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{{Adams
{{Adams
| number = ML003739985
| number = ML13038A435
| issue date = 05/31/1974
| issue date = 06/30/1973
| title = Design Considerations for Minimizing Residual Holdup of Special Nuclear Material in Drying and Fluidized Bed Operations
| title = Design Considerations for Minimizing Residual Holdup of Special Nuclear Material in Drying and Fluidized Bed Operations
| author name =  
| author name =  
Line 10: Line 10:
| license number =  
| license number =  
| contact person =  
| contact person =  
| document report number = RG-5.008, Rev. 1
| document report number = RG-5.008
| document type = Regulatory Guide
| document type = Regulatory Guide
| page count = 5
| page count = 5
}}
}}
{{#Wiki_filter:Revision 1 May 1974 ir U.S. ATOMIC ENERGY COMMISSION  
{{#Wiki_filter:June 1973 U.S. ATOMIC ENERGY COMMISSION
~RREQULATO.RY  
                                *
GUID -.j~ DIRECTORATE
                                    R EGU LATO.RY GU I D E
OF REGULATORY  
                                        IDIRECTORATE i:.OF REGULATORY STANDARDS
STANDARDS  
                                                      Il          -      NIPt4                            GI1015.8 Rm
REGULATORY
                            !"DESIGN CONSIDERATIONS FOR MINIMIZING RESIDUAL HOLDUP
GUIDE 5.8 DESIGN CONSIDERATIONS  
                          -CIALNUCLEARMATERIAL IN DRYING AND FLUIDIZED BED OPERATIONS.
FOR MINIMIZING  
RESIDUAL HOLDUP OF SPECIAL NUCLEAR MATERIAL IN DRYING AND FLUIDIZED  
BED OPERATIONS


==A. INTRODUCTION==
iNTROUCTION~"'=505                                          ldi, or hidden inventory. A characteristic amount of
Section 70.22, "Contents of Applications," of 10 CFR Part 70, "Special Nuclear Material,," requires, in part, ' that each application for a license to possess at any one Itime more than one effective kilogram of special nuclear material (SNM) contain a full description of the applicant's procedures for control of and accounting for SNM which will be In his possession under license, including procedures for controlling SNM during its processing or use in the facility.
                              'Wmateal                                                                                              that is difficult to locate, sample, identify, o.22 -"Cbiiitets 6r'applications,"'of'Io0,                                     !quantify, and analyze is held up in equipment for a given
                          :.I:SpeCial
                          :applicationfor    Nuclear       Material,";requires," indg;
                                                      alicenseto                                            design, mode of operation, and type of process material.


Furthermore, Section 70.51. "Material Balance, -Inventory, and Records Requirements,'  
possess certainri ,                :I'This holdup may be decreased as the status of the special nuclear material (SNM) contain a                                    *:equipment changes progressively through the four stages i of the applicant's procedures for control:                                  *consisting, of operation, shutdown, draindown, and inting;.for.: SNMWTwhichý,will.be, in ..hi! !,Siý,:cleanout.. Simultaneously, the number of sources of ider ;license,':ý!.including'-`procedureso                                        uncertainty and the levels of uncertainty in the physical
requires, in part, that certain licensees conduct at specified intervals physical inventories of the SNM in their possession  
                          4M .during its '.processing.,,or, use- in -the:ii inventory may be reduced.-.                                                          ..
'under license. The control of and accounting for SNM can be made more effective by minimizing the residual holdup after shutdown, after draindown, and after cleanout of the equipment used to process SNM, thereby reducing the component of uncertainty contributed by residual holdup to a physical inventory and lessening the severity of problems associated with determination of residual holdup. This regulatory guide describes acceptable design features and characteristics for minimizing the residual holdup of SNM in drying and fluidized bed operations after shutdown, draindown, or cleanout in order to facilitate material control and accountability procedures.
                          procedures' by which' proces'losses are                                            -.......              '.
                          quihermore; Section','nth'.51fo"rm                                    ,':*'q;*,,,.tý.          e'      ofnventory
                                                                                                                                    "relation ui        of SNM in process equipment in quirements,".requires;in pa rt; that certain                                       the form of residual holdup following shutdown, iduct"<' at ;specified intervals *,;physical                                       draindown, and cleanout could have adverse effects on a
                          .the NM i their possession under license. 4t'&#xfd; materials control program. Minimizing that quantity of if.and .accounting for SNM can be'made'.&#xfd;-                                    -&#xfd;material retained in process equipment enhances the
                          'tby minimizing the residual holdup after                                   *A.effectiveness of a materials protection program in the er.; draindowni and after cleanout of the -                                        following wy"
                          A'.'4t0oprocess SNM,'thereby reducing the'                                        followin'gway:                    ,,
                            .. ..Uncertai...'..ontributed.                    residual,,,,,,.                        a&#xfd;.,. Te quality of a physical inventory is improved
                                                                                            4it ne'Vy'reducing y                      uncertainty due to holdup. For example, issociated:
                            :..
                            . .              with
                                          ....
                                            .r&#xfd;',..  determination
                                                  . .,'j:
                                                        'd.      .      :of ..residual !* *t the              heAcontribution n r b t o off uunmeasured m a u r d hholdup l u material a ei l tto the  h Se:re gulatry i;ide',describes".,&#xfd;'acceptable6-,; icategory of material unaccounted for (MUF) may be sand characteristics 'for. minimizing thel                                      -lessened,:' and, the influence of uncertainty associated Ipof-.'SNM                                 -fluidized bed gwith            'in'dryiri"id    measured holdup on the limit of error on material er shutdown;'.draindown,' or cleanout in'*-                                        unaccounted for (LEMUF) in a material balance may be itate', material 'control and accountability~fll                                  lessened. Furthermore,. the extent to which the hese 'features and characteristics are not-:*.                                            eruncertainty ,;in.. holdup contributes to a physical terfere with process operations.-K                            i            '&#xfd;,inventory              depends on the magnitude of the amount
                                    ,                                      -          ,,                : present and how precisely and accurately that amount is B.amenableOto**,B
                                          'DISCUSSION                                                                                being measured. Therefore, reducing the q..uantityof holdup directly decreases the uncertainty
                                                              .                          .                ..contributed to a physical inventory.


These features and. characteristics are not expected to interfere with process operations.
amt~ pr'esses'*permit~~accu                      laton ,,,o                          ,h b.'A reduction in the quantity of holdup material s'iN which are referred to as residual'                              ;.
                                                      ts  o
                                                    ..........
                                                      .*,,1
                                                      .        SNM~  -....
                                                                        .. *                                shutdown,              drain down.-.following tmustbe:recovered.                  and cleanoutthe three  of stages processof
  *j~j;,This Is a qw umtlty exceeedla-uan yor tltni,                            mo s                      'equipment decreases the quantity of SNM susceptible to i6ontained Vurani urn' f23S'fouraniuim;233*,*,itor plutoniumtor,..              any..the                  diversion during sampling, identification, and subsequent
  'combination'" thuclei"eaciorlicensed pursuaatitoi 1 CtFeRPartan                                          separation .'.or: recycle of this material as may be operation of 'n
    50 brfasiealed 3tOur.re*,,                                                                            !necessary to complete a physical inventor


==B. DISCUSSION==
====y. A reduction====
1. Background Ceftain unit processes permit accumulation of sizable amounts of SNM which are referred to as residual holdup, or hidden inventory.
                                                'USAEC EGULATOCopUies                                                of published gulidemay be obtained by request Indicating the divisions
                              ~  ,~                                                *~,&"y~desired to the US. Atomic Energy Commission. Washington. D.C. 20545, Reuaoy'udsae'sud tdecbendrk ailbtthpulc                                                      Attention: Director of Regulatory Standardls. Comments en suggestions for methds ace          oteACRgltrrtf
                            4able                            fIpeetn pcfcprso K im'provemnentt                              In theseguides are encouraged and should be gent to the Secretary the Commission's regulations, to delineate techniques used by the staff In' kOf the Commissuion,                                U.S. Atomic Energy Commisusion. Washington, D.C. 20645.


A characteristic amnount of Indicales changec from previous issue.this material that is difficult to locate, sample, identify.
evaluating tpeciflc problems or postulated accidents, or to provide guidance to                        Attention: Chief. Public Proceedings Staff.


quantify, and analyze is held up in equipment for a given design, mode of operation, and type of process material.
applicants. Regulatory Guides era not substitutes for regulations and compliaAce Z                          .... -
)  with -them is not required. Methods and solutions diffternt from those set out in the guides will be accoptable if they provide a basis for the findings requisite to the issuance or continuance of apermit or iicensa by the Commission.


This holdup may be decreased as the status of the equipmenit changes progressively through the four stages consisting of operation, shutdown, draindown, and cleanout.
7.          .
                                                                                -
                                                                                    ""    ''
                                                                                                    '
                                                                                                      '1.


Simultaneously.
'2.


the number of sources of uncertainty and the levels of uncertainty in the physical inventory may be reduced.
The guides ae IssuedIn the following ton brood visions:
                                                                                                                Power Reacto        ' '
                                                                                                                  Research andTest Reactors
                                                                                                                                            '.
                                                                                                            3. Fuels and Materials Facilities Producu
                                                                                                                                                          7. Traneportation I. Occupational Heatth Publishe gudes will be revse perlodcally,*asappropriate, to aoenmmodate ,;                              4. Environmental and Siting                  9. Antitf it Review comments andto reflect new Inforrmation or eXperience. -..            .
                t:ta                                                                                                          n  lP.0                        en


The accumulation of SNM in process equipment in the form. of residual holdup follcwing shutdown.
in holdup also can enhance process operations by                                              For certain processes, however, batch drying is decreasing the extent and time of., unit, process                                  advantageous. With individual batches it is possible to innterruptions for material accountabllity. For example.                          imaintain batch identity. However, batch driers require jfor a process amenable to dynamic inventory techniques,                          ,,more physical handling of material than continuous icredibility'.In" such .a '.technique may be. increased by;                          driers, may be difficult to automate, and may necessitate
                :ducingthe;detrimental effects of residual holdup on              iadditional equipment cleanout between batches.


draindown, and dleanout could have ac~verse effects on a materials control program. Minimuiziing that quantity of material retained in process equipment enhances the effectiveness of a materials protection program in the following ways: a. The quality of a physical inventory is improved by reducing uncertainty due to holdu~p. For example, the contribution of unmeasured holdu-p material to the category of material unaccounted for (MUF) may be lessened, and the influence of uncertainty associated with measured holdup on the limit of error on material unaccounted for (LEMUF) in a material balance may be lessened.
c an invent o,                                                 Wy***                    SFor' directly heated fluid-bed ders and spray driers, effort requnIredo"stablish the presence of an :io.remove residual material for a physical inventor""                          't re is a tendency for dry product to adhere to the Ws:ireduced "Consequently, '.the amount of time and thei                        ,walls and bottom of the drier, particularly if the product Thme:      of people who need access to SNM are reduced.'                          is very fine. Internal mechanical scrapers constitute an The,'opp ortunity..rfor unauthorized .individuals to gain                        4additional Impediment to cleaning the drying chamber.


Furthermore, the extent to which' the uncertainty in holdup contributes to a physical inventory depends on the magnitude of the amount present and how precisely and accurately that amount is amenable to being measured.
:Sccess to SNM during this stage of a physical Inventory, l"iso ninv he retplme J.A      *)              -ski3.


Therefore, reducing the quantity of holdup directly decreases the uncertainty
h1,       ri~        'i,'*:    , ,. 6T id,,i*I      ndirectly heated driers inwhich 'the material being dried contacts a heated surface, sweep gas may be
'contributed to a physical inventory.
                                                                                  ,.used to carry away the vapor from the drying solid.


b. A reduction in the quantity of holdup material that must be recovered following the. three stages of shutdown.
&#xfd;&#xfd;Unless the exit .velocity, of this vapor is low, some
                                                                                  4:material will be entrained in the gas and may be retained Jin: ducts. :'Also,: for indirectly heated continuous screw
                                                                                    'conveyor driers, as the feed drys to an adhesive paste It
                                                                                    !has a tendency to cake and choke off the flow or to spill jout. of the drier. Furthermore,-. the screw, conveyor is idifficult to clean and tends to be a significant source of
                                                                                  &#xfd;holdup.-`'f`:';
                                                                                          (.7,'Rotary      driers have been used to combine a drying
                                                                                  ;.peration with a calcining operation in separately heated
                                                                                    ;zones. An intermediate paste having a high bulk density and viscosity has a tendency to adhere to most materials.


draindown, and cleanout of process, equipment decreases the 'quantity of SNIM susceptible to diversion during sampling, identification.
which it contacts such as flight carriage surfaces. Such'
                                                                                    surfaces contribute to holdup by impeding material flow
                                                                                  ",during emptying. Therefore, special attention, may be
                                                                                  *&#xa3;necessary for cleanout or draindown. Directly heated r'.7otary driers also may be accompanied by carry over of
                                                                                                                                                      &#xa3;1
                                                                                  ,`,dust or ultrafine powder which becomes a form of
                                                                                        *!!Woven metal belt driers have a high surface area and high porosity. Consequently, they may be a significant:
                                                                                    ~,source of material holdup.          .;,
                                                                                      .,-, Batch *,'pan driers are completely enclosed and
  :inif a' bnt'ainei .';.the &#xfd;gas l'steam and must be,                            rlsuaUy are equipped with agitators which constitute a collected 'ri:filtersand recovered from the process. The,                           source'of material holdup upon emptying. Agitators also entrainment    hcontrbutes'to holdup' of, fines in ductwork"                      Scauseg~more,,,difficulty,". for a ,*,complete.,, cleanout.


and subsequent separation or recycle of this material aS may be necessary to complete a physical inventory.
and Wfiters.'!On&#xfd; itihie ',bthfer':,,!hand;:,dirctlyv1heated dr..ieri&#xfd;          -Continuous. driers'.with open :static beds such as pans, usinfi*i*i                ea lap ps %are:advaniageous'*sin **?                    .boats, ,or trays. do not contribute significantly to holdup entrain&#xfd;mifent the':niis'irnimal.'Use&#xfd;':of agitators in' diictll3                .inless"'they are accidentally tipped -or the contents are'.
  heated driers 1rmay'.:..be:,'.desirable',,,from ".",an"',ioperating              ,otherwise Spilled.' Trays` pans, and boats also may be.,
  standpoint However,'.;'driers with agitators are difficult to                      j..easy to empty and clean if necessary.:
  empty and clean                    '.". ',, ""    ' i' '    '          *. ..-
                                                                                      !3;,Holdupn'iFluidized Bed Operations
                                                                                    !          Because. of the numerous interrelated components high.thioughput si".low-holduip.i* ope6ration. :*,This '~;arises                    ofa fluidized bed operation that contact the process largely*!,from .:incrieased :;continuity iof 'operation :iand in creased'unimiforrnity! offmat erial handling.' Continuous                        rmaterial, there 'exists a large number of locations where operatioi~.have;the:' advant agers of ,firinimaphysica1                            holdup may occur and numerous sources initiating its
                                                                                  ,.,occurrence.".'.';,However,' holdup in fluidized beds handlin"'aw*el                as'sgreate** r      potential. for*,*i process      `commonly '.depends upon .the 'size and growth of automation -                                                '.                 '&#xfd;;%&#xfd;particles throughout the syste


A reduction USAEC REGULATORY
====m. I Beginning with the====
GUIDES Copies ot pukihedt guldes nay be obtabned by request indkinaing the diviesions desired lst.0 US. Atomric Energ Commiteision.
                                                                                        !;.**:*:,-.i**!..* **.**::,/  ..*. . .:..,.


Washingtont.
input, screw conveyors, pneumatic carriers, dip pipes,                                                connecting lines is sensitive to process variables such as seal legs, injectors, or other means are used to introduce                                              temperature. Severe . operating conditions such as solids into, the reactor proper. Difficulties with holdup                                              temperature excursions are particularly conducive to arise and :speclal '.techniques become "necessary when                                              , severe segregation and packing of SNM against the base sol:dsare
                1          not free flowing, such as filtered precipitates' .&#xfd;'.and                                        interior walls. The existence of holdup may and other moist solids. Since it is difficult by means of ag,-gi. compound an excursion by its sudden release to the
*          screw conveyor to feed wet material to a reactor, it may                                            &#xa2;fluidized -bed for reaction, which induces further be necessary to assist handling by wetting the material t                                            excursion and additional resulting holdup by the i~iattain&#xfd;.a>,slurry,! consistency be fore feeding.-JIf $1urrr'5,0,Itmechanisms of packing and fusion..
  V' 2.conststency.,dts `iundesirable for the'material,, the solieh                                                                  of packing and fusion.


D.C. 2045.  Regulatory Guides wer issued to describe and stake available to the public Attention:
Tproduct may.be recycled to mix with the feed to dry txl AVeral                                                                              i      fses acheve~~eterjhanlinRL-Exiting materil consists of product and offgass and~herby.
Directoi of Raulatorvi
$tander&e.


Comnnunts end sugesttons for tehos acpobla to If.. AEC Regulatory etaf" of irnpaemanting Wecific parts of NpOftlt 0teead e= V er nouee nd uho1 e in t te ecetr the'Cornmessin's viegulations.
iand*.-therebyR'(. a chi eve'&#xfd;Icbe tter .*'ihan dlin gqualities.-I --Prouct may be batch removed by freely draining Nonhomogeneous :--feed &#xfd;,containing lumps of dryo*                                                  through a bottom outlet valve or by a screw conveyor, i                smidry',solids, i~tend - to .,&#xfd;compound the problem; by`?&;Howeve, depending upon the characteristics of the
  '        aglomeratingand fusing together instead of breaking 4i ' particulate matter, solids may adhere to the walls or the
  *        apartiy"Agglomerate's 'which are 'much larger. than'. the                                      a          s distribution plate. If excessive caking occurs, larger
  %:Monriginalparticle size subsequintly. tend to segregate out&#xfd;, :agglomerates may form that do not drain through f:the'bed *rAftera period of time,'the fluidized bed may* '-                                              niopeng in the exitvalve          -
      D'becomrei sstatic        1&.thereby Wnecessitating,-, shutdown-., and ",                                  .                       s:          '      "
                    nou s                                                                                                      er "ypes of outlets for continuous product
                                                                                              ':.  "          iremoval are: (1) a simple weir pernmtting overflow, (2) a iquidfeed nee~sitaies use of an injection nozzle'i                                    "flapper-type check valve to restrict gas flow through the wan 'atomizing 0gas &#xfd;The" liquid input system consists of k                                                      and (3) a seal leg with a solids flow control valve to
          -01), C,'sprayi.


to del~neaft hahnlques used by the staff in of the ConMleisU
.a          injection '-nozzle," (2)                    liquid chemical                  *"equalize external and internal pressures. In each case.
imcEeg omission.


Utdsington.
..,injectionj ,system, *and ,.(3) .a* , fluidizing gas 'system.ni ',,obstruction and accumulation as a result of inadequate
    ,'&#xfd;'; Injection&#xfd;'-nozzles have :'been shown to be a source o,                                          Wdesign may'result in large quantities of holdup material.


D.C. 2064A. ewsluating specific probtarm )r pastuketea acicidents or to provide guiance to Attention:
'*locahzed. cake .formation and holdup: Furthermore,
Chie. Public Proceeding Stae". eWlicalnts.
    *a'..'area .of -the' equipment directly across the'fluidized bed                                                        fses are discharged near'the top of a fluidized
        !, bopposltt,.the vnozzle'also'              &#xfd;Kb has'beerin-"shown-,16`b -                            ".bed reactor through a variety of components which are
            'susceptible,
                .,,.                          cake formationo An *                                .            sto;u.. 'of holdup. These include cyclones for dust i,. &#xfd;consequence            whch fu q*!iin ter fer enc&c!r4:,... f .'ck propags          hm          orenoval,                              carbon or sintered metal filters, and cold traps.


Regulatory Gui0im. Or
'              ':.`,ihJ,~o o rt
                                            .f            e      t no a.%operation' t Holdup in these. devices occurs to such an extent that it epositedoat"tthe bottom'of the fluidized                                *:is necessary to recover the solids which are carried by d-'.*d on ?'the *igas&#xfd;distribution:.plate'&sect;interferewith                                          s leaving the fluidized bed.


====a. not GulrleuteAS ====
::,-,"fluidization and may~cause localized hot spots. Also, t
for regulations wn4 compi~ance with themn isacnt *equlred.
          .',&#xfd;product ',&#xfd;overflow :tube may-become blocked. ,Typical                                          ,'.
                                                                                                                ..        One 'of the advantages of utilizing a fluidized bed is cauisesof this agglomeration are impurities in feed, fines*'i&#xfd;' 'Its favorable heat transfer performanc


Methodi a" toiutmons different from thineset at otai The gulds eam issued on the following oan broad divitions: ,the fluitsnwill beacceptaLle If they pro"id a hea for the findinresrortikiste Voi eotr the isuanenmor continuance of a prrwt5or Roomnsby the Commission.
====e. Unfortunately====
              "from-"the recovery!system,.poor.gas distri.                                                        from "the: viewpoint of mmizig holdup, heat
          ,;spray.&#xfd; nozzle operation, generally, poor fluidization, and`                                        exchanger tubes manifolded at the bottom and top or Aother unfavorable operating conditions.",*                        ,k;'                        '.bayonets              internal to the reactor are sometimes used.


I .P4e eatr .Products 2. Research and Too Reactors
. At
                      ' -""                              .                                                 '    Such use should be avoided where possible since it
            .' The.fluidized bhed ",chemical 'reactor'~syste            'may"'
                                                                              t                                    aggravates the problems of holdup and cleanout.


===7. Trmmsportetiofi ===
consst"~of~ne1 ot ,:several ,configurations. 'A series of                          ~ J"~~~~
3. Ftoes 9anld Malterials Facilities it. Occupational Health Published guides will be revsvpe' periodically.
            individ ual; reactorSasb            i wellas a ngle.reactor.wi th                                                            the absence of moving parts contnrbutes inddual*pcomacin                      e ttanbeien                          t      r                      icantgeneral iused        effective: cleanouts. For tall reactors.


as appropriate.
ubltiple 6ontactig:ta                        :, nfortusgately,.,iplO                   
* however,", or* for:'a mixture of fluidized solids with compartments as well as the series configuration provide&#xfd;                                          differentcharacteristics, mechanical mixing may be multipl l1cations' fodr holdutpii In either casea'.i sufficient..                                      tiized to reduce segregation. Without adeqate mixing, w          'of 'gasis necessarxy .toq forestall, plugging and                                  ;aigglomeration may. occur because 'of particle fusion or chann*elin                                                                                          poor dispersion of adhesive feed solids.


ta' accommivodate
'n, &#xfd;generali~poes~crdtoi~                                          lec~                                fi~"'con"toa                'atcegrowth
4. Envionmental and Siting 9. Anttitruti~
                                                                                                                                                                'size reduction in foratzon of holdupVarables whic~h'-yfldized.beds-:                                                                              contributes" to' the generation and formationtare'xnlet. gas composition ad velocbty;,bedis4,iubsequent deposition 'of fines. Major size reduction temperature -and depthi ;and feed miterial temperaturil. _Pmechanisms in fluid beds" ar attrition, impact, and and. ._consistiency .'.-The !;generationriof.. f'mes 'esped ally is'.&#xfd;Yg e rmal decrepitation. All three mechanisms produce.
Review commrents and to refleI= new infoirmation or esipaerinca.


6, Materials and Plant Postectio
deperident on the ioperating rangedof :process varablet2 &t,`fmes' which may contribute to holdup, especially in Buildup'of fines may. cause bridging of. solids 'inthe;;i filters or components downline from the fluidized bed reactor structure .In, addition,, deposition of substances * ._ reactor. Exceptionally fine particles may necessitate an on internal'surfaces."of the --reactor structure. and min._',.-"offgas cleanup system on-line rather than a complete
1 0. General 1 1 1 E
                                          *::. * ..*/ :*.*<```**&#xa3;
iii holdop also can enhance process operations by decreasing the extent and time of unit process inlerra)Lions for material accountability.
                                                      `i* .``* :.`***;.***.*    **z.`.: * * .*.&*,*''''.*:k',***:o;'5'83,*.*,.          ..


For example.
shutdown periodically. An alternative is to use an                        wails, covers, or other, means of containment to prevent internal fines filter.                                                      spilling or release of the contents during operation.


for ai ;rocess amenable to dynamic inventory techniques, credibility in such a technique may be increased by ;educing the detrimental effects of residual holdup on such an inventory.
. k The, feed material is properly prepared to nirnintatibni 'of: fli        b    ed act
                                                    66rs ?largil3    ~mn-mize the potential for holdup formation within a
            ~Of. "gtemperature and ...i pressure. snsor                    fluldized !bed. Also,- sizing.. operations ::,prior to IO&Pl,&#xfd;..,wells;,.and:1/2&#xfd;tressure,,t aps &#xfd;.are  otenHA          iAntroduction of particles are evaluated.',
                                                                                          The influence of operating variables such as gas
                                                                        *low.*.rate and: temperature Jis evaluated to reduce undesirable Tormation of holdup such as caking which
                                                                        .,may be induced by operating in an undesirable range of
                                                                              -            '.E pment *-has :.':minimum ",of 'internal
                                                                        .Rcomponents upon which process material can collect;
                                                                        tequipmento'is free from internal structural supports, flanges,;-&#xfd; support ..rings,-trays, or devices that are not iessential to operation.'i;.,-          ,.v-        :>,',          ,
                                                                                ,b-:Racks.,.carriages,"'conveyor*, guides, or drive
                                                                        -mechanisms that are used to assist or direct the transport
                                                                          .bOf --trays ,through ..a tray drier-are designed so that
                                                                        1'individual ;.trays :..cannot be tipped or ride over one
                                                                        , another. For: example,.: for ,.&#xfd;."walking-beam" drives,            -..
                                                                        !vertical travel is constrained to less than one-fourth the ei t of.the. tray to minimize the probability of tray
                                                                          *override;              ::Zi*.*- )
* are"
                                                                                                  .4-                                      to
                                                                            2-. .:,Mecharical          :agitat6ro are designed to permit
                                                                          01surfaces to drain freely and present minimum surface for collection of solids. !            !      '`.    .-.              .-
                                                                                  Sd,'ti  Sensing:, devices
                                                                                                        '      such .as thermocouples are tstalled in a manner that minimizes the amount of solid                          A
                                                                        *!material that can be retained by sensing devices.,.                              5
                                                                            -2? e.,,t,-Pressure taps projecting into the equipment'
                                                                        *'hve the capability for being gas purged.'
                                                                        *        f...Because of highly abrasive wear in fluldized
                                                                        'beds and potential for SNM retention on horizontal-
                                                                          *ielements and protection tubes, installation of internal
                                                                          ,telements, are positioned, for example vertical, to reduce'
                                                                          *surface erosion and holdup. Examples of such elements                        -
                                                                            may be sensing elements, bayonet heaters, mechanical mixers, and heat transfer fins.                      .. '
                                                                                  :g.*iPermanen tly ,,mounted              p~rocess 'equipment
                                                                          'nternals; that -cannot.. be removed for cleaning allow
                                                                          1-'rinsings and normal contents of vessels such as fluidized,
                                                                          'bed . driers ,-to *:drain, freely;: from the.. bottom: of the,...
                                                                                  ,h`;,&#xfd;Th6 iegt oth~disengaging section above the .-
                                                                            >expanded bed is adequate to reduce particle entrainment.


c. The effort required to establish the presence of and to remove residual material for a physical inventory is reduced. Consequently, the amount of time and the number of people who need access to SNM are reduced.
'which:',contnrbutes ; to! holdup .in :the. *offgas recovery
                                                                        * .teni'for the fluidized bed operatfons.-                      .*--'      .
                                                                          *        f,.Filters'and/or cyclones are provided above the','
                                                                        Rexpanded.bed to sepaiate elutriated particulates, fines, are1-1imt-u'cted ;'with" 'adeq uate ,strength.top&#xfd; ,.pclude                .and 1dust from'the exhaust gases. These are designed to".
-breakage and deteoration,              r &#xfd;M                        *.return accumulated solids to the bed; for example, filters S-*Tray s. in.tray' driersre ad~signednot toi tip np*              .,.are equipped with an automatic cyclic blowback feature, .
  spill, thecontents"-durng handling '.and' ope ration.- Fo                  or a.n external bin is designed to accumulate solids."                '    .
  exam~plew*hen fully :oade d,*the distance of the cente                          .,":;Cyclones,',are ,equipped: with suitable solids ogravityifrom 'any .side- is at cast four timies tsdisano          M:. retum":ines,*;-that .:.canbe, completely emptied.- for from the b6ottom othe  f                                        "P;9        draindown of the reactor.. ,.',                          :
        .il    le quipment ,in,- hic,* ha.:rat l is:'agitated                      ' ,Flow- ;control valves .and spray nozzles for
                .4        A      anit-Alltr vt 'PneIcvp wiith -td          feeding solutions to the fluidized bed are designed and
                                                                      !-.A.A      '.'...        .


The opportunity for unauthorized individuals to gain access to SNM during this stage of a physical inventory also may be reduced.
,*,'Installed to' mHnimize cake'
                                                  ror~ti. on......    th ozl or hn the equipment.


This guide is addressed mainly to two unit processes-drying and fluidized bed operations.
91        S 1;: Components mcias meal lega4 nd 'Penings hdob    .structo are.. designed
                                                  .....
                                          .. .. to.. minimie btrution by particulatamter;
                                                            niie
                                                            .
                                                                          vas"hain              4 DeSgn for Cleaou't Where Necessar a..-Driers ar. provided with access ports,
                                                                                                    .....
                                                                      ..accumulation' & removable.i: covers,&#xfd;<,
                                                                                        ?finspectfon of the internai surfaces.


The unit drying. operation is commonly applied to remove moisture, vapors, and/or solvent from a wet feed material to produce a dry. solid product. A unit operation for dewatering slurries normally precedes drying. Commercial applications of fluidized beds are manifold.
or. removable                    sides for visual g~~        Holes "drilled Tncal, `3o:              ',!.'tein perforated suppr'pe%
                                                                                                                                                      ..!II'-*?*::-*..:.: .
          1 7lca .,r . -oreduce*h,,
                        r          .edue                      ZI! ,*t~pates f,,
                                        h'earea of flat surfaces.on.which          ./ir          ,,.b.`,tAccess ports or removable panels are provded appropriatecamethods may stagnate and cake during react&#xfd;l
                                                                                              , ccaning for"
                                                                                            *tsuch internalv surfaces
                                                                                                      :as b rusing,                au umin& bywashin                                    pn o r u                                                                iTo.   .
      SuiduOf          th operation of~the bed lar-"ge  particles that cannot be drained                                            remove, dislodge, or dissolve SNM particles.--
        thereactor Isequipped with a gas-jet                                  readily,      - .... to Equipment Srnsing
                                                                                                                              ,iis provided .with grInder*,.-                  Tconnections          for washdown and rinsing with-fittings                        liquids that for
  *..ftorn t Preclude the  ve~essel  for'the    fluidized                                  :will  remove, accumulation bedmaterialhas a tapere          1                      dislndge, or dissolve all particulate process
    -'_sintered
          *:...*
            *,**,:SNM..... in*.cm cor'Oa  ers at the b ottr,, of;*.'-V.`,_,      such materia,_. ......
                                                                                          *;material, residua. iquid, and I'remtain on internal surfaces condensed vapors that may after the equipment has been
                                                                                        ,&#xfd;'shut
                                                                                                                                                                                          'ollectin g
                                                                                        ,Tnsings  I .N;    which SNMI"s InProvision                        entrained gma maydbe f-*and                   or dissolved. ..
....l'2i*
      "ondestructive'assay
            .. ... arance .                      :t4o permit,          next                -4 .*:Y.f,      multiple."stages .inh'fluidized bed
                                3 :-instruments or internal                                                                                                                        reactors
._&#xfd;'detectf the:preencebf:or                                             .pr                      empOY!surfonaceluha
.:-residual material not.visually to "identify          sb
                                                                'the loc
                                                                                                                'defflestio-baffles                              perforated ;gas p                              &#xfd;for.m&`Ing, and p~late'
                                                                                                                                      owcomers&#xfd;5t'-Pflanges b."`The2 bodyr,1,of t                                                                                                                                                                for
  !equipped with' vibrators"or                    fluidized'dea(                          baffles for, pairtitioning, external                                                                            these are accessible for cleanout.


Generally.
*7or prevent packing and adhesion of impactors to
    ' '. .,Extended ':heat                                                              M*        '.':Supplementa
                                                                                          ,.otpermanently.                        Interalmechanical equipment,..
                                                                                                                      mounted fins -and'tubesg                      "transfer" surfaces,.o ,r                      rinsers, or atomizers Inside such as scrapers,- agitators,
                :.'*i~~~i0for :both-heating
                                  "'~          ti g n co l                                                                            equipment is capable of being to th fluidizedibed containmenta"nd coolin'gare                  ae e3                disassembled and removed for cleaning and inspection Sourcef heat may be preheated                    structure.-An      alt              ibottom                                                                                                .;.
                                                                                                                            outlet                          d      to        facilitate d..Fgroun                                    inputs.;                                              and cleano'ut "                        .
                  idied! r,breed                      r                                lhaptleanu'.e. "io rn tprevenit build.-b up"0of. stat                                                                        ..          ...or"s:ut ch..                  material is used, to: prevent                                                            packing becoming encrusted, which may                  the bottom outlet from case.bdexpasO                    ndconsequent.:;"                                                                                    hinder bed-rmaterial during equipment the discharge of rei luidized cleanoutv';                                                          draindown and.'
                                                                                                                        .  .  ..        .....
                                                                                                                                                                  '.
                                                                                                                                            i .*.'                      .      :- ,-..:  ...
                                                                                                            ;IW4* 470
                                                                                                                                            4            :y : :.-,      .
                                                                                                                                  M-,
                                                                                                                                          --                        ''-      :7...
                                                                                                                                                                                  ..
                                                                                                                                          U.,*:.*..-.
                                                                                                                                            ,.,--.-.        ,..            ..
                                                                                                                    : Y.


the fluidized bed is used for gas-solid, gas-gas, or gas-liquid contacting to effect dewatering.
." .P* .
 
                                                                                5.8-5}}
drying, calcining, chemical reaction, or particle coating. Frequently, shutdown and/or draindown of process equipment used for drying or fluidized bed operations results in a substantial quantity of residual material held up in the equipment.
 
Consequently, design guidance is provided to facilitate minimizing holdup material in driers and fluidized bed equipment after shutdown and after draindown as well as after cleanout.
 
2. Holdup in Driers A variety of driers is used in nuclear fuel fabrication.
 
The holdup problems associated with each are peculiar to the state of the material being processed, the mode of operation, and particularly the specific type of drier.  With directly heated driers using a heated stream, fines may be entrained in the gas stream and must be collected in filters and recovered from the process. The entrainment contributes to holdup of fines in ductwork and filters. On the other hand. directly heated driers using infrared heat lamps are advantageous since entrainment then is minimal. Use of agitators in directly heated. driers may be desirable from an operating standpoint However, driers with agitators are difficult to empty and clean.
 
driers are desirable for a i,. gh-throu.0
put low-holdup operation.
 
This arises :rom a...cased continuity of operation and trcreawd w:iior,ni~y of material handling.
 
Continuous operations have the advantages of minimal physical !i.inJlinst as well as greater potential for process anitor.nlation.
 
For certain -processes, however, batch drying is advantageous.
 
With individual batches it is 'possible to maintain batch identity:
However, batch drieri require Smore physical handling of material than continuous driers, may be difficult t6 automate, and may ncessitate additional equipment cleanout between batches.
 
For directly heated fluid-bed driers and spray driers, there is a tendency for dry product to adhere to the walls and bottom of the drier, particularly if tht. product is very fine, Internal mechanical scrapers constitute an additional impediment to cleaning the drying chamber.
 
For indirectly heated driers in which the material being dried contacts a heated surface, sweep gas may be used to carry away the vapor from the drying solid.  Unless the exit velocity of this, vapor is lew, some material will be entrained in the gas and may be retained in ducts. Also, for indirectly heated continuous screw conveyor driers, as the feed drys to an adhesive paste it has a tendency to cake and choke off the flow or to spill out of the drier. Furthermore, the screw conveyor is difficult to: clean and tends to be a significant
..ource of holdup.  Rotary driers have been used to combine a drying operation with a calcining operation in separately heated zone
 
====s. Ah intermediate ====
'paste having a high bulk density and viscosity has a tendency to adhere to most materials which it contacts such as flight carriap surfaces.
 
Such surfaces contribute to holdup by impeding material flow during emptying.
 
Therefore, special attention may be necessary for cleanout or draindown.
 
Directly heated rotary driers also may be accompanied by carry over of dust or ultrafmne powder which becomes a form of holdup.  Woven metal belt driers have a high surface area and high porosity.
 
Consequently, they may be a significant source of material holdup.  Batch pan driers are completely enclosed and usually are equipped with agitators which constitute a source of material holdup upon emptying.
 
Agitators also cause more difficulty for a complete cleanout.
 
Continuous driers with open static beds such as pans, boats, or trays do not contribute significantly to holdup unless they are accidentally tipped or the contents are otherwise spilled. Trays. pans,: and boats also may be easy to empty and clean if necessary.
 
3. Holdup in Fluidized Bed Operations Because of the numerous interrelated components of a fluidized bed operation that contact the process material.
 
there exists a large number of locations where holdup may occur and numerous sources initiating its occurrence.
 
However, holdup in fluidized
'beds commonly depends upon the size and growth of particles throughout the system, Beginning with the 5.8-2 K K1
111ut, screw conveyors.
 
pneumatic carriers.
 
dip pipes.  .-ai iegs. injectors, or olhet means a-c used to introduce olids ilo the reactor proper. Difficulties with holdup .,rise :td special techniques become necessary when solids ate not free flowing, such as filtered precipitates and other moist solids. Since it is difficult by means of a screw conveyor to feed wet material to a reactor, it may be necessary to assist handling by wetting the material to attain a slurry consistency before feeding. If slurry consistency is undesirable for the material, the solid product may be recycled to mix with the feed to dry it and thereby achieve better handling qualities.
 
Nonhomogeneous teed containing lumps of dry or semidry solids tend to compound the problem by agglomerating and fusing together instead of breaking apart. Agglomerates which are much larger than the original particle size subsequently tend to segregate out of the bed. After a period of time, the fluidized bed may become static thereby necessitating shutdown and cleanout.
 
Liquid feed necessitates use of an injection nozzle and atomizing gas. The liquid input system consists of (I) a spray Injection nozzle, (2) a liquid chemical injection system, and (3) a fluidizing gas system.  Injection nozzles have been shown to be a source of localized cake formation and holdup. Furthermore, the area of the equipment directly across the fluidized bed opposite the nozzle also has been shown to be susceptible to cake formation.
 
An additional consequence which further propagates holdup formation is interference of cake with normal operation.
 
Agglomerates deposited at the bottom of the fluidized bed and on the gas distribution plate interfere with fluidization and may cause localized hot spots. Also, the product overflow tube may become blocked. Typical causes of this agglomeration are impurities in feed, fines from the recovery system, poor gas distribution, poor spray nozzle operation, generally poor fluidization, and other unfavorable operating conditions.
 
The fluidized bed chemical reactor system may consist of one of several configurations.
 
A series of individual reactors as well as a single reactor with individual compartments have been used to provide nmultiple contacting stages. Unforturiately, multiple compartments as well as the series configuration provide multiple locations for holdup. In either case, a sufficient flow rate of gas is necessary to forestall plugging and channeling.
 
In general, process conditions influence the formation of holdup. Variables which may induce this formation are inlet gas composit:on and velocity, bed temperature and depth. and feed material temperature and consistency.
 
TIh generationi of fines especially is depedntdc, on tlw operating range ,t process variables.
 
Buildup of fine" ,',uy cause bridpngt o; sotuds in the ,tea.jct itrutture.
 
Ii .iddiioiv.
 
ccpo:.l_ %) stl Stv.5falnces otn lnh'rnal of idi, reactot structure anid in ,.oiaiccting lines is sensitive to process variables such as temperature.
 
Severe operating coaitions such as temperature cxcursicns are particularvy conducive to severe segregation and packing of SNM against the base and interior walls; The existence of holdup may compound an excursion by its sudden release to the fluidized bed for reaction, which induces further excursion and additional resulting holdup by the mechanisms of packing and fusion.  Exiting material consists of product and offgases.
 
Product may be batch removed by freely draining through a bottom outlet valve or by a screw conveyor.
 
However, depending upon the characteristics of the particulate matter, solids may adhere to the walls or the gas distribution plate. If excessive caking occurs, larger agglomerates may form that do not drain through openings in the exit valve. Other types of outlets for continuous product removal are: (1) a simple weir permitting overflow, (2) a flapper-type check valve to restrict gas flow through the exit, and (3) a seal leg with a solids flow control valve to equalize external and internal pressures.
 
In each case.  obstruction and accumulation as a result of inadequate design may result in large quantities of holdup material.
 
Offgases are discharged near the top of a fluidized bed reactor through a variety of components which are sources of holdup. These include cyclones for dust removal, carbon or sintered metal filten, and cold traps.  Holdup in these devices occurs to such an extent that it is necessary to recover the solids which are carried by gases leaving the fluidized bed.  One of the advantages of utilizing a fluidized bed is its favorable heat transfer performance.
 
Unfortunately from the viewpoint of minimizing holdup, heat exchanger tubes manifolded at the bottom and top or bayonets internal to the reactor are sometimes used.  Such use should be avoided where possible since it aggravates the problems of holdup and clsanout.
 
In general, the absence of moving parts contributes significantly to effective cleanouts.
 
For tall reactors, however, or for a mixture of fluidiLed solids with different characteristics, mechanical mixing may be utilized to reduce segregation.
 
Without adequate mixing, agglomeration may occur because of particle fusion or poor dispersion of adhesive feed solids.  In contrast to particle growth. si e reduction in fluidi/ed beds contributes to the generation and sub'cqeient deposition of fines. Major size reduction mechanisms in fluid beds are attrition, impact, and .hetmal decrepitation.
 
All three mechanisms produce t1nes whikih may coTribute to holdup. especially in Alltes or downhine from the fluidized bed rca.,to'.
ExceptionJlty fine particles may necessitate an oITgxs '-!Canup system on-line rather than a complete i1-1 shutdown periodically.
 
An alternative is to use an internal tines filter.  li.strumentation of fluid bed reactors largely of temperature and pressure sensors.
 
Thermocouple wells and pressure taps are potential locations for retaining SNM during shutdown and draindown.
 
C. REGULATORY
POSITION For purposes of facilitating (i) control of SNM during processing or use, including shutdown, draindown.
 
and cleanout, (2) determination of process losses by lessening the magnitude of the contribution of residual holdup to process losses, and (3) performance of a physical inventory, which may include an uncertainty component due to residual holdup, it is appropriate to minimize the amount of SNM retained inside equipment as residual holdup. The design of equipment used to carry out physical or chemical changes on SNM by drying or fluidized bed operations should include an evaluation of the desirability of incorporating features for purposes of minimizing residual holdup after shutdown, after draindown, and after cleanout.
 
Appropriate features acceptable to the Regulatory staff for consideration include the following:
1. General Design a. Surfaces are free from crevices, cracks, protrusions, and other irregularities that could entrap material.
 
b. Overlapping metal surfaces in contact with process material are sealed by welding; internal welds are ground flush with inner surfaces.
 
c. The internal angles and corners, particularly in tray driers, are rounded -with a radius larger than a minimum radius, for example, one fourth inch.  d. Seams that promote corrosion are absent.  e. Materials of construction that contact SNM are compatible with the contents so that surfaces do not corrode, dissolve, or erode during operation or during contact with rinse solutions used for cleaning after shutdown.
 
f. Surfaces that contact SNM are selected, coated, polished or machined to prevent or resist the adherence of liquids and solids.  g. Structural integrity is adequate to resist formation of leaks, cracks, and crevices due to localized stresses such as thermal and vibratory stresses during operation.
 
h. Containers, for example, boats, pans. and trays, are constructed with adequate strength to preclude breakage and deterioration.
 
i. Trays iii tray driers are designed not to tip and spill the contents during handling and operation.
 
For example. when tully loaded, the distance of the center of gravity from any -ide is at least foul times its distance from Ihe bottom of e irav j. All equipment in wlhd, is agitated.
 
sprayed, or removed mechanically is enclosed with side walls, covers, or other means of containment to prevent spilling or release of the contents during operai ion.  k, The feed material is properly prepared to minimize the potential for holdup formatiov, within a fluidized bed. Also, sizing operations prior to introduction of particles are evaluated.
 
I. The influence of operating variables such as gas flow rate and temperature is evaluated to reduce undesirable formation of holdup such as cak'ng which may be induced by operating in an undesirable range of operating conditions.
 
2. Internal Design a. Equipment has a minimum of internal components upon which process material cen collect; equipment is free from internal structural supports, flanges, support rings, trays, or devices that are not essential to operation.
 
b. .Racks, carriages, conveyors, guides, or drive mechanisms that are used to assist or direct the transport of trays through a tray drier are designed so that individual trays cannot be tipped or ride over one another. For example, for "walking-beam" drives, vertical travel is constrained to less than one-fourth the height of the tray to minimize the probability of tray override.
 
c. Mechanical agitators are designed to permit surfaces to drain freely and present minimum s irface for collection of solids.  d. Sensing devices such as thermocouples are installed in a manner that minimizes the amount of solid material that can be retained by sensing devices.
 
e. Pressure taps projecting into the equipment have the capability for being gas purged.  .Because of highly abrasive wear in fluidized beds and potential for SNM retention on forizontal elements and protection tubes, installation of internal elements are positioned, for example vertical, to reduce surface erosion and holdup. Examples of such elements may be sensing elements, bayonet heaters, mechanical mixers, and heat transfer fins.  g. Permanently mounted process equipment internals that cannot be removed for cleaning allow rinsing% and normal contents of vessels such as fluidized bed driers to drain freely from the bottom of the equipment.
 
h. The height of the disengaging section above the expanded bed is adequate to reduce particle entrainment which contributes to holdup in the offgas recovery system for the fluidized bed operations.
 
i. Filters and/or cyclones are provided above the expanded bed to separate elutriated particulates, fines.  and dust from the exhaust gases. These are designed to return accumulated solids to the bed; for example, filters arc equipped with an automatic cyclic blowback feature, or an external bin is designed to accumulate solids.  ;. Cyclones are .equipped with suitable solids return hiues that can be completely emptied for drainmtown of the reactor.
 
k. Flow *..ontrol valves and spray no%.zles for feeding solutions to the fluidized bed are designed and" 5.8-4 I\
installed to minimize cake formation on the nozzle or within the equipment.
 
I. Components such as seal legs and valves having fixed openings are designed to minimize accumulation and obstruction by particulate matter.  m. Holes drilled in perforated support plates are conical to reduce the area of flat surfaces on which solids may stagnate and cake during reaction.
 
n. If the operation of the bed can result in the buildup of large particles that cannot be drained readily, the reactor is equipped with a gas-jet grinder.
 
o. The vessel for the fluidized bed has a tapered bottom to preclude the accumulation of material such as sintered SNM in comers at the bottom.  3. External Design a. Clearance is provided to permit external use of nondestructive assay instruments or internal probes to detect the presence of or to identify the location of residual material not visually accessible.
 
b. The body of the fluidized bed reactor is equipped with vibrators or external impactors to reduce or prevent packing and adhesion of SNM.  c. Extended heat transfer surfaces, for example fins and tubes, for both heating and cooling are external to the fluidized bed containment structure.
 
An alternate source of heat may be preheated inputs.  d. Fluidized bed structures are electrically grounded to prevent buildup of static charge which causes bed expansion and consequent occurrence of holdup.4. Design for Cleanout Where Necessary a. Driers are provided with access ports, removable covers, or removable sides for visual inspection of the internal surfaces.
 
b. Access ports or removable pane s are provided for cleaning internal surfaces by appropriate methods such as brushing, vacuuming, washing. scraping, or rinsing to remove, dislodge, or dissolve SNM particles.
 
c. Equipment is provided with fittings for connections for washdown and rinsing with liquids that will remove, dislodge, or dissolve all part culate process material, residual liquid, and condensed vupors that may remain on internal surfaces after the equil ment has been shut down.  d. Provision is made for draining and collecting rinsings in which SNM may be entrained or dissolved.
 
e. If multiple stages in fluidized bed reactors employ horizontal surfaces such as perforated gas distributor plates, downcomers, flanges for segmentation, deflection baffles for mixing, and plate baffles for partitioning, these are accessibl.-
for cleanout.
 
f. Supplementary internal mechanii:a equipment not permanently mounted such as scrapers, agitators, rinsers, or atomizers inside equipment is capable of being disassembled and removed for cleaning and inspection.
 
g. A bottom outlet is provided to facilitate draindown and deanout.
 
h. A gas plenum region or sui.ble packing material is used to prevent the bottom outlet from becoming encrusted, which may hinder the discharge of fluidized bed material during equipment draindown and cleanout.
 
5.8-5 I II}}


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Latest revision as of 23:32, 4 November 2019

Design Considerations for Minimizing Residual Holdup of Special Nuclear Material in Drying and Fluidized Bed Operations
ML13038A435
Person / Time
Issue date: 06/30/1973
From:
Office of Nuclear Regulatory Research
To:
References
RG-5.008
Download: ML13038A435 (5)
v • d • e


June 1973 U.S. ATOMIC ENERGY COMMISSION

R EGU LATO.RY GU I D E

IDIRECTORATE i:.OF REGULATORY STANDARDS

Il - NIPt4 GI1015.8 Rm

!"DESIGN CONSIDERATIONS FOR MINIMIZING RESIDUAL HOLDUP

-CIALNUCLEARMATERIAL IN DRYING AND FLUIDIZED BED OPERATIONS.

iNTROUCTION~"'=505 ldi, or hidden inventory. A characteristic amount of

'Wmateal that is difficult to locate, sample, identify, o.22 -"Cbiiitets 6r'applications,"'of'Io0, !quantify, and analyze is held up in equipment for a given

.I:SpeCial
applicationfor Nuclear Material,";requires," indg;

alicenseto design, mode of operation, and type of process material.

possess certainri , :I'This holdup may be decreased as the status of the special nuclear material (SNM) contain a *:equipment changes progressively through the four stages i of the applicant's procedures for control: *consisting, of operation, shutdown, draindown, and inting;.for.: SNMWTwhichý,will.be, in ..hi! !,Siý,:cleanout.. Simultaneously, the number of sources of ider ;license,':ý!.including'-`procedureso uncertainty and the levels of uncertainty in the physical

4M .during its '.processing.,,or, use- in -the:ii inventory may be reduced.-. ..

procedures' by which' proces'losses are -....... '.

quihermore; Section','nth'.51fo"rm ,':*'q;*,,,.tý. e' ofnventory

"relation ui of SNM in process equipment in quirements,".requires;in pa rt; that certain the form of residual holdup following shutdown, iduct"<' at ;specified intervals *,;physical draindown, and cleanout could have adverse effects on a

.the NM i their possession under license. 4t'ý materials control program. Minimizing that quantity of if.and .accounting for SNM can be'made'.ý- -ýmaterial retained in process equipment enhances the

'tby minimizing the residual holdup after *A.effectiveness of a materials protection program in the er.; draindowni and after cleanout of the - following wy"

A'.'4t0oprocess SNM,'thereby reducing the' followin'gway: ,,

.. ..Uncertai...'..ontributed. residual,,,,,,. aý.,. Te quality of a physical inventory is improved

4it ne'Vy'reducing y uncertainty due to holdup. For example, issociated:

..

. . with

....

.rý',.. determination

. .,'j:

'd. . :of ..residual !* *t the heAcontribution n r b t o off uunmeasured m a u r d hholdup l u material a ei l tto the h Se:re gulatry i;ide',describes".,ý'acceptable6-,; icategory of material unaccounted for (MUF) may be sand characteristics 'for. minimizing thel -lessened,:' and, the influence of uncertainty associated Ipof-.'SNM -fluidized bed gwith 'in'dryiri"id measured holdup on the limit of error on material er shutdown;'.draindown,' or cleanout in'*- unaccounted for (LEMUF) in a material balance may be itate', material 'control and accountability~fll lessened. Furthermore,. the extent to which the hese 'features and characteristics are not-:*. eruncertainty ,;in.. holdup contributes to a physical terfere with process operations.-K i 'ý,inventory depends on the magnitude of the amount

, - ,,  : present and how precisely and accurately that amount is B.amenableOto**,B

'DISCUSSION being measured. Therefore, reducing the q..uantityof holdup directly decreases the uncertainty

. . ..contributed to a physical inventory.

amt~ pr'esses'*permit~~accu laton ,,,o ,h b.'A reduction in the quantity of holdup material s'iN which are referred to as residual'  ;.

ts o

..........

.*,,1

. SNM~ -....

.. * shutdown, drain down.-.following tmustbe:recovered. and cleanoutthe three of stages processof

  • j~j;,This Is a qw umtlty exceeedla-uan yor tltni, mo s 'equipment decreases the quantity of SNM susceptible to i6ontained Vurani urn' f23S'fouraniuim;233*,*,itor plutoniumtor,.. any..the diversion during sampling, identification, and subsequent

'combination'" thuclei"eaciorlicensed pursuaatitoi 1 CtFeRPartan separation .'.or: recycle of this material as may be operation of 'n

50 brfasiealed 3tOur.re*,, !necessary to complete a physical inventor

y. A reduction

'USAEC EGULATOCopUies of published gulidemay be obtained by request Indicating the divisions

~ ,~ *~,&"y~desired to the US. Atomic Energy Commission. Washington. D.C. 20545, Reuaoy'udsae'sud tdecbendrk ailbtthpulc Attention: Director of Regulatory Standardls. Comments en suggestions for methds ace oteACRgltrrtf

4able fIpeetn pcfcprso K im'provemnentt In theseguides are encouraged and should be gent to the Secretary the Commission's regulations, to delineate techniques used by the staff In' kOf the Commissuion, U.S. Atomic Energy Commisusion. Washington, D.C. 20645.

evaluating tpeciflc problems or postulated accidents, or to provide guidance to Attention: Chief. Public Proceedings Staff.

applicants. Regulatory Guides era not substitutes for regulations and compliaAce Z .... -

) with -them is not required. Methods and solutions diffternt from those set out in the guides will be accoptable if they provide a basis for the findings requisite to the issuance or continuance of apermit or iicensa by the Commission.

7. .

-

""

'

'1.

'2.

The guides ae IssuedIn the following ton brood visions:

Power Reacto ' '

Research andTest Reactors

'.

3. Fuels and Materials Facilities Producu

7. Traneportation I. Occupational Heatth Publishe gudes will be revse perlodcally,*asappropriate, to aoenmmodate ,; 4. Environmental and Siting 9. Antitf it Review comments andto reflect new Inforrmation or eXperience. -.. .

t:ta n lP.0 en

in holdup also can enhance process operations by For certain processes, however, batch drying is decreasing the extent and time of., unit, process advantageous. With individual batches it is possible to innterruptions for material accountabllity. For example. imaintain batch identity. However, batch driers require jfor a process amenable to dynamic inventory techniques, ,,more physical handling of material than continuous icredibility'.In" such .a '.technique may be. increased by; driers, may be difficult to automate, and may necessitate

ducingthe;detrimental effects of residual holdup on iadditional equipment cleanout between batches.

c an invent o, Wy*** SFor' directly heated fluid-bed ders and spray driers, effort requnIredo"stablish the presence of an :io.remove residual material for a physical inventor"" 't re is a tendency for dry product to adhere to the Ws:ireduced "Consequently, '.the amount of time and thei ,walls and bottom of the drier, particularly if the product Thme: of people who need access to SNM are reduced.' is very fine. Internal mechanical scrapers constitute an The,'opp ortunity..rfor unauthorized .individuals to gain 4additional Impediment to cleaning the drying chamber.

Sccess to SNM during this stage of a physical Inventory, l"iso ninv he retplme J.A *) -ski3.

h1, ri~ 'i,'*: , ,. 6T id,,i*I ndirectly heated driers inwhich 'the material being dried contacts a heated surface, sweep gas may be

,.used to carry away the vapor from the drying solid.

ýýUnless the exit .velocity, of this vapor is low, some

4:material will be entrained in the gas and may be retained Jin: ducts. :'Also,: for indirectly heated continuous screw

'conveyor driers, as the feed drys to an adhesive paste It

!has a tendency to cake and choke off the flow or to spill jout. of the drier. Furthermore,-. the screw, conveyor is idifficult to clean and tends to be a significant source of

ýholdup.-`'f`:';

(.7,'Rotary driers have been used to combine a drying

.peration with a calcining operation in separately heated
zones. An intermediate paste having a high bulk density and viscosity has a tendency to adhere to most materials.

which it contacts such as flight carriage surfaces. Such'

surfaces contribute to holdup by impeding material flow

",during emptying. Therefore, special attention, may be

  • £necessary for cleanout or draindown. Directly heated r'.7otary driers also may be accompanied by carry over of

£1

,`,dust or ultrafine powder which becomes a form of

  • !!Woven metal belt driers have a high surface area and high porosity. Consequently, they may be a significant:

~,source of material holdup. .;,

.,-, Batch *,'pan driers are completely enclosed and

inif a' bnt'ainei .';.the ýgas l'steam and must be, rlsuaUy are equipped with agitators which constitute a collected 'ri:filtersand recovered from the process. The, source'of material holdup upon emptying. Agitators also entrainment hcontrbutes'to holdup' of, fines in ductwork" Scauseg~more,,,difficulty,". for a ,*,complete.,, cleanout.

and Wfiters.'!Oný itihie ',bthfer':,,!hand;:,dirctlyv1heated dr..ieriý -Continuous. driers'.with open :static beds such as pans, usinfi*i*i ea lap ps %are:advaniageous'*sin **? .boats, ,or trays. do not contribute significantly to holdup entrainýmifent the':niis'irnimal.'Useý':of agitators in' diictll3 .inless"'they are accidentally tipped -or the contents are'.

heated driers 1rmay'.:..be:,'.desirable',,,from ".",an"',ioperating ,otherwise Spilled.' Trays` pans, and boats also may be.,

standpoint However,'.;'driers with agitators are difficult to j..easy to empty and clean if necessary.:

empty and clean '.". ',, "" ' i' ' ' *. ..-

!3;,Holdupn'iFluidized Bed Operations

! Because. of the numerous interrelated components high.thioughput si".low-holduip.i* ope6ration. :*,This '~;arises ofa fluidized bed operation that contact the process largely*!,from .:incrieased :;continuity iof 'operation :iand in creased'unimiforrnity! offmat erial handling.' Continuous rmaterial, there 'exists a large number of locations where operatioi~.have;the:' advant agers of ,firinimaphysica1 holdup may occur and numerous sources initiating its

,.,occurrence.".'.';,However,' holdup in fluidized beds handlin"'aw*el as'sgreate** r potential. for*,*i process `commonly '.depends upon .the 'size and growth of automation - '. 'ý;%ýparticles throughout the syste

m. I Beginning with the

!;.**:*:,-.i**!..* **.**::,/ ..*. . .:..,.

input, screw conveyors, pneumatic carriers, dip pipes, connecting lines is sensitive to process variables such as seal legs, injectors, or other means are used to introduce temperature. Severe . operating conditions such as solids into, the reactor proper. Difficulties with holdup temperature excursions are particularly conducive to arise and :speclal '.techniques become "necessary when , severe segregation and packing of SNM against the base sol:dsare

1 not free flowing, such as filtered precipitates' .ý'.and interior walls. The existence of holdup may and other moist solids. Since it is difficult by means of ag,-gi. compound an excursion by its sudden release to the

  • screw conveyor to feed wet material to a reactor, it may ¢fluidized -bed for reaction, which induces further be necessary to assist handling by wetting the material t excursion and additional resulting holdup by the i~iattainý.a>,slurry,! consistency be fore feeding.-JIf $1urrr'5,0,Itmechanisms of packing and fusion..

V' 2.conststency.,dts `iundesirable for the'material,, the solieh of packing and fusion.

Tproduct may.be recycled to mix with the feed to dry txl AVeral i fses acheve~~eterjhanlinRL-Exiting materil consists of product and offgass and~herby.

iand*.-therebyR'(. a chi eve'ýIcbe tter .*'ihan dlin gqualities.-I --Prouct may be batch removed by freely draining Nonhomogeneous :--feed ý,containing lumps of dryo* through a bottom outlet valve or by a screw conveyor, i smidry',solids, i~tend - to .,ýcompound the problem; by`?&;Howeve, depending upon the characteristics of the

' aglomeratingand fusing together instead of breaking 4i ' particulate matter, solids may adhere to the walls or the

  • apartiy"Agglomerate's 'which are 'much larger. than'. the a s distribution plate. If excessive caking occurs, larger

%:Monriginalparticle size subsequintly. tend to segregate outý, :agglomerates may form that do not drain through f:the'bed *rAftera period of time,'the fluidized bed may* '- niopeng in the exitvalve -

D'becomrei sstatic 1&.thereby Wnecessitating,-, shutdown-., and ", . s: ' "

nou s er "ypes of outlets for continuous product

':. " iremoval are: (1) a simple weir pernmtting overflow, (2) a iquidfeed nee~sitaies use of an injection nozzle'i "flapper-type check valve to restrict gas flow through the wan 'atomizing 0gas ýThe" liquid input system consists of k and (3) a seal leg with a solids flow control valve to

-01), C,'sprayi.

.a injection '-nozzle," (2) liquid chemical *"equalize external and internal pressures. In each case.

..,injectionj ,system, *and ,.(3) .a* , fluidizing gas 'system.ni ',,obstruction and accumulation as a result of inadequate

,'ý'; Injectioný'-nozzles have :'been shown to be a source o, Wdesign may'result in large quantities of holdup material.

'*locahzed. cake .formation and holdup: Furthermore,

  • a'..'area .of -the' equipment directly across the'fluidized bed fses are discharged near'the top of a fluidized

!, bopposltt,.the vnozzle'also' ýKb has'beerin-"shown-,16`b - ".bed reactor through a variety of components which are

'susceptible,

.,,. cake formationo An * . sto;u.. 'of holdup. These include cyclones for dust i,. ýconsequence whch fu q*!iin ter fer enc&c!r4:,... f .'ck propags hm orenoval, carbon or sintered metal filters, and cold traps.

' ':.`,ihJ,~o o rt

.f e t no a.%operation' t Holdup in these. devices occurs to such an extent that it epositedoat"tthe bottom'of the fluidized *:is necessary to recover the solids which are carried by d-'.*d on ?'the *igasýdistribution:.plate'§interferewith s leaving the fluidized bed.

,-,"fluidization and may~cause localized hot spots. Also, t

.',ýproduct ',ýoverflow :tube may-become blocked. ,Typical ,'.

.. One 'of the advantages of utilizing a fluidized bed is cauisesof this agglomeration are impurities in feed, fines*'iý' 'Its favorable heat transfer performanc

e. Unfortunately

"from-"the recovery!system,.poor.gas distri. from "the: viewpoint of mmizig holdup, heat

,;spray.ý nozzle operation, generally, poor fluidization, and` exchanger tubes manifolded at the bottom and top or Aother unfavorable operating conditions.",* ,k;' '.bayonets internal to the reactor are sometimes used.

. At

' -"" . ' Such use should be avoided where possible since it

.' The.fluidized bhed ",chemical 'reactor'~syste 'may"'

t aggravates the problems of holdup and cleanout.

consst"~of~ne1 ot ,:several ,configurations. 'A series of ~ J"~~~~

individ ual; reactorSasb i wellas a ngle.reactor.wi th the absence of moving parts contnrbutes inddual*pcomacin e ttanbeien t r icantgeneral iused effective: cleanouts. For tall reactors.

ubltiple 6ontactig:ta  :, nfortusgately,.,iplO

  • however,", or* for:'a mixture of fluidized solids with compartments as well as the series configuration provideý differentcharacteristics, mechanical mixing may be multipl l1cations' fodr holdutpii In either casea'.i sufficient.. tiized to reduce segregation. Without adeqate mixing, w 'of 'gasis necessarxy .toq forestall, plugging and ;aigglomeration may. occur because 'of particle fusion or chann*elin poor dispersion of adhesive feed solids.

'n, ýgenerali~poes~crdtoi~ lec~ fi~"'con"toa 'atcegrowth

'size reduction in foratzon of holdupVarables whic~h'-yfldized.beds-: contributes" to' the generation and formationtare'xnlet. gas composition ad velocbty;,bedis4,iubsequent deposition 'of fines. Major size reduction temperature -and depthi ;and feed miterial temperaturil. _Pmechanisms in fluid beds" ar attrition, impact, and and. ._consistiency .'.-The !;generationriof.. f'mes 'esped ally is'.ýYg e rmal decrepitation. All three mechanisms produce.

deperident on the ioperating rangedof :process varablet2 &t,`fmes' which may contribute to holdup, especially in Buildup'of fines may. cause bridging of. solids 'inthe;;i filters or components downline from the fluidized bed reactor structure .In, addition,, deposition of substances * ._ reactor. Exceptionally fine particles may necessitate an on internal'surfaces."of the --reactor structure. and min._',.-"offgas cleanup system on-line rather than a complete

  • . * ..*/ :*.*<```**£

`i* .``* :.`***;.***.* **z.`.: * * .*.&*,*'.*:k',***:o;'5'83,*.*,. ..

shutdown periodically. An alternative is to use an wails, covers, or other, means of containment to prevent internal fines filter. spilling or release of the contents during operation.

. k The, feed material is properly prepared to nirnintatibni 'of: fli b ed act

66rs ?largil3 ~mn-mize the potential for holdup formation within a

~Of. "gtemperature and ...i pressure. snsor fluldized !bed. Also,- sizing.. operations ::,prior to IO&Pl,ý..,wells;,.and:1/2ýtressure,,t aps ý.are otenHA iAntroduction of particles are evaluated.',

The influence of operating variables such as gas

  • low.*.rate and: temperature Jis evaluated to reduce undesirable Tormation of holdup such as caking which

.,may be induced by operating in an undesirable range of

- '.E pment *-has :.':minimum ",of 'internal

.Rcomponents upon which process material can collect;

tequipmento'is free from internal structural supports, flanges,;-ý support ..rings,-trays, or devices that are not iessential to operation.'i;.,- ,.v-  :>,', ,

,b-:Racks.,.carriages,"'conveyor*, guides, or drive

-mechanisms that are used to assist or direct the transport

.bOf --trays ,through ..a tray drier-are designed so that

1'individual ;.trays :..cannot be tipped or ride over one

, another. For: example,.: for ,.ý."walking-beam" drives, -..

!vertical travel is constrained to less than one-fourth the ei t of.the. tray to minimize the probability of tray

  • override;  ::Zi*.*- )
  • are"

.4- to

2-. .:,Mecharical :agitat6ro are designed to permit

01surfaces to drain freely and present minimum surface for collection of solids. !  ! '`. .-. .-

Sd,'ti Sensing:, devices

' such .as thermocouples are tstalled in a manner that minimizes the amount of solid A

  • !material that can be retained by sensing devices.,. 5

-2? e.,,t,-Pressure taps projecting into the equipment'

  • 'hve the capability for being gas purged.'
  • f...Because of highly abrasive wear in fluldized

'beds and potential for SNM retention on horizontal-

  • ielements and protection tubes, installation of internal

,telements, are positioned, for example vertical, to reduce'

  • surface erosion and holdup. Examples of such elements -

may be sensing elements, bayonet heaters, mechanical mixers, and heat transfer fins. .. '

g.*iPermanen tly ,,mounted p~rocess 'equipment

'nternals; that -cannot.. be removed for cleaning allow

1-'rinsings and normal contents of vessels such as fluidized,

'bed . driers ,-to *:drain, freely;: from the.. bottom: of the,...

,h`;,ýTh6 iegt oth~disengaging section above the .-

>expanded bed is adequate to reduce particle entrainment.

'which:',contnrbutes ; to! holdup .in :the. *offgas recovery

  • .teni'for the fluidized bed operatfons.- .*--' .
  • f,.Filters'and/or cyclones are provided above the','

Rexpanded.bed to sepaiate elutriated particulates, fines, are1-1imt-u'cted ;'with" 'adeq uate ,strength.topý ,.pclude .and 1dust from'the exhaust gases. These are designed to".

-breakage and deteoration, r ýM *.return accumulated solids to the bed; for example, filters S-*Tray s. in.tray' driersre ad~signednot toi tip np* .,.are equipped with an automatic cyclic blowback feature, .

spill, thecontents"-durng handling '.and' ope ration.- Fo or a.n external bin is designed to accumulate solids." ' .

exam~plew*hen fully :oade d,*the distance of the cente .,":;Cyclones,',are ,equipped: with suitable solids ogravityifrom 'any .side- is at cast four timies tsdisano M:. retum":ines,*;-that .:.canbe, completely emptied.- for from the b6ottom othe f "P;9 draindown of the reactor.. ,.',  :

.il le quipment ,in,- hic,* ha.:rat l is:'agitated ' ,Flow- ;control valves .and spray nozzles for

.4 A anit-Alltr vt 'PneIcvp wiith -td feeding solutions to the fluidized bed are designed and

!-.A.A '.'... .

,*,'Installed to' mHnimize cake'

ror~ti. on...... th ozl or hn the equipment.

91 S 1;: Components mcias meal lega4 nd 'Penings hdob .structo are.. designed

.....

.. .. to.. minimie btrution by particulatamter;

niie

.

vas"hain 4 DeSgn for Cleaou't Where Necessar a..-Driers ar. provided with access ports,

.....

..accumulation' & removable.i: covers,ý<,

?finspectfon of the internai surfaces.

or. removable sides for visual g~~ Holes "drilled Tncal, `3o: ',!.'tein perforated suppr'pe%

..!II'-*?*::-*..:.: .

1 7lca .,r . -oreduce*h,,

r .edue ZI! ,*t~pates f,,

h'earea of flat surfaces.on.which ./ir ,,.b.`,tAccess ports or removable panels are provded appropriatecamethods may stagnate and cake during reactýl

, ccaning for"

  • tsuch internalv surfaces
as b rusing, au umin& bywashin pn o r u iTo. .

SuiduOf th operation of~the bed lar-"ge particles that cannot be drained remove, dislodge, or dissolve SNM particles.--

thereactor Isequipped with a gas-jet readily, - .... to Equipment Srnsing

,iis provided .with grInder*,.- Tconnections for washdown and rinsing with-fittings liquids that for

  • ..ftorn t Preclude the ve~essel for'the fluidized :will remove, accumulation bedmaterialhas a tapere 1 dislndge, or dissolve all particulate process

-'_sintered

  • ...*
  • ,**,:SNM..... in*.cm cor'Oa ers at the b ottr,, of;*.'-V.`,_, such materia,_. ......
  • material, residua. iquid, and I'remtain on internal surfaces condensed vapors that may after the equipment has been

,ý'shut

'ollectin g

,Tnsings I .N; which SNMI"s InProvision entrained gma maydbe f-*and or dissolved. ..

....l'2i*

"ondestructive'assay

.. ... arance . :t4o permit, next -4 .*:Y.f, multiple."stages .inh'fluidized bed

3 :-instruments or internal reactors

._ý'detectf the:preencebf:or .pr empOY!surfonaceluha

.:-residual material not.visually to "identify sb

'the loc

'defflestio-baffles perforated ;gas p ýfor.m&`Ing, and p~late'

owcomersý5t'-Pflanges b."`The2 bodyr,1,of t for

!equipped with' vibrators"or fluidized'dea( baffles for, pairtitioning, external these are accessible for cleanout.

  • 7or prevent packing and adhesion of impactors to

' '. .,Extended ':heat M* '.':Supplementa

,.otpermanently. Interalmechanical equipment,..

mounted fins -and'tubesg "transfer" surfaces,.o ,r rinsers, or atomizers Inside such as scrapers,- agitators,

.'*i~~~i0for :both-heating

"'~ ti g n co l equipment is capable of being to th fluidizedibed containmenta"nd coolin'gare ae e3 disassembled and removed for cleaning and inspection Sourcef heat may be preheated structure.-An alt ibottom .;.

outlet d to facilitate d..Fgroun inputs.; and cleano'ut " .

idied! r,breed r lhaptleanu'.e. "io rn tprevenit build.-b up"0of. stat .. ...or"s:ut ch.. material is used, to: prevent packing becoming encrusted, which may the bottom outlet from case.bdexpasO ndconsequent.:;" hinder bed-rmaterial during equipment the discharge of rei luidized cleanoutv'; draindown and.'

. . .. .....

'.

i .*.' .  :- ,-..: ...

IW4* 470

4 :y : :.-, .

M-,

-- - :7...

..

U.,*:.*..-.

,.,--.-. ,.. ..

Y.

." .P* .

5.8-5


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