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* AnalytiKEM An American NuKEM Company 92 10020120 PDR ADOCK
* AnalytiKEM         An American NuKEM Company AnalytiKEM Inc.
* PDR p TEST REPORT NO. A28173 September 3, 1992 Prepared for:. PSE&G P.O. Bo:s: 236 Mail Code.N34 Hancocks Bridge, NJ 08038 Attention:
28 Springdale Road Cherry Hill. NJ 08003 6091751-1122 1-800-TRY-LAB1 Fax: 6091751-0824 TEST REPORT NO. A28173 September 3, 1992 Prepared for:.
James Sterner Project: Fuel Oil Spills, Crane & Filter Reviewed & Approved by: Name: Title: QA/QC Manager AnalytiKEM Inc. 28 Springdale Road Cherry Hill. NJ 08003 6091751-1122 1-800-TRY-LAB1 Fax: 6091751-0824 TABLE OF CONTENTS 4nal_ytikE\.1 Page I. Certification 1 II. Definition of Terms 2 III. Sample Designations 3 IV. Methodology 4 v. Analytical Results 5 -6 VI. Quality Control Data 7 -8
PSE&G P.O. Bo:s: 236 Mail Code.N34 Hancocks Bridge, NJ 08038 Attention:   James Sterner Project:   Fuel Oil Spills, Crane & Filter Reviewed &
.,, ' . Test Report Page l I. Certification AnalytiKEM, Inc. Current Certifications/Regulatory Approvals 4.na/ytikEH Tabulated below are the current laboratory certifications that are held by each AnalytiKEM Laboratory.
Approved by:
Analyses performed at multiple AnalytiKEM locations will be noted in the test report. Cherry Hill, NJ Rock Hill, SC Houston Analytical, TX State Cert # State Cert*# State Cert # !Arkansas
Name:
* s. Carolina 46067 N. Dakota R-006 Connecticut PH-'0715 N. Carolina 316 Oklahoma 8403 Florida 880985G New Jersey 79795 Texas Water Commission
Title:   QA/QC Manager 9210020120 9 ADOCK 0 5* PDR 2 866~ 72 PDR p
* Massachusetts NJ117 Louisiana 92-07 New Jersey 04012 s. Carolina 82011 New York 10815 N. Carolina 367 N. Carolina 258 Wisconsin 998010530 N. Dakota R-038 New Jersey 82869 Pennsylvania 68366 s. Carolina 94004 Tennessee 02908 Vermont
 
* Oklahoma 9107
TABLE OF CONTENTS 4nal_ytikE\.1 Page I. Certification                             1 II. Definition of Terms                       2 III. Sample Designations                       3 IV. Methodology                               4
* No certification numbers are issued for these states.
: v. Analytical Results                     5 - 6 VI. Quality Control Data                   7 - 8
..,.., ' . II. ---------------.
 
Test Report No. A 28173 Page 2 Definition of Terms 4..nalytik.EU D DI J MS/MSD NA ND NR NTU RPD RSD u ppb ppm ug/l ug/kg ug/kg dw CCC SPCC PQL B Definition*
.,,             Test Report  N~A 28173
Detected; result must be greater than zero. Deionized Water Compound was detected at levels below the practical quantitation limit. The level reported is approximate.
    ' .         Page l I. Certification                                               4.na/ytikEH AnalytiKEM, Inc.
Matrix Spike/Matrix Spike Duplicate.
Current Certifications/Regulatory Approvals Tabulated below are the current laboratory certifications that are held by each AnalytiKEM Laboratory. Analyses performed at multiple AnalytiKEM locations will be noted in the test report.
Analysis not applicable to the sample matrix. Not Detected Not Requested Nephelometric Turbidity Units Relative Percent Difference Relative Standard Deviation Compound was analyzed for but not detected.
Cherry Hill, NJ             Rock Hill, SC         Houston Analytical, TX State             Cert # State         Cert*# State           Cert #
The preceding number is the practical quantitation limit for the compound.
        !Arkansas
Parts-per-billion; may be converted to ppm by dividing by 1,000. Parts-per-million; may be converted to ppb by multiplying by 1,000. Micrograms of constituent per liter of sample; equivalent to parts-per-billion.
* s. Carolina   46067   N. Dakota       R-006 Connecticut         PH-'0715 N. Carolina   316     Oklahoma         8403 Florida             880985G New Jersey     79795   Texas Water Commission
Micrograms of constituent per kilogram of sample; equivalent to parts-per-billion.
* Massachusetts       NJ117                           Louisiana       92-07 New Jersey         04012                           s. Carolina     82011 New York           10815                           N. Carolina     367 N. Carolina         258                             Wisconsin       998010530 N. Dakota           R-038                           New Jersey       82869 Pennsylvania       68366
Micrograms of constituent per kilogram of sample reported on a dry weight basis. Calibration Check Compound; used to verify the precision of a GC/MS calibration curve. System Performance Check Compound; used to verify the correct operation of a GC/MS instrument.
: s. Carolina       94004 Tennessee         02908 Vermont
Practical Quantitation Limit; the minimum level at which compounds can be dependably quantitated.
* Oklahoma           9107
Analyte detected in associated blank as well as the sample. It indicates possible/probable blank contamination.
* No certification numbers are issued for these states.
Test Report No.
 
Page 3 e III. Sample Designations AnalytiKEM Designation A28173-l A28173-2 Client Designation HZS-92-08-01 HZS-92-08-02 Matrix Nonaqueous Nonaqueous 4nalytil\EH Date Sampled 8/11/92 8/11/92 Note: Samples will be held for 30 days beyond the test report date unless otherwise requested.
Test Report No. A28173 Page 2      ~
' . *-Test Report No. A 28173 Page 4 e IV. Methodology Polychlorinated Biphenyls
..,..,
.:\nd/ytil\E Method 3550, Sonication Extraction, Test Methods for Evaluating Solid Waste, Physical/Chemical Methods, SW846, Third Edition, USEPA, 1986, with all promulgated revisions.
      ' .
II. Definition of Terms                                         4..nalytik.EU Definition*
D            Detected; result must be greater than zero.
DI          Deionized Water J            Compound was detected at levels below the practical quantitation limit. The level reported is approximate.
MS/MSD      Matrix Spike/Matrix Spike Duplicate.
NA          Analysis not applicable to the sample matrix.
ND          Not Detected NR            Not Requested NTU          Nephelometric Turbidity Units RPD          Relative Percent Difference RSD          Relative Standard Deviation u            Compound was analyzed for but not detected. The preceding number is the practical quantitation limit for the compound.
ppb          Parts-per-billion; may be converted to ppm by dividing by 1,000.
ppm          Parts-per-million; may be converted to ppb by multiplying by 1,000.
ug/l        Micrograms of constituent per liter of sample; equivalent to parts-per-billion.
ug/kg        Micrograms of constituent per kilogram of sample; equivalent to parts-per-billion.
ug/kg dw    Micrograms of constituent per kilogram of sample reported on a dry weight basis.
CCC          Calibration Check Compound; used to verify the precision of a GC/MS calibration curve.
SPCC        System Performance Check Compound; used to verify the correct operation of a GC/MS instrument.
PQL          Practical Quantitation Limit; the minimum level at which compounds can be dependably quantitated.
B            Analyte detected in associated blank as well as the sample.
It indicates possible/probable blank contamination.
 
~*
Page 3      e Test Report No. A28~73 III. Sample Designations 4nalytil\EH AnalytiKEM           Client                                  Date Designation         Designation            Matrix            Sampled A28173-l             HZS-92-08-01           Nonaqueous        8/11/92 A28173-2            HZS-92-08-02           Nonaqueous       8/11/92 Note: Samples will be held for 30 days beyond the test report date unless otherwise requested.
 
e Test Report No. A28173 Page 4
  ' . IV. Methodology
*-                                                                      .:\nd/ytil\E ~1 Polychlorinated Biphenyls Method 3550, Sonication Extraction, Test Methods for Evaluating Solid Waste, Physical/Chemical Methods, SW846, Third Edition, USEPA, 1986, with all promulgated revisions.
Method 8080, Organochlorine Pesticides and PCBs, Test Methods for Evaluating Solid Waste Physical/Chemical Methods, SW846, Third Edition, USEPA, 1986, with all promulgated revisions.
Method 8080, Organochlorine Pesticides and PCBs, Test Methods for Evaluating Solid Waste Physical/Chemical Methods, SW846, Third Edition, USEPA, 1986, with all promulgated revisions.
General Chemistry Method 1010, Flashpoint (Pensky-Martens Closed-Cup Method for Determining Ignitability), Test Methods for Evaluating Solid Waste, Physical/Chemical Methods, SW846, Third Edition, USEPA, 1986, with all promulgated revisions.
General Chemistry Method 1010, Flashpoint (Pensky-Martens Closed-Cup Method for Determining Ignitability), Test Methods for Evaluating Solid Waste, Physical/Chemical Methods, SW846, Third Edition, USEPA, 1986, with all promulgated revisions.
Method 9045, Soil pH, Test Methods for Evaluating Solid Waste, Physical/Chemical Methods, SW846, Third Edition, USEPA, 1986, with all promulgated revisions.
Method 9045, Soil pH, Test Methods for Evaluating Solid Waste, Physical/Chemical Methods, SW846, Third Edition, USEPA, 1986, with all promulgated revisions.
Section 7.3.3.2, Test Method to Determine Hydrogen Cyanide Released from Wastes (Interim Guidance for Reactive Cyanide), Test Methods for Evaluating Solid Waste, Physical/Chemical Methods, SW846, Third Edition, USEPA, Revison 1 November 1990. Section 7.3.4.2, Test Method to Determine Hydrogen Sulfide Released from Wastes (Interim Guidance for Reactive Sulfide), Test Methods for Evaluating Solid Waste, Physical/Chemical Methods, SW846, Third Edition, USEPA, Revison 1 November 1990.
Section 7.3.3.2, Test Method to Determine Hydrogen Cyanide Released from Wastes (Interim Guidance for Reactive Cyanide), Test Methods for Evaluating Solid Waste, Physical/Chemical Methods, SW846, Third Edition, USEPA, Revison 1 November 1990.
r' I ' . Test Report No. A 28173 Page 5 e V. Analytical Results Polychlorinated Biphenyls Parameter Aroclor 1016 Aroclor 1221 Aroclor 1232 Aroclor 1242 Aroclor 1248 Aroclor 1254 Aroclor 1260 Units Method Blank 650 u 650 u 650 u 650 u 650 u 650 u 650 u (ug/kg) Sample Designation A28173-l HZS-92-08-01 650 u 650 u 650 u 650 u 650 u 650 u 650 u (ug/kg) A28173-2 HZS-92-08-02 650 u 650 u 650 u 650 u 650 u 650 u 650 u (ug/kg) Note: All compounds reported at levels exceeding the PQL have been confirmed by alternate column GC.
Section 7.3.4.2, Test Method to Determine Hydrogen Sulfide Released from Wastes (Interim Guidance for Reactive Sulfide), Test Methods for Evaluating Solid Waste, Physical/Chemical Methods, SW846, Third Edition, USEPA, Revison 1 November 1990.
... * <"' *
 
* Test Report A2a 173 Page 6 W V. Analytical Results (Cont'd) General Chemistry Parameter Flashpoint, closed cup, &deg;F pH, units Reactivity
r' I Page 5      e Test Report No. A28173
-Sulfide Reactivity
    ' . V. Analytical Results Polychlorinated Biphenyls Sample Designation Method      A28173-l      A28173-2 Parameter                     Blank      HZS-92-08-01  HZS-92-08-02 Aroclor 1016                   650 u         650 u         650 u Aroclor 1221                  650 u         650 u         650 u Aroclor 1232                  650 u         650 u         650 u Aroclor 1242                  650 u         650 u         650 u Aroclor 1248                  650 u         650 u         650 u Aroclor 1254                  650 u         650 u         650 u Aroclor 1260                  650 u         650 u         650 u Units                        (ug/kg)        (ug/kg)       (ug/kg)
-Cyanide Units
Note: All compounds reported at levels exceeding the PQL have been confirmed by alternate column GC.
* Duplicate analysis Method Blank 50,000 u 50,000 u (ug/kg) 4nalytik.E'H Sample Designation A28173-l A28173-2 HZS-92-08-01 HZS-92-08-02  
 
> 200 > 200 9.5 7.7 50,000 u 50,000 u* ' 50,000 u
Test Report ~ A2a 173
* 50,000 u 50,000 U* ' 50,000 u * (ug/kg) (ug/kg)
  ...           Page 6      W
... Test Report No. A 28173 Page 7 e , VI. Quality Control Data Polychlorinated Biphenyls Nonagueous Matrix Spike/Matrix Spike Duplicate Recovery Data Sample Spiked A28213-2  
*   <"' *
----4nalytik.E\.1 Control Limits Ainount Recovery Max. Parameter of Spike MS MSD RPD Recovery RPD Aroclor 1242 20 51 64 23 70-130 40 Aroclor 1242 ; 20 86 70-130 40 Units (ug) (%) (%) (%) (%) (%) ; Spike performed on DI Water. Recovery:
* V. Analytical Results (Cont'd) 4nalytik.E'H General Chemistry Sample Designation Method        A28173-l       A28173-2 Parameter                    Blank        HZS-92-08-01   HZS-92-08-02 Flashpoint, closed cup, &deg;F                  >     200       >   200 pH, units                                            9.5           7.7 Reactivity - Sulfide        50,000 u         50,000 u      50,000  u*'
out of outside control limits RPO:
50,000   u
out of outside control limits Test Report A 28173 Page 8 e VI. Quality Control Data (Cont'dl Polychlorinated Biphenyls Nonagueous Surrogate Recovery Data and Retention Time Shift Sample Designation Method Blank A28213-2 Spike A28213-2 Spike Dup. DI Water Spike A28173-1 A28173-2 Units Control Limits Dibutylchlorendate (2.0 ug Added) Retention Recovery Time Shift 97 1.0 74 0.03 73 0.7 77 1.0 102 0.7 96 0.7 (%) (%) 40-156 0-2 .\na/ytif...E,1 out of surrogate recoveries are outside control limits.}}
* Reactivity - Cyanide        50,000  u          50,000   u     50,000   U*'
50,000   u
* Units                        (ug/kg)            (ug/kg)       (ug/kg)
* Duplicate analysis
 
                                                                                    ----
                                                                                -~---
e Test Report No. A28173 Page 7
... , VI. Quality Control Data 4nalytik.E\.1 Polychlorinated Biphenyls Nonagueous Matrix Spike/Matrix Spike Duplicate Recovery Data Sample Spiked A28213-2 Control Limits Ainount   Recovery                 Max.
Parameter                 of Spike MS   MSD RPD   Recovery RPD Aroclor 1242                 20     51   64   23   70-130   40 Aroclor 1242 ;               20     86             70-130   40 Units                       (ug)   (%) (%)   (%)     (%)   (%)
          ; Spike performed on DI Water.
Recovery: ~-2~  out of ~-3~  outside control limits RPO:       ~-0~  out of ~-1~  outside control limits
 
Test Report Page 8     e
                ~o. A28173 VI. Quality Control Data (Cont'dl
                                                                  .\na/ytif...E,1 Polychlorinated Biphenyls Nonagueous Surrogate Recovery Data and Retention Time Shift Dibutylchlorendate (2.0 ug Added)
Sample                                        Retention Designation                      Recovery   Time Shift Method Blank                        97           1.0 A28213-2 Spike                      74           0.03 A28213-2 Spike Dup.                  73           0.7 DI Water Spike                      77           1.0 A28173-1                            102           0.7 A28173-2                            96           0.7 Units                              (%)         (%)
Control Limits                    40-156       0-2
    ~-0~  out of ~-6~  surrogate recoveries are outside control limits.}}

Revision as of 10:09, 21 October 2019

Test Rept A28173 for Project, Fuel Oil Spills,Crane & Filter.
ML18096B005
Person / Time
Site: Salem  PSEG icon.png
Issue date: 09/03/1992
From: Fioriglio C
ANALYTIKEM, INC. (FORMERLY S-R ANALYTICAL, INC.)
To:
Shared Package
ML18096B004 List:
References
A28173, NUDOCS 9210020128
Download: ML18096B005 (10)
v • d • e


Text

'-* ,- -,___ I

  • AnalytiKEM An American NuKEM Company AnalytiKEM Inc.

28 Springdale Road Cherry Hill. NJ 08003 6091751-1122 1-800-TRY-LAB1 Fax: 6091751-0824 TEST REPORT NO. A28173 September 3, 1992 Prepared for:.

PSE&G P.O. Bo:s: 236 Mail Code.N34 Hancocks Bridge, NJ 08038 Attention: James Sterner Project: Fuel Oil Spills, Crane & Filter Reviewed &

Approved by:

Name:

Title: QA/QC Manager 9210020120 9 ADOCK 0 5* PDR 2 866~ 72 PDR p

TABLE OF CONTENTS 4nal_ytikE\.1 Page I. Certification 1 II. Definition of Terms 2 III. Sample Designations 3 IV. Methodology 4

v. Analytical Results 5 - 6 VI. Quality Control Data 7 - 8

.,, Test Report N~A 28173

' . Page l I. Certification 4.na/ytikEH AnalytiKEM, Inc.

Current Certifications/Regulatory Approvals Tabulated below are the current laboratory certifications that are held by each AnalytiKEM Laboratory. Analyses performed at multiple AnalytiKEM locations will be noted in the test report.

Cherry Hill, NJ Rock Hill, SC Houston Analytical, TX State Cert # State Cert*# State Cert #

!Arkansas

s. Carolina 94004 Tennessee 02908 Vermont
  • No certification numbers are issued for these states.

Test Report No. A28173 Page 2 ~

..,..,

' .

II. Definition of Terms 4..nalytik.EU Definition*

D Detected; result must be greater than zero.

DI Deionized Water J Compound was detected at levels below the practical quantitation limit. The level reported is approximate.

MS/MSD Matrix Spike/Matrix Spike Duplicate.

NA Analysis not applicable to the sample matrix.

ND Not Detected NR Not Requested NTU Nephelometric Turbidity Units RPD Relative Percent Difference RSD Relative Standard Deviation u Compound was analyzed for but not detected. The preceding number is the practical quantitation limit for the compound.

ppb Parts-per-billion; may be converted to ppm by dividing by 1,000.

ppm Parts-per-million; may be converted to ppb by multiplying by 1,000.

ug/l Micrograms of constituent per liter of sample; equivalent to parts-per-billion.

ug/kg Micrograms of constituent per kilogram of sample; equivalent to parts-per-billion.

ug/kg dw Micrograms of constituent per kilogram of sample reported on a dry weight basis.

CCC Calibration Check Compound; used to verify the precision of a GC/MS calibration curve.

SPCC System Performance Check Compound; used to verify the correct operation of a GC/MS instrument.

PQL Practical Quantitation Limit; the minimum level at which compounds can be dependably quantitated.

B Analyte detected in associated blank as well as the sample.

It indicates possible/probable blank contamination.

~*

Page 3 e Test Report No. A28~73 III. Sample Designations 4nalytil\EH AnalytiKEM Client Date Designation Designation Matrix Sampled A28173-l HZS-92-08-01 Nonaqueous 8/11/92 A28173-2 HZS-92-08-02 Nonaqueous 8/11/92 Note: Samples will be held for 30 days beyond the test report date unless otherwise requested.

e Test Report No. A28173 Page 4

' . IV. Methodology

  • - .:\nd/ytil\E ~1 Polychlorinated Biphenyls Method 3550, Sonication Extraction, Test Methods for Evaluating Solid Waste, Physical/Chemical Methods, SW846, Third Edition, USEPA, 1986, with all promulgated revisions.

Method 8080, Organochlorine Pesticides and PCBs, Test Methods for Evaluating Solid Waste Physical/Chemical Methods, SW846, Third Edition, USEPA, 1986, with all promulgated revisions.

General Chemistry Method 1010, Flashpoint (Pensky-Martens Closed-Cup Method for Determining Ignitability), Test Methods for Evaluating Solid Waste, Physical/Chemical Methods, SW846, Third Edition, USEPA, 1986, with all promulgated revisions.

Method 9045, Soil pH, Test Methods for Evaluating Solid Waste, Physical/Chemical Methods, SW846, Third Edition, USEPA, 1986, with all promulgated revisions.

Section 7.3.3.2, Test Method to Determine Hydrogen Cyanide Released from Wastes (Interim Guidance for Reactive Cyanide), Test Methods for Evaluating Solid Waste, Physical/Chemical Methods, SW846, Third Edition, USEPA, Revison 1 November 1990.

Section 7.3.4.2, Test Method to Determine Hydrogen Sulfide Released from Wastes (Interim Guidance for Reactive Sulfide), Test Methods for Evaluating Solid Waste, Physical/Chemical Methods, SW846, Third Edition, USEPA, Revison 1 November 1990.

r' I Page 5 e Test Report No. A28173

' . V. Analytical Results Polychlorinated Biphenyls Sample Designation Method A28173-l A28173-2 Parameter Blank HZS-92-08-01 HZS-92-08-02 Aroclor 1016 650 u 650 u 650 u Aroclor 1221 650 u 650 u 650 u Aroclor 1232 650 u 650 u 650 u Aroclor 1242 650 u 650 u 650 u Aroclor 1248 650 u 650 u 650 u Aroclor 1254 650 u 650 u 650 u Aroclor 1260 650 u 650 u 650 u Units (ug/kg) (ug/kg) (ug/kg)

Note: All compounds reported at levels exceeding the PQL have been confirmed by alternate column GC.

Test Report ~ A2a 173

... Page 6 W

  • <"' *
  • V. Analytical Results (Cont'd) 4nalytik.E'H General Chemistry Sample Designation Method A28173-l A28173-2 Parameter Blank HZS-92-08-01 HZS-92-08-02 Flashpoint, closed cup, °F > 200 > 200 pH, units 9.5 7.7 Reactivity - Sulfide 50,000 u 50,000 u 50,000 u*'

50,000 u

  • Reactivity - Cyanide 50,000 u 50,000 u 50,000 U*'

50,000 u

  • Units (ug/kg) (ug/kg) (ug/kg)
  • Duplicate analysis

-~---

e Test Report No. A28173 Page 7

... , VI. Quality Control Data 4nalytik.E\.1 Polychlorinated Biphenyls Nonagueous Matrix Spike/Matrix Spike Duplicate Recovery Data Sample Spiked A28213-2 Control Limits Ainount Recovery Max.

Parameter of Spike MS MSD RPD Recovery RPD Aroclor 1242 20 51 64 23 70-130 40 Aroclor 1242  ; 20 86 70-130 40 Units (ug) (%) (%) (%) (%) (%)

Spike performed on DI Water.

Recovery: ~-2~ out of ~-3~ outside control limits RPO: ~-0~ out of ~-1~ outside control limits

Test Report Page 8 e

~o. A28173 VI. Quality Control Data (Cont'dl

.\na/ytif...E,1 Polychlorinated Biphenyls Nonagueous Surrogate Recovery Data and Retention Time Shift Dibutylchlorendate (2.0 ug Added)

Sample Retention Designation Recovery Time Shift Method Blank 97 1.0 A28213-2 Spike 74 0.03 A28213-2 Spike Dup. 73 0.7 DI Water Spike 77 1.0 A28173-1 102 0.7 A28173-2 96 0.7 Units (%) (%)

Control Limits40-156 0-2

~-0~ out of ~-6~ surrogate recoveries are outside control limits.

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