ML081570609

Notification of Application for Renewal of National Pollutant Discharge Elimination System Permit, M10005827

ML081570609
Person / Time
Site:	Cook
Issue date:	05/28/2008
From:	Peifer M Indiana Michigan Power Co
To:	Document Control Desk, Office of Nuclear Reactor Regulation
References
AEP:NRC:2401-19, FOIA/PA-2010-0209
Download: ML081570609 (169)

Text

Indiana Michigan Power Company INDIANA Nuclear Generation Group One Cook Place MICHIGAN Bridgman, Ml 49106 WijIER aep.com May 28, 2008 AEP:NRC:2401-19 Docket Nos.: 50-315 50-316 U. S. Nuclear Regulatory Commission ATTN: Document Control Desk Mail Stop O-P 1-17 Washington, D.C. 20555-0001 Donald C. Cook Nuclear Plant Units 1 and 2 NOTIFICATION OF APPLICATION FOR RENEWAL OF NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM PERMIT, M10005827 In a letter dated April 2, 2008, Indiana Michigan Power Company (I&M), the licensee for Donald C. Cook Nuclear Plant (CNP) Units 1 and 2, submitted an application for renewal of National Pollutant Discharge Elimination System (NPDES) permit number M10005827 to the Michigan Department of Environmental Quality (MDEQ). In addition, a supplement was required because I&M's contracted lab was unable to meet the required quantification levels for Silver, Selenium, and Arsenic for Outfall OOB.

The reanalysis of these parameters at the required quantification levels was transmitted to MDEQ in a letter dated May 27, 2008.

Section 3.2 of Part II of Appendix B of the Environmental Technical Specifications (ETS) for CNP requires that the Nuclear Regulatory Commission (NRC) be provided a copy of the application for renewal of the NPDES permit at the same time the application is submitted to the permitting agency.

A copy of the application for renewal of the NPDES Permit, as described above, was not previously provided to the NRC as required by ETS 3.2. Enclosure 1 to this letter provides a copy of that application as required by ETS 3.2. Enclosure 2 is the supplemental data that was transmitted to the MDEQ. The late transmittal of the application for renewal of CNP's NPDES Permit to the NRC has been entered into CNP's Corrective Action Program.

This letter contains no new commitments.

U. S. Nuclear Regulatory Commission AEP:NRC:2401-19 Page 2 Should you have any questions or concerns regarding this notification, please contact Mr. Jon H. Hamer, Environmental Manager, at (269) 465-5901, extension 2102.

Sincerely, Mark A. Peo Site Vice President JEN/rdw Enclosures c:

w/o enclosures J. L. Caldwell, NRC Region III K. D. Curry, AEP Ft. Wayne J. T. King, MPSC MDEQ - WHMD/RPS NRC Resident Inspector P. S. Tam, NRC Washington, DC

ENCLOSURE I TO AEP:NRC:2401-19 APPLICATION FOR RENEWAL OF NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM PERMIT

• INDIAtNA MI A

Indiana Michigan Power One Cook Place Bridgman, Ml 49105 A unit of American Electric Power IndianalMichiganPower.com April 2, 2008 CC 2008-245 Michigan Department of Environmental Quality Cashier's Office WB-NP2 5 th Floor South, Constitution Hall 525 West Allegan Lansing, M1 48933

Subject:

Cook Nuclear Plant NPDES Permit M10005827 Application

Dear Sir or Madam:

Indiana Michigan Power Company (I&M) is hereby submitting an Industrial and Commercial Wastewater Discharge Application for renewal of the Donald C. Cook Nuclear Plant National Pollutant Discharge Elimination System (NIPDES) Permit. The enclosed application is being submitted on or before April 4, 2008, as required by the current permit.

.By letter dated January 24, 2008 (enclosed), the Michigan Department of Environmental Quality (NMIl DEQ) notified I&M to reapply for NPDES Permit, MI0005827. This letter stated that the January 2008 revision of the permit application was required to be used and was available electronically on the internet. I&M obtained a copy of the application from the intemet in January 2008. A review of the completed application revealed that it contained an erroneous revision date in the footer of the application of 11/2007. In a telephone conversation on March 26,.2008, between I&M staff and MI DEQ staff, it was determined that the application dated November 2007 is the January 2008 revision and should be considered as such. MI DEQ staff indicated that since the initial internet posting of the January 2008 revision, typographical corrections have been made to the revision including the revision date in the footer of the document.

By letter dated February 21, 2007 (enclosed), I&M requested to use, in the permit application submittal, data from representative outfalls to. characterize effluent characteristics for similar outfalls. By letter dated February 12, 2008 (enclosed), MI DEQ granted permission of this request. The enclosed application permit reflects this allowance for the outfall data.

The NPDES Permit Application, General Provisions, step 5, discusses requirements for quantification levels of select parameters identified in the Appendix, Table 7. I&M's contracted lab was unable to meet the required quantification levels for Silver, Selenium, and Arsenic for Outfall OOB. In telephone

DEQ - Water Bureau CC 2008-245 Page 2 conversations in February between I&M staff and MI DEQ staff, lI\\

DEQ staff stated that completion of the application with the current analyzed values and/or a value of less than the quantification level achieved would be acceptable to consider the application complete. MI DEQ still requires these parameters to be analyzed at the required quantification levels and agreed to accept the analysis riesults for the application at a later date. I&M has re-sampled these parameters and will submit the analysis data, using the specified quantification levels, to MI DEQ by May 31, 2008.

By letter dated February 27, 2007'(enclosed), I&M notified MI DEQ that the signature authority for NPDES and groundwater related issues includes, Jon H. Harner, Environmental Manager.

In accordance with Michigan Act 451, please find an enclosed check for the Application Fee of $750.

Should ýou have any questions, please contact me at (269) 465-5901, extension 2102, orBlair Zordell at (269) 465-5901, extension 2006.

Sincerely, Jon H. Harner Environmental Manager HLE/rdw Enclosures c:

Mr. John Vollmer, MIDEQ - Kalamazoo, w/o enclosures

Z POWER Indiana Michigan Power Company Cook Nuclear Plant One Cook Place Bridgman, Ml 49106 Mr.. Greg Danneffel Michigan Department of Environmental Quality 7953 Adobe Road Kalamazoo, MI 49009-5026 February 27, 2007

Subject:

Signatory Authority Dear Mr.

Danneffel:

This letter identifies that Jon H.

Harner, Environmental Manager, has signatory authority for NPDES and groundwater related issues.

Signatory authority is based on job function as permitted by regulatory requirements.

The objective in establishing signatory authority by position was to identify a broad class of job families so that as process improvements are made, managers who are most familiar with the work will have the appropriate signatory authority to meet environmental regulatory requirements for permits, licenses and reports.

For Nuclear Generation Facilities:

l)the Manager of Site Operations (Plant Manager); 2)the.AEP Nuclear Generation Group Manager(Site Vice President); and 3) the AEP Manager of Environmental Services (Environmental Manager).

The persons holding all of the above named positions have the necessary responsibility and authority to ensure that accurate permit and license application and/orreport are prepared and appropriate corporate resources are dedicated to achieve compliance with the permits for their respective functional areas.

Sincerely, 31N.

Jensen Site Vice President c:

NDM (2007-191)

(h 4C

Indiana Michigan Power Company Cook Nuclear Plant MICHIGANOne Cook Place PO WER

. Bridgman, 1,l 49ID6 Mr.

Greg Danneffel Surface Water Quality Division Michigan Department of Environmental Quality 7953 Adobe Road Kalamazoo, MI 49009 February 21, 2007

Subject:

Donald C.

Cook Nuclear Plant NPDES Permit No.

MI0005827 We are currently preparing the Wastewater Discharge Permit Application to renew our current NPDES operating permit.

As noted in Section IIIB -

Industrial and Commercial. Wastewater, Part B. Outfall Information Item B.3, paragraph 5 contains instructions to request permission to use a single sample for similar outfalls.

We request that Outfall 001 be used as a representative sample for Outfalls 002 (Unit Two Noncontact Cooling Water) and Outfall 003 (De-icing Mode).

Outfalls 002 and 003 are identical to Outfall 001, the source of these Outfalls is Lake Michigan, similar waste streams enter each Outfall prior to discharge.

In addition, we are requesting Outfall 00B (Unit Two Steam Generator Blowdown) to be used as a representative sample for Outfall OOA (Unit One Steam Generator Blowdown),

and Outfall 00C (Plant Heating Boiler Blowdown).

Outfall OOA and Outfall 00B are identical discharges, with the exception that Outfall O0A originates from the Unit One Steam Generators, and Outfall 00B originates from the Unit Two Steam Generators.

Outfall OOC is boiler blowdown, the supply water is from the same source.

The treatment chemicals/ranges in the three systems are hydrazine/(0-400 ppm),

ethanolamine/(0-100 ppm),

carbohydrazide/(0-40 ppm).

The current auxiliary boiler on the site is undergoing repairs and will be unavailable for sampling in the upcoming year.

If you have any questions, please contact me at (269) 465-5901, ext. 1153.

Sincerely, J hn P.

Carlson nvironmental Manager c:

Jon Vollmer -

MDEQ Plainwell Sylvia Heaton -

MDEQ Lansing

Page Two Mr. Danneffel February 21, 2007 I certify under penalty of law that I have personally examined and am familiar with the information submitted on this and all attached documents, and based on my inquiry of those individuals immediately responsible for obtaining the information, I believe the submitted information is

true, accurate and complete.

I am aware that there are significant penalties for submitting false information, including the possibility of fine and imprisonment.

Environmental Manager

STATE 0OF NUCIMGAŽ DEPARTMENT OF ENVIRONMENTAL QUALITY LANSING JENNIFER M. GRANHOLM STEVEN E. CHESTER GOVERNOR DIRECTOR January 24, 2008 Indiana Michigan Power Company.

One Cook Place Bridgman, MI 49106

SUBJECT:

Notification to Reapply for National Pollutant Discharge Elimination System (NPDES) Permit, M10005827 Our records indicate that American Electric Power Company, Donald C. Cook Nuclear Plant was issued an NPDES discharge permit, Permit No. M10005827, on 9/24/2004, pursuant to Part 31, Water Resources Protection, of the Natural Resources and Environmental Protection Act, 1994 PA 451, as amended (Act 451). This authorization to discharge will expire on 10/1/2008.

In order to retain the authorization to discharge beyond the expiration date, Indiana Michigan Power Company shall submit the information and forms required by the Department of Environment Quality (DEQ) to the Water Bureau no later than 180 days prior to the expiration date noted above.

To fulfill the reapplication requirements, you need to complete a State of Michigan NPDES Permit Application form with a revision date of January 2008. The Application and Appendix may be downloaded from the internet at www.michigan.gov/deq. In the left column click on water, then surface water. In the right column, click on How to Apply for an NPDES Permit.

To access the documents, click on Permit Application-for Surface Water Discharge and/or Permit Application Appendix. If you do not have access to the internet, please contact the Permits Section at 517-241-1346, and an Application form and Appendik will be sent to you.

You must complete all the items on the form that are applicable to your discharge. An incomplete application does not fulfill the reapplication provisions of your permit.

Act 451 requires an Application fee when submitting an Application for reissuance of an NPDES permit. The fee for your facility is $750. This fee must accompany the Application in order for the DEQ to consider the Application complete. Please make sure that the facility's NPDES Permit number and the designation "WB-NP2" appear on the check.

Please complete the required forms and submit them to our office with the Application fee by April 4, 2008.

If you have any questions regarding this letter, please contact me at 517-335-4129.

Sincerely, Kevin Cook Permits Section Water Bureau cookk@michigan.gov CONSTITUTION HALL 525 WEST ALLEGAN STREET - RO. BOX 30273 - LANSING, MICHIGAN 48909-7773 www.mrrchigan.gowQ F17.) 24t-+200

NIFER M. GRANHOLM GOVERNOR STATE OF l~li-ncfGAN DEPARTMENT OF ENVIRONMENTAL QUALITY K-AL*MzZOO DisTicT OFFICE STEVEN E. CHESTER

. DIRECTOR February 12, 2008 Mr. Blaire Zordell Cook Nuclear Plant One Cook Plaza Bridgman, Michigan 49106

SUBJECT:

Application Renewal for NPDES Permit National Pollutant Discharge Elimination System (NPDES) No. M10005827 Designated Name: American Elec Power-Cook Pit, Berrien County We have reviewed the information provided in your letter of February 21, 2007. In that letter, you requested that the data from representative outfalls be used in the permit application submittal to characterize effluent characteristics for similar outfalls. We approve your request as follows:

1. Effluent from Outfall 001 will be considered representative of outfalls 001, 002, and 003.

2. Effluent from Outfall 00B will be considered representative of Outfalls 00A, 00B, and 00C.

Please feel free to contact me if you have any questions.

Sincere*y, 5ohn Vollmer Environmental Quality Analyst Kalamazoo District Office Field Operations Division Water Bureau 269-567-3576 jv/dms cc: Mr. Dan Dell, DEQ Mr. Michael Walterhouse, DEQ C-2:L) 7953 ADOBE ROAD - KALAMAZOO, MICHIGAN 49009-5026 www.michigan.go*V (269) 567-3500

Michigan Department of Environmental Quality-Water Bureau WASTEWATER DISCHARGE PERMIT APPLICATION SECTION I - General Information

-"tion I shall be completed by all permit applicants. Instructions

.ompleting Section I, Pages 1 and 2, are on Page 2 of the Appendix. To submit additional information, see Page ii, item 3.

Waiter Bureau Use On1 Cashier Use Ordy: 37000-40538-9412-4B1000.00 PLEASE TYPE OR PRINT 4;lNPDES PERMIT NUMBER I

Vii UUUD0/(

Applicant Name Indiana Michigan Power Company Address Address 2 or P.O. Box One Cook Place NA City State ZIP Code Bridgman MI 49106 Telephone (with area code)

FAX (with area code)

Applicant Web Address 1i (269) 465-5901 (269) 466-2550 http://www.aep.com/

21 Facility Name 1 iii Donald C. Cook Nuclear Plant i Facility Name 2

.,* NA Facility Name 3 NA Street Address (do not use a P.O. Box Number)

One Cook Place

-l City State ZIP Code Bridgman Ml 49106 Telephone (with area code)

FAX (with area code)

Facility Web Address (269) 465-5901 1(269) 466-2550 http://www.aep.com/

First Name Last Name El1 Application Contact Jon Harner Z

Facility Contact Title Business Environmental Manager NA Z

Discharge Monitoring Reports Address 1 Address 2 Storm Water Billing One Cook Place I Environmental Department 5A El Biosolids Billing City State ZIP Code Bridgman M

49106 El NPDES Annual Billing Telephone (with area code)

FAX (with area code) emi drs (269) 465-5901 x 2102 (269) 466-2550 jhhamer@aep.com First Name Last Name

[

Application Contact Blair Zordell E] Facility Contact Title Business Environmental Specialist NA El Discharge Monitoring Reports Address 1 Address 2 El Storm Water Billing One Cook Place Environmental Department 5A C

Brd Bil city State city iosolis iing Bridgman IMI 149106 i*1:3NPDES Annual Billing mi drs Telephone (with area code)

• FAX (with area code) e-mail address

( 269) 465-5901 x 2006 (269) 466-2550 bkzordell@aep.com First Name Last Name i':} [Application Contact NA NA

"*".ITitle Business El Facility Contact NA NA El Discharge Monitoring Reports Address 1 Address 2 E] Storm Water Billing NA NA jt El Biosolids Billing NACiyNA StteNACt El NPDES Annual Billing Telephone (with area code)

FAX (with area code) e-mail address L

NA NA NA I

EQP 4659-A (Rev. 11/2007) NP2

Michigan Department of Environmental Quality-Water Bureau WASTEWATER DISCHARGE PERMIT APPLICATION SECTION I - General Information PLEASE TYPE OR PRINT ITY NAME NPDES PERMIT NUMBER

_. did C. Cook Nuclear Plant M10005827

5.

PERMIT ACTION REQUESTED (Check one box only) - Instructions for this item are on Page 2 of the Appendix.

[E NEW USE A proposed discharge.

El EXISTING DISCHARGE that is currently unpermitted.

0D REISSUANCE of current permit.

El MODIFICATION of current permit. Attach a description of the proposed modification.

Note: Applications for New Use discharges, Existing Discharges that are currently unpermitted and applications for either Reissuance or Modification that include an increased loading of pollutants to the receiving water are required to submit a Rule 98 Demonstration with the Application. See Item 6.

6.

RULE 98 - ANTIDEGRADATION REQUIREMENTS - Instructions for this item are on Page 2 of the Appendix.

In accordance with Rule 323.1098 of the Michigan Water Quality Standards, the applicant is required to submit an Antidegradation Demonstration for any new or increased loading of pollutants to the surface waters of the state. An Antidegradation Demonstration must contain the information specified in Rule 1098, outlined in the Antidegradation section of the Appendix. For assistance in completing this item, contact the Permits Section.

Will this discharge be an increased loading of pollutants to the surface waters of the state? El Yes, continue below.

[D No.

El Antidegradation Demonstration provided. [I Increased loading of pollutants is exempt from Antidegradation Demonstration as indicated below:

El A short-term (weeks to months) or temporary lowering of water quality.

[E Bypasses that are not prohibited by regulations set forth in 40 CFR §122.41(m).

El Response actions undertaken to alleviate a release of pollutants into the environment that may pose an imminent and substantial danger to the public health or welfare.

El Discharges of pollutant quantities from the intake water at a facility if the intake and discharge are.to the same body of water.

El Increases in flow, if the increase is within the design flow of the facility, it is not specifically authorized in the current permit, and there is no significant change expected in the characteristics of the wastewater collected.

El Intermittent increased loading related to wet-weather conditions.

El New or increased loading due to MDEQ-approved controls related to wet-weather conditions.

El Discharges authorized by certificates of coverage and notices of coverage.

El Increased loadings within the authorized levels of a limit in an existing control document, except those loadings that result from actions by the permittee that would otherwise require submittal of an increased use request.

El Increased loadings of a pollutant which do not involve a Bioaccumulative Chemicals of Concern (BCC) and which use less than 10 percent of the unused loading capacity that exists at the time of the request.

7 ADDITIONAL FACILITY LOCATION INFORMATION - Instructions for this item are on Page 2 of the Appendix. E] No Change From Last Application Local Unit of Government (LUG)

UG e-mail address A Lake Township laketwpawmis.net B

C.

D.

County Township Berrien Lake Town Range Section

/

Y4, 1/4 Private (French) Land Claim 06S1 19W 06 NW SW Latitude Longitude 41 58'32.07"

-86 33' 54.87" 8.

CERTIFIED OPERATOR El No Change From Last Application Does the facility have an MDEQ certified operator?

Z Yes El No Instructions for this item are on Page 2 of the Appendix.

First Name Last Name Blair Zordell Certification Number Certification Classification(s) 4537 A-id, A-lh, A-2e, B-lb, B-2a, C-2e Address 1 Address 2 One Cook Place Environmental Department 5A City State Zip Code Bridgman MT 49106 Telephone Number Fax Number e-mail address (269) 465-5901 x 2006 1(269) 466-2550 bkzordelf@aep.com 2

EQP 4659-A (Rev. 11/2007)

. Michigan Department of Environmental Quality-Water Bureau WASTEWATER DISCHARGE PERMIT APPLICATION SECTION I - General Information PLEASE TYPE OR PRINT

-ITY NAME NPDES PERMIT NUMBER uonald C. Cook Nuclear Plant M10005827

9.

OTHER ENVIRONMENTAL PERMITS 0l No Change From Last Application Provide the information requested below for any other federal, state, or local environmental permits in effect or applied for at the time of submittal of this Application Form; including, but not limited to, permits issued under any of the following programs: Air Pollution Control, Hazardous Waste Management, Wetlands Protection, Soil Erosion and Sedimentation Control, and other NPDES permits. To submit additional information, see Page ii, Item 3.

Issuing Agency Permit or COC Number Permit Type MDEQ -WMD GW1810102 Groundwater Discharge USACE -

LRE-2001-561367-N07 Excavation on Lake Bottom Berrien County Drain Commission 5753 Soil and Erosion MDEQ Geological and Land Management Divison 94-BR-321-C Crit Dunes MDEQ Geological and Land ManagementDivision 03-11-0127-P Part 325 Submerged Land USACE 69-056-004-7 Dept of Army Permit MDEQ-Air quality Division 460-93,34-05,260-03, Air use permits

10.

WATER FLOW DIAGRAM AND NARRATIVE DESCRIPTION El No Change From Last Application Drovide a flow diagram (using 8%" x 11" paper if possible) showing the wastewater flow through the facility (from intake through discharge),

including all processes, treatment units (identify treatment units that operate intermittently), and bypass piping, and include a narrative description that explains the diagram.

Show all operations contributing wastewater and the locations of flow meters, chemical feeds, and monitoring and discharge points. The water balance shall shoW the daily average flow rates at the intake and discharge points, and approximate daily flow rates between treatment units, including influent and treatment rates. Use actual measurements whenever available, otherwise use the best estimate.

Show all significant losses of water to products, atmosphere, and discharge. In addition, provide a flow diagram for any storm water discharges from secondary structures that are required by state or federal law, and for storm water runoff from any Site of Environmental Contamination, pursuant to Part 201 of the Michigan Act. Do not send blueprints.

Do the treatment facility processes described above include any lagoons or ponds used for wastewater treatment or storage?

Z Yes [:

No If yes, include the ponds or lagoons in the flow diagram.

Municipal Facilities - Include a narrative that briefly describes the history of the wastewater treatment facility and collection system, including the initial construction, the facility improvements that have been made, future plans for upgrade, the location of all constructed emergency overflows, and other pertinent information.

Industrial and Commercial Facilities - The line diagram shall include all operations contributing wastewater, including process and production areas, sanitary flows, cooling water, and storm water runoff. Also include a narrative that provides a brief description of the nature of the business and the manufacturing processes.

ATTACH THIS INFORMATION TO THIS APPLICATION. PLEASE DO NOT BIND THIS INFORMATION.

11.

MAP OF FACILITY AND DISCHARGE LOCATION El No Change From Last Application Provide a detailed map on 81/" x 11" paper showing the location of the existing or proposed facility, wastewater and biosolid treatment system(s),

and wastewater monitoring and discharge points into receiving waters (including bypasses). Include the exact location of the wastewater monitoring and discharge point(s) and all areas through which the discharge flows (e.g., wetlands, open drains, storm sewers), if applicable, between the discharge point and the receiving water. If the discharge is to a storm sewer, label the storm sewer and show its flow path to the receiving water.

Also include the location of any water supply intakes or wells, and groundwater monitoring wells. This map shall be a United States Geological Survey quadrangle (7.5 minute series) or other map of comparable detail, scale, and quality (which shows surface water bodies, roads, bathing

)eaches, and other pertinent landmarks). It is preferred that the minimum area this map shall encompass is approximately one mile beyond the property boundaries.

ATTACH THIS INFORMATION TO THIS APPLICATION.

3..

EQP 4659-A (Rev. 11/2007)

I Donald C. Cook Nuclear Plant Permit Number: M10005827 I

Michigan Department Of Environmental Quality-Water Bureau WASTEWATER DISCHARGE PERMIT APPLICATION SECTION I - General Information Section 9. OTHER ENVIRONMENTAL PERMITS Supplemental information Issuing Agency Permit or COC Number Permit Type USEPA MID098647621 Hazardous Waste 91084649 Above Ground Storage Tank PR-0050-05 (AOT Generators) 91084649 Above Ground Storage Tank MDEQ PR-0367-06 (Contingency Boiler)

Part 325 MDEQ 07-11-0145-P Great Lakes Submerged Lands.

(fish avoidance repair)

Section I, Item,I

.V10005827

-,Uti-2UUg.n I Description AVG Flow Outfall in MOD "I

Inlet - Lake Twp Water Source

- 0.042 001 U-1 Circ. Water 974 002 U-2 Circ. Water 1137 003 De ce (MA ti-1 RI MIInwdcwn f.I1 DEFINITIONS NESW-NONESSENTIAL SERVICE WATER ESW-ESSENTIAL SERVICE WATER MDT-MISC. DRAIN TANK LChemical Addition points WASTEWATER FLOW DIAGRAM DONALD C. COOK NUCLEAR PLANT PATSITE SANITMYvn 00B U-2 SG Slowdown 0.240 00C HtI Bir Discharge 0.00001 LORATORYWASTE

1.

00 TRS Discharge 0.407 CSAASLNOA.

ElhiASSIc.

OREA LACE TOROTECTIABN 00E Sewage Treatment Plant 0.020 WATER SUPPLY OOG RO Reject Flow 0.2641 0

PGLA OOH TRS Entergency Overflow 0.00008 rELTEORNATEH0TGj T-TATESR FOAAE4P CONENOTSATE SYSTEM LAYU?

DRAIN TOTURBINEELERADT..TN SROM SUMP TRAINING BUILDING VAC CERCESNED SRALVO.

SECUOEIT D

O SEL SON-BACW CONENAT SYTNIRW CONTACTACLSRMS COOLNG ATE OUEAL 003LDO TAOS TOREINE"ROOM RAM El NOMA FLS TN OUTFALL 002 DILI~~M~eU W^TeATN WAERUNT TA ARO TURBINEM myOM

`UN

• UNIT I CO.pOENT OFeNOONO$TO SSEOTEM ORAI IA I6IfSPL_

LT' S.......

OUTFALL I~~.~SO SEZUENIC.I BATCH REACT xeORo

.. JjjAIAAR__=55_TJ OU0tTFALLIU.S.LSj L00-0 cNROEE

.P W

A 5.1 LAKE MICHIGANTRN

• In addition to Stormwater outfall E

ources as listed. typical drainage Isources such as rooftops, Parking lots, Coaowys exst as etaled inWP tP.

~Cook Plant SWPPP.

i CATCHAGA ITS UNIT WNIT IIMTRTNIMMEn OLM/ATER OREWELL RROUNDWATER

-5(STO WATER)

SEPARATOR

Section I, Item,u

[

M10005827 N

EFINITIONS ESW-NONE5SENTIAL SERVICE WATER ESW-ESSENTIAL SERVICE WATER Description AVG Flow MDT-MISC. DRAIN TANK Outfall in MGD WASTEWATER FLOW DIAGRAM 001 Inlet - Lake Tw Water Source 0.042 001 U-11 Circ. Water 974 500 u-2----

wa-er 137 DONALD C. COOK NUCLEAR PLANT 05',

.s..e..n OOA U-1 SG olowdown 0.116 KT, 000 U-2 SG Slowdown 0.240 OU TFALL 00C Htg Blr Discharge 0.00001 L neSoY. SUTEso

.00 000)

TRS Discharge 0.407 M...

-o o..

=......

m..

0.

PMEPE

=-1 I

o-000 Sewage Treatment Plant 0.020 W

SUPPLY L'

000 RO Reaect Flow 0.2134 001-TRS Emergency Overflow 0.00008 EýA1N

":!ýUW:'.IENMN C

upoNoS e

S.S... 0 5

OUTFALLCONE.

000 SYSTt PA rANK I

u E... I BP L A msc~ee TRANSFORMER~

OUTAL 001*_

II::=

o___.... ;_____......

ti.

CAtCRAtHDAH3tsaMRGECYDAIN Mt5.

wAnOSYSYTE t

I ntI c OMPONENI l l 005OS5 ONENATSYTEiOAt7a waresUL 0055 MOO-1 AK TR-TN OUTFALL 00 I

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OUFL 0Y~t ARGE BAYr *7 mic. ecSC COOLtNGWT RAE 05

.F14H.E Sottnnoeti.

OUTFALL 002

/

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a~*A~

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41 00

,nOneO F

SL 003 SOUTH ECUt----

sAoSPwnTER-

[SSTO O

L-0 LAKE MICHIGAN 00I' STORMWAtERO

..coE.STE Sr*

E tfltI

_ In addition to Stor..wal. outfall EM.E.E.. O......

55t STO.*':e o urces as listed, typical drainege sources such as rooftops. Parking lots, Roadways exist as detailed In the UNI 1..

1 Cook Plant SWPPP.

CASOSSM 1-T2

~

tOT

~0f~5 pnnoeoo~no ouwset R oti Sonwrt IR O~~~cK SePO ER 11OOSDAI

Section I, Item 10 Stormwater discharges from Secondary Structures NPDES Permit Mi0005827 halt X.

X. X X XAsphalt X X.

XRoadway Transformer 12 TR-SACB Location: South side of protected area East of Secuity Complex Construction: Concrete floor and curbing Volume: 205 gallons 23 gallons per inch I-------------------------------------------

j I

Storm Drain I

4-Storm Drain Bulk Chemical Unloading area.

Location: West side of protected area between screenhouse and office building.

Construction: Concrete curbing with polyethylene liner covered with stone and asphalt.

Actual Volume: 18,275 gallons Working Volume: 90 gallons or 2 gallons per inch (below stormgrate) approx. 314 gallons (using stone as a border) or 52 gallons per inch for liquid above storm grate.

Stone area: approximately 10' x 5'in size.

Transformer 12 TRCAB Location: East side of protected area West of RPAC Construction: Concrete floor and curbing Volume: 254 gallons 30 gallons per inch.

L------------------------------------------------------------------------

SECTION I, ITEM 10 Cont'd N-PDES Waste Stream Narrative This narrative describes all outfalls discharging to Lake Michigan. Flows are based on a review of previous NPDES applications, Plant system descriptions, or previously submitted Discharge Monitoring Reports (DMR). The chemical additives described below may include a manufacturer's name as an example of the type of product used in a specific system. Indiana Michigan Power may substitute vendors of chemical additives provided that the chemical ingredients are similar. Discharge values are based on maximum release rates and volumes, dilution rates are based on a minimum number of pumps running.

OUTFALL 001 - Unit 1 Circulating Water Discharge Outfall 001 is a non-contact cooling water discharge. The majority of non-contact cooling water (Circulating Water System, -690,000 GPM) is used to condense the steam exhausting from steam driven turbines. Non-contact cooling water is drawn from Lake Michigan approximately one-half mile from shore through three 16 ft. diameter tunnels. Water enters the tunnels via intake cribs at an approximate velocity of 1.3 feet per second. The water enters to a forebay where it is screened to remove large debris that may be entrained in the water. It is routed through the Unit 1 condensers and then discharged to Lake Michigan through a 16 foot diameter tunnel. The water exits the tunnels through high velocity discharges at a rate of approximately 13 feet per second approximately 1/4 mile from shore. Outfall 001 also includes internal Outfalls (as designated by the Michigan Department of Environmental Quality)

Steam Generator Blowdown (OOA, OOB), Plant Heating Boiler (OOC), Reverse Osmosis Unit (OOG), and the Turbine Room Sump Emergency Overflow (OOH) described in detail later in this document.

Outfall 001 also may contain the effluent flow from both Units' Essential Service Water (ESW) systems, both Units' Non-Essential Service Water (NESW) system, and monitor tank releases. ESW (-40,000 GPM) is Lake Michigan water taken from the forebay that is used to provide cooling to safety-related equipment. NESW (- 18,000 GPM) is also Lake Michigan water taken from the forebay used for I

non-contact cooling for various plant systems including oil coolers, a source of water for the demineralized makeup system (MUP), and a water supply for non-safety related equipment. Monitor tank releases (-15,000 to 20,000 gallons per event) are regulated by the NRC and consist of wastewater from various system and equipment leakage that may be generated within the auxiliary building area.

Minor leakage from systems containing lube oil, hydrazine, carbohydrazide, ethanolamine or closed-loop cooling systems containing a maximum concentration of gluteraldehyde (100 ppm), methyl (bis) thiocyanate (10 ppm), tolyltriazole (60 ppm), Molybdate (1000 ppm), and nitrite (1200 ppm), may be discharged via monitor tank releases.

The non-contact cooling water for the Circulating Water, the ESW and the NESW, and Miscellaneous Sealing and Cooling Water Systems is treated for biological control using sodium hypochlorite. This same water is periodically treated using a non-oxidizing biocide to eradicate zebra mussels from the cooling systems. The biocides (Betz Spectrus CT-1300, Calgon H-130M, Calgon EVAC and NALCO Macro-Trol 9380) are polyquats, and are used as required to protect plant systems while meeting water quality based effluent limits. The treatments can be directed to various critical plant systems from the intake structures through the entire plant cooling system, including the Circulating Water System, ESW and NESW systems and other non-contact cooling water. The biocide may be added to the systems via a chemical injection pipeline through a ring header located inside the intake crib, or directly applied at a specific system. A chemical injection pipeline may be installed and is designed to feed chemicalsfrom inside the plant. The intake chemical injection header may be stored with chemical inside the pipe to prevent zebra mussel infestation. The header may also be leak checked using approved dyes such as fluorescein, or other indicators such as Nalco Trasar 23299. Non-contact cooling systems biocide treatments are dependent upon zebra mussel infestation. Concentrations and chemical feed points are chosen to minimize the amount of biocide required and to maximize the efficacy on zebra mussels.

Bentonite clay may be added to detoxify the biocide prior to discharge. The plant non-contact cooling water systems may be treated concurrently or individually to allow more efficient use of chemicals. Plant systems are treated to assure safe operation of the nuclear generating units.

The piping used to apply chemicals is regularly cleaned of calcium carbonate scale buildup. A small amount of weak acid cleaner such as Betz FerroQuest FQ LP 7200 may be used to remove accumulated carbonate scale deposits. The accumulated deposits will be discharged via Outfalls 001/003. Circulating water will dilute the weak acid prior to discharge to Lake Michigan.

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Condensate flushes are performed periodically to purge the plant's secondary water system from layup chemistry specifications during shutdown conditions to startup chemistry specifications prior to startup of the unit. Water containing up to 4 ppm hydrazine [Betz Cortrol OS5035, Betz Cortrol OS5010, NALCO 19H], 10 ppm carbohydrazide (NALCO 1250 plus, or equivalent), 100 ppm ethanolamine (Betz Powerline 1440, Betz Powerline 1480, NALCO 92UM00 1), is overboarded to Outfall 001 as required to remove contaminants to meet desired startup secondary Chemistry specifications. This flowrate averages 70 GPM, but may reach 600 GPM for short periods of time. The flowrate is dependent on chemistry specification parameters and makeup water availability. The maximum output from the MUP is approximately 600 GPM or 864,000 GPD. (See Outfalls OOA, 00B for further description.)

Monitor tanks receive treated water from the auxiliary building radioactive waste removal system and other sources such as ice production and removal processes from the ice condenser systems and other radioactively contaminated wastes generated at the facility. This system handles wastes generated from the reactor coolant pump seal leakoffs, the refueling cavity water, equipment leaks, floor drains, valve stem leakoffs, system sampling, and waste sample solutions. It also handles laboratory wastes from the radiochemistry analysis in the hot chemical laboratory, system equipment drains, non-contact cooling water, ice production/removal and decontamination processesand any contaminated liquid waste generated in the auxiliary building area. The wastes are collected in one of several tanks and are treated when enough water is collected. The treatment utilizes a demineralizer system to minimize radioactive contaminants. A small amount of wastewater may bypass the treatment because it cannot be processed by resin.

Other special drains of non-radioactive process water systems such as-Component Cooling Water system flushes with biocides such as gluteraldehyde (100 ppm), methyl (bis) thiocyanate (10 ppm), tolyltriazole (60 ppm), Molybdate (1000 ppm) and nitrite (1200 ppm), and borated icemaking/ice removal operations, can be routed directly to the plant's monitor tanks without treatment. For maintenance purposes to prevent microbial growth, Component Cooling Water flushes are performed generating approximately 281,000 gallons per year of flushwater to the monitor tanks.

Borated icemaking/ice removal operations occur for maintenance of the plant's ice condenser systems.

This process produces a solution of sodium tetraborate (approximately 2200 ppm as boron) that can be drained to the monitor tanks. This process takes place approximately every 18 months and may produce up to 70,000 gallons of sodium tetraborate solution.

Both the treated wastewater and the special drains are accumulated in the monitor tanks and sampled to ensure the waste meets the radiological requirements prior to being discharged into the Circulating Water System.

Periodically, due to equipment leaks and/or system upsets, a waste stream is generated that contains radioactively contaminated ethylene glycol and water. Incidental amounts of ethylene glycol generated from equipment leaks may be drained directly to the monitor tanks or treated by the radwaste processing system. Small amounts of ethylene glycol may be discharged to outfalls 001, 002, or 003.

Sulfur hexafluoride gas (SF6) is utilized in the non-contact cooling water systems at the plant to detect leaks in various components such as the condensers. The gas is injected in the cooling water stream and discharged to outfalls 001, 002 or 003 at less than 54 ul/1.

Aryl sulfate liquid (NALCO Trasar 23299) is utilized in the non-contact cooling water systems at the plant to determine flow through Various parts of the system. The liquid is injected into the service water system to reach a target concentration of approximately 2 mg/l. The service water is discharged to Outfalls 001, 002, or 003, which would, in turn, dischaige at less than 0.15 mg/I. The liquid is also injected into the circulating water system to reach a target concentration of approximately 2 mg/l.

Control Room Air Conditioning (CRAC) testings Approximately 1440 gallons/yr. of CRAC water may mix with ESW and then be discharged to the forebay during a monthly test of the system. CRAC water is demineralized water, and may contain up to: 2000 ppm nitrite [Calgon LCS 60, Betz Corrshield NT 4205, BETZ CORRSHIED NT 4201, Betz Corrshield NT 4203, or equivalent], 100 ppm gluteraldehyde

[from Betz Biotrol 107 (Spectrus NX 1105), Calgon H-300, or equivalent], 60 ppm tolyltriazole [from Calgon LCS-60, Betz AZ8101, Betz Corrshield NT 4205, BETZ CORRSHIED NT 4201, Betz Corrshield NT 4203, or equivalent], 10 ppm methyl (his) thiocyanate (from Betz 3610), 1000 ppm molybdate from Betz Corrshield MD 4103, and Betz Ferroquest FQ7101 and FQ7102 for CRAC HX cleaning.

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Three roadway storm drains route small amounts of stormwater from a small section of roadway that traverses over the Circulating Water Forebay. The three storm drains are designed to route accumulated stormwater from this small roadway to the forebay below. A small amount of de-icing compound used on this section of road could potentially enter these small (Approximately 8") gratings. Screened material collected from the plant's intakes is also stored in this area in designated trash dumpsters. Fish exudiates are now drained to the forebay as recommended by the MDEQ stormwater and NPDES inspection team (M. Fields and J. Molloy 1997).

During upset conditions it is possible to overflow the contents of the Turbine Room Sump (See Outfall OOH) to Outfalls 00 1, 002 and/or 003 if the flow path to the on-site absorption pond cannot be used.

OUTFALL 002 - Unit 2 Circulating Water Discharge Outfall 002 is a non-contact cooling water discharge. The majority of non-contact cooling water (Circulating Water System, -920,000 GPM) is used to condense the steam exhausting from steam driven turbines. Non-contact cooling water is drawn from Lake Michigan approximately one-half mile from shore through three 16 ft. diameter tunnels. Water enters the tunnels via intake cribs at an approximate velocity of 1.3 feet per second. The water enters to a forebay where it is screened to remove large debris that may be entrained in the water. It is routed through the Unit 2 condensers and then discharged to Lake Michigan through an 18 foot diameter tunnel. The water exits the tunnels through high velocity discharges at a rate of approximately 13 feet per second approximately 1/4 mile from shore. Outfall 002 also includes internalOutfalls (as designated by the Michigan Department of Environmental Quality)

Steam Generator Blowdown (OOA, OOB), Plant Heating Boiler (0OC), Reverse Osmosis Unit (OOG), and the Turbine Room Sump Emergency Overflow (OOH) described in detail later in this document.

Outfall 002 also may contain the effluent flow from both Units' Essential Service Water (ESW) systems, both Units' Non-Essential Service Water (NESW) system, and monitor tank releases. ESW (-40,000 GPM) is Lake Michigan water taken from the forebay that is used to provide cooling to safety-related equipment. NESW (-18,000 GPM) is also Lake Michigan water taken from the forebay used for 5

non-contact cooling for various plant systems including oil coolers, a source of water for the demineralized makeup system (M-UP), and a water supply for non-safety related equipment. Monitor tank releases (-15,000 to 20,000 gallons per event) are regulated by the NRC and consist of wastewater from various system and equipment leakage that may be generated within the auxiliary building area.

Minor leakage from systems containing lube oil, hydrazine, carbohydrazide, ethanolamine or closed-loop cooling systems containing a maximum concentration of gluteraldehyde (100 ppm), methyl (bis) thiocyanate (10 ppm), tolyltriazole (60 ppm), Molybdate (1000 ppm), and nitrite (1200 ppm), may be discharged via monitor tank releases.

The non-contact cooling water for the Circulating Water, the ESW and the NESW, and Miscellaneous Sealing and Cooling Water Systems is treated for biological control using sodium hypochlorite. This same water is periodically treated using a non-oxidizing biocide to eradicate zebra mussels from the cooling systems. The biocides (Betz Spectrus CT-1300, Calgon H-130M, Calgon EVAC and NALCO Macro-Trol 9380) are polyquats, and are used as required to protect plant systems while meeting water quality based effluent limits. The treatments can be directed to various critical plant systems from the intake structures through the entire plant cooling system, including the Circulating Water System, ESW and NESW systems and other non-contact cooling water. The biocide may be added to the systems via a chemical injection pipeline through a ring header located inside the intake crib, or directly applied at a specific system. A chemical injection pipeline may be installed and is designed to feed chemicals from inside the plant. The intake chemical injection header may be stored with chemical inside the pipe to prevent zebra mussel infestation. The header may also be leak checked using approved dyes such as fluorescein, or other indicators such as Nalco Trasar 23299. Non-contact cooling systems biocide treatments are dependent upon zebra mussel infestation. Concentrations and chemical feed points are chosen to minimize the amount of biocide required and to maximize the efficacy on zebra mussels.

Bentonite clay may be added to detoxify the biocide prior to discharge. The plant non contact cooling water systems may be treated at the concurrently or individually to allow more efficient use of chemicals.

Plant systems are treated to assure safe operation of the nuclear generating units.

The piping used to apply chemicals is regularly cleaned of calcium carbonate scale buildup. A small amount of weak acid cleaner such as Betz FerroQuest FQ LP 7200 may be used to remove accumulated carbonate scale deposits. The accumulated deposits will be discharged via Outfalls 002/003. Circulating water will dilute the weak acid prior to discharge to Lake Michigan.

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Condensate flushes are performed periodically to purge 'the plant's secondary water system from layup chemistry specifications during shutdown conditions to startup chemistry specifications prior to startup of the unit. Water containing up to 4 ppm hydrazine [Betz Cortrol OS5035, Betz Cortrol OS5010, NALCO 19H], 10 ppm carbohydrazide (NALCO 1250 plus, or equivalent), 100 ppm ethanolamine (Betz Powerline 1440, Betz Powerline 1480, NALCO 92UM00 1), is overboarded to Outfall 002 as required to remove contaminants to meet desired startup secondary Chemistry specifications. This flowrate averages 70 GPM, but may reach 600 GPM for short periods of time. The flowrate is dependent on chemistry specification parameters and makeup water availability. The maximum output from the MUP is approximately 600 GPM or 864,000 GPD. (See Outfalls OOA, OOB for further description.)

Monitor tanks receive treated water from the auxiliary building radioactive waste removal system and other sources such as ice production and removal processes from the ice condenser systems and other radioactively contaminated wastes generated at the facility. This system handles wastes generated from the reactor coolant pump seal leakoffs, the refueling cavity water, equipment leaks, floor drains, valve stem leakoffs, system sampling, and waste sample solutions. It also handles laboratory wastes from the radiochemistry analysis in the hot chemical laboratory, system equipment drains, non-contact cooling water, ice production/removal and decontamination processes and any contaminated liquid waste generated in the auxiliary building area. The wastes are collected in one of several tanks and are treated when enough water is collected. The treatment utilizes a demineralizer system to minimize radioactive contaminants. A small amount of wastewater may bypass the treatment because it cannot be processed by resin.

Other special drains of non-radioactive process water systems such as Component, Cooling Water system flushes with biocides such as gluteraldehyde (100 ppm), methyl (bis) thiocyanate (10 ppm), tolyltriazole (60 ppm), Molybdate (1000 ppm) and nitrite (1200 ppm), and borated icemaking/ice removal operations, can be routed directly to the plant's monitor tanks without treatment. For maintenance purposes to prevent microbial growth, Component Cooling Water flushes are performed generating approximately 281,000 gallons per year of flushwater to the monitor tanks.

Borated icemaking/ice removal operations occur for maintenance of the plant's ice condenser systems.

This process produces a solution of sodium tetraborate (approximately 2200 ppm as boron) that can be drained to the monitor tanks. This process takes place approximately every 18 months and may produce up to 70,000 gallons of sodium tetraborate solution.

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Both the treated wastewater and the special drains are accumulated in the monitor tanks and sampled to ensure the waste meets the radiological requirements prior to being discharged into the Circulating Water System.

Periodically, due to equipment leaks and/or system upsets, a waste stream is generated that contains radioactively contaminated ethylene glycol and water. Incidental amounts of ethylene glycol generated from equipment leaks may be drained directly to the monitor tanks or treated by the radwaste processing system. Small amounts of ethylene glycol may be discharged to outfalls 001, 002, or 003.

Sulfur hexafluoride gas (SF6) is utilized in the non-contact cooling water systems at the plant to detect leaks in various components such as the condensers. The gas is injected in the cooling water stream and discharged to outfalls 001, 002 or 003 at less than 54 ul/l.

Aryl sulfate liquid (NALCO Trasar 23299) is utilized in the non-contact cooling water systems at the plant to determine flow through various parts of the system. The liquid is injected into the service water system to reach a target concentration of approximately 2 mg/I. The service water is discharged to Outfalls 001, 002, or 003, which would, in turn, discharge at less than 0.15 mg/I: The liquid is also injected into the circulating water system to reach a target concentration of approximately 2 mgl.

Control Room Air Conditioning (CRAC) testing: Approximately 1440 gallons/yr. of CRAC water may mix with ESW and then be discharged to the forebay during a monthly test of the system. CRAC water is demineralized water, and may contain up to: 2000 ppm nitrite [Calgon LCS 60, Betz Corrshield NT 4205, BETZ CORRSHIED NT 4201, Betz Corrshield NT 4203, or equivalent], 100 ppm gluteraldehyde

[from Betz Biotrol 107 (Spectrus NX 1105), Calgon H-300, or equivalent], 60 ppm tolyltriazole [from Calgon LCS-60, Betz AZ8101, Betz Corrshield NT 4205, BETZ CORRSHIED NT 4201, Betz Corrshield NT 4203, or equivalent], 10 ppm methyl (bis) thiocyanate (from Betz 3610), 1000 ppm molybdate from Betz Corrshield.MD 4103, and BetzFerroquest FQ7101 and FQ7102 for CRAC HX cleaning.

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Three roadway storm drains route small amounts of stormwater from a small section of roadway that traverses over the Circulating Water Forebay. The three storm drains are designed to route accumulated stormwater from this small roadway to the forebay below. A small amount of de-icing compound used on this section of road could potentially enter these small (Approximately 8") gratings. Screened material collected from the plant's intakes is also. stored in this area in designated trash dumpsters. Fish exudiates are now drained to the forebay as recommended by the MDEQ stormwater and NPDES inspection team (M. Fields and J. Molloy 1997).

During upset conditions it is possible to overflow the contents of the Turbine Room Sump (See Outfall OOH) to Outfalls 001, 002 and/or 003 if the flow path to the on-site absorption pond cannot be used.

OUTFALL 003 - Deicing Discharge Outfall 003 is a deicing discharge which is used when water temperatures approach freezing temperatures. A portion of the flow from Outfall 001 and /or Outfall 002 is directed through the center intake tunnel to temper the intake water and prevent ice buildup on the intake structures which could restrict intake flow. The velocity at the other two intake structures during de-icing mode increases to approximately 1.9 feet per second. Discharge velocity will be less that 13 feet per second since a portion of the discharge is routed out the center intake tunnel.

The Essential and Non-Essential Service Water System (ESW and NESW) may be recirculated with a combination of Circulating Water Pumps in service to raise the forebay temperature to prevent frazil ice formation during cold weather periods. During shutdown conditions when normal operating heat addition is not available, portable heat.addition units may be placed in the forebay to prevent frazil ice formations that may prevent flow to safety systems in the plant.

OUTFALL OOA - Unit 1 Steam Generator Blowdown The steam generators (part of the secondary water system) require ultra high purity water for operation.

Makeup water used in the steam generators is withdrawn from the intake forebay (or from Lake Township water supply or a blending of both sources) and treated so most natural impurities are removed through sedimentation, filtration, reverse osmosis, and demineralization. Impurities concentrate in the steam generators as the water is turned to steam and must be removed to protect the steam turbines and 9

heat transfer surfaces of the steam generators. The impurities are removed by continuously draining a portion of the water from the steam generators in a process called "blowdown".

In the steam generator, steam is separated from the water, further heated, and then routed to the turbines.

When the steam'separates from the water, the impurities remain in the water, concentrating in the steam generator. Blowdown consists of two forms, a liquid portion (700 gpm max) and a wet steam portion, which is exhausted to the atmosphere. The liquid portion of the steam generator blowdown is discharged to the screenhouse forebay either directly (Nornal Flash Tank), or after processing through mixed bed demineralizers. Impurities in this discharge may consist of small quantities of insoluble iron and copper or impurities from the Circulating Water System used to cool the condensers should condenser tube leaks occur. Steam generator additives consist of ethanolamine (Betz Powerline 1440, Betz Powerline 1480, NALCO 92UM001) for pH adjustment, hydrazine [Betz Cortrol OS5035, Betz Cortrol OS501 0, NALCO 19H] and/or carbohydrazide (NALCO 1250 plus, or equivalent) for oxygen scavenging.

When the units are not operating, the steam generators are placed in wet layup conditions to protect against corrosion during storage. Layup water is periodically discharged through the outfall to the Circulating Water Forebay. The layup water contains a maximum concentration of 400 ppm hydrazine

[Betz Powerline Cortrol OS5035, Betz Cortrol OS5010, NALCO 19H] and/or 40 ppm carbohydrazide (NALCO 1250 plus, or equivalent), and /or 100 ppm ethanolamine (Betz Powerline 1440, Betz Powerline 1480, NALCO 92UM001). The waste strength of this discharge is reduced through mixing with Outfalls 001, 002, or 003.

During the Sludge Lancing Process, demineralized water or secondary water is used to pressure clean the steam generators during outage periods. The water is recirculated through temporary filters to remove entrained solids. The major constituent of the solids is iron oxide from the steam generators.

The water is then returned to the steam generators and can be drained to Outfalls O0A, O0B, to Outfall 001, 002, 003, OOD or OOH. The suspended solids are analyzed for radioactivity prior to disposal.

OUTFALL OOB - Unit 2 Steam Generator Blowdown The steam generators (part of the secondary water system) require ultra high purity water for operation.

Makeup water used in the steam generators is withdrawn from the intake forebay (or from Lake Township water supply or a blending of both sources) and treated so most natural impurities are removed 10

through sedimentation, filtration, reverse osmosis, and demineralization. Impurities concentrate in the steam generators as the water is turned to steam and must be removed to protect the steam turbines and heat transfer surfaces of the steam generators. The impurities are removed by continuously draining a portion of the-water from the steam generators in a process called "blowdown". -

In the steam generator, steam is separated from the water, further heated, and then routed to the turbines.

When the steam separates from the water, the impurities remain in the water, concentrating in the steam generator. Blowdown consists of two forms, a liquid portion (700 gpm max) and a wet steam portion, which is exhausted to the atmosphere. The liquid portion of the steam generator blowdown is discharged to the screenhouse forebay either directly (Normal Flash Tank), or after processing through mixed bed demineralizers. Impurities in this discharge may consist of small quantities of insoluble iron and copper or impurities from the Circulating Water System used to cool the condensers should condenser tribe leaks occur. Steam generator additives consist of ethanolamine (Betz Powerline 1440, Betz Powerline 1480, NALCO 92UM001) for pH adjustment, hydrazine [Betz Cortrol OS5035, Betz Cortrol OS5010, NALCO 19H] and/or carbohydrazide (NALCO 1250 plus, or equivalent) for oxygen scavenging.

When the units are not operating, the steam generators are placed in wet layup conditions to protect against corrosion during storage. Layup water is periodically discharged through the outfall to the Circulating Water Forebay. The layup water contains a maximum concentration of 400 ppm hydrazine

[Betz Powerline Cortrol OS5035, Betz Cortrol OS5010, NALCO 19H] and/or 40 ppm carbohydrazide (NALCO 1250 plus, or equivalent), and /or 100 ppm ethanolamine (Betz Powerline 1440, Betz Powerline 1480, NALCO 92UM001). The waste strength of this discharge is reduced through mixing with Outfalls 001, 002, or 003.

During the Sludge Lancing Process, demineralized water or secondary water is used to pressure clean the steam generators during outage periods. The water is recirculated through temporary filters to remove entrained solids. The major constituent of the solids is iron oxide from the steam generators.

The water is then returned to the steam generators and can be drained to Outfalls OOA, OOB, to Outfall 001, 002, 003, OOD or 0011. The suspended solids are analyzed for radioactivity prior to disposal.

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OUTFALL OOC - Plant Heating Boiler A heating boiler (150,000 lb/hr capacity) operates to supply plant heating and auxiliary steam when Unit 1 and/or Unit 2 are out of service. The boiler is also fired periodically for testing purposes to ensure its availability.

During periods when not in operation, the heating boiler may be stored full of treated boiler water containing up to 400 ppm hydrazine [Betz Cortrol OS5035, Betz Cortrol OS5010, NALCO 19H] or 40 ppm carbohydrazide (NALCO 1250 plus, or equivalent) for oxygen scavenging and or 50 ppm ethanolamine (Betz Powerline 1440, Betz Powerline 1480, NALCO 92UM001) for corrosion protection.

Prior to use, this "wet lay-up" water is drained to Outfall OOC via blowdown, which discharges to the intake forebay. The volume drained is approximately 600 gallons. This boiler may also be occasionally drained for maintenance activities, approximately 6,000 gallons of treated boiler water would be directed to Outfall 00C or OOD/OOH for such purposes.

Impurities from the boiler water consisting primarily of insoluble iron and copper are discharged via blowdown (30 GPM-) to the intake forebay during operation as needed for Chemistry control. Boiler water treatment additives consist of up to 15 ppm ethanolamine (Betz Powerline 1440, Betz Powerline 1480, NALCO 92UM001) for pH adjustment, up to 150 ppb hydrazine.[Betz Cortrol OS5035, Betz Cortrol OS5010, NALCO 19H] and/or 150 ppb carbohydrazide (NALCO 1250 plus, or equivalent) for oxygen scavenging.

Just after boiler shutdown, the boiler may be placed in dry layup. The boiler contents (up to 6,000 gallons) are drained via blowdown to the intake forebay. Boiler water treatment additives consist of up to 3 ppm ethanolamine (Betz Powerline 1440, Betz Powerline 1480, NALCO 92UM001) for pH adjustment and up to 150 ppb hydrazine [Betz Cortrol OS5035, Betz Cortrol OS5010, NALCO 19H]

and/or 150 ppb carbohydrazide (NALCO 1250 plus, or equivalent) for oxygen scavenging. The boiler is then dried out and stored empty. This process saves on chemicals and prevents unnecessary discharge of wet layup chemicals.

A smaller boiler may be installed to provide back-up heat if the permanent heating boiler was out of service. This back-up boiler may be located outdoors on the West Side of the turbine building. The blowdown line is directed to the Unit One forebay, near the same discharge point as the permanently installed heating boiler.

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The same boiler treatment chemistry will be maintained in the back-up boiler as is used in the permanent heating boiler. The back-up boiler treatment additives consist of ethanolamine (Betz Powerline 1440, Betz Powerline i480, NALCO 92UMOO 1) for pH adjustment, and hydrazine [Betz Powerline Cortrol OS5035, Betz Cortrol OS5010, NALCO 19H] and/or carbohydrazide (NALCO 1250 plus, or equivalent) for oxygen scavenging. This boiler may be occasionally drained for maintenance activities, approximately 6,000 gallons of treated boiler water would be directed to Outfall OOC for such purposes.

Impurities from the boiler water consisting primarily of insoluble iron and copper are discharged via blowdown (30 GPM maximum) to the intake forebay during operation as needed for Chemistry control.

OUTFALL OOG - Reverse Osmosis System The Reverse Osmosis System (RO) is used to assist in the removal of dissolved solids from the lake water prior to demineralization. Reject water flow is directed to the forebay, which leads to Outfalls 001, 002, and 003. Reject water flow rates may reach up to 0.366 MGD. The RO system must maintain very clean membranes to assure efficient operation and purity of water. Several methods are used to maintain this level of cleanliness from scale and biofouling. Hydrochloric acid or sulfuric acid is fed at approximately 1.3 GPH continually when the RO is in service to lower the pH to reduce the scaling tendencies of the water. The reject water from the RO unit consists of concentrated Lake Michigan water and a small amount of acid that inhibits scale buildup in the membranes.

Approximately once per month, a flush is performed using approximately 1,000 gallons of a nominal

.0.05% hydrochloric acid solution. This is followed with approximately 1,000 gallons of a nominal 0.1%

sodium hydroxide solution. This flush will dissolve any scale that deposits on the membranes. The total amount of flushing solution will average approximately 5,000 gallons per event. Sodium bisulfite is used to preserve the membranes during long-term shutdown periods. Approximately 15 lbs. of sodium bisulfite per year is used in this manner.

The chemical cleaning involves several steps and may contain citric acid, hydrochloric acid, phosphoric acid, sodium hydroxide, and a neutral pH detergent. The periodic cleaning process averages approximately 10,000 gallons per event, diverted either to the Turbine Room Sump (Outfall 001/O0D),

through the Neutralization Tank to the Turbine Room Sump (Outfall 00H/00D), or to the Circulating Water Forebay (Outfall 001, 002, or 003).

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OUTFALL OOH - Turbine Room Sumo Emergencv Overflow Utility wastewater from within the plant is discharged via the turbine room sump (TRS) into an on-site absorption pond (Outfall 0OD). The nor-mal disposition of these wastewaters is to an on-site absorption pond, which eventually Vents via groundwater to Lake Michigan. In the unlikely event that the normal flow path to the absorption pond is not available, the overflow line (Outfall OOH) will direct the TRS flow to the plant's intake forebay. The wastewaters associated with this Outfall include:

Wastes from the makeup water treatment system.

NESW: (144,000 GPD) The main contributor to this waste stream is the degassifier pump seal water.

Non-Essential Service Water (NESW) from Lake Michigan supplies the vacuum degassifier pumps which utilize up to 100 GPM to remove non-condensable gases (primarily carbon dioxide and oxygen) from the makeup plant water and exhausts them to the atmosphere.

Pre-filter backwash: (Estimated 98,000 GPD) Six pre-filters are backwashed with Lake Michigan water to remove the suspended matter captured on the filter media. Alum solution (aluminum sulfate 0.5 lb. per gallon) is added to the pre-filter influent as a flocculent. The alum is added via a coag*ilant feed pump. Approximately 50 lb./day of alum is used in this process. The alum contained in the backwash is discharged in the form of insoluble aluminum hydroxide.

Carbon filter backwash: (Estimated 42,000 GPD) Carbon filters are periodically backwashed with Lake Michigan water to the TRS. These filters primarily remove organics, chlorine and small amounts of iron.

Demineralizer regeneration: (Estimated 50,000 gallons per regeneration) occurs 2-4 times per month when the RO is in service and more often when it is not in service. Dilute sulfuric acid and sodium hydroxide used by the system to regenerate the resin. Dilute sulfuric acid, sodium hydroxide, and contaminates from the demineralization process is discharged to the neutralization tank or TRS.

The pH is then adjusted to between 5.5 and 9.0 with sulfuric acid, or sodium hydroxide prior to discharge.

• MIJP Neutralization Tank provides a place for demineralization regeneration wastes, and Reverse Osmosis Unit cleaning flushes to be neutralized prior to being discharged to the TRS and ultimately 14

the absorption pond. When the MUP resin beds are regenerated, up to 50,000 gallons of regeneration chemicals, and backwash waters are processed in the neutralization tank. The Reverse Osmosis cleaning flushes average approximately 5,000 gallons per event. When the water is neutralized, it is pumped to the TRS via a 2,000 GPM neutralization waste pump.

The Retention Tank is periodically blown down, discharging small volumes of solid material removed by settling. The retention tank contains a mixture of Lake Township water and filtered Lake Michigan water waiting further processing by the Makeup Plant.

The Reverse Osmosis System (RO) Cleaning. Normal reject water flow is to Lake Michigan via Outfall 00G. The RO system must maintain very clean membranes to assure efficient operation and purity of water. Several methods are used to maintain this level of cleanliness from scale and biofouling. Hydrochloric acid or sulfuric acid is fed at approximately 1.3 GPH continually when the RO is in service to lower the pH to reduce the scaling tendencies of the water. The reject water from the RO unit consists of concentrated Lake Michigan water and a small amount of acid that inhibits scale buildup in the membranes.

Approximately once per month, a flush is, performed using approximately 1,000 gallons of a nominal 0.05% hydrochloric acid solution. This is followed with approximately.1,000 gallons of a nominal 0.1% sodium hydroxide solution. This flush will dissolve any scale that deposits on the membranes.

The total amount of flushing solution will average approximately 5,000 gallons per event. Sodium bisulfite is used to preserve the membranes during long-term shutdown periods. Approximately 15 lbs. of sodium bisulfite per year is used in this manner.

The chemical cleaning involves several steps and may contain citric acid, hydrochloric acid, phosphoric acid, sodium hydroxide, anda neutral pH detergent. The periodic cleaning process averages approximately 10,000 gallons per event, diverted either to the Turbine Room Sump (Outfall 00H), through the Neutralization Tank to the Turbine Room Sump (Outfall OOH), or to the Circulating Water Forebay (Outfall 001,.002, or 003).

Waste from miscellaneous processes.

During periods when not in operation, the heating boiler may be stored full of treated boiler water containing at most 400 ppm hydrazine [Betz Cortrol OS5035, Betz Cortrol OS5010, NALCO 19H] or 40 ppm carbohydrazide (NALCO 1250 plus, or equivalent) for oxygen scavenging and/or 50 ppm 15

ethanolamine (Betz Powerline 1440, Betz Powerline 1480, NALCO 92UM001) for corrosion protection. Prior to use, this "wet lay-up" water, is drained to the TRS. The volume drained is approximately 600 gallons.

The Circulating Water System cooling water contained in the condensers during shutdowns are periodically drained to the TRS. (Six condenser halves and 2 feedpump condensers, approximately 37,000 gallons of lake water per half).

The Component Cooling Water system (CCW) is periodically drained to allow for equipment inspection, maintenance or repair. This system uses deminerali'zed water from the makeup plant as its source of makeup water along with a maximum of: 1200 ppm nitrite [from Calgon LCS 60, Betz Corrshield NT 4205, BETZ CORRSI-IED NT 4201, Betz Corrshield NT 4203, or equivalent], 100 ppm gluteraldehyde [from Betz Spectrus NX 1105, Calgon H-300, or equivalent], methyl (bis) thiocyanate (10 ppm) [from Betz 3610 or equivalent], 60 ppm tolyltriazole (from Betz AZ8101, Calgon LCS-60, or equivalent) ), 1000 ppm molybdate from Betz Corrshield MD 4103. The infrequent drainings release approximately 60,000 gallons of treated water to the TRS per year.

There are four Emergency Diesel Generators that-are each cooled by an Emergency Diesel Generator cooling jacket water system (D.TW), which employs chemical control for corrosion with a maximum of 2000 ppm nitrite [Calgon LCS 60 or Betz Corrshield NT 4205, BETZ CORRSHIED NT 4201, Betz Corrshield NT 4203 or equivalent], 100 ppm gluteraldehyde [Betz Spectrus NX 1105, Calgon H-300, or equivalent], methyl (bis) thiocyanate (10 ppm) [from Betz 3610 or equivalent], 60 ppm tolyltriazole [Betz AZ8 010, Calgon LCS-60, or equivalent]), 1000 ppm molybdate from Betz Corrshield MD 4103.

This system is drained through the floor drains to the TRS when maintenance is performed. Each system volume is approximately 1000 gallons. Any system leaks would also be directed to the floor drain during normal operations.

Control Room Air Conditioning (CRAC) drains: Approximately.1440 gallons/yr. of CRAC water is drained to the TRS. CRAC Water is demineralized water, and may contain up to: 2000 ppm nitrite

[Calgon LCS 60, Betz Corrshield NT 4205, BETZ CORRSHIED NT 4201, Betz Corrshield NT 4203 or equivalent], 100 ppm gluteraldehyde [Betz Spectrus NX 1105, CalgonH-300, or equivalent],

methyl (bis) thiocyanate (10 ppm) [from Betz 3610 or equivalent], 60 ppm tolyltriazole (Calgon 16

LCS-60, Betz AZ8101, or equivalent) ), 1000 ppm molybdate from Betz Corrshield MD 4103, and Betz Ferroquest FQ7101 and FQ7102 for CRACIHX cleaning. The system may be flushed with demineralized water, and when completed, corrosion control chemicals will be added back to the system. No additions of corrosion controlling chemicals are performed during the demineralized water flush.

The Essential Service Water systems (ESW) and Non-Essential Service Water systems (NESW) are also periodically drained to allow for equipment inspection, maintenance, or repair. These drains may discharge Lake Michigan water used for non-contact cooling into the TRS. This water may be chlorinated for zebra mussel control. During some special treatment periods, this water may contain zebra mussel biocides, used as a molluscicide for zebra mussel control. Periodically, components of the ESW or NESW systems may be chemically cleaned to remove iron deposits using vendor supplied cleaning solution such as EDTA (ethylenediaminetetraacetic acid) or ascorbic acid, acetic acid and ammonia. These wastes could either be drained to the TRS or Lake Michigan via Outfall 001, 002, or 003.

During wet lay-up, the steam generators are stored full of water with up to 400 ppm of hydrazine from Betz Cortrol OS5035, Betz Cortrol OS5010, NALCO 19H or 40 ppmcarbohydrazide (NALCO 1250 plus, or equivalent) and 100 ppm ethanolamine (Betz Powerline 1440, Betz Powerline 1480, NALCO 92UM001) are added for corrosion control. The water may also contain up to 20 ppm boron. This water is normally drained to surface water via NPDES Outfalls O0A or OOB, but may be drained to the TRS in some instances. Drain volume will be approximately 32,000 gallons for each of the unit's four steam generators.

The Miscellaneous Drain Tanks can be aligned to discharge to the TRS. As much as 350,000 gallons per day per unit may be directed to the TRS to control the chemistry limitations on the secondary water systems. Water chemistry is primarily the same as in the steam generators. This type of batch drain occurs in concert with condensate flushing activities, or it may occur during normal operation to adjust system chemistry. The overboarded water is normal secondary water. It may contain a mixture of ethanolamine, hydrazine [Betz Cortrol OS5035, Betz Cortrol OS5010, NALCO 19H], or carbohydrazide (NALCO 1250 plus, or equivalent). Maximum flows may approach 240 GPM as makeup plant water supplies can deliver.

17

Condensate flushes are performed periodically to clean up the plant's secondary system prior to startup, and can be discharged to the TRS. Water containing up to 4 ppm hydrazine [Betz Cortrol OS5035, Betz Cortrol OS5010, NALCO 19H], 10 ppm carbohydrazide (NALCO 1250 plus, or equivalent), 100 ppm ethanolamine (Betz Powerline 1440, Betz Powerline 1480, NALCO 92UM00 1), is overboard to the TRS as required to remove contaminants. This flow rate averages 70 GPM, but may reach 600 GPM for short periods of time. The flow rate is dependent on water demands in the plant. Maximum output from the MULP is approximately 600 GPM.

Around the plant, miscellaneous sumps collect an estimated 45,000 GPD of water from various equipment drains (ESW pipe tunnel sump). Water and condensate leaks from valves and pumps (Circulating Water condenser pit sumps, ESW pipe tunnel sump, heater drain pump room sump, screen wash pump room sump, acid and caustic room sumps, elevator pit sumps, screenhouse electrical equipment enclosure sump) will also be drained to the TRS. Steam jet air ejector drains also are directed to the heater drain pump room sump prior to pumping to the TRS. Betz FerroQuest FQ LP 7200 may be added to this sump to prevent scale buildup.

Miscellaneous floor drains are located throughout the plant to provide a safe working environment by routing spilled or leaked water to the TRS. The major chemical influx into these drains is from general floor cleaning products used to maintain the floors. Also routed to the TRS through the floor drains are fire protection water, chlorinated Lake Township water, drinking water, cooling water (ESW/NESW), and drains from bioboxes used to monitor the zebra mussel control measures and other chemical control monitors. The bioboxes will discharge chlorine and zebra mussel biocides during periods when the Service Water Systems are treated with previously mention biological control agents.

Chemical feed tank drains (drains are limited to emergencies only). There are eight chemical feed tanks that are approximately 200 gallons each that contain hydrazine [Betz Cortrol OS5035, Betz Cortrol OS5010, NALCO 1911] at approximately 2%, ethanolamine (Betz Powerline 1440, Betz Powerline 1480, NALCO 92UM001), at approximately 5%, carbohydrazide (NALCO 1250 plus, or equivalent), approximately 2%. Normal process will be to collect these tank volumes to be reused whenever possible.

18

Chemical cleaning tank drains: During refueling and maintenance outages, the chemical cleaning tank, and or temporary tanks may be used to mix borax (sodium tetraborate @ approximately 2000 ppm as boron) solutions for ice making operations. Small portions of the system may be drained to the TRS. In the unlikely event that a full tank is drained, approximately 3500 gallons will be directed to the TRS.

Non-radiological chemical lab sink and floor drains are routed to the TRS for disposal. The drains carry water and the wastes generated while performing analyses and preparing laboratory standard including those on the attached list. Also discharged will be glassware cleaning and normal laboratory cleaning wastes. The average volume directed to the TRS is estimated to be 500 -1000 GPD.

Secondary sample water from continuous analyzers are routed to drains which discharge to the TRS and/or the miscellaneous drain tank. The analyzers are on the cycles that may contain as much as 1-50 ppb hydrazine from either a direct feed or (as a breakdown product of carbohydrazide, and 2.5 ppm ethanolamine). The analyzers measure corrosion transport at an average flow of 1440 gallons per day when in operation.

Miscellaneous sealing and cooling water (MSCW) supplies cooling and sealing water to the TRS pumps, Condensate Booster Pumps, Circulating Water Pumps, Vacuum Priming Pumps, Drain Seal Reservoir Tanks, MSCW pump sealing water, screen wash pumps sealing water, and Drain Sample Coolers. The flow per day may reach approximately 576,000 gallons; this water is filtered and chlorinated Lake Michigan water.

o Non-essential service water supplies approximately 53,000 GPD of non-contact cooling water to various sample coolers throughout the plant's turbine building.

19

Chemical spills that enter the TRS may be neutralized within the sump to prevent a discharge to the environment. The potential for spills to the TRS exists for the following chemicals with the proposed neutralizers listed:

Chemical Associated Neutralizer Sulfuric acid Sodium hydroxide Sodium hydroxide Sulfuric acid Sodium hypochlorite Sodium thiosulfate Hydrazine NESW (lake water), Hydrogen peroxide, sodium hypochlorite.

Ethanolamine Sodium Hypochlorite, Hydrogen Peroxide, or ozone.

Ethylene glycol Hydrogen peroxide Reduction of hydrazine and ETA prior to discharge to the absorption pond may include additions of chemicals such as sodium hypochlorite, hydrogen peroxide, or ozone to the Turbine Room Sump in batches, or to the discharge piping as continuous treatment. A downstream treatment system provided by a vendor may be used to break down the hydrazine and ETA.

20

ADDITIONAL CHEMICAL LAB ANALYSES Additional Information Section I Item 11 Donald C. Cook Nuclear Plant Surface Water Permit Application Plant Chemistry Lab (To Outfall OOH/OOD)

Laboratory sink drains from the 633' Turbine lab are directed to the 90,000 gallon Turbine Room Sump.

The sump contents are normally directed to the groundwater discharge (outfall GOD). Occasionally the Emergency by-pass may be utilized and the sump's contents will be discharged to the surface water discharge (outfall OGH). The following analyses are performed in the lab. Laboratory wastes from the analyses are discarded in the sink.

Parameter Analysis Method Nitrite HACH DR-2000 Method 373, HACH DR 2010 Method 373 Hydrazine ASTMD-1385 -88 Oil and Grease EPA-600-4-79-020 Method 413.1 pH Standard Methods for the examination of Water and Wastewater, ASTM-1293 Total Phosphorus EPA-600-4-79-029 Method 365.3 Sulfate EPA-600-4-79-020 Method 375.4 Total Residual Chlorine EPA-600-4-79-020 Method 330.5 Ethanolamine (ETA)

Betz Standatd Operating Procedure. (Betz proprietary Method adapted from HACH Dr-2000 1,2-Naphthoguinone-4-sulfonic acid Method.)

ICP Metals Standard Methods for Examination of water and wastewater - 17th ed. 1989, 3120B.

Tolyltriazole HACH DR-2000 Method 730 Carbohydrazide HACH DR-2000 Method 732 HACH DR-2010 Method 182 N,N Diethyihyroxylamine (DEI-A)

HACH DR-2010 Method 182 Silica ASTM D 859-88 21

GROUNDWATER DISCHARGES OUTFALL 00D - Turbine Room Sump Utility wastewater from within the plant is discharged via the turbine room sump (TRS) into an on-site absorption pond (Outfall OOD). The normal disposition of these wastewaters is to an on-site absorption pond, which eventually vents via groundwater to Lake Michigan. In the unlikely event that the normal flow path to the absorption pond is not available, the overflow line (Outfall OOH) will direct the TRS flow to the plant's intake forebay. The wastewaters associated with this Outfall include:

Wastes from the makeup water treatment system.

NESW: (144,000 GPD) The main contributor to this waste stream is the degassifier pump seal water.

Non-Essential Service Water (NESW) from Lake Michigan supplies the vacuum degassifier pumps which utilize up to 100 GPM to remove non-condensable gases (primarily carbon dioxide and oxygen) from the makeup plant water and exhausts them to the atmosphere.

• Pre-filter backwash: (Estimated 98,000 GPD) Six pre-filters are backwashed with Lake Michigan water to remove the suspended matter captured on the filter media. Alum solution (aluminum sulfate 0.5 lb. per gallon) is added to the pre-filter influent as a flocculent.. The alum is added via a coagulant feed pump. Approximately 50 lb./day of alum is used in this process. The alum contained in the backwash is discharged in the form of insoluble aluminum hydroxide.

Carbon filter backwash: (Estimated 42,000 GPD) Carbon filters are periodically backwashed with Lake Michigan water to the TRS. These filters primarily remove organics, chlorine and small amounts of iron.

Dernineralizer regeneration: (Estimated 50,000 gallons per regeneration) occurs 2-4 times per month when the RO is in service and more often when it is not in service. Dilute sulfuric acid and sodium hydroxide used by the system to regenerate the resin. Dilute sulfuric acid, sodium hydroxide, and contaminates from the demineralization process is discharged to the neutralization tank or TRS.

The pH is then adjusted.to between 5.5 and 9.0 with sulfuric acid, or sodium hydroxide prior to discharge.

22

• MUP Neutralization Tank provides a place for dermineralization regeneration wastes, and.Reverse Osmosis Unit cleaning flushes to be neutralized prior to being discharged to the TRS and ultimately the absorption pond. When the MUP resin beds are regenerated, up to 50,000 gallons of regeneration chemicals, and backwash waters are processed in the neutralization tank. The Reverse Osmosis cleaning flushes average approximately 5,000 gallons per event. When the water is neutralized, it is pumped to the TRS via a 2,000 GPM neutralization waste pump.

The Retention Tank is periodically blown down, discharging small volumes of solid material removed by settling. The retention tank contains a mixture of Lake Township water and filtered Lake Michigan water waiting further processing by the Makeup Plant.

The Reverse Osmosis System (RO) Cleaning. Normal reject water flow is to Lake Michigan'via Outfall 00G. The RO system must maintain very clean membranes to assure efficient operation and purity of water. Several Methods are used to maintain this level of cleanliness from scale and biofouling. Hydrochloric acid or sulfuric acid is fed at approximately 1.3 GPH continually when the RO is in service to lower the pH to reduce the scaling tendencies of the water. The reject water from the RO unit consists of concentrated Lake Michigan water and a smhall amount of acid that inhibits scale buildup in the membranes.

Approximately once per month, a flush is performed using approximately 1,000 gallons of a nominal 0.05% hydrochloric acid solution. This is followed with approximately 1,000 gallons of a nominal 0.1% sodium hydroxide solution. This flush will dissolve any scale that deposits on the membranes.

The total amount of flushing solution will average approximately 5,000 gallons per event. Sodium bisulfite is used to preserve the membranes during long-term shutdown periods. Approximately 15 lbs. of sodium bisulfite per year is used in this manner.

The chemical cleaning involves several steps and may contain citric acid, hydrochloric acid, phosphoric acid, sodium hydroxide, and a neutral pH detergent. The periodic cleaning process averages approximately 10,000 gallons per event, diverted either to the Turbine Room Sump (Outfall 00H), through the Neutralization Tank to the Turbine Room Sump (Outfall 00H), or to the Circulating Water Forebay (Outfall 001, 002, or 003).

23

Waste from miscellaneous processes.

" During periods when not in operation, the heating boiler may be stored full of treated boiler water containing at most 400 ppm hydrazine [Betz Cortrol OS5035, Betz Cortrol OS5010, NALCO 19H] or 40 ppm carbohydrazide (NALCO 1250 plus, or equivalent) for oxygen scavenging and/or 50 ppm ethanolamine (Betz Powerline 1440, Betz Powerline 1480, NALCO 92UM001) for corrosion protection. Prior to use, this "wet lay-up" water is drained to the TRS. The, volume drained is approximately 600 gallons.

The Circulating Water System cooling water contained in the condensers during shutdowns are periodically drained to the TRS. (Six condenser halves arnd 2 feedpump condensers, approximately 37,000 gallons of lake water per half).

The Component Cooling Water system (CCW) is periodically drained to allow for equipment inspection, maintenance or repair. This system uses demineralized water from the makeup plant as its source of makeup water along with a maximum of: 1200 ppm nitrite [from Calgon LCS 60, Betz Corrshield NT 4205, BETZ CORRSHIED NT 4201, Betz Corrshield NT 4203, or equivalent], 100 ppm gluteraldehyde [from Betz Spectrus NX 1105, Calgon H-300, or equivalent], methyI (bis) thiocyanate (10 ppm) [from Betz 3610 or equivalent], 60 ppm tolyltriazole (from Betz AZ8101, Calgon LCS-60, or equivalent) ), 1000 ppm molybdate from Betz Corrshield MD 4103. The infrequent drainings release approximately 60,000 gallons of treated water to the TRS per year.

o There are four Emergency Diesel Generators that are each cooled by an Emergency Diesel Generator cooling jacket water system (DJW), which employs chemical control for corrosion with a maximum of 2000 ppm nitrite [Calgon LCS 60 or Betz Corrshield NT 4205, BETZ CORRSHIED NT 4201, Betz Corrshield NT 4203 or equivalent], 100 ppm gluteraldehyde [Betz Spectrus NX 1105, Calgon H-300, or equivalent], methyl (bis) thiocyanate (10 ppm) [from Betz 3610 or equivalent], 60 ppm tolyltriazole [Betz AZ8 101, Calgon LCS-60, or equivalent] ), 1000 ppm molybdate from Betz Corrshield MD 4103.

This system is drained through the floor drains to the TRS when maintenance is performed. Each system volume is approximately 1000 gallons. Any system leaks would also be directed to the floor drain during normal operations.

24

Control Room Air Conditioning (CRAC) drains: Approximately 1440 gallons/yr. of CRAC water is drained to the TRS. CRAC Water is demineralized water, and may contain up to: 2000 ppm nitrite

[Calgon LCS 60, Betz Corrshield NT 4205, BETZ CORRSHIED NT 4201, Betz Corrshield NT 4203 or equivalent], 100 ppm gluteraldehyde [Betz Spectrus NX 1105, Calgon H-300, or equivalent],

methyl (his) thiocyanate (10 ppm) [from Betz 3610 or equivalent], 60 ppm tolyltriazole (Calgon LCS-60, Betz AZ8 101, or equivalent) ), 1000 ppm molybdate from Betz Corrshield MD 4103, and Betz Ferroquest FQ7101 and FQ7102 for CRAC HX cleaning. The system may be flushed with demineralized water, and when completed, corrosion control chemicals will be added back to the system. No additions of corrosion controlling chemicals are performed during the demineralized water flush.

The Essential Service Water systems (ESW) and Non-Essential Service Water systems (NESW) are also periodically drained to allow for equipment inspection, maintenance, or repair. These drains may discharge Lake Michigan water used for non-contact cooling into the TRS. This water may be chlorinated for zebra mussel control. During some special treatment periods, this water may contain zebra mussel biocides, used as a molluscicide for zebra mussel control. Periodically,. components of the ESW or NESW systems maybe chemically cleaned to remove iron deposits using vendor supplied cleaning solution such as EDTA (ethylenediaminetetraacetic acid) or ascorbic acid, acetic acid and ammonia. These wastes could either be drainedto the TRS or Lake Michigan via Outfall 001, 002, or 003.

During wet lay-up, the steam generators are stored full of water with up to 400 ppm of hydrazine from Betz Cortrol OS5035, Betz Cortrol OS5010, NALCO 19H or 40 ppm carbohydrazide (NALCO 1250 plus, or equivalent) and 100 ppm ethanolamine (Betz Powerline 1440, Betz Powerline 1480, NALCO 92UM00 1) are added for corrosion control. The water may also contain up to 20 ppm boron. This water is normally drained to surface water via NPDES Outfalls O0A or 0OB, but may be drained to the TRS in some instances. Drain volume will be approximately 32,000 gallons for each of the unit's four steam generators.

The Miscellaneous Drain Tanks can be aligned to discharge to the TRS. As much as 350,000 gallons per day per unit may be directed to the TRS to control the chemistry limitations on the secondarywater systems. Water chemistry is primarily the same as in the steam generators. This type of batch drain occurs in concert with condensate flushing activities, or it may occur during normal operation to adjust system chemistry. The overboarded water is normal secondary water. It 25

may contain a mixture of ethanolamine, hydrazine [Betz Cortrol OS5035, Betz Cortrol OS5010, NALCO 19H], or carbohydrazide (NALCO 1250 plus, or equivalent). Maximum flows may approach 240 GPM as makeup plant water supplies can deliver.

Condensate flushes are performed.periodically to clean up the plant's secondary system prior to startup, and can be discharged to the TRS. Water containing up to 4 ppm hydrazine [Betz Cortrol OS5035, Betz Cortrol OS5010, NALCO 19H], 10 ppm carbohydrazide (NALCO 1250 plus, or equivalent), 100 ppm ethanolamine (Betz Powerline 1440, Betz Powerline 1480, NALCO 92UM00 1), is overboard to the TRS as required to remove contaminants. This flow rate averages 70 GPM, but may reach 600 GPM for short periods of time. The flow rate is dependent on water demands in the plant. Maximum output from the MUP is approximately 600 GPM.

Around the plant, miscellaneous sumps collect an estimated 45,000 GPD of water from various equipment drains (ESW pipe tunnel sump). Water and condensate leaks from valves and pumps (Circulating Water condenser pit sumps, ESW pipe tunnel sump, heater drain pump room sump, screen wash pump room sump, acid and caustic room sumps, elevator pit sumps, screenhouse.

electrical equipment enclosure sump) will also be drained to the TRS. Steam jet air ejector drains also are directedto the heater drain pump room sump prior to pumping to the TRS. Betz FerroQuest FQ LP 7200 may be added to this sump to prevent scale buildup.

Miscellaneous floor drains are located throughout the plant to provide a safe working environment by routing spilled or leaked water to the TRS. The major chemical influx into these drains is from general floor cleaning products used to maintain the floors. Also routed to the TRS through the floor drains are fire protection water, chlorinated Lake Township water, drinking water, cooling water (ESW/NESW), and drains from bioboxes used to monitor the zebra mussel control measures and other chemical control monitors. The bioboxes will discharge chlorine and zebra mussel biocides during periods when the Service Water Systems are treated with previously mention biological control agents.

Chemical feed tank drains (drains are limited to emergencies only). There are eight chemical feed tanks that are approximately 200 gallons each that contain hydrazine [Betz Cortrol OS5035, Betz Cortrol OS5010, NALCO 19H] at approximately 2%, ethanolamine (Betz Powerline 1440, Betz Powerline 1480, NALCO 92UM001), at approximately 5%, carbohydrazide (NALCO 1250 plus, or 26

equivalent), approximately 2%. Normal process will be to collect these tank volumes to be reused whenever possible.

Chemical cleaning tank drains: During refueling and maintenance outages, the chemical cleaning tank, and or temporary tanks may be used to mix borax (sodium tetraborate @ approximately 2000 ppm as boron) solutions for ice making operations. Small portions of the system may be drained to the TRS. In the unlikely event that a full tank is drained, approximately 3500 gallons will be directed to the TRS.

Non-radiological chemical lab sink and floor drains are routed to the TRS for disposal. The drains carry water and the wastes generated while performing analyses and preparing laboratory standards including those on the attached list. Also discharged will be glassware cleaning and normal laboratory cleaning wastes. The average volume directed to the TRS is estimated to be 500 -1000 GPD.

Secondary sample water from continuous analyzers are routed to drains which discharge to the TRS and/or the miscellaneous drain tank. The analyzers are on the cycles that may contain as much as 150 ppb hydrazine from either a direct feed or (as a breakdown product of carbohydrazide, and 2.5 ppm ethanolamine). The analyzers measure corrosion transport at an average flow of 1440 gallons per day when in operation.

Miscellaneous sealing and cooling water (MSCW) supplies cooling and sealing water to the TRS pumps, Condensate Booster Pumps, Circulating Water Pumps, Vacuum Priming Pumps, Drain Seal Reservoir Tanks, MSCW pump sealing water, screen wash pumps sealing water, and Drain Sample Coolers. The flow per day may reach approximately 576,000 gallons; this water is filtered and chlorinated Lake Michigan water.

Non-essential service water supplies approximately 53,000 GPD of non-contact cooling water to various sample coolers throughout the plant's turbine building.

27

Chemical spills that enter the TRS may be neutralized within the sump to prevent a discharge to the environment. The potential for spills to the TRS exists for the following chemicals with the proposed neutralizers listed:

Chemical Associated Neutralizer Sulfuric acid Sodium hydroxide Sodium hydroxide Sulfuric acid Sodium hypochlorite Sodium thiosulfate Hydrazine NESW (lake water), Hydrogen peroxide, sodium hypochlorite.

Ethanolamine Sodium Hypochlorite, Hydrogen Peroxide, or ozone.

Ethylene glycol Hydrogen peroxide Reduction of hydrazine and ETA prior to discharge to the absorption pond may include additions of chemicals such as sodium hypochlorite, hydrogen peroxide, or ozone to the Turbine Room Sump in batches, or to the discharge piping as continuous treatment. A downstream treatment system provided by a vendor may be used to break down the hydrazine and ETA.

28

ADDITIONAL CHEMICAL LAB ANALYSES Additional Information Section I Item 11 Donald C. Cook Nuclear Plant Surface Water Permit Application Plant Chemistry Lab (To Outfall OOL/OOD)

Laboratory sink drains from the 633'Turbine lab are directed to the 90,000 gallon Turbine Room Sump.

The sump contents are normally directed to the groundwater discharge (outfall 0OD). Occasionally the Emergency by-pass may be utilized and the sump's contents will be discharged to the surface water discharge (outfall OOH). The following analyses are performed in the lab. Laboratory wastes from the analyses are discarded in the sink.

Parameter Analysis Method Nitrite HACH DR-2000 Method 373, I-HACH DR 2010 Method 373 Hydrazine ASTM D-1385 -88 Oil and Grease EPA-600-4-79-020 Method 413.1 pH Standard Methods for the examination of Water arid Wastewater, ASTM-1293 Total Phosphorus EPA-600-4-79-020 Method 365.3 Sulfate EPA-600-4-79-020 Method 375.4 Total Residual Chlorine EPA-600-4-79-020 Method 330.5 Ethanolarine (ETA)

Betz Standard Operating Procedure. (Betz proprietary Method adapted from HACH Dr-2000 1,2-Naphthoquinone-4-sulfonic acid Method).

ICP Metals' Standard Methods for Examination of water and wastewater - 17t" ed. 1989, 3120B.

Tolyltriazole HACH DR-2000 Method 730 Carbohydrazide HACH DR-2000 Method 732 HACH DR-20 10 Method 182 N,N Diethylhyroxylamine (DEHA)

HACH DR-2010 Method 182 Silica ASTM D 859-88 OUTFALL 00E - Sanitary Waste Discharaes The system operates at a designed flow of 50,000 GPD with a maximum flow capacity of 60,000 GPD.

The Sequencing Batch Reactor (SBR) system treats the wastewater and discharges to an effluent tank where it can be filtered prior to discharge to one of two seepage lagoons. The lagoons discharge into the groundwater with the ultimate disposition venting to Lake Michigan. The sludge removed from the digester tank basins is taken to a local POTW (public owned treatment works) for disposal or dewatered and stored as low level radioactive waste, and disposed of as appropriate.

29

To aid in the settling process, flocculents such as ferric chloride, pH controllers such as magnesium hydroxide, or polymers (such as Axchem AF4500) are added to the process. To selectively enhance biosolids, bioaugmentation nutrients (such as Bioprime Dosfolat) are added to the process. This is a nutrient that encourages the growth of beneficial microbes in the activated sludge. Sodium hypochlorite is added in small amounts to the process to control filamentous bacteria growth if needed. Sodium hypochlorite and detergent are also added to the sand filters to clean them periodically. These are then backwashed into the equalization basin to be reprocessed by the SBR treatment process.

Plant sanitary waste consists of shower and rest room facilities, and janitor washbasins located throughout the Plant's non-radiological property. Kitchen wastes are generated from the plant cafeteria, the Cook Energy Information Center and Training buildings.

The chemistry training laboratory discharges to the sewage treatment plants through a limestone bed neutralization tank. The chemistry lab is used to train technicians on analyses performed in the plant.

The discharge from the lab carries water and wastes generated while performing analyses and preparing laboratory standards including those on the attached list. The training building HVAC system also drains through the limestone bed.

The wastewater treatment plant laboratory discharges to the sewage treatment plants. The discharge from the lab carries water and wastes generated from performing analyses and preparing laboratory standards used for compliance monitoring of the sewage treatment plant under groundwater discharge permit GW1810102.

Portable toilet wastes on the plant site may be collected anddischarged to the sewage treatment, plants.

A biodegradable deodorant is used in the portable toilets. Sludge effluent waste may also be recycled through the plants to decrease the amount of sludge for processing when possible.

Miscellaneous rinsing of waste receptacles and possible cleaning operations waste, utilizing various detergents, may be rinsed to the sewage treatment plants.

30

Donald C. Cook Nuclear Plant MI0005827 Part 11

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Donald C. Cook Nuclear Plant Part 11 M10005827 OU0AO1

Michigan Department of Environmental Quality-Water Bureau WASTEWATER DISCHARGE PERMIT APPLICATION SECTION I - General Information PLEASE TYPE OR PRINT CILITY NAME

.onald C. Cook Nuclear Plant I NPDES PERMIT NUMBER MI 0005827

12. CONTRACT LABORATORIES THAT PROVIDE ANALYTICAL SUPPORT El No Change From Last Application Provide the name and address of each contract laboratory or consulting firm that performed any analyses submitted as part of this Application. To submit additional information, see Page ii, Item 3.

Laboratory Name Laboratory Name John E. Dolan Labs General Engineering Labs Street Address Street Address 4001 Bixby Road 2040 Savage Road City State ZIP Code City State ZIP Code Groveport Ohio 43125 Charleston South Carolina 29407 Telephone (with area code)

Fax (with area code)

Telephone (with area code)

Fax (with area code)

(614) 836-4215 (614) 836-4168 (843) 556-8171 (843) 766-1178' Analysis Performed Analysis Performed Oil and Grease, routine DMR compliance analyses Required Table 2-5 analyses from appendix.

Laboratory Name Laboratory Name KAR Labs Cook Nuclear Plant Street Address Street Address 4425 Manchester Road 1 Cook Place City State ZIP Code City State ZIP Code Kalamazoo Michigan 49001 Bridgman Michigan 49106 Telephone (with area code)

Fax (with area code)

Telephone (with area code)

Fax (with area code)

(269) 381-9666 (269) 381-9698 (269) 465-5901x 2006 1(269)-466-2550 Analysis Performed Analysis Performed Total Available Cyanide OIA-1677 Routine DMR compliance analyses.

I. LIST ADJACENT PROPERTY OWNERS El No Change From Last Application List the names and mailing addresses of all property owners for all properties adjacent to the facility, treatment systems, and discharge locations.

For vacant lots or empty buildings, supply the owner's mailing address - NOT the lot or building property address. To submit additional information, see Page ii, Item 3.

Name Address City State ZIP Code See attached.

I 4

EQP 4659-A (Rev. 11/2007)

Michigan Department of Environmental Quality-Surface Water Quality Division Wastewater Discharge Permit Application SECTION I - General Information PLEASE TYPE OR PRINT ACILITY NAME NPDES PERMIT OR COC NUMBER Donald C. Cook Nuclear Plant Ml0005827 13 List adjacent property owners List the names and addresses of all property owners adjacent to the facility, treatment systems, and discharge locations. List this information in the space provided below or include the information as an attachment on 8 1/2" x 1 1" paper. If additional space is necessary, copy this blank page and attach this information to this application.

Location Property Number Name Address NORTH Grand Mere State 11-11-0006-0002-03-1 Michigan Department of Natural PO Box 30735 Park Resources Lansing, MI 48909 Rosemary Beach 11-11-0006-0004-02-5 Rosemary Beach Corp.

C/O Secretary 3415 S. 59 St.

Cicero IL 60650 Rosemary Beach 11-11-0006-0004-00-9 Franklin Real Estate c/o Indiana Michigan Power Co. PO Box 16428 Columbus OH 43216 Attn: Tax section.

Rosemary Beach 11-11-0006-0004-01-7 Caparo, William E. & Oyler, Kathryn E.

122 S. Ellsworth Pl.

South Bend, IN 46635 Rosemary Beach 11-11-0006-0004-04-1 Temmel, Edward P.

9617 E. Shore Dr.

Oak Lawn IL 60453 Rosemary Beach 11-11-0006-0004-09-2 Mcaloon, Sharon 1707 Dumont Ln Schaumburg, IL 60194 Rosemary Beach 11-11-0006-0004-05-0 West, Kathleen M.

3423 N. Seminary Ave Trustee Chicago, IL 60657 Rosemary Beach 11-11-0006-0004-10 Olofsson, Erik J.

P0 Box 74 Stevensville, MI 49127 Rosemary Beach 11-11-0006-0004-11 Olofsson, Harold W.

P0 Box 299 Oak Lawn, IL 60454 Rosemary Beach 11-11-0006-0004-12 Addante, Joseph 576 Hawhorne Elmhurst IL 60126-3301 Rosemary Beach 11-11-6800-0026-10 O'Malley, Sean A.

5025 N. Central Park

+ Wyse, Jeffery D.

Chicago, IL 60625 Rosemary Beach 11-11-6800-0026-09 O'Malley, Sean A:

5025 N. Central Park

+ Wyse, Jeffery D.

Chicago, IL 60625 Rosemary Beach 11-11-6800-0027-02-0 Herbert, Rosemary C.

22 S. Archer Ave Mundelein IL 60060 Rosemary Beach 11-11-6800-0028-00-0 Herbert, Rosemary C.

22 S. Archer Ave Mundelein IL 60060 Rosemary Beach 11-11-6800-0028-01-8 Balka, Janet M.

3334 Louise Dr.

Lansing, IL 60438 Rosemary Beach 11-11-6800-0030-02-1 Gottschall, Bruce A. & Susan M.

5760 S. Blackstone Chicago, IL 60637 Rosemary Beach 11-11-6800-0032-01-5 Giese Marie E.

4291 Lake Road Stevensville, MI 49127 Rosemary Beach 11-11-6800-0033-00-3 Gilpin, Nancy 714 S Dearborn #8 Chicago, IL 60605 Rosemary Beach 11-11-6800-0036-00-2 Lewis, James G. Jr.

4183.Lake Ct.

Stevensville, MI 49127 Rosemary Beach 11-11-6800-0037-00-9 Kobler, Rich +Matthews, Larry.

4155 Lake Road Stevensville, MI 49127 Rosemary Beach 11-11-6800-0037-01-7 Gielniewski, MichaelZ. & Teresa B.

1113 Independence Road Bartlett, IL 60103

Section !, Item 13 Adjacent Property Owners Paae 2 of 2 MI0005827 Location Property Number Name Address Rosemary Beach 1 1-11-6800-0037-02-5 Tengerstrom Eric H.

7470 Rosemary Rd Trustee LE & Martin, Holly Stevensville, MI 49127 Rosemary Beach 11-11-6800-0038-00-5 Tengerstrom, Eric H.

747Q Rosemary Rd Trustee LE & Martin, Holly Stevensville, MI 49127 NORTH 11-11-0005-0029-00-3 Technisand, Inc.

P0 Box 177 Wedron, IL 60557 NORTH 11-11-0005-0027-00-1 Technisand, Inc.

PO Box 177 Wedron, IL 60557 NORTH 11-11-0005-0036-01-8 Ruff, Timothy W.

7500 Thorton Dr.

_Stevensville, MI 49127 NORTH 11-11-0005-0036-06-9 Emery, Martin; Hopkins, Elwood J. &

7499 Thorton Dr.

Mable N.;

Stevensville, MI 49127 NORTH 11-11-0005-0036-02-6 Indiana Michigan Power Company C/O. P0 Box 16428 Columbus OH 43216 Attn: Tax section.

EAST 11-11-0005-0024-00 Marshke, Dale A.

7552 Jericho Road Stevensville MI 49127 EAST 11-11-0005-0016-00 Westlake, Anita 7622 Red Arrow Highway Stevensville, MI 49127 EAST 11-11-0005-0002-01-6 Blue Jay Assoc.

C/O. P0 Box 16428 (VISITOR CENTER)

Columbus OH 43216 Attn: Tax section.

EAST Interstate 1-94 Michigan Dept of State Highways SOUTH 11-11-0008-06-00 Indiana Michigan Power Company C/O. P0 Box 16428 Columbus OH 43216 Attn: Tax section.

SOUTH 11-11-0008-0041-00-8 Michigan Dept. of Transportation Lansing MI 48900 SOUTH 11-11-0008-0009-00-7 Franklin Real Estate C/O P0 Box 16428 Columbus OH 43216 Attn: Tax section..

SOUTH 11-11-0007-0013-00-6 Lake Charter Twp.

Shawnee Rd.

Bridgman, MI 49106 SOUTH 11-11-0007-0013-01-4 Lake Charter Twp.

Shawnee Rd.

Bridgman, MI 49106 SOUTH 11-11-0007-0006-01-8 Indiana Michigan Power Company C/O P0 Box 16428 Columbus OH 43216 Attn: Tax section.

SOUTH 11-11-0007-0004-01-5 Lake Charter Twp.

Shawnee Rd.

Bridgman, MI 49106 SOUTH 11-11-0007-0001-01-6 Lake Charter Twp.

Shawnee Rd.

Bridgman, MI 49106 WEST Lake Michigan State of Michigan and F

United States of America

Michigan Department of Environmental Quality-Water Bureau WASTEWATER DISCHARGE PERMIT APPLICATION SECTION I - General Information PLEASE TYPE OR PRINT

'CILITY NAME NPDES PERMIT NUMBER

.nald C. Cook Nuclear Plant TMI0005827 14.. APPLICATION CERTIFICATION Rule 323.2114(1-4), promulgated under the Michigan Act, requires that this Application must be signed as follows:

A. For an organization, company, corporation, or authority, by a principal executive office, vice president, or higher.

B. For a partnership, by a general partner.

C. For a sole proprietor, by the proprietor.

D. For a municipal, state, or other public facility, by a principal executive officer or ranking elected official (such as the mayor, village president, city or village manager, or clerk).

Note: If the signatory is not listed above, but is authorized to sign the Application, please provide documentation of that authorization.

"1 certify under penalty of law that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and'belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fine and imprisonment for having knowledge of violations."

The last application for this facility was submitted on: March 28, 2003 I understand that my signature constitutes a legal agreement to comply with the requirements of the NPDES Permit. I certify under penalty of law that I possess full authority on behalf of the legal owner/permittee to sign and submit this application.

Jon H. Hamer Environmental Manager Print Name:

Title:

Signature:

i. I1.

/7 Date:

2/

This completesSection I.

Publicly-Owned Treatment Works (POTWs) discharging sanitary and industrial wastewater to the.

surface waters, and privately-owned treatment works discharging sanitary wastewater to the surface waters should complete Section Ii. Privately-owned treatment works include, but are not limited to, Mobile Home Parks, Campgrounds, Condominiums, Hotels and Motels, Nursing Homes, etc. All other applicants should complete Section III. If assistance is needed to complete this Application, contact the Permits Section.

Permit Application Submittal Checklist Please confirm the following before submitting the Application Form:

0 1.Section I has been completed, including all diagrams, maps, and the treatment process narrative.

E 2. The Application has been signed as required above in Section 1.14. (A.-D.) or a copy of the letter authorizing the signatory to sign the letter has been included, as appropriate.

Z 3.Section II or Section III has been completed, including any additional information or submissions.

0 4.Section IV has been completed by any facility that discharges storm water.

5. A check or Money Order for the appropriate Application Fee has been made out to the "State of Michigan" and has been included with the Application submittal.

5 5EQP 4659-A (Rev. 11/2007)

Michigan Department-of Environmental Quality-Water Bureau WASTEWATER DISCHARGE PERMIT APPLICATION SECTION II - General Information PLEASE TYPE OR PRINT Section II is to be completed by Publicly-Owned Treatment Works discharging treated or untreated sanitary and industrial wastewater to the surface waters.

-tion Il is also to be completed by all privately-owned treatment works discharging treated sanitary wastewater to the surface waters. The privately-owned

.ment works include, but are not limited to, Mobile Home Parks, Campgrounds, Condominiums, Hotels and Motels, and Nursing Homes.

A. Facility Information FACILITY NAME NPDES PERMIT NUMBER THIS SECTION IS NOT REQUIRED TO BE FILLED OUT

1.

WATER SUPPPLY INFORMATION EJ No Change From Last Application List the source(s) of the water supply in the area served by sewers. Identify groundwater wells and surface water intakes, as well as the name(s) of any surface water(s) from which intake water is drawn.

2.

SERVICE AREA INFORMATION E2 No Change From Last Application Publicly-Owned Treatment Works are required to provide the following information: List the governmental jurisdictions (cities, townships, villages, etc.) that this facility serves (applicants should include themselves). What is the population in each jurisdiction? Is the jurisdiction's collection system separate, combined, or both? If the collection system is both separate and combined, what percentage is combined? To submit additional information, see Page ii, Item 3.

Municipality and E-Mail Address Type of Collection System Percent Combined Population Served F1 Separate E2 Combined

[I Separate E2 Combined E2 Separate 12 Combined E1 Separate 17 Combined El Separate El Combined Total population served by this facility:

Privately-Owned Treatment Works are required to provide the following information:

Describe the area served by this facility (mobile home park, condominium, nursing home, etc.).

Provide the number of residential units served by this facility:

3.

BIOMONITORING FOR ACUTE AND CHRONIC TOXICITY POTWs meeting one or more of the following criteria are required to submit with this Application the results of four Whole Effluent Toxicity (WET) tests for each of the facility's discharge points, excluding combined sewer overflows: 1) POTWs with a design flow rate greater than or equal to one (1) million gallons per day; 2) POTWs with an approved Federal Industrial Pretreatment Program (FIPP); and/or 3) POTWs required to develop a FIPP.

The results of the tests shall be reported using the Acute Toxicity Test Report, Ceriodaphnia dubia Chronic Toxicity Test Report and the Fathead Minnow Chronic Toxicity Test Report available in the Appendix. Please do not submit additional forms or paperwork pertaining to WET tests with this Application.

At a minimum, the applicant shall submit the results of quarterly WET testing for a 12-month period prior to this Application, or the results of annual WET tests conducted during the five years prior to this Application. In addition, the applicant shall submit the results of any other WET tests from the past five years. If a WET test in the past 41/a years revealed toxicity, provide all the information on the cause of toxicity or the results of all toxicity reduction evaluations, if any were conducted. The applicant does not need to submit results for previously-submitted WET Tests. For assistance, see the "Whole Effluent Toxicity Test Guidance and Requirements" section in the Appendix.

.6 EQP 4659-B (Rev. 11/2007)

Michigan Department of Environmental Quality-Water Bureau WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater Section III is to be completed by all facilities classified as Industrial or Commercial facilities. Industrial and Commercial facilities include, but are not limited to, facilities that discharge or propose to discharge a wastewater generated by a production process, a service provided, or through a remediation

.-oject.

Municipal and public facilities are not required to complete Section Ill (unless requesting authorization for discharges other than sanitary astewater).

A. Facility Information PLEASE TYPE OR PRINT FACILITY NAME Donald C. Cook Nuclear Plant NPDES PERMIT NUMBER M10005827

1.

BUSINESS INFORMATION E No Change From Last Application A. Provide up to four Standard Industrial Classification (SIC) or North American Industry Classification System (NAICS) codes, in order of economic importance, which best describe the major products or services provided by this facility.

1.221113 2.4911

3.

4.

B. Indicate if this facility is a primary industry (refer to Table 1 of the Appendix to determine if this facility is a primary industry).

[

Yes. This facility is a primary industry. Indicate tbe primary industry as identified in Table 1 of the Appendix: Steam Electric

[] No. This facility is not a primary industry.

C. Is this facility a Concentrated Animal Feeding Operation (CAFO)?

E Yes. Continue with Section II1.B.11.

[No.

2.

WATER SUPPLY AND DISCHARGE TYPE 17E No Change From Last Application A. Identify all water sources entering the facility and treatment systems, and provide average flows. The volume may be estimated from water supply meter readings, pump capacities, etc. Provide the name of the source where appropriate (i.e., Grand River, Lake Michigan, City of Millpond). To submit additional information, see Page ii, Item 3.

Name and Location of Source Average Volume or Flow Rate Units Municipal Supply Surface Water Intake Private Well Other:

Lake Township water Plant/ Bridgman MI I 0.042 MGD Lake Michigan 2112.005 MGD B.

Identify water discharged by the facility and treatment systems, and provide average flows. If water is first used for one purpose and then is subsequently used for another purpose, indicate the type and amount of the last use. For example, if water is initially used for noncontact cooling water and then for process water, indicate the amount of process water. The amount of water from sources should approximate the amount of water usage. If they are different, provide an explanation.

Average Flow Rate Units Average Flow Rate Units Process Wastewater Contact Cooling Water Noncontact Cooling Water

"*undwater Cleanup 1.027 MGD NA MGD 2111 NA NA NA Sanitary Wastewater Regulated Storm Water High Pressure Test Water Other.'

0.020 MGD 5.169 (calc)

MGD Note: For A and B above, indicate units as MGD (million gallons per day), MGY (million gallons per year), GPD (gallons per day), or other appropriate unit.

18 EQP 4659-C (Rev. 11/2007)

Michigan Department of Environmental Quality-Water Bureau WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information

'i-"mplete a separate Section III.B. - Outfall Information (Pages 20-25) - for each outfall at the facility. Make copies of this

.nk section of the Application as necessary for additional outfalls.

PLEASE TYPE OR PRINT FACILITY NAME NPDES PERMIT NUMBER OUTFALL NUMBER Donald C. Cook Nuclear Plant Mi0005827 INTAKE

1.

OUTFALL INFORMATION - Instructions for this item are on Page 3 of the Appendix.

El No Change From Last Application, Items A. - D.

A.

B.

C.

D.

Receiving Water Hydrologic Unit Code (HUC)

Lake Michigan 04040001 County Township Berrien Lake Town Range Section 1/4 1/4, 1/ 4 Private (French) Land Claim) 06S 19W 06 NW S

Latitude Longitude 41 58.668'

-086 34.448' E.

Type of Wastewater Discharged (check all that apply to this outfall):

El No Change From Last Application, Item E.

El Contact Cooling E] Groundwater Cleanup El Hydrostatic Pressure Test El Noncontact Cooling Water El Process Wastewater El Sanitary Wastewater El Storm Water - not regulated El Storm Water - regulated El Storm water subject to effluent guidelines (indicate under which category):

[

Other - specify (see "Table 8 - Other Common Types of Wastewater" - in the Appendix). Intake water F.

What is the Maximum Design Flow Rate for this outfall: 23 What is the Maximum Authorized Discharge Flow for this outfall for the next five years?

El No Change From Last Application, Items F. - G.

Seasonal Dischargers na - intake MGY (Continue with Item H).

Continuous Dischargers na-intake MGD (Continue with Item I).

H.

Seasonal Discharge:

List the discharge periods (by month) and the volume discharged in the space provided below.

1.

From Through Actual Discharge Volume (MGD)

Annual Total From Through Actual Discharge Volume (MGD)

From Through Actual Discharge Volume (MGD)

From Through Actual Discharge Volume (MGD)

Continuous Discharge:

How often is there a discharge from this outfall (on average)?

Hours/Day Days/Year Batch dischargers are required to provide the following additional information:

Is there effluent flow equalization?

El Yes El No Batch Peak Flow Rate:

Number of batches discharged per day: __

Minimum Average Maximum Batch Volume (gallons)

Batch Duration (minutes)

I 2

EQP 4659-C (Rev. 11/2007)

Michigan. Department of Environmental Quality-Water Bureau WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information DLEASE TYPE OR PRINT

ILITY NAME NPDES PERMIT NUMBER OUTFALL NUMBER donald C. Cook Nuclear Plant MI0005827 INTAKE

2.

PROCESS STREAMS CONTRIBUTING TO OUTFALL DISCHARGE E] No Change From Last Application Federal regulations require that different industries report different information, depending on the type of facility. The information below is used to determine the applicable federal regulations for this facility. An abbreviated list is in the Summary of Information to be reported by Industry Type section of the Appendix. Applicants are required to provide the name and the SIC or the NAICS code for each process at the facility. Facilities with production-based limits must report an estimated annual production rate for the next five years, or the life of the permit If the wastestream is not regulated under federal categorical standards, the applicant is required to report all pollutants which have the reasonable potential to be present in the discharge. To submit additional information, see Page ii, Item 3.-

PROCESS INFORMATION A.

Name of the process contributing to the discharge: __

B.

SIC or NAICS code:

C.

Describe the process and provide measures of production:

PROCESS INFORMATION A.

Name of the process contributing to the discharge: __

B.

SIC or NAICS code:

C.

Describe the process and provide measures of production:

PROCESS INFORMATION A.

Name of the process contributing to the discharge: __

B.

SIC or NAICS code:

C.

Describe the process and provide measures of production:

PROCESS INFORMATION A.

Name of the process contributing to the discharge: __

B.

SIC or NAICS code:

C.

Describe the process and provide measures of production:

PROCESS INFORMATION A.

Name of the process contributing to the discharge:

B.

SIC or NAICS code:

C.

Describe the process and provide measures of production:

PROCESS INFORMATION A.

Name of the process contributing to the discharge:

B.

SIC or NAICS code:

C.

Describe the process and provide measures of production:

3 EQP 4659-C (Rev. 11/2007)

Michigan Department of Enviro ital Quality-Water Bureau WASTEWATER DISCHARGiE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information PLEASE TYPE OR PRINT FACILITY NAME NPDES PERMIT NUMBER OUTFALL NUMBER Donald C. Cook Nuclear Plant M10005827 INTAKE

3.

EFFLUENT CHARACTERISTICS - CONVENTIONAL POLLUTANTS - Instructions for this item are on Page 4 of the Appendix.

F! Check this box if additional information is included as an attachment. To submit additional information, see Page ii, Item 3.

Please Note: Rule 323.1062 allows the use of either Escherichia Coli or Fecal Coliform Bacteria as an indicator that effluent has been disinfected. The MDEQ will use the indicator selected below in the permit issued based on this Aoolication. n-Use Escherichia Coli as an Indicator of disinfection.

171 Use Fecal Coliform Bacteria as an indicator of disinfection.

El Biochemical Oxygen Demand - five day (BOD5) mg/I L] Grab El 24 Hr Comp El Chemical Oxygen Demand (COD) mg/I E] Grab El 24 Hr Comp El Total Organic Carbon (TOC) mg/I El Grab

_] 24 Hr Comp El Ammonia Nitrogen (as N) mg/I El G4 rab o El Grab3 El Total Suspended Solids mg/I El 24 Hr Comp STotal Dissolved Solids mg/I El Grab Te 24 Hr Comp El Grab El Total Phosphorus (as P) mg/I F1 Grab El24 Hr Comp El Fecal Coliform Bacteria (report geometric means)

Maximum-7day counts/100mi Grab' El Escherichia Coli (report geometric means)

Maximum-7day counts/100 ml Grab El Total Residual Chlorine El mg/i Grab

_El.g/I Minimum daily mI Grab El Dissolved Oxygen

-9 ON "1-mg/I El 24 Hr Comp Minimum Maximum El Grab El pH (report maximum and minimum of individual samples) standard units E

24 Hr Comp El Grab El Temperature, Summer El OF E]

EC[]24 Hr Comp El Temperature,Winter F

[IC EGrab El 24 Hr Comp El Oil & Grease mg/I Grab 4

EQP 4659-C (Rev. 11/2007)

Michigan Department of Environmental Quality-Water Bureau WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information PLEASE TYPE OR PRINT

,ILITY NAME NPDES PERMIT NUMBER OUTFALL NUMBER Luonald C. Cook Nuclear Plant I M10005827 INTAKE Note: For questions on this page, Tables 1-5 are found in the Appendix.

4.

PRIMARY INDUSTRY PRIORITY POLLUTANT INFORMATION Existing primary industries that discharge process wastewater are required to submit the results of at least one permittee-collected effluent analysis for selected organic pollutants identified in Table 2 (as determined from Table 1, Testing Requirements for Organic Toxic Pollutants by Industrial Category), and all of the pollutants identified in Table 3. Existing primary industries are required to also provide the results of at least one permittee-collected effluent analysis for any other chemical listed in Table 2 known or believed to be present in the facility's effluent.

In addition, submit the results of all other effluent analyses performed within the last three years for any chemical listed in Tables 2 and 3.

New primary industries that propose to discharge process wastewater are required to provide an estimated effluent concentration for any chemical listed in Tables 2 and 3 expected to be present in the facility's effluent.

5.

DIOXIN AND FURAN CONGENER INFORMATION Existing industries that use or manufacture 2,3,5-trichlorophenoxy acetic acid (2,4,5-T); 2-(2,3,5-trichlorophenroxy) propanoic acid, (Silvex, 2,3,5-TP); 2-(2,4,5-trichlorophenoxy) ethyl 2,2-dichloropropionate (Erbon); 0,0-dimethyl 0-(2,4,5-trichlorophenyl) phosphorothionate (Ronnel);

2,4,5-trichlorophenol (TCP); or hexachlorophrene (HCP), or knows or has reason to believe that 2,3,7,8-Tetrachlorodibenzo-p-dioxin (TCDD) is present in the facility's effluent, are required to submit the results of at least one effluent analysis for the dioxin and furan congeners listed in Table

6. All effluent analyses for dioxin and furan congeners shall be conducted using USEPA Method 1613.

In addition, submit the results of all other effluent analyses performed within the last three years for any dioxin and furan congener listed in Table 6.

New industries that expect to use or manufacture 2,3,5-trichlorophenoxy acetic acid (2,4,5-T); 2-(2,3,5-tdchlorophenoxy) propanoic acid (Silvex, 2,3,5-TP); 2-(2,4,5-trichlorophenoxy) ethyl 2,2-dichloropropionate (Erbon); 0,0-dimethyl 0-(2,4,5-trichlorophenyl) phosphorothionate (Ronnel);

2,4,5-trichlorophenol (TCP); or hexachlorophrene (HCP), or knows or has reason to believe that 2,3,7,8-Tetrachlorodibenzo-p-dioxin (TCDD) is present in the facility's effluent, shall provide estimated effluent concentrations for the dioxin and furan congeners listed in Table 6.

OTHER INDUSTRY PRIORITY POLLUTANT INFORMATION Existing secondary industries, or existing primary industries that discharge nonprocess wastewater, are required to submit the results of at least one effluent analysis for any chemical listed in Tables 2 and 3 known or believed to be present in the facility's effluent.

In addition, submit the results of all other effluent analyses performed within the last three years for any chemical listed in Tables 2 and 3.

New secondary industries, or new primary industries that propose to discharge nonprocess wastewater, are required to provide an estimated effluent concentration for any chemical listed in Tables 2 and 3 expected to be present in the facility's effluent.

7.

ADDITIONAL TOXIC AND OTHER POLLUTANT INFORMATION All existing industries, regardless of discharge type, are required to provide the results of at least one analysis for any chemical listed in Table 4 known or believed to be present in the facility's effluent, and a measured or estimated effluent concentration for any chemical listed in Table 5 known or believed to be present in the facility's effluent. In addition, submit the results of any effluent analysis performed within the last three years for any chemical listed in Tables 4 and 5.

New industries, regardless of discharge type, are required to provide an estimated effluent concentration for any chemical listed in Tables 4 and 5 expected to be present in the facility's effluent.

8.

INJURIOUS CHEMICALS NOT PREVIOUSLY REPORTED New or existing industries, regardless of discharge type, are required to provide a measured or estimated effluent concentration for any toxic or otherwise injurious chemicals known or believed to be present in the facility's effluent that have not been previously identified in this Application.

Quantitative effluent data for these chemicals that is less than five years old shall be reported.

NOTE: All effluent data submitted in response to questions 4, 5, 6, 7, and 8 above should be recorded on Page 24.

To submit additional information, see Page ii, Item 3. If the effluent concentrations are estimated, place an "E in the "Analytical Method" column. The following fields shall be completed for each data row:

Parameter, CAS No., Concentration(s), Sample Type, and Analytical Method.

For analytical test requirements, see Page ii, Item 5.

If Alternate Test Procedures have been approved for any parameter listed above (Items 4 through 8), see Page ii, Item 5 for additional instructions.

5

Michigan Department of Environmental Quality-Water Bureau WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B.

Outfall Information PLEASE TYPE OR PRINT ITY NAME NPDES PERMIT NUMBER OUTFALL NUMBER Ad C. Cook Nuclear Plant M10005827 INTAKE Submitted SAMPLE DATE 4 2/18/08 2/18/08 2/19/08 2/19/08 via DMR's PAAM E CS7 co Samp°

le El Mercury 007439976 0.0013 0.0005

<0.0005

<0.0005 grab 1631 O

Arsenic (3/24/2008) 7440382 1.3 grab 200.8 El Selenium(3/24/2008) 7782492

<0.5 grab 200.8 El Silver(3/24/2008) 7440224

<0.05 grab 200.8 F1 El El El El El El El E]

F-1 El El El El El El El El F-1 El El El 6

EQP 4659-C (Rev. 11/2007)

Michigan Department of Environmental Quality-Water Bureau WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information

.EASE TYPE OR PRINT

,-kCILITY NAME NPDES PERMIT NUMBER OUTFALL NUMBER Donald C. Cook Nuclear Plant M10005827 INTAKE

9.

WATER TREATMENT ADDITIVES Water treatment additives include any material that is added to water used at the facility or to wastewater generated by the facility to condition or treat the water.

Approvals of water treatment additives are authorized by the MDEQ under separate correspondence. The issuance of an NPDES permit does not constitute approval of the water treatment additives that are included in this Application.

A. Are there water treatment additives-in the discharge from this facility?

El Yes.

El No. Proceed to Item 10.

B. Have these water treatment additives been previously approved?

El Yes. Submit a list of the previously-approved water treatment additives and the date on which they were approved. The information listed in Item C., Items 1-8 shall be updated if it has changed since the previous approval.

El No. Continue with Item C.

C. Submit a list of water treatment additives that are or may be discharged from the facility. Applicants are required to submit the information listed below for each additive.

1.

The water treatment additive Material Safety Data Sheet.

2.

The proposed water treatment additive discharge concentration.

3.

The discharge frequency (i.e., number of hours per day, week, etc.).

4.

The outfall from which the water treatment additive is to be discharged.

5.

The type of removal treatment, if any, that the water treatment additive receives prior to discharge,

6.

The water treatment additive function (i.e., microbiocide, flocculant, etc.).

7.

A 48-hour LC50 or EC50 for a North American freshwater planktonic crustacean (either Ceriodaphnia sp., Daphnia sp., or Simocephalus sp.).

8.

The results of a toxicity test for one other North American freshwater aquatic species (other than a planktonic crustacean) that meets a minimum requirement of Rule 323.1057(2)(a) of the Water Quality Standards. Examples of tests that would meet this requirement include a 96-hour LC50 for rainbow trout, bluegill, or fathead minnow.

The required toxicity information (described in Items 7 and 8 above) is currently available in the Water Bureau files for the water treatment additihes listed on the MDEQ's Internet page. To access that information, go to http://www.michigan.gov/deq, click on "Site Map," at the bottom of the right column under Water Quality Monitoring, click on "Assessment of Michigan Waters."

Under the Information heading, click on the "Water Treatment Additive List." If you intend to use one of the water treatment additives on this list, only the information in Items 1 through 6 above needs to be submitted to the Water Bureau.

Note: The availability of toxicity information for a water treatment additive does not constitute approval to discharge the water treatment additive.

10.

WHOLE EFFLUENT TOXICITY (WET) TESTS Have any acute or chronic WET tests been conducted on any discharges or receiving water(s) in relation to facility discharges within the last three years? If yes, identify the tests and summarize the results on a separate sheet, unless the test has been submitted to the MDEQ in the last three years. For assistance with WET testing, see "Whole EffluentToxicity Test Guidance and Requirements" in the Appendix.

11: CONCENTRATED ANIMAL FEEDING OPERATION (CAFO) INFORMATION. To be completed by CAFOs only The applicant shall provide: Specific information about the number and type of animals, and type of housing; the type of containment and storage, and the total capacity for CAFO waste storage; CAFO waste storage structure design; the total number of acres under the control of the applicant that is available for land application of CAFO waste; the estimated amounts of CAFO. waste generated per year; the estimated amounts of CAFO waste that is transferred to other persons per year; a list and map(s) showing the location of all land -application fields; and all potential receiving waters for both the production and all land application areas. For additional information, see "CAFO Guidance and Requirements" in the Appendix.

This completesSection III. Return the completed Application (Sections I, Il, and IV and any attachments) to. one of the addresses Page ii of this Application. If assistance is needed to complete this Application, contact the Permits Section.

7 EQP 4659-C (Rev. 11/2007)

Michigan Department of Environmental Quality-Water Bureau WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information

_'*mplete a separate Section III.B. - Outfall Information (Pages 20-25) - for each outfall at the facility. Make copies of this ink section of the Application as necessary for additional outfalls.

PLEASE TYPE OR PRINT FACILITY NAME NPDES PERMIT NUMBER OUTFALL NUMBER Donald C. Cook Nuclear Plant MI0005827 001

1.

OUTFALL INFORMATION - Instructions for this item are on Page 3 of the Appendix.

El No Change From Last Application, Items A. - D.

A.

B.

C.

D.

Receiving Water Hydrologic Unit Code (HUC)

Lake Michigan 04040001 County Township Berrien Lake Town Range Section NWY 4, 1/4 Private (French) Land Claim) 06S 19W 06 NW S

Latitude Longitude 41 58' 37.2282"

-086 34' 15.9054" E.

Type of Wastewater Discharged (check all that apply to this outfall):

El No Change From Last Application, Item E.

El Contact Cooling El Groundwater Cleanup El Hydrostatic Pressure Test 0

Noncontact Cooling Water 0

Process Wastewater Dl Sanitary Wastewater 0l Storm Water - not regulated 0

Storm Water - regulated El Storm water subject to effluent guidelines (indicate under which category):

ED Other - specify (see "Table 8 - Other Common Types of Wastewater" - in the Appendix)

Intake Screen Backwash, Floor Drainage water, F.

What is the Maximum Design Flow Rate for this outfall:

2369 MGD G

What is the Maximum Authorized Discharge Seasonal Di*

Flow for this outfall for the next five years?

Continuous 03 No Change From Last Application, Items F. - G.

schargers MGY (Continue with Item H).

Dischargers 1500 MGD (Continue with Item I).

H.

Seasonal Discharge:

List the discharge periods (by month) and the volume discharged in the space provided below.

1.

From Through Actual Discharge Volume (MGD)

Annual Total From Through Actual Discharge Volume (MGD)

From Through Actual Discharge Volume (MGD)

From Through Actual Discharge Volume (MGD)

Continuous Discharge:

How often is there a discharge from this outfall (on average)?

24 Hours/Day 365 Days/Year Batch dischargers are required to provide the following additional information:

Is there effluent flow equalization?

El Yes rl No Batch Peak Flow Rate:

Number of batches discharged per day: __

Minimum Average Maximum Batch Volume (gallons)

Batch Duration (minutes) 2 EQP 4659-C (Rev. 11/2007)

Michigan Department of Environmental Quality-Water Bureau WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information "LEASE TYPE OR PRINT CILITY NAME I NPDES PERMIT NUMBER I OUTFALL NUMBER Donald C. Cook Nuclear Plant MID0005827 D001

2.

PROCESS STREAMS CONTRIBUTING TO OUTFALL DISCHARGE El No Change From Last Application Federal regulations require that different industries report different information, depending on the type of facility. The information below is used to.

determine the applicable federal regulations for this facility. An abbreviated list is in the Summary of Information to be reported by Industry Type section of the Appendix. Applicants are required to provide the name and the SIC or the NAICS code for each process at the facility. Facilities with production-based limits must report an estimated annual production rate for the next five years, or the life of the permit If the wastestream is not regulated under federal categorical standards, the applicant is required to report all pollutants which have the reasonable potential to be present in the discharge. To submit additional information, see Page ii, Item 3.

PROCESS INFORMATION A.

Name of the process contnbuting to the discharge: 00A B.

SIC or NAICS code:. SIC-4911. NAICS 221113 C.

Describe the process and provide measures of production:

Steam Generator Blowdown. 1 MGD maximum flow, 2247 MWE total plant electrical generation PROCESS INFORMATION A.

Name of the process contributing to the discharge: 00B B.

SIC or NAICS code: SIC - 4911. NAICS 221113 C.

Describe the process and provide measures of production:

Steam Generator Blowdown. 1 MGD maximum flow, 2247 MWE total plant electrical generation PROCESS INFORMATION A.

Name of the process contributing to the discharge: 00C B.

SIC or NAICS code: SIC - 4911, NAICS 221113 C.

Describe the process and provide measures of production:

Auxiliary boiler Blowdown. 0.043 MGD maximum flow, 2247 MWE total plant electrical generation PROCESS INFORMATION A.

Name of the process contributing to the discharge: OOG B.

SIC or NAICS code: SIC -4911, NAICS 221113 C.

Describe the process and provide measures of production:

Reverse osmosis reject stream 0.366 MGD maximum flow 2247 MWE total plant electrical generation.

PROCESS INFORMATION A.

Name of the process contributing to the discharge: OOH B.

SIC or NAICS code: SIC - 4911, NAICS 221113 C.

Describe the process and provide measures of production:

Miscellaneous equipment drains and processes. Maximum flow is 5.2 MGD. 2247 MWE total plant electrical generation. This Outfall is used for emergency purposes only.

PROCESS INFORMATION A.

Name of the process contributing to the discharge: Misc Minor Stormwater drains B.

SIC or NAICS code: SIC - 4911, NAICS 221113 C.

Describe the process and provide measures of production:

if drains from the screenhouse roof,' small roadway gratings above the forebay road.

EQP 4659-C (Rev. 11/2007)

Michigan Department of Enviro ital Quality-Water Bureau WASTEWATER DISCHARGc PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information PLEASE TYPE OR PRINT FACILITY NAME NPDES PERMIT NUMBER OUTFALL NUMBER Donald C. Cook Nuclear Plant M10005827

-001

3.

EFFLUENT CHARACTERISTICS - CONVENTIONAL POLLUTANTS - Instructions for this item are on Page 4 of the Appendix.

[

Check this box if additional information is Included as an attachment. To submit additional information, see Page ii, Item 3.

Please Note: Rule 323.1062 allows the use of either Escherichia Coli or Fecal Coliform Bacteria as an indicator that effluent has been disinfected. The MDEQ will use the indicator selected below in the permit ihqqjPld h3ed nn thiq Annliritinn M-I JQP PcF hirirhin nloi n nn indirntnr nf dicinfip tinn Fl I k" I F

Iprql flolifnrm Rnr.lprin ;

in inrlirntnr nf dikinfgnlinn LI Biochemical Oxygen Demand - five day (BOD5) 1.14 1.14 mg/I 1

El Grab ZI 24 Hr Comp LI Chemical Oxygen Demand (COD) 31.2 31.2 mg/I 1

[1 Grab

[] 24 Hr Comp

[I Total Organic Carbon (TOC) 3.71 3.71 mg/I 1

n2 Grab

.,Z[

24 Hr Comp El Grab LI Ammonia Nitrogen (as N)

<0.030

<0.030 mg/I 1

Z 24 Hr Comp LI Grab LI Total Suspended Solids 4.8 4.8 mg/I 1

E 2rCo

[]24 Hr Comp L.

Total Dissolved Solids 173 173 mg/I 1

Grab E] 24 Hr Comp

] LGrab LI Total Phosphorus (as P)

<0.05

<0.05 mg/I 1

E 2rCo N( 24 Hr Comp LI Not expected to be present Fecal Coliform Bacteria (report geometric means)

Maximum-7day counts/1 00ml Grab

[]

Not expected to be present Escherichia Cali (report geometric means)

Maximum-7day counts/1 00 ml Grab z

Total Residual Chlorine LI mg/I Grab LI[] g/I Dissolved Oxygen r-.

.,Minimum daily mg/I 1

Z Grab y7.5

] 24 Hr Comp Minimum Maximum

[] Grab z

pH (report maximum and minimum of individual samples) standard units LI 2rCo El 24 Hr Comp z

Temperature, Summer

" -F L

C LI Grab IL 24 Hr Comp z

Temperature, Winter L I"F LI"C LI Grab LI 24 Hr Comp LI Oil & Grease 1.00 1.00 mg/I 1

Grab 4~

TQ 69-Rv 1/07 4

EQP 4659-C (Rev. 11/2007)

Michigan Department of Environmental Quality-Water Bureau WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information 0 LEASE TYPE OR PRINT

,CILITY NAME NPDES PERMIT NUMBER OUTFALL NUMBER Donald C. Cook Nuclear Plant MI10005827 001 Note: For questions on this page, Tables 1-5 are found in the Appendix.

4.

PRIMARY INDUSTRY PRIORITY POLLUTANT INFORMATION Existing primary industries that discharge process wastewater are required to submit the results of at least one permittee-collected effluent analysis for selected organic pollutants identified in Table 2 (as determined from Table 1, Testing Requirements for Organic Toxic Pollutants by Industrial Category), and all of the pollutants identified in Table 3. Existing primary industries are required to also provide the results of at least one permittee-collected effluent analysis for any other chemical listed in Table 2 known or believed to be present in the facility's effluent.

In addition, submit the results of all other effluent analyses performed within the last three years for any chemical listed in Tables 2 and 3.

New primary industries that propose to discharge process wastewater are required to provide an estimated effluent concentration for any chemical listed in Tables 2 and 3 expected to be present in the facility's effluent.

5.

DIOXIN AND FURAN CONGENER INFORMATION Existing industries that use or manufacture 2,3,5-trichlorophenoxy acetic acid (2,4,5-T); 2-(2,3,5-trichlorophenoxy) propanoic acid, (Silvex, 2,3,5-TP); 2-(2,4,5-trichlorophenoxy) ethyl 2,2-dichloropropionate (Erbon); 0,0-dimethyl 0-(2,4,5-trichlorophenyl) phosphorothionate (Ronnel);

2,4,5-trichlorophenol (TCP); or hexachlorophrene (HCP), or knows or has reason to believe that 2,3,7,8-Tetrachlorodibenzo-p-dioxin (TCDD) is present in the facility's effluent, are required to submit the results of at least one effluent analysis for the dioxin and furan congeners listed in Table

6. All effluent analyses for dioxin and furan congeners shall be conducted using USEPA Method 1613.

In addition, submit the results of all other effluent analyses performed within the last three years for any dioxin and furan congener listed in Table 6.

New industries that expect to use or manufacture 2,3,5-trichlorophenoxy acetic acid (2,4,5-T); 2-(2,3,5-trichlorophenoxy) propanoic acid (Silvex, 2,3,5-TP); 2-(2,4,5-trichlorophenoxy) ethyl 2,2-dichloropropionate (Erbon); 0,0-dimethyl 0-(2,4,5-trichlorophenyl) phosphorothionate (Ronnel);

2,4,5-trichlorophenol (TCP); or hexachlorophrene (HCP), or knows or has reason to believe that 2,3,7,8-Tetrachlorodibenzo-p-dioxin (TCDD) is present in the facility's effluent, shall provide estimated effluent concentrations for the dioxin and furan congeners listed in Table 6.

OTHER INDUSTRY PRiORITY POLLUTANT INFORMATION Existing secondary industries, or existing primary industries that discharge nonprocess wastewater, are required to submit the results of at least one effluent analysis for any chemical listed in Tables 2 and 3 known or believed to be present in the facility's effluent.

In addition, submit the results of all other effluent analyses performed within the last three years for any chemical listed in Tables 2 and 3.

New secondary industries, or new primary industries that propose to discharge nonprocess wastewater, are required to provide an estimated effluent concentration for any chemical listed in Tables 2 and 3 expected to be present in the facility's effluent.

7.

ADDITIONAL TOXIC AND OTHER POLLUTANT INFORMATION All existing industries, regardless of discharge type, are required to provide the results of at least one analysis for any chemical listed in Table 4 known or believed to be present in the facility's effluent, and a measured or estimated effluent concentration for any chemical listed in Table 5 known or believed to be present in the facility's effluent. In addition, submit the results of any effluent analysis performed within the last three years for any chemical listed in Tables 4 and 5.

New industries, regardless of discharge type, are required to provide an estimated effluent concentration for any chemical listed in Tables 4 and 5 expected to be present in the facility's effluent.

8.

INJURIOUS CHEMICALS NOT PREVIOUSLY REPORTED New or existing industries, regardless of discharge type, are required to provide a measured or estimated effluent concentration for any toxic or otherwise injurious chemicals known or believed to be present in the facility's effluent that have not been previously identified in this Application.

Quantitative effluent data for these chemicals that is less than five years old shall be reported.

NOTE: All effluent data submitted in response to questions 4, 5, 6, 7, and 8 above should be recorded on Page 24.

To submit additional information, see Page ii, Item 3. If the effluent concentrations are estimated, place an "E in the "Analytical Method" column. The following fields shall be completed for each data row:

Parameter, CAS No., Concentration(s), Sample Type, and Analytical Method.

For analytical test requirements, see Page ii, Item 5.

If Alternate Test Procedures have been approved for any parameter listed above (Items 4 through 8), see Page ii, Item 5 for additional instructions.

5

.Michigan Department of Environmental Quality-Water Bureau WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information

-EASE TYPE OR PRINT FACILITY NAME NPDES PERMIT NUMBER OUTFALL NUMBER Donald C. Cook Nuclear Plant M10005827 001 Submitted SAMPLE DATE 4 3/5/08 via OMVR's I~ RAAOEE AS P, I nly El Arsenic 7440382 1.3 1l Selenium 7782792

<0.5 11 Silver 7440224

<0.05 El Additional data attached El See attached electronic data.

El El El El El El El El r-I.

El El El El El El El El El El FE1 17l El EQP 4659-C (Rzv. 11/2007)

Donald C. Cook Nuclear Plant NPDES Permit M10005827 Table 1 required analyses Analysis (Gray highlite is repeat from previous table)

Sample Received CAS Outfall 001 All samples are GRAB, unless otherwise noted, at Lab Method number sampled 4/30/07 Required Biochemical Oxygen Demand (Five day BOD5) (24 hr Comp) gel SM 5210B None 1.14 mg/I Chemical oxygen Demand (COD) (24 hr Comp) gel EPA 410.4 None 31.2 mg/I Total organic carbon (TOC) (24 hr Comp) gel SM 5310B None 3.71 mg/I Ammonia Nitrogen (as N) (24 hr Comp) gel EPA 350.1 7664417

<0.03 mg/I Total Suspended Solids (24 hr Comp) gel SM 2540D None 4.8. mg/I Temperature Summer (Max July 07)

Cook SM 25508 None EDMR Temperature Winter (Max Jan 07)

Cook SM 2550B None EDMR pH Cook SM 4500-H+B None EDMR Report available data Total Dissolved Solids gel SM 2540C None 173 mg/I Total Phosphorus (24 hr Comp) gel EPA 365.4 7723140

<0.05 mg/I Total Residual Chlorine COOK EPA 330.5 electrode 7762505 EDMR Dissolved oxygen COOK SM 4500-0 C None 7.5 mg/I.

Oil and Grease gel EPA1664a None

<4.0 mg/I Table 2-Organic Toxic Pollutants (Table II from 40 CFR 122, Appendix D)

Volatiles 1,1,1-Trichloroethane gel EPA 624 71556

<1.00 ug/I 1,1,2,2-Tetrachloroethane gel EPA 624 79345

<1.00 ug/I 1,1,2-Trichloroethane gel EPA 624 79005

<1.00 ug/I 1, 1-Dichloroethane gel EPA 624 75343

<1.00 ug/I 1,1-Dichloroethylene gel EPA 624 75354

<1.00 ug/I 1,2-Dichloroethane gel EPA 624 107062

<1.00 ug/I 1,2-Dichloropropane gel EPA 624 78875

<1.00 ug/I 1,2-Trans-Dichloroethylene gel EPA 624 156605

<1.00 ug/Il 1,3-Dichloropropylene (Listed in GEL as cis 1,3 Dichloropropylene and Trans 1,3 Dichloropropylene) gel EPA 624 542756

<1.00 ug/I 2-Chloroethylvinylether gel EPA 624 110758

<5.00 ug/I

Donald C. Cook Nuclear Plant NPDES Permit M10005827 Table 1 required analyses Analysis (Gray highlite is repeat from previous table)

Sample Received CAS Outfall 001 All samples are GRAB, unless otherwise noted, at Lab Method number sampled 4/30/07 Acrolein gel EPA 624 107028

<5.00 ug/I Acrylonitrile gel EPA 624 107131

<5.00 ug/I Benzene gel EPA 624 71432

<1.00 ug/I Bromoform gel EPA 624 75252

<1.00 ug/I Carbon Tetrachloride gel EPA 624 56235

<1.00 ug/I Chlorobenzene gel EPA 624 108907

<1.00 ugil Chlorodibromomethane (Dibromochloromethane) gel EPA 624 124481

<1.00 ug/I Chloroethane gel EPA 624 75003

<1.00 ug/I Chloroform gel EPA 624.

67663

<1.00 ug/I Dichlorobromomethane(bromodichloromethane) gel EPA 624 75274

<1.00 ug/I Ethytbenzene gel EPA 624 100414

<1.00 ug/I Methyl Bromide(bromomethane) gel EPA 624 74839

<1.00 ug/I Methyl Chloride (chloromethane) gel EPA 624 74873

<1.00 ug/l Methylene Chloride gel EPA 624 75092

<2.00 ug/I Tetrachloroethylene gel EPA 624 127184

<1.00 ug/I Toluene gel EPA 624 108883

<1.00 ug/I Trichloroethylene gel EPA 624

79016,

<1.00 ug/I Vinyl Chloride gel EPA 624 750174

<1.00 ug/I Acid Compounds 2,4,6-Trichlorophenol gel EPA 625 88062

<8:93 ug/I 2,4-Dichlorophenol gel EPA 625 120832

<8.93 ug/I 2,4-Dimethylphenol gel EPA 625 105679

<8.93 ug/I 2,4-Dinitrophenol gel EPA 625 51285

<17.9 ug/I 2-Chlorophenol gel EPA 625 95578

<8.93 ug/l 2-nitrophenol gel EPA 625 88755

<8.93 ug/I 4,6-Dinitro-O-Cresol (2-Methyl-4,6-Dinitrophenol) gel EPA 625 534521

<8.93 ug/!

4-Nitrophenol gel EPA 625 100027

<8.93 ug/I P-Chloro-M-Cresol (4-chloro-3-methylphenol) gel EPA 625 none

<8.93 ug/I Pentachloro henol gel EPA 625 87865

<8.93 ug/I Phenol gel EPA 625 108952

<8.93 ug/I Base/Neutral I

Donald C. Cook Nuclear Plant NPDES Permit M10005827 Table 1 required analyses Analysis (Gray highlite is repeat from previous table)

Sample Received CAS Outfall 001 All samples are GRAB, unless otherwise noted, at Lab Method number sampled 4/30/07 1,2,4-TrichlIorobenzene gel EPA 625 120821

<8.93 ug/I I

_2-Dichlorobenzene gel EPA 625 95501.

<8.93 ug/I 1,2-Diphenylhydrazine (As Azobenzene) gel EPA 625 122667

<8.93 ug/I 1 3-Dichlorobenzene gel EPA 625 541731

<8.93 ug/h 1,4-Dichlorobenzene gel EPA 625 106467

<8.93 ug/I 2,4-Dinitrotoluene gel EPA 625 121142

<8.93 ug/I 2,6-Dinitrotoluene gel EPA 625 606201

<8.93 ug/I 2-Chloronaphthalene gel EPA 625 91587

<0.893 ug/I 3,3'-Dichlorobenzidine gel EPA 625 91941

<8.93 ug/l 3,4-Benzofluoranthene (Benzo(b)fluoranthene,)

gel EPA 625 205992

<0.893 ug9/

4-Bromophenylphenylether gel EPA 625 101553

<8.93 ug/I 4-Chlorophenyl Phenyl Ether gel EPA 625 7005723

<8.93 ug/I Acenaphthene gel EPA 625 83329

<0.893 ug/I Acenaphthylene gel EPA 625 208968

<0.893 ug/I Anthracene gel EPA 625 120127

<0.893 ug/I Benzidine (benzyl alcohol) gel EPA 625 92875

<8.93 ug/I Benzo (a) Anthracene gel EPA 625 56553

<0.893 ug/lh Benzo (a) Pyrene gel EPA 625 50328

<0.893 ug/I Benzo (ghi) Perylene gel EPA 625 191242

<0.893 ug/I Benzo (k) Fluoranthene gel EPA 625 207089

<0.893 ug/I Bis (2-Chloroethoxy) Methane gel EPA 625 111911

<8.93 ug/I Bis (2-Chloroethyl) Ether gel EPA 625 111444

<8.93 ug/I Bis (2-Chloroisopropyl) Ether gel EPA 625 108601

<8.93 ug/I Bis (2-Ethylhexyl) Phthalate gel EPA 625 117817

<8.93 ug/I Butylbenzyl Phthalate gel EPA 625 85687

<8.93 ug9/

.Chrysene gel EPA 625 218019

<0.893 ug/I Di-N-Butyl Phthalate gel EPA 625 84742

<8.93 ugh!

Di-N-Octyl Phthalate gel EPA 625 117840

<8.93 ug/I Dibenzo (a,h) Anthracene gel EPA 625 53703

<0.893 ug/h Diethyl Phthalate gel EPA 625 84662

<8.93 ug/I Dimethyl Phthalate gel EPA 625 131113

<8.93 ug9/

Flu oranth en e gel EPA 625 206440

<0.893 ug/I

Donald C. Cook Nuclear Plant NPDES Permit M10005827 Table 1 required analyses Analysis (Gray highlite is repeat from previous table)

Sample Received CAS Outfall 001 All samples are GRAB, unless otherwise noted, at Lab Method number sampled 4/30/07 Fluorene gel EPA 625 86737

<0.893 ug/I Hexachlorobenzene gel EPA 625 118741

<8.93 ug/I Hexachlorobutadiene gel EPA 625 87683

<8.93 ug/I Hexachlorocyclopentadiene gel EPA 625 77474

<8.93 ug/I Hexachloroethane gel EPA 625 67721

<0,893 ug/I Indeno (1,2,3-cd) Pyrene gel EPA 625 193395

<0.893 ug/I Isophorone gel EPA 625 78591

<8.93 ug/I N-Nitrosodi-N-Propylamine gel EPA 625 none

<8.93 ug/I N-Nitrosodimethylamine (N-methyl-N-nitrosomethylamine) gel EPA 625 62759

<8.93 ug/I N-Nitrosodiphenylamine (Diphenylamine) gel EPA 625 86306

<8.93 ug/I Naphthalene gel EPA 625 91203

<0.893 ug/I Nitrobenzene gel EPA 625 98953

<8.93 ug/I Phenanthrene gel.-

EPA 625 85018

<0.893 ug/I Pyrene gel EPA 625 129000

<0.893 ug/I Table 3 -Other Toxic Pollutants (metals and. Cyanide) and Total Phenols.

(Table III from 40 CFR 122, Appendix D)

Total Antimony gel EPA 200.8 7440360

<1 ug/I Total Arsenic gel EPA 200.8 7440382

<1,50 ug/I Total Beryllium gel EPA 200.8 7440417

<1 ug/I Total Cadmium gel EPA 200.8 7440439

<0,2 ughi Total Chromium gel EPA 200.8 7440473

<10 ug/I Total Copper gel EPA 200.8 7440508 1.19 ug9/

EPA method Available Cyanide kar OIA-1677 57125

<2 ug/I Total Lead gel EPA 200.8 7439921

<1 ug/I EPA method Total Mercury gel 1631 7439976 0.996 ng/I Total Nickel

gel, EPA 200.8 7440020

<5 ug/I Total Phenols gel EPA 420.2 none

<5.00 ug/I Total Selenium gel EPA 200.8 7782792

<2.50 ug/I

Donald C. Cook Nuclear Plant NPDES Permit.M10005827 Table 1 required analyses Analysis (Gray highlite is repeat from previous table)

Sample Received CAS Outfall 001 All samples are GRAB, unless otherwise noted.

at Lab Method number sampled 4/30/07 Total Silver gel EPA 200.8 7440224

<1 ug/I Total Thallium gel EPA 200.8 7440280

<1 ug/I Total Zinc gel EPA 200.8 7440666

<10 ug/I Table 4 Conventional and Non-conventional pollutants to be tested by existing discharges if expected to be present in discharge (Table IV from 40CFR 122, Appendix D)

Aluminum, Total gel EPA 200.8 7429905 67.9 ug/I Barium, Total gel EPA 200.8 7440393 23.0 ug/I Boron, Total gel EPA 200.8 7440428 26.0 ug/I Bromide gel EPA 300 7726956.0

<0.200 mg/I Cobalt, Total gel EPA 200.8 62207765

<1.00 ug/I Fluoride gel SM 4500-F B 7782414 0.110 mg/I Iron, Total gel EPA 200.8 none 316 ug/I Magnesium, Total gel EPA 200.8 7439954 12400 ug/I Manganese, Total gel EPA 200.8 7439965 7.27 ug/I Molybdenum, total gel EPA 200.8 7439987 1.26 ug/I Nitrate-Nitrite (as N) gel EPA 353.2 none 0.446 mg/I EPA Nitrogen, total Organic (as N) gel 351.2/350.1 none 193 ug/I Radioactivity gel EPA 900 none Alpha, total gel EPA 900 none

<5.00 pCi/I Beta, total gel EPA 900 none

<5.00 pCi/I Radium, Total gel EPA 900 7440144

<1.00 pCi/I Radium 226, total gel EPA 900 7440144

<1..00 pci/I Sulfate (as S04) gel EPA 300.0 none 24.6 mg/I Sulfide (as S) gel SM 4500-S F 18496258

<0.100 mg/I

.Sulfite (as S03) gel SM 4500-SO3 B none

<2.00 mg/I Tin, Total gel EPA 200.8 7440315

<5.0 ug/I

Donald C. Cook Nuclear Plant NPDES Permit M10005827 Table 1 required analyses Analysis (Gray highlite is repeat from previous table)

Sample Received CAS Outfall 001 All samples are GRAB, unless otherwise noted.

at Lab Method number sampled 4/30/07 Titanium, total gel EPA 200.8 7440326

<10 ug/I Table 5 - Toxic pollutants and hazardous Substances required to be identified by Existing Discharges if Expected to Be present in Discharge (Table V from 40 CFR 122, Appendix D)

Toxic Pollutant Hazardous Substances I

1,2 Napthoquinone-4 sulfonic Acid method

Michigan Department of Environmental Quality-Water Bureau WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information EASE TYPE OR PRINT

.-CILITY NAME NPDES PERMIT NUMBER OUTFALL NUMBER Donald C. Cook Nuclear PlantI M10005827I 001

9.

WATER TREATMENT ADDITIVES Water treatment additives include any material that is added to water used at the facility or to wastewater generated by the facility to condition or treat the water.

Approvals of water treatment additives are authorized by the MDEQ under separate correspondence. The issuance of an NPDES permit does not constitute approval of the water treatment additives that are included in this Application.

A. Are there water treatment additives in the discharge from this facility?

Z Yes.

Ej No. Proceed to Item 10.

B. Have these water treatment additives been previously approved?

12 Yes. Submit a list of the previously-approved water treatment additives and the date on which they were approved. The information listed in Item C., Items 1-8 shall be updated if it has changed since the previous approval.

E] No. Continue with Item C.

C. Submit a list of water treatment additives that are or may be discharged from the facility. Applicants are required to submit the information listed below for each additive.

1.

The water treatment additive Material Safety Data Sheet.

2.

The proposed water treatment additive discharge concentration.

3.

The discharge frequency (i.e., number of hours per day, week, etc.).

4.

The outfall from which the water treatment additive is to be discharged.

5.

The type of removal treatment, if any, that the water treatment additive receives prior to discharge.

6.

The water treatment additive function (i.e., microbiocide, flocculant, etc.).

7.

A 48-hour LC50 or EC50 for a North American freshwater planktonic crustacean (either Ceriodaphnia sp., Daphnia sp., or Simocephalus sp.).

8.

The results of a toxicity test for one other North American freshwater aquatic species (other than a planktonic crustacean) that meets a minimum requirement of Rule 323.1057(2)(a) of the Water Quality Standards. Examples of tests that would meet this requirement include a 96-hour LC50 for rainbow trout, bluegill, or fathead minnow.

The required toxicity information (described in Items 7 and 8 above) is currently available in the Water Bureau files for the water treatment additives listed on the MDEQ's Internet page. To access that information, go to http://www.michigan.gov/deq, click on "Site Map," at the bottom of the right

.column under Water Quality Monitoring, click on 'Assessment of.Michigan Waters."

Under the Information heading, click on the 'Water Treatment Additive List." 'If you intend to use one of the water treatment additives on this list, only the information in Items 1 through 6 above needs to be submitted to the Water Bureau.

Note: The availability of toxicity information for a water treatment additive does not constitute approval to discharge the water treatment additive.

10.

WHOLE EFFLUENT TOXICITY (WET) TESTS Have any acute or chronic WET tests been conducted on any discharges or receiving water(s) in relation to facility discharges within the last three years? If yes, identify the tests and summarize the results on a separate sheet, unless the test has been submitted to the MDEQ in the last three years. For assistance with WET testing, see '*Whole Effluent Toxicity Test Guidance and Requirements" in the Appendix.

11.

CONCENTRATED ANIMAL FEEDING OPERATION (CAFO) INFORMATION. To be completed by CAFOs only The applicant shall provide: Specific information about the number and type of animals, and type of housing; the type of containment and storage, and the total capacity for CAFO waste storage; CAFO waste storage structure design; the total number of acres under the control of the applicant that is available for land application of CAFO waste; the estimated amounts of CAFO waste generated per year; the estimated amounts of CAFO waste that is transferred to other persons per year; a list and map(s) showing the location of all land application fields; and all potential receiving waters for both the production and all land application areas. For additional information, see "CAFO Guidance and Requirements" in the Appendix.

This completesSection III. Return the completed Application (Sections I, Ill, and IV and any attachments) to one of the addresses Page ii of this Application. If assistance is needed to complete this Application, contact the Permits Section.

7 EQP 4659-C (Rev. 11/2007)

Michigan Department of Environmental Quality-Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION mI

- Industrial and Commercial Wastewater B. Outfall Information PLEASE TYPE OR PRINT FACILITY NAME NPDES or COC PERMIT NUMBER Outfall Number Donald C. Cook Nuclear Plant MI0005827 001,002,003

9. WATER TREATMENT ADDITIVES Previously permitted Maximum discharge Water Treatment Additive Approval Date concentrations. As applied for under Part 1.6 of the current NPDES permit, "Request for Discharge of Water Treatment Additives." (Based on 2 circ water pumps in operation during discharge event)

Sodium Hypochlorite 5/23/00 NPDES Permit approval 9/28/95 38 ugi (continuous) 200 ug/1 (intermittent)

Betz CT-1300 Formerly called Betz NPDES Permit approval 9/28/95, 5/23/00, 0.07 mg/i CT-2 (Molluscicide) 2/28/02, 6/13/03 Calgon H-130M (Molluscicide) 8/16/95, 5/23/00 0.012 ag/I Calgon EVAC (Molluscicide) 8/8/00 0.078 mg/1 Nalco Macrotrol 9380 (Molluscicide) 8/16/95, 5/23/00, 2/28/02 0.01 mg/1 (4)

Nalco Macrotrol 9210 (Molluscicide) 8/16/95, 5/23/00, 2/28/02 0.08 mg/1 (4)

Nalco TRASAR 23299 5/23/00, 9/17/96 0.146 mg/1 (4)

Fluorescein Dye 9/21/98 Per rule 97 for certification of Dyes Bentonite Clay 5/23/2000, NPDES Permit approval 9/28/95 (5)

Betz Ferroquest FQ LP 7200 (Formerly 11/14/94, 5/23/00, 9/17/96, NPDES Permit 0.033 mg/1 Called Betz Depositrol 855D) approval 9/28/95 Sodium Tetraborate (Borax) 5/23/00,4/16/98 1.5 mag/i (6)

SF6 (Sulphur hexafluoride gas)

NPDES Permit approval 9/28/95 2.5 mg/1 Betz Corrshield NT 4205 (Formerly 6/23/99, 9/17/96 2.6 mg/1 (3)

Powerline 3231) (Nitrite additive.)

Calgon LCS-60 (Nitrite additive.)

6/23/99, NPDES Permit apprdval 9/28/95 0.86 mg/1 Betz Corrshield NT4201 5/17/02 1.95 mg/1 (2)

(Nitrite additive.)

Betz Corrshield NT 4203 9/18/02 1.48 rg/1 (1)

(Nitrite additive.)

Spectrus NX 1105 (Formerly Betz 6/23/99, 5/23/00 0.083 mg/1 Biotrol 107) (Gluteraldehyde)

Calgon H-300 (Gluteraldehyde) 6/23/99, 5/23/00 0.065 rg/1 Betz AZ 8103 (Formerly Betz Copper-12/18/95, 6/23/99, 5/23/00 0.2 mg/i Trol Cu-I (Tolyltriazole)

Betz 3610 (Methyl (Bis) Thiocyanate) 6/23/99 0.026 mg/I Betz MD-4103 (Mo0 4) 3/26/02 1.65 mg/1 Carbohydrazide solutions such as: Betz 3/24/94 NPDES application, 4/15/94 0.029 mg/1 Cortrol OS5613, Nalco 1250 plus approval, NPDES Permit approval 9/28/95 Ethanolamine 5/23/00, NPDES approval 9128/95 0.01 mg/I Betz Steamate 1480N, Nalco 92UM001 Hydrazine:

5/23/00, NPDES approval 9/28/95

0. 1 rng/

Betz Cortrol OS5035, OS 5010, Nalco 19H Betz AZ8101 3/31/2005 0.32 mg/1 Betz Ferroquest FQ7 101 8/28/2007 0.54 mg/!

Betz Ferroquest FQ7)102 8/28/2007 0.27 mg/1 Betz Spectrus DT 1404 Approved 2/13/08 0.21 rg/1 (Sodium Bisulfite)

(1) 3 pumps running for extra dilution: 1.0 mg/1 (2) 3 pumps running for extra dilution: 1.3 mg/I (3) 3 pumps running for extra dilution: 1.7 mg/i (4) 6 times per year, 16 hrs per day (5)

Nalco 9380: 9.8-14.3 lbs clay: 1 lb of 9380 Betz CT-1300: 7.5 lbs clay: 1 lb of CT-1300 (6) 1 Circ pump minimum dilution

Michigan Department of Environmental Quality-Water Bureau WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information complete a separate Section III.B. - Outfall Information (Pages 20-25) - for each outfall at the facility. Make copies of this ink section of the Application as necessary for additional outfalls.

PLEASE TYPE OR PRINT FACILITY NAME NPDES PERMIT NUMBER OUTFALL NUMBER.

Donald C. Cook Nuclear Plant IMI0005827I 002

1.

OUTFALL INFORMATION - Instructions for this item are on Page 3 of the Appendix.

El No Change From Last Application, Items A. - D.

A.

B.

C.

D.

Receiving Water Hydrologic Unit Code (HUC)

Lake Michigan 04040001 County Township Berrien Lake Town Range Section.

Y4

'A, Y4 Private (French) Land Claim) 06S 19W 06 NW SW Latitude Longitude 41 58'35.1"

-086 34'16.8" E.

Type of Wastewater Discharged (check all that apply to this outfall):

El No Change From Last Application, Item E.

El Contact Cooling E) Groundwater Cleanup El Hydrostatic Pressure Test

[

Noncontact Cooling Water Z

Process Wastewater E] Sanitary Wastewater El Storm Water - not regulated

[

Storm Water - regulated El Storm water subject to effluent guidelines (indicate under which category):

[

Other - specify (see "Table 8 - Other Common Types of Wastewater" - in the Appendix) Intake Screen Backwash, Floor Drainage water, F.

What is the Maximum Design Flow Rate for this outfall: 23 G

What is the Maximum Authorized Discharge Flow for this outfall for the next five years?

No Change From Last Application, Items F. - G.

Seasonal Dischargers MGY (Continue with Item H).

Continuous Dischargers 1820 MGD (Continue with Item I).

H.

Seasonal Discharge:

List the discharge periods (by month) and the volume discharged in the space provided below.

1.

From Through Actual Discharge Volume (MGD)

Annual Total From Through.

Actual Discharge Volume (MGD)

From Through Actual Discharge Volume (MGD)

From Through Actual Discharge Volume (MGD)

Continuous Discharge:

How often is there a discharge from this outfall (on average)?

24 Hours/Day 365 Days/Year Batch dischargers are required to provide the following additional information:

Is there effluent flow equalization?

El Yes El No Batch Peak Flow Rate:

Number of batches discharged per day: __

Minimum Average Maximum -

Batch Volume (gallons)

Batch Duration (minutes)

I 2

EQP 4659-C (Rev. 11/2007)

Michigan Department of Environmental Quality-Water Bureau WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information

'iLEASE TYPE OR PRINT

,CILITY NAME Donald C. Cook Nuclear Plant NPDES PERMIT NUMBER M10005827 OUTFALL NUMBER 002 2.

PROCESS STREAMS CONTRIBUTING TO OUTFALL DISCHARGE El ýNo Change From Last Application Federal regulations require that different industries report different information, depending on the type of facility. The information below is used to determine the applicable federal regulations for this facility. An abbreviated list is in the Summary of Information to be reported by Industry Type section of the Appendix. Applicants are required to provide the name and the SIC or the NAICS code for each process at the facility. Facilities with production-based limits must report an estimated annual production rate for the next five years, or the life of the permit. -If the wastestream is not regulated under federal categorical standards, the applicant is required to report all pollutants which have the reasonable potential to be present in the discharge. To submit additional information, see Page ii, Item 3.

PROCESS INFORMATION A.

Name of the process contributing to the discharge: OA B.

SIC or NAICS code: SIC -4911, NAICS 221113 C.

Describe the process and provide measures of production:

Steam Generator Blowdown. 1 MGD maximum flow 2247 MWE total plant electrical generation PROCESS INFORMATION A.

Name of the process contributing to the discharge: DOB B.

SIC or NAICS code: SIC -4911. NAICS 221113 C. Describe the process and provide measures of production:

Steam Generator Blowdown". 1 MGD maximum flow, 2247 MWE total plant electrical generation PROCESS INFORMATION A.

Name of the process contributing to the discharge: DOC B.

SICorNAICS code: SIC-4911, NAICS 221113 C.

Describe the process and provide measures of production:

Auxiliary boiler Blowdown. 0.043 MGD maximum flow, 2247 MWE total plant electrical generation PROCESS INFORMATION A.

Name of the process contributing to the discharge: COG B.

SIC or NAICS code: SIC - 4911, NAICS 221113 C.

Describe the process and provide measures of production:

Reverse osmosis reject stream 0.366 MGD maximum flow 2247 MWE total plant electrical generation.

PROCESS INFORMATION A.

Name of the process contributing to the discharge: 00H B.

SIC or NAICS code: SIC -4911, NAICS 221113 C.

Describe the process and provide measures of production:

Miscellaneous equipment drains and processes. Maximum flow is 5.2 MGD. 2247 MWE total plant electrical generation. This Outfall is used for emergency purposes only.

PROCESS INFORMATION A.

Name of the process contributing to the discharge: Misc Minor Stormwater drains B.

SIC or NAICS code: SIC - 4911, NAICS221113 C.

Describe the process and provide measures of production:

.-of drains from the screenhouse roof, small roadway gratings above the forebay road.

3 EQP 4659-C (Rev. 11/2007)

Michigan Department of Environmental Quality-Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information PLEASE TYPE OR PRINT FACILITY NAME NPDES or COC PERMIT NUMBER Outfall Number Donald C. Cook Nuclear Plant MJ0005827 002

3. Effluent characteristics Conventional pollutants.

Water discharged from Outfall 002 is the same as Outfall 001 and 002. Written permission has been obtained from the Kalamazoo District Office on February 12. 2008 to use the Table 1 data from Outfall 001 to characterize this discharge.

Michigan Department of Enviro, ital Quality-Water Bureau WASTEWATER DISCHARGe: PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information PLEASE TYPE OR PRINT FACILITY NAME NPDES PERMIT NUMBER OUTFALL NUMBER Donald C. Cook Nuclear Plant M10005827 002

3.

EFFLUENT CHARACTERISTICS - CONVENTIONAL POLLUTANTS - Instructions for this item are on Page 4 of the Appendix.

[

Check this box if additional information is included as an attachment. To submit additional information, see Page ii, Item 3.

Please Note: Rule323.1062 allows the use of either Escherichia Cofi or Fecal Coliform Bacteria as an indicator that effluent has been disinfected. The MDEQ will use the indicator selected below in the permit issued based on this Aoolication. M-Use Escherichia Coil as an indicator of disinfection.

171 Use Fecal Coliform Bacteria as an indicator of disinfection.

I Biochemical Oxygen Demand - five day (BOD5) 1.14 1.14 mg/I 1 1 EC Grab 0

24 Hr Comp 0

Chemical Oxygen Demand (COD) 31.2 31.2 mg/I 1

Z2 Grab

[] 24 Hr Comp FC Total Organic Carbon (TOC) 3.71 3.71 mg/I 1

C Grab

[

24 Hr Comp C

Ammonia Nitrogen.(as N)

<0.030

<0.030 mg/i 1

Z Grab El 24 Hr Comp Total Suspended Solids 4.8 4.0 mg/Cl 1

El Grab C

Total Dissolved Solids 1mg/

Grab 173 ~ ~

~

~

E 173 g/I 1C2 rCm Total E 24 Hr Comp z

TeperaureSumer E OF I -

24 Hr Comp C]

Not expected to be present Fecal Coliform Bacteria (report geometric means)

Maximum-7day counts/100~mi Grab C]

Not expected to be present Escherichia Coil (report geometric means)

Maiu-dy counts/i100 ml Grab

[]Total Residual Chlorine C] mg/I Grab C] i-g/I Minimum daily

[]Grab C]

Dissolved Oxygen mg/I 1C2 rCm

[]pH (report maximum and minimum of individual samples) standard units

~Ga 24 Hr Comp*

Cl Grab Temperature, Summer C 24 Hr Comp STemperature, Winter C0F

°C C

Grab

_______24___rC24H omm C]

Oil & Grease 1.00 1.00 "mg/I 1Grab

.4 EQP 4659-C (Rev. 11/2007)

Michigan Department of Environmental Quality-Water Bureau WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information

'.EASE TYPE OR PRINT

.CILITY NAME NPDES PERMIT NUMBER OUTFALL NUMBER oonald C. Cook Nuclear Plant M10005827 002 Note: For questions on this page, Tables 1-5 are found in the Appendix.

4.

PRIMARY INDUSTRY PRIORITY POLLUTANT INFORMATION Existing primary industries that discharge process wastewater are required to submit the results of at least one permittee-collected effluent analysis for selected organic pollutants identified in Table 2 (as determined from Table 1, Testing Requirements for Organic Toxic Pollutants by Industrial Category), and all of the pollutants identified in Table 3. Existing primary industries are required to also provide the results of at least one permittee-collected effluent analysis for any other chemical listed in Table 2 known or believed to be present in the facility's effluent.

In addition, submit the results of all other effluent analyses performed within the last three years for any chemical listed in Tables 2 and 3.

New primary industries that propose to discharge process wastewater are required to provide an estimated effluent concentration for any chemical listed in Tables 2 and 3 expected to be present in the facility's effluent.

5.

DIOXIN AND FURAN CONGENER INFORMATION Existing industries that use or manufacture 2,3,5-tdchlorophenoxy acetic acid (2,4,5-T); 2-(2,3,5-tdchlorophenoxy) propanoic acid, (Silvex, 2,3,5-TP); 2-(2,4,5-trichlorophenoxy) ethyl 2,2-dichloropropionate (Erbon); 0,0-dimethyl 0-(2,4,5-trichlorophenyl) phosphorothionate (Ronnel);

2,4,5-trichlorophenol (TCP); or hexachlorophrene (HCP), or knows or has reason to believe that 2,3,7,8-Tetrach)orodibenzo-p-dioxin (TCDD) is present in the facility's effluent, are required to submit the results of at least one effluent analysis for the dioxin and furan congeners listed in Table

6. All effluent analyses for dioxin and furan congeners shall be conducted using USEPA Method 1613.

In addition, submit the results of all other effluent analyses performed within the last three years for any dioxin and furan congener listed in Table 6.

New industries that expect to use or manufacture 2,3,5-trichlorophenoxy acetic acid (2,4,5-T); 2-(2,3,5-tfichlorophenoxy) propanoic acid (Silvex, 2,3,5-TP); 2-(2,4,5-trichlorophenoxy) ethyl 2,2-dichloropropionate (Erbon); 0,0-dimethyl 0-(2,4,5-trichlorophenyl) phosphorothionate (Ronnel);

2,4,5-trichlorophenol (TCP); or hexachlorophrene (HCP), or knows or has reason to believe that 2,3,7,8-Tetrachlorodibenzo-p-dioxin (TCDD) is present in the facility's effluent, shall provide estimated effluent concentrations for the dioxin and furan congeners listed in Table 6.

OTHER INDUSTRY PRIORITY POLLUTANT INFORMATION Existing secondary industries, or existing primary industries that discharge nonprocess wastewater, are required to submit the results of at least one effluent analysis.for any chemical listed in Tables 2 and 3 known or believed to be present in the facility's effluent.

In addition, submit the results of all other effluent analyses performed within the last three years for any chemical listed in Tables 2 and 3.

New secondary industries, or new primary industries that propose to discharge nonprocess wastewater, are required to provide an estimated effluent concentration for any chemical listed in Tables 2 and 3 expected to be present in the facility's effluent.

7.

ADDITIONAL TOXIC AND OTHER POLLUTANT INFORMATION All existing industries, regardless of discharge type, are required to provide the results of at least one analysis for any chemical listed in Table 4 known or believed to be present in the facility's effluent, and a measured or estimated effluent concentration for any chemical listed in Table 5 known or believed to be present in the facility's effluent. In addition, submit the results of any effluent analysis performed within the last three years for any chemical listed in Tables 4 and 5.

New industries, regardless of discharge type, are required to provide an estimated effluent concentration for any chemical listed in Tables 4 and 5 expected to be present in the facility's effluent.

8.

INJURIOUS CHEMICALS NOT PREVIOUSLY REPORTED New or existing industries, regardless of discharge type, are required to provide a measured or estimated effluent concentration for any toxic or otherwise injurious chemicals known or believed to be present in the facility's effluent that have not been previously identified in this Application.

Quantitative effluent data for these chemicals that is less than five years old shall be reported.

NOTE: All effluent data submitted in response to questions 4, 5, 6, 7, and 8 above should be recorded on Page 24. To submit additional information, see Page ii, Item 3. If the effluent concentrations are estimated, place an "E in the "Analytical Method" column. The following fields shall be completed for each data row:

Parameter, CAS No., Concentration(s), Sample Type, and Analytical Method.

For analytical test requirements, see Page ii, Item 5.

If Alternate Test Procedures have been approved for any parameter listed above (Items 4 through 8), see Page ii, Item 5 for additional instructions.

5

Michigan Department of Environmental Quality-Water Bureau WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information

._ASE TYPE OR PRINT FACILITY NAME NPDES PERMIT NUMBER OUTFALL NUMBER Donald C. Cook Nuclear Plant M10005827 002 Submitted SMLDAE4 3/5/08_]

via DMR's CSc,-C-Cn

,oý,

CC l-ape

ý-ln El Arsenic 7440382 1.3 El Selenium 7782792

<0.5 El Silver 7440224

<0.05 El Additional data attached El See attached electronic data.

El El El E3 El El El El El El El El El El El El El El El El El El 6

EQP 4659-C (Rev. 1112007),

Donald C, Cook Nuclear Plant NPDES Permit M10005827 Table 1 required analyses Analysis (Gray highlite is repeat from previous table)

Sample Received CAS Outfall 002 All samples are GRAB, unless otherwise noted, at Lab Method number sampled 4/30/07 Required Biochemical Oxygen Demand (Five day BOD5) (24 hr Comp) gel SM 5210B None 1.14 mg/I Chemical oxygen Demand (COD) (24 hr Comp) gel EPA 410.4 None 31.2 mg/I Total organic carbon (TOC) (24 hr Comp) gel SM 5310B None 3.71 mg/I Ammonia Nitrogen (as N) (24 hr Comp) gel EPA 350.1 7664417

<0.03 mg/I Total Suspended Solids (24 hr Comp) gel SM 2540D None 4.8 mg/I Temperature Summer (Max July 07)

Cook SM 2550B None EDMR Temperature Winter (Max Jan 07)

Cook SM 2550B None EDMR pH Cook SM 4500-H+B None EDMR Report available data Total Dissolved Solids gel SM 2540C0 None 173 mg/I Total Phosphorus (24 hr Comp) gel EPA 365.4 7723140

<0.05 mg/I Total Residual Chlorine COOK EPA 330.5 electrode 7782505 EDMR Dissolved oxygen COOK SM 4500-0 C None 7.5 mg/I Oil and Grease gel EPA1664a None

<4.0 mg/I Table 2-Organic Toxic Pollutants (Table II from 40 CFR 122, Appendix D)

Volatiles 1,1,1-Trichloroethane gel EPA 624 71556

,<1.00 ug/I 1,1,2,2-Tetrachloroethane gel EPA 624 79345

<1.00 ug/I 1,1,2-Trichloroethane gel EPA 624 79005

<1.00 ug/l I1,-Dichloroethane gel EPA 624 75343

<1.00 ug/I 1,1-Dichloroethylene gel EPA 624 75354

<1.00 ug/I 1,2-Dichloroethane gel EPA 624 107062

<1.00 ug/I 1,2-Dichloropropane gel EPA 624 76875

<1.00 ug/I 1,2-Trans-Dichloroethylene gel EPA 624 156605

<1.00 ug/I 1,3-Dichloropropylene (Listed in GEL as cis 1,3 Dichloropropylene and Trans 1,3 Dichloropropylene) gel EPA 624 542756

<1.00 ug/I 2-Chloroethylvinylether gel EPA 624 110758

<5.00 ug/I

Donald C. Cook Nuclear Plant NPDES Permit M10005827 Table 1 required analyses Analysis (Gray highlite is repeat from previous table)

Sample Received CAS Outfall 002 All samples are GRAB, unless otherwise noted.

at Lab Method number sampled 4/30/07 Acrolein gel EPA 624 107028

<5.00 ug/I Acrylonitrile gel EPA 624 107131

<5.00 ug/I Benzene gel EPA 624 71432

<1.00 ug/I Bromoform gel EPA 624 75252

<1.00 ug/I Carbon Tetrachloride gel EPA 624 56235

<1.00 ug/I Chlorobenzene gel EPA 624 108907

<1.00 ug/I Chlorodibromomethane (Dibromochloromethane) gel EPA 624 124481

<1.00 ug/I Chloroethane gel EPA 624 75003

<1.00 ug/I Chloroform gel EPA 624 67663

<1.00 Ug/I Dichlorobromomethane(bromodichloromethane) gel EPA 624 75274

<1.00 ug/I Ethylbenzene gel EPA 624 100414

<1.00 ug/I Methyl Bromide(bromomethane) gel EPA 624 74839

<1.00 ug/I Methyl Chloride (chloromethane) gel EPA 624 74873

<1.00 ug/I Methylene. Chloride gel EPA 624 75092

<2.00 ug/I Tetrachloroethylene gel EPA 624 127184

<1.00 ug/I Toluene gel EPA 624 108883

<1.00 ug9/

Trichloroethylene gel EPA 624 79016

<1.00 ug/I Vinyl Chloride gel EPA 624 750174

<1.00 ug/I Acid Compounds 2,4,6-Trichlorophenol gel EPA 625 88062

<8.93 ug/I 2,4-Dichlorophenol gel EPA 625 120832

<8.93 ug9/

2,4-Dimethylphenol gel EPA 625 105679

<8.93 ug/I 2,4-Dinitrophenol gel EPA 625 51285

<17.9 ug/i 2-Chlorophenol gel EPA 625 95578

<8.93 ug/I 2-nitrophenol gel EPA 625 88755

<8.93 ug9/

4,6-Dinitro-O-Cresol (2-Methyl-4,6-Dinitrophenol) gel EPA 625 534521

<8.93 ug/I 4-Nitrophenol gel EPA 625 100027

<8.93 ug/I P-Chloro-M-Cresol (4-chloro-3-methylphenol) gel EPA 625 none

<8.93 ug/I Pentachlorophenol gel EPA 625 87865

<8.93 ug/I Phenol gel EPA 625 108952

<8,93 ug/I Base/Neutral

Donald C. Cook Nuclear Plant NPDES Permit M1.0005827 Table 1 required analyses Analysis (Gray highlite is repeat from previous table)

Sample Received CAS Outfall 002 All samples are GRAB, unless otherwise noted, at Lab Method number sampled 4/30/07 1,2,4-Trichlorobenzene gel EPA 625 120821

<8.93 ug/I 1,2-Dichlorobenzene gel EPA 625 95501

<8.93 ug/I 1,2-Diphenylhydrazine (As Azobenzene) gel EPA 625 122667

<8.93 ug/1' 1,3-Dichlorobenzene gel EPA 625 541731

<8.93 ug/I 1,4-Dichlorobenzene gel EPA 625 106467

<8.93 ug/I 2,4-Dinitrotoluene

-gel EPA 625 121142

<8.93 ug/I 2,6-Dinitrotoluene gel EPA 625 606201

<8.93 ug/I 2-Chloronaphthalene gel EPA 625 91587

<0.893 ug/I 3,3 -Dichlorobenzidine gel EPA 625 91941

<8.93 ug/I 3,4-Benzofluoranthene (Benzo(b)fluoranthene,)

gel EPA 625 205992

<0.893 ug/I 4-Bromophenylphenylether gel EPA 625 101553

<8.93 ug/I 4-Chlorophenyl Phenyl Ether gel EPA 625 7005723

<8.93 ug/

Acenaphthene gel EPA 625 83329

<0.893 ug/I Acenaphthylene gel EPA 625 208968

<0.893 ug/I Anthracene gel EPA 625 120127

<0.893 ug/I Benzidine (benzyl alcohol) gel EPA 625 92875

<8.93 ug/I Benzo (a) Anthracene gel EPA 625 56553

<0.893 ug/I Benzo (a) Pyrene gel EPA 625 50328

<0.893 u9/1 Benzo (ghi)-Perylene gel EPA 625 191242

<0.893 ug/I Benzo (k) Fluoranthene gel EPA 625 207089

<0.893 ugll Bis (2-Chloroethoxy) Methane gel EPA 625 111911

<8.93 ug/I Bis (2-Chloroethyl) Ether gel EPA 625 111444

<8,93 ug/i Bis (2-Chloroisopropyl) Ether gel EPA 625 108601.

<8,93 ug/I Bis (2-Ethylhexyl) Phthalate gel EPA 625 117817

<8.93 ug/I Butylbenzyl Phthalate gel EPA 625 85687

<8.93 ug/I Chrysene gel EPA 625 218019

<0.893 ug/I Di-N-Butyl Phthalate gel EPA 625 84742

<8.93 ug/I Di-N-Octyl Phthalate gel EPA 625 117840

<8.93 ug/I Dibenzo (a,h) Anthracene gel EPA 625 53703

<0.893 ug/I Diethyl Phthalate gel EPA 625 84662

<8.93 ug/I Dimethyl Phthalate gel EPA 625 131113

<8.93 ug/I Fluoranthene gel EPA 625 206440

<0.893 ug/I

Donald C. Cook Nuclear Plant NPDES Permit M10005827 Table 1 required analyses Analysis (Gray highlite is repeat from previous table)

Sample Received CAS Outfall 002 All samples are GRAB, unless otherwise noted, at Lab Method number sampled 4/30/07 Fluorene gel EPA 625 86737

<0.893 ug/I Hexachlorobenzene gel.

EPA 625 118741

<8.93 ug/I Hexachlorobutadiene gel EPA 625' 87683

<8.93 ug/I Hexachlorocyclopentadiene gel EPA 625 77474

<8.93 ug/I Hexachloroethane gel EPA*625 67721

<0.893 ug/I Indeno (1,2,3-cd) Pyrene gel EPA 625 193395

<0.893 ug/I Isophorone gel EPA 625 78591

<8.93 ug/I N-Nitrosodi-N-Propylamine gel EPA 625 none

<8.93 ug/I N-Nitrosodimethylamine (N-methyl-N-nitrosomethylamine) gel EPA 625 62759

<8.93 ug/I N-Nitrosodiphenylamine (Diphenylamine) gel EPA 625 86306

<8.93 ug/I Naphthalene gel EPA 625 91203

<0.893 ug/I Nitrobenzene gel EPA 625 98953

<8.93 ug/I Phenanthrene gel EPA 625 85018

<0.893 ug/I Pyrene gel EPA 625 129000

<0.893 ug/I Table 3 -Other Toxic Pollutants (metals and Cyanide) and Total Phenols.

(Table III from 40 CFR 122, Appendix D)

Total Antimony gel EPA 200.8 7440360

<1 ug/I Total Arsenic gel EPA 200.8 7440382

<1.50 ug/I Total Beryllium gel EPA 200.8 7440417

<1 ug/I Total Cadmium gel EPA 200.8 7440439

<0.2 ug/I Total Chromium gel EPA 200.8 7440473

<10 ug/I Total Copper gel EPA 200.8 7440508 1.19 ug/h EPA method Available Cyanide kar OIA-1677 57125

<2 ug/l Total Lead gel EPA 200.8 7439921

<1 ug/I EPA method Total Mercury.

gel 1631 7439976 0.996 ng/h Total Nickel gel EPA 200.8 7440020

<5 ug/I Total Phenols gel EPA 420.2 none

<5.00 ug/I Total Selenium gel EPA 200.8 7782792

<2.50 ug/I

Donald C. Cook Nuclear Plant NPDES Permit M10005827 Table 1 required analyses Analysis (Gray highlite is repeat from previous table)

Sample Received CAS Outfall 002 All samples are GRAB, unless otherwise noted, at Lab Method number sampled 4/30/07 Total Silver gel EPA 200.8 7440224

<1 ug/I Total Thallium gel EPA 200.8 7440280

<1 ug/l Total Zinc gel EPA 200.8 7440666

<10 ug/I Table 4 Conventional and Non-conventional pollutants to be tested by existing discharges if expected to be present in discharge (Table IV from 40CFR 122, Appendix D)

Aluminum, Total gel EPA 200.8 7429905 67.9 ug/I Barium, Total gel EPA 200.8 7440393 23.0 ug/I Boron, Total gel EPA 200.8 7440428 26.0 ug/I Bromide gel EPA 300 7726956.0

<0.200 mg/I Cobalt, Total gel EPA 200.8 62207765

<1.00 ug/I Fluoride gel SM 4500-F B 7782414 0.110 mg/I Iron, Total gel EPA 200.8 none 316 ug/I Magnesium, Total gel EPA 200.8 7439954 12400 ug/I Manganese, Total gel EPA 200.8 7439965 7.27 ug/I Molybdenum, total gel EPA 200.8 7439987 1.26 ug/I Nitrate-Nitrite (as N) gel EPA 353.2 none 0.446 mg/I EPA Nitrogen, total Organic. as N gel 351.2/350.1 none 193 ug/I n

e Radioactivity gel EPA 900 none Alpha, total gel EPA 900 none

<5.00 pCi/I Beta, total gel EPA 900 none

<5.00 pci/I Radium, Total gel EPA 900 7440144

<1.00 pci/I Radium 226, total gel EPA 900 7440144

<1.00-pCi/I Sulfate (as S04) gel EPA 300.0 none 24.6 mg/I Sulfide (as S) gel SM 4500-S F 18496258

<0.100 Mg/I Sulfite (as S03) gel SM 4500-SO3 B none

<2.00 mg/I Tin, Total gel EPA 200.8 7440315.

<5.0 ug/I

Donald C. Cook Nuclear Plant NPDES Permit IM10005827 Table 1 required analyses Analysis (Gray highiite is repeat from previous table)

Sample Received CAS Outfall 002 All samples are GRAB, unless otherwise noted.

at Lab Method number sampled 4/30/07 Titanium, total gel EPA 200.8 7440326

<10 ug/I Table 5 - Toxic pollutants and hazardous Substances required to be identified by Existing Discharges if Expected to Be present in Discharge (Table V from 40 CFR 122, Appendix D)

Toxic Pollutant Hazardous Substances 1,2 Napthoquinone-4 sulfric Acid method Hydrazine ug/l COOK ASTM*D-1385-88 302012

<3.0 Lithium gel EPA 200U 11097691

<96.0 ug/h Polychlorinated biphenyIs (PCB) gel 5WV 846 8082 11097691

<0.0943 uG/h Conductivitiy COOK 1201 none 324 us/cm

Michigan Department of Environmental Quality-Water Bureau WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information EASE TYPE OR PRINT ACILITY NAME NPDES PERMIT NUMBER OUTFALL NUMBER Donald C. Cook Nuclear Plant MI0005827 002

9.

WATER TREATMENT ADDITIVES Water treatment additives include any material that is added to water used at the facility or to wastewater generated by the facility to condition or treat the water.

Approvals of water treatment additives are authorized by the MDEQ under separate correspondence. The issuance of an.NPDES permit does not constitute approval of the water treatment additives that are included in this Application.

A. Are there water treatment additives in the discharge from this facility?

[

Yes.

ED No. Proceed to Item 10.

B. Have these water treatment additives been previously approved?

Z Yes. Submit a list of the previously-approved water treatment additives and the date on which they were approved. The information listed in Item C., Items 1-8 shall be updated if it has changed since the. previous approval.

El No. Continue with Item C.

C. Submit a list of water:treatment additives that are or may be discharged from the facility. Applicants are required to submit the information listed below for each additive.

1.

The water treatment additive Material.Safety Data Sheet.

2.

The proposed water treatment additive discharge concentration.

3.

The discharge frequency (i.e., number of hours per day, week, etc.).

4.

The outfall from which the wafter treatment additive is to be discharged.

5.

The type of removal treatment, if any, that the water treatment additive receives prior to discharge.

6.'

The water treatment additive function (i.e., microbiocide, flocculant, etc.).

7.

A 48-hour LC50 or EC50 for a North American freshwater planktonic crustacean (either Ceriodaphnia sp., Daphnia sp., or Simocephalus sp.).

8.

The results of a toxicity test for one other North American freshwater aquatic species (other than a planktonic crustacean) that meets a minimum requirement of Rule 323.1057(2)(a) of the Water Quality Standards. Examples of tests that would meet this requirement include a 96-hour LC50 for rainbow trout, bluegill, or fathead minnow.

The required toxicity information (described in Items 7 and 8 above) is currently available in the Water Bureau files for the water treatment additives listed on the MDEQ's Internet page. To access that information, go to http://www.michigan.govldeq, click on "Site Map," at the bottom of the right column under Water Quality Monitoring, click on "Assessment of Michigan Waters."

Under the Information heading, click on the "Water Treatment Additive List." If you intend to use one of the" water treatment additives on this list, only the information in Items 1 through 6 above needs to be submitted to the Water Bureau.

Note: The availability of toxicity information for a water treatment additive does not constitute approval to discharge the water treatment additive.

10.

WHOLE EFFLUENT TOXICITY (WET) TESTS Have any acute or chronic WET tests been conducted on any discharges or receiving water(s) in relation to facility discharges within the last three

.years? If yes, identify the tests and summarize the results on a separate sheet, unless the test has been submitted to the MDEQ in the last three years. For assistance with VVET testing, see Whole Effluent Toxicity Test Guidance and Requirements" in the Appendix.

11.

CONCENTRATED ANIMAL FEEDING OPERATION (CAFO) INFORMATION. To be completed by CAFOs only The applicant shall provide: Specific information about the number and type of animals, and type of housing; the type of containment and storage, and the total capacity for CAFO waste storage; CAFO waste storage structure design; the total number of acres under the control of the applicant that is available for land application of CAFO waste; the estimated amounts of CAFO waste generated per year; the estimated amounts of CAFO waste that is transferred to other persons per year; a list and map(s) showing the location of all land application fields; and all potential receiving waters for both the production and all land application areas. For additional information, see "CAFO Guidance and Requirements" in the Appendix.

-his completes Section II1. Return the completed Application (Sections I, Ill, and IV and any attachments) to one of the addresses Page ii of this Application. If assistanceis needed to complete this Application, contact the Permits Section.

7 EQP 4659-C (Rev. 11/2007)

Michigan Department of Environmental Quality-Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION II - Industrial and Commercial Wastewater B. Outfall Information PLEASE TYPE OR PRINT FACILITY NAME I

Donald C. Cook Nuclear Plant NPDES or COC PERMIT NUMBER Outfall Number M10005827 001,002,003

9. WATER TREATMENT ADDITIVES Previously permitted Maximum discharge Water Treatment Additive Approval Date concentrations. As applied for under Part 1.6 of the current NPDES permit, "Request for Discharge of Water Treatment Additives." (Based on 2 cire water pumps in operation during discharge event)

Sodium Hypochlorite 5/23/00 NPDES Permit approval 9/28/95 38 ug/1 (continuous) 200 ug/1 (intermittent)

Betz CT-1300 Formerly called Betz NPDES Permit approval 9/28/95, 5/23/00, 0.07 mg/1 CT-2 (Molluscicide) 2/28/02, 6/13/03 Calgon H-130M (Molluscicide) 8/16/95, 5/23/00 0.012 mg/1 Calgon EVAC (Molluscicide) 8/8/00 0.078 mg/I Nalco Macrotrol 9380 (Molluscicide) 8/16/95, 5/23/00, 2/28/02 0.01 mg/1 (4)

Nalco Macrotrol 9210 (Molluscicide) 8/16/95, 5/23/00, 2/28/02 0.08 mg/I (4)

Nalco TRASAR 23299 5/23/00, 9/17/96 0.146 rg/i (4)

Fluorescein Dye 9/21/98 Per rule 97 for certification of Dyes Bentonite Clay 5/23/2000, NPDES Permit approval 9/28/95 (5)

Betz Ferroquest FQ LP 7200 (Formerly 11/14/94, 5/23/00, 9/17/96, NPDES Permit 0.033 mg/I Called Betz Depositrol 855D) approval 9/28/95 Sodium Tetraborate (Borax) 5/23/00, 4/16/98 1.5 mg/1 (6)

SF6 (Sulphur hexafluoride gas)

NPDES Permit approval 9/28/95 2.5 mg/1 Betz Corrshield NT 4205 (Formerly 6/23/99, 9/17/96 2.6 mg/1 (3)

Powerline 3231) (Nitrite additive.)

Calgon LCS-60 (Nitrite additive.)

6/23/99, NPDES Permit approval 9/28/95 0.86 mg/1 Betz Corrshield NT4201 5/17/02 1.95 mg/1 (2)

(Nitrite additive.)

Betz Corrshield NT 4203 9/18/02 1.48 mg/1 (1)

(Nitrite additive.)

Spectrus NX 1105 (Formerly Betz 6/23/99, 5/23/00 0.083 mg/I Biotrol 107) (Gluteraldehyde)

Calgon H-300 (Gluteraldehyde) 6/23/99, 5/23/00 0.065 mg/1 Betz AZ 8103 (Formerly Bet Copper-12/18/95, 6/23/99, 5/23/00 0.2 mg/1 Trol Cu-1 (Tolyltriazole)

Betz 3610 (Methyl (Bis) Thiocyanate) 6/23/99 0.026 ms/1 Betz MD-4103 (Mo0 4) 3/26/02

].65 Mg]

Carbohydrazide solutions such as: Betz 3/24/94 NPDES application, 4/15/94

• 0.029 mg/1 Cbrtro) OS5613, Nalco 1250 plus approval, NPDES Permit approval 9/28/95 Ethanolamine 5/23/00, NPDES approval 9/28/95 0.01 mg/1 Betz Steamate 1480N, Nalco 92UM001 Hydrazine:

5/23/00, NPDES approval 9/28/95 0.1 MOg/

Betz Cortrol 0S5035, OS 5010, Nalco 19H Betz AZ8101 3/31/2005 0.32 mg/1 Betz Ferroquest FQ7101 8/28/2007 0.54 mg/I Betz Ferroquest FQ7102 8/28/2007 0.27 mg/i Betz Spectrus DT 1404 Approved 2/13/08 0.21 rmg/1 (Sodium Bisulfite)

(1) 3 pumps running for extra dilution: 1.0 mg/I (2) 3 pumps running for extra dilution: 1.3 mg/I (3) 3 pumps running for extra'dilution':.t:.7irg/1 (4) 6 times per year, 16 hrs per day (5)

Nalco 9380: 9.8-14.3 lbs clay: I lb of 9380 Betz CT-1300: 7.5 lbs clay: 1 lb of CT-1300 (6) 1 Circ pump minimum dilution

Michigan Department of Environmental Quality-Water Bureau WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information omplete a separate Section III.B. - Outfall Information (Pages 20-25) - for each outfall at the facility. Make copies of this

.nk section of the Application as necessary for additional outfalls.

PLEASE TYPE OR PRINT FACILITY NAME NPDES PERMIT NUMBER OUTFALL NUMBER Donald C. Cook Nuclear Plant MI0005827J 003

1.

OUTFALL INFORMATION - Instructions for this item are on Page 3 of the Appendix.

El No Change From Last Application, Items A. - D.

A.

B.

C.

D.

Receiving Water Hydrologic Unit Code (HUC)

Lake Michigan 04040001 County Township Berrien Lake Town Range Section 24 Y/4, /4 Private (French) Land Claim) 06S 19W 06 NW SW Latitude Longitude 41 58.668'

-086 34.448' E.

Type of Wastewater Discharged (check all that apply to this outfall):

El No Change From Last Application, Item E.

[

Contact Cooling El Groundwater Cleanup Rl Hydrostatic Pressure Test El Noncontact Cooling Water

[

Process Wastewater El Sanitary Wastewater El Storm Water - not regulated

[

Storm Water - regulated El Storm water subject to effluent guidelines (indicate under which category):

[

Other - specify (see "Table 8 - Other Common Types of Wastewater" - in the Appendix) Intake Screen Backwash. Floor Drainage water, F.

What is the Maximum Design Flow Rate for this outfall:

2369 MGD El No Change From Last Application, Items F. - G.

G What is the Maximum Authorized Discharge Flow for this outfall for the next five years?

Seasonal Dischargers Continuous Dischargers MGY (Continue with Item H).

MGD (Continue with Item I).

H.

Seasonal Discharge:

List the discharge periods (by month) and the volume discharged in the space provided below.

1.

From Through Actual Discharge Volume (MGD)

Annual Total From Through Actual Discharge Volume (MGD)

From Through Actual Discharge Volume (MGD)

From Through Actual Discharge Volume (MGD)

Continuous Discharge:

How often is there a discharge from this outfall (on average)?

24 Hours/Day 365 Days/Year Batch dischargers are required to provide the following additional information:

Is there effluent flow equalization?

El Yes El No Batch Peak Flow Rate:

Number of batches discharged per day: __

Minimum Average Maximum Batch Volume (gallons)

Batch Duration (minutes) 2 EQP 4659-C (Rev. 11/2007)

Michigan Department of Environmental Quality-Water Bureau WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information "LEASE TYPE OR PRINT CILITY NAME Donald C. Cook Nuclear Plant NPDES PERMIT NUMBER I M10005827 OUTFALL NUMBER 003

2.

PROCESS STREAMS CONTRIBUTING TO OUTFALL DISCHARGE

[] No Change From Last Application Federal regulations require that different industries report different information, depending on the type of facility. The information below is used to determine the applicable federal regulations for this facility. An abbreviated list is in the Summary of Information to be reported by Industry Type section of the.Appendix. Applicants are required to provide the name and the SIC or the NAICS code for each process at the facility. Facilities with production-based limits must report an estimated annual production rate for the next five years, or the life of the permit. If the wastestream is not regulated under federal categorical standards, the applicant is required to report all pollutants which have the reasonable potential to be present in the discharge. To submit additional information, see Page ii, Item 3.

PROCESS INFORMATION A.

Name of the process contributing to the discharge: ODA B.

SICorNAICS code: SIC-4911, NAICS221113 C.

Describe the process and provide measures of production:

Steam Generator Blowdown. 1 MGD maximum flow,2247 MWE total plant electrical generation PROCESS INFORMATION A.

Name of the process contributing to the discharge: 0DB B.

SIC or NAICS code: SIC - 4911, NAICS 221113 C.

Describe the process and provide measures of production:

.Steam Generator Blowdown. 1 MGD maximum flow, 2247 MWE total plant electrical generation PROCESS INFORMATION A.

Name of the process contributing to the discharge: O0C B.

SIC or NAICS code: SIC - 4911. NAICS 221113 C.

Describe the process and provide measures of production:

Auxiliary boiler Blowdown. 0.043 MGD maximum flow, 2247 MWE total plant electrical generation PROCESS INFORMATION A.

Name of the process contributing to the discharge: DOG B.

SIC or NAICS code: SIC - 4911, NAICS 221113 C.

Describe the process and provide measures of production:

Reverse osmosis reject stream 0.366 MGD maximum flow 2247 MWE total plant electrical generation.

PROCESS INFORMATION A.

Name of the process contributing to the discharge: 00H B.

SIC or NAICS code: SIC - 4911. NAICS 221113 C.

Describe the process and provide measures of production:

Miscellaneous equipment drains and processes. Maximum flow is 5.2 MGD. 2247 MWE total plant electrical generation. This Outfall is used for emergency purposes only.

PROCESS INFORMATION A.

Name of the process contributing to the discharge: Misc Minor Stormwater drains B.

SIC or NAICS code: SIC - 4911, NAICS 221113 C.

Describe the process and provide measures of production:

.)of drains from the screenhouse roof, small roadway gratings above the forebay road.

3 EQP 4659-C (Rev. 11/2007)

Michigan Department of Environmental Quality-Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information PLEASE TYPE OR PRINT FACILITY NAME ClNPDES or COC PERMIT NUMBER Outfall Number Donald C. Cook Nuclear Plant[

M10005827 003

3. Effluent characteristics Conventional pollutants.

Water discharged from Outfall 003 is the same as Outfall 001 and 002. Permission has been granted to use the Table 1 data from Outfall 001 to characterize this discharge.

IENNIFER M-GRANHOLM GOVERNOR STATE OF.M]CI-nGAN DEPARTMENT OF ENVIRONMENTAL QUALITY KALAMAZOO DISTRIcT OFFICE STEVEN E. CHESTER DIRECTOR February 12, 2008 Mr. Blaire Zordell Cook Nuclear Plant One Cook Plaza Bridgman, Michigan 49106

SUBJECT:

Application Renewal for NPDES Permit National Pollutant Discharge Elimination System (NPDES) No. M10005827 Designated Name: American Elec Power-Cook Pit, Berrien County..

We have reviewed the information provided in your letter of February 21, 2007. In that letter, you requested that the data from representative outfalls be used in the permit application submittal to characterize effluent characteristics for similar outfalls. We approve your request as follows:

1. Effluent from Outfall 001 will be considered representative of outfalls 001, 002, and 003.

2. Effluent from Outfall 00B will be considered representative of Outfalls O0A, 00B, and 00C.

Please feel free to contact me if you have any questions.

Sincerely, J5ohn Vollmer Environmental Quality Analyst Kalamazoo District Office Field Operations Division Water Bureau 269-567-3576 jv/dims cc: Mr. Dan Dell, DEQ Mr. Michael Walterhouse, DEQ CS-f 7953 ADOBE ROAD " <ALAMAZOO, MICHIGAN 49009-5026 www.michigan.gov - (269) 567-3500

'6~L~r-

Michigan Department of Envir(

ntal Quality-Water Bureau WASTEWATER DISCHARUtE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information PLEASE TYPE OR PRINT FACILITY NAME

/ NPDES PERMIT NUMBER OUTFALL NUMBER Donald C. Cook Nuclear Plant M10005827 003

3.

EFFLUENT CHARACTERISTICS - CONVENTIONAL POLLUTANTS - Instructions for this item are on Page 4 of the Appendix.

El Check this box if additional information is included as an attachment. To submit additional information, see Page ii, Item 3.

Please Note: Rule 323.1062 allows the use of either Escherichia Coil or Fecal Coliform Bacteria as an indicator that effluent has been disinfected. The MDEQ will use the indicator selected below in the permit issued based on this Annlicatinn 1-] H.s Escherichia Coi as; an indicator of disinfection M-t se Fecal Coliform Bacteria as an indicator of disinfection.

17 Use Outfall 001 data Biochemical Oxygen Demand - five day (BODs) mg/I I

LI Grab El 24 Hr Comp El Use Outfall 001 data Chemical Oxygen Demand (COD) mg/I El Grab El 24 Hr Comp E)

Use Outfall 001 data Total Organic Carbon (TOC) mg/i El Grab El 24 Hr Comp El Grab El Use Outfall 001 data Ammonia Nitrogen (as N) mg/I El 2rCo

[]24 Hr Comp El Grab El Use Outfall 001 data Total Suspended Solids mg/I El 24 Hr Comp 4 HGrab El Use Outfall 001 data Total Dissolved Solids mg/I El 24 Hr Comp El Grab El Use Outfall 001 data Total Phosphorus (as P) mg/I El 24 Hr Comp El Use Outfall 001 data Fecal Coliform Bacteria (report geometric means)

Maximum-7day counts/i100ml Grab El Use Outfall 001 data Escherichia Co/i (report geometric means)

Maximum-7day counts/100 ml Grab El Use Outfall 001 data Total Residual Chlorine El mg/I Grab

______________E

1. ig/I Grab_____

Minimum daily El Grab E]

Use Outfall 001 data Dissolved Oxygen Pi."got i.24 HrmC/I

,_______E 24 Hr Comp Minimum Maximum[]Ga El Use Outfall 001 data pH (report maximum and minimum of individual samples) standard units Grab El 24 Hr Comp El Grab El Use Outfall 001 data Temperature, Summer El OF E[C El Grab E

24 Hr Comp

[]Grab El Use Outfall 001 data Temperature, Winter

'F E

C.

El Gra Use__

001__ data_

Oil El 24 Hr Comp El Use Outfall 001 data Oil & Grease mg/I Grab 4

EQP 4659-C (Rev. 11/2007)

Michigan Department of Environmental Quality-Water Bureau WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information

)mplete a separate Section IlIl.B. - Outfall Information (Pages 20-25) - for each outfall at the facility. Make copies of this

.ank section of the Application as necessary for additional outfalls.

PLEASE TYPE OR PRINT FACILITY NAME NPDES PERMIT NUMBER I OUTFALL NUMBER Donald C. Cook Nuclear PlantI M10005827 00A

1.

OUTFALL INFORMATION - Instructions for this item are on Page 3 of the Appendix.

El No Change From Last Application, Items A. - D.

A.

B.

C.

D.

Receiving Water Hydrologic Unit Code (HUC)

Lake Michigan 04040001 County Township Berrien Lake Town Range Section

/4 Y4, Y Private (French) Land Claim) 06S 19W 06 NW SW Latitude Longitude na - internal outfall na - internal outfall E.

Type of Wastewater Discharged (check all that apply to this outfall):

El No Change From Last Application, Item E.

El Contact Cooling E] Groundwater Cleanup El Hydrostatic Pressure Test El Noncontact Cooling Water

[

Process Wastewater El Sanitary Wastewater El Storm Water - not regulated El Storm Water - regulated r_

Storm water subject to effluent guidelines (indicate under which category):

El Other - specify (see "Table 8 - Other Common Types of Wastewater" - in the Appendix)

F.

What is the Maximum Design Flow Rate for this outfall:

1 G

What is the Maximum Authorized Discharge Flow for this outfall for the next five years?

El No Change From Last Application, Items F. - G.

Seasonal Dischargers MGY (Continue with Item H).

Continuous Dischargers 1 MGD (Continue with Item 1).

H.

Seasonal Discharge:

List the discharge periods (by month) and the volume discharged in the space provided below.

1.

From Through Actual Discharge Volume (MGD)

Annual Total From Through Actual Discharge Volume (MGD)

From Through Actual Discharge Volume (MGD)

From Through Actual Discharge Volume (MGD)

Continuous Discharge:

How often is there a discharge from this outfall (on average)?

24 Hours/Day 365 Days/Year Batch dischargers are required to provide the following additional information:

Is there effluent flow equalization?

El Yes El No Batch Peak Flow Rate: '

Number of batches discharged per day: __

Minimum Average Maximum Batch Volume (gallons)

Batch Duration (minutes) 2 EQP 4659-C (Rev. 11/2007)

Michigan Department of Environmental Quality-Water Bureau WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information

-EASE TYPE OR PRINT

.31L1-TY NAME uonald C. Cook Nuclear Plant NPDES PERMIT NUMBER

. M10005827 OUTFALL NUMBER OQA

2.

PROCESS STREAMS CONTRIBUTING TO OUTFALL DISCHARGE l] No Change From Last Application Federal regulations require that different industries report different information, depending on the type of facility. The information below is used to determine the applicable federal regulations for this facility. An abbreviated list is in the Summary of Information to be reported by Industry Type section of the Appendix. Applicants are required to provide the name and the SIC or the NAICS code for each process at the facility. Facilities with production-based limits must report an estimated annual production rate for the next five years, or the life of the permit. If the wastestream is not regulated under federal categorical standards, the applicant is required to report all pollutants which have the reasonable potential to be present in the discharge. To submit additional information, see Page ii, Item 3.

PROCESS INFORMATION A.

Name of the process contributing to the discharge: Unit One Steam Generator Blowdown B.

SIC or NAICS code: SIC-4911, NAICS 221113 C.

Describe the process and provide measures of production:

Steam Generator Blowdown. 1 MGD maximum flow, 2247 mWe total electrical generation PROCESS INFORMATION A.

Name of the process contributing to the discharge: __

B.

SIC or NAICS code:

C.

Describe the process and provide measures of production:

PROCESS INFORMATION A.

Name of the process contributing to the discharge: __

B.

SIC or NAICS code:

C.

Describe the process and provide measures of production:

PROCESS INFORMATION A.

Name of the process contributing to the discharge:

B.

SIC Or NAICS code:

C.

Describe the process and provide measures of production:

PROCESS INFORMATION A.

Name of the process contributing to the discharge: __

B.

SIC or NAICS code:

C.

Describe the process and provide measures of production:

PROCESS INFORMATION A.

Name of the process contributing to the discharge:*

B.

SIC or NAICS code:

C.

Describe the process and provide measures of production:

3 EQP 4659-C (Rev. 11/2007)

Michigan Department of Environmental Quality-Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information PLEASE TYPE OR PRINT FACILITY NAME NPDES or COC PERMIT NUMBER

[ Outfall Number Donald C. Cook Nuclear Plant M10005827 OOA

3. Effluent characteristics Conventional pollutants.

Water Discharged from Outfall 0OB is the same as Outfall OOA and Outfall 00C. Written permission has been obtained from the Kalamazoo District Office on February 12. 2008 to use the Table 1 data from Outfall GOB to characterize this discharge. When available, Outfall O0A data has been included in the submittal. In Section III.B.3, pH and Dissolved.Oxygen data is from Outfall O0A.

Applicable process control data is included electronically as additional data from Outfall O0A.

JENNIFER M. GRANHOLM GOVERNOR STATE OF NVfiCHIGAN DEPARTMENT OF ENVIRONMENTAL QUALITY KALAMAZOO DisTRIC OFFICE STEVEN E. CHESTER DIRECTOR February 12, 2008 Mr. Blaire Zordell Cook Nuclear Plant One Cook Plaza Bridgman, Michigan 49106

SUBJECT:

Application Renewal for NPDES Permit National Pollutant Discharge Elimination System (NPDES) No. M10005827 Designated Name: American Elec Power-Cook PIt, Berrien County We have reviewed the information provided in your letter of February'21, 2007. In that letter, you requested that the data from representative outfalls be used in the permit application submittal to characterize effluent characteristics for similar outfalls. We approve your request as follows:,

1. Effluent from Outfall 001 will be considered representative of outfalls 001, 002, and 003.

2. Effluent from Outfall 0OB will be considered representative of Outfalls OOA, 00B, and 00C.

Please feel free to contact me if you have any questions.

Sincerely,

/

John Vollmer Environmental Quality Analyst Kalamazoo District Office Field Operations Division Water Bureau 269-567-3576 jv/dms cc:

Mr. Dan Dell, DEQ Mr. Michael Walterhouse, DEQ

~00 gI v-'

7953 ADOBE ROAD - KALAMAZOO, MICHIGAN 49009-5026 www.michigan.gov - (269) 567-3500 i~&-~- (~g I

Michigan Department of Envirc ntal Quality-Water Bureau WASTEWATER DISCHARurE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information PLEASE TYPE OR PRINT FACILITY NAME NPDES PERMIT NUMBER OUTFALL NUMBER Donald C. Cook Nuclear Plant M10005827 O0A

3.

EFFLUENT CHARACTERISTICS - CONVENTIONAL POLLUTANTS - Instructions for this item are on Page 4 of the Appendix.

[

Check this box if additional information is included as an attachment. To submit additional information, see Page ii, Item 3.

Please Note: Rule 323.1062 allows the use of either Escherichia Colt or Fecal Coliform Bacteria as an indicator that effluent has been disinfected. The MDEQ will use the indicator selected below in the permit issued based on this Annlication F-I Us-e Escherichia Coli as an indicator of disinfectionM I]-, Use Fecal Coliform Bacteria as an indicator of disinfection.

Rl Biochemical Oxygen Demand - five day (BOD5) 5.24 5.24 mg/I 1

EL Grab

0. 24 Hr Comp El Chemical Oxygen Demand (COD) 27.9 27.9 mg/i EI Grab

[24 Hr Comp El Total Organic Carbon (TOC) 3.62 3.62 mg/I 1

El Grab

[]24 Hr Camp El Ammonia Nitrogen (as N) 1.38 1.38 mg/I 1

E Grab

[

24 Hr Comp El Total Suspended Solids

<6.25

<6.25 mg/I 1

El Grab

_ _ 24 Hr Comp

[] Grab El Total Dissolved Solids 12.0 12.0 mg/I 1

2 r Co El 24 Hr Comp El Grab El Total Phosphorus (as P)

<0.05

<0.05 mg/I 1

E 2rCm

[] 24 Hr Comp El Not expected to be present Fecal Coliform Bacteria (report geometric means)

Maximum-7day counts/100mi Grab El Not expected to be present Escherichia Colt (report geometric means)

Maximum-7day counts/100 ml Grab El Total Residual Chlorine

<80

<80 1l mg/I Grab SPg/I Dissolved Oxygen Minimum daily mg/I 5

Grab 0

El 24 Hr Comp Minimum Maximum ED~ Grab El pH (report maximum and minimum of individual samples) 1istandard units 9E 2rC 9.7 10.3 stnadEnt 93[

24 Hr Comp El-Grab El na-internal outfall Temperature, Summer EOF EOC

[I 2rab El 24 Hr Comp El na - internal outfall Temperature, Winter El "F El C

El Grab E] 24.Hr Comp El Oil & Grease

<4.0

<4.0 mg/i 1

Grab 4

EQP 4659-C (Rev. 11/2007)

Michigan Department of Environmental Quality-Water Bureau WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information

-' EASE TYPE OR PRINT OILITY NAME NPDES PERMIT NUMBER OUTFALL NUMBER oonald C. Cook Nuclear PlantI MI0005827 00A Note: For questions on this page, Tables 1-5 are found in the Appendix.

4.

PRIMARY INDUSTRY PRIORITY POLLUTANT INFORMATION Existing primary industries that discharge process wastewater are required to submit the results of at least one permittee-collected effluent analysis for selected organic pollutants identified in Table 2 (as determined from Table 1, Testing Requirements for Organic Toxic Pollutants by Industrial Category), and all of the pollutants identified in Table 3. Existing primary industries are required to also provide the results of at least one permittee-collected effluent analysis for any other chemical listed in Table 2 known or believed to be present in the facility's effluent.

In addition, submit the results of all other effluent analyses performed within the last three years for any chemical listed in Tables 2 and 3.

New primary industries that propose to discharge process wastewater are required to provide an estimated effluent concentration for any chemical listed in Tables 2 and 3 expected to be present in the facility's effluent.

5.

DIOXIN AND FURAN CONGENER INFORMATION Existing industries that use or manufacture 2,3,5-tdchlorophenoxy acetic acid (2,4,5-T); 2-(2,3,5-trichlorophenoxy) propanoic acid, (Silvex, 2,3,5-TP); 2-(2,4,5-trichlorophenoxy) ethyl 2,2-dichloropropionate (Erbon); 0,0-dimethyl 0-(2,4,5-trichlorophenyl) phosphorothionate (Ronnel);

2,4,5-trichlorophenol (TCP); or hexachlorophrene (HCP), or knows or has reason to believe that 2,3,.7,8-Tetrachlorodibenzo-p-dioxin (TCDD) is present in the facility's effluent, are required to submit the results of at least one effluent analysis for the dioxin and furan congeners listed in Table

6. All effluent analyses for dioxin and furan congeners shall be conducted using USEPA Method 1613.

In addition, submit the results of all other effluent analyses performed within the last three years for any dioxin and furan congener listed in Table 6.

New industries that expect to use or manufacture 2,3,5-trichlorophenoxy acetic acid (2,4,5-T); 2-(2,3,5-trichlorophenoxy) propanoic acid (Silvex, 2,3,5-TP); 2-(2,4,5-trichlorophenoxy) ethyl 2,2-dichloropropionate (Erbon); 0,0-dimethyl 0-(2,4,5-tdchlorophenyl) phosphorothionate (Ronnel);

2,4,5-trichlorophenol (TCP); or hexachlorophrene (HCP), or knows or has reason to believe that 2;3,7,8-Tetrachlorodibenzo-p-dibxin (TODD) is present in the facility's effiuent, shall provide estimated effluent concentrations for the dioxin and uran congeners listed in Tabie 6.

OTHER INDUSTRY PRIORITY POLLUTANT INFORMATION Existing secondary industries, or existing primary industries that discharge nonprocess wastewater, are required to submit the results of at least one effluent analysis for ary chemical listed in Tables 2 and 3 known or believed to be present in the facility's effluent.

In addition, submit the results of all other effluent analyses performed within the last three years for any chemical listed in Tables 2 and 3.

New secondary industries, or new primary industries that propose to discharge nonprocess wastewater, are required to provide an estimated effluent concentration for any chemical listed in Tables 2 and 3 expected to be present in the facility's effluent.

7.

ADDITIONAL TOXIC AND OTHER POLLUTANT INFORMATION All existing industries, regardless of discharge type, are required to provide the results of at least one analysis for any chemical listed in Table 4 known or believed to be present in the facility's effluent, and a measured or estimated effluent concentration for any chemical listed in Table 5 known or believed tobe present in the facility's effluent. In addition, submit the results of any effluent analysis performed within the last three years for any chemical listed in-Tables 4 and 5.

New industries, regardless of discharge type, are required to provide an estimated effluent concentration for any chemical listed in Tables 4 and 5 expected to be present in the facility's effluent.

8.

INJURIOUS CHEMICALS NOT PREVIOUSLY REPORTED

• New or existing industries, regardless of discharge type, are required to provide a measured or estimated effluent concentration for any toxic or otherwise injurious chemicals known or believed to be present in the facility's effluent that have not been previously identified in this Application.

Quantitative effluent data for these chemicals that is less than five years old shall be reported.

NOTE: All effluent data submitted in response to questions 4, 5, 6, 7, and 8 above should be recorded on Page 24.

To submit additional information, see Page ii, Item 3. If the effluent concentrations are estimated, place an "E in the "Analytical Method" column. The following fields shall be completed for each data row:

Parameter, CAS No., Concentration(s), Sample Type, and Analytical Method.

For analytical test requirements, see Page ii, Item 5.

If Alternate Test Procedures have been approved for any parameter listed above (Items 4 through 8), see Page ii, Item 5 for additional instructions.

5

Michigan Department of Environmental Quality-Water Bureau WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B.

Outfall Information

-EASE TYPE OR PRINT

,-ACILITY NAME Donald C. Cook Nuclear Plant NPDES PERMIT NUMBER M10005827 OUTFALL NUMBER I oA I

Submitted via DMR's El See attached data sheet.

0]

See attached electronic data.

0 0]

0]

0]

0[

0 0

0]

0]

0].

0]

0]

0]

0]

0]

0]

0]

0]

0]

0]

1 -

6 EQP 4659-C (Rev. 11/2007)

Donald C, Cook Nuclear Plant NPDES Permit M10005827 Table I required analyses Analysis (Gray highlite is repeat from previous table)

Sample Received CAS Outfall OOA All samples are GRAB, unless otherwise noted, at Lab Method number sampled 5/01/07

• Addltional data found Required In electronic form Biochemical Oxygen Demand (Five day BOD5) (24 hr Comp) gel SM 5210B None 5.24 mg/I Chemical oxygen Demand (COD) (24 hr Comp) gel EPA 410.4 None 27.9 mg/I Total organic carbon (TOC) (24 hr Comp) gel SM 5310B None 3.62 mg/I Ammonia Nitrogen (as N) (24 hr Comp) gel EPA 350.1 7664417 1.38 mg/I Total Suspended Solids (24 hr Comp) gel SM 2540D None

<6.25 mg/I Temperature Summer (Max July 07)

Cook SM 2550B None na-internal outfall Temperature Winter (Max Jan 07)

Cook SM 2550B None na-internal outfall pH Cook SM 4500-H+B None From plant data*

• Addltlonal data found Report available data In electronic form Total Dissolved Solids gel SM 2540C None 12.0 mg/I Total Phosphorus (24 hr Comp) gel EPA 365.4 7723140

<0.05 mg/I Total Residual Chlorine COOK EPA 330.5 electrode 7782505

<80 ug/h Dissolved oxygen COOK SM 4500-0 C None From plant data*

Oil and Grease gel EPA1664a None

<4.0 mg/I Table 2-Organic Toxic Pollutants (Table II from 40 CFR 122, Appendix D)

Volatiles 1,1,1-Trichloroethane gel EPA 624

.71556

<1.00 ug/I 1,1,2,2-Tetrachloroethane gel EPA 624 79345

<1.00 ug/I 1,1,2-Trichloroethane gel EPA 624 79005

<1.00 ug/I 1,1-Dichloroethane gel EPA 624 75343

<1.00 ug/I 1,1-Dichloroethylene gel EPA 624 75354

<1.00 ug/I 1,2-Dichloroethane gel EPA 624 107062

<1.00 ug/I 1, 2-Dichloropropane gel EPA 624 78875

<1.00 ug/I 1,2-Trans-Dichloroethylene gel EPA 624 1 56605

<1.00 ug/I 1,3-Dichloropropylene (Listed in GEL as cis 1,3 Dichloropropylene and Trans 1,3 Dichloropropylene) gel EPA 624 542756

<1.00 ug/I 2-Chloroethylvinylether gel EPA624 110758

<5.00 ug/I

Donald C. Cook Nuclear Plant NPDES Permit M10005827 Table 1 required analyses Analysis (Gray highlite is repeat from previous table)

Sample Received CAS Outfall O0A All samples are GRAB, unless otherwise noted, at Lab Method number sampled 5/01/07 Acrolein gel EPA 624 107028

<5.00 ug/I Acrylonitrile gel EPA 624 107131

<5.00 ug/I Benzene gel.

EPA 624 71432

<1.00 ug/I Bromoform gel EPA 624 75252

<1.00 ug/I Carbon Tetrachloride gel EPA 624 56235

<1.00 Ug/I Chlorobenzene gel EPA 624 108907

<1.00 ug/I Chlorodibromomethane (Dibromochloromethane) gel EPA 624 124481

<1.00 ug/I Chloroethane gel EPA 624 75003

<1.00 ug/I Chloroform gel EPA 624 67663

<1.00 ug/I Dichlorobromomethane(bromodichloromethane) gel EPA 624 75274

<1.00 ug/I Ethylbenzene gel EPA 624 100414

<1.00 ug/I Methyl Bromide(brornomethane) gel EPA 624 74839

<1.00 ug/!

Methyl Chloride (chloromethane) gel '

EPA 624 74873

<1.00 ug/l Methylene Chloride gel.

EPA 624 75092

<2.00 ugh!

Tetrachloroethylene gel EPA624 127184

<1.00 ug/I Toluene gel EPA 624 108883

<1.00 ug/I Trichloroethylene gel.

EPA 624 79016

<1.00 ug/I Vinyl Chloride gel EPA 624 750174

<1.00 ug/I Acid Compounds 2,4,6-Trichlorophenol gel.

EPA 625 88062

<9.62 ug/I 2,4-Dichlorophenol gel EPA 625 120832

<9.62 ug/I 2,4-Dimethylphenol gel EPA 625 105679

<9.62 ug/I 2,4-Dinitrophenol gel EPA 625 51285

<19.2 ug/I 2-Chlorophenol gel EPA 625 95578

<9.62 ugh!

2-nitrophenol gel EPA 625 88755

<9.62 ug/I 4,6-Dinitro-O-Cresol (2-Methyl-4,6-Dinitrophenol) gel EPA 625 534521

<9.62 ug/I 4-Nitrophenol gel EPA 625 100027

<9.62 ug/I P-Chloro-M-Cresol (4-chloro-3-methylphenol) gel EPA 625 none

<9.62 ug/I Pentachlorophenol gel EPA 625 87865

<9.62 ug/I Phenol gel EPA 625 108952

<9.62 ug/I Base/Neutral

Donald C. CooK Nuclear Plant NPDES Permit'MI0005827 Table 1 required analyses Analysis (Gray highlite is repeat from previous table)

Sample Received CAS Outfall OOA All samples are GRAB, unless otherwise noted, at Lab Method number sampled 5/01/07 1,2,4-Trichlorobenzene gel EPA 625 120821

<9.62 ug/I 1,2-Dichlorobenzene gel EPA 625 95501

<9.62 ug/I 1,2-Diphenylhydrazine (As Azobenzene) gel EPA 625 122667

<9.62 ug/I 1,3-Dichlorobenzene gel.

EPA 625 541731

<9.62 ug/I 1,4-Dichlorobenzene gel EPA 625 106467

<9.62 ug/I 2,4-Dinitrotoluene gel EPA 625 121142

<9.62 ug/I 2,6-Dinitrotoluene gel EPA 625 606201

<9.62 ug/I 2-Chloronaphthalene gel EPA 625 91587

<0.962 ug/I 3,3'-Dichlorobenzidine gel EPA 625 91941

<9.62 ug/I 3,4-Benzofluoranthene (Benzo(b)fluoranthene,)

. gel EPA 625 205992

<0.962 ug/I 4-Bromoph enylphenylether gel EPA 625 101553

<9.62 ug/I 4-Chlorophenyl Phenyl Ether gel EPA 625 7005723

<9.62 ug/I Acenaphthene gel.

EPA 625 63329

<0.962 ug/I Acenaphthylene gel EPA 625 208968

<0.962 ug/I Anthracene g el EPA 625 120127

<0.962 ug/I Benzidine (benzyl alcohol) gel.

EPA 625 92875

<9.62 ug/I Benzo (a) Anthracene gel EPA 625 56553

<0.962. ug/I Benzo (a) Pyrene gel EPA 625 50328

<0.962 ug/I Benzo (ghi) Perylene gel EPA 625 191242

<0.962 ug/I Benzo (k) Fluoranthene gel EPA 625 207089

<0.962 ug/I Bis (2-Chloroethoxy) Methane gel; EPA 625 111911

<9.62 ug/I Bis (2-Chloroethyl) Ether gel EPA 625 111444

<9.62 ug/I Bis (2-Chloroisopropyl) Ether gel EPA 625 108601

<9.62 ug/I Bis (2-Ethylhexyl) Phthalate gel EPA 625 117817

<9.62 ug/I Butylbenzyl Phthalate gel EPA 625 85687

<9.62 ug/I Chrysene gel EPA 625 218019

<0.962 ug/I Di-N-Butyl Phthalate gel EPA 625 84742

<9.62 ug/f Di-N-Octyl Phthalate gel EPA 625 117840

<9.62 ug/I Dibenzo (a,h) Anthracene gel EPA 625 53703

<0.962 ug/I Diethyl Phthalate

. gel EPA 625 84662

<9.62 ug/I Dimethyl Phthalate gIel.

EPA 625 131113

<9.62 ug/I Fluoranthene gel EPA 625 206440

<0.962 ug/I

Donald C. Cook Nuclear Plant NPDES Permit M10005827 Table 1 required analyses Analysis (Gray highlite is-repeat from previous table)

Sample Received CAS Outfall OOA All samples are GRAB, unless otherwise noted.

at Lab Method number sampled 5/01/07 Fluorene gel EPA 625 86737

<0.962 ug/I Hexachlorobenzene gel EPA 625 118741

<9.62 ugll Hexachlorobutadiene gel EPA 625 87683

<9.62 ug/I Hexachlorocyclopentadiene gel -

EPA 625 77474

<9.62 ug/I Hexachloroethane gel EPA 625

• 67721

<9.62 ug/I Indeno (1,2,3-cd). Pyrene gel EPA 625 193395

<0.962 ugli Isophorone gel EPA 625 78591

<9.62 ug/I N-Nitrosodi-N-Propylamine gel EPA 625 none

<9.62 ug/I N-Nitrosodimethylamine (N-methyl-N-nitrosomethylamine) gel EPA 625 62759

<9.62 ug/I N-Nitrosodiphenylamine (Diphenylamine) gel EPA 625 86306

<9.62 ug/I Naphthalene gel EPA 625 91203

<0.962 ug/I Nitrobenzene gel EPA 625 98953

<9.62 ughI Phenanthrene gel EPA 625 85018

<0.962 ug/I Pyrene gel-EPA 625 129000

<0.962 ug/I Table 3 -Other Toxic Pollutants (metals and Cyanide) and Total Phenols.

(Table III from 40 CFR 122, Appendix D)

Total Antimony gel EPA 200.8 7440360

<1 ug/I Total Arsenic gel EPA 200.6 7440382

<1.50 ug/I Total Beryllium gel EPA 200,8 7440417

<1 ug/I Total Cadmium gel EPA 200.6 7440439

<0.2 ug/I Total Chromium gel EPA 200.8 7440473

<10 ug/I Total Copper gel EPA 200.8 7440508

<1 ug/I EPA method Available Cyanide kar OIA-1677 57125 7 ug/I Total Lead gel EPA 200.8 7439921

<1 ug/I EPA method Total Mercury gel 1631 7439976

<0.5 ng/I Total Nickel gel EPA 200.8 7440020

<5 ugh Total Phenols gel EPA 420.2 none

<5.00 ug/I Total Selenium gel EPA 200.8 7782792

<2.50 ug/I

Donald C. Cook Nuclear Plant NPDES Permit MI0005827 Table 1 required analyses Analysis (Gray highlite is repeat from previous table)

Sample Received CAS Outfall OOA All samples are GRAB, unless otherwise noted, at Lab Method number sampled 5/01/07 Total Silver gel EPA 200.8 7440224

<1 ug/I Total Thallium gel EPA 200.8 7440280

<1 ug/i Total Zinc gel EPA 200.8 7440666

<10 ug/I Table 4 Conventional and Non-conventional pollutants to be tested by existing discharges if expected to be present in discharge

• Additional data found (Table IV from 40CFR 122, Appendix D)

In electronic form Aluminum, Total gel EPA 200.8 7429905

<15.0 ug/I Barium, Total gel EPA 200.8 7440393

<2.0 ug/)

Boron, Total gel EPA 200.8 7440428

<20 ug/I Bromide gel EPA 300 7726956.0

<0.200 mg/I Cobalt, Total gel EPA 200.8 62207765

<1.00 ugh Fluoride gel SM 4500-F B 7782414

<0.1 mg/I Iron, Total gel EPA 200.8 none

<25.0 ug/I Magnesium, Total gel EPA 200.8 7439954

<15.0 ug/I

• Manganese, Total gel -

EPA 200.8 7439965

<5.00 ug/I

• Molybdenum, total gel EPA.200.8 7439987

<0.5 ug/h Nitrate-Nitrite (as N)

gel, EPA 353.2 none

<0.05 mg/I EPA Nitrogen, total Organic as N) gel

.351.2/350.1 none 1020 ug/1 x.......

Radioactivity gel EPA 900 none I

Alpha, total gel EPA 900 none

<5.00 pci/I Beta, total gel EPA 900 none

<5.00 pci/I Radium, Total gel EPA 900 7440144

<1.00 pci/I Radium 226, total gel EPA 900 7440144

<1.00 pci/I Sulfate (as S04) gel EPA 300.0 none

<0.400 mg/I

• Sulfide (as S) gel SM 4500-S F 18496258

<0.100 mg/I Sulfite (as S03) gel SM4500-SO3 B none

<2.00 mg/I Tin, Total gel EPA 200.8 7440315

<5.0 ug/I

Donald C. Cook Nuclear Plant NPDES Permit M10005827 Table 1 required analyses Analysis (Gray highlite is repeat from previous table)

Sample Received CAS Outfall OOA All samples are GRAB, unless otherwise noted.

at Lab Method number sampled 5101/07 Titanium, total gel EPA 200.8 7440326

<10 ug/I Table 5 - Toxic pollutants and hazardous Substances required to be identified by Existing Discharges if Expected to Be present in Discharge

• Additional data found (Table V from 40 CFR 122, Appendix D)

In electronic form Toxic Pollutant Hazardous Substances 1,2 Napthoquinone-4 sulfonic Ethanolamine mg/I COOK Acid method 141435 1.5*

Hydrazine ug/l COOK ASTM D-1385-88 302012 89.3

• Lithium gel EPA 200.8 11097691

<96.0 ug/I Polychlorinated bi hen Is PCB glSW 846 8082 11961<0.098 ug/I C. nductiv.

10..

g CondctivtiyCOOK120.

noe 0.6 uScm

Michigan Department of Environmental Quality-Water Bureau WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III -. Industrial and Commercial Wastewater B. Outfall Information EASE TYPE OR PRINT ACILITY NAME I NPDES PERMIT NUMBER OUTFALL NUMBER Donald C. Cook Nuclear Plant MI0005827 ODA

9.

WATER TREATMENT ADDITIVES Water treatment additives include any material that is added to water used at the facility or to wastewater generated by the facility to condition or treat the water.

Approvals of water treatment additives are authorized by the MDEQ under separate correspondence. The issuance of an NPDES permit does not

• constitute approval of the water treatment additives that are included in this Application.

A. Are there water treatment additives in the discharge from this facility?.

El Yes.

El No. Proceed to Item 10.

B. Have these water treatment additives been previously approved?

ED Yes. Submit a list of the previously-approved water treatment additives and the date on which they were approved. The information listed in Item C., Items 1-8 shall be updated if it has changed since the previous approval.

El No. Continue with Item C.

C. Submit a list of water treatment additives that are or may be discharged from the facility. Applicants are required to submit the information listed below for each additive.

1.

The water treatment additive Material Safety Data Sheet.

2.

The proposed water treatment additive discharge concentration.

3.

The discharge frequency (i.e., number of hours per day, week, etc.).

4.

The outfall from which the water treatment additive is to be discharged.

5.

The type of removal treatment, if any, that the water treatment additive receives prior to discharge.

6.

The water treatment additive function (i.e., microbiocide, flocculant, etc.).

7.

A 48-hour LC50 or EC50 for a North American freshwater planktonic crustacean (either Ceriodaphnia sp., Daphnia sp., or Simocephalus sp.).

8.

The results of a toxicity test for one other North American freshwater aquatic species (other than a'planktonic crustacean) that meets a minimum requirement of Rule 323.1057(2)(a) of the Water Quality Standards. Examples of tests that would meet this requirement include a 96-hour LC50 for rainbow trout, bluegill, or fathead minnow.

The required toxicity information (described in Items 7 and 8 above) is currently available in the Water Bureau files for the water treatment additives listed on the MDEQ's Internet page' To access that information, go to http://www.michigan.gov/deq, click on "Site Map," at the bottom of the right column under Water Quality Monitoring, click on "Assessment of Michigan Waters."

Under the Information heading,.click on the "Water Treatment Additive List." If you intend to use one of the water treatment additives on this list, only the information in Items I through 6 above needs to be submitted to the Water Bureau.

Note: The availability of toxicity information for a water treatment additive does not constitute approval to discharge the water treatment additive.

10.

WHOLE EFFLUENT TOXICITY (WET) TESTS Have any acute or chronic WET tests been conducted on any discharges or receiving water(s) in relation to facility discharges within the last three years? If yes, identify the tests and summarize the results on a separate sheet, unless the test has been submitted to the MDEQ in the last three years. For assistance with WET testing, see 'Whole Effluent Toxicity Test Guidance and Requirements" in the Appendix.

11: CONCENTRATED ANIMAL FEEDING OPERATION (CAFO) INFORMATION. To be completed by CAFOs only The applicant shall provide: Specific information about the number and type of animals, and type of housing; the type of containment and storage, and the total capacity for CAFO waste storage; CAFO waste storage structure design; the total number of acres under the control of the applicant that is available for land application of CAFO waste; the estimated amounts of CAFO waste generated per year; the estimated amounts of CAFO waste that is transferred to other persons per year; a list and map(s) showing the location of all land application fields; and all potential receiving waters for both the production and all land application areas. For additional information, see "'CAFO Guidance and Requirements" in the Appendix.

'is completesSection III. Return the completed Application (Sections I, III, and IV and any attachments) to one of the addresses

,Page ii of this Application. If assistance is needed to complete this Application, contactthe Permits Section.

7 EQP 4659-C (Rev. 11/2007)

Michigan Department of Environmental Quality-Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information PLEASE TYPE OR PRINT FACILITY NAME NPDES or COC PERMIT NUMBER Outfall Number Donald C. Cook Nuclear Plant M10005827 O0A

9. WATER TREATMENT ADDITIVES Previously permitted Maximum discharge Water Treatment Additive Approval Date concentrations. As applied for under Part 1.6 of the current NPDES permit, "Request for Discharge of Water Treatment Additives." (Based on 2 circ water pumps in operation during discharge event)

Carbohydrazide solutions such as: Betz 3/24/94 NPDES application, 4/15/94 0.029 mg/I Cortrol OS5613, Nalco 1250 plus approval, NPDES Permit approval 9/28/95 Ethanolamine 5/23/00, NPDES approval 9/28/95 0.01 mg/I Betz Steamate 1480N, Nalco 92UM001_

Hydrazine:

5/23/00, NPDES approval 9/28/95

0. 1 mg/1 Betz Cortrol OS5035, OS 5010, Nalco 19H

Michigan Department of Environmental Quality-Water Bureau WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information Tomplete a separate Section III.B. - Outfall Information (Pages 20-25) - for each outfall at the facility. Make copies of this ink section of the Application as necessary for additional outfalls.

PLEASE TYPE OR PRINT FACILITY NAME NPDES PERMIT NUMBER OUTFALL NUMBER Donald C. Cook Nuclear Plant M10005827 OB

1.

OUTFALL INFORMATION - Instructions for this item are on Page 3 of the Appendix.

El No Change From Last Application,. Items A. - D.

A.

B.

C.

D.

Receiving Water Hydrologic Unit Code (HUC)

Lake Michigan 014040001 County Township Berrien Lake Town Range Section Y4*, Y4 Private (French) Land Claim) 06S 19W 06 NW SW Latitude Longitude na - internal outfall na - internal outfall E.

Type of Wastewater Discharged (check all that apply to this outfall):

El No Change From Last Application, Item E.

El Contact Cooling El Groundwater Cleanup El Hydrostatic Pressure Test El Noncontact Cooling Water

[

Process Wastewater El Sanitary Wastewater El Storm Water - not regulated El Storm Water - regulated El Storm water subject to effluent guidelines (indicate under which category):

E] Other - specify (see "Table 8 - Other Common Types of Wastewater" - in the Appendix)

F.

What is the Maximum Design Flow Rate for this outfall: 1 G

What is the Maximum Authorized Discharge Flow for this outfall for the next five years?

El No Change From Last Application, Items F. - G.

Seasonal Dischargers MGY (Continue with Item H).

Continuous Dischargers 1 MGD (Continue with Item I).

H.

Seasonal Discharge:

List the discharge periods (by month) and the volume discharged in the space provided below.

1.

From Through Actual Discharge Volume (MGD)

Annual Total From Through Actual Discharge Volume (MGD)

From Through Actual Discharge Volume (MGD)

From Through Actual Discharge Volume (MGD)

Continuous Discharge:

.How often is there a discharge from this outfall (on average)?

24 Hours/Day 365 Days/Year Batch dischargers are required to provide the following additional information:

Is there effluent flow equalization?

El Yes El No Batch Peak Flow Rate:

Number of batches discharged per day: __

Minimum Average Maximum Batch Volume (gallons)

Batch Duration (minutes)

I 2

EQP 4659-C (Rev. 11/2007)

Michigan Department of Environmental Quality-Water Bureau WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information OLEASE TYPE OR PRINT

ýCILITY NAME Donald C. Cook Nuclear Plant NPDES PERMIT NUMBER M10005827 I OUTFALL NUMBER 00B13

2.

PROCESS STREAMS CONTRIBUTING TO OUTFALL DISCHARGE

[I No Change From Last Application Federal regulations require that different industries report different information, depending on the type of facility. The information below is used to determine the applicable federal regulations for this facility. An abbreviated list is in the Summary of Information to be reported by Industry Type section of the Appendix. Applicants are required to provide the name and the SIC or the NAICS code for each process at the facility. Facilities with production-based limits must report an estimated annual production rate for the next five years, or the life of the permit. If the wastestream is not regulated under federal categorical standards, the applicant is required to report all pollutants which have the reasonable potential to be present in the discharge. To submit additional information, see Page ii, Item 3.

PROCESS INFORMATION A.

Name of the process contributing to the discharge: Unit Two Steam Generator Blowdown.

B.

SIC or NAICS code: SIC -4911, NAICS 221113 N

C.

Describe the process and provide measures of production:

Steam Generator Blowdown. 1 MGD maximum flow,2247 MWE total plant electrical generation PROCESS INFORMATION A.

Name of the process contributing to the discharge:

B.

SIC or NAICS code:

C.

Describe the process and provide measures of production:

PROCESS INFORMATION A.

Name of the process contributing to the discharge: __

B.

SIC or NAICS code:

C.

Describe the process and provide measures of production:

PROCESS INFORMATION A.

Name of the process contributing to the discharge: __

B.

SIC or NAICS code:

C.

Describe the process and provide measures of production:

PROCESS INFORMATION A.

Name of the process contributing to the discharge: __

B.

SIC or NAICS code:

C.

Describe the process and provide measures of production:

PROCESS INFORMATION A.

Name of the process contributing to the discharge: __

B.

SIC or NAICS code:

C.

Describe the process and provide measures of production:

3 EQP 4659-C (Rev. 11/2007)

Michigan Department of Enviror tal Quality-Water Bureau WASTEWATER DISCHARG-PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information PLEASE TYPE OR PRINT FACILITY NAME NPDES PERMIT NUMBER OUTFALL NUMBER Donald C. Cook Nuclear Plant M10005827 OOB

3.

EFFLUENT CHARACTERISTICS - CONVENTIONAL POLLUTANTS - Instructions for this item are on Page 4 of the Appendix.

0 Check this box if additional information is included as an attachment. To submit additional information, see Page ii, Item 3.

Please Note: Rule 323.1062 allows the use of either Escherichia Coil or Fecal Coliform Bacteria as an indicator that effluent has been disinfected. The MDEQ will use the indicator selected below in the permit issued based on this Annircation. 1-is-qe E.whe~richia Coniq

a. an indicator of di.infP.ctino I iHe Fpr.l Cioliform Racteria as an indicator of disinfection.

El I Biochemical Oxygen Demand - five day (BOD5) 5.24 5.24 mg/i 1 1 El Grab 0 24 Hr Comp El Chemical Oxygen Demand (COD) 27.9 27.9 mg/I 1

El Grab

[_ 024 Hr Comp El Total Organic Carbon (TOC) 3.62 3.62 mg/I 1

El Grab Z0 24 Hr Comp E0 Ammonia Nitrogen (as N) 1.38 1.38 mg/I 1

El Grab 0] 24 Hr Comp El Total Suspended Solids

<6.25

<6.25 mg/I 1

]Ga El 24 Hr Comp El Total Dissolved Solids 12.0 12.0 mg/I 1

Grab E] 24 Hr Comp El Total Phosphorus (as P)

<0.05

<0.05 mg/I 1

0 Grab

[] 24 Hr Comp El Not expected to be present Fecal Coliform Bacteria (report geometric means)

Maximum-7day counts/100ml Grab El Not expected to be present Escherichia Coil (report geometric means)

Maximum-7day counts/100 ml Grab El Total Residual Chlorine

<80

<80 El mg/I 1

Grab Minimum daily mgI E 24GraCom El Dissolved. Oxygen mg/I 1

0.01

[] 24 Hr Comp Minimum Maximum 0] Grab El pH (report maximum and minimum of individual samples) 9.M 10.2 standard units 894 El 24 Hr Comp 9.8 10.2 El G4rabom El na-internal outfall Temperature, Summer EO -F El oC El Grab E] 24 Hr Comp El na - internal outfall Temperature, Winter El oF Eo °C El Grab

[] 24 Hr Comp El Oil & Grease

<4.0

<4.0 mg/I 1

Grab 4

EQP 4659-C (Rev. 11/2007)

Michigan Department of Environmental Quality-Water Bureau WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III Industrial and Commercial Wastewater B. Outfall Information DLEASE TYPE OR PRINT CILITY NAME NPDES PERMIT NUMBER OUTFALL NUMBER oonald C. Cook Nuclear Plant M10005827 D00B Note: For questions on this page, Tables 1-5 are found in the Appendix.

4.

PRIMARY INDUSTRY PRIORITY POLLUTANT INFORMATION Existing primary industries that discharge process wastewater are required to submit the results of at least one pemiittee-collected effluent analysis for selected organic pollutants identified in Table 2 (as determined from Table 1, Testing Requirements for Orqanic Toxic Pollutants by Industrial Categjory), and all of the pollutants identified in Table 3. Existing primary industries are required to also provide the results of at least one permittee-collected effluent analysis for any other chemical listed in Table 2 known or believed to be present in the facility's effluent.

In addition, submit the results of all other effluent analyses performed within the last three years for any chemical listed in Tables 2 and 3.

New primary industries that propose to discharge process wastewater are required to provide an estimated effluent concentration for any chemical listed in Tables 2 and 3 expected to be present in the facility's effluent.

5.

DIOXIN AND FURAN CONGENER INFORMATION Existing industries that use or manufacture 2,3,5-trichlorophenoxy acetic acid (2,4,5-T); 2-(2,3,5-tdchlorophenoxy) propanoic acid, (Silvex, 2,3,5-TP); 2-(2,4,5-trichlorophenoxy) ethyl 2,2-dichloropropionate (Erbon); 0,0-dimethyl 0-(2,4,5-trichlorophenyl) phosphorothionate (Ronnel);

2,4,5-trichlorophenol (TCP); or hexachlorophrene (HCP), or knows or has reason to believe that 2,3,7,8-Tetrachlorodibenzo-p-dioxin (TCDD) is present in the facility's effluent, are required to submit the results of at least one effluent analysis for the dioxin and furan congeners listed in Table

6. All effluent analyses for dioxin and furan congeners shall be conducted using USEPA Method 1613.

In addition, submit the results of all other effluent analyses performed within the last three years for any dioxin and furan congener listed in Table 6.

New industries that expect to use or manufacture 2,3,5-trichlorophenoxy acetic acid (2,4,5-T); 2-(2,3,5-trichlorophenoxy) propanoic acid (Silvex, 2,3,5-TP); 2-(2,4,5-trichlorophenoxy) ethyl 2,2-dichloropropionate (Erbon); 0,0-dimethyl 0-(2,4,5-trichlorophenyl) phosphorothionate (Ronnel);

2,4,5-trichlorophenol (TCP); or hexachlorophrene (HCP), or knows or has reason to believe that 2,3,7,8-Tetrachlorodibenzo-p-dioxin (TCDD) is present in the facility's effluent, shall provide estimated effluent concentrations for the dioxin and furan congeners listed in Table 6.

OTHER INDUSTRY PRIORITY POLLUTANT INFORMATION Existing secondary industries, or existing primary industries that discharge nonprocess wastewater, are required to, submit the results of at least one effluent analysis for any chemical listed in Tables 2 and 3 known or believed to be present in the facility's effluent.

In addition, submit the results of all other effluent analyses performed within t he last three years for any chemical listed in Tables 2 and 3.

New secondary industries, or new primary industries that propose to discharge nonprocess wastewater, are required to provide an estimated effluent concentration for any chemical listed in Tables 2 and 3 expected to be present in the facility's effluent.

7.

ADDITIONAL TOXIC AND OTHER POLLUTANT INFORMATION All existing industries, regardless of discharge type, are required to provide the results of at least one analysis for any chemical listed in Table 4 known or believed to be present in the facility's effluent, and a measured or estimated effluent concentration for any chemical listed in Table 5 known or believed to be present in the facility's effluent. In addition, submit the results of any effluent analysis performed within the last three years for any chemical listed in Tables 4 and 5.

New industries, regardless of discharge type, are required to provide an estimated effluent concentration for any chemical listed in Tables 4 and 5 expected to be present in the facility's effluent.

8.

INJURIOUS CHEMICALS NOT PREVIOUSLY REPORTED New or existing industries, regardless of discharge type, are required to provide a measured or estimated effluent concentration for any toxic or otherwise injurious chemicals known or believed to be present in the facility's effluent that have not been previously identified in this Application.

Quantitative effluent data for these chemicals that is less than five years old shall be reported.

NOTE: All effluent data submitted in response to questions 4, 5, 6, 7, and 8 above should be recorded on Page 24.

To submit additional information, see Page ii, Item 3. If the effluent concentrations are estimated, place an "E in the "Analytical Method" column. The following fields shall be completed for each data row:

Parameter, CAS No., Concentration(s), Sample Type, and Analytical Method.

For analytical test requirements, see Page ii, Item 5.

If Alternate Test Procedures have been approved for any parameter listed above (Items 4 through 8), see Page ii, Item 5 for additional instructions.

5

Michigan Department of Environmental Quality-Water Bureau WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information

""LEASE TYPE OR PRINT

, tACILITY NAME Donald C. Cook Nuclear Plant NPDES PERMIT NUMBER M10005827 OUTFALL NUMBER I nnl Submitted via DMR's El See attached data sheet.

El See attached electronic data.

El El El El El El El El El E]

El El El El El El El El El I.

J

-J 6

EQP 4659-C (Rev. 11/2007)

Donald C. Cook Nuclear Plant NPDES Permit M10005827 Table 1 required analyses Analysis (Gray highlite is repeat from previous table)

Sample Received CAS Outfall OOB All samples are GRAB, unless otherwise noted.

at Lab Method number sampled 5101/07

• Additional data found Required in electronic form Biochemical Oxygen Demand (Five day BOD5) (24 hr Comp) gel SM 5210B None 5.24 mg/I Chemical oxygen Demand (COD) (24 hr Comp) gel EPA 410.4 None 27,9 mg/I Total organic carbon (TOC) (24 hr Comp) gel SM 531OB None 3.62 mg/I Ammonia Nitrogen (as N) (24 hr Comp) gel EPA 350.1 7664417 1.38 mg/I Total Suspended Solids (24 hr Comp) gel SM 2540D None

<6.25 mg/I Temperature Summer (Max July 07)

Cook SM 2550B None na-internal outfall Temperature Winter (Max Jan 07)

Cook SM 2550B None na. int.ernal outfall pH Cook SM 4500-H+B None From plant data'

• Additional data found Report availabledata In electronic form Total Dissolved Solids gel SM 2540C None 12.0 mg/I Total Phosphorus (24 hr Comp) gel EPA 365.4 7723140

<0.05 mg/I Total Residual Chlorine COOK EPA 330.5 electrode 7782505

<80 Ug/I Dissolved oxygen COOK SM 4500-0 C None 0.01-mg/I Oil and Grease gel EPA1664a None

<4.0 mg/I Table 2-Organic Toxic Pollutants (Table II from 40 CFR 122, Appendix D)

Volatiles 1,1,1-Trichloroethane gel EPA 624 71556

<1.00 ug/I 1,12,2-Tetrachloroethane gel EPA 624 79345

<1.00 ug/I 1,1,2-Trichloroethane gel EPA 624 79005

<1.00 ug/I 1,1-Dichloroethane gel EPA 624 75343

<1.00 ug/I 1,1-Dichloroethylene gel EPA 624 75354

<1.00 ug/I 1,2-Dichloroethane gel EPA 624 107062

<1.00 ug/I 1,2-Dichloropropane gel EPA 624 78875

<1.00 ug/I 1,2-Trans-Dichloroethylene gel EPA 624 156605

<1.00 ug/I 1,3-Dichloropropylene (Listed in GEL as cis 1,3 Dichloropropylene and Trans 1,3 Dichloropropylene) gel EPA 624 542756

<1.00 ug/1 2-Chloroethylvinylether gel EPA 624 110758

<5.00 ug/I

Donald C. Cook Nuclear Plant NPDES Permit M10005827 Table 1 required analyses Analysis (Gray highlite is repeat from previous table)

Sample Received CAS Outfall 00B All samples are GRAB, unless otherwise noted, at Lab Method number sampled 5/01/07 Acrolein gel EPA 624 107028

<5.00 ug/I Acrylonitrile gel EPA 624 107131

<5.00 ug/I Benzene gel EPA 624 71432

<1.00 ug/I Bromoform gel EPA 624 75252

<1.00 ug/I Carbon Tetrachloride gel EPA 624 56235

<1.00 ug/I Chlorobenzene gel EPA 624 108907

<1.00 ug/I Chlorodibromomethane (Dibromochloromethane) gel EPA 624 124481

<1.00 ug/I Chloroethane gel EPA 624 75003

<1.00 ughi Chloroform gel EPA 624 67663

<1.00 ug/I Dichlorobromomethane(bromodichloromethane) gel EPA 624 75274

,<1.00 ug/I Ethylbenzene gel EPA 624 100414

<1.00 ug/i Methyl Bromide(bromomethane) gel EPA 624 74839

<1.00 ug/I Methyl Chloride (chloromethane) gel.

EPA 624 74873

<1.00 ug/I Methylene Chloride gel EPA 624 75092

<2.00 ug/I Tetrachloroethylene gel EPA 624 127184

<1.00 ug/I Toluene gel EPA 624 108883

<1.00 ug/I Trichloroethylene gel

'EPA 624.

79016

<1.00 ug/I Vinyl Chloride gel EPA 624 750174

<1.00 ug/I Acid Compounds 2,4,6-Trichlorophenol gel.

EPA 625 68062

<9.62 ug/I 2,4-Dichlorophenol gel EPA 625 120832

<9.62 ug/I 2,4-Dimethylphenol gel EPA 625 105679

<9.62 ug/I 2,4-Dinitrophenol gel EPA 625 51285

<19.2 ug/I 2-Chlorophenol gel EPA 625 95578

<9.62 ug/I 2-nitrophenol gel EPA 625 88755

<9.62 ug/I 4,6-Dinitro-O-Cresol (2-Methyl-4,6-Dinitrophenol) gel EPA 625 534521

<9.62 ug/I 4-Nitrophenol gel EPA 625 100027

<9.62 ug/I P-Chloro-M-Cresol (4-chloro-3-methylphenol) gel EPA 625 none

<9.62 ug/I Pentachlorophenol gel EPA 625 87865

<9.62 ug/I Phenol

-gel..

EPA 625 108952

<9.62 ug/I Base/Neutral

Donald C. Cook Nuclear Plant NPDES Permit M10005827 Table I required analyses Analysis (Gray highfite is repeat from previous table)

Sample Received CAS Outfall OOB All samples are GRAB, unless otherwise noted.

at Lab Method number sampled 5/01/07 1,2,4-Trichlorobenzene gel-EPA 625 120821

<9.62 ug/I 1,2-Dichlorobenzene gel EPA 625 95501

<9.62 ug/I 1,2-Diphenylhydrazine (As Azobenzene) gel

• EPA 625 122667

<9.62 ug/I 1,3-Dichlorobenzene gel EPA 625 541731

<9.62 ug/I.

1,4-Dichlorobenzene gel EPA 625 106467

<9.62 ugh!

2,4-Dinitrotoluene gel EPA 625 121142

<9.62 ug/I 2,6-Dinitrotoluene gel EPA 625 606201

<9.62 ug/I 2-Chloronaphthalene gel EPA 625 91587

<0.962 ug/I 3,3'-Dichlorobenzidine gel EPA 625 91941

<9.62 ug/I 3,4-Benzofluoranthene (Benzo(b)fluoranthene,)

gel EPA 625 205992

<0.962 ug/!

4-Bromophenylphenylether gel EPA 625 101553

<9.62 ug/I 4-Chlorophenyl Phenyl Ether gel EPA 625 7005723

<9.62 ug/I Acenaphthene gel EPA 625 83329

<0.962 ug/i Acenaphthylene gel

• . EPA 625 208968

<0.962 ug/I Anthracene gel EPA 625 120127.

<0.962 ug/I Benzidine (benzyl alcohol) gel EPA 625 92875

<9.62 ug/I Benzo (a) Anthracene gel EPA 625 56553

<0.962ug/I Benzo (a) Pyrene gel.

EPA 625 50328

<0.962 ug/I Benzo (ghi). Perylene gel.

EPA 625 191242

<0.962 ug/I Benzo (k) Fluoranthene gel EPA 625 207089

<0.962 ug/I Bis (2-Chloroethoxy) Methane gel EPA 625 111911

<9.62 ug/I Bis (2-Chloroethyl) Ether gel EPA 625 111444

<9.62 ug/!

Bis (2-Chloroisopropyl) Ether gel EPA 625 108601

<9,62 ug/I Bis (2-Ethylhexyl) Phthalate gel EPA 625 117817

<9.62 ug/I Butylbenzyl Phthalate gel EPA 625 85687

<9.62 ug/I Chrysene gel EPA 625 218019

<0.962 ug/I Di-N-Butyl Phthalate gel EPA 625 84742

<9.62 ug/I Di-N-Octyl Phthalate gel EPA 625 117840

<9.62 ug/I Dibenzo (a,h) Anthracene gel EPA 625 53703

<0.962 ug/I Diethyl Phthalate gel

._EPA 625 84662

<9.62 ug/I Dimethyl Phthalate gel.

EPA 625 131113

<9.62 ug/h Fluoranthene gel-EPA 625 206440

<0.962 ug/I

Donald C. Cook Nuclear Plant NPDES Permit M10005827 Table 1 required analyses Analysis (Gray highfite is repeat from previous table)

Sample Received CAS Outfall 00B All samples are GRAB, unless otherwise noted.

at Lab Method number sampled 5/01/07 Fluor6ne gel E'PA 625 86737

<0.962 ug/I Hexachlorobenzene gel EPA 625 116741

<9.62 ug/I Hexachlorobutadiene gel EPA 625 87683

<9.62 ug/I Hexachlorocyclopentadiene gel EPA 625 77474

<9.62 ug/I Hexachloroethane gel EPA 625 67721

<9.62 ug/l Indeno (1,2,3-cd) Pyrene gel EPA 625 193395

<0.962 ug/I Isophorone gel EPA 625 78591

<9.62 ug/I N-Nitrosodi-N-Propylamine gel EPA 625 none

<9.62 ug/I N-Nitrosodimethylamine (N-methyl-N-nitrosomethylamine) gel EPA 625 62759

<9.62 ug/I N-Nitrosodiphenylamine (Diphenylamine) gel EPA 625 86306

<9.62 ug/l Naphthalene gel EPA 625 91203

<0.962 ug/I Nitrobenzene gel EPA 625 98953

<9.62 ug/I Phenanthrene gel EPA 625 85018

<0.962 ug/I Pyrene gel EPA 625 129000

<0.962 ug/I Table 3 -Other Toxic Pollutants (metals and Cyanide) and Total Phenols.

(Table III from 40 CFR 122, Appendix D)

Total Antimony gel EPA,200.8 7440360

<1 ug/I Total Arsenic gel EPA 200.6 7440382

<1.50 ughI Total Beryllium gel EPA 200.8 7440417

<1 ug/I Total Cadmium gel EPA 200.8 7440439

<0.2 ug/l Total Chromium gel EPA 200.8 7440473

<10 ug/I Total Copper gel EPA 200.8 7440508

<1 ug/I EPA method Available Cyanide kar OIA-1677 57125 7 ug/I Total Lead gel EPA 200.8 7439921

<1 ugIh EPA method Total Mercury gel 1631 7439976

<0.5 ng/I Total Nickel gel EPA 200.8 7440020

<5 ug/I Total Phenols gel EPA 420.2 none

<5.00 ug/I Total Selenium gel EPA'200.8 7782792

<2.50 ug/I

Donald C. Cook Nuclear Plant NPDES Permit Mi0005827 Table 1 required analyses Analysis (Gray highlite is repeat from previous table)

Sample Received CAS Outfall 00B All samples are GRAB, unless otherwise noted.

at Lab Method number sampled 5/01/07 Total Silver gel EPA 200.8 7440224

<1 ug/h Total Thallium gel EPA 200.8 7440280

<1 ug/I Total Zinc gel EPA 200.8 7440666

<10 ug/h Table 4 Conventional and Non-conventional pollutants to be tested by existing discharges if expected to be present in discharge

• Additional data found (Table IV from 40CFR 122, Appendix D)

In electronic form Aluminum, Total gel EPA 200.8 7429905

<15.0 ug/I Barium, Total gel EPA 200.8 7440393

<2.0 ug/h Boron, Total gel EPA 200.8 7440428

<20 ug/1 Bromide gel EPA 300 7726956.0

<0.200 mg/I Cobalt, Total -

gel EPA 200.8 62207765

<1.00 ug/I Fluoride gel SM 4500-F B 7782414

<0.1 mg/I*

Iron, Total gel EPA 200.8 none

<25.0 ug/I Magnesium, Total gel EPA 200.8.

7439954

<15.0 ughi

• Manganese, Total gel EPA 200.8 7439965

<5.00 ug/

• Molybdenum, total gel EPA 200.8 7439987

<0.5 ug/I Nitrate-Nitrite (as N) gel EPA 353.2 none

<0.05 mg/I EPA Nitrogen, total Organic (as N) gel 351.2350.1 none 1020 ug/I X.::: ft:.

M.:;-Xi".;:.

Radioactivity gel EPA.900 none Alpha, total gel EPA 900 none

<5.00 pci/I Beta, total gel EPA 900 none

<5.00 pci/I Radium, Total gel EPA 900 7440144

<1.00 pCi/I Radium 226, total gel EPA 900 7440144

<1.00 pCi/I Sulfate (as S04)

. gel EPA 300.0 none

<0.400 mg/I*

Sulfide (as S) gel SM 4500-S F 18496258

<0.100 mg/I Sulfite (as S03) gel SM 4500-SO3 B none

<2.00 mg/I Tin, Total gel EPA 200.8 7440315

<5.0 ug/I

NPDES. Permit M10005827 Table 1 required analyses Donald C. Cook Nuclear Plant Analysis (Gray highlite is repeat from previous table)

Sample-Received CAS Outfall OOB All samples are GRAB, unless otherwise noted, at Lab Method number sampled 5/01107 Titanium, total gel EPA 200.8 7440326

<10 ug/I Table 5 - Toxic pollutants and hazardous Substances required to be identified by Existing Discharges if Expected to Be present in Discharge

• Additional data found (Table V from 40 CFR 122, Appendix D)

In electronic form Toxic Pollutant Hazardous Substances 1,2 Nrapthoquinone-4 sulfonic Arid m-th-1

Michigan Department of Environmental Quality-Water Bureau WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information

'EASE TYPE OR PRINT

,CILITY NAME NPDES PERMIT NUMBER OUTFALL NUMBER Donald C. Cook Nuclear Plant MI0005827 0DB

9.

WATER TREATMENT ADDITIVES Water treatment additives include any material that is added to water used at the facility or to wastewater generated by the facility to condition or treat the water.

Approvals of water treatment additives are authorized by the MDEQ under separate correspondence. The issuance of an NPDES permit does not constitute approval of the water treatment additives that are included in this Application.

A. Are there water treatment additives in the discharge from this facility?

23 Yes.

1l No. Proceed to Item 10.

B. Have these water treatment additives been previously approved?

[

Yes. Submit a list of the previously-approved water treatment additives and the date on which they were approved. The information listed in Item C., Items 1-8 shall be updated if it has changed since the previous approval.

Ml No. Continue with Item C.

C. Submit a list of water treatment additives that are or may be discharged from the facility. Applicants are required to submit the information listed below for each additive.

1.

The water treatment additive Material Safety Data Sheet.

2.

The proposed water treatment additive discharge concentration.

3.

The discharge frequency (i.e., number of hours per day, week, etc.).

4.

The outfall from which the water treatment additive is to be discharged.

5.

The type of removal treatment, if any, that the water treatment additive: receives prior to discharge.

6.

The water treatment additive function (i.e., microbiocide, flocculant, etc.).

7.

A 48-hour LC50 or EC50 for a North American freshwater planktonic crustacean (either Ceriodaphnia sp., Daphnia sp., or Simocephalus sp.).

8.

The results of a toxicity test for one other North American freshwater aquatic species (other than a planktonic crustacean) that meets a minimum requirement of Rule 323.1057(2)(a) of the Water Quality Standards. Examples of tests that would meet this requirement include a 96-hour LC50 for rainbow trout, bluegill, or fathead minnow.

The required toxicity information (described in Items 7 and 8 above) is currently available in the Water Bureau files for the water treatment additives listed on the MDEQ's Internet page. To access that information, go to http://Www.michigan.gov/deq, click on "Site Map," at the bottom of the right column under Water Quality Monitoring, click on "Assessment of Michigan Waters."

Under the Information heading, click on the "Water Treatment Additive List." If you intend to use one of the water treatment additives on this list, only the information in Items 1 through 6 above needs to be submitted to the Water Bureau.

Note: The availability of toxicity information for a water treatment additive does not constitute approval to discharge the water treatment additive.

10.

WHOLE EFFLUENT TOXICITY (WET)TESTS Have any acute or chronic WET tests been conducted on any discharges or receiving water(s) in relation to facility discharges within the last three years? If yes, identify the tests and summarize the results on a separate sheet, unless the test has been submitted to the MDEQ in the last three years. For assistance with WET testing, see Whole Effluent Toxicity Test Guidance and Requirements" in the Appendix.

11.

CONCENTRATED ANIMAL FEEDING OPERATION (CAFO) INFORMATION. To be completed by CAFOs only The applicant shall provide: Specific information about the number and type of animals, and type of housing; the type of containment and storage, and the total capacity for CAFO waste storage; CAFO waste storage structure design; the total number of acres under the control of the applicant that is available for land application of CAFO waste; the estimated amounts of CAFO waste generated per year; the estimated amounts of CAFO waste that is transferred to other persons per year; a list and map(s) showing the location of all land application fields; and all potential receiving waters for both the production and all land application areas. For additional information, see "CAFO Guidance and Requirements" in the Appendix.

'his completesSection III. Return the completed Application (Sections 1, 111, and IV and any attachments) to one of the addresses Page ii of this Application. If assistance is needed to complete this Application, contact the Permits Section.

7 EQP 4659-C (Rev. 11/2007)

Michigan Department of Environmental Quality-Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information PLEASE TYPE OR PRINT FACILITY NAME NPDES or COC PERMIT NUMBER Outfall Number Donald C. Cook Nuclear Plant M10005827 OOB

9. WATER TREATMENT ADDITIVES Previously permitted Maximum discharge Water Treatment Additive Approval Date concentrations. As applied for under Part 1.6 of the current NPDES permit, "Request for Discharge of Water Treatment Additives." (Based on 2 circ water pumps in operation during discharge event)

Carbohydrazide solutions such as: Betz 3/24/94 NPDES application, 4/15/94 0.029 mg/1 Cortrol OS5613, Nalco 1250 plus approval, NPDES Permit approval 9/28/95 Ethanolamine 5/23/00, NPDES approval 9/28/95 0.01 mg/1 Betz Steamate 1480N, Nalco

.92UM001 Hydrazine:

5/23/00, NPDES approval 9/28/95 0.1 mg/1 Betz Cortrol OS5035, OS 5010, Nalco 19H

Michigan Department of Environmental Quality-Water Bureau WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information omplete a separate Section III.B. - Outfall Information (Pages 20-25) - for each outfall at the facility. Makecopies of this 3nk section of the Application as necessary for additional outfalls.

PLEASE TYPE OR PRINT FACILITY NAME NPDES PERMIT NUMBER OUTFALL NUMBER Donald C. Cook Nuclear PlantI MI0005827 00C

1.

OUTFALL INFORMATION - Instructions for this item are on Page 3 of the Appendix.

El No Change From Last Application, Items A. - D.

A.

B.

C.

D.

Receiving Water Hydrologic Unit Code (HUC)

Lake Michigan 04040001 County Township Berrien Lake Town Range Section 1/4 1/4, 1/4 Private (French) Land Claim) 06S 19W 06 NW SW Latitude Longitude na - internal outfall na - internal outfall E.

Type of Wastewater Discharged (check all that apply to this outfall):

E] No Change From Last Application, Item E.

El Contact Cooling 0l Groundwater Cleanup El Hydrostatic Pressure Test El Noncontact Cooling Water

[

Process Wastewater El Sanitary Wastewater E3 Storm Water - not regulated El Storm Water - regulated El Storm water subject to effluent guidelines (indicate under which category):

ED Other - specify (see "Table 8 - Other Common Types of Wastewater" - in the Appendix)

F.

What is the Maximum Design Flow Rate for.this outfall: 0.043 MGD G

What is the Maximum Authorized Discharge Seasonal Dis Flow for this outfall for the next five years?

Continuous E El No Change From Last Application, Items F. - G.

chargers MGY (Continue with Item H).

)ischargers 0.043. MGD (Continue with Item I).

H.

Seasonal Discharge:

List the discharge periods (by month) and the volume discharged in the space provided below.

1.

From Through Actual Discharge Volume (MGD)

Annual Total From Through Actual Discharge Volume (MGD)

From Through Actual Discharge Volume (MGD)

From Through Actual Discharge Volume (MGD)

Continuous Discharge:

How often is there a discharge from this outfall (on average)?

24 Hours/Day 365 Days/Year Batch dischargers are required to provide the following additional information:

Is there effluent flow equalization?

El Yes El No Batch Peak Flow Rate:

Number of batches discharged per day: __

Minimum Average Maximum Batch Volume (gallons)

Batch Duration (minutes) 2 EQP 4659-C (Rev. 11/2007)

Michigan Department of Environmental Quality-Water Bureau WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information PLEASE TYPE OR PRINT CILITY NAME

,onald C. Cook Nuclear Plant NPDES PERMIT NUMBER M10005827 I OUTFALL NUMBER 00C

2.

PROCESS STREAMS CONTRIBUTING TO OUTFALL DISCHARGE El No Change From Last Application Federal regulations require that different industries report different information, depending on the type of facility. The information below is used to determine the applicable federal regulations for this facility. An abbreviated list is in the Summary of Information to be reported by Industry Type section of the Appendix., Applicants are required to provide the name and the SIC or the NAICS code for each process at the facility. Facilities with production-based limits must report an estimated annual production rate for the next five years, or the life of the permit If the wastestream is not regulated under federal categorical standards, the applicant is required to report all pollutants which have the reasonable potential to be present in the discharge. To submit additional information, see Page ii, Item 3.

PROCESS INFORMATION A.

Name of the process contributing to the discharge: Plant heating boiler blowdown B.

SIC or NAICS code: SIC - 4911. NAICS 221113 C.

Describe the process and provide measures of production:

Plant heating boiler blowdown 0.043 MGD maximum flow. 2247 MWE total plant electrical generation.

PROCESS INFORMATION A.

Name of the process contributing to the discharge:

B.

SIC.or NAICS code:

C.

Describe the process and provide measures of production:

PROCESS INFORMATION A.

Name of the process contributing to the discharge: __

B.

SIC or NAICS code:

C.

Describe the process and provide measures of production:

PROCESS INFORMATION A.

Name of the process contributing to the discharge: __

B.

SIC or NAICS code:

C.

Describe the process and provide measures of production:

PROCESS INFORMATION A.

Name of the process contributing to the discharge:

B.

SIC or NAICS code:

C.

Describe the process and provide measures of production:

PROCESS INFORMATION A.

Name of the process contributing to the discharge:

B.

SIC or NAICS code:

C.

Describe the process and provide measures of production:

3 EQP 4659-C (Rev. 11/2007)

Michigan Department of Environmental Quality-Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information PLEASE TYPE OR PRINT FACILITY NAME NPDES or COC PERMIT NUMBER Outfall Number Donald C. Cook Nuclear Plant M10005827 00C

3. Effluent characteristics Conventional pollutants.

Water Discharged from Outfall 0GB is the same as Outfall O0A and Outfall 00C.' Written permission has been obtained from the Kalamazoo District Office on February 12. 2008 to use the Table 1 data from Outfall 0OB to characterize this discharge. When available, Outfall 00C data has been included in the submittal. In Section III.B.3, pH and Dissolved Oxygen data is from Outfall 0OC. Applicable process control data is included electronically as additional data from Outfall 00C.

hNNIFER M. GRANHOLM GOVERNOR STATE OF N1"ICI-nc.AN DEPARTMENT OF ENVIRONMENTAL QUALITY KALAMAZOO DIsTRICT OFFICE D,

STEVEN E. CHESTER DIRECTOR February 12, 2008 Mr. Blaire Zordell Cook Nuclear Plant One Cook Plaza Bridgman, Michigan 49106

SUBJECT:

Application Renewal for NPDES Permit National Pollutant Discharge Elimination System (NPDES) No. M10005827 Designated Name: American Elec Power-Cook Pit, Berrien County We have reviewed the information provided in your letter of February 21, 2007. In that letter, you requested that the data from representative outfalls be used in the permit application submittal to characterize effluent characteristics for similar outfalls. We approve your request as follows:

1. Effluent from Outfall 001 will be considered representative of outfalls 001, 002, and 003.

2. Effluent from Outfall 00B will be considered representative of Outfalls O0A, OOB, and OOC.

Please feel free to contact me if you have any questions.

Sincerely,:

John Vollmer Environmentai Quality Analyst Kalamazoo District Office Field Operations Division Water Bureau 269-567-3576 jv/dms cc: Mr. Dan Dell, DEQ Mr. Michael Walterhouse, DEQ 7953 ADOBE ROAD-KALAMAZOO, MICHIGAN 49009-5026 www.michigan.gov - (269) 567-3500

Michigan Department of Enviro ital Quality-Water Bureau WASTEWATER DISCHARGe-PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information PLEASE TYPE OR PRINT FACILITY NAME NPDES PERMIT NUMBER OUTFALL NUMBER Donald C. Cook Nuclear Plant M0005827 NUMBC

3.

• EFFLUENT CHARACTERISTICS - CONVENTIONAL POLLUTANTS - Instructions for this item are on Page 4 of the Appendix.

0 Check this box if additional information is included as an attachment. To submit additional information, see Page ii, Item 3.

Please Note: Rule 323.1062 allows the use of either Escherichia Coli or Fecal Coliform Bacteria as an indicator that effluent has been disinfected. The MDEQ will use the indicator selected below in the permit Biochemical Oxygen Demand - five day (BODs) 5.24 5.24 mg/I 1

0l Grab Z 24 Hr Comp Ej Grab Chemical Oxygen Demand (COD) 27.9 27.9 mg/I 1

]0 24 Hr Comp El Grab Total Organic Carbon (TOC) 3.62 3.62 mg/I 1

E 2rCo

[] 24 Hr Comp Ammonia Nitrogen (as N) 1.38 1.38 mg/i 1

El Grab 0 24 Hr Comp

[]Grab Total Suspended Solids mg/I El 24 Hr Comp 0 Grab Total Dissolved Solids 12.0 12.0 mg/I 1

El 24 Hr Comp 0] Grab Total Phosphorus (as P)

<0.05

<0.05 mg/I 1

El Grab Total 0 24 Hr Comp Not expected to be present Fecal Coliform Bacteria (report geometric means)

Maximum-7day counts/100mi Grab Not expected to be present Eschefichia Colt (report geometric means)

Maximum-7day counts/1 00 ml Grab Total Residual Chlorine

<80

<80 mg/i 1

Grab

[] ýtg/l Minimum daily 0] Grab Dissolved Oxygen Y

' Net Use mg/I 10 0

El 24 Hr Comp Minimum Maximum 0] Grab pH (report maximum and minimum of individual samples) 8.3 9.7 standard units 9

El 24 Hr Comp El Grab na-internal outfall Temperature, Summer El

°F El C El 2rCo

• .[j 24 Hr Comp El Grab

.na - internal outfall Temperature, Winter E]

°F E]

EC 24 HrCb El 24 Hr Comp Oil & Grease

<4.0

<4.0 mg/I 1

Grab 4

EQP 4659-C (Rev. 1112007)

Michigan Department of Environmental Quality-Water Bureau WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information PLEASE TYPE OR PRINT

.CILITY NAME I NPDES PERMIT NUMBER OUTFALL NUMBER Oonald C. Cook Nuclear PlantI Mi0005827 00C Note: For questions on this page, Tables 1-5 are found in the Appendix.

4.

PRIMARY INDUSTRY PRIORITY POLLUTANT INFORMATION Existing primary industries that discharge process wastewater are required to submit the results of at least one permittee-collected effluent analysis for selected organic pollutants identified in Table 2 (as determined from Table 1, Testinq Requirements for Organic Toxic Pollutants by Industrial Category), and all of the pollutants identified in Table 3. Existing primary industries are required to also provide the results of at least one permittee-collected effluent analysis for any other chemical listed in Table 2 known or believed to be present in the facility's effluent.

In addition, submit the results of all other effluent analyses performed within the last three years for any chemical listed in Tables 2 and 3.

New primary industries that propose to discharge process wastewater are required to provide an estimated effluent concentration for any chemical listed in Tables 2 and 3 expected to be present in the facility's effluent.

5.

DIOXIN AND FURAN CONGENER INFORMATION Existing industries that use or manufacture 2,3,5-trichlorophenoxy acetic acid (2,4,5-T); 2-(2,3,5-trichlorophenoxy) propanoic acid, (Silvex, 2,3,5-TP); 2-(2,4,5-trichlorophenoxy) ethyl 2,2-dichloropropionate (Erbon); 0,0-dimethyl 0-(2,4,5-trichlorophenyl) phosphorothionate (Ronnel);

• 2,4,5-trichlorophenol (TCP); or hexachlorophrene (HCP), or knows or has reason to believe that 2,3,7,8-Tetrachlorodibenzo-p-dioxin (TCDD) is present in the facility's effluent, are required to submit the results of at least one effluent analysis for the dioxin and furan congeners listed in Table

6. All effluent analyses for dioxin and furan congeners shall be conducted using USEPA Method 1613.

In addition, submit the results of all other effluent analyses performed within the last three years for any dioxin and furan congener listed in Table 6.

New industries that expect to use or manufacture 2,3,5-trichlorophenoxy acetic acid (2,4,5-T); 2-(2,3,5-trichlorophenoxy) propanoic acid (Silvex, 2,3,5-TP); 2-(2,4,5-trichlorophenoxy) ethyl 2,2-dichloropropionate (Erbon); 0,0-dimethyl 0-(2,4,5-trichlorophenyl) phosphorothionate (Ronnel);

2,4,5-trichlorophenol (TCP); or hexachlorophrene (HCP), or knows or has reason to believe that 2,3,7,8-Tetrachlorodibenzo-p-dioxin (TCDD) is present in the facility's effluent, shall provide estimated effluent concentrations for the dioxin and furan congeners listed in Table 6.

OTHER INDUSTRY PRIORITY POLLUTANT INFORMATION Existing secondary industries, or existing primary industries that discharge nonprocess wastewater, are required to submit the results of at least one effluent analysis for any chemical listed in Tables 2 and 3 known or believed to be present in the facility's effluent.

In addition, submit the results of all other effluent analyses performed within the last three years for any chemical listed in Tables 2 and 3.

New secondary industries, or new primary industries that propose to discharge nonprocess wastewater, are required to provide an estimated effluent concentration for any chemical listed in Tables 2 and 3 expected to be present in the facility's effluent

7.

ADDITIONAL TOXIC ANDOTHER POLLUTANT INFORMATION All existing industries, regardless of discharge type, are required to provide the results of at least one analysis for any chemical listed in Table 4 known or believed to be present in the facility's effluent, and a measured or estimated effluent concentration for any chemical listed in Table 5 known or believed tobe present in the facility's effluent. In addition, submit the results of any effluent analysis performed within the last three years for any chemical listed in Tables 4 and 5.

New industries, regardless of discharge type, are required to provide an estimated effluent concentration for any chemical listed in Tables 4 and 5 expected to be present in the facility's effluent.

8.

INJURIOUS CHEMICALS NOT PREVIOUSLY REPORTED New or existing industries, regardless of discharge type, are required to provide a measured or estimated effluent concentration for any toxic or otherwise injurious chemicals known or believed to be present in the facility's effluent that have not been previously identified in this Application.

Quantitative effluent data for these chemicals that is less than five years old shall be reported.

NOTE: All effluent data submitted in response to questions 4, 5, 6, 7, and 8 above should be recorded on Page 24. To submit additional information, see Page ii, Item 3. If the. effluent concentrations are estimated, place an "E in the "Analytical Method" column. The following fields shall be completed for each data row:

Parameter, CAS No., Concentration(s), Sample Type, and Analytical Method.

For analytical test requirements, see Page ii, Item 5.

If Alternate Test Procedures have been approved for any parameter listed above (Items 4 through 8), see Page ii, Item 5 for additional instructions.

5

Michigan Department of Environmental Quality-Water Bureau WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B.

Outfall Information PLEASE TYPE OR PRINT

. ACILITY NAME Donald C. Cook Nuclear Plant NPDES PERMIT NUMBER M10005827 OUTFALL NUMBER Ir nn-I via DMR's El See attached data sheet.

El See attached electronic data.

El El El El El El El El El_

El El El El El FJ El El El El El El El El El 6

EQP 4659-C (Rev. 11/2007)

Donald C. Cook Nuclear Plant

-NPDES Permit M1000582.7 Table 1 required analyses Analysis (Gray highlite is repeat from previous table)

Sample Received CAS Outfall 00C All samples are GRAB, unless otherwise noted.

at Lab Method number sampled 5/01/07

• Additional data found Required In electronic form Biochemical Oxygen Demand (Five day BOD5) (24 hr Comp) gel SM 5210B None 5.24 mg/I Chemical oxygen Demand (COD) (24 hr Comp) gel EPA 410.4 None 27.9 mg/I Total organic carbon (TOC) (24 hr Comp) gel SM 5310B None 3.62 mg/I Ammonia Nitrogen (as N) (24 hr Comp) gel EPA 350.1 7664417 1.38 mg/I Total Suspended Solids (24 hr Comp) gel SM 2540D None.

EDMR Temperature Summer (Max July 07)

Cook SM 2550B None na-Internal outfall Temperature Winter (Max Jan 07)

Cook SM 2550B None na-internal outfall pH Cook SM 4500-H+B None From plant data*

• Additional data found Report available data In electronic form Total Dissolved Solids gel SM 2540C None 12.0 mg/I Total Phosphorus (24 hr Comp) gel EPA 365..4 7723140

<0.05 mg/I Total Residual Chlorine COOK EPA 330.5 electrode 7782505

<80 ug/h Dissolved oxygen COOK SM 4500:0 C None From plant data*

Oil and Grease gel EPA1664a None

<4.0 mg/I Table 2-Organic Toxic Pollutants (Table II from 40 CFR 122, Appendix D)

Volatiles 1,1 1-Trichloroethane gel '

EPA 624 71556

<1.00 ug/1 1,1,2,2-Tetrachloroethane gel EPA 624 79345

<1.00 ug/I 1,1,2-Trichloroethane gel EPA 624 79005

<1.00 ug/I 1,1-Dichloroethane gel EPA 624 75343

<1.00 ug/I 1,1-Dichloroethylene gel EPA 624 75354

<1.00 ug/I 1,2-Dichloroethane gel EPA 624 107062

<1. Mug/I 1,2-Dichloropropane gel EPA 624 78875

<1.00 ug/h 1,2-Trans-Dichloroethylene gel EPA 624 156605

<1.00 ug/I 1,3-Dichloropropylene (Listed in GEL as cis 1,3 Dichloropropylene and Trans 1,3 Dichloropropylene) gel...

EPA.624 542756

<1.00 ug/I 2-Chloroethylvinylether gel EPA 624 110758

<5.00 ug/I

Donald C. Cook Nuclear Plant NPDES Permit MI0005827 Table 1 required analyses Analysis (Gray highfite is repeat from previous table)

Sample. Received CAS Outfall 0OC All samples are GRAB, unless otherwise noted.

at Lab Method number sampled 5/01/07 Acrolein gel EPA 624 107028

<5.00 ug/I Acrylonitrile gel EPA 624 107131

<5.00 ug/I Benzene gel EPA 624 71432

<1.00 ug/I Bromoform gel EPA.624 75252

<1.00 ug/I Carbon Tetrachloride gel EPA 624 56235

<1.00 ug/I Chlorobenzene gel EPA 624 108907

<1.00 ug/I Chlorodibromomethane (Dibromochloromethane) gel EPA 624 124481

<1.00 ug/I Chloroethane gel EPA 624 75003

<1.00 ug/I Chloroform gel EPA 624 67663

<1.00 ugq/

Dichlorobromomethane(bromodichloromethane) gel EPA 624 75274

<1.00 ug/I Ethylbenzene gel EPA 624 100414

<1.00 ug/I Methyl Bromide(bromomethane) gel EPA.624 74839

<1.00 ug/I.

Methyl Chloride (chloromethane) gel EPA 624 74673

<1.00 ug/I Methylene Chloride gel-EPA 624 75092

<2.00 ug/I Tetrachloroethylene gel EPA 624 127184

<1.00 ug/I Toluene gel

.EPA 624 108883

<1.00 ug/I Trichloroethylene gel

.. EPA 624 79016

<1.00 ug/I Vinyl Chloride gel EPA 624 750174

<1.00 ugh!

Acid Compounds 2,4,6-Trichlorophenol gel EPA 625 88062

<9.62 ughI 2,4-Dichlorophenol gel EPA625 120832

<9.62 ug/I 2,4-Dimethylphenol gel EPA 625 105679

<9.62 ug/I 2,4-Dinitrophenol gel EPA 625 51285

<19.2 ug/I 2-Chlorophenol gel EPA 625 95578

<9.62 ug/I 2-nitrophenol gel EPA 625 88755

<9.62 ug/I 4,6-Dinitro-O-Cresol (2-Methyl-4,6-Dinitrophenol) gel EPA 625 534521

<9.62 ug/I 4-Nitrophenol gel EPA 625 100027

<9.62 ug/I P-Chloro-M-Cresol (4-chloro-3-methylphenol) gel EPA 625 none

<9.62 ug/I Pentachlorophenol gel EPA 625 87865

<9.62 ug/I Phenol gel EPA 625.

108952

<9.62 ug/!

Base/Neutral

Donald C. Cook Nuclear Plant NPDES Permit M10005827 Table 1 required analyses Analysis (Gray highite is repeat from previous table)

Sample'Received CAS Outfall 00C All samples are GRAB, unless otherwise noted, at Lab Method number sampled 5/0 1/0 7 1,2,4-Trichlorobenzene gel EP.A 625 120821'

<9.62 ug/I 1,2-Dichlorobenzene gel EPA 625 95501

<9.62 ug/h 1,2-Diphenylhydrazine (As Azobenzene) gel EPA 625 122667

<9.62 ug/I 1,3-Dichlorobenzene gel EPA 625 541731

<9.62 ug/I 1,4-Dichlorobenzene gel EPA 625 106467

<9.62 ug/I 2,4-Dinitrotoluene gel EPA 625 121142

<9.62 ug/I 2,6-Dinitrotoluene gel EPA 625 606201

<9.62 ug/I 2-Chloronaphthalene gel EPA 625 91587

<0.962 ug/I 3,3'-Dichlorobenzidine gel EPA 625 91941

<9.62 ug/I 3,4-Benzofluoranthene (Benzo(b)fluoranthene,)

gel EPA 625 205992

<0.962 ug/I 4-Bromophenylphenylether gel EPA 625 101553

<9.62 ug/I 4-Chlorophenyl Phenyl Ether gel EPA 625 7005723

<9.62 ug/I Acenaphthene gel EPA 625 83329

<0.962 ug/I Acenaphthylene gel EPA 625 206968

<0.962 ug/I Anthracene gel EPA 625 120127

<0.962 ug/I Benzidine (benzyl alcohol) gel EPA 625 92875

<9.62 ug/I Benzo (a) Anthracene gel.

EPA 625 56553

<0.962 ug/I Benzo (a) Pyrene gel EPA 625 50328

<0.962 ug/I Benzo (ghi) Perylene gel..

EPA 625 191242

<0.962 ug/I Benzo (k) Fluoranthene gel.

EPA 625 207089

<0.962 ug/I Bis (2-Chloroethoxy) Methane gel EPA 625 111911

<9.62 ug/I Bis (2-Chloroethyl) Ether gel EPA 625 111444

<9.62 ug/I Bis (2-Chloroisopropyl) Ether gel--

EPA 625 108601

<9.62 ug/

Bis (2-Ethylhexyl) Phthalate gel EPA 625 117817

<9.62 ug/I Butylbenzyl Phthalate gel EPA 625 85687

<9.62 ug/I Chrysene gel EPA 625 218019

<0.962 ug/I Di-N-Butyl Phthalate gel EPA 625 84742

<9.62 ug/I Di-N-Octyl Phthalate gel EPA 625 117840

<9.62 ug/I Dibenzo (a,h) Anthracene gel EPA 625 53703

<0.962 ug/I Diethyl Phthalate gel EPA 625 64662

<9.62 ug/I Dimethyl Phthalate gel EPA 625 131113

<9.62 ug/I Fluoranthene gel EPA 625 206440

<0.962 ug/I

Donald C. Cook Nuclear Plant NPDES Permit M10005827 Table 1 required analyses Analysis (Gray highlite is repeat from previous table)

Sample Received CAS Outfall OOC All samples are GRAB, unless otherwise noted, at Lab Method number sampled 5/01/07 Fluorene gel. -

EPA 625 86737

<0.962 ug/I Hexachlorobenzene gel EPA 625 118741

<9.62 ug/I Hexachlorobutadiene gel -

EPA 625 87683

<9.62 ug/I Hexachlorocyclopentadiene gel EPA 625 77474

<9.62 ug/I Hexachloroethane gel EPA 625 67721

<9.62 ug/I Incdeno (1,2,3-cd) Pyrene gel EPA 625 193395

<0.962 ug/I Isophorone gel EPA 625 78591

<9.62 ug/f N-Nitrosodi-N-Propylamine gel EPA 625 none

<9.62 ug/I N-Nitrosodimethylamine (N-methyl-N-nitrosomethylamine) gel EPA 625 62759

<9.62 ug/I N-Nitrosodiphenylamine (Diphenylamine) gel EPA 625 86306

<9.62 ug/I Naphthalene gel EPA 625 91203

<0.962 ug/I Nitrobenzene gel EPA 625 98953

<9.62 ug/I Phenanthrene gel EPA 625 85018

<0.962 ug/I Pyrene gel EPA 625 129000

<0.962 ug/I Table 3 -Other Toxic Pollutants (metals and Cyanide) and Total Phenols.

(Table III from 40 CFR 122, Appendix D)

Total Antimony gel EPA 200.8 7440360

<1 ug/I Total Arsenic gel EPA 200.8 7440382

<1.50 ug/I Total Beryllium gel EPA 200.8 7440417

<1 ug/I Total Cadmium gel EPA 200.8 7440439

<0.2 ug/I "Total Chromium gel EPA 200.8 7440473

<10 ug/i

Total Copper gel EPA 200.8 7440508

<1 ugli EPA method Available Cyanide kar OIA-1677 57125 7 ug/I Total Lead gel EPA 200.8 7439921

<1 ug/I EPA method Total Mercury gel 1631 7439976

<0.5 ng/I Total Nickel gel EPA 200.8 7440020

<5 ug/I Total Phenols gel EPA 420.2 none

<5.00 ug/I Total Selenium gel EPA 200.8 7782792

<2.50 ug/I

Donald C. Cook Nuclear Plant NPDES Permit M10905827 Table 1 required analyses Analysis (Gray highlite is repeat from previous table)

Sample Received CAS Outfall 00C All samples are GRAB, unless otherwise noted, at Lab Method number sampled 5/01/07 Total Silver gel EPA 200.8 7440224

<1 ug/h Total Thallium gel EPA 200.8 7440280

<1 ug/h Total Zinc gel EPA 200.8 7440666

<10 ug/I Table 4 Conventional and Non-conventional pollutants to be tested by existing discharges if expected to be present in discharge

• Additional data found (Table IV from 40CFR 122, Appendix D)

In electronic form Aluminum, Total gel EPA 200.8 7429905

<15.0 ug/h Barium, Total gel EPA 200.8 7440393

<2.0 ug/h Boron, Total gel EPA 200.8 7440428

<20 ug/h Bromide gel EPA 300 7726956.0

<0.200 mg/I Cobalt, Total gel EPA 200.8 62207765

<1.00 ug/h Fluoride gel SM 4500-F B 7782414

<0.1 mg/I Iron, Total gel EPA 200.8 none

<25.0 ug/h Magnesium, Total gel EPA 200.8 7439954

<15.0 ug/h Manganese, Total gel EPA 200.8 7439965

<5.00 ug/h Molybdenum, total gel........

EPA"200.8 7439987

<0.5 ug/h Nitrate-Nitrite (as N) gel EPA 353.2 none

<0.05 mg/I EPA Nitrogen, total Organic (as N gel 351.21350.1 n

Rad ioa ctivity gel EPA 900 none Alpha, total gel EPA 900

'none

<5.oo pCi/I Beta, total gel EPA 900 none

<5.00 pci/I Radium, Total.

gel EPA 900 7440144

<1..00 pci/I Radium 226, total gel EPA 900 7440144

<1.00 pCi/I Sulfate as St 4) gel EPA 300.0 none

<0.400 mg/I Sulfide (as.)

gel SM 4500-S F 18496258

<0.100 mg/I SulfiteBas St3) gel SM 4500-SO3 B none

<2.00 mg/I Tin, Total gel EPA 200.8 7440315

<5.0 ug/I

Donald C. Cook Nuclear Plant NPDES Permit.M10005827 Table 1 required analyses Analysis (Gray highlite is repeat from previous table)

Sample Received CAS Outfall 00C All samples are GRAB, unless otherwise noted, at Lab Method number sampled 5/01/07 Titanium, total gel EPA 200.8 7440326

<10 ug/I Table 5 - Toxic pollutants and hazardous Substances required to be identified by Existing Discharges if Expected to Be present in Discharge Additonal data found (Table V from 40 CFR 122, Appendix D) in electronic form Toxic Pollutant Hazardous Substances 1,2 Napthoquinone-4 sulfonic

Michigan Department of Environmental Quality-Water Bureau WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information EASE TYPE OR PRINT

ýCILITY NAME NPDES PERMIT NUMBER OUTFALL NUMBER Donald C. Cook Nuclear Plant M10005827I O0C

9.

WATER TREATMENT ADDITIVES Water treatment additives include any material that is added to water used at the facility or to wastewater generated by the facility to condition or treat the water.

Approvals of water treatment additives are authorized by the MDEQ Under separate correspondence. The issuance of an NPDES permit does not constitute approval of the water treatment additives that are included in this Application.

A. Are there water treatment additives in the discharge from this facility?

[R Yes.

E No. Proceed to Item 10.

B. Have these water treatment additives been previously approved?

[

Yes. Submit a list of the previously-approved water treatment additives and the date on which they were approved. The information listed in Item C., Items 1-8 shall be updated if it has changed since the previous approval.

El No. Continue with Item C.

C. Submit a list of water treatment additives that are or may be discharged from the facility. Applicants are required to submit the information listed below for each additive.

1.

The water treatment additive Material Safety Data Sheet

2.

The proposed water treatment additive discharge concentration.

3.

The discharge frequency (i.e., numbei of hours per day, week, etc.).

4.

The outfall from which the water treatment additive is to be discharged.

5.

The type of removal treatment, if any, that the water treatment additive receives prior to discharge.

6.

The water treatment additive function (i.e., microbiocide, flocculant, etc.).

7.

A 48-hour LC5O or EC50 for a North American freshwater planktonic crustacean (either Ceriodaphnia sp., Daphnia sp., or Simocephalus sp.).

8.

The results of a toxicity test for one other North American freshwater aquatic species (other than a planktonic crustacean) that meets a minimum requirement of Rule 323.1057(2)(a) of the Water Quality Standards. Examples of tests that would meet this requirement include a 96-hour LC50 for rainbow trout, bluegill, or fathead minnow.

The required toxicity information (described in Items 7 and 8 above) is currently available in the Water Bureau files for the water treatment additives listed on the MDEQ's Internet page. To access that information, go to http://www.michigan.gov/deq, click on "Site Map," at the bottom of the right column under Water Quality Monitoring, click on "Assessment of Michigan Waters." Under the Information heading, click on the "Water Treatment Additive List." If you intend to use one of the water treatment additives on this list, only the information in Items 1 through 6 above needs to be submitted to the Water Bureau.

Note: The availability of toxicity information for a water treatment additive does not constitute approval to discharge the water treatment additive.

10.

WHOLE EFFLUENT TOXICITY (WET) TESTS Have any acute or chronic WET tests been conducted on any discharges or receiving water(s) in relation to facility discharges within the last three years? If yes, identify the tests and summarize the results on a separate sheet, unless the test has been submitted to the MDEQ in the last three years. For assistance with WET testing, see Whole Effluent Toxicity Test Guidance and Requirements" in the Appendix.

11.

CONCENTRATED ANIMAL FEEDING OPERATION (CAFO) INFORMATION. To be completed by CAFOs only The applicant shall provide: Specific information about the number and type of animals, and type of housing; the type of containment and storage, and the total capacity for CAFO waste storage; CAFO waste storage structure design; the total number of acres under the control of the applicant that is available for land application of CAFO waste; the estimated amounts of CAFO waste generated per year; the estimated amounts of CAFO waste that is transferred to other persons per year; a list and map(s) showing the location of all land application fields; and all potential receiving waters for both the production and all land application areas. For additional information, see "CAFO Guidance and Requirements" in the Appendix.

"This completesSection III. Return the completed Application (Sections I, Ill, and IV and any attachments) to one of the addresses Page ii of this Application. If assistance is needed to complete this Application, contact the Permits Section.

7 EQP 4659-C (Rev. 11/2007)

Michigan Department of Environmental Quality-Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information PLEASE TYPE OR PRINT FACILITY NAME NPDES or COC PERMIT NUMBER Outfall Number Donald C. Cook Nuclear Plant M10005827 00C

9. WATER TREATMENT ADDITIVES Previously permitted Maximum discharge Water Treatment Additive Approval Date concentrations. As applied for under Part 1.6 of the current NIPDES permit, "Request for Discharge of Water Treatment Additives." (Based on 2 circ water pumps in operation during discharge event)

Carbohydrazide solutions such as: Betz 3/24/94 NPDES application, 4/15/94 0.029 mg/1 Cortrol OS5613, Nalco 1250 plus approval, NPDES Permit approval 9/28/95 Ethanolamine 5/23/00, NPDES approval 9/28/95 0.0 1 rug/i Betz Steamate 1480N, Nalco 92UM001 Hydrazine:

5/23/00, NPDES approval 9/28/95 0.1 mg/i Betz Cortrol OS5035, OS 5010, Nalco 19H

Michigan Department of Environmental Quality-Water Bureau WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information "omplete a separate Section III.B. - Outfall Information (Pages 20-25) - for each outfall at the facility. Make copies of this ink section of the Application as necessary for additional outfalls.

PLEASE TYPE OR PRINT FACILITY NAME iNPDES PERMIT NUMBER I OUTFALL NUMBER Donald C. Cook Nuclear Plant'I MI0005827I OOG

1.

OUTFALL INFORMATION - Instructions for this item are on Page 3 of the Appendix.

El No Change From Last Application, Items A. - D.

Receiving Water Hydrologic Unit Code (HUC)

Lake Michigan 04040001 County Township Berrien Lake Town Range Section 1/ 4 W/4, 1/4 Private (French) Land Claim) 06S 19W 06 NW S

Latitude Longitude na - internal outfall na - internal outfall Type of Wastewater Discharged (check all that apply to this outfall):

El No Change From Last Application, Item E.

El Contact Cooling El Groundwater Cleanup El Hydrostatic Pressure Test E) Noncontact Cooling Water

[

Process Wastewater El Sanitary Wastewater E] Storm Water - not regulated El Storm Water - regulated El Storm water subject to effluent guidelines.(indicate under which category):

El Other - specify (see '"able 8 -Other Common Types of Wastewater" - in the Appendix)

What is the Maximum Design Flow Rate for this outfall: 0.366 MGD El No Change From Last Application, Items F. - G.

What is the Maximum Authorized Discharge Seasonal Dischargers MGY (Continue with Item H).

Flow for this outfall for the next five years?

Continuous Dischargers 0.366 MGD (Continue with Item I).

Seasonal Discharge:

List the discharge periods (by month) and the volume discharged in the space provided below.

From Through Actual Discharge Volume (MGD)

Annual Total From Through Actual Discharge Volume (MGD)

From Through Actual Discharge Volume (MGD)

From Through Actual Discharge Volume (MGD)

Continuous Discharge:

How often is there a discharge from this outfall (on average)?

24 Hours/Day 365 Days/Year Batch dischargers are required to provide the following additional information:

Is there effluent flow equalization?

El Yes El No Batch Peak Flow Rate:

Number of batches discharged per day: __

Minimum Average Maximum Batch Volume (gallons)

Batch Duration (minutes)

I 2

EQP 4659-C (Rev. 11/2007)

Michigan Department of Environmental Quality-Water Bureau WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information

" EASE TYPE OR PRINT

• ILITY NAME NPDES PERMIT NUMBER OUTFALL NUMBER Donald C. Cook Nuclear PlantI M10005827 OG

2.

PROCESS STREAMS CONTRIBUTING TO OUTFALL DISCHARGE 0l No Change From Last Application Federal regulations require that different industries report different information, depending on the type of facility. The information below is used to determine the applicable federal regulations for this facility. An abbreviated list is in the Summary of Information to be reported by Industry Type section of the Appendix. Applicants are required to provide the name and the SIC or the NAICS code for each process at the facility. Facilities with production-based limits must report an estimated annual production rate for the next five years, or the life of the permit. If the wastestream is not regulated under federal categorical standards, the applicant is required to report all pollutants which have the reasonable potential to be present in the discharge. To submit additional information, see Page ii, Item 3.

PROCESS INFORMATION A.

Name of the process contributing to the discharge: Reverse osmosis system reiect water.

B.

SIC or NAICS code: SIC -4911, NAICS 221113 C.

Describe the process and provide measures of production:

Reverse osmosis system reject flow 0.366 MGD maximum flow, 2247 MWE total plant electrical generation.

PROCESS INFORMATION A.

Name of the process contributing to the discharge:__

B.

SIC or NAICS code:

C.

Describe the process and provide measures of production:

PROCESS INFORMATION A.

Name of the process contributing to the discharge: __

B.

SIC or NAICS code:

C.

Describe the process and provide measures of production:

PROCESS INFORMATION A.

Name of the process contributing to the discharge:

B.

SIC or NAICS code:

C.

Describe the process and provide measures of production:

PROCESS INFORMATION A.

Name of the process contributing to the discharge:

B.

SIC or NAICS code:

C.

Describe the process and provide measures of production:

PROCESS INFORMATION A.

Name of the process contributing to the discharge: __

B.

SIC or NAICS code:

C.

Describe the process and provide measures of production:

3 EQP 4659-C (Rev. 11/2007)

Michigan Department of Enviro ital Quality-Water Bureau WASTEWATER DISCHARGf-PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information PLEASE TYPE OR PRINT FACILITY NAME NPDES PERMIT NUMBER I OUTFALL NUMBER Donald C. Cook Nuclear PlantI M10005827 I OOG

3.

EFFLUENT CHARACTERISTICS - CONVENTIONAL POLLUTANTS - Instructions for this item are on Page 4 of the Appendix.

0 Check this box if additional information is included as an attachment. To submit additional information, see Page ii, Item 3.

Please Note: Rule 323.1062 allows the use of either Escherichia.Coli or Fecal Coliform Bacteria as an indicator that effluent has been disinfected. The MDEQ will use the indicator selected below in the permit El Biochemical Oxygen Demand - five day (BOD5) 3.44 3.44 mg/I I

El Grab 0 24 Hr Comp El Chemical Oxygen Demand (COD) 29.5 29.5 mg/I 1

El Grab

[] 24 Hr Comp El Grab

[]

Total Organic Carbon (TOC) 4.43 4.43 mg/I 1

E 2rCo

[] 24 Hr Comp El Ammonia Nitrogen (as N)

<0.03

<0.03 mg/I 1

0l Grab

[] 24 Hr Comp 0

Total Suspended Solids mg/I 0

Grab El 24 Hr Comp 0] Grab El Total Dissolved Solids 519 519 mg/I 1

E 2ra m

[

24 Hr Comp 171 Grab El Total Phosphorus (as P)

<0.05

<0.05 mg/I 1

0 2rab

]

24 Hr Comp El Not expected to be present Fecal Coliform Bacteria (report geometric means)

Maximum-7day counts/iOml Grab El Not expected to be present Escherichia Coil (report geometric means)

Maximum-7day counts/100 ml Grab E]

Total Residual Chlorine 90 100 El mg/I 2

Grab Minimum daily 0] Grab El Dissolved Oxygen 7.6 mg/I 1

2 r Co 7.8 El 24 Hr Comp Minimum Maximum 0] Grab E]

pH (report maximum and minimum of individual samples) 5M5 7.0 standard units 21 El 24 Hr Comp El na-internal outfall Temperature, Summer EOF E oc El Grab El 24 Hr Comp El na - internal outfall Temperature, Winter E]El Grab El 24 Hr Comp El Oil & Grease

<4.0

<4.0 mg/I 1

Grab 4

EQP 4659-C (Rev. 11/2007)

Michigan Department of Environmental Quality-Water Bureau WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B.

Outfall Information ASE TYPE OR PRINT FACILITY NAME NPDES PERMIT NUMBER OUTFALL NUMBER Donald C. Cook Nuclear Plant MI0005827 QOG Submitted SAMPLE DATE 4 3/5/08 CA co c?

1ý hal"'ticai vaDMR's CoSml El Arsenic 7440382 2.6 C

Selenium 7782792

<0.5 E3 Silver 7440224 0.18 El Additional data attached.

El See attached electronic data.

F1 El El El El El El El El El El r-1 F1 El El El El El El

.E1 El El El EQP 4659-Cf(Revs. 11/2007)

.6

Donald C. Cook Nuclear Plant NPDES Permit M10005827 Table 1 required analyses Analysis (Gray highfite is repeat from previous table)

Sample Received CAS Outfall 00G All samples are GRAB, unless otherwise noted.

at Lab Method number sampled 4/30/07

• Additional data found Required In electronic form Biochemical Oxygen Demand (Five day BOD5) (24 hr Comp) gel SM 5210B None 3.44 mg/I Chemical oxygen Demand (COD) (24 hr Comp) gel EPA 410.4 None 29.5 mg/I Total organic carbon (TOC) (24 hr Comp) gel SM 5310B None 4.43 mg/I Ammonia Nitrogen (as N) (24 hr Comp) gel EPA 350.1 7664417

.<0.03 mg/I Total Suspended Solids (24 hr Comp) gel SM 2540D None EDMR Temperature Summer (Max July 07)

Cook SM 2550B None no-Internal outfall Temperature Winter (Max Jan 07)

Cook SM 2550B None no-internal outfall pH Cook SM 4500-H+B None From plant data*

• Additional data found Report available data in electronic form Total Dissolved Solids gel SM.2540C None 519 ug/I Total Phosphorus (24 hr Comp) gel EPA 365.4 7723140

<0.05 mg/I Total Residual Chlorine COOK EPA 330.5 electrode 7782505 100 ug/h Dissolved oxygen COOK SM 4500-0 c None 7.8 mg/I Oil and Grease gel EPA1664a None

<4.0 Table 2-Organic Toxic Pollutants (Table II from 40 CFR 122, Appendix D)

Volatiles 1,1,1-Trichloroethane gel EPA 624 71556

<1.00 ug/-

1,1,2,2-Tetrachloroethane gel EPA 624 79345

<1.00 ug/I 1,1,2-Trichloroethane gel EPA 624 79005

<1.00 ug/l 1,1-Dichloroethane gel EPA 624 75343

<1.00 ug/h 1,1-Dichloroethylene gel EPA 624 75354

<1.00 ug/Il 1,2-Dichloroethane gel EPA 624 107062

<1.00 ug/!

1,2-Dichloropropane gel EPA 624 78875

<1.00 ughi 1,2-Trans-Dichloroethylene gel EPA 624 156605

<1.00 ug/l 1,3-Dichloropropylene (Listed in GEL as cis 1,3 Dichloropropylene and Trans 1,3 Dichloropropylene) gel EPA 624 542756

<1.00 ug/l 2-Chloroethylvinylether gel EPA624 110758

<5.00 ug/l

Donald C. Cook Nuclear Plant NPDES Perm it;M 10005827 Table 1 required analyses Analysis (Gray highite is repeat from previous table)

Sample Received CAS Outfall OOG All samples are GRAB, unless otherwise noted, at Lab Method number sampled 4130/07 Acrolein gel EPA 624 107028

<5.00 ug/I Acrylonitrile gel EPA 624 107131

<5.00 ug/i Benzene gel EPA 624 71432

<1.00 ug/i Bromoform gel EPA 624 75252

<1.00 ugI1 Carbon Tetrachloride gel EPA 624 56235

<1.00 ug/I Chlorobenzene gel EPA624 108907

<1.00 ug/I Chlorodibromomethane (Dibromochloromethane) gel EPA 624 124481

<1.00 ug/I Chloroethane gel EPA 624 75003

<1.00 ug/I Chloroform gel EPA 624 67663 7.67 ug/I Dichlorobromomethane(bromodichloromethane) gel EPA 624 75274 3.0 ugth Ethylbenzene gel EPA 624 100414

<1.00 ug/I Methyl Bromide(bromomethane) gel EPA'624 74839

<1.00 ughI Methyl Chloride (chloromethane) gel EPA 624 74873

<1.00 ug/I Methylene Chloride gel EPA 624 75092

<2.00 ug/I Tetrachloroethylene gel EPA 624 127184

<1.00 ug/I Toluene gel EPA 624 108883

<1.00 ug/I Trichloroethylene gel EPA 624 79016

<1.00 ug/I Vinyl Chloride gel EPA 624 750174

<1.00 ug/I Acid Compounds 2,4,6-Trichlorophenol gel EPA 625 88062

<9.52 ug/I 2,4-Dichlorophenol gel EPA 625 120832

<9.52 ug/I 2,4-Dimethylphenol gel EPA 625 105679

<9.52 ug/I 2,4-Dinitrophenol gel EPA 625 51285

<19.0 ug/I 2-Chlorophenol gel EPA 625 95576

<9.52 ug/I 2-nitrophenol gel EPA 625 88755

<9.52 ug/I 4,6-Dinitro-O-Cresol (2-Methyl-4,6-Dinitrophenol) gel EPA 625 534521

<9.52 ug/I 4-Nitrophenol gel EPA 625 100027

<9.52 ug/I P-Chloro-M-Cresol (4-ch oro-3-methylphenol) gel EPA 625 none

<9.52 ug/I Pentachlorophenol gel EPA 625 87865

<9.52 ugll Phenol

-gel EPA 625 108952

<9.52 ug/I

,Base/Neutral

Donald C. Cook Nuclear Plant NPDES Permit M10005827 Table 1 required analyses Analysis (Gray highlite is repeat from previous table)

Sample Received CAS Outfall OOG All samples are GRAB, unless otherwise noted, at Lab Method number sampled 4/30/07 1,2,4-Trichlorobenzene gel EPA 625 120821

<9,52 ug/I 1,2-Dichlorobenzene gel EPA 625 95501

<9.52 ug/I 1,2-Diphenylhydrazine (As Azobenzene) gel EPA 625.

122667

<9.52 ug/I 1, 3-Dichlorobenzene gel EPA 625 541731

<9.52 ug/I 1,4-Dichlorobenzene gel EPA 625 106467

<9.52 ug/I 2,4-Dinitrotoluene gel EPA 625 121142

<9.52 ug/I 2,6-Dinitrotoluene gel EPA 625 606201

<9.52 ug/I 2-Chloronaphthalene gel EPA 625 91587

<0.952 ug/I 3,3'-Dichlorobenzidine gel EPA 625 91941

<9.52 ug/I 3,4-Benzofluoranthene (Benzo(b)fluoranthene,)

gel EPA 625 205992

<0.952 ug/

4-Bromophenylphenylether gel EPA 625 101553

<9.52 ug/I 4-Chlorophenyl Phenyl Ether.

gel EPA 625 7005723

<9.52 ug/I Acenaphthene gel EPA 625 83329

<0.952 ug/I Acenaphthylene gel EPA 625 208968

<0.952 ug/I Anthracene gel EPA 625 120127

<0.952 ug/I Benzidine (benzyl alcohol) gel EPA 625 92875

<9.52 ug/I Benzo (a) Anthracene gel.

EPA 625 56553

<0.952 ug/I Benzo (a) Pyrene gel EPA 625 50328

<0.952 ugl/

Benzo (ghi) Perylene gel EPA 625 191242

<0.952 ug/I Benzo (k) Fluoranthene gel EPA 625 207089

<0.952 ug/I Bis (2-Chloroethoxy) Methane gel EPA 625 111911

<9.52 ug/I Bis (2-Chloroethyl) Ether gel EPA 625 111444

<9.52 ug/I Bis (2-Chloroisopropyl) Ether gel EPA 625 108601

<9.52 ug/I Bis (2-Ethylhexyl) Phthalate gel EPA 625 117817

<9.52 ug/I Butylbenzyl Phthalate gel EPA 625 85687

<9.52 ug/I Chrysene gel EPA 625 218019

<0.952 u9/g Di-N-Butyl Phthalate gel EPA 625 84742

<9.52 ug/I Di-N-Octyl Phthalate gel EPA 625 117840

<9.52 ug/I Dibenzo (a,h) Anthracene gel-EPA 625 53703

<0.952 ug/I Diethyl Phthalate gel EPA 625 84662

<9.52 ug/I Dimethyl Phthalate gel EPA;625 131113

<9.52 ug9/

Fluoranthene gel EPA 625 206440

<0.952 ug/I

Donald C. Cook Nuclear Plant NPDES Permit MIOO.5827 Table 1 required analyses Analysis (Gray hightite is repeat from previous table)

Sample Received CAS Outfall OOG All samples are GRAB, unless otherwise noted.

at Lab

- Method number sampled 4/30/07 Fluorene gel EPA 625

.86737

<0.952 ug/I Hexachlorobenzene gel

. EPA 625 118741

<9.52 ug/I Hexachlorobutadiene gel

. EPA 625 87683

<9.52 ug/I Hexachlorocyclopentadiene gel EPA 625 77474

<9.52 ug/I Hexachloroethane gel EPA 625 67721

<9.52 ug/I Indeno (1,2,3-cd) Pyrene gel EPA 625 193395

<0.952 ug/I Isophorone gel EPA 625 78591

<9.52 ug/I N-Nitrosodi-N-Propylamine gel EPA 625 none

<9.52 ug/I N-Nitrosodimethylamine (N-methyl-N-nitrosomethylamine) gel EPA 625 62759.

<9.52 ug/I N-Nitrosodiphenylamine (Diphenylamine) gel EPA 625 86306

<9.52 ug/I Naphthalene gel EPA 625 91203

<0.952 ug/I Nitrobenzene gel EPA 625 98953

<9.52 ug/I Phenanthrene gel EPA 625 85018

<0.952 ug/I Pyrene gel EPA 625 129000

<0.952 ug/I Table 3 -Other Toxic Pollutants (metals and Cyanide) and Total Phenols.

(Table III from 40 CFR 122, Appendix D)

Total Antimony gel EPA 200.8 7440360

<1 ug/I Total Arsenic gel EPA 200.8 7440382

<1.50 ug/I Total Beryllium gel EPA 200.8 7440417

<1 ug/I Total Cadmium gel EPA 200.8 7440439

<0.2 ug/I Total Chromium gel EPA 200.8 7440473

<10 ug/I Total Copper gel EPA 200.8 7440506 1.34 ug/I EPA method Available Cyanide kar OIA-1677 57125

<2 ug/I Total Lead gel EPA 200.8 7439921

<1 uglh EPA method Total Mercury gel 1631 7439976 1.47 ng/I Total Nickel gel EPA 200.8 7440020

<5 ug/I Total Phenols g9l EPA 420.2 none

<5.00 ug/I Total Selenium gel '

EPA200.8 7782792

<2.50 ug/l

Donald C. Cook Nuclear Plant NPDES Permit MI0005827 Table I required analyses Analysis (Gray hightite is repeat from previous table)

Sample Received CAS Outfall OOG All samples are GRAB, unless otherwise noted, at Lab Method number sampled 4/30/07 Total Silver gel EPA 200M8 7440224

<5,00 ug9/

Total Thallium gel EPA 200.8 7440280

<1 ug/I Total Zinc gel EPA 200.8 7440666

<10 ug/I Table 4 Conventional and Non-conventional pollutants to be tested by existing discharges if expected to be present in discharge

• Additional data found (Table IV from 40CFR 122, Appendix D) in electronic form Aluminum, Total gel EPA 200.6 7429905 78.4 ug/h Barium, Total gel EPA 200.8 7440393 49.1 ug/!

Boron, Total gel EPA 200.8 7440428 50.4 mg/I Bromide gel EPA 300 7726956.0

<0,200 mg/I Cobalt, Total gel EPA 200.8 62207765

<1.00 ug/I Fluoride gel SM 4500-F B 7782414 0.199 mg/I Iron, Total gel EPA 200.6 none 487 ughI Magnesium, Total gel EPA 200,8 7439954 28300 ug/h Manganese, Total gel EPA 200.8 7439965

<5.00 ugh, Molybdenum, total gel EPA 200.8 7439987 3.13 mg/I Nitrate-Nitrite (as N) gel EPA 353.2 none 1.12 mg/I EPA Nitrogen, total Organic (as N) gel 351.2/350.1 none 548 ug/I Radioactivity gel EPA 900 none Alpha, total gel EPA 900 none

<5.00 pci/I Beta, total gel EPA 900 none

<5.00 pci/I Radium, Total gel EPA 900 7440144

<1.00 pci/I Radium 226, total gel EPA 900 7440144

<1.00 pci/I Sulfate (as S04) gel EPA 300.0 none 260 mg/I Sulfide (as S) gel SM 4500-S F 18496258

<0.100 mg/i Sulfite (as S03) gel SM 4500-SO3 B none

<2.00 mg/I Tin, Total gel EPA 200.8 7440315

<5.0 ug/I

Donald C. Cook Nuclear Plant NPDES Permit M10005827 Table 1 required analyses Analysis (Gray highlite is repeat from previous table)

Sample Received CAS Outfall OOG All samples are GRAB, unless otherwise noted.

at Lab Method number sampled 4/30/07 Titanium, total gel EPA 200.8 7440326

<10 ug/I Table 5 - Toxic pollutants and hazardous Substances required to be identified by Existing Discharges if Expected to Be present in Discharge data found (Table V from 40 CFR 122, Appendix D)

In electronic form Toxic Pollutant Hazardous Substances 1,;- Napthoquinone-4 sulfonic Acid method Si ~ i !iiiiii!

iiii~iii~ii ii~~iii~i~

ii! iiii i~iiii~iiiiii i ~ii~i!!!ii!iiiiii i

iiii ii iiiiiii~iii~iiiiii~iiiiiiii!i!!ii!

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!iiii ii i !i ! !!iiii! iii i ! iiiii~

iiiiii~iii i !! ii ii!! ! !iiiiiiiiiii~~i!

~iii iiiiiii~

ii ! !ii~

iiiii!!i

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~iiiiiiiiiiii iiiiiiii iiiiii~iiX,~

Michigan Department of Environmental Quality-Water Bureau WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information

-' EASETYPE OR PRINT

,CILITY NAME I NPDES PERMIT NUMBER OUTFALL NUMBER Donald C. Cook Nuclear PlantI M10005827 OQG

9.

WATER TREATMENT ADDITIVES Water treatment additives include any material that is added to water used at the facility or to wastewater generated by the facility to condition or treat the water.

Approvals of water treatment additives are authorized by the MDEQ under separate correspondence. The issuance of an NPDES permit does not constitute approval of the water treatment additives that are included in this Application.

A. Are there water treatment additives in the discharge from this facility?

0 Yes.

C No. Proceed to Item 10.

B. Have these water treatment additives been previously approved?

0 Yes. Submit a list of the previously-approved water treatment additives and the date on which they were approved. The information listed in Item C., Items 1-8 shall be updated if it has changed since the previous approval.

C No. Continue with Item C.

C. Submit a list of water treatment additives that are or may be discharged from the facility. Applicants are required to submit tle information listed below for each additive.

1.

The water treatment additive Material Safety Data Sheet

2.

The proposed water treatment additive discharge concentration.

3.

The discharge frequency (i.e., number of hours per day, week, etc.).

4.

The outfall from which the water treatment additive is to be discharged.

5.

The type of removal treatment, if any, that the water treatment additive receives prior todischarge.

6.

The water treatment additive function (i.e., microbiocide, flocculant, etc.).

7.

A 48-hour LC50 or EC50 for a North American freshwater planktonic crustacean (either Ceriodaphnia sp., Daphnia sp., or Simocephalus sp.).

8.

The results of a toxicity test for one other North American freshwater aquatic species (other than a planktonic crustacean) that meets a minimum requirement of Rule 323.1057(2)(a) of the Water Quality Standards. Examples of tests that would meet this requirement include a 96-hour LC50 for rainbow trout, bluegill, or fathead minnow.

The required toxicity information (described in Items 7 and 8 above) is currently available in the Water Bureau files for the water treatment additives listed on the MDEQ's Internet page. To access that information, go to http://www.michigan.gov/deq, click on "Site Map," at the bottom of the right column under Water Quality Monitoring, click on "Assessment of Michigan Waters." Under the Information heading, click on the 'Water Treatment Additive List." If you intend to use one of the water treatment additives on this list, only the information in Items 1 through 6 above needs to be submitted to the Water Bureau.

Note: The availability of toxicity information for a water treatment additive does not constitute approval to discharge the water treatment additive.

10.

WHOLE EFFLUENT TOXICITY (WET) TESTS Have any acute or chronic WET tests been conducted on any discharges or receiving water(s) in relation to facility discharges within the last three years? If yes, identify the tests and summarize the results on a separate sheet, unless the test has been submitted to the MDEQ in the last three years. For assistance with WET testing, see 'Whole Effluent Toxicity Test Guidance and Requirements" in the Appendix.

11.

CONCENTRATED ANIMAL FEEDING OPERATION (CAFO) INFORMATION. To be completed by CAFOs only The applicant shall provide: Specific information about the number and type of animals, and type of housing; the type of containment and storage, and the total capacity for CAFO waste storage; CAFO waste storage structure design; the total number of acres under the control of the applicant that is available for land application of CAFO waste; the estimated amounts of CAFO waste generated per year; the estimated amounts of CAFO waste that is transferred to other persons per year; a list and map(s) showing the location of all land application fields; and all potential receiving waters for both the production and all land application areas. For additional information, see "CAFO Guidance and Requirements" in the Appendix.

This completesSection III. Return the completed Application (Sections I, III, and IV and any attachments) to one of the addresses Page ii of this Application. If assistance is needed to complete this Application, contact the Permits Section.

7 EQP 4659-C (Rev. 11/2007)

Michigan Department of Environmental Quality-Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information PLEASE TYPE OR PRINT FACILITY NAME NPDES or COC PERMIT NUMBER Outfall Number Donald C.'Cook Nuclear Plant MI0005827 OOG

9. WATER TREATMENT ADDITIVES Water Treatment Additive Approval Date Hydrochloric Acid (pH control) 11/14/96 Change of process application, 11/25/96 approval.

NPDES Permit application approval 9/28/00, 5/23/00.

Sulfuric Acid (pH control) 11/14/96 Change of process application, 11/25/96 approval.

NPDES Permit application approval 9/28/00, 5/23/00.

Sodium Hydroxide 11/14/96 Change of process application, 11/25/96 approval.

NPDES Permit application approval 9/28/00, 5/23/00.

Sodium Bisulfite 11/14/96 Change of process application, 11/25/96 approval.

NPDES Permit application approval 9/28/00, 5/23/00.

Citric Acid 11/14/96 Change of process application, 11/25/96 approval.

NPDES Permit application approval 9/28/00, 5/23/00.

Phosphoric Acid 11/14/96 Change of process application, 11/25/96 approval.

NPDES Permit application approval 9/28/00, 5/23/00.

Tide Detergent or equivalent 11/14/96 Change of process application, 11/25/96 approval.

INPDES Permit application approval 9/28/00, 5/23/00.

Michigan Department of Environmental Quality-Water Bureau WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information

'ýomplete a separate Section III.B. - Outfall Information (Pages 20-25) - for each outfall at the facility. Make copies of this ink section of the Application as necessary for additional outfalls.

PLEASE TYPE OR PRINT FACILITY NAME NPDES PERMIT NUMBER OUTFALL NUMBER Donald C. Cook Nuclear Plant M10005827I 00H 1.

OUTFALL INFORMATION - Instructions for this item are on Page 3 of the Appendix.

El No Change From Last Application, Items A. - D.

A.,

B.

C.

D.

Receiving Water Hydrologic Unit Code (HUC)

Lake Michigan 04040001 County Township Berrien Lake Town Range Section 1/4 1/4, Y/4 Private (French) Land Claim) 06S 19W 06 NW SW Latitude Longitude na - internal outfall na - internal outfall E.

Type of Wastewater Discharged (check all that apply to this outfall):

El No Change From Last Application, Item E.

El Contact Cooling E] Groundwater Cleanup El Hydrostatic Pressure Test

[

Noncontact Cooling Water

] Process Wastewater El Sanitary Wastewater El Storm Water - not regulated El Storm Water - regulated El Storm water subject to effluent guidelines (indicate under which category):

El Other - specify (see "Table 8 - Other Common Types of Wastewater" - in the Appendix) __

F.

What is the Maximum Design Flow Rate for this outfall:

2.(

G What is the Maximum Authorized Discharge Flow for this outfall for the next five years?

El No Change From Last Application, Items F. - G.

Seasonal Dischargers MGY (Continue with Item H).

Continuous Dischargers 2.6 MGD (Continue with Item I).

HF. Seasonal Discharge:

List the discharge periods (by month) and the volume discharged in the space provided below.

1.

From Through Actual Discharge Volume (MGD)

Annual Total From Through Actual Discharge Volume (MGD)

From Through Actual Discharge Volume (MGD)

From Through Actual Discharge Volume (MGD)

Continuous Discharge:

How often is there a discharge from this outfall (on average)?

24 Hours/Day 365 Days/Year Batch dischargers are required to provide the following additional information:

Is there effluent flow equalization?

El Yes El No Batch Peak Flow Rate:

Number of batches discharged per day: __

Minimum Average Maximum Batch Volume (gallons)

Batch Duration (minutes) 2 EQP 4659-C (Rev. 11/2007)

Michigan Department of Environmental Quality-Water Bureau WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information PLEASE TYPE OR PRINT CILITY NAME NPDES PERMIT NUMBER OUTFALL NUMBER

,onald C. Cook Nuclear Plant M10005827 OOH

2.

PROCESS STREAMS CONTRIBUTING TO OUTFALL DISCHARGE El No Change From Last Application Federal regulations require that different industries report different information, depending on. the type of facility. The information below is used to determine the applicable federal regulations for this facility. An abbreviated list is in the Summary of Information to be reported by Industry Type section of the Appendix. Applicants are required to provide the name and the SIC or the NAICS code for each process at the facility. Facilities with production-based limits must report an estimated annual production rate for the next five years, or the life of the permit. If the wastestream is not regulated under federal categorical standards, the applicant is required to report all pollutants which have the reasonable potential to be present in the discharge. To submit additional information, see Page ii, Item 3.

PROCESS INFORMATION A.

Name of the process contributing to the discharge: Steam Electric B.

SICorNAICS code: SIC-4911. NAICS 221113 C.

Describe the process and provide measures of production:

Misc plant services, see Waste stream diagram and description in section I. 2.6 MGD maximum flow, 2247 MWE total plant electrical generation.

PROCESS INFORMATION A.

Name of the process contributing to the discharge:

B.

SIC or NAICS code:

C.

Describe the process and provide measures of production:

PROCESS INFORMATION A.

Name of the process contributing to the discharge: __

B.

SIC or NAICS code:

C.

Describe the process and provide measures of production:

PROCESS INFORMATION A.

Name of the process contributing to the discharge:

B.

SIC or NAICS code:

C.

Describe the process and provide measures of production:

PROCESS INFORMATION A.

Name of the process contributing to the discharge:

B.

SICor NAICS code:

C.

Describe the process and provide measures of production:

PROCESS INFORMATION A.

Name of the process contributing to the discharge: __

B, SIC or NAICS code:

C.

Describe the process and provide measures of production:

3 I EQP 4659-C (Rev. 11/2007)

Michigan Department of Enviroi ital Quality-Water Bureau WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information PLEASE TYPE OR PRINT FACILITY NAME I NPDES PERMIT NUMBER OUTFALL NUMBER Donald C. Cook Nuclear Plant I M10005827 I OOH

3.

EFFLUENT CHARACTERISTICS - CONVENTIONAL POLLUTANTS - Instructions for this item are on Page 4 of the Appendix.

Z Check this box if additional information is included as an attachment. To submit additional information, see Page ii, Item 3.

Please Note: Rule 323.1062 allows the use of either Escherichia Coil or Fecal Coliform Bacteria as an indicator that effluent hasbeen disinfected. The MDEQ will use the indicator selected below in the permit is.ijPd bal.P-d on thiq Annlinntinn

-1 I J.1 F.*zhp.rirhii Coil nn indicatnr of diqinfPrctinn Fi-I IN FPprl Coliform R rteria a; ;in indicator of disinfection.

I I Biochemical Oxygen Demand - five day (BOD5) 2.62 2.62 mg/I 1

El Grab 0 24 Hr Comp El Grab Chemical. Oxygen Demand (COD)

<20.0

<20.0 mg/I 1

0 24 Hr Comp Total Organic Carbon (TOC) 3.13 3.13 mg/I 1

C-2 Grab N[ 24 Hr Comp El Grab Ammonia Nitrogen (as N) 4.25 4.25 mg/I 1

Z 24 Hr Comp El Grab Total Suspended Solids

<2.5

<2.5 mg/I 1

0 2rCo S] 24 Hr Comp 0] Grab Total Dissolved Solids 147 147 mg/I 1

E 2rCo

[] 24 Hr Comp El Grab Total Phosphorus (as P)

<0.05

<0.05 mg/I 1

24 HrCo Nr 24 Hr Comp Not expected to be present Fecal Coliform Bacteria (report geometric means)

Maximum-7day counts/100ml Grab Not expected to be present Escherichia Coli (report geometric means)

Maiu-dy counts/!00 ml Grab E] mg/I Total Residual Chlorine

<60

<80 1

Grab

[] ltg/I Minimum daily 0] Grab Dissolved Oxygen 7e mg/i 1

E 2r Co 7.4 E] 24 Hr Comp Minimum Maximum 0] Grab pH (report maximum and minimum of individual samples) 7.0 "x8.9 standard units 116 Il 24 Hr Comp na-internal outfall Temperature, Summer

[E °F

[E

°C El Grab El 24 Hr Comp na - internal outfall Temperature, Winter El -F 17 EC El Grab El 24 Hr Comp Oil & Grease

<4.0

<4.0 mg/i 1

Grab 4

EQP 4659-C (Rev, 11/2007)

Michigan Department of.Environmental Quality-Water Bureau WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information PLEASE TYPE OR PRINT ZILITY NAME NPDES PERMIT NUMBER OUTFALL NUMBER Uonald C. Cook Nuclear PlantI M10005827 OOH Note: For questions on this page, Tables 1-5 are found in the Appendix.

4.

PRIMARY INDUSTRY PRIORITY POLLUTANT INFORMATION Existing primary industries that discharge process. wastewater are required to submit the results of at least one permittee-collected effluent analysis for selected, organic pollutants identified in Table 2 (as determined from Table 1, Testing Requirements for Organic Toxic Pollutants by Industrial Category), and all of the pollutants identified in Table 3. Existing primary industries are required to also provide the results of at least one permittee-collected effluent analysis for any other chemical listed in Table 2 known or believed to be present in the facility's. effluent.

In addition, submit the results of all other effluent analyses performed within the last three years for any chemical listed in Tables 2 and 3.

New primary industries that propose to discharge process wastewater are required to provide an estimated effluent concentration for any chemical listed in Tables 2 and 3 expected to be present in the facility's effluent.

5.

'DIOXIN AND FURAN CONGENER INFORMATION Existing industries that use or manufacture 2,3,5-trichlorophenoxy acetic acid (2,4,5-T); 2-(2,3,5-trichlorophenoxy) propanoic acid, (Silvex, 2,3,5-TP); 2-(2,4,5-trichlorophenoxy) ethyl 2,2-dichloropropionate (Erbon); 0,0-dimethyl 0-(2,4,5-trichlorophenyl) phosphorothionate (Ronnel);

2,4,5-trichlorophenol (TCP); or hexachlorophrene (HCP), or knows or has reason to believe that 2,3,7,8-Tetrachlorodibenzo-p-dioxin (TCDD) is present in the facility's effluent, are required to submit the results of at least one effluent analysis for the dioxin and furan congeners listed in Table

6. All effluent analyses for dioxin and furan congeners shall be conducted using USEPA Method 1613.

In addition, submit the results of all other effluent analyses performed within the last three years for any dioxin and furan congener listed in Table 6.

New industries that expect to use or manufacture 2,3,5-trichlorophenoxy acetic acid (2,4,5-T); 2-(2,3,5-trichlorophenoxy) propanoic acid (Silvex, 2,3,5-TP); 2-(2,4,5-trichlorophenoxy) ethyl 2,2-dichloropropionate (Erbon); 0,0-dimethyl 0-(2,4,5-trichlorophenyl) phosphorothionate (Ronnel);

2,4,5-trichlorophenol (TCP); or hexachlorophrene (HCP), or knows or has reason to believe that 2,3,7,8-Tetrachlorodibenzo-p-dioxin (TCDD) is present in the facility's effluent, shall provide estimated effluent concentrations for the dioxin and furan congeners listed in Table 6.

OTHER INDUSTRY PRIORITY POLLUTANT INFORMATION Existing secondary industries, or existing primary industries that discharge nonprocess wastewater, are required to submit the results of at least one effluent analysis for any chemical listed in Tables 2 and 3 known or believed to be present in the facility's effluent.

In addition, submit the results of all other effluent analyses performed within the last three years for any chemical listed in Tables 2 and 3.

New secondary industries, or new primary industries that propose to discharge nonprocess wastewater, are required to provide an estimated effluent concentration for any chemical listed in Tables 2 and 3 expected to be present in the facility's effluent.

7.

ADDITIONAL TOXIC AND OTHER POLLUTANT INFORMATION All existing industries, regardless of discharge type, are required to provide the results of at least one analysis for any chemical listed in Table 4 known or believed to be present in the facility's effluent, and a measured or estimated effluent concentration for any chemical listed in Table 5 known or believed to be present in the facility's effluent. In addition, submit the results of any effluent analysis performed within the last three years for any chemical listed in Tables 4 and 5.

New industries, regardless of discharge type, are required to provide an estimated effluent concentration for any chemical listed in Tables 4 and 5 expected to be present in the facility's effluent.

8.

INJURIOUS CHEMICALS NOT PREVIOUSLY REPORTED New or existing industries, regardless of discharge type, are required to provide a measured or estimated effluent concentration for any toxic or otherwise injurious chemicals known or believed to be present in the facility's effluent that have not been previously identified in this Application.

Quantitative effluent data for these chemicals that is less than five years old shall be reported.

NOTE: All effluent data submitted in response to questions 4, 5, 6, 7, and 8 above should be recorded on Page 24.

To submit additional information, see Page ii, Item 3. If the effluent concentrations are estimated, place an "E in the "Analytical Method" column. The following fields shall be completed for each data row:

Parameter, CAS No., Concentration(s), Sample Type, and Analytical Method.

For analytical test requirements, see Page ii, Item 5.

If Alternate Test Procedures have been approved for any parameter listed above (Items 4 through 8), see Page ii, Item 5 for additional instructions.

5

Michigan Department of Environmental Quality-Water Bureau WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information

-\\SE TYPE OR PRINT FACILITY NAME NPDES PERMIT NUMBER OUTFALL NUMBER Donald C. Cook Nuclear Plant MI0O05B27 00H Submitted SAMPLE DATE +

3/5/08

=

Submitted C

Arsenic 7440382 1.3 C

Selenium 7782792

<0.5 C

Silver 7440224

<0.05

,E)

Additional data attached.

EC See attached electronic data.

El ED C]

11 El F1 17 C]

C]

C]

rC C]

C]

C]

C]

C]

C.]

C]

C]

C]

C]

6 EQP 4659-C(Rev. 11/2007)

Donald C. Cook Nuclear Plant NPDES Permit M10005827 Table 1 required analyses Analysis (Gray highlite is repeat from previous table)

Sample Received CAS Outfall OOH All samples are GRAB, unless otherwise noted, at Lab Method number sampled 4/30/07

• Additional data found Required In electronic form Biochemical Oxygen Demand (Five day BOD5) (24 hr Comp) gel SM.5210B None 2.62 mgfl Chemical oxygen Demand (COD) (24 hr Comp) gel EPA 410.4 None

<20.0 mg/l Total organic carbon (TOC) (24 hr Comp) gel SM 531OB None 3.13 mglI Ammonia Nitrogen (as N) (24 hr Comp) gel EPA 350.1 7664417 4.25 mg/I Total Suspended Solids (24 hr Comp) gel SM 2540D None

<2.5 mg/I Temperature Summer (Max July 07)

Cook SM 2550B None na-Internal outfall Temperature Winter (Max Jan 07)

Cook..

SM 2550B None na. internal outfall pH Cook SM 4500-H+B None From plant data*

'Additional data found Report available data In electronic form Total Dissolved Solids gel.

SM 2540C None 147 ug/I Total Phosphorus (24 hr Comp) gel EPA 365.4 7723140

<0.05 mg/I Total Residual Chlorine COOK EPA 330.5 electrode 7782505

<80 Ug/h Dissolved oxygen COOK SM 4500-0 C None 7.4 mg/I Oil and Grease gel EPA1664a None

<4.0 Table 2-Organic Toxic Pollutants (Table II from 40 CFR 122, Appendix D)

V olatiles 1,1,1-Trichloroethane gel EPA 624 71556

<1.00 ug/h 1,1,2,2-Tetrachloroethane gel EPA 624 79345

<1.00 ug/h 1,1,2-Trichloroethane gel EPA 624 79005

<1.00 ug/1 1,1-Dichloroethane gel EPA 624 75343

<1.00 ug/I 1,1-Dichloroethylene gel EPA 624 75354

<1.00 ug/I 1,2-Dichloroethane gel EPA 624 107052

<.00 ug/I 1,2-Dichloropropane gel EPA 624 76875

<1.00 ug/h 1,2-Trans-Dichloroethylene gel EPA 624 156605

<1.00 ug/I 1,3-Dichloropropylene (Listed in GEL as cis 1,3 Dichloropropylene and Trans 1,3 Dichloropropylene) gel EPA 624 542756

<1.00 ug/I 2-Chloroethylvinylether gel EPA 624 110758

<5.00 ug/I

Donald C. Cook Nuclear Plant NPDES-Perm it:M 10005827 Table 1 required analyses Analysis (Gray highlite is repeat from previous table)

Sample Received CAS Outfall OOH All samples are GRAB, unless otherwise noted.

at. Lab Method number sampled 4/30/07 Acrolein gel EPA 624 107028

<5.00 ug/I Acrylonitrile gel EPA 624 107131

<5.00 ug/I Benzene gel EPA 624 71432

<1.00 ug/I Bromoform gel EPA 624.

75252

<1.00 ug/I Carbon Tetrachloride gel EPA 624 56235

<1.00 ug/

Chlorobenzene gel EPA 624 108907

<1.00 ug/I Chlorodibromomethane (Dibromochloromethane) gel EPA 624 124481

<1.00 ug/I Chloroethane gel EPA 624 75003

<1.00 ug/I Chloroform gel EPA 624 67663 1.93 ug/I Dichlorobromomethane(bromodichloromethane) gel EPA 624 75274

<1.00 ug/I Ethylbenzene gel EPA624 100414

<1.00 ug/I Methyl Bromide/bromorethane) gel EPA 624 74839

<1,00 ug/I Methyl Chloride (chloromethane) gel EPA 624 74873

<1.00 ug/I Methylene Chloride gel EPA 624 75092

<2.00 ug/I Tetrachloroethylene gel EPA 624 127184

<1.00 ug/I Toluene gel.

EPA 624 108883

<1.00 ug/I Trichloroethylene gel EPA 624 79016

<1.00 ug/I Vinyl Chloride gel EPA 624 750174

<1.00 ughf Acid Compounds 2,4,6-Trichlorophenol gel EPA 625 88062

<9.43 ug/I 2,4-Dichlorophenol gel EPA 625 120832

<9.43 ug/I 2,4-Dimethylphenol gel EPA 625 105679

<9.43 ug/I 2,4-Dinitrophenol gel EPA 625 51285

<18.9 ug/I 2-Chlorophenol gel EPA 625 95578

<9.43 ug/I 2-nitrophenol gel EPA 625 88755

<9.43 ug/I 4,6-Dinitro-OCresol (2-Methyl-4,6-Dinitrophenol) gel EPA 625 534521

<9.43 ug/I 4-Nitrophenol gel EPA 625 100027

<9.43 ug/I P-Chloro-M-Cresol (4-chloro-3-methylphenol) gel EPA 625 none

<9.43 ug/I Pentachlorophenol gel EPA 625 87865

<9.43 ug/I Phenol gel EPA 625 108952

<9.43 ug/I Base/Neutral I.II

Donald C. Cook Nuclear Plant NPDES Permit M10005827 Table I required analyses Analysis (Gray highfite is repeat from previous table).

Sample Received CAS Outfall OOH All samples are GRAB, unless otherwise noted.

at Lab Method number sampled 4/30/07 1,2,4-Trichlorobenzene gel EPA 625 120821

<9.43 ug/I 1,2-Dichlorobenzene gel EPA 625 95501

<9.43 ug/I 1,2-Diphenylhydrazine (As Azobenzene) gel

-EPA 625 122667

<9.43 ug/I 1,3-Dichlorobenzene gel EPA 625 541731

<9.43 ugh 1,4-Dichlorobenzene gel EPA 625 106467

<9.43 ug/I 2,4-Dinitrotoluene gel EPA 625 121142

<9.43 ug/I 2,6-Dinitrotoluene gel EPA 625 606201

<9.43 ug/I 2-Chloronaphthalene gel EPA 625 91587

<0.943 ug/I 3,3'-Dichlorobenzidine gel EPA 625 91941

<9.43 ug/I 3,4-Benzofluoranthene (Benzo(b)fluoranthene,)

gel EPA 625 205992

<0.943 ug/I

..4-Bromophenylphenylether gel EPA 625 101553

<9,43 ug/I 4-Chlorophenyl Phenyl Ether gel EPA 625 7005723

<9.43 ug/!

Acenaphthene gel EPA 625 83329

<0.943 ug/I Acenaphthylene gel EPA 625 208968

<0.943 ug/I

__Anthracene gel EPA 625 120127

<0.943 ug/I Benzidine (benzyl alcohol) gel EPA 625 92875

<9.43 ug/I Benzo (a) Anthracene gel.

EPA 625 56553

<0.943 ug/I Benzo (a) Pyrene gel EPA 625 50328

<0.943 ug/I Benzo (ghi) Perylene gel EPA 625 191242

<0.943 ug/!

Benzo (k) Fluoranthene gel EPA 625 207089

<0.943 ug/I Bis (2-Chloroethoxy) Methane gel

• EPA 62.5 111911

<9.43 Ug/I Bis (2-Chloroethyl) Ether gel EPA 625 111444

<9.43 ug/I Bis (2-Chloroisopropyl) Ether gel EPA 625 108601

<9.43 ug/I Bis (2-Ethylhexyl) Phthalate gel EPA 625 117817

<9.43 ug/I Butylbenzyl Phthalate gel EPA 625 85687

<9.43 ug/I Chrysene gel EPA 625 218019

<0.943 ug/!

Di-N-Butyl Phthalate gel EPA 625 84742

<9.43 ug/I Di-N-Octyl Phthalate gel EPA 625 117840

<9.43 ug/I Dibenzo (a,h) Anthracene gel EPA 625 53703

<0.943 ug/I Diethyl Phthalate gel EPA 625 84662

<9.43 ug/I Dimethyl Phthalate gel EPA 625 131113

<9.43 ug/I Fluoranthene gel EPA 625 206440

<0.943 ug/I

Donald C. Cook Nuclear Plant NPDES Permit M10005827 Table 1 required analyses Analysis (Gray highlite is repeat from previous table)

SampleReceived CAS Outfall OOH All samples are GRAB, unless otherwise noted.

at Lab Method number sampled 4/30/07 Fluorene g el EPA 625 86737

<0.943 ug/I Hexachlorobenzene gel EPA 625 118741

<9.43 ug/l Hexachlorobutadiene gel EPA 625.

87683

<9.43 ug/I Hexachlorocyclopentadiene gel EPA 625 77474

<9.43 ug/I Hexachloroethane gel EPA 625 67721

<9.43 ug/I Indeno (1,2,3-cd) Pyrene gel EPA 625 193395

<0.943 ug/I Isophorone gel EPA 625 78591

<9.43 ug/I N-Nitrosodi-N-Propylamine gel EPA 625 none

<9.43 ug/I N-Nitrosodimethylamine (N-methyl-N-nitrosomethylamine) gel EPA 625 62759

<9.43 ug/I N-Nitrosodiphenylamine (Diphenylamine) gel EPA 625 86306

<9.43 ug/I Naphthalene gel EPA 625 91203

<0.943 ug/I Nitrobenzene gel EPA 625 98953

<9.43 ug/!

Phenanthrene gel EPA 625 85018

<0.943 ug/I Pyrene gel EPA 625 129000

<0,943 ug/I Table 3 -Other Toxic Pollutants (metals and Cyanide) and Total Phenols.

(Table III from 40 CFR 122, Appendix D)

Total Antimony gel EPA 200.8 7440360

<1 ug/I Total Arsenic gel EPA 200.8 7440382

<1.50 ug/I.

Total Beryllium gel.

EPA 200.8 7440417

<1 ug/I Total Cadmium gel EPA 200.8 7440439

<0.2 ug/I Total Chromium gel

.EPA 200.8 7440473

<10 ug/I Total Copper gel EPA 200.8 7440508 12.5 ug/I EPA method Available Cyanide kar OIA-1677 57125

<2 ug/I Total Lead gel EPA 200.8 7439921

<1 ug/I EPA method Total Mercury gel 1631 7439976 1.78 ng/I Total Nickel gel EPA 200.8 7440020

<5 ug/I Total Phenols gel.

EPA 420.2 none

<5,00 ug/I Total Selenium gel EPA 200.8 7782792

<2.50 ug/I

Donald C. Cook Nuclear Plant NPDES Permit M10005827 Table-1 required analyses Analysis (Gray highlite is repeat from previous table).

Sample Received CAS Outfall OOH All samples are GRAS, unless otherwise noted, at Lab Method number sampled 4/30/07 Total Silver gel EPA 200.8 7440224

<1.00 ug/h Total Thallium gel.EPA 200.8 7440280

<1 6g/1 Total Zinc gel EPA 200.8 7440666

<10 ug/h Table 4 Conventional and Non-conventional pollutants to be tested by existing discharges if expected to be present in discharge "Addltlonal data found (Table IV from 40CFR 122, Appendix D)

In electronic form Aluminum, Total gel EPA 200.8 7429905 279.0 mg/A Barium, Total gel.

EPA 200.8 7440393 18.1 ughI BoronTotal gel EPA 200.8 7440428 30.1 mg/I Bromide gel EPA 300 7726956.0

<0.200 mg/I Cobalt, Total gel EPA 200.8 62207765

<1.00 ughI Fluoride gel SM 4500-F B 7782414

<0.100 mg/I Iron, Total gel EPA 200.8 none 267 ug/h Magnesium, Total gel EPA 200.8 7439954 10100 ug/h Manganese, Total gel EPA 200.8 7439965

<5.00 ug/I Molybdenum, total gel EPA 200.8 7439987 5.74 ug/h Nitrate-Nitrite (as N) gel EPA 353.2 none 0.467 mg/I EPA Nitrogen, total Organic (as N) gel 351.2/350.1 none

<500 ug/

Radioactivity gel EPA 900 none Alpha, total gel EPA 900 none

<5.00 pCi/I Beta, total gel EPA 900 none

<5.00 pci/I Radium, Total gel EPA 900 7440144

'<1.00 pCi/I Radium 226, total gel EPA 900 7440144

<1.00 pCi/I Sulfate (as S04) gel EPA 300.0 none 36.5 mg/i

• Sulfide (as-S) gel SM 4500-S F 18496258

<0.100 mg/I Sulfite (as S03) gel SM 4500-SO3 B none

<2.00 mg/I Tin, Total gel EPA 200.8 7440315

<5.0 ug/I

Donald C. Cook Nuclear Plant NPDES Permit M10005827 Table 1 required analyses Analysis (Gray highlite is repeat from previous table)

Sample Received CAS Outfall OOH All samples are GRAB, unless otherwise noted, at Lab Method number sampled 4/30/07 Titanium, total gel.........

EPA 200.8 7440326

<10 ug/I Table 5 - Toxic pollutants and hazardous Substances required to be identified by Existing Discharges if Expected to Be present in Discharge Addlto.a data found (Table V from 40 CFR 122, Appendix D)

In electronic form Toxic Pollutant Hazardous Substances 1,2 Napthoquinone-4 sulfonic Ethanolamine mg/I COOK Acid method 141435

<0.7 H drazine u /l COOK ASTMD-1385-88 302012 1

<3.0

Michigan Department of Environmental Quality-Water Bureau WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III.- Industrial and Commercial Wastewater B. Outfall Information EASE TYPE OR PRINT

.CILITY NAME NPDES PERMIT NUMBER OUTFALL NUMBER Donald C. Cook Nuclear Plant M10005827 OOH

9.

WATER TREATMENT ADDITIVES Water treatment additives include any material that is added to water used at the facility or to wastewater generated by the facility to condition or treat the water.

Approvals of water treatment additives are authorized by the MDEQ under separate correspondence. The issuance of an NPDES permit does not constitute approval of the water treatment additives that are included in this Application.

A. Are there water treatment additives in the discharge from this facility?

[

Yes.

El No. Proceed to Item 10.

B. Have these water treatment additives been previously approved?

[

Yes. Submit a list of the previously-approved water treatment additives and the date on which they were approved. The information listed in Item C., Items 1-8 shall be updated if it has changed since the previous approval.

E] No. Continue with Item C.

C. Submit a list of water treatment additives that are or may be discharged from the facility. Applicants are required to submit the information listed below for each additive.

1.

The water treatment additive Material Safety Data Sheet.

2.

The proposed water treatment additive discharge concentration.

3.

The discharge frequency (i.e., number of hours per day, week, etc.).

4.

The outfall from which the water treatment additive is to be discharged.

5.

The type of removal treatment, if any, that the water treatment additive receives prior to discharge.

6.

The water treatment additive function (i.e., microbiocide, flocculant, etc.).

7.

A 48-hour LC50 or EC50 for a North American freshwater planktonic crustacean (either Ceriodaphnia sp., Daphnia sp., or Simocephalus sp.).

8.

The results of a toxicity test for one other North American freshwater aquatic species (other than a planktonic crustacean) that meets a minimum requirement of Rule 323.1057(2)(a) of the Water Quality Standards. Examples of tests that would meet this requirement include a 96-hour LC50 for rainbow trout, bluegill, or fathead minnow.

The required toxicity information (described in Items 7 and 8 above) is currently available in the Water Bureau files for the water treatment additives listed on the MDEQ's Internet page. To access that information, go to http://www.michigan.gov/deq, click on "Site Map," at the bottom of the right column under Water Quality Monitoring, dick on "Assessment of Michigan Waters."

Under the Information heading, click on the 'Water Treatment Additive List." If you intend to use one of the water treatment additives on this list, only the information in Items 1 through 6 above needs to be submitted to the Water Bureau.

Note: The availability of toxicity information for a water treatment additive does not constitute approval to discharge the water treatment additive.

10.

WHOLE EFFLUENT TOXICITY (WET) TESTS Have any acute or chronic WET tests been conducted on any discharges or receiving water(s) in relation to facility discharges within the last three years? If yes, identify the tests and summarize the results on a separate sheet, unless the test has been submitted to the MDEQ in the last three years. For assistance with WET testing, see 'Whole Effluent Toxicity Test Guidance and Requirements" in the Appendix.

11.

CONCENTRATED ANIMAL FEEDING OPERATION (CAFO) INFORMATION. To be completed by CAFOs only The applicant shall provide: Specific information about the number and type of animals, and type of housing; the type of containment and storage, and the total capacity for CAFO waste storage; CAFO waste storage structure design; the total number of acres under the control of the applicant that is available for land application of CAFO waste; the estimated amounts of CAFO waste generated per year; the estimated amounts of CAFO waste that is transferred to other persons per year, a list and map(s) showing the location of all land application fields; and all potential receiving waters for both the production and all land application areas. For additional information, see "CAFO Guidance and Requirements" in the Appendix.

-his completes Section I1i. Return the completed Application (Sections I, 1l1, and IV and any attachments) to one of the-addresses Page ii of this Application. If assistance is'needed to complete this Application, contact the Permits Section.

7 EQP 4659-C (Rev. 11/2007)

Michigan Department of Environmental Quality-Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information PLEASE TYPE OR PRINT FACILITY NAME NPDES or COC PERMIT NUMBER Outfall Number Donald C. Cook Nuclear Plant M10005827 00H

9. WATER TREATMENT ADDITIVES Water Treatment Additive Approval Date Hydrochloric Acid (pH control) 11/14/96 Change of process application, 11/25/96 approval.

NPDES Permit application approval 9/28/00, 5/23/00.

Sulfuric Acid (pH control) 11/14/96 Change of process application, 11/25/96 approval.

NPDES Permit application approval 9/28/00, 5/23/00.

Sodium Hydroxide 11/14/96 Change of process application, 11/25/96 approval.

NPDES Permit application approval 9/28/00, 5/23/00.

Sodium Bisulfite 11/14/96 Change of process application, 11/25/96 approval.

NPDES Permit application approval 9/28/00, 5/23/00.

Citric Acid 11/14/96 Change of process application, 11/25/96 approval.

NPDES Permit application approval 9/28/00, 5/23/00.

Phosphoric Acid 11/14/96 Change of process application, 11/25/96 approval.

NPDES Permit application approval 9/28/00, 5/23/00.

Tide Detergent or equivalent 11/14/96 Change of process application, 11/25/96 approval.

NPDES Permit application approval 9/28/00, 5/23/00.

Aluminum Sulfate 7/20/94 Carbohydrazide solutions such as: Betz Cortrol OS5613, Nalco 1250 plus 3/24/94 NPDES application, 4/15/94 approval, NPDES Permit' approval 9/28/95 Ethanolamine 5/23/00, NPDES approval 9/28/95 Betz Steamate 1480N, Nalco 92UM001 Hydrazine:

5/23/00, NPDES approval 9/28/95 Betz Cortrol OS5035, OS 5010, Nalco 19H

Michigan Department of Environmental Quality-Water Bureau WASTEWATER DISCHARGE PERMIT APPLICATION SECTION IV - Storm Water OR PRINT v AME NPDES PERMIT NUMBER

..C. Cook Nuclear Plant M10005827 STORM WATER DISCHARGES Facilities that discharge storm water must provide the following information. (Please Note: The following discharges are also covered by storm water authorization, provided they are addressed in the facility's Storm Water Pollution Prevention Plan [SWPPP]): Discharges from fire hydrant flushing; potable water sources, including water line flushing; fire system test water, irrigation drainage; lawn watering; routine building wash down which does not use detergents or other compounds; pavement wash waters where spills or leaks of toxic or hazardous materials have not occurred (unless all spilled material has been removed) and where detergents are not used; air conditioning condensate; springs; uncontaminated ground water; and foundation or footing drains where flows are not contaminated with process materials such as solvents.

A. Does this facility have a certified industrial storm water operator who supervises the facility's storm water treatment and control measures included in the SWPP?

Z Yes.

Blair Zordell 02351 Storm Water Operator Name Certification Number l]

No. Note: The applicant must complete this program element to receive storm water discharge authorization.

B.

Is any of the storm water discharged from (check all that apply):

0 Secondary containment structures that are required by state or federal law. On a separate page, provide a list the materials that are stored in this area.

[

Areas identified on Michigan's list of Sites of Environmental Contamination, pursuant to the Natural Resources and Environmental Protection Act, PA 451 of 1994, Part 201 (formerly 307).

C. The storm water from this facility discharges to the following receiving water(s): Lake Michigan Please note that applicants should provide any sample data taken of the storm water discharge as an attachment. To submit additional information, see Page ii, Item 3.

STORM WATER CERTIFICATON Rule 323.2114(1-4), promulgated under the Michigan Act, requires that this Application must be signed as follows:

A. For an organization, company, corporation, or authority, by a principal executive office, vice president or higher.

B.

For a partnership, by a general partner.

C. For a soleproprietor, by the proprietor.

D. For a municipal, state, or other public facility, by a principal executive officer or ranking elected official (such as the mayor, village president, city or village manager, or clerk).

• • Note: If the signatory is not listed above, but is authorized to sign the Application please provide documentation of that authorization.

I certify that my facility has developed a SWPPP according to the requirements of the Storm Water General Permit.

I certify that my facility has no unauthorized discharges.

I certify that my facility has. implemented the nonstructural controls as described in the SWPPP. New facilities shall fulfill this requirement when industrial activity begins.

I certify my facility has completed construction and will put into operation all structural controls as described in the SWPPP. If necessary, new facilities shall fulfill this requirement when industrial activity begins.

I certify, under penalty of law, that this document and all attachments were prepared by me, or under my direction or supervision in accordance with a system to assure qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person(s) who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware there are significant penalties for submitting false information, including the possibility of fine and imprisonment for knowing violations.

I understand that my signature constitutes a legal agreement to comply with the requirements of the appropriate NPDES General Storm Water Permit. I certify under penalty of law that I possess full authority on behalf of the legal ownerlpermittee to sign and submit this Notice of Intent.

Print Name:

Jon H. Hamer

Title:

Environmental Manager Signature:

0

i.

/Ao.-

Date:

L-2--0.7 25 EQP 4659-C (Rev 9/04)

Michigan Department of Environmental Quality-Surface Water Quality'Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION IV - Stormwater PLEASE TYPE OR PRINT FACILITY NAME NPDES or COC PERMIT NUMBER Donald C. Cook Nuclear Plant M10005827 I. Stormwater discharges C. List of materials that are stored in the site's secondary containment structures that are required by state or federal law.

1.

Sodium hypochlorite.

2.

Misc. oil-filled electrical transformers (non PCB mineral oil).

3.

Fuel oil.

4.

Sulfuric acid.

5.

Sodium hydroxide (Indoor storage).-

6.

Hydrazine (Indoor storage).

7.

Misc. lubricating oils (Indoor storage).

8.

Chemical unloading areas: (fuel oil, sodium hydroxide, sulfuric acid).

9.

Temporary equipment such as diesel generators, or diesel pumps that could reach storm drains:

10. Sodium Bisulfite.

11. Proprietary molluscicides during treatment periods.

12. Bentonite clay during treatment periods.

13. Resin bed regeneration waste (Stored in double walled tank).

14. Misc. paints and solvents (Indoor storage).

ENCLOSURE 2 TO AEP:NRC:2401-19 SUPPLEMENT TO NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM PERMIT RENEWAL APPLICATION

Indiana Michigan Power Company UNDOAN-A Nuclear Generation Group One Cook Place Bridgman, MI 49106 POWR aep.com May 27, 2008 AEP-MDEQ-2008-2 Michigan Department of Environmental Quality.

Water Bureau Attn: Mr. Sean Syts P. 0. Box 30273 Lansing, MI 48909-7773

Subject:

Cook Nuclear Plant Supplement to NPDES Permit M10005827 Application

Dear Mr. Syts,

On April 2, 2008, Indiana Michigan Power Company (I&M) submitted an Industrial and Commercial Wastewater Discharge Application for renewal of the Cook Nuclear Plant National Pollutant Discharge Elimination System (NPDES) Permit. At the time the application for renewal was submitted, I&M's contracted lab was unable to meet the required quantification levels for Silver, Selenium, and Arsenic for Outfall 00B. In subsequent telephone conversations between I&M staff and Michigan Department of Environmental Quality (MDEQ) staff, MDEQ staff agreed to accept the analysis results for the application at a later date.

Enclosed is the supplemental data for Outfall OOB. This data meets the required quantification levels and completes our submittal of the permit application. Also included for your information are the data sheets for Outfalls O0A and OOC, which are intended only to provide a complete set of data sheets.

Should you have any questions, please contact me at (269) 465-5901,extension 2102, or Blair Zordell at (269) 465-5901, extension.2006.

Sincerely, Jon H. Hamer Environmental Manager Enclosures JEN/rdw c:

Mr. John Vollmer, MDEQ - Kalamazoo w/o enclosures

Michigan Departmentbf Environmental Quality-Water Bureau WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information PLEASE TYPE OR PRINT FACILITY NAME NPDES PERMIT NUMBER OUTFALL NUMBER Donald C. Cook Nuclear Plant M10005827 O0A Submitted SAMPLE DATE 4 4/2/2008 via DMIR's PAAETRCAS Conc.

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7440382

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Selenium 7782492

<0.5 Grab 200.8 EI Silver 7440224

<0.05 Grab 200.8 0I Additional data attached

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EQP4.4659-C (Rev. 11/2007)

Michigan Department of Environmental Quality-Water Bureau WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information PLEASE TYPE OR PRINT FACILITY NAME NPDES PERMIT NUMBER OUTFALL NUMBER Donald C. Cook Nuclear Plant M10005827 DOB Submitted SAMPLE DATE +

4/2/2008

-7 via DMR's PARAMET R CAS.

c Sample Analyt No.I)

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K~(~I Type Method El Arsenic 7440382

<0.1 Grab 200.8 r-Selenium 7782492

<0.5 Grab 200.8 El Sliver 7440224

<0.05 Grab 200.8 Additional data attached El See attached electronic data.

El El r3 El El 0-El El El El 1.E El r-l El El El El]

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EQP 4659-C (Rev. 11/2007)

Michigan Department of Environmental Quality-Water Bureau WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information PLEASE TYPE OR PRINT FACILITY NAME NPDES PERMIT NUMBER OUTFALL NUMBER Donald C. Cook Nuclear Plant M10005827 00C Submitted SAMPLE DATE "

4/2/2008 PAAMTE DICAS,,

Conc.~ ~Cnc.

Conc. C oc Sample Anaytical El Arsenic 7440382

<0.1 Grab 200.8 Selenium 7782492

<0.5 Grab 200.8

-l Silver 7440224

<0.05 Grab 200.8 El Additional data attached El See attached electronic data.

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6 EQP 4659-C (Rev. 11/2007)