ML18096B005

Test Rept A28173 for Project, Fuel Oil Spills,Crane & Filter.

ML18096B005
Person / Time
Site:	Salem
Issue date:	09/03/1992
From:	Fioriglio C ANALYTIKEM, INC. (FORMERLY S-R ANALYTICAL, INC.)
To:
Shared Package
ML18096B004	List: A28173, Test Rept A28173 for Project, Fuel Oil Spills,Crane & Filter ML18096B003 ML18096B005 ML18096B008
References
A28173, NUDOCS 9210020128
Download: ML18096B005 (10)

Text

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• AnalytiKEM An American NuKEM Company AnalytiKEM Inc.

28 Springdale Road Cherry Hill. NJ 08003 6091751-1122 1-800-TRY-LAB1 Fax: 6091751-0824 TEST REPORT NO. A28173 September 3, 1992 Prepared for:.

PSE&G P.O. Bo:s: 236 Mail Code.N34 Hancocks Bridge, NJ 08038 Attention: James Sterner Project: Fuel Oil Spills, Crane & Filter Reviewed &

Approved by:

Name:

Title:

QA/QC Manager 9210020120 9 ADOCK 0 5* PDR 2 866~ 72 PDR p

TABLE OF CONTENTS 4nal_ytikE\.1 Page I. Certification 1 II. Definition of Terms 2 III. Sample Designations 3 IV. Methodology 4

v. Analytical Results 5 - 6 VI. Quality Control Data 7 - 8

.,, Test Report N~A 28173

' . Page l I. Certification 4.na/ytikEH AnalytiKEM, Inc.

Current Certifications/Regulatory Approvals Tabulated below are the current laboratory certifications that are held by each AnalytiKEM Laboratory. Analyses performed at multiple AnalytiKEM locations will be noted in the test report.

Cherry Hill, NJ Rock Hill, SC Houston Analytical, TX State Cert # State Cert*# State Cert #

!Arkansas

• s. Carolina 46067 N. Dakota R-006 Connecticut PH-'0715 N. Carolina 316 Oklahoma 8403 Florida 880985G New Jersey 79795 Texas Water Commission

• Massachusetts NJ117 Louisiana 92-07 New Jersey 04012 s. Carolina 82011 New York 10815 N. Carolina 367 N. Carolina 258 Wisconsin 998010530 N. Dakota R-038 New Jersey 82869 Pennsylvania 68366

s. Carolina 94004 Tennessee 02908 Vermont Oklahoma 9107

• No certification numbers are issued for these states.

Test Report No. A28173 Page 2 ~

II. Definition of Terms 4..nalytik.EU Definition*

D Detected; result must be greater than zero.

DI Deionized Water J Compound was detected at levels below the practical quantitation limit. The level reported is approximate.

MS/MSD Matrix Spike/Matrix Spike Duplicate.

NA Analysis not applicable to the sample matrix.

ND Not Detected NR Not Requested NTU Nephelometric Turbidity Units RPD Relative Percent Difference RSD Relative Standard Deviation u Compound was analyzed for but not detected. The preceding number is the practical quantitation limit for the compound.

ppb Parts-per-billion; may be converted to ppm by dividing by 1,000.

ppm Parts-per-million; may be converted to ppb by multiplying by 1,000.

ug/l Micrograms of constituent per liter of sample; equivalent to parts-per-billion.

ug/kg Micrograms of constituent per kilogram of sample; equivalent to parts-per-billion.

ug/kg dw Micrograms of constituent per kilogram of sample reported on a dry weight basis.

CCC Calibration Check Compound; used to verify the precision of a GC/MS calibration curve.

SPCC System Performance Check Compound; used to verify the correct operation of a GC/MS instrument.

PQL Practical Quantitation Limit; the minimum level at which compounds can be dependably quantitated.

B Analyte detected in associated blank as well as the sample.

It indicates possible/probable blank contamination.

~*

Page 3 e Test Report No. A28~73 III. Sample Designations 4nalytil\EH AnalytiKEM Client Date Designation Designation Matrix Sampled A28173-l HZS-92-08-01 Nonaqueous 8/11/92 A28173-2 HZS-92-08-02 Nonaqueous 8/11/92 Note: Samples will be held for 30 days beyond the test report date unless otherwise requested.

e Test Report No. A28173 Page 4

' . IV. Methodology

• - .:\nd/ytil\E ~1 Polychlorinated Biphenyls Method 3550, Sonication Extraction, Test Methods for Evaluating Solid Waste, Physical/Chemical Methods, SW846, Third Edition, USEPA, 1986, with all promulgated revisions.

Method 8080, Organochlorine Pesticides and PCBs, Test Methods for Evaluating Solid Waste Physical/Chemical Methods, SW846, Third Edition, USEPA, 1986, with all promulgated revisions.

General Chemistry Method 1010, Flashpoint (Pensky-Martens Closed-Cup Method for Determining Ignitability), Test Methods for Evaluating Solid Waste, Physical/Chemical Methods, SW846, Third Edition, USEPA, 1986, with all promulgated revisions.

Method 9045, Soil pH, Test Methods for Evaluating Solid Waste, Physical/Chemical Methods, SW846, Third Edition, USEPA, 1986, with all promulgated revisions.

Section 7.3.3.2, Test Method to Determine Hydrogen Cyanide Released from Wastes (Interim Guidance for Reactive Cyanide), Test Methods for Evaluating Solid Waste, Physical/Chemical Methods, SW846, Third Edition, USEPA, Revison 1 November 1990.

Section 7.3.4.2, Test Method to Determine Hydrogen Sulfide Released from Wastes (Interim Guidance for Reactive Sulfide), Test Methods for Evaluating Solid Waste, Physical/Chemical Methods, SW846, Third Edition, USEPA, Revison 1 November 1990.

r' I Page 5 e Test Report No. A28173

' . V. Analytical Results Polychlorinated Biphenyls Sample Designation Method A28173-l A28173-2 Parameter Blank HZS-92-08-01 HZS-92-08-02 Aroclor 1016 650 u 650 u 650 u Aroclor 1221 650 u 650 u 650 u Aroclor 1232 650 u 650 u 650 u Aroclor 1242 650 u 650 u 650 u Aroclor 1248 650 u 650 u 650 u Aroclor 1254 650 u 650 u 650 u Aroclor 1260 650 u 650 u 650 u Units (ug/kg) (ug/kg) (ug/kg)

Note: All compounds reported at levels exceeding the PQL have been confirmed by alternate column GC.

Test Report ~ A2a 173

... Page 6 W V. Analytical Results (Cont'd) 4nalytik.E'H General Chemistry Sample Designation Method A28173-l A28173-2 Parameter Blank HZS-92-08-01 HZS-92-08-02 Flashpoint, closed cup, °F > 200 > 200 pH, units 9.5 7.7 Reactivity - Sulfide 50,000 u 50,000 u 50,000 u*'

50,000 u

• Reactivity - Cyanide 50,000 u 50,000 u 50,000 U*'

50,000 u

• Units (ug/kg) (ug/kg) (ug/kg)

• Duplicate analysis

-~---

e Test Report No. A28173 Page 7

... , VI. Quality Control Data 4nalytik.E\.1 Polychlorinated Biphenyls Nonagueous Matrix Spike/Matrix Spike Duplicate Recovery Data Sample Spiked A28213-2 Control Limits Ainount Recovery Max.

Parameter of Spike MS MSD RPD Recovery RPD Aroclor 1242 20 51 64 23 70-130 40 Aroclor 1242  ; 20 86 70-130 40 Units (ug) (%) (%) (%) (%) (%)

Spike performed on DI Water.

Recovery: ~-2~ out of ~-3~ outside control limits RPO: ~-0~ out of ~-1~ outside control limits

Test Report Page 8 e

~o. A28173 VI. Quality Control Data (Cont'dl

.\na/ytif...E,1 Polychlorinated Biphenyls Nonagueous Surrogate Recovery Data and Retention Time Shift Dibutylchlorendate (2.0 ug Added)

Sample Retention Designation Recovery Time Shift Method Blank 97 1.0 A28213-2 Spike 74 0.03 A28213-2 Spike Dup. 73 0.7 DI Water Spike 77 1.0 A28173-1 102 0.7 A28173-2 96 0.7 Units (%) (%)

Control Limits40-156 0-2

~-0~ out of ~-6~ surrogate recoveries are outside control limits.