ACILITY NAME NPDES PERMIT NUMBER OUTFALL NUMBER Donald C. Cook Nuclear Plant M10005827 INTAKE

2.

PROCESS STREAMS CONTRIBUTING TO OUTFALL DISCHARGE This information is used to determine the applicable federal regulations for this discharge. The information required to be reported is dependent on the type of facility. Page 7 of the appendix contains an abbreviated list of vanous industries and the types of information each shall report in this application. For assistance call the Permits Section All industries shall provide the name of each process and the SIC or the NAICS code for the process. If the wastestream is not regulated under federal categorical standards, the applicant shall report all pollutants which have the reasonable potential to be present in the discharge To submit additional information see page ii, item 8.

PROCESS INFORMATION A. Name of the process contributing to the discharge.

B SIC or NAICS code:

C. Describe the process and provide measures of production (see the instructions to determine the appropriate information to be reported)

PROCESS INFORMATION A

Name of the process contributing to the discharge B. SICorNAICScode C. Describe the process and provide measures of production (see the instructions to determine the appropriate information to be reported),

PROCESS INFORMATION A. Name of the process contributing to the discharge:

B. SIC or NAICS code C Descnbe the process and provide measures of production (see the instructions to determine the appropnate information to be reported)

PROCESS INFORMATION A. Name of the process contributing to the discharge B. SIC or NAICS code:

C. Describe the process and provide measures of production (see the instructions to determine the appropriate information to be reported)

PROCESS INFORMATION A. Name of the process contributing to the discharge B. SIC orNAICS code C. Describe the process and provide measures of production (see the instructions to determine the appropriate information to be reported)

Michigan Department of Environmental Quality-Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information ISTRUCTIONS FOR COMPLETING SECTION III, ITEM B.3.

7:9 In accordance with 40 CFR 122.21, all applicants must report CBOD5, Chemical Oxygen Demand, Total Organic Carbon, Total Suspended Solids, Ammonia as N, Temperature (both summer and winter), and pH. The applicant may, however, request that reporting of data for one or more of these required parameters be waived Such request must be supported by adequate rationale. The request shall be included as an attachment to this application.

Report available discharge data for the parameters listed. Actual data shall be provided for existing discharges and expected or estimated data provided for proposed discharges Please include an explanation if 'Pollution Prevention" is expected to provide reduction of pollutants. See Page 8 of the appendix for a list of specific parameters for which data must be provided for specific types of discharges (e.g, noncontact cooling waters, gasoline groundwater cleanups, etc.). For assistance in determining the appropriate parameters to report, call the Permits Section If data are available for other parameters not listed in Section lIl.B 3, the applicant shall report these data in the blank spaces provided or attach the information to this application on 81/2W x 11' paper.

Report all data in the units provided and for the sample types specified in the table. If more than one option is available, check the appropriate box. The units are as follows: pg/I = micrograms per liter, mg/l = milligrams per liter, OF = degrees Fahrenheit, OC = degrees Celsius See page ii number 5 for analytical requirements.

To analyze for pH, temperature, total residual chlonne, oil and grease, and fecal coliform use Grab Samples unless other frequency-sample type analyses are available. To analyze for total BOD5, total phosphorus, COD, TOC, ammonia nitrogen and total suspended solids use 24-hour composite samples unless other frequency-sample type analyses are available.

ror two or more substantially identical outfalls, permission may be requested from the appropriate district office to sample and analyze only one outfall and submit the results of the analysis for other substantially identical outfalls. If the request is granted by the district office, on a separate sheet attached to the application form, identify which outfall was sampled and descnbe why the outfalls which were not sampled are substantially identical to the outfall which was sampled.

See pages ii and iii for sampling definitions, including 'maximum daily concentration', and 'maximum monthly concentration".

REPORTING OF INTAKE DATA Applicants are required to report intake water data when they are attempting to demonstrate eligibility for 'net' effluent limitations for one or more pollutants A "net" effluent limitation is determined by subtracting the average level of the pollutant(s) present in the intake waters remaining after treatment which is not removed by the treatment system.

NPDES regulations allow net limitations only in certain circumstances (see 40 CFR Part 122.45(g)). To demonstrate eligibility, report the average concentration and/or mass of the results of the analyses on the intake water. If the intake water is treated prior to use, report the intake concentrations and/or mass after treatment. In addition to the analytical results, the following information shall be submitted for each parameter:

a) A statement that the intake water is drawn from the body of water into which the discharge is made. If the discharge is not to the same body of water from which the water is withdrawn, the facility is not eligible for net limitations.

b) A statement of the extent to which the level of the pollutant in the intake water is reduced by treatment of the wastewater. Limitations for the net removal of pollutants are adjusted only to the extent that the pollutant is not removed c)

When applicable (for example, when the pollutant represents a class of compounds, e.g., BOD5, TSS, etc.), a demonstration of the extent to which the pollutants in the intake vary physically, chemically and biologically from the pollutants contained in the discharge. Limitations are adjusted only to the extent that the concentrations of the intake pollutants vary from the discharged pollutants Note: Applicants for groundwater remediation discharges should also report the intake characteristics of contaminated groundwater.

Michigan Department of Environmental Quality-Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater I

B. Outfall Information INT PLEASE TYPE OR PR

/

ACILITY NAME Donald C. Cook Nuclear Plant NPDES PERMIT NUMBER I M10005827 I

OUTFALL NUMBERKE IINTAKE__/

3 WASTEWATER CHARACTERISTICS - CONVENTIONAL POLLUTANTS - Instructions for completing this page are on the facing page.

l Check this box if additional information is included as an attachment. To submit additional information see page ii, item 8 iMaxim~im-.z' Maimii1 Concentration Cdoncentration U'Anal yes Sam T

,A E.l. Grab Biochemical Oxygen Demand - five day (BODs) 3 3

mgI 1

2 24 Hr Comp mg Grab COD (Chemical oxygen demand) 6 6

gA 1

24 Hr Comp mg/I li Grab TOC (Total organic carbon) 2 2

g/

1 3 24 Hr Comp LE Grab Ammonia Nitrogen (as N)

<0 05

<0.05 g/

1 l

24 Hr Comp mg Grab Total Suspended Solids 40 15 mgA 12 24 Hr Comp Li Grab Total Dissolved Solids NA NA mgA NA L 24 Hr Comp mg Grab Total Phosphorus (as P)

NA NA mgA NA L 24 Hr Comp maximum-7day counts/100ml Fecal Coliform Bactena (report geometnc means)

NA NA NA Grab

• otal Residual Chlorine I Dissolved Oxycen

<0 08

<0.08 E

mgA O7 pgA 1

Grab minimum daily NA

-- i jo PIG; i Me mgA NA 171 Grab F-1 24 Hr Comol pH minimum maximum s

Grab (report maximum and minimum of individual samples) 7.93 7.93 standard units 1

24 Hr Comp E

-F

[]-C E Grab Temperature, Summer 80 8 74.0 1

F EI°C 188 24 HrComp E] -F E -C Grab Temperature, Winter 48 8 42.7 170 24 Hr Camp Oil & Grease NA NA mg/I NA Grab gi Grab

[

24HraComp Ei Grab E] 24 Hr Comp LI1 Grab El 24 Hr Comp El Grab El 24 Hr Comp L Grab EL 24 Hr Comp Li Grab El 24 Hr Camp Li Grab

_[

-I 2 4 H r C o m p Li Grab Eli 24 HrComn I

El Grab I1 24 Hr CompI

Michigan Department of Environmental Quality-Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information PLEASE TYPE OR PRINT CILITY NAME I

NPDES PERMIT NUMBER OUTFALL NUMBER Donald C Cook Nuclear Plant M10005827-l INTAKE

4.

PRIMARY INDUSTRY PRIORITY POLLUTANT INFORMATION Existing pnmary industnes that discharge process wastewater must submit the results of at least one effluent analysis for selected organic pollutants identified in Table 2 (as determined from Table 1, Testing Requirements for Organic Toxic Pollutants by Industrial Category), and all the pollutants identified in Table 3 Existing pnmary industries must also provide the results of at least one effluent analysis for any other chemical listed in Table 2 known or believed to be present in facility effluent In addition, submit the results of all other effluent analyses performed within the last 5 years for any chemical listed in Tables 2 and 3 New pnmary industries that propose to discharge process wastewater must provide an estimated effluent concentration for any chemical listed in Tables 2 and 3 expected to be present in facility effluent

5.

DIOXIN AND FURAN CONGENER INFORMATION Existing industries that use or manufacture 2,3,5-trichlorophenoxy acetic acid (2,4,5-T), 2- (2,3,5-trichlorophenoxy) propanoic acid, (Silvex, 2,3,5-TP), 2-(2,4,5-trichlorophenoxy) ethyl 2,2-dichloropropionate (Erbon), 0,0-dimethyl 0-(2,4,5-trichlorophenyl) phosphorothionate (Ronnel), 2,4,5-trichlorophenol (TCP) or hexachlorophrene (HCP), or knows or has reason to believe that 2,3,7.8-Tetrachlorodibenzo-p-dioxin (TCDD) is present in facility effluent, must submit the results of at least one effluent analysis for the dioxin and furan congeners listed in Table 6 All effluent analyses for dioxin and furan congeners must be conducted using EPA Method 1613.

In addition, submit the results of all other effluent analyses performed within the last 5 years for any dioxin and furan congener listed in Table 6 New industries that expect to use or manufacture 2,3,5-trichlorophenoxy acetic acid (2,4,5-T), 2- (2,3,5-trichlorophenoxy) propanoic acid (Silvex, 2,3,5-TP); 2-(2,4,5-trichlorophenoxy) ethyl 2,2-dichloropropionate (Erbon), 0,0-dimethyl 0-(2,4,5-tnchlorophenyl) phosphorothionate (Ronnel), 2,4,5-trichlorophenol (TCP) or hexachlorophrene (HCP), or knows or has reason to believe that 2,3,7,8-Tetrachlorodibenzo-p-dioxin (TCDD) is present in facility effluent must provide estimated effluent concentrations for the dioxin and furan congeners listed in Table 6.

6 OTHER INDUSTRY PRIORITY POLLUTANT INFORMATION Existing secondary industries, or existing pnmary industries that discharge non-process wastewater, must submit the results of at least one effluent analysis for any chemical listed in Tables 2 and 3 known or believed to be present in facility effluent In addition, submit the results of all other effluent analyses performed within the last 5 years for any chemical listed in Tables 2 and 3.

New secondary industries, or new pnmary industries that propose to discharge non-process wastewater, must provide an estimated effluent concentration for any chemical listed in Tables 2 and 3 expected to be present in facility effluent.

7.

ADDITIONAL TOXIC AND OTHER POLLUTANT INFORMATION All existing industries, regardless of discharge type, must provide the results of at least one analyses for any chemical listed in Table 4 known or believed to be present in facility effluent, and a measured or estimated effluent concentration for any chemical listed in Table 5 known or believed to be present in facility effluent In addition, submit the results of any effluent analysis performed within the last 5 years for any chemical listed in Tables 4 and 5.

New industries, regardless of discharge type, must provide an estimated effluent concentration for any chemical listed in Tables 4 and 5 expected to be in facility effluent 8

INJURIOUS CHEMICALS NOT PREVIOUSLY REPORTED New or existing industnes, regardless of discharge type, must provide a measured or estimated effluent concentration for any toxic or otherwise injurious chemicals known or believed to be present in facility effluent that have not been previously identified in this application Quantitative effluent data that are less than 5 years old for these chemicals must be reported.

NOTE: All effluent data submitted in response to questions 4, 5, 6, 7, and 8 above should be recorded on page 31. To submit additional information see page il, item 8. If the effluent concentrations are estimated, place an E in the 'Analytical Method' column. The following fields must be completed for each data row. Parameter, CAS No, Concentration(s), Sample Type, Analytical Method, Quantification Level and Detection Level See page it, number 5 for analytical test requirements

Section III.B.6 and 7 Additional Sample Data Summary Sheet Intake For Intake Sample Max Max of Parameter 03/12/02 03/14/02 03/18/02 03/19/02 03/20/02 03/21/02 03/25/02 03/26/02 03/27/02 04/01/02 04/02/02 04/03/02 05/30/02 type Daily Analytical monthly Analyses Table 2-t i

g 2

t fft;1t xp2l No Data Antimony (ug/l)

I

<1 II_

Grab

<1 200 7

<1 1

Arsenic (ug/l)

<1 Grab

<1 200 7

<1 1

Beryllium (ug/l)

<0 2 Grab

<02 200 7

<0 2 1

Cadmium (ug/l)

<0 2 Grab

<02 200 7

<0 2 1

Chromium (ug/l)

<2 Grab

<2 200 7

<2 1

Copper (ug/l) 1

<1 Grab 1

200 7 1

2 Lead (ug/l)

<1 Grab

<1 200 7

<1 1

Selenium (ug/l)

<1 Grab

<1 270 3

<1 1

Silver(ug/1)

<0.2 Grab

<02 200 7

<0 2 1

Nickel (ug/l)

<3 Grab

<3 200 7

<3 1

Thallium -(ug/l)

<1 Grab

<1 2792

<1 1

Zinc (ugi7) 5

<4 Grab 5

200 7 5

-2 Cyanide (mg/i)

I_<0 01 Grab

<0 01 335 2

<0 01 1

Mercury (ng/l) 2.11 1 04 (1 08 Grab 2.11 1631 2.11 3

Fluoride (mg/l) 02 0 1 0.1 0 1 01 01 0.1 0 1 01 01 0 1 l

Grab 01 340 2 0.1 11 Iron (mg/l) 0 35 0 21 0.31 0 24 018 0.97 0.72 082 0 23 02 0 78 Grab 097 200.7 048 11 Magnesium (mg/l) 11 8 11.7 12.2 12 1 12 14 14 2 14 3 12 1 123 129 Grab 14.3 200 7 128

^

11 Sulfate (mg/i) 22 22 23 23 22 23 28 26 27 23 24 23 l Composit 28 375 4 24 12 Ta b 5 Id 4 --

u Z 7 7 ;;

No Data Additional Data=

-K T

3 3 t 4

a Calcium (mg/I) 36 3 36 2 39 5 39 2 37.9 44 4 45 7 45 2 38 7 39 41.5 Grab 45 7 200 7 40 6 11 Chloride (mg/l) 15 13 12 13 12 15 15 15 17 20 16 I

Grab 20 325 3 17.7 11 Hardness (mg/l) 139 139 149 147 144 169 173 172 146 148 157 Grab 173 130 2 154 0 11 Silica (mg/i) 1 79 168 2 07 2 05 1 87

<02 1 92 214 2 07 1,71 1.73 1 67 l Grab 214 200 7 1 9 12 Analysis performed by Belomonte Park Labs

(

(

c

Information

-I 12-TEP-6020.ADM.010 I

Rev. 5B Page 7 of 8 ANALYTICAL RESULTS Data Sheet 2 NPDES Results Page: 7 Sample Identification:

f( o Sample Date:

3-Z6 Received Date/Time:

Analysis Date I

I

7 Sampler's Initials

_

Sample Time:

6' Receiver's Initials:

Ae I

o CALCULATIONS/RESULTS s

(Wr)

-(Wi xl100/ V) ppm CDMS Trend (S)(l)(D)

Tim:

L(Wr)

-(W) x1000/(V)Results in Spec nalyss Tirne:Equip ID.:

Analyst's Initals.

u&G R-(Wr)

-(WO) jB(Wr)

-(WO CDMS Trend (S)(m)D)

Results in Spec (R)

• (B)

I(t)

R pm STD#

R*(Wr)

-(WI)

• B (Wr)

-(Wi) p

.R)

-(V) ppm Analysis Time:

Equip ID.:

Analysaf Initials:

s (A)

(a) x lGool(C) ppm (A)

• -i) x10001(C)

.ppm CDMS Trend

.(S)(l)tD)

Results in Spec

.A)

(B) xlOOOI(C) ppm alysis Time:

Equip ID.:

Analyst's initials:

S04 (Dilution Factor) x (Sample Reading)

(ppm)

CDMS Trend

.(S)(I)(D)

[

_Results in Spec STD#

(Dilution Factor) x (Stsndard Reading) mg/L(ppm)

Analysis Time:

Equip ID*:

Analyst's Initials:

PH ISample Temperature:

2 4-. "c Result-

-7 5?

CDMS Trend w

[Theoretical Value:7, Co Standard Temperature:

3 Result-i-

(S)(l)(D)

Analysis Time:

Analyst's Initials:

Results n Spec 1

1 r

otal P Result-ppm STD#:

Result-ppm CDMS Trend (S)(l)(D)

Analysis Time:

Equip ID.:

Analyst's Initials:

Results in Spec Analysis Analysis Time z

Equipment ID Results Analysts CDMS Trend

- J J

Initials I1 -I A

0-7 7 3,j elG Afx7te 8fu I) o7 0p 2)-0Z1,&- Y Comments/Corrective Actions/Notifications:

to -

x C. 0 81 L.

n C)>

h KUs I

DEW-Michigan Department of Enm mental Quality-Water Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information PLEASE TYPE OR PRINT FACILITY NAME NPDES PERMIT NUMBER OUTFALL NUMBER Donald C Cook Nuclear Plant

__M10005827 INTAKE SAMPLE DATE4 3/12/02 3/14/02 3/18/02 3/19/02 3/20/02 3/25/02 3/26/02 3/27/02 4/1/02 4/2/02 CAS Conc.

ZConc;.>, 1Conc.'--'IConc.

Conc.

Conc;

'- Conc.

o nc.

bnc.c.'.

w Conc.,',Sample

,Analytic, :

PARAMETER '"

7No:

(uggl) l).

(ug/),

(ug/lj (Ug/l)

-'~(ug/l)' -

' (ug/I)l f< 5(u/u)g (ug/)V

'Type Fal r

fL<

DL Fluonde 200 100 100 100 100 100 100 100 100 100 Grab 340 2 100 8

Iron 350 210 310 240 180 970 720 820 230 200 Grab 200.7 10 10 Sulfate 22000 22000 23000 23000 22000 28000 26000 27000 23000 24000 Grab 375.4 1000 470 See Attached for additional data.

(

EQP (

-C (Rev 1/03)

Michigan Department of Environmental Quality-Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information PLEASE TYPE OR PRINT FACILITY NAME NPDES PERMIT NUMBER OUTFALL NUMBER Donald C. Cook Nuclear Plant M10005827 INTAKE

9.

WATER TREATMENT ADDITIVES Water treatment additives include any matenal that is added to water used at the facility or to a wastewater generated by the facility to condition or treat the water.

Approvals of water treatment additives are authorized by the DEQ under separate correspondence The issuance of an NPDES permit does not constitute approval of the water treatment additives that are included in this application A. Are there water treatment additives in the discharge from this facility?

3 No, proceed to item 4 LI Yes B Have these water treatment additives been previously approved?

EI No, continue with C below.

E] Yes Submit a list of the previously approved water treatment additives and the date they were approved. The information listed in C 1-8 must be updated if it has changed since the previous approval C. Submit a list of water treatment additives that are or may be discharged from the facility Applicants must submit the information listed below for each additive

1.

The water treatment additive Matenal Safety Data Sheet

2.

The proposed water treatment additive discharge concentration.

3 The discharge frequency (i e., number of hours per day, week, etc)

4.

The outfall the water treatment additive is to be discharged from 5

The type of removal treatment, if any, that the water treatment additive receives pnor to discharge 6

The water treatment additive function (i.e., microbiocide, flocculant, etc )

7.

A 48-hour LC50 or EC50 for a North Amencan freshwater planktonic crustacean (either Cenodaphnia sp, Daphnia sp, or Simocephalus sp.)

8 The results of a toxicity test for one other North Amiencan freshwater aquatic species (other than a planktonic crustacean) that meets a minimum requirement of Rule 323.1057(2)(a) of the Water Quality Standards Examples of tests that would meet this requirement include a 96-hour LC50 for a rainbow trout, bluegill, or fathead minnow The required toxicity information (described in items 7 and 8 above) is currently available in the SWQD files for the water treatment additives listed on the DEQ's Internet page http:ilwww.deq.state.mi.us/swqlgleasidocslwtaNVTAlist.doc If you intend to use one of the water treatment additives on this list, only the information in items 1 through 6 above needs to be submitted to the SWQD.

Note: The availability of toxicity information for a water treatment additive does not constitute approval to discharge the water treatment additive

10. WHOLE EFFLUENTTOXICITYTESTS Have any acute or chronic WET tests been conducted on any discharges or receiving water in relation to facility discharges within the last three years?

If yes, identify the tests and summanze the results below unless the test has been submitted to the department in the last 5 years L

Section III.B Outfall 001

Michigan Department of Environmental Quality-Surface Water Quality Division DE-.

WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information

\\

nplete a separate Section III.B. - Outfall Information (pages 26-3 1) for each outfall at the facility Make copies of this blank section o1 the application for additional outfalls as necessary.

PLEASE TYPE OR PRINT FACILITY NAME NPDES PERMIT NUMBER OUTFALL NUMBER Donald C. Cook Nuclear Plant M10005827 001

1.

OUTFALL INFORMATION (see page 25 for instruction on completion of this page)

A Watershed Lower St Joseph Receiving Water I ira KA-hin. -

County Township Berrien Lake

%4, Y

1/4 Section Town Range SW NW 06 l 06S 19W Latitude Longitude 41 58'30" 86 34' 30" Type of Wastewater Discharged (Check all that apply to this outfall)

EJ Contact Cooling D

Sanitary Wastewater a

Groundwater Cleanup 3

Storm Water (regulated) l Noncontact Cooling

[D Process Wastewater

[

Hydrostatic Pressure Test U Storm Water (not regulated)

[

Storm water subject to effluent guidelines (indicate under which category) 423-Steam Electric D] Other - specify (see 'Table 8 - Other Common Types of Wastewater' in appendix)

What is the maximum Facility Design Flow Rate 2369 MGD What is the maximum discharge flow authonzed for this outfall:

Seasonal Dischargers MGY Continue with Item H.

Continuous Dischargers 1500 MGD Continue with Item I.

Seasonal Discharge List the discharge penods (by month) and the volume discharged in the space provided below.

From Through Discharge Volume Annual Total From Through Discharge Volume From Through Discharge Volume From Through Discharge Volume Continuous Discharge How often is there a discharge from this outfall (on the average)7 24 Hours/Day 365 Days/Year Batch dischargers must provide the following additional information:

Is there effluent flow equalization?

El Yes

[ No Batch Peak Flow Rate, Number of batches discharged per day.

Minimum Average Maximum Batch Volume (gallons)

Batch Duration (minutes)

I Michigan Department of Environmental Quality-Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information 7ASE TYPE OR PRINT

.ILITY NAME l NPDES PERMIT NUMBER OUTFALL NUMBER Donald C. Cook Nuclear Plant M10005827 001

2.

PROCESS STREAMS CONTRIBUTING TO OUTFALL DISCHARGE This information is used to determine the applicable federal regulations for this discharge. The information required to be reported is dependent on the type of facility. Page 7 of the appendix contains an abbreviated list of various industries and the types of information each shall report in this application. For assistance call the Permits Section All industries shall provide the name of each process and the SIC or the NAICS code for the process. If the wastestream is not regulated under federal categorical standards, the applicant shall report all pollutants which have the reasonable potential to be present in the discharge. To submit additional information see page ii, item 8 PROCESS INFORMATION A

Name of the process contributing to the discharge: OOA B SIC orNAICS code. 4911 C. Describe the process and provide measures of production (see the instructions to determine the appropriate information to be reported): Steam Generator Blowdown. 1 MGD maximum flow 2247 MWE total plant electncal generation PROCESS INFORMATION A. Name of the process contributing to the discharge 001B B. SIC or NAICS code: 4911 C. Descnibe the process and provide measures of production (see the instructions to determine the appropnate information to be reported) Steam Generator Blowdown 1 MGD maximum flow 2247 MWE total plant electrical generation PROCESS INFORMATION A Name of the process contnbuting to the discharge: OOC B SIC or NAICS code-4911 C. Descnbe the process and provide measures of production (see the instructions to determine the appropnate information to be reported): Plant heating boiler blowdown. 0 043 MGD maximum flow 2247 MWE total plant electrical generation.

PROCESS INFORMATION A. Name of the process contributing to the discharge OOG B. SIC or NAICS code: 4911 C. Describe the process and provide measures of production (see the instructions to determine the appropriate information to be reported)- Reverse osmosis reject stream 0.366 MGD maximum flow. 2247 MWE total plant electrical generation PROCESS INFORMATION A. Name of the process contributing to the discharge-OOH B. SIC or NAICS code 4911 C. Describe the process and provide measures of production (see the instructions to determine the appropriate informabon to be reported):

Miscellaneous equipment drains and processes Maximum flow is 5 2 MGD 2247 MWE total plant electrical generation. This Outfall is used for emergency purposes only

- Michigan Department of Environmental Quality-Surface Water Quality Division

`WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information EASE TYPE OR PRINT Z

• CILITY NAME NPDES PERMIT NUMBER OUTFALL NUMBER -

Donald C Cook Nuclear Plant M10005827 l 001 2

PROCESS STREAMS CONTRIBUTING TO OUTFALL DISCHARGE This information is used to determine the applicable federal regulations for this discharge The information required to be reported is dependent on the type of facility Page 7 of the appendix contains an abbreviated list of vanous industries and the types of Information each shall report in this application For assistance call the Permits Section All industries shall provide the name of each process and the SIC or the NAICS code for the process. If the wastestream is not regulated under federal categorical standards, the applicant shall report all pollutants which have the reasonable potential to be present in the discharge To submit additional information see page ii, item 8.

PROCESS INFORMATION A

Name of the process contributing to the discharge, Unit One Cooling Water B SIC orNAICS code: 4911 C. Describe the process and provide measures of production (see the instructions to determine the appropnate information to be reported) Once-through non-contact cooling, maximum flow is 1500 MGD, 2247 MWE total plant electrical.

PROCESS INFORMATION A. Name of the process contnbuting to the discharge Unit Two Cooling Water B. SIC or NAICS code: 4911 C Descnbe the process and provide measures of production (see the instrucbons to determine the appropnate information to be reported) Once-through non-contact cooling, maximum flow is 1820 MGD, 2247 MWE total plant electrical.

PROCESS INFORMATION A Name of the process contnbuting to the discharge: Misc Minor Stormwater drains B SIC or NAICS code 4911 C Describe the process and provide measures of production (see the instructions to determine the appropriate information to be reported) Roof drains from the screenhouse roof, small roadway gratings above the forebay road.

PROCESS INFORMATION A Name of the process contnbuting to the discharge:

B SIC or NAICS code C. Descnbe the process and provide measures of production (see the instructions to determine the appropriate information to be reported):

PROCESS INFORMATION A Name of the process contnbuting to the discharge:

B. SIC or NAICS code C. Descnbe the process and provide measures of production (see the instructions to determine the appropriate information to be reported)

Michigan Department of Environmental Quality-Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information i 4STRUCTIONS FOR COMPLETING SECTION III, ITEM B.3.

In accordance with 40 CFR 122.21, all applicants must report CBOD5, Chemical Oxygen Demand, Total Organic Carbon, Total Suspended Solids, Ammonia as N, Temperature (both summer and winter), and pH. The applicant may, however, request that reporting of data for one or more of these required parameters be waived. Such request must be supported by adequate rationale. The request shall be included as an attachment to this application.

Report available discharge data for the parameters listed. Actual data shall be provided for existing discharges and expected or estimated data provided for proposed discharges.

Please include an explanation if 'Pollution Prevention" is expected to provide reduction of pollutants. See Page 8 of the appendix for a list of specific parameters for which data must be provided for specific types of discharges (e g., noncontact cooling waters, gasoline groundwater cleanups, etc.). For assistance in determining the appropriate parameters to report, call the Permits Section.

If data are available for other parameters not listed in Section III.B.3, the applicant shall report these data in the blank spaces provided or attach the information to this application on 8Y/2 x 11" paper.

Report all data in the units provided and for the sample types specified in the table. If more than one option is available, check the appropriate box. The units are as follows: Vg/I = micrograms per liter, mg/A = milligrams per liter, IF = degrees Fahrenheit, "C = degrees Celsius. See page ii number 5 for analytical requirements.

To analyze for pH, temperature, total residual chlorine, oil and grease, and fecal coliform use Grab Samples unless other frequency-sample type analyses are available To analyze for total BODs, total phosphorus, COD, TOC, ammonia nitrogen and total suspended solids use 24-

' -ur composite samples unless other frequency-sample type analyses are available.

For two or more substantially identical outfalls, permission may be requested from the appropnate district office to sample and analyze only-/

one outfall and submit the results of the analysis for other substantially identical outfalls. If the request is granted by the district office, on a separate sheet attached to the application form, identify which outfall was sampled and describe why the outfalls which were not sampled are substantially identical to the outfall which was sampled.

See pages ii and iii for sampling definitions, including 'maximum daily concentration", and 'maximum monthly concentration".

REPORTING OF INTAKE DATA Applicants are required to report intake water data when they are attempting to demonstrate eligibility for 'net" effluent limitations for one or more pollutants. A 'net' effluent limitation is determined by subtracting the average level of the pollutant(s) present in the intake waters remaining after treatment which is not removed by the treatment system.

NPDES regulations allow net limitations only in certain circumstances (see 40 CFR Part 122.45(g)). To demonstrate eligibility, report the average concentration and/or mass of the results of the analyses on the intake water. If the intake water is treated prior to use, report the intake concentrations and/or mass after treatment In addition to the analytical results, the following information shall be submitted for each parameter:

a) A statement that the intake water is drawn from the body of water into which the discharge is made. If the discharge is not to the same body of water from which the water is withdrawn, the facility is not eligible for net limitations.

b) A statement of the extent to which the level of the pollutant in the intake water is reduced by treatment of the wastewater. Limitations for the net removal of pollutants are adjusted only to the extent that the pollutant is not removed.

c)

When applicable (for example, when the pollutant represents a class of compounds, e.g, BOD5, TSS, etc.), a demonstration of the extent to which the pollutants in the intake vary physically, chemically and biologically from the pollutants contained in the discharge. Limitations are adjusted only to the extent that the concentrations of the intake pollutants vary from the discharged pollutants.

Note: Applicants for groundwater remediation discharges should also report the intake characteristics of contaminated groundwater.

NPDES Pernit M10005827 STATE OF MICHIGAN JOHN ENGLER, Governor REPLYT-DEPARTMENT OF ENVIRONMENTAL QUALITY PLAhNWELLDISTRICTOFFICE

'Better Ser-vce for a Better Environment PLAINWELL MI 49080-1915 HOLLISTER BUILDING PO BOX 30473. LANSING MI 48909-7973 INTERNET www deq state ml us RUSSELL J. HARDING, Director January28, 1999 Mr. John P. Carlson Environmental Compliance Manager Cook Nuclear Plant One Cook Place Bridgman, Michigan 49106

SUBJECT:

Application for Renewal of NPI)ES PermitNo. M10005827 -

We have reviewed the information provided in your letter of January 25, 1999. In that letter you request that representative outfalls be used to characterize effluent characteristics for similar outfalls. We approve your request as follows:

1. Effluent from Outfall 001 will be considered representative of outfalls 001, 002, and 003.

2. Effluent from Outfall 0OB will be considered representative of outfalls OOA and OOB.

Please feel free to contact me if you have any questions.

Sincerely, Gregory

. anneffl Plainwell District Office Surface Water Quality Division 616-692-6968 cc: Mr. Blair Zordell, Cook Nuclear Plant Mr. Dan Dell, Permits Section, SWQD Ms. Sylvia Heaton, GLEAS, SWQD EOP 01O0e (Rev 1/98)

I American Electric Power Cook Nuclear Plant OneCookPlace Bridgman, MI 49106 616 465 5901 vAMERICAN ELECTRIC POWER Mr.

Fred Morley Surface Water Quality Division Michigan Department of Environmental Quality 1342 SR89 West Suite B Plainwell, MI 49080 January 25, 1999

Subject:

NPDES Permit No. MI0005827 Application We are currently preparing the Wastewater Discharge Permit Application to renew our current NPDES operating permit. As noted in Section III -

Industrial and Commercial Wastewater, Part B. Outfall Information Item 6, paragraph 5 contains instructions to request permission to use a single sample for similar outfalls for application purposes.

We request that Outfall 001 be used as a representative sample for Outfalls 002 (Unit Two Noncontact Cooling Water) and Outfall 003 (De-icing Mbde) for application use only.

Outfalls 002 and 003 are substantially identical to Outfall 001. The source of these Outfalls is Lake Michigan; similar waste streams enter each Outfall prior to discharge.

In addition, we are requesting Outfall OOB (Unit Two Steam Generator Blowdown) to be used as a representative sample for Outfall OA (Unit One Steam Generator Blowdown).

Outfall OOA and Outfall GOB are substantially identical discharges, with the exception that Outfall OA originates from the Unit One Steam Generators, and Outfall OOB originates from the Unit Two Steam Generators.

If you have any questions, please contact me at (616) 465-5901, ext. 1153.

Sincerely, John P. Carlson Environmental Compliance Manager

/tlm c:

Greg Danneffel -

MDEQ Plainwell Sylvia Heaton -

MDEQ Lansing

Page Two Mr. Morley January 25, 1999 I certify under penalty of law that I have personally examined and am familiar with the information submitted on this and all attached documents, and based on my inquiry of those individuals immediately responsible for obtaining the information, I believe the submitted information is true, accurate and complete.

I am aware that there are significant penalties-for submitting false information, including the possibility of fine and imprisonment.

D. E. Cooper Plant Manager N

Michigan Department of Environmental Quality-Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information iNT

'SE TYPE OR PR

,..ILITY NAME Do nald C Cook Nuclear Plant l NPDES PERMIT NUMBER I M10005827 OUTFALL NUMBER I 001

3.

WASTEWATER CHARACTERISTICS - CONVENTIONAL POLLUTANTS - Instructions for completing this page are on the facing page.

s Check this box if additional information is included as an attachment To submit additional information see page ii, item 8.

M Maimum E

n MaximiKn Di'<<

MonthlY.

'Numbi611er o f Param~eter~'

C6ncenteationK, Con~rcent'ration Unitsm

'EAnalyses> <Sa mple Type mg/I E] Grab Biochemical Oxygen Demand - five day (BODs) 3 3

mg/I 2

1 24 Hr Comp aI Grab COD (Chemical oxygen demand) 6 6

mgI 2

l 24 Hr Comp m/ Grab TOC (Total organic carbon) 4 5 4 5 mgI 2

1 24 Hr Comp Ammonia Nitrogen (as N)

<0 5

<0 5 2

24 Hr Comp Total Suspended Solids 29 29 2

24HrComp mg/l E] Grab Total Dissolved Solids NA NA m'

NA El 24 Hr Comp mgA n

Grab Total Phosphorus (as P) 0 37 0 37 1

E 24 Hr Comp maximum-7day counts/i O0mi Fecal Coliform Bacteria (report geometric means)

NA NA NA Grab El mg/I il Residual Chlorine 386 180 1

Ig/l 252 Grab minimum daily I'm El Grab Dissolved Oxygen NA NA aI 24 Hr Comp pH minimum maximum snr Grab (report maximum and minimum of individual samples) 7 8 8.5 standard units 98 L 24 Hr Comp l OF [nm -C Grab Temperature, Summer 105 2 96 4 188 El 24 Hr Comp

!0'IF El C Grab Temperature, Winter 79 8 73 5 170 24 Hr Compa Oil & Grease

<5

<5 mg/I 2

Grab a

Grab See Attached for additional Data L 24 Hr Comp L Grab

_L 24 Hr Comp LI Grab

__L 24 Hr Comp LI Grab

_ _ _ 24 Hr Comp El Grab EL 24 Hr Comp LI Grab

__L 24 Hr Comp El Grab EL 24 Hr Comp E] Grab l_

a 24 Hr Comr

-I j

L al Grab M 24 Hr Comol I -

Michigan Department of Environmental Quality-Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information EASE TYPE OR PRINT

..CILITY NAME NPDES PERMIT NUMBER OUTFALL NUMBER Donald C Cook Nuclear Plant M10005827 001 4

PRIMARY INDUSTRY PRIORITY POLLUTANT INFORMATION Existing primary industries that discharge process wastewater must submit the results of at least one effluent analysis for selected organic pollutants

.identified in Table 2 (as determined from Table 1, Testing Requirements for Organic Toxic Pollutants by Industrial Category), and all the pollutants identified in Table 3 Existing primary industries must also provide the results of at least one effluent analysis for any other chemical listed in Table 2 known or believed to be present in facility effluent In addition, submit the results of all other effluent analyses performed within the last 5 years for any chemical listed in Tables 2 and 3 New primary industries that propose to discharge process wastewater must provide an estimated effluent concentration for any chemical listed in Tables 2 and 3 expected to be present in facility effluent 5

DIOXIN AND FURAN CONGENER INFORMATION Existing industries that use or manufacture 2,3,5-trichlorophenoxy acetic acid (2,4,5-T), 2- (2,3,5-trichlorophenoxy) propanoic acid, (Silvex, 2,3,5-TP); 2-(2,4,5-trichlorophenoxy) ethyl 2,2-dichloropropionate (Erbon), 0,0-dimethyl 0-(2,4,5-trichlorophenyl) phosphorothionate (Ronnel), 2,4,5-trichlorophenol (TCP) or hexachlorophrene (HCP), or knows or has reason to believe that 2,3,7,8-Tetrachlorodibenzo-p-dioxin (TCDD) is present in facility effluent, must submit the results of at least one effluent analysis for the dioxin and furan congeners listed in Table 6. All effluent analyses for dioxin and furan congeners must be conducted using EPA Method 1613 In addition, submit the results of all other effluent analyses performed within the last 5 years for any dioxin and furan congener listed in Table 6.

New industries that expect to use or manufacture 2,3,5-trichlorophenoxy acetic acid (2,4,5-T), 2- (2,3,5-tnchlorophenoxy) propanoic acid (Silvex, 2,3,5-TP), 2-(2,4,5-trichlorophenoxy) ethyl 2,2-dichloropropionate (Erbon), 0,0-dimethyl 0-(2,4,5-tnchlorophenyl) phosphorothionate (Ronnel), 2,4,5-tnchlorophenol (TCP) or hexachlorophrene (HCP), or knows or has reason to believe that 2,3,7,8-Tetrachlorodibenzo-p-dioxin (TCDD) is present in facility effluent must provide estimated effluent concentrations for the dioxin and furan congeners listed in Table 6.

'OTHER INDUSTRY PRIORITY POLLUTANT INFORMATION Existing secondary industries, or existing primary industries that discharge non-process wastewater, must submit the results of at least one effluent analysis for any chemical listed in Tables 2 and 3 known or believed to be present in facility effluent In addition, submit the results of all other effluent analyses performed within the last 5 years for any chemical listed in Tables 2 and 3 New secondary industnes, or new primary industries that propose to discharge non-process wastewater, must provide an estimated effluent concentration for any chemical listed in Tables 2 and 3 expected to be present in facility effluent.

7.

ADDITIONAL TOXIC AND OTHER POLLUTANT INFORMATION All existing industries, regardless of discharge type, must provide the results of at least one analyses for any chemical listed in Table 4 known or believed to be present in facility effluent, and a measured or estimated effluent concentration for any chemical listed in Table 5 known or believed to be present in facility effluent In addition, submit the results of any effluent analysis performed within the last 5 years for any chemical listed in Tables 4 and 5 New industnes, regardless of discharge type, must provide an estimated effluent concentration for any chemical listed in Tables 4 and 5 expected to be in facility effluent

8.

INJURIOUS CHEMICALS NOT PREVIOUSLY REPORTED New or existing industries, regardless of discharge type, must provide a measured or estimated effluent concentration for any toxic or otherwise injurious chemicals known or believed to be present in facility effluent that have not been previously identified in this application Quantitative effluent data that are less than 5 years old for these chemicals must be reported.

NOTE: All effluent data submitted in response to questions 4, 5, 6, 7, and 8 above should be recorded on page 31. To submit additional information see page ii, item 8.. If the effluent concentrations are estimated, place an E in the "Analytical Method' column. The following fields must be completed for each data row Parameter, CAS No, Concentration(s), Sample Type, Analytical Method, Quantification Level and Detection Level.

See page ii, number 5 for analytical test requirements

DE-I PLEASE TYPE OR PRINT Michigan Department of En, imental Quality-Water Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information FACILITY NAME l NPDES PERMIT NUMBER l OUTFALL NUMBER Donald C Cook Nuclear Plant M1 M0005827 l 001 SAMPLE DATE 4 1/8/01 7/17/01 8/7/01 8/14/01 9/4/01 9/18/01 10/9/01 10/23/01 11/6/01 1/22/02 l

2>2,^,,.'

CAS Cone.

C Ce.'eonc.oCCo..or.Ce oe Cn.SalConc.

CaAnaConc.ti, Sample,.

Analytic XPARAMETER-No :

(ug I1

( gI' (ul)l' I

Z ug '- (ug/l)

(ug/l) U

-- (ug/l)'

(ug/l)-

1Type '

al

^

DL Hyrazine 7803578

<10

<3

<3

<3

<3

<3

<3

<3

<3 5 8 Grab D1385 3

10 Date 2/4/02 2/8/02 1/4/00 1/5/00 1/8/00 1/26/00 2/12/00 2/17/00 2/19/00 2/21/00 Boron 7440428 114 28 9 638 297 224 383 857 627 466 603 Grab 200.7 13.1 39 3 See Attached for additional data.

(

(

6 EQPQ 1-C (Rev 1/03)

(

Section III.B.6 and 7 Additional Sample Data Summary Sheet 001 For Outfall 001 Parameter l

211199 3/21102 5130/02 Sample type Max Daily Analytical Max Analyses T a b l e^2.'rxi

,#S ; § 4 ;a of P.

.s.-

X 1 > '

o2 s 4

i ~i t

___________ mi'2 See Attached data set from Belmonte Park Laboratories.

Antimony (ugA)

<1

<1 Grab

<1 204.2/200.7

<1 2

Arsenic (ug/)

<1 1

<1 Grab 1

206 2/200.7 1

3 Beryllium (ug/)

<1

<0 2 Grab

<1 200.7

<1 2

Cadmium (ugh)

<0 2

<0 2 Grab

<0.2 213.2/200.7

<0.2 2

Chromium (ug1)

<10

<2 Grab

<10 200 7

<10 2

Copper (ugA)

<1 3

2 Grab 3

220 2/200.7 3

3 Lead (ug/1)

<1 1

<2 Grab 1

239 2/200 7 1

3 Nickel (ug/)

<5

<3 Grab

<5 249 2/200.7

<5 2

Total Phenols (ug/1)

<10 Grab

<10 420.1

<10 1

Selenium (ug/1)

<1.0 Grab

<1.0 270.3

<1 0 1 -

Silver(ugAl)

<0 5

<0.2 Grab

<0.5 272.2/200.7.

<0 5 2

Thallium -(ug/l)

<1

- <1 Grab

<1 279.2

<1 2

Zinc (ug/1)

<4-Grab

<4 200.7

<4 1

Cyanide (mg/i)

<0 01

<0 01 Grab

<0 01 335 2

<0 01 2

Mercury (ng/l) 2.69 0.954 Grab 2 69 1631 2.69 2

Sulfate (mg/l)

<10 23 Composite 23 375 4 23 2

Additional Data From Belmonte Park Laboratories is attached See Attached Data set from Cook Nuclear Plant Laboratory See Attached data set from Belmonte Park Laboratories.

See Attached Data set from Cook Nuclear Plant Laboratory

Section III.13.6 Non-routine sample data From Table 4 001 TRC USEPA Method 330.5 Outfall 001 Jan-1 Feb-01 Mar-01 Apr-01 May-01 Jun-01 Jul-01 Aug-01 Sep-01 Oct-01 Nov-01 Dec-01 Jan-02 Feb-02 Mar-02 Apr-02 May-02 Jun-02 Jul-02 Auj-02 Sep-02 Oct-02 Nov-02 1

37 1

1 1

135 149 48 9

1

<1 149 1

<1 l

110 150 4 76 1

125 3

<1 140 80 187 176 5 78 101 3

<1 78 67 162 i 141 70 41 1

<1 103 171 55 148

' 84 83 51 1

<1 143 152 B 113 81 96 1

<1

=

156 143 3 115 1

<1 50 137 75 8

<1 131 90 18 135 139 91 172 6

<1 147 87 108 145 148 79 84 119 4

1 109 89 131 174 88 69 61 27 4

1 123 47 101 146 3 79 39 1

5 147

<1 143 180.3 5

37 4

33 2

49 1

159 194.3 1

20 26 5

67 1

21 2

114 79 135 174 386 87 20 4

1

=

55

=

<1 129 123 198

=

26 6

80 2

1 2

125 166 101 39 1

7 2

<1 56 120 99 68 1

71 5

2 1

75 129 107 75 32 5

158 2

1 113 139 149 91 6

67 11 1

85 139 166 3

99 1

77 13 71 1

1 106 141 178 1

90 1

117 7

143 3

159 116 2

91 37 1

110 9

148 5

92 122 2

22 119 3

2 64 181 2

30 13 107 6

2 76 153 3

86 97 6

2 51 151 186 173 2

80 170 4

2 96 181 1

74 1

2 1

104 151 178 71 1

16 2

2 176 DAILY MAX 141 0

Monthly avg 85 0

0 3

0 2

139 101 125 170 13 172 158 91 49 19 72 6

96 56 8

3 1

147 0

1 98 0

0 2

140 159 171 186 198 386 0

2 93 111 93 116 157 180 Number of analyses 239 Number of <det values 13 Daily Max 386 ug/L Total 252 Monthly Max 180 ug/L

(

I a

Belmonte Park

-aba Environrantolre

~

Laboratories AMERICAN ELECTRIC POWER (AEP) 1 COOK PLACE BRIDGMAN, MICHIGAN 49106 Attn: BLAIR ZORDELL Purchase Order: 4307976 Invoice Number:

Order #:

99-02-060 Date: 03/16/99 09:22 Work ID: OUTFALL 001 -

OOC Date Received:

02/02/99 Date Completed: 03/16/99 Client Code: AEP 4 ND= NONE DETECTED OHIO CERT.# 12345 SAMPLE IDENTIFICATION Sample Number 01 02 03

• j 04 05 06 07 08 09 10 11 12 13 14 15 16 17 18 19 20 21 22 23 Sample Description OUTFALL OUTFALL OUTFALL OUTFALL OUTFALL OUTFALL OUTFALL OUTFALL OUTFALL OUTFALL OUTFALL OUTFALL OUTFALL OUTFALL OUTFALL OUTFALL OUTFALL OUTFALL OUTFALL OUTFALL OUTFALL OUTFALL OUTFALL 001 001 001 001 001 001 001 001 001 001 001 001 001 001 001 OOG OOG OOG 00G 00G OOG OOG 00G 02/01/99 02/01/99 02/01/99 02/01/99 02/01/99 02/01/99 02/01/99 02/01/99 02/01/99 02/01/99 02/01/99 02/01/99 02/01/99 02/01/99 02/01/99 02/01/99 02/01/99 02/01/99 02/01/99 02/01/99 02/01/99 02/01/99 02/01/99 Sample Number 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 Sample Description OUTFALL 0OG OUTFALL 00G OUTFALL OOG OUTFALL OOG OUTFALL OOG OUTFALL 0OG OUTFALL 0OG OUTFALL OOC OUTFALL OOC OUTFALL OOC OUTFALL OOC OUTFALL OOC OUTFALL OOC OUTFALL OOC OUTFALL OOC OUTFALL OOC OUTFALL OOC OUTFALL OOC OUTFALL 00C OUTFALL OOC OUTFALL OOC OUTFALL OOC 02/01/99 02/01/99 02/01/99 02/01/99 02/01/99 02/01/99 02/01/99 02/01/99 02/01/99 02/01/99 02/01/99 02/01/99 02/01/99 02/01/99 02/01/99 02/01/99 02/01/99 02/01/99 02/01/99 02/01/99 02/01/99 02/01/99 46 Committed to Quality Since 1958 Dayton, Ohio 45426 II East Main Street (937) 837-3744

1 a Belmonte Park Env-ironmental Laboratores Order # 99-02-060 03/16/99 09:22 Page 2 Enclosed are results of specified samples submitted for analyses. If there are any questions, please contact Matt Lake.

Our Ohio EPA Certification numbers are 836 & 837.

Any result of "BDL" indicates "BELOW DETECTION LIMIT".

922 Certified By MATT LAKE r

Committed to Quality Since 1958 Dayton, Ohio 45426 I11 Frnqt Mnin XStr - -t (937) 837-3744

X X

Belmonte Park ad B

^Environmental Laboratories Order # 99-02-060 03/16/99 09:22 Page 3 TEST RESULTS BY SAMPLE Sample: 01A OUTFALL 001 Test Description Sday CBOD, EPA 405.1 SUSPENDED SOLIDS,EPA 160.2 Sample: 02A OUTFALL 001 02/01/99 Collected: 02/01/99 Category: AQUEOUS Result 3

BDL Detection Limit 2

5 Units mg/L mg/L Analyzed 02/08/99 02/11/99 Bv PT KC 02/01/99 Collected: 02/01/99 Category: AQUEOUS Test Description

COD, TOC, EPA 410.4 EPA 415.1 Result 6

4.5 Detection Limit 5

1 Units mg/L mg/L Analyzed 02/19/99 02/09/99 fx LG Jw Sample: 03A OUTFALL 001 02/01/99 Collected: 02/01/99 Category: AQUEOUS Test Description AMMONIA N, Result BDL Detection Limit 0.5 Units Analvzed mg/L 02/11/99 BY JB EPA 350.2 Sample: 05A OUTFALL 001 Test Description EPA-625 SEMI VOL. EXTRACT EXTRACTION, EPA 608 Sample: 06A OUTFALL 001 02/01/99 Collected: 02/01/99 Detection Limit Result Category: AQUEOUS Units Analyzed BY SD SD Category: AQUEOUS 02/01/99 Collected: 02/01/99 Test Description

ALUMINUM, ANTIMONY,

ARSENIC, BARIUM, BERYLLIUM,

BORON, CADMIUM,

CHROMIUM, COBALT,

COPPER, IRON,

LEAD, it

LITHIUM, EPA EPA EPA EPA EPA EPA EPA EPA EPA EPA EPA EPA EPA 200.7 204.2 206.2 200.7 200.7 200.7 213.2 200.7 200.7 220.2 200.7 239.2 200.7 Result 0.05 BDL BDL 0.021 BDL 0.07 BDL BDL BDL BDL BDL BDL 0.01 Detection Limit 0.05 0.001 0.001 0.005 0.001 0.05 0.0002 0.01 0.01 0.001 0.1 0.001 0.01 Units mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L Analyzed 02/12/99 03/05/99 03/05/99 02/11/99 02/11/99 02/12/99 03/08/99 02/11/99 02/11/99 03/08/99 02/11/99 03/0 5/9 9 02/12/99 By RJE RJE RJE RJE RJE RJE RJE RJE RJE RJE RJE RJE RJE Committed to Quality Since 1958 Dayton. Ohio 45426 (937) 837-3744 I1I r-nc+ t~ran qtrs==t

I Belmonte Park I :

s

=

Environmental id Laboratories Order # 99-02-060 03/16/99 09:22 Page 4 TEST RESULTS BY SAMPLE Test Description MAGNESIUM, EPA 200.7 MANGANESE, EPA 200.7

MERCURY, EPA 245.1 METALS DIGESTION, WATER MOLYBDENUM,

NICKEL, SELENIUM,

SILVER, STRONTIUM,

THALLIUM, URANIUM

ZINC, EPA EPA EPA EPA EPA EPA EPA EPA 200.7 249.2 200.7 272.2 200.7 279.2 200.7 200.7 Result 11 BDL BDL BDL BDL BDL BDL 0.12 BDL BDL BDL Detection Limit 1

0.01 0.0002 0.01 0.005 0.1 0.0005 0.01 0.001 0.1 0.02 Units mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L Analyzed 02/12/99 02/11/99 02/11/99 02/11/99 03/08/99 02/11/99 03/08/99 02/12/99 03/05/99 02/15/99 02/11/99 Ry RJE RJE RJE EP RJE RJE RJE RJE RJE RJE RJE RJE Sample: 07A OUTFALL 001 02/01/99 Collected: 02/01/99 Category: AQUEOUS Test Description

SULFIDE, TOTAL CYANIDE, EPA 376.1 EPA 335.2 Result BDL BDL Detection Limit 1

0.01 Units mg/L mg/L Analyzed 03/05/99 03/04/99 Ly LG iLG Sample: 08A OUTFALL 001 02/01/99 Collected: 02/01/99 Category: AQUEOUS Test Description PHENOLICS, Result BDL Detection Limit 0.01 Units Analyzed mg/L 02/23/99

]ly JB EPA 420.1 Sample: 09A OUTFALL 001 02/01/99 Collected: 02/01/99 Category: AQUEOUS Test Description CHLORINE, RESIDUAL TOTAL Result BDL Detection Limit 0.05 Units Analyzed mg/L 02/03/99 By ML Sample: 10A OUTFALL 001 02/01/99 Collected: 02/01/99 Category: AQUEOUS Test Description NITRATE-NITRITE N ORGANIC NITROGEN PHOSPHORUS, EPA 365.1

TKN, EPA 351.3 Result 0.38 BDL 0.37 BDL Detection Limit 0.2 0.5 0.1 0.5 Units mg/L mg/L mg/L mg/L Analyzed 02/05/99 02/11/99 02/18/99 02/06/99 By LG JB LG JB Committed to Quality Since 1958 Dayton, Ohio 45426

__ I11 Pnqt Mnin Stre~et (937) 837-3744

Belmonte Park I.-La Environrnral

, =

Laboratories Order # 99-02-060 03/16/99 09:22 Sample: 1lA OUTFALL 001 Page 5 TEST RESULTS BY SAMPLE 02/01/99 Collected: 02/01/99 Category: AQUEOUS Test Description OIL & GREASE, Result BDL Detection Limit 5

Units Analyzed By mg/L 02/10/99 PT EPA 413.1 Sample: 12A OUTFALL 001 02/01/99 Collected: 02/01/99 Category: AQUEOUS Test Description GROSS ALPHA, GROSS BETA,

RADIUM, RADIUM-226, IN WATER IN WATER IN WATER IN WATER Result EDL BDL BDL BDL Detection Limit 3

4 1

1 Units pCi/L pCi/L pCi/L pCi/L Analyzed 03/08/99 03/08/99 03/10/99 03/10/99 BlY SF SF SF SF Sample: 13A OUTFALL 001 02/01/99 Collected: 02/01/99 Category: AQUEOUS Test Description METHYLENE BLUE ACTIVE SUB.

SULFATE, EPA 375.4

SULFITE, Sample: 14A OUTFALL 001 Result BDL BDL BDL Detection Limit 0.01 10 2

Units mg/L mg/L mg/L Analyzed 02/17/99 02/18/99 02/17/99 By ML JB ML 02/01/99 Collected: 02/01/99-Category: AQUEOUS Test Description ASBESTOS WATER Result ND Detection Limit 0.2 Units Analyzed MF/L, >lOum 02/12/99 EY EM Sample: 16A OUTFALL OOG Test Description 5day CBOD, EPA 405.1 SUSPENDED SOLIDS,EPA 160.2 Sample: 17A OUTFALL OOG 02/01/99 Collected: 02/01/99 Category: AQUEOUS Detection Result Limit Units Analyzed 4

2 mg/L 02/08/99 BDL 5

mg/L 02/11/99 02/01/99 Collected: 02/01/99 Category: AQUEOUS BY PT KC Test Description

COD, TOC, EPA 410.4 EPA 415.1 Result BDL 2.1 Detection Limit 5

1 Units mg/L mg/L Analyzed 02/19/99 02/09/99 LG JW

'I' Committed to Quality Since 1958 Dayton, Ohio 45426 (937) 837-3744 11 East Main Street

I O Belmonte Park a

F ^Environmental Laboratories Order # 99-02-060 03/16/99 09:22 Page 6 TEST RESULTS BY SAMPLE Sample: 18A OUTFALL OOG 02/01/99 Collected: 02/01/99 Category: AQUEOUS Test Description AMMONIA N, Result BDL Detection Limit 0.5 Units Analyzed By mg/L 02/11/99 JB EPA 350.2 Sample: 20A OUTFALL 0OG 02/01/99 Collected: 02/01/99 Category: AQUEOUS Detection Limit Test Description EPA 625 SEMI VOL. EXTRACT EXTRACTION, EPA 608 Sample: 21A OUTFALL OOG Result Units Analyzed Category: AQUEOUS By SD SD 02/01/99 Collected: 02/01/99 Test Description

ALUMINUM, EPA

ANTIMONY, EPA

ARSENIC, EPA

BARIUM, EPA BERYLLIUM, EPA

BORON, EPA

CADMIUM, EPA

CHROMIUM, EPA

COBALT, EPA

COPPER, EPA

IRON, EPA

LEAD, EPA

LITHIUM, EPA MAGNESIUM, EPA MANGANESE, EPA

MERCURY, EPA METALS DIGESTION, MOLYBDENUM, EPA

NICKEL, EPA

SELENIUM, EPA

SILVER, EPA STRONTIUM, EPA

THALLIUM, EPA URANIUM EPA

ZINC, EPA 1a 200.7 204.2 206.2 200.7 200.7 200.7 213.2 200.7 200.7 220.2 200.7 239.2 200.7 200.7 200.7 245.1 WATER 200.7 249.2 200.7 272.2 200.7 279.2 200.7 200.7 Result BDL BDL BDL 0.022 BDL 0.06 BDL BDL BDL BDL BDL BDL BDL 12 BDL BDL BDL BDL BDL BDL 0.14 BDL BDL BDL Detection Limit 0.05 0.001 0.001 0.005 0.001 0.05 0.0002 0.01 0.01 0.001 0.1 0.001 0.01 1

0.01 0.0002 Units mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L Analvzed 02/12/99 03/05/99 03/05/99 02/11/99 02/11/99 02/12/99 03/08/99 02/11/99 02/11/99 03/08/99 02/11/99 03/05/99 02/12/99 02/12/99 02/11/99 02/11/99 02/11/99 03/08/99 02/11/99 03/08/99 02/12/99 03/05/99 02/15/99 02/11/99 Bv RJEL RJE RJE RJE RJE RJE RJE RJE RJE RJE RJE RJE RJE RJE RJE RJE RJE EP RJE RJE RJE RJE RJE RJE RJE RJE 0.01 0.005 0.1 0.0005 0.01 0.001 0.1 0.02 Committed to Quality Since 1958 nr4Arn rNhir% A-R9

o.

w (937) 837-3744

Belmonte Park i =

Environmental I

Laboratories Order # 99-02-060 03/16/99 09:22 Page 7 TEST RESULTS BY SAMPLE Sample: 22A OUTFALL 00G 02/01/99 Collected: 02/01/99 Category: AQUEOUS Test Description

SULFIDE, TOTAL CYANIDE, EPA 376.1 EPA 335.2 Result BDL BDL Detection Limit 1

0.01 Units mg/L mg/L Analyzed 03/05/99 03/15/99 BL LG LG Sample: 23A OUTFALL OOG 02/01/99 Collected: 02/01/99 Category: AQUEOUS Test Description PHENOLICS, Result BDL Detection Limit 0.01 Units Analyzed mg/L 02/23/99 BY JB EPA 420.1 Sample: 24A OUTFALL 00G I

Test Description

'14 CHLORINE, RESIDUAL TOTAL Sample: 25A OUTFALL OOG 02/01/99 Collected: 02/01/99 Result BDL Detection Limit 0.05 Category: AQUEOUS Units Analyzed mg/L 02/03/99 Category: AQUEOUS BY ML 02/01/99 Collected: 02/01/99 Test Description NITRATE-NITRITE N ORGANIC NITROGEN PHOSPHORUS, EPA 365.1

TKN, EPA 351.3 Result 0.50 BDL BDL BDL Detection Limit 0.2 0.5 0.1 0.5 Units mg/L mg/L mg/L mg/L Analyzed 02/05/99 02/11/99 02/18/99 02/06/99 By LG JB LG JB Sample: 26A OUTFALL OOG 02/01/99 Collected: 02/01/99 Category: AQUEOUS Test Description OIL & GREASE, Result BDL Detection Limit 5

Units Analyzed mg/L 02/10/99 By PT EPA 413.1 Sample: 27A OUTFALL 00G 02/01/99 Collected: 02/01/99 Category: AQUEOUS Test Description GROSS ALPHA, GROSS BETA,

RADIUM, RADIUM-226, IN IN IN IN WATER WATER WATER WATER Result BDL BDL BDL BDL Detection Limit 3

4 1

1 Units pCi/L pCi/L pCi/L pCi/L Analyzed 03/08/99 03/08/99 03/10/99 03/10/99 Bv SF SF SF SF I4 Committed to Quality Since 1958 nrivtnn C)hl, 4A9A 1 1 Cc+ UjIr% 4Zt,==t (937) 837-3744

Belmonte Park e z Environmental Laboratories Order # 99-02-060 03/16/99 09:22 Page 8 TEST RESULTS BY SAMPLE Sample: 28A OUTFALL 00G Test Description METHYLENE BLUE ACTIVE SUB.

SULFATE, EPA 375.4

SULFITE, 02/01/99 Collected: 02/01/99 Category: AQUEOUS Result BDL 113 BDL Detection Limit 0.01 10 2

Units mg/L mg/L mg/L Analyzed 02/17/99 02/18/99 02/17/99 ML JB ML Sample: 29A OUTFALL OOG Test Description ASBESTOS WATER Sample: 31A OUTFALL OOC 02/01/99 Collected: 02/01/99 Category: AQUEOUS Result ND Detection Limit 0.2 Units Analyzed MF/L, >lOum 02/12/99 By EM 02/01/99 Collected: 02/01/99 Category: AQUEOUS -

J Test Description 5day CBOD, EPA 405.1 SUSPENDED SOLIDS,EPA 160.2 Result 4

BDL Detection Limit 2

5 Units mg/L mg/L Analyzed 02/08/99 02/11/99 BY_

PT KC Sample: 32A OUTFALL 00C 02/01/99 Collected: 02/01/99 Category: AQUEOUS Test Description

COD, TOC, EPA 410.4 EPA 415.1 Result BDL BDL Detection Limit 5

1 Units mg/L mg/L Analyzed 02/19/99 02/09/99 LG JW Sample: 33A OUTFALL OOC 02/01/99 Collected: 02/01/99 Category: AQUEOUS Test DescriPtion AMMONIA N, Result BDL Detection Limit 0.5 Units Analyzed By mg/L 02/11/99 JB EPA 350.2 Sample: 35A OUTFALL OOC 02/01/99 Collected: 02/01/99 Category: AQUEOUS Detection Limit Test Description EPA 625 SEMI VOL. EXTRACT EXTRACTION, EPA 608 Result Units Analyzed SD SD SD Committed to Quality Since 1958 Dayton, Ohio 45426 I11 East Main Street (937) 837-3744

Belmonte Park

.1)

Environmental Laboratores Order # 99-02-060 03/16/99 09:22 Page 9 TEST RESULTS BY SAMPLE 02/01/99 Collected: 02/01/99 Sample: 36A OUTFALL 0OC Category: AQUEOUS Test Description

ALUMINUM, ANTIMONY,

ARSENIC, BARIUM, BERYLLIUM,

BORON, CADMIUM,

CHROMIUM, COBALT,

COPPER, IRON,

LEAD, LITHIUM, MAGNESIUM, MANGANESE,

MERCURY, METALS DIGESTION, EPA EPA EPA EPA EPA EPA EPA EPA EPA EPA EPA EPA EPA EPA EPA EPA EPA EPA EPA EPA EPA EPA EPA EPA 200.7 204.2 206.2 200.7 200.7 200.7 213.2 200.7 200.7 220.2 200.7 239.2 200.7 200.7 200.7 245.1 WATER Result BDL 0.002 BDL BDL BDL BDL BDL BDL BDL 0.012 BDL BDL BDL BDL 0.01 BDL Detection Limit 0.05 0.001 0.001 0.005 0.001 0.05 0.0002 0.01 0.01 0.001 0.1 0.001 0.01 1

0.01 0.0002 Units mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L Analyzed 02/12/99 03/05/99 03/05/99 02/11/99 02/11/99 02/12/99 03/08/99 02/11/99 02/11/99 03/08/99 02/11/99 03/05/99 02/12/99 02/12/99 02/11/99

-02/11/99 02/11/99 03/08/99 02/11/99 03/08/99 02/12/99 03/05/99 02/15/99 02/11/99 RJ RJE RJE RJE RJE RJE RJE RJE RJE RJE RJE RJE RJE RJE RJE RJE RJE EP RJE RJE RJE RJE RJE RJE RJE RJE MOLYBDENUM,

NICKEL, SELENIUM,

SILVER, STRONTIUM,

THALLIUM, URANIUM

ZINC, 200.7 249.2 200.7 272.2 200.7 279.2 200.7 200.7 BDL BDL BDL BDL BDL BDL BDL BDL 0.01 0.005 0.1 0.0005 0.01 0.001 0.1 0.02 mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L Sample: 37A OUTFALL 0OC 02/01/99 Collected: 02/01/99 Category: AQUEOUS Test Description

SULFIDE, TOTAL CYANIDE, EPA 376.1 EPA 335.2 Result BDL BDL Detection -

Limit 1

0.01 Units mg/L mg/L Analyzed 03/05/99 03/04/99 LY LG LG Sample: 38A OUTFALL DOC 02/01/99 Collected: 02/01/99 Category: AQUEOUS Test Description PHENOLICS, Result BDL Detection Limit 0.01 Units Analyzed By mg/L 02/23/99 JB EPA 420.1 Committed to Quality Since 1958 Dayton. Ohio 45426 11 East Main Street (937) 837-3744

a' hBelmonte Park i

Environmental Laboratories Order # 99-02-060 03/16/99 09:22 Page 10 TEST RESULTS BY SAMPLE Sample: 39A OUTFALL OOC 02/01/99 Collected: 02/01/99 Category: AQUEOUS Test Description

CHLORINE, RESIDUAL TOTAL Result BDL Detection Limit 0.05 Units Analyzed mg/L 02/03/99 By ML Sample: 40A OUTFALL OOC 02/01/99 Collected: 02/01/99 Category: AQUEOUS Test Description NITRATE-NITRITE N ORGANIC NITROGEN PHOSPHORUS, EPA 365.1

TKN, EPA 351.3 Result BDL BDL BDL BDL Detection Limit 0.2 0.5 0.1 0.5 Units mg/L mg/L mg/L mg/L Analyzed 02/05/99 02/11/99 02/18/99 02/06/99 By LG JB LG JB Sample: 41A OUTFALL OOC 02/01/99 Collected: 02/01/99 Category: AQUEOUS Test Description OIL & GREASE, Result BDL Detection Limit 5

Units Analyzed mg/L 02/10/99 BY PT EPA 413.1 Sample: 42A OUTFALL OOC 02/01/99 Collected: 02/01/99 Category: AQUEOUS Test Description GROSS ALPHA, GROSS BETA,

RADIUM, RADIUM-226, IN IN IN IN WATER WATER WATER WATER Result BDL BDL BDL BDL Detection Limit 3

4 1

1 Units pCi/L pCi/L pCi/L pCi/L Analyzed 03/08/99 03/08/99 03/10/99 03/10/99 BY SF SF SF SF Sample: 43A OUTFALL OOC 02/01/99 Collected: 02/01/99 Category: AQUEOUS Test Description METHYLENE BLUE ACTIVE SUB.

SULFATE, EPA 375.4

SULFITE, Result BDL BDL BDL Detection-Limit 0.01 10 2

Units mg/L mg/L mg/L Analyzed 02/17/99 02/18/99 02/17/99 iBx ML JB ML Sample: 44A OUTFALL OOC Test Description ASBESTOS WATER 02/01/99 Collected: 02/01/9 Result ND Detection Limit 0.2 99 Category: AQUEOUS Units Analyzed Py MF/L, >lOum 02/12/98 EM Committed to Quality Since 1958 Dayton, Ohio 45426 11 I nct Mnin.Strizit (937) 837-3744

Belmonte Park J

Environmental Laboratories Order # 99-02-060 03/16/99 09:22 Page 11 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL 001 Test

Description:

EPA 624 Collected: 02/01/99 02/01/99 Lab No: 04A Method: 624 Category: AQUEOUS Test Code: 624 X PARAMETER RESULT LIMIT

-I, ACROLEIN ACRYLONITRILE 2-CHLOROETHYLVINYL ETHER BENZENE CARBON TETRACHLORIDE CHLOROBENZENE 1,2-DICHLOROETHANE 1,1,1-TRICHLOROETHANE l,1-DICHLOROETHANE 1,1,2-TRICHLOROETHANE 1,1,2,2-TETRACHLOROETHANE CHLOROETHANE CHLOROFORM 1,1-DICHLOROETHYLENE 1,2-TRANS-DICHLOROETHYLENE 1,2-DICHLOROPROPANE CIS-1,3-DICHLOROPROPYLENE TRANS-1,3-DICHLOROPROPYLENE ETHYLBENZENE 1,2-DICHLOROBENZENE 1,3-DICHLOROBENZENE 1,4-DICHLOROBENZENE METHYLENE CHLORIDE CHLOROMETHANE BROMOMETHANE BROMOFORM DICHLOROBROMOMETHANE TRICHLOROFLUOROMETHANE CHLORODIBROMOMETHANE TETRACHLOROETHYLENE TOLUENE TRICHLOROETHENE VINYL CHLORIDE XYLENES BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL-BDL BDL BDL BDL BDL BDL BDL 20 20 20 2

2 2

2 2

2 2

2 10 2

2 2

2 2

2 2

2 2

2 10 10 2

2 2

2 2

2 2

2 10 10 1 1 East Main Street SURROGATE D4-1,2 DICHLOROETHANE D8-TOLUENE

%RECOVERY 112 94 LIMITS 76 88 114 110 Committed to Quality Since 1958 Dayton, Ohio 45426 (937) 837-3744

I O h Belmonte Park

.J A Envirnl EnAraonmental Laboratories Order # 99-02-060 03/16/99 09:22 Page 12 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL 001 Test

Description:

EPA 624 Collected: 02/01/99 02/01/99 Lab No: 04A Method: 624 Category: AQUEOUS Test Code: 624 X 4-BROMOFLUOROBENZENE 96 115 Notes and Definitions for this Report:

DATE RUN 02/09/99 ANALYST JMM INSTRUMENT GC/MS FILE ID 9020934 UNITS us/L METHOD EPA 624 BDL BELOW DETECTION LIMIT Committed to Quality Since 1958 Dayton, Ohio 4542M 1 1 Pnst Mciln Street (937) 837-3744

I

^Belmonte Park I

= Environmental Laboratories Order # 99-02-060 03/16/99 09:22 Page 13 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL 001 02/01/99 Lab No: 05A Test

Description:

EPA 625 SEMI VOLATILES Method: 625 Collected: 02/01/99 Category: AQUEOUS Test Code: 625 AE PARAMETER RESULT LIMIT 2,4,6-TRICHLOROPHENOL 4-CHLORO-3-METHYLPHENOL 2-CHLOROPHENOL 2,4-DICHLOROPHENOL 2,4-DIMETHYLPHENOL 2-NITROPHENOL 4-NITROPHENOL 2,4-DINITROPHENOL 2-METHYL-4,6-DINITROPHENOL PENTACHLOROPHENOL PHENOL ACENAPHTHENE BENZIDENE 1,2,4-TRICHLOROBENZENE HEXACHLOROBENZENE HEXACHLOROETHANE BIS(2-CHLOROETHYL)ETHER 2-CHLORONAPHTHALENE 1,2 DICHLOROBENZENE 1,3-DICHLOROBENZENE 1,4-DICHLOROBENZENE 3,3-DICHLOROBENZIDINE 2,4-DINITROTOLUENE 2,6-DINITROTOLUENE FLUORANTHENE 4-CHLOROPHENYL PHENYL ETHER 4-BROMOPHENYL PHENYL ETHER BIS(2-CHLOROISOPROPYL) ETHER BIS(2-CHLOROETHOXY) METHANE HEXACHLOROBUTADIENE HEXACHLOROCYCLOPENTADIENE ISOPHORONE NAPHTHALENE NITROBENZENE N-NITROSODIMETHYLAMINE N-NITROSODIPHENYLAMINE N-NITROSODI-N-PROPYLAMINE BIS(2-ETHYLHEXYL)PHTHALATE BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL-BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 10 10 10 10 10 10 50 50 50 50 10 10 50 10 10 10 10 10 10 10 10 20 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 Committed to Quality Since 1958 nnvtnn Ohio A5A26 1 c+c Ksriin 4Ztrnimt (937) 837-3744

I Belmonte Park

-. )

Environnmntal ia Laboratories Order # 99-02-060 03/16/99 09:22

'J Page 14 TEST RESULTS BY SAMPLE Sample

Description:

Test

Description:

Collected:

OUTFALL 001 02/01/99 Lab No: 05A EPA 625 SEMI VOLATILES Method: 625 02/01/99 Category: AQUEOUS Test Code: 625 AE BUTYL BENZYLPHTHALATE DI-N-BUTYL PHTHALATE DI-N-OCTYL PHTHALATE DIETHYL PHTHALATE DIMETHYL PHTHALATE BENZO(A)ANTHRACENE BENZO (A) PYRENE 3,4-BENZOFLUORANTHENE BENZO(K)FLUORANTHENE CHRYSENE ACENAPHTHYLENE ANTHRACENE BENZO(GHI)PERYLENE FLUORENE PHENANTHRENE DIBENZO(A,H)ANTHRACENE INDENO(1,2,3-CD)PYRENE PYRENE ETHANOL AMINE HYDRAZINE BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 10 10 10 10 10 10 10 10 10 10 10 10 50 10 10 50 50 10 100 200 SURROGATE NITROBENZENE-d5 2-FLUOROBIPHENYL p-TERPHENYL-d14 PHENOL-d6 2-FLUOROPHENOL 2,4,6-TRIBROMOPHENOL

%RECOVERY 85 72 95 46 74 50 LIMITS 35 43 33 10 21 10 114 116 141 94 100 123 Notes and Definitions for this Report:

EXTRACTED 02/07/99 DATE RUN 02/25/99 ANALYST TC INSTRUMENT GC/MS FILE ID S9022524 UNITS ug/L METHOD EPA 625 BDL BELOW DETECTION LIMIT it Committed to Quality Since 1958 Dayton, Ohio 45426 1 1 East Main Street (937) 837-3744

Belmonte Park

. > ^

Environmental Laboratories Order # 99-02-060 03/16/99 09:22 Page 15 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL 001 02/01/99 Lab No: 05A Test

Description:

PCB/PESTICIDES EPA 608 Method: 608 Collected: 02/01/99 Category: AQUEOUS Test Code: 608 PARAMETER RESULT LIMIT I\\
. 4 ALDRIN ALPHA-BHC BETA-BHC DELTA-BHC GAMMA-BHC CHLORDANE 4,4-DDT 4,4-DDE 4,4-DDD DIELDRIN ALPHA ENDOSULFAN BETA ENDOSULFAN ENDOSULFAN SULFATE ENDRIN ENDRIN ALDEHYDE HEPTACHLOR HEPTACHLOR EPOXIDE PCB-1016 PCB-1221 PCB-1232 PCB-1242 PCB-1248 PCB-1254 PCB-1260 TOXAPHENE BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 0. 010 0.010 0.010 0. 010 0.010 0.010 0.010 0. 010 0.010 0.010 0.010 0.010 0.10 0.010 0.020 0.030 0.10 0.10 0.20 0.10 0.10 0.10 0.10 0.10 0.20 SURROGATE DBC(SURROGATE,

% RECOVERY) 2,4,5,6-TCX(SURROGATE

% REC.)

%RECOVERY 90 93 LIMITS 70 70 130 130 Notes and Definitions for this Report:

EXTRACTED 02/06/99 DATE RUN 02/09/99 ANALYST JW INSTRUMENT GC FILE ID A020913 UNITS uq/L Committed to Quality Since 1958 Dayton, Ohio 45426 (937) 837-3744 11 Fnst Main Street

I B

Belmonte Park Environmental.

Laboratories Order # 99-02-060 03/16/99 09:22 Page 16 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL 001 02/01/99 Lab No:

Test

Description:

PCB/PESTICIDES EPA 608 Method:

Collected: 02/01/99 Category:

05A 608 AQUEOUS Test Code: 608 METHOD EPA 608 BDL BELOW DETECTION LIMIT Committed to Quality Since 1958 Dayton, Ohio 45426 I11 East Main Street (937) 837-3744

Belmonte Park KcJ pr

^Environment Laboratories Order # 99-02-060 03/16/99 09:22 Page 17 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL 001 02/01/99 Lab No: 15A Test

Description:

Triaryl Phosphate Sub-Out Method: Special Test Test Collected: 02/01/99 Category: AQUEOUS Code: 8270 U PARAMETER TRIPHENYL PHOSPHATE ESTER TRICRESYL PHOSPHATE ESTER RESULT LIMIT BDL 5

BDL 5

SURROGATE NITROBENZENE-D5 2-FLUOROBIPHENYL p-TERPHENYL-d14 PHENOL-d6 2-FLUOROPHENOL 2,4,6-TRIBROMOPHENOL

%RECOVERY 65 78 113 25 30

-_1 93' LIMITS 35 43 33 10 21 10 114 116 141 94 100 123 Notes and Definitions for this Report:

EXTRACTED 02/08/99 DATE RUN 02/11/99 ANALYST JAT INSTRUMENT SATURN FILE ID 0206501W UNITS us/L METHOD 8270 BDL BELOW DETECTION

- LIMIT Committed to Quality Since 1958 Datvton. Ohio 45426 1 I r-et hAnin qetr&==t (937) 837-3744

I Belmonte Park

.)

Enviromental Laboratories Order # 99-02-060 03/16/99 09:22 Page 18 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL OOG Test

Description:

EPA 624 Collected: 02/01/99 02/01/99 Lab No: 19A Method: 624 Category: AQUEOUS Test Code: 624 X PARAMETER RESULT LIMIT 9

ACROLEIN ACRYLONITRILE 2-CHLOROETHYLVINYL ETHER BENZENE CARBON TETRACHLORIDE CHLOROBENZENE 1,2-DICHLOROETHANE 1,1,1-TRICHLOROETHANE 1,1-DICHLOROETHANE 1,1,2-TRICHLOROETHANE 1,1,2,2-TETRACHLOROETHANE CHLOROETHANE CHLOROFORM 1,1-DICHLOROETHYLENE 1,2-TRANS-DICHLOROETHYLENE 1,2-DICHLOROPROPANE CIS-1,3-DICHLOROPROPYLENE TRANS-1,3-DICHLOROPROPYLENE ETHYLBENZENE 1,2-DICHLOROBENZENE 1,3-DICHLOROBENZENE 1,4-DICHLOROBENZENE METHYLENE CHLORIDE CHLOROMETHANE BROMOMETHANE BROMOFORM DICHLOROBROMOMETHANE TRICHLOROFLUOROMETHANE CHLORODIBROMOMETHANE TETRACHLOROETHYLENE TOLUENE TRICHLOROETHENE VINYL CHLORIDE XYLENES BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL-BDL BDL BDL BDL BDL BDL BDL 20 20 20 2

2 2

2 2

2 2

2 10 2

2 2

2 2

2 2

2 2

2 10 10 2

2 2

2 2

2 2

2 10 10 SURROGATE D4-1,2 DICHLOROETHANE D8-TOLUENE

%RECOVERY 113 92 LIMITS 76 88 114 110 Committed to Quality Since 1958 Dayton, Ohio 45426 1 1 East Main Street (937) 837-3744

Belmonte Park Environmental Laboratories Page 19 Order # 99-02-060 03/16/99 09:22 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL OOG Test

Description:

EPA 624 Collected: 02/01/99 02/01/99 Lab No: 19A Method: 624 Category: AQUEOUS Test Code: 624 X 4-BROMOFLUOROBENZENE 93 86 115 Notes and Definitions for this Report:

DATE RUN 02/09/99 ANALYST JMM INSTRUMENT GC/MS FILE ID 9020935 UNITS uq/L METHOD EPA 624

• BDL BELOW DETECTION LIMIT

'4 1 110 Committed to Quality Since 1958 MnAr^n nhirn ArA)

(937) 837-3744

.S...^

I Belmonte Park Environmental Laboratores Order # 99-02-060 03/16/99 09:22 Page 20 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL OOG 02/01/99 Lab No: 20A Test

Description:

EPA 625 SEMI VOLATILES Method: 625 Collected: 02/01/99 Category: AQUEOUS Test Code: 625 AE PARAMETER RESULT LIMIT 2,4,6-TRICHLOROPHENOL 4-CHLORO-3-METHYLPHENOL 2-CHLOROPHENOL 2,4-DICHLOROPHENOL 2,4-DIMETHYLPHENOL 2-NITROPHENOL 4-NITROPHENOL 2,4-DINITROPHENOL 2-METHYL-4,6-DINITROPHENOL PENTACHLOROPHENOL PHENOL ACENAPHTHENE BENZIDENE 1,2,4-TRICHLOROBENZENE HEXACHLOROBENZENE HEXACHLOROETHANE BIS(2-CHLOROETHYL)ETHER 2-CHLORONAPHTHALENE 1,2-DICHLOROBENZENE 1,3-DICHLOROBENZENE 1,4-DICHLOROBENZENE 3,3-DICHLOROBENZIDINE 2,4-DINITROTOLUENE 2,6-DINITROTOLUENE FLUORANTHENE 4-CHLOROPHENYL PHENYL ETHER 4-BROMOPHENYL PHENYL ETHER BIS(2-CHLOROISOPROPYL)

ETHER BIS(2-CHLOROETHOXY)

METHANE HEXACHLOROBUTADIENE HEXACHLOROCYCLOPENTADIENE ISOPHORONE NAPHTHALENE NITROBENZENE N-NITROSODIMETHYLAMINE N-NITROSODIPHENYLAMINE N-NITROSODI-N-PROPYLAMINE BIS(2-ETHYLHEXYL)PHTHALATE BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL.

BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 10 10 10 10 10 10 50 50 SO 50 10 10 so 10 10 10 10 10 10 10 10 20 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 Committed to Quality Since 1958 Davton. Ohio 45426 (937) 837-3744 11 I Pnt KAninl qfr==t

I Belmonte Park i^

x Environmental.

Laboratories Order # 99-02-060 03/16/99 09:22 Page 21 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL OOG 02/01/99 Lab No: 20A Test

Description:

EPA 625 SEMI VOLATILES Method: 625 Collected: 02/01/99 Category: AQUEOUS Test Code: 625 AE BUTYL BENZYLPHTHALATE DI-N-BUTYL PHTHALATE DI-N-OCTYL PHTHALATE DIETHYL PHTHALATE DIMETHYL PHTHALATE BENZO(A)ANTHRACENE BENZO(A)PYRENE 3,4-BENZOFLUORANTHENE BENZO(K)FLUORANTHENE CHRYSENE ACENAPHTHYLENE ANTHRACENE BENZO(GHI)PERYLENE FLUORENE PHENANTHRENE DIBENZO(A,H)ANTHRACENE INDENO(1,2,3-CD)PYRENE PYRENE ETHANOL AMINE HYDRAZINE BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 10 10 10 10 10 10 10 10 10 10 10 10 SO 10 10 50 50 10 100 200

-)

SURROGATE NITROBENZENE-d5 2-FLUOROBIPHENYL p-TERPHENYL-d14 PHENOL-d6 2-FLUOROPHENOL 2,4,6-TRIBROMOPHENOL

%RECOVERY 64 65 77 35 33 65 LIMITS 35 43 33 10 21 10 114 116 141 94 100 123 Notes and Definitions for this Report:

EXTRACTED 02/07/99 DATE RUN 02/25/99 ANALYST TC INSTRUMENT GC/MS FILE ID S9022525 UNITS ua/L METHOD EPA 625 BDL BELOW DETECTION LIMIT J4 Committed to Quality Since 1958 Dayton, Ohio 45426 11 East Main Street (937) 837-3744

Belmonte Park Environmental Laboratories Order # 99-02-060 03/16/99 09:22 Page 22 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL OOG 02/01/99 Lab No: 20A Test

Description:

PCB/PESTICIDES EPA 608 Method: 608 Collected: 02/01/99 Category: AQUEOUS Test Code: 608 PARAMETER RESULT LIMIT ALDRIN ALPHA-BHC BETA-BHC DELTA-BHC GAMMA-BHC CHLORDANE 4,4-DDT 4,4-DDE 4,4-DDD DIELDRIN ALPHA ENDOSULFAN BETA ENDOSULFAN ENDOSULFAN SULFATE ENDRIN ENDRIN ALDEHYDE HEPTACHLOR HEPTACHLOR EPOXIDE PCB-1016 PCB-1221 PCB-1232 PCB-1242 PCB-1248 PCB-1254 PCB-1260 TOXAPHENE BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 0. 010 0.010 0. 010 0.010 0.010

0. 010 0. 010 0. 010 0. 010

0. 010 0.010 0. 010 0.10 0.010 0.020 0.030 0.10 0.10 0.20 0.10 0.10 0.10 0.10 0.10 0.20

.Y LIMITS 70 70 SURROGATE DBC(SURROGATE,

% RECOVERY) 2,4,5,6-TCX(SURROGATE

% REC.)

%RECOVER 89 94 130 130 Notes and Definitions for this Report:

EXTRACTED 02/06/99 DATE RUN 02/09/99 ANALYST JW INSTRUMENT GC FILE ID A020914 UNITS uq/L Committed to Quality Since 1958 Dayton, Ohio 45426 1 1 East Main Street (937) 837-3744

Belmonte Park h -

^Environmental Laboratories Order # 99-02-060 03/16/99 09:22 Page 23 TEST RESULTS BY SAMPLE Sample

Description:

Test

Description:

Collected:

OUTFALL OOG 02/01/99 Lab No:

PCB/PESTICIDES EPA 608 -

Method:

02/01/99 Category:

20A 608 AQUEOUS Test Code: 608 METHOD EPA 608 BDL BELOW DETECTION LIMIT

. 'i Committed to Quality Since 1958 Dayton, Ohio 45426 (937) 837-3744 1 -East Main Street

I Belmonte Park i

Environmental Laboratories Order # 99-02-060 03/16/99 09:22 Page 24 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL OOG 02/01/99 Lab No: 30A Test

Description:

Triaryl Phosphate Sub-Out Method: Special Test Test Collected: 02/01/99

• Category: AQUEOUS Code: 8270 U PARAMETER TRIPHENYL PHOSPHATE ESTER TRICRESYL PHOSPHATE ESTER RESULT LIMIT BDL 5

BDL 5

SURROGATE NITROBENZENE-D5 2-FLUOROBIPHENYL p-TERPHENYL-d14 PHENOL-d6 2-FLUOROPHENOL 2,4,6-TRIBROMOPHENOL

%RECOVERY 60 78 115 28 35 85 LIMITS 35 43 33 10 21 10 114 116 141 94 100 123 Notes and Definitions for this Report:

EXTRACTED 02/08/99 DATE RUN 02/11/99 ANALYST JAT INSTRUMENT SATURN FILE ID 0206504W UNITS uL/L METHOD 8270 BDL BELOW DETECTION LIMIT I'

Committed to Quality Since 1958 Dayton, Ohio 45426 I11 Pnqt Moin Street (937) 837-3744

I>

Belmonte Park 1114 i~ ^Environmental v

~Laboratories Order # 99-02-060 03/16/99 09:22 Page 25 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL OOC Test

Description:

EPA 624 Collected: 02/01/99 02/01/99 Lab No: 34A Method: 624 Category: AQUEOUS Test Code: 624 X PARAMETER RESULT LIMIT

,4 ACROLEIN ACRYLONITRILE 2-CHLOROETHYLVINYL ETHER BENZENE CARBON TETRACHLORIDE CHLOROBENZENE 1,2-DICHLOROETHANE 1,1,1-TRICHLOROETHANE 1,1-DICHLOROETHANE 1,1,2-TRICHLOROETHANE 1,1,2,2-TETRACHLOROETHANE CHLOROETHANE CHLOROFORM 1,1-DICHLOROETHYLENE 1,2-TRANS-DICHLOROETHYLENE 1,2-DICHLOROPROPANE CIS-1,3-DICHLOROPROPYLENE TRANS-1,3-DICHLOROPROPYLENE ETHYLBENZENE 1,2-DICHLOROBENZENE 1,3-DICHLOROBENZENE 1,4-DICHLOROBENZENE METHYLENE CHLORIDE CHLOROMETHANE BROMOMETHANE BROMOFORM DICHLOROBROMOMETHANE TRICHLOROFLUOROMETHANE CHLORODIBROMOMETHANE TETRACHLOROETHYLENE TOLUENE TRICHLOROETHENE VINYL CHLORIDE XYLENES BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 20 20 20 2

2 2

2 2

2 2

2 10 2

2 2

2 2

2 2

2 2

2 10 10 2

2 2

2 2

2 2

2 10 10 SURROGATE D4-1,2 DICHLOROETHANE D8-TOLUENE

%RECOVERY 114 94 LIMITS 76 88 114 110 Committed to Quality Since 1958 Davton, Ohio 45426 (937) 837-3744 i 1 r__4 FL A-a Ctrmm

Belmonte Park

A..

Environmental J

=

Laboratores

'Ki Order # 99-02-060 03/16/99 09:22 Page 26 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL OOC Test

Description:

EPA 624 Collected: 02/01/99 02/01/99 Lab No: 34A Method:'624 Category: AQUEOUS Test Code: 624 X 4-BROMOFLUOROBENZENE 93 115 Notes and Definitions for this Report:

DATE RUN 02/09/99 ANALYST JMM INSTRUMENT GC/MS FILE ID 9020936 UNITS uq/L METHOD EPA 624 BDL BELOW DETECTION LIMIT Committed to Quality Since 1958 Dayton, Ohio 45426 11 East Main Street (937) 837-3744

<'j Belmonte Park I..

Environmental J

a Laboratories Order # 99-02-060 03/16/99 09:22 Page 27 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL OOC 02/01/99 Lab No: 35A Test

Description:

EPA 625 SEMI VOLATILES Method: 625 Collected: 02/01/99 Category: AQUEOUS Test Code: 625 AE PARAMETER RESULT LIMIT I

II.

2,4,6-TRICHLOROPHENOL 4-CHLORO-3-METHYLPHENOL 2-CHLOROPHENOL 2,4-DICHLOROPHENOL

-2,4-DIMETHYLPHENOL 2-NITROPHENOL 4-NITROPHENOL 2,4-DINITROPHENOL 2-METHYL-4,6-DINITROPHENOL PENTACHLOROPHENOL PHENOL ACENAPHTHENE BENZIDENE 1,2,4-TRICHLOROBENZENE HEXACHLOROBENZENE HEXACHLOROETHANE BIS(2-CHLOROETHYL)ETHER 2-CHLORONAPHTHALENE 1,2-DICHLOROBENZENE 1,3-DICHLOROBENZENE 1,4-DICHLOROBENZENE 3,3-DICHLOROBENZIDINE-2,4-DINITROTOLUENE 2,6-DINITROTOLUENE FLUORANTHENE 4-CHLOROPHENYL PHENYL ETHER 4-BROMOPHENYL PHENYL ETHER BIS(2-CHLOROISOPROPYL)

ETHER BIS(2-CHLOROETHOXY)

METHANE HEXACHLOROBUTADIENE HEXACHLOROCYCLOPENTADIENE ISOPHORONE NAPHTHALENE NITROBENZENE N-NITROSODIMETHYLAMINE N-NITROSODIPHENYLAMINE N-NITROSODI-N-PROPYLAMINE BIS(2-ETHYLHEXYL)PHTHALATE BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL

-BDL BDL BDL BDL BDL BDL BDL BDL 10 10 10 10 10 10 50 50 50 so 10 10 so 10 10 10 10 10 10 10 10 20 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 to Committed to Quality Since 1958 Dayton, Ohio 45426 (937) 837-3744 11 East Main Street

I Belmonte Park

'z Environmental Laboratories Order # 99-02-060 03/16/99 09:22 Page 28 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL OOC 02/01/99 Lab No: 35A Test

Description:

EPA 625 SEMI VOLATILES Method: 625 Collected: 02/01/99 Category: AQUEOUS Test Code: 625_AE BUTYL BENZYLPHTHALATE DI-N-BUTYL PHTHALATE DI-N-OCTYL PHTHALATE DIETHYL PHTHALATE DIMETHYL PHTHALATE BENZO(A)ANTHRACENE BENZO(A)PYRENE 3,4-BENZOFLUORANTHENE BENZO(K)FLUORANTHENE CHRYSENE ACENAPHTHYLENE ANTHRACENE BENZO(GHI)PERYLENE FLUORENE PHENANTHRENE DIBENZO(A,H)ANTHRACENE INDENO (12,3-CD)PYRENE PYRENE ETHANOL AMINE HYDRAZINE BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 10 10 10 10 10 10 10 10 10 10 10 10 50 10 10 50 50 10 100 200 SURROGATE NITROBENZENE-d5 2-FLUOROBIPHENYL p-TERPHENYL-d14 PHENOL-d6 2-FLUOROPHENOL 2,4,6-TRIBROMOPHENOL

%RECOVERY 77 66 82 62 71 66 LIMITS 35 43 33 10 21 10 114 116 141 94 100 123 Notes and Definitions for this Report:

EXTRACTED 02/07/99 DATE RUN 02/25/99 ANALYST TC INSTRUMENT GC/MS FILE ID S9022526 UNITS ucr/L METHOD EPA 625 BDL BELOW DETECTION LIMIT Committed to Qualilty Since 1958 Dayton, Oh1o 45426 I11 East Main Street (937) 837-3744

a h Belmonte Park

11.

Environmental Laboratories Order # 99-02-060 03/16/99 09:22 Page 29 TEST RESULTS BY SAMPLE I Sample

Description:

OUTFALL OOC 02/01/99 Lab No: 35A Test

Description:

-PCB/PESTICIDES EPA 608 Method: 608 Collected: 02/01/99 Category: AQUEOUS Test Code: 608 PARAMETER RESULT LIMIT 0 ALDRIN ALPHA-BHC BETA-BHC DELTA-BHC GAMMA-BHC CHLORDANE 4,4-DDT 4,4-DDE 4,4-DDD DIELDRIN ALPHA ENDOSULFAN BETA ENDOSULFAN ENDOSULFAN SULFATE ENDRIN ENDRIN ALDEHYDE HEPTACHLOR HEPTACHLOR EPOXIDE PCB-1016 PCB-1221 PCB-1232 PCB-1242 PCB-1248 PCB-1254 PCB-1260 TOXAPHENE BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL

• BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 0.010 0. 010

0. 010 0.010

0. 010

0. 010 0.010 0. 010 0.010

0. 010 0.010 0. 010 0.10

0. 010 0.020 0.030 0.10 0.10 0.20 0.10 0.10 0.10 0.10 0.10 0.20 SURROGATE DBC(SURROGATE,

% RECOVERY) 2,4,5,6-TCX(SURROGATE % REC.)

%RECOVERY 93 92 LIMITS 70 70 130 130 Notes and Definitions for this Report:

EXTRACTED 02/06/99 DATE RUN 02/09/99 ANALYST JW INSTRUMENT GC FILE ID A020915 UNITS ua/L Committed to Quality Since 1958 nrvton, Ohio 45426 (937) 837-3744 I I,_

A-:

^

__C4-_+

Belmonte Park Environmental Laboratories Order # 99-02-060 03/16/99 09:22 Page 30 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL OOC 02/01/99 Lab No: 35A Test

Description:

PCB/PESTICIDES EPA 608 Method: 608 Collected: 02/01/99 Category: AQUEOUS Test Code: 608 METHOD EPA 608 BDL BELOW DETECTION LIMIT Committed to Quality Since 1958 Dayton, Ohio 45426 1 1 East Main Street (937) 837-3744

a h Belmonte Park Environmental -

W Laboratories z

Order # 99-02-060 03/16/99 09:22 Page 31 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL 0CC 02/01/99 Test

Description:

Triaryl Phosphate Sub-Out Collected: 02/01/99 Cc Lab No: 45A Method: Spei ategory: AQUI

ial Test Test EOUS Code: 8270 U PARAMETER RESULT LIMIT TRIPHENYL PHOSPHATE ESTER TRICRESYL PHOSPHATE ESTER BDL 5

BDL 5

SURROGATE NITROBENZENE-D5 2-FLUOROBIPHENYL p-TERPHENYL-d14 PHENOL-dG 2-FLUOROPHENOL 2,4,6-TRIBROMOPHENOL

%RECOVERY 63 70 100 25 38 83 LIMITS 35 43 33 10 21 10 114 116 141 94 100 123 Notes and Definitions for this Report:

EXTRACTED 02/08/99 DATE RUN 02/11/99 ANALYST JAT INSTRUMENT SATURN FILE ID 0206503W UNITS ug/L METHOD 8270 BDL BELOW DETECTION LIMIT Committed to Quality Since 1958 Davton, Ohio 45426 I11 Pnqt Mnin S#Ptr~

(937) 837-3744

I i:

se Ie jteN Facility name.

NPDES Permit number:

Outfal Number:

Donald C. Cook Nuclear Plant MI0005827 j 001 Addendum to NPDES Renewal Application Section III.B.10 Toxic Pollutant Reasonable Potential Effluent Data Sampling results indicate the presence of toxic pollutants in the Cook Nuclear Plant discharges as follows:

Strontium was detected in Outfall 001 (Unit 1 Non-Contact Cooling Water Discharge).

There are no plant processes that use strontium. Strontium is a trace element (21St among the elements in the earth's crust) usually associated with calcium and barium minerals in veins in limestone. The chief use of strontium is in fireworks, red signal flares, or on tracer bullets. Therefore, we do not believe that there is reasonable potential for strontium to be present in these discharges as a result of plant operations. We believe that strontium is present in the intake.

Michigan Department of Environmental Quality-Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Ouffall Information PLEASE TYPE OR PRINT FACILITY NAME NPDES PERMIT NUMBER OUTFALL NUMBER Donald C. Cook Nuclear Plant M10005827 001

9.

WATER TREATMENT ADDITIVES Water treatment additives include any material that is added to water used at the facility or to a wastewater generated by the facility to condition or treat the water.

Approvals of water treatment additives are authorized by the DEQ under separate correspondence The issuance of an NPDES permit does not constitute approval of the water treatment additives that are included in this application A. Are there water treatment additives in the discharge from this facility?

El No, proceed to item 4.

s Yes.

B. Have these water treatment additives been previously approved?

E No, continue with C. below.

[

Yes. Submit a list of the previously approved water treatment additives and the date they were approved. The information listed in C. 1-8 must be updated if it has changed since the previous approval.

C. Submit a list of water treatment additives that are or may be discharged from the facility. Applicants must submit the information listed below for each additive.

1.

The water treatment additive Matenal Safety Data Sheet 2

The proposed water treatment additive discharge concentration.

3 The discharge frequency (i.e, number of hours per day, week, etc) 4 The outfall the water treatment additive is to be discharged from

5.

The type of removal treatment, if any, that the water treatment additive receives pnor to discharge.

6 The water treatment additive function (i e., microbiocide, flocculant, etc )

7.

A 48-hour LC50 or EC50 for a North Amencan freshwater planktonic crustacean (either Cenodaphnia sp., Daphnia sp., or Simocephalus sp) 8 The results of a toxicity test for one other North American freshwater aquatic species (other than a planktonic crustacean) that meets a minimum requirement of Rule 323.1057(2)(a) of the Water Quality Standards. Examples of tests that would meet this requirement include a 96-hour LC50 for a rainbow trout, bluegill, or fathead minnow.

The required toxicity information (described in items 7 and 8 above) is currently available In the SWOD files for the water treatment additives listed on the DEQ's Internet page http:l/www.deq.state.mi.uslswq/gleas/docslwta)WTAlist.doc.

If you intend to use one of the water treatment additives on this list, only the information in items I through 6 above needs to be submitted to the SWQD.

Note: The availability of toxicity information for a water treatment additive does not constitute approval to discharge the water treatment additive

10.

WHOLE EFFLUENTTOXICITYTESTS Have any acute or chronic WET tests been conducted on any discharges or receiving water in relation to facility discharges within the last three years' If yes, identify the tests and summarize the results below unless the test has been submitted to the department in the last 5 years NO l

Michigan Department of Environmental Quality-Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information PLEASE TYPE OR PRINT FACILITY NAME NPDES or COC PERMIT NUMBER Outfall Number Donald C. Cook Nuclear Plant M10005827 001

9. WATER TREATMENT ADDITIVES Water Treatment Additive Approval Date Sodium Hypochlonte 5123/00 NPDES Permit approval 9/28/95 Betz CT-1300 Formerly called Betz CT-2 5123/00, 2128/02, 9/13/94, NPDES Permit approval 9128/95 Betz CT-4 5/23/00, NPDES Permit approval 9/28/95 Calgon H-130M 8/16195, 5/23/00 Calgon EVAC 8/8/00 Nalco Macrotrol 9380 8/16/95, 5/23/00, 2128102 Nalco Macrotrol 9210 8/16195, 5/23/00, 2/28/02 Nalco TRASAR 23299 5/23/00, 9/17/96 Fluorescein Dye 9/21/98 Bentonite Clay 5/23/2000, NPDES Permit approval 9/28/95 Betz Ferroquest FQ LP 7200 (Formerly Call Betz Depositrol 855D) 11/14/94, 5/23/00, 9/17/96, NPDES Permit approval 9/28/95 u-d.-'

Sodium Tetraborate (Borax) 5/23/00 SF6 (Sulphur hexafluonde gas)

NPDES Permit approval 9/28/95 Betz Corrshield NT 4205 (Formerly Powerline 3231) 6123/99, 9/17/96 Calgon LCS-60 6/23199, NPDES Permit approval 9/28/95 Betz Corrshield NT4201 5117/02 Betz Corrshield NT 2403 9/18/02 Spectrus NX 1105 (Formerly Betz Biotrol 107) 6/23/99, 5/23/00 Calgon H-300 6123/99, 5/23100 Betz AZ 8103 (Formerly Betz Copper-Trol Cul 12/18/95, 6123/99, 5/23/00 Betz 3610 6/23/99 Betz MD-4103 3/26/02 Nalco 22199 9/17/96 32 EQP 4659-C (Rev 1/03)

Section III.B Outfall 002

- X Michigan Department of Environmental Quality-Surface Water Quality Division DE-s WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater

-1B. Outfall Information

-mplete a separate Section III.B. - Outfall Information (pages 26-3 1) for each outfall at the facility. Make copies of this blank section Jf the application for additional outfalls as necessary.

PLEASE TYPE OR PRINT FACILITY NAME NPDES PERMIT NUMBER l OUTFALL NUMBER Donald C. Cook Nuclear Plant M10005827 l 002

1.

OUTFALL INFORMATION (see page 25 for instruction on completion of this page)

A.

Watershed Lower St Joseph Receiving Water Lake Michioan B.

C D.

E.

F.

J.

G.

H.

County Township Bemen Lake

/4, %l4 l

Section Town Range SW NW 06 l 06S 19W Latitude Longitude 41 58' 30" 86 34' 30" Type of Wastewater Discharged (Check all that apply to this outfall)

E] Contact Cooling

1 Sanitary Wastewater D Groundwater Cleanup A

Storm Water (regulated) 3 Noncontact Cooling ED Process Wastewater E] Hydrostatic Pressure Test El Storm Water (not regulated) 3 Storm water subject to effluent guidelines (indicate under which category) 423-Steam Electnc E Other-specify (see 'Table 8 - Other Common Types of Wastewater" in appendix)

What is the maximum Facility Design Flow Rate:

2074 MGD What is the maximum discharge flow authorized for this outfall:

Seasonal Dischargers MGY Continue with Item H.

Continuous Dischargers 1820

'MGD Continue with Item I Seasonal Discharge List the discharge periods (by month) and the volume discharged in the space provided below.

From Through Discharge Volume Annual Total From Through Discharge Volume From Through Discharge Volume From Through Discharge Volume Continuous Discharge How often is there a discharge from this outfall (on the average)?

24 Hours/Day 365 Days/Year Batch dischargers must provide the following additional Information:

Is there effluent flow equalization?

El Yes E1 No Batch Peak Flow Rate:

Number of batches discharged per day.

Minimum Average Maximum Batch Volume (gallons)

Batch Duration (minutes)

I

Michigan Department of Environmental Quality-Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information

--ASE TYPE OR PRINT 2.ILITY NAME NPDES PERMIT NUMBER OUTFALL NUMBER Donald C. Cook Nuclear Plant M10005827 002

2.

PROCESS STREAMS CONTRIBUTING TO OUTFALL DISCHARGE This information is used to determine the applicable federal regulations for this discharge. The information required to be reported is dependent on the type of facility. Page 7 of the appendix contains an abbreviated list of various industries and the types of information each shall report in this application For assistance call the Permits Section. All industries shall provide the name of each process and the SIC or the NAICS code for the process. If the wastestream is not regulated under federal categorical standards, the applicant shall report all pollutants which have the reasonable potential to be present in the discharge. To submit additional information see page ii, item 8.

PROCESS INFORMATION A Name of the process contributing to the discharge: 0OA B. SICorNAICS code: 4911 C Descnbe the process and provide measures of production (see the instructions to determine the appropriate information to be reported) Steam Generator Blowdown. 1 MGD maximum flow 2247 MWE total plant electrical generation PROCESS INFORMATION A. Name of the process contributing to the discharge: 00B B. SIC or NAICS code: 4911 C. Describe the process and provide measures of production (see the instructions to determine the appropriate information to be reported): Steam Generator Blowdown. 1 MGD maximum flow 2247 MWE total plant electrical generation.

PROCESS INFORMATION A. Name of the process contnbuting to the discharge: GOC B SIC orNAICS code: 4911 C. Describe the process and provide measures of production (see the instructions to determine the appropriate information to be reported) Plant heating boiler blowdown 0.043 MGD maximum flow. 2247 MWE total plant electical generation PROCESS INFORMATION A. Name of the process contributing to the discharge: OOG B. SIC or NAICS code: 4911 C. Descnbe the process and provide measures of production (see the instructions to determine the appropnate information to be reported): Reverse osmosis reject stream 0 366 MGD maximum flow. 2247 MWE total plant electrical generation PROCESS INFORMATION A. Name of the process contnbuting to the discharge. 0H B. SIC or NAICS code: 4911 C Describe the process and provide measures of production (see the instructions to determine the appropriate information to be reported).

Miscellaneous equipment drains and processes Maximum flow is 5 2 MGD. 2247 MWE total plant electrical generation. This Outfall is used for emergency purposes only.

Michigan Department of Environmental Quality-Surface Water Quality Division WASTEWATER DISCHARGE PERMIT-APPLICATION SECTION III - Industrial and Commercial Wastewater B Outfall Information

,-'EASE TYPE OR PRINT ACiLITY NAME NPDES PERMIT NUMBER OUTFALL NUMBER Donald C Cook Nuclear Plant M10005827 002

2.

PROCESS STREAMS CONTRIBUTING TO OUTFALL DISCHARGE This information is used to determine the applicable federal regulations for this discharge The information required to be reported is dependent on the type of facility. Page 7 of the appendix contains an abbreviated list of various industries and the types of information each shall report in this application For assistance call the Permits Section All industries shall provide the name of each process and the SIC or the NAICS code for the process If the wastestream is not regulated under federal categorical standards, the applicant shall report all pollutants which have the reasonable potential to be present in the discharge. To submit additional information see page il, item 8 PROCESS INFORMATION A. Name of the process contributing to the discharge Unit One Cooling Water B. SIC or NAICS code. 4911 C Describe the process and provide measures of production (see the instructions to determine the appropriate information to be reported) Once-through non-contact cooling, maximum flow is 1500 MGD, 2247 MWE total plant electncal.

PROCESS INFORMATION A

Name of the process contnbuting to the discharge. Unit Two Cooling Water B SIC or NAICS code. 4911 C Describe the process and provide measures of production (see the instructions to determine the appropriate information to be reported) Once through non-contact cooling, maximum flow is 1820 MGD, 2247 MWE total plant electrical.

PROCESS INFORMATION A. Name of the process contnbuting to the discharge Misc minor stormwater drains B. SICorNAICScode 4911 C Descnbe the process and provide measures of production (see the instructions to determine the appropriate information to be reported): Roof drains from the screenhouse roof, small roadway gratings above the forebay road.

PROCESS INFORMATION A. Name of the process contributing to the discharge B. SIC or NAICS code C Describe the process and provide measures of production (see the instructions to determine the appropriate information to be reported)

PROCESS INFORMATION A Name of the process contributing to the discharge:

B SICorNAICS code C. Describe the process and provide measures of production (see the instructions to determine the appropriate information to be reported)

I Michigan Department of Environmental Quality-Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information JSTRUCTIONS FOR COMPLETING SECTION III, ITEM B.3.

In accordance with 40 CFR 122.21, all applicants must report CBODs, Chemical Oxygen Demand, Total Organic Carbon, Total Suspended Solids, Ammonia as N, Temperature (both summer and winter), and pH. The applicant may, however, request that reporting of data for one or more of these required parameters be waived. Such request must be supported by adequate rationale. The request shall be included as an attachment to this application.

Report available discharge data for the parameters listed. Actual data shall be provided for existing discharges and expected or estimated data provided for proposed discharges.

Please include an explanation if 'Pollution Prevention" is expected to provide reduction of pollutants. See Page 8 of the appendix for a list of specific parameters for which data must be provided for specific types of discharges (e g., noncontact cooling waters, gasoline groundwater cleanups, etc.). For assistance in determining the appropriate parameters to report, call the Permits Section.

If data are available for other parameters not listed in Section 1ll.B 3., the applicant shall report these data in the blank spaces provided or attach the information to this application on 81/2" x 11" paper.

Report all data in the units provided and for the sample types specified in the table. If more than one option is available, check the appropriate box. The units are as follows: g/I = micrograms per liter, mg/I = milligrams per liter, OF = degrees Fahrenheit, 0C = degrees Celsius. See page ii number 5 for analytical requirements.

To analyze for pH, temperature, total residual chlorine, oil and grease, and fecal coliform use Grab Samples unless other frequency-sample type analyses are available. To analyze for total BOD5, total phosphorus, COD, TOC, ammonia nitrogen and total suspended solids use 24-hour composite samples unless other frequency-sample type analyses are available.

For two or more substantially identical outfalls, permission may be requested from the appropriate district office to sample and analyze oney--

one outfall and submit the results of the analysis for other substantially identical outfalls. If the request is granted by the distnct office, on a separate sheet attached to the application form, identify which outfall was sampled and describe why the outfalls which were not sampled are substantially identical to the outfall which was sampled.

See pages ii and iii for sampling definitions, including 'maximum daily concentration", and 'maximum monthly concentration".

REPORTING OF INTAKE DATA Applicants are required to report intake water data when they are attempting to demonstrate eligibility for "net" effluent limitations for one or more pollutants. A "net" effluent limitation is determined by subtracting the average level of the pollutant(s) present in the intake waters remaining after treatment which is not removed by the treatment system.

NPDES regulations allow net limitations only in certain circumstances (see 40 CFR Part 122 45(g)). To demonstrate eligibility, report the average concentration and/or mass of the results of the analyses on the intake water. If the intake water is treated pnor to use, report the intake concentrations and/or mass after treatment. In addition to the analytical results, the following information shall be submitted for each parameter:

a) A statement that the intake water is drawn from the body of water into which the discharge is made. If the discharge is not to the same body of water from which the water is withdrawn, the facility is not eligible for net limitations.

b) A statement of the extent to which the level of the pollutant in the intake water is reduced by treatment of the wastewater. Limitations for the net removal of pollutants are adjusted only to the extent that the pollutant is not removed.

c)

When applicable (for example, when the pollutant represents a class of compounds, e g., BOD5, TSS, etc.), a demonstration of the extent to which the pollutants in the intake vary physically, chemically and biologically from the pollutants contained in the discharge. Limitations are adjusted only to the extent that the concentrations of the intake pollutants vary from the discharged pollutants.

Note: Applicants for groundwater remediation discharges should also report the intake characteristics of contaminated groundwater.

NPIDES Permit MI0005827 K>.

TSiATE OF MICHIGAN a

JOHN ENGLER, Govemor DEPARTMENT OF ENVIRONMENTAL QUALITY

'Better Service for a Better Environments HOLLISTER BUILDING, PO BOX 30473, LANSING MI 48909-7973 REPLY TO PLAINWELL DISTRICT OFFICE 1342 SR 89 W STE B PLAINWEIL MI 49080-1915 INTERNET www deq state mi us RUSSELL J. HARDING, Director January 28, 1999 Mr. John P. Carlson Environmental Compliance Manager Cook Nuclear Plant One Cook Place Bridgman, Michigan 49106

SUBJECT:

Application for Renewal of NPDES PermitNo. MI0005827 We have reviewed the information provided in your letter of January 25, 1999. In that letter you request that representative outfalls be used to characterize effluent characteristics for similar outfalls. We approve your request as follows:

1. Effluent from Outfall 001 will be considered representative of outfalls 001, 002, and 003.

2. Effluent from Outfall 00B will be considered representative of outfalls OOA and 00B.

Please feel free to contact me if you have any questions.

Sincerely, Plainwell District Office Surface Water Quality Division 616-692-6968 cc: Mr. Blair Zordell, Cook Nuclear Plant Mr. Dan Dell, Permits Section, SWQD Ms. Sylvia Heaton, GLEAS, SWQD EOP 0100e (Rev 1198)

American Electric Power Cook Nuclear Plant One Cook Place Brdgman, MI 49106 616465 5901 AMERICAN ELECTRIC POWER Mr. Fred Morley Surface Water Quality Division Michigan Department of Environmental Quality 1342 SR89 West Suite B Plainwell, MI 49080 January 25, 1999

Subject:

NPDES Permit No. MI0005827 Application we are currently preparing the Wastewater Discharge Permit Application to renew our current NPDES operating permit.

As noted in Section III -

Industrial and Commercial Wastewater, Part B. Outfall Information Item 6, paragraph 5 contains instructions to request permission to use a single sample for similar outfalls for application purposes.

We request that Outfall 001 be used as a representative sample for Outfalls 002 (Unit Two Noncontact Cooling Water) and Outfall 003 (De-icing Mode) for application use only.

Outfalls 002 and

-_003 are substantially identical to Outfall 001. The source of these Outfalls is Lake Michigan; similar waste streams enter each Outfall prior to discharge.

In addition, we are requesting Outfall 0GB (Unit Two Steam Generator Blowdown) to be used as a representative sample for Outfall OA (Unit One Steam Generator Blowdown).

Outfall OA and Outfall OOB are substantially identical discharges, with the exception that Outfall OOA originates from the Unit One Steam Generators, and Outfall 0GB originates from the Unit Two Steam Generators.

If you have any questions, please contact me at (616) 465-5901, ext. 1153.

Sincerely, John P. Carlson Environmental Compliance Manager

/tlm c:

Greg Danneffel -

MDEQ Plainwell Sylvia Heaton -

MDEQ Lansing 1n.

A Page Two

)

Mr. Morley January 25, 1999 I certify under penalty of law that I have personally examined and am familiar with the information submitted on this and all attached documents, and based-on my inquiry of those individuals immediately responsible for obtaining the information, I believe the submitted information is true, accurate and complete.

I am aware that there are significant penalties for submitting false information, including the possibility of fine and imprisonment.

D. E. Cooper Plant Manager

I Michigan Department of Environmental Quality-Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information ZINT PLEASE TYPE OR PF

\\CILITY NAME Donald C Cook Nuclear Plant NPDES PERMIT NUMBER I M10005827 OUTFALL NUMBER I 002 K>,

3.

WASTEWATER CHARACTERISTICS - CONVENTIONAL POLLUTANTS - Instructions for completing this page are on the facing page.

3 Check this box if additional information is included as an attachment To submit additional information see page ii, item 8.

im-M aximnniM a

C, D 'ily4' AM enthly-a,Numer-;

Parameter ncnratit

Concentratinoi Unitsi Analyses S

p Type mg/l El Grab Biochemical Oxygen Demand - five day (BOD 5) 3 3

mg/2 24 Hr Comp mgA El Grab COD (Chemical oxygen demand) 6 6

mg/i

• 2 ED 24 Hr Comp El] Grab TOC (Total organic carbon) 4 5 4.5mg/i

• 2 1

24 Hr Comp Ammonia Nitrogen (as N)

<0 5

<0 5 2g/

24 HrComp Total Suspended Solids 8

8 2

24HraComp Total Dissolved Solids NA NA NA El 24HrComp Total Phosphorus (as P) 0 37 0 37 24 1

2HraComp maximum-7day Fecal Coliform Bactena (report geometnc means)

NA NA counts/lO0mi NA Grab El mg/I tal Residual Chlorine 200 169 El jg/i 212 Grab Dissolved Oxygen minimum daily NA mg/A NA F1 Grab I-M ')A W, r---

1-/

._~~L-

..,L -S noblp pH minimum maximum Grab (report maximum and minimum of individual samples) 7 9 8 5 standard units 96 El 24 Hr Comp

~OF El Grab Temperature, Summer 96 0 88 3 C °F 1 °c 176 24 Hr Comp m O-F r-,.

O Grab Temperature, Winter 65 3 58 9 170 E24 Hr Comp Oil & Grease

<5 mgA 2

Grab E Grab El 24 Hr Comp a

Grab See Attached for additional Data El1 24 Hr Comp El Grab El 24 Hr Comp El Grab El 24 Hr Comp El] Grab

• Water discharged from Outfall 002 El 24 Hr Comp El Grab is the same as Outfall 001 and 003 El 24 Hr Comp El Grab Permission has been granted to use the 24 Hr Comp ElGrab

.creening data from Outfall 001 to El 24 Hr Coin El Grab characterize this discharge.

El 24 Hr Co mp I2

Michigan Department of Environmental Quality-Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information K

.LEASE TYPE OR PRINT N.

.ACILITY NAME l NPDES PERMIT NUMBER OUTFALL NUMBER Donald C Cook Nuclear Plant M10005827 002

4.

PRIMARY INDUSTRY PRIORITY POLLUTANT INFORMATION Existing primary industnes that discharge process wastewater must submit the results of at least one effluent analysis for selected organic pollutants identified in Table 2 (as determined from Table 1, Testing Requirements for Organic Toxic Pollutants by Industrial Category), and all the pollutants identified in Table 3 Existing primary industries must also provide the results of at least one effluent analysis for any other chemical listed in Table 2 known or believed to be present in facility effluent.

In addition, submit the results of all other effluent analyses performed within the last 5 years for any chemical listed in Tables 2 and 3.

New primary industries that propose to discharge process wastewater must provide an estimated effluent concentration for any chemical listed in Tables 2 and 3 expected to be present in facility effluent 5

DIOXIN AND FURAN CONGENER INFORMATION Existing industnes that use or manufacture 2,3,5-trichlorophenoxy acetic acid (2,4,5-T), 2- (2,3,5-tnchlorophenoxy) propanoic acid, (Silvex, 2,3,5-TP); 2-(2,4,5-tnchlorophenoxy) ethyl 2,2-dichloropropionate (Erbon); 0,0-dimethyl 0-(2,4,5-tnchlorophenyl) phosphorothionate (Ronnel), 2,4,5-trichlorophenol (TCP) or hexachlorophrene (HCP), or knows or has reason to behiee that 2,3,7,8-Tetrachlorodibenzo-p-dioxin (TCDD) is present in facility effluent, must submit the results of at least one effluent analysis for the dioxin and furan congeners listed in Table 6 All effluent analyses for dioxin and furan congeners must be conducted using EPA Method 1613 In addition, submit the results of all other effluent analyses performed within the last 5 years for any dioxin and furan congener listed in Table 6.

New industries that expect to use or manufacture 2,3,5-trichlorophenoxy acetic acid (2,4,5-T), 2- (2,3,5-trichlorophenoxy) propanoic acid (Silvex, 2,3,5-TP), 2-(2,4,5-tnchlorophenoxy) ethyl 2,2-dichloropropionate (Erbon), 0,0-dimethyl 0-(2,4,5-trichlorophenyl) phosphorothionate (Ronnel), 2.4,5-tnchlorophenol (TCP) or hexachlorophrene (HCP), or knows or has reason to believe that 2,3,7,8-Tetrachlorodibenzo-p-dioxin (TCDD) is present in facility effluent must provide estimated effluent concentrations for the dioxin and furan congeners listed in Table 6 F;

OTHER INDUSTRY PRIORITY POLLUTANT INFORMATION Existing secondary industries, or existing pnmary industnes that discharge non-process wastewater, must submit the results of at least one effluent analysis for any chemical listed in Tables 2 and 3 known or believed to be present in facility effluent In addition, submit the results of all other effluent analyses performed within the last 5 years for any chemical listed in Tables 2 and 3 New secondary industnes, or new primary industries that propose to discharge non-process wastewater, must provide an estimated effluent

'concentration for any chemical listed in Tables 2 and 3 expected to be present in facility effluent.

7.

ADDITIONAL TOXIC AND OTHER POLLUTANT INFORMATION All existing industries, regardless of discharge type, must provide the results of at least one analyses for any chemical listed in Table 4 known or believed to be present in facility effluent, and a measured or estimated effluent concentration for any chemical listed in Table 5 known or believed to be present in facility effluent In addition, submit the results of any effluent analysis performed within the last 5 years for any chemical listed in Tables 4 and 5 New industnes, regardless of discharge type, must provide an estimated effluent concentration for any chemical listed in Tables 4 and 5 expected to be in facility effluent 8

INJURIOUS CHEMICALS NOT PREVIOUSLY REPORTED New or existing industries, regardless of discharge type, must provide a measured or estimated effluent concentration for any toxic or otherwise injunous chemicals known or believed to be present in facility effluent that have not been previously identified in this application Quantitative effluent data that are less than 5 years old for these chemicals must be reported NOTE: All effluent data submitted in response to questions 4, 5, 6, 7, and 8 above should be recorded on page 31 To submit additional information see page ii, item B. If the effluent concentrations are estimated, place an E in the 'Analytical Method' column. The following fields must be completed for each data row Parameter, CAS No, Concentration(s), Sample Type, Analytical Method. Quantification Level and Detection Level See page ii, number 5 for analytical test requirements

DE_

Michigan Department of En' imental Quality-Water Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information PLEASE TYPE OR PRINT FACILITY NAME NPDES PERMIT NUMBER OUTFALL NUMBER Donald C. Cook Nuclear Plant M10005827 002 SAMPLE DATE 4 1/8/01 7/17/01 8/7/01 8/14/01 9/4/01 9/18/01 10/9/01 10/23/01 11/6/01 1/22/02

.t CAS Conc.

.Conc<

Cone:.

Conc.o

.Cone.

Cono.'n Conc.>

c.

Cone.

Sample Analytic PARAMETER '

(ug/l)

(u l)'

(ug l i.(ug/1)

-(u

1)

(uig/l)

(ug/l)

(ug/l)

'i(ug/I)

(ug)

%Typei-Q' nal^'

O"

'DL Hyrazine 7803578

<10

<3

<3

<3

<3

<3

<3

<3

<3

<3 Grab D1385 3

10 Date 5/11/02 5/18/02 5/22/02 5/13/00 5/16/00 5/19/00 9/14/00 9/17/00 9/18/00 10/2/00 Boron 7440428 181 251 249 139 145 331 217 94 258 210 Grab 200.7 13.1 39.3 See Attached for additional data

(

(

5 EQP(

'-C (Rev 1/03)

C I

'I Section lll.B 6 and 7 Additional Sample Data Summary Sheet 002 For Outfall 002 Sample Max of Parameter 2/1199 3121102 5130/02 type Max Daily Analytical monthly Analyses See Attached data set from Belmonte Park Laboratories._____

Table

\\

I-.i Antimony (ug/f)

<1..

<1 Grab

<1 204 2/200 7

<1 2

Arsenic (ug/1)

<1..

2

<1 Grab 2

206 2/200 7 2

3 Beryllium (ug/1)

<1..

<0 2 Grab

<1 200 7

<1 2

Cadmium (ug/1)

<0 2*

<0 2 Grab

<02 213 2/200 7

<0 2 2

Chromium (ug/1)

<10..

3

<2 Grab 3

200 7 3

3 Copper (ug/1)

<1..

5 1

Grab 5

220.2/200.7 5

___3 Lead (ug/1)

<1..

2

<2 Grab 2

239 2/200 7 2

3 Nickel (ug/h)

<5..

<3 Grab

<5 249 2/200 7

<5 2

Total Phenols (ug/1)

<10" Grab

<10 420 1

-<10 1

Selenium (ug/1)

<1 Grab

<1 270 3

<1 1

Silver(ug/1)

<0 5"

<0 2 Grab

<0 5 272 2/200 7

<0 5-2 Thallium -(ug/1)

<1..

<1 Grab

<1 279 2

<1 2

Zinc (ug/1) 7

<4 Grab 7

200 7 7

2 Cyanide (mg/I)

<0 01**

<0 01 Grab

<0 01 335 2

<0 01 2

Mercury (ng/1)

I 7.36 1 1 Grab 7.36 1631 7 36 2

Table 4;- ~.9K~

.~

~~

~

A~.p Sulfate (mg/I)

<1

~23 Composite 23 375 4 23 2

Additional Data From Belmonte Park Laboratories Is attached See Attached Data set from Cook Nuclear Plant Laboratory Thble P27 7>--

p See Attached data set from Belmonte Park Laboratories._____

ISee Attached Data set from Cook Nuclear Plant Laboratory_____

I I I I I

I I

I I

I I

I I

I I

I I.

I 1-I I

I,

I

• • 001 used for 002

Section llI.B.6 Non-routine sample data 002 TRC From Table 4 USEPA Method 330.5 Outfall 002 Jan-01 Feb-01 Mar-01 Apr-01 May-01 Jun-01 Jul-01 Aug-01 Sep-01 Oct-01 Nov-01 Dec-01 Jan-02 Feb-02 Mar-02 Apr-02 May-02 Jun-02 Jul-02 Aug-02 Sep-02 Oct-02 Nov-02 1

97 53 10 9

3 119 1159 2

51 1

6 2

143 3

5 3

11l 141 4

48 81 120 2

1

_.123 2

184 176 5 52 108 4

1 184 3

158 6

74 94 107 4

1 188 110

<1 165 7

35 67 3

1 144 172 8 46

=

81 69

=

6 1

=

=

165 162 9 44 6

1

___145 10 30 2

I 85

<1 24 11 34 85 152 2

1 138 4

157 130 12

=

16 80

=

166 1

2 67 29 167 13 15 82 200 66 2

=

3 34 14

__8 71 2

-_131 15 68 70 107 2

161 16 6

45 69 160 2

1 173 125 1

13 180 17 84 70 2

71

=

172

=

136 24 180 18 74 41 129 3

=

17 164 19 131 93 19 5

15 20 127 109 15 107 4

22 II 21 116 111 97 67 3

158 174 l 22 118 36 93 3

134 151 170 23

=

103 10 103 172 2

139 116 168 157 24 3

104 7

140 159 6

145 125 155 l_

l 25 1

103 95 12 144 99 7

93 170 26 5

48 117 7

188 27 2

52 99 148 8

179 28 3

92.

143 12

-180 165 154 29 5

88 111 5

158 l_

l 30 2

96 76 4

158 4

104 164 l

_l 31 101 66 41 4

170 176 l_l DAILYMAX 74 5

131 111 200 148 172 67 12 3

71 0

0 173 188 138 110 188 184 176 Monthlyavg 42 3

84 82 60 98 132 26 4

2 36 0

0 156 169 117 45 71 153 161 Number of analyses 210 Daily Max 200 ug/h Numberof<detvalues 2

MonthlyMax 169 ug/h Total 212

Belmonte Park Environmental.

W Laboratores AMERICAN ELECTRIC POWER (AEP) 1 COOK PLACE BRIDGMAN, MICHIGAN 49106f Attn: BLAIR ZORDELL Purchase Order: 4307976 Invoice Number:

Order #:

99-02-060 Date: 03/16/99 09:22 Work ID: OUTFALL 001 -

OOC Date Received:

02/02/99 Date Completed: 03/16/99 Client Code: AEP 4 ND= NONE DETECTED OHIO CERT.# 12345 SAMPLE IDENTIFICATION Sample Number 01 02 03 04 05 06 07 08 09 10 11 12 13 14 15 16 17 18 19 20 21 22 23 Sample Description OUTFALL OUTFALL OUTFALL OUTFALL OUTFALL OUTFALL OUTFALL OUTFALL OUTFALL OUTFALL OUTFALL OUTFALL OUTFALL OUTFALL OUTFALL OUTFALL OUTFALL OUTFALL OUTFALL OUTFALL OUTFALL OUTFALL OUTFALL 001 001 001 001 001 001 001 001 001 001 001 001 001 001 001 00G 00G 00G 00G 00G OG OG 00G 02/01/99 02/01/99 02/01/99 02/01/99 02/01/99 02/01/99 02/01/99 02/01/99 02/01/99 02/01/99 02/01/99 02/01/99 02/01/99 02/01/99 02/01/99 02/01/99 02/01/99 02/01/99 02/01/99 02/01/99 02/01/99 02/01/99 02/01/99 Sample Number 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 Sample Descrirption OUTFALL 00G OUTFALL 0OG OUTFALL 00G OUTFALL 0OG OUTFALL 0OG OUTFALL 0OG OUTFALL 0OG OUTFALL 00C OUTFALL OOC OUTFALL OOC OUTFALL OOC OUTFALL 0OC OUTFALL OOC OUTFALL OOC OUTFALL OOC OUTFALL OOC OUTFALL OOC OUTFALL OOC OUTFALL OOC OUTFALL 00C OUTFALL OOC OUTFALL 0OC 02/01/99 02/01/99 02/01/99 02/01/99 02/01/99 02/01/99 02/01/99 02/01/99 02/01/99 02/01/99 02/01/99 02/01/99 02/01/99 02/01/99 02/01/99 02/01/99 02/01/99 02/01/99 02/01/99 02/01/99 02/01/99 02/01/99

' 4 Committed to Quality Since 1958

d4 Belmonte Park Envronmental Laboratories i

Order # 99-02-060 03/16/99 09:22 Enclosed are results of specified samples submitted for analyses. If there are any questions, please contact Matt Lake.

Our Ohio EPA Certification numbers are 836 & 837.

Any result of "BDL" indicates "BELOW DETECTION LIMIT".

Page 2 922~ dJQQ

Certified By MATT LAKE Committed to Quality Since 1958

Belmonte Park

' -> 4 Environmental Laboratories Order # 99-02-060 03/16/99 09:22 Page 3 TEST RESULTS BY SAMPLE Sample: 01A.OUTFALL 001 Test Description 5day CBOD, EPA 405.1 SUSPENDED SOLIDS,EPA 160.2 Sample: 02A OUTFALL 001 02/01/99 Collected: 02/01/99 Category: AQUEOUS Result 3

BDL Detection Limit 2

5 Units mg/L mg/L Analyzed 02/08/99 02/11/99 By PT KC 02/01/99 Collected: 02/01/99 Category: AQUEOUS Test Description

COD, TOC, EPA 410.4 EPA 415.1 Result 6

4.5 Detection Limit 5

1 Units mg/L mg/L Analyzed 02/19/99 02/09/99 B~y LG JW Sample: 03A OUTFALL 001 Test Description AMMONIA N, EPA 350.2 Sample: 05A OUTFALL 001 Test Description EPA 625 SEMI VOL. EXTRACT EXTRACTION, EPA 608 Sample: 06A OUTFALL 001 02/01/99 Collected: 02/01/99 Result BDL Detection Limit 0.5 02/01/99 Collected: 02/01/99 Category: AQUEOUS Units Analyzed Bv mg/L 02/11/99 JB Category: AQUEOUS Units Analyzed By SD SD Category: AQUEOUS Detection Limit Result 02/01/99 Collected: 02/01/99 Test Description

ALUMINUM, ANTIMONY,

ARSENIC, BARIUM, BERYLLIUM,

BORON, CADMIUM,

CHROMIUM, COBALT,

COPPER, IRON,

LEAD, Gil

LITHIUM, EPA 200.7 EPA 204.2 EPA 206.2 EPA 200.7 EPA 200.7 EPA 200.7 EPA 213.2 EPA 200.7 EPA 200.7 EPA 220.2 EPA 200.7 EPA 239.2 EPA 200.7 Result 0.05 BDL BDL 0.021 BDL 0.07 BDL BDL BDL BDL BDL BDL 0.01 Detection Limit 0.05 0.001 0.001 0.005 0.001 0.05 0.0002 0.01 0.01 0.001 0.1 0.001 0.01 Units mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L Analyzed 02/12/99 03/05/99 03/05/99 02/11/99 02/11/99 02/12/99 03/08/99 02/11/99 02/11/99 03/08/99 02/11/99 03/05/99 02/12/ 99 BY RJE RJE RJE RJE RJE RJE RJE RJE RJE RJE RJE RJE RJE Committed to Quality Since 1958

.i a w Belmonte Park

.6~

Environmental Laboratories Order # 99-02-060 03/16/99 09:22 Page 4 TEST RESULTS BY SAMPLE Test Description MAGNESIUM, EPA MANGANESE, EPA

MERCURY, EPA METALS DIGESTION, MOLYBDENUM, EPA

NICKEL, EPA

SELENIUM, EPA

SILVER, EPA STRONTIUM, EPA

THALLIUM, EPA URANIUM EPA

ZINC, EPA 200.7 200.7 245.1 WATER 200.7 249.2 200.7 272.2 200.7 279.2 200.7 200.7 Result 11 BDL BDL BDL BDL BDL BDL 0.12 BDL BDL BDL Detection Limit 1

0.01 0.0002 0.01 0.005 0.1 0.0005 0.01 0001 0.1 0.02 Units mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L Analvzed 02/12/99 02/11/99 02/11/99 02/11/99 03/08/99 02/11/99 03/08/99 02/12/99 03/05/99 02/15/99 02/11/99 BR RJE RJE RJE EP RJE RJE RJE R J E RJE RJE RJE RJE Sample: 07A OUTFALL 001 02/01/99 Collected: 02/01/99 Category: AQUEOUS Test Description

SULFIDE, TOTAL CYANIDE, EPA 376.1 EPA 335.2 Result BDL BDL Detection Limit 1

0.01 Units mg/L mg/L Analyzed 03/05/99 03/04/99 BL LG LG Sample: 08A OUTFALL 001 02/01/99 Collected: 02/01/99 Category: AQUEOUS Test Description PHENOLICS, Result BDL Detection Limit 0.01 Units Analyzed mg/L 02/23/99 BY JB EPA 420.1 Sample: 09A OUTFALL 001 Test Description CHLORINE, RESIDUAL TOTAL Sample: 10A OUTFALL 001 02/01/99 Collected: 02/01/99 Result BDL Detection Limit 0.05 Category: AQUEOUS Units Analyzed mg/L 02/03/99 Category: AQUEOUS By ML 02/01/99 Collected: 02/01/99 Test Description NITRATE-NITRITE N ORGANIC NITROGEN PHOSPHORUS, EPA 365.1

TKN, EPA 351.3 Result 0.38 BDL 0.37 3DL Detection Limit 0.2 0.5 0.1 0.5 Units mg/L mg/L mg/L mg/L Analyzed 02/05/99 02/11/99 02/18/99 02/06/99 BV LG J3 LG JB Committed to Quality Since 1958

-U 1' E Belmonte Park I.) x Environmental Laboratories Order # 99-02-060 03/16/99 09:22 Sample: 11A OUTFALL OC Page 5 TEST RESULTS BY SAMPLE 11 02/01/99 Collected: 02/01/99 Category: AQUEOUS Test Description OIL & GREASE, Result BDL Detection Limit S

Units Analyzed By mg/L 02/10/99 PT EPA 413.1 Sample: 12A OUTFALL 001 02/01/99 Collected: 02/01/99 Category: AQUEOUS Test Description GROSS ALPHA, GROSS BETA,

RADIUM, RADIUM-226, IN IN IN IN WATER WATER WATER WATER Result EDL BDL BDL BDL Detection Limit 3

4 1

2.

Units pCi/L pCi/L pCi/L pCi/L Analyzed 03/08/99 03/08/99 03/10/99 03/10/99 BY SF SF SF SF Sample: 13A OUTFALL 001 02/01/99 Collected: 02/01/99 Category: AQUEOUS

, J Test Description METHYLENE BLUE ACTIVE SUB.

SULFATE, EPA 375.4

SULFITE, Result BDL BDL BDL Detection Limit 0.01 10 2

Units mg/L mg/L mg/L Analyzed 02/17/99 02/18/99 02/17/99 PLY ML JB ML Sample: 14A OUTFALL 001 02/01/99 Collected: 02/01/99 Category: AQUEOUS Test Description ASBESTOS WATER Result ND Detection Limit 0.2 Units Analyzed MF/L, >lOum 02/12/99 BY EM Sample: 16A OUTFALL OOG Test Description 5day CBOD, EPA 405.1 SUSPENDED SOLIDS,EPA 160.2 Sample: 17A OUTFALL OOG 02/01/99 Collected: 02/01/99 Category: AQUEOUS Result 4

BDL Detection Limit 2

5 Units mg/L mg/L Analyzed 02/08/99 02/11/99 Bly PT KC 02/01/99 Collected: 02/01/99 Category: AQUEOUS Test DescriPtion COD,-

TOC, EPA 410.4 EPA 415.1 Result BDL 2.1 Detection Limit 5

1 Units mg/L mg/L Analyzed 02/19/99 02/09/99 Ly LG jw Committed to Quality Since 1958

Belmonte Park s) J = Environmental Laboratories Order # 99-02-060 03/16/99 09:22 Page 6 TEST RESULTS BY SAMPLE Sample: 18A OUTFALL 00G 02/01/99 Collected: 02/01/99 Category: AQUEOUS Test Description AMMONIA N, Result BDL Detection Limit 0.5 Units Analyzed mg/L 02/11/99 BY JB EPA 350.2 Sample: 20A OUTFALL OOG Test Description EPA 625 SEMI VOL. EXTRACT EXTRACTION, EPA 608 Sample: 21A OUTFALL 00G 02/01/99 Collected: 02/01/99 Category: AQUEOUS Detection Limit Result Units Analyzed By SD SD 02/01/99 Collected: 02/01/99 Category: AQUEOUS Test Description

ALUMINUM, ANTIMONY,

ARSENIC, BARIUM, BERYLLIUM,

BORON, CADMIUM,

CHROMIUM, COBALT,

COPPER, IRON,

LEAD, LITHIUM, MAGNESIUM, MANGANESE,

MERCURY, METALS DIGESTION, MOLYBDENUM,

NICKEL, SELENIUM,

SILVER, STRONTIUM,

THALLIUM, URANIUM

ZINC, EPA EPA EPA EPA EPA EPA EPA EPA EPA EPA EPA EPA EPA EPA EPA EPA 200.7 204.2 206.2 200.7 200.7 200.7 213.2 200.7 200.7 220.2 200.7 239.2 200.7 200.7 200.7 245.1 WATER Result BDL BDL BDL 0.022 BDL 0.06 BDL BDL BDL BDL BDL BDL BDL 12 BDL BDL BDL BDL BDL BDL 0.14 BDL BDL BDL Detection Limit 0.05 0.001 0.001 0.005 0.001 0.05 0.0002 0.01 0.01 0.001 0.1 0.001 0.01 1

0.01 0.0002 0.01 0.005 0.1 0.0005 0.01 0.001 0.1 0.02 Units mg/L mg/L mg/L

. mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L Analyzed 02/12/99 03/05/99 03/05/99 02/11/99 02/11/99 02/12/99 03/08/99 02/11/99 02/11/99 03/08/99 02/11/99 03/05/99 02/12/99 02/12/99 02/11/99 02/11/99 02/11/99 03/08/99 02/11/99 03/08/99 02/12/99 03/05/99 02/15/99 02/11/99 Rs J RJE RJE RJE RJE RJE RJE RJE RJE RJE RJE RJE RJE RJE RJE RJE EP RJE RJE RJE RJE RJE RJE RJE RJE EPA 200.7 EPA 249.2 EPA 200.7 EPA 272.2 EPA 200.7 EPA 279.2 EPA 200.7 EPA 200.7 Committed to Qualily Since 1958

K>

-'m OR Belmonte Park Environmental Laboratores Order # 99-02-060 03/16/99 09:22 Page 7 TEST RESULTS BY SAMPLE Sample: 22A OUTFALL 0OG 02/01/99 Collected: 02/01/99 Category: AQUEOUS Test Description

SULFIDE, TOTAL CYANIDE, EPA 376.1 EPA 335.2 Result BDL BDL Detection Limit 1

0.01 Units mg/L mg/L Analyzed 03/05/99 03/15/99 Ly LG LG Sample: 23A OUTFALL OOG 02/01/99 Collected: 02/01/99 Category: AQUEOUS Test Description PHENOLICS, Result BDL Detection Limit 0.01 Units Analyzed mg/L 02/23/99 EB JB EPA 420.1 Sample: 24A OUTFALL COG Test Description CHLORINE, RESIDUAL TOTAL Sample: 25A OUTFALL OOG Result BDL 02/01/99 Collected: 02/01/99 Detection Limit 0.05 Category: AQUEOUS Units Analyzed mg/L 02/03/99 Category: AQUEOUS BY Ml, 02/01/99 Collected: 02/01/99 Test Description NITRATE-NITRITE N ORGANIC NITROGEN PHOSPHORUS, EPA 365.1 TKN; EPA 351.3 Result 0.50 BDL BDL BDL Detection Limit 0.2 0.5 0.1 0.5 Units mg/L mg/L mg/L mg/L Analyzed 02/05/99 02/11/99 02/18/99 02/06/99 By LG JB LG JB Sample: 26A OUTFALL OOG 02/01/99 Collected: 02/01/99 Category: AQUEOUS Test DescriPtion OIL & GREASE, Result BDL Detection Limit 5

Units Analyzed mg/L 02/10/99 PT EPA 413.1 Sample: 27A OUTFALL COG 02/01/99 Collected: 02/01/99 Category: AQUEOUS Test Description GROSS ALPHA, GROSS BETA,

RADIUM, RADIUM-226, IN IN IN WATER WATER WATER Result BDL BDL BDL BDL Detection Limit 3

4 1

1 Units pCi/L pCi/L pCi/L pCi/L Analyzed 03/08/99 03/08 /9 9 03/10/99 03/10/99 BS SF SF SF SF IN WATER Committed to Quality Since 1958

a I Belmonte Park I-t J Environmental Laboratories v>

Order # 99-02-060 03/16/99 09:22 Page 8 TEST RESULTS BY SAMPLE Sample: 28A OUTFALL OOG Test Description METHYLENE BLUE ACTIVE SUB.

SULFATE, EPA 375.4

SULFITE, Sample: 29A OUTFALL OOG 02/01/99 Collected: 02/01/99 Category: AQUEOUS Result BDL 113 BDL Detection Limit 0.01 10 2

Units mg/L mg/L mg/L Analyzed 02/17/99 02/18/99 02/17/99 ML JB ML 02/01/99 Collected: 02/01/99 Category: AQUEOUS Test Description ASBESTOS WATER Sample: 31A OUTFALL OOC Result ND Detection Limit 0.2 Units Analyzed MF/L,

>lOum 02/12/99 EM 02/01/99 Collected: 02/01/99 Category: AQUEOUS,

j Detection

^

Test Description 5day CBOD, EPA 405.1 SUSPENDED SOLIDS,EPA 160.2 Sample: 32A OUTFALL OOC Test Description

COD, EPA 410.4

TOC, EPA 415.1 Result Limit Units Analyzec 4

2 mg/L 02/08/95 BDL 5

mg/L 02/11/9S 02/01/99 Collected: 02/01/99 Category: AQUEOUS i-By PT KC Result BDL BDL Detection Limit 5

1 Units mg/L mg/L Analyzed 02/19/99 02/09/99 LG JW Sample: 33A OUTFALL OOC 02/01/99 Collected: 02/01/99 Category: AQUEOUS Test Description AMMONIA N, Result BDL Detection Limit 0.5 Units Analyzed mg/L 02/11/99 BY JB EPA 350.2 Sample: 35A OUTFALL O0C Test Description EPA 625 SEMI VOL. EXTRACT EXTRACTION, EPA 608 02/01/99 Collected: 02/01/99 Detection Limit Category: AQUEOUS Units Analyzed Result SD SD SD Committed to Quality Since 1958

1 l4 = Belmonte Park Environmental Laboratories Order X 99-02-060 03/16/99 09:22 Page 9 TEST RESULTS BY SAMPLE Sample: 36A OUTFALL OOC 02/01/99 Collected: 02/01/99 Category: AQUEOUS Test Description

ALUMINUM, ANTIMONY,

ARSENIC, BARIUM, BERYLLIUM,

BORON, CADMIUM,

CHROMIUM, COBALT,

COPPER, IRON,

LEAD, LITHIUM, MAGNESIUM, MANGANESE,

MERCURY, METALS DIGESTION, MOLYBDENUM,

NICKEL, SELENIUM,

SILVER, STRONTIUM,

THALLIUM, URANIUM

ZINC, EPA EPA EPA EPA EPA EPA EPA EPA EPA EPA EPA EPA EPA EPA EPA EPA EPA EPA EPA EPA EPA EPA EPA EPA 200.7 204.2 206.2 200.7 200.7 200.7 213.2 200.7 200.7 220.2 200.7 239.2 200.7 200.7 200.7 245.1 WATER 200.7 249.2 200.7 272.2 200.7 279.2 200.7 200.7 Result BDL 0.002 BDL BDL BDL BDL

• BDL BDL BDL 0.012 BDL BDL BDL BDL 0.01 BDL IBDL BDL BDL

BDL BDL BDL BDL BDL Detection Limit 0.05 0.001 0.001 0.005 0.001 0.05 0.0002 0.01 0.01 0.001 0.1 0.001 0.01 1

0.01 0.0002 Units mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L Analyzed 02/12/99 03/05/99 03/05/99 02/11/99 02/11/99 02/12/99 03/08/99 02/11/99 02/11/99 03/08/99 02/11/99 03/05/99 02/12/99 02/12/99 02/11/99 02/11/99 02/11/99 03/08/99 02/11/99 03/08/99 02/12/99 03/05/99 02/15/99 02/11/99 Bvr RJE RJE RJE RJE RJE RJE RJE RJE RJE RJE RJE RJE RJE RJE RJE RJE RJE RJE RJE RJE RJE RJE RJE RJE 0.01 0.005 0.1 0.0005 0.01 0.001 0.1 0.02 Sample: 37A OUTFALL 00C 02j01/99 Collected: 02/01/99 Category: AQUEOUS Test Description

SULFIDE, TOTAL CYANIDE, EPA 376.1 EPA 335.2 Result BDL BDL Detection -

Limit 1

0.01 Units mg/L mg/L Analyzed 03/05/99 03/04/99 BL LG LG Sample: 38A OUTFALL 00C 02/01/99 Collected: 02/01/99 Category: AQUEOUS Test Description PHENOLICS, Result BDL Detection Limit 0.01 Units mg/L Analvzed Bv 02/23/99 JB EPA 420.1 Committed to Quality Since 1958

.-g 1 Belmonte Park

,j L

Environmental Laboratores Order # 99-02-060 03/16/99 09:22 Page 10 TEST RESULTS BY SAMPLE Sample: 39A OUTFALL OOC 02/01/99 Collected: 02/01/99 Category: AQUEOUS Test Description CHLORINE, RESIDUAL TOTAL Sample: 40A OUTFALL OOC Result BDL Detection Limit 0.05 Units Analyzed mg/L 02/03/99 Category: AQUEOUS By ML 02/01/99 Collected: 02/01/99 Test Description NITRATE-NITRITE N ORGANIC NITROGEN PHOSPHORUS, EPA 365.1

TKN, EPA 351.3 Result BDL BDL BDL BDL Detection Limit 0.2 0.5 0.1 0.5 Units mg/L mg/L mg/L mg/L Analyzed 02/05/99 02/11/99 02/18/99 02/06/99 py LG LG JB Sample: 41A OUTFALL OOC 02/01/99 Collected: 02/01/99 2)

Test Description OIL & GREASE, Result BDL Detection Limit 5

Category: AQUEOUS Units Analyzed mg/L 02/10/99 Bv PT EPA 413.1 Sample: 42A OUTFALL OOC 02/01/99 Collected: 02/01/99 Category: AQUEOUS Test Description GROSS ALPHA, GROSS BETA,

RADIUM, RADIUM-226, IN WATER IN WATER IN WATER IN WATER Result BDL BDL BDL BDL Detection Limit 3

4 1

1 Units pCi/L pCi/L pCi/L pCi/L Analyzed 03/08/9 9 03/08/99 03/10/99 03/10/99 ay SF SF SF SF Sample: 43A OUTFALL 00C 02/01/99 Collected: 02/01/99 Category: AQUEOUS Test Description METHYLENE BLUE ACTIVE SUB.

SULFATE, EPA 375.4

SULFITE, Sample: 44A OUTFALL OOC Result BDL BDL BDL Detection-Limit 0.01 10 2

Units mg/L mg/L mg/L Analyzed 02/17/99 02/18/99 02/17/99 By ML JB ML 02/01/99 Collected: 02/01/99 Category: AQUEOUS Test Description ASBESTOS WATER Result ND Detection Limit 0.2 Units Analvzed MF/L, >lOum 02/12/98 Ev EM Committed to Quality Since 1958

'IN Belmonte Park

--)

Environmental Laboratores Order # 99-02-060 03/16/99 09:22

-Page 11 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL 001 Test

Description:

EPA 624 Collected: 02/01/99 02/01/99 Lab No: 04A Method: 624 Category: AQUEOUS Test Code: 624 X PARAMETER RESULT LIMIT ACROLEIN ACRYLONITRILE 2-CELOROETHYLVINYL ETHER BENZENE CARBON TETRACHLORIDE CHLOROBENZENE 1,2-DICHLOROETHANE 1,1,1-TRICHLOROETHANE 1,1-DICHLOROETHANE 1,1,2-TRICHLOROETHANE 1,1,2,2-TETRACHLOROETHANE CHLOROETHANE CHLOROFORM 1,1-DICHLOROETHYLENE 1,2-TRANS-DICHLOROETHYLENE 1,2-DICHLOROPROPANE CIS-1,3-DICHLOROPROPYLENE TRANS-1,3-DICHLOROPROPYLENE ETHYLBENZENE 1,2-DICHLOROBENZENE 1,3-DICKLOROBENZENE 1,4-DICHLOROBENZENE METHYLENE CHLORIDE CHLOROMETHANE BROMOMETHANE BROMOFORM DICXLOROBROMOMETHANE TRICHLOROFLUOROMETHANE CHLORODIBROMOMETHANE TETRACHLOROETHYLENE TOLUENE TRICHLOROETHENE VINYL CHLORIDE XYLENES BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL-BDL BDL BDL BDL BDL BDL BDL 20 20 20 2

2 2

2 2

2 2

2 10 2

2 2

2 2

2 2

2 2

2 10 10 2

2 2

2 2

2 2

2 10 10

,

-j SURROGATE D4-1,2 DICXLOROETHANE D8-TOLUENE

%RECOVERY 112 94 LIMITS 76 88 114 110 Committed to Quality Since 1958

I

.I a lbBelmonte Park 9j i Environmental SUP Laboratories Order X 99-02-060 03/16/99 09:22 Page 12 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL 001 Test

Description:

EPA 624 Collected: 02/01/99 02/01/99 Lab No: 04A Method: 624 Category: AQUEOUS Test Code: 624 X 4-BROMOFLUOROBENZENE 86 115 Notes and Definitions for this Report:

DATE RUN 02/09/99 ANALYST JMM INSTRUMENT GC/MS FILE ID 9020934 UNITS uw/L METHOD EPA 624 BDL BELOW DETECTION LIMIT Committed to Quality Since 1958

u s Belmonte Park

=

Environmental Laboratores Order # 99-02-060 03/16/99 09:22 Page 13 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL 001 02/01/99 Lab No: 05A Test

Description:

EPA 625 SEMI VOLATILES Method: 625 Collected: 02/01/99 Category: AQUEOUS Test Code: 625_AE PARAMETER RESULT LIMIT 2,4,6-TRICHLOROPHENOL 4-CHLORO-3-METHYLPHENOL 2-CHLOROPHENOL 2,4-DICHLOROPHENOL 2,4-DIMETHYLPHENOL 2-NITROPHENOL 4-NITROPHENOL 2,4-DINITROPHENOL 2-METHYL-4,6-DINITROPHENOL PENTACHLOROPHENOL PHENOL ACENAPHTHENE BENZIDENE 1,2,4-TRICHLOROBENZENE HEXACHLOROBENZENE HEXACHLOROETHANE BIS(2-CHLOROETHYL)ETHER 2-CHLORONAPHTHALENE 1,2-DICHLOROBENZENE 1,3-DICHLOROBENZENE 1,4-DICHLOROBENZENE 3,3-DICHLOROBENZIDINE 2,4-DINITROTOLUENE 2,6-DINITROTOLUENE FLUORANTHENE 4-CHLOROPHENYL PHENYL ETHER 4-BROMOPHENYL PHENYL ETHER BIS(2-CHLOROISOPROPYL)

ETHER BIS(2-CHLOROETHOXY)

METHANE HEXACHLOROBUTADIENE HEXACHLOROCYCLOPENTADIENE ISOPHORONE NAPHTHAIENE NITROBENZENE N-NITROSODIMETXYLAMINE N-NITROSODIPHENYLAMINE N-NITROSODI-N-PROPYLAMINE BIS(2-ETHYLHEXYL)PHTHALATE BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 10 10 10 10 10 10 50 50 50 50 10 10 50 10 10 10 10 10 10 10 10 20 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 4

Committed to Quality Since 1958

lb hBelmonte Park d t J

Environmental Laboratories Order # 99-02-060 03/16/99 09:22 Page 14 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL 001 02/01/99 Lab No: 05A Test

Description:

EPA 625 SEMI VOLATILES Method: 625 Collected: 02/01/99 Category: AQUEOUS Test Code: 625_AE BUTYL BENZYLPHTHALATE DI-N-BUTYL PHTHALATE DI-N-OCTYL PHTHALATE DIETHYL PHTHALATE DIMETHYL PHTHALATE BENZO(A)ANTHRACENE BENZO(A)PYRENE 3,4-BENZOFLUORANTHENE BENZO(K)FLUORANTHENE CHRYSENE ACENAPHTHYLENE ANTHRACENE BENZO(GHI)PERYLENE FLUORENE PHENANTHRENE DIBENZO(A,H)ANTHRACENE INDENO(1,2,3-CD)PYRENE PYRENE ETHANOL AMINE HYDRAZINE BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 10 10 10 10 10 10 10 10 10 10 10 10 50 10 10 50 so 10 100 200 SURROGATE NITROBENZENE-dS 2-FLUOROBIPHENYL p-TERPHENYL-d14 PHENOL-d6 2-FLUOROPHENOL 2,4,6-TRIBROMOPHENOL

%RECOVERY 85 72 95 46 74 50 LIMITS 35 43 33 10 21 10 114 116 141 94 100 123 Notes and Definitions for this Report:

EXTRACTED 02/07/99 DATE RUN 02/25/99 ANALYST TC INSTRUMENT GC/MS FILE ID S9022524 UNITS ug/L METHOD EPA 625 BDL BELOW DETECTION LIMIT 46 Committed to Quality Since 1958

C a b Belmonte Park

,> 1 Environmental P Laboratores Page 15 Order # 99-02-060 03/16/99 09:22 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL 001 02/01/99 Lab No: 05A Test

Description:

PCB/PESTICIDES EPA 608 Method: 608 Collected: 02/01/99 Category: AQUEOUS Test Code: 608 PARAMETER RESULT LIMIT I

. 14 ALDRIN ALPHA-BHC BETA-BHC DELTA-BHC GAMMA-BHC CHLORDANE 4,4-DDT 4,4-DDE 4,4-DDD DIELDRIN ALPHA ENDOSULFAN BETA ENDOSULFAN ENDOSULFAN SULFATE ENDRIN ENDRIN ALDEHYDE HEPTACHLOR HEPTACHLOR EPOXIDE PCB-1016 PCB-1221 PCB-1232 PCB-1242 PCB-1248 PCB-1254 PCB-1260 TOXAPHENE BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 0.010 0.010 0. 010 0.010 0.010 0.010 0.010

0. 010 0.010 0. 010 0.010 0. 010 0.10 0.010 0.020 0.030 0.10 0.10 0.20 0.10 0.10 0.10 0.10 0.10 0.20 SURROGATE DBC (SURROGATE,

% RECOVERY) 2,4,5,6-TCX{SURROGATE

% REC.)

%RECOVERY 90 93 LIMITS 70 70 130 130 Notes and Definitions for this Report:

EXTRACTED 02/06/99 DATE RUN 02/09/99 ANALYST JW INSTRUMENT GC FILE ID A020913 UNITS ug/L Committed to Qulilty Since 1958

a h Belmonte Park tA Environmental.

Laboratories Order # 99-02-060 03/16/99 09:22 Page 16 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL 001 02/01/99 Lab No: b5A Test

Description:

PCB/PESTICIDES EPA 608 Method: 608 Collected: 02/01/99 Category: AQUEOUS Test Code: 608 METHOD EPA 608 BDL BELOW DETECTION LIMIT Committed to Quality Since 1958

Belmonte Park Environmental Laboratories Order # 99-02-060 03/16/99 09:22 Page 17 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL 001 02/01/99 Lab No:

Test

Description:

Triaryl Phosphate Sub-Out Method:

Collected: 02/01/99 Category:

15A Special AQUEOUS Test Test Code: 8270_U PARAMETER TRIPHENYL PHOSPHATE ESTER TRICRESYL PHOSPHATE ESTER RESULT LIMIT BDL 5

BDL 5

SURROGATE NITROBENZENE-DS 2-FLUOROBIPHENYL p-TERPHENYL-dl4 PHENOL-d6 2-FLUOROPHENOL 2,4,6-TRIBROMOPHENOL

%RECOVERY 65 78 113 25 30 93 LIMITS 35 43 33 10 21 10 114 116 141 94 100 123

_
I'-I
j Notes and Definitions for this Report:

EXTRACTED 02/08/99 DATE RUN 02/11/99 ANALYST JAT INSTRUMENT SATURN FILE ID 0206501W UNITS us/L METHOD 8270 BDL BELOW DETECTION LIMIT Committed to Quality Since 1958

Ilk Belmonte Park A92 Environmental Laboratories Order # 99-02-060 03/16/99 09:22 Page 18 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL OOG Test

Description:

EPA 624 Collected: 02/01/99 02/01/99 Lab No: 19A Method: 624 Category: AQUEOUS Test Code: 624 X PARAMETER RESULT LIMIT 9

ACROLEIN ACRYLONITRILE 2-CHLOROETHYLVINYL ETHER BENZENE CARBON TETRACHLORIDE CHLOROBENZENE 1,2-DICHLOROETHANE 1,l, 1-TRICHLOROETHANE 1,1-DICHLOROETHANE 1,1,2-TRICHLOROETHANE 1,1,2,2-TETRACHLOROETHANE CHLOROETHANE CHLOROFORM.

1,1-DICHLOROETHYLENE 1,2-TRANS-DICHLOROETHYLENE 1,2-DICHLOROPROPANE CIS-1,3-DICHLOROPROPYLENE TRANS-1,3-DICHLOROPROPYLENE ETHYLBENZENE 1,2-DICHLOROBENZENE 1,3-DICHLOROBENZENE 1,4 -DICHLOROBENZENE METHYLENE CHLORIDE CHLOROMETHANE BROMOMETHANE BROMOFORM DICHLOROBROMOMETHANE TRICHLOROFLUOROMETHANE CHLORODIBROMOMETHANE TETRACHLOROETHYLENE TOLUENE TRICHLOROETHENE VINYL CHLORIDE XYLENES BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL

-BDL BDL BDL BDL-BDL BDL BDL BDL BDL BDL BDL 20 20 20 2

2 2

2 2

2 2

2 10 2

2 2

2 2

2 2

2 2

2 10 10 2

2 2

2 2

2 2

2 10 10 SURROGATE D4-1,2 DICHLOROETHANE D8-TOLUENE

%RECOVERY 113 92 LIMITS 76 8_

Ji 114 i10 Committed to Qulilty Since 1958

. ^

(R7)

PqA7_17AA

M1h Ad Belmonte Park Environmental Laboratories Page 19 -

Order # 99-02-060 03/16/99 09:22 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL OOG Test

Description:

EPA 624 Collected: 02/01/99 4-BROMOFLUOROBENZENE 02/01/99 -Lab No: 19A Method: 624 Category: AQUEOUS Test Code: 624 X 93 86 115 Notes and Definitions for this Report:

DATE RUN 02/09/99 ANALYST JMM INSTRUMENT GC/MS FILE ID 9020935 UNITS us/L METHOD EPA 624

• BDL BELOW DETECTION LIMIT Committed to Quality Since 1958

-, I I
- -.:I *, --

I I I-1

, 1,

,. " I I -

I Belmonte Park

9Environmental Laboratories Order # 99-02-060 03/16/99 09

22 Page 20 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL OOG 02/01/99 Lab No:

Test

Description:

EPA 625 SEMI VOLATILES Method:

Collected: 02/01/99 Category:

PARAMETER RESULT 20A 625 AQUEOUS Test Code: 625_AE LIMIT 2,4,6-TRICHLOROPHENOL 4-CHLORO-3-METHYLPHENOL 2-CHLOROPHENOL 2,4-DICHLOROPHENOL 2,4-DIMETHYLPHENOL 2-NITROPHENOL 4-NITROPHENOL 2,4-DINITROPHENOL 2-METHYL-4,6-DINITROPHENOL PENTACHLOROPHENOL PHENOL ACENAPHTHENE BENZIDENE 1,2,4-TRICHLOROBENZENE HEXACHLOROBENZENE HEXACHLOROETHANE BIS(2-CHLOROETHYL)ETHER 2-CHLORONAPHTHALENE 1,2-DICHLOROBENZENE 1,3-DICHLOROBENZENE 1,4-DICHLOROBENZENE 3,3-DICHLOROBENZIDINE 2,4-DINITROTOLUENE 2,6-DINITROTOLUENE FLUORSSNTHENE 4-CHLOROPHENYL PHENYL ETHER 4-BROMOPHENYL PHENYL ETHER BIS(2-CHLOROISOPROPYL)

ETHER BIS(2-CHLOROETHOXY)

METHANE HEXACHLOROBUTADIENE HEXACHLOROCYCLOPENTADIENE ISOPHORONE NAPHTHALENE NITROBENZENE N-NITROSODIMETHYLAMINE N-NITROSODIPHENYLAMINE N-NITROSODI-N-PROPYLAMINE BIS(2-ETHYLHEXYL)PHTHALATE BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL.

BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 10 10 10 10 10 10 50 50 50 50 10 10 50 10 10 10 10 10 10 10 10 20 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 Committed to Qualilty Since 1958

Belmonte Park

). -

Environmental.

11 1~Laboratories I

Page 21 Order # 99-02-060 03/16/99 09:22 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL OOG 02/01/99 Lab No: 20A Test

Description:

EPA 625 SEMI VOLATILES Method: 625 Collected: 02/01/99 Category: AQUEOUS Test Code: 625 AE BUTYL BENZYLPHTHALATE DI-N-BUTYL PHTHALATE DI-N-OCTYL PHTHALATE DIETHYL PHTHALATE DIMETHYL PHTHALATE BENZO(A)ANTHRACENE BENZO(A)PYRENE 3,4-BENZOFLUORANTHENE BENZO(K)FLUORANTHENE CHRYSENE ACENAPHTHYLENE ANTHRACENE BENZO(GHI)PERYLENE FLUORENE PHENANTHRENE DIBENZO(A,H)ANTHRACENE INDENO(1,2,3-CD)PYRENE PYRENE ETHANOL AMINE HYDRAZINE BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL-BDL BDL BDL BDL BDL BDL 10 10 10 10 10 10 10 10 10 10 10 10 50 10 10 50 50 10 100 200 w

SURROGATE NITROBENZENE-ds 2-FLUOROBIPHENYL p-TERPHENYL-d14 PHENOL-d6 2-FLUOROPHENOL 2,4,6-TRIBROMOPHENOL

%RECOVERY 64 65 77 35 33 65 LIMITS 35 43 33 10 21 10 114 116 141 94 100 123 Notes and Definitions for this Report:

EXTRACTED 02/07/99 DATE RUN 02/25/99 ANALYST TC INSTRUMENT GC/MS FILE ID S9022525 UNITS ua/L METHOD EPA 625 BDL BELOW DETECTION LIMIT Committed to Quality Since 1958 l

A r

^Zt roa7N R7-A7AA

I

-MD lBelmonte Park

).." Wft Environmental

,J.

a Laboratories Order # 99-02-060 03/16/99 09:22 Page 22 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL OOG 02/01/99 Lab No: 20A Test

Description:

PCB/PESTICIDES EPA 608 Method: 608 Collected: 02/01/99 Category: AQUEOUS Test Code: 608 PARAMETER RESULT LIMIT ALDRIN ALPHA-BHC BETA-BHC DELTA-BHC GAMMA-BHC CHLORDANE 4,4-DDT 4,4-DDE 4,4-DDD DIELDRIN ALPHA ENDOSULFAN BETA ENDOSULFAN ENDOSULFAN SULFATE ENDRIN ENDRIN ALDEHYDE HEPTACHLOR HEPTACHLOR EPOXIDE PCB-1016 PCB-1221 PCB-1232 PCB-1242 PCB-1248 PCB-1254 PCB-1260 TOXAPHENE BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL

0. 010 0.010 0. 010

0. 010

0. 010 0.010 0.010 0. 010 0. 010 0. 010 0.010

0. 010 0.10

70.010 0.020 0.030 0.10 0.10 0.20 0.10 0.10 0.10 0.10 0.10 0.20 SURROGATE DBC(SURROGATE, % RECOVERY) 2,4,5,6-TCX(SURROGATE W REC.)

%RECOVERY 89 94 LIMITS 70 70 130 130 Notes and Definitions for this Report:

EXTRACTED 02/06/99 DATE RUN 02/09/99 ANALYST JW INSTRUMENT GC FILE ID A020914 UNITS ua/L Committed to Quality Since 1958

%f-lV_ Ar Aflt (o'47e RA7-174A

X.

A Belmonte Park Environmental Laboratories i

Page 23 Order # 99-02-060 03/16/99 09:22 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL OOG 02/01/99 Lab No: 20A Test

Description:

PCB/PESTICIDES EPA 608 Method: 608 Collected: 02/01/99 Category: AQUEOUS Test Code:

608 METHOD EPA 608 BDL BELOW DETECTION LIMIT

)

Committed to Quality Since 1958 rrn*7 wa.7-17AA

I a I Belmonte Park

f t Environmental 4 A Laboratores Order # 99-02-060 03/16/99 09

22 Page 24 TEST RESULTS BY SAMPLE Sample

Description:

Test

Description:

Collected:

OUTFALL OOG 02/01/99 Lab No: 30A Triaryl Phosphate Sub-Out Method: Special Test Test 02/01/99

' Category: AQUEOUS Code: 8270 U PARAMETER TRIPHENYL PHOSPHATE ESTER TRICRESYL PHOSPHATE ESTER RESULT LIMIT BDL 5

BDL 5

SURROGATE NITROBENZENE-D5 2-FLUOROBIPHENYL p-TERPHENYL-dl4 PHENOL-dG 2-FLUOROPHENOL 2,4,6-TRIBROMOPHENOL

%RECOVERY LIMITS 60 35 78 43 115 33 28 10 35 21 85 10 114 116 141 94 100 123 Notes and Definitions for this Report:

EXTRACTED 02/08/99 DATE RUN 02/11/99 ANALYST JAT INSTRUMENT SATURN FILE ID 0206504W UNITS ua/L METHOD 8270 BDL BELOW DETECTION LIMIT Committed to Quality Since 1958

K>.-

Rh Belmonte Park

,'_m.3% Environmental Laboratories Page 25 Order # 99-02-060 03/16/99 09:22 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL DOC Test

Description:

EPA 624 collected: 02/01/99 02/01/99 Lab No: 34A Method: 624 Category: AQUEOUS Test Code: 624_X RESULT LIMIT PARAMETER 4

ACROLEIN ACRYLONITRILE 2-CHLOROETHYLVINYL ETHER BENZENE CARBON TETRACHLORIDE CHLOROBENZENE 1,2-DICHLOROESHANE 1,1,1-TRICHLOROETHANE 1,1-DICHLOROETHASE 1,1,2-TRICHLOROETHANE 1,1,2,2-TETRACHLOROESHANE CHLOROETHANE CHLOROFORM 1,1 -DICHLOROETHYLENE 1,2-TRANS-DICHLOROETHYLENE 1,2-DICHLOROPROPANE CIS-1,3-DICHLOROPROPYLENE TRANS-1,3-DICHLOROPROPYLENE ETHYLBENZENE 1,2-DICHLOROBENZENE 1,3-DICHLOROBENZENE 1,4-DICHLOROBENZENE METHYLENE CHLORIDE CHLOROMETHANE BROMOMETHANE BROMOFORM DICHLOROBROMOMETHANE TRICHLOROFLUOROMETHANE CHLORODIBROMOMETHANE TETRACHLOROETHYLENE TOLUENE TRICHLOROETHENE VINYL CHLORIDE XYLENES BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDh BDL BDL BDL BDL BDh BDI BDL BDI BDI BDI BDI BDI B D:

20 20 2

2 2

2 2

2 2

2 10 2

2 2

2 2

2 2

2 2

2 10 102 2

2 2

i2 L-2 L

2 2

10 L1 10 SURROGATE D4-1,2 DICHLOROETHANE DS-TOLUENE

%RECOVERY 114 94 LIMITS 76 88 114 110 Committed to Quality Since 1958

.I

• a hBelmonte Park Environmental Laboratories Order # 99-02-060 03/16/99 09:22 Page 26 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL OOC Test

Description:

EPA 624 Collected: 02/01/99 02/01/99 Lab No: 34A Method:'624 Category: AQUEOUS Test Code: 624 X 4-BROMOFLUOROBENZENE 93 86 115 Notes and Definitions for this Report:

DATE RUN 02/09/99 ANALYST JMM INSTRUMENT GC/MS FILE ID 9020936 UNITS uq/L METHOD EPA 624 BDL BELOW DETECTION LIMIT to Committed to Quality Since 1958

Belmonte Park

< uEnvironmental

.1 Laboratores Page 27 Order # 99-02-060 03/16/99 09:22 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL OOC Test

Description:

EPA 625 SEMI Collected: 02/01/99 02/01/99 Lab No: 35A VOLATILES Method: 625 Category: AQUEOUS Test Code: 625 AE PARAMETER RESULT LIMIT

\\1-111-I-,-

.-;j 2,4,6-TRICHLOROPHENOL 4-CHLORO-3-METHYLPHENOL 2-CHLOROPHENOL 2,4-DICHLOROPHENOL 2,4-DIMETHYLPHENOL 2-NITROPHENOL 4-NITROPHENOL 2,4-DINITROPHENOL 2-METHYL-4,6-DINITROPHENOL PENTACHLOROPHENOL PHENOL ACENAPETHENE BENZIDENE 1,2,4-TRICHLOROBENZENE HEXACHLOROBENZENE HEXACHLOROETHANE BIS(2-CHLOROETHYL)ETHER 2-CHLORONAPETHALENE 1,2-DICHLOROBENZENE 1,3-DICHLOROBENZENE 1,4-DICHLOROBENZENE 3,3-DICHLOROBENZIDINE 2,4-DINITROTOLUENE 2,6-DINITROTOLUENE FLUORANTHENE 4-CHLOROPHENYL PHENYL ETHER 4-BROMOPHENYL PHENYL ETHER BIS(2-CHLOROISOPROPYL)

ETHER BIS(2-CHLOROETHOXY)

METHANE HEXACHLOROBUTADIENE HEXACHLOROCYCLOPENTADIENE ISOPHORONE NAPHTHALENE NITROBENZENE N-NITROSODIMETHYLAMINE N-NITROSODIPHENYLAMINE N-NITROSODI-N-PROPYLAMINE BIS(2-ETHYLEEXYL)PHTHALATE BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDI BDI BDI BDI BDI BDI EDI 10 10 10 10 10 10 50 50 50 50 10 10 50 10 10 10 10 10 10 10 10 20 10 10 10 10 10 10 10 10 10 10 10 i

10 10 L

10 L -

10 L

10 Committed to Quality Since 1958

EBelmonte Park yl-.i %

^Environmental

.14 Laboratories Order # 99-02-060 03/16/99 09:22 Page 28 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL OOC 02/01/99 Test

Description:

EPA 625 SEMI VOLATILES Collected: 02/01/99 BUTYL BENZYLPHTHALATE DI-N-BUTYL PHTHALATE DI-N-OCTYL PHTHALATE DIETHYL PHTHALATE DIMETHYL PHTHALATE BENZO(A)ANTHRACENE BENZO(A)PYRENE 3,4-BENZOFLUORANTHENE BENZO(K)FLUORANTHENE CHRYSENE ACENAPHTHYLENE ANTHRACENE BENZO(GHI)PERYLENE FLUORENE PHENANTHRENE DIBENZO(A,H)ANTHRACENE INDENO(1,2,3-CD)PYRENE PYRENE ETHANOL AMINE HYDRAZINE Lab No: 35A Method: 625 Category: AQUEOUS BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL Test Code: 625_AE 10 10 10 10 10 10 10 10 10 10 10 10 so 10 10 50 10 100 200 SURROGATE NITROBENZENE-dS 2-FLUOROBIPHENYL p-TERPHENYL-d14 PHENOL-d6 2-FLUOROPHENOL 2,4,6-TRIBROMOPHENOL 6RECOVERY 77 66 82 62 71 66 LIMITS 35 43 33 10 21 10 114 116 141 94 100 123 Notes and Definitions for this Report:

EXTRACTED 02/07/99 DATE RUN 02/25/99 ANALYST TC INSTRUMENT GC/MS FILE ID S9022526 UNITS ug/L METHOD EPA 625 BDL BELOW DETECTION LIMIT Committed to Quality Since 1958

Belmonte Park t",.'.

i Environmental Laboratories Page 29 order # 99-02-060 03/16/99 09:22 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL 00C 02/01/99 Lab No: 35A Test

Description:

PCB/PESTICIDES EPA 608 Method: 608 Collected: 02/01/99 Category: AQUEOUS Test Code: 608 RESULT LIMIT PARAMETER ALDRIN ALPHA-BHC BETA-BHC DELTA-BHC GAMMA-BHC CELORDANE 4,4-DDT 4,4-DDE 4,4-DDD DIELDRIN ALPHA ENDOSULFAN BETA ENDOSULFAN ENDOSULFAN SULFATE ENDRIN ENDRIN ALDEHYDE HEPTACHLOR HEPTACHLOR EPOXIDE PCB-1016 PCB-1221 PCB-1232 PCB-1242 PCB-1248 PCB-1254 PCB-1260 TOXAPHENE BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL

• BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 0. 010 0. 010

0. 010 0. 010

0. 010 0. 010 0.010 0.010 0.010-0.010 0.010 0.010 0.10 0.010 0.020 0.030 0.10 0.10 0.20 0.10 0.10 0.10 0.10 0.10 0.20 SURROGATE DBC(SURROGATE, % RECOVERY) 2,4,5,6-TCX(SURROGATE % REC.)

%RECOVERY 93 92 LIMITS 70 70 130 130 Notes and Definitions for this Report:

EXTRACTED 02/06/99 DATE RUN 02/09/99 ANALYST JW INSTRUMENT GC FILE ID A0209915 UNITS ug/L Committed to Quality Since 1958

I

~-I XB Belmonte Park Environmental Laboratores K11 Order # 99-02-060 03/16/99 09:22 Page 30 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL OOC 02/01/99 Lab No: 35A Test

Description:

PCB/PESTICIDES EPA 608 Method: 608 Collected: 02/01/99 Category: AQUEOUS Test Code: 608 METHOD EPA 608 BDL BELOW DETECTION LIMIT Committed to Quality Since 1958

I a ID Belmonte Park W2%Environmental Laboratories Order # 99-02-060 03/16/99 09:22 Page 31 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL DOC 02/01/99 Lab No: 45A Test

Description:

Triaryl Phosphate Sub-Out Method: Special Test Test Collected: 02/01/99 Category: AQUEOUS Code: 8270 U PARAMETER TRIPHENYL PHOSPHATE ESTER TRICRESYL PHOSPHATE ESTER RESULT LIMIT BDL 5

BDL 5

SURROGATE NITROBENZENE-DS 2-FLUOROBIPHENYL p-TERPHENYL-d14 PHENOL-d6 2-FLUOROPHENOL 2,4,6-TRIBROMOPHENOL

%RECOVERY 63 70 100 25 38 83 LIMITS 35 43 33 10 21 10 114 116 141 94 100 123 Notes and Definitions for this Report:

EXTRACTED 02/08/99 DATE RUN 02/11/99 ANALYST JAT INSTRUMENT SATURN FILE ID 0206503W UNITS u.aL METHOD 8270 BDL BELOW DETECTION LIMIT 40 Committed to Quality Since 1958

7 Facility name:

NPDES Permit number:

Outfall Number Donald C. Cook Nuclear Plant MI0005827 001 Addendum to NPDES Renewal Application Section III.B.10 Toxic Pollutant Reasonable Potential Effluent Data Sampling results indicate the presence of toxic pollutants in the Cook Nuclear Plant discharges as follows:

Strontium was detected in Outfall 001 (Unit 1 Non-Contact Cooling Water Discharge).

There are no plant processes that use strontium. Strontium is a trace element (21s among the elements in the earth's crust) usually associated with calcium and barium minerals in veins in limestone. The chief use of strontium is in fireworks, red signal flares, or on tracer bullets. Therefore, we do not believe that there is reasonable potential for strontium to be present in these discharges as a result of plant operations. We believe that strontium is present in the intake.

Michigan Department of Environmental Quality-Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information PLEASE TYPE OR PRINT FACILITY NAME l NPDES PERMIT NUMBER l OUTFALL NUMBER Donald C Cook Nidear Plant M10005827 002

9.

WATER TREATMENT ADDITIVES Water treatment additives include any material that is added to water used at the facility or to a wastewater generated by the facility to condition or treat the water Approvals of water treatment additives are authorized by the DEQ under separate correspondence The issuance of an NPDES permit does not constitute approval of the water treatment additives that are included in this application.

A Are there water treatment additives in the discharge from this facility?

M No. proceed to item 4 El Yes.

B Have these water treatment additives been previously approved?

LI No, continue with C below EI Yes Submit a list of the previously approved water treatment additives and the date they were approved The information listed in C. 1-8 must be updated if it has changed since the previous approval C. Submit a list of water treatment additives that are or may be discharged from the facility Applicants must submit the information listed below for each additive

1.

The water treatment additive Material Safety Data Sheet

2.

The proposed water treatment additive discharge concentration.

3.

The discharge frequency (i.e, number of hours per day, week, etc.)

4.

The outfall the water treatment additive is to be discharged from 5

The type of removal treatment, if any, that the water treatment additive receives pnor to discharge.

6 The water treatment additive function (i e., microbiocide, flocculant, etc.)

7.

A 48-hour LC50 or EC50 for a North American freshwater planktonic crustacean (either Cenodaphnia sp, Daphnia sp, or Simocephalus sp.)

8 The results of a toxicity test for one other North Amencan freshwater aquatic species (other than a planktonic crustacean) that meets a minimum requirement of Rule 323 1057(2)(a) of the Water Quality Standards. Examples of tests that would meet this requirement include a 96-hour LC50 for a rainbow trout, bluegill, or fathead minnow The required toxicity information (described in items 7 and 8 above) is currently available in the SWQD files for the water treatment additives listed on the DEQs Internet page httpIltwww.deq state.mi.us/swqfgleas/docslwtaiNTAlist.doc If you intend to use one of the water treatment additives on this list, only the information in items 1 through 6 above needs to be submitted to the SWQD.

Note: The availability of toxicity information for a water treatment additive does not constitute approval to discharge the water treatment additive 10 WHOLE EFFLUENTTOXICITYTESTS Have any acute or chronic WET tests been conducted on any discharges or receiving water in relation to facility discharges within the last three years?

If yes, identify the tests and summarize the results below unless the test has been submitted to the department in the last 5 years.

I

Michigan Department of Environmental Quality-Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information PLEASE TYPE OR PRINT FACILITY NAME l NPDES or COC PERMIT NUMBER Ouffall Number Donald C. Cook Nuclear Plant M10005827 002 9 WATER TREATMENT ADDITIVES Water Treatment Additive Approval Date Sodium Hypochlonte 5/23/00 NPDES Permit approval 9/28/95 Betz CT-1300 Formerly called Betz CT-2 5/23/00, 2/28/02, 9113194, NPDES Permit approval 9/28/95 Betz CT-4 5/23/00, NPDES Permit approval 9/28/95 Calgon H-130M 8/16195, 5/23/00 Calgon EVAC 8/8/00 Nalco Macrotrol 9380 8/16/95, 5123/00, 2128/02 Nalco Macrotrol 9210 8/16/95, 5/23/00, 2/28/02 Nalco TRASAR 23299 5/23/00, 9/17/96 Fluorescein Dye 9/21/98 Bentonite Clay 5/23/2000, NPDES Permit approval 9/28/95 Betz Ferroquest FQ LP 7200 (Formerly Call Betz Depositrol 855D) 11/14/94, 5/23100, 9/17/96, NPDES Permit approval 9/28/95 Sodium Tetraborate (Borax) 5/23/00 SF6 (Sulphur hexafluonde gas)

NPDES Permit approval 9/28/95 Betz Corrshield NT 4205 (Formerly Powerfine 3231) 6/23/99, 9/17/96 Calgon LCS-60 6/23/99, NPDES Permit approval 9/28/95 Betz Corrshield NT4201 5/17/02 Betz Corrshield NT 2403 9/18/02 Spectrus NX 1105 (Formerly Betz Biotrol 107) 6123/99, 5/23/00 Calgon H-300 6/23/99. 5/23/00 Betz AZ 8103 (Formerly Betz Copper-Trol Cul 12/18/95, 6/23/99, 5/23/00 Betz 3610 6/23/99 Betz MD-4103 3/26/02 Nalco 22199 9/17/96 32 EQP 4659-C (Rev 1/03)

Section III.B Outfall 003

Michigan Department of Environmental Quality-Surface Water Quality Division DE' WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information omplete a separate Section III.B - Outfall Information (pages 26-31) for each outfall at the facility. Make copies of this blank section of the application for additional outfalls as necessary.

PLEASE TYPE OR PRINT

-I lU U-r I

MI ICRDZ FACILITY NAME NPDES PERMIT NUMBER UU r,-7LL 1JIVIL)"S Donald C Cook Nuclear Plant I M10005827 l 003 L-1.

OUTFALL INFORMATION (see page 25 for instruction on completion of this page)

Watershed A

Lower St. Joseph B.

Receiving Water Lake Michigan County Tov C

Bemen Lak D. %%

Section SW NW 06 Latitude Lon 41 58' 30" 86:

F.

Type of Wastewater Discharged (Check all that apply to this outfall)

D71 Contact Cooling E1 Sanitary Wastewater

[] Groundwater Cleanup

[

Noncontact Cooling 3 Process Wastewater LI Hydrostatic Pressure Test E Storm water subject to effluent guidelines (indicate under which category) 423-Steam Electric

[

Other - specify (see 'Table 8 - Other Common Types of Wastewater' in appendix) 3 Storm Water (regulated)

Ii Storm Water (not regulated)

J What is the maximum Facility Design Flow Rate.

2074 MGD G.

What is the maximum discharge flow authonzed for this outfall Seasonal Dischargers Continuous Dischargers :

H.

Seasonal Discharge List the discharge periods (by month) and the volume discharged in the space provided below From Through Discharge Volume From Through Discharge Volume From Through Discharge Volume From Through Discharge Volume MGY Continue with Item H.

MGD Continue with Item I I

Continuous Discharge How often is there a discharge from this outfall (on the average)?

24 Hours/Day 365 Days/Year Batch dischargers must provide the following additional information:

Is there effluent flow equalization?

LI Yes

[

No Batch Peak Flow Rate:

I Number of batches discharged per day:

Minimum Average Maximum Batch Volume (gallons)

Batch Duration (minutes)

I

Michigan Department of Environmental Quality-Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information

--ASE TYPE OR PRINT

-CILITY NAME NPDES PERMIT NUMBER OUTFALL NUMBER Donald C Cook Nuclear Plant M10005827 003

2.

PROCESS STREAMS CONTRIBUTING TO OUTFALL DISCHARGE This information is used to determine the applicable federal regulations for this discharge. The information required to be reported is dependent on the type of facility. Page 7 of the appendix contains an abbreviated list of vanous industries and the types of information each shall report in this application. For assistance call the Permits Section. All industries shall provide the name of each process and the SIC or the NAICS code for the process. If the wastestream is not regulated under federal categorical standards, the applicant shall report all pollutants which have the reasonable potential to be present in the discharge To submit additional information see page it, item 8.

PROCESS INFORMATION A. Name of the process contributing to the discharge-OA B. SIC or NAICS code. 4911 C Descnbe the process and provide measures of production (see the instructions to determine the appropriate information to be reported): Steam Generator Blowdown 1 MGD maximum flow 2247 MWE total plant electrical generation.

PROCESS INFORMATION A Name of the process contributing to the discharge. 00B B. SIC or NAICS code 4911 C. Descnbe the process and provide measures of production (see the Instructions to determine the appropriate information to be reported): Steam Generator Blowdown 1 MGD maximum flow 2247 MWE total plant electrical generation PROCESS INFORMATION A. Name of the process contributing to the discharge OOC B. SIC or NAICS code: 4911 C Describe the process and provide measures of production (see the instructions to determine the appropriate information to be reported): Plant heating boiler blowdown. 0 043 MGD maximum flow. 2247 MWE total plant electrical generation PROCESS INFORMATION A. Name of the process contributing to the discharge, OOG B. SIC or NAICS code: 4911 C Describe the process and provide measures of production (see the instructions to determine the appropriate information to be reported): Reverse osmosis reject stream 0.366 MGD maximum flow. 2247 MWE total plant electrical generation.

PROCESS INFORMATION A. Name of the process contributing to the discharge. OOH B. SIC or NAICS code: 4911 C. Describe the process and provide measures of production (see the instructions to determine the appropriate information to be reported):

Miscellaneous equipment drains and processes. Maximum flow is 5 2 MGD. 2247 MWE total plant electrical generation. This Outfall is used for emergency purposes only.

Michigan Department of Environmental Quality-Surface Water Quality Division WASTEWATER DISCHARGE PERMIT-APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information DLEASE TYPE OR PRINT ACILITY NAME NPDES PERMIT NUMBER OUTFALL NUMBER Donald C Cook Nuclear Plant lMI0005827 l 003

2.

PROCESS STREAMS CONTRIBUTING TO OUTFALL DISCHARGE This information is used to determine the applicable federal regulations for this discharge The information required to be reported is dependent on the type of facility. Page 7 of the appendix contains an abbreviated list of various industries and the types of information each shall report in this application For assistance call the Permits Section All industries shall provide the name of each process and the SIC or the NAICS code for the process. If the wastestream is not regulated under federal categorical standards, the applicant shall report all pollutants which have the reasonable potential to be present in the discharge. To submit additional information see page ii, item 8 PROCESS INFORMATION A Name of the process contnbuting to the discharge OA B SIC or NAICS code: 4911 C Descnbe the process and provide measures of production (see the instructions to determine the appropriate information to be reported) Once-through non-contact cooling, maximum flow is 1500 MGD, 2247 MWE total plant electncal.

PROCESS INFORMATION A Name of the process contributing to the discharge. Unit Two Cooling Water B. SICorNAICS code 4911 C. Descnbe the process and provide measures of production (see the instructions to determine the appropriate information to be reported) Once-through non-contact cooling, maximum flow is 1820 MGD, 2247 MWE total plant electrical PROCESS INFORMATION A

Name of the process contnbuting to the discharge Misc minor stormwater drains B. SIC or NAICS code: 4911 C. Describe the process and provide measures of production (see the instructions to determine the appropriate information to be reported) Roof drains from the screenhouse roof, small roadway gratings above the forebay road PROCESS INFORMATION A Name of the process contributing to the discharge Deicino B SICorNAICScode 4911 C. Describe the process and provide measures of production (see the instructions to determine the appropriate information to be reported) The flow for this outfall is not monitored separately from outfalls 001 and 002.

PROCESS INFORMATION A

Name of the process contributing to the discharge:

B. SIC or NAICS code-C. Describe the process and provide measures of production (see the instructions to determine the appropriate information to be reported)

I Michigan Department of Environmental Quality-Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information ASTRUCTIONS FOR COMPLETING SECTION III, ITEM B.3. -

In accordance with 40 CFR 122.21, all applicants must report CBOD5, Chemical Oxygen Demand, Total Organic Carbon, Total Suspended Solids, Ammonia as N, Temperature (both summer and winter), and pH. The applicant may, however, request that reporting of data for one or more of these required parameters be waived. Such request must be supported by adequate rationale. The request shall be included as an attachment to this application.

Report available discharge data for the parameters listed. Actual data shall be provided for existing discharges and expected or estimated data provided for proposed discharges.

Please include an explanation if 'Pollution Prevention" is expected to provide reduction of pollutants. See Page 8 of the appendix for a list of specific parameters for which data must be provided for specific types of discharges (e g, noncontact cooling waters, gasoline groundwater cleanups, etc ). For assistance in determining the appropriate parameters to report, call the Permits Section.

If data are available for other parameters not listed in Section III B 3, the applicant shall report these data in the blank spaces provided or attach the information to this application on 8"2' x 11" paper Report all data in the units provided and for the sample types specified in the table. If more than one option is available, check the appropnate box. The units are as follows: pg/l = micrograms per liter, mg/I = milligrams per liter, OF = degrees Fahrenheit, IC = degrees Celsius. See page ii number 5 for analytical requirements.

To analyze for pH, temperature, total residual chlorine, oil and grease, and fecal coliform use Grab Samples unless other frequency-sample type analyses are available. To analyze for total BOD 5, total phosphorus, COD, TOC, ammonia nitrogen and total suspended solids use 24-hour composite samples unless other frequency-sample type analyses are available.

For two or more substantially identical outfalls, permission may be requested from the appropriate distrnct office to sample and analyze onl-,/

one outfall and submit the results of the analysis for other substantially identical outfalls. If the request is granted by the district office, on a separate sheet attached to the application form, identify which outfall was sampled and descnbe why the outfalls which were not sampled are substantially identical to the outfall which was sampled.

See pages ii and iii for sampling definitions, including 'maximum daily concentration", and "maximum monthly concentration".

REPORTING OF INTAKE DATA Applicants are required to report intake water data when they are attempting to demonstrate eligibility for 'net' effluent limitations for one or more pollutants. A 'net" effluent limitation is determined by subtracting the average level of the pollutant(s) present in the intake waters remaining after treatment which is not removed by the treatment system.

NPDES regulations allow net limitations only in certain circumstances (see 40 CFR Part 122.45(g)). To demonstrate eligibility, report the average concentration and/or mass of the results of the analyses on the intake water. If the intake water is treated prior to use, report the intake concentrations and/or mass after treatment. In addition to the analytical results, the following information shall be submitted for each parameter:

a) A statement that the intake water is drawn from the body of water into which the discharge is made. If the discharge is not to the same body of water from which the water is withdrawn, the facility is not eligible for net limitations.

b) A statement of the extent to which the level of the pollutant in the intake water is reduced by treatment of the wastewater. Limitations for the net removal of pollutants are adjusted only to the extent that the pollutant is not removed.

c) When applicable (for example, when the pollutant represents a class of compounds, e.g., BOD 5, TSS, etc ), a demonstration of the extent to which the pollutants in the intake vary physically, chemically and biologically from the pollutants contained in the discharge. Limitations are adjusted only to the extent that the concentrations of the intake pollutants vary from the discharged pollutants.

Note: Applicants for groundwater remediation discharges should also report the intake characteristics of contaminated groundwater

NPDES Permit MI0005827 STATE OF MICHIGAN JOHN ENGLER, Governor REPLYTO DEPARTMENT OF ENVIRONMENTAL QUALITY PLAJNWELLDISTRICTOFFICE

'Better Service for a Better Environments PLAJNWEL MI 49080-1915 HOLLISTER BUILDING PO BOX 3D473. LANSING Ml 48909-7973 INTERNET www deq state mi us RUSSELL J. HARDING, Director January 28, 1999 Mr. John P. Carlson Environmental Compliance Manager Cook Nuclear Plant One Cook Place Bridgman, Michigan 49106

SUBJECT:

Application for Renewal of NPDES PermnitNo. M10005827 We have reviewed the information provided in your letter of January 25, 1999. In that letter you request that representative outfalls be used to characterize effluent characteristics for similar outfalls. We approve your request as follows:

1. Effluent from Outfall 001 will be considered representative of outfalls 001, 002, and 003.

2. Effluent fr6on Outfall OOB will be considered representative of outfalls 00A and OOB.

Please feel free to contact me if you have any questions.

Sincerely,

/

2 ~~aneffel Gregory.anfe Plainwell District Office Surface Water Quality Division 616-692-6968 cc: Mr..Bladr Zordell, Cook Nuclear Plant Mr. Dan Dell, Permits Section, SWQD Ms. Sylvia EIeaton, GLEAS, SWQD EOP 100e (Rev 1198)

American Electric Power Cook Nuclear Plant One Cook Place Bndgman,M149106 616 465 5901 AMERICAM ELECTRIC POWER Mr. Fred Morley Surface Water Quality Division Michigan Department of Environmental Quality 1342 SRO9 West Suite B -

Plainwell, MI 49080 January 25, 1999

Subject:

NPDES Permit No. M10005827 Application We are currently preparing the Wastewater Discharge Permit Application to renew our current NPDES operating permit.

As noted in Section III -

Industrial and Commercial Wastewater, Part B. Outfall Information Item 6, paragraph 5 contains instructions to request permission to use a single sample for similar outfalls for application purposes.

We request that Outfall 001 be used as a representative sample for Outfalls 002 (Unit Two Noncontact Cooling Water) and Outfall 003 (De-icing Mode) for application use only.

Outfalls 002 and 003 are substantially identical to Outfall 001. The source of these Outfalls is Lake Michigan; similar waste streams enter each Outfall prior to discharge.

In addition, we are requesting Outfall COB (Unit Two Steam Generator Blowdown) to be used as a representative sample for Outfall OA (Unit One Steam Generator Blowdown).

Outfall OA and Outfall GOB are substantially identical discharges, with the exception that Outfall OA originates from the Unit One Steam Generators, and Outfall COB originates from the Unit Two Steam Generators.

If you have any questions, please contact me at (616) 465-5901, ext. 1153.

Sincerely,

-John P. Carlson Environmental Compliance Manager

/tlm c:

Greg Danneffel -

MDEQ Plainwell Sylvia Heaton -

MDEQ Lansing

7'"';,

Page Two Mr. Morley January 25, 1999 I certify under penalty of law that I have personally examined and am familiar with the information submitted on this and all attached documents, and based on my inquiry of those individuals immediately responsible for obtaining the information, I believe the submitted information is true, accurate and complete.

I am aware that there are significant penalties for submitting false information, including the possibility of fine and imprisonment.

D. E. Cooper Plant Manager

Michigan Department of Environmental Quality-Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information R NT

'LEASE TYPE OR PF ACILITY NAME Donald C. Cook Nuclear Plant NPDES PERMIT NUMBER I M10005827 OUTFALL NUMBER I 003

3.

WASTEWATER CHARACTERISTICS - CONVENTIONAL POLLUTANTS - Instructions for completing this page are on the facing page.

E Check this box if additional information is included as an attachment. To submit additional information see page li, item 8.

ax imi m-4 I ximur.,.

Daly ~<~', Mothl

'1 Number of >

Parameter-Conentratioiin-Concentration',

Units-Analyses.

Sample Type mg Grab Biochemical Oxygen Demand - five day (BOD5) m El 24 Hr Comp mg/I El Grab COD (Chemical oxygen demand) m*El 24 Hr Comp mg/I El Grab TOC (Total organic carbon) 9/

E 24 Hr Camp mg/I 1-7 Grab Ammonia Nitrogen (as N).

El 24 Hr Comp mg/I El1 Grab Total Suspended Solids

• El 24 HraComp al Grab Total Dissolved Solids lmg/i 24 Hr Comp mg/l aI Grab Total Phosphorus (as P)

• El 24 Hr Comp maximum-7day Fecal Coliform Bacteria (report geometric means) counts100ml Grab EL mg/I

,tal Residual Chlorine El 1g/i*

Grab minimum daily mg/I 2 Grab Dissolved Oxygen El 24 Hr Comp pH minimum maximum El Grab (report maximum and minimum of individual samples) standard units El 24 Hr Comp a E F

-C E

Grab Temperature, Summer 24 Hr Comp D WF

-OC El Grab Temperature, Winter E 24 Hr Comp Oil & Grease mg/l Grab E

Grab El 24 Hr Camp E Grab El 24 Hr Comp El Grab

• Water discharged from Outfall 003 El 24 Hr Comp El Grab is the same as Outfall 001 and 002 El 24 Hr Comp El Grab Permission has been granted to use the El 24 Hr Comp E

Grab Screening data from Outfall 001 to El 24 Hr Comp E

Grab characterize this discharge.

El 24 Hr Comp E

Grab l

E24 Hr Com I/

j I

El Grab F 24 Hr Cimni I

I__

I1 1

1_

_I

Michigan Department of Environmental Quality-Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information

'LEASE TYPE OR PRINT ACILITY NAME NPDES PERMIT NUMBER OUTFALL NUMBER Donald C. Cook Nuclear Plant l M10005827 l 003

4.

PRIMARY INDUSTRY PRIORITY POLLUTANT INFORMATION Existing primary industries that discharge process wastewater must submit the results of at least one effluent analysis for selected organic pollutants identified in Table 2 (as determined from Table 1, Testing Requirements for Organic Toxic Pollutants by Industrial Category), and all the pollutants identified in Table 3. Existing pnmary industries must also provide the results of at least one effluent analysis for any other chemical listed in Table 2 known or believed to be present in facility effluent In addition, submit the results of all other effluent analyses performed within the last 5 years for any chemical listed in Tables 2 and 3 New primary industries that propose to discharge process wastewater must provide an estimated effluent concentration for any chemical listed in Tables 2 and 3 expected to be present in facility effluent.

5 DIOXIN AND FURAN CONGENER INFORMATION Existing industries that use or manufacture 2,3,5-trichlorophenoxy acetic acid (2,4,5-T); 2- (2,3,5-tnchlorophenoxy) propanoic acid, (Silvex, 2,3,5-TP), 2-(2,4,5-trichlorophenoxy) ethyl 2,2-dichloropropionate (Erbon), 0,0-dimethyl 0-(2,4,5-tnchlorophenyl) phosphorothionate (Ronnel); 2,4,5-tnchlorophenol (TCP) or hexachlorophrene (HCP), or knows or has reason to believe that 2,3,7,8-Tetrachlorodibenzo-p-dioxin (TCDD) is present in facility effluent, must submit the results of at least one effluent analysis for the dioxin and furan congeners listed in Table 6 All effluent analyses for dioxin and furan congeners must be conducted using EPA Method 1613 In addition, submit the results of all other effluent analyses performed within the last 5 years for any dioxin and furan congener listed in Table 6 New industnes that expect to use or manufacture 2,3,5-trichlorophenoxy acetic acid (2,4,5-T), 2- (2,3,5-trichlorophenoxy) propanoic acid (Silvex, 2,3,5-TP), 2-(2,4,5-tnchlorophenoxy) ethyl 2,2-dichloropropionate (Erbon), 0,0-dimethyl 0-(2,4,5-trichlorophenyl) phosphorothionate (Ronnel), 2,4,5-trichlorophenol (TCP) or hexachlorophrene (HCP), or knows or has reason to believe that 2,3,7,8-Tetrachlorodibenzo-p-dioxin (TCDD) is present in facility effluent must provide estimated effluent concentrations for the dioxin and furan congeners listed in Table 6.

9 OTHER INDUSTRY PRIORITY POLLUTANT INFORMATION Existing secondary industries, or existing primary industries that discharge non-process wastewater, must submit the results of at least one effluent analysis for any chemical listed in Tables 2 and 3 known or believed to be present in facility effluent In addition, submit the results of all other effluent analyses performed within the last 5 years for any chemical listed in Tables 2 and 3 New secondary industnes, or new pnmary industries that propose to discharge non-process wastewater, must provide an estimated effluent concentration for any chemical listed in Tables 2 and 3 expected to be present in facility effluent

7.

ADDITIONAL TOXIC AND OTHER POLLUTANT INFORMATION All existing industries, regardless of discharge type, must provide the results of at least one analyses for any chemical listed in Table 4 known or believed to be present in facility effluent, and a measured or estimated effluent concentration for any chemical listed in Table 5 known or believed to be present in facility effluent In addition, submit the results of any effluent analysis performed within the last 5 years for any chemical listed in Tables 4 and 5 New industries, regardless of discharge type, must provide an estimated effluent concentration for any chemical listed in Tables 4 and 5 expected to be in facility effluent 8

INJURIOUS CHEMICALS NOT PREVIOUSLY REPORTED New or existing industries, regardless of discharge type, must provide a measured or estimated effluent concentration for any toxic or otherwise injunous chemicals known or believed to be present in facility effluent that have not been previously identified in this application. Quantitative effluent data that are less than 5 years old for these chemicals must be reported.

NOTE: All effluent data submitted in response to questions 4, 5, 6, 7, and 8 above should be recorded on page 31. To submit additional information see page ii, item 8.. If the effluent concentrations are estimated, place an E in the 'Analytical Method' column The following fields must be completed for each data row: Parameter, CAS No, Concentration(s), Sample Type, Analytical Method, Quantification Level and Detection Level.

See page li, number 5 for analytical test requirements.

F-I Michigan Department of En\\

imental Quality-Water Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information PLEASE TYPE OR PRINT FACILITY NAME NPDES PERMIT NUMBER OUTFALL NUMBER Donald C. Cook Nuclear Plant M10005827 003 SAMPLE DATE 4 CAS%

Ca-Conc.

CConc.

.Conc

.Conc

. § Conc.

Conc.

Conc. m MConc. i Z Conc.,j' Sample Analytic PARAMETER No.

' -I(ug) i)

(ug/l)

(ug/

Ig)

'(ugIl)'

^(ugtl) i (f ug/I

-ug/l) e QL--"

DL-IO ugl t "(u/l Tye;<a

(

3(

EQP(

'-C (Rev 1/03)

Michigan Department of Environmental Quality-Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information PLEASE TYPE OR PRINT FACILITY NAME l NPDES PERMIT NUMBER OUTFALL NUMBER Donald C Cook Nuclear Plant l M10005827 003 9

WATER TREATMENT ADDITIVES Water treatment additives include any matenal that is added to water used at the facility or to a wastewater generated by the facility to condition or treat the water.

Approvals of water treatment additives are authonzed by the DEQ under separate correspondence. The issuance of an NPDES permit does not constitute approval of the water treatment additives that are included in this application A. Are there water treatment additives in the discharge from this facility?

Z No, proceed to item 4.

fl Yes B. Have these water treatment additives been previously approved?

1 No, continue with C below.

171 Yes Submit a list of the previously approved water treatment additives and the date they were approved. The information listed in C. 1-8 must be updated if it has changed since the previous approval.

C. Submit a list of water treatment additives that are or may be discharged from the facility Applicants must submit the information listed below for each additive

1.

The water treatment additive Material Safety Data Sheet

2.

The proposed water treatment additive discharge concentration

3.

The discharge frequency (i.e., number of hours per day, week, etc).

4.

The outfall the water treatment additive is to be discharged from.

5 The type of removal treatment, if any, that the water treatment additive receives prior to discharge.

6 The water treatment additive function (i e, microbiocide, flocculant, etc.)

7.

A 48-hour LC50 or EC50 for a North American freshwater planktonic crustacean (either Ceriodaphnia sp, Daphnia sp, or Simocephalus sp).

8 The results of a toxicity test for one other North American freshwater aquatic species (other than a planktonic crustacean) that meets a minimum requirement of Rule 323.1057(2)(a) of the Water Quality Standards Examples of tests that would meet this requirement include a 96-hour LC50 for a rainbow trout, bluegill, or fathead minnow.

The required toxicity information (descnbed in items 7 and 8 above) is currently available in the SWQD files for the water treatment additives listed on the DEQs Internet page http:llwww.deq state.mi.us/swqlgieas/docslwtalWTAlist.doc.

If you intend to use one of the water treatment additives on this list, only the information in items 1 through 6 above needs to be submitted to the SWQD-Note: The availability of toxicity information for a water treatment additive does not constitute approval to discharge the water treatment additive.

10.

WHOLE EFFLUENT TOXICITY TESTS Have any acute or chronic WET tests been conducted on any discharges or receiving water in relation to facility discharges within the last three years?

If yes, identify the tests and summanze the results below unless the test has been submitted to the department in the last 5 years

Michigan Department of Environmental Quality-Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information PLEASE TYPE OR PRINT FACILITY NAME NPDES or COC PERMIT NUMBER Ouffall Number Donald C. Cook Nuclear Plant M10005827 l

003

9. WATER TREATMENT ADDITIVES Water Treatment Additive Approval Date Sodium Hypochlonte 5/23/00 NPDES Permit approval 9/28/95 Betz CT-1300 Formerly called Betz CT-2 5/23/00, 2/28/02, 9/13/94, NPDES Permit approval 9/28195 Betz CT-4 5/23/00, NPDES Permit approval 9/28/95 Calgon H-130M 8/16/95. 5/23/00 Calgon EVAC 8/8/00 Nalco Macrotrol 9380 8/16/95, 5/23/00, 2/28/02 Nalco Macrotrol 9210 8/16/95, 5/23/00, 2/28/02 Nalco TRASAR 23299 5/23/00, 9/17/96 Fluorescein Dye 9/21/98 Bentonite Clay 5/23/2000, NPDES Permit approval 9/28/95 Betz Ferroquest FQ LP 7200 (Formerly Call Betk Depositrol 855D) 11/14/94, 5/23/00, 9/17/96, NPDES Permit approval 9/28/95 Sodium Tetraborate (Borax) 5/23/00 SF6 (Sulphur hexatluoride gas)

NPDES Permit approval 9/28/95 Betz Corrshield NT 4205 (Formerly Powerline 3231) 6/23/99, 9/17/96 I

Calgon LCS-60 6/23/99, NPDES Permit approval 9/28/95 Betz Corrshield NT4201 5/17/02 Betz Corrshield NT 2403 9/18/02 Spectrus NX 1105 (Formerly Betz Biotrol 107) 6/23/99, 5/23/00 Calgon H-300 6/23/99, 5/23/00 Betz AZ 8103 (Formerly Betz Copper-Trol Cu1 12/18/95, 6/23/99, 5/23/00 Betz 3610 6/23/99 Betz MD-4103 3/26/02 Nalco 22199 9/17/96 32 EQP 4659-C (Rev 1/03)